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TRANSCRIPT
Page 88 of 88
#=CL#
May 27, 2015
LIMS USE: FR - JERRY MULLIN
LIMS OBJECT ID: 10306235
10306235
Project:
Pace Project No.:
RE:
Mr. Jerry MullinLandmark Environmental2042 West 98th StreetBloomington, MN 55431
HC-15-002 CSAH-53
Dear Mr. Mullin:
Enclosed are the analytical results for sample(s) received by the laboratory on May 13, 2015. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Jessica Patterson
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 1 of 58
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Minnesota Certification IDs1700 Elm Street SE Suite 200, Minneapolis, MN 55414A2LA Certification #: 2926.01Alaska Certification #: UST-078Alaska Certification #MN00064Alabama Certification #40770Arizona Certification #: AZ-0014Arkansas Certification #: 88-0680California Certification #: 01155CAColorado Certification #PaceConnecticut Certification #: PH-0256EPA Region 8 Certification #: 8TMS-LFlorida/NELAP Certification #: E87605Guam Certification #:14-008rGeorgia Certification #: 959Georgia EPD #: PaceIdaho Certification #: MN00064Hawaii Certification #MN00064Illinois Certification #: 200011Indiana Certification#C-MN-01Iowa Certification #: 368Kansas Certification #: E-10167Kentucky Dept of Envi. Protection - DW #90062Kentucky Dept of Envi. Protection - WW #:90062Louisiana DEQ Certification #: 3086Louisiana DHH #: LA140001Maine Certification #: 2013011Maryland Certification #: 322Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137Mississippi Certification #: PaceMontana Certification #: MT0092Nevada Certification #: MN_00064Nebraska Certification #: PaceNew Jersey Certification #: MN-002New York Certification #: 11647North Carolina Certification #: 530North Carolina State Public Health #: 27700North Dakota Certification #: R-036Ohio EPA #: 4150Ohio VAP Certification #: CL101Oklahoma Certification #: 9507Oregon Certification #: MN200001Oregon Certification #: MN300001Pennsylvania Certification #: 68-00563Puerto Rico CertificationSaipan (CNMI) #:MP0003South Carolina #:74003001Texas Certification #: T104704192Tennessee Certification #: 02818Utah Certification #: MN000642013-4Virginia DGS Certification #: 251Virginia/VELAP Certification #: PaceWashington Certification #: C486West Virginia Certification #: 382West Virginia DHHR #:9952CWisconsin Certification #: 999407970
Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334
North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Wisconsin Certification #: 405132750
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 2 of 58
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Lab ID Sample ID Matrix Date Collected Date Received
10306235001 LGP-18/3-5 Solid 05/12/15 00:00 05/13/15 14:34
10306235002 LGP-19/4-6 Solid 05/12/15 00:00 05/13/15 14:34
10306235003 LHA-20/5-7 Solid 05/12/15 00:00 05/13/15 14:34
10306235004 LHA-21/2-4 Solid 05/12/15 00:00 05/13/15 14:34
10306235005 LGP-22/4-6 Solid 05/12/15 00:00 05/13/15 14:34
10306235006 LGP-23/6-8 Solid 05/12/15 00:00 05/13/15 14:34
10306235007 LGP-23/17-20 Water 05/12/15 00:00 05/13/15 14:34
10306235008 LGP-24/3-5 Solid 05/12/15 00:00 05/13/15 14:34
10306235009 LGP-25/1-3 Solid 05/12/15 00:00 05/13/15 14:34
10306235010 LGP-25/15-20 Water 05/12/15 00:00 05/13/15 14:34
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 3 of 58
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
10306235001 LGP-18/3-5 EPA 6010C 7 PASI-MIP
EPA 7471B 1 PASI-MLMW
ASTM D2974 1 PASI-MJDL
EPA 8270D by SIM 19 PASI-MAS1
10306235002 LGP-19/4-6 WI MOD DRO 2 PASI-MMT
WI MOD GRO 2 PASI-MRTP
EPA 6010C 7 PASI-MIP
EPA 7471B 1 PASI-MLMW
ASTM D2974 1 PASI-MJDL
EPA 8270D by SIM 19 PASI-MAS1
EPA 8260B 70 PASI-MLPM
10306235003 LHA-20/5-7 EPA 6010C 7 PASI-MIP
EPA 7471B 1 PASI-MLMW
ASTM D2974 1 PASI-MJDL
EPA 8270D by SIM 19 PASI-MAS1
10306235004 LHA-21/2-4 WI MOD DRO 2 PASI-MMT
WI MOD GRO 2 PASI-MRTP
EPA 6010C 7 PASI-MIP
EPA 7471B 1 PASI-MLMW
ASTM D2974 1 PASI-MJDL
EPA 8270D by SIM 19 PASI-MAS1
EPA 8260B 70 PASI-MLPM
10306235005 LGP-22/4-6 WI MOD DRO 2 PASI-MMT
WI MOD GRO 2 PASI-MRTP
EPA 6010C 7 PASI-MIP
EPA 7471B 1 PASI-MLMW
ASTM D2974 1 PASI-MJDL
EPA 8270D by SIM 19 PASI-MAS1
EPA 8260B 70 PASI-MLPM
10306235006 LGP-23/6-8 WI MOD DRO 2 PASI-MMT
WI MOD GRO 2 PASI-MRTP
EPA 6010C 7 PASI-MIP
EPA 7471B 1 PASI-MLMW
ASTM D2974 1 PASI-MJDL
EPA 8270D by SIM 19 PASI-MAS1
EPA 8260B 70 PASI-MLPM
10306235007 LGP-23/17-20 WI MOD DRO 2 PASI-MJRH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 4 of 58
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
WI MOD GRO 1 PASI-GPMS
EPA 8260B 70 PASI-MAJC
10306235008 LGP-24/3-5 EPA 6010C 7 PASI-MIP
EPA 7471B 1 PASI-MLMW
ASTM D2974 1 PASI-MJDL
EPA 8270D by SIM 19 PASI-MAS1
10306235009 LGP-25/1-3 WI MOD DRO 2 PASI-MMT
WI MOD GRO 2 PASI-MRTP
EPA 6010C 7 PASI-MIP
EPA 7471B 1 PASI-MLMW
ASTM D2974 1 PASI-MJDL
EPA 8270D by SIM 19 PASI-MAS1
EPA 8260B 70 PASI-MLPM
10306235010 LGP-25/15-20 WI MOD DRO 2 PASI-MJRH
WI MOD GRO 1 PASI-GPMS
EPA 8260B 70 PASI-MAJC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 5 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-18/3-5 Lab ID: 10306235001 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic ND mg/kg 05/20/15 00:50 7440-38-205/18/15 04:460.95 1
Barium 83.7 mg/kg 05/20/15 00:50 7440-39-305/18/15 04:460.47 1
Cadmium 0.29 mg/kg 05/20/15 00:50 7440-43-905/18/15 04:460.14 1
Chromium 9.1 mg/kg 05/20/15 00:50 7440-47-305/18/15 04:460.47 1
Lead 5.3 mg/kg 05/20/15 00:50 7439-92-105/18/15 04:460.47 1
Selenium ND mg/kg 05/20/15 00:50 7782-49-205/18/15 04:460.95 1
Silver ND mg/kg 05/20/15 00:50 7440-22-405/18/15 04:460.47 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury 0.022 mg/kg 05/18/15 19:29 7439-97-605/17/15 15:180.021 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 13.0 % 05/19/15 09:040.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/20/15 06:07 83-32-905/15/15 22:170.011 1
Acenaphthylene ND mg/kg 05/20/15 06:07 208-96-805/15/15 22:170.011 1
Anthracene ND mg/kg 05/20/15 06:07 120-12-705/15/15 22:170.011 1
Benzo(a)anthracene ND mg/kg 05/20/15 06:07 56-55-305/15/15 22:170.011 1
Benzo(a)pyrene ND mg/kg 05/20/15 06:07 50-32-805/15/15 22:170.011 1
Benzo(b)fluoranthene ND mg/kg 05/20/15 06:07 205-99-205/15/15 22:170.011 1
Benzo(g,h,i)perylene ND mg/kg 05/20/15 06:07 191-24-205/15/15 22:170.011 1
Benzo(k)fluoranthene ND mg/kg 05/20/15 06:07 207-08-905/15/15 22:170.011 1
Chrysene ND mg/kg 05/20/15 06:07 218-01-905/15/15 22:170.011 1
Dibenz(a,h)anthracene ND mg/kg 05/20/15 06:07 53-70-305/15/15 22:170.011 1
Fluoranthene ND mg/kg 05/20/15 06:07 206-44-005/15/15 22:170.011 1
Fluorene ND mg/kg 05/20/15 06:07 86-73-705/15/15 22:170.011 1
Indeno(1,2,3-cd)pyrene ND mg/kg 05/20/15 06:07 193-39-505/15/15 22:170.011 1
Naphthalene ND mg/kg 05/20/15 06:07 91-20-305/15/15 22:170.011 1
Phenanthrene ND mg/kg 05/20/15 06:07 85-01-805/15/15 22:170.011 1
Pyrene ND mg/kg 05/20/15 06:07 129-00-005/15/15 22:170.011 1
Total BaP Eq. MN 2006sh. ND=0 ND mg/kg 05/20/15 06:0705/15/15 22:170.011 1
Surrogates2-Fluorobiphenyl (S) 70 %. 05/20/15 06:07 321-60-805/15/15 22:1755-125 1
p-Terphenyl-d14 (S) 77 %. 05/20/15 06:07 1718-51-005/15/15 22:1730-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 6 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-19/4-6 Lab ID: 10306235002 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: WI MOD DRO Preparation Method: WI MOD DROWIDRO GCS Silica Gel
WDRO C10-C28 45.3 mg/kg 05/19/15 10:20 T605/15/15 13:275.8 1
Surrogatesn-Triacontane (S) 312 %. 05/19/15 10:20 638-68-6 S505/15/15 13:2730-143 1
Analytical Method: WI MOD GRO Preparation Method: EPA 5030 Medium SoilWIGRO GCV
Gasoline Range Organics ND mg/kg 05/18/15 16:3905/15/15 14:5911.6 1
Surrogatesa,a,a-Trifluorotoluene (S) 116 %. 05/18/15 16:39 98-08-805/15/15 14:5980-150 1
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 1.2 mg/kg 05/20/15 00:55 7440-38-205/18/15 04:460.96 1
Barium 50.5 mg/kg 05/20/15 00:55 7440-39-305/18/15 04:460.48 1
Cadmium 0.22 mg/kg 05/20/15 00:55 7440-43-905/18/15 04:460.14 1
Chromium 6.5 mg/kg 05/20/15 00:55 7440-47-305/18/15 04:460.48 1
Lead 6.7 mg/kg 05/20/15 00:55 7439-92-105/18/15 04:460.48 1
Selenium ND mg/kg 05/20/15 00:55 7782-49-205/18/15 04:460.96 1
Silver ND mg/kg 05/20/15 00:55 7440-22-405/18/15 04:460.48 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/18/15 19:31 7439-97-605/17/15 15:180.020 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 11.1 % 05/19/15 09:040.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene 0.058 mg/kg 05/20/15 06:28 83-32-905/15/15 22:170.011 1
Acenaphthylene 0.078 mg/kg 05/20/15 06:28 208-96-805/15/15 22:170.011 1
Anthracene 0.24 mg/kg 05/20/15 06:28 120-12-705/15/15 22:170.011 1
Benzo(a)anthracene 0.86 mg/kg 05/20/15 17:13 56-55-305/15/15 22:170.11 10
Benzo(a)pyrene 1.1 mg/kg 05/20/15 17:13 50-32-805/15/15 22:170.11 10
Benzo(b)fluoranthene 1.3 mg/kg 05/20/15 17:13 205-99-205/15/15 22:170.11 10
Benzo(g,h,i)perylene 0.62 mg/kg 05/20/15 17:13 191-24-205/15/15 22:170.11 10
Benzo(k)fluoranthene 0.53 mg/kg 05/20/15 17:13 207-08-905/15/15 22:170.11 10
Chrysene 0.88 mg/kg 05/20/15 17:13 218-01-905/15/15 22:170.11 10
Dibenz(a,h)anthracene 0.17 mg/kg 05/20/15 06:28 53-70-305/15/15 22:170.011 1
Fluoranthene 1.8 mg/kg 05/20/15 17:13 206-44-005/15/15 22:170.11 10
Fluorene 0.043 mg/kg 05/20/15 06:28 86-73-705/15/15 22:170.011 1
Indeno(1,2,3-cd)pyrene 0.56 mg/kg 05/20/15 17:13 193-39-505/15/15 22:170.11 10
Naphthalene ND mg/kg 05/20/15 06:28 91-20-305/15/15 22:170.011 1
Phenanthrene 0.58 mg/kg 05/20/15 17:13 85-01-805/15/15 22:170.11 10
Pyrene 1.6 mg/kg 05/20/15 17:13 129-00-005/15/15 22:170.11 10
Total BaP Eq. MN 2006sh. ND=0 1.5 mg/kg 05/20/15 17:1305/15/15 22:170.11 10
Surrogates2-Fluorobiphenyl (S) 70 %. 05/20/15 06:28 321-60-805/15/15 22:1755-125 1
p-Terphenyl-d14 (S) 71 %. 05/20/15 06:28 1718-51-005/15/15 22:1730-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 7 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-19/4-6 Lab ID: 10306235002 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
Acetone ND mg/kg 05/19/15 21:27 67-64-105/18/15 16:311.1 1
Allyl chloride ND mg/kg 05/19/15 21:27 107-05-105/18/15 16:310.23 1
Benzene ND mg/kg 05/19/15 21:27 71-43-205/18/15 16:310.023 1
Bromobenzene ND mg/kg 05/19/15 21:27 108-86-105/18/15 16:310.057 1
Bromochloromethane ND mg/kg 05/19/15 21:27 74-97-505/18/15 16:310.057 1
Bromodichloromethane ND mg/kg 05/19/15 21:27 75-27-405/18/15 16:310.057 1
Bromoform ND mg/kg 05/19/15 21:27 75-25-205/18/15 16:310.23 1
Bromomethane ND mg/kg 05/19/15 21:27 74-83-905/18/15 16:310.57 1
2-Butanone (MEK) ND mg/kg 05/19/15 21:27 78-93-305/18/15 16:310.29 1
n-Butylbenzene ND mg/kg 05/19/15 21:27 104-51-805/18/15 16:310.057 1
sec-Butylbenzene ND mg/kg 05/19/15 21:27 135-98-805/18/15 16:310.057 1
tert-Butylbenzene ND mg/kg 05/19/15 21:27 98-06-605/18/15 16:310.057 1
Carbon tetrachloride ND mg/kg 05/19/15 21:27 56-23-505/18/15 16:310.23 1
Chlorobenzene ND mg/kg 05/19/15 21:27 108-90-705/18/15 16:310.057 1
Chloroethane ND mg/kg 05/19/15 21:27 75-00-305/18/15 16:310.57 1
Chloroform ND mg/kg 05/19/15 21:27 67-66-305/18/15 16:310.057 1
Chloromethane ND mg/kg 05/19/15 21:27 74-87-305/18/15 16:310.23 1
2-Chlorotoluene ND mg/kg 05/19/15 21:27 95-49-805/18/15 16:310.057 1
4-Chlorotoluene ND mg/kg 05/19/15 21:27 106-43-405/18/15 16:310.057 1
1,2-Dibromo-3-chloropropane ND mg/kg 05/19/15 21:27 96-12-805/18/15 16:310.57 1
Dibromochloromethane ND mg/kg 05/19/15 21:27 124-48-105/18/15 16:310.057 1
1,2-Dibromoethane (EDB) ND mg/kg 05/19/15 21:27 106-93-405/18/15 16:310.057 1
Dibromomethane ND mg/kg 05/19/15 21:27 74-95-305/18/15 16:310.23 1
1,2-Dichlorobenzene ND mg/kg 05/19/15 21:27 95-50-105/18/15 16:310.057 1
1,3-Dichlorobenzene ND mg/kg 05/19/15 21:27 541-73-105/18/15 16:310.057 1
1,4-Dichlorobenzene ND mg/kg 05/19/15 21:27 106-46-705/18/15 16:310.057 1
Dichlorodifluoromethane ND mg/kg 05/19/15 21:27 75-71-805/18/15 16:310.23 1
1,1-Dichloroethane ND mg/kg 05/19/15 21:27 75-34-305/18/15 16:310.057 1
1,2-Dichloroethane ND mg/kg 05/19/15 21:27 107-06-205/18/15 16:310.057 1
1,1-Dichloroethene ND mg/kg 05/19/15 21:27 75-35-405/18/15 16:310.057 1
cis-1,2-Dichloroethene ND mg/kg 05/19/15 21:27 156-59-205/18/15 16:310.057 1
trans-1,2-Dichloroethene ND mg/kg 05/19/15 21:27 156-60-5 L205/18/15 16:310.057 1
Dichlorofluoromethane ND mg/kg 05/19/15 21:27 75-43-405/18/15 16:310.57 1
1,2-Dichloropropane ND mg/kg 05/19/15 21:27 78-87-505/18/15 16:310.057 1
1,3-Dichloropropane ND mg/kg 05/19/15 21:27 142-28-905/18/15 16:310.057 1
2,2-Dichloropropane ND mg/kg 05/19/15 21:27 594-20-705/18/15 16:310.23 1
1,1-Dichloropropene ND mg/kg 05/19/15 21:27 563-58-605/18/15 16:310.057 1
cis-1,3-Dichloropropene ND mg/kg 05/19/15 21:27 10061-01-505/18/15 16:310.057 1
trans-1,3-Dichloropropene ND mg/kg 05/19/15 21:27 10061-02-605/18/15 16:310.057 1
Diethyl ether (Ethyl ether) ND mg/kg 05/19/15 21:27 60-29-705/18/15 16:310.23 1
Ethylbenzene ND mg/kg 05/19/15 21:27 100-41-405/18/15 16:310.057 1
Hexachloro-1,3-butadiene ND mg/kg 05/19/15 21:27 87-68-305/18/15 16:310.29 1
Isopropylbenzene (Cumene) ND mg/kg 05/19/15 21:27 98-82-805/18/15 16:310.057 1
p-Isopropyltoluene ND mg/kg 05/19/15 21:27 99-87-605/18/15 16:310.057 1
Methylene Chloride ND mg/kg 05/19/15 21:27 75-09-205/18/15 16:310.23 1
4-Methyl-2-pentanone (MIBK) ND mg/kg 05/19/15 21:27 108-10-105/18/15 16:310.29 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 8 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-19/4-6 Lab ID: 10306235002 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
Methyl-tert-butyl ether ND mg/kg 05/19/15 21:27 1634-04-405/18/15 16:310.057 1
Naphthalene ND mg/kg 05/19/15 21:27 91-20-305/18/15 16:310.23 1
n-Propylbenzene ND mg/kg 05/19/15 21:27 103-65-105/18/15 16:310.057 1
Styrene ND mg/kg 05/19/15 21:27 100-42-505/18/15 16:310.057 1
1,1,1,2-Tetrachloroethane ND mg/kg 05/19/15 21:27 630-20-605/18/15 16:310.057 1
1,1,2,2-Tetrachloroethane ND mg/kg 05/19/15 21:27 79-34-505/18/15 16:310.057 1
Tetrachloroethene ND mg/kg 05/19/15 21:27 127-18-405/18/15 16:310.057 1
Tetrahydrofuran ND mg/kg 05/19/15 21:27 109-99-905/18/15 16:312.3 1
Toluene ND mg/kg 05/19/15 21:27 108-88-305/18/15 16:310.057 1
1,2,3-Trichlorobenzene ND mg/kg 05/19/15 21:27 87-61-605/18/15 16:310.23 1
1,2,4-Trichlorobenzene ND mg/kg 05/19/15 21:27 120-82-105/18/15 16:310.23 1
1,1,1-Trichloroethane ND mg/kg 05/19/15 21:27 71-55-605/18/15 16:310.057 1
1,1,2-Trichloroethane ND mg/kg 05/19/15 21:27 79-00-505/18/15 16:310.057 1
Trichloroethene ND mg/kg 05/19/15 21:27 79-01-605/18/15 16:310.057 1
Trichlorofluoromethane ND mg/kg 05/19/15 21:27 75-69-405/18/15 16:310.23 1
1,2,3-Trichloropropane ND mg/kg 05/19/15 21:27 96-18-405/18/15 16:310.23 1
1,1,2-Trichlorotrifluoroethane ND mg/kg 05/19/15 21:27 76-13-1 L205/18/15 16:310.23 1
1,2,4-Trimethylbenzene ND mg/kg 05/19/15 21:27 95-63-605/18/15 16:310.057 1
1,3,5-Trimethylbenzene ND mg/kg 05/19/15 21:27 108-67-805/18/15 16:310.057 1
Vinyl chloride ND mg/kg 05/19/15 21:27 75-01-405/18/15 16:310.023 1
Xylene (Total) ND mg/kg 05/19/15 21:27 1330-20-705/18/15 16:310.17 1
Surrogates1,2-Dichloroethane-d4 (S) 102 %. 05/19/15 21:27 17060-07-005/18/15 16:3155-150 1
Toluene-d8 (S) 101 %. 05/19/15 21:27 2037-26-505/18/15 16:3161-125 1
4-Bromofluorobenzene (S) 102 %. 05/19/15 21:27 460-00-405/18/15 16:3154-131 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 9 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LHA-20/5-7 Lab ID: 10306235003 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 1.3 mg/kg 05/20/15 01:00 7440-38-205/18/15 04:461.0 1
Barium 45.5 mg/kg 05/20/15 01:00 7440-39-305/18/15 04:460.51 1
Cadmium 0.22 mg/kg 05/20/15 01:00 7440-43-905/18/15 04:460.15 1
Chromium 5.5 mg/kg 05/20/15 01:00 7440-47-305/18/15 04:460.51 1
Lead 5.2 mg/kg 05/20/15 01:00 7439-92-105/18/15 04:460.51 1
Selenium ND mg/kg 05/20/15 01:00 7782-49-205/18/15 04:461.0 1
Silver ND mg/kg 05/20/15 01:00 7440-22-405/18/15 04:460.51 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/18/15 19:33 7439-97-605/17/15 15:180.019 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 11.7 % 05/19/15 09:040.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/20/15 06:49 83-32-905/15/15 22:170.011 1
Acenaphthylene ND mg/kg 05/20/15 06:49 208-96-805/15/15 22:170.011 1
Anthracene ND mg/kg 05/20/15 06:49 120-12-705/15/15 22:170.011 1
Benzo(a)anthracene 0.023 mg/kg 05/20/15 06:49 56-55-305/15/15 22:170.011 1
Benzo(a)pyrene 0.027 mg/kg 05/20/15 06:49 50-32-805/15/15 22:170.011 1
Benzo(b)fluoranthene 0.041 mg/kg 05/20/15 06:49 205-99-205/15/15 22:170.011 1
Benzo(g,h,i)perylene 0.026 mg/kg 05/20/15 06:49 191-24-205/15/15 22:170.011 1
Benzo(k)fluoranthene 0.012 mg/kg 05/20/15 06:49 207-08-905/15/15 22:170.011 1
Chrysene 0.026 mg/kg 05/20/15 06:49 218-01-905/15/15 22:170.011 1
Dibenz(a,h)anthracene ND mg/kg 05/20/15 06:49 53-70-305/15/15 22:170.011 1
Fluoranthene 0.043 mg/kg 05/20/15 06:49 206-44-005/15/15 22:170.011 1
Fluorene ND mg/kg 05/20/15 06:49 86-73-705/15/15 22:170.011 1
Indeno(1,2,3-cd)pyrene 0.019 mg/kg 05/20/15 06:49 193-39-505/15/15 22:170.011 1
Naphthalene ND mg/kg 05/20/15 06:49 91-20-305/15/15 22:170.011 1
Phenanthrene 0.016 mg/kg 05/20/15 06:49 85-01-805/15/15 22:170.011 1
Pyrene 0.041 mg/kg 05/20/15 06:49 129-00-005/15/15 22:170.011 1
Total BaP Eq. MN 2006sh. ND=0 0.037 mg/kg 05/20/15 06:4905/15/15 22:170.011 1
Surrogates2-Fluorobiphenyl (S) 65 %. 05/20/15 06:49 321-60-805/15/15 22:1755-125 1
p-Terphenyl-d14 (S) 76 %. 05/20/15 06:49 1718-51-005/15/15 22:1730-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 10 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LHA-21/2-4 Lab ID: 10306235004 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: WI MOD DRO Preparation Method: WI MOD DROWIDRO GCS Silica Gel
WDRO C10-C28 15.3 mg/kg 05/19/15 10:35 T605/15/15 13:275.2 1
Surrogatesn-Triacontane (S) 72 %. 05/19/15 10:35 638-68-605/15/15 13:2730-143 1
Analytical Method: WI MOD GRO Preparation Method: EPA 5030 Medium SoilWIGRO GCV
Gasoline Range Organics ND mg/kg 05/18/15 17:0105/15/15 14:5911.5 1
Surrogatesa,a,a-Trifluorotoluene (S) 117 %. 05/18/15 17:01 98-08-805/15/15 14:5980-150 1
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 1.6 mg/kg 05/20/15 01:05 7440-38-205/18/15 04:461.0 1
Barium 57.5 mg/kg 05/20/15 01:05 7440-39-305/18/15 04:460.50 1
Cadmium 0.24 mg/kg 05/20/15 01:05 7440-43-905/18/15 04:460.15 1
Chromium 7.7 mg/kg 05/20/15 01:05 7440-47-305/18/15 04:460.50 1
Lead 13.6 mg/kg 05/20/15 01:05 7439-92-105/18/15 04:460.50 1
Selenium ND mg/kg 05/20/15 01:05 7782-49-205/18/15 04:461.0 1
Silver ND mg/kg 05/20/15 01:05 7440-22-405/18/15 04:460.50 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/18/15 19:36 7439-97-605/17/15 15:180.022 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 12.4 % 05/19/15 09:050.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/20/15 17:55 83-32-905/15/15 22:170.011 1
Acenaphthylene 0.034 mg/kg 05/20/15 17:55 208-96-805/15/15 22:170.011 1
Anthracene 0.019 mg/kg 05/20/15 17:55 120-12-705/15/15 22:170.011 1
Benzo(a)anthracene 0.015 mg/kg 05/20/15 17:55 56-55-305/15/15 22:170.011 1
Benzo(a)pyrene 0.028 mg/kg 05/20/15 17:55 50-32-805/15/15 22:170.011 1
Benzo(b)fluoranthene 0.041 mg/kg 05/20/15 17:55 205-99-205/15/15 22:170.011 1
Benzo(g,h,i)perylene 0.064 mg/kg 05/20/15 17:55 191-24-205/15/15 22:170.011 1
Benzo(k)fluoranthene 0.013 mg/kg 05/20/15 17:55 207-08-905/15/15 22:170.011 1
Chrysene 0.016 mg/kg 05/20/15 17:55 218-01-905/15/15 22:170.011 1
Dibenz(a,h)anthracene ND mg/kg 05/20/15 17:55 53-70-305/15/15 22:170.011 1
Fluoranthene ND mg/kg 05/20/15 17:55 206-44-005/15/15 22:170.011 1
Fluorene ND mg/kg 05/20/15 17:55 86-73-705/15/15 22:170.011 1
Indeno(1,2,3-cd)pyrene 0.037 mg/kg 05/20/15 17:55 193-39-505/15/15 22:170.011 1
Naphthalene ND mg/kg 05/20/15 17:55 91-20-305/15/15 22:170.011 1
Phenanthrene ND mg/kg 05/20/15 17:55 85-01-805/15/15 22:170.011 1
Pyrene 0.017 mg/kg 05/20/15 17:55 129-00-005/15/15 22:170.011 1
Total BaP Eq. MN 2006sh. ND=0 0.039 mg/kg 05/20/15 17:5505/15/15 22:170.011 1
Surrogates2-Fluorobiphenyl (S) 71 %. 05/20/15 17:55 321-60-805/15/15 22:1755-125 1
p-Terphenyl-d14 (S) 72 %. 05/20/15 17:55 1718-51-005/15/15 22:1730-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 11 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LHA-21/2-4 Lab ID: 10306235004 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
Acetone ND mg/kg 05/19/15 21:48 67-64-105/18/15 16:311.2 1
Allyl chloride ND mg/kg 05/19/15 21:48 107-05-105/18/15 16:310.23 1
Benzene ND mg/kg 05/19/15 21:48 71-43-205/18/15 16:310.023 1
Bromobenzene ND mg/kg 05/19/15 21:48 108-86-105/18/15 16:310.058 1
Bromochloromethane ND mg/kg 05/19/15 21:48 74-97-505/18/15 16:310.058 1
Bromodichloromethane ND mg/kg 05/19/15 21:48 75-27-405/18/15 16:310.058 1
Bromoform ND mg/kg 05/19/15 21:48 75-25-205/18/15 16:310.23 1
Bromomethane ND mg/kg 05/19/15 21:48 74-83-905/18/15 16:310.58 1
2-Butanone (MEK) ND mg/kg 05/19/15 21:48 78-93-305/18/15 16:310.29 1
n-Butylbenzene ND mg/kg 05/19/15 21:48 104-51-805/18/15 16:310.058 1
sec-Butylbenzene ND mg/kg 05/19/15 21:48 135-98-805/18/15 16:310.058 1
tert-Butylbenzene ND mg/kg 05/19/15 21:48 98-06-605/18/15 16:310.058 1
Carbon tetrachloride ND mg/kg 05/19/15 21:48 56-23-505/18/15 16:310.23 1
Chlorobenzene ND mg/kg 05/19/15 21:48 108-90-705/18/15 16:310.058 1
Chloroethane ND mg/kg 05/19/15 21:48 75-00-305/18/15 16:310.58 1
Chloroform ND mg/kg 05/19/15 21:48 67-66-305/18/15 16:310.058 1
Chloromethane ND mg/kg 05/19/15 21:48 74-87-305/18/15 16:310.23 1
2-Chlorotoluene ND mg/kg 05/19/15 21:48 95-49-805/18/15 16:310.058 1
4-Chlorotoluene ND mg/kg 05/19/15 21:48 106-43-405/18/15 16:310.058 1
1,2-Dibromo-3-chloropropane ND mg/kg 05/19/15 21:48 96-12-805/18/15 16:310.58 1
Dibromochloromethane ND mg/kg 05/19/15 21:48 124-48-105/18/15 16:310.058 1
1,2-Dibromoethane (EDB) ND mg/kg 05/19/15 21:48 106-93-405/18/15 16:310.058 1
Dibromomethane ND mg/kg 05/19/15 21:48 74-95-305/18/15 16:310.23 1
1,2-Dichlorobenzene ND mg/kg 05/19/15 21:48 95-50-105/18/15 16:310.058 1
1,3-Dichlorobenzene ND mg/kg 05/19/15 21:48 541-73-105/18/15 16:310.058 1
1,4-Dichlorobenzene ND mg/kg 05/19/15 21:48 106-46-705/18/15 16:310.058 1
Dichlorodifluoromethane ND mg/kg 05/19/15 21:48 75-71-805/18/15 16:310.23 1
1,1-Dichloroethane ND mg/kg 05/19/15 21:48 75-34-305/18/15 16:310.058 1
1,2-Dichloroethane ND mg/kg 05/19/15 21:48 107-06-205/18/15 16:310.058 1
1,1-Dichloroethene ND mg/kg 05/19/15 21:48 75-35-405/18/15 16:310.058 1
cis-1,2-Dichloroethene ND mg/kg 05/19/15 21:48 156-59-205/18/15 16:310.058 1
trans-1,2-Dichloroethene ND mg/kg 05/19/15 21:48 156-60-5 L205/18/15 16:310.058 1
Dichlorofluoromethane ND mg/kg 05/19/15 21:48 75-43-405/18/15 16:310.58 1
1,2-Dichloropropane ND mg/kg 05/19/15 21:48 78-87-505/18/15 16:310.058 1
1,3-Dichloropropane ND mg/kg 05/19/15 21:48 142-28-905/18/15 16:310.058 1
2,2-Dichloropropane ND mg/kg 05/19/15 21:48 594-20-705/18/15 16:310.23 1
1,1-Dichloropropene ND mg/kg 05/19/15 21:48 563-58-605/18/15 16:310.058 1
cis-1,3-Dichloropropene ND mg/kg 05/19/15 21:48 10061-01-505/18/15 16:310.058 1
trans-1,3-Dichloropropene ND mg/kg 05/19/15 21:48 10061-02-605/18/15 16:310.058 1
Diethyl ether (Ethyl ether) ND mg/kg 05/19/15 21:48 60-29-705/18/15 16:310.23 1
Ethylbenzene ND mg/kg 05/19/15 21:48 100-41-405/18/15 16:310.058 1
Hexachloro-1,3-butadiene ND mg/kg 05/19/15 21:48 87-68-305/18/15 16:310.29 1
Isopropylbenzene (Cumene) ND mg/kg 05/19/15 21:48 98-82-805/18/15 16:310.058 1
p-Isopropyltoluene 0.061 mg/kg 05/19/15 21:48 99-87-605/18/15 16:310.058 1
Methylene Chloride ND mg/kg 05/19/15 21:48 75-09-205/18/15 16:310.23 1
4-Methyl-2-pentanone (MIBK) ND mg/kg 05/19/15 21:48 108-10-105/18/15 16:310.29 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 12 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LHA-21/2-4 Lab ID: 10306235004 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
Methyl-tert-butyl ether ND mg/kg 05/19/15 21:48 1634-04-405/18/15 16:310.058 1
Naphthalene ND mg/kg 05/19/15 21:48 91-20-305/18/15 16:310.23 1
n-Propylbenzene ND mg/kg 05/19/15 21:48 103-65-105/18/15 16:310.058 1
Styrene ND mg/kg 05/19/15 21:48 100-42-505/18/15 16:310.058 1
1,1,1,2-Tetrachloroethane ND mg/kg 05/19/15 21:48 630-20-605/18/15 16:310.058 1
1,1,2,2-Tetrachloroethane ND mg/kg 05/19/15 21:48 79-34-505/18/15 16:310.058 1
Tetrachloroethene ND mg/kg 05/19/15 21:48 127-18-405/18/15 16:310.058 1
Tetrahydrofuran ND mg/kg 05/19/15 21:48 109-99-905/18/15 16:312.3 1
Toluene ND mg/kg 05/19/15 21:48 108-88-305/18/15 16:310.058 1
1,2,3-Trichlorobenzene ND mg/kg 05/19/15 21:48 87-61-605/18/15 16:310.23 1
1,2,4-Trichlorobenzene ND mg/kg 05/19/15 21:48 120-82-105/18/15 16:310.23 1
1,1,1-Trichloroethane ND mg/kg 05/19/15 21:48 71-55-605/18/15 16:310.058 1
1,1,2-Trichloroethane ND mg/kg 05/19/15 21:48 79-00-505/18/15 16:310.058 1
Trichloroethene ND mg/kg 05/19/15 21:48 79-01-605/18/15 16:310.058 1
Trichlorofluoromethane ND mg/kg 05/19/15 21:48 75-69-405/18/15 16:310.23 1
1,2,3-Trichloropropane ND mg/kg 05/19/15 21:48 96-18-405/18/15 16:310.23 1
1,1,2-Trichlorotrifluoroethane ND mg/kg 05/19/15 21:48 76-13-1 L205/18/15 16:310.23 1
1,2,4-Trimethylbenzene ND mg/kg 05/19/15 21:48 95-63-605/18/15 16:310.058 1
1,3,5-Trimethylbenzene ND mg/kg 05/19/15 21:48 108-67-805/18/15 16:310.058 1
Vinyl chloride ND mg/kg 05/19/15 21:48 75-01-405/18/15 16:310.023 1
Xylene (Total) ND mg/kg 05/19/15 21:48 1330-20-705/18/15 16:310.17 1
Surrogates1,2-Dichloroethane-d4 (S) 99 %. 05/19/15 21:48 17060-07-005/18/15 16:3155-150 1
Toluene-d8 (S) 101 %. 05/19/15 21:48 2037-26-505/18/15 16:3161-125 1
4-Bromofluorobenzene (S) 102 %. 05/19/15 21:48 460-00-405/18/15 16:3154-131 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 13 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-22/4-6 Lab ID: 10306235005 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: WI MOD DRO Preparation Method: WI MOD DROWIDRO GCS Silica Gel
WDRO C10-C28 ND mg/kg 05/19/15 10:4305/15/15 13:276.0 1
Surrogatesn-Triacontane (S) 88 %. 05/19/15 10:43 638-68-605/15/15 13:2730-143 1
Analytical Method: WI MOD GRO Preparation Method: EPA 5030 Medium SoilWIGRO GCV
Gasoline Range Organics ND mg/kg 05/18/15 18:0805/15/15 14:5911.7 1
Surrogatesa,a,a-Trifluorotoluene (S) 117 %. 05/18/15 18:08 98-08-805/15/15 14:5980-150 1
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic ND mg/kg 05/20/15 01:10 7440-38-205/18/15 04:460.93 1
Barium 55.2 mg/kg 05/20/15 01:10 7440-39-305/18/15 04:460.47 1
Cadmium 0.26 mg/kg 05/20/15 01:10 7440-43-905/18/15 04:460.14 1
Chromium 6.8 mg/kg 05/20/15 01:10 7440-47-305/18/15 04:460.47 1
Lead 4.8 mg/kg 05/20/15 01:10 7439-92-105/18/15 04:460.47 1
Selenium ND mg/kg 05/20/15 01:10 7782-49-205/18/15 04:460.93 1
Silver ND mg/kg 05/20/15 01:10 7440-22-405/18/15 04:460.47 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/18/15 19:39 7439-97-605/17/15 15:180.020 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 14.8 % 05/19/15 10:350.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/20/15 15:27 83-32-905/15/15 22:170.012 1
Acenaphthylene ND mg/kg 05/20/15 15:27 208-96-805/15/15 22:170.012 1
Anthracene ND mg/kg 05/20/15 15:27 120-12-705/15/15 22:170.012 1
Benzo(a)anthracene ND mg/kg 05/20/15 15:27 56-55-305/15/15 22:170.012 1
Benzo(a)pyrene ND mg/kg 05/20/15 15:27 50-32-805/15/15 22:170.012 1
Benzo(b)fluoranthene ND mg/kg 05/20/15 15:27 205-99-205/15/15 22:170.012 1
Benzo(g,h,i)perylene ND mg/kg 05/20/15 15:27 191-24-205/15/15 22:170.012 1
Benzo(k)fluoranthene ND mg/kg 05/20/15 15:27 207-08-905/15/15 22:170.012 1
Chrysene ND mg/kg 05/20/15 15:27 218-01-905/15/15 22:170.012 1
Dibenz(a,h)anthracene ND mg/kg 05/20/15 15:27 53-70-305/15/15 22:170.012 1
Fluoranthene ND mg/kg 05/20/15 15:27 206-44-005/15/15 22:170.012 1
Fluorene ND mg/kg 05/20/15 15:27 86-73-705/15/15 22:170.012 1
Indeno(1,2,3-cd)pyrene ND mg/kg 05/20/15 15:27 193-39-505/15/15 22:170.012 1
Naphthalene ND mg/kg 05/20/15 15:27 91-20-305/15/15 22:170.012 1
Phenanthrene ND mg/kg 05/20/15 15:27 85-01-805/15/15 22:170.012 1
Pyrene ND mg/kg 05/20/15 15:27 129-00-005/15/15 22:170.012 1
Total BaP Eq. MN 2006sh. ND=0 ND mg/kg 05/20/15 15:2705/15/15 22:170.012 1
Surrogates2-Fluorobiphenyl (S) 58 %. 05/20/15 15:27 321-60-805/15/15 22:1755-125 1
p-Terphenyl-d14 (S) 73 %. 05/20/15 15:27 1718-51-005/15/15 22:1730-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 14 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-22/4-6 Lab ID: 10306235005 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
Acetone ND mg/kg 05/19/15 19:26 67-64-105/18/15 16:311.2 1
Allyl chloride ND mg/kg 05/19/15 19:26 107-05-105/18/15 16:310.23 1
Benzene ND mg/kg 05/19/15 19:26 71-43-205/18/15 16:310.023 1
Bromobenzene ND mg/kg 05/19/15 19:26 108-86-105/18/15 16:310.058 1
Bromochloromethane ND mg/kg 05/19/15 19:26 74-97-505/18/15 16:310.058 1
Bromodichloromethane ND mg/kg 05/19/15 19:26 75-27-405/18/15 16:310.058 1
Bromoform ND mg/kg 05/19/15 19:26 75-25-205/18/15 16:310.23 1
Bromomethane ND mg/kg 05/19/15 19:26 74-83-905/18/15 16:310.58 1
2-Butanone (MEK) ND mg/kg 05/19/15 19:26 78-93-305/18/15 16:310.29 1
n-Butylbenzene ND mg/kg 05/19/15 19:26 104-51-805/18/15 16:310.058 1
sec-Butylbenzene ND mg/kg 05/19/15 19:26 135-98-805/18/15 16:310.058 1
tert-Butylbenzene ND mg/kg 05/19/15 19:26 98-06-605/18/15 16:310.058 1
Carbon tetrachloride ND mg/kg 05/19/15 19:26 56-23-505/18/15 16:310.23 1
Chlorobenzene ND mg/kg 05/19/15 19:26 108-90-705/18/15 16:310.058 1
Chloroethane ND mg/kg 05/19/15 19:26 75-00-305/18/15 16:310.58 1
Chloroform ND mg/kg 05/19/15 19:26 67-66-305/18/15 16:310.058 1
Chloromethane ND mg/kg 05/19/15 19:26 74-87-305/18/15 16:310.23 1
2-Chlorotoluene ND mg/kg 05/19/15 19:26 95-49-805/18/15 16:310.058 1
4-Chlorotoluene ND mg/kg 05/19/15 19:26 106-43-405/18/15 16:310.058 1
1,2-Dibromo-3-chloropropane ND mg/kg 05/19/15 19:26 96-12-805/18/15 16:310.58 1
Dibromochloromethane ND mg/kg 05/19/15 19:26 124-48-105/18/15 16:310.058 1
1,2-Dibromoethane (EDB) ND mg/kg 05/19/15 19:26 106-93-405/18/15 16:310.058 1
Dibromomethane ND mg/kg 05/19/15 19:26 74-95-305/18/15 16:310.23 1
1,2-Dichlorobenzene ND mg/kg 05/19/15 19:26 95-50-105/18/15 16:310.058 1
1,3-Dichlorobenzene ND mg/kg 05/19/15 19:26 541-73-105/18/15 16:310.058 1
1,4-Dichlorobenzene ND mg/kg 05/19/15 19:26 106-46-705/18/15 16:310.058 1
Dichlorodifluoromethane ND mg/kg 05/19/15 19:26 75-71-805/18/15 16:310.23 1
1,1-Dichloroethane ND mg/kg 05/19/15 19:26 75-34-305/18/15 16:310.058 1
1,2-Dichloroethane ND mg/kg 05/19/15 19:26 107-06-205/18/15 16:310.058 1
1,1-Dichloroethene ND mg/kg 05/19/15 19:26 75-35-405/18/15 16:310.058 1
cis-1,2-Dichloroethene ND mg/kg 05/19/15 19:26 156-59-205/18/15 16:310.058 1
trans-1,2-Dichloroethene ND mg/kg 05/19/15 19:26 156-60-5 L205/18/15 16:310.058 1
Dichlorofluoromethane ND mg/kg 05/19/15 19:26 75-43-405/18/15 16:310.58 1
1,2-Dichloropropane ND mg/kg 05/19/15 19:26 78-87-505/18/15 16:310.058 1
1,3-Dichloropropane ND mg/kg 05/19/15 19:26 142-28-905/18/15 16:310.058 1
2,2-Dichloropropane ND mg/kg 05/19/15 19:26 594-20-705/18/15 16:310.23 1
1,1-Dichloropropene ND mg/kg 05/19/15 19:26 563-58-605/18/15 16:310.058 1
cis-1,3-Dichloropropene ND mg/kg 05/19/15 19:26 10061-01-505/18/15 16:310.058 1
trans-1,3-Dichloropropene ND mg/kg 05/19/15 19:26 10061-02-605/18/15 16:310.058 1
Diethyl ether (Ethyl ether) ND mg/kg 05/19/15 19:26 60-29-705/18/15 16:310.23 1
Ethylbenzene ND mg/kg 05/19/15 19:26 100-41-405/18/15 16:310.058 1
Hexachloro-1,3-butadiene ND mg/kg 05/19/15 19:26 87-68-305/18/15 16:310.29 1
Isopropylbenzene (Cumene) ND mg/kg 05/19/15 19:26 98-82-805/18/15 16:310.058 1
p-Isopropyltoluene ND mg/kg 05/19/15 19:26 99-87-605/18/15 16:310.058 1
Methylene Chloride ND mg/kg 05/19/15 19:26 75-09-205/18/15 16:310.23 1
4-Methyl-2-pentanone (MIBK) ND mg/kg 05/19/15 19:26 108-10-105/18/15 16:310.29 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 15 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-22/4-6 Lab ID: 10306235005 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
Methyl-tert-butyl ether ND mg/kg 05/19/15 19:26 1634-04-405/18/15 16:310.058 1
Naphthalene ND mg/kg 05/19/15 19:26 91-20-305/18/15 16:310.23 1
n-Propylbenzene ND mg/kg 05/19/15 19:26 103-65-105/18/15 16:310.058 1
Styrene ND mg/kg 05/19/15 19:26 100-42-505/18/15 16:310.058 1
1,1,1,2-Tetrachloroethane ND mg/kg 05/19/15 19:26 630-20-605/18/15 16:310.058 1
1,1,2,2-Tetrachloroethane ND mg/kg 05/19/15 19:26 79-34-505/18/15 16:310.058 1
Tetrachloroethene ND mg/kg 05/19/15 19:26 127-18-405/18/15 16:310.058 1
Tetrahydrofuran ND mg/kg 05/19/15 19:26 109-99-905/18/15 16:312.3 1
Toluene ND mg/kg 05/19/15 19:26 108-88-305/18/15 16:310.058 1
1,2,3-Trichlorobenzene ND mg/kg 05/19/15 19:26 87-61-605/18/15 16:310.23 1
1,2,4-Trichlorobenzene ND mg/kg 05/19/15 19:26 120-82-105/18/15 16:310.23 1
1,1,1-Trichloroethane ND mg/kg 05/19/15 19:26 71-55-605/18/15 16:310.058 1
1,1,2-Trichloroethane ND mg/kg 05/19/15 19:26 79-00-505/18/15 16:310.058 1
Trichloroethene ND mg/kg 05/19/15 19:26 79-01-605/18/15 16:310.058 1
Trichlorofluoromethane ND mg/kg 05/19/15 19:26 75-69-405/18/15 16:310.23 1
1,2,3-Trichloropropane ND mg/kg 05/19/15 19:26 96-18-405/18/15 16:310.23 1
1,1,2-Trichlorotrifluoroethane ND mg/kg 05/19/15 19:26 76-13-1 L205/18/15 16:310.23 1
1,2,4-Trimethylbenzene ND mg/kg 05/19/15 19:26 95-63-605/18/15 16:310.058 1
1,3,5-Trimethylbenzene ND mg/kg 05/19/15 19:26 108-67-805/18/15 16:310.058 1
Vinyl chloride ND mg/kg 05/19/15 19:26 75-01-405/18/15 16:310.023 1
Xylene (Total) ND mg/kg 05/19/15 19:26 1330-20-705/18/15 16:310.17 1
Surrogates1,2-Dichloroethane-d4 (S) 102 %. 05/19/15 19:26 17060-07-005/18/15 16:3155-150 1
Toluene-d8 (S) 98 %. 05/19/15 19:26 2037-26-505/18/15 16:3161-125 1
4-Bromofluorobenzene (S) 105 %. 05/19/15 19:26 460-00-405/18/15 16:3154-131 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 16 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-23/6-8 Lab ID: 10306235006 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: WI MOD DRO Preparation Method: WI MOD DROWIDRO GCS Silica Gel
WDRO C10-C28 ND mg/kg 05/19/15 10:5105/15/15 13:275.9 1
Surrogatesn-Triacontane (S) 88 %. 05/19/15 10:51 638-68-605/15/15 13:2730-143 1
Analytical Method: WI MOD GRO Preparation Method: EPA 5030 Medium SoilWIGRO GCV
Gasoline Range Organics ND mg/kg 05/18/15 18:3105/15/15 14:5911.4 1
Surrogatesa,a,a-Trifluorotoluene (S) 119 %. 05/18/15 18:31 98-08-805/15/15 14:5980-150 1
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 2.4 mg/kg 05/20/15 01:15 7440-38-205/18/15 04:460.81 1
Barium 46.9 mg/kg 05/20/15 01:15 7440-39-305/18/15 04:460.40 1
Cadmium 0.22 mg/kg 05/20/15 01:15 7440-43-905/18/15 04:460.12 1
Chromium 7.0 mg/kg 05/20/15 01:15 7440-47-305/18/15 04:460.40 1
Lead 3.3 mg/kg 05/20/15 01:15 7439-92-105/18/15 04:460.40 1
Selenium ND mg/kg 05/20/15 01:15 7782-49-205/18/15 04:460.81 1
Silver ND mg/kg 05/20/15 01:15 7440-22-405/18/15 04:460.40 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/18/15 19:41 7439-97-605/17/15 15:180.020 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 10.5 % 05/19/15 10:350.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/20/15 15:48 83-32-905/15/15 22:170.011 1
Acenaphthylene ND mg/kg 05/20/15 15:48 208-96-805/15/15 22:170.011 1
Anthracene ND mg/kg 05/20/15 15:48 120-12-705/15/15 22:170.011 1
Benzo(a)anthracene ND mg/kg 05/20/15 15:48 56-55-305/15/15 22:170.011 1
Benzo(a)pyrene ND mg/kg 05/20/15 15:48 50-32-805/15/15 22:170.011 1
Benzo(b)fluoranthene ND mg/kg 05/20/15 15:48 205-99-205/15/15 22:170.011 1
Benzo(g,h,i)perylene ND mg/kg 05/20/15 15:48 191-24-205/15/15 22:170.011 1
Benzo(k)fluoranthene ND mg/kg 05/20/15 15:48 207-08-905/15/15 22:170.011 1
Chrysene ND mg/kg 05/20/15 15:48 218-01-905/15/15 22:170.011 1
Dibenz(a,h)anthracene ND mg/kg 05/20/15 15:48 53-70-305/15/15 22:170.011 1
Fluoranthene ND mg/kg 05/20/15 15:48 206-44-005/15/15 22:170.011 1
Fluorene ND mg/kg 05/20/15 15:48 86-73-705/15/15 22:170.011 1
Indeno(1,2,3-cd)pyrene ND mg/kg 05/20/15 15:48 193-39-505/15/15 22:170.011 1
Naphthalene ND mg/kg 05/20/15 15:48 91-20-305/15/15 22:170.011 1
Phenanthrene ND mg/kg 05/20/15 15:48 85-01-805/15/15 22:170.011 1
Pyrene ND mg/kg 05/20/15 15:48 129-00-005/15/15 22:170.011 1
Total BaP Eq. MN 2006sh. ND=0 ND mg/kg 05/20/15 15:4805/15/15 22:170.011 1
Surrogates2-Fluorobiphenyl (S) 57 %. 05/20/15 15:48 321-60-805/15/15 22:1755-125 1
p-Terphenyl-d14 (S) 73 %. 05/20/15 15:48 1718-51-005/15/15 22:1730-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 17 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-23/6-8 Lab ID: 10306235006 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
Acetone ND mg/kg 05/19/15 19:46 67-64-105/18/15 16:311.1 1
Allyl chloride ND mg/kg 05/19/15 19:46 107-05-105/18/15 16:310.23 1
Benzene ND mg/kg 05/19/15 19:46 71-43-205/18/15 16:310.023 1
Bromobenzene ND mg/kg 05/19/15 19:46 108-86-105/18/15 16:310.057 1
Bromochloromethane ND mg/kg 05/19/15 19:46 74-97-505/18/15 16:310.057 1
Bromodichloromethane ND mg/kg 05/19/15 19:46 75-27-405/18/15 16:310.057 1
Bromoform ND mg/kg 05/19/15 19:46 75-25-205/18/15 16:310.23 1
Bromomethane ND mg/kg 05/19/15 19:46 74-83-905/18/15 16:310.57 1
2-Butanone (MEK) ND mg/kg 05/19/15 19:46 78-93-305/18/15 16:310.29 1
n-Butylbenzene ND mg/kg 05/19/15 19:46 104-51-805/18/15 16:310.057 1
sec-Butylbenzene ND mg/kg 05/19/15 19:46 135-98-805/18/15 16:310.057 1
tert-Butylbenzene ND mg/kg 05/19/15 19:46 98-06-605/18/15 16:310.057 1
Carbon tetrachloride ND mg/kg 05/19/15 19:46 56-23-505/18/15 16:310.23 1
Chlorobenzene ND mg/kg 05/19/15 19:46 108-90-705/18/15 16:310.057 1
Chloroethane ND mg/kg 05/19/15 19:46 75-00-305/18/15 16:310.57 1
Chloroform ND mg/kg 05/19/15 19:46 67-66-305/18/15 16:310.057 1
Chloromethane ND mg/kg 05/19/15 19:46 74-87-305/18/15 16:310.23 1
2-Chlorotoluene ND mg/kg 05/19/15 19:46 95-49-805/18/15 16:310.057 1
4-Chlorotoluene ND mg/kg 05/19/15 19:46 106-43-405/18/15 16:310.057 1
1,2-Dibromo-3-chloropropane ND mg/kg 05/19/15 19:46 96-12-805/18/15 16:310.57 1
Dibromochloromethane ND mg/kg 05/19/15 19:46 124-48-105/18/15 16:310.057 1
1,2-Dibromoethane (EDB) ND mg/kg 05/19/15 19:46 106-93-405/18/15 16:310.057 1
Dibromomethane ND mg/kg 05/19/15 19:46 74-95-305/18/15 16:310.23 1
1,2-Dichlorobenzene ND mg/kg 05/19/15 19:46 95-50-105/18/15 16:310.057 1
1,3-Dichlorobenzene ND mg/kg 05/19/15 19:46 541-73-105/18/15 16:310.057 1
1,4-Dichlorobenzene ND mg/kg 05/19/15 19:46 106-46-705/18/15 16:310.057 1
Dichlorodifluoromethane ND mg/kg 05/19/15 19:46 75-71-805/18/15 16:310.23 1
1,1-Dichloroethane ND mg/kg 05/19/15 19:46 75-34-305/18/15 16:310.057 1
1,2-Dichloroethane ND mg/kg 05/19/15 19:46 107-06-205/18/15 16:310.057 1
1,1-Dichloroethene ND mg/kg 05/19/15 19:46 75-35-405/18/15 16:310.057 1
cis-1,2-Dichloroethene ND mg/kg 05/19/15 19:46 156-59-205/18/15 16:310.057 1
trans-1,2-Dichloroethene ND mg/kg 05/19/15 19:46 156-60-5 L205/18/15 16:310.057 1
Dichlorofluoromethane ND mg/kg 05/19/15 19:46 75-43-405/18/15 16:310.57 1
1,2-Dichloropropane ND mg/kg 05/19/15 19:46 78-87-505/18/15 16:310.057 1
1,3-Dichloropropane ND mg/kg 05/19/15 19:46 142-28-905/18/15 16:310.057 1
2,2-Dichloropropane ND mg/kg 05/19/15 19:46 594-20-705/18/15 16:310.23 1
1,1-Dichloropropene ND mg/kg 05/19/15 19:46 563-58-605/18/15 16:310.057 1
cis-1,3-Dichloropropene ND mg/kg 05/19/15 19:46 10061-01-505/18/15 16:310.057 1
trans-1,3-Dichloropropene ND mg/kg 05/19/15 19:46 10061-02-605/18/15 16:310.057 1
Diethyl ether (Ethyl ether) ND mg/kg 05/19/15 19:46 60-29-705/18/15 16:310.23 1
Ethylbenzene ND mg/kg 05/19/15 19:46 100-41-405/18/15 16:310.057 1
Hexachloro-1,3-butadiene ND mg/kg 05/19/15 19:46 87-68-305/18/15 16:310.29 1
Isopropylbenzene (Cumene) ND mg/kg 05/19/15 19:46 98-82-805/18/15 16:310.057 1
p-Isopropyltoluene ND mg/kg 05/19/15 19:46 99-87-605/18/15 16:310.057 1
Methylene Chloride ND mg/kg 05/19/15 19:46 75-09-205/18/15 16:310.23 1
4-Methyl-2-pentanone (MIBK) ND mg/kg 05/19/15 19:46 108-10-105/18/15 16:310.29 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 18 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-23/6-8 Lab ID: 10306235006 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
Methyl-tert-butyl ether ND mg/kg 05/19/15 19:46 1634-04-405/18/15 16:310.057 1
Naphthalene ND mg/kg 05/19/15 19:46 91-20-305/18/15 16:310.23 1
n-Propylbenzene ND mg/kg 05/19/15 19:46 103-65-105/18/15 16:310.057 1
Styrene ND mg/kg 05/19/15 19:46 100-42-505/18/15 16:310.057 1
1,1,1,2-Tetrachloroethane ND mg/kg 05/19/15 19:46 630-20-605/18/15 16:310.057 1
1,1,2,2-Tetrachloroethane ND mg/kg 05/19/15 19:46 79-34-505/18/15 16:310.057 1
Tetrachloroethene ND mg/kg 05/19/15 19:46 127-18-405/18/15 16:310.057 1
Tetrahydrofuran ND mg/kg 05/19/15 19:46 109-99-905/18/15 16:312.3 1
Toluene ND mg/kg 05/19/15 19:46 108-88-305/18/15 16:310.057 1
1,2,3-Trichlorobenzene ND mg/kg 05/19/15 19:46 87-61-605/18/15 16:310.23 1
1,2,4-Trichlorobenzene ND mg/kg 05/19/15 19:46 120-82-105/18/15 16:310.23 1
1,1,1-Trichloroethane ND mg/kg 05/19/15 19:46 71-55-605/18/15 16:310.057 1
1,1,2-Trichloroethane ND mg/kg 05/19/15 19:46 79-00-505/18/15 16:310.057 1
Trichloroethene ND mg/kg 05/19/15 19:46 79-01-605/18/15 16:310.057 1
Trichlorofluoromethane ND mg/kg 05/19/15 19:46 75-69-405/18/15 16:310.23 1
1,2,3-Trichloropropane ND mg/kg 05/19/15 19:46 96-18-405/18/15 16:310.23 1
1,1,2-Trichlorotrifluoroethane ND mg/kg 05/19/15 19:46 76-13-1 L205/18/15 16:310.23 1
1,2,4-Trimethylbenzene ND mg/kg 05/19/15 19:46 95-63-605/18/15 16:310.057 1
1,3,5-Trimethylbenzene ND mg/kg 05/19/15 19:46 108-67-805/18/15 16:310.057 1
Vinyl chloride ND mg/kg 05/19/15 19:46 75-01-405/18/15 16:310.023 1
Xylene (Total) ND mg/kg 05/19/15 19:46 1330-20-705/18/15 16:310.17 1
Surrogates1,2-Dichloroethane-d4 (S) 105 %. 05/19/15 19:46 17060-07-005/18/15 16:3155-150 1
Toluene-d8 (S) 101 %. 05/19/15 19:46 2037-26-505/18/15 16:3161-125 1
4-Bromofluorobenzene (S) 104 %. 05/19/15 19:46 460-00-405/18/15 16:3154-131 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 19 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-23/17-20 Lab ID: 10306235007 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: WI MOD DRO Preparation Method: WI MOD DROWIDRO GCS Silica Gel
WDRO C10-C28 ND mg/L 05/17/15 17:4005/15/15 13:230.14 1
Surrogatesn-Triacontane (S) 95 %. 05/17/15 17:40 638-68-6 P405/15/15 13:2362-125 1
Analytical Method: WI MOD GROWIGRO GCV
Gasoline Range Organics ND ug/L 05/23/15 00:2750.0 1
Analytical Method: EPA 8260B8260B VOC
Acetone ND ug/L 05/15/15 19:16 67-64-120.0 1
Allyl chloride ND ug/L 05/15/15 19:16 107-05-14.0 1
Benzene ND ug/L 05/15/15 19:16 71-43-21.0 1
Bromobenzene ND ug/L 05/15/15 19:16 108-86-11.0 1
Bromochloromethane ND ug/L 05/15/15 19:16 74-97-51.0 1
Bromodichloromethane ND ug/L 05/15/15 19:16 75-27-41.0 1
Bromoform ND ug/L 05/15/15 19:16 75-25-24.0 1
Bromomethane ND ug/L 05/15/15 19:16 74-83-94.0 1
2-Butanone (MEK) ND ug/L 05/15/15 19:16 78-93-35.0 1
n-Butylbenzene ND ug/L 05/15/15 19:16 104-51-81.0 1
sec-Butylbenzene ND ug/L 05/15/15 19:16 135-98-81.0 1
tert-Butylbenzene ND ug/L 05/15/15 19:16 98-06-61.0 1
Carbon tetrachloride ND ug/L 05/15/15 19:16 56-23-51.0 1
Chlorobenzene ND ug/L 05/15/15 19:16 108-90-71.0 1
Chloroethane ND ug/L 05/15/15 19:16 75-00-31.0 1
Chloroform ND ug/L 05/15/15 19:16 67-66-31.0 1
Chloromethane ND ug/L 05/15/15 19:16 74-87-34.0 1
2-Chlorotoluene ND ug/L 05/15/15 19:16 95-49-81.0 1
4-Chlorotoluene ND ug/L 05/15/15 19:16 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 05/15/15 19:16 96-12-84.0 1
Dibromochloromethane ND ug/L 05/15/15 19:16 124-48-11.0 1
1,2-Dibromoethane (EDB) ND ug/L 05/15/15 19:16 106-93-41.0 1
Dibromomethane ND ug/L 05/15/15 19:16 74-95-34.0 1
1,2-Dichlorobenzene ND ug/L 05/15/15 19:16 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 05/15/15 19:16 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 05/15/15 19:16 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 05/15/15 19:16 75-71-81.0 1
1,1-Dichloroethane ND ug/L 05/15/15 19:16 75-34-31.0 1
1,2-Dichloroethane ND ug/L 05/15/15 19:16 107-06-21.0 1
1,1-Dichloroethene ND ug/L 05/15/15 19:16 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 05/15/15 19:16 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 05/15/15 19:16 156-60-51.0 1
Dichlorofluoromethane ND ug/L 05/15/15 19:16 75-43-41.0 1
1,2-Dichloropropane ND ug/L 05/15/15 19:16 78-87-54.0 1
1,3-Dichloropropane ND ug/L 05/15/15 19:16 142-28-91.0 1
2,2-Dichloropropane ND ug/L 05/15/15 19:16 594-20-74.0 1
1,1-Dichloropropene ND ug/L 05/15/15 19:16 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 05/15/15 19:16 10061-01-54.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 20 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-23/17-20 Lab ID: 10306235007 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B8260B VOC
trans-1,3-Dichloropropene ND ug/L 05/15/15 19:16 10061-02-64.0 1
Diethyl ether (Ethyl ether) ND ug/L 05/15/15 19:16 60-29-74.0 1
Ethylbenzene ND ug/L 05/15/15 19:16 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 05/15/15 19:16 87-68-31.0 1
Isopropylbenzene (Cumene) ND ug/L 05/15/15 19:16 98-82-81.0 1
p-Isopropyltoluene ND ug/L 05/15/15 19:16 99-87-61.0 1
Methylene Chloride ND ug/L 05/15/15 19:16 75-09-24.0 1
4-Methyl-2-pentanone (MIBK) ND ug/L 05/15/15 19:16 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 05/15/15 19:16 1634-04-41.0 1
Naphthalene ND ug/L 05/15/15 19:16 91-20-34.0 1
n-Propylbenzene ND ug/L 05/15/15 19:16 103-65-11.0 1
Styrene ND ug/L 05/15/15 19:16 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 05/15/15 19:16 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 05/15/15 19:16 79-34-51.0 1
Tetrachloroethene ND ug/L 05/15/15 19:16 127-18-41.0 1
Tetrahydrofuran ND ug/L 05/15/15 19:16 109-99-910.0 1
Toluene ND ug/L 05/15/15 19:16 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 05/15/15 19:16 87-61-61.0 1
1,2,4-Trichlorobenzene ND ug/L 05/15/15 19:16 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 05/15/15 19:16 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 05/15/15 19:16 79-00-51.0 1
Trichloroethene ND ug/L 05/15/15 19:16 79-01-60.40 1
Trichlorofluoromethane ND ug/L 05/15/15 19:16 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 05/15/15 19:16 96-18-44.0 1
1,1,2-Trichlorotrifluoroethane ND ug/L 05/15/15 19:16 76-13-11.0 1
1,2,4-Trimethylbenzene ND ug/L 05/15/15 19:16 95-63-61.0 1
1,3,5-Trimethylbenzene ND ug/L 05/15/15 19:16 108-67-81.0 1
Vinyl chloride ND ug/L 05/15/15 19:16 75-01-40.40 1
Xylene (Total) ND ug/L 05/15/15 19:16 1330-20-73.0 1
Surrogates1,2-Dichloroethane-d4 (S) 94 %. 05/15/15 19:16 17060-07-075-125 1
Toluene-d8 (S) 100 %. 05/15/15 19:16 2037-26-575-125 1
4-Bromofluorobenzene (S) 98 %. 05/15/15 19:16 460-00-475-125 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 21 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-24/3-5 Lab ID: 10306235008 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 1.7 mg/kg 05/20/15 01:20 7440-38-205/18/15 04:461.1 1
Barium 67.0 mg/kg 05/20/15 01:20 7440-39-305/18/15 04:460.54 1
Cadmium 0.33 mg/kg 05/20/15 01:20 7440-43-905/18/15 04:460.16 1
Chromium 7.5 mg/kg 05/20/15 01:20 7440-47-305/18/15 04:460.54 1
Lead 19.8 mg/kg 05/20/15 01:20 7439-92-105/18/15 04:460.54 1
Selenium ND mg/kg 05/20/15 01:20 7782-49-205/18/15 04:461.1 1
Silver ND mg/kg 05/20/15 01:20 7440-22-405/18/15 04:460.54 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/18/15 19:43 7439-97-605/17/15 15:180.022 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 13.1 % 05/19/15 10:350.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/20/15 16:09 83-32-905/15/15 22:170.058 5
Acenaphthylene 0.087 mg/kg 05/20/15 16:09 208-96-805/15/15 22:170.058 5
Anthracene 0.081 mg/kg 05/20/15 16:09 120-12-705/15/15 22:170.058 5
Benzo(a)anthracene 0.34 mg/kg 05/20/15 16:09 56-55-305/15/15 22:170.058 5
Benzo(a)pyrene 0.46 mg/kg 05/20/15 16:09 50-32-805/15/15 22:170.058 5
Benzo(b)fluoranthene 0.58 mg/kg 05/20/15 16:09 205-99-205/15/15 22:170.058 5
Benzo(g,h,i)perylene 0.40 mg/kg 05/20/15 16:09 191-24-205/15/15 22:170.058 5
Benzo(k)fluoranthene 0.23 mg/kg 05/20/15 16:09 207-08-905/15/15 22:170.058 5
Chrysene 0.39 mg/kg 05/20/15 16:09 218-01-905/15/15 22:170.058 5
Dibenz(a,h)anthracene 0.084 mg/kg 05/20/15 16:09 53-70-305/15/15 22:170.058 5
Fluoranthene 0.66 mg/kg 05/20/15 16:09 206-44-005/15/15 22:170.058 5
Fluorene ND mg/kg 05/20/15 16:09 86-73-705/15/15 22:170.058 5
Indeno(1,2,3-cd)pyrene 0.28 mg/kg 05/20/15 16:09 193-39-505/15/15 22:170.058 5
Naphthalene ND mg/kg 05/20/15 16:09 91-20-305/15/15 22:170.058 5
Phenanthrene 0.27 mg/kg 05/20/15 16:09 85-01-805/15/15 22:170.058 5
Pyrene 0.67 mg/kg 05/20/15 16:09 129-00-005/15/15 22:170.058 5
Total BaP Eq. MN 2006sh. ND=0 0.65 mg/kg 05/20/15 16:0905/15/15 22:170.058 5
Surrogates2-Fluorobiphenyl (S) 66 %. 05/20/15 16:09 321-60-8 D405/15/15 22:1755-125 5
p-Terphenyl-d14 (S) 73 %. 05/20/15 16:09 1718-51-005/15/15 22:1730-150 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 22 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-25/1-3 Lab ID: 10306235009 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: WI MOD DRO Preparation Method: WI MOD DROWIDRO GCS Silica Gel
WDRO C10-C28 9.6 mg/kg 05/19/15 10:28 T605/15/15 13:275.5 1
Surrogatesn-Triacontane (S) 85 %. 05/19/15 10:28 638-68-605/15/15 13:2730-143 1
Analytical Method: WI MOD GRO Preparation Method: EPA 5030 Medium SoilWIGRO GCV
Gasoline Range Organics ND mg/kg 05/18/15 18:5305/15/15 14:5910.8 1
Surrogatesa,a,a-Trifluorotoluene (S) 116 %. 05/18/15 18:53 98-08-805/15/15 14:5980-150 1
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 1.4 mg/kg 05/20/15 01:25 7440-38-205/18/15 04:460.88 1
Barium 48.7 mg/kg 05/20/15 01:25 7440-39-305/18/15 04:460.44 1
Cadmium 0.22 mg/kg 05/20/15 01:25 7440-43-905/18/15 04:460.13 1
Chromium 7.1 mg/kg 05/20/15 01:25 7440-47-305/18/15 04:460.44 1
Lead 12.9 mg/kg 05/20/15 01:25 7439-92-105/18/15 04:460.44 1
Selenium ND mg/kg 05/20/15 01:25 7782-49-205/18/15 04:460.88 1
Silver ND mg/kg 05/20/15 01:25 7440-22-405/18/15 04:460.44 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury 0.019 mg/kg 05/18/15 19:45 7439-97-605/17/15 15:180.018 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 9.0 % 05/19/15 10:360.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/20/15 18:16 83-32-905/15/15 22:170.011 1
Acenaphthylene 0.021 mg/kg 05/20/15 18:16 208-96-805/15/15 22:170.011 1
Anthracene 0.022 mg/kg 05/20/15 18:16 120-12-705/15/15 22:170.011 1
Benzo(a)anthracene 0.11 mg/kg 05/20/15 18:16 56-55-305/15/15 22:170.011 1
Benzo(a)pyrene 0.15 mg/kg 05/20/15 18:16 50-32-805/15/15 22:170.011 1
Benzo(b)fluoranthene 0.18 mg/kg 05/20/15 18:16 205-99-205/15/15 22:170.011 1
Benzo(g,h,i)perylene 0.11 mg/kg 05/20/15 18:16 191-24-205/15/15 22:170.011 1
Benzo(k)fluoranthene 0.075 mg/kg 05/20/15 18:16 207-08-905/15/15 22:170.011 1
Chrysene 0.12 mg/kg 05/20/15 18:16 218-01-905/15/15 22:170.011 1
Dibenz(a,h)anthracene 0.028 mg/kg 05/20/15 18:16 53-70-305/15/15 22:170.011 1
Fluoranthene 0.17 mg/kg 05/20/15 18:16 206-44-005/15/15 22:170.011 1
Fluorene ND mg/kg 05/20/15 18:16 86-73-705/15/15 22:170.011 1
Indeno(1,2,3-cd)pyrene 0.082 mg/kg 05/20/15 18:16 193-39-505/15/15 22:170.011 1
Naphthalene ND mg/kg 05/20/15 18:16 91-20-305/15/15 22:170.011 1
Phenanthrene 0.032 mg/kg 05/20/15 18:16 85-01-805/15/15 22:170.011 1
Pyrene 0.17 mg/kg 05/20/15 18:16 129-00-005/15/15 22:170.011 1
Total BaP Eq. MN 2006sh. ND=0 0.21 mg/kg 05/20/15 18:1605/15/15 22:170.011 1
Surrogates2-Fluorobiphenyl (S) 64 %. 05/20/15 18:16 321-60-805/15/15 22:1755-125 1
p-Terphenyl-d14 (S) 65 %. 05/20/15 18:16 1718-51-005/15/15 22:1730-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 23 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-25/1-3 Lab ID: 10306235009 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
Acetone ND mg/kg 05/19/15 22:08 67-64-105/18/15 16:311.1 1
Allyl chloride ND mg/kg 05/19/15 22:08 107-05-105/18/15 16:310.22 1
Benzene ND mg/kg 05/19/15 22:08 71-43-205/18/15 16:310.022 1
Bromobenzene ND mg/kg 05/19/15 22:08 108-86-105/18/15 16:310.054 1
Bromochloromethane ND mg/kg 05/19/15 22:08 74-97-505/18/15 16:310.054 1
Bromodichloromethane ND mg/kg 05/19/15 22:08 75-27-405/18/15 16:310.054 1
Bromoform ND mg/kg 05/19/15 22:08 75-25-205/18/15 16:310.22 1
Bromomethane ND mg/kg 05/19/15 22:08 74-83-905/18/15 16:310.54 1
2-Butanone (MEK) ND mg/kg 05/19/15 22:08 78-93-305/18/15 16:310.27 1
n-Butylbenzene ND mg/kg 05/19/15 22:08 104-51-805/18/15 16:310.054 1
sec-Butylbenzene ND mg/kg 05/19/15 22:08 135-98-805/18/15 16:310.054 1
tert-Butylbenzene ND mg/kg 05/19/15 22:08 98-06-605/18/15 16:310.054 1
Carbon tetrachloride ND mg/kg 05/19/15 22:08 56-23-505/18/15 16:310.22 1
Chlorobenzene ND mg/kg 05/19/15 22:08 108-90-705/18/15 16:310.054 1
Chloroethane ND mg/kg 05/19/15 22:08 75-00-305/18/15 16:310.54 1
Chloroform ND mg/kg 05/19/15 22:08 67-66-305/18/15 16:310.054 1
Chloromethane ND mg/kg 05/19/15 22:08 74-87-305/18/15 16:310.22 1
2-Chlorotoluene ND mg/kg 05/19/15 22:08 95-49-805/18/15 16:310.054 1
4-Chlorotoluene ND mg/kg 05/19/15 22:08 106-43-405/18/15 16:310.054 1
1,2-Dibromo-3-chloropropane ND mg/kg 05/19/15 22:08 96-12-805/18/15 16:310.54 1
Dibromochloromethane ND mg/kg 05/19/15 22:08 124-48-105/18/15 16:310.054 1
1,2-Dibromoethane (EDB) ND mg/kg 05/19/15 22:08 106-93-405/18/15 16:310.054 1
Dibromomethane ND mg/kg 05/19/15 22:08 74-95-305/18/15 16:310.22 1
1,2-Dichlorobenzene ND mg/kg 05/19/15 22:08 95-50-105/18/15 16:310.054 1
1,3-Dichlorobenzene ND mg/kg 05/19/15 22:08 541-73-105/18/15 16:310.054 1
1,4-Dichlorobenzene ND mg/kg 05/19/15 22:08 106-46-705/18/15 16:310.054 1
Dichlorodifluoromethane ND mg/kg 05/19/15 22:08 75-71-805/18/15 16:310.22 1
1,1-Dichloroethane ND mg/kg 05/19/15 22:08 75-34-305/18/15 16:310.054 1
1,2-Dichloroethane ND mg/kg 05/19/15 22:08 107-06-205/18/15 16:310.054 1
1,1-Dichloroethene ND mg/kg 05/19/15 22:08 75-35-405/18/15 16:310.054 1
cis-1,2-Dichloroethene ND mg/kg 05/19/15 22:08 156-59-205/18/15 16:310.054 1
trans-1,2-Dichloroethene ND mg/kg 05/19/15 22:08 156-60-5 L205/18/15 16:310.054 1
Dichlorofluoromethane ND mg/kg 05/19/15 22:08 75-43-405/18/15 16:310.54 1
1,2-Dichloropropane ND mg/kg 05/19/15 22:08 78-87-505/18/15 16:310.054 1
1,3-Dichloropropane ND mg/kg 05/19/15 22:08 142-28-905/18/15 16:310.054 1
2,2-Dichloropropane ND mg/kg 05/19/15 22:08 594-20-705/18/15 16:310.22 1
1,1-Dichloropropene ND mg/kg 05/19/15 22:08 563-58-605/18/15 16:310.054 1
cis-1,3-Dichloropropene ND mg/kg 05/19/15 22:08 10061-01-505/18/15 16:310.054 1
trans-1,3-Dichloropropene ND mg/kg 05/19/15 22:08 10061-02-605/18/15 16:310.054 1
Diethyl ether (Ethyl ether) ND mg/kg 05/19/15 22:08 60-29-705/18/15 16:310.22 1
Ethylbenzene ND mg/kg 05/19/15 22:08 100-41-405/18/15 16:310.054 1
Hexachloro-1,3-butadiene ND mg/kg 05/19/15 22:08 87-68-305/18/15 16:310.27 1
Isopropylbenzene (Cumene) ND mg/kg 05/19/15 22:08 98-82-805/18/15 16:310.054 1
p-Isopropyltoluene ND mg/kg 05/19/15 22:08 99-87-605/18/15 16:310.054 1
Methylene Chloride ND mg/kg 05/19/15 22:08 75-09-205/18/15 16:310.22 1
4-Methyl-2-pentanone (MIBK) ND mg/kg 05/19/15 22:08 108-10-105/18/15 16:310.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 24 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-25/1-3 Lab ID: 10306235009 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
Methyl-tert-butyl ether ND mg/kg 05/19/15 22:08 1634-04-405/18/15 16:310.054 1
Naphthalene ND mg/kg 05/19/15 22:08 91-20-305/18/15 16:310.22 1
n-Propylbenzene ND mg/kg 05/19/15 22:08 103-65-105/18/15 16:310.054 1
Styrene ND mg/kg 05/19/15 22:08 100-42-505/18/15 16:310.054 1
1,1,1,2-Tetrachloroethane ND mg/kg 05/19/15 22:08 630-20-605/18/15 16:310.054 1
1,1,2,2-Tetrachloroethane ND mg/kg 05/19/15 22:08 79-34-505/18/15 16:310.054 1
Tetrachloroethene ND mg/kg 05/19/15 22:08 127-18-405/18/15 16:310.054 1
Tetrahydrofuran ND mg/kg 05/19/15 22:08 109-99-905/18/15 16:312.2 1
Toluene ND mg/kg 05/19/15 22:08 108-88-305/18/15 16:310.054 1
1,2,3-Trichlorobenzene ND mg/kg 05/19/15 22:08 87-61-605/18/15 16:310.22 1
1,2,4-Trichlorobenzene ND mg/kg 05/19/15 22:08 120-82-105/18/15 16:310.22 1
1,1,1-Trichloroethane ND mg/kg 05/19/15 22:08 71-55-605/18/15 16:310.054 1
1,1,2-Trichloroethane ND mg/kg 05/19/15 22:08 79-00-505/18/15 16:310.054 1
Trichloroethene ND mg/kg 05/19/15 22:08 79-01-605/18/15 16:310.054 1
Trichlorofluoromethane ND mg/kg 05/19/15 22:08 75-69-405/18/15 16:310.22 1
1,2,3-Trichloropropane ND mg/kg 05/19/15 22:08 96-18-405/18/15 16:310.22 1
1,1,2-Trichlorotrifluoroethane ND mg/kg 05/19/15 22:08 76-13-1 L205/18/15 16:310.22 1
1,2,4-Trimethylbenzene ND mg/kg 05/19/15 22:08 95-63-605/18/15 16:310.054 1
1,3,5-Trimethylbenzene ND mg/kg 05/19/15 22:08 108-67-805/18/15 16:310.054 1
Vinyl chloride ND mg/kg 05/19/15 22:08 75-01-405/18/15 16:310.022 1
Xylene (Total) ND mg/kg 05/19/15 22:08 1330-20-705/18/15 16:310.16 1
Surrogates1,2-Dichloroethane-d4 (S) 105 %. 05/19/15 22:08 17060-07-005/18/15 16:3155-150 1
Toluene-d8 (S) 102 %. 05/19/15 22:08 2037-26-505/18/15 16:3161-125 1
4-Bromofluorobenzene (S) 107 %. 05/19/15 22:08 460-00-405/18/15 16:3154-131 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 25 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-25/15-20 Lab ID: 10306235010 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: WI MOD DRO Preparation Method: WI MOD DROWIDRO GCS Silica Gel
WDRO C10-C28 ND mg/L 05/17/15 17:3205/15/15 13:230.13 1
Surrogatesn-Triacontane (S) 78 %. 05/17/15 17:32 638-68-6 P405/15/15 13:2362-125 1
Analytical Method: WI MOD GROWIGRO GCV
Gasoline Range Organics ND ug/L 05/23/15 00:5350.0 1
Analytical Method: EPA 8260B8260B VOC
Acetone ND ug/L 05/15/15 19:30 67-64-120.0 1
Allyl chloride ND ug/L 05/15/15 19:30 107-05-14.0 1
Benzene ND ug/L 05/15/15 19:30 71-43-21.0 1
Bromobenzene ND ug/L 05/15/15 19:30 108-86-11.0 1
Bromochloromethane ND ug/L 05/15/15 19:30 74-97-51.0 1
Bromodichloromethane ND ug/L 05/15/15 19:30 75-27-41.0 1
Bromoform ND ug/L 05/15/15 19:30 75-25-24.0 1
Bromomethane ND ug/L 05/15/15 19:30 74-83-94.0 1
2-Butanone (MEK) ND ug/L 05/15/15 19:30 78-93-35.0 1
n-Butylbenzene ND ug/L 05/15/15 19:30 104-51-81.0 1
sec-Butylbenzene ND ug/L 05/15/15 19:30 135-98-81.0 1
tert-Butylbenzene ND ug/L 05/15/15 19:30 98-06-61.0 1
Carbon tetrachloride ND ug/L 05/15/15 19:30 56-23-51.0 1
Chlorobenzene ND ug/L 05/15/15 19:30 108-90-71.0 1
Chloroethane ND ug/L 05/15/15 19:30 75-00-31.0 1
Chloroform ND ug/L 05/15/15 19:30 67-66-31.0 1
Chloromethane ND ug/L 05/15/15 19:30 74-87-34.0 1
2-Chlorotoluene ND ug/L 05/15/15 19:30 95-49-81.0 1
4-Chlorotoluene ND ug/L 05/15/15 19:30 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 05/15/15 19:30 96-12-84.0 1
Dibromochloromethane ND ug/L 05/15/15 19:30 124-48-11.0 1
1,2-Dibromoethane (EDB) ND ug/L 05/15/15 19:30 106-93-41.0 1
Dibromomethane ND ug/L 05/15/15 19:30 74-95-34.0 1
1,2-Dichlorobenzene ND ug/L 05/15/15 19:30 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 05/15/15 19:30 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 05/15/15 19:30 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 05/15/15 19:30 75-71-81.0 1
1,1-Dichloroethane ND ug/L 05/15/15 19:30 75-34-31.0 1
1,2-Dichloroethane ND ug/L 05/15/15 19:30 107-06-21.0 1
1,1-Dichloroethene ND ug/L 05/15/15 19:30 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 05/15/15 19:30 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 05/15/15 19:30 156-60-51.0 1
Dichlorofluoromethane ND ug/L 05/15/15 19:30 75-43-41.0 1
1,2-Dichloropropane ND ug/L 05/15/15 19:30 78-87-54.0 1
1,3-Dichloropropane ND ug/L 05/15/15 19:30 142-28-91.0 1
2,2-Dichloropropane ND ug/L 05/15/15 19:30 594-20-74.0 1
1,1-Dichloropropene ND ug/L 05/15/15 19:30 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 05/15/15 19:30 10061-01-54.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
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Page 26 of 58
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Sample: LGP-25/15-20 Lab ID: 10306235010 Collected: 05/12/15 00:00 Received: 05/13/15 14:34 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B8260B VOC
trans-1,3-Dichloropropene ND ug/L 05/15/15 19:30 10061-02-64.0 1
Diethyl ether (Ethyl ether) ND ug/L 05/15/15 19:30 60-29-74.0 1
Ethylbenzene ND ug/L 05/15/15 19:30 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 05/15/15 19:30 87-68-31.0 1
Isopropylbenzene (Cumene) ND ug/L 05/15/15 19:30 98-82-81.0 1
p-Isopropyltoluene ND ug/L 05/15/15 19:30 99-87-61.0 1
Methylene Chloride ND ug/L 05/15/15 19:30 75-09-24.0 1
4-Methyl-2-pentanone (MIBK) ND ug/L 05/15/15 19:30 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 05/15/15 19:30 1634-04-41.0 1
Naphthalene ND ug/L 05/15/15 19:30 91-20-34.0 1
n-Propylbenzene ND ug/L 05/15/15 19:30 103-65-11.0 1
Styrene ND ug/L 05/15/15 19:30 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 05/15/15 19:30 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 05/15/15 19:30 79-34-51.0 1
Tetrachloroethene ND ug/L 05/15/15 19:30 127-18-41.0 1
Tetrahydrofuran ND ug/L 05/15/15 19:30 109-99-910.0 1
Toluene ND ug/L 05/15/15 19:30 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 05/15/15 19:30 87-61-61.0 1
1,2,4-Trichlorobenzene ND ug/L 05/15/15 19:30 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 05/15/15 19:30 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 05/15/15 19:30 79-00-51.0 1
Trichloroethene ND ug/L 05/15/15 19:30 79-01-60.40 1
Trichlorofluoromethane ND ug/L 05/15/15 19:30 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 05/15/15 19:30 96-18-44.0 1
1,1,2-Trichlorotrifluoroethane ND ug/L 05/15/15 19:30 76-13-11.0 1
1,2,4-Trimethylbenzene ND ug/L 05/15/15 19:30 95-63-61.0 1
1,3,5-Trimethylbenzene ND ug/L 05/15/15 19:30 108-67-81.0 1
Vinyl chloride ND ug/L 05/15/15 19:30 75-01-40.40 1
Xylene (Total) ND ug/L 05/15/15 19:30 1330-20-73.0 1
Surrogates1,2-Dichloroethane-d4 (S) 92 %. 05/15/15 19:30 17060-07-075-125 1
Toluene-d8 (S) 98 %. 05/15/15 19:30 2037-26-575-125 1
4-Bromofluorobenzene (S) 97 %. 05/15/15 19:30 460-00-475-125 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 27 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/13744
EPA 5030 Medium Soil
WI MOD GRO
WIGRO Solid GCV
Associated Lab Samples: 10306235002, 10306235004, 10306235005, 10306235006, 10306235009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1966977
Associated Lab Samples: 10306235002, 10306235004, 10306235005, 10306235006, 10306235009
Matrix: Solid
Analyzed
Gasoline Range Organics mg/kg ND 10.0 05/18/15 11:05
a,a,a-Trifluorotoluene (S) %. 117 80-150 05/18/15 11:05
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1966978LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1966979
Gasoline Range Organics mg/kg 44.950 90 80-1208944.7 0 20
a,a,a-Trifluorotoluene (S) %. 129 80-150127
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1966980MATRIX SPIKE SAMPLE:
MSSpike
Result
10305711001
Gasoline Range Organics mg/kg 47.056.6 83 80-120ND
a,a,a-Trifluorotoluene (S) %. 134 80-150
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10305711002
1966981SAMPLE DUPLICATE:
Gasoline Range Organics mg/kg ND 20ND
a,a,a-Trifluorotoluene (S) %. 113 1115
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 28 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/14422
WI MOD GRO
WI MOD GRO
WIGRO GCV Water
Associated Lab Samples: 10306235007, 10306235010
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1163076
Associated Lab Samples:
Matrix: Water
Analyzed
Gasoline Range Organics ug/L ND 50.0 05/22/15 21:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1163077LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1163078
Gasoline Range Organics ug/L 195200 97 80-120102205 5 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 29 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/13552
EPA 7471B
EPA 7471B
7471B Mercury Solids
Associated Lab Samples: 10306235001, 10306235002, 10306235003, 10306235004, 10306235005, 10306235006, 10306235008,10306235009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1966049
Associated Lab Samples: 10306235001, 10306235002, 10306235003, 10306235004, 10306235005, 10306235006, 10306235008,10306235009
Matrix: Solid
Analyzed
Mercury mg/kg ND 0.019 05/18/15 19:07
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1966050LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/kg 0.49.48 101 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1966051MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
10306204001
1966052
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/kg .55 98 75-125100 10 20.48ND 0.54 0.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 30 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/54373
EPA 3050
EPA 6010C
6010C Solids
Associated Lab Samples: 10306235001, 10306235002, 10306235003, 10306235004, 10306235005, 10306235006, 10306235008,10306235009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1965104
Associated Lab Samples: 10306235001, 10306235002, 10306235003, 10306235004, 10306235005, 10306235006, 10306235008,10306235009
Matrix: Solid
Analyzed
Arsenic mg/kg ND 0.89 05/19/15 23:48
Barium mg/kg ND 0.45 05/19/15 23:48
Cadmium mg/kg ND 0.13 05/19/15 23:48
Chromium mg/kg ND 0.45 05/19/15 23:48
Lead mg/kg ND 0.45 05/19/15 23:48
Selenium mg/kg ND 0.89 05/19/15 23:48
Silver mg/kg ND 0.45 05/19/15 23:48
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1965105LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic mg/kg 45.248.5 93 80-120
Barium mg/kg 46.948.5 97 80-120
Cadmium mg/kg 44.448.5 91 80-120
Chromium mg/kg 46.748.5 96 80-120
Lead mg/kg 44.748.5 92 80-120
Selenium mg/kg 44.048.5 91 80-120
Silver mg/kg 22.324.3 92 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1965106MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
10306204001
1965107
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic mg/kg 45 97 75-125100 1 2044.21.9 45.5 46.2
Barium mg/kg 45 104 75-125122 9 2044.230.1 77.0 84.3
Cadmium mg/kg 45 95 75-12596 0 2044.20.16 42.7 42.5
Chromium mg/kg 45 97 75-12599 0 2044.25.6 49.3 49.2
Lead mg/kg 45 88 75-12594 4 2044.23.6 43.4 45.0
Selenium mg/kg 45 91 75-12595 3 2044.2ND 40.8 42.2
Silver mg/kg 22.5 96 75-12597 1 2022.2ND 21.7 21.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 31 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/54526
ASTM D2974
ASTM D2974
Dry Weight/Percent Moisture
Associated Lab Samples: 10306235001, 10306235002, 10306235003, 10306235004
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10305246003
1969511SAMPLE DUPLICATE:
Percent Moisture % 0.93 0 300.93
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10306235003
1969533SAMPLE DUPLICATE:
Percent Moisture % 11.7 1 3011.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 32 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/54527
ASTM D2974
ASTM D2974
Dry Weight/Percent Moisture
Associated Lab Samples: 10306235005, 10306235006, 10306235008, 10306235009
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10305312001
1969568SAMPLE DUPLICATE:
Percent Moisture % 8.6 4 309.0
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10306609002
1969569SAMPLE DUPLICATE:
Percent Moisture % 7.4 2 307.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 33 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/31467
EPA 5035/5030B
EPA 8260B
8260B MSV 5030 Med Level
Associated Lab Samples: 10306235002, 10306235004, 10306235005, 10306235006, 10306235009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1968956
Associated Lab Samples: 10306235002, 10306235004, 10306235005, 10306235006, 10306235009
Matrix: Solid
Analyzed
1,1,1,2-Tetrachloroethane mg/kg ND 0.050 05/19/15 17:45
1,1,1-Trichloroethane mg/kg ND 0.050 05/19/15 17:45
1,1,2,2-Tetrachloroethane mg/kg ND 0.050 05/19/15 17:45
1,1,2-Trichloroethane mg/kg ND 0.050 05/19/15 17:45
1,1,2-Trichlorotrifluoroethane mg/kg ND 0.20 05/19/15 17:45
1,1-Dichloroethane mg/kg ND 0.050 05/19/15 17:45
1,1-Dichloroethene mg/kg ND 0.050 05/19/15 17:45
1,1-Dichloropropene mg/kg ND 0.050 05/19/15 17:45
1,2,3-Trichlorobenzene mg/kg ND 0.20 05/19/15 17:45
1,2,3-Trichloropropane mg/kg ND 0.20 05/19/15 17:45
1,2,4-Trichlorobenzene mg/kg ND 0.20 05/19/15 17:45
1,2,4-Trimethylbenzene mg/kg ND 0.050 05/19/15 17:45
1,2-Dibromo-3-chloropropane mg/kg ND 0.50 05/19/15 17:45
1,2-Dibromoethane (EDB) mg/kg ND 0.050 05/19/15 17:45
1,2-Dichlorobenzene mg/kg ND 0.050 05/19/15 17:45
1,2-Dichloroethane mg/kg ND 0.050 05/19/15 17:45
1,2-Dichloropropane mg/kg ND 0.050 05/19/15 17:45
1,3,5-Trimethylbenzene mg/kg ND 0.050 05/19/15 17:45
1,3-Dichlorobenzene mg/kg ND 0.050 05/19/15 17:45
1,3-Dichloropropane mg/kg ND 0.050 05/19/15 17:45
1,4-Dichlorobenzene mg/kg ND 0.050 05/19/15 17:45
2,2-Dichloropropane mg/kg ND 0.20 05/19/15 17:45
2-Butanone (MEK) mg/kg ND 0.25 05/19/15 17:45
2-Chlorotoluene mg/kg ND 0.050 05/19/15 17:45
4-Chlorotoluene mg/kg ND 0.050 05/19/15 17:45
4-Methyl-2-pentanone (MIBK) mg/kg ND 0.25 05/19/15 17:45
Acetone mg/kg ND 1.0 05/19/15 17:45
Allyl chloride mg/kg ND 0.20 05/19/15 17:45
Benzene mg/kg ND 0.020 05/19/15 17:45
Bromobenzene mg/kg ND 0.050 05/19/15 17:45
Bromochloromethane mg/kg ND 0.050 05/19/15 17:45
Bromodichloromethane mg/kg ND 0.050 05/19/15 17:45
Bromoform mg/kg ND 0.20 05/19/15 17:45
Bromomethane mg/kg ND 0.50 05/19/15 17:45
Carbon tetrachloride mg/kg ND 0.20 05/19/15 17:45
Chlorobenzene mg/kg ND 0.050 05/19/15 17:45
Chloroethane mg/kg ND 0.50 05/19/15 17:45
Chloroform mg/kg ND 0.050 05/19/15 17:45
Chloromethane mg/kg ND 0.20 05/19/15 17:45
cis-1,2-Dichloroethene mg/kg ND 0.050 05/19/15 17:45
cis-1,3-Dichloropropene mg/kg ND 0.050 05/19/15 17:45
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 34 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1968956
Associated Lab Samples: 10306235002, 10306235004, 10306235005, 10306235006, 10306235009
Matrix: Solid
Analyzed
Dibromochloromethane mg/kg ND 0.050 05/19/15 17:45
Dibromomethane mg/kg ND 0.20 05/19/15 17:45
Dichlorodifluoromethane mg/kg ND 0.20 05/19/15 17:45
Dichlorofluoromethane mg/kg ND 0.50 05/19/15 17:45
Diethyl ether (Ethyl ether) mg/kg ND 0.20 05/19/15 17:45
Ethylbenzene mg/kg ND 0.050 05/19/15 17:45
Hexachloro-1,3-butadiene mg/kg ND 0.25 05/19/15 17:45
Isopropylbenzene (Cumene) mg/kg ND 0.050 05/19/15 17:45
Methyl-tert-butyl ether mg/kg ND 0.050 05/19/15 17:45
Methylene Chloride mg/kg ND 0.20 05/19/15 17:45
n-Butylbenzene mg/kg ND 0.050 05/19/15 17:45
n-Propylbenzene mg/kg ND 0.050 05/19/15 17:45
Naphthalene mg/kg ND 0.20 05/19/15 17:45
p-Isopropyltoluene mg/kg ND 0.050 05/19/15 17:45
sec-Butylbenzene mg/kg ND 0.050 05/19/15 17:45
Styrene mg/kg ND 0.050 05/19/15 17:45
tert-Butylbenzene mg/kg ND 0.050 05/19/15 17:45
Tetrachloroethene mg/kg ND 0.050 05/19/15 17:45
Tetrahydrofuran mg/kg ND 2.0 05/19/15 17:45
Toluene mg/kg ND 0.050 05/19/15 17:45
trans-1,2-Dichloroethene mg/kg ND 0.050 05/19/15 17:45
trans-1,3-Dichloropropene mg/kg ND 0.050 05/19/15 17:45
Trichloroethene mg/kg ND 0.050 05/19/15 17:45
Trichlorofluoromethane mg/kg ND 0.20 05/19/15 17:45
Vinyl chloride mg/kg ND 0.020 05/19/15 17:45
Xylene (Total) mg/kg ND 0.15 05/19/15 17:45
1,2-Dichloroethane-d4 (S) %. 101 55-150 05/19/15 17:45
4-Bromofluorobenzene (S) %. 107 54-131 05/19/15 17:45
Toluene-d8 (S) %. 105 61-125 05/19/15 17:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1968957LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane mg/kg 0.961 96 75-125
1,1,1-Trichloroethane mg/kg 0.851 85 66-125
1,1,2,2-Tetrachloroethane mg/kg 1.11 107 69-125
1,1,2-Trichloroethane mg/kg 0.981 98 75-125
1,1,2-Trichlorotrifluoroethane mg/kg 0.53 L01 53 55-125
1,1-Dichloroethane mg/kg 0.841 84 67-125
1,1-Dichloroethene mg/kg 0.711 71 62-125
1,1-Dichloropropene mg/kg 0.691 69 65-125
1,2,3-Trichlorobenzene mg/kg 0.921 92 58-132
1,2,3-Trichloropropane mg/kg 1.01 101 71-125
1,2,4-Trichlorobenzene mg/kg 0.931 93 63-128
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
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(612)607-1700
Page 35 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1968957LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene mg/kg 0.881 88 74-125
1,2-Dibromo-3-chloropropane mg/kg 2.52.5 100 55-142
1,2-Dibromoethane (EDB) mg/kg 0.891 89 75-125
1,2-Dichlorobenzene mg/kg 0.901 90 75-125
1,2-Dichloroethane mg/kg 0.901 90 71-125
1,2-Dichloropropane mg/kg 0.931 93 74-125
1,3,5-Trimethylbenzene mg/kg 0.901 90 72-125
1,3-Dichlorobenzene mg/kg 0.911 91 75-125
1,3-Dichloropropane mg/kg 0.971 97 75-125
1,4-Dichlorobenzene mg/kg 0.901 90 75-125
2,2-Dichloropropane mg/kg 0.911 91 45-125
2-Butanone (MEK) mg/kg 3.65 71 39-136
2-Chlorotoluene mg/kg 0.881 88 73-125
4-Chlorotoluene mg/kg 0.881 88 74-125
4-Methyl-2-pentanone (MIBK) mg/kg 4.55 90 55-132
Acetone mg/kg 5.85 116 55-131
Allyl chloride mg/kg 0.711 71 53-125
Benzene mg/kg 0.861 86 69-125
Bromobenzene mg/kg 0.941 94 75-125
Bromochloromethane mg/kg 0.781 78 75-125
Bromodichloromethane mg/kg 0.971 97 75-125
Bromoform mg/kg 0.951 95 71-125
Bromomethane mg/kg 0.821 82 42-150
Carbon tetrachloride mg/kg 0.751 75 62-125
Chlorobenzene mg/kg 0.931 93 75-125
Chloroethane mg/kg 0.961 96 41-150
Chloroform mg/kg 0.961 96 72-125
Chloromethane mg/kg 1.01 103 50-125
cis-1,2-Dichloroethene mg/kg 0.841 84 73-125
cis-1,3-Dichloropropene mg/kg 1.01 100 74-125
Dibromochloromethane mg/kg 1.01 105 75-125
Dibromomethane mg/kg 0.831 83 75-125
Dichlorodifluoromethane mg/kg 0.591 59 30-125
Dichlorofluoromethane mg/kg 0.941 94 30-150
Diethyl ether (Ethyl ether) mg/kg 0.701 70 58-125
Ethylbenzene mg/kg 0.911 91 72-125
Hexachloro-1,3-butadiene mg/kg 0.671 67 59-138
Isopropylbenzene (Cumene) mg/kg 0.811 81 72-125
Methyl-tert-butyl ether mg/kg 0.901 90 72-125
Methylene Chloride mg/kg 0.781 78 71-125
n-Butylbenzene mg/kg 0.881 88 65-125
n-Propylbenzene mg/kg 0.951 95 71-125
Naphthalene mg/kg 0.881 88 55-139
p-Isopropyltoluene mg/kg 0.851 85 69-125
sec-Butylbenzene mg/kg 0.831 83 68-125
Styrene mg/kg 0.901 90 75-125
tert-Butylbenzene mg/kg 0.921 92 70-125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 36 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1968957LABORATORY CONTROL SAMPLE:
LCSSpike
Tetrachloroethene mg/kg 0.751 75 69-125
Tetrahydrofuran mg/kg 12.010 120 62-129
Toluene mg/kg 0.891 89 72-125
trans-1,2-Dichloroethene mg/kg 0.67 L01 67 68-125
trans-1,3-Dichloropropene mg/kg 0.971 97 74-125
Trichloroethene mg/kg 0.911 91 72-125
Trichlorofluoromethane mg/kg 0.851 85 30-150
Vinyl chloride mg/kg 0.971 97 53-125
Xylene (Total) mg/kg 2.73 88 74-125
1,2-Dichloroethane-d4 (S) %. 96 55-150
4-Bromofluorobenzene (S) %. 104 54-131
Toluene-d8 (S) %. 100 61-125
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1968958MATRIX SPIKE SAMPLE:
MSSpike
Result
10306235005
1,1,1,2-Tetrachloroethane mg/kg 1.11.2 97 62-150ND
1,1,1-Trichloroethane mg/kg 1.01.2 86 58-150ND
1,1,2,2-Tetrachloroethane mg/kg 1.31.2 109 30-150ND
1,1,2-Trichloroethane mg/kg 1.11.2 96 61-149ND
1,1,2-Trichlorotrifluoroethane mg/kg 1.01.2 87 45-150ND
1,1-Dichloroethane mg/kg 1.01.2 88 56-150ND
1,1-Dichloroethene mg/kg 0.771.2 66 48-150ND
1,1-Dichloropropene mg/kg 0.781.2 67 58-150ND
1,2,3-Trichlorobenzene mg/kg 1.21.2 107 55-150ND
1,2,3-Trichloropropane mg/kg 1.21.2 103 57-148ND
1,2,4-Trichlorobenzene mg/kg 1.41.2 116 61-150ND
1,2,4-Trimethylbenzene mg/kg 1.11.2 96 64-150ND
1,2-Dibromo-3-chloropropane mg/kg 3.32.9 113 40-150ND
1,2-Dibromoethane (EDB) mg/kg 1.21.2 99 62-147ND
1,2-Dichlorobenzene mg/kg 1.21.2 102 73-133ND
1,2-Dichloroethane mg/kg 1.01.2 89 63-132ND
1,2-Dichloropropane mg/kg 1.11.2 93 69-127ND
1,3,5-Trimethylbenzene mg/kg 1.11.2 96 63-137ND
1,3-Dichlorobenzene mg/kg 1.21.2 102 69-133ND
1,3-Dichloropropane mg/kg 1.21.2 104 70-130ND
1,4-Dichlorobenzene mg/kg 1.11.2 98 69-130ND
2,2-Dichloropropane mg/kg 1.01.2 87 54-135ND
2-Butanone (MEK) mg/kg 4.75.9 81 49-145ND
2-Chlorotoluene mg/kg 1.11.2 98 68-129ND
4-Chlorotoluene mg/kg 1.11.2 97 67-134ND
4-Methyl-2-pentanone (MIBK) mg/kg 5.65.9 96 60-150ND
Acetone mg/kg 5.55.9 94 65-135ND
Allyl chloride mg/kg 0.811.2 69 55-126ND
Benzene mg/kg 0.991.2 85 63-126ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 37 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1968958MATRIX SPIKE SAMPLE:
MSSpike
Result
10306235005
Bromobenzene mg/kg 1.11.2 97 68-133ND
Bromochloromethane mg/kg 0.921.2 79 66-130ND
Bromodichloromethane mg/kg 1.21.2 99 68-129ND
Bromoform mg/kg 1.21.2 100 63-135ND
Bromomethane mg/kg 1.41.2 120 30-150ND
Carbon tetrachloride mg/kg 0.891.2 76 56-140ND
Chlorobenzene mg/kg 1.11.2 93 69-130ND
Chloroethane mg/kg 1.21.2 105 46-150ND
Chloroform mg/kg 1.21.2 99 70-127ND
Chloromethane mg/kg 1.11.2 95 51-125ND
cis-1,2-Dichloroethene mg/kg 0.991.2 84 68-125ND
cis-1,3-Dichloropropene mg/kg 1.11.2 93 67-126ND
Dibromochloromethane mg/kg 1.21.2 103 66-135ND
Dibromomethane mg/kg 1.11.2 95 68-132ND
Dichlorodifluoromethane mg/kg 1.21.2 103 30-138ND
Dichlorofluoromethane mg/kg 1.11.2 92 30-150ND
Diethyl ether (Ethyl ether) mg/kg 0.881.2 76 56-135ND
Ethylbenzene mg/kg 1.11.2 91 69-126ND
Hexachloro-1,3-butadiene mg/kg 1.21.2 102 50-150ND
Isopropylbenzene (Cumene) mg/kg 1.01.2 89 65-135ND
Methyl-tert-butyl ether mg/kg 1.11.2 96 66-129ND
Methylene Chloride mg/kg 0.871.2 74 64-125ND
n-Butylbenzene mg/kg 1.21.2 103 62-141ND
n-Propylbenzene mg/kg 1.21.2 105 65-135ND
Naphthalene mg/kg 1.21.2 106 62-150ND
p-Isopropyltoluene mg/kg 1.21.2 104 62-139ND
sec-Butylbenzene mg/kg 1.11.2 95 64-137ND
Styrene mg/kg 1.01.2 88 70-132ND
tert-Butylbenzene mg/kg 1.21.2 102 65-136ND
Tetrachloroethene mg/kg 0.901.2 77 61-142ND
Tetrahydrofuran mg/kg 11.411.7 98 68-138ND
Toluene mg/kg 1.01.2 88 66-128ND
trans-1,2-Dichloroethene mg/kg 0.831.2 71 63-129ND
trans-1,3-Dichloropropene mg/kg 1.21.2 100 67-132ND
Trichloroethene mg/kg 1.01.2 88 52-150ND
Trichlorofluoromethane mg/kg 1.21.2 105 39-150ND
Vinyl chloride mg/kg 1.11.2 93 50-125ND
Xylene (Total) mg/kg 3.13.5 90 70-130ND
1,2-Dichloroethane-d4 (S) %. 96 55-150
4-Bromofluorobenzene (S) %. 108 54-131
Toluene-d8 (S) %. 104 61-125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 38 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10306235006
1968959SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane mg/kg ND 30ND
1,1,1-Trichloroethane mg/kg ND 30ND
1,1,2,2-Tetrachloroethane mg/kg ND 30ND
1,1,2-Trichloroethane mg/kg ND 30ND
1,1,2-Trichlorotrifluoroethane mg/kg ND 30ND
1,1-Dichloroethane mg/kg ND 30ND
1,1-Dichloroethene mg/kg ND 30ND
1,1-Dichloropropene mg/kg ND 30ND
1,2,3-Trichlorobenzene mg/kg ND 30ND
1,2,3-Trichloropropane mg/kg ND 30ND
1,2,4-Trichlorobenzene mg/kg ND 30ND
1,2,4-Trimethylbenzene mg/kg ND 30ND
1,2-Dibromo-3-chloropropane mg/kg ND 30ND
1,2-Dibromoethane (EDB) mg/kg ND 30ND
1,2-Dichlorobenzene mg/kg ND 30ND
1,2-Dichloroethane mg/kg ND 30ND
1,2-Dichloropropane mg/kg ND 30ND
1,3,5-Trimethylbenzene mg/kg ND 30ND
1,3-Dichlorobenzene mg/kg ND 30ND
1,3-Dichloropropane mg/kg ND 30ND
1,4-Dichlorobenzene mg/kg ND 30ND
2,2-Dichloropropane mg/kg ND 30ND
2-Butanone (MEK) mg/kg ND 30ND
2-Chlorotoluene mg/kg ND 30ND
4-Chlorotoluene mg/kg ND 30ND
4-Methyl-2-pentanone (MIBK) mg/kg ND 30ND
Acetone mg/kg ND 30ND
Allyl chloride mg/kg ND 30ND
Benzene mg/kg ND 30ND
Bromobenzene mg/kg ND 30ND
Bromochloromethane mg/kg ND 30ND
Bromodichloromethane mg/kg ND 30ND
Bromoform mg/kg ND 30ND
Bromomethane mg/kg ND 30ND
Carbon tetrachloride mg/kg ND 30ND
Chlorobenzene mg/kg ND 30ND
Chloroethane mg/kg ND 30ND
Chloroform mg/kg .018J 30ND
Chloromethane mg/kg ND 30ND
cis-1,2-Dichloroethene mg/kg ND 30ND
cis-1,3-Dichloropropene mg/kg ND 30ND
Dibromochloromethane mg/kg ND 30ND
Dibromomethane mg/kg ND 30ND
Dichlorodifluoromethane mg/kg ND 30ND
Dichlorofluoromethane mg/kg ND 30ND
Diethyl ether (Ethyl ether) mg/kg ND 30ND
Ethylbenzene mg/kg ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 39 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10306235006
1968959SAMPLE DUPLICATE:
Hexachloro-1,3-butadiene mg/kg ND 30ND
Isopropylbenzene (Cumene) mg/kg ND 30ND
Methyl-tert-butyl ether mg/kg ND 30ND
Methylene Chloride mg/kg ND 30ND
n-Butylbenzene mg/kg ND 30ND
n-Propylbenzene mg/kg ND 30ND
Naphthalene mg/kg ND 30ND
p-Isopropyltoluene mg/kg ND 30ND
sec-Butylbenzene mg/kg ND 30ND
Styrene mg/kg ND 30ND
tert-Butylbenzene mg/kg ND 30ND
Tetrachloroethene mg/kg ND 30ND
Tetrahydrofuran mg/kg ND 30ND
Toluene mg/kg ND 30ND
trans-1,2-Dichloroethene mg/kg ND 30ND
trans-1,3-Dichloropropene mg/kg ND 30ND
Trichloroethene mg/kg ND 30ND
Trichlorofluoromethane mg/kg ND 30ND
Vinyl chloride mg/kg ND 30ND
Xylene (Total) mg/kg ND 30ND
1,2-Dichloroethane-d4 (S) %. 103 3105
4-Bromofluorobenzene (S) %. 103 2104
Toluene-d8 (S) %. 99 3101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 40 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/31440
EPA 8260B
EPA 8260B
8260B MSV 465 W
Associated Lab Samples: 10306235007, 10306235010
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1965484
Associated Lab Samples: 10306235007, 10306235010
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 1.0 05/15/15 13:30
1,1,1-Trichloroethane ug/L ND 1.0 05/15/15 13:30
1,1,2,2-Tetrachloroethane ug/L ND 1.0 05/15/15 13:30
1,1,2-Trichloroethane ug/L ND 1.0 05/15/15 13:30
1,1,2-Trichlorotrifluoroethane ug/L ND 1.0 05/15/15 13:30
1,1-Dichloroethane ug/L ND 1.0 05/15/15 13:30
1,1-Dichloroethene ug/L ND 1.0 05/15/15 13:30
1,1-Dichloropropene ug/L ND 1.0 05/15/15 13:30
1,2,3-Trichlorobenzene ug/L ND 1.0 05/15/15 13:30
1,2,3-Trichloropropane ug/L ND 4.0 05/15/15 13:30
1,2,4-Trichlorobenzene ug/L ND 1.0 05/15/15 13:30
1,2,4-Trimethylbenzene ug/L ND 1.0 05/15/15 13:30
1,2-Dibromo-3-chloropropane ug/L ND 4.0 05/15/15 13:30
1,2-Dibromoethane (EDB) ug/L ND 1.0 05/15/15 13:30
1,2-Dichlorobenzene ug/L ND 1.0 05/15/15 13:30
1,2-Dichloroethane ug/L ND 1.0 05/15/15 13:30
1,2-Dichloropropane ug/L ND 4.0 05/15/15 13:30
1,3,5-Trimethylbenzene ug/L ND 1.0 05/15/15 13:30
1,3-Dichlorobenzene ug/L ND 1.0 05/15/15 13:30
1,3-Dichloropropane ug/L ND 1.0 05/15/15 13:30
1,4-Dichlorobenzene ug/L ND 1.0 05/15/15 13:30
2,2-Dichloropropane ug/L ND 4.0 05/15/15 13:30
2-Butanone (MEK) ug/L ND 5.0 05/15/15 13:30
2-Chlorotoluene ug/L ND 1.0 05/15/15 13:30
4-Chlorotoluene ug/L ND 1.0 05/15/15 13:30
4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 05/15/15 13:30
Acetone ug/L ND 20.0 05/15/15 13:30
Allyl chloride ug/L ND 4.0 05/15/15 13:30
Benzene ug/L ND 1.0 05/15/15 13:30
Bromobenzene ug/L ND 1.0 05/15/15 13:30
Bromochloromethane ug/L ND 1.0 05/15/15 13:30
Bromodichloromethane ug/L ND 1.0 05/15/15 13:30
Bromoform ug/L ND 4.0 05/15/15 13:30
Bromomethane ug/L ND 4.0 05/15/15 13:30
Carbon tetrachloride ug/L ND 1.0 05/15/15 13:30
Chlorobenzene ug/L ND 1.0 05/15/15 13:30
Chloroethane ug/L ND 1.0 05/15/15 13:30
Chloroform ug/L ND 1.0 05/15/15 13:30
Chloromethane ug/L ND 4.0 05/15/15 13:30
cis-1,2-Dichloroethene ug/L ND 1.0 05/15/15 13:30
cis-1,3-Dichloropropene ug/L ND 4.0 05/15/15 13:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 41 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1965484
Associated Lab Samples: 10306235007, 10306235010
Matrix: Water
Analyzed
Dibromochloromethane ug/L ND 1.0 05/15/15 13:30
Dibromomethane ug/L ND 4.0 05/15/15 13:30
Dichlorodifluoromethane ug/L ND 1.0 05/15/15 13:30
Dichlorofluoromethane ug/L ND 1.0 05/15/15 13:30
Diethyl ether (Ethyl ether) ug/L ND 4.0 05/15/15 13:30
Ethylbenzene ug/L ND 1.0 05/15/15 13:30
Hexachloro-1,3-butadiene ug/L ND 1.0 05/15/15 13:30
Isopropylbenzene (Cumene) ug/L ND 1.0 05/15/15 13:30
Methyl-tert-butyl ether ug/L ND 1.0 05/15/15 13:30
Methylene Chloride ug/L ND 4.0 05/15/15 13:30
n-Butylbenzene ug/L ND 1.0 05/15/15 13:30
n-Propylbenzene ug/L ND 1.0 05/15/15 13:30
Naphthalene ug/L ND 4.0 05/15/15 13:30
p-Isopropyltoluene ug/L ND 1.0 05/15/15 13:30
sec-Butylbenzene ug/L ND 1.0 05/15/15 13:30
Styrene ug/L ND 1.0 05/15/15 13:30
tert-Butylbenzene ug/L ND 1.0 05/15/15 13:30
Tetrachloroethene ug/L ND 1.0 05/15/15 13:30
Tetrahydrofuran ug/L ND 10.0 05/15/15 13:30
Toluene ug/L ND 1.0 05/15/15 13:30
trans-1,2-Dichloroethene ug/L ND 1.0 05/15/15 13:30
trans-1,3-Dichloropropene ug/L ND 4.0 05/15/15 13:30
Trichloroethene ug/L ND 0.40 05/15/15 13:30
Trichlorofluoromethane ug/L ND 1.0 05/15/15 13:30
Vinyl chloride ug/L ND 0.40 05/15/15 13:30
Xylene (Total) ug/L ND 3.0 05/15/15 13:30
1,2-Dichloroethane-d4 (S) %. 101 75-125 05/15/15 13:30
4-Bromofluorobenzene (S) %. 98 75-125 05/15/15 13:30
Toluene-d8 (S) %. 101 75-125 05/15/15 13:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1965485LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 19.620 98 75-125
1,1,1-Trichloroethane ug/L 19.220 96 75-125
1,1,2,2-Tetrachloroethane ug/L 20.720 104 75-125
1,1,2-Trichloroethane ug/L 19.920 100 75-125
1,1,2-Trichlorotrifluoroethane ug/L 17.620 88 60-135
1,1-Dichloroethane ug/L 18.920 95 69-125
1,1-Dichloroethene ug/L 19.220 96 68-125
1,1-Dichloropropene ug/L 20.020 100 74-125
1,2,3-Trichlorobenzene ug/L 18.920 94 69-136
1,2,3-Trichloropropane ug/L 20.420 102 75-125
1,2,4-Trichlorobenzene ug/L 19.220 96 73-127
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 42 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1965485LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/L 19.220 96 75-125
1,2-Dibromo-3-chloropropane ug/L 47.550 95 65-145
1,2-Dibromoethane (EDB) ug/L 20.920 104 75-125
1,2-Dichlorobenzene ug/L 18.920 94 75-125
1,2-Dichloroethane ug/L 18.620 93 73-125
1,2-Dichloropropane ug/L 18.920 95 75-125
1,3,5-Trimethylbenzene ug/L 19.720 98 75-125
1,3-Dichlorobenzene ug/L 18.920 95 74-125
1,3-Dichloropropane ug/L 19.720 98 75-125
1,4-Dichlorobenzene ug/L 18.720 94 75-125
2,2-Dichloropropane ug/L 19.420 97 59-139
2-Butanone (MEK) ug/L 96.8100 97 63-130
2-Chlorotoluene ug/L 19.420 97 72-125
4-Chlorotoluene ug/L 19.120 96 73-125
4-Methyl-2-pentanone (MIBK) ug/L 105100 105 71-126
Acetone ug/L 106100 106 69-131
Allyl chloride ug/L 19.520 98 67-125
Benzene ug/L 19.520 97 71-125
Bromobenzene ug/L 19.820 99 75-125
Bromochloromethane ug/L 19.120 96 75-125
Bromodichloromethane ug/L 19.120 95 75-125
Bromoform ug/L 17.520 87 70-125
Bromomethane ug/L 20.520 102 30-150
Carbon tetrachloride ug/L 18.020 90 75-126
Chlorobenzene ug/L 19.820 99 75-125
Chloroethane ug/L 18.420 92 65-134
Chloroform ug/L 17.920 90 75-125
Chloromethane ug/L 21.620 108 39-150
cis-1,2-Dichloroethene ug/L 19.120 95 72-125
cis-1,3-Dichloropropene ug/L 19.120 95 75-125
Dibromochloromethane ug/L 18.220 91 75-125
Dibromomethane ug/L 19.820 99 75-125
Dichlorodifluoromethane ug/L 16.320 81 50-134
Dichlorofluoromethane ug/L 20.020 100 69-125
Diethyl ether (Ethyl ether) ug/L 19.020 95 72-125
Ethylbenzene ug/L 19.320 97 75-125
Hexachloro-1,3-butadiene ug/L 18.720 94 70-138
Isopropylbenzene (Cumene) ug/L 19.920 100 75-125
Methyl-tert-butyl ether ug/L 19.720 98 73-125
Methylene Chloride ug/L 18.520 93 73-125
n-Butylbenzene ug/L 20.020 100 72-133
n-Propylbenzene ug/L 19.920 99 72-126
Naphthalene ug/L 19.320 97 70-127
p-Isopropyltoluene ug/L 20.220 101 72-132
sec-Butylbenzene ug/L 20.120 101 73-132
Styrene ug/L 20.820 104 75-125
tert-Butylbenzene ug/L 19.820 99 73-128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
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1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 43 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1965485LABORATORY CONTROL SAMPLE:
LCSSpike
Tetrachloroethene ug/L 21.220 106 74-125
Tetrahydrofuran ug/L 209200 104 62-133
Toluene ug/L 20.220 101 74-125
trans-1,2-Dichloroethene ug/L 19.820 99 69-125
trans-1,3-Dichloropropene ug/L 20.120 100 75-125
Trichloroethene ug/L 20.520 103 75-125
Trichlorofluoromethane ug/L 19.320 96 74-127
Vinyl chloride ug/L 20.220 101 66-132
Xylene (Total) ug/L 59.660 99 75-125
1,2-Dichloroethane-d4 (S) %. 98 75-125
4-Bromofluorobenzene (S) %. 100 75-125
Toluene-d8 (S) %. 101 75-125
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1968758MATRIX SPIKE SAMPLE:
MSSpike
Result
10306158005
1,1,1,2-Tetrachloroethane ug/L 19.920 100 70-138ND
1,1,1-Trichloroethane ug/L 20.720 104 55-150ND
1,1,2,2-Tetrachloroethane ug/L 20.020 100 64-140ND
1,1,2-Trichloroethane ug/L 20.120 101 67-137ND
1,1,2-Trichlorotrifluoroethane ug/L 22.520 113 51-150ND
1,1-Dichloroethane ug/L 20.120 101 49-150ND
1,1-Dichloroethene ug/L 21.720 108 40-150ND
1,1-Dichloropropene ug/L 22.120 110 50-150ND
1,2,3-Trichlorobenzene ug/L 18.320 91 59-148ND
1,2,3-Trichloropropane ug/L 19.720 99 65-141ND
1,2,4-Trichlorobenzene ug/L 18.920 94 61-140ND
1,2,4-Trimethylbenzene ug/L 19.820 99 58-141ND
1,2-Dibromo-3-chloropropane ug/L 43.050 86 53-150ND
1,2-Dibromoethane (EDB) ug/L 20.620 103 65-137ND
1,2-Dichlorobenzene ug/L 19.520 97 66-133ND
1,2-Dichloroethane ug/L 18.920 94 54-138ND
1,2-Dichloropropane ug/L 19.520 98 62-138ND
1,3,5-Trimethylbenzene ug/L 20.320 102 58-140ND
1,3-Dichlorobenzene ug/L 19.920 99 66-132ND
1,3-Dichloropropane ug/L 19.120 95 66-134ND
1,4-Dichlorobenzene ug/L 19.420 97 65-129ND
2,2-Dichloropropane ug/L 20.720 103 40-150ND
2-Butanone (MEK) ug/L 91.3100 91 51-147ND
2-Chlorotoluene ug/L 20.120 100 58-147ND
4-Chlorotoluene ug/L 19.820 99 64-138ND
4-Methyl-2-pentanone (MIBK) ug/L 97.5100 97 59-143ND
Acetone ug/L 116100 116 63-147ND
Allyl chloride ug/L 20.620 103 45-150ND
Benzene ug/L 20.520 102 53-139ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
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Page 44 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1968758MATRIX SPIKE SAMPLE:
MSSpike
Result
10306158005
Bromobenzene ug/L 20.220 101 66-136ND
Bromochloromethane ug/L 20.620 103 64-136ND
Bromodichloromethane ug/L 19.520 98 66-138ND
Bromoform ug/L 16.820 84 59-136ND
Bromomethane ug/L 20.320 102 30-150ND
Carbon tetrachloride ug/L 20.020 100 56-150ND
Chlorobenzene ug/L 20.520 102 65-133ND
Chloroethane ug/L 17.620 88 48-150ND
Chloroform ug/L 18.120 90 57-145ND
Chloromethane ug/L 22.920 114 30-150ND
cis-1,2-Dichloroethene ug/L 20.120 100 49-150ND
cis-1,3-Dichloropropene ug/L 19.320 96 64-130ND
Dibromochloromethane ug/L 18.620 93 68-138ND
Dibromomethane ug/L 20.120 100 67-134ND
Dichlorodifluoromethane ug/L 18.720 94 45-150ND
Dichlorofluoromethane ug/L 19.420 97 54-150ND
Diethyl ether (Ethyl ether) ug/L 19.720 99 50-145ND
Ethylbenzene ug/L 20.320 102 55-139ND
Hexachloro-1,3-butadiene ug/L 20.220 101 49-150ND
Isopropylbenzene (Cumene) ug/L 20.820 104 64-142ND
Methyl-tert-butyl ether ug/L 20.420 102 62-129ND
Methylene Chloride ug/L 19.720 98 57-132ND
n-Butylbenzene ug/L 20.520 103 55-150ND
n-Propylbenzene ug/L 20.820 104 59-142ND
Naphthalene ug/L 18.920 95 51-150ND
p-Isopropyltoluene ug/L 21.120 106 60-149ND
sec-Butylbenzene ug/L 21.120 105 60-150ND
Styrene ug/L 21.520 108 68-134ND
tert-Butylbenzene ug/L 20.820 104 62-146ND
Tetrachloroethene ug/L 22.720 113 50-150ND
Tetrahydrofuran ug/L 243200 122 59-145ND
Toluene ug/L 20.720 103 52-148ND
trans-1,2-Dichloroethene ug/L 22.220 111 45-150ND
trans-1,3-Dichloropropene ug/L 19.320 97 68-132ND
Trichloroethene ug/L 21.820 109 52-150ND
Trichlorofluoromethane ug/L 20.820 104 55-150ND
Vinyl chloride ug/L 21.320 106 43-150ND
Xylene (Total) ug/L 62.560 104 54-144ND
1,2-Dichloroethane-d4 (S) %. 98 75-125
4-Bromofluorobenzene (S) %. 99 75-125
Toluene-d8 (S) %. 101 75-125
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 45 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10306158006
1968759SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1,2-Trichlorotrifluoroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,1-Dichloropropene ug/L ND 30ND
1,2,3-Trichlorobenzene ug/L .85J 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2,4-Trichlorobenzene ug/L .68J 30ND
1,2,4-Trimethylbenzene ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB) ug/L ND 30ND
1,2-Dichlorobenzene ug/L .27J 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,3,5-Trimethylbenzene ug/L ND 30ND
1,3-Dichlorobenzene ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2,2-Dichloropropane ug/L ND 30ND
2-Butanone (MEK) ug/L ND 30ND
2-Chlorotoluene ug/L ND 30ND
4-Chlorotoluene ug/L .22J 30ND
4-Methyl-2-pentanone (MIBK) ug/L ND 30ND
Acetone ug/L ND 30ND
Allyl chloride ug/L ND 30ND
Benzene ug/L ND 30ND
Bromobenzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Dichlorofluoromethane ug/L ND 30ND
Diethyl ether (Ethyl ether) ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
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1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 46 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10306158006
1968759SAMPLE DUPLICATE:
Hexachloro-1,3-butadiene ug/L .85J 30ND
Isopropylbenzene (Cumene) ug/L ND 30ND
Methyl-tert-butyl ether ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
n-Butylbenzene ug/L .59J 30ND
n-Propylbenzene ug/L ND 30ND
Naphthalene ug/L ND 30ND
p-Isopropyltoluene ug/L ND 30ND
sec-Butylbenzene ug/L ND 30ND
Styrene ug/L ND 30ND
tert-Butylbenzene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total) ug/L ND 30ND
1,2-Dichloroethane-d4 (S) %. 95 196
4-Bromofluorobenzene (S) %. 98 199
Toluene-d8 (S) %. 100 2101
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 47 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/29195
EPA 3550
EPA 8270D by SIM
8270D Solid PAH by SIM MSSV
Associated Lab Samples: 10306235001, 10306235002, 10306235003, 10306235004, 10306235005, 10306235006, 10306235008,10306235009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1967333
Associated Lab Samples: 10306235001, 10306235002, 10306235003, 10306235004, 10306235005, 10306235006, 10306235008,10306235009
Matrix: Solid
Analyzed
Acenaphthene mg/kg ND 0.010 05/20/15 02:38
Acenaphthylene mg/kg ND 0.010 05/20/15 02:38
Anthracene mg/kg ND 0.010 05/20/15 02:38
Benzo(a)anthracene mg/kg ND 0.010 05/20/15 02:38
Benzo(a)pyrene mg/kg ND 0.010 05/20/15 02:38
Benzo(b)fluoranthene mg/kg ND 0.010 05/20/15 02:38
Benzo(g,h,i)perylene mg/kg ND 0.010 05/20/15 02:38
Benzo(k)fluoranthene mg/kg ND 0.010 05/20/15 02:38
Chrysene mg/kg ND 0.010 05/20/15 02:38
Dibenz(a,h)anthracene mg/kg ND 0.010 05/20/15 02:38
Fluoranthene mg/kg ND 0.010 05/20/15 02:38
Fluorene mg/kg ND 0.010 05/20/15 02:38
Indeno(1,2,3-cd)pyrene mg/kg ND 0.010 05/20/15 02:38
Naphthalene mg/kg ND 0.010 05/20/15 02:38
Phenanthrene mg/kg ND 0.010 05/20/15 02:38
Pyrene mg/kg ND 0.010 05/20/15 02:38
2-Fluorobiphenyl (S) %. 78 55-125 05/20/15 02:38
p-Terphenyl-d14 (S) %. 96 30-150 05/20/15 02:38
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1967334LABORATORY CONTROL SAMPLE:
LCSSpike
Acenaphthene mg/kg 0.025.033 76 53-125
Acenaphthylene mg/kg 0.026.033 77 53-125
Anthracene mg/kg 0.029.033 86 61-125
Benzo(a)anthracene mg/kg 0.029.033 88 62-125
Benzo(a)pyrene mg/kg 0.032.033 97 64-125
Benzo(b)fluoranthene mg/kg 0.030.033 91 66-125
Benzo(g,h,i)perylene mg/kg 0.031.033 93 59-125
Benzo(k)fluoranthene mg/kg 0.034.033 101 61-125
Chrysene mg/kg 0.029.033 87 63-125
Dibenz(a,h)anthracene mg/kg 0.032.033 97 59-125
Fluoranthene mg/kg 0.030.033 89 64-125
Fluorene mg/kg 0.027.033 82 57-125
Indeno(1,2,3-cd)pyrene mg/kg 0.031.033 93 58-125
Naphthalene mg/kg 0.024.033 72 52-125
Phenanthrene mg/kg 0.025.033 74 60-125
Pyrene mg/kg 0.031.033 93 63-125
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 48 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1967334LABORATORY CONTROL SAMPLE:
LCSSpike
2-Fluorobiphenyl (S) %. 79 55-125
p-Terphenyl-d14 (S) %. 95 30-150
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1967335MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
10306204001
1967336
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Acenaphthene mg/kg .036 71 39-12563 12 30.036ND 0.026 0.023
Acenaphthylene mg/kg .036 68 30-15059 14 30.036ND 0.025 0.022
Anthracene mg/kg .036 80 30-15077 4 30.036ND 0.029 0.028
Benzo(a)anthracene mg/kg .036 86 30-15099 15 30.036ND 0.031 0.036
Benzo(a)pyrene mg/kg .036 99 30-150111 11 30.036ND 0.036 0.041
Benzo(b)fluoranthene mg/kg .036 95 30-150126 28 30.036ND 0.035 0.046
Benzo(g,h,i)perylene mg/kg .036 97 30-15099 2 30.036ND 0.036 0.036
Benzo(k)fluoranthene mg/kg .036 98 30-15095 3 30.036ND 0.036 0.035
Chrysene mg/kg .036 85 30-150100 17 30.036ND 0.031 0.037
Dibenz(a,h)anthracene mg/kg .036 91 30-15089 2 30.036ND 0.033 0.032
Fluoranthene mg/kg R1.036 90 30-150132 38 30.036ND 0.033 0.048
Fluorene mg/kg .036 78 30-14670 11 30.036ND 0.028 0.025
Indeno(1,2,3-cd)pyrene mg/kg .036 92 30-15095 4 30.036ND 0.034 0.035
Naphthalene mg/kg .036 64 30-13157 12 30.036ND 0.023 0.021
Phenanthrene mg/kg .036 72 30-15092 24 30.036ND 0.026 0.034
Pyrene mg/kg .036 97 30-150131 30 30.036ND 0.035 0.048
2-Fluorobiphenyl (S) %. 71 55-12571
p-Terphenyl-d14 (S) %. 83 30-15084
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 49 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/29194
WI MOD DRO
WI MOD DRO
WIDRO Solid GCV
Associated Lab Samples: 10306235002, 10306235004, 10306235005, 10306235006, 10306235009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1967249
Associated Lab Samples: 10306235002, 10306235004, 10306235005, 10306235006, 10306235009
Matrix: Solid
Analyzed
WDRO C10-C28 mg/kg ND 10.0 05/19/15 09:57
n-Triacontane (S) %. 91 30-143 05/19/15 09:57
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1967250LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1967251
WDRO C10-C28 mg/kg 74.780 93 64-1259374.5 0 20
n-Triacontane (S) %. 96 30-14393
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 50 of 58
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/29188
WI MOD DRO
WI MOD DRO
WIDRO GCS w/Cleanup
Associated Lab Samples: 10306235007, 10306235010
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1967124
Associated Lab Samples: 10306235007, 10306235010
Matrix: Water
Analyzed
WDRO C10-C28 mg/L ND 0.10 05/17/15 17:17
n-Triacontane (S) %. 72 62-125 05/17/15 17:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1967125LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1967126
WDRO C10-C28 mg/L 2.02 98 54-125931.9 5 20
n-Triacontane (S) %. 104 62-12597
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
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Minneapolis, MN 55414
(612)607-1700
Page 51 of 58
#=QL#
QUALIFIERS
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Green BayPASI-G
Pace Analytical Services - MinneapolisPASI-M
ANALYTE QUALIFIERS
Sample was diluted due to the presence of high levels of target analytes.D4
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results may be biased low.L2
Sample field preservation does not meet EPA or method recommendations for this analysis.P4
RPD value was outside control limits.R1
Surrogate recovery outside control limits due to matrix interferences (not confirmed by re-analysis).S5
High boiling point hydrocarbons are present in the sample.T6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
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Minneapolis, MN 55414
(612)607-1700
Page 52 of 58
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
10306235002 OEXT/29194 GCSV/15720LGP-19/4-6 WI MOD DRO WI MOD DRO
10306235004 OEXT/29194 GCSV/15720LHA-21/2-4 WI MOD DRO WI MOD DRO
10306235005 OEXT/29194 GCSV/15720LGP-22/4-6 WI MOD DRO WI MOD DRO
10306235006 OEXT/29194 GCSV/15720LGP-23/6-8 WI MOD DRO WI MOD DRO
10306235009 OEXT/29194 GCSV/15720LGP-25/1-3 WI MOD DRO WI MOD DRO
10306235007 OEXT/29188 GCSV/15708LGP-23/17-20 WI MOD DRO WI MOD DRO
10306235010 OEXT/29188 GCSV/15708LGP-25/15-20 WI MOD DRO WI MOD DRO
10306235002 GCV/13744 GCV/13747LGP-19/4-6 EPA 5030 Medium Soil WI MOD GRO
10306235004 GCV/13744 GCV/13747LHA-21/2-4 EPA 5030 Medium Soil WI MOD GRO
10306235005 GCV/13744 GCV/13747LGP-22/4-6 EPA 5030 Medium Soil WI MOD GRO
10306235006 GCV/13744 GCV/13747LGP-23/6-8 EPA 5030 Medium Soil WI MOD GRO
10306235009 GCV/13744 GCV/13747LGP-25/1-3 EPA 5030 Medium Soil WI MOD GRO
10306235007 GCV/14422LGP-23/17-20 WI MOD GRO
10306235010 GCV/14422LGP-25/15-20 WI MOD GRO
10306235001 MPRP/54373 ICP/23806LGP-18/3-5 EPA 3050 EPA 6010C
10306235002 MPRP/54373 ICP/23806LGP-19/4-6 EPA 3050 EPA 6010C
10306235003 MPRP/54373 ICP/23806LHA-20/5-7 EPA 3050 EPA 6010C
10306235004 MPRP/54373 ICP/23806LHA-21/2-4 EPA 3050 EPA 6010C
10306235005 MPRP/54373 ICP/23806LGP-22/4-6 EPA 3050 EPA 6010C
10306235006 MPRP/54373 ICP/23806LGP-23/6-8 EPA 3050 EPA 6010C
10306235008 MPRP/54373 ICP/23806LGP-24/3-5 EPA 3050 EPA 6010C
10306235009 MPRP/54373 ICP/23806LGP-25/1-3 EPA 3050 EPA 6010C
10306235001 MERP/13552 MERC/15762LGP-18/3-5 EPA 7471B EPA 7471B
10306235002 MERP/13552 MERC/15762LGP-19/4-6 EPA 7471B EPA 7471B
10306235003 MERP/13552 MERC/15762LHA-20/5-7 EPA 7471B EPA 7471B
10306235004 MERP/13552 MERC/15762LHA-21/2-4 EPA 7471B EPA 7471B
10306235005 MERP/13552 MERC/15762LGP-22/4-6 EPA 7471B EPA 7471B
10306235006 MERP/13552 MERC/15762LGP-23/6-8 EPA 7471B EPA 7471B
10306235008 MERP/13552 MERC/15762LGP-24/3-5 EPA 7471B EPA 7471B
10306235009 MERP/13552 MERC/15762LGP-25/1-3 EPA 7471B EPA 7471B
10306235001 MPRP/54526LGP-18/3-5 ASTM D2974
10306235002 MPRP/54526LGP-19/4-6 ASTM D2974
10306235003 MPRP/54526LHA-20/5-7 ASTM D2974
10306235004 MPRP/54526LHA-21/2-4 ASTM D2974
10306235005 MPRP/54527LGP-22/4-6 ASTM D2974
10306235006 MPRP/54527LGP-23/6-8 ASTM D2974
10306235008 MPRP/54527LGP-24/3-5 ASTM D2974
10306235009 MPRP/54527LGP-25/1-3 ASTM D2974
10306235001 OEXT/29195 MSSV/12351LGP-18/3-5 EPA 3550 EPA 8270D by SIM
10306235002 OEXT/29195 MSSV/12351LGP-19/4-6 EPA 3550 EPA 8270D by SIM
10306235003 OEXT/29195 MSSV/12351LHA-20/5-7 EPA 3550 EPA 8270D by SIM
10306235004 OEXT/29195 MSSV/12351LHA-21/2-4 EPA 3550 EPA 8270D by SIM
10306235005 OEXT/29195 MSSV/12351LGP-22/4-6 EPA 3550 EPA 8270D by SIM
10306235006 OEXT/29195 MSSV/12351LGP-23/6-8 EPA 3550 EPA 8270D by SIM
10306235008 OEXT/29195 MSSV/12351LGP-24/3-5 EPA 3550 EPA 8270D by SIM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
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Page 53 of 58
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
10306235
HC-15-002 CSAH-53
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
10306235009 OEXT/29195 MSSV/12351LGP-25/1-3 EPA 3550 EPA 8270D by SIM
10306235002 MSV/31467 MSV/31499LGP-19/4-6 EPA 5035/5030B EPA 8260B
10306235004 MSV/31467 MSV/31499LHA-21/2-4 EPA 5035/5030B EPA 8260B
10306235005 MSV/31467 MSV/31499LGP-22/4-6 EPA 5035/5030B EPA 8260B
10306235006 MSV/31467 MSV/31499LGP-23/6-8 EPA 5035/5030B EPA 8260B
10306235009 MSV/31467 MSV/31499LGP-25/1-3 EPA 5035/5030B EPA 8260B
10306235007 MSV/31440LGP-23/17-20 EPA 8260B
10306235010 MSV/31440LGP-25/15-20 EPA 8260B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/27/2015 12:27 PM
Pace Analytical Services, Inc.
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Minneapolis, MN 55414
(612)607-1700
Page 54 of 58
Page 55 of 58
Page 56 of 58
Page 57 of 58
Page 58 of 58
#=CL#
May 21, 2015
LIMS USE: FR - JERRY MULLIN
LIMS OBJECT ID: 10306204
10306204
Project:
Pace Project No.:
RE:
Mr. Jerry MullinLandmark Environmental2042 West 98th StreetBloomington, MN 55431
HC-15-002 CHAH-53
Dear Mr. Mullin:
Enclosed are the analytical results for sample(s) received by the laboratory on May 13, 2015. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Carol Davy for
Project Manager
Jessica Patterson
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 1 of 18
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
10306204
HC-15-002 CHAH-53
Minnesota Certification IDs1700 Elm Street SE Suite 200, Minneapolis, MN 55414A2LA Certification #: 2926.01Alaska Certification #: UST-078Alaska Certification #MN00064Alabama Certification #40770Arizona Certification #: AZ-0014Arkansas Certification #: 88-0680California Certification #: 01155CAColorado Certification #PaceConnecticut Certification #: PH-0256EPA Region 8 Certification #: 8TMS-LFlorida/NELAP Certification #: E87605Guam Certification #:14-008rGeorgia Certification #: 959Georgia EPD #: PaceIdaho Certification #: MN00064Hawaii Certification #MN00064Illinois Certification #: 200011Indiana Certification#C-MN-01Iowa Certification #: 368Kansas Certification #: E-10167Kentucky Dept of Envi. Protection - DW #90062Kentucky Dept of Envi. Protection - WW #:90062Louisiana DEQ Certification #: 3086Louisiana DHH #: LA140001Maine Certification #: 2013011Maryland Certification #: 322Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137Mississippi Certification #: PaceMontana Certification #: MT0092Nevada Certification #: MN_00064Nebraska Certification #: PaceNew Jersey Certification #: MN-002New York Certification #: 11647North Carolina Certification #: 530North Carolina State Public Health #: 27700North Dakota Certification #: R-036Ohio EPA #: 4150Ohio VAP Certification #: CL101Oklahoma Certification #: 9507Oregon Certification #: MN200001Oregon Certification #: MN300001Pennsylvania Certification #: 68-00563Puerto Rico CertificationSaipan (CNMI) #:MP0003South Carolina #:74003001Texas Certification #: T104704192Tennessee Certification #: 02818Utah Certification #: MN000642013-4Virginia DGS Certification #: 251Virginia/VELAP Certification #: PaceWashington Certification #: C486West Virginia Certification #: 382West Virginia DHHR #:9952CWisconsin Certification #: 999407970
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 2 of 18
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
10306204
HC-15-002 CHAH-53
Lab ID Sample ID Matrix Date Collected Date Received
10306204001 LGP-26/6-8 Solid 05/13/15 00:00 05/13/15 14:35
10306204002 LGP-27/1-3 Solid 05/13/15 00:00 05/13/15 14:35
10306204003 LGP-28/2-4 Solid 05/13/15 00:00 05/13/15 14:35
10306204004 LGP-29/2-4 Solid 05/13/15 00:00 05/13/15 14:35
10306204005 LGP-30/1-3 Solid 05/13/15 00:00 05/13/15 14:35
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 3 of 18
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
10306204
HC-15-002 CHAH-53
Lab ID Sample ID Method
Analytes
ReportedAnalysts
10306204001 LGP-26/6-8 EPA 6010C 7IP
EPA 7471B 1LMW
ASTM D2974 1JDL
EPA 8270D by SIM 19AS1
10306204002 LGP-27/1-3 EPA 6010C 7IP
EPA 7471B 1LMW
ASTM D2974 1JDL
EPA 8270D by SIM 19AS1
10306204003 LGP-28/2-4 EPA 6010C 7IP
EPA 7471B 1LMW
ASTM D2974 1JDL
EPA 8270D by SIM 19AS1
10306204004 LGP-29/2-4 EPA 6010C 7IP
EPA 7471B 1LMW
ASTM D2974 1JDL
EPA 8270D by SIM 19AS1
10306204005 LGP-30/1-3 EPA 6010C 7IP
EPA 7471B 1LMW
ASTM D2974 1JDL
EPA 8270D by SIM 19AS1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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1700 Elm Street - Suite 200
Minneapolis, MN 55414
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Page 4 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306204
HC-15-002 CHAH-53
Sample: LGP-26/6-8 Lab ID: 10306204001 Collected: 05/13/15 00:00 Received: 05/13/15 14:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 1.9 mg/kg 05/19/15 23:56 7440-38-205/18/15 04:460.90 1
Barium 30.1 mg/kg 05/19/15 23:56 7440-39-305/18/15 04:460.45 1
Cadmium 0.16 mg/kg 05/19/15 23:56 7440-43-905/18/15 04:460.13 1
Chromium 5.6 mg/kg 05/19/15 23:56 7440-47-305/18/15 04:460.45 1
Lead 3.6 mg/kg 05/19/15 23:56 7439-92-105/18/15 04:460.45 1
Selenium ND mg/kg 05/19/15 23:56 7782-49-205/18/15 04:460.90 1
Silver ND mg/kg 05/19/15 23:56 7440-22-405/18/15 04:460.45 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/18/15 19:11 7439-97-605/17/15 15:180.021 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 8.8 % 05/19/15 09:020.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/20/15 03:19 83-32-905/15/15 22:170.011 1
Acenaphthylene ND mg/kg 05/20/15 03:19 208-96-805/15/15 22:170.011 1
Anthracene ND mg/kg 05/20/15 03:19 120-12-705/15/15 22:170.011 1
Benzo(a)anthracene ND mg/kg 05/20/15 03:19 56-55-305/15/15 22:170.011 1
Benzo(a)pyrene ND mg/kg 05/20/15 03:19 50-32-805/15/15 22:170.011 1
Benzo(b)fluoranthene ND mg/kg 05/20/15 03:19 205-99-205/15/15 22:170.011 1
Benzo(g,h,i)perylene ND mg/kg 05/20/15 03:19 191-24-205/15/15 22:170.011 1
Benzo(k)fluoranthene ND mg/kg 05/20/15 03:19 207-08-905/15/15 22:170.011 1
Chrysene ND mg/kg 05/20/15 03:19 218-01-905/15/15 22:170.011 1
Dibenz(a,h)anthracene ND mg/kg 05/20/15 03:19 53-70-305/15/15 22:170.011 1
Fluoranthene ND mg/kg 05/20/15 03:19 206-44-0 R105/15/15 22:170.011 1
Fluorene ND mg/kg 05/20/15 03:19 86-73-705/15/15 22:170.011 1
Indeno(1,2,3-cd)pyrene ND mg/kg 05/20/15 03:19 193-39-505/15/15 22:170.011 1
Naphthalene ND mg/kg 05/20/15 03:19 91-20-305/15/15 22:170.011 1
Phenanthrene ND mg/kg 05/20/15 03:19 85-01-805/15/15 22:170.011 1
Pyrene ND mg/kg 05/20/15 03:19 129-00-005/15/15 22:170.011 1
Total BaP Eq. MN 2006sh. ND=0 ND mg/kg 05/20/15 03:1905/15/15 22:170.011 1
Surrogates2-Fluorobiphenyl (S) 70 %. 05/20/15 03:19 321-60-805/15/15 22:1755-125 1
p-Terphenyl-d14 (S) 83 %. 05/20/15 03:19 1718-51-005/15/15 22:1730-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/21/2015 04:20 PM
Pace Analytical Services, Inc.
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Page 5 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306204
HC-15-002 CHAH-53
Sample: LGP-27/1-3 Lab ID: 10306204002 Collected: 05/13/15 00:00 Received: 05/13/15 14:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 3.0 mg/kg 05/20/15 00:22 7440-38-205/18/15 04:460.94 1
Barium 65.9 mg/kg 05/20/15 00:22 7440-39-305/18/15 04:460.47 1
Cadmium 0.23 mg/kg 05/20/15 00:22 7440-43-905/18/15 04:460.14 1
Chromium 9.4 mg/kg 05/20/15 00:22 7440-47-305/18/15 04:460.47 1
Lead 6.7 mg/kg 05/20/15 00:22 7439-92-105/18/15 04:460.47 1
Selenium ND mg/kg 05/20/15 00:22 7782-49-205/18/15 04:460.94 1
Silver ND mg/kg 05/20/15 00:22 7440-22-405/18/15 04:460.47 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/18/15 19:17 7439-97-605/17/15 15:180.022 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 15.7 % 05/19/15 09:020.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/20/15 04:22 83-32-905/15/15 22:170.012 1
Acenaphthylene 0.014 mg/kg 05/20/15 04:22 208-96-805/15/15 22:170.012 1
Anthracene ND mg/kg 05/20/15 04:22 120-12-705/15/15 22:170.012 1
Benzo(a)anthracene 0.047 mg/kg 05/20/15 04:22 56-55-305/15/15 22:170.012 1
Benzo(a)pyrene 0.064 mg/kg 05/20/15 04:22 50-32-805/15/15 22:170.012 1
Benzo(b)fluoranthene 0.094 mg/kg 05/20/15 04:22 205-99-205/15/15 22:170.012 1
Benzo(g,h,i)perylene 0.048 mg/kg 05/20/15 04:22 191-24-205/15/15 22:170.012 1
Benzo(k)fluoranthene 0.028 mg/kg 05/20/15 04:22 207-08-905/15/15 22:170.012 1
Chrysene 0.065 mg/kg 05/20/15 04:22 218-01-905/15/15 22:170.012 1
Dibenz(a,h)anthracene ND mg/kg 05/20/15 04:22 53-70-305/15/15 22:170.012 1
Fluoranthene 0.12 mg/kg 05/20/15 04:22 206-44-005/15/15 22:170.012 1
Fluorene ND mg/kg 05/20/15 04:22 86-73-705/15/15 22:170.012 1
Indeno(1,2,3-cd)pyrene 0.038 mg/kg 05/20/15 04:22 193-39-505/15/15 22:170.012 1
Naphthalene ND mg/kg 05/20/15 04:22 91-20-305/15/15 22:170.012 1
Phenanthrene 0.057 mg/kg 05/20/15 04:22 85-01-805/15/15 22:170.012 1
Pyrene 0.12 mg/kg 05/20/15 04:22 129-00-005/15/15 22:170.012 1
Total BaP Eq. MN 2006sh. ND=0 0.085 mg/kg 05/20/15 04:2205/15/15 22:170.012 1
Surrogates2-Fluorobiphenyl (S) 65 %. 05/20/15 04:22 321-60-805/15/15 22:1755-125 1
p-Terphenyl-d14 (S) 80 %. 05/20/15 04:22 1718-51-005/15/15 22:1730-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/21/2015 04:20 PM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 6 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306204
HC-15-002 CHAH-53
Sample: LGP-28/2-4 Lab ID: 10306204003 Collected: 05/13/15 00:00 Received: 05/13/15 14:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 2.1 mg/kg 05/20/15 00:27 7440-38-205/18/15 04:461.0 1
Barium 74.8 mg/kg 05/20/15 00:27 7440-39-305/18/15 04:460.52 1
Cadmium 0.22 mg/kg 05/20/15 00:27 7440-43-905/18/15 04:460.16 1
Chromium 12.0 mg/kg 05/20/15 00:27 7440-47-305/18/15 04:460.52 1
Lead 9.4 mg/kg 05/20/15 00:27 7439-92-105/18/15 04:460.52 1
Selenium ND mg/kg 05/20/15 00:27 7782-49-205/18/15 04:461.0 1
Silver ND mg/kg 05/20/15 00:27 7440-22-405/18/15 04:460.52 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury 0.022 mg/kg 05/18/15 19:19 7439-97-605/17/15 15:180.019 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 12.5 % 05/19/15 09:030.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/20/15 17:34 83-32-905/15/15 22:170.011 1
Acenaphthylene ND mg/kg 05/20/15 17:34 208-96-805/15/15 22:170.011 1
Anthracene ND mg/kg 05/20/15 17:34 120-12-705/15/15 22:170.011 1
Benzo(a)anthracene 0.016 mg/kg 05/20/15 17:34 56-55-305/15/15 22:170.011 1
Benzo(a)pyrene 0.026 mg/kg 05/20/15 17:34 50-32-805/15/15 22:170.011 1
Benzo(b)fluoranthene 0.033 mg/kg 05/20/15 17:34 205-99-205/15/15 22:170.011 1
Benzo(g,h,i)perylene 0.036 mg/kg 05/20/15 17:34 191-24-205/15/15 22:170.011 1
Benzo(k)fluoranthene 0.014 mg/kg 05/20/15 17:34 207-08-905/15/15 22:170.011 1
Chrysene 0.020 mg/kg 05/20/15 17:34 218-01-905/15/15 22:170.011 1
Dibenz(a,h)anthracene ND mg/kg 05/20/15 17:34 53-70-305/15/15 22:170.011 1
Fluoranthene 0.024 mg/kg 05/20/15 17:34 206-44-005/15/15 22:170.011 1
Fluorene ND mg/kg 05/20/15 17:34 86-73-705/15/15 22:170.011 1
Indeno(1,2,3-cd)pyrene 0.020 mg/kg 05/20/15 17:34 193-39-505/15/15 22:170.011 1
Naphthalene ND mg/kg 05/20/15 17:34 91-20-305/15/15 22:170.011 1
Phenanthrene ND mg/kg 05/20/15 17:34 85-01-805/15/15 22:170.011 1
Pyrene 0.027 mg/kg 05/20/15 17:34 129-00-005/15/15 22:170.011 1
Total BaP Eq. MN 2006sh. ND=0 0.034 mg/kg 05/20/15 17:3405/15/15 22:170.011 1
Surrogates2-Fluorobiphenyl (S) 81 %. 05/20/15 17:34 321-60-805/15/15 22:1755-125 1
p-Terphenyl-d14 (S) 86 %. 05/20/15 17:34 1718-51-005/15/15 22:1730-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/21/2015 04:20 PM
Pace Analytical Services, Inc.
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Minneapolis, MN 55414
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Page 7 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306204
HC-15-002 CHAH-53
Sample: LGP-29/2-4 Lab ID: 10306204004 Collected: 05/13/15 00:00 Received: 05/13/15 14:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 2.3 mg/kg 05/20/15 11:00 7440-38-205/18/15 04:462.2 2
Barium 85.9 mg/kg 05/20/15 11:00 7440-39-305/18/15 04:461.1 2
Cadmium ND mg/kg 05/20/15 11:00 7440-43-905/18/15 04:460.33 2
Chromium 13.3 mg/kg 05/20/15 11:00 7440-47-305/18/15 04:461.1 2
Lead 8.8 mg/kg 05/20/15 11:00 7439-92-105/18/15 04:461.1 2
Selenium ND mg/kg 05/20/15 11:00 7782-49-205/18/15 04:462.2 2
Silver ND mg/kg 05/20/15 11:00 7440-22-405/18/15 04:461.1 2
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury 0.023 mg/kg 05/18/15 19:21 7439-97-605/17/15 15:180.023 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 19.1 % 05/19/15 09:030.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/20/15 05:04 83-32-905/15/15 22:170.012 1
Acenaphthylene ND mg/kg 05/20/15 05:04 208-96-805/15/15 22:170.012 1
Anthracene ND mg/kg 05/20/15 05:04 120-12-705/15/15 22:170.012 1
Benzo(a)anthracene ND mg/kg 05/20/15 05:04 56-55-305/15/15 22:170.012 1
Benzo(a)pyrene ND mg/kg 05/20/15 05:04 50-32-805/15/15 22:170.012 1
Benzo(b)fluoranthene ND mg/kg 05/20/15 05:04 205-99-205/15/15 22:170.012 1
Benzo(g,h,i)perylene ND mg/kg 05/20/15 05:04 191-24-205/15/15 22:170.012 1
Benzo(k)fluoranthene ND mg/kg 05/20/15 05:04 207-08-905/15/15 22:170.012 1
Chrysene ND mg/kg 05/20/15 05:04 218-01-905/15/15 22:170.012 1
Dibenz(a,h)anthracene ND mg/kg 05/20/15 05:04 53-70-305/15/15 22:170.012 1
Fluoranthene ND mg/kg 05/20/15 05:04 206-44-005/15/15 22:170.012 1
Fluorene ND mg/kg 05/20/15 05:04 86-73-705/15/15 22:170.012 1
Indeno(1,2,3-cd)pyrene ND mg/kg 05/20/15 05:04 193-39-505/15/15 22:170.012 1
Naphthalene ND mg/kg 05/20/15 05:04 91-20-305/15/15 22:170.012 1
Phenanthrene ND mg/kg 05/20/15 05:04 85-01-805/15/15 22:170.012 1
Pyrene ND mg/kg 05/20/15 05:04 129-00-005/15/15 22:170.012 1
Total BaP Eq. MN 2006sh. ND=0 ND mg/kg 05/20/15 05:0405/15/15 22:170.012 1
Surrogates2-Fluorobiphenyl (S) 79 %. 05/20/15 05:04 321-60-805/15/15 22:1755-125 1
p-Terphenyl-d14 (S) 88 %. 05/20/15 05:04 1718-51-005/15/15 22:1730-150 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/21/2015 04:20 PM
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Page 8 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10306204
HC-15-002 CHAH-53
Sample: LGP-30/1-3 Lab ID: 10306204005 Collected: 05/13/15 00:00 Received: 05/13/15 14:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic ND mg/kg 05/20/15 00:45 7440-38-205/18/15 04:460.85 1
Barium 40.0 mg/kg 05/20/15 00:45 7440-39-305/18/15 04:460.43 1
Cadmium ND mg/kg 05/20/15 00:45 7440-43-905/18/15 04:460.13 1
Chromium 6.0 mg/kg 05/20/15 00:45 7440-47-305/18/15 04:460.43 1
Lead 4.4 mg/kg 05/20/15 00:45 7439-92-105/18/15 04:460.43 1
Selenium ND mg/kg 05/20/15 00:45 7782-49-205/18/15 04:460.85 1
Silver ND mg/kg 05/20/15 00:45 7440-22-405/18/15 04:460.43 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/18/15 19:27 7439-97-605/17/15 15:180.022 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 10.0 % 05/19/15 09:030.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/20/15 05:25 83-32-905/15/15 22:170.011 1
Acenaphthylene ND mg/kg 05/20/15 05:25 208-96-805/15/15 22:170.011 1
Anthracene ND mg/kg 05/20/15 05:25 120-12-705/15/15 22:170.011 1
Benzo(a)anthracene ND mg/kg 05/20/15 05:25 56-55-305/15/15 22:170.011 1
Benzo(a)pyrene ND mg/kg 05/20/15 05:25 50-32-805/15/15 22:170.011 1
Benzo(b)fluoranthene ND mg/kg 05/20/15 05:25 205-99-205/15/15 22:170.011 1
Benzo(g,h,i)perylene ND mg/kg 05/20/15 05:25 191-24-205/15/15 22:170.011 1
Benzo(k)fluoranthene ND mg/kg 05/20/15 05:25 207-08-905/15/15 22:170.011 1
Chrysene ND mg/kg 05/20/15 05:25 218-01-905/15/15 22:170.011 1
Dibenz(a,h)anthracene ND mg/kg 05/20/15 05:25 53-70-305/15/15 22:170.011 1
Fluoranthene ND mg/kg 05/20/15 05:25 206-44-005/15/15 22:170.011 1
Fluorene ND mg/kg 05/20/15 05:25 86-73-705/15/15 22:170.011 1
Indeno(1,2,3-cd)pyrene ND mg/kg 05/20/15 05:25 193-39-505/15/15 22:170.011 1
Naphthalene ND mg/kg 05/20/15 05:25 91-20-305/15/15 22:170.011 1
Phenanthrene ND mg/kg 05/20/15 05:25 85-01-805/15/15 22:170.011 1
Pyrene ND mg/kg 05/20/15 05:25 129-00-005/15/15 22:170.011 1
Total BaP Eq. MN 2006sh. ND=0 ND mg/kg 05/20/15 05:2505/15/15 22:170.011 1
Surrogates2-Fluorobiphenyl (S) 67 %. 05/20/15 05:25 321-60-805/15/15 22:1755-125 1
p-Terphenyl-d14 (S) 82 %. 05/20/15 05:25 1718-51-005/15/15 22:1730-150 1
REPORT OF LABORATORY ANALYSIS
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Page 9 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306204
HC-15-002 CHAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/13552
EPA 7471B
EPA 7471B
7471B Mercury Solids
Associated Lab Samples: 10306204001, 10306204002, 10306204003, 10306204004, 10306204005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1966049
Associated Lab Samples: 10306204001, 10306204002, 10306204003, 10306204004, 10306204005
Matrix: Solid
Analyzed
Mercury mg/kg ND 0.019 05/18/15 19:07
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1966050LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/kg 0.49.48 101 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1966051MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
10306204001
1966052
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/kg .55 98 75-125100 10 20.48ND 0.54 0.49
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/21/2015 04:20 PM
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Page 10 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306204
HC-15-002 CHAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/54373
EPA 3050
EPA 6010C
6010C Solids
Associated Lab Samples: 10306204001, 10306204002, 10306204003, 10306204004, 10306204005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1965104
Associated Lab Samples: 10306204001, 10306204002, 10306204003, 10306204004, 10306204005
Matrix: Solid
Analyzed
Arsenic mg/kg ND 0.89 05/19/15 23:48
Barium mg/kg ND 0.45 05/19/15 23:48
Cadmium mg/kg ND 0.13 05/19/15 23:48
Chromium mg/kg ND 0.45 05/19/15 23:48
Lead mg/kg ND 0.45 05/19/15 23:48
Selenium mg/kg ND 0.89 05/19/15 23:48
Silver mg/kg ND 0.45 05/19/15 23:48
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1965105LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic mg/kg 45.248.5 93 80-120
Barium mg/kg 46.948.5 97 80-120
Cadmium mg/kg 44.448.5 91 80-120
Chromium mg/kg 46.748.5 96 80-120
Lead mg/kg 44.748.5 92 80-120
Selenium mg/kg 44.048.5 91 80-120
Silver mg/kg 22.324.3 92 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1965106MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
10306204001
1965107
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic mg/kg 45 97 75-125100 1 2044.21.9 45.5 46.2
Barium mg/kg 45 104 75-125122 9 2044.230.1 77.0 84.3
Cadmium mg/kg 45 95 75-12596 0 2044.20.16 42.7 42.5
Chromium mg/kg 45 97 75-12599 0 2044.25.6 49.3 49.2
Lead mg/kg 45 88 75-12594 4 2044.23.6 43.4 45.0
Selenium mg/kg 45 91 75-12595 3 2044.2ND 40.8 42.2
Silver mg/kg 22.5 96 75-12597 1 2022.2ND 21.7 21.4
REPORT OF LABORATORY ANALYSIS
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Page 11 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306204
HC-15-002 CHAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/54526
ASTM D2974
ASTM D2974
Dry Weight/Percent Moisture
Associated Lab Samples: 10306204001, 10306204002, 10306204003, 10306204004, 10306204005
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10305246003
1969511SAMPLE DUPLICATE:
Percent Moisture % 0.93 0 300.93
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10306235003
1969533SAMPLE DUPLICATE:
Percent Moisture % 11.7 1 3011.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/21/2015 04:20 PM
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1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 12 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306204
HC-15-002 CHAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/29195
EPA 3550
EPA 8270D by SIM
8270D Solid PAH by SIM MSSV
Associated Lab Samples: 10306204001, 10306204002, 10306204003, 10306204004, 10306204005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1967333
Associated Lab Samples: 10306204001, 10306204002, 10306204003, 10306204004, 10306204005
Matrix: Solid
Analyzed
Acenaphthene mg/kg ND 0.010 05/20/15 02:38
Acenaphthylene mg/kg ND 0.010 05/20/15 02:38
Anthracene mg/kg ND 0.010 05/20/15 02:38
Benzo(a)anthracene mg/kg ND 0.010 05/20/15 02:38
Benzo(a)pyrene mg/kg ND 0.010 05/20/15 02:38
Benzo(b)fluoranthene mg/kg ND 0.010 05/20/15 02:38
Benzo(g,h,i)perylene mg/kg ND 0.010 05/20/15 02:38
Benzo(k)fluoranthene mg/kg ND 0.010 05/20/15 02:38
Chrysene mg/kg ND 0.010 05/20/15 02:38
Dibenz(a,h)anthracene mg/kg ND 0.010 05/20/15 02:38
Fluoranthene mg/kg ND 0.010 05/20/15 02:38
Fluorene mg/kg ND 0.010 05/20/15 02:38
Indeno(1,2,3-cd)pyrene mg/kg ND 0.010 05/20/15 02:38
Naphthalene mg/kg ND 0.010 05/20/15 02:38
Phenanthrene mg/kg ND 0.010 05/20/15 02:38
Pyrene mg/kg ND 0.010 05/20/15 02:38
2-Fluorobiphenyl (S) %. 78 55-125 05/20/15 02:38
p-Terphenyl-d14 (S) %. 96 30-150 05/20/15 02:38
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1967334LABORATORY CONTROL SAMPLE:
LCSSpike
Acenaphthene mg/kg 0.025.033 76 53-125
Acenaphthylene mg/kg 0.026.033 77 53-125
Anthracene mg/kg 0.029.033 86 61-125
Benzo(a)anthracene mg/kg 0.029.033 88 62-125
Benzo(a)pyrene mg/kg 0.032.033 97 64-125
Benzo(b)fluoranthene mg/kg 0.030.033 91 66-125
Benzo(g,h,i)perylene mg/kg 0.031.033 93 59-125
Benzo(k)fluoranthene mg/kg 0.034.033 101 61-125
Chrysene mg/kg 0.029.033 87 63-125
Dibenz(a,h)anthracene mg/kg 0.032.033 97 59-125
Fluoranthene mg/kg 0.030.033 89 64-125
Fluorene mg/kg 0.027.033 82 57-125
Indeno(1,2,3-cd)pyrene mg/kg 0.031.033 93 58-125
Naphthalene mg/kg 0.024.033 72 52-125
Phenanthrene mg/kg 0.025.033 74 60-125
Pyrene mg/kg 0.031.033 93 63-125
2-Fluorobiphenyl (S) %. 79 55-125
p-Terphenyl-d14 (S) %. 95 30-150
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/21/2015 04:20 PM
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1700 Elm Street - Suite 200
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Page 13 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10306204
HC-15-002 CHAH-53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1967335MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
10306204001
1967336
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Acenaphthene mg/kg .036 71 39-12563 12 30.036ND 0.026 0.023
Acenaphthylene mg/kg .036 68 30-15059 14 30.036ND 0.025 0.022
Anthracene mg/kg .036 80 30-15077 4 30.036ND 0.029 0.028
Benzo(a)anthracene mg/kg .036 86 30-15099 15 30.036ND 0.031 0.036
Benzo(a)pyrene mg/kg .036 99 30-150111 11 30.036ND 0.036 0.041
Benzo(b)fluoranthene mg/kg .036 95 30-150126 28 30.036ND 0.035 0.046
Benzo(g,h,i)perylene mg/kg .036 97 30-15099 2 30.036ND 0.036 0.036
Benzo(k)fluoranthene mg/kg .036 98 30-15095 3 30.036ND 0.036 0.035
Chrysene mg/kg .036 85 30-150100 17 30.036ND 0.031 0.037
Dibenz(a,h)anthracene mg/kg .036 91 30-15089 2 30.036ND 0.033 0.032
Fluoranthene mg/kg R1.036 90 30-150132 38 30.036ND 0.033 0.048
Fluorene mg/kg .036 78 30-14670 11 30.036ND 0.028 0.025
Indeno(1,2,3-cd)pyrene mg/kg .036 92 30-15095 4 30.036ND 0.034 0.035
Naphthalene mg/kg .036 64 30-13157 12 30.036ND 0.023 0.021
Phenanthrene mg/kg .036 72 30-15092 24 30.036ND 0.026 0.034
Pyrene mg/kg .036 97 30-150131 30 30.036ND 0.035 0.048
2-Fluorobiphenyl (S) %. 71 55-12571
p-Terphenyl-d14 (S) %. 83 30-15084
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/21/2015 04:20 PM
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Page 14 of 18
#=QL#
QUALIFIERS
Pace Project No.:
Project:
10306204
HC-15-002 CHAH-53
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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Page 15 of 18
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
10306204
HC-15-002 CHAH-53
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
10306204001 MPRP/54373 ICP/23806LGP-26/6-8 EPA 3050 EPA 6010C
10306204002 MPRP/54373 ICP/23806LGP-27/1-3 EPA 3050 EPA 6010C
10306204003 MPRP/54373 ICP/23806LGP-28/2-4 EPA 3050 EPA 6010C
10306204004 MPRP/54373 ICP/23806LGP-29/2-4 EPA 3050 EPA 6010C
10306204005 MPRP/54373 ICP/23806LGP-30/1-3 EPA 3050 EPA 6010C
10306204001 MERP/13552 MERC/15762LGP-26/6-8 EPA 7471B EPA 7471B
10306204002 MERP/13552 MERC/15762LGP-27/1-3 EPA 7471B EPA 7471B
10306204003 MERP/13552 MERC/15762LGP-28/2-4 EPA 7471B EPA 7471B
10306204004 MERP/13552 MERC/15762LGP-29/2-4 EPA 7471B EPA 7471B
10306204005 MERP/13552 MERC/15762LGP-30/1-3 EPA 7471B EPA 7471B
10306204001 MPRP/54526LGP-26/6-8 ASTM D2974
10306204002 MPRP/54526LGP-27/1-3 ASTM D2974
10306204003 MPRP/54526LGP-28/2-4 ASTM D2974
10306204004 MPRP/54526LGP-29/2-4 ASTM D2974
10306204005 MPRP/54526LGP-30/1-3 ASTM D2974
10306204001 OEXT/29195 MSSV/12351LGP-26/6-8 EPA 3550 EPA 8270D by SIM
10306204002 OEXT/29195 MSSV/12351LGP-27/1-3 EPA 3550 EPA 8270D by SIM
10306204003 OEXT/29195 MSSV/12351LGP-28/2-4 EPA 3550 EPA 8270D by SIM
10306204004 OEXT/29195 MSSV/12351LGP-29/2-4 EPA 3550 EPA 8270D by SIM
10306204005 OEXT/29195 MSSV/12351LGP-30/1-3 EPA 3550 EPA 8270D by SIM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/21/2015 04:20 PM
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Page 16 of 18
Page 17 of 18
Page 18 of 18
#=CL#
July 01, 2015
LIMS USE: FR - JERRY MULLIN
LIMS OBJECT ID: 10307337
10307337
Project:
Pace Project No.:
RE:
Mr. Jerry MullinLandmark Environmental2042 West 98th StreetBloomington, MN 55431
HC-15-002 CSAH-53 REV
Dear Mr. Mullin:
Enclosed are the analytical results for sample(s) received by the laboratory on May 21, 2015. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Chris Bremer for
Project Manager
Jessica Patterson
Enclosures
REPORT OF LABORATORY ANALYSIS
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Page 1 of 73
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Minnesota Certification IDs1700 Elm Street SE Suite 200, Minneapolis, MN 55414A2LA Certification #: 2926.01Alaska Certification #: UST-078Alaska Certification #MN00064Alabama Certification #40770Arizona Certification #: AZ-0014Arkansas Certification #: 88-0680California Certification #: 01155CAColorado Certification #PaceConnecticut Certification #: PH-0256EPA Region 8 Certification #: 8TMS-LFlorida/NELAP Certification #: E87605Guam Certification #:14-008rGeorgia Certification #: 959Georgia EPD #: PaceIdaho Certification #: MN00064Hawaii Certification #MN00064Illinois Certification #: 200011Indiana Certification#C-MN-01Iowa Certification #: 368Kansas Certification #: E-10167Kentucky Dept of Envi. Protection - DW #90062Kentucky Dept of Envi. Protection - WW #:90062Louisiana DEQ Certification #: 3086Louisiana DHH #: LA140001Maine Certification #: 2013011Maryland Certification #: 322Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137Mississippi Certification #: PaceMontana Certification #: MT0092Nevada Certification #: MN_00064Nebraska Certification #: PaceNew Jersey Certification #: MN-002New York Certification #: 11647North Carolina Certification #: 530North Carolina State Public Health #: 27700North Dakota Certification #: R-036Ohio EPA #: 4150Ohio VAP Certification #: CL101Oklahoma Certification #: 9507Oregon Certification #: MN200001Oregon Certification #: MN300001Pennsylvania Certification #: 68-00563Puerto Rico CertificationSaipan (CNMI) #:MP0003South Carolina #:74003001Texas Certification #: T104704192Tennessee Certification #: 02818Utah Certification #: MN000642013-4Virginia DGS Certification #: 251Virginia/VELAP Certification #: PaceWashington Certification #: C486West Virginia Certification #: 382West Virginia DHHR #:9952CWisconsin Certification #: 999407970
REPORT OF LABORATORY ANALYSIS
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Page 2 of 73
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Lab ID Sample ID Matrix Date Collected Date Received
10307337001 LPG-31/1-3 Solid 05/19/15 00:00 05/21/15 08:35
10307337002 LPG-32/2-4 Solid 05/19/15 00:00 05/21/15 08:35
10307337003 LPG-33/2-4 Solid 05/19/15 00:00 05/21/15 08:35
10307337004 LPG-34/2-4 Solid 05/19/15 00:00 05/21/15 08:35
10307337005 LPG-35/6-8 Solid 05/19/15 00:00 05/21/15 08:35
10307337006 LPG-36/10-12 Solid 05/19/15 00:00 05/21/15 08:35
10307337007 LPG-36/18-20 Solid 05/19/15 00:00 05/21/15 08:35
10307337008 LPG-37/2-4 Solid 05/19/15 00:00 05/21/15 08:35
10307337009 LPG-38/4-6 Solid 05/19/15 00:00 05/21/15 08:35
10307337010 LPG-39/1-3 Solid 05/20/15 00:00 05/21/15 08:35
10307337011 LPG-40/2-4 Solid 05/20/15 00:00 05/21/15 08:35
10307337012 LPG-41/2-4 Solid 05/20/15 00:00 05/21/15 08:35
10307337013 LPG-41/19-22 Water 05/20/15 00:00 05/21/15 08:35
10307337014 LPG-42/1-3 Solid 05/20/15 00:00 05/21/15 08:35
10307337015 LPG-43/4-6 Solid 05/20/15 00:00 05/21/15 08:35
10307337016 LPG-44/5-7 Solid 05/20/15 00:00 05/21/15 08:35
10307337017 LPG-44/19-22 Water 05/20/15 00:00 05/21/15 08:35
10307337018 LPG-45/8-10 Solid 05/20/15 00:00 05/21/15 08:35
10307337019 LPG-45/12-20 Water 05/20/15 00:00 05/21/15 08:35
10307337020 TRIP BLANK Water 05/21/15 08:35
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 3 of 73
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Lab ID Sample ID Method
Analytes
ReportedAnalysts
10307337001 LPG-31/1-3 EPA 6010C 7DM
EPA 7471B 1DM
ASTM D2974 1JDL
EPA 8270D by SIM 19LT
10307337002 LPG-32/2-4 EPA 6010C 7DM
EPA 7471B 1DM
ASTM D2974 1JDL
EPA 8270D by SIM 19LT
10307337003 LPG-33/2-4 EPA 6010C 7DM
EPA 7471B 1DM
ASTM D2974 1JDL
EPA 8270D by SIM 19LT
10307337004 LPG-34/2-4 EPA 6010C 1DM
EPA 6010C 7DM
EPA 7471B 1DM
ASTM D2974 1JDL
EPA 8270D by SIM 19LT
10307337005 LPG-35/6-8 WI MOD DRO 2JRH
WI MOD GRO 2AEJ
EPA 6010C 7DM
EPA 7471B 1DM
ASTM D2974 1JDL
EPA 8270D by SIM 19LT
EPA 8260B 70AMT
10307337006 LPG-36/10-12 WI MOD DRO 2JRH
WI MOD GRO 2RTP
ASTM D2974 1JDL
EPA 8260B 70AMT
10307337007 LPG-36/18-20 WI MOD DRO 2JRH
WI MOD GRO 2RTP
ASTM D2974 1JDL
EPA 8260B 70AMT
10307337008 LPG-37/2-4 EPA 6010C 7DM
EPA 7471B 1DM
ASTM D2974 1JDL
EPA 8270D by SIM 19LT
10307337009 LPG-38/4-6 EPA 6010C 7DM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 4 of 73
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Lab ID Sample ID Method
Analytes
ReportedAnalysts
EPA 7471B 1DM
ASTM D2974 1JDL
EPA 8270D by SIM 19LT
10307337010 LPG-39/1-3 EPA 6010C 7DM
EPA 7471B 1DM
ASTM D2974 1JDL
EPA 8270D by SIM 19LT
10307337011 LPG-40/2-4 EPA 6010C 7DM
EPA 7471B 1DM
ASTM D2974 1JDL
EPA 8270D by SIM 19LT
10307337012 LPG-41/2-4 EPA 6010C 7DM, WBS
EPA 7471B 1DM
ASTM D2974 1JDL
EPA 8270D by SIM 19LT
10307337013 LPG-41/19-22 WI MOD DRO 2MT
WI MOD GRO 6LPM
EPA 8260B 70AJC
10307337014 LPG-42/1-3 EPA 6010C 7DM, WBS
EPA 7471B 1DM
ASTM D2974 1JDL
EPA 8270D by SIM 19LT
10307337015 LPG-43/4-6 EPA 6010C 7DM, WBS
EPA 7471B 1DM
ASTM D2974 1JDL
EPA 8270D by SIM 19LT
10307337016 LPG-44/5-7 WI MOD DRO 2JRH
WI MOD GRO 2RTP
ASTM D2974 1JDL
EPA 8260B 70LPM
10307337017 LPG-44/19-22 WI MOD DRO 2MT
WI MOD GRO 6LPM
EPA 8260B 70AJC
10307337018 LPG-45/8-10 WI MOD DRO 2JRH
WI MOD GRO 2RTP
EPA 6010C 7DM
EPA 7471B 1DM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 5 of 73
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Lab ID Sample ID Method
Analytes
ReportedAnalysts
ASTM D2974 1JDL
EPA 8270D by SIM 19LT
EPA 8260B 70LPM
10307337019 LPG-45/12-20 WI MOD DRO 2MT
WI MOD GRO 6LPM
EPA 8260B 70AJC
10307337020 TRIP BLANK EPA 8260B 70AJC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 6 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-31/1-3 Lab ID: 10307337001 Collected: 05/19/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 3.3 mg/kg 05/29/15 22:37 7440-38-205/29/15 10:351.2 1
Barium 69.2 mg/kg 05/29/15 22:37 7440-39-305/29/15 10:350.60 1
Cadmium ND mg/kg 05/29/15 22:37 7440-43-905/29/15 10:350.18 1
Chromium 10.3 mg/kg 05/29/15 22:37 7440-47-305/29/15 10:350.60 1
Lead 6.1 mg/kg 05/29/15 22:37 7439-92-105/29/15 10:350.60 1
Selenium ND mg/kg 05/29/15 22:37 7782-49-205/29/15 10:351.2 1
Silver ND mg/kg 05/29/15 22:37 7440-22-405/29/15 10:350.60 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/29/15 15:01 7439-97-605/29/15 08:010.023 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 21.8 % 05/28/15 15:450.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/29/15 01:55 83-32-905/27/15 23:330.013 1
Acenaphthylene ND mg/kg 05/29/15 01:55 208-96-805/27/15 23:330.013 1
Anthracene ND mg/kg 05/29/15 01:55 120-12-705/27/15 23:330.013 1
Benzo(a)anthracene ND mg/kg 05/29/15 01:55 56-55-305/27/15 23:330.013 1
Benzo(a)pyrene ND mg/kg 05/29/15 01:55 50-32-805/27/15 23:330.013 1
Benzo(b)fluoranthene 0.015 mg/kg 05/29/15 01:55 205-99-205/27/15 23:330.013 1
Benzo(g,h,i)perylene ND mg/kg 05/29/15 01:55 191-24-205/27/15 23:330.013 1
Benzo(k)fluoranthene ND mg/kg 05/29/15 01:55 207-08-905/27/15 23:330.013 1
Chrysene ND mg/kg 05/29/15 01:55 218-01-905/27/15 23:330.013 1
Dibenz(a,h)anthracene ND mg/kg 05/29/15 01:55 53-70-305/27/15 23:330.013 1
Fluoranthene 0.020 mg/kg 05/29/15 01:55 206-44-005/27/15 23:330.013 1
Fluorene ND mg/kg 05/29/15 01:55 86-73-705/27/15 23:330.013 1
Indeno(1,2,3-cd)pyrene ND mg/kg 05/29/15 01:55 193-39-505/27/15 23:330.013 1
Naphthalene ND mg/kg 05/29/15 01:55 91-20-305/27/15 23:330.013 1
Phenanthrene ND mg/kg 05/29/15 01:55 85-01-805/27/15 23:330.013 1
Pyrene 0.016 mg/kg 05/29/15 01:55 129-00-005/27/15 23:330.013 1
Total BaP Eq. MN 2006sh. ND=0 ND mg/kg 05/29/15 01:5505/27/15 23:330.013 1
Surrogates2-Fluorobiphenyl (S) 66 %. 05/29/15 01:55 321-60-805/27/15 23:3355-125 1
p-Terphenyl-d14 (S) 71 %. 05/29/15 01:55 1718-51-005/27/15 23:3330-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 7 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-32/2-4 Lab ID: 10307337002 Collected: 05/19/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 2.1 mg/kg 05/29/15 22:57 7440-38-205/29/15 10:351.1 1
Barium 24.7 mg/kg 05/29/15 22:57 7440-39-305/29/15 10:350.53 1
Cadmium ND mg/kg 05/29/15 22:57 7440-43-905/29/15 10:350.16 1
Chromium 7.1 mg/kg 05/29/15 22:57 7440-47-305/29/15 10:350.53 1
Lead 2.3 mg/kg 05/29/15 22:57 7439-92-105/29/15 10:350.53 1
Selenium ND mg/kg 05/29/15 22:57 7782-49-205/29/15 10:351.1 1
Silver ND mg/kg 05/29/15 22:57 7440-22-405/29/15 10:350.53 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/29/15 15:07 7439-97-605/29/15 08:010.021 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 6.5 % 05/28/15 15:450.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/29/15 02:17 83-32-905/27/15 23:330.011 1
Acenaphthylene ND mg/kg 05/29/15 02:17 208-96-805/27/15 23:330.011 1
Anthracene ND mg/kg 05/29/15 02:17 120-12-705/27/15 23:330.011 1
Benzo(a)anthracene ND mg/kg 05/29/15 02:17 56-55-305/27/15 23:330.011 1
Benzo(a)pyrene ND mg/kg 05/29/15 02:17 50-32-805/27/15 23:330.011 1
Benzo(b)fluoranthene ND mg/kg 05/29/15 02:17 205-99-205/27/15 23:330.011 1
Benzo(g,h,i)perylene ND mg/kg 05/29/15 02:17 191-24-205/27/15 23:330.011 1
Benzo(k)fluoranthene ND mg/kg 05/29/15 02:17 207-08-905/27/15 23:330.011 1
Chrysene ND mg/kg 05/29/15 02:17 218-01-905/27/15 23:330.011 1
Dibenz(a,h)anthracene ND mg/kg 05/29/15 02:17 53-70-305/27/15 23:330.011 1
Fluoranthene ND mg/kg 05/29/15 02:17 206-44-005/27/15 23:330.011 1
Fluorene ND mg/kg 05/29/15 02:17 86-73-705/27/15 23:330.011 1
Indeno(1,2,3-cd)pyrene ND mg/kg 05/29/15 02:17 193-39-505/27/15 23:330.011 1
Naphthalene ND mg/kg 05/29/15 02:17 91-20-305/27/15 23:330.011 1
Phenanthrene ND mg/kg 05/29/15 02:17 85-01-805/27/15 23:330.011 1
Pyrene ND mg/kg 05/29/15 02:17 129-00-005/27/15 23:330.011 1
Total BaP Eq. MN 2006sh. ND=0 ND mg/kg 05/29/15 02:1705/27/15 23:330.011 1
Surrogates2-Fluorobiphenyl (S) 58 %. 05/29/15 02:17 321-60-805/27/15 23:3355-125 1
p-Terphenyl-d14 (S) 78 %. 05/29/15 02:17 1718-51-005/27/15 23:3330-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 8 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-33/2-4 Lab ID: 10307337003 Collected: 05/19/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 1.8 mg/kg 05/29/15 23:00 7440-38-205/29/15 10:351.1 1
Barium 16.5 mg/kg 05/29/15 23:00 7440-39-305/29/15 10:350.55 1
Cadmium ND mg/kg 05/29/15 23:00 7440-43-905/29/15 10:350.16 1
Chromium 6.4 mg/kg 05/29/15 23:00 7440-47-305/29/15 10:350.55 1
Lead 2.3 mg/kg 05/29/15 23:00 7439-92-105/29/15 10:350.55 1
Selenium ND mg/kg 05/29/15 23:00 7782-49-205/29/15 10:351.1 1
Silver ND mg/kg 05/29/15 23:00 7440-22-405/29/15 10:350.55 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/29/15 15:09 7439-97-605/29/15 08:010.021 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 9.5 % 05/28/15 16:390.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/29/15 02:38 83-32-905/27/15 23:330.011 1
Acenaphthylene ND mg/kg 05/29/15 02:38 208-96-805/27/15 23:330.011 1
Anthracene ND mg/kg 05/29/15 02:38 120-12-705/27/15 23:330.011 1
Benzo(a)anthracene ND mg/kg 05/29/15 02:38 56-55-305/27/15 23:330.011 1
Benzo(a)pyrene ND mg/kg 05/29/15 02:38 50-32-805/27/15 23:330.011 1
Benzo(b)fluoranthene ND mg/kg 05/29/15 02:38 205-99-205/27/15 23:330.011 1
Benzo(g,h,i)perylene ND mg/kg 05/29/15 02:38 191-24-205/27/15 23:330.011 1
Benzo(k)fluoranthene ND mg/kg 05/29/15 02:38 207-08-905/27/15 23:330.011 1
Chrysene ND mg/kg 05/29/15 02:38 218-01-905/27/15 23:330.011 1
Dibenz(a,h)anthracene ND mg/kg 05/29/15 02:38 53-70-305/27/15 23:330.011 1
Fluoranthene ND mg/kg 05/29/15 02:38 206-44-005/27/15 23:330.011 1
Fluorene ND mg/kg 05/29/15 02:38 86-73-705/27/15 23:330.011 1
Indeno(1,2,3-cd)pyrene ND mg/kg 05/29/15 02:38 193-39-505/27/15 23:330.011 1
Naphthalene ND mg/kg 05/29/15 02:38 91-20-305/27/15 23:330.011 1
Phenanthrene ND mg/kg 05/29/15 02:38 85-01-805/27/15 23:330.011 1
Pyrene ND mg/kg 05/29/15 02:38 129-00-005/27/15 23:330.011 1
Total BaP Eq. MN 2006sh. ND=0 ND mg/kg 05/29/15 02:3805/27/15 23:330.011 1
Surrogates2-Fluorobiphenyl (S) 67 %. 05/29/15 02:38 321-60-805/27/15 23:3355-125 1
p-Terphenyl-d14 (S) 79 %. 05/29/15 02:38 1718-51-005/27/15 23:3330-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 9 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-34/2-4 Lab ID: 10307337004 Collected: 05/19/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 3010
Leachate Method/Date: EPA 1311; 06/25/15 12:03 Initial pH: 8.4; Final pH: 1.73
6010C MET ICP, TCLP
Lead ND mg/L 06/25/15 23:07 7439-92-106/25/15 14:100.050 1
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 1.8 mg/kg 05/29/15 23:03 7440-38-205/29/15 10:351.1 1
Barium 11.9 mg/kg 05/29/15 23:03 7440-39-305/29/15 10:350.56 1
Cadmium ND mg/kg 05/29/15 23:03 7440-43-905/29/15 10:350.17 1
Chromium 4.9 mg/kg 05/29/15 23:03 7440-47-305/29/15 10:350.56 1
Lead 3700 mg/kg 05/29/15 23:03 7439-92-105/29/15 10:350.56 1
Selenium ND mg/kg 05/29/15 23:03 7782-49-205/29/15 10:351.1 1
Silver ND mg/kg 05/29/15 23:03 7440-22-405/29/15 10:350.56 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/29/15 15:11 7439-97-605/29/15 08:010.023 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 19.3 % 05/28/15 16:390.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/28/15 22:19 83-32-905/27/15 23:330.012 1
Acenaphthylene 0.021 mg/kg 05/28/15 22:19 208-96-805/27/15 23:330.012 1
Anthracene 0.014 mg/kg 05/28/15 22:19 120-12-705/27/15 23:330.012 1
Benzo(a)anthracene 0.045 mg/kg 05/28/15 22:19 56-55-305/27/15 23:330.012 1
Benzo(a)pyrene 0.073 mg/kg 05/28/15 22:19 50-32-805/27/15 23:330.012 1
Benzo(b)fluoranthene 0.10 mg/kg 05/28/15 22:19 205-99-205/27/15 23:330.012 1
Benzo(g,h,i)perylene 0.069 mg/kg 05/28/15 22:19 191-24-205/27/15 23:330.012 1
Benzo(k)fluoranthene 0.029 mg/kg 05/28/15 22:19 207-08-905/27/15 23:330.012 1
Chrysene 0.058 mg/kg 05/28/15 22:19 218-01-905/27/15 23:330.012 1
Dibenz(a,h)anthracene ND mg/kg 05/28/15 22:19 53-70-305/27/15 23:330.012 1
Fluoranthene 0.067 mg/kg 05/28/15 22:19 206-44-005/27/15 23:330.012 1
Fluorene ND mg/kg 05/28/15 22:19 86-73-705/27/15 23:330.012 1
Indeno(1,2,3-cd)pyrene 0.045 mg/kg 05/28/15 22:19 193-39-505/27/15 23:330.012 1
Naphthalene ND mg/kg 05/28/15 22:19 91-20-305/27/15 23:330.012 1
Phenanthrene 0.019 mg/kg 05/28/15 22:19 85-01-805/27/15 23:330.012 1
Pyrene 0.073 mg/kg 05/28/15 22:19 129-00-005/27/15 23:330.012 1
Total BaP Eq. MN 2006sh. ND=0 0.095 mg/kg 05/28/15 22:1905/27/15 23:330.012 1
Surrogates2-Fluorobiphenyl (S) 74 %. 05/28/15 22:19 321-60-805/27/15 23:3355-125 1
p-Terphenyl-d14 (S) 79 %. 05/28/15 22:19 1718-51-005/27/15 23:3330-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 10 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-35/6-8 Lab ID: 10307337005 Collected: 05/19/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: WI MOD DRO Preparation Method: WI MOD DROWIDRO GCS Silica Gel
WDRO C10-C28 13.5 mg/kg 05/29/15 10:35 T605/28/15 17:105.1 1
Surrogatesn-Triacontane (S) 91 %. 05/29/15 10:35 638-68-605/28/15 17:1030-143 1
Analytical Method: WI MOD GRO Preparation Method: EPA 5030 Medium SoilWIGRO GCV
Gasoline Range Organics ND mg/kg 05/28/15 18:1905/27/15 15:5913.4 1
Surrogatesa,a,a-Trifluorotoluene (S) 108 %. 05/28/15 18:19 98-08-805/27/15 15:5980-150 1
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 3.5 mg/kg 05/29/15 23:06 7440-38-205/29/15 10:351.2 1
Barium 91.6 mg/kg 05/29/15 23:06 7440-39-305/29/15 10:350.62 1
Cadmium 0.21 mg/kg 05/29/15 23:06 7440-43-905/29/15 10:350.19 1
Chromium 9.6 mg/kg 05/29/15 23:06 7440-47-305/29/15 10:350.62 1
Lead 17.9 mg/kg 05/29/15 23:06 7439-92-105/29/15 10:350.62 1
Selenium ND mg/kg 05/29/15 23:06 7782-49-205/29/15 10:351.2 1
Silver ND mg/kg 05/29/15 23:06 7440-22-405/29/15 10:350.62 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury 0.035 mg/kg 05/29/15 15:13 7439-97-605/29/15 08:010.023 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 24.5 % 05/28/15 16:390.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene 0.015 mg/kg 05/28/15 22:40 83-32-905/27/15 23:330.013 1
Acenaphthylene 0.11 mg/kg 05/28/15 22:40 208-96-805/27/15 23:330.013 1
Anthracene 0.11 mg/kg 05/28/15 22:40 120-12-705/27/15 23:330.013 1
Benzo(a)anthracene 0.43 mg/kg 05/28/15 22:40 56-55-305/27/15 23:330.013 1
Benzo(a)pyrene 0.52 mg/kg 05/29/15 10:06 50-32-805/27/15 23:330.066 5
Benzo(b)fluoranthene 0.71 mg/kg 05/29/15 10:06 205-99-205/27/15 23:330.066 5
Benzo(g,h,i)perylene 0.37 mg/kg 05/28/15 22:40 191-24-205/27/15 23:330.013 1
Benzo(k)fluoranthene 0.23 mg/kg 05/28/15 22:40 207-08-905/27/15 23:330.013 1
Chrysene 0.53 mg/kg 05/29/15 10:06 218-01-905/27/15 23:330.066 5
Dibenz(a,h)anthracene ND mg/kg 05/28/15 22:40 53-70-305/27/15 23:330.013 1
Fluoranthene 0.82 mg/kg 05/29/15 10:06 206-44-005/27/15 23:330.066 5
Fluorene 0.027 mg/kg 05/28/15 22:40 86-73-705/27/15 23:330.013 1
Indeno(1,2,3-cd)pyrene 0.30 mg/kg 05/28/15 22:40 193-39-505/27/15 23:330.013 1
Naphthalene ND mg/kg 05/28/15 22:40 91-20-305/27/15 23:330.013 1
Phenanthrene 0.29 mg/kg 05/28/15 22:40 85-01-805/27/15 23:330.013 1
Pyrene 0.86 mg/kg 05/29/15 10:06 129-00-005/27/15 23:330.066 5
Total BaP Eq. MN 2006sh. ND=0 0.69 mg/kg 05/29/15 10:0605/27/15 23:330.066 5
Surrogates2-Fluorobiphenyl (S) 63 %. 05/28/15 22:40 321-60-805/27/15 23:3355-125 1
p-Terphenyl-d14 (S) 63 %. 05/28/15 22:40 1718-51-005/27/15 23:3330-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 11 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-35/6-8 Lab ID: 10307337005 Collected: 05/19/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
Acetone ND mg/kg 05/29/15 16:28 67-64-105/29/15 10:181.3 1
Allyl chloride ND mg/kg 05/29/15 16:28 107-05-105/29/15 10:180.26 1
Benzene ND mg/kg 05/29/15 16:28 71-43-205/29/15 10:180.026 1
Bromobenzene ND mg/kg 05/29/15 16:28 108-86-105/29/15 10:180.064 1
Bromochloromethane ND mg/kg 05/29/15 16:28 74-97-505/29/15 10:180.064 1
Bromodichloromethane ND mg/kg 05/29/15 16:28 75-27-405/29/15 10:180.064 1
Bromoform ND mg/kg 05/29/15 16:28 75-25-205/29/15 10:180.26 1
Bromomethane ND mg/kg 05/29/15 16:28 74-83-905/29/15 10:180.64 1
2-Butanone (MEK) ND mg/kg 05/29/15 16:28 78-93-305/29/15 10:180.32 1
n-Butylbenzene ND mg/kg 05/29/15 16:28 104-51-805/29/15 10:180.064 1
sec-Butylbenzene ND mg/kg 05/29/15 16:28 135-98-805/29/15 10:180.064 1
tert-Butylbenzene ND mg/kg 05/29/15 16:28 98-06-605/29/15 10:180.064 1
Carbon tetrachloride ND mg/kg 05/29/15 16:28 56-23-505/29/15 10:180.064 1
Chlorobenzene ND mg/kg 05/29/15 16:28 108-90-705/29/15 10:180.064 1
Chloroethane ND mg/kg 05/29/15 16:28 75-00-305/29/15 10:180.64 1
Chloroform ND mg/kg 05/29/15 16:28 67-66-305/29/15 10:180.064 1
Chloromethane ND mg/kg 05/29/15 16:28 74-87-305/29/15 10:180.26 1
2-Chlorotoluene ND mg/kg 05/29/15 16:28 95-49-805/29/15 10:180.064 1
4-Chlorotoluene ND mg/kg 05/29/15 16:28 106-43-405/29/15 10:180.064 1
1,2-Dibromo-3-chloropropane ND mg/kg 05/29/15 16:28 96-12-805/29/15 10:180.64 1
Dibromochloromethane ND mg/kg 05/29/15 16:28 124-48-105/29/15 10:180.064 1
1,2-Dibromoethane (EDB) ND mg/kg 05/29/15 16:28 106-93-405/29/15 10:180.064 1
Dibromomethane ND mg/kg 05/29/15 16:28 74-95-305/29/15 10:180.064 1
1,2-Dichlorobenzene ND mg/kg 05/29/15 16:28 95-50-105/29/15 10:180.064 1
1,3-Dichlorobenzene ND mg/kg 05/29/15 16:28 541-73-105/29/15 10:180.064 1
1,4-Dichlorobenzene ND mg/kg 05/29/15 16:28 106-46-705/29/15 10:180.064 1
Dichlorodifluoromethane ND mg/kg 05/29/15 16:28 75-71-805/29/15 10:180.26 1
1,1-Dichloroethane ND mg/kg 05/29/15 16:28 75-34-305/29/15 10:180.064 1
1,2-Dichloroethane ND mg/kg 05/29/15 16:28 107-06-205/29/15 10:180.064 1
1,1-Dichloroethene ND mg/kg 05/29/15 16:28 75-35-405/29/15 10:180.064 1
cis-1,2-Dichloroethene ND mg/kg 05/29/15 16:28 156-59-205/29/15 10:180.064 1
trans-1,2-Dichloroethene ND mg/kg 05/29/15 16:28 156-60-505/29/15 10:180.064 1
Dichlorofluoromethane ND mg/kg 05/29/15 16:28 75-43-405/29/15 10:180.64 1
1,2-Dichloropropane ND mg/kg 05/29/15 16:28 78-87-505/29/15 10:180.064 1
1,3-Dichloropropane ND mg/kg 05/29/15 16:28 142-28-905/29/15 10:180.064 1
2,2-Dichloropropane ND mg/kg 05/29/15 16:28 594-20-705/29/15 10:180.26 1
1,1-Dichloropropene ND mg/kg 05/29/15 16:28 563-58-605/29/15 10:180.064 1
cis-1,3-Dichloropropene ND mg/kg 05/29/15 16:28 10061-01-505/29/15 10:180.064 1
trans-1,3-Dichloropropene ND mg/kg 05/29/15 16:28 10061-02-605/29/15 10:180.064 1
Diethyl ether (Ethyl ether) ND mg/kg 05/29/15 16:28 60-29-705/29/15 10:180.26 1
Ethylbenzene ND mg/kg 05/29/15 16:28 100-41-405/29/15 10:180.064 1
Hexachloro-1,3-butadiene ND mg/kg 05/29/15 16:28 87-68-305/29/15 10:180.32 1
Isopropylbenzene (Cumene) ND mg/kg 05/29/15 16:28 98-82-805/29/15 10:180.064 1
p-Isopropyltoluene ND mg/kg 05/29/15 16:28 99-87-605/29/15 10:180.064 1
Methylene Chloride ND mg/kg 05/29/15 16:28 75-09-205/29/15 10:180.26 1
4-Methyl-2-pentanone (MIBK) ND mg/kg 05/29/15 16:28 108-10-105/29/15 10:180.32 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 12 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-35/6-8 Lab ID: 10307337005 Collected: 05/19/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
Methyl-tert-butyl ether ND mg/kg 05/29/15 16:28 1634-04-405/29/15 10:180.064 1
Naphthalene ND mg/kg 05/29/15 16:28 91-20-305/29/15 10:180.26 1
n-Propylbenzene ND mg/kg 05/29/15 16:28 103-65-105/29/15 10:180.064 1
Styrene ND mg/kg 05/29/15 16:28 100-42-505/29/15 10:180.064 1
1,1,1,2-Tetrachloroethane ND mg/kg 05/29/15 16:28 630-20-605/29/15 10:180.064 1
1,1,2,2-Tetrachloroethane ND mg/kg 05/29/15 16:28 79-34-505/29/15 10:180.064 1
Tetrachloroethene ND mg/kg 05/29/15 16:28 127-18-405/29/15 10:180.064 1
Tetrahydrofuran ND mg/kg 05/29/15 16:28 109-99-905/29/15 10:182.6 1
Toluene ND mg/kg 05/29/15 16:28 108-88-305/29/15 10:180.064 1
1,2,3-Trichlorobenzene ND mg/kg 05/29/15 16:28 87-61-605/29/15 10:180.064 1
1,2,4-Trichlorobenzene ND mg/kg 05/29/15 16:28 120-82-105/29/15 10:180.064 1
1,1,1-Trichloroethane ND mg/kg 05/29/15 16:28 71-55-605/29/15 10:180.064 1
1,1,2-Trichloroethane ND mg/kg 05/29/15 16:28 79-00-505/29/15 10:180.064 1
Trichloroethene ND mg/kg 05/29/15 16:28 79-01-605/29/15 10:180.064 1
Trichlorofluoromethane ND mg/kg 05/29/15 16:28 75-69-405/29/15 10:180.26 1
1,2,3-Trichloropropane ND mg/kg 05/29/15 16:28 96-18-405/29/15 10:180.26 1
1,1,2-Trichlorotrifluoroethane ND mg/kg 05/29/15 16:28 76-13-105/29/15 10:180.26 1
1,2,4-Trimethylbenzene ND mg/kg 05/29/15 16:28 95-63-605/29/15 10:180.064 1
1,3,5-Trimethylbenzene ND mg/kg 05/29/15 16:28 108-67-805/29/15 10:180.064 1
Vinyl chloride ND mg/kg 05/29/15 16:28 75-01-405/29/15 10:180.026 1
Xylene (Total) ND mg/kg 05/29/15 16:28 1330-20-705/29/15 10:180.19 1
Surrogates1,2-Dichloroethane-d4 (S) 100 %. 05/29/15 16:28 17060-07-005/29/15 10:1855-150 1
Toluene-d8 (S) 99 %. 05/29/15 16:28 2037-26-505/29/15 10:1861-125 1
4-Bromofluorobenzene (S) 101 %. 05/29/15 16:28 460-00-405/29/15 10:1854-131 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 13 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-36/10-12 Lab ID: 10307337006 Collected: 05/19/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: WI MOD DRO Preparation Method: WI MOD DROWIDRO GCS Silica Gel
WDRO C10-C28 92.9 mg/kg 05/29/15 12:0005/28/15 17:107.7 2
Surrogatesn-Triacontane (S) 80 %. 05/29/15 12:00 638-68-605/28/15 17:1030-143 2
Analytical Method: WI MOD GRO Preparation Method: EPA 5030 Medium SoilWIGRO GCV
Gasoline Range Organics 521 mg/kg 05/29/15 09:5705/27/15 15:5923.5 2
Surrogatesa,a,a-Trifluorotoluene (S) 34 %. 05/29/15 09:57 98-08-8 S205/27/15 15:5980-150 2
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 12.9 % 05/28/15 16:400.10 1
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
Acetone ND mg/kg 05/29/15 16:46 67-64-105/29/15 10:181.1 1
Allyl chloride ND mg/kg 05/29/15 16:46 107-05-105/29/15 10:180.23 1
Benzene ND mg/kg 05/29/15 16:46 71-43-205/29/15 10:180.023 1
Bromobenzene ND mg/kg 05/29/15 16:46 108-86-105/29/15 10:180.056 1
Bromochloromethane ND mg/kg 05/29/15 16:46 74-97-505/29/15 10:180.056 1
Bromodichloromethane ND mg/kg 05/29/15 16:46 75-27-405/29/15 10:180.056 1
Bromoform ND mg/kg 05/29/15 16:46 75-25-205/29/15 10:180.23 1
Bromomethane ND mg/kg 05/29/15 16:46 74-83-905/29/15 10:180.56 1
2-Butanone (MEK) ND mg/kg 05/29/15 16:46 78-93-305/29/15 10:180.28 1
n-Butylbenzene ND mg/kg 05/29/15 16:46 104-51-805/29/15 10:180.056 1
sec-Butylbenzene 0.87 mg/kg 05/29/15 16:46 135-98-805/29/15 10:180.056 1
tert-Butylbenzene ND mg/kg 05/29/15 16:46 98-06-605/29/15 10:180.056 1
Carbon tetrachloride ND mg/kg 05/29/15 16:46 56-23-505/29/15 10:180.056 1
Chlorobenzene ND mg/kg 05/29/15 16:46 108-90-705/29/15 10:180.056 1
Chloroethane ND mg/kg 05/29/15 16:46 75-00-305/29/15 10:180.56 1
Chloroform ND mg/kg 05/29/15 16:46 67-66-305/29/15 10:180.056 1
Chloromethane ND mg/kg 05/29/15 16:46 74-87-305/29/15 10:180.23 1
2-Chlorotoluene ND mg/kg 05/29/15 16:46 95-49-805/29/15 10:180.056 1
4-Chlorotoluene ND mg/kg 05/29/15 16:46 106-43-405/29/15 10:180.056 1
1,2-Dibromo-3-chloropropane ND mg/kg 05/29/15 16:46 96-12-805/29/15 10:180.56 1
Dibromochloromethane ND mg/kg 05/29/15 16:46 124-48-105/29/15 10:180.056 1
1,2-Dibromoethane (EDB) ND mg/kg 05/29/15 16:46 106-93-405/29/15 10:180.056 1
Dibromomethane ND mg/kg 05/29/15 16:46 74-95-305/29/15 10:180.056 1
1,2-Dichlorobenzene ND mg/kg 05/29/15 16:46 95-50-105/29/15 10:180.056 1
1,3-Dichlorobenzene ND mg/kg 05/29/15 16:46 541-73-105/29/15 10:180.056 1
1,4-Dichlorobenzene ND mg/kg 05/29/15 16:46 106-46-705/29/15 10:180.056 1
Dichlorodifluoromethane ND mg/kg 05/29/15 16:46 75-71-805/29/15 10:180.23 1
1,1-Dichloroethane ND mg/kg 05/29/15 16:46 75-34-305/29/15 10:180.056 1
1,2-Dichloroethane ND mg/kg 05/29/15 16:46 107-06-205/29/15 10:180.056 1
1,1-Dichloroethene ND mg/kg 05/29/15 16:46 75-35-405/29/15 10:180.056 1
cis-1,2-Dichloroethene ND mg/kg 05/29/15 16:46 156-59-205/29/15 10:180.056 1
trans-1,2-Dichloroethene ND mg/kg 05/29/15 16:46 156-60-505/29/15 10:180.056 1
Dichlorofluoromethane ND mg/kg 05/29/15 16:46 75-43-405/29/15 10:180.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 14 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-36/10-12 Lab ID: 10307337006 Collected: 05/19/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
1,2-Dichloropropane ND mg/kg 05/29/15 16:46 78-87-505/29/15 10:180.056 1
1,3-Dichloropropane ND mg/kg 05/29/15 16:46 142-28-905/29/15 10:180.056 1
2,2-Dichloropropane ND mg/kg 05/29/15 16:46 594-20-705/29/15 10:180.23 1
1,1-Dichloropropene ND mg/kg 05/29/15 16:46 563-58-605/29/15 10:180.056 1
cis-1,3-Dichloropropene ND mg/kg 05/29/15 16:46 10061-01-505/29/15 10:180.056 1
trans-1,3-Dichloropropene ND mg/kg 05/29/15 16:46 10061-02-605/29/15 10:180.056 1
Diethyl ether (Ethyl ether) ND mg/kg 05/29/15 16:46 60-29-705/29/15 10:180.23 1
Ethylbenzene 2.1 mg/kg 05/29/15 16:46 100-41-405/29/15 10:180.056 1
Hexachloro-1,3-butadiene ND mg/kg 05/29/15 16:46 87-68-305/29/15 10:180.28 1
Isopropylbenzene (Cumene) 0.86 mg/kg 05/29/15 16:46 98-82-805/29/15 10:180.056 1
p-Isopropyltoluene ND mg/kg 05/29/15 16:46 99-87-605/29/15 10:180.056 1
Methylene Chloride ND mg/kg 05/29/15 16:46 75-09-205/29/15 10:180.23 1
4-Methyl-2-pentanone (MIBK) ND mg/kg 05/29/15 16:46 108-10-105/29/15 10:180.28 1
Methyl-tert-butyl ether ND mg/kg 05/29/15 16:46 1634-04-405/29/15 10:180.056 1
Naphthalene 6.2 mg/kg 05/29/15 16:46 91-20-305/29/15 10:180.23 1
n-Propylbenzene 2.4 mg/kg 05/29/15 16:46 103-65-105/29/15 10:180.056 1
Styrene ND mg/kg 05/29/15 16:46 100-42-505/29/15 10:180.056 1
1,1,1,2-Tetrachloroethane ND mg/kg 05/29/15 16:46 630-20-605/29/15 10:180.056 1
1,1,2,2-Tetrachloroethane ND mg/kg 05/29/15 16:46 79-34-505/29/15 10:180.056 1
Tetrachloroethene ND mg/kg 05/29/15 16:46 127-18-405/29/15 10:180.056 1
Tetrahydrofuran ND mg/kg 05/29/15 16:46 109-99-905/29/15 10:182.3 1
Toluene 0.18 mg/kg 05/29/15 16:46 108-88-305/29/15 10:180.056 1
1,2,3-Trichlorobenzene ND mg/kg 05/29/15 16:46 87-61-605/29/15 10:180.056 1
1,2,4-Trichlorobenzene ND mg/kg 05/29/15 16:46 120-82-105/29/15 10:180.056 1
1,1,1-Trichloroethane ND mg/kg 05/29/15 16:46 71-55-605/29/15 10:180.056 1
1,1,2-Trichloroethane ND mg/kg 05/29/15 16:46 79-00-505/29/15 10:180.056 1
Trichloroethene ND mg/kg 05/29/15 16:46 79-01-605/29/15 10:180.056 1
Trichlorofluoromethane ND mg/kg 05/29/15 16:46 75-69-405/29/15 10:180.23 1
1,2,3-Trichloropropane ND mg/kg 05/29/15 16:46 96-18-405/29/15 10:180.23 1
1,1,2-Trichlorotrifluoroethane ND mg/kg 05/29/15 16:46 76-13-105/29/15 10:180.23 1
1,2,4-Trimethylbenzene 28.0 mg/kg 06/01/15 22:35 95-63-605/29/15 10:180.56 10
1,3,5-Trimethylbenzene 10.8 mg/kg 05/29/15 16:46 108-67-805/29/15 10:180.056 1
Vinyl chloride ND mg/kg 05/29/15 16:46 75-01-405/29/15 10:180.023 1
Xylene (Total) 23.2 mg/kg 05/29/15 16:46 1330-20-705/29/15 10:180.17 1
Surrogates1,2-Dichloroethane-d4 (S) 98 %. 05/29/15 16:46 17060-07-005/29/15 10:1855-150 1
Toluene-d8 (S) 112 %. 05/29/15 16:46 2037-26-505/29/15 10:1861-125 1
4-Bromofluorobenzene (S) 128 %. 05/29/15 16:46 460-00-405/29/15 10:1854-131 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 15 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-36/18-20 Lab ID: 10307337007 Collected: 05/19/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: WI MOD DRO Preparation Method: WI MOD DROWIDRO GCS Silica Gel
WDRO C10-C28 ND mg/kg 05/29/15 11:0605/28/15 17:106.7 1
Surrogatesn-Triacontane (S) 88 %. 05/29/15 11:06 638-68-605/28/15 17:1030-143 1
Analytical Method: WI MOD GRO Preparation Method: EPA 5030 Medium SoilWIGRO GCV
Gasoline Range Organics ND mg/kg 05/29/15 16:3305/27/15 15:5911.8 1
Surrogatesa,a,a-Trifluorotoluene (S) 101 %. 05/29/15 16:33 98-08-805/27/15 15:5980-150 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 14.5 % 05/28/15 16:400.10 1
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
Acetone ND mg/kg 05/31/15 22:47 67-64-105/29/15 10:181.2 1
Allyl chloride ND mg/kg 05/31/15 22:47 107-05-105/29/15 10:180.23 1
Benzene ND mg/kg 05/31/15 22:47 71-43-205/29/15 10:180.023 1
Bromobenzene ND mg/kg 05/31/15 22:47 108-86-105/29/15 10:180.059 1
Bromochloromethane ND mg/kg 05/31/15 22:47 74-97-505/29/15 10:180.059 1
Bromodichloromethane ND mg/kg 05/31/15 22:47 75-27-405/29/15 10:180.059 1
Bromoform ND mg/kg 05/31/15 22:47 75-25-205/29/15 10:180.23 1
Bromomethane ND mg/kg 05/31/15 22:47 74-83-905/29/15 10:180.59 1
2-Butanone (MEK) ND mg/kg 05/31/15 22:47 78-93-305/29/15 10:180.29 1
n-Butylbenzene ND mg/kg 05/31/15 22:47 104-51-805/29/15 10:180.059 1
sec-Butylbenzene ND mg/kg 05/31/15 22:47 135-98-805/29/15 10:180.059 1
tert-Butylbenzene ND mg/kg 05/31/15 22:47 98-06-605/29/15 10:180.059 1
Carbon tetrachloride ND mg/kg 05/31/15 22:47 56-23-505/29/15 10:180.059 1
Chlorobenzene ND mg/kg 05/31/15 22:47 108-90-705/29/15 10:180.059 1
Chloroethane ND mg/kg 05/31/15 22:47 75-00-305/29/15 10:180.59 1
Chloroform ND mg/kg 05/31/15 22:47 67-66-305/29/15 10:180.059 1
Chloromethane ND mg/kg 05/31/15 22:47 74-87-305/29/15 10:180.23 1
2-Chlorotoluene ND mg/kg 05/31/15 22:47 95-49-805/29/15 10:180.059 1
4-Chlorotoluene ND mg/kg 05/31/15 22:47 106-43-405/29/15 10:180.059 1
1,2-Dibromo-3-chloropropane ND mg/kg 05/31/15 22:47 96-12-805/29/15 10:180.59 1
Dibromochloromethane ND mg/kg 05/31/15 22:47 124-48-105/29/15 10:180.059 1
1,2-Dibromoethane (EDB) ND mg/kg 05/31/15 22:47 106-93-405/29/15 10:180.059 1
Dibromomethane ND mg/kg 05/31/15 22:47 74-95-305/29/15 10:180.059 1
1,2-Dichlorobenzene ND mg/kg 05/31/15 22:47 95-50-105/29/15 10:180.059 1
1,3-Dichlorobenzene ND mg/kg 05/31/15 22:47 541-73-105/29/15 10:180.059 1
1,4-Dichlorobenzene ND mg/kg 05/31/15 22:47 106-46-705/29/15 10:180.059 1
Dichlorodifluoromethane ND mg/kg 05/31/15 22:47 75-71-805/29/15 10:180.23 1
1,1-Dichloroethane ND mg/kg 05/31/15 22:47 75-34-305/29/15 10:180.059 1
1,2-Dichloroethane ND mg/kg 05/31/15 22:47 107-06-205/29/15 10:180.059 1
1,1-Dichloroethene ND mg/kg 05/31/15 22:47 75-35-405/29/15 10:180.059 1
cis-1,2-Dichloroethene ND mg/kg 05/31/15 22:47 156-59-205/29/15 10:180.059 1
trans-1,2-Dichloroethene ND mg/kg 05/31/15 22:47 156-60-505/29/15 10:180.059 1
Dichlorofluoromethane ND mg/kg 05/31/15 22:47 75-43-405/29/15 10:180.59 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 16 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-36/18-20 Lab ID: 10307337007 Collected: 05/19/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
1,2-Dichloropropane ND mg/kg 05/31/15 22:47 78-87-505/29/15 10:180.059 1
1,3-Dichloropropane ND mg/kg 05/31/15 22:47 142-28-905/29/15 10:180.059 1
2,2-Dichloropropane ND mg/kg 05/31/15 22:47 594-20-705/29/15 10:180.23 1
1,1-Dichloropropene ND mg/kg 05/31/15 22:47 563-58-605/29/15 10:180.059 1
cis-1,3-Dichloropropene ND mg/kg 05/31/15 22:47 10061-01-505/29/15 10:180.059 1
trans-1,3-Dichloropropene ND mg/kg 05/31/15 22:47 10061-02-605/29/15 10:180.059 1
Diethyl ether (Ethyl ether) ND mg/kg 05/31/15 22:47 60-29-705/29/15 10:180.23 1
Ethylbenzene ND mg/kg 05/31/15 22:47 100-41-405/29/15 10:180.059 1
Hexachloro-1,3-butadiene ND mg/kg 05/31/15 22:47 87-68-305/29/15 10:180.29 1
Isopropylbenzene (Cumene) ND mg/kg 05/31/15 22:47 98-82-805/29/15 10:180.059 1
p-Isopropyltoluene ND mg/kg 05/31/15 22:47 99-87-605/29/15 10:180.059 1
Methylene Chloride ND mg/kg 05/31/15 22:47 75-09-205/29/15 10:180.23 1
4-Methyl-2-pentanone (MIBK) ND mg/kg 05/31/15 22:47 108-10-105/29/15 10:180.29 1
Methyl-tert-butyl ether ND mg/kg 05/31/15 22:47 1634-04-405/29/15 10:180.059 1
Naphthalene ND mg/kg 05/31/15 22:47 91-20-305/29/15 10:180.23 1
n-Propylbenzene ND mg/kg 05/31/15 22:47 103-65-105/29/15 10:180.059 1
Styrene ND mg/kg 05/31/15 22:47 100-42-505/29/15 10:180.059 1
1,1,1,2-Tetrachloroethane ND mg/kg 05/31/15 22:47 630-20-605/29/15 10:180.059 1
1,1,2,2-Tetrachloroethane ND mg/kg 05/31/15 22:47 79-34-505/29/15 10:180.059 1
Tetrachloroethene ND mg/kg 05/31/15 22:47 127-18-405/29/15 10:180.059 1
Tetrahydrofuran ND mg/kg 05/31/15 22:47 109-99-905/29/15 10:182.3 1
Toluene ND mg/kg 05/31/15 22:47 108-88-305/29/15 10:180.059 1
1,2,3-Trichlorobenzene ND mg/kg 05/31/15 22:47 87-61-605/29/15 10:180.059 1
1,2,4-Trichlorobenzene ND mg/kg 05/31/15 22:47 120-82-105/29/15 10:180.059 1
1,1,1-Trichloroethane ND mg/kg 05/31/15 22:47 71-55-605/29/15 10:180.059 1
1,1,2-Trichloroethane ND mg/kg 05/31/15 22:47 79-00-505/29/15 10:180.059 1
Trichloroethene ND mg/kg 05/31/15 22:47 79-01-605/29/15 10:180.059 1
Trichlorofluoromethane ND mg/kg 05/31/15 22:47 75-69-405/29/15 10:180.23 1
1,2,3-Trichloropropane ND mg/kg 05/31/15 22:47 96-18-405/29/15 10:180.23 1
1,1,2-Trichlorotrifluoroethane ND mg/kg 05/31/15 22:47 76-13-105/29/15 10:180.23 1
1,2,4-Trimethylbenzene ND mg/kg 05/31/15 22:47 95-63-605/29/15 10:180.059 1
1,3,5-Trimethylbenzene ND mg/kg 05/31/15 22:47 108-67-805/29/15 10:180.059 1
Vinyl chloride ND mg/kg 05/31/15 22:47 75-01-405/29/15 10:180.023 1
Xylene (Total) ND mg/kg 05/31/15 22:47 1330-20-705/29/15 10:180.18 1
Surrogates1,2-Dichloroethane-d4 (S) 65 %. 05/31/15 22:47 17060-07-005/29/15 10:1855-150 1
Toluene-d8 (S) 65 %. 05/31/15 22:47 2037-26-505/29/15 10:1861-125 1
4-Bromofluorobenzene (S) 67 %. 05/31/15 22:47 460-00-405/29/15 10:1854-131 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 17 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-37/2-4 Lab ID: 10307337008 Collected: 05/19/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 2.7 mg/kg 05/29/15 23:09 7440-38-205/29/15 10:350.99 1
Barium 62.2 mg/kg 05/29/15 23:09 7440-39-305/29/15 10:350.50 1
Cadmium ND mg/kg 05/29/15 23:09 7440-43-905/29/15 10:350.15 1
Chromium 8.4 mg/kg 05/29/15 23:09 7440-47-305/29/15 10:350.50 1
Lead 5.4 mg/kg 05/29/15 23:09 7439-92-105/29/15 10:350.50 1
Selenium ND mg/kg 05/29/15 23:09 7782-49-205/29/15 10:350.99 1
Silver ND mg/kg 05/29/15 23:09 7440-22-405/29/15 10:350.50 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/29/15 15:20 7439-97-605/29/15 08:010.020 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 9.8 % 05/28/15 16:400.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/29/15 08:40 83-32-905/27/15 23:330.011 1
Acenaphthylene 0.012 mg/kg 05/29/15 08:40 208-96-805/27/15 23:330.011 1
Anthracene 0.015 mg/kg 05/29/15 08:40 120-12-705/27/15 23:330.011 1
Benzo(a)anthracene 0.037 mg/kg 05/29/15 08:40 56-55-305/27/15 23:330.011 1
Benzo(a)pyrene 0.047 mg/kg 05/29/15 08:40 50-32-805/27/15 23:330.011 1
Benzo(b)fluoranthene 0.063 mg/kg 05/29/15 08:40 205-99-205/27/15 23:330.011 1
Benzo(g,h,i)perylene 0.048 mg/kg 05/29/15 08:40 191-24-205/27/15 23:330.011 1
Benzo(k)fluoranthene 0.020 mg/kg 05/29/15 08:40 207-08-905/27/15 23:330.011 1
Chrysene 0.042 mg/kg 05/29/15 08:40 218-01-905/27/15 23:330.011 1
Dibenz(a,h)anthracene ND mg/kg 05/29/15 08:40 53-70-305/27/15 23:330.011 1
Fluoranthene 0.067 mg/kg 05/29/15 08:40 206-44-005/27/15 23:330.011 1
Fluorene ND mg/kg 05/29/15 08:40 86-73-705/27/15 23:330.011 1
Indeno(1,2,3-cd)pyrene 0.026 mg/kg 05/29/15 08:40 193-39-505/27/15 23:330.011 1
Naphthalene ND mg/kg 05/29/15 08:40 91-20-305/27/15 23:330.011 1
Phenanthrene 0.034 mg/kg 05/29/15 08:40 85-01-805/27/15 23:330.011 1
Pyrene 0.073 mg/kg 05/29/15 08:40 129-00-005/27/15 23:330.011 1
Total BaP Eq. MN 2006sh. ND=0 0.062 mg/kg 05/29/15 08:4005/27/15 23:330.011 1
Surrogates2-Fluorobiphenyl (S) 69 %. 05/29/15 08:40 321-60-805/27/15 23:3355-125 1
p-Terphenyl-d14 (S) 73 %. 05/29/15 08:40 1718-51-005/27/15 23:3330-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 18 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-38/4-6 Lab ID: 10307337009 Collected: 05/19/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 1.3 mg/kg 05/29/15 23:12 7440-38-205/29/15 10:351.0 1
Barium 32.3 mg/kg 05/29/15 23:12 7440-39-305/29/15 10:350.51 1
Cadmium ND mg/kg 05/29/15 23:12 7440-43-905/29/15 10:350.15 1
Chromium 4.9 mg/kg 05/29/15 23:12 7440-47-305/29/15 10:350.51 1
Lead 2.7 mg/kg 05/29/15 23:12 7439-92-105/29/15 10:350.51 1
Selenium ND mg/kg 05/29/15 23:12 7782-49-205/29/15 10:351.0 1
Silver ND mg/kg 05/29/15 23:12 7440-22-405/29/15 10:350.51 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/29/15 15:22 7439-97-605/29/15 08:010.022 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 10.8 % 05/28/15 16:400.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/29/15 00:28 83-32-905/27/15 23:330.011 1
Acenaphthylene ND mg/kg 05/29/15 00:28 208-96-805/27/15 23:330.011 1
Anthracene ND mg/kg 05/29/15 00:28 120-12-705/27/15 23:330.011 1
Benzo(a)anthracene 0.015 mg/kg 05/29/15 00:28 56-55-305/27/15 23:330.011 1
Benzo(a)pyrene 0.018 mg/kg 05/29/15 00:28 50-32-805/27/15 23:330.011 1
Benzo(b)fluoranthene 0.029 mg/kg 05/29/15 00:28 205-99-205/27/15 23:330.011 1
Benzo(g,h,i)perylene 0.015 mg/kg 05/29/15 00:28 191-24-205/27/15 23:330.011 1
Benzo(k)fluoranthene ND mg/kg 05/29/15 00:28 207-08-905/27/15 23:330.011 1
Chrysene 0.021 mg/kg 05/29/15 00:28 218-01-905/27/15 23:330.011 1
Dibenz(a,h)anthracene ND mg/kg 05/29/15 00:28 53-70-305/27/15 23:330.011 1
Fluoranthene 0.047 mg/kg 05/29/15 00:28 206-44-005/27/15 23:330.011 1
Fluorene ND mg/kg 05/29/15 00:28 86-73-705/27/15 23:330.011 1
Indeno(1,2,3-cd)pyrene 0.012 mg/kg 05/29/15 00:28 193-39-505/27/15 23:330.011 1
Naphthalene ND mg/kg 05/29/15 00:28 91-20-305/27/15 23:330.011 1
Phenanthrene 0.020 mg/kg 05/29/15 00:28 85-01-805/27/15 23:330.011 1
Pyrene 0.040 mg/kg 05/29/15 00:28 129-00-005/27/15 23:330.011 1
Total BaP Eq. MN 2006sh. ND=0 0.024 mg/kg 05/29/15 00:2805/27/15 23:330.011 1
Surrogates2-Fluorobiphenyl (S) 61 %. 05/29/15 00:28 321-60-805/27/15 23:3355-125 1
p-Terphenyl-d14 (S) 72 %. 05/29/15 00:28 1718-51-005/27/15 23:3330-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 19 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-39/1-3 Lab ID: 10307337010 Collected: 05/20/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 2.0 mg/kg 05/29/15 23:15 7440-38-205/29/15 10:350.95 1
Barium 25.8 mg/kg 05/29/15 23:15 7440-39-305/29/15 10:350.48 1
Cadmium ND mg/kg 05/29/15 23:15 7440-43-905/29/15 10:350.14 1
Chromium 6.3 mg/kg 05/29/15 23:15 7440-47-305/29/15 10:350.48 1
Lead 2.9 mg/kg 05/29/15 23:15 7439-92-105/29/15 10:350.48 1
Selenium ND mg/kg 05/29/15 23:15 7782-49-205/29/15 10:350.95 1
Silver ND mg/kg 05/29/15 23:15 7440-22-405/29/15 10:350.48 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/29/15 15:24 7439-97-605/29/15 08:010.021 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 5.2 % 05/28/15 16:410.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/29/15 09:01 83-32-905/27/15 23:330.011 1
Acenaphthylene 0.11 mg/kg 05/29/15 09:01 208-96-805/27/15 23:330.011 1
Anthracene 0.077 mg/kg 05/29/15 09:01 120-12-705/27/15 23:330.011 1
Benzo(a)anthracene 0.12 mg/kg 05/29/15 09:01 56-55-305/27/15 23:330.011 1
Benzo(a)pyrene 0.17 mg/kg 05/29/15 09:01 50-32-805/27/15 23:330.011 1
Benzo(b)fluoranthene 0.24 mg/kg 05/29/15 09:01 205-99-205/27/15 23:330.011 1
Benzo(g,h,i)perylene 0.17 mg/kg 05/29/15 09:01 191-24-205/27/15 23:330.011 1
Benzo(k)fluoranthene 0.078 mg/kg 05/29/15 09:01 207-08-905/27/15 23:330.011 1
Chrysene 0.14 mg/kg 05/29/15 09:01 218-01-905/27/15 23:330.011 1
Dibenz(a,h)anthracene ND mg/kg 05/29/15 09:01 53-70-305/27/15 23:330.011 1
Fluoranthene 0.13 mg/kg 05/29/15 09:01 206-44-005/27/15 23:330.011 1
Fluorene ND mg/kg 05/29/15 09:01 86-73-705/27/15 23:330.011 1
Indeno(1,2,3-cd)pyrene 0.11 mg/kg 05/29/15 09:01 193-39-505/27/15 23:330.011 1
Naphthalene ND mg/kg 05/29/15 09:01 91-20-305/27/15 23:330.011 1
Phenanthrene 0.043 mg/kg 05/29/15 09:01 85-01-805/27/15 23:330.011 1
Pyrene 0.17 mg/kg 05/29/15 09:01 129-00-005/27/15 23:330.011 1
Total BaP Eq. MN 2006sh. ND=0 0.23 mg/kg 05/29/15 09:0105/27/15 23:330.011 1
Surrogates2-Fluorobiphenyl (S) 80 %. 05/29/15 09:01 321-60-805/27/15 23:3355-125 1
p-Terphenyl-d14 (S) 85 %. 05/29/15 09:01 1718-51-005/27/15 23:3330-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 20 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-40/2-4 Lab ID: 10307337011 Collected: 05/20/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 2.5 mg/kg 05/29/15 23:18 7440-38-205/29/15 10:351.0 1
Barium 20.1 mg/kg 05/29/15 23:18 7440-39-305/29/15 10:350.51 1
Cadmium ND mg/kg 05/29/15 23:18 7440-43-905/29/15 10:350.15 1
Chromium 4.4 mg/kg 05/29/15 23:18 7440-47-305/29/15 10:350.51 1
Lead 2.2 mg/kg 05/29/15 23:18 7439-92-105/29/15 10:350.51 1
Selenium ND mg/kg 05/29/15 23:18 7782-49-205/29/15 10:351.0 1
Silver ND mg/kg 05/29/15 23:18 7440-22-405/29/15 10:350.51 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/29/15 15:26 7439-97-605/29/15 08:010.019 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 3.6 % 05/28/15 16:410.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/28/15 23:45 83-32-905/27/15 23:330.010 1
Acenaphthylene ND mg/kg 05/28/15 23:45 208-96-805/27/15 23:330.010 1
Anthracene ND mg/kg 05/28/15 23:45 120-12-705/27/15 23:330.010 1
Benzo(a)anthracene ND mg/kg 05/28/15 23:45 56-55-305/27/15 23:330.010 1
Benzo(a)pyrene ND mg/kg 05/28/15 23:45 50-32-805/27/15 23:330.010 1
Benzo(b)fluoranthene ND mg/kg 05/28/15 23:45 205-99-205/27/15 23:330.010 1
Benzo(g,h,i)perylene ND mg/kg 05/28/15 23:45 191-24-205/27/15 23:330.010 1
Benzo(k)fluoranthene ND mg/kg 05/28/15 23:45 207-08-905/27/15 23:330.010 1
Chrysene ND mg/kg 05/28/15 23:45 218-01-905/27/15 23:330.010 1
Dibenz(a,h)anthracene ND mg/kg 05/28/15 23:45 53-70-305/27/15 23:330.010 1
Fluoranthene ND mg/kg 05/28/15 23:45 206-44-005/27/15 23:330.010 1
Fluorene ND mg/kg 05/28/15 23:45 86-73-705/27/15 23:330.010 1
Indeno(1,2,3-cd)pyrene ND mg/kg 05/28/15 23:45 193-39-505/27/15 23:330.010 1
Naphthalene ND mg/kg 05/28/15 23:45 91-20-305/27/15 23:330.010 1
Phenanthrene ND mg/kg 05/28/15 23:45 85-01-805/27/15 23:330.010 1
Pyrene ND mg/kg 05/28/15 23:45 129-00-005/27/15 23:330.010 1
Total BaP Eq. MN 2006sh. ND=0 ND mg/kg 05/28/15 23:4505/27/15 23:330.010 1
Surrogates2-Fluorobiphenyl (S) 62 %. 05/28/15 23:45 321-60-805/27/15 23:3355-125 1
p-Terphenyl-d14 (S) 82 %. 05/28/15 23:45 1718-51-005/27/15 23:3330-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 21 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-41/2-4 Lab ID: 10307337012 Collected: 05/20/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic ND mg/kg 05/30/15 10:23 7440-38-205/29/15 10:355.1 5
Barium 35.4 mg/kg 05/29/15 23:21 7440-39-305/29/15 10:350.51 1
Cadmium ND mg/kg 05/29/15 23:21 7440-43-905/29/15 10:350.15 1
Chromium 4.6 mg/kg 05/29/15 23:21 7440-47-305/29/15 10:350.51 1
Lead 1.8 mg/kg 05/29/15 23:21 7439-92-105/29/15 10:350.51 1
Selenium ND mg/kg 05/30/15 10:23 7782-49-205/29/15 10:355.1 5
Silver ND mg/kg 05/29/15 23:21 7440-22-405/29/15 10:350.51 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/29/15 15:28 7439-97-605/29/15 08:010.021 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 3.1 % 05/28/15 16:410.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/29/15 09:23 83-32-905/27/15 23:330.010 1
Acenaphthylene ND mg/kg 05/29/15 09:23 208-96-805/27/15 23:330.010 1
Anthracene ND mg/kg 05/29/15 09:23 120-12-705/27/15 23:330.010 1
Benzo(a)anthracene ND mg/kg 05/29/15 09:23 56-55-305/27/15 23:330.010 1
Benzo(a)pyrene ND mg/kg 05/29/15 09:23 50-32-805/27/15 23:330.010 1
Benzo(b)fluoranthene ND mg/kg 05/29/15 09:23 205-99-205/27/15 23:330.010 1
Benzo(g,h,i)perylene ND mg/kg 05/29/15 09:23 191-24-205/27/15 23:330.010 1
Benzo(k)fluoranthene ND mg/kg 05/29/15 09:23 207-08-905/27/15 23:330.010 1
Chrysene ND mg/kg 05/29/15 09:23 218-01-905/27/15 23:330.010 1
Dibenz(a,h)anthracene ND mg/kg 05/29/15 09:23 53-70-305/27/15 23:330.010 1
Fluoranthene ND mg/kg 05/29/15 09:23 206-44-005/27/15 23:330.010 1
Fluorene ND mg/kg 05/29/15 09:23 86-73-705/27/15 23:330.010 1
Indeno(1,2,3-cd)pyrene ND mg/kg 05/29/15 09:23 193-39-505/27/15 23:330.010 1
Naphthalene ND mg/kg 05/29/15 09:23 91-20-305/27/15 23:330.010 1
Phenanthrene ND mg/kg 05/29/15 09:23 85-01-805/27/15 23:330.010 1
Pyrene ND mg/kg 05/29/15 09:23 129-00-005/27/15 23:330.010 1
Total BaP Eq. MN 2006sh. ND=0 ND mg/kg 05/29/15 09:2305/27/15 23:330.010 1
Surrogates2-Fluorobiphenyl (S) 70 %. 05/29/15 09:23 321-60-805/27/15 23:3355-125 1
p-Terphenyl-d14 (S) 73 %. 05/29/15 09:23 1718-51-005/27/15 23:3330-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 22 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-41/19-22 Lab ID: 10307337013 Collected: 05/20/15 00:00 Received: 05/21/15 08:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: WI MOD DRO Preparation Method: WI MOD DROWIDRO GCS Silica Gel
WDRO C10-C28 ND mg/L 05/28/15 12:2805/27/15 23:580.11 1
Surrogatesn-Triacontane (S) 84 %. 05/28/15 12:28 638-68-6 P405/27/15 23:5862-125 1
Analytical Method: WI MOD GROWIGRO GCV
Benzene ND ug/L 05/26/15 22:36 71-43-21.0 1
Ethylbenzene ND ug/L 05/26/15 22:36 100-41-41.0 1
Gasoline Range Organics ND ug/L 05/26/15 22:36100 1
Toluene ND ug/L 05/26/15 22:36 108-88-31.0 1
Xylene (Total) ND ug/L 05/26/15 22:36 1330-20-73.0 1
Surrogatesa,a,a-Trifluorotoluene (S) 101 %. 05/26/15 22:36 98-08-880-150 1
Analytical Method: EPA 8260B8260B VOC
Acetone ND ug/L 05/26/15 02:54 67-64-120.0 1
Allyl chloride ND ug/L 05/26/15 02:54 107-05-14.0 1
Benzene ND ug/L 05/26/15 02:54 71-43-21.0 1
Bromobenzene ND ug/L 05/26/15 02:54 108-86-11.0 1
Bromochloromethane ND ug/L 05/26/15 02:54 74-97-51.0 1
Bromodichloromethane ND ug/L 05/26/15 02:54 75-27-41.0 1
Bromoform ND ug/L 05/26/15 02:54 75-25-24.0 1
Bromomethane ND ug/L 05/26/15 02:54 74-83-910.0 1
2-Butanone (MEK) ND ug/L 05/26/15 02:54 78-93-35.0 1
n-Butylbenzene ND ug/L 05/26/15 02:54 104-51-81.0 1
sec-Butylbenzene ND ug/L 05/26/15 02:54 135-98-81.0 1
tert-Butylbenzene ND ug/L 05/26/15 02:54 98-06-61.0 1
Carbon tetrachloride ND ug/L 05/26/15 02:54 56-23-51.0 1
Chlorobenzene ND ug/L 05/26/15 02:54 108-90-71.0 1
Chloroethane ND ug/L 05/26/15 02:54 75-00-31.0 1
Chloroform ND ug/L 05/26/15 02:54 67-66-31.0 1
Chloromethane ND ug/L 05/26/15 02:54 74-87-34.0 1
2-Chlorotoluene ND ug/L 05/26/15 02:54 95-49-81.0 1
4-Chlorotoluene ND ug/L 05/26/15 02:54 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 05/26/15 02:54 96-12-810.0 1
Dibromochloromethane ND ug/L 05/26/15 02:54 124-48-11.0 1
1,2-Dibromoethane (EDB) ND ug/L 05/26/15 02:54 106-93-41.0 1
Dibromomethane ND ug/L 05/26/15 02:54 74-95-34.0 1
1,2-Dichlorobenzene ND ug/L 05/26/15 02:54 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 05/26/15 02:54 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 05/26/15 02:54 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 05/26/15 02:54 75-71-81.0 1
1,1-Dichloroethane ND ug/L 05/26/15 02:54 75-34-31.0 1
1,2-Dichloroethane ND ug/L 05/26/15 02:54 107-06-21.0 1
1,1-Dichloroethene ND ug/L 05/26/15 02:54 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 05/26/15 02:54 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 05/26/15 02:54 156-60-51.0 1
Dichlorofluoromethane ND ug/L 05/26/15 02:54 75-43-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 23 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-41/19-22 Lab ID: 10307337013 Collected: 05/20/15 00:00 Received: 05/21/15 08:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B8260B VOC
1,2-Dichloropropane ND ug/L 05/26/15 02:54 78-87-54.0 1
1,3-Dichloropropane ND ug/L 05/26/15 02:54 142-28-91.0 1
2,2-Dichloropropane ND ug/L 05/26/15 02:54 594-20-74.0 1
1,1-Dichloropropene ND ug/L 05/26/15 02:54 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 05/26/15 02:54 10061-01-54.0 1
trans-1,3-Dichloropropene ND ug/L 05/26/15 02:54 10061-02-64.0 1
Diethyl ether (Ethyl ether) ND ug/L 05/26/15 02:54 60-29-74.0 1
Ethylbenzene ND ug/L 05/26/15 02:54 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 05/26/15 02:54 87-68-31.0 1
Isopropylbenzene (Cumene) ND ug/L 05/26/15 02:54 98-82-81.0 1
p-Isopropyltoluene ND ug/L 05/26/15 02:54 99-87-61.0 1
Methylene Chloride ND ug/L 05/26/15 02:54 75-09-24.0 1
4-Methyl-2-pentanone (MIBK) ND ug/L 05/26/15 02:54 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 05/26/15 02:54 1634-04-41.0 1
Naphthalene ND ug/L 05/26/15 02:54 91-20-34.0 1
n-Propylbenzene ND ug/L 05/26/15 02:54 103-65-11.0 1
Styrene ND ug/L 05/26/15 02:54 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 05/26/15 02:54 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 05/26/15 02:54 79-34-51.0 1
Tetrachloroethene 2.8 ug/L 05/26/15 02:54 127-18-41.0 1
Tetrahydrofuran ND ug/L 05/26/15 02:54 109-99-910.0 1
Toluene ND ug/L 05/26/15 02:54 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 05/26/15 02:54 87-61-61.0 1
1,2,4-Trichlorobenzene ND ug/L 05/26/15 02:54 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 05/26/15 02:54 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 05/26/15 02:54 79-00-51.0 1
Trichloroethene ND ug/L 05/26/15 02:54 79-01-60.40 1
Trichlorofluoromethane ND ug/L 05/26/15 02:54 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 05/26/15 02:54 96-18-44.0 1
1,1,2-Trichlorotrifluoroethane ND ug/L 05/26/15 02:54 76-13-11.0 1
1,2,4-Trimethylbenzene ND ug/L 05/26/15 02:54 95-63-61.0 1
1,3,5-Trimethylbenzene ND ug/L 05/26/15 02:54 108-67-81.0 1
Vinyl chloride ND ug/L 05/26/15 02:54 75-01-41.0 1
Xylene (Total) ND ug/L 05/26/15 02:54 1330-20-73.0 1
Surrogates1,2-Dichloroethane-d4 (S) 85 %. 05/26/15 02:54 17060-07-075-125 1
Toluene-d8 (S) 102 %. 05/26/15 02:54 2037-26-575-125 1
4-Bromofluorobenzene (S) 102 %. 05/26/15 02:54 460-00-475-125 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 24 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-42/1-3 Lab ID: 10307337014 Collected: 05/20/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic ND mg/kg 05/30/15 10:26 7440-38-205/29/15 10:355.3 5
Barium 36.9 mg/kg 05/29/15 23:24 7440-39-305/29/15 10:350.53 1
Cadmium ND mg/kg 05/29/15 23:24 7440-43-905/29/15 10:350.16 1
Chromium 6.3 mg/kg 05/29/15 23:24 7440-47-305/29/15 10:350.53 1
Lead 9.6 mg/kg 05/29/15 23:24 7439-92-105/29/15 10:350.53 1
Selenium ND mg/kg 05/30/15 10:26 7782-49-205/29/15 10:355.3 5
Silver ND mg/kg 05/29/15 23:24 7440-22-405/29/15 10:350.53 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/29/15 15:30 7439-97-605/29/15 08:010.020 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 7.2 % 05/28/15 16:410.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/29/15 09:45 83-32-905/27/15 23:330.011 1
Acenaphthylene ND mg/kg 05/29/15 09:45 208-96-805/27/15 23:330.011 1
Anthracene ND mg/kg 05/29/15 09:45 120-12-705/27/15 23:330.011 1
Benzo(a)anthracene 0.014 mg/kg 05/29/15 09:45 56-55-305/27/15 23:330.011 1
Benzo(a)pyrene 0.018 mg/kg 05/29/15 09:45 50-32-805/27/15 23:330.011 1
Benzo(b)fluoranthene 0.025 mg/kg 05/29/15 09:45 205-99-205/27/15 23:330.011 1
Benzo(g,h,i)perylene 0.016 mg/kg 05/29/15 09:45 191-24-205/27/15 23:330.011 1
Benzo(k)fluoranthene ND mg/kg 05/29/15 09:45 207-08-905/27/15 23:330.011 1
Chrysene 0.020 mg/kg 05/29/15 09:45 218-01-905/27/15 23:330.011 1
Dibenz(a,h)anthracene ND mg/kg 05/29/15 09:45 53-70-305/27/15 23:330.011 1
Fluoranthene 0.031 mg/kg 05/29/15 09:45 206-44-005/27/15 23:330.011 1
Fluorene ND mg/kg 05/29/15 09:45 86-73-705/27/15 23:330.011 1
Indeno(1,2,3-cd)pyrene ND mg/kg 05/29/15 09:45 193-39-505/27/15 23:330.011 1
Naphthalene ND mg/kg 05/29/15 09:45 91-20-305/27/15 23:330.011 1
Phenanthrene 0.016 mg/kg 05/29/15 09:45 85-01-805/27/15 23:330.011 1
Pyrene 0.033 mg/kg 05/29/15 09:45 129-00-005/27/15 23:330.011 1
Total BaP Eq. MN 2006sh. ND=0 0.023 mg/kg 05/29/15 09:4505/27/15 23:330.011 1
Surrogates2-Fluorobiphenyl (S) 66 %. 05/29/15 09:45 321-60-805/27/15 23:3355-125 1
p-Terphenyl-d14 (S) 72 %. 05/29/15 09:45 1718-51-005/27/15 23:3330-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 25 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-43/4-6 Lab ID: 10307337015 Collected: 05/20/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic ND mg/kg 05/30/15 10:29 7440-38-205/29/15 10:355.0 5
Barium 24.0 mg/kg 05/29/15 23:33 7440-39-305/29/15 10:350.50 1
Cadmium ND mg/kg 05/29/15 23:33 7440-43-905/29/15 10:350.15 1
Chromium 5.1 mg/kg 05/29/15 23:33 7440-47-305/29/15 10:350.50 1
Lead 1.8 mg/kg 05/29/15 23:33 7439-92-105/29/15 10:350.50 1
Selenium ND mg/kg 05/30/15 10:29 7782-49-205/29/15 10:355.0 5
Silver ND mg/kg 05/29/15 23:33 7440-22-405/29/15 10:350.50 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/29/15 15:32 7439-97-605/29/15 08:010.020 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 2.4 % 05/28/15 16:410.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/29/15 01:12 83-32-905/27/15 23:330.010 1
Acenaphthylene ND mg/kg 05/29/15 01:12 208-96-805/27/15 23:330.010 1
Anthracene ND mg/kg 05/29/15 01:12 120-12-705/27/15 23:330.010 1
Benzo(a)anthracene ND mg/kg 05/29/15 01:12 56-55-305/27/15 23:330.010 1
Benzo(a)pyrene ND mg/kg 05/29/15 01:12 50-32-805/27/15 23:330.010 1
Benzo(b)fluoranthene ND mg/kg 05/29/15 01:12 205-99-205/27/15 23:330.010 1
Benzo(g,h,i)perylene ND mg/kg 05/29/15 01:12 191-24-205/27/15 23:330.010 1
Benzo(k)fluoranthene ND mg/kg 05/29/15 01:12 207-08-905/27/15 23:330.010 1
Chrysene ND mg/kg 05/29/15 01:12 218-01-905/27/15 23:330.010 1
Dibenz(a,h)anthracene ND mg/kg 05/29/15 01:12 53-70-305/27/15 23:330.010 1
Fluoranthene ND mg/kg 05/29/15 01:12 206-44-005/27/15 23:330.010 1
Fluorene ND mg/kg 05/29/15 01:12 86-73-705/27/15 23:330.010 1
Indeno(1,2,3-cd)pyrene ND mg/kg 05/29/15 01:12 193-39-505/27/15 23:330.010 1
Naphthalene ND mg/kg 05/29/15 01:12 91-20-305/27/15 23:330.010 1
Phenanthrene ND mg/kg 05/29/15 01:12 85-01-805/27/15 23:330.010 1
Pyrene ND mg/kg 05/29/15 01:12 129-00-005/27/15 23:330.010 1
Total BaP Eq. MN 2006sh. ND=0 ND mg/kg 05/29/15 01:1205/27/15 23:330.010 1
Surrogates2-Fluorobiphenyl (S) 67 %. 05/29/15 01:12 321-60-805/27/15 23:3355-125 1
p-Terphenyl-d14 (S) 84 %. 05/29/15 01:12 1718-51-005/27/15 23:3330-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 26 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-44/5-7 Lab ID: 10307337016 Collected: 05/20/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: WI MOD DRO Preparation Method: WI MOD DROWIDRO GCS Silica Gel
WDRO C10-C28 ND mg/kg 05/29/15 10:4305/28/15 17:105.1 1
Surrogatesn-Triacontane (S) 76 %. 05/29/15 10:43 638-68-605/28/15 17:1030-143 1
Analytical Method: WI MOD GRO Preparation Method: EPA 5030 Medium SoilWIGRO GCV
Gasoline Range Organics ND mg/kg 05/29/15 16:5505/27/15 15:5912.0 1
Surrogatesa,a,a-Trifluorotoluene (S) 100 %. 05/29/15 16:55 98-08-805/27/15 15:5980-150 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 17.1 % 05/28/15 16:420.10 1
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
Acetone ND mg/kg 06/01/15 19:37 67-64-106/01/15 09:531.2 1
Allyl chloride ND mg/kg 06/01/15 19:37 107-05-106/01/15 09:530.25 1
Benzene ND mg/kg 06/01/15 19:37 71-43-206/01/15 09:530.025 1
Bromobenzene ND mg/kg 06/01/15 19:37 108-86-106/01/15 09:530.062 1
Bromochloromethane ND mg/kg 06/01/15 19:37 74-97-506/01/15 09:530.062 1
Bromodichloromethane ND mg/kg 06/01/15 19:37 75-27-406/01/15 09:530.062 1
Bromoform ND mg/kg 06/01/15 19:37 75-25-206/01/15 09:530.25 1
Bromomethane ND mg/kg 06/01/15 19:37 74-83-906/01/15 09:530.62 1
2-Butanone (MEK) ND mg/kg 06/01/15 19:37 78-93-306/01/15 09:530.31 1
n-Butylbenzene ND mg/kg 06/01/15 19:37 104-51-806/01/15 09:530.062 1
sec-Butylbenzene ND mg/kg 06/01/15 19:37 135-98-806/01/15 09:530.062 1
tert-Butylbenzene ND mg/kg 06/01/15 19:37 98-06-606/01/15 09:530.062 1
Carbon tetrachloride ND mg/kg 06/01/15 19:37 56-23-506/01/15 09:530.062 1
Chlorobenzene ND mg/kg 06/01/15 19:37 108-90-706/01/15 09:530.062 1
Chloroethane ND mg/kg 06/01/15 19:37 75-00-306/01/15 09:530.62 1
Chloroform ND mg/kg 06/01/15 19:37 67-66-306/01/15 09:530.062 1
Chloromethane ND mg/kg 06/01/15 19:37 74-87-306/01/15 09:530.25 1
2-Chlorotoluene ND mg/kg 06/01/15 19:37 95-49-806/01/15 09:530.062 1
4-Chlorotoluene ND mg/kg 06/01/15 19:37 106-43-406/01/15 09:530.062 1
1,2-Dibromo-3-chloropropane ND mg/kg 06/01/15 19:37 96-12-806/01/15 09:530.62 1
Dibromochloromethane ND mg/kg 06/01/15 19:37 124-48-106/01/15 09:530.062 1
1,2-Dibromoethane (EDB) ND mg/kg 06/01/15 19:37 106-93-406/01/15 09:530.062 1
Dibromomethane ND mg/kg 06/01/15 19:37 74-95-306/01/15 09:530.062 1
1,2-Dichlorobenzene ND mg/kg 06/01/15 19:37 95-50-106/01/15 09:530.062 1
1,3-Dichlorobenzene ND mg/kg 06/01/15 19:37 541-73-106/01/15 09:530.062 1
1,4-Dichlorobenzene ND mg/kg 06/01/15 19:37 106-46-706/01/15 09:530.062 1
Dichlorodifluoromethane ND mg/kg 06/01/15 19:37 75-71-806/01/15 09:530.25 1
1,1-Dichloroethane ND mg/kg 06/01/15 19:37 75-34-306/01/15 09:530.062 1
1,2-Dichloroethane ND mg/kg 06/01/15 19:37 107-06-206/01/15 09:530.062 1
1,1-Dichloroethene ND mg/kg 06/01/15 19:37 75-35-406/01/15 09:530.25 1
cis-1,2-Dichloroethene ND mg/kg 06/01/15 19:37 156-59-206/01/15 09:530.062 1
trans-1,2-Dichloroethene ND mg/kg 06/01/15 19:37 156-60-5 L306/01/15 09:530.062 1
Dichlorofluoromethane ND mg/kg 06/01/15 19:37 75-43-406/01/15 09:530.62 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 27 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-44/5-7 Lab ID: 10307337016 Collected: 05/20/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
1,2-Dichloropropane ND mg/kg 06/01/15 19:37 78-87-506/01/15 09:530.062 1
1,3-Dichloropropane ND mg/kg 06/01/15 19:37 142-28-906/01/15 09:530.062 1
2,2-Dichloropropane ND mg/kg 06/01/15 19:37 594-20-706/01/15 09:530.25 1
1,1-Dichloropropene ND mg/kg 06/01/15 19:37 563-58-606/01/15 09:530.062 1
cis-1,3-Dichloropropene ND mg/kg 06/01/15 19:37 10061-01-506/01/15 09:530.062 1
trans-1,3-Dichloropropene ND mg/kg 06/01/15 19:37 10061-02-606/01/15 09:530.062 1
Diethyl ether (Ethyl ether) ND mg/kg 06/01/15 19:37 60-29-706/01/15 09:530.25 1
Ethylbenzene ND mg/kg 06/01/15 19:37 100-41-406/01/15 09:530.062 1
Hexachloro-1,3-butadiene ND mg/kg 06/01/15 19:37 87-68-306/01/15 09:530.31 1
Isopropylbenzene (Cumene) ND mg/kg 06/01/15 19:37 98-82-806/01/15 09:530.062 1
p-Isopropyltoluene ND mg/kg 06/01/15 19:37 99-87-606/01/15 09:530.062 1
Methylene Chloride ND mg/kg 06/01/15 19:37 75-09-206/01/15 09:530.25 1
4-Methyl-2-pentanone (MIBK) ND mg/kg 06/01/15 19:37 108-10-106/01/15 09:530.31 1
Methyl-tert-butyl ether ND mg/kg 06/01/15 19:37 1634-04-406/01/15 09:530.062 1
Naphthalene ND mg/kg 06/01/15 19:37 91-20-306/01/15 09:530.25 1
n-Propylbenzene ND mg/kg 06/01/15 19:37 103-65-106/01/15 09:530.062 1
Styrene ND mg/kg 06/01/15 19:37 100-42-506/01/15 09:530.062 1
1,1,1,2-Tetrachloroethane ND mg/kg 06/01/15 19:37 630-20-606/01/15 09:530.062 1
1,1,2,2-Tetrachloroethane ND mg/kg 06/01/15 19:37 79-34-506/01/15 09:530.062 1
Tetrachloroethene 0.15 mg/kg 06/01/15 19:37 127-18-406/01/15 09:530.062 1
Tetrahydrofuran ND mg/kg 06/01/15 19:37 109-99-906/01/15 09:532.5 1
Toluene ND mg/kg 06/01/15 19:37 108-88-306/01/15 09:530.062 1
1,2,3-Trichlorobenzene ND mg/kg 06/01/15 19:37 87-61-606/01/15 09:530.062 1
1,2,4-Trichlorobenzene ND mg/kg 06/01/15 19:37 120-82-106/01/15 09:530.062 1
1,1,1-Trichloroethane ND mg/kg 06/01/15 19:37 71-55-606/01/15 09:530.062 1
1,1,2-Trichloroethane ND mg/kg 06/01/15 19:37 79-00-506/01/15 09:530.062 1
Trichloroethene ND mg/kg 06/01/15 19:37 79-01-606/01/15 09:530.062 1
Trichlorofluoromethane ND mg/kg 06/01/15 19:37 75-69-406/01/15 09:530.25 1
1,2,3-Trichloropropane ND mg/kg 06/01/15 19:37 96-18-406/01/15 09:530.25 1
1,1,2-Trichlorotrifluoroethane ND mg/kg 06/01/15 19:37 76-13-106/01/15 09:530.25 1
1,2,4-Trimethylbenzene ND mg/kg 06/01/15 19:37 95-63-606/01/15 09:530.062 1
1,3,5-Trimethylbenzene ND mg/kg 06/01/15 19:37 108-67-806/01/15 09:530.062 1
Vinyl chloride ND mg/kg 06/01/15 19:37 75-01-406/01/15 09:530.025 1
Xylene (Total) ND mg/kg 06/01/15 19:37 1330-20-706/01/15 09:530.18 1
Surrogates1,2-Dichloroethane-d4 (S) 100 %. 06/01/15 19:37 17060-07-006/01/15 09:5355-150 1
Toluene-d8 (S) 102 %. 06/01/15 19:37 2037-26-506/01/15 09:5361-125 1
4-Bromofluorobenzene (S) 117 %. 06/01/15 19:37 460-00-406/01/15 09:5354-131 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 28 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-44/19-22 Lab ID: 10307337017 Collected: 05/20/15 00:00 Received: 05/21/15 08:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: WI MOD DRO Preparation Method: WI MOD DROWIDRO GCS Silica Gel
WDRO C10-C28 ND mg/L 05/28/15 12:3505/27/15 23:580.11 1
Surrogatesn-Triacontane (S) 84 %. 05/28/15 12:35 638-68-6 P405/27/15 23:5862-125 1
Analytical Method: WI MOD GROWIGRO GCV
Benzene ND ug/L 05/26/15 22:59 71-43-21.0 1
Ethylbenzene ND ug/L 05/26/15 22:59 100-41-41.0 1
Gasoline Range Organics ND ug/L 05/26/15 22:59100 1
Toluene ND ug/L 05/26/15 22:59 108-88-31.0 1
Xylene (Total) ND ug/L 05/26/15 22:59 1330-20-73.0 1
Surrogatesa,a,a-Trifluorotoluene (S) 99 %. 05/26/15 22:59 98-08-880-150 1
Analytical Method: EPA 8260B8260B VOC
Acetone ND ug/L 05/26/15 03:08 67-64-120.0 1
Allyl chloride ND ug/L 05/26/15 03:08 107-05-14.0 1
Benzene ND ug/L 05/26/15 03:08 71-43-21.0 1
Bromobenzene ND ug/L 05/26/15 03:08 108-86-11.0 1
Bromochloromethane ND ug/L 05/26/15 03:08 74-97-51.0 1
Bromodichloromethane ND ug/L 05/26/15 03:08 75-27-41.0 1
Bromoform ND ug/L 05/26/15 03:08 75-25-24.0 1
Bromomethane ND ug/L 05/26/15 03:08 74-83-910.0 1
2-Butanone (MEK) ND ug/L 05/26/15 03:08 78-93-35.0 1
n-Butylbenzene ND ug/L 05/26/15 03:08 104-51-81.0 1
sec-Butylbenzene ND ug/L 05/26/15 03:08 135-98-81.0 1
tert-Butylbenzene ND ug/L 05/26/15 03:08 98-06-61.0 1
Carbon tetrachloride ND ug/L 05/26/15 03:08 56-23-51.0 1
Chlorobenzene ND ug/L 05/26/15 03:08 108-90-71.0 1
Chloroethane ND ug/L 05/26/15 03:08 75-00-31.0 1
Chloroform ND ug/L 05/26/15 03:08 67-66-31.0 1
Chloromethane ND ug/L 05/26/15 03:08 74-87-34.0 1
2-Chlorotoluene ND ug/L 05/26/15 03:08 95-49-81.0 1
4-Chlorotoluene ND ug/L 05/26/15 03:08 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 05/26/15 03:08 96-12-810.0 1
Dibromochloromethane ND ug/L 05/26/15 03:08 124-48-11.0 1
1,2-Dibromoethane (EDB) ND ug/L 05/26/15 03:08 106-93-41.0 1
Dibromomethane ND ug/L 05/26/15 03:08 74-95-34.0 1
1,2-Dichlorobenzene ND ug/L 05/26/15 03:08 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 05/26/15 03:08 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 05/26/15 03:08 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 05/26/15 03:08 75-71-81.0 1
1,1-Dichloroethane ND ug/L 05/26/15 03:08 75-34-31.0 1
1,2-Dichloroethane ND ug/L 05/26/15 03:08 107-06-21.0 1
1,1-Dichloroethene ND ug/L 05/26/15 03:08 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 05/26/15 03:08 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 05/26/15 03:08 156-60-51.0 1
Dichlorofluoromethane ND ug/L 05/26/15 03:08 75-43-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 29 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-44/19-22 Lab ID: 10307337017 Collected: 05/20/15 00:00 Received: 05/21/15 08:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B8260B VOC
1,2-Dichloropropane ND ug/L 05/26/15 03:08 78-87-54.0 1
1,3-Dichloropropane ND ug/L 05/26/15 03:08 142-28-91.0 1
2,2-Dichloropropane ND ug/L 05/26/15 03:08 594-20-74.0 1
1,1-Dichloropropene ND ug/L 05/26/15 03:08 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 05/26/15 03:08 10061-01-54.0 1
trans-1,3-Dichloropropene ND ug/L 05/26/15 03:08 10061-02-64.0 1
Diethyl ether (Ethyl ether) ND ug/L 05/26/15 03:08 60-29-74.0 1
Ethylbenzene ND ug/L 05/26/15 03:08 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 05/26/15 03:08 87-68-31.0 1
Isopropylbenzene (Cumene) ND ug/L 05/26/15 03:08 98-82-81.0 1
p-Isopropyltoluene ND ug/L 05/26/15 03:08 99-87-61.0 1
Methylene Chloride ND ug/L 05/26/15 03:08 75-09-24.0 1
4-Methyl-2-pentanone (MIBK) ND ug/L 05/26/15 03:08 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 05/26/15 03:08 1634-04-41.0 1
Naphthalene ND ug/L 05/26/15 03:08 91-20-34.0 1
n-Propylbenzene ND ug/L 05/26/15 03:08 103-65-11.0 1
Styrene ND ug/L 05/26/15 03:08 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 05/26/15 03:08 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 05/26/15 03:08 79-34-51.0 1
Tetrachloroethene 9.9 ug/L 05/26/15 03:08 127-18-41.0 1
Tetrahydrofuran ND ug/L 05/26/15 03:08 109-99-910.0 1
Toluene ND ug/L 05/26/15 03:08 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 05/26/15 03:08 87-61-61.0 1
1,2,4-Trichlorobenzene ND ug/L 05/26/15 03:08 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 05/26/15 03:08 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 05/26/15 03:08 79-00-51.0 1
Trichloroethene ND ug/L 05/26/15 03:08 79-01-60.40 1
Trichlorofluoromethane ND ug/L 05/26/15 03:08 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 05/26/15 03:08 96-18-44.0 1
1,1,2-Trichlorotrifluoroethane ND ug/L 05/26/15 03:08 76-13-11.0 1
1,2,4-Trimethylbenzene ND ug/L 05/26/15 03:08 95-63-61.0 1
1,3,5-Trimethylbenzene ND ug/L 05/26/15 03:08 108-67-81.0 1
Vinyl chloride ND ug/L 05/26/15 03:08 75-01-41.0 1
Xylene (Total) ND ug/L 05/26/15 03:08 1330-20-73.0 1
Surrogates1,2-Dichloroethane-d4 (S) 90 %. 05/26/15 03:08 17060-07-075-125 1
Toluene-d8 (S) 101 %. 05/26/15 03:08 2037-26-575-125 1
4-Bromofluorobenzene (S) 104 %. 05/26/15 03:08 460-00-475-125 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 30 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-45/8-10 Lab ID: 10307337018 Collected: 05/20/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: WI MOD DRO Preparation Method: WI MOD DROWIDRO GCS Silica Gel
WDRO C10-C28 ND mg/kg 05/29/15 11:1405/28/15 17:103.9 1
Surrogatesn-Triacontane (S) 92 %. 05/29/15 11:14 638-68-605/28/15 17:1030-143 1
Analytical Method: WI MOD GRO Preparation Method: EPA 5030 Medium SoilWIGRO GCV
Gasoline Range Organics ND mg/kg 05/29/15 17:1805/27/15 15:5910.3 1
Surrogatesa,a,a-Trifluorotoluene (S) 104 %. 05/29/15 17:18 98-08-805/27/15 15:5980-150 1
Analytical Method: EPA 6010C Preparation Method: EPA 30506010C MET ICP
Arsenic 1.3 mg/kg 05/29/15 23:36 7440-38-205/29/15 10:350.95 1
Barium 11.9 mg/kg 05/29/15 23:36 7440-39-305/29/15 10:350.47 1
Cadmium ND mg/kg 05/29/15 23:36 7440-43-905/29/15 10:350.14 1
Chromium 4.7 mg/kg 05/29/15 23:36 7440-47-305/29/15 10:350.47 1
Lead 1.4 mg/kg 05/29/15 23:36 7439-92-105/29/15 10:350.47 1
Selenium ND mg/kg 05/29/15 23:36 7782-49-205/29/15 10:350.95 1
Silver ND mg/kg 05/29/15 23:36 7440-22-405/29/15 10:350.47 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B7471B Mercury
Mercury ND mg/kg 05/29/15 15:34 7439-97-605/29/15 08:010.020 1
Analytical Method: ASTM D2974Dry Weight
Percent Moisture 4.0 % 05/28/15 16:420.10 1
Analytical Method: EPA 8270D by SIM Preparation Method: EPA 35508270D MSSV PAH by SIM
Acenaphthene ND mg/kg 05/29/15 01:33 83-32-905/27/15 23:330.010 1
Acenaphthylene ND mg/kg 05/29/15 01:33 208-96-805/27/15 23:330.010 1
Anthracene ND mg/kg 05/29/15 01:33 120-12-705/27/15 23:330.010 1
Benzo(a)anthracene ND mg/kg 05/29/15 01:33 56-55-305/27/15 23:330.010 1
Benzo(a)pyrene ND mg/kg 05/29/15 01:33 50-32-805/27/15 23:330.010 1
Benzo(b)fluoranthene ND mg/kg 05/29/15 01:33 205-99-205/27/15 23:330.010 1
Benzo(g,h,i)perylene ND mg/kg 05/29/15 01:33 191-24-205/27/15 23:330.010 1
Benzo(k)fluoranthene ND mg/kg 05/29/15 01:33 207-08-905/27/15 23:330.010 1
Chrysene ND mg/kg 05/29/15 01:33 218-01-905/27/15 23:330.010 1
Dibenz(a,h)anthracene ND mg/kg 05/29/15 01:33 53-70-305/27/15 23:330.010 1
Fluoranthene ND mg/kg 05/29/15 01:33 206-44-005/27/15 23:330.010 1
Fluorene ND mg/kg 05/29/15 01:33 86-73-705/27/15 23:330.010 1
Indeno(1,2,3-cd)pyrene ND mg/kg 05/29/15 01:33 193-39-505/27/15 23:330.010 1
Naphthalene ND mg/kg 05/29/15 01:33 91-20-305/27/15 23:330.010 1
Phenanthrene ND mg/kg 05/29/15 01:33 85-01-805/27/15 23:330.010 1
Pyrene ND mg/kg 05/29/15 01:33 129-00-005/27/15 23:330.010 1
Total BaP Eq. MN 2006sh. ND=0 ND mg/kg 05/29/15 01:3305/27/15 23:330.010 1
Surrogates2-Fluorobiphenyl (S) 57 %. 05/29/15 01:33 321-60-805/27/15 23:3355-125 1
p-Terphenyl-d14 (S) 80 %. 05/29/15 01:33 1718-51-005/27/15 23:3330-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 31 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-45/8-10 Lab ID: 10307337018 Collected: 05/20/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
Acetone ND mg/kg 06/01/15 19:57 67-64-106/01/15 09:531.1 1
Allyl chloride ND mg/kg 06/01/15 19:57 107-05-106/01/15 09:530.21 1
Benzene ND mg/kg 06/01/15 19:57 71-43-206/01/15 09:530.021 1
Bromobenzene ND mg/kg 06/01/15 19:57 108-86-106/01/15 09:530.053 1
Bromochloromethane ND mg/kg 06/01/15 19:57 74-97-506/01/15 09:530.053 1
Bromodichloromethane ND mg/kg 06/01/15 19:57 75-27-406/01/15 09:530.053 1
Bromoform ND mg/kg 06/01/15 19:57 75-25-206/01/15 09:530.21 1
Bromomethane ND mg/kg 06/01/15 19:57 74-83-906/01/15 09:530.53 1
2-Butanone (MEK) ND mg/kg 06/01/15 19:57 78-93-306/01/15 09:530.27 1
n-Butylbenzene ND mg/kg 06/01/15 19:57 104-51-806/01/15 09:530.053 1
sec-Butylbenzene ND mg/kg 06/01/15 19:57 135-98-806/01/15 09:530.053 1
tert-Butylbenzene ND mg/kg 06/01/15 19:57 98-06-606/01/15 09:530.053 1
Carbon tetrachloride ND mg/kg 06/01/15 19:57 56-23-506/01/15 09:530.053 1
Chlorobenzene ND mg/kg 06/01/15 19:57 108-90-706/01/15 09:530.053 1
Chloroethane ND mg/kg 06/01/15 19:57 75-00-306/01/15 09:530.53 1
Chloroform ND mg/kg 06/01/15 19:57 67-66-306/01/15 09:530.053 1
Chloromethane ND mg/kg 06/01/15 19:57 74-87-306/01/15 09:530.21 1
2-Chlorotoluene ND mg/kg 06/01/15 19:57 95-49-806/01/15 09:530.053 1
4-Chlorotoluene ND mg/kg 06/01/15 19:57 106-43-406/01/15 09:530.053 1
1,2-Dibromo-3-chloropropane ND mg/kg 06/01/15 19:57 96-12-806/01/15 09:530.53 1
Dibromochloromethane ND mg/kg 06/01/15 19:57 124-48-106/01/15 09:530.053 1
1,2-Dibromoethane (EDB) ND mg/kg 06/01/15 19:57 106-93-406/01/15 09:530.053 1
Dibromomethane ND mg/kg 06/01/15 19:57 74-95-306/01/15 09:530.053 1
1,2-Dichlorobenzene ND mg/kg 06/01/15 19:57 95-50-106/01/15 09:530.053 1
1,3-Dichlorobenzene ND mg/kg 06/01/15 19:57 541-73-106/01/15 09:530.053 1
1,4-Dichlorobenzene ND mg/kg 06/01/15 19:57 106-46-706/01/15 09:530.053 1
Dichlorodifluoromethane ND mg/kg 06/01/15 19:57 75-71-806/01/15 09:530.21 1
1,1-Dichloroethane ND mg/kg 06/01/15 19:57 75-34-306/01/15 09:530.053 1
1,2-Dichloroethane ND mg/kg 06/01/15 19:57 107-06-206/01/15 09:530.053 1
1,1-Dichloroethene ND mg/kg 06/01/15 19:57 75-35-406/01/15 09:530.21 1
cis-1,2-Dichloroethene ND mg/kg 06/01/15 19:57 156-59-206/01/15 09:530.053 1
trans-1,2-Dichloroethene ND mg/kg 06/01/15 19:57 156-60-5 L306/01/15 09:530.053 1
Dichlorofluoromethane ND mg/kg 06/01/15 19:57 75-43-406/01/15 09:530.53 1
1,2-Dichloropropane ND mg/kg 06/01/15 19:57 78-87-506/01/15 09:530.053 1
1,3-Dichloropropane ND mg/kg 06/01/15 19:57 142-28-906/01/15 09:530.053 1
2,2-Dichloropropane ND mg/kg 06/01/15 19:57 594-20-706/01/15 09:530.21 1
1,1-Dichloropropene ND mg/kg 06/01/15 19:57 563-58-606/01/15 09:530.053 1
cis-1,3-Dichloropropene ND mg/kg 06/01/15 19:57 10061-01-506/01/15 09:530.053 1
trans-1,3-Dichloropropene ND mg/kg 06/01/15 19:57 10061-02-606/01/15 09:530.053 1
Diethyl ether (Ethyl ether) ND mg/kg 06/01/15 19:57 60-29-706/01/15 09:530.21 1
Ethylbenzene ND mg/kg 06/01/15 19:57 100-41-406/01/15 09:530.053 1
Hexachloro-1,3-butadiene ND mg/kg 06/01/15 19:57 87-68-306/01/15 09:530.27 1
Isopropylbenzene (Cumene) ND mg/kg 06/01/15 19:57 98-82-806/01/15 09:530.053 1
p-Isopropyltoluene ND mg/kg 06/01/15 19:57 99-87-606/01/15 09:530.053 1
Methylene Chloride ND mg/kg 06/01/15 19:57 75-09-206/01/15 09:530.21 1
4-Methyl-2-pentanone (MIBK) ND mg/kg 06/01/15 19:57 108-10-106/01/15 09:530.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 32 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-45/8-10 Lab ID: 10307337018 Collected: 05/20/15 00:00 Received: 05/21/15 08:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B Preparation Method: EPA 5035/5030B8260B MSV 5030 Med Level
Methyl-tert-butyl ether ND mg/kg 06/01/15 19:57 1634-04-406/01/15 09:530.053 1
Naphthalene ND mg/kg 06/01/15 19:57 91-20-306/01/15 09:530.21 1
n-Propylbenzene ND mg/kg 06/01/15 19:57 103-65-106/01/15 09:530.053 1
Styrene ND mg/kg 06/01/15 19:57 100-42-506/01/15 09:530.053 1
1,1,1,2-Tetrachloroethane ND mg/kg 06/01/15 19:57 630-20-606/01/15 09:530.053 1
1,1,2,2-Tetrachloroethane ND mg/kg 06/01/15 19:57 79-34-506/01/15 09:530.053 1
Tetrachloroethene ND mg/kg 06/01/15 19:57 127-18-406/01/15 09:530.053 1
Tetrahydrofuran ND mg/kg 06/01/15 19:57 109-99-906/01/15 09:532.1 1
Toluene ND mg/kg 06/01/15 19:57 108-88-306/01/15 09:530.053 1
1,2,3-Trichlorobenzene ND mg/kg 06/01/15 19:57 87-61-606/01/15 09:530.053 1
1,2,4-Trichlorobenzene ND mg/kg 06/01/15 19:57 120-82-106/01/15 09:530.053 1
1,1,1-Trichloroethane ND mg/kg 06/01/15 19:57 71-55-606/01/15 09:530.053 1
1,1,2-Trichloroethane ND mg/kg 06/01/15 19:57 79-00-506/01/15 09:530.053 1
Trichloroethene ND mg/kg 06/01/15 19:57 79-01-606/01/15 09:530.053 1
Trichlorofluoromethane ND mg/kg 06/01/15 19:57 75-69-406/01/15 09:530.21 1
1,2,3-Trichloropropane ND mg/kg 06/01/15 19:57 96-18-406/01/15 09:530.21 1
1,1,2-Trichlorotrifluoroethane ND mg/kg 06/01/15 19:57 76-13-106/01/15 09:530.21 1
1,2,4-Trimethylbenzene ND mg/kg 06/01/15 19:57 95-63-606/01/15 09:530.053 1
1,3,5-Trimethylbenzene ND mg/kg 06/01/15 19:57 108-67-806/01/15 09:530.053 1
Vinyl chloride ND mg/kg 06/01/15 19:57 75-01-406/01/15 09:530.021 1
Xylene (Total) ND mg/kg 06/01/15 19:57 1330-20-706/01/15 09:530.16 1
Surrogates1,2-Dichloroethane-d4 (S) 104 %. 06/01/15 19:57 17060-07-006/01/15 09:5355-150 1
Toluene-d8 (S) 105 %. 06/01/15 19:57 2037-26-506/01/15 09:5361-125 1
4-Bromofluorobenzene (S) 107 %. 06/01/15 19:57 460-00-406/01/15 09:5354-131 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 33 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-45/12-20 Lab ID: 10307337019 Collected: 05/20/15 00:00 Received: 05/21/15 08:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: WI MOD DRO Preparation Method: WI MOD DROWIDRO GCS Silica Gel
WDRO C10-C28 ND mg/L 05/28/15 12:4205/27/15 23:580.11 1
Surrogatesn-Triacontane (S) 73 %. 05/28/15 12:42 638-68-6 P405/27/15 23:5862-125 1
Analytical Method: WI MOD GROWIGRO GCV
Benzene ND ug/L 05/26/15 23:23 71-43-21.0 1
Ethylbenzene ND ug/L 05/26/15 23:23 100-41-41.0 1
Gasoline Range Organics ND ug/L 05/26/15 23:23100 1
Toluene ND ug/L 05/26/15 23:23 108-88-31.0 1
Xylene (Total) ND ug/L 05/26/15 23:23 1330-20-73.0 1
Surrogatesa,a,a-Trifluorotoluene (S) 102 %. 05/26/15 23:23 98-08-8 pH80-150 1
Analytical Method: EPA 8260B8260B VOC
Acetone ND ug/L 05/26/15 03:23 67-64-120.0 1
Allyl chloride ND ug/L 05/26/15 03:23 107-05-14.0 1
Benzene ND ug/L 05/26/15 03:23 71-43-21.0 1
Bromobenzene ND ug/L 05/26/15 03:23 108-86-11.0 1
Bromochloromethane ND ug/L 05/26/15 03:23 74-97-51.0 1
Bromodichloromethane ND ug/L 05/26/15 03:23 75-27-41.0 1
Bromoform ND ug/L 05/26/15 03:23 75-25-24.0 1
Bromomethane ND ug/L 05/26/15 03:23 74-83-910.0 1
2-Butanone (MEK) ND ug/L 05/26/15 03:23 78-93-35.0 1
n-Butylbenzene ND ug/L 05/26/15 03:23 104-51-81.0 1
sec-Butylbenzene ND ug/L 05/26/15 03:23 135-98-81.0 1
tert-Butylbenzene ND ug/L 05/26/15 03:23 98-06-61.0 1
Carbon tetrachloride ND ug/L 05/26/15 03:23 56-23-51.0 1
Chlorobenzene ND ug/L 05/26/15 03:23 108-90-71.0 1
Chloroethane ND ug/L 05/26/15 03:23 75-00-31.0 1
Chloroform ND ug/L 05/26/15 03:23 67-66-31.0 1
Chloromethane ND ug/L 05/26/15 03:23 74-87-34.0 1
2-Chlorotoluene ND ug/L 05/26/15 03:23 95-49-81.0 1
4-Chlorotoluene ND ug/L 05/26/15 03:23 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 05/26/15 03:23 96-12-810.0 1
Dibromochloromethane ND ug/L 05/26/15 03:23 124-48-11.0 1
1,2-Dibromoethane (EDB) ND ug/L 05/26/15 03:23 106-93-41.0 1
Dibromomethane ND ug/L 05/26/15 03:23 74-95-34.0 1
1,2-Dichlorobenzene ND ug/L 05/26/15 03:23 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 05/26/15 03:23 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 05/26/15 03:23 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 05/26/15 03:23 75-71-81.0 1
1,1-Dichloroethane ND ug/L 05/26/15 03:23 75-34-31.0 1
1,2-Dichloroethane ND ug/L 05/26/15 03:23 107-06-21.0 1
1,1-Dichloroethene ND ug/L 05/26/15 03:23 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 05/26/15 03:23 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 05/26/15 03:23 156-60-51.0 1
Dichlorofluoromethane ND ug/L 05/26/15 03:23 75-43-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 34 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: LPG-45/12-20 Lab ID: 10307337019 Collected: 05/20/15 00:00 Received: 05/21/15 08:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B8260B VOC
1,2-Dichloropropane ND ug/L 05/26/15 03:23 78-87-54.0 1
1,3-Dichloropropane ND ug/L 05/26/15 03:23 142-28-91.0 1
2,2-Dichloropropane ND ug/L 05/26/15 03:23 594-20-74.0 1
1,1-Dichloropropene ND ug/L 05/26/15 03:23 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 05/26/15 03:23 10061-01-54.0 1
trans-1,3-Dichloropropene ND ug/L 05/26/15 03:23 10061-02-64.0 1
Diethyl ether (Ethyl ether) ND ug/L 05/26/15 03:23 60-29-74.0 1
Ethylbenzene ND ug/L 05/26/15 03:23 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 05/26/15 03:23 87-68-31.0 1
Isopropylbenzene (Cumene) ND ug/L 05/26/15 03:23 98-82-81.0 1
p-Isopropyltoluene ND ug/L 05/26/15 03:23 99-87-61.0 1
Methylene Chloride ND ug/L 05/26/15 03:23 75-09-24.0 1
4-Methyl-2-pentanone (MIBK) ND ug/L 05/26/15 03:23 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 05/26/15 03:23 1634-04-41.0 1
Naphthalene ND ug/L 05/26/15 03:23 91-20-34.0 1
n-Propylbenzene ND ug/L 05/26/15 03:23 103-65-11.0 1
Styrene ND ug/L 05/26/15 03:23 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 05/26/15 03:23 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 05/26/15 03:23 79-34-51.0 1
Tetrachloroethene ND ug/L 05/26/15 03:23 127-18-41.0 1
Tetrahydrofuran ND ug/L 05/26/15 03:23 109-99-910.0 1
Toluene ND ug/L 05/26/15 03:23 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 05/26/15 03:23 87-61-61.0 1
1,2,4-Trichlorobenzene ND ug/L 05/26/15 03:23 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 05/26/15 03:23 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 05/26/15 03:23 79-00-51.0 1
Trichloroethene ND ug/L 05/26/15 03:23 79-01-60.40 1
Trichlorofluoromethane ND ug/L 05/26/15 03:23 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 05/26/15 03:23 96-18-44.0 1
1,1,2-Trichlorotrifluoroethane ND ug/L 05/26/15 03:23 76-13-11.0 1
1,2,4-Trimethylbenzene ND ug/L 05/26/15 03:23 95-63-61.0 1
1,3,5-Trimethylbenzene ND ug/L 05/26/15 03:23 108-67-81.0 1
Vinyl chloride ND ug/L 05/26/15 03:23 75-01-41.0 1
Xylene (Total) ND ug/L 05/26/15 03:23 1330-20-73.0 1
Surrogates1,2-Dichloroethane-d4 (S) 93 %. 05/26/15 03:23 17060-07-075-125 1
Toluene-d8 (S) 105 %. 05/26/15 03:23 2037-26-575-125 1
4-Bromofluorobenzene (S) 100 %. 05/26/15 03:23 460-00-475-125 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
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Minneapolis, MN 55414
(612)607-1700
Page 35 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: TRIP BLANK Lab ID: 10307337020 Collected: Received: 05/21/15 08:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B8260B VOC
Acetone ND ug/L 05/26/15 00:43 67-64-120.0 1
Allyl chloride ND ug/L 05/26/15 00:43 107-05-14.0 1
Benzene ND ug/L 05/26/15 00:43 71-43-21.0 1
Bromobenzene ND ug/L 05/26/15 00:43 108-86-11.0 1
Bromochloromethane ND ug/L 05/26/15 00:43 74-97-51.0 1
Bromodichloromethane ND ug/L 05/26/15 00:43 75-27-41.0 1
Bromoform ND ug/L 05/26/15 00:43 75-25-24.0 1
Bromomethane ND ug/L 05/26/15 00:43 74-83-910.0 1
2-Butanone (MEK) ND ug/L 05/26/15 00:43 78-93-35.0 1
n-Butylbenzene ND ug/L 05/26/15 00:43 104-51-81.0 1
sec-Butylbenzene ND ug/L 05/26/15 00:43 135-98-81.0 1
tert-Butylbenzene ND ug/L 05/26/15 00:43 98-06-61.0 1
Carbon tetrachloride ND ug/L 05/26/15 00:43 56-23-51.0 1
Chlorobenzene ND ug/L 05/26/15 00:43 108-90-71.0 1
Chloroethane ND ug/L 05/26/15 00:43 75-00-31.0 1
Chloroform ND ug/L 05/26/15 00:43 67-66-31.0 1
Chloromethane ND ug/L 05/26/15 00:43 74-87-34.0 1
2-Chlorotoluene ND ug/L 05/26/15 00:43 95-49-81.0 1
4-Chlorotoluene ND ug/L 05/26/15 00:43 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 05/26/15 00:43 96-12-810.0 1
Dibromochloromethane ND ug/L 05/26/15 00:43 124-48-11.0 1
1,2-Dibromoethane (EDB) ND ug/L 05/26/15 00:43 106-93-41.0 1
Dibromomethane ND ug/L 05/26/15 00:43 74-95-34.0 1
1,2-Dichlorobenzene ND ug/L 05/26/15 00:43 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 05/26/15 00:43 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 05/26/15 00:43 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 05/26/15 00:43 75-71-81.0 1
1,1-Dichloroethane ND ug/L 05/26/15 00:43 75-34-31.0 1
1,2-Dichloroethane ND ug/L 05/26/15 00:43 107-06-21.0 1
1,1-Dichloroethene ND ug/L 05/26/15 00:43 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 05/26/15 00:43 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 05/26/15 00:43 156-60-51.0 1
Dichlorofluoromethane ND ug/L 05/26/15 00:43 75-43-41.0 1
1,2-Dichloropropane ND ug/L 05/26/15 00:43 78-87-54.0 1
1,3-Dichloropropane ND ug/L 05/26/15 00:43 142-28-91.0 1
2,2-Dichloropropane ND ug/L 05/26/15 00:43 594-20-74.0 1
1,1-Dichloropropene ND ug/L 05/26/15 00:43 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 05/26/15 00:43 10061-01-54.0 1
trans-1,3-Dichloropropene ND ug/L 05/26/15 00:43 10061-02-64.0 1
Diethyl ether (Ethyl ether) ND ug/L 05/26/15 00:43 60-29-74.0 1
Ethylbenzene ND ug/L 05/26/15 00:43 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 05/26/15 00:43 87-68-31.0 1
Isopropylbenzene (Cumene) ND ug/L 05/26/15 00:43 98-82-81.0 1
p-Isopropyltoluene ND ug/L 05/26/15 00:43 99-87-61.0 1
Methylene Chloride ND ug/L 05/26/15 00:43 75-09-24.0 1
4-Methyl-2-pentanone (MIBK) ND ug/L 05/26/15 00:43 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 05/26/15 00:43 1634-04-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 36 of 73
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Sample: TRIP BLANK Lab ID: 10307337020 Collected: Received: 05/21/15 08:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260B8260B VOC
Naphthalene ND ug/L 05/26/15 00:43 91-20-34.0 1
n-Propylbenzene ND ug/L 05/26/15 00:43 103-65-11.0 1
Styrene ND ug/L 05/26/15 00:43 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 05/26/15 00:43 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 05/26/15 00:43 79-34-51.0 1
Tetrachloroethene ND ug/L 05/26/15 00:43 127-18-41.0 1
Tetrahydrofuran ND ug/L 05/26/15 00:43 109-99-910.0 1
Toluene ND ug/L 05/26/15 00:43 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 05/26/15 00:43 87-61-61.0 1
1,2,4-Trichlorobenzene ND ug/L 05/26/15 00:43 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 05/26/15 00:43 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 05/26/15 00:43 79-00-51.0 1
Trichloroethene ND ug/L 05/26/15 00:43 79-01-60.40 1
Trichlorofluoromethane ND ug/L 05/26/15 00:43 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 05/26/15 00:43 96-18-44.0 1
1,1,2-Trichlorotrifluoroethane ND ug/L 05/26/15 00:43 76-13-11.0 1
1,2,4-Trimethylbenzene ND ug/L 05/26/15 00:43 95-63-61.0 1
1,3,5-Trimethylbenzene ND ug/L 05/26/15 00:43 108-67-81.0 1
Vinyl chloride ND ug/L 05/26/15 00:43 75-01-41.0 1
Xylene (Total) ND ug/L 05/26/15 00:43 1330-20-73.0 1
Surrogates1,2-Dichloroethane-d4 (S) 93 %. 05/26/15 00:43 17060-07-075-125 1
Toluene-d8 (S) 100 %. 05/26/15 00:43 2037-26-575-125 1
4-Bromofluorobenzene (S) 102 %. 05/26/15 00:43 460-00-475-125 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 37 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/13777
EPA 5030 Medium Soil
WI MOD GRO
WIGRO Solid GCV
Associated Lab Samples: 10307337005, 10307337006, 10307337007, 10307337016, 10307337018
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1975914
Associated Lab Samples: 10307337005, 10307337006, 10307337007, 10307337016, 10307337018
Matrix: Solid
Analyzed
Gasoline Range Organics mg/kg ND 10.0 05/28/15 16:48
a,a,a-Trifluorotoluene (S) %. 108 80-150 05/28/15 16:48
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1975915LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1975916
Gasoline Range Organics mg/kg 44.250 88 80-1208844.0 1 20
a,a,a-Trifluorotoluene (S) %. 110 80-150107
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1977136MATRIX SPIKE SAMPLE:
MSSpike
Result
10307659001
Gasoline Range Organics mg/kg 41.4 C0,M053.4 67 80-120ND
a,a,a-Trifluorotoluene (S) %. 109 80-150
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10307659002
1977137SAMPLE DUPLICATE:
Gasoline Range Organics mg/kg 5.1J 20ND
a,a,a-Trifluorotoluene (S) %. 104 0104
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 38 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/13776
WI MOD GRO
WI MOD GRO
WIGRO GCV Water
Associated Lab Samples: 10307337013, 10307337017, 10307337019
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1975896
Associated Lab Samples: 10307337013, 10307337017, 10307337019
Matrix: Water
Analyzed
Benzene ug/L ND 1.0 05/26/15 16:17
Ethylbenzene ug/L ND 1.0 05/26/15 16:17
Gasoline Range Organics ug/L ND 100 05/26/15 16:17
Toluene ug/L ND 1.0 05/26/15 16:17
Xylene (Total) ug/L ND 3.0 05/26/15 16:17
a,a,a-Trifluorotoluene (S) %. 100 80-150 05/26/15 16:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1975897LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1975898
Benzene ug/L 99.7100 100 80-1208787.4 13 20
Ethylbenzene ug/L 104100 104 80-1209292.0 12 20
Gasoline Range Organics ug/L 9941000 99 80-12094941 5 20
Toluene ug/L 107100 107 80-1209494.3 12 20
Xylene (Total) ug/L 317300 106 80-12093280 12 20
a,a,a-Trifluorotoluene (S) %. 102 80-150106
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1976615MATRIX SPIKE SAMPLE:
MSSpike
Result
10306382006
Benzene ug/L 97.9100 98 80-120ND
Ethylbenzene ug/L 104100 104 80-120ND
Gasoline Range Organics ug/L 10101000 99 80-120ND
Toluene ug/L 106100 106 80-120ND
Xylene (Total) ug/L 308300 103 80-120ND
a,a,a-Trifluorotoluene (S) %. 108 80-150
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 39 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/13661
EPA 7471B
EPA 7471B
7471B Mercury Solids
Associated Lab Samples: 10307337001, 10307337002, 10307337003, 10307337004, 10307337005, 10307337008, 10307337009,10307337010, 10307337011, 10307337012, 10307337014, 10307337015, 10307337018
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1976702
Associated Lab Samples: 10307337001, 10307337002, 10307337003, 10307337004, 10307337005, 10307337008, 10307337009,10307337010, 10307337011, 10307337012, 10307337014, 10307337015, 10307337018
Matrix: Solid
Analyzed
Mercury mg/kg ND 0.019 05/29/15 14:57
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1976703LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/kg 0.46.45 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1976704MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
10307337001
1976705
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/kg .58 103 75-125102 4 20.56ND 0.62 0.59
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 40 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/55531
EPA 3010
EPA 6010C
6010C TCLP
Associated Lab Samples: 10307337004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2005637
Associated Lab Samples: 10307337004
Matrix: Water
Analyzed
Lead mg/L ND 0.050 06/25/15 23:01
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2003860
Associated Lab Samples: 10307337004
Matrix: Water
Analyzed
Lead mg/L ND 0.050 06/25/15 23:49
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2003861
Associated Lab Samples: 10307337004
Matrix: Water
Analyzed
Lead mg/L ND 0.050 06/25/15 23:52
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2005638LABORATORY CONTROL SAMPLE:
LCSSpike
Lead mg/L 4.75 93 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2005639MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
10307337004
2005640
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Lead mg/L 5 93 75-12593 0 305ND 4.7 4.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 41 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/54632
EPA 3050
EPA 6010C
6010C Solids
Associated Lab Samples: 10307337001, 10307337002, 10307337003, 10307337004, 10307337005, 10307337008, 10307337009,10307337010, 10307337011, 10307337012, 10307337014, 10307337015, 10307337018
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1975231
Associated Lab Samples: 10307337001, 10307337002, 10307337003, 10307337004, 10307337005, 10307337008, 10307337009,10307337010, 10307337011, 10307337012, 10307337014, 10307337015, 10307337018
Matrix: Solid
Analyzed
Arsenic mg/kg ND 0.98 05/29/15 22:31
Barium mg/kg ND 0.49 05/29/15 22:31
Cadmium mg/kg ND 0.15 05/29/15 22:31
Chromium mg/kg ND 0.49 05/29/15 22:31
Lead mg/kg ND 0.49 05/29/15 22:31
Selenium mg/kg ND 0.98 05/29/15 22:31
Silver mg/kg ND 0.49 05/29/15 22:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1975232LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic mg/kg 46.450 93 80-120
Barium mg/kg 50.150 100 80-120
Cadmium mg/kg 47.850 96 80-120
Chromium mg/kg 48.850 98 80-120
Lead mg/kg 48.050 96 80-120
Selenium mg/kg 46.350 93 80-120
Silver mg/kg 23.725 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1975233MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
10307337001
1975234
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic mg/kg 59.2 81 75-12585 3 2058.23.3 51.1 52.6
Barium mg/kg 59.2 96 75-12589 4 2058.269.2 126 121
Cadmium mg/kg 59.2 82 75-12586 3 2058.2ND 48.8 50.3
Chromium mg/kg 59.2 81 75-12588 5 2058.210.3 58.1 61.3
Lead mg/kg 59.2 81 75-12585 3 2058.26.1 54.0 55.4
Selenium mg/kg 59.2 80 75-12584 3 2058.2ND 47.4 49.1
Silver mg/kg 29.5 82 75-12586 3 2029ND 24.3 25.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 42 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/54713
ASTM D2974
ASTM D2974
Dry Weight/Percent Moisture
Associated Lab Samples: 10307337001, 10307337002
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10307337002
1978387SAMPLE DUPLICATE:
Percent Moisture % 6.2 4 306.5
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10307261002
1978514SAMPLE DUPLICATE:
Percent Moisture % 4.6 4 304.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 43 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/54734
ASTM D2974
ASTM D2974
Dry Weight/Percent Moisture
Associated Lab Samples: 10307337003, 10307337004, 10307337005, 10307337006, 10307337007, 10307337008, 10307337009,10307337010, 10307337011, 10307337012, 10307337014, 10307337015, 10307337016, 10307337018
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10307276001
1978612SAMPLE DUPLICATE:
Percent Moisture % 6.5 2 306.4
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10307382002
1978696SAMPLE DUPLICATE:
Percent Moisture % 14.8 17 3012.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 44 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/31586
EPA 5035/5030B
EPA 8260B
8260B MSV 5030 Med Level
Associated Lab Samples: 10307337005, 10307337006, 10307337007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1978671
Associated Lab Samples: 10307337005, 10307337006, 10307337007
Matrix: Solid
Analyzed
1,1,1,2-Tetrachloroethane mg/kg ND 0.050 05/29/15 14:22
1,1,1-Trichloroethane mg/kg ND 0.050 05/29/15 14:22
1,1,2,2-Tetrachloroethane mg/kg ND 0.050 05/29/15 14:22
1,1,2-Trichloroethane mg/kg ND 0.050 05/29/15 14:22
1,1,2-Trichlorotrifluoroethane mg/kg ND 0.20 05/29/15 14:22
1,1-Dichloroethane mg/kg ND 0.050 05/29/15 14:22
1,1-Dichloroethene mg/kg ND 0.050 05/29/15 14:22
1,1-Dichloropropene mg/kg ND 0.050 05/29/15 14:22
1,2,3-Trichlorobenzene mg/kg ND 0.050 05/29/15 14:22
1,2,3-Trichloropropane mg/kg ND 0.20 05/29/15 14:22
1,2,4-Trichlorobenzene mg/kg ND 0.050 05/29/15 14:22
1,2,4-Trimethylbenzene mg/kg ND 0.050 05/29/15 14:22
1,2-Dibromo-3-chloropropane mg/kg ND 0.50 05/29/15 14:22
1,2-Dibromoethane (EDB) mg/kg ND 0.050 05/29/15 14:22
1,2-Dichlorobenzene mg/kg ND 0.050 05/29/15 14:22
1,2-Dichloroethane mg/kg ND 0.050 05/29/15 14:22
1,2-Dichloropropane mg/kg ND 0.050 05/29/15 14:22
1,3,5-Trimethylbenzene mg/kg ND 0.050 05/29/15 14:22
1,3-Dichlorobenzene mg/kg ND 0.050 05/29/15 14:22
1,3-Dichloropropane mg/kg ND 0.050 05/29/15 14:22
1,4-Dichlorobenzene mg/kg ND 0.050 05/29/15 14:22
2,2-Dichloropropane mg/kg ND 0.20 05/29/15 14:22
2-Butanone (MEK) mg/kg ND 0.25 05/29/15 14:22
2-Chlorotoluene mg/kg ND 0.050 05/29/15 14:22
4-Chlorotoluene mg/kg ND 0.050 05/29/15 14:22
4-Methyl-2-pentanone (MIBK) mg/kg ND 0.25 05/29/15 14:22
Acetone mg/kg ND 1.0 05/29/15 14:22
Allyl chloride mg/kg ND 0.20 05/29/15 14:22
Benzene mg/kg ND 0.020 05/29/15 14:22
Bromobenzene mg/kg ND 0.050 05/29/15 14:22
Bromochloromethane mg/kg ND 0.050 05/29/15 14:22
Bromodichloromethane mg/kg ND 0.050 05/29/15 14:22
Bromoform mg/kg ND 0.20 05/29/15 14:22
Bromomethane mg/kg ND 0.50 05/29/15 14:22
Carbon tetrachloride mg/kg ND 0.050 05/29/15 14:22
Chlorobenzene mg/kg ND 0.050 05/29/15 14:22
Chloroethane mg/kg ND 0.50 05/29/15 14:22
Chloroform mg/kg ND 0.050 05/29/15 14:22
Chloromethane mg/kg ND 0.20 05/29/15 14:22
cis-1,2-Dichloroethene mg/kg ND 0.050 05/29/15 14:22
cis-1,3-Dichloropropene mg/kg ND 0.050 05/29/15 14:22
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 45 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1978671
Associated Lab Samples: 10307337005, 10307337006, 10307337007
Matrix: Solid
Analyzed
Dibromochloromethane mg/kg ND 0.050 05/29/15 14:22
Dibromomethane mg/kg ND 0.050 05/29/15 14:22
Dichlorodifluoromethane mg/kg ND 0.20 05/29/15 14:22
Dichlorofluoromethane mg/kg ND 0.50 05/29/15 14:22
Diethyl ether (Ethyl ether) mg/kg ND 0.20 05/29/15 14:22
Ethylbenzene mg/kg ND 0.050 05/29/15 14:22
Hexachloro-1,3-butadiene mg/kg ND 0.25 05/29/15 14:22
Isopropylbenzene (Cumene) mg/kg ND 0.050 05/29/15 14:22
Methyl-tert-butyl ether mg/kg ND 0.050 05/29/15 14:22
Methylene Chloride mg/kg ND 0.20 05/29/15 14:22
n-Butylbenzene mg/kg ND 0.050 05/29/15 14:22
n-Propylbenzene mg/kg ND 0.050 05/29/15 14:22
Naphthalene mg/kg ND 0.20 05/29/15 14:22
p-Isopropyltoluene mg/kg ND 0.050 05/29/15 14:22
sec-Butylbenzene mg/kg ND 0.050 05/29/15 14:22
Styrene mg/kg ND 0.050 05/29/15 14:22
tert-Butylbenzene mg/kg ND 0.050 05/29/15 14:22
Tetrachloroethene mg/kg ND 0.050 05/29/15 14:22
Tetrahydrofuran mg/kg ND 2.0 05/29/15 14:22
Toluene mg/kg ND 0.050 05/29/15 14:22
trans-1,2-Dichloroethene mg/kg ND 0.050 05/29/15 14:22
trans-1,3-Dichloropropene mg/kg ND 0.050 05/29/15 14:22
Trichloroethene mg/kg ND 0.050 05/29/15 14:22
Trichlorofluoromethane mg/kg ND 0.20 05/29/15 14:22
Vinyl chloride mg/kg ND 0.020 05/29/15 14:22
Xylene (Total) mg/kg ND 0.15 05/29/15 14:22
1,2-Dichloroethane-d4 (S) %. 102 55-150 05/29/15 14:22
4-Bromofluorobenzene (S) %. 102 54-131 05/29/15 14:22
Toluene-d8 (S) %. 98 61-125 05/29/15 14:22
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1978672LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane mg/kg 0.801 80 75-125
1,1,1-Trichloroethane mg/kg 0.731 73 66-125
1,1,2,2-Tetrachloroethane mg/kg 0.701 70 69-125
1,1,2-Trichloroethane mg/kg 0.761 76 75-125
1,1,2-Trichlorotrifluoroethane mg/kg 0.831 83 55-125
1,1-Dichloroethane mg/kg 0.791 79 67-125
1,1-Dichloroethene mg/kg 0.751 75 62-125
1,1-Dichloropropene mg/kg 0.731 73 65-125
1,2,3-Trichlorobenzene mg/kg 0.691 69 58-132
1,2,3-Trichloropropane mg/kg 0.731 73 71-125
1,2,4-Trichlorobenzene mg/kg 0.721 72 63-128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 46 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1978672LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene mg/kg 0.781 78 74-125
1,2-Dibromo-3-chloropropane mg/kg 1.52.5 60 55-142
1,2-Dibromoethane (EDB) mg/kg 0.761 76 75-125
1,2-Dichlorobenzene mg/kg 0.821 82 75-125
1,2-Dichloroethane mg/kg 0.761 76 71-125
1,2-Dichloropropane mg/kg 0.791 79 74-125
1,3,5-Trimethylbenzene mg/kg 0.801 80 72-125
1,3-Dichlorobenzene mg/kg 0.781 78 75-125
1,3-Dichloropropane mg/kg 0.751 75 75-125
1,4-Dichlorobenzene mg/kg 0.771 77 75-125
2,2-Dichloropropane mg/kg 0.681 68 45-125
2-Butanone (MEK) mg/kg 3.05 60 39-136
2-Chlorotoluene mg/kg 0.811 81 73-125
4-Chlorotoluene mg/kg 0.791 79 74-125
4-Methyl-2-pentanone (MIBK) mg/kg 3.25 64 55-132
Acetone mg/kg 4.25 85 55-131
Allyl chloride mg/kg 0.751 75 53-125
Benzene mg/kg 0.771 77 69-125
Bromobenzene mg/kg 0.801 80 75-125
Bromochloromethane mg/kg 0.801 80 75-125
Bromodichloromethane mg/kg 0.771 77 75-125
Bromoform mg/kg 0.721 72 71-125
Bromomethane mg/kg 0.851 85 42-150
Carbon tetrachloride mg/kg 0.751 75 62-125
Chlorobenzene mg/kg 0.761 76 75-125
Chloroethane mg/kg 1.11 106 41-150
Chloroform mg/kg 0.781 78 72-125
Chloromethane mg/kg 0.681 68 50-125
cis-1,2-Dichloroethene mg/kg 0.751 75 73-125
cis-1,3-Dichloropropene mg/kg 0.791 79 74-125
Dibromochloromethane mg/kg 0.751 75 75-125
Dibromomethane mg/kg 0.801 80 75-125
Dichlorodifluoromethane mg/kg 0.691 69 30-125
Dichlorofluoromethane mg/kg 0.861 86 30-150
Diethyl ether (Ethyl ether) mg/kg 0.791 79 58-125
Ethylbenzene mg/kg 0.781 78 72-125
Hexachloro-1,3-butadiene mg/kg 0.661 66 59-138
Isopropylbenzene (Cumene) mg/kg 0.761 76 72-125
Methyl-tert-butyl ether mg/kg 0.751 75 72-125
Methylene Chloride mg/kg 0.741 74 71-125
n-Butylbenzene mg/kg 0.741 74 65-125
n-Propylbenzene mg/kg 0.801 80 71-125
Naphthalene mg/kg 0.651 65 55-139
p-Isopropyltoluene mg/kg 0.791 79 69-125
sec-Butylbenzene mg/kg 0.781 78 68-125
Styrene mg/kg 0.781 78 75-125
tert-Butylbenzene mg/kg 0.791 79 70-125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 47 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1978672LABORATORY CONTROL SAMPLE:
LCSSpike
Tetrachloroethene mg/kg 0.761 76 69-125
Tetrahydrofuran mg/kg 8.210 82 62-129
Toluene mg/kg 0.751 75 72-125
trans-1,2-Dichloroethene mg/kg 0.691 69 68-125
trans-1,3-Dichloropropene mg/kg 0.741 74 74-125
Trichloroethene mg/kg 0.741 74 72-125
Trichlorofluoromethane mg/kg 0.811 81 30-150
Vinyl chloride mg/kg 0.691 69 53-125
Xylene (Total) mg/kg 2.43 78 74-125
1,2-Dichloroethane-d4 (S) %. 101 55-150
4-Bromofluorobenzene (S) %. 103 54-131
Toluene-d8 (S) %. 99 61-125
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1978673MATRIX SPIKE SAMPLE:
MSSpike
Result
10307014011
1,1,1,2-Tetrachloroethane mg/kg 1.01.2 85 62-150ND
1,1,1-Trichloroethane mg/kg 1.11.2 92 58-150ND
1,1,2,2-Tetrachloroethane mg/kg 0.921.2 76 30-150ND
1,1,2-Trichloroethane mg/kg 1.11.2 89 61-149ND
1,1,2-Trichlorotrifluoroethane mg/kg 1.51.2 122 45-150ND
1,1-Dichloroethane mg/kg 1.21.2 98 56-150ND
1,1-Dichloroethene mg/kg 1.21.2 98 48-150ND
1,1-Dichloropropene mg/kg 1.31.2 108 58-150ND
1,2,3-Trichlorobenzene mg/kg 1.11.2 88 55-150ND
1,2,3-Trichloropropane mg/kg 1.11.2 90 57-148ND
1,2,4-Trichlorobenzene mg/kg 1.11.2 89 61-150ND
1,2,4-Trimethylbenzene mg/kg 1.21.2 98 64-150ND
1,2-Dibromo-3-chloropropane mg/kg 2.83.1 91 40-150ND
1,2-Dibromoethane (EDB) mg/kg 1.11.2 92 62-147ND
1,2-Dichlorobenzene mg/kg 1.11.2 89 73-133ND
1,2-Dichloroethane mg/kg 1.11.2 93 63-132ND
1,2-Dichloropropane mg/kg 1.21.2 96 69-127ND
1,3,5-Trimethylbenzene mg/kg 1.21.2 97 63-137ND
1,3-Dichlorobenzene mg/kg 1.11.2 91 69-133ND
1,3-Dichloropropane mg/kg 1.11.2 92 70-130ND
1,4-Dichlorobenzene mg/kg 1.11.2 91 69-130ND
2,2-Dichloropropane mg/kg 1.11.2 94 54-135ND
2-Butanone (MEK) mg/kg 5.86.1 96 49-145ND
2-Chlorotoluene mg/kg 1.21.2 97 68-129ND
4-Chlorotoluene mg/kg 1.21.2 96 67-134ND
4-Methyl-2-pentanone (MIBK) mg/kg 5.56.1 91 60-150ND
Acetone mg/kg 4.66.1 76 65-135ND
Allyl chloride mg/kg 1.31.2 103 55-126ND
Benzene mg/kg 1.31.2 104 63-126ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 48 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1978673MATRIX SPIKE SAMPLE:
MSSpike
Result
10307014011
Bromobenzene mg/kg 1.11.2 87 68-133ND
Bromochloromethane mg/kg 1.11.2 94 66-130ND
Bromodichloromethane mg/kg 1.11.2 90 68-129ND
Bromoform mg/kg 0.961.2 79 63-135ND
Bromomethane mg/kg 1.21.2 102 30-150ND
Carbon tetrachloride mg/kg 1.21.2 99 56-140ND
Chlorobenzene mg/kg 1.11.2 92 69-130ND
Chloroethane mg/kg 1.01.2 83 46-150ND
Chloroform mg/kg 1.11.2 91 70-127ND
Chloromethane mg/kg 0.861.2 70 51-125ND
cis-1,2-Dichloroethene mg/kg 1.21.2 96 68-125ND
cis-1,3-Dichloropropene mg/kg 1.21.2 96 67-126ND
Dibromochloromethane mg/kg 1.11.2 88 66-135ND
Dibromomethane mg/kg 1.11.2 88 68-132ND
Dichlorodifluoromethane mg/kg 0.601.2 50 30-138ND
Dichlorofluoromethane mg/kg 1.6 CH1.2 130 30-150ND
Diethyl ether (Ethyl ether) mg/kg 1.21.2 95 56-135ND
Ethylbenzene mg/kg 1.21.2 97 69-126ND
Hexachloro-1,3-butadiene mg/kg 1.01.2 85 50-150ND
Isopropylbenzene (Cumene) mg/kg 1.11.2 92 65-135ND
Methyl-tert-butyl ether mg/kg 1.11.2 90 66-129ND
Methylene Chloride mg/kg 1.21.2 99 64-125ND
n-Butylbenzene mg/kg 1.21.2 96 62-141ND
n-Propylbenzene mg/kg 1.21.2 101 65-135ND
Naphthalene mg/kg 1.11.2 94 62-150ND
p-Isopropyltoluene mg/kg 1.21.2 96 62-139ND
sec-Butylbenzene mg/kg 1.21.2 96 64-137ND
Styrene mg/kg 1.11.2 90 70-132ND
tert-Butylbenzene mg/kg 1.11.2 92 65-136ND
Tetrachloroethene mg/kg 1.21.2 96 61-142ND
Tetrahydrofuran mg/kg 9.412.1 78 68-138ND
Toluene mg/kg 1.21.2 96 66-128ND
trans-1,2-Dichloroethene mg/kg 1.41.2 113 63-129ND
trans-1,3-Dichloropropene mg/kg 1.21.2 95 67-132ND
Trichloroethene mg/kg 1.31.2 106 52-150ND
Trichlorofluoromethane mg/kg 1.4 CH1.2 111 39-150ND
Vinyl chloride mg/kg 0.971.2 80 50-125ND
Xylene (Total) mg/kg 3.43.7 94 70-130ND
1,2-Dichloroethane-d4 (S) %. 102 55-150
4-Bromofluorobenzene (S) %. 104 54-131
Toluene-d8 (S) %. 103 61-125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 49 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10307014012
1978674SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane mg/kg ND 30ND
1,1,1-Trichloroethane mg/kg ND 30ND
1,1,2,2-Tetrachloroethane mg/kg ND 30ND
1,1,2-Trichloroethane mg/kg ND 30ND
1,1,2-Trichlorotrifluoroethane mg/kg ND 30ND
1,1-Dichloroethane mg/kg ND 30ND
1,1-Dichloroethene mg/kg ND 30ND
1,1-Dichloropropene mg/kg ND 30ND
1,2,3-Trichlorobenzene mg/kg ND 30ND
1,2,3-Trichloropropane mg/kg ND 30ND
1,2,4-Trichlorobenzene mg/kg ND 30ND
1,2,4-Trimethylbenzene mg/kg ND 30ND
1,2-Dibromo-3-chloropropane mg/kg ND 30ND
1,2-Dibromoethane (EDB) mg/kg ND 30ND
1,2-Dichlorobenzene mg/kg ND 30ND
1,2-Dichloroethane mg/kg ND 30ND
1,2-Dichloropropane mg/kg ND 30ND
1,3,5-Trimethylbenzene mg/kg ND 30ND
1,3-Dichlorobenzene mg/kg ND 30ND
1,3-Dichloropropane mg/kg ND 30ND
1,4-Dichlorobenzene mg/kg ND 30ND
2,2-Dichloropropane mg/kg ND 30ND
2-Butanone (MEK) mg/kg ND 30ND
2-Chlorotoluene mg/kg ND 30ND
4-Chlorotoluene mg/kg ND 30ND
4-Methyl-2-pentanone (MIBK) mg/kg ND 30ND
Acetone mg/kg ND 30ND
Allyl chloride mg/kg ND 30ND
Benzene mg/kg ND 30ND
Bromobenzene mg/kg ND 30ND
Bromochloromethane mg/kg ND 30ND
Bromodichloromethane mg/kg ND 30ND
Bromoform mg/kg ND 30ND
Bromomethane mg/kg ND 30ND
Carbon tetrachloride mg/kg ND 30ND
Chlorobenzene mg/kg ND 30ND
Chloroethane mg/kg ND 30ND
Chloroform mg/kg ND 30ND
Chloromethane mg/kg ND 30ND
cis-1,2-Dichloroethene mg/kg ND 30ND
cis-1,3-Dichloropropene mg/kg ND 30ND
Dibromochloromethane mg/kg ND 30ND
Dibromomethane mg/kg ND 30ND
Dichlorodifluoromethane mg/kg ND 30ND
Dichlorofluoromethane mg/kg ND 30ND
Diethyl ether (Ethyl ether) mg/kg ND 30ND
Ethylbenzene mg/kg ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 50 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10307014012
1978674SAMPLE DUPLICATE:
Hexachloro-1,3-butadiene mg/kg ND 30ND
Isopropylbenzene (Cumene) mg/kg ND 30ND
Methyl-tert-butyl ether mg/kg ND 30ND
Methylene Chloride mg/kg ND 30ND
n-Butylbenzene mg/kg ND 30ND
n-Propylbenzene mg/kg ND 30ND
Naphthalene mg/kg ND 30ND
p-Isopropyltoluene mg/kg ND 30ND
sec-Butylbenzene mg/kg ND 30ND
Styrene mg/kg ND 30ND
tert-Butylbenzene mg/kg ND 30ND
Tetrachloroethene mg/kg ND 30ND
Tetrahydrofuran mg/kg ND 30ND
Toluene mg/kg ND 30ND
trans-1,2-Dichloroethene mg/kg ND 30ND
trans-1,3-Dichloropropene mg/kg ND 30ND
Trichloroethene mg/kg ND 30ND
Trichlorofluoromethane mg/kg ND 30ND
Vinyl chloride mg/kg ND 30ND
Xylene (Total) mg/kg ND 30ND
1,2-Dichloroethane-d4 (S) %. 99 297
4-Bromofluorobenzene (S) %. 101 299
Toluene-d8 (S) %. 96 297
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 51 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/31613
EPA 5035/5030B
EPA 8260B
8260B MSV 5030 Med Level
Associated Lab Samples: 10307337016, 10307337018
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1981205
Associated Lab Samples: 10307337016, 10307337018
Matrix: Solid
Analyzed
1,1,1,2-Tetrachloroethane mg/kg ND 0.050 06/01/15 15:54
1,1,1-Trichloroethane mg/kg ND 0.050 06/01/15 15:54
1,1,2,2-Tetrachloroethane mg/kg ND 0.050 06/01/15 15:54
1,1,2-Trichloroethane mg/kg ND 0.050 06/01/15 15:54
1,1,2-Trichlorotrifluoroethane mg/kg ND 0.20 06/01/15 15:54
1,1-Dichloroethane mg/kg ND 0.050 06/01/15 15:54
1,1-Dichloroethene mg/kg ND 0.20 06/01/15 15:54
1,1-Dichloropropene mg/kg ND 0.050 06/01/15 15:54
1,2,3-Trichlorobenzene mg/kg ND 0.050 06/01/15 15:54
1,2,3-Trichloropropane mg/kg ND 0.20 06/01/15 15:54
1,2,4-Trichlorobenzene mg/kg ND 0.050 06/01/15 15:54
1,2,4-Trimethylbenzene mg/kg ND 0.050 06/01/15 15:54
1,2-Dibromo-3-chloropropane mg/kg ND 0.50 06/01/15 15:54
1,2-Dibromoethane (EDB) mg/kg ND 0.050 06/01/15 15:54
1,2-Dichlorobenzene mg/kg ND 0.050 06/01/15 15:54
1,2-Dichloroethane mg/kg ND 0.050 06/01/15 15:54
1,2-Dichloropropane mg/kg ND 0.050 06/01/15 15:54
1,3,5-Trimethylbenzene mg/kg ND 0.050 06/01/15 15:54
1,3-Dichlorobenzene mg/kg ND 0.050 06/01/15 15:54
1,3-Dichloropropane mg/kg ND 0.050 06/01/15 15:54
1,4-Dichlorobenzene mg/kg ND 0.050 06/01/15 15:54
2,2-Dichloropropane mg/kg ND 0.20 06/01/15 15:54
2-Butanone (MEK) mg/kg ND 0.25 06/01/15 15:54
2-Chlorotoluene mg/kg ND 0.050 06/01/15 15:54
4-Chlorotoluene mg/kg ND 0.050 06/01/15 15:54
4-Methyl-2-pentanone (MIBK) mg/kg ND 0.25 06/01/15 15:54
Acetone mg/kg ND 1.0 06/01/15 15:54
Allyl chloride mg/kg ND 0.20 06/01/15 15:54
Benzene mg/kg ND 0.020 06/01/15 15:54
Bromobenzene mg/kg ND 0.050 06/01/15 15:54
Bromochloromethane mg/kg ND 0.050 06/01/15 15:54
Bromodichloromethane mg/kg ND 0.050 06/01/15 15:54
Bromoform mg/kg ND 0.20 06/01/15 15:54
Bromomethane mg/kg ND 0.50 06/01/15 15:54
Carbon tetrachloride mg/kg ND 0.050 06/01/15 15:54
Chlorobenzene mg/kg ND 0.050 06/01/15 15:54
Chloroethane mg/kg ND 0.50 06/01/15 15:54
Chloroform mg/kg ND 0.050 06/01/15 15:54
Chloromethane mg/kg ND 0.20 06/01/15 15:54
cis-1,2-Dichloroethene mg/kg ND 0.050 06/01/15 15:54
cis-1,3-Dichloropropene mg/kg ND 0.050 06/01/15 15:54
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 52 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1981205
Associated Lab Samples: 10307337016, 10307337018
Matrix: Solid
Analyzed
Dibromochloromethane mg/kg ND 0.050 06/01/15 15:54
Dibromomethane mg/kg ND 0.050 06/01/15 15:54
Dichlorodifluoromethane mg/kg ND 0.20 06/01/15 15:54
Dichlorofluoromethane mg/kg ND 0.50 06/01/15 15:54
Diethyl ether (Ethyl ether) mg/kg ND 0.20 06/01/15 15:54
Ethylbenzene mg/kg ND 0.050 06/01/15 15:54
Hexachloro-1,3-butadiene mg/kg ND 0.25 06/01/15 15:54
Isopropylbenzene (Cumene) mg/kg ND 0.050 06/01/15 15:54
Methyl-tert-butyl ether mg/kg ND 0.050 06/01/15 15:54
Methylene Chloride mg/kg ND 0.20 06/01/15 15:54
n-Butylbenzene mg/kg ND 0.050 06/01/15 15:54
n-Propylbenzene mg/kg ND 0.050 06/01/15 15:54
Naphthalene mg/kg ND 0.20 06/01/15 15:54
p-Isopropyltoluene mg/kg ND 0.050 06/01/15 15:54
sec-Butylbenzene mg/kg ND 0.050 06/01/15 15:54
Styrene mg/kg ND 0.050 06/01/15 15:54
tert-Butylbenzene mg/kg ND 0.050 06/01/15 15:54
Tetrachloroethene mg/kg ND 0.050 06/01/15 15:54
Tetrahydrofuran mg/kg ND 2.0 06/01/15 15:54
Toluene mg/kg ND 0.050 06/01/15 15:54
trans-1,2-Dichloroethene mg/kg ND 0.050 06/01/15 15:54
trans-1,3-Dichloropropene mg/kg ND 0.050 06/01/15 15:54
Trichloroethene mg/kg ND 0.050 06/01/15 15:54
Trichlorofluoromethane mg/kg ND 0.20 06/01/15 15:54
Vinyl chloride mg/kg ND 0.020 06/01/15 15:54
Xylene (Total) mg/kg ND 0.15 06/01/15 15:54
1,2-Dichloroethane-d4 (S) %. 101 55-150 06/01/15 15:54
4-Bromofluorobenzene (S) %. 106 54-131 06/01/15 15:54
Toluene-d8 (S) %. 103 61-125 06/01/15 15:54
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1981206LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane mg/kg 1.01 101 75-125
1,1,1-Trichloroethane mg/kg 1.01 102 66-125
1,1,2,2-Tetrachloroethane mg/kg 0.981 98 69-125
1,1,2-Trichloroethane mg/kg 1.01 104 75-125
1,1,2-Trichlorotrifluoroethane mg/kg 1.21 118 55-125
1,1-Dichloroethane mg/kg 1.11 109 67-125
1,1-Dichloroethene mg/kg 1.11 106 62-125
1,1-Dichloropropene mg/kg 1.11 107 65-125
1,2,3-Trichlorobenzene mg/kg 0.981 98 58-132
1,2,3-Trichloropropane mg/kg 1.01 101 71-125
1,2,4-Trichlorobenzene mg/kg 0.961 96 63-128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 53 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1981206LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene mg/kg 1.11 106 74-125
1,2-Dibromo-3-chloropropane mg/kg 2.32.5 93 55-142
1,2-Dibromoethane (EDB) mg/kg 1.01 103 75-125
1,2-Dichlorobenzene mg/kg 1.01 102 75-125
1,2-Dichloroethane mg/kg 1.11 111 71-125
1,2-Dichloropropane mg/kg 1.11 111 74-125
1,3,5-Trimethylbenzene mg/kg 1.11 107 72-125
1,3-Dichlorobenzene mg/kg 1.01 105 75-125
1,3-Dichloropropane mg/kg 1.11 106 75-125
1,4-Dichlorobenzene mg/kg 1.11 110 75-125
2,2-Dichloropropane mg/kg 1.01 102 45-125
2-Butanone (MEK) mg/kg 6.25 124 39-136
2-Chlorotoluene mg/kg 1.11 108 73-125
4-Chlorotoluene mg/kg 1.11 113 74-125
4-Methyl-2-pentanone (MIBK) mg/kg 5.95 119 55-132
Acetone mg/kg 5.75 115 55-131
Allyl chloride mg/kg 1.11 109 53-125
Benzene mg/kg 1.21 120 69-125
Bromobenzene mg/kg 1.11 106 75-125
Bromochloromethane mg/kg 1.11 108 75-125
Bromodichloromethane mg/kg 1.11 106 75-125
Bromoform mg/kg 1.01 101 71-125
Bromomethane mg/kg 0.901 90 42-150
Carbon tetrachloride mg/kg 0.971 97 62-125
Chlorobenzene mg/kg 1.11 108 75-125
Chloroethane mg/kg 0.981 98 41-150
Chloroform mg/kg 1.11 105 72-125
Chloromethane mg/kg 0.881 88 50-125
cis-1,2-Dichloroethene mg/kg 1.11 109 73-125
cis-1,3-Dichloropropene mg/kg 1.11 110 74-125
Dibromochloromethane mg/kg 1.01 102 75-125
Dibromomethane mg/kg 1.01 104 75-125
Dichlorodifluoromethane mg/kg 0.501 50 30-125
Dichlorofluoromethane mg/kg 1.2 CH1 118 30-150
Diethyl ether (Ethyl ether) mg/kg 1.21 116 58-125
Ethylbenzene mg/kg 1.11 111 72-125
Hexachloro-1,3-butadiene mg/kg 0.951 95 59-138
Isopropylbenzene (Cumene) mg/kg 1.01 100 72-125
Methyl-tert-butyl ether mg/kg 1.11 110 72-125
Methylene Chloride mg/kg 1.11 106 71-125
n-Butylbenzene mg/kg 1.01 101 65-125
n-Propylbenzene mg/kg 1.11 111 71-125
Naphthalene mg/kg 1.01 101 55-139
p-Isopropyltoluene mg/kg 1.11 109 69-125
sec-Butylbenzene mg/kg 1.01 101 68-125
Styrene mg/kg 1.11 109 75-125
tert-Butylbenzene mg/kg 1.11 106 70-125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 54 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1981206LABORATORY CONTROL SAMPLE:
LCSSpike
Tetrachloroethene mg/kg 1.01 100 69-125
Tetrahydrofuran mg/kg 10.210 102 62-129
Toluene mg/kg 1.11 107 72-125
trans-1,2-Dichloroethene mg/kg 1.3 L01 126 68-125
trans-1,3-Dichloropropene mg/kg 1.11 108 74-125
Trichloroethene mg/kg 1.11 114 72-125
Trichlorofluoromethane mg/kg 1.0 CH1 103 30-150
Vinyl chloride mg/kg 0.831 83 53-125
Xylene (Total) mg/kg 3.33 109 74-125
1,2-Dichloroethane-d4 (S) %. 99 55-150
4-Bromofluorobenzene (S) %. 105 54-131
Toluene-d8 (S) %. 100 61-125
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1981207MATRIX SPIKE SAMPLE:
MSSpike
Result
10307379001
1,1,1,2-Tetrachloroethane mg/kg 1.11.1 102 62-150ND
1,1,1-Trichloroethane mg/kg 1.21.1 109 58-150ND
1,1,2,2-Tetrachloroethane mg/kg 1.11.1 106 30-150ND
1,1,2-Trichloroethane mg/kg 1.21.1 110 61-149ND
1,1,2-Trichlorotrifluoroethane mg/kg 1.41.1 127 45-150ND
1,1-Dichloroethane mg/kg 1.21.1 115 56-150ND
1,1-Dichloroethene mg/kg 1.21.1 110 48-150ND
1,1-Dichloropropene mg/kg 1.31.1 122 58-150ND
1,2,3-Trichlorobenzene mg/kg 1.11.1 100 55-150ND
1,2,3-Trichloropropane mg/kg 1.21.1 111 57-148ND
1,2,4-Trichlorobenzene mg/kg 1.11.1 99 61-150ND
1,2,4-Trimethylbenzene mg/kg 1.31.1 116 64-150ND
1,2-Dibromo-3-chloropropane mg/kg 2.82.7 104 40-150ND
1,2-Dibromoethane (EDB) mg/kg 1.21.1 109 62-147ND
1,2-Dichlorobenzene mg/kg 1.21.1 108 73-133ND
1,2-Dichloroethane mg/kg 1.21.1 114 63-132ND
1,2-Dichloropropane mg/kg 1.21.1 114 69-127ND
1,3,5-Trimethylbenzene mg/kg 1.31.1 116 63-137ND
1,3-Dichlorobenzene mg/kg 1.21.1 107 69-133ND
1,3-Dichloropropane mg/kg 1.21.1 111 70-130ND
1,4-Dichlorobenzene mg/kg 1.21.1 108 69-130ND
2,2-Dichloropropane mg/kg 1.21.1 108 54-135ND
2-Butanone (MEK) mg/kg 6.95.4 128 49-145ND
2-Chlorotoluene mg/kg 1.31.1 117 68-129ND
4-Chlorotoluene mg/kg 1.21.1 115 67-134ND
4-Methyl-2-pentanone (MIBK) mg/kg 6.65.4 121 60-150ND
Acetone mg/kg 5.75.4 106 65-135ND
Allyl chloride mg/kg 1.31.1 117 55-126ND
Benzene mg/kg 1.31.1 123 63-126ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 55 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1981207MATRIX SPIKE SAMPLE:
MSSpike
Result
10307379001
Bromobenzene mg/kg 1.11.1 104 68-133ND
Bromochloromethane mg/kg 1.21.1 112 66-130ND
Bromodichloromethane mg/kg 1.21.1 109 68-129ND
Bromoform mg/kg 1.11.1 101 63-135ND
Bromomethane mg/kg 1.11.1 96 30-150ND
Carbon tetrachloride mg/kg 1.21.1 113 56-140ND
Chlorobenzene mg/kg 1.21.1 108 69-130ND
Chloroethane mg/kg 0.961.1 89 46-150ND
Chloroform mg/kg 1.21.1 109 70-127ND
Chloromethane mg/kg 1.01.1 91 51-125ND
cis-1,2-Dichloroethene mg/kg 1.21.1 115 68-125ND
cis-1,3-Dichloropropene mg/kg 1.21.1 114 67-126ND
Dibromochloromethane mg/kg 1.21.1 106 66-135ND
Dibromomethane mg/kg 1.21.1 107 68-132ND
Dichlorodifluoromethane mg/kg 0.801.1 74 30-138ND
Dichlorofluoromethane mg/kg 1.3 CH1.1 117 30-150ND
Diethyl ether (Ethyl ether) mg/kg 1.31.1 122 56-135ND
Ethylbenzene mg/kg 1.21.1 114 69-126ND
Hexachloro-1,3-butadiene mg/kg 0.991.1 91 50-150ND
Isopropylbenzene (Cumene) mg/kg 1.21.1 107 65-135ND
Methyl-tert-butyl ether mg/kg 1.31.1 118 66-129ND
Methylene Chloride mg/kg 1.31.1 117 64-125ND
n-Butylbenzene mg/kg 1.21.1 107 62-141ND
n-Propylbenzene mg/kg 1.31.1 118 65-135ND
Naphthalene mg/kg 1.21.1 110 62-150ND
p-Isopropyltoluene mg/kg 1.21.1 112 62-139ND
sec-Butylbenzene mg/kg 1.21.1 112 64-137ND
Styrene mg/kg 1.21.1 108 70-132ND
tert-Butylbenzene mg/kg 1.21.1 110 65-136ND
Tetrachloroethene mg/kg 1.21.1 108 61-142ND
Tetrahydrofuran mg/kg 11.910.9 110 68-138ND
Toluene mg/kg 1.21.1 113 66-128ND
trans-1,2-Dichloroethene mg/kg 1.31.1 123 63-129ND
trans-1,3-Dichloropropene mg/kg 1.21.1 110 67-132ND
Trichloroethene mg/kg 1.21.1 115 52-150ND
Trichlorofluoromethane mg/kg 1.1 CH1.1 103 39-150ND
Vinyl chloride mg/kg 1.01.1 93 50-125ND
Xylene (Total) mg/kg 3.63.2 110 70-130ND
1,2-Dichloroethane-d4 (S) %. 103 55-150
4-Bromofluorobenzene (S) %. 105 54-131
Toluene-d8 (S) %. 103 61-125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 56 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10307379002
1981208SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane mg/kg ND 30ND
1,1,1-Trichloroethane mg/kg ND 30ND
1,1,2,2-Tetrachloroethane mg/kg ND 30ND
1,1,2-Trichloroethane mg/kg ND 30ND
1,1,2-Trichlorotrifluoroethane mg/kg ND 30ND
1,1-Dichloroethane mg/kg ND 30ND
1,1-Dichloroethene mg/kg ND 30ND
1,1-Dichloropropene mg/kg ND 30ND
1,2,3-Trichlorobenzene mg/kg ND 30ND
1,2,3-Trichloropropane mg/kg ND 30ND
1,2,4-Trichlorobenzene mg/kg ND 30ND
1,2,4-Trimethylbenzene mg/kg ND 30ND
1,2-Dibromo-3-chloropropane mg/kg ND 30ND
1,2-Dibromoethane (EDB) mg/kg ND 30ND
1,2-Dichlorobenzene mg/kg ND 30ND
1,2-Dichloroethane mg/kg ND 30ND
1,2-Dichloropropane mg/kg ND 30ND
1,3,5-Trimethylbenzene mg/kg ND 30ND
1,3-Dichlorobenzene mg/kg ND 30ND
1,3-Dichloropropane mg/kg ND 30ND
1,4-Dichlorobenzene mg/kg ND 30ND
2,2-Dichloropropane mg/kg ND 30ND
2-Butanone (MEK) mg/kg .18J 30ND
2-Chlorotoluene mg/kg ND 30ND
4-Chlorotoluene mg/kg ND 30ND
4-Methyl-2-pentanone (MIBK) mg/kg ND 30ND
Acetone mg/kg ND 30ND
Allyl chloride mg/kg ND 30ND
Benzene mg/kg ND 30ND
Bromobenzene mg/kg ND 30ND
Bromochloromethane mg/kg ND 30ND
Bromodichloromethane mg/kg ND 30ND
Bromoform mg/kg ND 30ND
Bromomethane mg/kg ND 30ND
Carbon tetrachloride mg/kg ND 30ND
Chlorobenzene mg/kg ND 30ND
Chloroethane mg/kg ND 30ND
Chloroform mg/kg .014J 30ND
Chloromethane mg/kg .013J 30ND
cis-1,2-Dichloroethene mg/kg ND 30ND
cis-1,3-Dichloropropene mg/kg ND 30ND
Dibromochloromethane mg/kg ND 30ND
Dibromomethane mg/kg ND 30ND
Dichlorodifluoromethane mg/kg ND 30ND
Dichlorofluoromethane mg/kg ND 30ND
Diethyl ether (Ethyl ether) mg/kg ND 30ND
Ethylbenzene mg/kg ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 57 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10307379002
1981208SAMPLE DUPLICATE:
Hexachloro-1,3-butadiene mg/kg ND 30ND
Isopropylbenzene (Cumene) mg/kg ND 30ND
Methyl-tert-butyl ether mg/kg ND 30ND
Methylene Chloride mg/kg ND 30ND
n-Butylbenzene mg/kg ND 30ND
n-Propylbenzene mg/kg ND 30ND
Naphthalene mg/kg ND 30ND
p-Isopropyltoluene mg/kg ND 30ND
sec-Butylbenzene mg/kg ND 30ND
Styrene mg/kg ND 30ND
tert-Butylbenzene mg/kg ND 30ND
Tetrachloroethene mg/kg ND 30ND
Tetrahydrofuran mg/kg ND 30ND
Toluene mg/kg ND 30ND
trans-1,2-Dichloroethene mg/kg ND 30ND
trans-1,3-Dichloropropene mg/kg ND 30ND
Trichloroethene mg/kg ND 30ND
Trichlorofluoromethane mg/kg ND 30ND
Vinyl chloride mg/kg ND 30ND
Xylene (Total) mg/kg ND 30ND
1,2-Dichloroethane-d4 (S) %. 100 8100
4-Bromofluorobenzene (S) %. 119 0110
Toluene-d8 (S) %. 101 10103
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 58 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/31527
EPA 8260B
EPA 8260B
8260B MSV 465 W
Associated Lab Samples: 10307337013, 10307337017, 10307337019, 10307337020
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1975160
Associated Lab Samples: 10307337013, 10307337017, 10307337019, 10307337020
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 1.0 05/26/15 00:14
1,1,1-Trichloroethane ug/L ND 1.0 05/26/15 00:14
1,1,2,2-Tetrachloroethane ug/L ND 1.0 05/26/15 00:14
1,1,2-Trichloroethane ug/L ND 1.0 05/26/15 00:14
1,1,2-Trichlorotrifluoroethane ug/L ND 1.0 05/26/15 00:14
1,1-Dichloroethane ug/L ND 1.0 05/26/15 00:14
1,1-Dichloroethene ug/L ND 1.0 05/26/15 00:14
1,1-Dichloropropene ug/L ND 1.0 05/26/15 00:14
1,2,3-Trichlorobenzene ug/L ND 1.0 05/26/15 00:14
1,2,3-Trichloropropane ug/L ND 4.0 05/26/15 00:14
1,2,4-Trichlorobenzene ug/L ND 1.0 05/26/15 00:14
1,2,4-Trimethylbenzene ug/L ND 1.0 05/26/15 00:14
1,2-Dibromo-3-chloropropane ug/L ND 10.0 05/26/15 00:14
1,2-Dibromoethane (EDB) ug/L ND 1.0 05/26/15 00:14
1,2-Dichlorobenzene ug/L ND 1.0 05/26/15 00:14
1,2-Dichloroethane ug/L ND 1.0 05/26/15 00:14
1,2-Dichloropropane ug/L ND 4.0 05/26/15 00:14
1,3,5-Trimethylbenzene ug/L ND 1.0 05/26/15 00:14
1,3-Dichlorobenzene ug/L ND 1.0 05/26/15 00:14
1,3-Dichloropropane ug/L ND 1.0 05/26/15 00:14
1,4-Dichlorobenzene ug/L ND 1.0 05/26/15 00:14
2,2-Dichloropropane ug/L ND 4.0 05/26/15 00:14
2-Butanone (MEK) ug/L ND 5.0 05/26/15 00:14
2-Chlorotoluene ug/L ND 1.0 05/26/15 00:14
4-Chlorotoluene ug/L ND 1.0 05/26/15 00:14
4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 05/26/15 00:14
Acetone ug/L ND 20.0 05/26/15 00:14
Allyl chloride ug/L ND 4.0 05/26/15 00:14
Benzene ug/L ND 1.0 05/26/15 00:14
Bromobenzene ug/L ND 1.0 05/26/15 00:14
Bromochloromethane ug/L ND 1.0 05/26/15 00:14
Bromodichloromethane ug/L ND 1.0 05/26/15 00:14
Bromoform ug/L ND 4.0 05/26/15 00:14
Bromomethane ug/L ND 10.0 05/26/15 00:14
Carbon tetrachloride ug/L ND 1.0 05/26/15 00:14
Chlorobenzene ug/L ND 1.0 05/26/15 00:14
Chloroethane ug/L ND 1.0 05/26/15 00:14
Chloroform ug/L ND 1.0 05/26/15 00:14
Chloromethane ug/L ND 4.0 05/26/15 00:14
cis-1,2-Dichloroethene ug/L ND 1.0 05/26/15 00:14
cis-1,3-Dichloropropene ug/L ND 4.0 05/26/15 00:14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 59 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1975160
Associated Lab Samples: 10307337013, 10307337017, 10307337019, 10307337020
Matrix: Water
Analyzed
Dibromochloromethane ug/L ND 1.0 05/26/15 00:14
Dibromomethane ug/L ND 4.0 05/26/15 00:14
Dichlorodifluoromethane ug/L ND 1.0 05/26/15 00:14
Dichlorofluoromethane ug/L ND 1.0 05/26/15 00:14
Diethyl ether (Ethyl ether) ug/L ND 4.0 05/26/15 00:14
Ethylbenzene ug/L ND 1.0 05/26/15 00:14
Hexachloro-1,3-butadiene ug/L ND 1.0 05/26/15 00:14
Isopropylbenzene (Cumene) ug/L ND 1.0 05/26/15 00:14
Methyl-tert-butyl ether ug/L ND 1.0 05/26/15 00:14
Methylene Chloride ug/L ND 4.0 05/26/15 00:14
n-Butylbenzene ug/L ND 1.0 05/26/15 00:14
n-Propylbenzene ug/L ND 1.0 05/26/15 00:14
Naphthalene ug/L ND 4.0 05/26/15 00:14
p-Isopropyltoluene ug/L ND 1.0 05/26/15 00:14
sec-Butylbenzene ug/L ND 1.0 05/26/15 00:14
Styrene ug/L ND 1.0 05/26/15 00:14
tert-Butylbenzene ug/L ND 1.0 05/26/15 00:14
Tetrachloroethene ug/L ND 1.0 05/26/15 00:14
Tetrahydrofuran ug/L ND 10.0 05/26/15 00:14
Toluene ug/L ND 1.0 05/26/15 00:14
trans-1,2-Dichloroethene ug/L ND 1.0 05/26/15 00:14
trans-1,3-Dichloropropene ug/L ND 4.0 05/26/15 00:14
Trichloroethene ug/L ND 0.40 05/26/15 00:14
Trichlorofluoromethane ug/L ND 1.0 05/26/15 00:14
Vinyl chloride ug/L ND 1.0 05/26/15 00:14
Xylene (Total) ug/L ND 3.0 05/26/15 00:14
1,2-Dichloroethane-d4 (S) %. 90 75-125 05/26/15 00:14
4-Bromofluorobenzene (S) %. 100 75-125 05/26/15 00:14
Toluene-d8 (S) %. 102 75-125 05/26/15 00:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1975161LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 19.720 98 75-125
1,1,1-Trichloroethane ug/L 16.320 82 75-125
1,1,2,2-Tetrachloroethane ug/L 20.220 101 75-125
1,1,2-Trichloroethane ug/L 19.720 98 75-125
1,1,2-Trichlorotrifluoroethane ug/L 14.320 71 60-135
1,1-Dichloroethane ug/L 16.420 82 69-125
1,1-Dichloroethene ug/L 15.620 78 68-125
1,1-Dichloropropene ug/L 18.020 90 74-125
1,2,3-Trichlorobenzene ug/L 19.620 98 69-136
1,2,3-Trichloropropane ug/L 18.320 91 75-125
1,2,4-Trichlorobenzene ug/L 19.320 97 73-127
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 60 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1975161LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/L 19.120 96 75-125
1,2-Dibromo-3-chloropropane ug/L 50.850 102 65-145
1,2-Dibromoethane (EDB) ug/L 18.420 92 75-125
1,2-Dichlorobenzene ug/L 18.920 94 75-125
1,2-Dichloroethane ug/L 16.920 85 73-125
1,2-Dichloropropane ug/L 17.920 89 75-125
1,3,5-Trimethylbenzene ug/L 18.420 92 75-125
1,3-Dichlorobenzene ug/L 19.720 98 74-125
1,3-Dichloropropane ug/L 22.020 110 75-125
1,4-Dichlorobenzene ug/L 19.620 98 75-125
2,2-Dichloropropane ug/L 16.320 82 59-139
2-Butanone (MEK) ug/L 97.4100 97 63-130
2-Chlorotoluene ug/L 17.820 89 72-125
4-Chlorotoluene ug/L 19.020 95 73-125
4-Methyl-2-pentanone (MIBK) ug/L 97.3100 97 71-126
Acetone ug/L 102100 102 69-131
Allyl chloride ug/L 19.120 95 67-125
Benzene ug/L 17.020 85 71-125
Bromobenzene ug/L 20.220 101 75-125
Bromochloromethane ug/L 19.220 96 75-125
Bromodichloromethane ug/L 16.820 84 75-125
Bromoform ug/L 19.220 96 70-125
Bromomethane ug/L 12.020 60 30-150
Carbon tetrachloride ug/L 15.620 78 75-126
Chlorobenzene ug/L 20.520 103 75-125
Chloroethane ug/L 17.920 89 65-134
Chloroform ug/L 17.720 89 75-125
Chloromethane ug/L 13.220 66 39-150
cis-1,2-Dichloroethene ug/L 17.720 89 72-125
cis-1,3-Dichloropropene ug/L 17.720 88 75-125
Dibromochloromethane ug/L 20.020 100 75-125
Dibromomethane ug/L 19.420 97 75-125
Dichlorodifluoromethane ug/L 15.420 77 50-134
Dichlorofluoromethane ug/L 16.420 82 69-125
Diethyl ether (Ethyl ether) ug/L 17.320 87 72-125
Ethylbenzene ug/L 17.720 89 75-125
Hexachloro-1,3-butadiene ug/L 19.620 98 70-138
Isopropylbenzene (Cumene) ug/L 18.420 92 75-125
Methyl-tert-butyl ether ug/L 18.420 92 73-125
Methylene Chloride ug/L 19.020 95 73-125
n-Butylbenzene ug/L 17.020 85 72-133
n-Propylbenzene ug/L 18.620 93 72-126
Naphthalene ug/L 23.220 116 70-127
p-Isopropyltoluene ug/L 19.220 96 72-132
sec-Butylbenzene ug/L 19.520 98 73-132
Styrene ug/L 20.420 102 75-125
tert-Butylbenzene ug/L 16.920 84 73-128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 61 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1975161LABORATORY CONTROL SAMPLE:
LCSSpike
Tetrachloroethene ug/L 18.020 90 74-125
Tetrahydrofuran ug/L 219200 109 62-133
Toluene ug/L 18.620 93 74-125
trans-1,2-Dichloroethene ug/L 15.620 78 69-125
trans-1,3-Dichloropropene ug/L 17.220 86 75-125
Trichloroethene ug/L 18.020 90 75-125
Trichlorofluoromethane ug/L 16.420 82 74-127
Vinyl chloride ug/L 16.220 81 66-132
Xylene (Total) ug/L 54.560 91 75-125
1,2-Dichloroethane-d4 (S) %. 93 75-125
4-Bromofluorobenzene (S) %. 102 75-125
Toluene-d8 (S) %. 99 75-125
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1975162MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
10306438008
1975163
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 97 70-13894 3 3020ND 19.5 18.8
1,1,1-Trichloroethane ug/L 20 102 55-150105 3 3020ND 20.4 21.0
1,1,2,2-Tetrachloroethane ug/L 20 103 64-140112 9 3020ND 20.6 22.5
1,1,2-Trichloroethane ug/L 20 90 67-13796 6 3020ND 18.1 19.2
1,1,2-Trichlorotrifluoroethane ug/L 20 91 51-15098 8 3020ND 18.1 19.6
1,1-Dichloroethane ug/L 20 103 49-15097 6 3020ND 20.7 19.4
1,1-Dichloroethene ug/L 20 89 40-150104 15 3020ND 17.8 20.7
1,1-Dichloropropene ug/L 20 101 50-15098 3 3020ND 20.1 19.6
1,2,3-Trichlorobenzene ug/L 20 101 59-14898 3 3020ND 20.1 19.6
1,2,3-Trichloropropane ug/L 20 96 65-14190 6 3020ND 19.1 18.0
1,2,4-Trichlorobenzene ug/L 20 100 61-140105 5 3020ND 19.9 21.0
1,2,4-Trimethylbenzene ug/L 20 98 58-141101 3 3020ND 19.6 20.2
1,2-Dibromo-3-chloropropane
ug/L 50 92 53-150103 12 3050ND 45.8 51.5
1,2-Dibromoethane (EDB) ug/L 20 95 65-13791 5 3020ND 19.1 18.2
1,2-Dichlorobenzene ug/L 20 92 66-13397 5 3020ND 18.5 19.5
1,2-Dichloroethane ug/L 20 91 54-13884 8 3020ND 18.2 16.8
1,2-Dichloropropane ug/L 20 106 62-138110 3 3020ND 21.3 21.9
1,3,5-Trimethylbenzene ug/L 20 95 58-14098 3 3020ND 19.0 19.5
1,3-Dichlorobenzene ug/L 20 94 66-132109 14 3020ND 18.9 21.8
1,3-Dichloropropane ug/L 20 105 66-134102 3 3020ND 21.0 20.3
1,4-Dichlorobenzene ug/L 20 97 65-12997 0 3020ND 19.4 19.4
2,2-Dichloropropane ug/L 20 102 40-15097 5 3020ND 20.4 19.5
2-Butanone (MEK) ug/L 100 90 51-14797 8 30100ND 89.7 97.2
2-Chlorotoluene ug/L 20 96 58-147102 6 3020ND 19.1 20.3
4-Chlorotoluene ug/L 20 102 64-138106 4 3020ND 20.4 21.2
4-Methyl-2-pentanone(MIBK)
ug/L 100 93 59-143102 9 30100ND 92.8 102
Acetone ug/L 100 142 63-147129 9 30100ND 142 129
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
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Page 62 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1975162MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
10306438008
1975163
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Allyl chloride ug/L 20 95 45-15099 4 3020ND 18.9 19.8
Benzene ug/L 20 94 53-13992 1 3020ND 18.7 18.4
Bromobenzene ug/L 20 105 66-136107 2 3020ND 21.0 21.5
Bromochloromethane ug/L 20 98 64-136107 9 3020ND 19.6 21.5
Bromodichloromethane ug/L 20 86 66-13895 10 3020ND 17.1 18.9
Bromoform ug/L 20 97 59-13699 3 3020ND 19.3 19.9
Bromomethane ug/L 20 61 30-15079 26 3020ND 12.2 15.8
Carbon tetrachloride ug/L 20 98 56-15098 0 3020ND 19.6 19.5
Chlorobenzene ug/L 20 104 65-13396 7 3020ND 20.8 19.3
Chloroethane ug/L 20 97 48-150116 18 3020ND 19.4 23.2
Chloroform ug/L 20 103 57-145104 2 3020ND 20.5 20.9
Chloromethane ug/L 20 78 30-15082 6 3020ND 15.5 16.5
cis-1,2-Dichloroethene ug/L 20 95 49-150100 5 3020ND 19.1 20.1
cis-1,3-Dichloropropene ug/L 20 95 64-13089 6 3020ND 19.0 17.9
Dibromochloromethane ug/L 20 100 68-138109 8 3020ND 20.0 21.7
Dibromomethane ug/L 20 100 67-13494 6 3020ND 20.0 18.8
Dichlorodifluoromethane ug/L 20 93 45-15096 3 3020ND 18.7 19.2
Dichlorofluoromethane ug/L 20 98 54-15093 5 3020ND 19.6 18.7
Diethyl ether (Ethyl ether) ug/L 20 94 50-14593 1 3020ND 18.7 18.6
Ethylbenzene ug/L 20 97 55-139100 3 3020ND 19.5 20.1
Hexachloro-1,3-butadiene ug/L 20 103 49-150115 12 3020ND 20.5 23.1
Isopropylbenzene (Cumene) ug/L 20 98 64-142105 6 3020ND 19.7 21.0
Methyl-tert-butyl ether ug/L 20 93 62-12992 1 3020ND 18.6 18.4
Methylene Chloride ug/L 20 98 57-13291 7 3020ND 19.5 18.2
n-Butylbenzene ug/L 20 100 55-15098 2 3020ND 20.1 19.6
n-Propylbenzene ug/L 20 102 59-142106 4 3020ND 20.4 21.2
Naphthalene ug/L 20 108 51-150113 5 3020ND 21.6 22.6
p-Isopropyltoluene ug/L 20 106 60-149113 6 3020ND 21.3 22.5
sec-Butylbenzene ug/L 20 100 60-150104 4 3020ND 20.0 20.7
Styrene ug/L 20 106 68-134106 1 3020ND 21.1 21.3
tert-Butylbenzene ug/L 20 95 62-146101 7 3020ND 18.9 20.3
Tetrachloroethene ug/L 20 93 50-150101 8 3020ND 18.6 20.1
Tetrahydrofuran ug/L 200 122 59-145114 7 30200ND 244 229
Toluene ug/L 20 99 52-14898 2 3020ND 19.9 19.5
trans-1,2-Dichloroethene ug/L 20 85 45-15090 5 3020ND 17.1 18.1
trans-1,3-Dichloropropene ug/L 20 88 68-13297 10 3020ND 17.6 19.4
Trichloroethene ug/L 20 98 52-150101 4 3020ND 19.5 20.2
Trichlorofluoromethane ug/L 20 87 55-150100 13 3020ND 17.5 19.9
Vinyl chloride ug/L 20 109 43-150117 7 3020ND 21.8 23.4
Xylene (Total) ug/L 60 100 54-144101 1 3060ND 60.2 60.9
1,2-Dichloroethane-d4 (S) %. 96 75-12595
4-Bromofluorobenzene (S) %. 101 75-125101
Toluene-d8 (S) %. 103 75-12599
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 63 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/29323
EPA 3550
EPA 8270D by SIM
8270D Solid PAH by SIM MSSV
Associated Lab Samples: 10307337001, 10307337002, 10307337003, 10307337004, 10307337005, 10307337008, 10307337009,10307337010, 10307337011, 10307337012, 10307337014, 10307337015, 10307337018
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1977121
Associated Lab Samples: 10307337001, 10307337002, 10307337003, 10307337004, 10307337005, 10307337008, 10307337009,10307337010, 10307337011, 10307337012, 10307337014, 10307337015, 10307337018
Matrix: Solid
Analyzed
Acenaphthene mg/kg ND 0.010 05/28/15 18:20
Acenaphthylene mg/kg ND 0.010 05/28/15 18:20
Anthracene mg/kg ND 0.010 05/28/15 18:20
Benzo(a)anthracene mg/kg ND 0.010 05/28/15 18:20
Benzo(a)pyrene mg/kg ND 0.010 05/28/15 18:20
Benzo(b)fluoranthene mg/kg ND 0.010 05/28/15 18:20
Benzo(g,h,i)perylene mg/kg ND 0.010 05/28/15 18:20
Benzo(k)fluoranthene mg/kg ND 0.010 05/28/15 18:20
Chrysene mg/kg ND 0.010 05/28/15 18:20
Dibenz(a,h)anthracene mg/kg ND 0.010 05/28/15 18:20
Fluoranthene mg/kg ND 0.010 05/28/15 18:20
Fluorene mg/kg ND 0.010 05/28/15 18:20
Indeno(1,2,3-cd)pyrene mg/kg ND 0.010 05/28/15 18:20
Naphthalene mg/kg ND 0.010 05/28/15 18:20
Phenanthrene mg/kg ND 0.010 05/28/15 18:20
Pyrene mg/kg ND 0.010 05/28/15 18:20
2-Fluorobiphenyl (S) %. 69 55-125 05/28/15 18:20
p-Terphenyl-d14 (S) %. 81 30-150 05/28/15 18:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1977122LABORATORY CONTROL SAMPLE:
LCSSpike
Acenaphthene mg/kg 0.028.033 83 53-125
Acenaphthylene mg/kg 0.027.033 80 53-125
Anthracene mg/kg 0.031.033 92 61-125
Benzo(a)anthracene mg/kg 0.028.033 84 62-125
Benzo(a)pyrene mg/kg 0.029.033 88 64-125
Benzo(b)fluoranthene mg/kg 0.030.033 90 66-125
Benzo(g,h,i)perylene mg/kg 0.028.033 85 59-125
Benzo(k)fluoranthene mg/kg 0.030.033 90 61-125
Chrysene mg/kg 0.028.033 84 63-125
Dibenz(a,h)anthracene mg/kg 0.028.033 84 59-125
Fluoranthene mg/kg 0.032.033 95 64-125
Fluorene mg/kg 0.029.033 87 57-125
Indeno(1,2,3-cd)pyrene mg/kg 0.028.033 83 58-125
Naphthalene mg/kg 0.028.033 85 52-125
Phenanthrene mg/kg 0.028.033 85 60-125
Pyrene mg/kg 0.031.033 93 63-125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 64 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1977122LABORATORY CONTROL SAMPLE:
LCSSpike
2-Fluorobiphenyl (S) %. 72 55-125
p-Terphenyl-d14 (S) %. 80 30-150
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1977123MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
10307150001
1977124
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Acenaphthene mg/kg .04 82 39-12577 7 30.04ND 0.033 0.031
Acenaphthylene mg/kg .04 79 30-15068 15 30.04ND 0.032 0.027
Anthracene mg/kg .04 91 30-15083 9 30.04ND 0.036 0.033
Benzo(a)anthracene mg/kg .04 82 30-15076 7 30.04ND 0.033 0.030
Benzo(a)pyrene mg/kg .04 87 30-15080 8 30.04ND 0.035 0.032
Benzo(b)fluoranthene mg/kg .04 88 30-15081 8 30.04ND 0.035 0.032
Benzo(g,h,i)perylene mg/kg .04 84 30-15076 9 30.04ND 0.033 0.030
Benzo(k)fluoranthene mg/kg .04 87 30-15080 8 30.04ND 0.035 0.032
Chrysene mg/kg .04 80 30-15076 6 30.04ND 0.032 0.030
Dibenz(a,h)anthracene mg/kg .04 82 30-15076 8 30.04ND 0.033 0.030
Fluoranthene mg/kg .04 93 30-15085 9 30.04ND 0.037 0.034
Fluorene mg/kg .04 87 30-14682 5 30.04ND 0.035 0.033
Indeno(1,2,3-cd)pyrene mg/kg .04 81 30-15075 9 30.04ND 0.033 0.030
Naphthalene mg/kg .04 83 30-13175 10 30.04ND 0.033 0.030
Phenanthrene mg/kg .04 84 30-15078 8 30.04ND 0.034 0.031
Pyrene mg/kg .04 92 30-15085 8 30.04ND 0.037 0.034
2-Fluorobiphenyl (S) %. 67 55-12564
p-Terphenyl-d14 (S) %. 71 30-15071
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 65 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/29342
WI MOD DRO
WI MOD DRO
WIDRO Solid GCV
Associated Lab Samples: 10307337005, 10307337006, 10307337007, 10307337016, 10307337018
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1978119
Associated Lab Samples: 10307337005, 10307337006, 10307337007, 10307337016, 10307337018
Matrix: Solid
Analyzed
WDRO C10-C28 mg/kg ND 10.0 05/29/15 09:33
n-Triacontane (S) %. 91 30-143 05/29/15 09:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1978120LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1978121
WDRO C10-C28 mg/kg 69.080 86 64-1259072.0 4 20
n-Triacontane (S) %. 90 30-14392
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 66 of 73
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/29307
WI MOD DRO
WI MOD DRO
WIDRO GCS w/Cleanup
Associated Lab Samples: 10307337013, 10307337017, 10307337019
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1976564
Associated Lab Samples: 10307337013, 10307337017, 10307337019
Matrix: Water
Analyzed
WDRO C10-C28 mg/L ND 0.10 05/28/15 12:14
n-Triacontane (S) %. 80 62-125 05/28/15 12:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1976565LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1976566
WDRO C10-C28 mg/L 1.42 71 54-125771.5 8 20
n-Triacontane (S) %. 76 62-12582
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 67 of 73
#=QL#
QUALIFIERS
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
WORKORDER QUALIFIERS
WO: 10307337
This report was revised on July 1, 2015 to add TCLP Lead to sample 004.[1]
ANALYTE QUALIFIERS
Result confirmed by second analysis.C0
The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biasedhigh.
CH
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits inassociated samples. Results unaffected by high bias.
L3
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Sample field preservation does not meet EPA or method recommendations for this analysis.P4
Surrogate recovery outside laboratory control limits due to matrix interferences (confirmed by similar results from samplere-analysis).
S2
High boiling point hydrocarbons are present in the sample.T6
Post-analysis pH measurement indicates insufficient VOA sample preservation.pH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 68 of 73
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
10307337005 OEXT/29342 GCSV/15797LPG-35/6-8 WI MOD DRO WI MOD DRO
10307337006 OEXT/29342 GCSV/15797LPG-36/10-12 WI MOD DRO WI MOD DRO
10307337007 OEXT/29342 GCSV/15797LPG-36/18-20 WI MOD DRO WI MOD DRO
10307337016 OEXT/29342 GCSV/15797LPG-44/5-7 WI MOD DRO WI MOD DRO
10307337018 OEXT/29342 GCSV/15797LPG-45/8-10 WI MOD DRO WI MOD DRO
10307337013 OEXT/29307 GCSV/15790LPG-41/19-22 WI MOD DRO WI MOD DRO
10307337017 OEXT/29307 GCSV/15790LPG-44/19-22 WI MOD DRO WI MOD DRO
10307337019 OEXT/29307 GCSV/15790LPG-45/12-20 WI MOD DRO WI MOD DRO
10307337005 GCV/13777 GCV/13785LPG-35/6-8 EPA 5030 Medium Soil WI MOD GRO
10307337006 GCV/13777 GCV/13785LPG-36/10-12 EPA 5030 Medium Soil WI MOD GRO
10307337007 GCV/13777 GCV/13785LPG-36/18-20 EPA 5030 Medium Soil WI MOD GRO
10307337016 GCV/13777 GCV/13785LPG-44/5-7 EPA 5030 Medium Soil WI MOD GRO
10307337018 GCV/13777 GCV/13785LPG-45/8-10 EPA 5030 Medium Soil WI MOD GRO
10307337013 GCV/13776LPG-41/19-22 WI MOD GRO
10307337017 GCV/13776LPG-44/19-22 WI MOD GRO
10307337019 GCV/13776LPG-45/12-20 WI MOD GRO
10307337004 MPRP/55531 ICP/24329LPG-34/2-4 EPA 3010 EPA 6010C
10307337001 MPRP/54632 ICP/23950LPG-31/1-3 EPA 3050 EPA 6010C
10307337002 MPRP/54632 ICP/23950LPG-32/2-4 EPA 3050 EPA 6010C
10307337003 MPRP/54632 ICP/23950LPG-33/2-4 EPA 3050 EPA 6010C
10307337004 MPRP/54632 ICP/23950LPG-34/2-4 EPA 3050 EPA 6010C
10307337005 MPRP/54632 ICP/23950LPG-35/6-8 EPA 3050 EPA 6010C
10307337008 MPRP/54632 ICP/23950LPG-37/2-4 EPA 3050 EPA 6010C
10307337009 MPRP/54632 ICP/23950LPG-38/4-6 EPA 3050 EPA 6010C
10307337010 MPRP/54632 ICP/23950LPG-39/1-3 EPA 3050 EPA 6010C
10307337011 MPRP/54632 ICP/23950LPG-40/2-4 EPA 3050 EPA 6010C
10307337012 MPRP/54632 ICP/23950LPG-41/2-4 EPA 3050 EPA 6010C
10307337014 MPRP/54632 ICP/23950LPG-42/1-3 EPA 3050 EPA 6010C
10307337015 MPRP/54632 ICP/23950LPG-43/4-6 EPA 3050 EPA 6010C
10307337018 MPRP/54632 ICP/23950LPG-45/8-10 EPA 3050 EPA 6010C
10307337001 MERP/13661 MERC/15908LPG-31/1-3 EPA 7471B EPA 7471B
10307337002 MERP/13661 MERC/15908LPG-32/2-4 EPA 7471B EPA 7471B
10307337003 MERP/13661 MERC/15908LPG-33/2-4 EPA 7471B EPA 7471B
10307337004 MERP/13661 MERC/15908LPG-34/2-4 EPA 7471B EPA 7471B
10307337005 MERP/13661 MERC/15908LPG-35/6-8 EPA 7471B EPA 7471B
10307337008 MERP/13661 MERC/15908LPG-37/2-4 EPA 7471B EPA 7471B
10307337009 MERP/13661 MERC/15908LPG-38/4-6 EPA 7471B EPA 7471B
10307337010 MERP/13661 MERC/15908LPG-39/1-3 EPA 7471B EPA 7471B
10307337011 MERP/13661 MERC/15908LPG-40/2-4 EPA 7471B EPA 7471B
10307337012 MERP/13661 MERC/15908LPG-41/2-4 EPA 7471B EPA 7471B
10307337014 MERP/13661 MERC/15908LPG-42/1-3 EPA 7471B EPA 7471B
10307337015 MERP/13661 MERC/15908LPG-43/4-6 EPA 7471B EPA 7471B
10307337018 MERP/13661 MERC/15908LPG-45/8-10 EPA 7471B EPA 7471B
10307337001 MPRP/54713LPG-31/1-3 ASTM D2974
10307337002 MPRP/54713LPG-32/2-4 ASTM D2974
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 69 of 73
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
10307337
HC-15-002 CSAH-53 REV
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
10307337003 MPRP/54734LPG-33/2-4 ASTM D2974
10307337004 MPRP/54734LPG-34/2-4 ASTM D2974
10307337005 MPRP/54734LPG-35/6-8 ASTM D2974
10307337006 MPRP/54734LPG-36/10-12 ASTM D2974
10307337007 MPRP/54734LPG-36/18-20 ASTM D2974
10307337008 MPRP/54734LPG-37/2-4 ASTM D2974
10307337009 MPRP/54734LPG-38/4-6 ASTM D2974
10307337010 MPRP/54734LPG-39/1-3 ASTM D2974
10307337011 MPRP/54734LPG-40/2-4 ASTM D2974
10307337012 MPRP/54734LPG-41/2-4 ASTM D2974
10307337014 MPRP/54734LPG-42/1-3 ASTM D2974
10307337015 MPRP/54734LPG-43/4-6 ASTM D2974
10307337016 MPRP/54734LPG-44/5-7 ASTM D2974
10307337018 MPRP/54734LPG-45/8-10 ASTM D2974
10307337001 OEXT/29323 MSSV/12419LPG-31/1-3 EPA 3550 EPA 8270D by SIM
10307337002 OEXT/29323 MSSV/12419LPG-32/2-4 EPA 3550 EPA 8270D by SIM
10307337003 OEXT/29323 MSSV/12419LPG-33/2-4 EPA 3550 EPA 8270D by SIM
10307337004 OEXT/29323 MSSV/12419LPG-34/2-4 EPA 3550 EPA 8270D by SIM
10307337005 OEXT/29323 MSSV/12419LPG-35/6-8 EPA 3550 EPA 8270D by SIM
10307337008 OEXT/29323 MSSV/12419LPG-37/2-4 EPA 3550 EPA 8270D by SIM
10307337009 OEXT/29323 MSSV/12419LPG-38/4-6 EPA 3550 EPA 8270D by SIM
10307337010 OEXT/29323 MSSV/12419LPG-39/1-3 EPA 3550 EPA 8270D by SIM
10307337011 OEXT/29323 MSSV/12419LPG-40/2-4 EPA 3550 EPA 8270D by SIM
10307337012 OEXT/29323 MSSV/12419LPG-41/2-4 EPA 3550 EPA 8270D by SIM
10307337014 OEXT/29323 MSSV/12419LPG-42/1-3 EPA 3550 EPA 8270D by SIM
10307337015 OEXT/29323 MSSV/12419LPG-43/4-6 EPA 3550 EPA 8270D by SIM
10307337018 OEXT/29323 MSSV/12419LPG-45/8-10 EPA 3550 EPA 8270D by SIM
10307337005 MSV/31586 MSV/31600LPG-35/6-8 EPA 5035/5030B EPA 8260B
10307337006 MSV/31586 MSV/31600LPG-36/10-12 EPA 5035/5030B EPA 8260B
10307337007 MSV/31586 MSV/31600LPG-36/18-20 EPA 5035/5030B EPA 8260B
10307337016 MSV/31613 MSV/31630LPG-44/5-7 EPA 5035/5030B EPA 8260B
10307337018 MSV/31613 MSV/31630LPG-45/8-10 EPA 5035/5030B EPA 8260B
10307337013 MSV/31527LPG-41/19-22 EPA 8260B
10307337017 MSV/31527LPG-44/19-22 EPA 8260B
10307337019 MSV/31527LPG-45/12-20 EPA 8260B
10307337020 MSV/31527TRIP BLANK EPA 8260B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/01/2015 11:38 AM
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
(612)607-1700
Page 70 of 73
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