pickling and passivating of stainless steel systems and installations
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Pickling and passivating of stainlesssteel systems and installationsStainlesssteelsystemsandinstallationsarecleanedpriortouseandinmanycasesperiodicallytoremoveprocesscontaminantssuchasscaling.
MetaltreatmentStainlesssteelmustpriortousebechemicallytreated.Thecorrosionresistanceofstainlesssteelisdeterminedbyachromiumrichoxidefilm.Assoonasthisfilmhasformedthematerialisdesignatedasbeingpassive.
Duringinstallationofthestainlesssteelpipinginasystemand/orinstallationthesurfaceisexposedtomanymechanicalandthermaltreatments.Thisresultsinlocaldamagetoandcontaminationoftheprotectiveoxidefilm.Thenthisresultsintheoxidefilmlosingitscorrosionresistantfeatureswiththesubstratematerialoftencorrodingmorerapidlythanwouldhavebeenthecasefortheoriginalpassivepanelmaterial.Itisthereforeveryimportantthatthischromiumrichoxidefilmiscompletelysealedandcleanbeforethesystem/installationisputintouseandexposedtochemicals/processandenvironment.
CorrosionStainlesssteelisnotcompletelyresistanttocorrosion.Itisimportantthatlightcorrosionproductsberemovedspecificallywithaviewtoavoidingdeeppitandsplitcorrosionwithalltheirnegativeconsequencesandalsotopreventcontaminationtheprocess/mediumintheinstallation/system.
PrecommissioningcleaningTheprecommissioningcleaningofAusteniticstainlesssteeltypescomprisesingeneralthreesteps:degreasing,picklingandpassivation.Degreasingisrequiredtoremoveoil,greaseandatmosphericpollutionandtorenderthesurfaceoptimallyaccessibletothepicklingagent.DegreasingisgenerallyconductedusingVecomMulticleaner/TP02orSteamcleanHPCNF.Thepicklingtreatmentremovescompletelyironparticlesandothersurfacecontaminantstothesurfaceresultingfromearliertreatmentsorotherwise.Afterthepicklingtreatmentthematerialisrinsedacidfreeusinglowchloridewater.Thepicklingtreatmentrendersthesurfacechromiumrich,thesurfacebeinginfactrefined.AlthoughtheAusteniticstainlesssteelis,afterpicklingandwhenexposedtosufficientatmosphericoxygen,abletopassivatespontaneously,closedsystemssucharegenerallytreatedchemicallyinordertopassivatetheirsurfaces.Thechemicalfluidsarecirculatedthroughtheinstallation/system.Thisisdoneusinganacidresistantpumpunit.Thetime
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occupiedbythistreatmentdependsonthetypeofstainlesssteelandthetemperature.Analysesoftheironcontentandacidconcentrations,determinewhenthetreatmentisfinished.Thetreatmentisfollowedbyrinsing,firstwithdrinkingwaterandthenwithdemineralizedwater.
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