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    Opatija, April 28th 29th, 2011 Ductile iron cored wire process O. BAHUON 1

    Technical overview of Cored WireTechnical overview of Cored Wire

    for Ductile Iron treatmentfor Ductile Iron treatment

    ElFiCastElFiCast

    Cored wire for iron foundriesCored wire for iron foundries

    11th International foundrymenconference

    Croatia, Opatija, April 28 29, 2011

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    Brief history of Cored Wire processBrief history of Cored Wire process

    The cored wire was introduced in the 1980s, first in the steelindustry, as a simple and economical way to introduce anyelement of addition or treatment in deep ladles of liquid metal.

    The advantage of this method was quickly understood andapplications for the treatment of ductile iron was developed.

    Several types of applications exist today in the elaboration of

    ductile iron, cored wire can be used for desulfurization, for thetreatment of spheroidization, for inoculation in ladle or even

    just before pouring, and some others applications linked tospecific requirements.

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    Opatija, April 28th 29th, 2011 Ductile iron cored wire process O. BAHUON 3

    Focus on theFocus on the

    Nodularization of the ductile iron graphiteNodularization of the ductile iron graphite

    Difficulties

    => Introduce the magnesium (boiling

    temperature at 1090 C) in liquidiron at 1450 C

    => Limited sobubility of magnesium inthe liquid iron

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    Opatija, April 28th 29th, 2011 Ductile iron cored wire process O. BAHUON 4

    Metallurgical High Consistency

    No Risk of Human Error

    Cost Automation

    High Productivity

    Health & Safety Safe Use of Hazardous material Storage Clean & Easy Handling

    Material Identified

    Lower Dispersion Injection parameters adjusted

    after the filling of the ladle

    Reduction of Mg Targeted high metal quality

    AdvantagesAdvantages ofofCoredCored WireWire processprocess

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    Savings using Cored WireSavings using Cored Wire

    SAVINGS

    Unknow parameters(weigth)

    Scattering

    Cored Wire addition% min

    Aim Using Lumps

    Aim Using CW

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    ComponentsComponents

    of the Cored Wire treatment processof the Cored Wire treatment process

    1) Consumable => wire + addition process

    2) Equipment => Ladle + feedings equipment3) Liquid Iron

    To highlight the benefits of Cored Wire process weneed to apply the best practices on these

    components

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    Opatija, April 28th 29th, 2011 Ductile iron cored wire process O. BAHUON 7

    What do we need for to produceWhat do we need for to producean effective and efficient cored wire ?an effective and efficient cored wire ?

    Choice and control of raw materials

    Chemistry, sizing, flowability, ISO certified suppliers Homogeneous and consistent powder metric weight

    weighting and blending in-situ

    Automatic control of each individual powder feeding

    & weighting system

    Mixing just before filling the wire

    Speed control of the profiling line

    Prevention of lock seam opening hazards

    Optimized final packaging

    Full traceability

    1

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    Keys successKeys successto produce a consistent cored wireto produce a consistent cored wire

    Homogeneity of encapsulated powder (blends)

    The homogeneity of the composition of the encapsulatedpowder is guarantied by in-situ weighting and lateblending of the single components

    Avoid to use pre-mix batches

    Consistent filling rate The consistency of the weight of encapsulated powder

    (grams of powder per meter of wire) all along the wire isobtained by using a permanent servo-controlled weightingsystem during filling

    Avoid to fill the wire at constant volume

    1

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    Ferrostatic

    Pressure

    - Memory of coiling

    - Flattening between feeder rolls

    - high distance between guide tube and ladle

    - low penetration into the liquid bath (twisting)

    - Release of Mg on the top of the ladle => poor

    efficiency nonnon--steady yieldssteady yields

    FeedingFeeding equipmentequipment2

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    FeedingFeeding equipmentequipment2

    Cored WireCored WireInjectionInjectionPracticesPractices

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    Straight and vertical injectionStraight and vertical injection

    Straighten the wire to avoid residual constraint

    Specific feeding equipment with adapted rolls

    Guiding tube perpendicular to the bath (vertical)

    Shorter distance between guiding tube and bath

    No effect of ferrostatic pressure

    Deeper penetration of wire into the melt

    Deeper release of the product and longerreaction time with the molten metal

    High and steadyHigh and steady yieldsyieldsDeep

    penetration

    2

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    WireWire straighteningstraightening

    Non-straightened wire Straightened wire

    2

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    GeometryGeometry of theof the treatmenttreatment ladleladle2

    A ratio of H/D = 2 minimum is recommended in order to

    have the highest metallo-static charge to oppose the

    magnesium vapor pressure.

    Also the height of the free board above the liquid surface

    in the ladle before treatment, must be compatible with the

    violence of the reaction.

    H/D is the critical factor for the yield ofmagnesium, with the same cored wire we

    can see a double consumption of wire withbad ratio

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    WireWire diameterdiameter linklink to theto the ladleladle

    Determinated by Mg content in the powder, requestedaddition of Mg, and speed of injection.

    Economy is also a factor, typically higher diameter lead to lowprice. The goal is to find a wire whose ratio is: weight ofpowder/weight of wire is as high as possible.

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    TemperatureTemperature ofofliquidliquid ironiron

    This is the most important factor since temperature dictates

    the vapor pressure of Magnesium (8 bars at 1400C, 17 barsat 1500C)

    Consequently the speed of the Mg vaporization increases. Inaddition, the instantaneous flow rate of Mg is affected by the

    injection speed (for a given Mg % in the powder)A greater Mg flow rate associated with liquid iron temperatureabove 1500C result in poor yields due to a formati on of biggerbubbles of Mg vapor.

    And dont forget that solubility of Mg in cast iron decreases withtemperature.

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    FactorsFactors toto bebe consideredconsidered whenwhen treatingtreating castcast ironiron

    Liquid iron treatment temperature

    Magnesium rate (for Mg treatment) Liquid iron weight

    Liquid iron characteristics (oxidation, % S)

    3

    Today we can achieve up to 60 % magnesiumrecovery with a pure magnesium patented cored

    wire and consistent process

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    Insulation which delays the heat transfer,

    thus protects the Magnesium (~1 second)

    deeper penetration of Mg into the liquidsteel. reduces the heat from thermalradiation. optimizes the wire guiding

    Dramatic Improvement in Mg RecoveryDramatic Improvement in Mg Recovery

    Very Steady ResultsVery Steady Results

    Highly Predictable ResultsHighly Predictable Results

    PAPMAGPAPMAGTechnologyTechnology

    Deep

    penet

    ration

    Externalsteel

    sheath

    Internalsteel

    sheath

    Insulation

    Powder

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    Pioneer, Leader, AFFIVAL is yourinnovative and sustainable partner.

    Thank you for your attention

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    Wire Feeding in FoundryWire Feeding in Foundry

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    Wire Feeder for foundriesWire Feeder for foundries

    Speed injection range: 0 to 120 m/min

    Very accurate and steady injection speed (cm/min)

    Very accurate length of wire fed (mm)

    Light equipment easy to locate (ladle, mould ) Customizable equipment for any customer requirement

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    Treatment booth for foundryTreatment booth for foundry

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    Treatment BoothTreatment Booth

    Wire feeder

    Entry guides Exit guide tubes

    Movable ladle cover

    Sliding Door

    De-dusting systemcompatible (not provided)

    Possible full automation

    All treatment Nodularization Inoculation

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    Treatment booth for foundryTreatment booth for foundry