pm in the czech republic jiří smolík and jaroslav schwarz aerosol laboratory institute of...
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PM in the Czech PM in the Czech RepublicRepublic
Jiří Smolík and Jaroslav Schwarz
AEROSOL LABORATORYInstitute of Chemical Process FundamentalsAcademy of Sciences of the Czech RepublicRozvojová 135, 165 02 Prague–Suchdol, CR
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MonitoringMonitoring
Czech Hydrometeorological Institute (95)
www.chmi.cz
Public Health Service + National Institute of Public Health + Others (24)
www.szu.cz
PM10 (119) + PM2,5 (5)
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AIMAIMautomated air pollution monitoringautomated air pollution monitoring
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AIMAIMautomated air pollution monitoringautomated air pollution monitoring
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LimitsLimits
TSP
60 µg/m3 – annual
150 µg/m3 – daily
PM10
40 (6,4) µg/m3 – annual
50 (20) µg/m3 – daily
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Annual average concentrations of TSPAnnual average concentrations of TSP
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ResearchResearch
Aerosol Laboratory ICPF AS CR NPI AS CR IAC AS CR
Institute of Environmental StudiesCharles University, Faculty of Science
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Aerosol LaboratoryAerosol Laboratory
Composition of atmospheric aerosols Indoor/outdoor aerosols Combustion aerosols Nucleation phenomena Nanoparticle synthesis
www.icpf.cas.cz/react/react.aspx#aero
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Aerosol LaboratoryAerosol Laboratory
Subgrid scale investigations of factors determining the occurrence of ozone and fine particles (5. FP SUB-AERO)
Characterisation of urban air quality – indoor/outdoor particulate matter chemical characteristics and source-to-inhaled dose relationships (5. FP URBAN-AEROSOL)
Comprehensive size resolved characterisation of atmospheric particulate matter in Prague (GA CR)
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Aerosol LaboratoryAerosol Laboratory
Detailed characterisation of PM10 fraction of atmospheric aerosol at suburban site of Prague and determination of urban influence on local Air Quality (GA CR submitted)
Prague suburb aerosol size dependent characterisation (COST 633, MEYS submitted)
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SUB-AEROSUB-AERO
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SUB-AEROSUB-AERO
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SUB-AEROSUB-AERO
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SUB-AEROSUB-AERO
Fig. 5b Athens, July 1 - July 2, 2000
-10
10
30
50
70
0.01 0.1 1 10 100
Dp [mm]
dm/d
log(
Dp)
[ mg/
m3 ]
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SUB-AEROSUB-AERO
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SUB-AEROSUB-AERO
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SUB-AEROSUB-AERO
0
10
20
30
40
50
60
70
80
10
Ju
l 00
12
Ju
l 00
14
Ju
l 00
16
Ju
l 00
18
Ju
l 00
20
Ju
l 00
22
Ju
l 00
24
Ju
l 00
26
Ju
l 00
28
Ju
l 00
30
Ju
l 00
7 J
an
01
9 J
an
01
11
Ja
n 0
1
13
Ja
n 0
1
Sampling start date
Mas
s co
nc.
[µg
/m3]
PM1 - darkPM10 - light
BOAT
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SUB-AEROSUB-AERO
Si
0
1000
2000
3000
4000
5000
6000
7000
8000
10
Ju
l 00
12
Ju
l 00
14
Ju
l 00
16
Ju
l 00
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Ju
l 00
20
Ju
l 00
22
Ju
l 00
24
Ju
l 00
26
Ju
l 00
28
Ju
l 00
30
Ju
l 00
7 J
an
01
9 J
an
01
11
Ja
n 0
1
13
Ja
n 0
1
Sampling start date
Mas
s c
on
c.
[ng
/m3] PM1 - dark
PM10 - light BOAT
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SUB-AEROSUB-AERO
K
0
100
200300
400
500
600
700800
900
10001
0 J
ul 0
0
12
Ju
l 00
14
Ju
l 00
16
Ju
l 00
18
Ju
l 00
20
Ju
l 00
22
Ju
l 00
24
Ju
l 00
26
Ju
l 00
28
Ju
l 00
30
Ju
l 00
7 J
an
01
9 J
an
01
11
Ja
n 0
1
13
Ja
n 0
1
Sampling start date
Mas
s co
nc.
[n
g/m
3] PM1 - dark
PM10 - light BOAT
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0
SUB-AEROSUB-AEROS
0
500
1000
1500
2000
2500
3000
3500
400010
Jul
00
12 J
ul 0
0
14 J
ul 0
0
16 J
ul 0
0
18 J
ul 0
0
20 J
ul 0
0
22 J
ul 0
0
24 J
ul 0
0
26 J
ul 0
0
28 J
ul 0
0
30 J
ul 0
0
7 Ja
n 01
9 Ja
n 01
11 J
an 0
1
13 J
an 0
1
Sampling start date
Mas
s co
nc.
[n
g/m
3] PM1 - dark
PM10 - light
BOAT
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SUB-AEROSUB-AERO
Cl
0
500
1000
1500
2000
2500
3000
3500
40001
0 J
ul 0
0
12
Ju
l 00
14
Ju
l 00
16
Ju
l 00
18
Ju
l 00
20
Ju
l 00
22
Ju
l 00
24
Ju
l 00
26
Ju
l 00
28
Ju
l 00
30
Ju
l 00
7 J
an
01
9 J
an
01
11
Ja
n 0
1
13
Ja
n 0
1
Sampling start date
Mas
s co
nc.
[n
g/m
3] PM1 - dark
PM10 - light
BOAT
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SUB-AEROSUB-AERO
Ni
0
1
23
4
5
6
78
9
101
0 J
ul 0
0
12
Ju
l 00
14
Ju
l 00
16
Ju
l 00
18
Ju
l 00
20
Ju
l 00
22
Ju
l 00
24
Ju
l 00
26
Ju
l 00
28
Ju
l 00
30
Ju
l 00
7 J
an
01
9 J
an
01
11
Ja
n 0
1
13
Ja
n 0
1
Sampling start date
Ma
ss
co
nc
. [n
g/m
3] PM1 - dark
PM10 - lightBOAT
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URBAN-AEROSOLURBAN-AEROSOL
Family house, Steinborgveien, Oslo, Norway,
3.-14.6.2002
Office of the Fondazione Lombardia per l’Ambiente
Milan, Italy, 8.-23.10.2002
Apartment, ICPF, Prague, Czech Republic,
16.-29.11.2002
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URBAN-AEROSOLURBAN-AEROSOL
NanoSMPS: 3 nm - 1 mm
DMA2 (EC 3085) + UCPC (3025)
SMPS: 7 nm - 1 mm
DMA1 (EC 3071A) + CPC (3022A)
APS (3321): 0,5 mm - 20 mm
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URBAN-AEROSOLURBAN-AEROSOL
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URBAN-AEROSOLURBAN-AEROSOL
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URBAN-AEROSOLURBAN-AEROSOL
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URBAN-AEROSOLURBAN-AEROSOL
Ion Chromatography:
NH4+, Na+, K+, Ca+, Mg+, SO4
2-, NO3-, Cl-
PIXE: Al,Ca,Cr,Cu,Fe,K,Mn,Ni,Pb,S,Si,Ti,V,Zn
INAA:Al,Ag,As,Au,Ba,Br,Ca,Cd,Ce,Cl,Co,Cr,Cu,Eu,Fe,Ga,Hf,I,K,La,Mg,Mn,Mo,Na,Ni,Rb,Sb,Sc,Se,Sm,Sr,Ta,Th,Ti,U,V,W,Zn
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URBAN-AEROSOLURBAN-AEROSOL
0
10
20
30
40
50
60
70
0,0 0,1 1,0 10,0 100,0
Dae (µm)
dm
/dlo
g(D
p),
µg
/m3
Outdoor
Indoor
0
5
10
15
20
25
30
35
40
0,0 0,1 1,0 10,0 100,0
Dae (µm)
dm
/dlo
g(D
p),
µg
/m3
Outdoor
Indoor
0
5
10
15
20
25
30
0,0 0,1 1,0 10,0 100,0
Dae (µm)
dm
/dlo
g(D
p),
µg
/m3
Outdoor
Indoor
0
10
20
30
40
50
0,0 0,1 1,0 10,0 100,0
Dae (µm)
dm
/dlo
g(D
p),
µg
/m3
Outdoor
Indoord)
a) b)
c)
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URBAN-AEROSOLURBAN-AEROSOLNO3
-
0
1
2
3
4
0,01 0,1 1 10 100
Dp [µm]
dm
/dlo
gD
p [
µg
/m3
]
indoor
outdoor
SO42-
0
1
2
3
4
0,01 0,1 1 10 100
Dp [µm]
dm
/dlo
gD
p [
µg
/m3
]
indoor
outdoor
NH4+
0
1
2
3
0,01 0,1 1 10 100
Dp [µm]
dm
/dlo
gD
p [
µg
/m3
]
indoor
outdoor
K+
0
0,1
0,2
0,3
0,4
0,5
0,01 0,1 1 10 100
Dp [µm]
dm
/dlo
gD
p [
µg
/m3
]indoor
outdoor
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URBAN-AEROSOLURBAN-AEROSOL
0
10
20
30
40
50
60
70
0,0 0,1 1,0 10,0 100,0
Dae (µm)
dm
/dlo
g(D
p),
µg
/m3
Outdoor
Indoor
0
30
60
90
120
150
180
0,0 0,1 1,0 10,0 100,0
Dae (µm)
dm
/dlo
g(D
p),
µg
/m3
Outdoor
Indoor
0
10
20
30
40
50
0,0 0,1 1,0 10,0 100,0
Dae (µm)
dm
/dlo
g(D
p),
µg
/m3
Outdoor
Indoorc)
a) b)
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URBAN-AEROSOLURBAN-AEROSOLNO3
-
0
2
4
6
8
10
12
0,01 0,1 1 10 100
Dp [µm]
dm
/dlo
gD
p [
µg
/m3
]
indoor
outdoor
SO42-
0
2
4
6
8
10
0,01 0,1 1 10 100
Dp [µm]
dm
/dlo
gD
p [
µg
/m3
]
indoor
outdoor
NH4+
0
2
4
6
8
0,01 0,1 1 10 100
Dp [µm]
dm
/dlo
gD
p [
µg
/m3
]
indoor
outdoor
K+
0
0,3
0,6
0,9
1,2
1,5
0,01 0,1 1 10 100
Dp [µm]
dm
/dlo
gD
p [
µg
/m3
]
indoor
outdoor
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URBAN-AEROSOLURBAN-AEROSOL
Matrix element size distribution - Outdoor
0
200
400
600
800
1000
1200
1400
0,01 0,1 1 10 100
Dp [µm]
dm/d
log(
Dp)
ng/
m3
AL
SI
S
CL
K
CA
FE
Matrix elements size distribution - Indoor
0
200
400
600
800
1000
1200
1400
0,01 0,1 1 10 100
Dp [µm]dm
/dlo
g(D
p) n
g/m
3
AL
SI
S
CL
K
CA
FE
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URBAN-AEROSOLURBAN-AEROSOL
Trace element size distribution - Outdoor
0
20
40
60
80
100
120
140
0,01 0,1 1 10 100
Dp [µm]
dm
/dlo
g(D
p)
ng/
m3
MN
CU
ZN
BR
PB
TI
Trace element size distribution - Indoor
0
20
40
60
80
100
120
140
0,01 0,1 1 10 100
Dp [µm]d
m/d
log
(Dp)
ng/
m3
MN
CU
ZN
BR
TI
PB3
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PRAGUE AEROSOLPRAGUE AEROSOL
Characterisation of atmospheric PM
at two locations in Prague
● NW suburb of Prague
● centre of Prague
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PRAGUE AEROSOLPRAGUE AEROSOL
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PRAGUE AEROSOLPRAGUE AEROSOL
Mass concentration
PM1, PM2.5, PM10, BLPI impactor
Chemical and elemental composition
IC, PIXE, INAA, ICP-MS, AAS
Number concentration
SMPS, APS
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PRAGUE AEROSOLPRAGUE AEROSOL
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PRAGUE AEROSOLPRAGUE AEROSOL
0
20
40
60
80
0,01 0,1 1 10
Dae (mm)
dm
/dlo
g(D
p),
mg
/m3
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PRAGUE AEROSOLPRAGUE AEROSOL
0
20
40
60
80
100
0,0 0,1 1,0 10,0
Dae (µm)
dm
/dlo
g(D
p),
µg
/m3
■ suburban site
□ downtown site
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PRAGUE AEROSOLPRAGUE AEROSOL
0
5
10
15
20
25
30
35
0,01 0,1 1 10
Dae (mm)
dm
/dlo
g(D
p),
mg
/m3
■ suburban site□ downtown site
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PRAGUE AEROSOLPRAGUE AEROSOL
Laboratory for Atmospheric Aerosol Research
Aerosol Laboratory ICPF AS CR
+
Czech Hydrometeorological Institute
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PRAGUE AEROSOLPRAGUE AEROSOL
Aerosol Laboratory:PM1, PM2.5, PM10, BLPI impactor, NanoSMPS, SMPS, APS
IC, PIXE, INAA, OCEC
Czech Hydrometeorological Institute:
SO2, NOx, O3, continuous PM10, meteorology
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PRAGUE AEROSOLPRAGUE AEROSOL
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PRAGUE AEROSOLPRAGUE AEROSOL