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    Reference Tables for Physical Setting/Chemistry 2011 Edition 1

    THE UNIVERSITY OF THE STATE OF NEW YORK THE STATE EDUCATION DEPARTMENT ALBANY, NY 12234

    Reference Tables for Physical Setting/CHEMISTRY2011 Edition

    Table AStandard Temperature and Pressure

    Table BPhysical Constants for Water

    Table CSelected Prefixes

    Table DSelected Units

    Name Value UnitStandard Pressure 101.3 kPa kilopascal

    1 atm atmosphere

    Standard Temperature 273 K kelvin0C degree Celsius

    Heat of Fusion 334 J/g

    Heat of Vaporization 2260 J/g

    Specific Heat Capacity of H2O() 4.18 J/gK

    Factor Prefix Symbol

    103 kilo- k

    101 deci- d

    102 centi- c

    103 milli- m

    106 micro-

    109 nano- n

    1012 pico- p

    Symbol Name Quantity m meter length

    g gram mass

    Pa pascal pressure

    K kelvin temperature

    mol mole amount ofsubstance

    J joule energy, work,quantity of heat

    s second time

    min minute time

    h hour time

    d day time

    y year time

    L liter volume

    ppm parts per million concentration

    M molarity solutionconcentration

    u atomic mass unit atomic mass

    C

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    Ions That FormSoluble Compounds Exceptions

    Group 1 ions(Li+, Na+, etc.)

    ammonium (NH4+)

    nitrate (NO3)

    acetate (C2H3O2 or

    CH3COO)

    hydrogen carbonate(HCO3)

    chlorate (ClO3)

    halides (Cl, Br, I) when combined withAg+, Pb2+, or Hg2

    2+

    sulfates (SO42) when combined with Ag+,

    Ca2+, Sr2+, Ba2+, or Pb2+

    Ions That FormInsoluble Compounds* Exceptions

    carbonate (CO32) when combined with Group 1

    ions or ammonium (NH4+)

    chromate (CrO42) when combined with Group 1

    ions, Ca2+, Mg2+, orammonium (NH4

    +)

    phosphate (PO43) when combined with Group 1

    ions or ammonium (NH4+)

    sulfide (S2

    ) when combined with Group 1ions or ammonium (NH4+)

    hydroxide (OH) when combined with Group 1ions, Ca2+, Ba2+, Sr2+, orammonium (NH4

    +)

    *compounds having very low solubility in H2O

    Formula Name Formula Name

    Reference Tables for Physical Setting/Chemistry 2011 Edition 2

    Table FSolubility Guidelines for Aqueous Solutions

    Table ESelected Polyatomic Ions

    H3O+ hydronium

    Hg22+ mercury(I)

    NH4+ ammonium

    C2H3O2

    acetateCH3COO

    }CN cyanide

    CO32 carbonate

    HCO3 hydrogen

    carbonate

    C2O42 oxalate

    ClO

    hypochloriteClO2

    chlorite

    ClO3 chlorate

    ClO4 perchlorate

    CrO42 chromate

    Cr2O72 dichromate

    MnO4 permanganate

    NO2 nitrite

    NO3 nitrate

    O22 peroxide

    OH hydroxide

    PO43 phosphate

    SCN thiocyanate

    SO32

    sulfiteSO4

    2 sulfate

    HSO4 hydrogen sulfate

    S2O32 thiosulfate

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    Reference Tables for Physical Setting/Chemistry 2011 Edition 3

    0 10. 20. 30. 40. 50. 60. 70. 80. 90. 100.

    Temperature(C)

    Solubility(gsolute/100.gH2

    O)

    150.

    140.

    130.

    120.

    110.

    100.

    90.

    80.

    70.

    60.

    50.

    40.

    30.

    20.

    10.

    0

    KI NaNO3

    KNO3

    NH4Cl

    HCl

    KCl

    NaCl

    KClO3

    NH3

    SO2

    Table GSolubility Curves at Standard Pressure

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    Reference Tables for Physical Setting/Chemistry 2011 Edition 4

    Table HVapor Pressure of Four Liquids

    0 25 50. 75 100. 125

    200.

    150.

    100.

    50.

    0

    Vapo

    rPressure(kPa)

    101.3 kPa

    propanone

    ethanol

    water

    ethanoicacid

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    Li

    Rb

    KCs

    Ba

    Sr

    Ca

    Na

    Mg

    Al

    Ti

    Mn

    Zn

    Cr

    Fe

    Co

    Ni

    Sn

    Pb

    H2

    Cu

    Ag

    Au

    F2

    Cl2

    Br2I2

    Reference Tables for Physical Setting/Chemistry 2011 Edition 5

    Table IHeats of Reaction at 101.3 kPa and 298 K

    Table JActivity Series**

    Reaction H (kJ)*

    CH4(g) + 2O2(g) CO2(g) + 2H2O() 890.4

    C3H8(g) + 5O2(g) 3CO2(g) + 4H2O() 2219.2

    2C8H18(

    ) + 25O2(g) 16CO2(g) + 18H2O() 10943

    2CH3OH() + 3O2(g) 2CO2(g) + 4H2O() 1452

    C2H5OH() + 3O2(g) 2CO2(g) + 3H2O() 1367

    C6H12O6(s) + 6O2(g) 6CO2(g) + 6H2O() 2804

    2CO(g) + O2(g) 2CO2(g) 566.0

    C(s) + O2(g) CO2(g) 393.5

    4Al(s) + 3O2(g) 2Al2O3(s) 3351

    N2(g) + O2(g) 2NO(g) +182.6

    N2(g) + 2O2(g) 2NO2(g) +66.4

    2H2(g) + O2(g) 2H2O(g) 483.6

    2H2(g) + O2(g) 2H2O() 571.6

    N2(g) + 3H2(g) 2NH3(g) 91.8

    2C(s) + 3H2(g) C2H6(g) 84.0

    2C(s) + 2H2(g) C2H4(g) +52.4

    2C(s) + H2(g) C2H2(g) +227.4

    H2

    (g) + I2

    (g) 2HI(g) +53.0

    KNO3(s)H2O K+(aq) + NO3

    (aq) +34.89

    NaOH(s)H2O Na+(aq) + OH(aq) 44.51

    NH4Cl(s)H2O NH4

    +(aq) + Cl(aq) +14.78

    NH4NO3(s)H2O NH4

    +(aq) + NO3(aq) +25.69

    NaCl(s)H2O Na+(aq) + Cl(aq) +3.88

    LiBr(s)H2O Li+(aq) + Br(aq) 48.83

    H+(aq) + OH(aq) H2O() 55.8

    *The Hvalues are based on molar quantities represented in the equations.A minus sign indicates an exothermic reaction.

    Metals Nonmetals MostActive

    MostActive

    LeastActive

    LeastActive

    **Activity Series is based on the hydrogenstandard. H

    2

    isnot a metal.

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    Reference Tables for Physical Setting/Chemistry 2011 Edition 6

    Table KCommon Acids

    Table LCommon Bases

    Table NSelected Radioisotopes

    Table MCommon AcidBase Indicators

    Formula Name

    HCl(aq) hydrochloric acid

    HNO2(aq) nitrous acid

    HNO3(aq) nitric acidH2SO3(aq) sulfurous acid

    H2SO4(aq) sulfuric acid

    H3PO4(aq) phosphoric acid

    H2CO3(aq)or carbonic acid

    CO2(aq)

    CH3COOH(aq) ethanoic acidor

    HC2H3O2(aq)

    (acetic acid)

    Formula Name

    NaOH(aq) sodium hydroxide

    KOH(aq) potassium hydroxide

    Ca(OH)2(aq) calcium hydroxide

    NH3(aq) aqueous ammonia

    ApproximateIndicator pH Range Color

    for Color ChangeChange

    methyl orange 3.14.4 red to yellow bromthymol blue 6.07.6 yellow to blue

    phenolphthalein 89 colorless to pink

    litmus 4.58.3 red to blue

    bromcresol green 3.85.4 yellow to blue

    thymol blue 8.09.6 yellow to blue

    Nuclide Half-Life Decay NuclideMode Name

    198Au 2.695 d gold-198

    14C 5715 y carbon-14

    37Ca 182 ms + calcium-37

    60Co 5.271 y cobalt-60

    137Cs 30.2 y cesium-137

    53Fe 8.51 min + iron-53

    220Fr 27.4 s francium-220

    3H 12.31 y hydrogen-3

    131I 8.021 d iodine-131

    37

    K 1.23 s +

    potassium-3742K 12.36 h potassium-42

    85Kr 10.73 y krypton-85

    16N 7.13 s nitrogen-16

    19Ne 17.22 s + neon-19

    32P 14.28 d phosphorus-32

    239Pu 2.410 104y plutonium-239

    226Ra 1599 y radium-226

    222Rn 3.823 d radon-22290Sr 29.1 y strontium-90

    99Tc 2.13 105y technetium-99

    232Th 1.40 1010y thorium-232

    233U 1.592 105y uranium-233

    235U 7.04 108y uranium-235

    238U 4.47 109y uranium-238

    Source: CRC Handbook of Chemistry and Physics,91st ed., 20102011,

    CRC Press

    Source: The Merck Index, 14th ed., 2006, Merck Publishing Group

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    Name General Examples

    Formula Name Structural Formula

    alkanes CnH2n+2 ethane

    alkenes CnH2n ethene

    alkynes CnH2n2 ethyne

    Reference Tables for Physical Setting/Chemistry 2011 Edition 7

    Table OSymbols Used in Nuclear Chemistry

    Table POrganic Prefixes

    Table QHomologous Series of Hydrocarbons

    Name Notation Symbol

    alpha particle 42He or42

    beta particle 01e or0

    1

    gamma radiation 00

    neutron 10n n

    proton 11H or11p p

    positron 0+1e or0

    +1 +

    Prefix Number ofCarbon Atoms

    meth- 1

    eth- 2

    prop- 3

    but- 4

    pent- 5

    hex- 6

    hept- 7

    oct- 8

    non- 9

    dec- 10

    H

    H H

    H

    H H

    C C

    C C HH

    H

    C C

    HH

    H

    Note:n = number of carbon atoms

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    Reference Tables for Physical Setting/Chemistry 2011 Edition 8

    O

    R C H

    OR C O R

    O

    CH3CCH2CH2CH32-pentanone

    O

    R C R

    O

    C H

    Table ROrganic Functional Groups

    Class ofCompound

    FunctionalGroup

    GeneralFormula Example

    halide

    (halocarbon)

    alcohol

    ether

    aldehyde

    F (fluoro-)Cl (chloro-)

    Br (bromo-)I (iodo-)

    OH

    R X(Xrepresents

    any halogen)

    R OH

    R O R

    CH3CHClCH32-chloropropane

    CH3CH2CH2OH

    1-propanol

    CH3OCH2CH3methyl ethyl ether

    amide

    O

    O

    C OH

    OC O

    O

    C NH

    N

    O

    C

    O

    CH3CH2C H

    propanal

    O R

    R C NH

    R

    R N R

    O

    R C OH

    ketone

    organic acid

    ester

    amine

    O

    CH3CH2C OH

    propanoic acid

    O

    CH3CH2COCH3methyl propanoate

    CH3CH2CH2NH21-propanamine

    O

    CH3CH2C NH2

    propanamideNote:R represents a bonded atom or group of atoms.

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    Reference Tables for Physical Setting/Chemistry 2011 Edition 10

    TableS

    PropertiesofSelectedElemen

    ts

    First

    Atomic

    Symbol

    Name

    Ioniza

    tion

    Electro-

    Melting

    Boiling*

    Density**

    Ato

    mic

    Number

    Energy

    negativity

    Point

    Point

    (g/cm3)

    Radius

    (kJ/m

    ol)

    (K)

    (K)

    (pm)

    1

    H

    hydrogen

    131

    2

    2.2

    14

    20.

    0.000082

    3

    2

    2

    He

    helium

    237

    2

    4

    0.000164

    3

    7

    3

    Li

    lithium

    52

    0.

    1.0

    454

    1615

    0.534

    13

    0.

    4

    Be

    beryllium

    90

    0.

    1.6

    1560.

    2744

    1.85

    9

    9

    5

    B

    boron

    80

    1

    2.0

    2348

    4273

    2.34

    8

    4

    6

    C

    carbon

    108

    6

    2.6

    .

    7

    5

    7

    N

    nitrogen

    140

    2

    3.0

    63

    77

    0.001145

    7

    1

    8

    O

    oxygen

    131

    4

    3.4

    54

    90.

    0.001308

    6

    4

    9

    F

    fluorine

    168

    1

    4.0

    53

    85

    0.001553

    6

    0.

    10

    Ne

    neon

    208

    1

    24

    27

    0.000825

    6

    2

    11

    Na

    sodium

    49

    6

    0.9

    371

    1156

    0.97

    16

    0.

    12

    Mg

    magnesium

    73

    8

    1.3

    923

    1363

    1.74

    14

    0.

    13

    Al

    aluminum

    57

    8

    1.6

    933

    2792

    2.70

    12

    4

    14

    Si

    silicon

    78

    7

    1.9

    1687

    3538

    2.3296

    11

    4

    15

    P

    phosphorus(white)101

    2

    2.2

    317

    554

    1.823

    10

    9

    16

    S

    sulfur(monoclinic)100

    0.

    2.6

    388

    718

    2.00

    10

    4

    17

    Cl

    chlorine

    125

    1

    3.2

    172

    239

    0.002898

    10

    0.

    18

    Ar

    argon

    152

    1

    84

    87

    0.001633

    10

    1

    19

    K

    potassium

    41

    9

    0.8

    337

    1032

    0.89

    20

    0.

    20

    Ca

    calcium

    59

    0.

    1.0

    1115

    1757

    1.54

    17

    4

    21

    Sc

    scandium

    63

    3

    1.4

    1814

    3109

    2.99

    15

    9

    22

    Ti

    titanium

    65

    9

    1.5

    1941

    3560.

    4.506

    14

    8

    23

    V

    vanadium

    65

    1

    1.6

    2183

    3680.

    6.0

    14

    4

    24

    Cr

    chromium

    65

    3

    1.7

    2180.

    2944

    7.15

    13

    0.

    25

    Mn

    manganese

    71

    7

    1.6

    1519

    2334

    7.3

    12

    9

    26

    Fe

    iron

    76

    2

    1.8

    1811

    3134

    7.87

    12

    4

    27

    Co

    cobalt

    76

    0.

    1.9

    1768

    3200.

    8.86

    11

    8

    28

    Ni

    nickel

    73

    7

    1.9

    1728

    3186

    8.90

    11

    7

    29

    Cu

    copper

    74

    5

    1.9

    1358

    2835

    8.96

    12

    2

    30

    Zn

    zinc

    90

    6

    1.7

    693

    1180.

    7.134

    12

    0.

    31

    Ga

    gallium

    57

    9

    1.8

    303

    2477

    5.91

    12

    3

    32

    Ge

    germanium

    76

    2

    2.0

    1211

    3106

    5.3234

    12

    0.

    33

    As

    arsenic(gray)

    94

    4

    2.2

    1090.

    5.75

    12

    0.

    34

    Se

    selenium(gray)

    94

    1

    2.6

    494

    958

    4.809

    11

    8

    35

    Br

    bromine

    114

    0.

    3.0

    266

    332

    3.1028

    11

    7

    36

    Kr

    krypton

    135

    1

    116

    120.

    0.003425

    11

    6

    37

    Rb

    rubidium

    40

    3

    0.8

    312

    961

    1.53

    21

    5

    38

    Sr

    strontium

    54

    9

    1.0

    1050.

    1655

    2.64

    19

    0.

    39

    Y

    yttrium

    60

    0.

    1.2

    1795

    3618

    4.47

    17

    6

    4 0

    Z

    i

    i

    6 4

    0

    1 3

    2 1 2 8

    4 6 8 2

    6 5 2

    1 6

    4

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    Reference Tables for Physical Setting/Chemistry 2011 Edition 11

    First

    Atomic

    Symbol

    Name

    Ioniza

    tion

    Electro-

    Melting

    Boiling*

    Density**

    Ato

    mic

    Number

    Energy

    negativity

    Point

    Point

    (g/cm

    3)

    Radius

    (kJ/m

    ol)

    (K)

    (K)

    (pm)

    41

    Nb

    niobium

    65

    2

    1.6

    2750.

    5017

    8.57

    15

    6

    42

    Mo

    molybdenum

    68

    4

    2.2

    2896

    4912

    10.2

    14

    6

    43

    Tc

    technetium

    70

    2

    2.1

    2430.

    4538

    11

    13

    8

    44

    Ru

    ruthenium

    71

    0.

    2.2

    2606

    4423

    12.1

    13

    6

    45

    Rh

    rhodium

    72

    0.

    2.3

    2237

    3968

    12.4

    13

    4

    46

    Pd

    palladium

    80

    4

    2.2

    1828

    3236

    12.0

    13

    0.

    47

    Ag

    silver

    73

    1

    1.9

    1235

    2435

    10.5

    13

    6

    48

    Cd

    cadmium

    86

    8

    1.7

    594

    1040.

    8.69

    14

    0.

    49

    In

    indium

    55

    8

    1.8

    430.

    2345

    7.31

    14

    2

    50

    Sn

    tin(white)

    70

    9

    2.0

    505

    2875

    7.287

    14

    0.

    51

    Sb

    antimony(gray)

    83

    1

    2.1

    904

    1860.

    6.68

    14

    0.

    52

    Te

    tellurium

    86

    9

    2.1

    723

    1261

    6.232

    13

    7

    53

    I

    iodine

    100

    8

    2.7

    387

    457

    4.933

    13

    6

    54

    Xe

    xenon

    117

    0.

    2.6

    161

    165

    0.005366

    13

    6

    55

    Cs

    cesium

    37

    6

    0.8

    302

    944

    1.873

    23

    8

    56

    Ba

    barium

    50

    3

    0.9

    1000.

    2170.

    3.62

    20

    6

    57

    La

    lanthanum

    53

    8

    1.1

    1193

    3737

    6.15

    19

    4

    Elements5871havebeenomitted.

    72

    Hf

    hafnium

    65

    9

    1.3

    2506

    4876

    13.3

    16

    4

    73

    Ta

    tantalum

    72

    8

    1.5

    3290.

    5731

    16.4

    15

    8

    74

    W

    tungsten

    75

    9

    1.7

    3695

    5828

    19.3

    15

    0.

    75

    Re

    rhenium

    75

    6

    1.9

    3458

    5869

    20.8

    14

    1

    76

    Os

    osmium

    81

    4

    2.2

    3306

    5285

    22.587

    13

    6

    77

    Ir

    iridium

    86

    5

    2.2

    2719

    4701

    22.562

    13

    2

    78

    Pt

    platinum

    86

    4

    2.2

    2041

    4098

    21.5

    13

    0.

    79

    Au

    gold

    89

    0.

    2.4

    1337

    3129

    19.3

    13

    0.

    80

    Hg

    mercury

    100

    7

    1.9

    234

    630.

    13.5336

    13

    2

    81

    Tl

    thallium

    58

    9

    1.8

    577

    1746

    11.8

    14

    4

    82

    Pb

    lead

    71

    6

    1.8

    600.

    2022

    11.3

    14

    5

    83

    Bi

    bismuth

    70

    3

    1.9

    544

    1837

    9.79

    15

    0.

    84

    Po

    polonium

    81

    2

    2.0

    527

    1235

    9.20

    14

    2

    85

    At

    astatine

    2.2

    575

    14

    8

    86

    Rn

    radon

    103

    7

    202

    211

    0.009074

    14

    6

    87

    Fr

    francium

    39

    3

    0.7

    300.

    24

    2

    88

    Ra

    radium

    50

    9

    0.9

    969

    5

    21

    1

    89

    Ac

    actinium

    49

    9

    1.1

    1323

    3471

    10.

    20

    1

    Elements

    90andabovehavebeenomitte

    d.

    *

    boilingpointatstandardpressure

    **

    densityofsolidsandliquidsatroomtemperatur

    eanddensityofgasesat298Kand1

    01.3kPa

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    R f T bl f Ph i l S tti /Ch i t 2011 Editi 12

    Table TImportant Formulas and Equations

    DET 609 ADU

    d = densityDensity d = m = mass

    V= volume

    Mole Calculations number of moles =

    Percent Error % error = 100

    Percent Composition % composition by mass = 100

    parts per million = 1000000

    Concentration

    molarity =

    P = pressureCombined Gas Law = V= volume

    T= temperature

    MA = molarity of H+ MB = molarity of OH

    Titration MAVA= MBVB VA = volume of acid VB = volume of base

    q =mCT q = heat Hf = heat of fusion

    Heat q =mHf m = mass Hv = heat of vaporization

    q =mHv C = specific heat capacity

    T = change in temperature

    Temperature K = C + 273 K = kelvin

    C = degree Celsius

    P2V2T2

    P1V1T1

    moles of solute

    liter of solution

    mass of solutemass of solution

    mass of part

    mass of whole

    measured value accepted value

    accepted value

    given massgram-formula mass

    mV