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Organic/Inorganic HybridMaterials—2007

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Cambridge University Press978-1-107-40867-8 - Organic/Inorganic Hybrid Materials—2007: Materials Research SocietySymposium Proceedings: Volume 1007Editors: Christophe Barbé, Richard M. Laine, Clément Sanchez and Ulrich Schubert

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MATERIALS RESEARCH SOCIETYSYMPOSIUM PROCEEDINGS VOLUME 1007

Organic/Inorganic HybridMaterials—2007

Symposium held April 9-13, 2007, San Francisco, California, U.S.A.

EDITORS:

Christophe BarbeCeramiSphere Pry Ltd

Sydney, Australia

Richard M. LaineUniversity of Michigan

Ann Arbor, Michigan, U.S.A.

Clement SanchezUniversite Pierre et Marie Curie

Paris, France

Ulrich SchubertVienna University of Technology

Wien, Austria

TMIRISIMaterials Research Society

Warrendale, Pennsylvania







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CONTENTS

Preface xi

Materials Research Society xii

ORGANOSILOXANE-BASED MATERIALS

* Nanostructuring of Hybrid Silicas: New Approach to BridgedSilsesquioxanes with Purine-Pyrimidine Base Pairs as BridgingUnits 3

Michel Wong Chi Man, Guilhem Arrachart, Carole Carcel,Joel J.E. Moreau, Christian Bonhomme, Florence Babonneau,Gaelle Creff, Jean-Louis Bantignies, Philippe Dieudonne,and Bruno Alonso

High Refractive Index Inorganic-Organic Hybrid Materialsfor Photonic Applications. 15

Pelagie Declerck, Ruth Houbertz, Georg Jakopic,Sven Passinger, and Boris Chichkov

The Study of Thermal Resistant Enhancement of Siloxane-Modified LED Transparent Encapsulants 23

Kai-Chi Chen, Chia-Wen Hsu, and Hsun-Tien Li

* Laddersiloxanes: Silsesquioxanes with Defined LadderStructure 29

Masafumi Unno

Comparison of Different Reversed-Phase Packing MaterialsBased on Higher Organic Hybrid Particles 41

Nicole L. Lawrence, Kevin D. Wyndham, Kenneth H. Glose,Jim T. Cook, Darryl W. Brousmiche, Pamela C. Iraneta,Bonnie A. Alden, Cheryl A. Boissel, and Thomas H. Walter

MESOPOROUS MA TERIALS AND FILMS

* Hierarchically Porous Oxides, Hybrids and PolymersVia Sol-Gel Accompanied by Phase Separation 51

Kazuki Nakanishi

* Invited Paper







Phase Separation in Alkoxy-Derived Silica SystemContaining Polyacrylamide 63

Kousuke Kawamoto, Kazuki Nakanishi, andTeiichi Hanada

Phase Separation in A12O3 Sol-Gel System Incorporatedwith High Molecular Weight Polyethylene oxide) 69

Yasuaki Tokudome, Kazuki Nakanishi, Koji Fujita,Kiyotaka Miura, and Kazuyuki Hirao

* Mesoporous Hybrid Thin Films: Building Blocks forComplex Materials with Spatial Organization 75

Galo J. Soler-Illia, Paula C. Angelome,M. Cecilia Fuertes, Alejandro Wolosiuk,Sara A. Bilmes, Francisco Javier Lopez-Alcaraz,and Hernan Miguez

Mesostructured Silica Films with Metal Oxide DopedPore Walls 87

Joachim Koehler, Jun Cai, Rolf Juergen Behm,and Nicola Huesing

Mesoporous Silica and Titania by Glycol-ModifiedPrecursors 93

Jasmin Geserick, Nicola Htising, Renate RoBmanith,Clemens K. Weiss, Katharina Landfester,Yvonne Denkwitz, R. Jurgen Behm, Ute Hormann,and Ute Kaiser

* From Polymeric to Particulate Inorganic MacrocellularFoams: Some Integrative Chemistry Synthetic Pathways 101

Florent Cam and Renal Backov

LA YERED MA TERIALS

Nacre-Like TiO2 - and ZnO-Based Organic/InorganicHybrid Systems 115

Zaklina Burghard, Luciana Pitta Bauermann,Aleksandar Tucic, Lars P.H. Jeurgens, Vesna Srot,Paul Bellina, Peter Lipowsky, Rudolf C. Hoffmann,Elazar Gutmanas, Joachim Bill, and Fritz Aldinger

* Invited Paper

VI







Material Characterization of a Novel Permeation Barrierfor Flexible Organic Displays 123

Jonathan Gartside, Prashant Mandlik, Sigurd Wagner,Teddy Zhou, Jeff Silvernail, and Mike Hack

New Organo-Inorganic Materials for Water ContaminantsRemediation 129

Araceli Ortiz-Polo, Rosa M. Richards-Uribe,Elena M. Otazo-Sanchez, Francisco Prieto-Garcia,Juan Hernandez-Avila, Otilio Acevedo-Sandoval,and Alberto Gordillo-Martinez

Improvements on Flame Retardant Properties ofPET/Montmorillonite Nanocomposite Caused byPolyborosiloxane 137

Yue Huo, Qinguo Fan, Nicholas A. Dembsey,and Prabir K. Patra

SURFACE AND INTERFACE MODIFICATIONSAND CHARACTERIZATION

Covalent Grafting of Organoalkoxysilanes on SilicaSurfaces in Water-Rich Medium as Evidenced by 29SiNMR 147

Christian Bonhomme, Sophie De Monredon,Francois Ribot, and Florence Babonneau

Polymer-Silica Nanocomposite Aerogels with EnhancedMechanical Properties Using Chemical Vapor Deposition(CVD) of Cyanoacrylates 153

Dylan J. Boday, Douglas A. Loy, Kimberley A. DeFriend,Kennard V. Wilson Jr., and David Coder

Composition and Functional Properties of OrganosiliconPlasma Polymers From Hexamethyldisiloxane andOctamethylcyclotetrasiloxane 159

Lenka Zajickova, Zuzana Kucerova, Vilma Bursikova,Daniel Franta, Vratislav Perina, and Anna Mackova

vn







CONTROLLED RELEASE ANDBIOLOGICAL APPLICATIONS

Effect of the Sol-Gel Synthesis Parameters on theIncorporation of an Anti-Inflammatory Drug in aCeramic Material 167

Aracely Hernandez, Patricia Esquivel-Ferrino,Idalia Gomez, and Lucia Cantu

* Evaluation of Cationic Biopolymers for the Designof Silica-Coated Alginate Capsules 175

Aurelie Bruyant and Thibaud Coradin

3D Composites Based on Hydroxyapatite-Chitosan-Polysiloxane as a Biomimetic Scaffold Materials 181

Andronico Neira-Carrillo, Jose Ignacio Arias,M. Soledad Fernandez, Ranjith Krishna Pai,Claudia Quilodran, and Jose L. Arias

Study of the Architecture of Inorganic-Organic Matrix inthe Ventral Segmental Concretion of Porcellius ChilensisNicolet, 1849 (Crustacea, Isopoda) 189

Ranjith Krishna Pai, Andronico Neira-Carrillo,Maria Soledad Fernandez, and Jose Luis Arias

NANOPARTICLES SYNTHESISAND ASSEMBLY

Versatile Hybrid Polymers as Matrices for NanoparticlePreparation 199

Claudia Feldgitscher, Sorin Ivanovici, and Guido Kickelbick

Hybrid Nanoparticles Prepared by In Situ and Post-SyntheticSurface Modification of Lanthanide-Based Nanoparticleswith Phosphonic Acid Derivatives 207

Christoph Rill, Sorin Ivanovici, and Guido Kickelbick

Metal Oxide Nanocrystals: Building Blocks for Mesostructuresand Precursors for Metal Nitrides 213

Markus Niederberger, Jelena Buha, and Igor Djerdj

*Invited Paper

Vlll







Design of Functionalized Fe3O4 Nanoparticles for Elaborationof Nanostructured Films with Magnetic Properties 223

Toufic Jean Daou, Fayna Mammeri, Saiwan Buathong,Yves Le Bras, Diane Ung, Jean Louis Gallani,Bertrand Donnio, Daniel Guillon, Genevieve Pourroy,and Sylvie Begin-Colin

NANOCOMPOSITES

Hybrid Nanocomposites Based on Metal Oxides andPolysiloxanes with Controlled Morphology 233

Sorin Ivanovici, Christoph Rill, Claudia Feldgitscher,and Guido Kickelbick

* Titanium Oxo-Clusters: Versatile Nano-Objects for theDesign of Hybrid Compounds 241

Laurence Rozes, Sebastien Cochet, Theo Frot,Giulia Fornasieri, Capucine Sassoye, Michael Popall,and Clement Sanchez

* Conjugated Polymers as Part of Multifunctional Organic/Inorganic Hybrid Materials for Photovoltaic Applications 249

Monica Lira-Cantu, Frederik C. Krebs,Pedro Gomez-Romero, and Shozo Yanagida

Luminescent Silica Thin Films 259Marie-Alexandra G. Neouze and Ulrich Schubert

Fabrication of Fluorescent Cellular Probes: HybridDendrimer/Gold Nanoclusters 265

Chang Zhong, Yuping Bao, Dung M. Vu,R. Brian Dyer, and Jennifer S. Martinez

Mechanical Behavior of Functional Hybrid Coating Basedon Anisotropic Iron Oxide Nanoparticles 271

Nicolas Chemin, Laurence Rozes, Corinne Chaneac,Sophie Cassaignon, Jean-Pierre Jolivet, Etienne Barthel,Eric Le Bourhis, and Clement Sanchez

Polymer Composite Reinforced with Nanodiamonds and Clay 279Valeriy V. Karbushev, Ivan Konstantinov,Alexander Semakov, Irina Parsamyan,Valery Kulichikhin, and Vladimir Popov

* Invited Paper

IX







NEW CONCEPTS

Polymerization Kinetics of Methacrylic Groups inOrganic-Inorganic Hybrid Polymeric Thin Films 287

Congji Zha, Xinshi Luo, and Barry Luther-Davies

Synthesis and Orientation of Poly(dialkylstannane)s 293Fabien Choffat, Sara Fornera, Paul Smith, andWalter Caseri

New Generation of Hybrid Organic-InorganicMacrocellular Foams: Integrative ChemistryToward Reaching Multifunctional Materials 301

Simona Ungureanu, Herve Deleuze,Marc Birot, Clement Sanchez, and Renal Backov

Low Temperature Deposition of Metal OxideThin Films in Supercritical Carbon DioxideUsing Metal-Organic Precursors 307

Theodosia Gougousi and Zhiying Chen

Author Index 313

Subject Index 317







PREFACE

Scientists from 27 different countries gathered to attend Symposium S, "Synthesis, Processingand Properties of Organic/Inorganic Hybrid Materials," held April 9-13 at the 2007 MRS SpringMeeting in San Francisco, California. During this week, 74 oral contributions and more than 100posters were presented, clearly confirming the role of this symposium as the premier forum forscientists from all over the world to discuss progress in the field of organic/inorganic hybridmaterials.

Since the inception of this seminar series in 1998, the field of organic/inorganic hybrids hasevolved significantly, providing materials with increasing architectural complexities andfunctionalities. The scientists involved in this field are gradually moving from building materialusing a classical molecular approach (e.g. polymerization) to assembling materials on thenanoscale using'a variety of innovative strategies, which can vary from the assembly of DNAmotifs, to the formation of mesoporous materials by spinodal decomposition, or the use ofnanoparticles or oxo-clusters as nano-building blocks for building complex structures such asnacre like transition metal oxides. This precise control over the materials architecture, also addsfunctionality to the hybrid materials whether it is for designing special membranes for phaseseparation and chromatography or thin films for photonic or magnetic applications.

This proceedings volume presents some of the contributions submitted during the symposium,which have been peer-reviewed and refereed. For clarity the papers are arranged in eight distinctsections: (1) organosiloxane-based materials, (2) mesoporous materials and films, (3) layeredmaterials, (4) surface and interface modification and characterization, (5) controlled releaseand biological applications, (6) nanoparticles synthesis and assembly, (7) nanocomposites, and(8) new concepts.

Christophe BarbeRichard M. LaineClement SanchezUlrich Schubert

March 2008







MATERIALS RESEARCH SOCIETY SYMPOSIUM PROCEEDINGS

Volume 989— Amorphous and Polycrystalline Thin-Film Silicon Science and Technology—2007, V. Chu,S. Miyazaki, A. Nathan, J. Yang, H.W. Zan, 2007, ISBN 978-1-55899-949-7

Volume 990— Materials, Processes, Integration and Reliability in Advanced Interconnects for Micro- andNanoelectronics, Q. Lin, E.T. Ryan, W-L. Wu, D.Y. Yoon, 2007, ISBN 978-1-55899-950-3

Volume 991— Advances and Challenges in Chemical Mechanical Planarization, C. Borst, L. Economikos,A. Philipossian, G. Zwicker, 2007, ISBN 978-1-55899-951-0

Volume 992E—Deposition onNonplanar Substrates, D. Josell, M. Brett, C. Witt, M. Ritala, 2007,ISBN 978-1-55899-952-7

Volume 993E— Pb-Free and RoHS-Compliant Materials and Processes for Microelectronics, E. Chason, 2007,ISBN 978-1-55899-953-4

Volume 994— Semiconductor Defect Engineering—Materials, Synthetic Structures and Devices II, S. Ashok,P. Kiesel, J. Chevallier, T. Ogino, 2007, ISBN 978-1-55899-954-1

Volume 995E—Extending Moore's Law with Advanced Channel Materials, S. Chakravarthi, R. Arghavani,G. Klimeck, 2007, ISBN 978-1-55899-955-8

Volume 996E— Characterization of Oxide/Semiconductor Interfaces for CMOS Technologies, Y. Chabal,A. Esteve, N. Richard, G. Wilk, 2007, ISBN 978-1-55899-956-5

Volume 997— Materials and Processes for Nonvolatile Memories II, T. Li, Y. Fujisaki, J. Slaughter,D. Tsoukalas, 2007, ISBN 978-1-55899-957-2

Volume 998E —Nanoscale Magnetics and Device Applications, S.S. Xue, 2007, ISBN 978-1-55899-958-9Volume 999E —Novel Semiconductor Materials for Room-Temperature Ferromagnetism, C.R. Abernathy,

S. Bedair, P. Ruterana, R. Frazier, 2007, ISBN 978-1-55899-959-6Volume 1000E—Functional Interfaces in Oxides, 2007, ISBN 978-1-55899-960-2Volume 100IE—Progress in High-Temperature Superconductors, P. Barnes, D. Lee, C. Park, N. Amemiya,

J. Reeves, 2007, ISBN 978-1-55899-961-9Volume 1002E—Printing Methods for Electronics, Photonics, and Biomaterials, G. Gigli, 2007,

ISBN 978-1-55899-962-6Volume 1003E—Organic Thin-Film Electronics—Materials, Processes, and Applications, A.C. Arias,

J.D. MacKenzie, A. Salleo, N. Tessler, 2007, ISBN 978-1-55899-963-3Volume 1004E—Materials and Strategies for Lab-on-a-Chip—Biological Analysis, Microfactories, and Fluidic

Assembly of Nanostructures, S. Grego, J.M. Ramsey, O. Velev, S. Verpoorte, 2007,ISBN 978-1-55899-964-0

Volume 1005E—Advances in Photo-Initiated Polymer Processes and Materials, A. Guymon, C. Hoyle,M. Shirai, E. Nelson, 2007, ISBN 978-1-55899-965-7

Volume 1006E—Transport Behavior in Heterogeneous Polymeric Materials and Composites, J. Grunlan,D. Bhattacharyya, E. Marand, O. Regev, A. Balazs, 2007, ISBN 978-1-55899-966-4







MATERIALS RESEARCH SOCIETY SYMPOSIUM PROCEEDINGS

Volume 1007— Synthesis, Processing, and Properties of Organic/Inorganic Hybrid Materials, R.M. Laine,C. Sanchez, C. Barbe, U. Schubert, 2007, ISBN 978-1-55899-967-1

Volume 1008E—The Nature of Design—Utilizing Biology's Portfolio, R.R. Naik, C.C. Perry, K. Shiba,R. Ulijn, 2007, ISBN 978-1-55899-968-8

Volume 1009E—Advanced Materials for Neuroprosthetic Interfaces, D.R. Kipke, S.P. Lacour, B. Morrison III,D. Tyler, 2007, ISBN 978-1-55899-969-5

Volume 1010E—Functional Materials for Chemical and Biochemical Sensors, E. Comini, P-I. Gouma, V. Guidi,X-D. Zhang, 2007, ISBN 978-1-55899-970-1

Volume 101 IE—Materials for Architecture, D.S. Ginley, K.E. Uhrich, B.J. Faircloth, J-J. Kim, 2007,ISBN 978-1-55899-971-8

Volume 1012— Thin-Film Compound Semiconductor Photovoltaics—2007, T. Gessert, K. Durose, S. Marsillac,T. Wada, C. Heske, 2007, ISBN 978-1-55899-972-5

Volume 1013E—Organic and Nanoparticle Hybrid Photovoltaic Devices, 2007, ISBN 978-1-55899-973-2Volume 1014E—Three-Dimensional Nano- and Microphotonics, P.V. Braun, S. Fan, A.J. Turberfield, S-Y. Lin,

2007, ISBN 978-1-55899-974-9Volume 1015E—Hybrid Functional Materials for Optical Application, A. Cartwright, T.M. Cooper, A. Koehler,

K.S. Schanze, 2007, ISBN 978-1-55899-975-6Volume 1016E—Materials and Material Structures Enabling Terahertz Technology, E. Stutz, I. Wilke,

K. Kreischer, Q. Hu, 2007, ISBN 978-1-55899-976-3Volume 1017E—Low-Dimensional Materials—Synthesis, Assembly, Property Scaling, and Modeling,

M. Shim, M. Kuno, X-M. Lin, R. Pachter, S. Kumar, 2007, ISBN 978-1-55899-977-0Volume 1018E—Applications of Nanotubes and Nanowires, L. Chen, M. Hersam, 2007,

ISBN 978-1-55899-978-7Volume 1019E—Engineered Nanoscale Materials for the Diagnosis and Treatment of Disease, V.A. Hackley,

A.K. Patri, J. Stein, B.M. Moudgil, 2007, ISBN 978-1-55899-979-4Volume 1020— Ion-Beam-Based Nanofabrication, D. ILA, J. Baglin, N. Kishimoto, P.K. Chu, 2007,

ISBN 978-1-55899-980-0Volume 102IE—Surface and Interfacial Nanomechanics, R.F. Cook, W. Ducker, I. Szlufarska, R.F. Antrim,

2007, ISBN 978-1-55899-981-7Volume 1022E—Nanoscale Heat Transport—From Fundamentals to Devices, S.R. Phillpot, S. Volz,

T. Borca-Tasciuc, M. Choi, 2007, ISBN 978-1-55899-982-4Volume 1023E—Functional Nanoscale Ceramics for Energy Systems, E. Ivers-Tiffee, S. Barnett, 2007,

ISBN 978-1-55899-983-1

Prior Materials Research Society Symposium Proceedings available by contacting Materials Research Society







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