organics in soils/and sediments - raybestos memorial ball ...gas chromatography-mass spectrometory...

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^ » ?.'*,. UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

REGION I ENVIRONMENTAL SERVICES DIVISION

60 WESTVIEW STREET, LEXINGTON, MASSACHUSETTS 02173-3185

SDMS DocID 493944

DATE: January 16, 1992

SUB J : Gas Chromatography-Mass Spectrometory Analysis of Extractable Organics in Soils/and Sediments - Raybestos Memorial Ball Field

FROM: Pete Philbrook /S iresli Snvastava, Shirish Vora and Dick Siscanaw, Chemistry Section

THRU: Dr. William J. Andrade, Chief, Chemistry Section

TO: Dorothy Girten l\7 7 ' i l l ^O Superfund Records Center SITE: fay^a^ BREAK: a-3 OTHER: PROJECT NUMBER: 92026

ANALYTICAL PROCEDURE:

All samples were received and logged in by the laboratory according to the chain of custody SOP (G-2, 11/88, DCN: CH001/88).

EPA Region 1 Procedure for Medium Level Analyses for Extractable Organics in Solid Matrix Samples. The samples are extracted by the medium method of RCRA 3550 using methylene chloride and acetone. The extracts are analyzed on a gas chromatograph/mass spectrometer. All the values are reported out on a dry weight basis.

Date(s) Samples Received by the Laboratory: 11/18/91

Date Analysis Started: 11/22/91

cc:

File: K:\CHEMSTRY\REPORTS\FINAL\92026SO.BNA

US ENVIRONMENTAL PROTECTION AGENCY 60 Westview Street

Lexington, MA 02173

QUALITY CONTROL:

1. A laboratory blank was analyzed before the sample analysis.

2. Each sample was spiked with several surrogate compounds at approximately 75 mg/kg concentration. The results for the surrogate recoveries are reported out for each sample.

3. One sample, 00550, was spiked as a matrix spike with the following compounds at approximately 75 mg/kg concentration.

Compound Rec. (%)

QC Range (%)

Comments

Acenaphthene 4-Chloro-3-methylphenol 2-Chlorophenol 1,4-Dichlorobenzene 2,4-Dinitrotoluene 4-Nitrophenol N-Nitrosodipropylamine Pentachlorophenol Phenol Pyrene 1,2,4-Trichlorobenzene

51 42 55 45 47 54 44 30 53 68 43

31-137 26-103 25-102 28-104 28-89 11-114 41-126 17-109 26-90 35-142 38-107

(Cont.)


Lexington, HA 02173

COMPOUNDS NOT IN THE SPIKING SOLUTION:

Target Compounds Cone,

(mg/kg)

Benzo(a)anthracene -0.9 Benzo(k)fluoranthene ~1 Benzo(a)pyrene -0.6 Chrysene -1 2-Methyl Naphthalene (isomer) -0.7

Tentatively Identified Cone, Compounds (mg/kg) _(top 5) None

NOTE: Phthalates (1,2-Benzenedicarboxylic esters) and adipates (hexanedioic esters) are common method contaminants. Values at the detection levels are most likely due to method contamination.

SAMPLES ANALYZED: 00533 00548 00549 00550 00551 00552

US ENVIRONMENTAL PROTECTION AGENCY 60 Westview street

Lexington, MA 02173

ANALYTICAL PARAMETERS

INSTRUMENTS:

Hewlett Packard 5890 Gas Hewlett Packard 5987 Gas Spectrometer

GC/FID Screening Conditions:

Gas:

Capillary Column:

Injection Mode:

Temperature Program:

GC-MS Conditions:

Gas:

Capillary Column:

Injection Mode:

Temperature Program:

Injector, Transfer Temperatures:

Electron Energy:

Mass Range:

Scan Rate:

Chromatograph Chromatograph-Mass

Hydrogen

DB-5, 30m, 0.32mm ID, 0.10 micron film thickness

Splitless

Isothermal for 3 min at 4 0°C, programmed at 15°C/min to 320°C for 3 min

Helium

DB-5, 60m, 0.25mm ID, 0.25 micron film thickness

Splitless

Isothermal for 4 min at 40°C, programmed at 7°C/min to 300°C

300°C, 290°C

70 V

35-550

0.9 seconds


Lexington, MA 02173

Chemist who reviewed data: Dick Siscanaw

Method modifications: None

Limitations of data: None

Laboratory blank problems: THe laboratory blank had dioctylhexanedioic acid ester- at approxiamately 4 mg/kg.

Instrument performance problems: None

Surrogate and spike recovery problems: None

Additional comments: None

FACILITY SAMPLED: RAYBESTOS MEMORIAL BALL FIELD

US ENVIRONMENTAL PROTECTION AGENCY REGION I LABORATORY GC/MS EXTRACTABLE ORGANIC ANALYSIS

SAMPLE NO. : 00533 Percent Moisture: 22 SAMPLE LOCATION: Dilution i Factors DATE OF COLLECTION: Base: 0.3 TIME OF COLLECTION: Acid: 0.3 SAMPLE RESULTS:

CAS STORET Compound Cone. PQL Comments NO. NO. (mg/kg) (mg/kg)

Priority Pollutants

83-32-9 34205 Acenaphthene ND 3E+00 208-96-8 34200 Acenaphthylene ND 3E+00 120-12-7 34220 Anthracene ND 3E+00 309-00-2 39330 Aldrin ND 3E+00 56-55-3 34526 Benzo(a)anthracene ND 3E+00 205-99-2 34230 Benzo(b)fluoranthene ND 3E+00 207-08-9 34242 Benzo(k)fluoranthene ND 3E+00 50-32-8 34247 Benzo(a)pyrene ND 3E+00 191-24-2 34521 Benzo(ghi)perylene ND 3E+00 85-68-7 34292 Benzyl butyl phthalate ND 3E+00 319-85-7 39338 beta-BHC ND 3E+00 319-86-8 34259 delta-BHC ND 3E+00 111-44-4 34273 Bis(2-chloroethyl)ether ND 3E+00 111-91-1 34278 Bis(2-chloroethoxy)methane ND 3E+00 117-81-7 39100 Bis(2-ethyIhexy1)phthalate ND 3E+00 108-60-1 34283 Bis(2-chloroisopropyl)ether ND 3E+00 101-55-3 34636 4-Bromophenylphenyl ether ND 3E+00 59-50-7 34452 4-Chloro-3-methylphenol ND 3E+00 91-58-7 34581 2-Chloronaphthalene ND 3E+00 95-57-8 34586 2-Chlorophenol ND 3E+00 7005-72-3 34641 4-ChlorophenyIpheny1 ether ND 3E+00 218-01-9 34320 Chrysene ND 3E+00 72-54-8 39310 4,4'-DDD ND 3E+00 72-55-9 39320 4,4'-DDE ND 3E+00 50-29-3 39300 4,4'-DDT ND 3E+00 53-70-3 34556 Dibenzo(a,h)anthracene ND 3E+00 84-74-2 39110 Di-n-butylphtalate ND 3E+00 541-73-1 34566 1,3-Dichlorobenzene ND 3E+00

(con't)


SAMPLE NO.: 00533 Sample Results Continued:


95-50-1 34536 1,2-Dichlorobenzene ND 3E+00 106-46-7 34571 1,4-Dichlorobenzene ND 3E+00 91-94-1 34631 3,3'-Dichlorobenzidine ND 6E+00 120-83-2 34601 2,4-Dichlorophenol ND 3E+00 60-57-1 39380 Dieldrin ND 3E+00 84-66-2 34336 Diethylphtalate ND 3E+00 105-67-9 34606 2-4-DimethyIphenol ND 3E+00 131-11-3 34341 DimethyIphthalate ND 3E+00 51-28-5 34616 2,4-Dinitrophenol ND 2E+01 121-14-2 34611 2,4-Dinitrotoluene ND 3E+00 606-20-2 34626 2,6-Dinitrotoluene ND 3E+00 117-84-0 34596 Di-n-octyIphthalate ND 3E+00 206-44-0 34376 Fluoranthene ND 3E+00 86-73-7 34381 Fluorene ND 3E+00 76-44-8 39410 Heptachlor ND 3E+00 1024-57-3 39420 Heptachlor epoxide ND 3E+00 118-74-1 39700 Hexachlorobenzene ND 3E+00 87-68-3 34391 Hexachlorobutadiene ND 3E+00 77-47-4 34386 Hexachlorocyclopentadiene ND 3E+00 67-72-1 34396 Hexachloroethane ND 3E+00 193-39-5 34403 Indeno(1,2,3-cd)pyrene ND 3E+00 78-59-1 34408 Isophorone ND 3E+00 534-52-1 34657 2-methyl-4,6-dinitrophenol ND 2E+01 91-20-3 34696 Naphthalene ND 3E+00 98-95-3 34447 Nitrobenzene ND 3E+00 88-75-5 34591 2-Nitrophenol ND 3E+00 100-02-7 34646 4-Nitrophenol ND 2E+01 86-30-3 34433 N-nitrosodiphenylamine ND 3E+00 621-64-7 34428 N-Nitrosodi-n-propylamine ND 3E+00 87-86-5 39032 Pentachlorophenol ND 2E+01 85-01-8 34461 Phenanthrene ND 3E+00 108-95-2 34694 Phenol ND 3E+00 129-00-0 34469 Pyrene ND 3E+00

(con't)


SAMPLE NO.: 0053 3 Sample Results Continued:

CAS NO.

STORET NO.

Compound Cone. (mg/kg)

PQL(mg/kg)

Comments

120-82-1 88-06-2

34551 34621

1,2,4—Trichlorobenzene 2,4,6-Trichlorophenol

ND ND

3E+00 3E+00

Hazardous Substances

65-53-3 65-85-0 100-51-6 106-47-8 132-64-9 534-52-1 91-57-6 95-48-7 106-44-5 88-74-4 99-09-2 100-01-6 95-95-4

77089 77247 77147

81302

34621

Aniline Benzoic Acid Benzyl Alcohol 4-Chloroaniline Dibenzofuran 4,6-Dinitro-2-methyIphenol 2-Methylnaphthalene 2-Methylphenol 4-MethyIphenol 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline 2,4,5-Trichlorophenol

ND ND ND ND ND ND ND ND ND ND ND ND ND

3E+00 2E+01 3E+00 3E+00 3E+00 2E+01 3E+00 3E+00 3E+00 2E+01 2E+01 2E+01 2E+01

Other Compounds Quantitated

None detected ND 2E+01

Est. Tentatively Identified Cone. PQL Compounds (mg/kg) (mg/kg)


PCBs confirmed. See PCB report for values.



Sample Recoveries For Surrogate Compounds:

Recoveries (%)

QC Range (%)

2-Fluorophenol 74 30-115 Phenol,d5 68 24-113 Nitrobenzene,d5 63 23-120 Fluorobiphenyl 75 30-115 2,4,6-Tribromophenol 50 19-122 p-Terphenyl,dl4 102 18-137

Notes: PQL = Practical quantitation level

6E+00 = 6, 1E+01 = 10, 4E-01 = 0.4 ND = None detected - = Approximate < = Less than > = Greater than

NA = Not available, due to sample dilution or interference E = Estimated value exceeds the calibration range L = Estimated value is below the calibration range B = Analyte is associated with the lab blank or trip blank

contamination. Values are reported when observed concentration is ten times higher than the common contaminates (phthalates and adipates) or is five times higher than the remaining contaminates.



SAMPLE NO.: 00548 Percent ;Moisture: 16 SAMPLE LOCATION: Dilution Factor: DATE OF COLLECTION: Base: 0.3 TIME OF COLLECTION: Acid: 0.3 SAMPLE RESULTS:

CAS STORET Compound Cone. PQL Coi tnments NO. NO. (mg/kg) (mg/kg)

Priority Pollutants

83-32-9 34205 Acenaphthene ND 3E+00 208-96-8 34200 Acenaphthylene ND 3E+00 120-12-7 34220 Anthracene ND 3E+00 309-00-2 39330 Aldrin ND 3E+00 56-55-3 34526 Benzo(a)anthracene ND 3E+00 205-99-2 34230 Benzo(b)fluoranthene ND 3E+00 207-08-9 34242 Benzo(k)fluoranthene ND 3E+00 50-32-8 34247 Benzo(a)pyrene ND 3E+00 191-24-2 34521 Benzo(ghi)perylene ND 3E+00 85-68-7 34292 Benzyl butyl phthalate ND 3E+00 319-85-7 39338 beta-BHC ND 3E+00 319-86-8 34259 delta-BHC ND 3E+00 111-44-4 34273 Bis(2-chloroethyl)ether ND 3E+00 111-91-1 34278 Bis(2-chloroethoxy)methane ND 3E+00 117-81-7 39100 Bis(2-ethyIhexy1)phthalate ND 3E+00 108-60-1 34283 Bis(2-chloroisopropyl)ether ND 3E+00 101-55-3 34636 4-BromophenyIpheny1 ether ND 3E+00 59-50-7 34452 4-Chloro-3-methylphenol ND 3E+00 91-58-7 34581 2-Chloronaphthalene ND 3E+00 95-57-8 34586 2-Chlorophenol ND 3E+00 7005-72-3 34641 4-ChlorophenyIpheny1 ether ND 3E+00 218-01-9 34320 Chrysene ND 3E+00 72-54-8 39310 4,4'-DDD ND 3E+00 72-55-9 39320 4,4'-DDE ND 3E+00 50-29-3 39300 4,4'-DDT ND 3E+00 53-70-3 34556 Dibenzo(a,h)anthracene ND 3E+00 84-74-2 39110 Di-n-butylphtalate ND 3E+00 541-73-1 34566 1,3-Dichlorobenzene ND 3E+00

(con't)

10



CAS NO.

STORET NO.

Compound Cone. PQL (mg/kg) (mg/kg)

Comments

95-50-1 34536 1,2-Dichlorobenzene ND 3E+00 106-46-7 34571 1,4-Dichlorobenzene ND 3E+00 91-94-1 34631 3,3'-Dichlorobenzidine ND 6E+00 120-83-2 34601 2,4-Dichlorophenol ND 3E+00 60-57-1 39380 Dieldrin ND 3E+00 84-66-2 34336 Diethylphtalate ND 3E+00 105-67-9 34606 2-4-DimethyIphenol ND 3E+00 131-11-3 34341 D imethyIphthalate ND 3E+00 51-28-5 121-14-2

34616 34611

2,4-Dinitrophenol 2,4-Dinitrotoluene

ND ND

2E+01 3E+00

606-20-2 34626 2,6-Dinitrotoluene ND 3E+00 117-84-0 206-44-0

34596 34376

Di-n-octyIphthalate Fluoranthene

ND ND

3E+00 3E+00

86-73-7 34381 Fluorene ND 3E+00 76-44-8 1024-57-3 118-74-1

39410 39420 39700

Heptachlor Heptachlor epoxide Hexachlorobenzene

ND ND ND

3E+00 3E+00 3E+00

87-68-3 34391 Hexachlorobutadiene ND 3E+00 77-47-4 67-72-1

34386 34396

Hexachlorocyclopentadiene Hexachloroethane

ND ND

3E+00 3E+00

193-39-5 78-59-1

34403 34408

Indeno(1,2,3-cd)pyrene Isophorone

ND ND

3E+00 3E+00

534-52-1 34657 2-methyl-4,6-dinitrophenol ND 2E+01 91-20-3 34696 Naphthalene ND 3E+00 98-95-3 34447 Nitrobenzene ND 3E+00 88-75-5 34591 2-Nitrophenol ND 3E+00 100-02-7 34646 4-Nitrophenol ND 2E+01 86-30-3 34433 N-nitrosodiphenylamine ND 3E+00 621-64-7 34428 N-Nitrosodi-n-propylamine ND 3E+00 87-86-5 39032 Pentachlorophenol ND 2E+01 85-01-8 34461 Phenanthrene ND 3E+00 108-95-2 34694 Phenol ND 3E+00 129-00-0 34469 Pyrene ND 3E+00

(cont't)

11



CAS NO.

STORET NO.


PQL(mg/kg)

CComments

120-82-1 88-06-2

34551 34621


-0.7 ND

3E+00 3E+00

L


65-53-3 65-85-0 100-51-6 106-47-8 132-64-9 534-52-1 91-57-6 95-48-7 106-44-5 88-74-4 99-09-2 100-01-6 95-95-4

77089 77247 77147

81302

34621

Aniline Benzoic Acid Benzyl Alcohol 4-Chloroaniline Dibenzofuran 4,6-Dinitro-2-methylphenol 2-Methylnaphthalene 2-Methylphenol 4-Methylphenol 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline 2,4,5-Trichlorophenol


3E+00 2E+01 3E+00 3E+00 3E+00 2E+01 3E+00 3E+00 3E+00 2E+01 2E+01 2E+01 2E+01




Dioctyl Hexanedioic acid 80 3E+00 ester

12



Sample Recoveries For Surrogate Compounds;

Recoveries (%)

QC Range (%)


Notes; PQL = Practical quantitation level

6E+00 = 6, 1E+01 = 10, 4E-01 = 0.4 ND = None detected - = Approximate < = Less than > = Greater than NA = Not available, due to sample dilution or interference E = Estimated value exceeds the calibration range L = Estimated value is below the calibration range B = Analyte is associated with the lab blank or trip blank


13



SAMPLE NO.: 00549 Percent Moisture: 20 SAMPLE LOCATION: Dilution Factor: DATE OF COLLECTION: Base: 0.26 TIME OF COLLECTION: Acid: 0.26 SAMPLE RESULTS:

CAS STORET Compound Cone. PQL CComments NO. NO. (mg/kg) (mg/kg)

Priority Pollutants

83-32-9 34205 Acenaphthene ND 3E+00 208-96-8 34200 Acenaphthylene ND 3E+00 120-12-7 34220 Anthracene ND 3E+00 309-00-2 39330 Aldrin ND 3E+00 56-55-3 34526 Benzo(a)anthracene -0.6 3E+00 L 205-99-2 34230 Benzo(b)fluoranthene ND 3E+00 207-08-9 34242 Benzo(k)fluoranthene -1 3E+00 L 50-32-8 34247 Benzo(a)pyrene -0.6 3E+00 L 191-24-2 34521 Benzo(ghi)perylene ND 3E+00 85-68-7 34292 Benzyl butyl phthalate ND 3E+00 319-85-7 39338 beta-BHC ND 3E+00 319-86-8 34259 delta-BHC ND 3E+00 111-44-4 34273 Bis(2-chloroethyl)ether ND 3E+00 111-91-1 34278 Bis(2-chloroethoxy)methane ND 3E+00 117-81-7 39100 Bis(2-ethyIhexy1)phthalate ND 3E+00 108-60-1 34283 Bis(2-chloroisopropyl)ether ND 3E+00 101-55-3 34636 4-BromophenyIpheny1 ether ND 3E+00 59-50-7 34452 4-Chloro-3-methylphenol ND 3E+00 91-58-7 34581 2-Chloronaphthalene ND 3E+00 95-57-8 34586 2-Chlorophenol ND 3E+00 7005-72-3 34641 4-Chlorophenylphenyl ether ND 3E+00 218-01-9 34320 Chrysene -0.9 3E+00 L 72-54-8 39310 4,4'-DDD ND 3E+00 72-55-9 39320 4,4'-DDE ND 3E+00 50-29-3 39300 4,4'-DDT ND 3E+00 53-70-3 34556 Dibenzo(a,h)anthracene ND 3E+00 84-74-2 39110 Di-n-butylphtalate ND 3E+00 541-73-1 34566 1,3-Dichlorobenzene ND 3E+00

(con't)

14


SAMPLE NO.: 00549 Sample Results Continued;


95-50-1 34536 1,2-Dichlorobenzene ND 3E+00 106-46-7 34571 1,4-Dichlorobenzene ND 3E+00 91-94-1 34631 3,3'-Dichlorobenzidine ND 5E+00 120-83-2 34601 2,4-Dichlorophenol ND 3E+00 60-57-1 39380 Dieldrin ND 3E+00 84-66-2 34336 Diethylphtalate ND 3E+00 105-67-9 34606 2-4-DimethyIphenol ND 3E+00 131-11-3 34341 D imethyIphthalate ND 3E+00 51-28-5 34616 2,4-Dinitrophenol ND 1E+01 121-14-2 34611 2,4-Dinitrotoluene ND 3E+00 606-20-2 34626 2,6-Dinitrotoluene ND 3E+00 117-84-0 34596 Di-n-octyIphthalate ND 3E+00 206-44-0 34376 Fluoranthene ND 3E+00 86-73-7 34381 Fluorene ND 3E+00 76-44-8 39410 Heptachlor ND 3E+00 1024-57-3 39420 Heptachlor epoxide ND 3E+00 118-74-1 39700 Hexachlorobenzene ND 3E+00 87-68-3 34391 Hexachlorobutadiene ND 3E+00 77-47-4 34386 Hexachlorocyclopentadiene ND 3E+00 67-72-1 34396 Hexachloroethane ND 3E+00 193-39-5 34403 Indeno(1,2,3-cd)pyrene ND 3E+00 78-59-1 34408 Isophorone ND 3E+00 534-52-1 34657 2-methyl-4,6-dinitrophenol ND 1E+01 91-20-3 34696 Naphthalene ND 3E+00 98-95-3 34447 Nitrobenzene ND 3E+00 88-75-5 34591 2-Nitrophenol ND 3E+00 100-02-7 34646 4-Nitrophenol ND 1E+01 86-30-3 34433 N-nitrosodiphenylamine ND 3E+00 621-64-7 34428 N-Nitrosodi-n-propylamine ND 3E+00 87-86-5 39032 Pentachlorophenol ND 1E+01 85-01-8 34461 Phenanthrene ND 3E+00 108-95-2 34694 Phenol ND 3E+00 129-00-0 34469 Pyrene -1 3E+00

(cont't)

15



CAS NO.

STORET NO.


Comments

120-82-1 88-06-2

34551 34621


ND ND

3E+00 3E+00


65-53-3 65-85-0 100-51-6 106-47-8 132-64-9 534-52-1 91-57-6 95-48-7 106-44-5 88-74-4 99-09-2 100-01-6 95-95-4

77089 77247 77147

81302

34621

Aniline Benzoic Acid Benzyl Alcohol 4-Chloroaniline Dibenzofuran 4,6-Dinitro-2-methylphenol 2-MethyInaphthalene 2-Methylphenol 4-Methylphenol 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline 2,4,5-Trichlorophenol


3E+00 1E+01 3E+00 3E+00 3E+00 1E+01 3E+00 3E+00 3E+00 1E+01 1E+01 1E+01 1E+01





16


SAMPLE NO.:Sample Results Continued:

00549

Sample ReSurrogate Compounds:

coveries For Recoveries (%)

QC Range (%)

2-Fluorophenol Phenol,d5 Nitrobenzene,d5 Fluorobiphenyl 2,4,6-Tribromophenol p-Terphenyl,dl4

74 67 66 71 44 83

30-115 24-113 23-120 30-115 19-122 18-137


6E+00 = 6, 1E+01 = 10, 4E-01 = 0.4 ND = None detected ~ = Approximate < = Less than > = Greater than



17



SAMPLE NO. : 00550 Percent Moisture: 16 SAMPLE LOCATION: Dilution i Factor: DATE OF COLLECTION: Base: 0.27 TIME OF COLLECTION: Acid: 0.27 SAMPLE RESULTS:


Priority Pollutants

83-32-9 34205 Acenaphthene ND 3E+00 208-96-8 34200 Acenaphthylene ND 3E+00 120-12-7 34220 Anthracene ND 3E+00 309-00-2 39330 Aldrin ND 3E+00 56-55-3 34526 Benzo(a)anthracene ND 3E+00 205-99-2 34230 Benzo(b)fluoranthene ND 3E+00 207-08-9 34242 Benzo(k)fluoranthene -0.6 3E+00 L 50-32-8 34247 Benzo(a}pyrene -0.4 3E+00 L 191-24-2 34521 Benzo(ghi)perylene ND 3E+00 85-68-7 34292 Benzyl butyl phthalate ND 3E+00 319-85-7 39338 beta-BHC ND 3E+00 319-86-8 34259 delta-BHC ND 3E+00 111-44-4 34273 Bis(2-chloroethyl)ether ND 3E+00 111-91-1 34278 Bis(2-chloroethoxy)methane ND 3E+00 117-81-7 39100 Bis(2-ethylhexyl)phthalate ND 3E+00 108-60-1 34283 Bis(2-chloroisopropyl)ether ND 3E+00 101-55-3 34636 4-Bromophenylphenyl ether ND 3E+00 59-50-7 34452 4-Chloro-3-methylphenol ND 3E+00 91-58-7 34581 2-Chloronaphthalene ND 3E+00 95-57-8 34586 2-Chlorophenol ND 3E+00 7005-72-3 34641 4-ChlorophenyIpheny1 ether ND 3E+00 218-01-9 34320 Chrysene -0.4 3E+00 L 72-54-8 39310 4,4'-DDD ND 3E+00 72-55-9 39320 4,4'-DDE ND 3E+00 50-29-3 39300 4,4'-DDT ND 3E+00 53-70-3 34556 Dibenzo(a,h)anthracene ND 3E+00 84-74-2 39110 Di-n-butylphtalate ND 3E+00 541-73-1 34566 1,3-Dichlorobenzene ND 3E+00

(con't)

18




95-50-1 34536 1,2-Dichlorobenzene ND 3E+00 106-46-7 34571 1,4-Dichlorobenzene ND 3E+00 91-94-1 34631 3,3'-Dichlorobenzidine ND 5E+00 120-83-2 34601 2,4-Dichlorophenol ND 3E+00 60-57-1 39380 Dieldrin ND 3E+00 84-66-2 34336 Diethylphtalate ND 3E+00 105-67-9 34606 2-4-DimethyIphenol ND 3E+00 131-11-3 34341 DimethyIphthalate ND 3E+00 51-28-5 34616 2,4-Dinitrophenol ND 1E+01 121-14-2 34611 2,4-Dinitrotoluene ND 3E+00 606-20-2 34626 2,6-Dinitrotoluene ND 3E+00 117-84-0 34596 Di-n-octyIphthalate ND 3E+00 206-44-0 34376 Fluoranthene ND 3E+00 86-73-7 34381 Fluorene ND 3E+00 76-44-8 39410 Heptachlor ND 3E+00 1024-57-3 39420 Heptachlor epoxide ND 3E+00 118-74-1 39700 Hexachlorobenzene ND 3E+00 87-68-3 34391 Hexachlorobutadiene ND 3E+00 77-47-4 34386 Hexachlorocyclopentadiene ND 3E+00 67-72-1 34396 Hexachloroethane ND 3E+00 193-39-5 34403 Indeno(1,2,3-cd)pyrene ND 3E+00 78-59-1 34408 Isophorone ND 3E+00 534-52-1 34657 2-methyl-4,6-dinitrophenol ND 1E+01 91-20-3 34696 Naphthalene ND 3E+00 98-95-3 34447 Nitrobenzene ND 3E+00 88-75-5 34591 2-Nitrophenol ND 3E+00 100-02-7 34646 4-Nitrophenol ND 1E+01 86-30-3 34433 N-nitrosodiphenylamine ND 3E+00 621-64-7 34428 N-Nitrosodi-n-propylamine ND 3E+00 87-86-5 39032 Pentachlorophenol ND 1E+01 85-01-8 34461 Phenanthrene ND 3E+00 108-95-2 34694 Phenol ND 3E+00 129-00-0 34469 Pyrene -0.5 3E+00 L

(cont't)

19



CAS NO.

STORET NO.


PQL(mg/kg)

Comments

120-82-1 88-06-2

34551 34621


ND ND

3E+00 3E+00


65-53-3 65-85-0 100-51-6 106-47-8 132-64-9 534-52-1 91-57-6 95-48-7 106-44-5 88-74-4 99-09-2 100-01-6 95-95-4

77089 77247 77147

81302

34621

Aniline Benzoic Acid Benzyl Alcohol 4-Chloroaniline Dibenzofuran 4,6-Dinitro-2-methyIphenol 2-Methylnaphthalene 2-Methylphenol 4-Methylphenol 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline 2,4,5-Trichlorophenol


3E+00 1E+01 3E+00 3E+00 3E+00 1E+01 3E+00 3E+00 3E+00 1E+01 1E+01 1E+01 1E+01





20




Recoveries (%)

QC Range (%)



6E+00 = 6, 1E+01 = 10, 4E-01 = 0.4 ND = None detected - = Approximate < = Less than > = Greater than



21




CAS STORET Compound Cone, PQL Comments NO. NO. (mg/kg) (mg/kg)

Priority Pollutants

83-32-9 34205 Acenaphthene ND 3E+00 208-96-8 34200 Acenaphthylene ND 3E+00 120-12-7 34220 Anthracene ND 3E+00 309-00-2 39330 Aldrin ND 3E+00 56-55-3 34526 Benzo(a)anthracene ND 3E+00 205-99-2 34230 Benzo(b)fluoranthene ND 3E+00 207-08-9 34242 Benzo(k)fluoranthene -0.4 3E+00 50-32-8 34247 Benzo(a)pyrene ND 3E+00 191-24-2 34521 Benzo(ghi)perylene ND 3E+00 85-68-7 34292 Benzyl butyl phthalate ND 3E+00 319-85-7 39338 beta-BHC ND 3E+00 319-86-8 34259 delta-BHC ND 3E+00 111-44-4 34273 Bis(2-chloroethyl)ether ND 3E+00 111-91-1 34278 Bis(2-chloroethoxy)methane ND 3E+00 117-81-7 39100 Bis(2-ethyIhexyl)phthalate -0.8 3E+00 108-60-1 34283 Bis(2-chloroisopropyl)ether ND 3E+00 101-55-3 34636 4-Bromophenylphenyl ether ND 3E+00 59-50-7 34452 4-Chloro-3-methylphenol ND 3E+00 91-58-7 34581 2-Chloronaphthalene ND 3E+00 95-57-8 34586 2-Chlorophenol ND 3E+00 7005-72-3 34641 4-ChlorophenyIpheny1 ether ND 3E+00 218-01-9 34320 Chrysene -0.4 3E+00 72-54-8 39310 4,4'-DDD ND 3E+00 72-55-9 39320 4,4'-DDE ND 3E+00 50-29-3 39300 4,4'-DDT ND 3E+00 53-70-3 34556 Dibenzo(a,h)anthracene ND 3E+00 84-74-2 39110 Di-n-butylphtalate ND 3E+00 541-73-1 34566 1,3-Dichlorobenzene ND 3E+00

(con't)

22



CAS NO.

STORET NO.


Comments

95-50-1 34536 1,2-Dichlorobenzene ND 3E+00 106-46-7 34571 1,4-Dichlorobenzene ND 3E+00 91-94-1 34631 3,3'-Dichlorobenzidine ND 5E+00 120-83-2 34601 2,4-Dichlorophenol ND 3E+00 60-57-1 39380 Dieldrin ND 3E+00 84-66-2 34336 Diethylphtalate ND 3E+00 105-67-9 34606 2-4-DimethyIphenol ND 3E+00 131-11-3 34341 DimethyIphthalate ND 3E+00 51-28-5 34616 2,4-Dinitrophenol ND 1E+01 121-14-2 34611 2,4-Dinitrotoluene ND 3E+00 606-20-2 34626 2,6-Dinitrotoluene ND 3E+00 117-84-0 34596 Di-n-octyIphthalate ND 3E+00 206-44-0 34376 Fluoranthene ND 3E+00 86-73-7 34381 Fluorene ND 3E+00 76-44-8 1024-57-3 118-74-1

39410 39420 39700

Heptachlor Heptachlor epoxide Hexachlorobenzene

ND ND ND

3E+00 3E+00 3E+00

87-68-3 34391 Hexachlorobutadiene ND 3E+00 77-47-4 67-72-1

34386 34396

Hexachlorocyclopentadiene Hexachloroethane

ND ND

3E+00 3E+00

193-39-5 34403 Indeno(l,2,3-cd)pyrene ND 3E+00 78-59-1 34408 Isophorone ND 3E+00 534-52-1 34657 2-methyl-4,6-dinitrophenol ND 1E+01 91-20-3 34696 Naphthalene ND 3E+00 98-95-3 34447 Nitrobenzene ND 3E+00 88-75-5 34591 2-Nitrophenol ND 3E+00 100-02-7 34646 4-Nitrophenol ND 1E+01 86-30-3 34433 N-nitrosodiphenylamine ND 3E+00 621-64-7 34428 N-Nitrosodi-n-propylamine ND 3E+00 87-86-5 39032 Pentachlorophenol ND 1E+01 85-01-8 34461 Phenanthrene ND 3E+00 108-95-2 34694 Phenol ND 3E+00 129-00-0 34469 Pyrene 0.4 3E+00

(cont't)

23



CAS NO.

STORET NO.

Compound Cone. PQL(mg/kg) (mg/kg)

Comments

120-82-188-06-2

34551 34621


ND ND

3E+00 3E+00


65-53-3 65-85-0 100-51-6 106-47-8 132-64-9 534-52-1 91-57-6 95-48-7 106-44-5 88-74-4 99-09-2 100-01-6 95-95-4

77089 77247 77147

81302

34621

Aniline Benzoic Acid Benzyl Alcohol 4-Chloroaniline Dibenzofuran 4,6-Dinitro-2-methyIphenol 2-Methylnaphthalene 2-Methylphenol 4-Methylphenol 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline 2,4,5-Trichlorophenol


3E+00 1E+01 3E+00 3E+00 3E+00 1E+01 3E+00 3E+00 3E+00 1E+01 1E+01 1E+01 1E+01




Hexacosane 3E+00

24




Recoveries (%)

QC Range (%)





25





Priority Pollutants

83-32-9 34205 Acenaphthene ND 3E+00 208-96-8 34200 Acenaphthylene ND 3E+00 120-12-7 34220 Anthracene ND 3E+00 309-00-2 39330 Aldrin ND 3E+00 56-55-3 34526 Benzo(a)anthracene ND 3E+00 205-99-2 34230 Benzo(b)fluoranthene ND 3E+00 207-08-9 34242 Benzo(k)fluoranthene ND 3E+00 50-32-8 34247 Benzo(a)pyrene ND 3E+00 191-24-2 34521 Benzo(ghi)perylene ND 3E+00 85-68-7 34292 Benzyl butyl phthalate ND 3E+00 319-85-7 39338 beta-BHC ND 3E+00 319-86-8 34259 delta-BHC ND 3E+00 111-44-4 34273 Bis(2-chloroethyl)ether ND 3E+00 111-91-1 34278 Bis(2-chloroethoxy)methane ND 3E+00 117-81-7 39100 Bis(2-ethylhexyl)phthalate ND 3E+00 108-60-1 34283 Bis(2-chloroisopropyl)ether ND 3E+00 101-55-3 34636 4-Bromophenylphenyl ether ND 3E+00 59-50-7 34452 4-Chloro-3-methylphenol ND 3E+00 91-58-7 34581 2-Chloronaphthalene ND 3E+00 95-57-8 34586 2-Chlorophenol ND 3E+00 7005-72-3 34641 4-ChlorophenyIpheny1 ether ND 3E+00 218-01-9 34320 Chrysene ND 3E+00 72-54-8 39310 4,4'-DDD ND 3E+00 72-55-9 39320 4,4'-DDE ND 3E+00 50-29-3 39300 4,4'-DDT ND 3E+00 53-70-3 34556 Dibenzo(a,h)anthracene ND 3E+00 84-74-2 39110 Di-n-butylphtalate ND 3E+00 541-73-1 34566 1,3-Dichlorobenzene ND 3E+00

(con't)

26




95-50-1 34536 1,2-Dichlorobenzene ND 3E+00 106-46-7 34571 1,4-Dichlorobenzene ND 3E+00 91-94-1 34631 3,3'-Dichlorobenzidine ND 6E+00 120-83-2 34601 2,4-Dichlorophenol ND 3E+00 60-57-1 39380 Dieldrin ND 3E+00 84-66-2 34336 Diethylphtalate ND 3E+00 105-67-9 34606 2-4-DimethyIphenol ND 3E+00 131-11-3 34341 DimethyIphthalate ND 3E+00 51-28-5 34616 2,4-Dinitrophenol ND 2E+01 121-14-2 34611 2,4-Dinitrotoluene ND 3E+00 606-20-2 34626 2,6-Dinitrotoluene ND 3E+00 117-84-0 34596 Di-n-octyIphthalate ND 3E+00 206-44-0 34376 Fluoranthene ND 3E+00 86-73-7 34381 Fluorene ND 3E+00 76-44-8 39410 Heptachlor ND 3E+00 1024-57-3 39420 Heptachlor epoxide ND 3E+00 118-74-1 39700 Hexachlorobenzene ND 3E+00 87-68-3 34391 Hexachlorobutadiene ND 3E+00 77-47-4 34386 Hexachlorocyclopentadiene ND 3E+00 67-72-1 34396 Hexachloroethane ND 3E+00 193-39-5 34403 Indeno(1,2,3-cd)pyrene ND 3E+00 78-59-1 34408 Isophorone ND 3E+00 534-52-1 34657 2-methy1-4,6-dinitrophenol ND 2E+01 91-20-3 34696 Naphthalene ND 3E+00 98-95-3 34447 Nitrobenzene ND 3E+00 88-75-5 34591 2-Nitrophenol ND 3E+00 100-02-7 34646 4-Nitrophenol ND 2E+01 86-30-3 34433 N-nitrosodiphenylamine ND 3E+00 621-64-7 34428 N-Nitrosodi-n-propylamine ND 3E+00 87-86-5 39032 Pentachlorophenol ND 2E+01 85-01-8 34461 Phenanthrene ND 3E+00 108-95-2 34694 Phenol ND 3E+00 129-00-0 34469 Pyrene ND 3E+00

(cont't)

27



CAS NO.

STORET NO.

Compound Cone. PQL(mg/kg) (mg/kg)

Comments

120-82-188-06-2

34551 34621


ND ND

3E+00 3E+00


65-53-3 65-85-0 100-51-6 106-47-8 132-64-9 534-52-1 91-57-6 95-48-7 106-44-5 88-74-4 99-09-2 100-01-6 95-95-4

77089 77247 77147

81302

34621

Aniline Benzoic Acid Benzyl Alcohol 4-Chloroaniline Dibenzofuran 4,6-Dinitro-2-methylphenol 2-Methylnaphthalene 2-Methylphenol 4-Methylphenol 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline 2,4,5-Trichlorophenol


3E+00 2E+01 3E+00 3E+00 3E+00 2E+01 3E+00 3E+00 3E+00 2E+01 2E+01 2E+01 2E+01




Benzodioxole 30 3E+00 Hexacosane 5 3E+00

28




Recoveries (%)

QC Range (%)





29

organics in soils/and sediments - raybestos memorial ball ...gas chromatography-mass spectrometory...

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