polydentate ligands & nomenclature chapter 24 – lecture 2
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Polydentate Ligands & Nomenclature Chapter 24 – Lecture 2. Chemistry 123 Spring 2008 Dr. Woodward. Chelating (Polydentate) Ligands. Porphyrins. Porphine (C 20 H 14 N 4 ). Myoglobin & Hemoglobin. Chlorophyll. Rules for Naming Coordination Compounds. - PowerPoint PPT PresentationTRANSCRIPT
Polydentate Ligands & Polydentate Ligands & Nomenclature Nomenclature
Chapter 24 – Lecture 2Chapter 24 – Lecture 2
Chemistry 123Spring 2008
Dr. Woodward
Chelating (Polydentate) Chelating (Polydentate) LigandsLigands
PorphyrinsPorphyrins
Porphine Porphine (C(C2020HH1414NN44))
Myoglobin & Myoglobin & HemoglobinHemoglobin
ChlorophyllChlorophyll
Rules for Naming Coordination Rules for Naming Coordination CompoundsCompounds
1. For ionic compounds the cation comes before the anion.2. For the complex ion part (within brackets) the ligands are
listed in alphabetical order before the metal.3. Anionic ligands end in the letter o, neutral ligands retain
their names (NH3 = ammine, H2O = aqua).ClCl−− = chloro = chloro BrBr−− = bromo = bromo I I−− = iodo = iodoOHOH−− = hydroxo = hydroxo CNCN−− = cyano = cyano O O2−2− = oxo = oxo
4. Greek prefixes are used to indicate the number of ligands (different prefixes are used if the ligand itself has one of these prefixes).
2 = di 3 = tri 4 = tetra 5 = penta 6 = hexa 2 = di 3 = tri 4 = tetra 5 = penta 6 = hexa 2 = bis 3 = tris 4 = tetrakis (alternate prefixes)2 = bis 3 = tris 4 = tetrakis (alternate prefixes)
5. If the complex ion has a negative charge it ends in ate.6. The oxidation number of the metal is given in parentheses
in roman numerals.
0.0
0.2
0.4
0.6
0.8
1.0
1.2
250 300 350 400 450 500 550 600 650 700wavelength (nm)
abso
rban
ce (C
rO42-
)
0
1
2
3
4
5
abso
rban
ce (S
rCrO
4, Pb
CrO
4)
dilute CrO42-
solution
SrCrO4 PbCrO4
conc. CrO4
2-
solution
Color: CrOColor: CrO44-- & Chromate & Chromate
SaltsSalts
SrCrO4 behaves much like a concentrated CrO42- solution. Sr2+ ions have
little effect on the electronic absorption, whereas Pb2+ ions shift the absorption edge to lower energy (longer wavelengths).