ncn 1 neophytos neophytou advisory committee chairs: mark lundstrom, gerhard klimeck members:...
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www.nanoHUB.orgwww.nanoHUB.org
Neophytos Neophytou
Advisory Committee Chairs: Mark Lundstrom, Gerhard Klimeck Members: Ashraful Alam, Ahmed Sameh
Network for Computational Nanotechnology Purdue UniversityWest Lafayette, Indiana USA
Quantum and atomistic effects in nano-electronic devices
Ph.D. Thesis Defense, May 22nd, 2008
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Introduction – Device trend
Robert Chau (Intel), 2004Robert Chau (Intel), 2004
Device Challenges:1) Atoms are countable2) Strain3) Material /potential variations on nanoscale4) Crystal orientation5) III-V, Ge, InGaAs
Electronic structure features:1) Strong quantization2) Band coupling3) Non-parabolicities4) Quantum mechanics
Design Challenges1) Low dimensionality2) Parameter fluctuations3) Scalable – last for 2 generations
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Si MOSFET alternatives? CNTs
Issues: Chirality Metallic vs. Semiconducting Alignment
CNT (Delft group-1998)
Top gate+High-k(Javey et. al.) BTBT(IBM) Oscillator (IBM)
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Si MOSFET alternatives? NWs
Singapore group (IEDM 2006)
Samuelson groupEDL 2006
Still based on Si, so might have easier integration Gate all around for better electrostatics
Scattering in 1D – surface roughness? Bandstructure effects?
Samsung (APL 2008)D=8nmL=22nm
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Si MOSFET alternatives? III-Vs
Kim et. al. 200660nm InGaAs
Kim et. al. 200740nm InAs
Freescale IEDM 2007
Intel EDL 2008
High mobility, high speed, close to the ballistic limit, but low DOS (DOS Bottleneck) Lower VD, low dissipation - tunneling/leakage? Large series resistance
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Open questions
How will these devices perform at the scaling limit? What parameters control their performance? Low dimensionality: Sensitivity to defects and fluctuations?
Are they advantageous to the Si MOSFET?
Modeling tools used here: Quantum transport – NEGF (CNT, III-V HEMT) 3D (CNTs) Atomistic bandstructure (NWs)
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Why atomistic is needed –motivation
Valley splitting Band coupling
Valence band anisotropy Warped bands
m* valid m* NOT valid
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Motivation for TB
NN sp3d5s*-SO
The bulk bandstructure(from Anisur Rahman’s thesis)
[100] [110] [111]
Based on Localized Atomic OrbitalsSuitable for: Structure deformations, strain Material variations, heterostructures Surface truncation Potential variations: treated easily
Needs a large set of fitting parameters Computationally expensive
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Outline
1) 1D channel sensitivity to atomistic defects
2) Bandstructure effects in nanowires:
Self consistent model for NWs
Electron transport
Hole transport
3) III-V HEMT devices
4) Conclusions – Future work
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Defects in 1D channels
vacancy
Neophytou APL 2006, APL 2007, JCE 2007
Gate
Gate
Insulator: 4nm HfO2 (k=16)S D
22.5 nmDoping: ND = 109 /m
22.5 nmDoping: ND = 109 /m
25 nmIntrinsic
Gate
Gate
Insulator: 4nm HfO2 (k=16)S D
22.5 nmDoping: ND = 109 /m
22.5 nmDoping: ND = 109 /m
25 nmIntrinsic
1) NEGF2) 3D electrostatics3) Atomistic TB
CNTFET on nanoHUB.org
ID: ~27% reduction
Dangling bonds in NWs
CB
A
CB
A
CB
A
CB
A
CB
A
CB
A
CB
A
CB
A
ID: ~30% reduction
charged impurity
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Outline
1) 1D channel sensitivity to atomistic defects
2) Bandstructure effects in nanowires:
Self consistent model for NWs
Electron transport
Hole transport
3) III-V HEMT devices
4) Conclusions – Future work
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The self-consistent model for NWs
Bandstructure
(states)
+k-k
EF1 - qVDS
Uscf
EF1
E(k)
EC(x)Semiclassical
Ballistic Transport
+k-k
EF1 - qVDS
Uscf
EF1
E(k)
EC(x)Semiclassical
Ballistic Transport
Transport(state filling - charge)
oxide
gate
CHANNEL
oxide
gate
CHANNEL
Poisson
Charge Potential
Simple model but provides physical insight
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Why need a SC model? ~0.5nm
Neophytou SISPAD 2007
Charge Variations
CS
Ec changes
Ev changes
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Numerical issues of the SC model
Hamiltonian size – (dep. on wire size and orientation)3nm x 3nm with SO: 4k x 4k - 9k x 9k12m x 12nm with SO: 55k x 55k
eigenvalue problem150 k-points, 60 eigenvalues
Parallelized per bias point: Vd is constant Vg is varied
Timing (per bias point):3nm device: a few hours 12nm devices: 1 – 2 days
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Outline
1) 1D channel sensitivity to atomistic defects
2) Bandstructure effects in nanowires:
Self consistent model for NWs
Electron transport
Hole transport
3) III-V HEMT devices
4) Conclusions – Future work
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NMOS [100], [110], [111] wire comparison
Cox
CS
VG
ψs
GND
Same capacitance/ charge in all wires [110], [100], then [111] on performance
OX Stot
OX S
C CC
C C
Neophytou TED 2008
CS: - CQ (30%)-potential/charge variations
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Masses change with quantization
C
B’
AA’
C’
B
C
B’
AA’
C’
B
mlmtmtC
mtmlmtB
mtmtmlA
mz *my *mx *
mlmtmtC
mtmlmtB
mtmtmlA
mz *my *mx *
zx
y
NW mass is controlled by
quantization of the 6 ellipsoids
[100], [111] wire masses increase [110] mass decreases
Neophytou TED 2008
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Non-parabolicity and anisotropy in the dispersion
kx
Neophytou TED 2008
[010]
[110]
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Outline
1) 1D channel sensitivity to atomistic defects
2) Bandstructure effects in nanowires:
Self consistent model for NWs
Electron transport
Hole transport
3) III-V HEMT devices
4) Conclusions – Future work
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Ek for holes in 6nm wires
Corner effects – electrostatics Directionality in the charge - bandstructure
High gate bias
Neophytou TED 2008
(100
)(1
-10)
(010)
(11-
2)
(1-10)
(001)
Energy surfaces
[100]
[110]
[111]
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Anisotropy implications on the device performance
Kobayashi et. al.JAP 103, 2008
[110] side variations, do not affect the device – VT, Ion [100] side variations, affect the device
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Outline
1) 1D channel sensitivity to atomistic defects
2) Bandstructure effects in nanowires:
Self consistent model for NWs
Electron transport
Hole transport
3) III-V HEMT devices
4) Conclusions – Future work
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Motivation: del Alamo group HEMTs
Source Drain
InGaAs/InAlAs
InAlAs(11 nm)
InGaAs(MQW)
InAlAsBuffer
InP(6 nm)
tins
Lside
Typical IDS vs. VDS
Reference: Dae-Hyun Kim et al. IEDM 2006
• how close to ballistic limit? • role of mobility• degradation of gm at high VG
Typical Gm vs. VGS
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Approach
Simulation:
• 2D Poisson in the cross section • NEGF in the channel and upper buffer layer (ballistic)• Include Rs to fit low VDS conductance to experiment• Bulk material masses (In0.7Ga0.3As)• Adjust ΦB to achieve the experimental VT
• Parallelization: One VG set per CPU (constant VD) 2 hours per bias point – 20 hours per I-V
δ-dop. n++
Gate
L_side2.1e12/cm2 10e12/cm2
3nm
sou
rce
dra
in
L_side2.1e12/cm210e12/cm2
n+
60nm40nm 60nm
15nmInGaAs
InAlAs
500nmInAlaAs
n+ n++δ-dop. n++
Gate
L_side2.1e12/cm2 10e12/cm2
3nm
sou
rce
dra
in
L_side2.1e12/cm210e12/cm2
n+
60nm40nm 60nm
15nmInGaAs
InAlAs
500nmInAlaAs
n+ n++
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Series resistance and “Ballistic” mobility
2
170 - m( )
~ 170 - 450 cm /V-s
DSCH
DS B ins G T
B
V LR
I W C V V
(Depending on the Tins)
ballistic simulation
measured(Tins = 3 nm, L = 60 nm)
ballistic + Rs = 400 -m
“ballistic mobility:”
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LG = 60 nm vs. Tins
Tins=3nm Tins=11nmTins=7nm
1) Except for high VG, all results can be explained as a ballistic FET with series R
2) Series resistance increases as Tins decreases
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Source limits
2) Barrier collapses
Gm rolls off in the ballistic model too.
1) OFF state
3) Gate loses control
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Charge
CS degrades Cins by 2.5 x
Q=Cins(VG-VT)
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Velocity
1) Non-parabolicity degrades the velocity by ~10%
Velocity is low:
Due to quantum mechanical reflections and tunneling
v ~ 2.7
v~ 4
v~ 3.6
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Outline
1) 1D channel sensitivity to atomistic defects
2) Bandstructure effects in nanowires:
Self consistent model
Electron transport
Hole transport
3) III-V HEMT devices
4) Conclusions – Future work
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Conclusions (1)
1) 1D channel are sensitivity to single atomistic defects:
Vacancy, charged impurities, dangling bonds
2) Transport in nanowires:
Non-parabolicity, anisotropy causes mass variations, charge distribution variations
EMA cannot be used in general
NMOS: [110], [100] perform better, [111] worse
PMOS: [111], [110] perform better, [100] worse
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Conclusions (2)
3) III-V HEMT devices:
Ballistic channel + RSD
Low charge and velocity, low “apparent” mobility
Importance of the source design
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General concluding comments
Low dimensional devices:
Importance of CS, CQ, that degrade COX
But variations in parameters that influence C do not affect the device
Velocity is important
But, low mass tunnels more so the velocity can be reduced
Device is mostly controlled by external parameters rather than the channel (RSD, parasitics)
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Future work
Identifying the ultimate MOSFET: Perform appropriate comparisons between Si MOSFETs and UTB, NW devices at the scaling limit. Power, speed, Ion, Ion/Ioff, leakage, parasitics Device to circuit level Optimal strain and wafer/transport orientation, material, Is it different at each technology node? Which device for which application – identify appropriate use
Modeling for nanoscale devices: Contacts in low dimensional devices: DD + Ballistic NEGF, dephasing mechanisms (equilibrium or not?) Schottky barriers Inexpensive treatment and use of complex bandstructures, and distortions. (zone unfolding). NEGF + TB – real or mode space for PMOS in NWs and UTB
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AcknowledgementsProf. Mark LundstromProf. Gerhard KlimeckProf. Ashraful AlamProf. Ahmed Sameh
Jin Guo, Siyu Koswatta, M.P. Anantram (CNT)Diego Kienle, Eric Polizzi, Shaikh Ahmed (CNTFET)Anisur Rahman, Jing Wang, Mathieu Luisier (Bandstructure)Abhijeet Paul (generalized poisson for SC model)Titash Rakshit (HEMT)
Yang Liu (UTB work)Gengchiau Liang, Dmitri Nikonov (Graphene)
All others in EE350
NCN for the computational resourcesCheryl Haines
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BACKUP
Neophytou APL 2006
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Explanations for the Ek - transport
[100] subbands [110] subbands
Quantization surfaces-Structural
-Electrostatic
Neophytou TED 2008
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Anisotropy implications on the device performance
Neophytou, in preparation
[100]
[1-10]
(i)
(ii)
(iii)
(vii)
(vi)
(v)
(iv)
(110)
(100)
BA
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Figure 1 – The different quantizations of the different surfaces
(110) surface(100) surface
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Figure 2 – Current surface for variation of the dimensions
[100]
[1-10]
(i)
(ii)
(iii)
(vii)
(vi)
(v)
(iv)
(110)
(100)
BA
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Tins / gate length dependence
- Low DOS degrades charge
- At high VG the measured current deviates from the ballistic limit.
- As LG decreases, ID approaches the ballistic limit
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3nm wire dispersions in different orientations
3nm-[100] 3nm-[110] 3nm-[111]
Mass at Γ: 0.27 (0.19) Degeneracy : 4 Excited states shift down
Mass at Γ: 0.16 (0.19) Degeneracy : 2 Valley Splitting
Mass: 0.46 (0.43) Degeneracy: 6
OFF-Γ
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Approach - Bandstructure
In0.7Ga0.3As – undistortedm*=0.048m0 (matches DOS up to 0.2eV) (account for non-parabolicity)L valleys are too high
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Transconductance degradation
1) Cannot be explained by series resistance
2) Possibly scattering at high VG (not loss of confinement or upper valleys
3) Is there a ballistic mechanism that can
explain this?