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1 Overview of Pyrolysis Experience in Canada Fernando Preto CanmetENERGY Natural Resources Canada IEA Task 34, Espoo, Finland June, 2010 Industry/Government study has concluded that bioenergy and bio- product opportunities are stronger economically and socially when integrated within the traditional industry’s operations rather than on a stand-alone basis. Pyrolysis (and gasification) generally ranked at the top of the bioenergy opportunities.

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Page 1: Overview of Pyrolysis Experience in Canada - Pynepyne.co.uk/Resources/user/COUNTRY REPORT CANADA - June 2010.pdf · 1 Overview of Pyrolysis Experience in Canada Fernando Preto CanmetENERGY

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Overview of Pyrolysis Experience in Canada

Fernando Preto

CanmetENERGY

Natural Resources Canada

IEA Task 34, Espoo, Finland June, 2010

Industry/Government study has concluded that bioenergy and bio-

product opportunities are stronger economically and socially when integrated within the traditional industry’s operations rather than on a stand-alone basis. Pyrolysis (and gasification) generally ranked at the top of the bioenergy opportunities.

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Companies with G/P Experience*

Gasification

Enerkem

Norampac

Nexterra

Plasco

Pyrolysis

ABRI Tech

Agritherm

Alterna

Dynamotive

Ensyn

Pyrovac

RTI

Titan

*Listed alphabetically

5 tpd Mobile Pyrolysis Plant

•Joint venture between Advanced Biorefinery Inc (Peter Fransham) and Forespect (Namure, Quebec) fabricators.

•1 tpd portable “farm” & “research” units built: CanmetENERGY; Saskatchewan Research Council; AES BioEnergy, New Zealand; US Forest Service

•50 tpd units built for Ontario and Iowa (commissioing not completed)

ABRI TechSingle Auger Fast Pyrolysis

Modular Portable Units

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ABRI Tech50 tpd Portable Unit (Iowa)

Grinder / Drier Reactor Condenser

4 tpd

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Agri-therm Units:

1 - 10 tpd unit used for R&D

1 - 10 tpd unit shipped to Mexico

1 - 10 tpd unit being built as mobile laboratory

Maximizing Charcoal Yield

Alterna Biochar, Prince George, BC

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Alterna Biochar

Operated pilot “box” pyrolyzer ( = 5 – 10 min)

Successfully produced briquettes

Future efforts:

Scale-up

Char pellets

Char gasification

Other char uses

Dynamotive

Fluid bed fast pyrolysis

“Biotherm” projects

include a 15TPD Pilot

Plant, a 130TPD Plant in

West Lorne, and a

200TPD Plant in Guelph

Orenda

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Ensyn “Utilization” Initiatives:

- Slow Diesel Testing (Manitoba Hydro)

- Commercial Burner Development (BMA & CanmetENERGY)

- Potential for District Heating CanmetENERGY Complex (3 MWth)

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PyroVac

Christian Roy, founder of PyroVac has since co-founded

Vaperma Inc, and is co-inventor of Siftek™ polymer membrane

technology. He is contemplating a return to the pyrolysis field

including application of membranes to separate water from

light soluble organics

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RTI – Resource Transforms Int. Ltd

Principal Contact: Jan Piskorz

R&D and Consulting

Optimize pyrolysis (WFPP) for maximum liquid yields

Pathways for selective formation of market-oriented

specific chemicals: glycoaldehyde,

hydroxyacetaldehyde

“Bio-char mixes”

Titan Clean Energy (SK) Organic Power (BC)

Slow Pyrolysis for Biochar…

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Government & Academia

Agriculture and Agri-Food Canada

CanmetENERGY (Natural Resources Canada)

National Research Council

Saskatchewan Research Council

Ecole Polytechnique de Montréal

University of Toronto

University of Western OntarioUniversity of British Columbia and University of Saskatchewan [Gasification of Bio-oil]

Principal Contact: Carlos M. MonrealAgriculture and Agri-Food Canada

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CanmetENERGY (Natural Resources Canada)

Principal Contacts:

Fernando Preto (Research Side)

Ed Hogan (Program Side)

Nozzle and Burner Development

Pyrolysis Process Development

20 kg Batch Pyrolysis Unit

Catalytic Conversion and Emulsification

Financial and Technical Support for Industry

Pyrolysis Process Development

Feedstock and Product Characterization

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CanmetENERGY Bio-Oil Nozzle: External mix air assist atomiser. Fuel is injected

through a central pipe with a slight contraction at the tip allowing for a slight

pressure build-up to aid atomisation – Firing into tunnel furnace ~100 kg/h

Tote #1 Comb Air T = 117 C

Tote #1 Comb Air T = 46 C

Tote #2 –Modified Nozzle

Tote #2 - Plugged

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Saskatchewan Research Council:Installing ABRI Tech 1 tpd Unit

Principal Contact: Darren Anweiler

Focus on Ag residues: Wheat & Flax Straw, Poultry Litter

Ecole Polytechnique de Montréal

Principal Contact: Jamal Chaouki

Microwave Pyrolysis of biomass and wastes

Problems associated with chloride

Focus on “fluff” due to problems associated with

chloride and high metals content

6 PhD and 2 post-docs

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University of Toronto

Principal Contact:

Murray Thompson

Burner development (Swirl &

Atomization)

Combustion of 80/20

bio-oil/ethanol mixtures

CFD Combustion model

Bio-oil upgrading

4 Grad students + 2 in Fall 10 kW Burner

University of Western Ontario

Principal Contact: Franco Berrutti

5 pyrolysis pilot plants ( 1-2 kg/h)

Valorization of different feedstocks

Primary “cheap” upgrading

Co-processing with fossil fuels

Catalytic pyrolysis

Gasification of pyrolysis oils

>10 students and pdfs

Principals in Agri-Therm

Research Instutute: ICFAR

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Fernando [email protected]

Tel: +1-613-996-5589

Thank You!

http://canmetenergy.nrcan.gc.ca/