nox control for stationary gas engines - marama end applications in power plants, waste...
TRANSCRIPT
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NOx Control for Stationary Gas Engines
Advances in Air Pollution Control TechnologyMARAMA Workshop
May 19, 2011
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Outline
• Types of Gas Engines• 3-Way NSCR• SCR• Field Experience
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Types of Gas Engines
• Rich Burn - Excess amount of fuel to air(exhaust contains < 1% O2)
• Lean Burn - Excess amount of air to fuel(exhaust contains > 4% O2)
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NOx Control Technologiesfor Gas Engines
4SRB:• 3-Way (NSCR)
2SLB and 4SLB:• SCR (Selective Catalytic Reduction) – Urea
and Ethanol
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NSCR Systems
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0102030405060708090
100
14.5 15.0 15.5 16.0 16.5 17.0 17.5
NOxCOTHC
Rich Stoich LeanA/F Ratio (Mass)
% Conversion
NSCR Performance Curve
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3-Way NSCR Catalytic Convertersfor Stationary Gas Engines
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Stationary Engine Gas Compression
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3–Way NSCR Performance and Cost
Typical Rich Burn Engine for Gas Compression• Engine Type & Model: Waukesha P9390 • Engine HP: 1980• Expected NOx reduction: 98%+• Target NOx 0.15 g/bhp-hr • Expected CO reduction (HAP’s) 76%+
• Offered in both silenced and non silenced versions to meet state regulations and NESHAPS
• Silenced versions pricing = approx $18.00 per Hp. • Non-silenced version pricing = approx. $ 15.00 per Hp.
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SCR Systems
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Typical V-SCR NOx Activity
lower
V2O5 Content
150 200 250 300 350 400 450 500 550
high
medium
kNO
x
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V-SCR Operating Temperatures
200°C 350°COperating Temperature
400°F 1000°F600°F 800°F
Typical High Dust Applicationsin Power Plants
Simple Cycle Gas Turbines
Combined Cycle Power Plants
IC Engines
SINOx® Low TemperatureCatalyst
SINOx® High TemperatureCatalyst
Tail End Applications inPower Plants, Waste Incinerations
Standard SINOx®
or Coated Catalyst
550°C
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Ethanol SCR NOx Performance
E85 Reductant, Inlet NOx=500ppm, C1:NOx=5
0
20
40
60
80
100
100 200 300 400 500
Temperature (Celsius)
NO
x C
onve
rsio
n (%
)
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Coated Metal Honeycomb Catalyst
CONFI DENTI AL
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Extruded SCR Catalyst
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IC Engine SCR System
SCR Catalyst CO Oxidation Catalyst
(optional) Catalyst Housings Mixing Duct Injection Lance Urea Injection Control
System Air Purge On-site Training/Start-up
Service (O&M Manual)
OxidationCatalyst
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SCR Catalyst Housing for IC Engines
Stainless steel construction
Access door for inspection/ maintenance
Designed for even flow distribution
Ports available for monitoring ∆P and T
Extra space available for additional catalyst
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Urea Injection Control Panel
Electronics located in the top of the panel
Instrumentation in the bottom of the panel
Precise control of urea delivery
Redundant magnetic gear driven pumps
Urea or aqueous ammonia compatible
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Urea Injection System
Control Panel
Injection Schemes
Piping Panel
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SCR System Controls
Electronics located in the top of the panel Touch screen operator interface PC based with Intel processor Feed forward, feed back/closed loop injection control SCADA compatible Data storage capability with Ethernet access External Communication- RS-485, RS-232 I/Os accessed for remote monitoring and data
collection. ModBus communication protocol
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Injection Lance
Pipe in pipe arrangement- urea in center pipe Air utilized for cooling and atomization Urea and air mix in the injection nozzle Layer of insulation around air pipe Small urea droplet size facilitates the SCR reaction
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Budgetary Cost of SCR System
$60,000
$70,000
$80,000
$90,000
$100,000
$110,000
$120,000
$130,000
$140,000
0 500 1000 1500 2000 2500 3000 3500
Power (hp)
SC
R B
udge
tary
Pri
ce
$42/hp
$150/hp
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SCR Installations
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Gas Compressor SCR/CO System Installations
Engine Model
EngineHp
NOxg/bhp-hr
CO*g/bhp-hr
NOx Reduction
CO* Reduction
CAT G3516
1340 1.5 1.88 90% 90%
CAT G3608
2370 0.7 2.5 90% 90%
CAT G3612
3550 0.7 2.5 90% 90%
CAT G3616
4735 0.7 2.5 80% 90%
These engines are installed and operating at Loudon Compressor Station,Clarksburg, WV and Lodi Compression/Storage, Sacramento, CA
*Installed prior to HAPs requirement
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Lodi Gas Compression/StorageKirby Hills, CA
• Engines - CAT G3516• Installed 2006
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Hotel & Casino CHP Plant (SCR/CO)