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Zip'Chem Products AP-280 Liquid

Material Safety Data Sheet

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Section: 1 CHEMICAL PRODUCT AND COMPANY INFORMATION

Product Name:

Chemical Family:

Manufacturer:

AP-280 Liquid

Silicone Adhesive

Zip-Chem Products 400 Jarvis Drive Morgan Hill, CA 95037

For Addit ional Product Information:

1 (800) 648-2661

In Emergency: 1 (800) 424-9300

Section: 2 COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

FOR EXPOSURE LIMITS SEE SECTION 8 FOR OTHER TOXICOLOGICAL INFORMATION SEE SECTION 11

HAZARDOUS INGREDIENTS

Descriptive Name

[sopropyl Alcohol

Elhyl Benzene

Xylene

Octamelhylcyclotetrasiloxane

Tetra {trimethylsiloxy) -silane

Decamethylcyclopentasiloxane

Toluene

CAS Number

67-63-0

100-41-4

1330-20-7

556-67-2

3555-47-3

541-02-6

108-88-3

Percentage Range

<5%

10%

50%

6%

4%

4%

<0.5%

Hazard Type per

CFR 1910.1200 Flammable

Toxic

Toxic

Toxic

Toxic

Toxic

Toxic

Exposure Limits

OSHA PEL 400 ppm ACGIH TLV 400 ppm OSHAPEL lOOppm ACGIH TLV 100 ppm

OSHA PEL 100 ppm ACGIH TLV lOOppm OSHA PEL 10 ppm ACGIH TLV 10 ppm OSHA PEL 100 ppm ACGIH TLV 100 ppm QSHA PEL 100 ppm ACGIH TLV 100 ppm OSHA PEL 100 ppm ACGIH TLV 100 ppm

LDso

Not Determined

Nol Delermined

Not Determined

Not Delermined

Not Determined

Not Determined

Not Determined

LCso

Not Determined

Not Determined

Not Determined

Not Determined

Not Determined

Not Delermined

Not Determined

NTP, IARC, OrOSHA

Carcinogen

No

IARC Group 2 B -

Possibly Carcinogenic

to Humans No

No

No

No

No

Sect ion : 3 HAZARDS IDENTIFICATION

PHYSICAL HAZARDS: Flammable liquid ACUTE HEALTH EFFECTS: Breathing high concentrafions of vapors may cause temporary nervous

system depression with anesthefic effects such as dizziness, headache, nausea

CHRONIC HEALTH EFFECTS: Prolonged exposure to extremely high concentrafions ofthe vapors may lead to narcosis, cardiac irregularifies, unconsciousness or death.

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Prolonged or repeated exposure to skln may cause dermatifis. HMIS RATINGS:

Health: 2 Flammability: 3 Reactivity: 0 Protecfive Equipment: H

Sect ion : 4 FIRST AID MEASURES

EYES: Flush immediately with water for 15 minutes and take to physician.

SKIN: Wash affected area and consult a physician if irritation persists.

INGESTION: Do not Induce vomiting so as to avoid aspirafion of material into the lungs.

INHALATION: Remove from exposure and restore breathing. Seek medical attenfion.

Sect ion : 5 FIRE AND EXPLOSION HAZARDS

FLAMMABILITY DATA: FLAMMABLE/COMBUSTIBLE/PYROPHORIC: Flammable FLASH POINT AND METHOD: S r F PMCC AUTOIGNITION TEMPERATURE: Not established

FLAMMABLE LIMITS AT NORMAL TEMPERATURE AND PRESSURE (PERCENT VOLUME IN AIR):

LEL: 1% UEL: 7%

NFPA RATINGS (per NFPA 704): Health - 2 Flammability - 3 Instability - 0

EXPLOSION DATA:

SENSITIVITY TO MECHANICAL IMPACT: Not Sensitive

SENSITIVITY TO STATIC DISCHARGE: Not Sensitive

EXTINGUISHING MEDIA: Foam, C02, Dry Chemical

FIRE FIGHTING TECHNIQUES AND COMMENTS: Use standard firefighfing techniques to fight fires involving this material

HAZARDOUS COMBUSTION PRODUCTS: Carbon dioxide, carbon monoxide, nitrous oxide, silicon compounds, formaldehyde

Sect ion : 6 ACCIDENTAL SPILL/RELEASE INFORMATION

FOR ALL TRANSPORTATION ACCIDENTS CALL CHEMTREC AT 1 -800-424-9300.

REPORTABLE QUANTITY: Not Applicable

SPILL MITIGATION PROCEDURES: Stop source of spill as soon as possible and notify appropriate personnel. Burm around spill area to prevent spill from spreading. Venfilate area. Do not flush into sewers.

AIR RELEASE: Vapors may be suppressed by use of water fog or spray. Contain all liquid for treatment or neutralizafion.

WATER RELEASE: This material is lighter than and neariy insoluble in water. It can be contained by damming the water

and removing top layer of the mixture.

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LAND SPILL: Create a trench to contain materials. Spilled materials may be contained using sand, clay, earth or a commercial absorbent. Do not place materials back in their original container.

SPILL RESIDUES: Dispose of per guidelines under secfion 13, DISPOSAL CONSIDERATIONS.

PERSONNEL PROTECTION FOR EMERGENCY SPILL AND FIRE FIGHTING SITUATIONS: Additional protective clothing must be worn to prevent personal contact with this material. Those items include but are not limited to gloves, apron, and safety glasses.

Sect ion : 7 HANDLING AND STORAGE

DO NOT TAKE INTERNALLY. AVOID CONTACT WITH EYES AND CLOTHING. UPON CONTACT WITH SKIN OR EYES WASH OFF WITH WATER.

STORAGE CONDITIONS: Store in a cool, dry, well-venfilated place. STORE AT TEMPERATURES BETWEEN 40-100'F. DO NOT STORE OR USE NEAR HEAT, SPARKS. OR FLAMES. AVOID BREATHING VAPORS. VAPORS ARE HEAVIER THAN AIR AND WILL COLLECT IN LOW AREAS AND OTHER CONFINED AREAS.

PRODUCT STABILITY AND COMPATIBILITY: SHELF LIFE LIMITATIONS: 6 months from date of shipment when stored at recommended storage conditions. INCOMPATIBLE MATERIALS FOR STORAGE OR TRANSPORT: None known INCOMPATIBLE MATERIALS FOR PACKAGING: None known

Sect ion : 8 PREVENTIVE MEASURES

PERSONAL PROTECTION FOR ROUTINE USE OF THIS PRODUCT: RESPIRATORY PROTECTION: Not necessary SKIN AND EYE PROTECTIVE EQUIPMENT: Safety glasses, gloves.

ENGINEERING CONTROLS

VENTILATION: Local or mechanical to keep Section II ingredients below their exposure limits. EQUIPMENT SPECIFICATIONS (WHEN APPLICABLE):

RESPIRATOR TYPE: None required PROTECTIVE CLOTHING TYPE; (This includes: gloves, boots, apron, protective suit): Gloves, safety glasses

WASTE DISPOSAL: Spilled material collected in absorbent material should be transferred to steel disposal or recovery drums. If this product becomes a waste, it DOES NOT meet the criteria of a hazardous waste as defined under 40 CFR 261, in that it does not exhibit the characterisfics of hazardous waste under Subpart D. If this product becomes a waste, it should be disposed of in accordance with local, state and federal regulafions by incineration.

Sect ion : 9 PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE(gas, liquid, solid): Liquid APPEARANCE: Clear liquid ODOR: Aromafic odor FREEZING POINT: Not Determined BOILING RANGE: Not Determined

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DECOMPOSITION TEMPERATURE: Not Determined SPECIFIC GRAVITY (H20=1): 0.9 pH @ 25 Deg C; Not Applicable VAPOR PRESSURE @ 25 Deg C: Not Determined SOLUBILITY IN WATER: Not Determined EVAPORATION RATE: Not Available VAPOR DENSITY: Heavier than air VOLATILE ORGANIC COMPOUND (VOC) 558 grams/Liter

Sect ion : 10 STABILITY AND REACTIVITY DATA

CONDITIONS UNDER WHICH THIS PRODUCT MAY BE UNSTABLE; MECHANICAL SHOCK OR IMPACT: No ELECTRICAL (STATIC) DISCHARGE: No HAZARDOUS POLYMERIZATION; Will Not Occur INCOMPATIBLE MATERIALS: Strong oxidizing agents CONDITIONS OF REACTIVITY: None known HAZARDOUS DECOMPOSITION PRODUCTS: None expected.

Sect ion : 11 TOXICOLOGICAL PROPERTIES

ROUTES OF ABSORPTION Inhalation is the most likely route of absorption.

WARNING STATEMENTS AND WARNING PROPERTIES: DO NOT TAKE INTERNALLY. MAY CAUSE EYE AND MUCOUS MEMBRANE IRRITATION.

SIGNS, SYMPTOMS AND EFFECTS OF EXPOSURE INHALATION

ACUTE: Vapor may irritate nose and throat. Overexposure by inhalation may cause drowsiness, dizziness, confusion or loss of coordinafion. CHRONIC: Overexposure by inhalation may injure the following organs: liver, kidneys, nervous system, blood, lungs, reproducfive organs, bone marrow.

SKIN ACUTE: May cause moderate irritafion. CHRONIC; Prolonged or repeated contact may cause defatfing and drying of skin which may result in skin irritation and dermatifis.

EYE Direct contact may cause severe irritation. Vapor may cause eye irritation.

INGESTION ACUTE: May cause vomifing. Aspiration of liquid while vomifing may injure lungs. CHRONIC: If large quantities are swallowed, do not induce vomifing as it might cause aspirafion of

vomitus into the lungs. Take to a physician Immediately.

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Zip 'Chem Products AP-280 Liquid


MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None known. INTERACTIONS WITH OTHER CHEMICALS THAT ENHANCE TOXICITY: None known ACUTE TARGET ORGAN TOXICITY: No organs know to be damaged from exposure to this product. CHRONIC TARGET ORGAN TOXICITY: Repeated inhalafion or oral exposure to octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane produced an Increase in liver size in mice and rats. No gross histopathological or significant clinical chemistry effects were observed. An increase In liver metabolizing enzymes, as well as a transient increase in the number of normal cells (hyperplasia) followed by an Increase in cell size (hypertrophy) were determined to be the underiying cause of the liver enlargement. The biochemical mechanisms producing these effects are highly sensitive In rodents, while similar mechanisms in humans are Insensitive. Good industrial hygiene practice minimizes Inhalafion exposure. REPRODUCTIVE AND DEVELOPMENTAL TOXICITY: Octamethylcyclotetrasiloxane administered to rats by whole body inhalation at concentrations of 500 to 700 ppm for 70 days prior to mafing, gestation, and lactation resulted In decreases in live litter size. Addifionally, Increases in the Incidence of deliveries of offspring extending over an unusually long fime period (dystocia) were observed at these concentrafions. Stafisficaiiy significant alterations in these parameters were not observed in the lower concentrations evaluated (300 ppm to 700 ppm). In a previous range finding study, rats exposed to vapor concentrafions of 700 ppm had decreases in the number of implantafion sites and live litter size. The significance of these findings to humans Is not known. CARCINOGENICITY: NTP? NO IARC MONOGRAPHS? NO OSHA REGULATED? NO MUTAGENICITY: This product is not known to be mutagenic. EXPOSURE LIMITS: Not Determined

Sect ion : 12 ECOLOGICAL INFORMATION

AQUATIC TOXICITY: None known or reported.

Sect ion : 13 DISPOSAL CONSIDERATIONS

Spilled material collected in absorbent material should be transferred to steel disposal or recovery drums.

If this product becomes a waste. It DOES NOT meet the criteria of a hazardous waste as defined under 40 CFR 261, In that It does not exhibit the characteristics of hazardous waste under Subpart D. If this product becomes a waste, it should be disposed of in accordance with local, state and federal regulations by Incinerafion.

Sect ion : 14 TRANSPORT INFORMATION

DOT SHIPPING NAME: FLAMMABLE LIQUID, N.O.S. (XYLENE. ISOPROPYL ALCOHOL) DOT HAZARD CLASS: 3 UN NUMBER 1993 DOT PACKING GROUP: 111 DOT REPORTABLE QUANTITY: None found In 49 CFR 172.101

Sect ion : 15 REGULATORY INFORMATION

INTERNATIONAL All components of this product are listed on the following inventories: MITI (Japan) EINECS (EEC) DSL (Canada).

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FEDERAL TOXIC SUBSTANCES CONTROL ACT (TSCA): The components ofthis product are listed on the TSCA Inventory. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT TITLE III (SARA): Section 302/304 Requires emergency planning based on Threshold Planning Quantifies' (TPQs), and release reporting based on Reportable Quantifies (RQs) of 'Extremely Hazardous Substances' (EHS) listed in Appendix A of 40 CFR 355. There are no components of this material with known CAS numbers that are on the EHS list. Section 311 & 312 Based upon the available information, this material and/or components is classified as a health and/or physical hazards according to Section 311 & 312:

Descriptive Name

Ethyl Benzene

Xylene

Section 313 This material c SARA Tifie III,

Descriptive Name

Ethyl Benzene

Xylene

CAS Number

100-41-4

1330-20-7

Percentage Range

10%

50%

ontains chemicals with k Section 313 and 40 OFF

CAS Number

100-41-4

1330-20-7

Percentage Range

10%

50%

Hazard Type per CFR

1910.1200

Toxic

Toxic

nown CAS nu ?372:

Hazard Type per CFR

1910.1200 Toxic

Toxic

Exposure Limits

OSHA PEL 100 ppm ACGIH TLV

lOOppm


100 ppm

L D M

Not Determined

Nol Determined

LCso

Nol Determined

Not Delermined

NTP, IARC, OrOSHA

Carcinogen

IARC Group 2 B -

Possibly Carcinogenic

to Humans No

Tibers subject to the reporting requirements of

Exposure Limits


100 ppm


100 ppm

LD,o

Not Determined

Not Determined

LCso

Not Determined

Not Determined

NTP, IARC, Or OSHA

Carcinoqen IARC Group

2 8 -Possibly

Carcinogenic to Humans

No

Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) This material does not contain chemical(s) with known CAS numbers classified as hazardous substances subject to the reporting requirements of CERCLA (40 CFR 302) and to the release reporting requirements of SARA (Section 302) based on reportable quantities (RQs):

OSHA Regulations 'Chemical-specific' U. S. Occupafional Safety and Health Administration (OSHA) regulafions (1910.1002 to 1910.1050) presented under 29 CFR 1910 do not apply to this material or its components.

Other EPA Regulations No addifional informafion available.

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State California Safe Drinking Water and Toxic Enforcement Act of 1988- Proposit ion 65

This material contains chemicals listed as carcinogens or reproducfive toxins under California Proposition 65 at levels that would be subject to the proposition: Toluene CAS 108-88-3

California South Coast Air Quality Management District (SCAQMD) Rule 443.1 (VOC's) A Volafile Organic Compound (VOC) is any volatile compound of carbon excluding methane, carbon monoxide, carbonic acid, metallic carbides or carbonates, ammonium carbonate, 1,1,1-trichloroethane, methylenechloride, FC-23. CFC-113, CFC-12, CFC-11, CFC-22. CFC-114, and CFC-115. By this definifion, this is a VOC material.

Massachusetts Right to Know Substance List (MSL) [105 CMR 670.000] Hazardous Substances (MSL-HS) on the MSL must be identified when present in materials at levels greater than state specified criterion. The criterion is: >=17o. Components with CAS numbers present in this material at a level which could require reporting under the statute are:

Chemical CAS Number

Ethyl Benzene 100-41-4

Xylene 1330-20-7

Isopropyl Alcohol 67-63-0

Extraordinarily Hazardous Substances (MSL-EHS) on the MSL must be Identified when present in materials at levels greater than state specified criterion. The criterion is >= 0.0001%. There are no materials present that could require reporting under this statute. Pennsylvania Right to Know Hazardous Substance List Hazardous Substances (PA-HS) must be identified when present in materials at levels greater than the state specified criterion. The criterion is >=1%. Components with CAS numbers present In this material at a level that could require reporting under the statute are:

Chemical CAS Number

Ethyl Benzene 100-41-4

Xylene 1330-20-7

Isopropyl Alcohol 67-63-0

Octamethylcyclo-tetrasiloxane 556-67-2

Tetra{lrimethylsiloxy)silane 3555-47-3

Decamethylcydo-pentasiloxane 541-02-6

Sect ion : 16 PREPARATION INFORMATION

REVISION INFORMATION: Periodic review PREPARED BY: J Smith APPROVAL DATE: 1/12/09 SUPERSEDES: 8/29/06

This information is furnished without warranty, expressed or Implied, except that it is accurate to the best knowledge of Zlp-Chem Products Company. The data in this sheet is related only to the specific material designated herein. Zlp-Chem Products Company assumes no legal responsibility for use or reliance upon these data.

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Zip'Chem Products AP-280 Powder


Section: 1 CHEMICAL PRODUCT AND COMPANY INFORMATION

Product Name:

Chemical Family:

Manufacturer:

AP-280 Powder

Aluminum Powder

Zlp-Chem Products 400 Jan/is Drive Morgan Hill, CA 95037

For Addit ional Product Information:

1 (800) 648-2661

In Emergency: 1 (800) 424-9300

Section: 2 COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

FOR EXPOSURE LIMITS SEE SECTION 8 FOR OTHER TOXICOLOGICAL INFORMATION SEE SECTION 11

HAZARDOUS INGREDIENTS

Descriptive Name

Aluminum

CAS Number

7429-90-5

Percentage Range

100%

Hazard Type per

CFR 1910.1200

Physical: Dust can be explosive

Exposure Limits

Not Delermined

LD50

N/A

LCso

N/A

NTP, IARC, Or OSHA

Carcinogen

No

Section: 3 HAZARDS IDENTIFICATION

PHYSICAL HAZARDS:

ACUTE HEALTH EFFECTS:

CHRONIC HEALTH EFFECTS; HMIS RATINGS:

Health: Flammability; Reacfivity:

Aluminum dust may be Ignited by stafic discharge and burn at extremely high temperature. In bulk form, it is ignited by static discharge with difficulty. Once suspended in dust laden air cloud, it Is readily ignited and very explosive. Breathing high concentrafions of vapors may cause irritation of the respiratory system. Treat as a nuisance dust. None known

Protecfive Equipment:

Sect ion : 4 FIRST AID MEASURES

EYES; Flush immediately with water for 15 minutes and take to physician if irritation persists.

SKIN: Wash affected area with soap and water. INGESTION: Call a physician and/or transport to emergency facility Immediately. Do not induce vomifing

so as to avoid aspirafion of material into the lungs.

INHALATION: Remove to fresh air

Z i p ' C h e m P r o d u c t s AP-280 Powder


Page 2 of 7

Sect ion : 5 FIRE AND EXPLOSION HAZARDS

FLAMMABILITY DATA: FLAMMABLE/COMBUSTIBLE/PYROPHORIC: N/A FLASH POINT AND METHOD: N/A AUTOIGNITION TEMPERATURE: Not established

FLAMMABLE LIMITS AT NORMAL TEMPERATURE AND PRESSURE (PERCENT VOLUME IN AIR):

LEL: N/A UEL: N/A

NFPA RATINGS (per NFPA 704): Health - 0 Flammability - 2 Instability - 0 EXPLOSION DATA:

SENSITIVITY TO MECHANICAL IMPACT; Not Sensitive

SENSITIVITY TO STATIC DISCHARGE: Aluminum dust may be ignited by stafic discharge and burn at extremely high temperature. In bulk form. It is ignited by stafic discharge with difficulty. Once suspended in dust laden air cloud, it is readily ignited and very explosive.

EXTINGUISHING MEDIA: Foam, C02, Dry Chemical

FIRE FIGHTING TECHNIQUES AND COMMENTS: Aluminum dust may be ignited by static discharge and burn at extremely high temperature. Once suspended in dust laden air cloud. It Is readily Ignited and very explosive.

HAZARDOUS COMBUSTION PRODUCTS: Aluminum oxide

Section: 6 ACCIDENTAL SPILL/RELEASE INFORMATION

FOR ALL TRANSPORTATION ACCIDENTS CALL CHEMTREC AT 1-800-424-9300.

REPORTABLE QUANTITY: Not Applicable

SPILL MITIGATION PROCEDURES: Stop source of spill as soon as possible and notify appropriate personnel. Burm around spill area to prevent spill from spreading. Venfilate area. Do not flush into sewers.

AIR RELEASE: Avoid stafic discharge, especially if powder is airborne.

WATER RELEASE: Contain release and remove powder. Dispose of wet powder.

LAND SPILL; Contain spilled material. Do not place materials back In their original container.

SPILL RESIDUES; Dispose of per guidelines under secfion 13, DISPOSAL CONSIDERATIONS.

PERSONNEL PROTECTION FOR EMERGENCY SPILL AND FIRE FIGHTING SITUATIONS: Additional protective clothing must be worn to prevent personal contact with this material. Those items Include but are not limited to gloves, apron, and safety glasses.

Sect ion : 7 HANDLING AND STORAGE

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DO NOT TAKE INTERNALLY. AVOID CONTACT WITH EYES AND CLOTHING. UPON CONTACT WITH SKIN OR EYES WASH OFF WITH WATER.

STORAGE CONDITIONS: Store in a cool, dry, well-venfilated place. STORE AT TEMPERATURES BETWEEN 40-1 DOT. DO NOT STORE OR USE NEAR HEAT, SPARKS, OR FLAMES.

PRODUCT STABILITY AND COMPATIBILITY: INCOMPATIBLE MATERIALS FOR STORAGE OR TRANSPORT: Reacts violently with halogenated hydrocarbons and with oxidizers to produce heat. INCOMPATIBLE MATERIALS FOR PACKAGING: No common metal alloys known to be incompafible.

Sect ion : 8 PREVENTIVE MEASURES

PERSONAL PROTECTION FOR ROUTINE USE OF THIS PRODUCT: RESPIRATORY PROTECTION: Use a dust mask when working with the atomized product. Refer

to NIOSH publicafion No. 89-105 and NIOSH No. 87-116. See OSHA requirement under 29 CFR 1910.1025 and 29 CFR 1910.134.

SKIN AND EYE PROTECTIVE EQUIPMENT: Impervious gloves are recommended to prevent skin contact. Chemical goggles to prevent eye contact are recommended.

ENGINEERING CONTROLS VENTILATION: Local or mechanical to keep Section II ingredients below their exposure limits.

EQUIPMENT SPECIFICATIONS (WHEN APPLICABLE): RESPIRATOR TYPE: Use a dust mask PROTECTIVE CLOTHING TYPE: (This includes: gloves, boots, apron, protecfive suit): Gloves, safety glasses

WASTE DISPOSAL: Spilled material collected in absorbent material should be transferred to steel disposal or recovery drums. If this product becomes a waste, it DOES NOT meet the criteria of a hazardous waste as defined under 40 CFR 261, In that It does not exhibit the characteristics of hazardous waste under Subpart D. If this product becomes a waste, it should be disposed of in accordance with local, state and federal regulafions by incineration.

Sect ion : 9 PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE(gas. liquid, solid): Solid APPEARANCE: Gray Solid ODOR: No odor FREEZING POINT: Not Applicable BOILING RANGE: Not Applicable DECOMPOSITION TEMPERATURE: Not Applicable SPECIFIC GRAVITY (H20=1): 2.7 pH @ 25 Deg C; Not Applicable VAPOR PRESSURE @ 25 Deg C: Not Applicable SOLUBILITY IN WATER; None EVAPORATION RATE: Not Applicable VAPOR DENSITY: Not Applicable VOLATILE ORGANIC COMPOUND (VOC) 0 grams/Liter

Sect ion : 10 STABILITY AND REACTIVITY DATA

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Zip'Chem Products AP-280 Powder


CONDITIONS UNDER WHICH THIS PRODUCT MAY BE UNSTABLE: MECHANICAL SHOCK OR IMPACT: No ELECTRICAL (STATIC) DISCHARGE; Yes HAZARDOUS POLYMERIZATION: Will Not Occur INCOMPATIBLE MATERIALS: Reacts violently with halogenated hydrocarbons and with oxidizers to produce heat. CONDITIONS OF REACTIVITY; None known HAZARDOUS DECOMPOSITION PRODUCTS: Aluminum oxide

Sect ion : 11 TOXICOLOGICAL PROPERTIES

ROUTES OF ABSORPTION Inhalafion is the most likely route of absorpfion.

WARNING STATEMENTS AND WARNING PROPERTIES: DO NOT TAKE INTERNALLY. AVOID STATIC DISCHARGE NEAR DUST OF PRODUCT.

SIGNS, SYMPTOMS AND EFFECTS OF EXPOSURE INHALATION

ACUTE; May cause irritafion of the respiratory system. Treat as nuisance dust CHRONIC: May aggravate pre-exisfing respiratory and lung diseases.

SKIN ACUTE: None known CHRONIC: None known

EYE May cause irritafion.

INGESTION ACUTE: May cause irritafion ofthe dlgesfive tract. CHRONIC: If large quanfifies are swallowed, do not induce vomifing as it might cause aspirafion of

vomitus into the lungs. Take to a physician immediately.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-exisfing upper respiratory and lung diseases such as. but not limited to. bronchifis, emphysema, and asthma. INTERACTIONS WITH OTHER CHEMICALS THAT ENHANCE TOXICITY: None known ACUTE TARGET ORGAN TOXICITY: No organs know to be damaged from exposure to this product. CHRONIC TARGET ORGAN TOXICITY: There are no known effects from repeated exposure. REPRODUCTIVE AND DEVELOPMENTAL TOXICITY; There are no known effects from repeated exposure. CARCINOGENICITY: NTP? NO IARC MONOGRAPHS? NO OSHA REGULATED? NO MUTAGENICITY: This product is not known to be mutagenic. EXPOSURE LIMITS: Not Determined

Sect ion : 12 ECOLOGICAL INFORMATION

AQUATIC TOXICITY: None known or reported.

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Section: 13 DISPOSAL CONSIDERATIONS

Spilled material collected in absorbent material should be transferred to steel disposal or recovery drums.

If this product becomes a waste. It DOES NOT meet the criteria of a hazardous waste as defined under 40 CFR 261, In that it does not exhibit the characteristics of hazardous waste under Subpart D. If this product becomes a waste. It should be disposed of in accordance with local, state and federal regulafions by Incineration.

Sect ion : 14 TRANSPORT INFORMATION

DOT SHIPPING NAME: NON-REGULATED (ALUMINUM POWDER) DOT HAZARD CLASS: None UN NUMBER None DOT PACKING GROUP: None DOT REPORTABLE QUANTITY: None found in 49 CFR 172.101

Sect ion : 15 REGULATORY INFORMATION

INTERNATIONAL All components ofthis product are listed on the following inventories: MITI (Japan) EINECS (EEC) DSL (Canada).

FEDERAL TOXIC SUBSTANCES CONTROL ACT (TSCA): The components ofthis product are listed on the TSCA inventory. SUPERFUND AMENDMENTS AND REAUTHORfZATION ACT TITLE IK (SARA): Section 302/304 Requires emergency planning based on Threshold Planning Quantifies' (TPQs), and release reporting based on Reportable Quantifies (RQs) of 'Extremely Hazardous Substances' (EHS) listed in Appendix A of 40 CFR 355. There are no components of this material with known CAS numbers that are on the EHS list. Section 311 &312 Based upon the available information, this material and/or components Is classified as a health and/or physical hazards according to Secfion 311 & 312:

Descriptive Name

None

CAS Number

Percentage Range

Hazard Type per CFR

1910.1200

Exposure Limits

LDso LCsc NTP, IARC, Or OSHA

Carcinogen

Section 313 This material contains chemicals with known CAS numbers subject to the reporting requirements of SARA Tifie III, Secfion 313 and 40 CFR 372:

CAS Number

Percentage Range

Hazard Type per CFR

1910.1200

Exposure Limits

LDso LCso NTP, IARC, Or OSHA

Carcinogen

Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) This material does not contain chemical(s) with known CAS numbers classified as hazardous substances subject to the reporting requirements of CERCLA (40 CFR 302) and to the release reporting requirements of SARA (Secfion 302) based on reportable quanfifies (RQs):

of 7



OSHA Regulations 'Chemical-specific' U. S. Occupafional Safety and Health Administration (OSHA) regulations (1910.1002 to 1910.1050) presented under 29 CFR 1910 do not apply to this material or its components.

Other EPA Regulations No addifional information available.

of 7



State California Safe Drinking Water and Toxic Enforcement Act of 1988- Proposit ion 65

This material does not contain chemicals listed as carcinogens or reproducfive toxins under California Proposifion 65 at levels that would be subject to the proposition.

California South Coast Air Quality Management District (SCAQMD) Rule 443.1 (VOC's) A Volafile Organic Compound (VOC) is any volatile compound of carbon excluding methane, carbon monoxide, carbonic acid, metallic carbides or carbonates, ammonium carbonate, 1,1,1-trichloroethane, methylene chloride, FC-23, CFC-113, CFC-12. CFC-11. CFC-22, CFC-114, and CFC-115. By this definition, this is not a VOC material.

Massachusetts Right to Know Substance List (MSL) [105 CMR 670.000] Hazardous Substances (MSL-HS) on the MSL must be idenfified when present 'in materials at levels greater than state specified criterion. The criterion Is: >=1%. Components with CAS numbers present in this material at a level which could require reporting under the statute are:

Chemical CAS Number

Extraordinarily Hazardous Substances (MSL-EHS) on the MSL must be identified when present in materials at levels greater than state specified criterion. The criterion is >= 0.0001 %. There are no materials present that could require reporting under this statute. Pennsylvania Right to Know Hazardous Substance List Hazardous Substances (PA-HS) must be Idenfified when present in materials at levels greater than the state specified criterion. The criterion is >=1%. Components with CAS numbers present in this material at a level that could require reporting under the statute are:

Chemical CAS Number

Sect ion : 16 PREPARATION INFORMATION

REVISION INFORMATION: Periodic review PREPARED BY: J Smith APPROVAL DATE: 1/12/09 SUPERSEDES: 8/29/06

This Information Is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Zlp-Chem Products Company. The data in this sheet is related only to the specific material designated herein. Zip-Chem Products Company assumes no legal responsibility for use or reliance upon these data.

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