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April 8, 2016 D825-TV Plastics Advisor Alert (TechVision) Plastics for the Aerospace Industry Thermoplastics and composites can replace metals and thermosets in the aerospace industry

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April 8, 2016

D825-TV

Plastics Advisor Alert

(TechVision)

Plastics for the Aerospace Industry

Thermoplastics and composites can replace metals and

thermosets in the aerospace industry

2 D825-TV

Section Slide Numbers

Innovations in Plastics for the Aerospace Industry 3

Openair Plasma Technology by Plasmatreat 4

KYDEX by Curbell Plastics 5

Tegralite by Solvay 6

Nylatron® 66 SA FST by Quadrant Engineering Plastic Products 7

SPD-Smart Electronically Dimmable Windows by Isoclima 8

VICTREX PAEK by Victrex 9

3D Printed Economy Class Seat that can Reduce Aeroplane Costs by SABIC 10

ThermoPlastic Consolidated Laminate by Toho Tenax 11

Strategic Insights 12

Key Patents 15

Industry Contacts 18

Contents

3 D825-TV

Innovations in Plastics for the Aerospace Industry

4 D825-TV

1

2

3

Pretreatment methods, which are normally used, do not activate

the surface to a great degree like corona treatment.

Usually, the pretreatment processes involve the use of solvents

containing volatile organic compounds (VOCs) which are

harmful for the environment.

The pretreatment methods normally produce a lot of scrap and

the processes are not in-line with mechanical methods such as

roughening.

Unmet Needs Technology Profile

Who

The technology was

developed by Plasmatreat, a

US-based company involved

in the development of high

efficiency surface

pretreatment methods for

various types of materials.

Where

This technology was

developed in the company’s

manufacturing facility in

Illinois, USA.

What

Openair Plasma is a simple, safe, and

environmental friendly technology.

This does not require any chamber system unlike

the low pressure plasma technology

It can be used for cleaning; activating; and coating

plastics metals, glass, and composites

Here; the process can be done under normal

pressure; only air, electrical power, and the

production line are required.

Innovation Attributes

This technology can be used

to treat carbon fiber

reinforced plastics which are

used in aircraft. It improves

the stability of the plastics.

This technology helps in

superior quality processing in

downstream bonding and

painting operations of the

aircraft.

The technology enables the

plasma pretreatment of the

materials to be done in-line

along with the other

processes such as blasting

Potential Applications

The technology can be used in

the aircraft industry and also in

all the areas of industrial

manufacturing.

The technology involves high

speed and produces very low

scrap. Hence, the process

efficiency is very high.

Commercialization

Strategy The company is looking to

commercialize this technology

by partnering with other

companies in Europe and Asia

Pacific.

Openair Plasma technology uses atmospheric pressure for pretreatment and does not require any other set-up apart from air, electrical

power, and existing production line. This technology also reduces the expenses and hence it is unique in its own way.

Analyst Perspective

Marketing

Strategy

The company promoted

this technology at

different events such as

INDUSTRIE Paris in

2016 and Highly-

functional Material

World in Japan in 2016.

Openair Plasma Technology by Plasmatreat New pre-treatment technology of plastics under atmospheric conditions

5 D825-TV

Unmet Needs Technology Profile

Innovation Attributes

Potential Applications Commercialization

Strategy The company plans to

collaborate with leading

universities to improve properties

such as toughness. It also plans

to commercialize this product by

partnering with companies.

The product has very high impact resistance and is easy to thermoform unlike other products. Hence, this will be able to capture a good

portion of the aerospace products market.

Plastics sheets such as acrylonitrile butadiene styrene

(ABS) and high impact polystyrene (HIPS) that are used

in aircraft interiors do not have high impact resistance.

Thermoplastics used in the aerospace industry

especially for deep-draw parts are not easy to

thermoform.

What

Where Who

KYDEX is a thermoplastic sheet that is a

combination of ABS and polyvinyl chloride

(PVC).

The product was developed

in the company’s

manufacturing facility in

Orchard Park, New York,

USA.

The product was

developed by Curbell

Plastics, a US-based

company that

manufactures plastic

sheets, rods, films,

adhesives, and sealants.

The product is used where

toughness and complex

thermoforming is required. Hence,

it is used in thermoformed

equipment housings, airplane, bus,

kiosks, and point of purchase

(POP) displays.

The sheet is tough, durable and is easy to

thermoform deep-draw parts

The sheet provides excellent impact

resistance, good strength and stiffness

The product is easy to machine and

fabricate using normal processes and

equipment.

Analyst Perspective

Future Plans Curbell Plastics is developing more variations of KYDEX,

which will be meant for more targeted and customized use.

The company wants this product to be of choice when it

comes to areas where complex thermoforming is required.

The product has various

grades such as

KYDEX® 100,

KYDEX® T Sheet for

O&P. All these grades

have different

customized properties.

Different grades

KYDEX by Curbell Plastics Thermoplastic sheet with very high impact resistance

6 D825-TV

Unmet Needs Technology Profile

Innovation Attributes

Potential Applications Commercialization

Strategy The company is collaborating

with Aonix Advanced Materials,

JSP, and 3A Composites to

commercialize this product.

Tegralite can improve efficiency of aircraft as it consumes less fuel and is lightweight. Thus, the product is disruptive in its own way in the

aerospace components market.

Metals and heavier plastic parts used in aerospace

industry are unable to resist shock, impact and high

temperature

Plastics used in the aerospace industry are very costly

and require high maintenance which increases the

overall cost of aircraft maintenance cost.

What

Where Who

Tegralite is a family of high performance

thermoplastic based materials. It includes

foams, composites and sandwich structures.

The product was

developed in the

company’s

manufacturing facility

in Brussels, Belgium.

The product was

developed by Solvay, a

Belgium-based chemical

company. It is a diversified

company that serves many

industries such as

electronics, aerospace,

and energy.

The product is used various

applications in aircraft—from

floor to ceiling, radomes, cargo

compartments, engine covers

and so on.

The product requires less labor costs for primary

and secondary operations. Hence for the more

complex parts, the savings are higher.

The product is completely thermoplastic in

nature due to which on board welding is

possible unlike thermosets.

The product reduces the overall weight of

the aircraft and fuel consumption. Hence it

increases the efficiency and cost

effectiveness

Analyst Perspective

Future Plans Solvay expects that Tegralite can address the order backlog in

commercial aviation. It is trying to expand the Tegralite range of

products (with new and improved properties), which are market

ready.

Tegralite has various

grades like Tegracore

PPSU foam and

thermoplastic sandwich

structures, which are

used in aircraft cabins

and other aircraft

applications.

Different grades

Tegralite by Solvay Thermoplastic solution for increasing time and cost efficiencies

7 D825-TV

The product is extremely lightweight and is fire smoke and toxicity retardant. It also complies with Federal Aviation Regulations FAR 25.853. All

these factors make it a attractive proposition for the global market.

Analyst Perspective

Aerospace companies are in constant need of lightweight and flexible materials, which can tolerate high

temperature and pressure without any degradation.

Technology Profile The product was developed by

Quadrant Engineering Plastic

Products, which is involved in

the manufacture of high

performance polymers such

as ultra high molecular weight

polyethylene, nylon.

Nylatron® 66 SA FST is a specially

designed high quality polyamide

material that can be used in aircraft. It

is the first engineering plastic product

to be available in semi-finished forms

(rods and sheets).

The product was

developed in the

company’s

manufacturing

facility in Tielt,

Belgium.

Who

What

Where

Innovation Attributes The product complies with the Federal Aviation Regulations FAR

25.853. It is the first engineering plastic to achieve this standard.

The product is fire-, smoke-, and toxicity retardant, which enables it to

withstand temperatures of up to 175 degrees C.

It has a very beneficial cost-performance ratio. It is extremely

lightweight, easy to machine, and produces minimal sound/noise.

Potential Applications

The product is mainly used for aircraft interiors

where metal parts like brackets, seal bushings,

slide rails and duct seals have traditionally been

used.

Marketing Strategy

Quadrant Engineering Plastic Products

showcased this product at the Paris Air Show in

June 2015. It also showcased the product at the

Singapore Air Show in 2016.

Commercialization Strategy

The company is planning to commercialize this

product across the aerospace industry by

partnering with other companies operating in this

segment such as aircraft manufacturers, suppliers

to the aircraft industry.

Nylatron® 66 SA FST by Quadrant Engineering Plastic Products Innovative polyamide material for withstanding extreme temperatures

8 D825-TV

The product has the ability to adjust to the amount of light and the degree of transparency on its own which is quite unique. Hence, this product

is quite disruptive and on commercialization has the capacity to capture a good portion of the market.

Analyst Perspective

Windows used in aircraft can not adjust to light or heat automatically and also can not change their level of

transparency.

Technology Profile Isoclima, is a Italy-based glass

processing company catering to

the aerospace and building &

construction industries. It is a

licensee of Research Frontiers,

developer of Suspended Particles

Device (SPD)-Smart light-control

technology

SPD-Smart Electronically Dimmable

Window is developed using SPD-Smart

EDW film technology of Research

Frontiers, and SABIC’s polycarbonate

LEXAN (that has high optical clarity).

This product is a part of the CromaLite

range.

The product was

developed in

Isoclima’s

manufacturing

facility in Este,

Province of

Padua, Italy.

Who

What

Where

Innovation Attributes The product can instantly adjust to the amount of light, glare, and heat

passing through the window.

The product can change its level of transparency rapidly, uniformly, and

precisely to any level independent of the window size.

The product uses LEXAN brand of SABIC, which is why it has high

impact resistance, optical clarity, abrasion resistance as well as

enhanced light transmission.

Potential Applications

The product is mainly used for aircraft interiors

such as windows. It can also be applied on curved

surfaces. Apart from the aerospace industry, it is

also used in roofs of big buildings

Marketing Strategy

Isoclima and SABIC Innovative Plastics

showcased this new generation of CromaLite

brand of Electronically Dimmable Windows at

Aircraft Interiors Expo in Hamburg, Germany, in

April 2015.

Commercialization Strategy

The company is looking to commercialize this

product by partnering with companies like SABIC

and Research Frontiers. Isoclima uses the

technology of Research Frontiers and Lexan

brand of polycarbonate of SABIC.

SPD-Smart Electronically Dimmable Windows by Isoclima Innovative smart glass that can adjust automatically to light

9 D825-TV

The product has the ability to reduce aircraft weight by 60%. In addition, it can be processed at lower temperatures than other composites,

which leads to energy savings. These factors will help the product to capture the global aerospace market.

Analyst Perspective

Metals or thermosets used in aircraft increase the overall weight of the aircraft considerably.

Technology Profile

The product was developed by

Victrex, an UK-based

company involved in the

manufacture and marketing of

high performance aromatic

polyketones.

Victrex has developed the

polyaryletherketone (PAEK)-based

polymer. PAEK can be used along with

fiber-reinforced Victrex

polyetheretherketone (PEEK) polymer

for aircraft interiors. The product uses a

hybrid molding technology, which

enables overmolding of the PAEK-based

composite.

The product was

developed in the

company’s

manufacturing

facility in

Cleveland, UK.

Who

What

Where

Innovation Attributes The PAEK-based polymer can deliver up to 60% of weight savings

compared to stainless steel or titanium

The polymer has an optimum level of crystallinity which helps in good

mechanical properties like strength, stiffness and temperature properties

The polymer along with reinforced thermoplastic composite can be

processed at a temperature of 40 degrees C, which is lesser than that of

traditional composites.

Potential Applications

The product is mainly used for aircraft interiors

such as brackets. Commercial aircraft use

thousands of brackets from the cockpit to the tail

of the plane. The polymer can also be used in

other industries such as automotive, energy, and

consumer electronics.

Partnerships & Collaborations

Victrex is collaborating with Tri-Mack Plastics

Manufacturing Corporation to develop this

polymer. Tri Mack Plastics is a US-based high

performance thermoplastics company, which

supplies to varied industries.

Marketing Strategy

Victrex along with Tri Mack Plastics is marketing

this product by participating in different events and

forums across the world. The reason behind

collaborating with Tri Mach Plastics is to help the

product capture the US market.

VICTREX PAEK by Victrex Polymer that can deliver weight savings of up to 60% in an aircraft

10 D825-TV

The 3D printed seat can be made from less than 15 components and is compliant with the regulations of the aircraft industry. It can also reduce

aircraft cost. Thus, it has the ability to capture the aircraft interiors market.

Analyst Perspective

Aircraft seats are made up of more than 150 components, which increase the overall manufacturing cost of seats and as a

result the increase in price is passed down to the traveller.

Technology Profile The product was developed by

SABIC, a Saudi Arabia- based

diversified manufacturing

company involved in

chemicals and industrial

polymers.

The seat was made from SABIC’s

ULTEM 9085 resin. The three-

dimensional (3D) printing was done by

Stratasys using SABIC’s resin. The

resin is compatible for 3D printing, is

toxicity compliant, has low moisture

absorption and has design flexibility.

The product was

developed in the

company’s

manufacturing

facility in Riyadh,

Saudi Arabia.

Who

What

Where

Innovation Attributes The seat meets all the regulatory requirements of the aircraft industry

and OEM (original equipment manufacturer) specific heat release,

flame, and smoke requirements The use of 3D printing has enabled quick prototyping of the required

design without the need for tooling, which results in the seat being

produced with less than 15 components The ULTEM resin is lightweight, can be recycled, and is inexpensive.

Hence, it addresses the need to control costs related to raw materials,

processing.

Potential Applications

The product can be used not only for making

seats, but also in other aircraft interiors such as

dividers, security partitions, oversized interior

windows, backlit signs and panels.

Commercialization Strategy

SABIC is partnering with other companies

operating in this segment for commercializing

this product.

Marketing Strategy

SABIC has showcased this innovative 3D printed

seat at the Aircraft Interiors Expo in Hamburg,

Germany, in 2015.

3D Printed Economy Class Seat for Aircraft by SABIC Innovative aircraft seat made of fewer components

11 D825-TV

The product has high mechanical properties and is resistant to solvents and chemicals. It can be processed by thermoforming and is

recyclable. All these properties make this product a lucrative option for the global aircraft components market.

Analyst Perspective

Most of the plastics that are used in aircraft components are not recyclable and can benefit from increased strength.

Technology Profile The product was developed by

Toho Tenax, a Japanese

company that manufactures

carbon fibre composites. It is

part of the Teijin Group.

ThermoPlastic Consolidated Laminate

(TPCL) is made of multiple layers of

thermoplastic (polyetheretherketone

[PEEK]) and is impregnated with

carbon woven fabric. The product can

be processed by heating it above its

melting temperature in a mold within a

press.

The product was

developed in the

company’s

manufacturing

facility in Tokyo,

Japan.

Who

What

Where

Innovation Attributes The product has high mechanical properties such as strength, stiffness,

toughness, flexural strength, and tensile strength.

It is resistant to chemicals and solvents, has very low flammability and

toxicity, and produces less smoke when burnt. It can be stored and

shipped at room temperature. The product can be processed by thermoforming and the cycle time is

short. It is also recyclable and is compliant with the regulations of the

aerospace industry.

Potential Applications

The product can be used for making structural

components such as brackets, clips in aircrafts. It

is used in the Airbus A350 aircraft.

Different grades

Toho Tenax offers this product in different sizes

from 800 millimeter to 1200 millimeter with

varying stacking sequences of the thermoplastic

layers and special surface layers.

Marketing Strategy

Toho Tenax is marketing this product by

partnering with companies across the value chain

as well as showcasing the product in different

events, seminars, and conferences across the

globe.

ThermoPlastic Consolidated Laminate by Toho Tenax High strength thermoplastic sheets that can be used in aircraft components

12 D825-TV

Strategic Insights

13 D825-TV

Competitive Landscape and Patent Analysis

Intellectual Property (IP)

• A total of 4500 patents were granted from 2011 to

2015 for plastics used in the aerospace industry.

• The key assignees include The Boeing Company,

PPG Industries, Ethicon, and Airbus.

• The United States has filed the maximum number

of patents in the last 5 years.

• In the last 5 years, 7922 patents were filed

globally and out of which 4500 were granted.

• In the aerospace plastics sector, companies have

filed more patents than universities/research

institutes as the organizations are trying to

find/develop different solutions/properties of

reinforced plastics such as aramid, carbon fiber,

and glass fiber.

Competitive Landscape o North America and Europe are the largest markets for aerospace plastics

industry. Frost & Sullivan estimates that Europe leads with a market share

of 44% while North America accounted for 33% of $8.2 billion global

revenue in 2015. In Europe, investments and supportive government

policies have resulted in a spike in R&D activities for new product

development. Hence, the manufacturers are attracted toward this region.

o Toray, Hexcel Corporation, Hyosung Corporation, Mitsubishi Heavy

Industries, Kaman Corporation, Ensinger and Composite Holding, Cytec

Industries, SABIC, and Toho Tenax are among the key market participants.

NORTH AMERICA

SOUTH AMERICA

AFRICA

EUROPE ASIA

AUSTRALIA

Low

High

Medium

0

200

400

600

800

1000

1200

2011 2012 2013 2014 2015

Gra

nte

d P

ate

nts

Year

No of granted patents, globally (2011-2015)

14 D825-TV

Strategic Insights

Key Research and Development Focus

Areas One of the focus areas is on composites and

nanocomposites. Another key focus will be

environmental friendly plastics/composites. 3D printing

of aircraft components is also in focus.

The 2020 Scenario Plastics will be very predominant in the

aerospace market. The key plastics, which

will be used are aramid reinforced plastics,

nanocomposites. High quality plastics,

which will require lower costs to fabricate

will be a key trend in 2020.

Funding Scenario The sector has experienced more funding

from the government (public) compared to

private. For example, Canada-based

Cyclone Manufacturing has received $8

million funding from the Federal Economic

Development Agency for Southern Ontario

to increase production capacity and

customer base.

Adoption Barriers The key barriers are toxicity

issues during the manufacture of

reinforced plastics, high

manufacturing and processing

costs, and flaw detection issues.

Growth Factors Increase in manufacture of

commercial and military aircrafts

with enhanced shelf life and fuel

efficiency along with reduced

maintenance costs are the key

drivers for this sector.

Market Potential Plastics in the aerospace industry

have good market potential due to

the rising application room of

lightweight materials in the

aerospace industry. The market is

expected to reach around $14 billion

by 2020 at a CAGR of 8.1%.

15 D825-TV

Key Patents

16 D825-TV

Key Patents

No. Patent No. Publication Date Title Assignee

1 EP_2997271_A1 March 23, 2016 Method for producing a corrugated foil bearing

stiffener and obtained stiffener

Liebherr Aerospace Toulouse

Sas

The invention concerns a method for producing a corrugated foil bearing stiffener which involves starting with an austenitic nickel superalloy

sheet (15) having an elasticity limit higher than 500 MPa, and subjecting the sheet (15) to at least one step of press bending plastic deformation

of the entire thickness of same with a deformation energy higher than 10 kJ in a time shorter than 10-5 s in such a way as to create

corrugations.

2 EP_2621995_B1 March 23, 2016 Advanced epoxy resin compositions Dow Global Technologies

An epoxy resin composition of the following chemical structure: where n is a number from 1 to about 3000; each m independently has a value

of 0 or 1; each R0 is independently —H or —CH3; each R1 is independently —H or a C1 to C6 alkylene radical (saturated divalent aliphatic

hydrocarbon radical), Ar is a divalent aryl group or heteroarylene group; and X is a cycloalkylene group, including a substituted cycloalkylene

group, where the substituent group include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substituent group, for example, a halogen, a

nitro, or a blocked isocyanate, an alkyloxy group; the combination of cycloalkylene and alkylene groups and the combination of alkylene and

cycloalkylene group with a bridging moiety in between.

3 US_2016_0076579_A1 March 17, 2016 Attachment bolt for positive locking Lisi Aerospace

The invention relates to a fastening bolt (10) comprising: A screw (11), said screw having a threaded portion (17) and a terminal portion (18)

whose diameter (19) is less than that of the threaded portion, an end surface (21) of said terminal portion comprising a transverse opening

groove (22); A nut (30) comprising a threaded body (32) and an unthreaded crown (34) drilled with at least two holes (35) diametrically

opposite to one another; A rod (23), able to fit in the groove of the screw and in the two lateral holes of the nut to lock the bolt; the threaded rod

of the nut comprises a driving portion (38), as well as a chimney (34) less thick than the driving portion; the nut comes from a method

comprising an elliptical deformation of the chimney previously in a circular shape.

17 D825-TV

Key Patents (continued)

No. Patent No. Publication Date Title Assignee

4 US_2016_0075916_A1 March 17, 2016 Insulating coating material and use of same Kaneka Corporation

An insulating coating material is provided herein. In some embodiments, the insulating coating material comprises an insulating film comprising

a polyimide resin, wherein the insulating film, when measuring a tensile elasticity in accordance with ASTM D882, having a stress at 5% strain

of 180 MPa or greater and a stress at 15% strain of 225 MPa or greater, wherein the stress at 15% strain is greater than the stress at 5%

strain.

5 US_2016_0075837_A1] March 17, 2016 Method for removing bubbles in polyimide

solution

Everdisplay Optronics

The present disclosure provides a method for removing bubbles in polyimide solution, including: putting the polyimide solution in an open

container; and emitting microwaves to the polyimide solution using a microwave generator to perform a microwave treatment lasting a time

period so as to remove the bubbles in the polyimide solution. Using the method of the present disclosure to process polyimide solution may

conveniently and quickly remove the bubbles in the polyimide solution. This greatly reduces the time required by the process and thus may

meet industrialization demands. Meanwhile, the method effectively reduces the volatilization of an organic solvent having a low melting point in

the polyimide solution, thereby maintaining proportion stability of the polyimide solution and avoiding defects generated in subsequent coating

processes.

18 D825-TV

Industry Contacts

19 D825-TV

Industry Contacts

Calvin Yong, Regional Manager, Toho Tenax, Kasumigaseki Common Gate West Tower 3-2-1 Kasumigaseki, Chiyoda-ku 100-8585, Tokyo

Japan. Phone: +81-3-3506-6829. E-mail: [email protected] URL: http://www.tohotenax.com/

Kim Choate, Market Director, Mass Transportation, SABIC Innovative Plastics, PO Box 5101, Riyadh 11422, Saudi Arabia.

Phone: +966-011- 225-8000. E-mail: [email protected]. URL: http://www.sabic.com/

Jeff Leighty, Sales & Marketing Manager, Plasmatreat USA, 2541 Technology Drive, Suite 407 Elgin, Illinois 60124.

Phone: +1-847-783-0622. E-mail: [email protected]. URL: http://www.plasmatreat.com/

Tim Herr, Director, Aerospace Strategic Business Unit Director, Victrex, Seal Sands Middlesbrough TS2 1UB Cleveland UK.

Phone: +44-1642-543150. E-mail: [email protected]. URL: https://www.victrex.com/en/

Tracy Schiedel, Director of Marketing, Curbell Plastics, 7 Cobham Drive Orchard Park, New York 14127. Phone: +1-716-667-3377.

E-mail: [email protected]. URL: https://www.curbellplastics.com/

Frank Johänning, Global Market Manager, Aerospace, Quadrant Engineering Plastic Products, I.P. Noord - Szamotulystraat 14

8700 Tielt, Belgium. Phone: +32-0-51-42-35-11. E-mail: [email protected]. URL: http://www.quadrantplastics.com/en/

Marco Bertolini, Head, R&D and Product Development, Isoclima SpA Alessandro Volta, 14 - 35042 Este (PD) Italy. Phone: +39-0429-55788.

E-mail: [email protected]. URL: http://www.isoclima.net/

Augusto Di Donfrancesco, President, Specialty Polymers GBU, Solvay, Rue De Ransbeek, 310,1120 Brussels, Belgium.

Phone: +32-2-264-2111. E-mail: [email protected]. URL: http://www.solvay.com/en/