플라즈마 표면처리가 poly(ethylene terephthalate) 필름의 effects of...

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61 플라즈마 표면처리가 Poly(ethylene terephthalate) 필름의 전기적 및 기계적 성질에 미치는 영향 임경범 이덕출 인하대학교 공과대학 전기공학과 (2001. 6. 8. 접수 / 2001. 9. 1. 선택) Effects of Plasma Surface Treatment on Electrical and Mechanical Properties of Poly(ethylene terephthalate) Films Kyung-Bum Lim Duck-Chool Lee Department of Electrical Engineering, Inha University (Received June 8, 2001 / Accepted September 1, 2001) Abstract : In this study, the electrical and mechanical characteristics of PET films were analyzed after plasma surface treatment. After plasma treatment, the surface potential decay, surface resistivity, and dielectric property were evaluated to analyze the electrical insulating property, and the tensile strength was measured as the mechanical characteristic. When plasma treatment was conducted for less than 10 minutes, it was found that the electrical insulating property was improved through evaporation of low molecular weight materials and cleaning of surface. However, for more than 10 minutes, the insulating property of plasma treated PET films was decreased due to excessive discharge energy. The tensile strength was hardly changed by plasma treatment. Key Words : PET films, plasma treatment, electrical insulating property, mechanical characteristic 1. 서 론 1) 최근 고분자 화학의 급속한 발전에 따라 우수한 특성을 가진 다양한 절연재료가 지속적으로 개발되 어 왔으며, 산업의 고도화로 인한 전력수요의 증가 로 인하여 이러한 유기고분자 재료의 용도와 수요 가 매년 급증하고 있다. 이들 고분자 재료 중 poly (ethylene terephthalate)(PET) 필름은 절연성, 물리적, 화학적인 우수성과 기계적 특성을 지님으로써 자기 테이프, 사진필름, 전기․전자용, 기어휠 등 구조용 에 이르기까지 다양하게 사용되고 있으며, 전기․전 자용으로는 콘덴서, 모터절연, 전선절연, PCB 회로 기판 등에 많이 사용되고 있다. 13) 그러나 이러한 고분자재료는 실제 환경에서 사용하는 경우 사용환 경 조건에 따라 다양한 열화요인, 즉 태양의 복사열, To whom correspondence should be addressed. [email protected] 자외선, 수분, 온도의 극한적 변화, 염분, 방전 등에 노출되어 물리․화학적 변형을 유발시켜 안정적으 로 요구되는 제반 특성에 심각한 문제를 일으켜 성 능저하를 초래하게 된다. 하지만, 개개의 고분자 절 연물마다 실제 환경에서의 열화과정이 모두 다르게 나타나고 있고, 사용환경에 따른 열화기구는 아직 규명된 자료가 극히 미흡한 실정이다. 또한 고분자 표면에 관한 연구도 오래 전부터 여 러 분야에서 다양한 형태로 이루어져 왔으나 고분 자 표면은 내부와는 다른 결합형태 및 이종매체와 의 상호작용으로 인하여 표면에너지에 따른 안정화 도 및 화학구조 뿐만 아니라, 표면과 접하는 매체를 고려한 전반적 특성이 내부의 성질과는 전혀 다르 게 취급된다. 4,5) 이로 인하여 표면이 어떠한 환경에 노출되는가가 오히려 어떠한 내부적 성질을 갖는가 보다 훨씬 중요하게 고려되고, 한정적으로 표면을 3의 영역으로 설정한 다양한 연구 및 응용이 이 루어지고 있다. 6,7) 특히, 고분자 절연재료의 표면분

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  • 61

    Poly(ethylene terephthalate)

    (2001. 6. 8. / 2001. 9. 1. )

    Effects of Plasma Surface Treatment on Electrical and Mechanical Properties of Poly(ethylene terephthalate) Films

    Kyung-Bum LimDuck-Chool LeeDepartment of Electrical Engineering, Inha University

    (Received June 8, 2001 / Accepted September 1, 2001)

    Abstract : In this study, the electrical and mechanical characteristics of PET films were analyzed after plasma surfacetreatment. After plasma treatment, the surface potential decay, surface resistivity, and dielectric property were evaluatedto analyze the electrical insulating property, and the tensile strength was measured as the mechanical characteristic. When plasma treatment was conducted for less than 10 minutes, it was found that the electrical insulating property was improved through evaporation of low molecular weight materials and cleaning of surface. However, for more than 10minutes, the insulating property of plasma treated PET films was decreased due to excessive discharge energy. The tensile strength was hardly changed by plasma treatment.Key Words : PET films, plasma treatment, electrical insulating property, mechanical characteristic

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  • Poly(ethylene terephthalate)

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    Journal of the KIIS, Vol. 16, No. 3, 200164

    Fig. 1. Schematic diagram of corona discharge apparatus

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  • Poly(ethylene terephthalate)

    , 16 3, 2001 65

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    Journal of the KIIS, Vol. 16, No. 3, 200166

    Fig. 6. Relative dielectric constant versus frequency of plasma treated PET films

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