please let us know if we met your expectations by rating ......^ icv,ccv,icb,ccb, isa, isb, cri,...

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Taylor, Dianna

From: Sadler, BillSent: Monday, January 05, 2015 8:00 AMTo: Taylor, DiannaSubject: FW: TestAmerica report files from 480-72941-1 Union County Landfill - GroundwaterAttachments: J72941-1 UDS Level 2 Report Final Report.pdf

Dianna – please put in the file for Union County Class 1 Thanks

From: Pridgeon, Anne [mailto:[email protected]]Sent: Monday, December 29, 2014 10:51 AM To: Dana Derrington; Sadler, Bill Subject: TestAmerica report files from 480-72941-1 Union County Landfill - Groundwater

Hello,

Attached please find the report files for job 480-72941-1; Union County Landfill - Groundwater

Please feel free to contact me or your PM Ryan VanDette if you have any questions.

Thank you.

Please let us know if we met your expectations by rating the service you received from TestAmerica on this project by visiting our website at: Project Feedback

ANNE PRIDGEONProject Management Assistant I

TestAmerica Buffalo THE LEADER IN ENVIRONMENTAL TESTING

Tel: 716.691,2600www.testamericainc.com

Reference: [176131] Attachments: 1

Rec’d Digitally

AFIN:_________________________

PMT#:_________________________ SW

DOC ID#:______________________ MD

TO:___________________________

70-00364

0248-S1-R4

By Dianna Taylor at 10:32 am, Jan 08, 2015

66925

BS>File

ANALYTICAL REPORTTestAmerica Laboratories, Inc.TestAmerica Buffalo10 Hazelwood DriveAmherst, NY 14228-2298Tel: (716)691-2600

TestAmerica Job ID: 480-72941-1Client Project/Site: Union County Landfill - GroundwaterSampling Event: Groundwater

For:Waste Corporation of America1001 South Rockwell AveOklahoma city, Oklahoma 73128

Attn: Randy Tourville

Authorized for release by:12/29/2014 11:14:59 AMAnne Pridgeon, Project Management Assistant [email protected]

Designee for

Ryan VanDette, Project Manager II(716)[email protected]

The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accreditedparameters, exceptions are noted in this report. This report may not be reproduced except in full,and with written approval from the laboratory. For questions please contact the Project Managerat the e-mail address or telephone number listed on this page.

This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

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https://secure.testamericainc.com/TotalAccess/login.aspx

http://www.testamericainc.com/AskTheExpert/Expert_index.htm

http://www.testamericainc.com

mailto:[email protected]

mailto:[email protected]

Table of Contents

Client: Waste Corporation of AmericaProject/Site: Union County Landfill - Groundwater

TestAmerica Job ID: 480-72941-1

Page 2 of 67TestAmerica Buffalo

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Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35

QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36

QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47

Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53

Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58

Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59

Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60

Detection Limit Exceptions Summary . . . . . . . . . . . . . . . . . . . . . . . . . . 61

Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62

Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67

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Definitions/GlossaryTestAmerica Job ID: 480-72941-1Client: Waste Corporation of America

Project/Site: Union County Landfill - Groundwater

Qualifiers

GC/MS VOA

Qualifier Description

* LCS or LCSD exceeds the control limits

Qualifier

Metals

Qualifier Description

^ ICV,CCV,ICB,CCB, ISA, ISB, CRI, CRA, DLCK or MRL standard: Instrument related QC exceeds the control limits.

Qualifier

B Compound was found in the blank and sample.

Glossary

These commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CFL Contains Free Liquid

CNF Contains no Free Liquid

DER Duplicate error ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision level concentration

MDA Minimum detectable activity

EDL Estimated Detection Limit

MDC Minimum detectable concentration

MDL Method Detection Limit

ML Minimum Level (Dioxin)

NC Not Calculated

ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RER Relative error ratio

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

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Case NarrativeClient: Waste Corporation of America TestAmerica Job ID: 480-72941-1


Job ID: 480-72941-1

Laboratory: TestAmerica Buffalo

Narrative

Job Narrative

480-72941-1

Comments

No additional comments.

Receipt

The samples were received on 12/12/2014 9:00 AM; the samples arrived in good condition, properly preserved and, where required, on

ice. The temperatures of the 3 coolers at receipt time were 2.5º C, 3.0º C and 3.4º C.

GC/MS VOA

Method(s) 8260C: The following volatiles samples were diluted due to foaming at the time of purging during the original sample analysis:

(480-72941-9 MS), (480-72941-9 MSD), Leachate (480-72941-9). Elevated reporting limits (RLs) are provided.

Method(s) 8260C: The following samples were collected in properly preserved vials for analysis of volatile organic compounds (VOCs).

However, the pH was outside the required criteria when verified by the laboratory, and corrective action was not possible: (480-72941-9

MS), (480-72941-9 MSD), Leachate (480-72941-9).

Method(s) 8260C: The continuing calibration verification (CCV) associated with batch 220234 recovered above the upper control limit for

1,1,1-Trichloroethane and Vinyl acetate. The samples associated with this CCV were non-detects for the affected analytes; therefore, the

data have been reported. The following samples are impacted: (CCVIS 480-220234/3).

Method(s) 8260C: The laboratory control sample (LCS) for batch 220234 recovered outside control limits for the following analyte: Vinyl

acetate . This analyte was biased high in the LCS and was not detected in the associated samples; therefore, the data have been

reported.

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

HPLC/IC

Method(s) 9056A: The following sample(s) was diluted due to elevated conductivity readings indicating a high presence of ions and other

constituents: Leachate (480-72941-9), MW-20 (480-72941-8), MW-7 (480-72941-5), MW-9 (480-72941-11). Elevated reporting limits (RLs)

are provided.


Metals

Method(s) 6010C: The Low Level Continuing Calibration Verifications (CCVL 480-219551/16 and 480-219551/20) contained total copper

outside the control limits. All reported samples (MB 480-219088/1-A) associated with this CCVL were either below the laboratory's

standard reporting limit for this analyte or contained this analyte at a concentration greater than 10X the value found in the CCVL; therefore,

re-analysis of samples was not performed.


outside the control limits. All reported samples (LCS 480-219088/2-A), MW-12 (480-72941-4), MW-2 (480-72941-1), MW-5R

(480-72941-2), MW-6 (480-72941-3) associated with this CCVL were either below the laboratory's standard reporting limit for this analyte

or contained this analyte at a concentration greater than 10X the value found in the CCVL; therefore, re-analysis of samples was not

performed.


outside the control limits. All reported samples (480-72941-13 SD), MW-14 (480-72941-7), MW-18 (480-72941-12), MW-20

(480-72941-8), MW-21 (480-72941-13), MW-7 (480-72941-5), MW-8 (480-72941-6), MW-9 (480-72941-11) associated with this CCVL

were either below the laboratory's standard reporting limit for this analyte or contained this analyte at a concentration greater than 10X the

value found in the CCVL; therefore, re-analysis of samples was not performed.

Method(s) 6010C: The Low Level Continuing Calibration Verifications (CCVLs 480-219551/44 and 480-219551/53) contained total copper

outside the control limits. All reported samples (480-72941-13 MS), (480-72941-13 MSD), (480-72941-13 PDS) associated with this

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Case NarrativeClient: Waste Corporation of America TestAmerica Job ID: 480-72941-1


Job ID: 480-72941-1 (Continued)

Laboratory: TestAmerica Buffalo (Continued)

CCVL were either below the laboratory's standard reporting limit for this analyte or contained this analyte at a concentration greater than

10X the value found in the CCVL; therefore, re-analysis of samples was not performed.

Method(s) 6010C: The Low Level Continuing Calibration Verification (CCVL 480-219551/53) contained total manganese outside the

control limits. All reported samples (480-72941-13 MS), (480-72941-13 MSD), (480-72941-13 PDS) associated with this CCVL were

either below the laboratory's standard reporting limit for this analyte or contained this analyte at a concentration greater than 10X the value

found in the CCVL; therefore, re-analysis of samples was not performed.

Method(s) 6010C: The method blank for batch 480-219088 contained total copper above the client detection limit. This target analyte

concentration was less than the laboratory's standard reporting limit (RL); therefore, re-extraction and/or re-analysis of samples MW-12

(480-72941-4), MW-14 (480-72941-7), MW-18 (480-72941-12), MW-2 (480-72941-1), MW-20 (480-72941-8), MW-21 (480-72941-13),

MW-4 (480-72941-10), MW-5R (480-72941-2), MW-6 (480-72941-3), MW-7 (480-72941-5), MW-8 (480-72941-6), MW-9 (480-72941-11)

was not performed.


General Chemistry

Method(s) SM 2540C: Due to the matrix, the initial volume(s) used for the following sample(s) deviated from the standard procedure:

Leachate (480-72941-9). The reporting limits (RLs) have been adjusted proportionately.



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Detection SummaryTestAmerica Job ID: 480-72941-1Client: Waste Corporation of America


Client Sample ID: MW-2 Lab Sample ID: 480-72941-1

Barium

RL

0.0020 mg/L

MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA10.13 6010C

Cobalt 0.0010 mg/L Total/NA10.0063 6010C

Copper 0.0020 mg/L Total/NA10.0078 B ^ 6010C

Iron 0.10 mg/L Total/NA10.53 6010C

Manganese 0.010 mg/L Total/NA10.013 6010C

Zinc 0.010 mg/L Total/NA10.027 6010C

Arsenic 0.0010 mg/L Total/NA10.0044 6020A

Nickel 0.0010 mg/L Total/NA10.0075 6020A

Selenium 0.0010 mg/L Total/NA10.0025 6020A

Chloride 0.50 mg/L Total/NA145.7 9056A

Sulfate 2.0 mg/L Total/NA177.7 9056A

Total Organic Carbon 1.0 mg/L Total/NA16.4 9060A

Total Dissolved Solids 10.0 mg/L Total/NA1270 SM 2540C

Client Sample ID: MW-5R Lab Sample ID: 480-72941-2

Barium

RL

0.0020 mg/L


Total/NA10.21 6010C











Barium

RL

0.0020 mg/L


Total/NA10.052 6010C














Barium

RL

0.0020 mg/L


Total/NA10.18 6010C

Cadmium 0.00050 mg/L Total/NA10.00076 6010C

TestAmerica Buffalo

This Detection Summary does not include radiochemical test results.

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Client Sample ID: MW-12 (Continued) Lab Sample ID: 480-72941-4

Cobalt

RL

0.0010 mg/L








Mercury 0.00020 mg/L Total/NA10.0012 7470A






Barium

RL

0.0020 mg/L


Total/NA10.39 6010C







Chloride 2.5 mg/L Total/NA5202 9056A




Barium

RL

0.0020 mg/L










Total Dissolved Solids 10.0 mg/L Total/NA171.0 SM 2540C


Barium

RL

0.0020 mg/L


Total/NA10.10 6010C








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Barium

RL

0.0020 mg/L


Total/NA10.39 6010C











Client Sample ID: Leachate Lab Sample ID: 480-72941-9

Barium

RL

0.0020 mg/L


Total/NA12.3 6010C

Chromium 0.0020 mg/L Total/NA10.016 6010C


Copper 0.0020 mg/L Total/NA10.0049 6010C



Vanadium 0.0020 mg/L Total/NA10.017 6010C

Zinc 0.010 mg/L Total/NA10.85 B 6010C

Antimony 0.0010 mg/L Total/NA10.0029 6020A




Chloride 100 mg/L Total/NA2002250 9056A

Total Organic Carbon 4.0 mg/L Total/NA4207 9060A

Total Dissolved Solids 100 mg/L Total/NA15410 SM 2540C


cis-1,2-Dichloroethene

RL

0.0010 mg/L


Total/NA10.0010 8260C

Barium 0.0020 mg/L Total/NA10.40 6010C

Beryllium 0.0010 mg/L Total/NA10.0016 6010C

Chromium 0.0020 mg/L Total/NA10.0024 6010C


Copper 0.0020 mg/L Total/NA10.0079 B 6010C











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1,1-Dichloroethane

RL

0.0010 mg/L


Total/NA10.0037 8260C

1,2-Dichloroethane 0.0010 mg/L Total/NA10.0011 8260C

cis-1,2-Dichloroethene 0.0010 mg/L Total/NA10.0012 8260C

Trichloroethylene 0.0010 mg/L Total/NA10.0019 8260C

Barium 0.0020 mg/L Total/NA10.056 6010C

Beryllium 0.0010 mg/L Total/NA10.0021 6010C















Barium

RL

0.0020 mg/L


Total/NA10.18 6010C














Copper

RL

0.0020 mg/L


Total/NA1B ^0.0077 6010C


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Client Sample ResultsTestAmerica Job ID: 480-72941-1Client: Waste Corporation of America


Lab Sample ID: 480-72941-1Client Sample ID: MW-2Matrix: WaterDate Collected: 12/09/14 16:35

Date Received: 12/12/14 09:00

Method: 8260C - Volatile Organic Compounds by GC/MSRL MDL

1,1,1,2-Tetrachloroethane ND 0.0010 mg/L 12/20/14 14:30 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

0.0010 mg/L 12/20/14 14:30 11,1,1-Trichloroethane ND

0.0010 mg/L 12/20/14 14:30 11,1,2,2-Tetrachloroethane ND


0.0010 mg/L 12/20/14 14:30 11,1-Dichlorethylene ND

0.0010 mg/L 12/20/14 14:30 11,1-Dichloroethane ND

0.0025 mg/L 12/20/14 14:30 11,2,3-Trichloropropane ND

0.0050 mg/L 12/20/14 14:30 11,2-Dibromo-3-Chloropropane ND

0.0010 mg/L 12/20/14 14:30 11,2-Dibromoethane ND

0.0010 mg/L 12/20/14 14:30 11,2-Dichlorobenzene ND


0.0010 mg/L 12/20/14 14:30 11,2-Dichloropropane ND


0.015 mg/L 12/20/14 14:30 12-Butanone (MEK) ND

0.010 mg/L 12/20/14 14:30 12-Hexanone ND

0.010 mg/L 12/20/14 14:30 14-Methyl-2-pentanone (MIBK) ND

0.050 mg/L 12/20/14 14:30 1Acetone ND

0.010 mg/L 12/20/14 14:30 1Acrylonitrile ND

0.0010 mg/L 12/20/14 14:30 1Benzene ND

0.0010 mg/L 12/20/14 14:30 1Bromochloromethane ND

0.0010 mg/L 12/20/14 14:30 1Bromodichloromethane ND

0.0010 mg/L 12/20/14 14:30 1Bromoform ND

0.0010 mg/L 12/20/14 14:30 1Carbon disulfide ND

0.0010 mg/L 12/20/14 14:30 1Carbon tetrachloride ND

0.0010 mg/L 12/20/14 14:30 1Chlorobenzene ND

0.0050 mg/L 12/20/14 14:30 1Chloroethane ND

0.0050 mg/L 12/20/14 14:30 1Chloroform ND

0.0010 mg/L 12/20/14 14:30 1cis-1,2-Dichloroethene ND

0.0010 mg/L 12/20/14 14:30 1cis-1,3-Dichloropropene ND

0.0010 mg/L 12/20/14 14:30 1Dibromochloromethane ND

0.0010 mg/L 12/20/14 14:30 1Ethylbenzene ND

0.0050 mg/L 12/20/14 14:30 1Methyl bromide ND

0.0025 mg/L 12/20/14 14:30 1Methyl chloride ND

0.010 mg/L 12/20/14 14:30 1Methyl iodide ND

0.0010 mg/L 12/20/14 14:30 1Methylene bromide ND

0.0050 mg/L 12/20/14 14:30 1Methylene Chloride ND

0.0010 mg/L 12/20/14 14:30 1Styrene ND

0.0010 mg/L 12/20/14 14:30 1Tetrachloroethene ND

0.0050 mg/L 12/20/14 14:30 1Toluene ND

0.0010 mg/L 12/20/14 14:30 1trans-1,2-Dichloroethene ND

0.0010 mg/L 12/20/14 14:30 1trans-1,3-Dichloropropene ND

0.0025 mg/L 12/20/14 14:30 1trans-1,4-Dichloro-2-butene ND

0.0010 mg/L 12/20/14 14:30 1Trichloroethylene ND

0.0050 mg/L 12/20/14 14:30 1Trichlorofluoromethane ND

0.010 mg/L 12/20/14 14:30 1Vinyl acetate ND *

0.0010 mg/L 12/20/14 14:30 1Vinyl chloride ND

0.0030 mg/L 12/20/14 14:30 1Xylenes, Total ND

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1,2-Dichloroethane-d4 (Surr) 109 66 - 137 12/20/14 14:30 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

4-Bromofluorobenzene (Surr) 90 12/20/14 14:30 173 - 120

Dibromofluoromethane (Surr) 106 12/20/14 14:30 160 - 140

Toluene-d8 (Surr) 97 12/20/14 14:30 171 - 126

Method: 6010C - Metals (ICP)RL MDL

Barium 0.13 0.0020 mg/L 12/15/14 08:50 12/16/14 19:47 1


0.0010 mg/L 12/15/14 08:50 12/16/14 19:47 1Beryllium ND

0.00050 mg/L 12/15/14 08:50 12/16/14 19:47 1Cadmium ND

0.0020 mg/L 12/15/14 08:50 12/16/14 19:47 1Chromium ND

0.0010 mg/L 12/15/14 08:50 12/16/14 19:47 1Cobalt 0.0063

0.0020 mg/L 12/15/14 08:50 12/16/14 19:47 1Copper 0.0078 B ^

0.10 mg/L 12/15/14 08:50 12/16/14 19:47 1Iron 0.53

0.010 mg/L 12/15/14 08:50 12/16/14 19:47 1Manganese 0.013

0.0020 mg/L 12/15/14 08:50 12/16/14 19:47 1Vanadium ND

0.010 mg/L 12/15/14 08:50 12/16/14 19:47 1Zinc 0.027

Method: 6020A - Metals (ICP/MS)RL MDL

Antimony ND 0.0010 mg/L 12/15/14 13:18 12/17/14 21:49 1


0.0010 mg/L 12/15/14 13:18 12/17/14 21:49 1Arsenic 0.0044

0.0010 mg/L 12/15/14 13:18 12/17/14 21:49 1Lead ND

0.0010 mg/L 12/15/14 13:18 12/17/14 21:49 1Nickel 0.0075

0.0010 mg/L 12/15/14 13:18 12/17/14 21:49 1Silver ND

0.0010 mg/L 12/15/14 13:18 12/17/14 21:49 1Selenium 0.0025

0.0010 mg/L 12/15/14 13:18 12/17/14 21:49 1Thallium ND

Method: 7470A - Mercury (CVAA)RL MDL

Mercury ND 0.00020 mg/L 12/15/14 09:30 12/15/14 14:05 1


General ChemistryRL MDL

Chloride 45.7 0.50 mg/L 12/17/14 17:05 1


2.0 mg/L 12/17/14 17:05 1Sulfate 77.7

1.0 mg/L 12/19/14 16:40 1Total Organic Carbon 6.4

10.0 mg/L 12/15/14 22:04 1Total Dissolved Solids 270

Lab Sample ID: 480-72941-2Client Sample ID: MW-5RMatrix: WaterDate Collected: 12/10/14 10:00










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Method: 8260C - Volatile Organic Compounds by GC/MS (Continued)RL MDL

1,2,3-Trichloropropane ND 0.0025 mg/L 12/20/14 14:52 1









0.010 mg/L 12/20/14 14:52 12-Hexanone ND


0.050 mg/L 12/20/14 14:52 1Acetone ND


0.0010 mg/L 12/20/14 14:52 1Benzene ND



0.0010 mg/L 12/20/14 14:52 1Bromoform ND















0.0010 mg/L 12/20/14 14:52 1Styrene ND


0.0050 mg/L 12/20/14 14:52 1Toluene ND













Toluene-d8 (Surr) 97 12/20/14 14:52 171 - 126

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Barium 0.21 0.0020 mg/L 12/15/14 08:50 12/16/14 19:50 1


0.0010 mg/L 12/15/14 08:50 12/16/14 19:50 1Beryllium ND

0.00050 mg/L 12/15/14 08:50 12/16/14 19:50 1Cadmium ND

0.0020 mg/L 12/15/14 08:50 12/16/14 19:50 1Chromium ND

0.0010 mg/L 12/15/14 08:50 12/16/14 19:50 1Cobalt 0.0077

0.0020 mg/L 12/15/14 08:50 12/16/14 19:50 1Copper 0.0081 B ^

0.10 mg/L 12/15/14 08:50 12/16/14 19:50 1Iron 4.4

0.010 mg/L 12/15/14 08:50 12/16/14 19:50 1Manganese 0.19

0.0020 mg/L 12/15/14 08:50 12/16/14 19:50 1Vanadium ND

0.010 mg/L 12/15/14 08:50 12/16/14 19:50 1Zinc 0.013


Antimony ND 0.0010 mg/L 12/15/14 13:18 12/17/14 21:54 1


0.0010 mg/L 12/15/14 13:18 12/17/14 21:54 1Arsenic 0.0032

0.0010 mg/L 12/15/14 13:18 12/17/14 21:54 1Lead ND

0.0010 mg/L 12/15/14 13:18 12/17/14 21:54 1Nickel 0.017

0.0010 mg/L 12/15/14 13:18 12/17/14 21:54 1Silver ND

0.0010 mg/L 12/15/14 13:18 12/17/14 21:54 1Selenium ND

0.0010 mg/L 12/15/14 13:18 12/17/14 21:54 1Thallium ND


Mercury ND 0.00020 mg/L 12/15/14 09:30 12/15/14 14:10 1



Chloride 97.9 0.50 mg/L 12/17/14 17:15 1


2.0 mg/L 12/17/14 17:15 1Sulfate ND

1.0 mg/L 12/19/14 17:39 1Total Organic Carbon ND


















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1,4-Dichlorobenzene ND 0.0010 mg/L 12/20/14 15:14 1



0.010 mg/L 12/20/14 15:14 12-Hexanone ND


0.050 mg/L 12/20/14 15:14 1Acetone ND


0.0010 mg/L 12/20/14 15:14 1Benzene ND



0.0010 mg/L 12/20/14 15:14 1Bromoform ND















0.0010 mg/L 12/20/14 15:14 1Styrene ND


0.0050 mg/L 12/20/14 15:14 1Toluene ND













Toluene-d8 (Surr) 100 12/20/14 15:14 171 - 126


Barium 0.052 0.0020 mg/L 12/15/14 08:50 12/16/14 19:52 1


0.0010 mg/L 12/15/14 08:50 12/16/14 19:52 1Beryllium ND

0.00050 mg/L 12/15/14 08:50 12/16/14 19:52 1Cadmium ND

0.0020 mg/L 12/15/14 08:50 12/16/14 19:52 1Chromium ND

0.0010 mg/L 12/15/14 08:50 12/16/14 19:52 1Cobalt 0.0063

0.0020 mg/L 12/15/14 08:50 12/16/14 19:52 1Copper 0.0075 B ^

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Method: 6010C - Metals (ICP) (Continued)RL MDL

Iron 0.62 0.10 mg/L 12/15/14 08:50 12/16/14 19:52 1


0.010 mg/L 12/15/14 08:50 12/16/14 19:52 1Manganese 0.011

0.0020 mg/L 12/15/14 08:50 12/16/14 19:52 1Vanadium ND

0.010 mg/L 12/15/14 08:50 12/16/14 19:52 1Zinc 0.030


Antimony ND 0.0010 mg/L 12/15/14 13:18 12/17/14 22:00 1


0.0010 mg/L 12/15/14 13:18 12/17/14 22:00 1Arsenic 0.0028

0.0010 mg/L 12/15/14 13:18 12/17/14 22:00 1Lead ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:00 1Nickel 0.0098

0.0010 mg/L 12/15/14 13:18 12/17/14 22:00 1Silver ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:00 1Selenium 0.0013

0.0010 mg/L 12/15/14 13:18 12/17/14 22:00 1Thallium ND


Mercury ND 0.00020 mg/L 12/15/14 09:30 12/15/14 14:12 1



Chloride 32.9 0.50 mg/L 12/17/14 17:24 1


2.0 mg/L 12/17/14 17:24 1Sulfate 45.0





















0.010 mg/L 12/20/14 15:36 12-Hexanone ND


0.050 mg/L 12/20/14 15:36 1Acetone ND


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Benzene ND 0.0010 mg/L 12/20/14 15:36 1




0.0010 mg/L 12/20/14 15:36 1Bromoform ND















0.0010 mg/L 12/20/14 15:36 1Styrene ND


0.0050 mg/L 12/20/14 15:36 1Toluene ND













Toluene-d8 (Surr) 98 12/20/14 15:36 171 - 126


Barium 0.18 0.0020 mg/L 12/15/14 08:50 12/16/14 19:55 1


0.0010 mg/L 12/15/14 08:50 12/16/14 19:55 1Beryllium ND

0.00050 mg/L 12/15/14 08:50 12/16/14 19:55 1Cadmium 0.00076

0.0020 mg/L 12/15/14 08:50 12/16/14 19:55 1Chromium ND

0.0010 mg/L 12/15/14 08:50 12/16/14 19:55 1Cobalt 0.011

0.0020 mg/L 12/15/14 08:50 12/16/14 19:55 1Copper 0.0081 B ^

0.10 mg/L 12/15/14 08:50 12/16/14 19:55 1Iron 0.23

0.010 mg/L 12/15/14 08:50 12/16/14 19:55 1Manganese 0.097

0.0020 mg/L 12/15/14 08:50 12/16/14 19:55 1Vanadium ND

0.010 mg/L 12/15/14 08:50 12/16/14 19:55 1Zinc 0.018

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Antimony ND 0.0010 mg/L 12/15/14 13:18 12/17/14 22:06 1


0.0010 mg/L 12/15/14 13:18 12/17/14 22:06 1Arsenic ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:06 1Lead ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:06 1Nickel 0.0091

0.0010 mg/L 12/15/14 13:18 12/17/14 22:06 1Silver ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:06 1Selenium ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:06 1Thallium ND


Mercury 0.0012 0.00020 mg/L 12/15/14 09:30 12/15/14 14:13 1



Chloride 20.5 0.50 mg/L 12/17/14 17:33 1


2.0 mg/L 12/17/14 17:33 1Sulfate 14.3





















0.010 mg/L 12/20/14 15:59 12-Hexanone ND


0.050 mg/L 12/20/14 15:59 1Acetone ND


0.0010 mg/L 12/20/14 15:59 1Benzene ND



0.0010 mg/L 12/20/14 15:59 1Bromoform ND




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Chloroethane ND 0.0050 mg/L 12/20/14 15:59 1












0.0010 mg/L 12/20/14 15:59 1Styrene ND


0.0050 mg/L 12/20/14 15:59 1Toluene ND













Toluene-d8 (Surr) 97 12/20/14 15:59 171 - 126


Barium 0.39 0.0020 mg/L 12/15/14 08:50 12/16/14 20:05 1


0.0010 mg/L 12/15/14 08:50 12/16/14 20:05 1Beryllium ND

0.00050 mg/L 12/15/14 08:50 12/16/14 20:05 1Cadmium ND

0.0020 mg/L 12/15/14 08:50 12/16/14 20:05 1Chromium ND

0.0010 mg/L 12/15/14 08:50 12/16/14 20:05 1Cobalt ND

0.0020 mg/L 12/15/14 08:50 12/16/14 20:05 1Copper 0.0075 B ^

0.10 mg/L 12/15/14 08:50 12/16/14 20:05 1Iron 15.3

0.010 mg/L 12/15/14 08:50 12/16/14 20:05 1Manganese 0.29

0.0020 mg/L 12/15/14 08:50 12/16/14 20:05 1Vanadium ND

0.010 mg/L 12/15/14 08:50 12/16/14 20:05 1Zinc 0.018


Antimony ND 0.0010 mg/L 12/15/14 13:18 12/17/14 22:30 1


0.0010 mg/L 12/15/14 13:18 12/17/14 22:30 1Arsenic 0.0018

0.0010 mg/L 12/15/14 13:18 12/17/14 22:30 1Lead ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:30 1Nickel 0.0050

0.0010 mg/L 12/15/14 13:18 12/17/14 22:30 1Silver ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:30 1Selenium ND

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Method: 6020A - Metals (ICP/MS) (Continued)RL MDL

Thallium ND 0.0010 mg/L 12/15/14 13:18 12/17/14 22:30 1



Mercury ND 0.00020 mg/L 12/15/14 09:30 12/15/14 14:15 1



Chloride 202 2.5 mg/L 12/17/14 17:42 5


2.0 mg/L 12/18/14 21:58 1Sulfate 9.4





















0.010 mg/L 12/20/14 16:21 12-Hexanone ND


0.050 mg/L 12/20/14 16:21 1Acetone ND


0.0010 mg/L 12/20/14 16:21 1Benzene ND



0.0010 mg/L 12/20/14 16:21 1Bromoform ND










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Methyl bromide ND 0.0050 mg/L 12/20/14 16:21 1






0.0010 mg/L 12/20/14 16:21 1Styrene ND


0.0050 mg/L 12/20/14 16:21 1Toluene ND













Toluene-d8 (Surr) 97 12/20/14 16:21 171 - 126


Barium 0.027 0.0020 mg/L 12/15/14 08:50 12/16/14 20:08 1


0.0010 mg/L 12/15/14 08:50 12/16/14 20:08 1Beryllium ND

0.00050 mg/L 12/15/14 08:50 12/16/14 20:08 1Cadmium ND

0.0020 mg/L 12/15/14 08:50 12/16/14 20:08 1Chromium ND

0.0010 mg/L 12/15/14 08:50 12/16/14 20:08 1Cobalt ND

0.0020 mg/L 12/15/14 08:50 12/16/14 20:08 1Copper 0.0074 B ^

0.10 mg/L 12/15/14 08:50 12/16/14 20:08 1Iron 1.5

0.010 mg/L 12/15/14 08:50 12/16/14 20:08 1Manganese 0.022

0.0020 mg/L 12/15/14 08:50 12/16/14 20:08 1Vanadium ND

0.010 mg/L 12/15/14 08:50 12/16/14 20:08 1Zinc ND


Antimony ND 0.0010 mg/L 12/15/14 13:18 12/17/14 22:36 1


0.0010 mg/L 12/15/14 13:18 12/17/14 22:36 1Arsenic 0.0012

0.0010 mg/L 12/15/14 13:18 12/17/14 22:36 1Lead ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:36 1Nickel 0.0018

0.0010 mg/L 12/15/14 13:18 12/17/14 22:36 1Silver ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:36 1Selenium ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:36 1Thallium ND


Mercury ND 0.00020 mg/L 12/15/14 09:30 12/15/14 14:17 1


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Chloride 6.0 0.50 mg/L 12/17/14 17:51 1


2.0 mg/L 12/17/14 17:51 1Sulfate 10.8


10.0 mg/L 12/16/14 16:34 1Total Dissolved Solids 71.0



















0.010 mg/L 12/20/14 16:43 12-Hexanone ND


0.050 mg/L 12/20/14 16:43 1Acetone ND


0.0010 mg/L 12/20/14 16:43 1Benzene ND



0.0010 mg/L 12/20/14 16:43 1Bromoform ND















0.0010 mg/L 12/20/14 16:43 1Styrene ND


0.0050 mg/L 12/20/14 16:43 1Toluene ND

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trans-1,2-Dichloroethene ND 0.0010 mg/L 12/20/14 16:43 1













Toluene-d8 (Surr) 98 12/20/14 16:43 171 - 126


Barium 0.10 0.0020 mg/L 12/15/14 08:50 12/16/14 20:11 1


0.0010 mg/L 12/15/14 08:50 12/16/14 20:11 1Beryllium ND

0.00050 mg/L 12/15/14 08:50 12/16/14 20:11 1Cadmium ND

0.0020 mg/L 12/15/14 08:50 12/16/14 20:11 1Chromium ND

0.0010 mg/L 12/15/14 08:50 12/16/14 20:11 1Cobalt ND

0.0020 mg/L 12/15/14 08:50 12/16/14 20:11 1Copper 0.0069 B ^

0.10 mg/L 12/15/14 08:50 12/16/14 20:11 1Iron 0.19

0.010 mg/L 12/15/14 08:50 12/16/14 20:11 1Manganese ND

0.0020 mg/L 12/15/14 08:50 12/16/14 20:11 1Vanadium ND

0.010 mg/L 12/15/14 08:50 12/16/14 20:11 1Zinc 0.011


Antimony ND 0.0010 mg/L 12/15/14 13:18 12/17/14 22:41 1


0.0010 mg/L 12/15/14 13:18 12/17/14 22:41 1Arsenic ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:41 1Lead ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:41 1Nickel 0.0025

0.0010 mg/L 12/15/14 13:18 12/17/14 22:41 1Silver ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:41 1Selenium ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:41 1Thallium ND


Mercury ND 0.00020 mg/L 12/15/14 09:30 12/15/14 14:22 1



Chloride 2.6 0.50 mg/L 12/17/14 18:00 1


2.0 mg/L 12/17/14 18:00 1Sulfate 5.1



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0.010 mg/L 12/20/14 17:05 12-Hexanone ND


0.050 mg/L 12/20/14 17:05 1Acetone ND


0.0010 mg/L 12/20/14 17:05 1Benzene ND



0.0010 mg/L 12/20/14 17:05 1Bromoform ND















0.0010 mg/L 12/20/14 17:05 1Styrene ND


0.0050 mg/L 12/20/14 17:05 1Toluene ND











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Method: 8260C - Volatile Organic Compounds by GC/MS (Continued)

4-Bromofluorobenzene (Surr) 94 73 - 120 12/20/14 17:05 1



Toluene-d8 (Surr) 99 12/20/14 17:05 171 - 126


Barium 0.39 0.0020 mg/L 12/15/14 08:50 12/16/14 20:13 1


0.0010 mg/L 12/15/14 08:50 12/16/14 20:13 1Beryllium ND

0.00050 mg/L 12/15/14 08:50 12/16/14 20:13 1Cadmium ND

0.0020 mg/L 12/15/14 08:50 12/16/14 20:13 1Chromium ND

0.0010 mg/L 12/15/14 08:50 12/16/14 20:13 1Cobalt ND

0.0020 mg/L 12/15/14 08:50 12/16/14 20:13 1Copper 0.0076 B ^

0.10 mg/L 12/15/14 08:50 12/16/14 20:13 1Iron 15.7

0.010 mg/L 12/15/14 08:50 12/16/14 20:13 1Manganese 0.29

0.0020 mg/L 12/15/14 08:50 12/16/14 20:13 1Vanadium ND

0.010 mg/L 12/15/14 08:50 12/16/14 20:13 1Zinc 0.020


Antimony ND 0.0010 mg/L 12/15/14 13:18 12/17/14 22:47 1


0.0010 mg/L 12/15/14 13:18 12/17/14 22:47 1Arsenic 0.0020

0.0010 mg/L 12/15/14 13:18 12/17/14 22:47 1Lead ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:47 1Nickel 0.0049

0.0010 mg/L 12/15/14 13:18 12/17/14 22:47 1Silver ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:47 1Selenium 0.0012

0.0010 mg/L 12/15/14 13:18 12/17/14 22:47 1Thallium ND


Mercury ND 0.00020 mg/L 12/15/14 09:30 12/15/14 14:24 1



Chloride 207 2.5 mg/L 12/17/14 18:09 5


2.0 mg/L 12/18/14 22:06 1Sulfate 9.2



Lab Sample ID: 480-72941-9Client Sample ID: LeachateMatrix: WaterDate Collected: 12/11/14 11:00










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1,2,3-Trichloropropane ND 0.050 mg/L 12/20/14 17:28 20









0.20 mg/L 12/20/14 17:28 202-Hexanone ND


1.0 mg/L 12/20/14 17:28 20Acetone ND


0.020 mg/L 12/20/14 17:28 20Benzene ND



0.020 mg/L 12/20/14 17:28 20Bromoform ND















0.020 mg/L 12/20/14 17:28 20Styrene ND


0.10 mg/L 12/20/14 17:28 20Toluene ND













Toluene-d8 (Surr) 100 12/20/14 17:28 2071 - 126

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Barium 2.3 0.0020 mg/L 12/15/14 10:54 12/16/14 19:04 1


0.0010 mg/L 12/15/14 10:54 12/16/14 19:04 1Beryllium ND

0.00050 mg/L 12/15/14 10:54 12/16/14 19:04 1Cadmium ND

0.0020 mg/L 12/15/14 10:54 12/16/14 19:04 1Chromium 0.016

0.0010 mg/L 12/15/14 10:54 12/16/14 19:04 1Cobalt 0.017

0.0020 mg/L 12/15/14 10:54 12/18/14 12:50 1Copper 0.0049

0.10 mg/L 12/15/14 10:54 12/16/14 19:04 1Iron 30.1

0.010 mg/L 12/15/14 10:54 12/18/14 12:50 1Manganese 2.5

0.0020 mg/L 12/15/14 10:54 12/16/14 19:04 1Vanadium 0.017

0.010 mg/L 12/15/14 10:54 12/16/14 19:04 1Zinc 0.85 B


Antimony 0.0029 0.0010 mg/L 12/15/14 13:18 12/17/14 22:53 1


0.0010 mg/L 12/15/14 13:18 12/17/14 22:53 1Arsenic 0.16

0.0010 mg/L 12/15/14 13:18 12/17/14 22:53 1Lead ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:53 1Nickel 0.12

0.0010 mg/L 12/15/14 13:18 12/17/14 22:53 1Silver ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:53 1Selenium 0.15

0.0010 mg/L 12/15/14 13:18 12/17/14 22:53 1Thallium ND


Mercury ND 0.00020 mg/L 12/16/14 08:45 12/16/14 13:58 1



Chloride 2250 100 mg/L 12/17/14 18:19 200


400 mg/L 12/17/14 18:19 200Sulfate ND

4.0 mg/L 12/23/14 16:23 4Total Organic Carbon 207

100 mg/L 12/16/14 16:34 1Total Dissolved Solids 5410

















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1,4-Dichlorobenzene ND 0.0010 mg/L 12/20/14 17:51 1



0.010 mg/L 12/20/14 17:51 12-Hexanone ND


0.050 mg/L 12/20/14 17:51 1Acetone ND


0.0010 mg/L 12/20/14 17:51 1Benzene ND



0.0010 mg/L 12/20/14 17:51 1Bromoform ND






0.0010 mg/L 12/20/14 17:51 1cis-1,2-Dichloroethene 0.0010









0.0010 mg/L 12/20/14 17:51 1Styrene ND


0.0050 mg/L 12/20/14 17:51 1Toluene ND













Toluene-d8 (Surr) 100 12/20/14 17:51 171 - 126


Barium 0.40 0.0020 mg/L 12/15/14 08:50 12/16/14 20:16 1


0.0010 mg/L 12/15/14 08:50 12/16/14 20:16 1Beryllium 0.0016

0.00050 mg/L 12/15/14 08:50 12/16/14 20:16 1Cadmium ND

0.0020 mg/L 12/15/14 08:50 12/16/14 20:16 1Chromium 0.0024

0.0010 mg/L 12/15/14 08:50 12/16/14 20:16 1Cobalt 0.029

0.0020 mg/L 12/15/14 08:50 12/17/14 11:49 1Copper 0.0079 B

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Method: 6010C - Metals (ICP) (Continued)RL MDL

Iron 19.3 0.10 mg/L 12/15/14 08:50 12/16/14 20:16 1


0.010 mg/L 12/15/14 08:50 12/16/14 20:16 1Manganese 0.29

0.0020 mg/L 12/15/14 08:50 12/16/14 20:16 1Vanadium ND

0.010 mg/L 12/15/14 08:50 12/16/14 20:16 1Zinc 0.051


Antimony ND 0.0010 mg/L 12/15/14 13:18 12/17/14 22:58 1


0.0010 mg/L 12/15/14 13:18 12/17/14 22:58 1Arsenic 0.014

0.0010 mg/L 12/15/14 13:18 12/17/14 22:58 1Lead ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:58 1Nickel 0.017

0.0010 mg/L 12/15/14 13:18 12/17/14 22:58 1Silver ND

0.0010 mg/L 12/15/14 13:18 12/17/14 22:58 1Selenium 0.0093

0.0010 mg/L 12/15/14 13:18 12/17/14 22:58 1Thallium ND


Mercury ND 0.00020 mg/L 12/15/14 09:30 12/15/14 14:26 1



Chloride 58.1 0.50 mg/L 12/17/14 18:28 1


2.0 mg/L 12/17/14 18:28 1Sulfate 20.9












0.0010 mg/L 12/20/14 18:13 11,1-Dichloroethane 0.0037





0.0010 mg/L 12/20/14 18:13 11,2-Dichloroethane 0.0011




0.010 mg/L 12/20/14 18:13 12-Hexanone ND


0.050 mg/L 12/20/14 18:13 1Acetone ND


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Benzene ND 0.0010 mg/L 12/20/14 18:13 1




0.0010 mg/L 12/20/14 18:13 1Bromoform ND






0.0010 mg/L 12/20/14 18:13 1cis-1,2-Dichloroethene 0.0012









0.0010 mg/L 12/20/14 18:13 1Styrene ND


0.0050 mg/L 12/20/14 18:13 1Toluene ND




0.0010 mg/L 12/20/14 18:13 1Trichloroethylene 0.0019









Toluene-d8 (Surr) 96 12/20/14 18:13 171 - 126


Barium 0.056 0.0020 mg/L 12/15/14 08:50 12/16/14 20:19 1


0.0010 mg/L 12/15/14 08:50 12/16/14 20:19 1Beryllium 0.0021

0.00050 mg/L 12/15/14 08:50 12/16/14 20:19 1Cadmium 0.0084

0.0020 mg/L 12/15/14 08:50 12/16/14 20:19 1Chromium ND

0.0010 mg/L 12/15/14 08:50 12/16/14 20:19 1Cobalt 0.027

0.0020 mg/L 12/15/14 08:50 12/16/14 20:19 1Copper 0.0073 B ^

0.10 mg/L 12/15/14 08:50 12/16/14 20:19 1Iron 1.7

0.010 mg/L 12/15/14 08:50 12/16/14 20:19 1Manganese 0.32

0.0020 mg/L 12/15/14 08:50 12/16/14 20:19 1Vanadium ND

0.010 mg/L 12/15/14 08:50 12/16/14 20:19 1Zinc 0.039

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Antimony ND 0.0010 mg/L 12/15/14 13:18 12/17/14 23:04 1


0.0010 mg/L 12/15/14 13:18 12/17/14 23:04 1Arsenic 0.0050

0.0010 mg/L 12/15/14 13:18 12/17/14 23:04 1Lead ND

0.0010 mg/L 12/15/14 13:18 12/17/14 23:04 1Nickel 0.041

0.0010 mg/L 12/15/14 13:18 12/17/14 23:04 1Silver ND

0.0010 mg/L 12/15/14 13:18 12/17/14 23:04 1Selenium 0.0023

0.0010 mg/L 12/15/14 13:18 12/17/14 23:04 1Thallium ND


Mercury ND 0.00020 mg/L 12/15/14 09:30 12/15/14 14:31 1



Chloride 252 5.0 mg/L 12/17/14 19:04 10


20.0 mg/L 12/17/14 19:04 10Sulfate 81.1





















0.010 mg/L 12/20/14 18:36 12-Hexanone ND


0.050 mg/L 12/20/14 18:36 1Acetone ND


0.0010 mg/L 12/20/14 18:36 1Benzene ND



0.0010 mg/L 12/20/14 18:36 1Bromoform ND




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Chloroethane ND 0.0050 mg/L 12/20/14 18:36 1












0.0010 mg/L 12/20/14 18:36 1Styrene ND


0.0050 mg/L 12/20/14 18:36 1Toluene ND













Toluene-d8 (Surr) 100 12/20/14 18:36 171 - 126


Barium 0.18 0.0020 mg/L 12/15/14 08:50 12/16/14 20:21 1


0.0010 mg/L 12/15/14 08:50 12/16/14 20:21 1Beryllium ND

0.00050 mg/L 12/15/14 08:50 12/16/14 20:21 1Cadmium 0.00057

0.0020 mg/L 12/15/14 08:50 12/16/14 20:21 1Chromium ND

0.0010 mg/L 12/15/14 08:50 12/16/14 20:21 1Cobalt 0.035

0.0020 mg/L 12/15/14 08:50 12/16/14 20:21 1Copper 0.0059 B ^

0.10 mg/L 12/15/14 08:50 12/16/14 20:21 1Iron 52.2

0.010 mg/L 12/15/14 08:50 12/16/14 20:21 1Manganese 1.0

0.0020 mg/L 12/15/14 08:50 12/16/14 20:21 1Vanadium ND

0.010 mg/L 12/15/14 08:50 12/16/14 20:21 1Zinc 0.025


Antimony ND 0.0010 mg/L 12/15/14 13:18 12/17/14 23:09 1


0.0010 mg/L 12/15/14 13:18 12/17/14 23:09 1Arsenic 0.0088

0.0010 mg/L 12/15/14 13:18 12/17/14 23:09 1Lead ND

0.0010 mg/L 12/15/14 13:18 12/17/14 23:09 1Nickel 0.028

0.0010 mg/L 12/15/14 13:18 12/17/14 23:09 1Silver ND

0.0010 mg/L 12/15/14 13:18 12/17/14 23:09 1Selenium 0.0037

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Method: 6020A - Metals (ICP/MS) (Continued)RL MDL

Thallium ND 0.0010 mg/L 12/15/14 13:18 12/17/14 23:09 1



Mercury ND 0.00020 mg/L 12/15/14 09:30 12/15/14 14:32 1



Chloride 24.3 0.50 mg/L 12/17/14 19:13 1


2.0 mg/L 12/17/14 19:13 1Sulfate ND





















0.010 mg/L 12/20/14 18:58 12-Hexanone ND


0.050 mg/L 12/20/14 18:58 1Acetone ND


0.0010 mg/L 12/20/14 18:58 1Benzene ND



0.0010 mg/L 12/20/14 18:58 1Bromoform ND










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Methyl bromide ND 0.0050 mg/L 12/20/14 18:58 1






0.0010 mg/L 12/20/14 18:58 1Styrene ND


0.0050 mg/L 12/20/14 18:58 1Toluene ND













Toluene-d8 (Surr) 98 12/20/14 18:58 171 - 126


Barium ND 0.0020 mg/L 12/15/14 08:50 12/16/14 20:24 1


0.0010 mg/L 12/15/14 08:50 12/16/14 20:24 1Beryllium ND

0.00050 mg/L 12/15/14 08:50 12/16/14 20:24 1Cadmium ND

0.0020 mg/L 12/15/14 08:50 12/16/14 20:24 1Chromium ND

0.0010 mg/L 12/15/14 08:50 12/16/14 20:24 1Cobalt ND

0.0020 mg/L 12/15/14 08:50 12/16/14 20:24 1Copper 0.0077 B ^

0.10 mg/L 12/15/14 08:50 12/16/14 20:24 1Iron ND

0.010 mg/L 12/15/14 08:50 12/16/14 20:24 1Manganese ND

0.0020 mg/L 12/15/14 08:50 12/16/14 20:24 1Vanadium ND

0.010 mg/L 12/15/14 08:50 12/16/14 20:24 1Zinc ND


Antimony ND 0.0010 mg/L 12/15/14 13:18 12/17/14 23:15 1


0.0010 mg/L 12/15/14 13:18 12/17/14 23:15 1Arsenic ND

0.0010 mg/L 12/15/14 13:18 12/17/14 23:15 1Lead ND

0.0010 mg/L 12/15/14 13:18 12/17/14 23:15 1Nickel ND

0.0010 mg/L 12/15/14 13:18 12/17/14 23:15 1Silver ND

0.0010 mg/L 12/15/14 13:18 12/17/14 23:15 1Selenium ND

0.0010 mg/L 12/15/14 13:18 12/17/14 23:15 1Thallium ND


Mercury ND 0.00020 mg/L 12/15/14 09:30 12/15/14 14:34 1


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Chloride ND 0.50 mg/L 12/17/14 19:23 1


2.0 mg/L 12/17/14 19:23 1Sulfate ND



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Surrogate SummaryTestAmerica Job ID: 480-72941-1Client: Waste Corporation of America


Method: 8260C - Volatile Organic Compounds by GC/MSPrep Type: Total/NAMatrix: Water

Lab Sample ID Client Sample ID (66-137) (73-120) (60-140) (71-126)

12DCE BFB DBFM TOL

109 90 106 97480-72941-1

Percent Surrogate Recovery (Acceptance Limits)

MW-2

108 89 104 97480-72941-2 MW-5R

111 91 108 100480-72941-3 MW-6

111 91 107 98480-72941-4 MW-12

111 91 107 97480-72941-5 MW-7

108 91 110 97480-72941-6 MW-8

109 90 105 98480-72941-7 MW-14

111 94 107 99480-72941-8 MW-20

112 92 106 100480-72941-9 Leachate

102 91 103 99480-72941-9 MS Leachate

107 92 104 100480-72941-9 MSD Leachate

107 91 105 100480-72941-10 MW-4

109 89 105 96480-72941-11 MW-9

112 92 109 100480-72941-12 MW-18

109 92 108 98480-72941-13 MW-21

104 93 103 96LCS 480-220234/5 Lab Control Sample

109 90 104 97MB 480-220234/7 Method Blank

Surrogate Legend

12DCE = 1,2-Dichloroethane-d4 (Surr)

BFB = 4-Bromofluorobenzene (Surr)

DBFM = Dibromofluoromethane (Surr)

TOL = Toluene-d8 (Surr)

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QC Sample ResultsTestAmerica Job ID: 480-72941-1Client: Waste Corporation of America


Method: 8260C - Volatile Organic Compounds by GC/MS

Client Sample ID: Method BlankLab Sample ID: MB 480-220234/7

Matrix: Water Prep Type: Total/NA

Analysis Batch: 220234

RL MDL


MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

ND 0.0010 mg/L 12/20/14 12:28 11,1,1-Trichloroethane

ND 0.0010 mg/L 12/20/14 12:28 11,1,2,2-Tetrachloroethane

ND 0.0010 mg/L 12/20/14 12:28 11,1,2-Trichloroethane

ND 0.0010 mg/L 12/20/14 12:28 11,1-Dichlorethylene

ND 0.0010 mg/L 12/20/14 12:28 11,1-Dichloroethane

ND 0.0025 mg/L 12/20/14 12:28 11,2,3-Trichloropropane

ND 0.0050 mg/L 12/20/14 12:28 11,2-Dibromo-3-Chloropropane

ND 0.0010 mg/L 12/20/14 12:28 11,2-Dibromoethane

ND 0.0010 mg/L 12/20/14 12:28 11,2-Dichlorobenzene

ND 0.0010 mg/L 12/20/14 12:28 11,2-Dichloroethane

ND 0.0010 mg/L 12/20/14 12:28 11,2-Dichloropropane

ND 0.0010 mg/L 12/20/14 12:28 11,4-Dichlorobenzene

ND 0.015 mg/L 12/20/14 12:28 12-Butanone (MEK)

ND 0.010 mg/L 12/20/14 12:28 12-Hexanone

ND 0.010 mg/L 12/20/14 12:28 14-Methyl-2-pentanone (MIBK)

ND 0.050 mg/L 12/20/14 12:28 1Acetone

ND 0.010 mg/L 12/20/14 12:28 1Acrylonitrile

ND 0.0010 mg/L 12/20/14 12:28 1Benzene

ND 0.0010 mg/L 12/20/14 12:28 1Bromochloromethane

ND 0.0010 mg/L 12/20/14 12:28 1Bromodichloromethane

ND 0.0010 mg/L 12/20/14 12:28 1Bromoform

ND 0.0010 mg/L 12/20/14 12:28 1Carbon disulfide

ND 0.0010 mg/L 12/20/14 12:28 1Carbon tetrachloride

ND 0.0010 mg/L 12/20/14 12:28 1Chlorobenzene

ND 0.0050 mg/L 12/20/14 12:28 1Chloroethane

ND 0.0050 mg/L 12/20/14 12:28 1Chloroform

ND 0.0010 mg/L 12/20/14 12:28 1cis-1,2-Dichloroethene

ND 0.0010 mg/L 12/20/14 12:28 1cis-1,3-Dichloropropene

ND 0.0010 mg/L 12/20/14 12:28 1Dibromochloromethane

ND 0.0010 mg/L 12/20/14 12:28 1Ethylbenzene

ND 0.0050 mg/L 12/20/14 12:28 1Methyl bromide

ND 0.0025 mg/L 12/20/14 12:28 1Methyl chloride

ND 0.010 mg/L 12/20/14 12:28 1Methyl iodide

ND 0.0010 mg/L 12/20/14 12:28 1Methylene bromide

ND 0.0050 mg/L 12/20/14 12:28 1Methylene Chloride

ND 0.0010 mg/L 12/20/14 12:28 1Styrene

ND 0.0010 mg/L 12/20/14 12:28 1Tetrachloroethene

ND 0.0050 mg/L 12/20/14 12:28 1Toluene

ND 0.0010 mg/L 12/20/14 12:28 1trans-1,2-Dichloroethene

ND 0.0010 mg/L 12/20/14 12:28 1trans-1,3-Dichloropropene

ND 0.0025 mg/L 12/20/14 12:28 1trans-1,4-Dichloro-2-butene

ND 0.0010 mg/L 12/20/14 12:28 1Trichloroethylene

ND 0.0050 mg/L 12/20/14 12:28 1Trichlorofluoromethane

ND 0.010 mg/L 12/20/14 12:28 1Vinyl acetate

ND 0.0010 mg/L 12/20/14 12:28 1Vinyl chloride

ND 0.0030 mg/L 12/20/14 12:28 1Xylenes, Total

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MB MB

Surrogate Dil FacPrepared AnalyzedQualifier Limits%Recovery

90 12/20/14 12:28 14-Bromofluorobenzene (Surr) 73 - 120

104 12/20/14 12:28 1Dibromofluoromethane (Surr) 60 - 140

97 12/20/14 12:28 1Toluene-d8 (Surr) 71 - 126

Client Sample ID: Lab Control SampleLab Sample ID: LCS 480-220234/5



1,1-Dichlorethylene 0.0250 0.0251 mg/L 100 58 - 121

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec.

Limits

1,1-Dichloroethane 0.0250 0.0264 mg/L 105 71 - 129

1,2-Dichlorobenzene 0.0250 0.0264 mg/L 105 80 - 124

1,2-Dichloroethane 0.0250 0.0282 mg/L 113 75 - 127

Acrylonitrile 0.250 0.230 mg/L 92 63 - 138

Benzene 0.0250 0.0257 mg/L 103 71 - 124

Chlorobenzene 0.0250 0.0251 mg/L 100 72 - 120

cis-1,2-Dichloroethene 0.0250 0.0258 mg/L 103 74 - 124

Ethylbenzene 0.0250 0.0258 mg/L 103 77 - 123

Tetrachloroethene 0.0250 0.0240 mg/L 96 74 - 122

Toluene 0.0250 0.0257 mg/L 103 80 - 122

trans-1,2-Dichloroethene 0.0250 0.0248 mg/L 99 73 - 127

Trichloroethylene 0.0250 0.0263 mg/L 105 74 - 123

1,2-Dichloroethane-d4 (Surr) 66 - 137

Surrogate

104

LCS LCS

Qualifier Limits%Recovery

934-Bromofluorobenzene (Surr) 73 - 120

103Dibromofluoromethane (Surr) 60 - 140

96Toluene-d8 (Surr) 71 - 126

Client Sample ID: LeachateLab Sample ID: 480-72941-9 MS



1,1-Dichlorethylene ND 0.500 0.454 mg/L 91 58 - 121

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

1,1-Dichloroethane ND 0.500 0.499 mg/L 100 71 - 129

1,2-Dichlorobenzene ND 0.500 0.514 mg/L 103 80 - 124

1,2-Dichloroethane ND 0.500 0.528 mg/L 106 75 - 127

Acrylonitrile ND 5.00 4.54 mg/L 91 63 - 138

Benzene ND 0.500 0.504 mg/L 98 71 - 124

Chlorobenzene ND 0.500 0.487 mg/L 97 72 - 120

cis-1,2-Dichloroethene ND 0.500 0.503 mg/L 101 74 - 124

Ethylbenzene ND 0.500 0.496 mg/L 99 77 - 123

Tetrachloroethene ND 0.500 0.437 mg/L 87 74 - 122

Toluene ND 0.500 0.488 mg/L 98 80 - 122

trans-1,2-Dichloroethene ND 0.500 0.478 mg/L 96 73 - 127

Trichloroethylene ND 0.500 0.489 mg/L 98 74 - 123

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Client Sample ID: LeachateLab Sample ID: 480-72941-9 MS




Surrogate

102

MS MS





Client Sample ID: LeachateLab Sample ID: 480-72941-9 MSD



1,1-Dichlorethylene ND 0.500 0.518 mg/L 104 58 - 121 13 16

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

1,1-Dichloroethane ND 0.500 0.529 mg/L 106 71 - 129 6 20

1,2-Dichlorobenzene ND 0.500 0.524 mg/L 105 80 - 124 2 20

1,2-Dichloroethane ND 0.500 0.545 mg/L 109 75 - 127 3 20

Acrylonitrile ND 5.00 4.62 mg/L 92 63 - 138 2 20

Benzene ND 0.500 0.535 mg/L 105 71 - 124 6 13

Chlorobenzene ND 0.500 0.501 mg/L 100 72 - 120 3 25

cis-1,2-Dichloroethene ND 0.500 0.526 mg/L 105 74 - 124 5 15

Ethylbenzene ND 0.500 0.520 mg/L 104 77 - 123 5 15

Tetrachloroethene ND 0.500 0.470 mg/L 94 74 - 122 7 20

Toluene ND 0.500 0.517 mg/L 103 80 - 122 6 15

trans-1,2-Dichloroethene ND 0.500 0.516 mg/L 103 73 - 127 8 20

Trichloroethylene ND 0.500 0.518 mg/L 104 74 - 123 6 16


Surrogate

107

MSD MSD





Method: 6010C - Metals (ICP)

Client Sample ID: Method BlankLab Sample ID: MB 480-219088/1-A


Analysis Batch: 219551 Prep Batch: 219088

RL MDL

Barium ND 0.0020 mg/L 12/15/14 08:50 12/16/14 19:23 1

MB MB


ND 0.0010 mg/L 12/15/14 08:50 12/16/14 19:23 1Beryllium

ND 0.00050 mg/L 12/15/14 08:50 12/16/14 19:23 1Cadmium

ND 0.0020 mg/L 12/15/14 08:50 12/16/14 19:23 1Chromium

ND 0.0010 mg/L 12/15/14 08:50 12/16/14 19:23 1Cobalt

0.00628 ^ 0.0020 mg/L 12/15/14 08:50 12/16/14 19:23 1Copper

ND 0.10 mg/L 12/15/14 08:50 12/16/14 19:23 1Iron

ND 0.010 mg/L 12/15/14 08:50 12/16/14 19:23 1Manganese

ND 0.0020 mg/L 12/15/14 08:50 12/16/14 19:23 1Vanadium

ND 0.010 mg/L 12/15/14 08:50 12/16/14 19:23 1Zinc

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Method: 6010C - Metals (ICP) (Continued)

Client Sample ID: Lab Control SampleLab Sample ID: LCS 480-219088/2-A



Barium 0.200 0.203 mg/L 102 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Beryllium 0.200 0.201 mg/L 101 80 - 120

Cadmium 0.200 0.208 mg/L 104 80 - 120

Chromium 0.200 0.199 mg/L 99 80 - 120

Cobalt 0.200 0.198 mg/L 99 80 - 120

Copper 0.200 0.220 ^ mg/L 110 80 - 120

Iron 10.0 9.88 mg/L 99 80 - 120

Manganese 0.200 0.207 mg/L 103 80 - 120

Vanadium 0.200 0.218 mg/L 109 80 - 120

Zinc 0.200 0.206 mg/L 103 80 - 120

Client Sample ID: MW-21Lab Sample ID: 480-72941-13 MS



Barium ND 0.200 0.204 mg/L 102 75 - 125

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Beryllium ND 0.200 0.206 mg/L 103 75 - 125

Cadmium ND 0.200 0.210 mg/L 105 75 - 125

Chromium ND 0.200 0.204 mg/L 102 75 - 125

Cobalt ND 0.200 0.201 mg/L 101 75 - 125

Copper 0.0077 B ^ 0.200 0.224 ^ mg/L 108 75 - 125

Iron ND 10.0 10.18 mg/L 102 75 - 125

Manganese ND 0.200 0.213 ^ mg/L 106 75 - 125

Vanadium ND 0.200 0.226 mg/L 113 75 - 125

Zinc ND 0.200 0.221 mg/L 108 75 - 125

Client Sample ID: MW-21Lab Sample ID: 480-72941-13 MSD



Barium ND 0.200 0.202 mg/L 101 75 - 125 1 20

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Beryllium ND 0.200 0.203 mg/L 101 75 - 125 2 20

Cadmium ND 0.200 0.207 mg/L 103 75 - 125 2 20

Chromium ND 0.200 0.203 mg/L 102 75 - 125 1 20

Cobalt ND 0.200 0.198 mg/L 99 75 - 125 2 20

Copper 0.0077 B ^ 0.200 0.224 ^ mg/L 108 75 - 125 0 20

Iron ND 10.0 10.02 mg/L 100 75 - 125 2 20

Manganese ND 0.200 0.210 ^ mg/L 105 75 - 125 1 20

Vanadium ND 0.200 0.226 mg/L 113 75 - 125 0 20

Zinc ND 0.200 0.220 mg/L 108 75 - 125 0 20




RL MDL

Barium ND 0.0020 mg/L 12/15/14 10:54 12/16/14 18:30 1

MB MB


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RL MDL

Beryllium ND 0.0010 mg/L 12/15/14 10:54 12/16/14 18:30 1

MB MB


ND 0.00050 mg/L 12/15/14 10:54 12/16/14 18:30 1Cadmium

ND 0.0020 mg/L 12/15/14 10:54 12/16/14 18:30 1Chromium

ND 0.0010 mg/L 12/15/14 10:54 12/16/14 18:30 1Cobalt

ND 0.10 mg/L 12/15/14 10:54 12/16/14 18:30 1Iron

ND 0.0020 mg/L 12/15/14 10:54 12/16/14 18:30 1Vanadium




RL MDL

Copper ND 0.0020 mg/L 12/15/14 10:54 12/18/14 12:31 1

MB MB


ND 0.010 mg/L 12/15/14 10:54 12/18/14 12:31 1Manganese

ND 0.010 mg/L 12/15/14 10:54 12/18/14 12:31 1Zinc




Barium 0.200 0.212 mg/L 106 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Beryllium 0.200 0.203 mg/L 101 80 - 120

Cadmium 0.200 0.209 mg/L 105 80 - 120

Chromium 0.200 0.215 mg/L 108 80 - 120

Cobalt 0.200 0.210 mg/L 105 80 - 120

Iron 10.0 11.04 mg/L 110 80 - 120

Vanadium 0.200 0.231 mg/L 115 80 - 120

Zinc 0.200 0.217 mg/L 109 80 - 120




Copper 0.200 0.202 mg/L 101 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Manganese 0.200 0.202 mg/L 101 80 - 120

Zinc 0.200 0.212 mg/L 106 80 - 120

Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 480-219173/3-A



Barium 0.200 0.213 mg/L 107 80 - 120 1 20

Analyte

LCSD LCSD


Spike

Added

%Rec.

Limits LimitRPD

RPD

Beryllium 0.200 0.204 mg/L 102 80 - 120 0 20

Cadmium 0.200 0.211 mg/L 106 80 - 120 1 20

Chromium 0.200 0.218 mg/L 109 80 - 120 1 20

Cobalt 0.200 0.212 mg/L 106 80 - 120 1 20

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Iron 10.0 10.96 mg/L 110 80 - 120 1 20

Analyte

LCSD LCSD


Spike

Added

%Rec.

Limits LimitRPD

RPD

Vanadium 0.200 0.232 mg/L 116 80 - 120 1 20

Zinc 0.200 0.219 mg/L 110 80 - 120 1 20




Copper 0.200 0.206 mg/L 103 80 - 120 2 20

Analyte

LCSD LCSD


Spike

Added

%Rec.

Limits LimitRPD

RPD

Manganese 0.200 0.206 mg/L 103 80 - 120 2 20

Zinc 0.200 0.215 mg/L 108 80 - 120 1 20

Method: 6020A - Metals (ICP/MS)




RL MDL

Antimony ND 0.0010 mg/L 12/15/14 13:18 12/17/14 20:20 1

MB MB


ND 0.0010 mg/L 12/15/14 13:18 12/17/14 20:20 1Arsenic

ND 0.0010 mg/L 12/15/14 13:18 12/17/14 20:20 1Nickel

ND 0.0010 mg/L 12/15/14 13:18 12/17/14 20:20 1Silver

ND 0.0010 mg/L 12/15/14 13:18 12/17/14 20:20 1Selenium




RL MDL

Lead ND 0.0010 mg/L 12/15/14 13:18 12/18/14 19:05 1

MB MB


ND 0.0010 mg/L 12/15/14 13:18 12/18/14 19:05 1Thallium




Arsenic 0.0200 0.0196 mg/L 98 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Nickel 0.0200 0.0201 mg/L 101 80 - 120

Silver 0.0200 0.0198 mg/L 99 80 - 120

Selenium 0.0200 0.0196 mg/L 98 80 - 120

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Method: 6020A - Metals (ICP/MS) (Continued)




Lead 0.0200 0.0198 mg/L 99 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Thallium 0.0200 0.0199 mg/L 100 80 - 120

Method: 7470A - Mercury (CVAA)




RL MDL

Mercury ND 0.00020 mg/L 12/15/14 09:30 12/15/14 13:30 1

MB MB





Mercury 0.00667 0.00682 mg/L 102 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits




RL MDL

Mercury ND 0.00020 mg/L 12/15/14 09:30 12/15/14 14:19 1

MB MB





Mercury 0.00667 0.00658 mg/L 99 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits




Mercury 0.00667 0.00683 mg/L 102 80 - 120 4 20

Analyte

LCSD LCSD


Spike

Added

%Rec.

Limits LimitRPD

RPD




RL MDL

Mercury ND 0.00020 mg/L 12/16/14 08:45 12/16/14 13:48 1

MB MB


TestAmerica Buffalo

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Method: 7470A - Mercury (CVAA) (Continued)




Mercury 0.00667 0.00673 mg/L 101 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits




Mercury 0.00667 0.00657 mg/L 98 80 - 120 3 20

Analyte

LCSD LCSD


Spike

Added

%Rec.

Limits LimitRPD

RPD

Method: 9056A - Anions, Ion Chromatography




RL MDL

Chloride ND 0.50 mg/L 12/17/14 16:56 1

MB MB


ND 2.0 mg/L 12/17/14 16:56 1Sulfate




Chloride 20.0 19.32 mg/L 97 83 - 121

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Sulfate 20.0 19.49 mg/L 97 80 - 129




Chloride 58.1 25.0 81.21 mg/L 93 83 - 121

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Sulfate 20.9 25.0 45.49 mg/L 99 80 - 129




Chloride ND 25.0 24.41 mg/L 98 83 - 121

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Sulfate ND 25.0 24.60 mg/L 98 80 - 129




RL MDL

Chloride ND 0.50 mg/L 12/18/14 21:17 1

MB MB


TestAmerica Buffalo

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Method: 9056A - Anions, Ion Chromatography (Continued)




RL MDL

Sulfate ND 2.0 mg/L 12/18/14 21:17 1

MB MB





Chloride 20.0 20.45 mg/L 102 83 - 121

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Sulfate 20.0 20.44 mg/L 102 80 - 129

Method: 9060A - Organic Carbon, Total (TOC)




RL MDL

Total Organic Carbon ND 1.0 mg/L 12/20/14 03:38 1

MB MB





RL MDL


MB MB





Total Organic Carbon 60.0 61.34 mg/L 102 90 - 110

Analyte

LCS LCS


Spike

Added

%Rec.

Limits





Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Client Sample ID: MW-5RLab Sample ID: 480-72941-2 MS



Total Organic Carbon ND 20.0 23.01 mg/L 111 54 - 131

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

TestAmerica Buffalo

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Method: 9060A - Organic Carbon, Total (TOC) (Continued)




Total Organic Carbon 1.3 20.0 22.08 mg/L 104 54 - 131

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Client Sample ID: MW-2Lab Sample ID: 480-72941-1 DU



Total Organic Carbon 6.4 6.23 mg/L 3 20

Analyte

DU DU

DUnitResult Qualifier

Sample

Result

Sample

Qualifier LimitRPD

RPD




Total Organic Carbon 9.1 8.99 mg/L 2 20

Analyte

DU DU


Sample

Result

Sample

Qualifier LimitRPD

RPD




RL MDL


MB MB






Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Method: SM 2540C - Solids, Total Dissolved (TDS)




RL MDL

Total Dissolved Solids ND 10.0 mg/L 12/15/14 22:04 1

MB MB





Total Dissolved Solids 505 490.0 mg/L 97 85 - 115

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

TestAmerica Buffalo

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Method: SM 2540C - Solids, Total Dissolved (TDS) (Continued)




Total Dissolved Solids 56.0 65.00 mg/L 15 20

Analyte

DU DU


Sample

Result

Sample

Qualifier LimitRPD

RPD




RL MDL

Total Dissolved Solids ND 10.0 mg/L 12/16/14 16:34 1

MB MB





Total Dissolved Solids 504 529.0 mg/L 105 85 - 115

Analyte

LCS LCS


Spike

Added

%Rec.

Limits




Total Dissolved Solids 71.0 80.00 mg/L 12 20

Analyte

DU DU


Sample

Result

Sample

Qualifier LimitRPD

RPD

TestAmerica Buffalo

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QC Association SummaryTestAmerica Job ID: 480-72941-1Client: Waste Corporation of America


GC/MS VOA


Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Water 8260C480-72941-1 MW-2 Total/NA

Water 8260C480-72941-2 MW-5R Total/NA







Water 8260C480-72941-9 Leachate Total/NA

Water 8260C480-72941-9 MS Leachate Total/NA

Water 8260C480-72941-9 MSD Leachate Total/NA





Water 8260CLCS 480-220234/5 Lab Control Sample Total/NA

Water 8260CMB 480-220234/7 Method Blank Total/NA

Metals

Prep Batch: 219081


Water 7470A480-72941-1 MW-2 Total/NA

Water 7470A480-72941-2 MW-5R Total/NA





Water 7470ALCS 480-219081/2-A Lab Control Sample Total/NA

Water 7470AMB 480-219081/1-A Method Blank Total/NA

Prep Batch: 219082









Water 7470ALCSD 480-219082/24-A Lab Control Sample Dup Total/NA


Prep Batch: 219088







TestAmerica Buffalo

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Metals (Continued)

Prep Batch: 219088 (Continued)









Water 3005A480-72941-13 MS MW-21 Total/NA

Water 3005A480-72941-13 MSD MW-21 Total/NA



Prep Batch: 219170










Water 3020A480-72941-9 Leachate Total/NA







Prep Batch: 219173








Water 7470A 219081480-72941-1 MW-2 Total/NA

Water 7470A 219081480-72941-2 MW-5R Total/NA











TestAmerica Buffalo

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Metals (Continued)

Analysis Batch: 219286 (Continued)


Water 7470A 219081LCS 480-219081/2-A Lab Control Sample Total/NA


Water 7470A 219082LCSD 480-219082/24-A Lab Control Sample Dup Total/NA

Water 7470A 219081MB 480-219081/1-A Method Blank Total/NA


Prep Batch: 219300








Water 7470A 219300480-72941-9 Leachate Total/NA


Water 7470A 219300LCSD 480-219300/3-A Lab Control Sample Dup Total/NA




Water 6010C 219088480-72941-1 MW-2 Total/NA

Water 6010C 219088480-72941-2 MW-5R Total/NA











Water 6010C 219088480-72941-13 MS MW-21 Total/NA

Water 6010C 219088480-72941-13 MSD MW-21 Total/NA

Water 6010C 219088LCS 480-219088/2-A Lab Control Sample Total/NA

Water 6010C 219088MB 480-219088/1-A Method Blank Total/NA



Water 6010C 219173480-72941-9 Leachate Total/NA


Water 6010C 219173LCSD 480-219173/3-A Lab Control Sample Dup Total/NA





TestAmerica Buffalo

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Metals (Continued)




Water 6020A 219170480-72941-2 MW-5R Total/NA







Water 6020A 219170480-72941-9 Leachate Total/NA









Water 6010C 219173480-72941-9 Leachate Total/NA


Water 6010C 219173LCSD 480-219173/3-A Lab Control Sample Dup Total/NA






General Chemistry



Water SM 2540C480-72941-1 MW-2 Total/NA



Water SM 2540C480-72941-7 DU MW-14 Total/NA

Water SM 2540CLCS 480-219258/2 Lab Control Sample Total/NA

Water SM 2540CMB 480-219258/1 Method Blank Total/NA



Water SM 2540C480-72941-2 MW-5R Total/NA




Water SM 2540C480-72941-6 DU MW-8 Total/NA


Water SM 2540C480-72941-9 Leachate Total/NA



TestAmerica Buffalo

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General Chemistry (Continued)





Water SM 2540CLCS 480-219468/2 Lab Control Sample Total/NA

Water SM 2540CMB 480-219468/1 Method Blank Total/NA


















Water 9056ALCS 480-219673/3 Lab Control Sample Total/NA

Water 9056AMB 480-219673/4 Method Blank Total/NA










Water 9060A480-72941-1 DU MW-2 Total/NA


Water 9060A480-72941-2 MS MW-5R Total/NA


Water 9060A480-72941-3 DU MW-6 Total/NA












TestAmerica Buffalo

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General Chemistry (Continued)











TestAmerica Buffalo

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Lab ChronicleClient: Waste Corporation of America TestAmerica Job ID: 480-72941-1


Client Sample ID: MW-2 Lab Sample ID: 480-72941-1Matrix: WaterDate Collected: 12/09/14 16:35


Analysis 8260C 12/20/14 14:30 NMD11 220234 TAL BUF

Type

Batch Batch

MethodPrep Type LabAnalystRun

Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA

Prep 3005A 219088 12/15/14 08:50 TAS TAL BUFTotal/NA

Analysis 6010C 1 219551 12/16/14 19:47 LMH TAL BUFTotal/NA


Analysis 6020A 1 219940 12/17/14 21:49 MTM2 TAL BUFTotal/NA

Prep 7470A 219081 12/15/14 09:30 LRK TAL BUFTotal/NA

Analysis 7470A 1 219286 12/15/14 14:05 LRK TAL BUFTotal/NA

Analysis 9056A 1 219673 12/17/14 17:05 NDB TAL BUFTotal/NA

Analysis 9060A 1 220394 12/19/14 16:40 CAS TAL BUFTotal/NA

Analysis SM 2540C 1 219258 12/15/14 22:04 JMB TAL BUFTotal/NA

Client Sample ID: MW-5R Lab Sample ID: 480-72941-2Matrix: WaterDate Collected: 12/10/14 10:00



Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA









Analysis SM 2540C 1 219468 12/16/14 16:34 RP TAL BUFTotal/NA




Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA










TestAmerica Buffalo

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Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA













Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA














Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA









TestAmerica Buffalo

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Analysis SM 2540C 12/16/14 16:34 RP1 219468 TAL BUF

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA




Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA













Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA











Client Sample ID: Leachate Lab Sample ID: 480-72941-9Matrix: WaterDate Collected: 12/11/14 11:00



Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA


TestAmerica Buffalo

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Client Sample ID: Leachate Lab Sample ID: 480-72941-9Matrix: WaterDate Collected: 12/11/14 11:00


Analysis 6010C 12/16/14 19:04 AMH1 219608 TAL BUF

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA


Analysis 6010C 1 220046 12/18/14 12:50 TRB TAL BUFTotal/NA











Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA




Analysis 6010C 1 219849 12/17/14 11:49 AMH TAL BUFTotal/NA











Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA








TestAmerica Buffalo

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Analysis 9060A 12/20/14 00:39 CAS1 220394 TAL BUF

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA





Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA













Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA










Laboratory References:

TAL BUF = TestAmerica Buffalo, 10 Hazelwood Drive, Amherst, NY 14228-2298, TEL (716)691-2600

TestAmerica Buffalo

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Certification SummaryClient: Waste Corporation of America TestAmerica Job ID: 480-72941-1


Laboratory: TestAmerica BuffaloUnless otherwise noted, all analytes for this laboratory were covered under each certification below.

Authority Program EPA Region Certification ID Expiration Date

Arkansas DEQ 88-06866State Program 07-06-15

Analysis Method Prep Method Matrix Analyte

The following analytes are included in this report, but certification is not offered by the governing authority:

9056A Water Chloride

9056A Water Sulfate

TestAmerica Buffalo

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Method SummaryTestAmerica Job ID: 480-72941-1Client: Waste Corporation of America


Method Method Description LaboratoryProtocol

SW8468260C Volatile Organic Compounds by GC/MS TAL BUF

SW8466010C Metals (ICP) TAL BUF

SW8466020A Metals (ICP/MS) TAL BUF

SW8467470A Mercury (CVAA) TAL BUF

SW8469056A Anions, Ion Chromatography TAL BUF

SW8469060A Organic Carbon, Total (TOC) TAL BUF

SMSM 2540C Solids, Total Dissolved (TDS) TAL BUF

Protocol References:

SM = "Standard Methods For The Examination Of Water And Wastewater",

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory References:

TAL BUF = TestAmerica Buffalo, 10 Hazelwood Drive, Amherst, NY 14228-2298, TEL (716)691-2600

TestAmerica Buffalo

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Sample SummaryTestAmerica Job ID: 480-72941-1Client: Waste Corporation of America


Lab Sample ID Client Sample ID ReceivedCollectedMatrix

480-72941-1 MW-2 Water 12/09/14 16:35 12/12/14 09:00

480-72941-2 MW-5R Water 12/10/14 10:00 12/12/14 09:00

480-72941-3 MW-6 Water 12/10/14 11:00 12/12/14 09:00

480-72941-4 MW-12 Water 12/09/14 15:40 12/12/14 09:00

480-72941-5 MW-7 Water 12/10/14 13:00 12/12/14 09:00

480-72941-6 MW-8 Water 12/10/14 14:45 12/12/14 09:00

480-72941-7 MW-14 Water 12/09/14 14:30 12/12/14 09:00

480-72941-8 MW-20 Water 12/10/14 13:10 12/12/14 09:00

480-72941-9 Leachate Water 12/11/14 11:00 12/12/14 09:00

480-72941-10 MW-4 Water 12/10/14 15:55 12/12/14 09:00

480-72941-11 MW-9 Water 12/11/14 09:45 12/12/14 09:00

480-72941-12 MW-18 Water 12/11/14 08:35 12/12/14 09:00

480-72941-13 MW-21 Water 12/11/14 10:30 12/12/14 09:00

TestAmerica Buffalo

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Detection Limit Exceptions SummaryClient: Waste Corporation of America TestAmerica Job ID: 480-72941-1


Method Lab PQLClient RLUnitsAnalyteMatrix

The requested project specific reporting limits listed below were less than laboratory standard quantitation limits (PQL) but greater

than or equal to the laboratory method detection limits (MDL). It must be noted that results reported below lab standard

quantitation limits may result in false positive/false negative values and less accurate quantitation. Routine laboratory procedures

do not indicate corrective action for detections below the laboratory's PQL.

6010C 0.0020.0010mg/LBerylliumWater

6010C 0.0020.00050mg/LCadmiumWater

6010C 0.0040.0020mg/LChromiumWater

6010C 0.0040.0010mg/LCobaltWater

6010C 0.010.0020mg/LCopperWater

6010C 0.0050.0020mg/LVanadiumWater

TestAmerica Buffalo

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Login Sample Receipt Checklist

Client: Waste Corporation of America Job Number: 480-72941-1

Login Number: 72941

Question Answer Comment

Creator: Kolb, Chris M

List Source: TestAmerica Buffalo

List Number: 1

TrueRadioactivity either was not measured or, if measured, is at or below

background

TrueThe cooler's custody seal, if present, is intact.

TrueThe cooler or samples do not appear to have been compromised or

tampered with.

TrueSamples were received on ice.

TrueCooler Temperature is acceptable.

TrueCooler Temperature is recorded.

TrueCOC is present.

TrueCOC is filled out in ink and legible.

TrueCOC is filled out with all pertinent information.

TrueIs the Field Sampler's name present on COC?

TrueThere are no discrepancies between the sample IDs on the containers and

the COC.

TrueSamples are received within Holding Time.

TrueSample containers have legible labels.

TrueContainers are not broken or leaking.

TrueSample collection date/times are provided.

TrueAppropriate sample containers are used.

TrueSample bottles are completely filled.

TrueSample Preservation Verified

TrueThere is sufficient vol. for all requested analyses, incl. any requested

MS/MSDs

TrueVOA sample vials do not have headspace or bubble is <6mm (1/4") in

diameter.

TrueIf necessary, staff have been informed of any short hold time or quick TAT

needs

TrueMultiphasic samples are not present.

TrueSamples do not require splitting or compositing.

TrueSampling Company provided. FTN ASSOC.

FalseSamples received within 48 hours of sampling.

TrueSamples requiring field filtration have been filtered in the field.

N/AChlorine Residual checked.


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