natural resource technology
TRANSCRIPT
NATURAL
RESOURCE
TECHNOLOGY
Ms. Mary Logan United States Environmental Protection Agency 77 West Jackson Boulevard / SR-6J Chicago, IL 60604-3507
Ms. Kristen DuFresne 2984 Shawano Ave P.O. Box 10448 Green Bay, Wl 54307-0448
September 20, 2005 (1549)
EPA Region 5 Records Ctr.
364525
RE: Groundwater Monitoring Update: 2004 Well Construction, Repair and Abandonment; and November 22,2004 and April 13 <& 14, 2005 (jroundwater Sampling Events Former Manufactured Gas Plant Site, 1603 Ely Street, Marinette, Wisconsin EPA ID# WIN000509952 Wl BRRTS ID # 02-38-000047
Dear Ms. Mary Logan and Ms. Kristen DuFresne:
On behalf of Wisconsin Public Service Corporation (WPSC), Natural Resource Technology, Inc. (NRT) is pleased to provide this update of recent monitoring well construction activities (repair, new construction, abandonment, and replacement) and groundwater monitoring data for wells sampled November 22 and December 2,2004 and April 13 and 14, 2005 at the former Manufactured Gas Plant (MGP) located in Marinette, Wisconsin (Figure 1).
Site monitoring wells were sampled utilizing low-flow techniques in general accordance with ASTM Standard Practice for Low-Flow Purging and Sampling for Wells and Devices Used for Ground-Water Quality Investigations (Publication D 6771-02) and dedicated bailers following WDNR guidelines as specified in Groundwater Sampling Desk Reference (WDNR PUBL-DG-037 96) and Groundwater Sampling Field Manual (WDNR PUBL-DG-038 6). Depth to water was also measured in all site monitoring wells and piezometers. Water table and piezometric surface elevations are summarized on Table 1 and the water table elevations are contoured on Figures 2 and 3. Analytical results are summarized in Tables 2 through 4 and on Figures 4 and 5.
Generally, the data indicate MGP-related constituents have not migrated vertically downward to the bedrock aquifer, constituent concentrations exceeding groundwater quality standards are predominantly present within the former MGP slough, and their extent is defined in the downgradient direction.
WELL CONSTRUCTION, REPAIR, AND ABANDONMENT
The following well construction, repair and abandonment activities were scheduled to be completed in 2004 and 2005, as proposed in NRT's June 21, 2004 letter to Ms. Cathy Rodda, WDNR:
• Construct three shallow monitoring wells and one piezometer, MW-308, MW-309, MW-310 and P-305, to monitor downgradient groundwater quality near Boom Landing Park;
• Repair or replace MW-1 and MW-3;
• Repair or abandon MW-2; and.
23713 W. Paul Rd., Ste. D • Pewaukee, Wl 53072 • Phone: 262.523.9000 • Fax: 262.523.9001 • vwvw.naturairt.com Pewaukee • Madison
Ms. Mary Logan and Ms. Kristen DuFresne USEPA and WDNR September 20, 2005 Page 2
• Abandon MW-301 and P-301 prior to the City of Marinette brick interceptor sewer project to prevent downward migration of contaminants along a preferential pathway created by disturbance to the well nest.
The following well construction, abandonment and repair activities were completed as planned:
Groundvfater Monitoring Well/ Piezometer MW-308, MW-310, P-305 MW-1 MW-301/P-301
Activity, Date Installed and developed June 2004. Redeveloped June 2004. Abandoned January 27, 2004.
Trace tar droplets were observed in water from drill cuttings during installation of P-305 at 27 feet below ground surface (bgs), within shallow fractured bedrock. During drilling and well installation activities, approximately 500 gallons of groundwater with trace emulsified tar and sheen were purged from this bedrock interval. The purge water was treated and disposed with the on-site trench water treatment system utilized during the interceptor sewer construction activities conducted by the City of Marinette. NRT did not observe tar, sheen, or odor in the water during subsequent well development or sampling activities.
Deviations to the proposed well repair, replacement and/or installation activities are detailed below:
Location MW-2
MW-3
MW-4
MW-307
MW-309
MW-311
Activity, Date Removed in
2004 Abandonment
Scheduled, Replaced in
October 2004
Abandoned in April 2005 Abandoned
and replaced in October
2004 Installation Postponed
Installed in October 2004
Deviation Description Well was removed during utility construction activities by the City of Marinette. Well could not be located for abandonment. Well location had been determined by WPSC survey crew and staked. Location was subsequently buried with approximately 20 feet of sand by the City of Marinette. Well is scheduled for abandonment concurrent with future drilling activities. Well was damaged and could not be repaired
City of Marinette construction activities damaged the well.
Well is scheduled to be installed upon completion of the construction activities planned at Boom Landing Park as part of WPSC s sediment remediation project.
Initially intended to replace well MW-2; the location was moved per City of Marinette requests and the location of a new utility corridor installed through the former MW-2 location. The well was too far from MW-2 to be considered a replacement well, and was likely within the former MGP operational slough. Well MW-311 now serves to monitor groundwater quality within the former slough.
Replacement To be
evaluated MW-3R
To be evaluated MW-307R
N/A
N/A
5 j l Primed on paper coiiuiininy 60"-<i recycled fibers and .•?(l'!o post-consumer waste
NATURAL RESOURCE TECHNOLOGY
Ms. Mary Logan and Ms. Kristen DuFresne USEPA and WDNR September 20, 2005 Page 3
Monitoring wells were constructed and developed in accordance with Wisconsin Administrative Code NR 141. WDNR Soil Boring Log Information, Monitoring Well Construction, Monitoring Well Development and Borehole Abandonment forms are included in Appendix A.
New site wells were surveyed on January 22, 2005 (Appendix B). Survey data from wells MW-308, MW-310, MW-311, and P-305 were inconsistent with previous elevation data, which is likely due to errors in the new survey data. Correspondingly, groundwater elevations from those wells were not used in the construction of groundwater elevation contours as discussed in detail below. An additional survey will be conducted for the wells and.water level elevation data will be included in future groundwater flow analysis thereafter.
GROUNDWATER FLOW DIRECTION AND GRADIENTS
Prior to sampling, elevation measurements in water table wells and piezometers were recorded during both the November 2004 and April 2005 sampling rounds (Table 1). Water table elevations for both rounds (Figures 2 and 3) indicate a generally east-northeast flow for shallow groundwater, similar to historic flow direction interpretations. Piezometric surface elevations could not be contoured for either event due to uncharacteristic groundwater elevations. Evaluation of deep groimdwater flow will be addressed in a groundwater quality update to be issued in early 2006 as discussed below.
ANALYTICAL DATA
Groundwater analytical samples were analyzed by Pace Analytical (formerly En Chem, Inc., Green Bay, Wisconsin) for petroleum volatile organic compounds (PVOCs; including benzene, toluene, ethylbenzene, and total xylenes [BTEX]; 1,2,4- and 1,3,5-trimethylbenzenes [TMBs]; and methyl tert-butyl ether [MTBE], Table 2), available cyanide (OIA-1677 Method, Table 2) and polynuclear aromatic hydrocarbons (PAHs, Table 3). Remedial natural attenuation (RNA) parameters analyzed included dissolved iron, dissolved manganese, nitrate and nitrite, sulfate and methane (Table 4). Limited RNA analytical data has been collected from monitoring wells. Therefore, these data are presented for informational purposes and will be evaluated following subsequent sampling events.
Samples collected from MW-4 on November 22, 2004 were inadvertently damaged after collection. However, a quality control field duplicate sample was also collected from MW-4 (labeled QC-2) and submitted for analysis. Additionally, piezometer P-304 did not recover following sampling purge activities on November 22, 2004; therefore, analytical samples were not collected.
The method of cyanide analysis for the site was transitioned to available cyanide analysis by the OIA-1677 Method for the November 2004 sampling event. Cyanide results from this sampling round appeared to be high (11 to 600 \ig/L), in some cases higher than historic total cyanide concentrations (6 to 474 jxg/L), likely due to sulfide interference. Consequently, future samples for available cyanide will be preserved with lead carbonate to modify the likely effects of sulfide. The samples collected for cyanide analysis during the April 2005 sampling event were field preserved with lead carbonate. The resulting cyanide concentrations were lower, with 10 of the 14 samples indicating non-detects and four samples with concentrations ranging from 5.1 to 8.0 |ig/L, well below the NR 140 Preventive Action Limit (PAL) of 40 ^lg/L. These data indicate the
NATURAL
RESOURCE ' j l I'rniieo on paper coniaiiiing ou"'o recycled tmeis anu nr'» post-consumer wa.ste ^^^^HTFrHNioi o r v % j l Primed on paper containing 60% recycled fibeis and 3(K'i> post-consumer wa.ste
Ms. Mary Logan and Ms. Kristen DuFresne USEPA and WDNR September 20, 2005 Page 4
November 2004 cyanide samples likely do not represent actual groundwater quality conditions. Therefore, November 2004 cyanide data will not be used when evaluating groundwater quality trends in this and future reports.
Based on a review of the historic and recent analytical data for PVOCs, cyanide, and PAHs in Tables 2 and 3 and Figures 4 and 5, the site groundwater quality has generally remained stable or fluctuated within probable seasonal variations between August 2003 and April 2005. The apparent decline in PAH concentrations observed in most site wells (except MW-305 and MW-306 as discussed below) is likely due to implementation of low-flow sampling techniques and not likely an indication of groundwater quality trends. A number of the wells have had insufficient water volume for low-flow sampling. Therefore, a complete assessment of the impact of low-flow sampling on the groundwater quality data set cannot be evaluated at this time. PAH concentrations will continue to be monitored and assessed for quality trends with samples collected using low-flow techniques.
MGP-related constituent concentrations that exceed Wisconsin groundwater quality standards for PVOCs and PAHs (benzo(a)pyrene [BaP], benzo(b)fluorene [BbF], chrysene, fluoranthene, fluorene, naphthalene, and pyrene) are predominately present in shallow wells located within the former slough (MW-301 (historically), MW-302, and MW-311). A few constituent concentrations (benzene, BaP, BbF, chrysene, and naphthalene) were slightly above PALs in side- and downgradient wells MW-303, MW-304, MW-307R, and MW-308. Constituent concentrations exceeding groundwater quality standards were not detected in samples collected from MW-1, MW-2 (historically), MW-3R (MW-3 historically), and MW-5. Generally, MGP-related constituents were not detected in piezometers except P-302 and P-303. PAH concentrations exceeding PALs or ESs were only detected in samples that could not be collected with true low-flow samphng techniques due to insufficient water volumes within the wells.
Samples collected from upgradient wells MW-305 and MW-306 have contained fluctuating concentrations of PAHs that exceed PALs or ESs. MW-306 samples have also contained fluctuating concentrations of PVOCs as detailed below. Additional sampling rounds are required to assess these trends and determine if these constituent concentrations are related to an off-site source or MGP-related residuals.
Of note during the November 2004 and April 2005 sampling events:
• Cyanide concentrations did not exceed the NR 140 PAL of 40 mg/L in wells sampled during the April 2005 sampling event. As previously noted, the November 2005 cyanide data is likely skewed high due to sulfide interference and not representative of groundwater quality.
• Tar was not noted in any monitoring well or piezometer during either the November 2004 or the April 2005 sampling events. Tar has largely been noted in MW-301 in the past. As previously stated, MW-301 was abandoned January 27, 2004;
• Continued BTEX and naphthalene concentration fluctuations in samples collected from MW-306 since August 2002 suggest a potential off-site source area, possibly related to historical placement of MGP-related fill off-site. However, the ratio of benzene to ethylbenzene, xylenes, and TMBs is dissimilar to those observed in MW-301, MW-302, MW-304, and MW-311 samples, indicating a potential non-MGP source area.
NATURAL
RESOURCE e* 9 W ^ ^ ^ KESOURCE
^ Primed on paper containing 60% recycled fibers and .30'!-.i post-consumer wa.ste ^ ^ ^ ^ i T r r H N O i cic\
Ms. Mary Logan and Ms. Kristen DuFresne USEPA and WDNR September 20, 2005 Page 5
• Benzene was detected just above the PAL at MW-307R during both sampling events. PAH compounds were not detected above standards at this location during either event, suggesting the extent of concentrations of MGP residuals above groundwater quality standards is defined in the northern (downgradient) direction.
• Benzene was detected above the ES in MW-311, which appears to be within the former MGP slough. Benzene was detected just below the PAL downgradient of MW-311 at MW-308 and MW-310, along the northern (leading) edge of the plume.
• Naphthalene was detected just above the PAL in MW-308. All other MGP-related constituent concentrations in this well were below detection limits or considerably below their respective PALs.
• Benzene concentrations dropped below the ES of 5 jxg/L in MW-304 for the first time in April 2005. Benzene also remained near the PAL in MW-302. Naphthalene concentrations at these two wells have also decreased over the past few years, suggesting that the extent of MGP-related impacts is defined to the south (side-gradient).
• BTEX compounds were not detected in MW-305 samples from either sampling event. BaP, BbF and chrysene were detected at or slightly above their respective ESs in the April 2005 samples, similar to historic levels, suggesting that the southwestern extent of elevated concentrations is defined and the plume is stable in that direction.
• BaP, BbF and chrysene were detected just above the PAL in the sample fi-om P-303 in November, 2004. These concentrations were detected between the limit of detection and the limit of quantitation and therefore are estimated concentrations. These detections were the only MGP-related constitoent concentrations that exceeded groundwater quality standards in all piezometers during the November 2004 and April 2005 sampling events.
CONCLUSIONS
The extent of MGP-related impacts for BTEX (Figure 4) and PAHs (Figure 5) suggest that BTEX and PAH compounds have not migrated vertically downward to the piezometers. MGP-related constituent concentrations appear to be highest at shallow wells in the vicinity of the former slough (Figures 4 and 5) that traversed the former MGP facility, including wells MW-301 (historically), MW-302, MW-307R, and MW-311. Overall, the groundwater analytical data suggest the downgradient extent of groundwater impacts has been defined.
PROJECT DIRECTION
One additional round of groimdwater sample collection is tentatively scheduled for the week of September 26, 2005. USEPA, WPSC, and NRT have agreed to continue with annual site monitoring until USEPA has had an opportunity to review all project files. NRT recommends annual sampling commence in September 2005, in accordance with previous recommendations to WDNR. Groundwater analytical samples will be collected with low-flow sampling techniques from the 17 site monitoring wells as detailed in the table below. A brief groundwater quality update report summarizing groundwater data collected in September 2005 will be submitted to USEPA in January 2006.
SNATURAL RESOURCE
^ riimcii on paper conutiinng oo-o recycicii liners and .)O;M post-consumer waste • ^ rrinteu on paper comaming ou".o recycieii iiPcrs and Mr/« post-consumer waste 5 ^ ^ ^ B T F r H N n i n r v
Ms. Mary Logan and Ms. Kristen DuFresne USEPA and WDNR September 20, 2005 Page 6
Sampling Event Date September 2005
2006
Water Level Measurement
Collected All Monitoring
Wells
To Be Determined
Well Samples Analyzed for Constituents of
Concern (COC) All Monitoring Wells
To Be Determined
Well Samples Analyzed for Remedial Natural Attenuation
(RNA) Parameters MW-302, MW-304, MW-306, MW-310, MW-311, MW-305,
MW-308, MW-5, P-302, P-303, P-305
To Be Determined Monitoring Weils: Monitoring Wells: MW-302, MW-303, MW-304, MW-305, MW-306, MW-307R, MW-308,
MW-310, MW-311, MW-1, MW-3R, MW-4, MW-5, P-302, P-303, P-304, and P-305. COC: Petroleum volatile organic compounds (PVOCs, SW846 8021B), polynuclear aromatic hydrocarbons (PAHs,
SW846 8270), and available cyanide (OIA-1677). RNA: Sulfate (EPA 300.0), dissolved ferrous iron (SW846 6010), nitrate-i-nitrite (EPA 300.0), dissolved manganese
(SW846 6010), methane (EPA 8015 MOD), alkalinity (EPA 310.2), and field measured parameters (temperature, field conductivity, pH, dissolved oxygen, and oxidation/reduction potential).
Please contact the undersigned at 262.523.9000 or Ms. Shiriey Scharff at 920.433.1396 if you have any questions or comments regarding this update or the schedule of future activities.
Sincerely,
NATURAL RESOURCE TECHNOLOGY, INC.
Paula A. Richardson Hydrogeologist
Rebecca J. Cai^ll, Senior Hydrogeologist
Weber, PE Senior Engineer / Project Manager
cc: Ms. Shirley Scharff, Wisconsin Public Service Corporation (w/attach)
Attachments: Figures 1,2,3,4, and 5 Tables 1,2, 3, and 4 Appendices A, B, and C
[P:\1549\Rpts & Wik Plns\Gmdwtr Qulty Updts\2005 April Sanip\1549 EPA GW Qlty Updt 050920 Ltr.doc]
f j ( Printed i>n paper containing 60".o recycled fibers and V)'.-',\ post-consumer waste
NATURAL
RESOURCE
TECHNOLOGY
FIGURES
Figure 1 Site Location Map (1549/A02gw) Figure 2 Groundwater Elevation Contours, November 22, 2004 (1549-9-BO6.DWG)
Figure 3 Groundwater Elevation Contours, April 13 & 14, 2005 (1549-9-B07.DWG)
Figure 4 Groundwater Benzene, Total BTEX, and Cyanide Analytical Summary (I549-9-B04.DWG)
Figure 5 Groundwater Naphthalene and PAH Analytical Summary (I549-9-B05.DWG)
r
SOURCE: u s e s 7.5 MINUTE QUADRANGLE, MARINETTE EAST. DATED 1963. PHOTOREVISED 1976.
(vy WISCONSIN i:
QUADRANGLE LOCATION
0 2000 4000
SCALE IN FEET CONTOUR INTERVAL 10 FEET
NATURAL RESOURCE TECHNOLOGY
SITE LOCATION MAP FORMER MARINETTE MANUFACTURED GAS PLANT
WISCONSIN PUBLIC SERVICE CORPORATION MARINETTE, WISCONSIN
DRAWN BYiTAS APPROVED BY: RJC DATE: 04 /01 /05
PROJECT NO. 1549
DRAWING NO. 1549-A02gw
FIGURE NO. 1
" "^"OMlNEERiVEf ,^
LEGEND
<s
* MW-5
583.56
* P-301
MW-2
(579.19)»
NGVD
I 1 I I
WATER TABLE ELEVATION CONTOUR, FT. (NGVD)
SHALLOW GROUNDWATER FLOW DIRECTION
MONITORING WELL AND WATER TABLE ELEVATION, FT. (NGVD)
PIEZOMETER
ABANDONED MONITORING WELL
WATER TABLE ELEVATIONS NOT USED FOR CONTOURING
NATIONAL GEODETIC VERTICAL DATUM
CITY OF MARINETTE PROPOSED BRICK INTERCEPTOR SEWER REPLACEMENT
FORMER SLOUGH
FORMER MGP STRUCTURE
EXISTING STRUCTURE
l l l l l l l l l l l l l l l l l l l l RAILROAD
NOTE: • SURVEY DATA FOR WELLS MW-2R, MW-308 . M W - J t O AND MW-311 ARE INCONSISTENT
wnH PREVIOUS SITE ELEVATION DATA. CONSEQUENTLY, THESE WELLS WERE NOT USED IN CONSTRUCTION OF CONTOURS. WELLS WILL BE RESURVEYED IN 2005.
I 40 80 160
SCALE IN FEET
SOURCE NOTE: t . THIS DRAWING WAS DEVELOPED FROM A MAP BY THE CITY OF MARINETTE. 2. PORTIONS OF THE DRAWING ARE FROM A DIGITAL HLE FROM STS CONSULTANTS. LTD.
CONSULTING ENGINEERS, GREEN BAY. WISCONSIN. PROJECT NUMBER 26936. REVISED JANUARY 2 0 0 t . HYDROGRAPHIC SURVEY OF RIVER WAS PERFORMED BY AYRES AND ASSOCIATES ON JULY 2 4 - 2 6 , 2 0 0 1 . VERTICAL CONTROL IS U.S.G.S. DATUM. BUILDING AND STREET LOCATIONS NORTH OF RAILROAD TRACKS WERE SUPPUED BY MARINETTE MARINE CORPORATION.
3. PORTIONS OF THIS DRAWING ARE FROM HYDRO-SEARCH DRAWING. 4. EXISTING STRUCTURES AND UTILITIES FROM FOTH i t VAN DYKE ENGINEERS/ARCHrTECTS,
GRADING PLAN, DIGITAL FILE 7m755c06.DWG. RECORD DRAWING REVISIONS 2 / 2 2 / 9 0 . 5. WEIX LOCATIONS FROM A SURVEY BY WPSC DATED OCTOBER 8, 2003, REVISED
OCTOBER 3 1 , 2003. 6. BRiCK INTERCEPTOR SEWER REPLACEMENT TAKEN FROM DRAWING BY AYRES
ASSOCIATES, GREEN BAY, WISCONSIN, JOB NO. 1 6 - 0 1 8 9 . 1 0 . DRAWING NO. P101 . SHEET NO. 7. DATED 3 / 1 4 / 0 3 .
7. MONITORING WELLS MW-2R. MW-3R. MW-307R INSTALLED OCTOBER 2004 AND MW-305, MW-310, P - 3 0 5 INSTALLED JUNE 2004 . SURVEYED BY WPSC IN JANUARY 2005. CNGVD88. MARINETIE COUNTY COORDINATES).
NATURAL RESOURCE TECHNOLOGY
PROJECT NO.
1549/9
DRAWN BY; RLH/
TAS 04/04/05
CHECKED BY:
PAR 04/04/05
APPROVED BY;
RJC 09/20/05
GROUNDWATER ELEVATION CONTOURS, NOVEMBER 22, 2004
NOVEMBER 2004 GROUNDWATER QUALITY UPDATE FORMER MARINETTE MANUFACTURED GAS PLANT SITE
WISCONSIN PUBLIC SERVICE CORPORATION MARINETTE, WISCONSIN
DRAWING N 0 ; 1 5 4 9 - 9 - B 0 6
REFERENCE; •
FIGURE NO.
""^"^OMINEERIVEH^
LEGEND
<s "b ^
MW-5
584.04
^ P-301
MW-2
(579.65)*
NGVD
" -1
CZZl
l l l l l l l l l l l l l l l l l l l l
WATER TABLE ELEVATION CONTOUR, FT. (NGVD)
SHALLOW GROUNDWATER FLOW DIRECTION
MONITORING WELL AND WATER TABLE ELEVATION, FT. (NGVD)
PIEZOMETER
ABANDONED MONITORING WELL
WATER TABLE ELEVATIONS NOT USED FOR CONTOURING
NATIONAL GEODETIC VERTICAL DATUM
CITY OF MARINETTE PROPOSED BRICK INTERCEPTOR SEWER REPLACEMENT
FORMER SLOUGH
FORMER MGP STRUCTURE
EXISTING STRUCTURE
RAILROAD
NOTE: • SURVEY DATA FOR WELLS MW-2R, MW-308, MW-310 AND MW-311 ARE INCONSISTENT
WITH PREVIOUS SITE ELEVATION DATA CONSEQUENTLY. THESE WELLS WERE NOT USED IN CONSTRUCTION OF CONTOURS. WELLS WIU BE RESURVEYED IN 2005.
I 40 80 160
SCALE IN FEET
SOURCE NOTE: 1. THIS DRAWING WAS DEVELOPED FROM A MAP BY THE CITY OF MARINETTE. 2. PORTIONS OF THE DRAWING ARE FROM A DIGITAL FILE FROM STS CONSULTANTS. LTD.
CONSULTING ENGINEERS. GREEN BAY, WISCONSIN, PROJECT NUMBER 26936. REVISED JANUARY 2001. HYDROGRAPHIC SURVEY OF RIVER WAS PERFORMED BY AYRES AND ASSOCIATES ON JULY 24-26, 2001. VERTICAL CONTROL IS U.S.G.S. DATUM. BUILDING AND STREET LOCATIONS NORTH OF RAILROAD TRACKS WERE SUPPUED BY MARINETTE MARINE CORPORATION.
3. PORTIONS OF THIS DRAWING ARE FROM HYDRO-SEARCH DRAWING. 4. EXISTING STRUCTURES AND UTILmES FROM FOTH 4 VAN DYKE ENGINEERS/ARCHITECTS.
GRADING PLAN. DIGITAL FILE 7m755c05.DWG. RECORD DRAWING REVISIONS 2/22/90. 5. WaL LOCATIONS FROM A SURVEY BY WPSC DATED OCTOBER 8. 2003, REVISED
OCTOBER 31. 2003. 6. BRICK INTERCEPTOR SEWER REPLACEMENT TAKEN FROM DRAWING BY AYRES
ASSOCIATES, GREEN BAY, WISCONSIN, JOB NO. 16-0189.10. DRAWING NO. PlOl . SHEET NO. 7, DATED 3/14/03.
7. MONITORING WELLS MW-2R. MW-3R. MW-307R INSTALLED OCTOBER 2004 AND MW-308. MW-310. P-305 INSTALLED JUNE 2004. SURVEYED BY WPSC IN JANUARY 2005. (NGVDSS. MARINETTE COUNTY COORDINATES).
NATURAL RESOURCE TECHNOLOGY
PROJECT NO. 1549/9
DRAWN BY: RLH/
TAS 09/07/05
CHECKED BY:
PAR 09/07/05
APPROVED BY; RJC 09/20/05
GROUNDWATER ELEVATION CONTOURS, APRIL 13 & 14, 2005
APRIL 2005 GROUNDWATER QUALITY UPDATE FORMER MARINETTE MANUFACTURED GAS PLANT SITE
WISCONSIN PUBLIC SERVICE CORPORATION MARINETTE, WISCONSIN
DRAWING N0;1549-9-B07 FIGURE NO.
'^^ '^OM,NEER,VHR^ MW-1
04/13/94
osnam 08/27/02 08/13/03 MW-1
11/22A)4 04/13/05
BEN <0.7 <0.7
BTEX 3.7 nd
CYNW/U) <3J <3.5
WeU could not be located WeU could not be located
BEN <0.14 <0.I4
BTEX nd nd
CYNAVL 54 Z <5.0
MW-311 11/22/04 04/13/05
BEN SSOK 260
BTEX 2,619 1.335
CYNAVL 12 Z <5.0
MW-2 04/14/94 05/11/94 08/27/02 08/13/03 11/22A)4
BEN <0.7 <0.7
BTEX nd nd
CYNWAD <3.5 <3.5
WeU could not be located WcU could not be localed
WeU abandoned October 2004
Diy WcU
0.14 I nd I
MW-4 (wiAm OS/11/94 O8C7/02 08/14/03 MW-4
11/22/04
04/13A>S
BEN 13
<17.5 0.48 OJO BEN
0.15 0
BTEX 1.943 2,789
nd nd
BTEX 0.2
CYNWAD <3.5 <3.5 40 0
L CYNAVL
I IZ WeU abandoned April 2005 |
< 6 . 0 X
0.20Q
<0M
MW-305
oenAm 08/12/96 08a7/02 08/14/03 MW-305 11/22/04 04/14/05
BEN
<oso <0.50 <0.4« <0J0 BEN 0.14 <0.14
BTEX nd nd nd nd
BTEX nd nd .,
CYNWAD
/ - / - ' / 19/'/
,U / OVNAVL ~
/ /22Z ' /• <5.0
<7
/ •
^ ^
05/10/94
umii>-_A. . ' °5BTSO3/ MW-3a2
liMO
0.76 O
3,090
LEGEND
/
^ MW-1
^ P-301
, SB-333
^ MW-2
A HP-301
t ^ TP-305
L-_~_"_l
l l l l l l l l l l l l l l l l l l l l
1 1
1 1
APPROXIMATE EXTENT OF BTEX CONCENTRATIONS THAT EXCEED AN NR140 ES
APPROXIMATE EXTENT OF BTEX CONCENTRATIONS THAT EXCEED AN NR140 PAL
MONITORING WELL
PIEZOMETER'
SOIL BORING
ABANDONED MONITORING WELL
HYDRO-PUNCH SAMPLE
TEST PIT
CIIY 01- MAKINLIIL PROPOSED BRICK INTERCEPTOR SEWER REPUCEMENT
FORMER MGP STRUCTURE
FORMER SLOUGH
RAILROAD
EXISTING STRUCTURE
FORMER WASTE WATER TREATMENT PLANT STRUCTURE
SA1>(PI.H LOCATION
SAMn£DA-m
BEN
BENZENE 0*1)
BTEX
BENZENE, TOUTOffi,
ETHYLBENZENE, TOTAL
XYLENE 01*1.)
CYNWAD
CYANIDE, WEAK ACID
DISSOCIABLE UlS/L. t-UlLU FILTERED)
CYNAVL
CYANIDE AVAILABLE
01A.16T7 ( M / Z U F I E U J FILTERED)
Waaniun Oiuimlwmi Qnilily Sanlcili (NH 1«, 2003)
EntonxoKBt Stmlxnl (ES) OJ 9
n m
40 200
40 200
N B E N ~ B T E X / ^ e V N A Y K
y ^^.x/^
DATA QUALIFIERS:
£ « CaNCENTRAnON ATT/UNS OR EXCEEDS AN NR 140 PREVENTIVE ACnON LMTT
4 C CONCENTRATtON ATT/UNS OR EXCEEDS AN NR 1 « ENFORCEMENT STANDARD
n d NOT DETECTED
01 STANDARD DAS NOT BEEN ESTABLISHED
ANALYSIS NOT PERFORMED
MtCROORAMS PER LITER
CONSnTUBNr WAS NOT IDENnFIHD ABOVE THE UMTT OP DHTBCTION INDICATED.
L/^ORATORY NOTE-PRECISION NOT WTTHIN CONTROL LIMTTS.
LABORATORY NOTE-DETECTION UMIT MAY BE ELEVATED DUE TO THE PRESENCE OP /W UNREQUESTED ANALYTE.
CYANIDB ANALYSIS W/IS NOT PERFORMED DUE TO LABORATORY ERROR.
LABORATORY NOTE - THE ANALYTE HAS BEEN DETECTED BETWEEN THE UMTT OF DBTECnON (LOD) AND LIMTT OF QUANnTATION (LOQ).
ftli-
P-302 06/24^6 0S/12M 08/27/02 08/13/03
P-302 11/22/04 (M/14/05
BEN <0.50 O.50 0.48 OJO BEN 0.14 <0.I4
BTEX nd nd nd nd
BTEX nd nd
CYNWAD
_ -13 L
CYNAVL <5Z <5.0
AV/ULABLB CY/WIDB RESULTS MAY BE BIASED HIGH DUE TO INTERFERENCE OF SULFIDE WTTH /^NALYSIS METHOD. SAMPLES WERE NOT FIELD PRESERVED WITH LEAD CARBONATE.
NOTE; I. DUPUCATE S/UrfPLES WERE COLLECTED DURINO EACH
SAMPUNO EVENT. BENZENE. BENZENE, TOLUENE, ETHYLBENZENE, TOTAL XYLENE, CY/UflDE-WEAK ACID DISSOCIABLE. AND CYANIDE-AVAILABLB CONCENTRATIONS SHOWN REFLECT THE HtOHER CONCENTRATION BETWEEN WELL SAMPLES /WD DUPUCATE SAMPLES.
SOURCE NOTE: 1. THIS DRAWING WAS DEVELOPED FROM A MAP BY THE CHY OF MARINETTE. 2. PORTIONS OF THE DRAWING ARE FROM A DIGITAL RLE FROM STS CONSULTANTS. LTD. CONSULTING ENGINEERS.
GREEN BAY, WISCONSIN, PROJECT NUMBER 26936, REVISED JANUARY 2001. HYDROGRAPHIC SURVEY OF RIVER WAS PERFORMED BY AYRES AND ASSOCIATES ON JULY 24-26, 2001. VERTICAL CONTROL IS U.S.G.S. DATUM. BUILDING AND STREET LOCATIONS NORTH OF RAILROAD TRACKS WERE SUPPUED BY MARINETTE MARINE CORPORATION.
3. PORTIONS OF THIS DRAWING ARE FROM HYDRO-SEARCH DRAWING. 4. EXISTING STRUCTURES AND UTILITIES FROM FOTH & VAN DYKE ENGINEERS/ARCHITECTS. GRADING PLAN, DIGITAL
RLE 7m755c06.DWG. RECORD DRAWING REVISIONS 2/22/90. 5. WELL LOCATIONS FROM A SURVEY BY WPSC DATED OCTOBER 8. 2003, REVISED OCTOBER 31. 2003. 6. BRICK INTERCEPTOR SEWER REPLACEMENT T/kKEN FROM DRAWING BY AYRES ASSOCIATES, GREEN BAY. 0
WISCONSIN, JOB NO. 16-0189.10, DRAWING NO. P101. SHEET NO. 7, DATED 3/14/03. 7. MONITORING WELLS MW-2R. MW-3R. MW-307R INSTALLED OCTOBER 2004 AND MW-308. MW-310, P-305
INSTALLED JUNE 2004. SURVEYED BY WPSC IN JANUARY 2005. (NGVDSS. MARINETTE COUNTY COORDINATES).
40 80 160
SCALE IN FEET
MW-5 04/14/94 05/11/94 08^7/02 08/14/03 MW-5
11/22/04 04/14/05
BEN 0 .7 0 .7 0.4S OJO BEN 0.75
0.14
BTEX nd nd nd nd
BTEX 1.4 nd
CYNWAD <3.5 \ <3.5 <2.7
L CYNAVL
<5Z <5.0
NATURAL RESOURCE TECHNOLOGY
PROJECT NO.
1549/9
DRAWN BY: RLH/
TAS 09/12/05
CHECKED BY;
PAR 09/12/05
/APPROVED BY:
RJC 09/20/C5
GROUNDWATER BENZENE, TOTAL BTEX, AND CYANIDE ANALYTICAL SUMMARY
APRIL 2005 GROUNDWATER QUALITY UPDATE FORMER MARINETTE MANUFACTURED GAS PLANT SITE
WISCONSIN PUBLIC SERVICE CORPORATION MARINETTE. WISCONSIN
DRAWING NO;1549-9-B04
REFERENCE: \CAD TABLES APRIL 2005.XLS FIGURE NO.
MW-1
04/13/94
05/10/94
attiim OS/13/03
11/22A>4
04/13/05
~—-_ NAPH
<1.10
<1.10
PAH
nd
nd
WeU could not be located
WeU could not be located
0.14
0.055 0
02
0.1
MW-307
oenAm 0&'13/96
08^7/02
08/13/03
MW-307R
ni22m 04/13/05
NAPH
<1.0
<1.0
<0.067
0.033 Q*
NAPH
3.2 D
0.55 0
PAH
I J
nd
1.9
0.2
PAH
31
15
MW-311
11/22/04
04/13/05
NAPH
3J00D
2,000 D
PAH
3,969
2,679
MW-2
04/14A>4
05/11/94
08^7/02
08/13A)3
11/22A)4
NAPH
334
1.75
PAH
3.3
1.8
WeU could not be located
WeU could not be localed
WeU abandoned October 2004
MW-310
11/22/04
04/13/05
NAPH
5.4 D
3.7
PAH ,
23
19
MW-4
04/14/94
05/11/94
08^7/02
08/14A)3
11/22/D4
04/13A)5
NAPH
393
147
0.96
0.026 ty
0.026 Q
Well abandons
PAH
393
147
1.0
0.03
0.03
dALpril2005
MW-308
11/22W4
04/13/05
/ / /
/
NAPH
<2.2
72
PAH
|45
P-305
11/22A)4
04/14A)5
NAPH
0.025 Q
0.026 Q 1
60
PAH
0.1
0.04
P-304
06/24/96
08/12«6
08/27/02
08/13/03
U/22M
04/14/05
NAPH
_ <1.0
O.067
PAH 1 _ nd 1 nd 1
DiyweU, not sampled
Dry well, not sampled
O.I7 1 nd 1
..7.9
O.ll 'Cy
,<0.022
WEA/O/W/^EER,^^^^
Weil ' c o v M i ^ b e l o c ^ B i H H - ,
Well could not be located
Well scheduled for abandonmmt
I D I '
p-303
^06n4ffl6.
08/12/96
7
"N/ t fH—I
P-302
06/24/96
Og/l2«6
08/27/02
08/13/03
n/22m M/\W5
NAPH
<1.0
<1.0
0.18 Q
0.43"
O.022
0.022
PAH
n d \
nd , '
0.2V
0.8 "
nd
nd
~
MW-302
04/14m
05/10/94
0807/02
08/13A)3
11/22^4
04/14/05
NAPH
2J00
2,520
;; 0.85'
«e <0.45
PAH
2,705
2.627
507
13
590
26
.•'MW-'303
'06/24fl6
08/12/96
08^7/02
08/13/03
/ l im /04
xO4/l'4/05
NAPH /
/<1 .0 (
'^ <1.0
,<a067'""
/ 0.039 Q
0.032 Q
0.18
PAH
nd
" \ nd
-.« '9 J
~0.7 "'"^
0.6 " • -
0.7
MW-5
04/14/94
05/11/94
08/27/02
08/14A)3
11/22/04
04/14/05
NAPH
<1.10
<1.10
3.9
Pjulx
nd \ .
0.2
10
Sample botde biokai in transport
1.4 D
0.034 Q
1.7
0.03
MW-304-
06Q4/96'
08/12/96
08/27/02
.08/13/1^
11/22W^
04/14/05
. xNAPH
•^ 310
120
190
100 D
\ 2 7
X 0.06aQ
PAH
402
226
296
121
30
0.5
LEGEND
^ " ^ ^
.fh. MW-1
^ P-301
MW-2
A HP-301
j ^ TP-J05
C I Z U
-Hf+fl-t+fH+HH4-H+f
1 1
APPROXIMATE EXTENT OF PAH CONCENTRATIONS THAT EXCEED AN NR 140 ES
APPROXIMATE EXTENT OF PAH CONCENTRATIONS THAT EXCEED AN NR 140 PAL
MONITORING WELL
PIEZOMETER
ABANDONED MONITORING WELL
HYDRO-PUNCH SAMPLE
TEST PIT
CITY OF MARINETTE PROPOSED BRICK INTERCEPTOR SEWER REPLACEMENT
FORMER MGP STRUCTURE
FORMER SLOUGH
RAILROAD
EXISTING STRUCTURE
FORMER WASTE WATER TREATMENT PLANT STRUCTURE
SAMPLE LOCATION
SAMPLE DATE
NAPH
NAPHTHALENE
(Itg/L)
PAH
TOTAL POLYNUCLEAR
/SOMATIC
HYDROCARBONS
(^g/L)
1 Wisconsin Grotmdwatcr Quality Stsndaids (NR 140, 2003)
1 Preventive Action Limit (PAL)
1 Enfoicemcnt Standard (ES)
8 40
ns ns
MW-301
04/1S/U
05/loM -08OTTO
0&'14y<03'
M1/22A)4
NAPH
3J2(i
2J40
.^^300 /
iiiOraD*
/PAH'
/ 3,7»7
2312
8^359-^
^-54340
WeU Abandoned /
DATA QDAUFIERS; 4 CONCENTRATION ATTAINS OR EXCEEDS AN NR 140 PREVENTIVE ACTION LIMIT
310 CONCENTRATTON ATTAINS OR EXCEEDS AN NR 140 ENFORCEMENT STANDARD
Mg/L
X J'-301
~04/14»4
05/^1/94
08 /27 /M '
11/22/04
/NAPH'
/ <1.I0
' /- / / 2 . 7 /
/ PAH
/ 12
_ 3.6
.Well Abmdoned
NOT DETECTED STANDAKD HAS NOT BEEN ESTABLISHED AN/UwYSIS N(7T PERFORMED MICROGRAMS PER LTTER CONSTTrUENT WAS NOT IDENTIPIED ABOVE THE UMIT OF DETECTION INDICATED. LABORATORY N0TE.PRECISI0N NOT WTTtON C»NTROL LDiOTS. LABORATORY NOT1E-ANALYTE VAUJE FROM DILUTED ANALYSIS. LABORATORY NOTE - THE ANALYTE HAS BEEN DETECTED BETWEEN THE LIMIT OF DETECTION (LOD) AND LIMTT OF QUANTITATION (LOQ). LABORATORY NOTE-PRECISION NOT WTIHIN CONTROL LIMTTS.
NOTE: 1. DUPUCATE SAMPLES WERE COLLECTED IXnUNO EACH SAMPUNO
EVENT. NAPHTHALENE AND TOTAL POLYI>JUCLEAR AROMATIC HYDROCARBONS CONCENTRATIONS SHOWN REFLECT THE HIOHER CONCENTRATTON BETWEEN WELL SAMPLES AND DUPLICATE SAMPLES.
SOURCE NOTE; 1. THIS DRAWING WAS DEVELOPED FROM A MAP BY THE CITY OF MARINETTE. 2. PORTIONS OF THE DRAWING ARE FROM A DIGITAL FILE FROM STS CONSULTANTS, LTD. CONSULTING ENGINEERS,
GREEN BAY, WISCONSIN, PROJECT NUMBER 26936. REVISED JANUARY 2 0 0 1 . HYDROGRAPHIC SURVEY OF RIVER WAS PERFORMED BY AYRES AND ASSOCIATES ON JULY 2 4 - 2 6 , 2 0 0 1 . VERTICAL CONTROL IS U.S.G.S. DATUM. BUILDING AND STREET LOCATIONS NORTH OF RAILROAD TRACKS WERE SUPPLIED BY MARINETTE MARINE CORPORATION.
3. PORTIONS OF THIS DRAWING ARE FROM HYDRO-SEARCH DRAWING. 4. EXISTING STRUCTURES AND UTILITIES FROM FOTH Sc VAN DYKE ENGINEERS/ARCHITECTS, GRADING PLAN, DIGITAL
FILE 7m755c06.DWG, RECORD DRAWING REVISIONS 2 / 2 2 / 9 0 . 5. WELL LOCATIONS FROM A SURVEY BY WPSC DATED OCTOBER 8, 2003, REVISED OCTOBER 3 1 , 2003. 6. BRICK INTERCEPTOR SEWER REPLACEMENT TAKEN FROM DRAWING BY AYRES ASSOCIATES, GREEN BAY.
WISCONSIN, JOB NO. 1 6 - 0 1 8 9 . 1 0 , DRAWING NO. P l O l , SHEET NO. 7, DATED 3 / 1 4 / 0 3 . 7. MONITORING WELLS MW-2R. MW-3R, MW-307R INSTALLED OCTOBER 2004 AND M W - 3 0 a , MW-3 tO . P -305
INSTAaED JUNE 2004. SURVEYED BY WPSC IN JANUARY 2005. (NGVDSS, MARINETTE COUNTY COORDINATES).
^ 0 80
SCALE IN FEET
160
\
NATURAL RESOURCE TECHNOLOGY
PROJECT NO.
1 5 4 9 / 9
DRAWN BY; R L h /
TAS 0 9 / 1 2 / 0 5
CHECKED BY:
PAR 0 9 / 1 2 / 0 5
APPROVED BY;
RJC 0 9 / 2 0 / 0 5
GROUNDWATER NAPHTHALENE AND PAH ANALYTICAL SUMMARY
APRIL 2005 GROUNDWATER QUALITY UPDATE FORMER MARINETTE MANUFACTURED GAS PLANT SITE
WISCONSIN PUBLIC SERVICE CORPORATION MARINETTE, WISCONSIN
DRAWING NO: 1 5 4 9 - 9 - 8 0 5
REFERENCE; \CAD TABLES APRIL 2005.XLS
FIGURE NO.
TABLES
Table 1 Groun(Jwater Elevations Table 2 Groundwater /Analytical Results - PVOC and Cyanide Table 3 Groundwater Analytical Results - Polynuclear Aromatic Hydrocarbons (PAH) Table 4 Groundwater Analytical Results - RNA Parameters
Table 1 - Groundwater Elevations April 2005 Groundwater Quality Update -1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS U: 02-38-000047
Well Construction Data Well Depth from TOC (feet) Screen Length (feet) Surface Elevation (NAVD) Top of Casing Elevation (NAVD) Top of Screen Elevation (NAVD) Screen Bottom Elevation (NAVD)
Date 04/14/94 04/15/94 05/10/94 05/11/94 08/13/96 08/27/02 08/13/03 11/22/04
04/13/05 & 04/14/05
IVIW-1
14.24 10
582.63 585.09 580.85 570.85
Depth to Water from TOC
(feet) 3.84 3.54 4.36 4.31
Water Elevation (NAVD) 581.25 581.55 580.73 580.78
well could not be located well could not be located
Located/repaired October 2004 6.39 5.06
578.70 580.03
IVIW-2
11.65 5
584.66 586.5 579.85 574.85
Depth to Water from TOC (feet)
6.04 5.66 6.02 5.98 5.71
Water Elevation (NAVD) 580.46 580.84 580.48 580.52 580.79
MW-2 could not be located MW-2 could not be located Abandoned October 2004
MW-3 MW-3R Scheduled for Installed Abandonment 10/04
15.53 14.84 10 10
586.03 585.68 587.69 585.50 582.16 580.66 572.16 570.66
Depth to Water from TOC (feet)
6.69 6.46 6.99 6.95 8.16
Water Elevation (NAVD) 581.00 581.23 580.70 580.74 579.53
MW-3 could not be located MW-3 could not be located
6.60 6.24
578.90 579.26
MW-4 12.
5 35
586.06 587.92 580.27 575.27
Depth to Water from TOC
(feet) 5.89 5.84 5.97 5.96 6.02 6.45 6.81 8.02
Water Elevation (NAVD) 582.03 582.08 581.95 581.96 581.90 581.47 581.11 579.90
Abandoned April 2005
Well Construction Data Well Depth from TOC (feet) Screen Length (feet) Surface Elevation (NAVD) Top of Casing Elevation (NAVD) Top of Screen Elevation (NAVD) Screen Bottom Elevation (NAVD)
Date 04/14/94 04/15/94 05/10/94 05/11/94 08/13/96 08/27/02 08/13/03 11/22/04
04/13/05 & 04/14/05
MW-5 16.66
10 590.14 591.76 585.10 575.10
Depth to Water from TOC
(feet) 7.27 7.25 6.78 6.76 6.04 7.40 8.11 8.20 7.72
Water Elevation (NAVD) 584.49 584.51 584.98 585.00 585.72 584.36 583.65 583.56 584.04
MW-301 16.1 10
587.00 ""58a'55 ^'
583.45 573.19
Depth to Water from TOC (feet)
8.81 8.68 9.08 nm
8.59 10.00
Water Elevation (NAVD) 580.74 580.87 580.47
nm 580.96 579.55
Tar present - not measured Abandoned February 2004
MW-302 18.27
id 591.82 594.'94' 586.67 576.67
Depth to Water from TOC (feet)
13.37 13.25 13.23 13.12 12.15 11.20 14.24 14.07 13.46
Water Elevation (NAVD) 581.57 581.69 581.71 581.82 582.79 583.74 580.70 580.87 581.48
MW-303 12.57
10 584.99 584.62 582.05 572.05
Depth to Water from TOC
(feet)
Water Elevation (NAVD)
Constructed August 1996 3.40 4.65 5.57 5.62 5.05
581.22 579.97 579.05 579.00 579.57
1549GWQualilyData 050809 TbI 1 WTR Elevations Page 1 of 3 S^
Table 1 - Groundwater Elevations April 2005 Groundwater Quality Update -1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS #; 02-38-000047
Well Construction Data Well Depth from TOC (feet) Screen Lengtfi (feet) Surface Elevation {NAyp)_ top of Casing Elevation (NAVD) Top of Screen Elevation (NAVD) Screen Bottom Elevation (NAVD)
Date 04/14/94 04/15/94 05/10/94 05/11/94 08/13/96 08/27/02 08/13/03 11/22/04
04/13/05 & 04/14/05 .
IVIW-304 15.97
10 585.20 587;73 581.76 571.76
Depth to Water from TOC
(feet)
Water Elevation (NAVD)
Constructed August 1996 5.99 4.10 8.25 7.91 7.35
581.74 583.63 579.48 579.82 580.38
MW-305 22.57
10 ' " 594.71 597'25 584.68 574.68
Depth to Water from TOC (feet)
Water Elevation (NAVD)
Constructed August 1996 3.40 14.48 15.15 15.96 15.39
593.85 582.77 582.10 581.29 581.86
MW-306 10.19
10 586.22 585'77 585.58 575.58
Depth to Water from TOC (feet)
Water Elevation (NAVD)
Constructed August 1996 3.75 4.15 4.49 5.66 4.44
582.02 581.62 581.28 580.11 581.33
MW-307 Abandoned
10/04
11.78 To
584.98 584!47' 582.70 572.70
Depth to Water from TOC
(feet)
Constructed 3.59 4.85 5.63 5.94 5.47
MW-307 R Installed
10/04
12.6 10
585.07 584.70 582.10 572.10 Water
Elevation (NAVD)
August 1996 581.11 579.85 579.07 578.76 579.23
Well Construction Data Well Depth from TOC (feet) Screen Length (feet) Surface Elevation (NAVD) fop of Casing'Elevatiori(NA\/bj Top of Screen Elevation (NAVD) Screen Bottom Elevation (NAVD)
Date 08/13/03 11/22/04
04/13/05 & 04/14/05
MW-308 12.59
10 586.94 586'62 584.04 574:04 " "
Depth to Water from TOC
(feet)
Water Elevation (NAVD)
Constructed June 2004 8.21 7.79
578.41 578.83
MW-310 12.58
10 585.90 585!50 581.89 "57i:89
Depth to Water from TOC (feet)
Water Elevation (NAVD)
Constructed June 2004 6.31 5.85
579.19 579.65
MW-311 14.29
10 585.60 585.20 580.91 570:9
Depth to Water from TOC (feet)
Water Elevation (NAVD)
Constructed October 2004 | 7.01 6.19
578.19 579.01
1549G WQualityData 050809 TbI 1 WTR Elevations Page 2 of 3
Table 1 - Groundwater Elevations April 2005 Groundwater Ouality Update -1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS #; 02-38-000047
Well Construction Data Well Depth from TOC (feet) Screen Length (feet) Surface Elevation (NAVD) Top of Casing Elevation (NAVD) Top of Screen Elevation (NAVD) Screen Bottom Elevation (NAVD)
Date 04/14/94 04/15/94 05/10/94 05/11/94 08/13/96 08/27/02 08/13/03 11/22/04
04/13/05 & 04/14/05
P-301 43.00
5 587.24 589.67 551.67 '546.67
Depth to Water from TOC
(feet) 40.89 41.81 42.36 42.95 40.55 33.50 41.58
Water Elevation (NAVD) 548.78 547.86 547.31 546.72 549.12 556.17 548.09
Abandoned February 2004
P-302 30.74
5 591.46 594.00 568.26 563:26
Depth to Water from TOC (feet)
Water Elevation (NAVD)
Constructed August 1996 12.08 13.20 14.24 14.07 13.48
581.92 580.80 579.76 579.93 580.52
P-303 34.72
5 585.43 587.65 557.93 552.93
Depth to Water from TOC (feet)
Water Elevation (NAVD)
Constructed August 1996 32.46 14.20 30.84 30.45
nm
557.21 575.47 558.83 559.22
nm
P-304 34.80
5 585.68 587.92 558.12 553.12
Depth to Water from TOC
(feet)
Water Elevation (NAVD)
Constructed August 1996 27.71 23.05 32.49 32.85 nm
561.96 566.62 557.18 556.82
nm
Well Construction Data Well Depth from TOC (feet) Screen Length (feet) Surface Elevation (NAVD) Top of Casing Elevation (NAVD) Top of Screen Elevation (NAVD) Screen Bottom Elevation (NAVD)
Date 08/13/03 11/22/04
04/13/05 & 04/14/05
P-305 26.63
5 586.96 586.96 565.33 560.33
Depth to Water from TOC
(feet)
Water Elevation (NAVD)
Constructed June 2004 | 7.32 6.94
579.64 580.02
[JTB/XSRL Ofl/OZKRJCJTB t I/02J[PAR/JTB 0'X)3I[MJR''JTB-2'05I[PAR/TILH5/05|
Notes: Monitoring wells were surveyed October 8, 2003 and January 2005. Survey data for wells MW-308, MW-310 and MW-311 are inconsistent with 2003 ground surface elevations. Wells will be surveyed in 2005.
TOC NAVD
Top of PVC well casing Vertical Datum is NAVD88 (North American Vertical Datum • Water level elevation above top of screen elevation
feet) MW
PZ nm
monitoring well piezometer not measured
1549GWQualityData 050809
TbI 1 WTR Elevations Page 3 of 3
Table 2 - Groundwater Analytical Results - PVOCs and Cyanide Apri l 2005 Groundwater Quality Update - 1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS #; 02-38-000047
Sample Location
Preventive Actio Enforcement Stc
MW-301
MW-302 dup
dup
dup (QA/QC 1)
dup (QC-2)
MW-303
MW-304 dup
dup(QC-l)
MW-305
MW-306
dup(QC-1)
Sample Date
Wisconsin n Limit (PAL) mdard (ES)
04/15/94 05/10/94 08/27/02 08/14/03 11/22/04
04/14/94 04/14/94 05/10/94 05/11/94 08/27/02 08/27/02 08/13/03 08/13/03 11/22/04 04/14/05
06/24/96 08/12/96 08/27/02 08/13/03 11/22/04 04/14/05
06/24/96 06/24/96 08/12/96 08/27/02 08/13/03 08/13/03 11/22/04 04/14/05
06/24/96 08/12/96 08/27/02 08/14/03 11/22/04 04/14/05
06/24/96 08/13/96 08/27/02 08/14/03 11/22/04 11/22/04 04/13/05
Petroleum Volatile Organic Compounds (pg/L)
c
s c m
01 c 0) N c
UJ
0)
c 3
re
o c 0)
>. X
Groundwater Quality Standards (NR 0.5 5
770 321
2,600 1,200 K
1,230 980 482 <0.7
0.58 Q 0.76 Q
19 19 4.6 £9
<0.50 <0.50 <0.48 <0.30 <0.14
1.5
150 180 260 100 94 K 97 29
M <0.50 <0.50 <0.48 <0.30 <0.14 <0.14
<0.50 <0.50 <2.4
<6.0K 0.20Q 0.15 Q <0.34
140 700 650 720 910
520 K
200 1,000 580 434 830
470 K Well abandoned
380 440 538 <0.9 <0.43 <0.43 4.2 4.2 8.6
0.57 Q
<1.0 <1.0 <0.43 <0.60 <0.40 0.53 Q
48 64 39 13
11 K 12 5.9
<0.40
<1.0 <1.0 <0.43 <0,60 <0.40 <0.40
4.7 9.5 390
930 K 0.41 O <0.40 350
520 640 405 <1.0 <0.47 <0.47 <0.58 <0.58 <0.36 <0.36
<1.0 <1.0 <0.47 <0.58 <0.36 <0.36
23 29 62 22
21 K 22 5.1
<0.36
<1.0 <1.0
<0.47 <0.58 <0.36 <0.36
<1.0 <1.0 88
150 K <0.36 <0.36
13
1,000 10,000
840 782
680 O 510K
X LU 1 -
m
o
U IT)
c " -o '-" 5 -a
t CM
f=6
Cyanide (pg/L)
.-1
.;«: O
0) <n
5 5 140, February 2004)
ns ns
2,840 2,257 5,020 2,700
96 480
--
140 Q 162 KQ
ns ns 76
474 81 L
as part of sewer construction during 2004
390 1.030 1,090 <1.5 <1.4 <1.4 <1.2 <1.2 6.2
<0.74
<3.0 <3.0 <1.4 <1.2 <0.74 <0.74
58 76
<150 28
22.6 K 22.6 8.6
<0.74
<3.0 <3.0 <1.4 <1.2 <0.74 <0.74
21 66
1,020 2.160 K
2.3 1.8 690
2,520 3,090 2,515
nd 0.6 0.8 23 23 19 5.5
nd nd nd nd nd 2.0
279 349 361 163 149 154 49 1.1
nd nd nd nd nd nd
26 76
1,498 3,240
2.9 2.0
1,053
----
<0.52 <0.52 <0.66 <0.66
0.61 Q <0.40
--
<0.52 <0.66 <0.40 <0.40
--~
10.7 0 6.0 KQ 6.0 KQ 2.53 Q <0.40
--
<0.52 <0.66 <0.40 <0.40
--
321 920 K
5.5 4.2 375
68 72 77
<3.5 <2.7 8,0 Q
L L
----
6 Q L
-----20 L L
----19 L
----
<2.7 L -" -
5 ! ^ .a <o ra 1-•5 <
40 200
----
--------
69 Z 8.0
----
38 Z <5.0
------
660 Z 7.8
----
22 Z <5.0
----
28 Z 31 Z <5.0
1 o "5 c 0) .c Q.
1,200 6,000 7,460 140 --
138 493 <15 20 ------------------------------— --
1549GWQualityData 050809 TbI 2 GW PVOC + Cn Page 1 of 3 SE;
Table 2 - Groundwater Analytical Results - PVOCs and Cyanide Apr i l 2005 Groundwater Quality Update - 1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS #.- 02-38-000047
Sample Location
Preventive Actio Enforcement St<
MW-307
IVIW-307R
dup(QC-l)
MW-308
MW-310
MW-311
MW-1
MW-2
MW-3
MW-3R
MW-4
dup (QC-2)
MW-5
dup (QC-2)
Sample Date
Wisconsin n Limit (PAL) mdard (ES)
06/24/96 08/12/96 08/27/02 08/14/03 11/22/04 11/22/04 04/13/05 04/13/05
11/22/04 04/13/05
11/22/04 04/13/05
11/22/04 04/13/05
04/13/94 05/10/94 08/27/02 08/13/03 11/22/04 04/13/05
04/14/94 05/11/94 08/27/02 08/13/03 11/22/04
04/14/94 05/11/94 08/27/02 08/13/03 11/22/04 11/22/04 04/14/05
04/14/94 05/11/94 08/27/02 08/14/03 11/22/04 11/22/04 04/13/05
04/14/94 05/11/94 08/27/02 08/14/03 11/22/04 04/14/05 04/14/05
Petroleum Volatile Organic Compounds (pg/L)
0) c 0) N c iS
hyl
benze
ne
luene
lenes,
Tota
l
tal B
TE
X
meth
ylbenze
ne
2,4
-an
d 1
,3,5
-)
^ o ;»> o 1. -LU 1- X 1- 1- C
Cyanide (pg/L)
2 ^
X o ca in Q) (/}
5 5 Groundwater Quality Standards (NR 140, February 2004)
0.5 5
0.63 1.2
<0.48 <0.30
0.67 0.57 0.80
0.61 0.33 Q
0.68 <0.14
SSOK 260
<0.7 <0.7
<0.14 <0.14
<0.7 <0.7
<0.7 <0.7
<0.14 <0.14
13 <17.5 <0.48 <0.30
0.15 Q
<0.7 <0.7 <0,48 <0.30 0.73
<0.14 <0.14
140 200 1,000 ns 96 700 1,000 10,000 ns 480
<1.0 <1.0 <3.0 0.6 <1,0 <1.0 <3.0 1.2
<0.43 <0.47 <1.4 nd <0.52 <0.60 <0.58 <1.2 nd <0.66
ns ns
--
5.0 Q L
Well abandoned October 2004, replaced with MW-307R <0.40 <0.36 <0,74 0.6 0.69 Q <0.40 <0.36 <0.74 0.6 <0.40 <0.40 <0.36 <0.74 0.8 <0.40
<0.40 <0.36 1.00 Q 1.6 0.90 Q 0.71 Q <0.36 0,76 Q 1.8 1.4
0.89 Q <0.36 <0.74 1.6 0.46 Q <0.40 <0.36 <0.74 nd <0.40
1 , 2 0 0 K 1 9 Q , K 820 K 2,619 207 K 700 15 360 1,335 110
<0.9 1.1 2.6 3.7 <0.9 <1.0 <1.5 nd
---------
<3.5 <3.5
Well could not be located during the sampling event. Well could not be located during the sampling event.
<0.40 <0.36 <0.74 nd <0.40 <0.40 <0.36 <0.74 nd <0.40
<0.9 <1.0 <1.5 nd <0.9 <1.0 <1.5 nd
--
<3.5 <3.5
Well could not be located during the sampling event. Well could not be located during the sampling event.
Well abandoned during October 2004
<0.9 <1.0 <1.5 nd - <3.5 <0.9 <1.0 <1.5 nd - <3.5
Well could not be located during the sampling event. Well could not be located during the sampling event.
Well scheduled for abandonment, replaced with MW-3R <0.40 <0.36 <0.74 nd <0.40 <0.40 <0.36 <0.74 nd <0.40
280 270 1.380 1.943 411 568 1,810 2,789
<0.43 <0.47 <1.4 nd <0.52 <0.60 <0.58 <1.2 nd <0.66
--
<3.5 <3.5 40 Q
L Samples damaged, unable to analyze
<0.40 <0.36 <0.74 0.2 <0.40 | Well damaged, abandoned April 2005
<0.9 <1.0 <1.5 nd <0.9 <1.0 <1.5 nd <0.43 <0.47 <1.4 nd <0.52 <0.60 <0.58 <1.2 nd <0.66 0.63 Q <0.36 <0.74 1.4 <0.40 <0.40 <0.36 <0.74 nd <0.40 <0.40 <0.36 <0.74 nd <0.40
<3.5 <3.5 <2.7
L ---
Si (O re 1-re < ^ 2 .
40 200
----
46 Z <5.0 6.6
27 Z <5.0
68 Z 5.1
12Z <5.0
__ -
54 Z <5.0
--
--
<5Z <5.0
----
11Z
----
<5Z <5.0 <5,0
1j "5,
(A O
"5 c Q)
a
1.200 6,000
----
---------
8 <15
--24 <15
30 20
--<8 20 --
14 <15 -----
1549GWQualityData 050809 TbI 2 GW PVOC + Cn Page 2 of 3
Table 2 - Groundwater Analytical Results - PVOCs and Cyanide Apr i l 2005 Groundwater Ouality Update -1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS tt: 02-38-000047
Sample Location
Preventive Actio Enforcement Stj
Sample Date
Wisconsin n Limit (PAL) indard (ES)
Petroleum Volatile Organic Compounds (pg/L)
0)
c V N c
<s
hyl
benze
ne
luene
lenes,
Tota
l
tal
BTE
X
meth
ylbenze
ne
2,4
-an
d 1
,3,5
-)
m K X t- ^ Z ,
Cyanide (pg/L)
J£ O
5 5 Groundwater Quality Standards (NR 140, February 2004)
0.5 5
140 200 1,000 ns 96 700 1,000 10,000 ns 480
ns ns
.Q (O re 1 -
re < < o
40 200
PIEZOMETERS P-301
P-302
dup (QA/QC 2)
P-303
P-304
P-305
04/14/94 05/11/94 08/27/02 08/13/03 11/22/04
06/24/96 08/12/96 08/27/02 08/27/02 08/13/03 11/22/04 04/14/05
06/24/96 08/12/96 08/27/02 08/14/03 11/22/04 04/14/05
06/24/96 08/12/96 08/27/02 08/13/03 11/22/04 04/14/05
11/22/04 04/13/05
<0.7 <0.7 <0.48
<0.50 <0.50 <0.48 <0.48 <0.30 <0.14 <0.14
<0.50 <0.50 <0.48 <0.30 <0.14 <0,14
22 2.1
<0.48 <0.30
<0.14
<0.14 <0.14
0.9 33.6 <1.5 35 <0.9 26 <1.5 26 <0.43 <0.47 <1.4 nd <0.52
--
<2.7 Well not sampled - well did not recover after purge
Well abandoned as part of sewer construction during 2004
<1.0 <1.0 <3.0 nd <1.0 <1.0 <3.0 nd
<0.43 <0.47 <1.4 nd <0.52 <0.43 <0.47 <1.4 nd <0.52 <0.60 <0.58 <1.2 nd <0.66 <0.40 <0.36 <0.74 nd <0.40 <0.40 <0.36 <0.74 nd <0.40
<1.0 <1.0 <3.0 nd <1.0 <1.0 <3.0 nd <0.43 <0.47 <1.4 nd <0.52 <0.60 <0.58 <1.2 nd <0,66 <0.40 <0.36 <0.74 nd <0.40 <0.40 <0.36 <0.74 nd <0.40
5.7 1.5 8.3 38 <1.0 <1.0 <3.0 2.1 <0.43 <0.47 <1.4 nd <0.52 <0.60 <0.58 <1.2 nd <0.66
--13
<2.7 L ----16 L
. ---~
7.0 Q L
Insufficient water volume to purge and sample <0.40 <0.36 <0.74 nd <0.40
<0.40 <0.36 <0.74 nd <0.40 <0.40 <0.36 <0.74 nd <0.40
--
---
-----
<5Z <5.0
----
53 Z <5.0
----
-<5Z <5.0
s (A O
0 C 0)
a
1,200 6,000
13 --
---------— -----------
Temporary Monitoring Locations | SB-327
SB-333
SB-338
SB-340
04/01/96
04/01/96
04/02/96
04/02/96
<0.50
<0.50
5,300
650
<1.0 2.8 <3.0 nd
<1.0 <1.0 <3.0 nd
3,900 3,700 <3,000 12,900
1,400 <100 900 2,950
---~
----
----
2/051IPAR/RLH OT5
Notes:
1) 2)
dup : * •
A : D: H : K: L : N : Q ; Z :
n d :
ns :
Not detected. Analysis not performed, standard not established
Concentrations that attain/exceed a PAL are underlined/italicized. Concentrations that attain/exceed an ES are underlined/bold. Field duplicate sample, field identification in parentheses. Laboratory note - precision not within control limits. Laboratory note - Detected in method blank at 0.16 pg/L. Laboratory note - Analyte value from diluted analysis. Laboratory note - Extraction or analysis performed past hold time. Laboratory note - Detection limit may be elevated due to the presence of an unrequested analyte. Cyanide analysis was not performed due to laboratory error. Laboratory note - Spiked sample recovery not within limits. Interference not related to sulfides/aldehydes Laboratory note - Analyte detected between the limit of detection (LOD) and limit of quantitation (LOQ). 11/22/04 available cyanide samples were not field preserved with lead carbonate. Data may be biased
high due to sulfide interference. 1549GWQualityData 050809 K ^ TbI 2 GW PVOC -I- Cn Page 3 of 3 S8?;
Table 3 - Groundwater Analytical Results - Polynuclear Aromatic Hydrocarbons (PAHs) Apri l 2005 Groundwater Quality Update - 1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS #; 02-38-000047
c o '^ re u
3 0) a E re
Prevent ive Ac t i on
En fo rcemen t Stanc
MW-301
MW-302
dup
dup
dup (QA/QC 1)
dup (QC-2)
MW-303
MW-304
dup(QC-l)
dup(OC-l)
MW-305
MW-306
dup(QC-l)
3 re Q 0)
a . E re CO
Limi t (PAL)
Jard (ES)
04/15/94
05/10/94
08/27/02
08/14/03
11/22/04
04/14/94
04/14/94
05/10/94
05/11/94
08/27/02
08/27/02
08/13/03
08/13/03
11/22/04
04/14/05
06/24/96
08/12/96
08/27/02
08/13/03
11/22/04
04/14/05
06/24/96
06/24/96
08/12/96
08/27/02
08/13/03
08/13/03
11/22/04
04/14/05
06/24/96
08/12/96
08/27/02
08/14/03
11/22/04
04/14/05
06/24/96
08/13/96
08/27/02
08/14/03
11/22/04
11/22/04
04/13/05
Po lynuc lea r A roma t i c Hyd roca rbon (pg/L)
a c
lU
Q. re c 0) o < ns
ns
<7.26
<0.66
240
1 ,300*
<7.26
<7.26
<0.66
<0.66
2.4
1.9
0 . 8 7 *
1 .4*
5.3 Q
0.40 0
<1.0
<1.0
<0.053
0.11
0.46
0.26
<1.0
<1.0
20
13
3.1
2.8 Q,*
<1.9
<0.019
<1.0
<1.0
<0.053
<0.036*
<0.019
<0.019
<1.0
<1.0
<0.053
0 . 1 7 *
0.18
0.080
0.67 E
0) c 0) >. .c
a re (U u
<
ns
ns
<17.6
<1.60
340
2,900 *
<17.6
<17.6
<1.60
<1.60
1.4
<0.16
0.51 *
0.61 *
27
1 .2Q
<2.0
<2.0
<0.16
0.025 Q
0.060 Q
0.068
<2.0
<2.0
61
9.9
2.2
<1.9*
<1.9
<0.019
<2.0
<2.0
<0.16
0 . 4 2 *
<0.019
0.35
<2.0
<2.0
<0.16
0.055 Q,*
<0.019
<0.019
0.082
c V u 5 .c c
<
600
3,000
26
13
240
1.700
17
15
23
<0.05
29
19
0.56
0 . 4 9 *
45
0.96 Q
<0.20
<0.20
0.19
<0.021
<0.018
<0.018
2.8
3
1.4
2.5
<0.40
<2.0
<1.8
0.027 Q
0.33
<0.20
<0 .024 .
0.12 Q
<0.018
0.098
<0.20
<0.20
<0.024
<0.020
<0.018
<0.018
0.022 Q
(U c (U
m 01
ns
ns
8.5
1.28
220
1,300
2.7
1.6
1.83
<0.04
53
28
1.0
0.98
70
2.5
<0.050
<0.050
0.80
0.035 Q
<0.020
<0.020
0.14
0.21
0.65
16
0.53 Q
<1.2
<2.0
0.020 Q
0.71
0.31
<0.030
0.23
<0.020
0.24
0.05
0.05
<0.030
<0.012
<0.020
<0.020
<0.020
0)
c
o
N C m
0.02
0.2
7.6
1.69
34
1.100
2.6
1.1
1.75
<0.05
54
27
1.1
1.0
80
M <0.024
<0.024
0.59
0.045 Q
<0.018
<0.018
<0.024
0.18
0.65
3.1
0.54 Q
<1.4
<1.8
0.023 Q
0.26
0.14
0.21
0.20
<0.018
0.20
<0.024
<0.024
<0.022
<0.014
<0.018
<0.018
<0.018
(1) c (U
f l c o
0.02
0.2
3.6
0.51
80
720
<0.88
<0.88
0.61
<0.08
55
25
0.78
0.70
45
Z 3
<0.050
<0.050
1.0
0.051
<0.018
<0.018
0.05
0.05
2.2
3.9
0.46 Q
<1.3
<1.8
0.036 Q
0.15
0.08
0.26
0.26
<0.018
0.24
0.05
0.05
<0.036
<0.013
<0.018
<0.018
<0.018
Is O 0)
ffl a.
ns
ns
<0.77
<0.07
44
560
<0.77
<0.77
<0.07
<0.07
30
19
0.61
0.56
4 2 *
2.0
<0.20
<0.20
0.54
0.039 Q
<0 .021*
<0.021
<0.20
<0.20
0.54
2.4
0.35 Q
<1.6
< 2 . r
0.026 Q
0.41
<0.20
0.36
0.28
<0 .021*
0.24
<0.20
<0.20
<0.087
<0.016
<0 .021*
<0.021
<0.021
o c 01
2-5
1 = CD m
o c a> (A
>.
O
c c re 0)
• re
0) c 0) £ c re o 3 Li.
c o o 3
W i s c o n s i n G r o u n d w a t e r Qual i ty S tanda rds (NR
ns
ns
2.9
0.43
69
780
1
0.5
0.47
<0.04
22
12
0.72
0.65
4 7 *
1.9
<0.050
<0.050
0.42
0.039 Q
<0.019*
<0.019
0.05
<0.050
0.12
0.67
0.41 Q
<1.9
<1.9*
0.028 Q
0.3
0.07
0.37
0.21
<0.019*
0.21
0.05
0.05
<0.067
<0.019
<0.019*
<0.019
<0.019
0.02
0.2
4.5
0.84
47
1,200
ns
ns
~ ~ 25
180 Q
80
400
<0.28
<0.28
130
3,400
Wel l abandoned February 2004
1.4
0.8
1.4
<0.05
45
22
0.83
0.83
59
1.9
<0.10
<0.10
0.96
0.043 Q
<0.016
<0.016
<0.10
<0.10
0.28
2.8
0.51 Q
<1.4
<1.6
0.025 Q
0.32
0.18
<0.022
0.23
<0.016
0.21
<0.10
<0.10
<0.022
<0.014
<0.016
<0.016
<0.017
~ -~ ~
8.1
3.9
0 .17Q
0 .16Q
13 Q , *
0.62 Q
--
0.12
<0.017
<0.022*
<0.022
---
0.59
<0.32
<1.6
<2.2*
<0.022
--
0.080 Q
0.071 Q
<0.022*
0.071 Q
-..
<0.036
<0.016
<0.022*
<0.022
<0.022
<3.08
<3.08
<0.28
<0.28
73
37
1.4
1.4
1 1 0 D
3.5
<0.20
<0.20
1.9
0 .10&
0.032 Q
0.017 Q
3.0
2.5
3.0
6.9
1.4&
<1.3
<1.7
0.041 Q
0.62
<0.20
<0.053
0.25
0.018 Q
0.21
<0.20
<0.20
<0.053
0.036 Q
0.035 Q
0.037 Q
0.12
80
400
74
43
390
2,100 *
62
55
46
<0.11
5.4
5.9
0.18 Q,*
0 .35 *
4.9 Q
<0.44
<0.40
<0.40
<0.025
<0.018
<0.022
<0.022
29
23
9.1
4.3
0.60 Q
<1.7*
<2.2
<0.022
<0,40
<0.40
<0.025
<0.034*
<0.22
<0.022
<0.40
<0.40
<0.025
0.099 *
0.031 Q
<0,022
0.17
c >. 4) a.
.E u
a c V re
a re Z
140, February 2004)
ns
ns
4.4
0.66
70
500
1.4
<0.88
0.58
<0.08
41
20
0.54
0.51
3 9 *
1.8
<0.10
<0.10
0.64
0,033 Q
<0.017*
<0.017
<0.10
<0.10
0.49
6.1
<0.42
<2.1
<1.7*
0.021 Q
0.29
<0.10
0.34
0.21
<0.17*
0.19
<0.10
<0.10
<0.030
<0.021
<0.017*
<0,017
<0.017
8
40
3,520
2,240
4,300
18,000 D,*
2,500
1,770
2,520
<1.10
11
6.6
0.60
0 . 8 5 *
13 O
<0,45
<1.0
<1.0
<0.067
0.039 Q
0.032 Q
0.18
310
230
120
190
100 D
81 D,*
2 7
0.060 Q
<1.0
<1.0
<0.067
0.11 Q,*
<0.022
0.098
<1.0
7.9
<0.067
600 D.*
0.37
0.11
410 D
c
£ c re c 0) .c a.
ns
ns
135
11
720
6,000 D
117
108
31
0.15
16
13
0.27
0.32
22
1 .2Q
<0.40
<0.40
0.76
0.030 Q
<0.020
<0,020
9
11
5.0
4.4
0.72 Q
<1.6
<2.0
<0.020
<0.40
<0.40
<0.036
0.11
<0.020
0.10
<0.40
<0.40
<0.036
0.077
<0.020
<0.020
0.050 Q
0) c 0)
a.
50
250
<0.33
<0.03
320
2,900
<0.33
<0.33
<0.03
<0.03
56
28
1.2
1.2
78
3.0
<0.20
<0.20
1.4
0.091 &
0.035 Q
0.020 Q
1.1
0.69
1.4
4.5
1.2&
<1.7
<1.6
0.031 Q
1.5
<0.20
<0.13
0.35
<0.016
0.32
<0.20
<0.20
<0.13
0.067
0.24
0.24
0.23
0) c 0)
t l 1 re
1 - c
ns
ns
<1.20
-520
4,100 D,Q,*
<1.20
<1.20
--
0.84
<0.095
0 . 4 7 *
0 . 6 6 *
<4.0
<0.40
<1.0
<1.0
<0.095
<0.019
<0.020
0.063 Q
35
19
<1.0
18
7.0
6 , 4 *
2.5 Q
0.12
<1.0
<1.0
<0.095
<0.036*
<0.020
0.025 Q
<1.0
<1.0
<0.095
6.7 D,Q,*
1 .8D
0.54 D
7.4 E
0) c 0)
It ^ re CM c
ns
ns
<0.21
-770
5,600 D,*
<0.21
<0.21
-3.5
<0.096
<0.068*
0.079 Q,*
<4.5
<0.45
<1.0
<1,0
<0.096
<0.018
<0.023
0.058 Q
12
14
<1.0
6.5
2.2
2.2 Q,*
<2.3
<0.023
<1.0
<1.0
<0.096
0.043 Q,*
<0.023
0.036 Q
<1.0
<1.0
<0.096
<3.4 D*
<0.023
<0.023
0.46
(fl X < Q.
2 o 1-
ns
ns
3,787
2,312
8,559
54,340
2,705
1,952
2,627
0.15
507
268
12
13
590
26
nd
nd
9.3
0.7
0.6
0.7
402
304
226
296
121
92
30
0.5
4.9
0.8
1.6
3.1
0.02
2.8
0.2
8,1
nd
: 607
: 2.7
! 1.0
i 419
0) 3
t o re V cn 1-
bailer
bailer
bailer
bailer
-bailer
bailer
bailer
bailer
bailer
bailer
low f low
low f low
low f low
low f low
bailer
bailer
bailer
low f low
low f low
low f low
bailer
bailer
bailer
bailer
low f low
low f low
low f low
low f low
bailer
bailer
bailer
low f low
low f low
low f low
bailer
bailer
bailer
low f low
low f low
low f low
low f low
m 'c 0) E E o XJ 0)
i l 1
--
MGP type odor, sheen, black
MGP type odor, emulsif ied tar
-
----
---
insufficient well volume for complete purge
-
-
---
---
slight MGP type odor
--
well parameters did not stabi l ize
---
insufficient well volume for complete purge
-insufficient well volume for complete purge
--
slight MGP type odor
MGP type odor
-- •
insufficient well volume for complete purge
1549GWQualityData 050809 TbI 3 - GW PAH Page 1 of 3
Table 3 - Groundwater Analytical Results - Polynuclear Aromatic Hydrocarbons (PAHs) Apri l 2005 Groundwater Quality Update - 1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS It: 02-38-000047
o TO U
0) a. B re t n
£ re Q o o . E re
CO
Prevent ive A c t i o n L im i t (PAL)
En fo rcemen t S t a n d a r d (ES)
IVIW-307
MW-307R
dup(QC- l )
MW-308
MW-310
MW-311
MW-1
MW-2
MW-3
MW-3R
MW-4
dup (QC-2)
06/24/96
08/13/96
08/27/02
08/14/03
11/22/04
04/13/05
04/13/05
11/22/04
04/13/05
11/22/04
04/13/05
11/22/04
04/13/05
04/13/94
05/10/94
08/27/02
08/13/03
11/22/04
04/13/05
04/14/94
05/11/94
08/27/02
08/13/03
11/22/04
04/14/94
05/11/94
08/27/02
08/13/03
11/22/04
11/22/04
04/14/05
04/14/94
05/11/94
08/27/02
08/14/03
11/22/04
11/22/04
04/14/05
P o l y n u c l e a r A romat i c Hyd roca rbon (pg/L)
0) c 0)
o. re c 0) u
<
ns
ns
<1.0
<1.0
<0 .053
0.038 Q,*
7.4 D
3.4
5.5
11
19
5.2 D
5.3
< 2 4 0 D
170 D,Q
<0.66
<0.66
0.022 Q
0.042 0
<0.66
<0.66
<0.66
<0.66
1 4 D
<0.019
<0.66
<0.66
<0.053
<0.018*
<0 .019
a> c (U
>. .c Q. re c 0) o
<
ns
ns
<2.0
<2.0
<0.16
<0.019
0.25
<0.20
<0.39
3.6 Q
2.3 Q
0.067
<0.39
3.7 Q
4.6 Q
<1.60
<1.60
<0.019
<0.020
<1.60
<1.60
<1.60
<1.60
0.28
<0.019
<1.60
<1.60
<0.16
<0.019*
<0.019
u c 0) o re
<
600 •
3.000
0.39
<0.20
0.23
<0.020
1.0 D,Q
0.55 Q
1.2
1.8 Q
2.0 Q
0.70 D,Q
1.3
9.9
15 •
<0.05
<0.05
<0.018
<0.018
<0.05
<0.05
<0.05
<0.05
0.15
0.018 Q
0.06
<0.05
<0.024
<0.020
<0.018
c
ns
ns
0.15
<0.050
<0.030
<0.012
0.50 0 , 0
<0.20
<0.39
<2.0
<2.0
0.051 Q
<0.40
<2.0
<3,9
<0.04
<0.04
<0.020
<0.020
<0.04
<0.04
0.21
<0.04
<0.020
<0.020
<0.04
<0.04
<0.030
<0.012
<0.020
0) c <u i ->. a. S-"o" N C <u m
0.02
0.2
<0.024
<0.024
0.15
<0.014
0.31
<0.18
<0.36
<1.8
<1.8
<0.018
<0.37
<1.8
<3.6
<0.05
<0.05
<0.018
<0.018
<0.05
<0.05
<0.05
<0.05
<0.018
<0.018
<0.05
<0.05
<0.022
<0.014
<0.018
0)
f l c o
0.02
0.2
<0.050
<0.050
0.24
0.015 Q
0.180 Q
<0.18
<0.36
<1.8
<1.8
<0.018
<0.36
<1.8
<3.6
<0.08
<0.08
<0.018
<0.018
<0.08
<0.08
0.18
<0.08
<0.018
<0,018
<0.08
<0.08
<0.036
<0.013
<0.018
Benzp
(ghi)
pery
lene
Ben
zo(l<
) flu
ora
nth
ene
Ch
ryse
ne
Dib
enz(
ah)
an
thra
cen
e
Flu
ora
nth
ene
Flu
ore
ne
W i s c o n s i n G roundwa te r Qual i ty S tanda rds (NR
ns ns 0.02 ns 80 80
ns ns 0.2 ns 400 400
c ><
0) a
It
0) c: 3 re
Q. re Z
140, February 2004)
ns
ns
<0.20 <0.050 <0.10 - 0.31 <0.40 <0.10
<0.20 <0.050 <0.10 - <0.20 <0.40 <0.10
<0.087 <0.067 0.31 <0.036 0.37 <0.025 <0.030
0.017 Q <0.019 <0.014 <0.016 0.029 Q <0.017* <0.021
Wel l abandoned during October 2004, replaced with MW-307R
0.15* 0.17* 0.34 0.053 Q,* 1.8 D 2.5 D
<0.21 <0.19 <0.17 <0.22 0.53 0 0.90
<0.41 <0.39 <0.33 <0.44 0.56 Q 1.2 O
<2 .1 * <1.9* <1.6 <2.2* <1.6 <2.2
<2.1 <2.0 <1.7 <2.2 <1.7 <2.2
<0.021* <0 .019 ' 0.035 Q <0.022* 0.37 1.9 D
<0.42 <0.39 <0.33 <0.44 0.41 0 1.6
< 2 . 1 * <1.9* <1.6 <2.2* 3.9 0 36
<4.1 <3.9 <3.3 <4.4 3.8 37
<0.07 <0.04 <0.05 - <0.28 <0.11
<0.07 <0.04 <0.05 - <0.28 <0.11
Wel l could not be located during the sampling event.
Wel l could not be located during the sampling event.
<0.021* <0.019* <0.016 <0.022* <0.016 <0.022
<0.021 <0.020 <0.017 <0.022 <0.017 <0.022
0.14*
<0.17
<0.34
<1.7*
<1.7
<0.017*
<0.34
<1,7*
<3.4
<0.08
<0.08
<0.017*
<0.017
<0.07 <0.04 <0.05 - <0.28 <0.11 <0.08
<0.07 <0.04 <0.05 - <0.28 <0.11 <0.08
Wel l could not be located during the sampling event.
Wel l could not be located during the sampling event.
Wel l abandoned October 2004 - Replacement is not Planned
<0.07 <0.04 <0.05 - <0.28 0.61
<0.07 <0.04 <0.05 - <0.28 0.27
Wel l could not be located during the sampling event.
Wel l cou ld not be located during the sampling event.
Well scheduled for abandonment, replaced with MW-3R
<0.021* <0.019* <0.016 <0.022* 0.15 2.4 D,Q
<0.021 <0.019 <0.016 <0.022 <0.016 <0.022
<0.07 <0.04 <0.05 ~ <0.28 <0.11
<0.07 <0.04 <0.05 ~ <0.28 <0.11
<0.087 <0.067 <0.022 <0.036 <0.053 <0.025
<0.016 <0.019 <0.014 <0.016 <0.013 <0.017*
Samples damaged, unable to analyze
<0.021 <0.019 <0.016 <0.022 <0.016 <0.022
Wel l damaged, abandoned April 2005
<0.08
<0.08
<0.017*
<0.017
<0.08
<0.08
<0.030
<0.021
<0.017
8
40
<1.0
<1.0
<0.067
0.033 0
3.2 D
0.48 0
0.55 0
<2.2
1 2
5.4 D
3.7
3,200 D
2,000 D
<1.10
<1.10
0.14
0.055 0
3.34
1.75
2.52
0.29
<1.1 D
<0.022
393
147
0.96
0.026 Q,*
0.026 0
o c Si c re c <u . c a .
ns
ns
<0.40
<0.40
0.26
0.017 O
4.8 D
1.1
2.1
11
3.7 0
3.0
2.8
32
33
<0.15
<0.15
<0.020
<0.021
<0.15
<0.15
0.69
<0.15
0.049 0
<0.020
<0.15
<0.15
<0.036
<0.016
<0.020
0) c Si >.
Q .
50
250
0.38
<0.2P
0.37 0
0.028 0
1.6 D
0.51
0.59 0
<1.6
<1.7
0.39
0.46 0
3.7 0
5.1 O
<0.03
<0.03
<0.016
<0.017
<0.03
<0.03
<0.03
<0.03
0.093
<0.016
<0.03
<0.03
<0.13
<0.017
<0.016
0) c u
^ ^ S °-, re 1 - c
ns
ns
<1.0
<1.0
<0.095
<0.018*
6.0 D
2.1
3.0
1.8 21
4.4 D
3.4
350 D ,0
170 D,Q
<1.20
<1.2
<0.020
<0.020
<1.20
2.63
0,18
<0.020
<1.20
<0.095
<0.018*
<0.020
o c 0)
>> re
1 re
CM c ns
ns
<1.0
<1.0
<0.096
<0.017*
0.84 D,0
<0,23
<0.45
<2.3
<2.3
1.3 D,Q
<0.46
330 D,Q
240 E
<0,21
<1.2
<0.023
<0.023
<0.21
<0.21
0.051 0
<0.023
<0,21
<0.096
<0.017*
<0.023
(A X < Q .
1 ns
ns
1.2
nd
1.9
0.2
31
10
15
45
60
23
19
3,969
2,679
nd
nd
0.2
0.1
3.3
1.8
6.8
0.6
17
0.02
393
147
1.0
0.03
0.03
OJ 3
9) . ?
fc O re IB If) \ -
c
£ E o o •o a i l
1
bailer
bailer
bailer
low f low
bailer
low f low
low f low
low f low
low f low
low f low
low f low
bailer
low f low
bailer
bailer
low f low
low f low
bailer
bailer
bailer
bailer
low f low
low f low
bailer
bailer
bailer
low f low
low f low
low f low
gray/black, organic odor
insufficient well volume for comple te purge
-
-
;
-
-
:
slight MGP type odor
1549GWQualityData 050809 TbI 3 - GW PAH Page 2 of 3
Table 3 - Groundwater Analytical Results - Polynuclear Aromatic Hydrocarbons (PAHs) Apr i l 2005 Groundwater Ouality Update -1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS #; 02-38-000047
c _o re
0) Q-E re O)
Preventive Action Enforcement Stanc
MW-5
dup (QC-2)
i i
V Q. E re
Limit (PAL) Jard (ES)
04/14/94 05/11/94 08/27/02 08/14/03 11/22/04 04/14/05 04/14/05
Polynuclear Aromatic Hydrocarbon (pg/L) I
0) c «
Q. re c 0) u <
ns ns
<0.66 <0.66
<0.053
0.060 0 <0.019 <0.019
0) c Q)
a. re c 0) u < ns ns
<1.60 <1.60 <0.16
<0.019 <0.019 <0.019
«> c 0) o E .n c <
600 3,000
<0.05 <0.05 0.22
<0.018 <0.018 <0.018
V
Si ns ns
<0.04 0.06
<0.030
<0.020 <0.020 <0.020
0) c o >. Q. "re" o N C 0)
CQ
0.02 0.2
<0.05 <0.05 0.69
<0.018 <0.018 <0.018
0) c 0)
S B N £ c o m ;?
0.02 0.2
<0.08 <0.08 0.50
Is O V
CQ Q.
ns ns
<0.07 <0.07 0.31
Ben
zo(k
) flu
oran
then
e
Chr
ysen
e
Dib
enz(
ah)
anth
race
ne
Flu
oran
then
e
Flu
oren
e
Wisconsin Groundwater Quality Standards (NR ns 0.02 ns 80 80 ns 0.2 ns 400 400
<0.04 <0.05 ~ <0.28 <0.11 <0.04 <0.05 ~ <0.28 <0.11 0.45 0.54 0.070 0 0.92 <0.025
CO CV4 <U
« a
0) c re
.c o. re z
140, February 2004)
ns ns
<0.08 <0.08 0.35
Sample bottle broken in transit to laboratory, analysis could not be performed <0.018 <0.018 <0.018
0.022 0 <0.021 <0.021
0.022 O 0.025 Q <0.022 <0.016 <0.022 <0.019 <0.016 <0.022 <0.016 <0.022 <0.019 <0.016 <0.022 <0.016 <0.022
<0.017 <0.017 <0.017
8 40
<1.10 <1.10
3.9
1.4 D <0.022 0.034 O
c u .c c re c 0) .c a.
ns ns
<0.15 <0.15 0.55
0.027 0 <0.020 <0.020
c
0)
Q.
50 250
<0.03 0.18 0.71
<0.016 <0.016 <0.016
0) c «
, re 1 - c
ns ns
<1.20 —
0.32
0.087 <0.020 <0.020
0) c «
>. re
.c £ o .c S °-. re
CM c
ns ns
<0.21 -
0.56
0.085 <0.023 <0.023
lA X < Q.
"re
1°
ns ns
nd 0.2 10
1.7 nd
0.03
3
c o re 0) in 1-
bailer bailer bailer
-bailer
low flow low flow
O E E o
0)
i l 1
---
insufficient well volume for complete purge --
PIEZOMETERS | P-301
P-302
dup (QA/QC 2)
P-303
P-304
P-305
04/14/94 05/11/94 08/27/02 08/13/03 11/22/04
06/24/96 08/12/96 08/27/02 08/27/02 08/13/03 11/22/04 04/14/05
06/24/96 08/12/96 08/27/02 08/14/03 11/22/04 04/14/05
06/24/96 08/12/96 08/27/02 08/13/03 11/22/04 04/14/05
11/22/04
04/13/05
<0.66 -
<0.053
<1.0 • <1.0 <0.053 <0.053 <0.018* <0.019 <0.019
-<1.0
<0.053 <0.018* <0.019 <0.019
-<1.0
<0,053
<0.15
0.051 0
<0.019
<1.60 -
<0.16
<2.0 <2.0
<0.16 <0.16
<0.019* <0.019 <0.019
-<2.0 <0.16
0.024 O* 0.027 0 <0.019
-<2.0 <0.16
<0.15
<0.019
<0.019
0.49 -
0.18
<0.20 <0.20 <0.024 <0.024 <0.020 <0.018 <0.018
-<0.20
<0.024 <0.020 <0.018 <0.018
-<0.20
<0.024
<0.13
<0.018
<0.018
0.08 —
0.21
0.1 <0.050 <0.030 <0.030 0.022 O <0.020 <0.020
— <0.050
0.18 0.048
0.050 Q <0.020
-<0.050 <0.030
<0.15
<0.020
<0.020
<0.05 -
<0.022
<0.024 <0.024 <0.022 <0.022 0.030 Q <0.018 <0,018
-<0.024 <0.022 0.042 Q 0.041 Q <0.018
--<0.024 <0.022
<0.14
<0.018
<0.018
<0.08 -
<0.036
<0.050 <0.050 <0.036
0.20 0.036 Q <0.018 <0.018
-<0.050 <0.036 0.032 Q 0.026 Q <0.018
-<0.050 <0.036
<0.07 -
<0.087
<0.04 <0.05 - <0.28 0.62 ..
<0.067 0.090 <0.036 <0.053 <0.025 Well not sampled - well did not recover after purge
<0.08 -
<0.030
Well abandoned as part of sewer construction during 2004
<0.20 <0.20
<0.087 <0.087 0.058
<0.021 <0.021
-<0.20 <0.087 0.025 0 0.023 O <0.021
-<0.20
<0.087 Not sampled
<0.14
<0.018
<0.018
<0.16
<0.021
<0.021
<0.050 <0.10 - <0.20 <0.40 <0.050 <0.10 - <0.20 <0.40 <0.067 <0.022 <0.036 <0.053 <0.025 <0.067 <0.022 <0.036 <0.053 <0.025 0.025 0 0.021 Q 0.047 0 0.020 0 <0.017* <0.019 <0.016 <0.022 <0.016 <0022 <0.019 <0.016 <0.022 <0.016 <0.022
.. <0.050 <0.10 - <0.20 <0.40 <0.067 0.12 <0.036 <0,053 <0.025 0.027 Q 0.033 Q <0.016 0.059 <0.017* 0.030 0 0.039 Q <0.022 0.071 <0.022 <0.019 <0.016 <0.022 0.027 0 <0.022
-<0.050 <0.10 - <0.20 <0.40 <0.067 <0.022 <0.036 <0,053 <0.025
<0.10 <0.10
<0.030 <0.030 0.054 0 <0.017 <0.017
-<0.10
<0.030 0.022 0 0.019 Q <0.017
-<0.10
<0.030 Well did not recover sufficiently after purge for analysis of PAHs
Insufficient water volume to purge and sample <0.15 <0.12 <0.17 <0.12 <0.16
<0.019 <0.016 <0.022 <0.016 <0.022
<0.019 <0.016 <0.022 0.018 0 <0.022
<0.13
<0.017
<0.017
<1.10 -
2.7
<1.0 <1.0
<0.067 0.18 0 0.43* <0.022 <0.022
-<1.0
<0.067 <0.024 <0.022 <0.022
<1.0 <0.067
<0.17
0.025 0
0.026 0
<0.15 -
0.46
<0.40 <0.40
<0.036 <0.036 <0.016 <0.020 <0.020
-<0.40
<0.036 0.034 Q 0.044 0 <0.020
-<0.40
<0.036
<0.15
<0.020
<0.020
<0.03 -
<0.13
<0.20 <0.20 <0.13 <0.13
0.020 0 <0.016 <0.016
-<0.20 <0.13 0.065* 0.067
0.027 0
-<0.20 <0.13
<0.12
<0.016
<0.016
<1.20 -
<0.095
<1.0 <1.0
<0.095 <0.095 <0.018* <0.020 <0.020
-<1.0
<0.095 <0.018* <0.020 <0.020
-<1.0
<0.095
<0.15
<0.020
<0.020
<0.21 -
<0.096
<1.0 <1.0
<0.096 <0.096 <0.017* <0.023 <0.023
-<1.0
<0.096 <0.017* <0.023 <0.023
-<1.0
<0.096
<0.17
<0.023
<0.023
1.2 -
3.6
nd nd nd 0.2 0.8 nd nd
-nd nd 0.4 0.4 0.05
--nd nd
nd
0.1
0.04
bailer bailer bailer
--
bailer bailer bailer bailer
low flow low flow low flow
bailer bailer bailer bailer bailer bailer
bailer bailer bailer bailer bailer bailer
low flow
low flow
1
--
----
insufficient well volume for complete purge --
---
insufficient well volume for complete purge insufficient well volume for complete purge insufficient well volume for complete purge
--
slight MGP type odor --
insufficient well volume for complete purge
-
-
|U -JTB /GHL08 /021 |U-RJC/JTB12 /021 (U-PAR/JTB 9 /0311U-MJR/JTB 2/0511PAR/RLH 5/05]
Notes: 1) Concentrations that attain/exceed a PAL are underlined/italicized. 2) Concentrations that attain/exceed an ES are underlined/bold,
nd : Not detected. ns : Standard has not been established. ~ : Analysis not performed.
dup : Field duplicate sample, field identification in parentheses. - : Not recorded.
< : Constituent was not identified above the limit of detection indicated. D : Laboratory note - Analyte value from diluted analysis. E : Laboratory note - Analyte value exceeds calibration range. Q : Laboratory note - The analyte has been detected between the limit of detection (LOD) and limit of quantitation (LOO). & : Laboratory note-Laboratory Control Spike recovery not within control limits. * : Laboratory note-precision not within control limits.
1549GWOualityData 050809 TbI 3 - GW PAH Page 3 of 3
Table 4 - Groundwater Analytical Results - RNA Parameters Apr i l 2005 Groundwater Ouality Update -1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS #; 02-38-000047
S a m p l e L o c a t i o n Sam
ple
Dat
e
L a b o r a t o r y Pa rame te rs (mg/L)
•D 0) > o in in
5 c o
c "> re .i2 E D
(A
< o
CM O z
• I -CO O z c 0) O) o z
c re 3
re I S 3 in
W i s c o n s i n G r o u n d w a t e r Qua l i t y S t a n d a r d s (NR 140
P r e v e n t i v e A c t i o n L im i t (PAL)
E n f o r c e m e n t S t a n d a r d (ES)
MW-302
MW-303
MW-304
MW-305
MW-306
d u p ( Q C - l )
MW-307R
d u p ( Q C - l )
MW-308
MW-310
MW-311
MW-1
MW-3R
MW-4
d u p ( Q C - 1 )
MW-5
dup (QC-2)
11/22/04
04/14/05
11/22/04
04/14/05
11/22/04
04/14/05
11/22/04
04/14/05
11/22/04
11/22/04
04/13/05
11/22/04
04/13/05
04/13/05
11/22/04
04/13/05
11/22/04
04/13/05
11/22/04
04/13/05
11/22/04
04/13/05
11/22/04
04/14/05
11/22/04
11/22/04
04/14/05
11/22/04
04/14/05
04/14/05
0.15 0.3
0.92
1.1
8.9
0.19
0.28
0.026
0.061
15
4.5
20
28
0.71
0.35
28
21
1.2
2.7
11 12
1 1 <0.017
M
0.018
<0.017
0.025
0.05
0.13
0.16
1.3
0.92
0.25
0.32
0.00045
0.0081
0.39
0.39
0.65
2J
1.5
1.5
2.2
1.5
3
2.7
0.81
1.3
1.2
0.021
0.68
0.48
0.42
140
700
2 5 0
3 8 0
600
4 0 0
2 2 0
490
2 7 0
2 6 0
350
350
380
6 5 0
710
590
540
400
370
1,100
690
590
5 4 0
850
4 0 0
410
2 7 0
3 0 0
2
10
<0.063
<0.061
<0.063
0.43
0.064 0
0.58
4.3
6.6
<0.063
<0.063
<0.061
<0.063
<0.061
<0.063 <0.061
<0.063 <0.061
<0.063
<0.061
<0.063 <0.061
0.80
0 4
ns
ns
0.22
0.04
0.85
0.48
0.033
<0.01
<0.01
<0.01
0.043
0.05
0.11
4.1
4.2
2.1
0.66
0.17
0.034
1.3
1.2
3.2
5.3
0.035 <0.01
125 250
52
160
24
67
490
630
34
47
9.8
9.7
100
5.3
12
25
14
49
32
13
28
5.0
20
290
280
Samples damaged,
<0.063 <0.01 93
Wel l damaged, aban
2 .7
Z 9
<0.01
<0.01
66
38
F ie ld Pa rame te rs
3
X a.
B, °
o 3
, February 2004)
ns ns
ns
ns
o o
O 3
1 .
a E
ns
ns
c: O) >> X O T3 C _>
o S
ns ns
E.
X 0)
ns
ns
insufficient well vo lume for readings
6.73 2.22 7.58 0.87 427
7.31
7.21
8.00
7,14
7.9 7.24
7.52
7.43
8.1
7.05
8.05
6.-97
7.23
6.88
7.18
7.17
7.27
7.07
7.61
7.01
1.766
1.48
1.425
1.92
1.400
2.17
0.615
0.911
1.313
1.39
2.1
2.01
1.237
0.98
1.984
2.12
2.870
2.390
1.960
1.260
jnab le to analyze
7.85 1.73
doned April 2005
7.76
7.10
1.439
1.54
13.18
9.13
13.53
5.98
12.98
8.73
10.77
6.2
12.7
6.23
11.8
11.56
12.94
8.02
12.11
6.82
10.31
4.82
13.96
7.90
10.16
11.67
9.86
1.48
0.29
1.39
1.16
5.99
2.27
1.45
0.70
0.40
0.56
0.64
0.45
1.2
0.64
1.08
0.96
0.76
1.77
6.88
2.83
0,84
0.70
93,5
160
72.9
430
360
425
104.5
320
220
219
250
265
63.2
224
167.5
337
284
244
385
395
420
168.1
423
P IEZOMETERS |
P-302
P-303
P-304
P-305
11/22/04
04/14/05
11/22/04
04/14/05
11/22/04
04/14/05
11/22/04
6.6
6 ^
0.04 0
0.033 0
4.7
0.23
0.23
0.0038 0.034
1.7
2 6 0
250
2 0 0
190
0.063 0
<0.061
0.26
0 . 1 8 Q
<0.01
0.017
<0.01
<0.01
30
30
670
680
Insufficient water volume
Insufficient water volume
720 0.22 0.038 76
8.22
7.28
--
to purge
to purge
7.42
0.970
1.09
::
12.00
10.18
-and sample
and sample
1.99 12.78
0.68
0.30
-
3.60
238
80
""
366
1549GWQualityDala 050809 TbI 4 - RNA Page 1 of 2
Table 4 - Groundwater Analytical Results - RNA Parameters A p r i l 2 0 0 5 G r o u n d w a t e r Oua l i t y Upda te - 1603 E l y St reet , Mar ine t te , W i s c o n s i n
W i s c o n s i n Pub l i c Se rv i ce C o r p o r a t i o n • F o r m e r M a r i n e t t e M a n u f a c t u r e d G a s P lant S i te
B R R T S #; 02-38-000047
S a m p l e Loca t i on
s 0) a. E re
CO
L a b o r a t o r y Pa ramete rs (mg/L)
0)
> o (A 0)
5 C o
Man
gane
se,
Dis
solv
ed
Alk
alin
ity (
as
CaC
03)
Nitr
ogen
, N
03 -i
N02
Met
hane
Sul
fate
W i s c o n s i n G r o u n d w a t e r Qua l i t y S tanda rds (NR 140
P reven t i ve Ac t i on L im i t (PAL)
E n f o r c e m e n t S t a n d a r d (ES)
04/13/05
0.15 0.3
6 ^
0.025 140 2 ns 125 0.05 700 10 ns 250
1.8 690 0,11 0 0.054 150
Field Pa ramete rs |
3 J2-X a
li = E o 3
, F e b r u a r y ^ 2 0 0 ^
ns ns
6.71
ns
ns
1.46
o o
s; 3
£ Q. E 0)
1-
ns
ns
9.36
c o ai >. O •o >
§ 1 5 S
ns ns
0.82
>" E,
I
ns
ns
323
IJTB/PAR 2;05)|PAFVRLH 5/05)
Notes :
1) 2)
R N A : ns :
p m h o s / c m
d u p :
Concentrat ions that attain/exceed a PAL are underlined/italicized.
Concentrat ions that attain/exceed an ES are unde r l i ned /bo ld .
Remedial Natural Attenuat ion.
Standard has not been establ ished.
Analysis not performed.
I^icromhos per centimeter.
Field duplicate sample, f ield identif ication in parentheses.
°C : Degrees Celsius.
mV : Millivolts.
s . u . : Standard units.
Q : Laboratory note - Analyte detected between the limit of detection (LOD) and limit of quantitation (LOO).
1549GWQualityData 050809 TbI 4 - RNA Page 2 of 2
APPENDIX A
SOIL BORING LOG INFORMATION, MONITORING WELL CONSTRUCTION, MONITORING WELL
DEVELOPMENT, AND BOREHOLE ABANDONMENT FORMS
State ofWisconsin Department of Natural Resources
W E L L / D R I L L H O L E / B O R E H O L E A B A N D O N M E N T Form 3300-5 2/2000 Page 1 of 2
Nodce: Please complete Form 3300-5 and return it to the appropriate DNR office anci bureau. Completion of this report is required by chs. 160, 281, 283,289, 291. 292, 293, 295. and 299, Wis. Stats., and ch. NR 141, Wis. Adm. Code. In accordance with chs. 281. 289, 291, 292, 293,295, and 299. Wis. Stats., failure to file this form may result in a forfeiture of between $10 and $25,000, or imprisonment for up to one year, depending on the program and conduct involved. Personally identifiable infonnation on this form is not intended to be used for any other purpose. NOTE: See the instructions for more infomiation.
Route to:l I Drinking Water I I Waiershed/Wastewater I I Waste Management I 1 Remediation/RedevelopmentI 1 Other
(1) G E N E R A L I N F O R M A T I O N i (2) F A C I L I T Y / O W N E R I N F O R M A T I O N Wl Unique Well No. DNR Well ID No. County Facility Name
Former Marinette M G P Site (1549)
Common Well Name. M W - 2
1/4 of Grid Location
)/4ofSec.
Gov't Lot (if applicable)
_ N ; R n ^
• W
Facility ID
238000047
License/Permit/Monitoring No.
.ft. n N. D s.,
Street Address of Well
Mann St. Marinette, Wl
.ft. D E. n W. City, Village, or Town
Local Grid Origin W (estimated: I I ) or Well Location I I
O I t l o t t '
Lat Long or
Present Well Owner
Shirlev Scharff
Original Owner
Wisconsin Public Service CorDoration
State Plane. .fi.N.
S C N
.ft. E. D D D Zone Street Address or Route of Owner
400 N. Adams St. PO Box 19002 Reason For Abandonment
Utility Construction
Wl Unique Well No.
of Replacement Well N/A
City, State, Zip Code
Green Bav,Wl 54307 (3) W E L L / D R I L L H O L E / B O R E H O L E I N F O R M A T I O N f4) P U M P . L I N E R . S C R E E N . C A S I N G . & S E A L I N G M A T E R I A L
Original Construction Date
l2Sl Monitoring Well D Water Well
D Drillhole/Borehole
Construction Type:
Kl Drilled
D Other (Specify)
Formation Type:
5/25/1990
If a Well Consttuction Report is available, please attach.
Pump & Piping Removed? Liner(s) Removed? Screen Removed? Casing Left in Place?
D Yes D No l SI Not Applicable • Yes D No M Not Applicable Kl Yes D No D Not Applicable D Yes I S No
I I Driven (Sandpoint) D Dug
Was Casing Cut Off Below Surface? Did Sealing Material Rise to Surface? Did Material Senle After 24 Hours?
If Yes, Was Hole Retopped?
D Yes D No D Yes D No D Yes D No D Yes n No
Unconsolidated Formation
9.9 Total Well Depth ( f t )_ (From ground surface)
Lower Drillhole Diameter (in.)_
I I Bedrock
Casing Diameter (in.).
Casing Depth (ft.)
2.05
Required Method of Placing Sealing Material
I I Conductor Pipe - Gravity I I Conductor Pipe - Pumped I I Screened & Poured ^ Other (Explain) Construction
(Bentonite Chips) Activities
9.9
8.0
Was Well Annular Space Grouted? CD Yes
If Yes, To What Depth?
Depth to Water (Feet)
No I I Unknown
Feet
3.9
Sealing Materials I I Neat Cement Grout I I Sand-Cement (Concrete) Grout I I Concrete I I Clay-Sand Slurry I I Bentonite-Sand Slurry I I Chipped Bentonite
For monitoring wells and monitoring well boreholes only
I I Bentonite Chips I I Granular Bentonite I I Bentonite-Cement Grout I I Bentonite - Sand Slurry
(5) Sealing Material Used From (Ft.) To (Ft.) Mix Ratio or Mud Weight
Granular Backfill Surface > 9 . 9
(6) Comments Removed dur ing utility construction.
(7) Name of Person or Firm Reporting
Natural Resource Techno logy . Inc. rft of Person Reponii Z ! L ^
Street or Route
23713 W. P a u l R d . Ste. D
Date of . ilinnrlnnwifni
8^27/04 i ^ a m t g D Date SigT^d
Telephone Numbe!
262.523.9000 Cit>', State. Zip Code
Pewaukee, Wl 53072
STS Consultants Ltd.
OWNER
C i t y of M a r i n e t t e
PROJECT NAME Former Coal G a s i f i c a t i o n P l a n t
LOG OF BORING NUMBER
B-2 ( f V \ U j - 2 -
ENGINEER STS C o n s u l t a n t s , L td .
SITE LOCATION
S
Wastewater T rea tmen t P l a n t C i ty of M a r i n e t t e , Wisconsin
WELL INSTALLATION TOP STANDPIPE EL. + 586.38
DESCRIPTION OF MATERIAL
SURFACE ELEVATION 584.42
^ t :
I -< CO
LU m
o
O LU
otr: <
CO a . < ^
i n >
LU fC S i i
SS
SS
SS
Dark brown to black fine sand (SM) - trace of coarse sand - trace of fine gravel - trace of wood, organics - dry - loose to medium dense fluvial
12 210
SS
-te
ll
SS
Brown to reddish brown silty clay (CL) - trace of fine sand - trace of fine to medium gravel -wet - loose - fluvial
Black fine to medium silty sand (SM) - trace of fine to coarse gravel - a little wood - wet -extremely dense - fluvial
15
End of Boring Boring advanced from 0.0 to 10.9 feet with hollow stem auger 2-inch Schedule 40 PVC monitoring well installed at 9.9 feet with protector pipe and lock
1004 320
Thtf s i ra l t l l ca t ion lines reoreaant ine apofoxtmi ia DounOfV o^ lwtBn so*l types. In altu. tn« i r a n m i o n may DC graouaj. W i w f tevwft w r e maaaureo at trw urrws ind tca l t l . W t e r Igv ia may vafV aeaaonil
«l- 6 . 5 ' WS
WL.T. PIPE DATE
BORING STARTHD 5-25-90
BORING COMPLETED 5 - 2 5 - 9 0
RIO M o b i l e B61
FOREMAN TT
STS OFFICE 540 Lambeau S t r e e t Green Bay, Wl 54303
DRAWN BY PDP
APP-D. BY p L E STS JOB NO. 17538XF
BCG 9421
£5^ HELD WELL INSTALLATION DIAGRAM
TND CAP WTTM HOLt r >-''-' ON STANDAPIPE
^ , ^ ' STANDPIPE SnCK-UP
I
i I a
z "3 E
U
It.
o a.
PIPE DIA.
'Z- INCH
SCH. J i ^ (F r<ve laD)
( p ^ '
' f ' f
zx nLTER.PACK
lo BACI
I ;LL NO.
ILLER .
ELEV. TOP OP PIPE
PROTECTIVE PIPE LENCTW ^ - . O
SURFACE SEAL
ANNULAR SPACE SEAL
BENTONITE SEAL
c-r)'SCREEN •' LENGTH
1) TTPE OF PIPE?
C ^ D GALVANIZED. STAJNliSS, OTHER
2) TrPE OF PIPE JOINTS? Q H R E A D ^ (3THER
3) TYPE OF WELL SCREEN?
( ^ J ) (3ALVANI2ED. STAINLESS. OTHER
4) SCREEN SIZE? 10 6uo-r
5) INSTALLED PROTECTOR PIPE WITH LOCK?
( ^ ) NO
6) WAS DRILUNG MUD USED? YES
SOUD AUGER. CWLLOW STEM AUGES) WATER. REVERTT BENTONITE
7) DID S T M W \ P t COME UP WHEN CASINO WAS PULLED? ^ — 1 ^
8) DEPTH OF WEU FROM TOP OF PVC ' ' • '
9) FILTER PACK: NO. OF BAGS. D.'Z>
10) RNE SAND SEAL: NO OF BAGS
11) BENTONITE SEAL NO. OF BAGS OR PAILS. /
12) ANNULAR SPACE SEALS; BAGS/INCHES WATER
/ INCHES
TT^EMIE D POURED D
INCHES PUMPED
NOTE: INCHES OF WATER AS MEASURED IN SS GAL DRUM
BOTTOM CAP , ^ , WTFH HOLE - ^ E . - )
3 ' l J m r ' ^ ^ ^ INSTALLED ^ - " ^ ^ ^ ^ ^
^ • V - M - DRILL CREW 0-^- ^ ^ - ^ -
DRILL RIG ^ 3
3/CLIENT C ^ ^ ^ 6r'-ASS\?^ICATiOvJ STS JOB Kin n ^ ^ ' b ^ F
MBtT'.
Stale of Wisconsin Depanment of Natural Resources
MONITORING WELL CCWSTRUCTION Form 4400-113A 8-89
Faciiiiy/Projeci Name f^}r(Y\^r !%sf i ^ t t c
Facility License, Permit or Momionng Numbw
Gndl
lypeofWeil Wsie Table Obsavaioa Weli,
PiezCTneter D12 Chstance Well is rrom Waste/ilource tioundaiy
- - 3 0 0 ft Is WeU A Pomiof Enforcement Std. Applicaaon?
ISfYes n hfc
shxre^'V\£ij\€ Coord' nare .
^ m . ^ U . O ft. ^ K n s. a . l rW^^n .^ ft. )^E. DW.
SecooB Location ^ ^ 1/4 of S ^ 1/4 of Section ^
Location of WeU ReUuve ^ Wasiey'Source Q Upgradmt
^ S ^ Downgradient D Sidegndoent n Not Known
Well Name \i\\}0 - z-
"DRTwar
bate Well Insuiletf
WeU installed By: (Peisoo's Name
0.^1^^12.0. m m 0 o Y V
and firm)"
A. Protective pipe, \ap elevation ft. MSL
B. WeU casing, top elevation _ ^ £'ii? -sS 2 ^ ^ ^ ^
C. Land surface elevation _ i . % ^ . ^ f* MSL
D. Surface seaL botttwn ._ ft M S L or _ i 2 . Z ft-
1. Cap and lock? 2. PrDlectivc cover pipe;
£. Inside diameter b. Length: c. MateriaL
12. u s e s classification of soil near screen: D G P n G M n G C D G W D S W D S P B S M D S C n M L D M H ; ^ C L D CH DBedrock
13. Sieve analysis attached? D Yes W No
14. Drilling method used: Rotary 0 5 0 Hollow Stem Auger ^ 0 ^ 4 1
d. Additional protection? If yes, describe;
Surface seal:
15
i <
17
Drilling fluid used:Water D 0 2 Drilling Mud [3 0 3
Drilling additives used? D Yes
Describe Source of water (attach analysis):
\JIISS
Air None
D 01 J S ( 9 9
x
E. Benionite seal, top fl. MSL or ._ ft.
F. Fine sand, top ft. MSL or fl
G. FUter pack, top ft-MSLor_^_2 ^ '
H. Well SCTeen, top ft. MSL or _ _ ^ . 5
[. Well screen, bottom ft- MSL or _ J ^ f^
I. Filter pack, bottom ft- MSL or _ j ^ Q ^
K. Borehole, bottom ft- MSL or _ X (2 . 2
' ^.i-^r-^Knlc Akcsn^' isr r-/ r^ iL.U ^^
M. C D . well casing _ ( £ .-2 in.
^. LD. wen casing _ ^ . 0 . 6 . ~ »»-
^ Y « D
Sted JE^ 0 4
D Yes a ; hfe
Bentonite Concrete
D D
30 01
. Material between well casing and proiecdvei)ip)e: protecnvepiise: Bentonite D
Annular space seal M Otter D
5. Annular space seal: Granular Bentoniie O Lbs/gal mud weight... BentoniiB-sand shiny n Lbs/gal mud weight Bentonite shmy D % Bentqnite Bauonite-cemenl grout D
' " vohitne added for any of the above Tremie Q
Tremie pumped •
30
33
35
31
50
01
02 Gravity " ^ o 8
Bentonite granules • 33
D1/4 in. D3/8 in. D 1/2 in. Bentonite pellets Q 3 2
Other D 1_:
7. Fine sand material: Manufacturer, product name and mesh size
8. Filler pack material: Manufactuier, product nam<
Voliine added " / 7 < ft3 9. Well casing:
le and mesh size
Flush ihreadsd PVC schedule 40 JSL 2 3 Flush threaded PVC schedule SO C 24
Otter D m
10. Screen material: Screen type;
^ D V T "
Facteay cm JS^ 11 Continuous slot O 0 1
^ Other D 1 1 Manufacmrer GTTPfS i i H t^ I j ] / o r ^ igr»T A^^ 5t^pplid SkK size: ' Q. dLQ'rs-Stotied lengdi: _i ' .Oft-
11. BadcGU material (bdowSlterps^v J NCSB •
Q^;gl Qbv certify that the information on this form is true and correct to the best of my knowledge.
>l£D&£urc mill ^U . ^ , , . _ . . ..,„„.... . 1 ^ Q- - ^ P i e a » complete Hid tetmil'lJQlh sKiei(4!)t tins form as reqiured oy ch^ 144, 147 and 160, Wis. Stais^ anft ch. NR 141. Wit. Aom. Cooe. in accordance with h. 144, Wis Stais.. failure to fik this form i i u y r e s u k in a forfeitiBe of not lest tiiacSlO.iiac more than SS.OOO for each day of v iola tk^ inaccordance ^ith ciL 147, Wis. Stats., failure to fik this form may result in a forfeiture of not HXKB than 510,000 far each day of violatioii.
i-fOTH: Shaded areas arc for DNR use onty. See instructions for moRinfcnnaticK.
Stale ofWisconsin Depanment ofNatural Resources
Route To: Waiershed/Wastewater D
Remediation/Redevelopment I
SOIL BORING LOG INFORMATION Form 4400-122 Rev. 7-98
Waste Management D
Other D
Page 1 of 2 Facillly/Projecl Name
Former Marinette MGP Site (1549) License/PermiL/Moniioring Number Boring Number
MW-3R Boring Drilled By: Name of crew chief (first, last) and Finn
Paul Boart Longyear
Date Drilling Started
10/7/2004
Date Drilling Completed
10/8/2004
Drilling Method
hollow Stem auger
Wl Unique Well No. DNR Well ID No. Common Well Name
MW-3R Final Static Water Level
579.2 Feet MSL Surface Elevation
585.7 Feet MSL Borehole Diameter
8.3 inches Local Grid Origin
State Plane
1/4 of
(estimated; Q ) or Boring Location Q
N, E S/C/N 1/4 of Section T N, R
Lat .
L o n g .
Local Grid Location
lEl N Kl E JH8447.37 Feet D S 805728.41 Feel D W
Facility ID
238000047 County
Marinette County Code
38 Civil Town/City/ or Village
Marinette
Sample
Z a
— -a < E
CJ OJ
-J a:
o U
m
Soil/Rock Description
And Geologic Origin For
Each Major Unit 1/3
U t / ) tn 00
— 00
O'
g u. Q
Soil Properties
u in o D =
0 0
0'-2' ORGANIC SOIL organic material and sand
OL
1 SS
2
s's
SS
4 SS
5 SS
24 24
24 20
24 24
24 18
24 10 12 13 16
— 4
-5
-6
— 7
2'-4.5' POORLY GRADED SAND light brown, fine, trace gravel
\ (5), 4.5' 1" layer of wood 4.5'-7.5'SILTY CLAY, black
(@ 5' 2" sand lens @ 5.5' few fine sand @ 6' few organics and wood pieces,
petroleum-like odor
SP
:L/MU
7.5'-12' POORLY GRADED SAND grey, fine, trace rounded gravel, no odor
- 1 0
— 11
•12
SP
I hereby certify that the information on this form is true and correct to the best of my knowledge.
Sianature J > - ^ ^ /_ Firm ]\jatural Resource Technology, Inc. 23713 W. Paul Road, Unit D Pewaukee. Wl 53072
Tel: (262) 523-9000 Fax:(262)523-9001
Template: WDNR SBL 1998 - Projeci; 1549GINT.GPJ This form is authonzed by Chapters 281. 283, 289. 291. 292, 293. 295. and 299. Wis. Stats. Completion of this form is mandatory. Failure 10 file this form ma\ result in forfeiture of between $10 and S25.000, or imprisonment for up to one year, depending on the program and conduct involved. Personally ideniifiabic information on this form is not intended to be be used for any other purpose. NOTE: See instructions for more information, including where the completed fon should be sent.
State ofWisconsin Depanment ofNatural Resources
SOIL BORING LOG INFORMATION SUPPLEMENT Fomi4400-122A
Boring Number M W - j R Use only as an attachment to Form 4400-122. Page 2 of 2
Sample
i ^ < H
cb O QJ ID
O
Soil/Rock Description
And Geologic Origin For
Each Major Unit c/) U t / i nj CO
63 ? Q D
Soil Properties
u
CJ
a 5
6 SS
7 SS
24 17
24 16
9 1 1 15 19
10 15 20 25
•13
- 1 4
•15
•16
12'-16'SILT, pink, trace rounded gravel
14' pink to gray, no odor, sheen ML
END OF BORING (a). 16'
Slate ofWisconsin Departmeni of Natural Resources „ _ ,,, , . , , , , i—i
Route To: Waiershed/Wastewater LJ Remediation/Redevelopment [
Waste Management D MONITORING WELL CONSTRUCTION Other D Form4400-113A Rev. 7-98
Faciliiy/Projecl Name
Former Marinette MGP Site (1549)
Local Grid Location of Well
148447.37 fl ^ ^ - 805728.41 _fl. G W .
Well Name
MW-3R Facility License, Permit or Monitoring No. Local Grid Origin
Lat.
(estimated: n ) of
Long. 1
Well Location •
or
Wis. Unique Well No. DNR Well Number
Facility ID St. Plane ft. N. ft. E. S /C /N 238000047 Section Location of Waste/Source
Date Well Installed
10/O8/2004 Type of Well
Well Code 11/mw .1/4 of. 1/4 of Sec. T. . N. R.
DE -D W
Distance from Waste/ Source ft.
Enf. Slds. Apply
Location of Well Relative to Waste/Source u D Upgradieni s D Sidegradient
d D Downgradient n D Nol Kjiown
Gov. Lot Number
Well Installed By: (Person's Name and Firm)
PauJ
Boart Longyear
585.68 f,, MSL A. Protective pipe, top elevation _
B. Well casing, top elevation _
C. Land surface elevation _
D. Surface seal, bottom 584.7 ft M S L or '•O ft.
585.50 fi. MSL
585.7 f,, MSL
12.
13
14
15
16
17
u s e s classification of soil near screen: GP D GMD GCD GWD SW D SP 12 SMD s e n MLSI MHD CL SI CH D Bedrock D
Sieve analysis attached? D Yes S No
Drilling method used: Rotary DSC Hollow Stem Auger S 4 1
Other n
Drilling fluid used: Water D 0 2 Air D 0 1 DnllingMud DO 3 None Kl 9 9
Drilling additives used? DYes H No
Dpsri-ibp
Source of water (attach analysis, if required):
n/a
E. Bentonite seal, top
F. Fine sand, lop
G. Filter pack, top
H. Screen joint, lop
1. Well bottom
fl. MSL or
582.7 fl, MSL or 3.0 ft.
582.2 ft MSI, or 3.5 ft.
580.7 ft MSL or 5.0 ft .
570.7 ft, MSL or ' 5 0 ft.
J. Filter pack, bottom 570.2 ft MSl .nr '5.5 ft
K. Borehole, bottom 569.7 ft, M S L or I M ft.
L. Borehole, diameter "•3 in.
M. O.D. well casing -^33 in.
N. l.D. well casing 2.07
1. Cap and lock?
• 2. Protective cover pipe:
a. Inside diameter:
b. Lengih:
c. Material:
Yes D No
8.0
iS/tiiL d. Additional protection?
If yes, describe:
Steel D
Other K
D Yes B
' 3. Surface seal: Benionite D
Concrete IE
_ Other D
4. Material between well casing and protective pipe:
Bentonite D sand Other IS
• 5. Annular space seal: a. Granular/Chipped Bentonite B
b Lbs/gal mud weight. . . Bentonite-sand slurry D
c Lbs/gal mud weight. . . Bentonite slurry D
d % Bentonite . . . Benionite-cemenl grout D
e Ft'' volume added for any of the above
r How installed: Tremie D
Tremie pumped D
Gravity H
6. Benionite seal: a. Benionite granules D
b. D 1/4 in. D 3/8 in. D l / 2 m . Bentonite chips •
c Other O
, 1 . Fine sand material: Manufacturer, product name & mesh :
a itl Badger
in.
L ft. 04
No
30 01
30
33 35 3 1 50
01
02
08
33
32
b. Volume added ft^ _ 8. Filter pack material: Manufacturer, product name & mesh size
a #40 Badger
b. Volume added ft
9. Well casing: Flush threaded PVC schedule 40 B 2 3
Flush threaded PVC schedule 80 D 2 4
Other D
10. Screen material:
a. Screen Type:
PVC
Factory cut K 11
Continuous slot D 0 1
Other D Boart Longvear b. Manufacturer _
c. Slot size:
d. Slotted length:
11. Backfill material (below filter pack):
O.OIO in.
'0-0 ft.
None D 1 4
Other Kl
I hereby certify that the information on this form is true and correct to the best of my knowledge. Signature
^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ Firm Natural Resource Technology. Inc.
23713 W. Paul Road, Unit D Pewaukee. Wl 53072 Tel: (262)523-9000 Fax: (262) 523-9001
Please iofnpleie Both Forms 4400-113A and 4400-113B and rerum them to the appropriate DNR office and bureau. Completion of these reports is required bv chs. 160. 281. 283. 289, 291. 292. 293. 295. and 299. Wis. Siai.s.. and ch. N'R 141. Wis. Adm. Code. In accordance with chs. 281. 289. 291. 292. 293. 295. and 299. Wis. Siais.. failure to file these forms may result in a forfeiture of between SIO and S25,000. or imprisonment for up to one year, depcndinii on the program and conduct involved. Personally identifiable information on these form IS not intended to be used for any other purpose. NOTL. Sec Ihe instruciions for more infonnation. including where the completed forms should be seni.
Stale ofWisconsin Department ofNatural Resources
MONITORING WELL DEVELOPMENT Form 4400-113B Rev. 7-98
Route To: Watershed/WastewaterCH
Remediaiion/RedevelopmenB
Waste Management CI
Other D Facility/Project Name
Former Marinette MGP Site (1549) Facility License, Permit or Moniloring Number
1. Can this well be purged dry?
2. Well development method: surged with bailer and bailed surged with bailer and pumped surged with block and bailed surged with block and pumped surged with block, bailed, and pumped compressed air bailed only pumped only pumped slowly other
3. Time spent developing well
4. Depth of well (from top of well casing)
5. Inside diameter of well
6. Volume of water in filter pack and well casing
7. Volume of water removed from well
8. Volume of water added (if any)
9. Source of water added N/A
10. Analysis performed on water added? (If yes, attach results)
IS
D D D • D D D
D D
D
County
Marinette Counry Code
38
Yes D No
4 1 61 42 62 70 20 1 0 5 1 50
54 min.
14.8 fl.
2.07 in.
8.0 gal.
24.0 gal.
0.0 gal.
Yes D No
Well Name
MW-3R Wis. Unique Well Number DNR Well Number
Before Development After Development 11. Depth to Water
(from top of ^ 6 5 0 ^ 13.53 ft. well casing)
Date b. 10/8/2004 10/8/2004
B a.m. S a. Time c. 10:40 D p.m. 11:34 D p
12. Sediment in well 0.8 inches inches bottom
13. Water clarity Clear D 10 Clear H 20 Turbid B 1 5 Turbid D 2 5 (Describe) (Describe)
Dark brown, silty,
opaque
Fill in if drilling fluids were used and well is at solid waste facility:
14. Total suspended mg/1 mg/1 solids
15. COD mg/1 mg/1
16. Well developed by: Person's Name and Firm
Jody Barbeau
Natural Resource Technology, Inc. 17. Additional comments on development:
Pumped dry 4 t imes during d e v e l o p m e n t
Facility Address or Owner/Responsible Parly Address'
Name: Shirley Scharff
Film: Wisconsin Public Service Corpo ra t i on
Street: 700 N . Adams St. PO Box 19002
City/Staie/Zip: Green Bay, Wl 54307
I hereby certify that the above infonnation is true and correct lo the best of my knowledge.
Signamre:
y Pnm Name: Jody B a r b e a u .
YxYm: Na tu ra l Resou rce Technology. Inc.
N O T E : See instructions for more in format ion including a list of county c o d e s and well type codes.
Stale o fWiscons in
Department ofNatural Resources
W E L L / D R r L L H O L E / B O R E H O L E A B A N D O N M E N T Form 3300-5 2/2000 Page I of 2
Notice: Please complete Form 3300-5 and rerum it to the appropriaic DNR office and bureau. Completion of this report is required by chs. 160, 281. 283, 289, 291, 292,293, 295, and 299, Wis. Stats., and ch. NR 141, Wis. Adm. Code. In accordance wiih chs. 281. 289. 291, 292, 293, 295, and 299, Wis. Stais.. failure to file ihis form may result in a forfeiture of between SIO and S25.000, or imprisonment for up to one year, depending on the program and conduct involved. Personally identifiable information on this form is not intended to be used for any other purpose. NOTE: See the instruciions for more information.
Route to:l I Drinking Water I ^ Waiershcd/Wastcwaicr I I Waste Management B ] Rcmcdiation/Redevelopmenll I Other
( I ) G E N E R A L I N F O R M A T I O N | (2) F A C I L I T Y / O W N E R I N F O R M A T I O N
Wl Unique Well No.
N/A
DNR Well ID No. County
Marinet te
Facility Name
Former Marinette M G P Site (1549)
Common Well Name _
1/4 of Grid Location
MW-4
1/4 of Sec.
Gov't Lot (if applicable)
_ . N ; R n ^
• w ft. D E. n w.
Facility ID
238000047
Liccnse/Pcrmit/Monilorine No.
ft. D N. D s.,
Local Grid Origin QQ (estimated: I I ) or Well Location I I
O < It o I "
Lat Lone oi
Street Address of Well
1603 Ely St. Marinette. Wl City. Village, or Town
Marinette Present Well Owner
Shirlev Scharff
Original Owner
Wisconsin Public Service Corpo ra t i on
Slate Plane. . ft. N. .ft E. D D D Zone Street Address or Route of Owner
400 N. Adams St. PO Box 19002 Reason For Abandonment
Ulilitv Conslruclion
Wl Unique Well No.
of Replacement Well N/A
City, State. Zip Code
Green Bay. Wl 54307
(3) W E L L / D R I L L H O L E / B O R E H O L E I N F O R M A T I O N (4^ P U M P . L I N E R . S C R E E N . C A S I N G , & S E A L I N G M A T E R I A L
Original Construction Date
QSi Monitoring Well
D Water Well
n Drillhole/Borehole
Construction Type:
1 3 Drilled
n Other (Specify)
Formation Type:
5/25/1990
If a Well Construction Report is available, please attach.
Pump & Piping Removed?
Lincr(s) Removed?
Screen Removed?
Casing Left in Place?
D Yes D No I2SJ Not Applicable
D Yes n No ^ Nol Applicable
1 3 Yes n No D Nol Applicable
D Yes 1 3 No
I I Driven (Sandpoint) D Dug
Was Casing Cut Off Below Surface?
Did Sealing Material Rise to Surface?
Did Malerial Seitlc Afier 24 Hours?
If Yes, Was Hole Retopped?
a Yes
1 3 Yes
D Yes
D Yes
D No
No
No
No
Unconsolidated Formation
9.9
8.0
Total WellDeplh(ft)_ (From ground surface)
Lower Drillhole Diameter (in.)_
Was Well Annular Space Grouted? I I Yes
If Yes, To What Depth?
Depth to Water (Feet).
i m Bedrock
Casing Diameter (in.).
Casing Depth (ft.)
2.05
Required Method of Placing Sealing
Q^ Conductor Pipe - Gravity
l_J Screened & Poured
(Bentonite Chips)
Material
1 I Conductor Pipe - Pumped
D Other (E.xplain)
9.9
No I I Unknown
Feet
5.0
Scaling Materials
I I Neat Cement Grout
I I Sand-Ccmcnt (Concrete) Grout
I 1 Concrete
I I Clay-Sand Slurry
I I Bcntonitc-Sand Slurry
123 Chipped Bentonite
For monitoring wells and
monitoring well boreholes only
' I I Bentonite Chips
ID Granular Bentonite
I I I Bentonite-Cement Groui
I I I Bentonite - Sand Slurry
Sealing Material Used From (Ft.) To (Ft.) Mix Ratio or Mud Weight
3/8" Chipped bentoniie Surface 12.5
(6) Comments Well dama.ged beyond repair
(7) Name of Person or Firm Ding Sealing Work
Namral Resource Technology. Inc.
Date of Abandonment
8/27/04
Sigoauire of Person Doing Work . r r l / ^
./Cr2>.^v.-j^_./_ '<LJ>c/..-i^nJu...tf Street or Route < \
23713 W. Paul Rd. Ste. D
Date Signed
9 / / 9 /0 r Telephone Number
262 .523 .9000
City, State, Zip Code
Pewaukee. W l 53072
STS Consultants Ltd.
OWNER
City of Marinette
PROJECT NAME Former Coal Gasification Plant
LOG OF BpRING NUMBER
B-4 / i H u ) - ^ ENGINEER STS Consultants, Ltd.
SITE LOCATION Wastewater Treatment Plant City of Marinette, Wisconsin
SE
WELL INSTALLATION „ . , , . , TOP STANDPIPE EL. + 5B7.67
DESCRIPTION OF MATERIAL
SURFACE ELEVATION 585 .61
E ^
S=:
IXJC/?
o-o < " J
i s 2 i i
SS Topsoil
- n -
ss
SS
ss
ss 5A SS
Brown fine to medium sand (SM) to (SP) - t r a ce of fine gravel - t race to a l i t t l e s i l t a t 7.5 to . 9.0 feet - wet at 5.0 feet - loose to dense -g lac ia l outwash
Gray clayey s i l t (ML) - t r ace of fine to medium sand - t r ace of organics - wet - dense -l acus t r ine
24
^ 1
-= 1
<Ll
41 •1
-11
End of Boring Boring advanced from 0.0 to 12.5 feet with hollow stem auger 2-inch Schedule 40 PVC monitoring well installed at 10.9 feet with protector pipe and loclc
Tne atrittlicatton lines repreaeni ttw appfojtimaie tX)uno«fy wtwwn ion tvpaa. in aitu. the tranalllon rrmv pa Qimouml. Wwar i»vwa wun m—aurgo at ine itmas indioieo. Walw levaia miy v»fv saasonidy
5 . 0 ' WS TIME WL.T, PIPE TIME
SORING STARTED 5-25-90
BORING COMPLETED 5 - 2 5 - 9 0
RIG CME 55
FOREMAN EVH
b4C) Lambeau S t r e e t Green Bay, Wl 54303
DRAWN BY PDP
PLE
SHEET 1 OF 1
17538XF BCG B421
HELD WELL INSTALLATION DIAGRAM
STANDPIPE
sncK-up
-7
m
Ul
in
I § E O
O
0.
PIPE DIA.
_ 1 _ | N C H
SCH. _ ! £ ,
6.1
u
WELL NO.
DRILLER _
RLTER, PACK
3ACKF11X 1 ^ 1 llf?
END CAP VWTH HOL£ x / ^ ON STANOAPIPE J _ I T
ELEV. TOP or PIPE
PROTECTIVE PIPE LENCTH 5 ' , o '
SURFACE SEAL
ANNULAR SPACE SEAL
BENTONITE SEAL
FINE SAND
WELL <'SCREEN
LENGTH
BOTTOM CAP WITH HOLE
1) TYPE OF PIPE?
C ^ J ) GALVANIZED. STAINLESS, OTHER
2) TYPE OF PIPE JOirfTS? C^REAOm^ OTHER
3) TYPE or WEa SCREEN?
( F ^ GALVANIZED, STAINLESS, OTHER
10 6 LOT 4) SCREEN SIZE?
3) INSTALLED PROTECTOR PIPE WTTH LOCK?
C ^ ^ NO
6) WAS DRIUJNC MUD USED? YES . C N O ^
SOUD AUGER. <pOUJDW STEM A U G ^ WATER. REVERT. BENTONITE
7) DID STANDPIPE COME UP WHEN CASING WAS PULLED? ^—s.
8) DEPTH or WELL FROM TOP OF PVC !!.=?
9) FILTER PACK: NO. OF BAGS. 6 10) nNE SAND SEAL; NO OF BAGS '
11) BENTONITE SEAL: NO. OF BAGS OR PAILS, , 7 -
12) ANNULAR SPACE SEALS: BAGS/INCHES WATER
/ INCHES
TREMIE D POURED D
INCHES PUMPED
NOTE: INCHES OF WATER AS MEASURED IN 35 GAL DRUM
DATE INSTALLED
DRILL CREW
^'ZS'°}0
u.e i f.(3-. DRILL RIG. ZS
JQR/CLIFNT mAi(.l*J5rTEr COAU C^^<£.[<^\i^^iod STS JOB N O J 3 S M _ v J ^
Stiie ofWisconsin Depvtmeni of Natural Resoutcss
raciiiiyypro,eci Name f i r m e r / / h o V l f / f£^ pridLocabon 5 t f l t e "^loft* (JXira)na.VC IWeUNinie
Coal (Sasifitrafio^t^lmii- I ^ 7 4 ^^4^/^ f«- p( H D S
MONITORING WELL CONSTRUCTION Fom 4400-113 A 8.89
I i-aciliiy License, Peniiii or Moniionng Number
lypeofWeU WucTTaUeOtaerviticmWeUJ^
PJezometer WO, L>jstance Well is hom Wasta/Source Boundajy
-(303 / is WtU A Pouuof Enfoicemem SuL Applicauon?
'Yes D hfa
;5[2sS22l ft-^ E. D w. ^ n o n Lr>r>rmR
. S ^ 1/4 of 5 ^ 1/4 of Section C^
T : ? 0 N . R ^ ^ t r E D W Location of WeU Relative to Wasi^/Source
a Upipadiea D Sioegradien I t Etewngradiatt • Not Known
B
Date Well installed ' ^ 7 7 , . . '
^ £ / 4 4 / £ i 2 m m g o y V
Well installed By: (Penon's l^ame n d Rnn)"
1
67:^5 Cnn^ulJ-oiAi^. l i - J A. ProtecDve pipe, top elevation . _ _ ft- MSL •
B. Well casing, top elevation ^ ^ . Z I . L ' l ^ MSL •
C. Land surface elevation ^ 6 . 1 ^ 6 .le f* MSL>
D. Surface seaL bottom ft. MSLor _ ' X . O ft-s
f l Z u s e s classification of soil near screen: DGP DGMnocncwnsw H'SP S'SM D SC OML D MH D CL B CH • Bokock
13. Sieve analysis attached? DYes ^B^Ni
14. Drilling method used; Rotary D 5 0 Hollow Stem Auger £ l 4 1
. Otter D mmi
12. Drilling fluid used-Watff J } 0 2 Air D 0 1 Dtil l ingMudDoB N O K D 9 9
16. Drilling additives used? D Y e s
Describe
35'No
17. Source of water (attach analysis):
. 1 . Cap and lock? . 2. Protective cover pqie:
a. inside diameter b. L x n j ^ c. MateriaL
d. Additional protection? If yes, describe:
• O i f
oiter n u D Yei JSLl
E . Bentonite seal, top . , ft- ^ ^ ^ °^ . - f \
F. Fine sand, top ft. MSL or ft-
G. Filler pack, top ft. MSLor _ _ j / _ ^ ft
H. WeU screen, top ft- MSL or _ _ . 5 . 2
L Wel l screen, bottom ft.MSLor__/5 2
J. Filter p a c t bottom ._ ft-MSLor _ J^S ^ fL.
K. Borehole,bottom ft.MSLot_iS.^ ft-^
L. Borehole, diametH ' _ ^ ^ 0 in.
M. O.D. weD casing _ 3 ^ 3 ^ in.
•>(. LD.wellciiing _ A .Q . -^ in. -
' 3. Surface seaL 1 Bentoniie D 31
/ I Concrete LJ 0! hgn-bnii-&/-^nrf .^/urnj othg -a^ J
' 4. Matoial between well casing and proiective^ipe: ~W Benionite D 3 (
Annular space seal Q • ^ Other n J
- 5. Aimuiar space seal: Granular B«ntoniiB O 3 3 Lbs/gal mud weight.. . BenKsiite-sand slurry V ^ 3 j Lbs/gal mud weiglu Bentonite shmy D 31 % Bentonite Bentonite-cement grout O 5
How installed: .Ft volume added for any of the above
Tremie • 0 Tremie pumped Q 0
Gravity j ^ Q
6. Bentonite seal: Bentonite granules • 3 D1/4 in. 03/8 in. D 1/2 in. Bentonite pellets Q 3
Other n ;_ , 7. Fine sand material: Manufacturer, product name and mesh S)
Volume added nnaini [e and mesh si , 8. Filter pack material: Manufacturer, product
Vofiime added ^ a , 0 ft 3 9. WeU casing: Bush threaded PVC schedule 40 3 ^ ^ 2 3
Bush threaded PVC schedule 80 Q 2
Oew D i
I I 8
I 1 1
' 10. Screen material: Screen type:
^VO F a c m t y c u i ^ ^ ^ B
Continuous slot Q 0 l l .Other D i l
' hereby certify that the information on this form is true and correct to th* beaf of my knowledge
Manufacmter G r P ^ I i r € ^ / / y f J f i h p ( Y \ / t i < ^ Slot size; 7 O . O I u a M Sk)iuxi length: j i - O f W
iL-BaekfiUmaterial (bekw Stterpfck): / None Q
r ^ / W 7^a(-r^i l i ra ^ i d n ^ ' ^
til fuim as recnuret r r -n - t r romplm Bitd iTiTim tvith liiirri iriT^ ^ ^ H I MT iiiilK>n VVii "ran iiirtrh NF 111 Wji Aiim nwli In •rmnlnTifT in-iih • :h. 144, WisStats.. failitretofUethiafoimmayresiihinaforfeiiiireofiiotleaa tfaai$10.Hrin(MethmS5,000foreachdayofviolatioiL Ina B vitti ch. 147. Wis. Stats., failure to fik ifaia form may resolt in a forfeiwre of not more than SlOjOOO fior each day of violation.
, j f r i ' t - ' . ct>.«ia>4 —.^ — . c — r t k T B •-- "--• • ' . . .
I piTw ofWisconsin. lenarnneat of Natural Resources
W E L U D R I L L H O t E / B O R E H O L E ABANDONMENT Fonn 3300-5 2/2000 Page 1 of2
Niiiice: Please complete Form J300-5and return il lotheappropiate DNR office and bureau. Completion of tliis report is required by clis.160,281.283,289, '291.292,293,295, and 299.Wis.Stats.,and ch. imi41. Wis. .Adm. Code. In accordance with chs.. 281, 289, 291, 292, 293. 295, and 299, Wis.Sl2is.. failure to file liiis form may result in a forteiture of between SIO and 225.000, or imprisonment for up to one year, depending on theprogram and conduct involved. Personally identifiable iniormation on tiiis form is not intended to be used for any other purpose. NOTE: See the instructions for more information.
Rome lo: I I Drinking Water Cj Vatereiled/Waste^watE^ D Waste Management • REmediacion/'RedgveiormicnT DOther (I) GENSHAL INFORMATION (2) F A a U T Y I O VVNER iWFORJViATlON Wl Uniaue Weil No. DNR Well ID No. Counry Facility Name
(y \ \ ) J ' l>o \ Gov't Lai flf applicable)
S 2 Common Well Name
i ^ 1/4 of i ^ l / 4 o f S c c _ L ; T. ^ ° N;R. i ^ L Grid Locarion
fi. • N. n s.-Local Grid Oriain Q ( estimated: Q ) or Weil Location Q
o f f l » r II
Lat : Long : or S C N
St.Plane ft N. __ft. E. 0 1 1 1 0 Zone
Faciitty LD License/Perrait/Monitoring No.
Street Address of Weil
ft. D E. n "w. City, Village, or Town
Present Weil Owner Originai Owner
street Address jor Route of Owner
Resson For Abandonmcai IW IWlUniojueWellNo.
Seniacement Weil
City, State, Zip Code \ ^ 'SMl.o^
(3) WELL/DRILLHOLE/BOREHOLE INFORMATION 1(4) P U M P , LDJER, SCREEN, CASING. & SEAUNG MATERIAL
If a Well Consiruciion Report is available, pieas-e attach.
Original Consirucrion Date _ £ ^ J _ ^ ^ J j _ W \
lA^ Monitoring "Well
• Water Wen
• Borehole/Drillhole
Consnuction Tyj^c:
I ^ Drilled [ ] Driven (Sandpoint) D ^ S
• Other (Specify)
Formaiion Type:
K ! Unconsolidated Fomiadtjn LJ Bedrock
Total Well Depth (ft.) ' ^ Casing Diameter fm.) ^•O^*'? ^t>
(Fiomgroundsurfacs) Casing,Depth (ft.)
Lower Drillhole Diameter (in.) j £
Was Well Annular Space Grooted? • Yta 0 No • Unknown
IfYes. To Whar Depth? Feet.
Depth to Water {Peel)
P i n n p i Piping Rcmtyved? • Yes Q No • Not A-ppiitable
Ljncr(s) Removed? • Yes • No Q Not Applicable Screen Removed? Q Yes Q No Q Not Appiicajjlc Casing Left. in.Placii? 1 3 Yes • ' N o
Was Casing Car Off Below Surface? ^ Yes Q No .
Did Scaling MaierialRiie TO Surface? 0 Yes Q No
Did Mitcrial Settle After 24 Hoars? Q Yes ^ No
If Yes, Was Hole Retopped? Q Y e s ^ No
Required Method of Plating Scaling Material
1 2 Conductor Pipe-Gravity 1 I Condntanr Pipe-Pumped
n Screened 3L Poured O Other (Explain) (Bentonite Chips)
Sealing Materials 1 I Neat Clement Grout [~1 Sand-^Zement (Concrete) Grout n Concrete [~l Clay-Sand Sluny (11 IbJgal. wt) • Benioniie-Sand Sluny " " r~l Bentonite Chips
Formonitoring wells and monitoring well boieiioies tmly
H Bentonite Cliips
I I Granular Bentonite
M Bentonite - Cement Groui
I I Bentonite - Sand .Slurry
(5) Maierial Used To FHI Well/Drillhole
V?" cUlfpc-) la -^-Vc
From (Ft)
Surfata:
To (Ft).
T or Vohmic ""•=)
1
Mix Ratio or Mud Weight
(6) Comments:
(7) Name of Person or Firm Domg Scaling Woric Dale ot Abandonment FOR DNK OR COUT TY USE ONLY
Signature of Person Doing Woii: DaieSignca , I / / IS
j Date Reixived Noted Bv
Sfiieet or Route Tcicprione Ntimbcr I Comments
C:ty, Slate. Zio Code
StJia of Wisconsin aouiC IS: soua waste U M«. W u t r U Wastewater U DcpsnmcntofN»nffalR«ouro:s Env. ResDsnsc i Rcoair D UndcrOTund TsrJa • O&a D
MO.NTTORING V,-ELL CON'STRuJ Form 4400-n3A Rc^B
^ ^ • ^ , . . ^ / t ^ ^ g ^ - ^ / ^ S C j 7^l l r> ' ljc=nsc Pcnrai or Momtormg N u m t w
'ype oi WcU Water Table Observanon W e U a 4 1 T / " a n Pjezometg
T>isu:«e WcJJ is rtnm Wasie/Soince Boundaiy
f t is Well A Point oi Eniorccmaii Sid. Appiication?
n Ya n hb
Grid Origin Locidon
St Plane .
DE. DJiL
fWcilKOTK
W'li. UnwueW
, Long,
ft. .N. .ft-E. Secaon Ltjcationof Waste/Sotn-ci
^iiJ.1/4 of | ife"l/4 of Sec. _C.,T. •?(? N. R. 2fC
Locauon of Weil Reifidvc to Waste/Source u D Upgradient s D Sidegradiait
d D Downgradient n D Not Known
tli Number::;;. cUN
Dale-WeU imiAUed . , _ " — — ^
m in a d Y V ^ 1 Wellinsumcd ijy: (i^cBon's Wamt: and P M
A. Protective pipe, top elevation ft M S L "
B. Well tasing, lop elevziion ft- M ^ L -
C Ijmd sinface elevation . _ ft M S L
D. Surface seal bonom f t MSL or .rtTTtT f t
IZ u s e s dassiiication of soil near screen:
GP a G M D G C D G W D S W S C SP n . S M D s e n M L D M H D CL-^D CH D
B e a r a t D . 13. Sieve analysis anachsd? • Yes ' S j f a
14. Drilling method used; Rotary • 5 0 HoUow Stem Auger S 0 1
Otha - ' a l i
15. Drilling Quid used: Wan- 0 0 2 Air D 0 1 Drilling Mud • o 3 Nane~;;0c2 9
16. Diiliing additives used? D Yes J ^ 5 t .
Deso i te .
17. Source of water (attach analysis):
L. Boreiolt, diameter ^ 0
M. O.D. well casing J L ' . h ' l . in.
N. LD. weD casing _ ' L . t ^ in.
E Bentonite seal, top ft- MSL or (l Jz. f u
F. Fine sand, top ft MSL or Z O ^'-N
G. Filter pack, top ft MSL or { J^. ^^v
H. Screen joint top fl. MSL or f . i ) f t .
L Wcllbonom ft MSL o r _ j j g ' . D i t ^
J. FDicT pick, bonom ft. MSL or _ _/ f'. f ft-
K. Borehole, boaom ft MSL or _ 1 f . ^ f t .
- 1 . Cap and lock?
J l . Protective cover pipe:
a. Inside diameter:
b. Lengih:
c Material:
I Sled 'a: ; Qteln
d. Aciditional proieciion?
If yes, describe; n Yes KL' I
'S.Suri&cesffzl: BenioiuLT
Concrete
Ote D n
4 . Matnial between well caiing and piDiccrivc pipe: ^
B e n i D m t e i ^ ^ J
Annular space s e a J ^ n ^ P
Otha-^ i - , . . ^ ( ) a. Gnmuiar Bcnionile'^,E^ H
Lbs/gal mud weigh t . . . Bentonite-sand shmy D fl
' 5 . Anmalai space seal:
b c Lbs/gal mud weight Bentonite sluny • d . . z: % Benionite Bcntonite-cemcm grout D
e. [^ - -^ Ft volimic added for any of the above
£ How installed: Treme •
Trnnie ptimpKi D 0
Gravity ' 'Qc
6. Bentonite seal: a. Bentonite granul: I b. n i / 4 i i i . n 3 / 8 in. D 1/2 in. BcntDnitepellets'D 3
c • - ^ ' Othr D m p . Fine sand material: Manufacmrer, product name k. mesh s i z H
b. Voiume'ifeided O- S ' ftS
8. rilterpack material: Manufacturer, nroduci name and mesh
b. Volumi 9. Well casing:
^ Hush threaded PVC schedule 4Q..-^S_ 21
Flush threaded PVC schedule 80 D 21
Oths- D -10. Screen material: f"^C 6 ^ . ' ^ O
•a. Screen-tj'p;: Factory cut
Continuous slot' Q Q
. Oihe D i b . Manufacmrer
c Sbl sixe:
d Sloned length:
11. BacJdiD material (below filler pack): Othr n
.ierebv ceniiv ihal Ihe iniorrr.aiion on this iorm is true antj correci lo ihe best of my knowletjoe.
I I
I I I
Nar=;:sd 1
:3ignarurs_^-'
i^rz ^ ^ j 4 ^ ^ ^ ^ ± 2 ^ / _ ^ 0^-=^ /rri. '- ' ^ C ^ Please complete both sides ot this iorm and reaim to the sppropnaie DHX. oiiicc k'iied at the top ol^lhis lorm as required tjy chs. 144, 14? and It^lfWis^ Stztij and ch. NR'l41. Wis. Ad. Code. In accordance with ch.l'W, W'is Stats., failure lo Hie this form may result in i t'orfcimre of not less than SIO, nor more than S5000 for eschday of violadon. In accordance whh ch. 147, Wis. Stau.. I'tilure lo Tile this form may result in a foncinirc of not more than SIO.OOO for each day of vioiauon. NOTE: Shaded areas are for DNR use only. See instructions for more informaiion inciuding where the compleied form should be seni.
s t a t e 01 Wisconsin
D e p a r t m e n t of Natu ra l Resources
Houte lo: D Solid Waste
D Emergency Response
D Wastewater
D S u p e r t u n d
D H a z . Waste
D Underground Tanks
D Water Resources
• D Other:
SOIL BORING LOG INFORMATK Form 4400-122 Rev. 5-
Page I c
iFecDIty/ProjetrtKame •PSC-MSP/Marinette, H I
License/Permlt/Monltorlng Number Boring Numt>er Mi^-301
Bortng Drilled By (Firm name and naitis Hisconsin Test Drilling Eric Schoenberg
of crew chief) Date Drilllns S ta r ted 3 / 3 0 / 9 4
Date OrllllnQ Conipieted 3 /30 /94
Drilling Method l-iollow stem Auger
DNR Faci l i ty Well No. MI Unique Mel! No. Common Well Name MW-301
Final S ta t i c Water Level Feet MSL
SurfBi:e Elevation 5B7.07 Fest MSL
Borehole Dlametsr 6 inches
Boring Location Sta te Plane SH 1/4 of NE 1/4 of Section 6, T30N. R24E
Lat Long
Local Grid Location (If applicable) 5459 feet E l W 1342 feet E I £
a s atf County Marinette
DNR County Code 38
Civil Town/City/ or Village Ci ty of Marinette
Sample
m a tt) a
Soil/Rock Descript ion
And Geologic Origin For Each Major Unit CO
CJ cn CD CT
i - O CD _ 1
a
a
Soli Properties
a ^ E «; o — o cn
CO —
o S D o D
Cl c:
— 2
— 4
f^ibin anrt STI T- ToDsoil, Drown to black fine sands, silts, and gravels.
SjANO^Dark t)rown to brown, loose, fine, poorly gradea sands - look like beach sands - little odor. Mosit to wet at 6 lee t .
r SE. ML
SP Hit concrete or weathered bearoc:k between B and 9 feet.
— 10
MW-301-13
5/5 5/8
MW-301-15
4/3 Stop
-12
•14
-16
169
Hit concrete or bearack at 15 feet Daring at IS feet.
227
— 18
—20
— 22
I h e r e o y cer t i iy that the information on this form is t rue and correct to the oest of my knowledge.
Locate 3 feet from MW-301A. Drilled blind to i; feet where spoon samples were collected. Log, based boring MW-301A.
•qnaturs
/ Z - t ^ / 2 . - J -
g ^ : ^ ^ ^ Natrual Resource Technology
This form is authonzed by Chapters 144.147 and 1B2, Wis. Stats. Completion of this rsDort is manaatory. Penalties; Forfeit not less than £10 nor more than SS.OOO for each violation. Fined not less than SIO or more than S100 or imprisoned not less than 30 days, or both t o r each violation. Each day of ctjni inued violat ion is a separate offense, pursuant to ss 144.99 and 162.06, Wis. Stats.
Stale ofWisconsin Depamncnc of Nannal Resources
WELLyORILLHOLE/BOREHOLE ABANDONMETsrr Form 3300-5 272000 Page 1 of 2
Niitice: Please complete Form J30O-5and return it lotheappropiate DNB. oSicE and bureau. Completion of this report is required by chs. 160,281.233,289, 191. 292, 293, 295. and 299.Wis. Stats..3nd cii. NUl41. Wis! .4dm. Code, in accordance wiiit chs. 281, 289. 291, 292, 293. 295. and 299, Wis.Stats., failure to file this form may result in a forteiture of between 510 andS25,000, or imprisonment for up to one year, depending on theprogram and conduct involved. Personally identifiable information on this form is not intended to be used forany other purpose. NOTE: See the instructions for more informauon.
Romero: d j Drinking "Water CjWatersietl/Wssiewater O WastB Managemciii D Remctiiatinn/Redeveiaomgnt DOih i r
(I) GENERAL INFORMATION (2) F A a U T Y / O W N E R UNFORJVlATiON
Wl Unique Weil No. DNRWelUDNo. County . ¥ V c
Facility Naine
Common Well Name p - ^ o l
Sv^' 1/4 of j ^ IMofScs. ^ ; T: 1 ° N;R. "^H Grid Location
Gov't Lt:! fif aippiicabic^ H E
.ft D N - Ds.. , ft • R • -w. Local Grid OriainQ ( estimated: Q ) or Weil Location Q
9 1 I I » I n
Lat : Long . or S O N
StPlane ft N. ft. E. D D D Zone
n aciiily l u License/ P ermit/fvioniioring iN o.
Street Address of Weil
City, Village, or Town r ^ <^v:/^cVV<L-
P eseIU: Well Owner Original Owner
Street Address jor Route of Owner 7 ( 0 0 \ / - K ^ K r ^ i jyv-ccV, ^ p . 0 . 0 . 0 / . ^ ^ 0 0 " ^
Reason For Aijandomncnc WlUmmieWenNo.
of Reniacement Well
City, State,Zip Code V/vJ ^ M ^ O ^
(3) WELL/DRILLHOLE/BOREHOLE INFORMATION 1(4) P U M P , LINER. SCREEN, CASING, & SEAUNG MATERIAL
If a Well Construction Report is available, please attacii.
Original Construction Date - f / P ' a / I ' 4
iKj Monianjag WeU
n Water Well
• Borehole / Drillhole
Consnuiaion. Type:
^ Drilled • Dnvea (Sandpoint) D ^ ^
• Other (Specify) '
Pump (tPrping Removed? Liner(s) Removed? Screen Removed? Casing Left in.Place?
• Yes • No • Not Applitable
• Yes • Ko • Not Applicable • Yes • No • Kot Applicable 12 Yes n - N o
Parmaiion Type:
I I UnctJnsolidaied FonnatitJii S Bedrtick
Total Well Depth ( f t . ) _ i i £ : £ _ _ Casing Diameter fm.) 'X.O^'T^'^ (From gnatmdsurfatis) Casing. Dtrpth (ft.) HQ-O
Lower DrilHiolc Diameter (in.)
Was WeU Ammlar Space Granted? • Yes 0 No • Unknown
IfYes, To What Depth? Feet
Depth to Water (Feet) '
Was Casing Cat Off Bciow Surface? g ] Yes • No
Did Scaling Material Rise to Surface? 0 Yes [ ] No
Did Material Settle After 24 Hotrts? • Yes ^ No
If Yes, Was Hole Retopped? Q Y e s Q No
Required Method of Placing Scaling Matcnai
1^ Condntsor Pipe-Gravity Q Ctmductor Pipe-Pmnped n Screened &. Poured Q Other (Explain)
(Bentonite Chips) Scaling Materials n Neat Cement Grout I I Sand-Ccmcal (Concrete) Grout I 1 Concrete • aay-Sand Slurry (11 IbJgal. -vrt.)
• Bentonite-Sand Slurry " "
r~l Bentonite Chips
Formonittsring wells and monitoring well borchoies cmly
Ixj Bentonite Chips
I I Granular Bentonite
I I Bentonite - Cement Groui
M Bentonite - Sand Slurry'
(5) Maierial Used To FHT Well/Drillhole
Vf-" ck-YpJ i,_v.-,-.u
Frtmi (Ft.)
Surface
To (FL).
Ho ^ ^ ' ^ '
3
Mix Ratio or Mud Weight
(6) Comments:
(7) Name of Person or Firm Domg Scaling WorK
tw '^^ ' ' ' ^ -»J^»;5^ ; ' 5 w i _ .
Date of Abandonment
Sigpannp of Person Doing Woti: DareSignca ' / / X , / X o o H
gircet or Route Telephone Number
Ciry, Slate. Zip Coac ^ ? A 15 T X.
i FOR DNR OR CDUiNTi' USE ONLY \ Date Received Noted By
ConmientK
^ ^ l i ^ m t ^ N ^ i u n d Rcsourees ^ ^ Restxinse & Retair D UndenjT".rvJ Tir,to D Otto D ^"^^ — - ' II I A _ ^ T' _ T " ' " M V " 11
Form 4400-1 IS.-k v-U.'t STRUCT
Rev.;
r .ahty/r to^J
rialJty Lc=n5C I'crnut or Momtormg .'^umtw Gild Origin Locsbon
MI.
i'cil Wntc-Table Obsen-shon WcH D 11
Pieiomeier " " SQ^ Disifflte Well is rrom Wasie/Soun^ Boundary
ft is Weil A Point oi Hnioitwnaii Sid. Applicauon!
DYes Dhfa
Local Gnd Lociucm o( ^''cil ,, DN. ft.
DE.
nw
Well Name
5 ' Pl-ne
Long,
ft. .' ,
Section Location of WasiA'Source
gVl/4 of /S)fl/4 of Sec. ^ , T . J D N . R.!:!.! Location of Well Relaave to Waste/Source u n UpgrDdiail d • Eb-ft-ngradient
5 D Sidegradiait n D Not Known
?'Z:0.\
Date Weil Installed ^ ,,. ^ ^ ^ ~
m in Q d v v' Well installed By: (Pciron's i^am: md Pu^
uj)~rjN CJ
A. Protecdve pipe, top eievauon
B. Wen casing, top elevalion
C. Land surface ele -adon
D. Surface seal boaom
fLMSL
ft. MSL
ft. MSL.
fLMSL or _ ^ . 0 ft.
12. u s e s ciassklcation of soil near screen:
GP n GMD G C D G W D SW • SP • S M D s e n M L D M H D C L D C H n Be!iT5*>eri
13. Sieve analysis anached? • Yes "'^;>3'T^
14. Drjlliiig —cthod used: K o i s ^ ^ ^ S : ; ^ Hollow Stem Auger D 4 1
Other n i ^
15. Diilliiig fluid iised: Wai=- D 0 2 Drilling Mud • o 3
16. Drilling ac5dirives used? D Yes
None 0 9 9
Describe.
17. Source of water (attach ar.ajysis):
E. Bentonite seal, top
F. Fine sand, top
G. Filter pack, top
H. Screen joint, top
L Wen bonom
J. Filler pack, boaom
. K. Borehoie, bononi
L Borehole, diameter
M. O.D. well casing
N. l.D. well casing _ Z . d h
__ ft. MSL or _ ^ : ? - . ^ ft.
_ ft. MSLor__J2.X> "•
__ f L M S L o r _ 3 j . ^ fL.
._ fi.}ASLar _ S ^ _ d ft.
__ fi..MSLoT_Jf^j^ fl.
._ fL MSL or _ J ^ . / ) ft-
. _ f L M S L o r _ i / i . O ft.
.1 .l<
1. Cap and lock? • 2. Protective cover pipe:
a. Inside diameter: b. Length: . c Material:
^>Q:Y= Yes D >
d. Additional protection? If yes, describe:
if-Q
SleelJQ—J
a Yes n N
3 . Surface seal; BemoiiiLt-^Sl. :
Cono-ete D C
Otic- n ;: 4 . Maierial betweai well casing and protective pipe:
BmionitE^j;^ 3
-Aimuiar space jcal D
othe- n 5. Annular space seal: a. Grsnulzr Bentonite D 3
_Lbs/gal mud weight . . . Bcruonite-sand shrry D 3 _Lbs/gal mud weigh: Bentonite siuny ! HC 3 , To Bentonite Bentoniie-cemeni grout D 5
:^ Ft ^ voiume added for any of ihe aixive How installed: Tremie Q 0
Trnnie pumpad ' ^ ^ g GraMty Q g
6. Bentonite seal: ' a. B enLonite granules • 3
b. D1/4 in. I23/8 in. D 1/2 in. B enionitc pclleis>3 3
c — : othe- n m .7. Fine sand material: Manufacturer, product name & mesh size
X b. Volume ^ e d .
8. Filter pact: maifjiai: Manufacmrer... .n-'
b. Volume
9. Well casing:
• pacKmaiinaJ: Manufacnirer^nroductnai
Dlume a d S i < ft-^
iuct name and mesh si
Rush threaded PVC schedule 40 W 2 :
Flush threaded PVC sciiedule SCro" 2 :
oibe- n ?••;'*
10. Screen material: a. Screen t)pe:
T'I/C S . - l ^ ur) FactDiy cut 5 [ 11
Continuous s l o t ' n o j
Other D Pv
b. Manufacmrer _ c Slot siie; d Sloned length:
• . \ r ^ ^ t^^ S.?--
oo/Qi^
11. Bacidill material (below iiltcTpaci:): N O T T ^ '
oths-' d
. I - Q n 1 4
•reby ceniiv Ihat the iniormaiion on this form is true and correcl 10 the best of mv knowledoe.
^ g a / ^ ychs. 144, 14/ «finrreQ/Wi:.: laicise complete oolh sides or ihu form and return to the ippropnaie DNK olfic: iL<;u at the top 01 this lonn as requircB-t?y chs. IM, 14/ «finn^7Wi:. Suas.,
andch. N R ' M I . Wis Ad Code. In accordance with ch.l44. Wis Stats., failure to file this form may result in 1 fon'eimrt of not less than SJfif noi more than 15000 for each day of vioiarion. In accordance with ch. !47, Wis. Stau,. I'ailurc 10 ul!: this form may result in a forfcinire of not more than SICOOO for c*:h day of violation. NOTE: Shaded areas are for DNR use only. See insmjctions for more infotmaiion including where the completed form-should be sent. .
s ta te of Wisconsir Route To: SOIL BORING LOG INFORMATlM Department of Natural Resources • S o l i d Waste DHaz. Waste Form 4400-122
D Emergency Response D Underground Tanks D Wastewater D Water Resources D Stjperfund D Other:
'acl l l ty/ProJect Name ,PSC-HlpP/Marinette. MI
BorIno Drll lsd By (Firm name and name of crew chief)
Hisconsin Test Drilling
Eric Schoenberg
DNR Faclf l ty HeB No, Wl Unique Well No, Common Well Name P-301
Boring Locat ion
State Plane
Ucsnse/Permlt /Monitar lng Number
Date DrllUna S t a r t e d 4/4/94
F l n ^ Stat ic Water Level Feet MSL
Lat Lono "
SH 1/4 o f NE 1/4 o f Section 6. T30N, R24E 1 "
County Marinette
Sample
,_ D. Q) > .
n 1—
•^ CD
— -o
OJ OJ
_ j a :
•<*-
= 3
o o o
CD •
. 0)
£ "Q.
OJ
D
_
^ 1 — — — 4 — _
^ 6
—
1 1
1 1
1 1
1 II
1 1
1 F3
o
°=
-—
t-!4 L
— IR
^ 1 8
~ 2 2
DNR County Code 38
Soil/Rock Description And Geologic Origin For
Each Major Unit
RANH Rnct STl T: ToD.'jnll. brown to tilacl< 11ns "\ sands, silts, ana gravels. / "
SAiiDlOark Brown to brown, loose, fine, well graded sands - look like beach sands - little odor. MosIt to wet at 6 feet.
Hit weathered bedrock at approximately 12 feet. Have layers of weathered bedrock and sediments.
nni OMTTP- Have coranatent bedrock at IB feet. Doloirlte, hard, grey, dense. Water yreldeo throughout arming but amount decreases with depth.
. cn CJ cn
5£. ML
SP
DLM
DLM
Boring Number P-301
Date Drilling Completed
4/sm
Surface Hevat ion 587.17 Fee t MSL
Drilling Method
Rev. 5 - ~
• j
Page 1 o |
• 1
Mud/Air Rotary ^
Borehoie Diameter | 6 inches
Local Grid Locat ion (If applicable) 5452 feet Ei N 1326 feet S E
D s Dy^ Civil Town/Ci ty / or vniage City of Marinette
o
• •
* _ •
, • . •
• •
• : •
;
T ^
/
7 "
/
/
/ / /
/ / • /
/ / /
/ / )
/ / /
/ -/ 1
1 / /
E m
_ CT
3 a
1 ^ f S $ % • ^
1 %
1 ^ ^ ?$ 1 !8
1 1 ^
s
'
s
!
a u, o SI
\ -
I i
I 3 R
E
\
\
I '
•
X
i <
! .
<
X
>
Soil Properties
>. S £
£2. C
O —
o cn
•
(U — .
3 £ o o S CJ — 1 — J l a
c=> o C\J
c
• • 1 ••
1 C3 D ^ OZ CJ
• 1
Drilled to 23 feet with mud.B Only • water w a ^ used directly _ from theH City of H Marinette water systsm M • bentonl t™ Due to the _
. IncredlbiS hardness^ of the aoiomite switched • to air • rotory W drilling below 23 faet. I
1 • • • ^ • • •
I herepy certify tiiat ttie information on this form is true and correct to.the oest of my knowleoge.
•nature ^ ^ - y j / C ^ ^ ^ Natrual Resource Technology •
This form is authorized by Chapters 144.147 and 162, Wis. Stats. Completion of this report is mandatory. Penalties: Forfeit not less than £10 nor more than $5,000 for each violation. Fined not less than SIO or more than $100 or imprisoned not less than 30 days, or Doth for each violation. Each day of continued violation is a separate offense, pursuant to ss 144.99 and 162.06, Wis. Stats.
• 1 1
Number and Type
Lengih A l l . G Recovered (In)
Blow Counts
1 I I I I l~IT| I I I I I I I I [ I I I I I I I I I I I I I I I I I I I I I I I I I I I i I I I I I I I I I I I I I I I I I I I I I I I i I I I I I I I I I I I I I I i i I I I I I I I I I i I I cn ro O
Ol 00
cn CD
a i en t \ j
Ol O 133 cn ro o
OJ CD CD
CJJ CO ro
CO o
ro CD
ro CD
Depth in Feet
Q. 9
- • " • S '
ill l 5
o =>
uses
Graphic Log
\;:^f:•:.i•^.;V;:X.:V:r^^'cf:•<i:::•!^^;i•;;^^.;^•r^i;• r i j : - : - : - ; ^ Well Diagram
PID/FID
Compressive
Strength
Moisture
Contenl
Liquid
Limit
Plasllcl ly Index
P 200
RQD/ Commeiils
Sta te o f W i s c o n s i n
D e p a r t m e n t o fNa tu ra l Resources
W E L L / D R I L L H O L E / B O R E H O L E A B A N D O N M E N T Form 3300-5 2 / 2 0 0 0 Page 1 of 2
Notice: Please complete Form 3300-5 and return it to the appropriate DNR office and bureau. Completion of this report is required by chs. 160. 281, 283. 289, 291, 292 .293. 295, and 299, Wis. Stats., and ch. NR 141, Wis. Adm. Code. In accordance with chs. 281. 289, 291, 292, 293, 295, and 299, Wis. Stats., failure to Hie this form may result in a forfeiture of berween $10 and $25,000, or imprisonment for up to one year, depending on the program and conduct involved. Personally identifiable information on this form is not intended to be used for any other purpose. NOTE; See the instructions for more information.
Route loj I Drinking Water I I Watershed/Wastewater I i Waste Management L J Remediation/RedevelopmentI I Other
( n G E N E R A L I N F O R M A T I O N (2) F A C I L I T Y / O W N E R I N F O R M A T I O N Wl Unique Well No. DNR Well ID No. County
Marinet te
Facility Name
Former Marinet te M G P Site (1549)
Common Well Name M W - 3 0 7
. 1/4 of Sec. _ 1/4 of Grid Location
;T.
.ft. a N. D s..
Gov't Lot (if applicable)
_ N ; R . ^ n ' ^ • W ft. n E. n w.
Facility ID
238000047
License/Permil/Monitoring No.
Street Address of Well
Mann St. Mar ine t te . Wl
Local Grid Origin IAI (estimated: I I ) or Well Location I I
O I n O t M
Lat Long or
City, Village, or Town
Marinette Present Well Owner
Shirley Scharff
State Plane. . ft. N.
S C N
. ft. E. D D D Zone Street Address or Route of Owner
400 N. A d a m s St. PO Box 19002
Original Owner
Wiscons in Public Service Corporation
Reason For Abandonment
well d a m a g e d and replaced
Wl Unique Well No.
of Replacement Well
City, State. Zip Code
Green Bay. W l 54307
(3) W E L L / D R I L L H O L E / B O R E H O L E I N F O R M A T I O N (4) P U M P , L I N E R . S C R E E N . C A S I N G , & S E A L I N G M A T E R I A L
Original Construction Date
K l Monitoring Well
[ D Water Well
n Drillhole/Borehole
Construction Type:
1 3 Drilled
D Other (Specify)
Formation Type:
6/12/1996
If a Well Construction Report is available, please attach.
Pump & Piping Removed?
Liner(s) Removed?
Screen Removed?
Casine Left in Place?
n Yes d l No K Nol Applicable
D Yes • No K Not Applicable
K Yes CH No n Not Applicable
D Yes • No
I I Driven (Sandpoint) D Dug
Was Casing Cut Off Below Surface?
Did Sealing Maierial Rise to Surface?
Did Matenal Settle After 24 Hours?
IfYes, Was Hole Retopped?
n Yes m K Yes D D Yes K D Yes K l
No
No
No
No
12SI Unconsolidated Formation
Total Well Depth rfi) 12.5
6.0
(From groimd surface)
Lower Drillhole Diameter (in.)
Was Well Annular Space Grouted? CD Yes
IfYes, To What Depth?
Depth to Water (Feet).
CH Bedrock
Casing Diameter ( in . ) .
Casing Depth (ft.)
2.00
Required Method of Placing Sealing Material
l2Sl Conductor Pipe - Gravity I I Conductor Pipe - Pumped
I I Screened & Poured I I Other (Explain)
(Bentoniie Chips)
12.5
No I I Unknown
Feet
5.4
Sealing Materials
I I Neat Cement Grout
I I Sand-Cement (Concrete) Groui
I I Concrete
I I Clay-Sand Slurry
I I Bentonite-Sand Slurry
1 ^ Chipped Bentonite
For monitoring wells and
monitoring well boreholes only
I I Bentonite Chips
I I Granular Bentonite
I I Bentonite-Cement Groui
L J Bentonite - Sand Slurry
(5) Sealing Material Used From (Ft.) To (Ft.; Mix Ratio or Mud Weigh!
3/8" Ch ipped benionite Surface 14.0
(6) Comments Overdri l led to 14', backfilled with bentoni te
(7) Name of Person or Firm Doing Sealing Work
Natura l Resource Technology. Inc. Signature of Person Doin ing Work
SUA Street o t ^ o u i e f
23713 W. Paul Rd, Ste. D
' JMJA--mic
Date of Abandonment
10/7/08 Date Signed
Telephone Number
262 .523 .9000 City. State, Zip Code
P e w a u k e e . Wl 53072
FOR DNR OR COUNTY USE ONLY
Date Received Noted By
Comments
E t a t e o f Wiscons in
D e p a r t m e n t o f N a t u r a l R e s o u r c e s
I Route To:
D Solid Waste
D Emergency Response
D Wastewater
D Super fund
D Haz. Waste
n Underground Tanks
D Water Resources
D Other:
I
SOIL BORING LOG INFORMATION Form 4 4 0 0 - 1 2 2 R e v . 5 - 9 2
Page i of i
FacffltyyProiect Name NPSC-MGP/Marinet te, Wl
Ucense/Pennlt/Honltoring Number Borlng MuBber
MH-307
Bor ing Dril led By (Firm name and name of crew chief)
Wisconsin Test Drill ing
Dan Z ie lszowsid
Date Drilling 6/12/96
Sta r ted D a t e Drilling Completed
6 /12 /96 Orllllna Method Hollow Stem A u g e r
DNR Fac i l i t y Well No. HI Unique Well No. CoRiBon Mell Name M H - 3 D 7
Final S ta t i c Hater Level
Feet MSL
S u r f a c e Beva t ion
F e e t MSL Borehoie Diameter 6 inches
Bor ing L i jca t lon
S t a t e Plane
SW 1/4 of NE 1/4 o f Sect ion 6. T30N, R24E
F e e t N
F e e t E Lat Long
Loca l Srid Locat ion (I f applicable)
UN D E U s Un
Coun ty
Mar ine t te
DNR County Code 3B
Civil T o w n / a t y / or VDlage
City o f Mar ine t te
Sample
0) Q. >,
t—
-o fO
MW-3 0 7 - 3
" 5
MW-307-6
MW-3 0 7 - 8
MW-307-10
MW-307-12
24
o 2
6 /4 I3/ ia
14/11 11/13
4/1 I/I — a
IB
4/2 3/7
5/6 9/8
Q. 0)
— 10
— 12
1—14
-16
— 18
— 20
— 22
Soi l /Rock Desc r ip t i on
And Geologic Origin For
Each Major Unit
B" o< Aasphait underlain oy 1.5 tes t large gravel 1111.
FTLL-SANO/GRAVFL: Park Drown, f - c , loose sanas, crs. gravel, red brick, dry to moist.
/ "
SAND: Dark Drown to tJlat:k, f - c , loose well graded sanas, trc. silt with slight odor (not tar odor though).
SAHIXLSILI l Dark red crown, silt w/ f. sands S organic material.
SANHY ni AY- Red Drown to red gray clay till w/ f - c sand, sticky, plastic - hit bedrock at 13 feet.
Hii bearactc at 13 feet - e n a boring at 13 leet.
cn cn 3
10 _ 5i QJ J 5 3: a
Asoh.
SE. GP
SW
(dL SM
CL SC
• - O - i
Soil Properties
c! c
o — o cn
J2 c o o z a
3.8
4.1
Q.8
o o
a o cc o
I he rePy ce r t i f y tha t the information qn this form is t rue and correct to the best of my knowledge.
S igna tu Firm Natural Resource Technology
This form is author ized by Chapters 144.147 and 162, Wis. S ta ts . Completion of this reoort is mandatory . Penalties: Forfei t not less
t h a n SIQ nor more than 35 ,000 for each violation. F ined not less than SIO or more than SIQO or imprisoned not less than 30 cays,
or b o t h for each violat ion. Each day of cont inued v io la t ion is a separate of fense, pursuant to ss 144.99 and 162.06, Wis. Stats.
Stale ofWisconsin Depanment ofNatural Resources
Route To:
SOIL BORING LOG INFORMATION Form 4400-122
Watershed/Wastewater CD
Remediaiion/Redevelopmeni I
Waste Management D
Other D
Rev. 7-98
of 2 Facility/Project Name
Former Marinette MGP Site (1549) License/Permit/Monitonng Number Boring Number
MW-307R Boring Drilled By: Name of crew chief (first, last) and Firm
Paul Boart Longvear
Date Drilling Started
10/7/2004
Date Drilling Compleied
10/7/2004
Drilling Method
hollow Stem auger
Wl Unique Well No. DNR Well ID No. Common Well Name
MW-307R Final Static Water Level
579.1 Feet MSL Surface Elevation
585.1 Feet MSL Borehole Diameter
8.3 inches Local Grid Ongin
State Plane
1/4 of
(estimated: • ) or Boring Location Q]
N , E S / C / N
1/4 of Section , T N. R
Lat .
Long .
Local Grid Location
lEI N lEl E 48820.08 Feel D S 805551 Feet D W
Facility ID
238000047 Counly
Marinette County Code
38 Civil Town/City/ or Village
Marinette
Sample
••h- CJ) o ^ o (o to
_1 Di
o u _o ED
- 3
—4
- 7
- 1 0
- 1 1
- 1 2
Soil/Rock Description
And Geologic Origin For
Each Major Unit
0'-14' Blind drill-lithology taken from log of MW-307. See soil boring log for MW-307 for complete description.
cn U cn
O J
SW
SW
ML
CL
Q c- U cn
Soil Properties
u S- E '3 '3
o
c_ .E O- o
1 hereby certify that the infonnation on this form is true and correct to the besl of my knowledge.
Signature
/.--^>- /3Ue^^ Finn Natural Resource Technology, Inc. 23713 W. Paul Road. Unit D Pewaukee, Wl 53072
Tel: (262) 523-9000 Fax: (262)523-9001
T'' Templaie: WDNR SBL I99K - Frqjeci: 1549GINT.GPJ(_ This form is authorized by Chapters 281. 283. 289. 291. 292, 293. 295. and 299. Wis. Slats. Completion of this form is mandatory. Failure to file this form maN result in forfeiture of between $10 and $25,000, or imprisonment for up lo one year, depending on the program and conduct involved. Personally identifiable information on ihis form is nol intended to be be used for any other purpose. NOTE: See instruciions for more infonnation. including where the compleied fo should be sent.
Slate ofWisconsin Depanment ofNatural Resources
SOIL BORING LOG INFORMATION SUPPLEMENT Fonn 4400-122A
Bonng Number IVTW-SOTR Use only as an attachment to Form 4400-122. Page 2 of
Sample
' ^ < 2
U
CD
Soil/Rock Description
And Geologic Origin For
Each Major Unit cn U cn
CL ra DO •- o 5 Q
D
0) -3
(J on
Soil Properties
a u
- 1 3
•14
CL
^ @ 14'refusal-bedrock END OF BORING (a! 14'
State ofWisconsin Depanment ofNatural Resources
Route To: Watershed/Wastewater D Remediation/Redevelopment I
Waste Management CD Other D
IMONITORING WELL CONSTRUCTION Fonn 4400-113A Rev. 7-98
Facility/Project Name
Fonner Marinette MGP Site (1549)
Local Grid Location of Well
148820.08 ft ^ ^ ' - 805551 , ISE. -fi- D W .
Well Name
MW-307R Facility License, Permit or Moniloring No. Local Grid Origin
Lat. 1
(estimated: Q ) or
Long.
Well Location D
or
Wis. Unique Well No. DNR Well Number
Faciliiv ID St. Plane ft. N, ft. E. S / C / N 238000047 Section Location of Waste/Source
Date Well Installed
10/07/2004 Type of Well
Well Code I 1/mw .1/4 of. 1/4 of Sec. . T.. .N.R.
D E . D W
Distance from Waste/ Source
ft.
Enf. Slds. Apply
Location of Well Relative to Waste/Source u n Upgradient s D Sidegradient
d D Downgradient n D Not Known
Gov. Lot Number
Well Installed By: (Person's Name and Firm)
Paul
Boart Lonavear
A. Protective pipe, top elevation
B. Well casing, top elevalion
C. Land surface elevation
585.07 fl. MSL
584.70 f,. MSL
D. Surface seal, bottom
585.1 ft. MSL
584.1 fl. MSL or '-0 ft.
12.
13.
14
15
16
17
u s e s classification of soil near screen: GP D GMD GCD GWD SWB SP D SMD SC D MLK MHD CLE! CH D Bedrock D
Sieve analysis attached? D Yes B No
Drilling method used: Rotary 0 5 0 Hollow Stem Auger H 4 1
Other n
Drilling fiuid used: Water D 0 2 Air D 0 1 Drilling Mud D 0 3 None 13 9 9
Drilling additives used? D Yes H No
Describe Source of water (attach analysis, if required):
n/a
E. Bentonite seal, top
F. Fine sand, top
G. Filter pack, top
H. Screen joint, top
I. Well bottom
J. Filler pack, bottom
K. Borehole, bottom
L. Borehole, diameter
M. O.D. well casing
N. l.D. well casing
fl. MSL or
582.1 ft. MSL or M .
581-6 fl. MSL or 3.5 ft
581.1 ft MSl.nr 10_ ft.
57L1 fl. MSL or '4.0 ft
57L1 ft. MSL or '4.0 ft
571.1 fl. MSL or '4.0 fl
8.3
2.33
1. Cap and lock?
2. Protective cover pipe:
a. Inside diameter:
b. Length:
c. Maierial:
Yes D No
;.o
d. Additional protection?
If yes, describe:
Steel D
Other S
D Yes B
3. Surface seal: Bentoniie D
Concrete B
_ Other D
in .
L ft.
04
No
30
0 1
4. Material between well casing and protective pipe:
Bentonite D
52nd Other IS
5. Annular space seal: a. Granular/Chipped Bentonite B
b Lbs/gal mud weight. . . Bentonite-sand slurry D
c Lbs/gal mud weight . . . Benionite slurry D
d % Bentonite . . . Bentonite-cement grout D
e Fr volume added forany of the above
How installed: Tremie D
Tremie pumped D
Gravity K
6. Bentonite seal: a. Bentoniie granules D
b, D 1/4 in. D 3/8 in. D 1/2 in. Benionite chips D
c Other D
7. Fine sand material: Manufacturer, product name & mesh i
a #7 Badger
30
33
35
3 1
50
01
02
08
3 3
32
b. Volume added ft
8. Filter pack maierial: Manufacturer, product name & mesh size
#40 Badger
b. Volume added fl'
9. Well casing: Flush threaded PVC schedule 40 El 2 3
Flush threaded PVC schedule 80 D 2 4
Other D
10. Screen matenal:
a. Screen Type:
PVC
Factory cut E 11
Continuous slot D 0 1
Other D _ _ Boart Longvear b. Manufacturer
c. Slot size:
d. Slotted length:
11. Backfill material (below filter pack):
2.07
0.010 ,n
'O-O ft.
None D 1 4
Other K _ _
1 hereby certify thai the information on Ihis fomi is true and conect lo the best of my knowledge. Signature
j : ^ ^ ^ ^ , , .
Firm Natural Resource Technology. Inc. 23713 W. Paul Road. Unil D Pewaukee. Wl 53072
Tel: (262)523-9000 Fax: (262)523-9001
Plea.sc cornffleic both Fonns 4400-1 MA and 4400-113B and rerum them to the appropnaie DNR ofike and bureau. Completion of these reports is required by chis. 160. 28] , 283. 2 291,292. 293. 295. and 299. Wis. Stats., and ch. NR 141. Wis. Adm. Code. In accordance with chs. 281. 2S9. 291. 292. 293. 295. and 299. Wis. Slats., failure to file these foniis may resiili in a forfeiture of berween S10 and S25.000. or imprisonment for up to one year, depending: on the program and conduci involved. Personally idcniifiable infonnation on these fon" is not intended to be used foi any other purpose. NOTE. See ihe instruciions for more infomiation. including where the completed foniis should be sent
Stale of Wisconsin Depanment ofNatural Resources
MONITORING WELL DEVELOPMENT Forni 4400-113B Rev. 7-98
Route To: Watershed/WastewaterCH
Remediation/Redevelopment
Waste ManagemenlD
Other D
Facility/Project Name
Fonner Marinette MGP Site (1549)
County Marinette
Well Name
MW-307R Facility License, Permit or Moniloring Number County Code
38
Wis. Unique Well Number DNR Well Number
1. Can this well be purged dry?
2. Well development method: surged with bailer and bailed surged with bailer and pumped surged with block and bailed surged with block and pumped surged with block, bailed, and pumped compressed air bailed only pumped only pumped slowly other
3. Time spent developing well
4. Depth of well (from top of well casing)
5. Inside diameter of well
6. Volume of water in filter pack and well casing
7. Volume of water removed from well
8. Volume of water added (if any)
9. Source of water added N/A
10. Analysis performed on water added? (If yes, attach results)
Yes D No
D 4 1 D 6 1 D D
42 62
D 70 D 20 D
a D
1 0 5 1 50
66 min.
13.3 ft.
2.07 in.
7.1 gal.
16.0 gal.
0.0 gal.
D Yes D No
11. Depth to Water (from top of well casing)
Date
Time
Before Development After Development
5.88 ft.
10/7/2004
D a.m. 12:55 SI p.m.
8.2 inches
7.59 ft.
10/7/2004
D a.m. 02:01 IS p.m.
12. Sediment in well bottom
13. Water clarity Clear D 10 Clear D 20 Turbid IS 1 5 Turbid K 2 5 (Describe) (Describe)
Dark brown, silty. Light brown, opaque translucent
inches
Fill in if drilling fluids were used and well is at solid waste facility:
mg/I mg/1 14. Total suspended solids
15. COD mg/1 mg/1
16. Well developed by: Person's Name and Firm
Jody Barbeau
Natural Resource Technology, Inc. 17. Additional comments on development:
Pumped dry 7 times during development
Facility Address or Owner/Responsible Party Address
TManie: Shirley Scharff
Firm: Wisconsin Public Service Corporation
Street: 700 N. Adams St. PO Box 19002
Ciiy/Staie/Zip: Green Bay. Wl 54307
I hereby certify that the above information is true and correct to the best of my knowledge.
Signature: /
Pnm Name: Jodv Barbeau
Finn: Natural Resource Technology, Inc.
"NOTE: See iiistnjctions for more infomiation includins a list of countv codes and well tyoe codes.
State ofWisconsin Departmeni of Natural Resources
SOIL BORING LOG INFORMATION Form 4400-122 Rev. 7-98
Route To: Watershed/Wastewater D
Remediation/Redevelopment K
Waste Management CD
Other D
Page of Facility/Project Name
Former Marinette MGP Site (1549) License/Permit/Monitoring Number Boring Number
MW-308 Boring Drilled By: Name of crew chief (first, last) and Firm
Boart Longyear
Date Drilling Started
6/21/2004
Dale Drilling Completed
6/21/2004
Drilling Method
hollow Stem aueer
WI Unique Well No. DNR Well ID No. Common Well Name
MW-308 Final Static Water Level
Feet MSL Surface Elevalion
586.9 Feet MSL Borehole Diameter
8.3 inches Local Grid Origin
State Plane
1/4 of
(estimated: CD ) or Boring Location Q
N , E S / C / N
1/4 of Section T N.R
Lat .
Long.
Local Grid Location
IE! N lEI E 48611.73 Feet D S 805727.28 Feel D W
Facility ID
238000047 County
Marinette County Code
38 Civil Town/City/ or Village
Marinette Sample
1 SS
2
s's
3
ss
4 SS
5 SS
— -a < a
24
24
24 6
24 9
24 16
o U
- 1
-2
-3
-4
-5
-6
-7
-8
1-9
• 1 0
-11
•12
-13
Soil/Rock Description
And Geologic Origin For
Each Major Unit
0-2' ORGANIC SOIL WITH SAND organic material (roots) trees, old asphalt pieces DL/OF
2' - 6'FILL, 2' - 2.3' old asphalt, gravel, 2.3' - 4' Sand seam, red to yellow, fine (a). 3' - 4' Sand with debris(slag, etc.)
4' to 6' Sand with trace clay, debris(glass, slag, broken brick)piedium. no odor, end of spoon wet
8' - 13' POORLY GRADED SAND gray to brown, wet
8' to 10' one-inch lens of wood debris in middle of spoon
END OF BORING (% 13'
^ 15 D
• . OB
S g O cn
Soil Properties
u a 5 c; u
300 1b hammer
1 hereby certify that the information on this form is true and correct lo the best of my knowledge.
Signature Firm NJatural Resource Technology, Inc. . 23713 W. Paul Road, Unil D Pewaukee. Wl 53072
Tel: (262) 523-9000 Fax: (262)523-9001
^ Template: WDNR SBL 1998 - Projeci: ! ,549G1NT.GPJ This fonn is authorized by Chapters 2S1. 2S3. 289. 291. 292. 293. 295. and 299, Wi.s. Stats. Completion of this form is mandator)'. Failure lo file this form ma resull in forfeiture of between JIO and S25.000, or imprisonment for up lo one year, depending on the program and conduci involved. Personally identifiable information on this fomi is nol inlended to be be used for any other purpose. NOTE: See instructions for more information, including where the completed fo should be seni.
State ofWisconsin Department of Namral Resources R ^ ^ , ^ J ^ . Walershed/Waslewaier D Waste Management D MONITORING W E L L CONSTRUCTION
Remediaiion/Redevelopmeni Kl Other D Forni 4400-113A Rev. 7-98
Facility/Project Name
FonnerMannelte MGP Site (1549) Facility License, Permit or Moniloring No.
Facility ID
238000047 Type of Well
Well Code 11/mw Distance from Wasie/ Source „
Enf. Slds. Apply ^
Local Grid Location of Well
148611.73 ft ^ ^ - 805727.28 f, S E . D W ,
Local Grid Origin ^ (esiimated: D ) or Well Local
Lai ° ' " long.
St Plane ft N
Section Location of Wasie/Source
1/4 of IMofSer ,T Location of Well Relative to Wasie/Source
u D Upgradient s D Sidegradient
d D Downaradienl n D Not Known
_ ft. E.
N.R. _
ion D
or
S/C/N
D E
nw Gov, Lot Number
Well Name
MW-308 Wis. Unique Well No. DNR Well Number
Dale Well Installed
06/21/2004 Well Installed By: (Person's Name and Firm)
Mike
Boart Longyear
A. Protective pipe, top elevation
B. Well casing, top elevalion
C. Land surface elevalion
586.94 ft. MSL
586.62 ft, MSL
586.9 ft. MSL
D. Surface seal, bottom 584.4 ft M S L or ^-5 ft.
12
13
14
15
16
17
uses classification of soil
GP D GMD G C D SMD SC D M L D Bedrock D
Sieve analysis attached?
Drilling method used: Holl
Drilling fluid used: Water Drilling Mud
Drilling additives used?
Desrrihe
Source of water (attach ana
near screen:
GWD S W D SP El M H D CL D CH D
D Yes
Rotary ow Stem Auger
Other
DO 2 Air D 0 3 None
D Yes
ysis, if required
D N o
D 5 0 S 4 1
D
D O l
D 9 9
H N o
:
584.4 ft. MSL or L l fl.
583.9 ft. MSL or 1 1 ft.
E. Bentonite seal, top fl. MSL or
F. Fine sand, top ft. MSL or
G. Filter pack, top
H. Screen joint, top
1. Well bottom 573.9 ft M S L or '3.0 ft
J. Filter pack, bottom 573.9 f, MSl.nr '3.0 ft
K. Borehole, bottom 573.4 ft M S L or '3.5 ft
L. Borehole, diameter 8 3 . in.
M. O.D. well casing ---^3 jt,.
N. l.D. well casing --Q^ in.
1. Cap and lock?
- 2. Protective cover pipe:
a. Inside diameter:
b. Lengih:
c. Maierial:
Yes D No
;.o
t£f£JlX d. Additional protection?
If yes, describe:
Steel D
Other K
D Yes la
' 3 . Surface seal Bentonite D
Concrete H
_ Other D
in.
0_ ft.
04
No
30
01
' 4. Material between well casing and protective pipe:
Bentonite D Sand Other 12
Annular space seal: a. Granular/Chipped Bentonite SI
Lbs/gal mud weight. . . Bentonite-sand slurry D
Lbs/gal mud weight. . . Bentonite slurry D
% Bentonite . . . Benionile-cement grout D
Ft voiume added for any of the above
How installed: Tremie D
Tremie pumped D
Gravity IS
Bentonite seal: a. Bentoniie granules H
b. D 1/4 in. D 3/8 in. D 1/2 in. Bentoniie chips D
c Other D
, 7. Fine sand maierial: Manufacturer, product name & mesh size
30
3 3
35
3 I
50
01
02
0 8
33
32
a
b. Volume added ft-
8. Filter pack material: Manufacturer, product name & mesh size
a Red Flint
b. Volume added fl'
9, Well casing: Flush threaded PVC schedule 40 Kl 2 3
Flush threaded PVC schedule 80 D 2 4
Other D
• 10. Screen material:
a. Screen Type:
PVC
Factory cut K 11
Continuous slot D 0 1
Other D _ _ Boart Longyear b. Manufacturer _
c. Slot size:
d. Slotted length;
11. Backfill maierial (below filter pack):
0.010 in
'Q-Q ft.
None D 1 4
Other El
1 hereby certify that the information on this fonn is true and conecl lo the besl of my knowledge.
Natural Resource Technology. Inc. 23713 W. Paul Road. Unit D Pewaukee. Wl 53072
Tel: (262)523-9000 Fax: (262)523-9001
S igna tu r e^ . y ' Z ^ Fi rm
Pfease coniplete both Forms 4400-113A and 4400-113B and return them to the appropriate DNR office and bureau. Completion oi these reports is required by chs. 160. 281. 283. 289, 291.292. 293. 295. and 299. Wis. Siais.. and ch. NR 141. Wis. Adm. Code. In accordance with chs. 281. 289. 291. 292. 293. 295, and 299. Wis. Stats., failure to file these fomis may lesulf jn a forfeiture of hcrv\-een .SIO and 525.000. or impri.sonmeni for up lo one year, dcpendinij on ihc proi:ram and conduct involved. Personally ideniifiabic infonnalion on ihese fom) is nol intended to be used for any other purpose. NOTE: See the instructions for more information, ineludinij where the completed forms should be sent.
State ofWisconsin Department ofNatural Resources
MONITORING W E L L DEVELOPMENT Forni 4400-113B Rev. 7-98
Route To: Watershed/WastewaierD Waste ManagemenlD
Remedialion/Redeve Facility/Project Name
Former Marinette MGP Site (1549) Facility License, Permit or Moniloring Number
opmenS Other D Counly
Marinette County Code
38
Well Name
Wis. Unique Well Number MW-308
DNR Well Number
1. Can this well be purged dry?
2. Well development method:
surged with bailer and bailed
surged with bailer and pumped
surged with block and bailed
surged with block and pumped
surged with block, bailed, and pumped
compressed air
bailed only
pumped only
pumped slowly
other
3. Time spent developing well
4. Depth of well (from top of well casing)
5. Inside diameter of well
6. Volume of water in filter pack and well casing
7. Volume of water removed from well
8. Volume of water added (if any)
9. Source of water added i^'P^
10. Analysis performed on water added?
(If yes, attach results)
D Yes S No
D D D El D D D D D D
4 i
6 1
4 2
6 2
7 0
2 0
1 0
5 1
5 0
6 0 min.
12.6 ft.
2 .07 in.
gal.
6 5 . 0 gal.
0 .0 gal.
D Yes D No
1 1. Depth to Water (from top of
Before Development After Development
well casing)
Dale b.
Time c.
6.30 ft.
6/22/2004
6.44 ft.
6/22/2004
Kl a.m. l l : 5 4 D p . m .
inches
D a.m. 12:54 Ei p.m.
12. Sediment in well bottom
13. Water claniy Clear D 10 Clear El 2 0 Turbid B 1 5 Turbid D 2 5
(Describe) (Describe)
Dark brown, silt
inches
Fill in if drilling fluids were used and well is at solid waste facility:
mg/1 mg/1 14. Total suspended solids
15. COD mg/1 mg/I
16. Well developed by: Person's Name and Firm
Jody Barbeau
Natural Resource Technology, Inc. 17. Additional comments on development:
Water turned clear after approximately 8 gallons removed.
Facility Address or Owner/Responsible Party Address
Name: Shirley Scharff
Finn: Wisconsin Public Service Corporation
Street: 700 "N. Adams St. PO Box 19002
City/Siaie/Zip: Green Bay. W] 54307
1 hereby certify thai the above information is true and correct to the besl of my knowledge.
Signalure: ^ A ^ - ^ ^ ^.w^L^^^ Pnm Name: Jody Barbeau
Finn: Natural Resource Technology, Inc.
NOTE: See instructions for more information includin.s a list of county codes and well type codes.
State ofWisconsin Department ofNatural Resources
Route To: Watershed/Wastewater D
Remediation/Redevelopment [
Waste Management D
Other D
SOIL BORING LOG INFORMATION Fonn 4400-122 Rev. 7-98
Page 1 of 1
Facility/Project Name
Former Marinette MGP Site (1549) License/Permit/Monitoring Number Boring Number
MW-310 Bonng Drilled By: Name of crew chief (first, last) and Firm
Boart Longyear
Date Drilling Started
6/21/2004
Dale Drilling Completed
6/21/2004
Drilling Method
hollow stem auger
Wl Unique Well No. DNR Well ID No. Common Well Name
MW-310 Final Static Water Level
Feet MSL Surface Elevation
585.9 Feet MSL Borehole Diameter
8.3 inches Local Grid Origin
Slate Plane
1/4 of
(estimated: • ) or Bonng Location •
N, E S/C/N 1/4 of Section N.R
La t .
Long .
Local Grid Location
Kl N S E 48714.51 Feet D S 805639.53 Feet D W
Facility ID
238000047 County
Marinette Counry Code
38 Civil Town/City/ OT Village
Marinette Sample
=« o
U
24
15 17 17 19
16 16
14 11 10 4
10 1 1 9
6 9 4
9 1 I 11 9
— 1
'—2
' - 3
- 4
5
- 6
- 7
-8
-9
-10
-11
-12
-13
-14
Soil/Rock Description
And Geologic Origin For
Each Major Unit
0' -8' FILL 0'-0.5' asphalt 0.5' - 6' Poorly graded sand with gravel, brown to black, medium to fine sand, end of spoon moist
(a} 4' Trace silt, scattered debris(slag), moist
6' red brick pieces.slag, possible weathered tar, odor present wet
8'-13' POORLY GRADED SAND gray, medium, trace fine gravel, rounded, water in spoon
13'-14' SILTY LEAN CLAY, tan, hard
END OF BORING O, 14'
Fill
SP
? 5
D u-D
D. P O . U (
Soil Properties
^ i a o C4 u
I hereby certify that the information on this form is true and correcl to the best of my knowledge.
Signature
^ : ^ ^ ^ ^'"^ Natural Resource Technology, Inc.
23713 W. Paul Road, UnitD Pewaukee. Wl 53072 Tel: (262) 523-9000 Fax:(262)523-9001
^ . Template: WDNR SBL 1998 - Prqiect: J549G1NT.GP.I This form is authonzed by Chapters 281. 283, 289. 291, 292,293, 295. and 299, Wis. Stats. Completion of this form is mandatory. Failure to file this form ma> result in forfeiture of between $10 and S25.000, or imprisonment for up to one year, depending on the program and conduct involved. Personally identifiable infomiation on this form is not intended to be be used for any other purpose. NOTE: See instructions for more infomiation. including where the completed fon should be sent.
State ofWisconsin Deparrment of Natural Resources Route To: Watershed/Wastewater D
Remediation/Redevelopment I Waste Management CH Other D
MONITORING WELL CONSTRUCTION Fomi 4400-113A Rev. 7-98
Facility/Project Name
Former Marinette MGP Site (1549)
Local Grid Location of Well , K N . ft- n s . 148714.51 805639.53 ^ S E .
-fl- D W .
Well Name
MW-310 Facility License, Permit or Moniloring No. Local Grid Origin
Lat. 1
(estimated: Q ) o''
Long.
Well Location Q Wis. Unique Well No. DNR Well Number
Facility ID St. Plane ft.N, fl. E. S / C / N
238000047 Section Location of Waste/Source
Date Well Installed
06/21/2004 Type of Well
Well Code 11/mw .1/4 o f . 1/4 of Sec. . -, T. .N, R.
D E . D W
Distance from Waste/ Source
ft.
Enf Stds. Apply
Location of Well Relative to Waste/Source u D Upgradient s D Sidegradient
d D Downeradienl n D Not Known
Gov. Lot Number
Well Installed By: (Person's Name and Firm)
Mike
Boart Longvear
A. Protective pipe, top elevation
B. Well casing, lop elevation
C. Land surface elevation
D. Surface seal, bottom ^"-^-^ ft. MSL or
585.90 ft. MSL
585.50 ft. MSL
585.9 ft. MSL
2.5 ft.
12.
13
14
15
16
17
u s e s classification of soil near screen: GP D GMD GCD GWD SWD SP B SMD SC D MLEl MHD CL El CH D Bedrock D
Sieve analysis attached? D Yes D No
Drilling method used: Rotaiy D 5 0 Hollow Stem Auger K 4 1
Other n
Drilling fluid used: Water D 0 2 Air DOl Drilling Mud D 0 3 None D 9 9
Drilling additives used? D Yes K No
rv<;r-rihp
Source of water (attach analysis, if required):
E. Bentoniie seal, top
F. Fine sand, top
G. Filter pack, top
H. Screen joint, lop
I. Well bottom
J. Filler pack, bottom
K. Borehole, bottom
L. Borehole, diameter
ft. MSL or
ft. MSL or
583.4 ft. MSL or 2.5 ft..
582.9 ft. MSL or l i ft.
572.9 ft. MSL or '3-0 ft. -
571.9 ft. MSL or '4-0 ft.
57L9 ft. MSL or '4.0 ft.
8.3
1 Cap and lock?
•2. Protective cover pipe:
a. Inside diameter:
b. Lengih:
c. Material:
Yes D No
8.0 in.
£ . fl.
0 4
cSrtSfL d. Additional protection?
1 f ves, describe:
Steel D
Other K
D Yes IE No
' 3. Surface seal Bentonite D
Concrete K
_ Other D
30 0 1
4. Maierial between well casing and protective pipe:
Benionite D Sand Other S
- 5. Annular space seal: a. Granular/Chipped Bentonite B
b Lbs/gal mud weight. . . Bentonite-sand slurry D
c Lbs/gal mud weight. . . Bentonite slurry D
d % Bentonite . . . Benloniie-cement grout D
e Ft volume added for any of the above
f. How installed: Tremie D
Tremie pumped D
Gravity K
6. Bentonite seal: a. Bentonite granules K
b. D 1/4 in. D3/8in. D 1/2 in. Bentoniie chips D
c Other D
. 7. Fine sand material: Manufacturer, product name & mesh size
30
3 3
3 5
3 1
5 0
0 1
0 2
0 8
3 3
3 2
b. Volume added ft' . 8. Filter pack material: Manufacturer, product name & mesh size
a Red Flint
b. Volume added ft'
9. Well casing: Flush threaded PVC schedule 40 El 2 3
Flush threaded PVC schedule 80 D 2 4
Other D
10. Screen material:
a. Screen Type:
PVC
Factory cut H 11
Continuous slot D 0 1
Other D Boan Longyear
M. O.D. well casing 2.33 jf,
N. LD. well casing 2.07 jp
b. Manufacturer _
c. Slot size:
d. Slotted length:
1 1. Backfill material (below filter pack):
0.010 ,n.
lQ-0 ft.
None D 14
Other K
I hereby cenify that the information on this form is true and conect to the best of my knowledge. Signaiure
, ^ , / ^ Firm Natural Resource Technology. Inc.
23713 W. Paul Road, Unil D Pewaukee, Wl 53072 Tel: (262)523-9000 Fax: (262) 523-9001
Pleastf compleic both Forms 4400-113A and 4400-113B and rerum them to the appropriate DNR office and bureau. Completion of ihese reports is required by chs. 160. 281. 283. 289 291. 292. 293. 295, and 299, Wis. Stats., and ch. NR 14L Wis. Adm. Code. In accordance with chs. 281. 289. 291. 292. 293. 295. and 299, Wis, Stats., failure to file these forms may resull in a forfeiture of between SIO and S25.000. or imprisonment for up lo one year, depending on the program and conduci involved. Personally identifiable infon^nation on these foi IS noi inlended lo be used for any other purpose. NOTE: See the instructions for more information, including where the completed forms should be seni.
State ofWisconsin Depanment ofNatural Resources
MONITORING WELL DEVELOPMENT Forni 4400-113B Rev. 7-98
Route To: Watershed/WastewaierD
Remediation/Redevelopment Facility/Project Name
Former Marinette MGP Site 11549) Facility License, Permit or Moniionng Number
1. Can this well be purged dr>'?
2, Well development method: suraed with bailer and bailed surged with bailer and pumped surged with block and bailed surged with block and pumped surged with block, bailed, and pumped compressed air bailed only pumped only pumped slowly nthnr
3. Time spent developing well
4. Depth of well (from lop of well casing)
5. Inside diameter of well
6. Volume of water in filter pack and well casing
7. Volume of water removed from well
8. Volume of water added (if any)
0 Sniircp nf water adflprl N/A
D
D D D
D D D D D D
County
Waste ManagemenlD Other D
Marinette County Code
38
Yes 12 No
4 1 61 42 62 70 20 1 0 5 1 50
50 min,
12.6 ft.
2.07 m.
gal.
60.0 gal.
0.0 gal.
Well Name
MW-310 Wis, Unique Well Number DNR Well Number
Before Development After De 1 1, Depth lo Water
(from top of ^ 5Qg^^ well casing)
Date b. 6/21/2004
D a.m. Time c. 03:35 El p.m.
12. Sediment in well inches bottom
13. Water clarity Clear D 10 Clear Turbid H 1 5 Turbid (Describe)
Gray, siltv
velopment
5.72 ft.
6/21/2004
D a.m 04:20 El p.m
D (Describe)
inches
20 25
Fill in if drilling fluids were used and well is at solid waste facility:
14. Total suspended mg/1 solids
15. COD mg/1
16. Well developed by: Person's Name and Firm
mg/1
mg/1
10. Analysis performed on water added? (If yes, attach results)
D Yes D No Jody Barbeau
Natural Resource Technology, Inc. 17. Additional comments on development:
Facility Address or Owner/Responsible Pany Address
Name: Shirley Scharff
Finn: Wisconsin Public Service Corporation
Street: 700 N. Adams SL P Q BOX 19002
Ciiy/State/Zip: Green Bay, WI 54307
I hereby cenify that the above information is true and correct lo the best of my knowledge.
Signature: ^
Pnm Name: Jody Barbeau
Z^^ ^ / 2^^^
Finn: Natural Resource Technoloiry, Inc.
NOTE: See instructions for more information including a list of county codes and well type codes.
State OfWisconsin Department ofNatural Resources
Route To: Watershed/Wastewater D
Remediation/Redevelopment
Waste Management D
Other D
SOIL BORING LOG INFORMATION Fomi 4400-122 Rev. 7-98
Page 1 of 2
Facility/Project Name
Former Marinette MGP Site (1549) License/Permit/Monitoring Number Boring Number
MW-311 Bonng Drilled By: Name of crew chief (first, last) and Firm
Paul Boart Longyear
Date Drilling Started
10/7/2004
Date Drilling Completed
10/7/2004
Drilling Method
hollow stem auger
WI Unique-Well No.
PP724 DNR Well ID No. Common Well Name
MW-311 Final Static Water Level
579.1 Feet MSL Local Grid Origin g ] (estimated: • ) or Boring Location •
State Plane N , E S /C /N
1/4 of 1/4 of Section , T N, R
Surface Elevation
585.6 Feet MSL Borehole Diameter
8.3 inches
Lat .
Long
Local Grid Location
13 N Kl E 148612.58 Ft n S 805565.06 Feet D W
Facility ID
238000047 County
Marinette County Code
38 Civil Town/City/ or Village
Sample
z l
u
Soil/Rock Description
And Geologic Origin For
Each Major Unit cn U cn
O -J m ^ 5 Q
o. S o . U c
Soil Properties
3 C ••— a>
l a J J
Q E C o CJ U
— 1
19 16 0 0
— 4 100 r 0 0 -0 - 5
40 10 5 5
2 2 4 6 1-9
0'-9' FILL. ORGANIC SOIL
@ 1' POORLY GRADED SAND WITH GRAVEL, light brown, fine angular gravel
(^2 ' slightly moist
OL
SP
o •. ,1
m ) : • • • : : • ;
• o : • . • • . . <
):-. (@ 8' weathered tar in sand matrix,
sheen, odor, wet
9'-10'SILTY SAND, gray, fine sand, few organics SM
16 25 25 30
-10 10'-12' POORLY GRADED SAND WITH GRAVEL, fine to medium sand, coarse rounded gravel, organics, wood pieces, plant parts, sheen, odor
SP a
•O;-
•12
1 hereby certifi' that the information on this form is true and conect to the best of my knowledge.
Firm ivjatural Resource Technology, Inc. 23713 W. Paul Road, Suite D. • Pewaukee, WL 53213
Tel: (262) 523-9000 Fax: (262) 523-9001
T Template: WDNR SBL 1998-Proiect: 1549GINT.GP.1 This forni is authorized by Chapters 281, 283, 289, 291, 292, 293, 295, and 299, Wis. Stats. Completion of this fonn is mandatory. Failure to file this form may result in forfeiture of between $10 and $25,000, or imprisonment for up to one year, depending on the program and conduct involved. Personally identifiable infomiauon on this fomi is not intended to be be used for any otlier purpose. NOTE: See instmctions for more information, including where the completed fomi should be sent.
State OfWisconsin Department of Natural Resources
SOIL BORING LOG INFORMATION SUPPLEMENT Form 4400-122A
Boring Number M W - 3 1 1 Use only as an attachment to Form 4400-122. Page 2 of 2
Sample
OJ
•Bf-
E -a
_J Qi
u
Soil/Rock Description
And Geologic Origin For
Each Major Unit cn O cn ca 60
62 = : DO
^ Q
D
D
Soil Properties
u 6
SS 24 12
5 7 9 18 h '
12'-14.5' SILTY SAND, pink to gray, trace fine rounded gravel, hard, odor
ML
- 1 4
Pocket penetrometer: 0.5
END OF BORING (S, 14.5'
State ofWisconsin . Department of Natural Resources „ _ ,,, , , „ , , r—i
Route To: Watershed/Wastewater U Remediation/Redevelopment
Waste Management D M O N I T O R I N G W E L L C O N S T R U C T I O N Other D Form 4400-113A Rev. 7-98
Facility/Project Name
Fonner Marinette MGP Site (1549)
Local Grid Location of Well ft. ^ N . 805565.06 ft. ^ ^ 148612.58
Well Name
MW-311 Facility License, Permit or Monitoring No. Local Grid Origin
Lat. 1
(estimated: • ) or
Long. 1 Facility ID
St. Plane ft.N,
Well Location •
or
.ft. E. S / C / N .
Wis. Unique Well No.
PP724
DNR Well Number
238000047 Section Location of Waste/Source
Date Well Installed
10/07/2004 Type of Well
Well Code 11/mw 1/4 o f . 1/4 of Sec. ,T, .N , R,
D E - D W
Distance from Waste/ Source
ft.
Enf Stds, Apply
Location of Well Relative to Waste/Source u D Upgradieni s D Sidegradient d D Downgradient n D Not Kno-wn
Gov, Lot Number
Well Installed By: (Person's Name and Firm)
Paul
Boan Longyear
585,60 ft. MSL A, Protective pipe, top elevation _
B, Well casing, top elevation _
C, Land surface elevation _
D, Surface seal, bottom 584,6 ft M S L or '-0 ft.
585.20 ft. MSL
585,6 ft. MSL
12
13
14
15
16
17
u s e s classification of soil near screen:
GP D G M D G C D G W D S W D SP El SM El s c D ML El MH D CL D CH D Bedrock D
Sieve analysis attached? D Yes
Drilling method used: Rotary
Hollow Stem Auger Other
Drilling fluid used: Water D 0 2 Air
Drilling Mud D 0 3 None
Drilling additives used? D Yes
Describe
Source of water (attach analysis, if required):
n/a
El No
D 5 0
E14 1
D£l
DO 1 E199
El No
E, Bentonite seal, top
F, Fine sand, top
G, Filter pack, top
H, Screen joint, top
1, Well bottom
J, Filter pack, bottom
K, Borehole, bottom
L, Borehole, diameter
M, 0 ,D, well casing
N, 1,D, well casing
ft, MSL or
582,6 ft. MSL or 3,0
582,1 ft. MSL( J A ft.
58 L6 ft. MSL or ^-0 ft,
571-6 ft. MSL or ' 4 0 ft.
57L1 ft MSL or '4,5 ft
57 ' - ' ft, MSL or '4-5 ft.
8,3
1, Cap and lock?
-2, Protective cover pipe;
a. Inside diameter:
b. Length:
c. Material:
Yes D No
JLL ft.
d. Additional protection?
If yes, describe:
Steel D 04
Other El 'LM
D Yes El No
"3, Surface seal: Bentonite D 3 0
Concrete 01
Other D m
^ 4, Material between well casing and protective pipe:
Bentonite D 3 0 sand Other El S i
•5, Annular space seal: a, Granular/Chipped Bentonite B 33
b Lbs/gal mud weight. , , Bentonite-sand slurry D 3 5
c Lbs/gal mud weight, , , Bentonite slurry D 3 1
d % Bentonite , , , Bentonite-cement grout D 5 0
e Ft volume added for any of the above
f How installed: Tremie D 0 1
Tremie pumped D 0 2
Gravity El 0 8
6, Bentonite seal: a, Bentonite granules D 3 3
b, D l / 4 m . D 3/8 in, D 1/2 in, Bentonite chips D 3_2
c Other D M i
, 7, Fine sand material: Manufacturer, product name & mesh size
a #7 Badger 'Wt
b. Volume added ,ft ' ^ 8, Filter pack material: Manufacturer, product name & mesh size
a #40 Badger j ^
b. Volume added
9, Well casing: .ft '
Flush threaded PVC schedule 40 E
Flush threaded PVC schedule 80 D
Other D
23 24
2.07
10. Screen material:
a. Screen Type:
b. Manufacturer
c. Slot size:
d. Slotted length:
PVC ' ^
Factory cut H 1 1 .
Continuous slot D 0 1
Boart Longvear
11. Backfill material (below filter pack):
Other n »4-
0.010 in
10.0 fl
None D 1 4 O t h e r U •*•«'<
hereby certify that the infonnation on this form is true and conect to the best of my knowledge. Signau-ire C ~-y Fimi Natural Resource Tecluiology, Inc.
23713 W. Paul Road. Suite D. Pewaukee, Wl. 53213 Tel: (262)523-9000 Fa.x: (262)523-9001
Mease complete both Forms 4400-1 13A and 4400-113B and return them to the appropriate DNR office and bureau. Compleiion of these reports is required by chs. 160, 281, 283, 289, 291, 292. 293, 295, and 299. Wis. Stats., and ch. NR 141, Wis. Adm Code. In accordance with chs. 281, 289, 291, 292. 293, 295, and 299. Wis. Stals.. failure to file these forms may result in a t'orfeuure of between $10 and S25.000. or imprisonment for up to one vear, depending on Ihe program and conduct involved. Personally identifiable information on these forms is nol intended to be used for anv other purpose NOTE. See the instriictians for more information, including where the completed forms should be sent.
State of V/isconsin Department ofNatural Resources
MONITORING WELL DEVELOPMENT Fonn 4400-1 !3B Rev. 7-98
Route To: Watershed/Wastewater D
Remediation/Redevelopment t
Waste Management LZl
Other D
Facility/Project Name
Former Marinette MGP Site (1549) County
Marinette
Well Name
MW-311 Facility License, Permit or Monitoring Number County Code
38
Wis. Unique Well Number
PP724 DNR Well Number
1. Can this well be purged dry?
2. Well development method:
surged with bailer and bailed
surged with bailer and pumped
surged with block and bailed
surged with block and pumped
surged with block, hailed, and pumped
compressed air
bailed only
pumped only
pumped slowly
other
3. Time spent developing well
4. Depth of well (from top of well casing)
5. Inside diameter of well
6. Volume of water in filter pack and well casing
7. Volume of water removed from well
8. Volume of water added (if any)
9. Source of water added N/A
10. Analysis performed on water added?
(If yes, attach results)
El Yes D No
D 4 1
D 6 1
D 42
D 62
D 70
D 20
D 1 0
El 5 1
D 50
D m
155 mm.
14.3 ft.
2 .07 in.
7.5 gal.
9.0 gal.
0.0 gal.
D Yes D No
Before Development After Development 11
12
13
Depth to Water (from top of well casing)
Date
Time
Sediment in well bottom
Water clarity
a.
b.
c.
Clear Turbid
6.44 ft.
10/8/2004
H a.m. 07:13 D p.m.
2.9 inches
D 1 0 Clear El 1 5 Turbid
12.90 ft.
10/8/2004
El D
(Describe) (Describe)
Dark brown, silty. opaq ue, odor
Ei a.m 09:48 D p.m
inches
20 25
Fill in if drilling fluids were used and well is at solid waste facility:
mg/1 14. Total suspended solids
15. COD mg/I
mg/1
mg/1
16. Well developed by: Person's Name and Firm
Jody Barbeau
Natural Resource Technology, Inc. 17. Additional comments on development:
Pumped dry 5 times during development, took approximately 2.5 hours to recover.
Facility Address or Owner/Responsible Party Address
Name: Shirley Scharff
Firni: Wisconsin Public Service Corporation
Street:
City/State/Zip: Green Bay, Wl 54307
700 N. Adams St. PO Box 19002
1 hereby certify that the above information is true and conect to the best of my knowledge.
Signature: ~ ^
/ i ^ < ^ ^ Z ^ - ^ - " - -
Pnnt Name: Jody B a r b e a u
Fimi: Natural Resource Technology, Inc.
NOTE: See instructions for more information including a list of county codes and well type codes.
State ofWisconsin Depanment ofNatural Resources
SOIL BORING LOG INFORMATION Forni 4400-122 Rev, 7-98
Route To: Watershed/Wastewater d
Remediation/Redevelopment S
Waste Management D
Other D
Page of 2 Faciliiy/Project Name
Former Marinette MGP Site (1549) License/Permit/Moniloring Number Boring Number
P-305 Boring Drilled By: Name of crew chief (first, last) and Firm
Boart Longyear
Dale Drilling Started
6/21/2004
Date Drilling Completed Drilling Method
6/22/2004 hsa/air rotary Wl Unique Well No, DNR Well ID No, Common Well Name
P-305 Final Static Water Level
Feet MSL Surface Elevalion
587.0 Feet MSL Borehole Diameter
6.1 inches Local Grid Ongin ^ (estimated: • ) or Bonng Location •
State Plane N , E S / C / N
1/4 of 1/4 of Section , T N.R
Lat .
L o n g .
Local Grid Location
Kl N M E j|48612.26 Feet D S 805734,08 Feet D W
Facilily ID
238000047 County
Marinette County Code
38 Civil Town/City/ or Village
Marinette Sample
< ^ . =
o
-9
-10
1—11
-12
-13
•14
-15
Soil/Rock Description
And Geologic Origin For
Each Major Unit
0'-6'FILL, (ORGANIC SOIL WITH SAND), organic material (roots) trees, old asphalt pieces
@ 2' asphalt and gravel @ 2.3' - 4' (POORLY GRADED SAND), red to yellow, fine @ 3' Sand with slag, bricks, and gravel (@ 4' trace clay,glass, slag, broken brick medium sand, no odor
"\(S, 6' wet 6' - 12' POORLY GRADED SAND gray to brown, wet
(5) 9' one-inch lense of wood
12'- 17' WELL GRADED SAND WITH GRAVEL brown, medium with trace rounded gravel,
14' - 17'POORLY GRADED SAND medium brown, trace gravel,
cn U cn Z)
Fill (OL)
Fill (SP)
SP
SW
Q C L
y.-y. • • a t . ' . '
CL
o . O c
Soil Properties
S u D S O 5 oi U
4 1/4 HSA
Refusal for Hollow Stem Auger,Change| to Air Rotary
I hereby certify that the infonnation on this form is true and conect to the besl of my knowledge.
Signature
"A^^ ^ /3^. Firm "Natuj-al Resource Technology, Inc. 23713 W. Paul Road. UnitD Pewaukee, Wl 53072
Tel: (262) 523-9000 Fax: (262)523-9001
W Template: WDNR SBL 199K-Hroiecl: 1549G1NT.GP, This form is authorized by Chapters 281, 283. 289, 291, 292, 293, 295. and 299, Wis. Stats. Completion of this form is mandatory. Failure lo file this form maT resull in forfeiture of between SIO and £25.000. or imprisonment for up lo one year, depending on the program and conduci involved. Personally identifiable information on this fonn is nol intended lo be be used for any other purpose. NOTE: See instructions for more infonnation, including where ihe completed foi should be sen
State ofWisconsin Depanment ofNatural Resources
SOIL BORING LOG INFORMATION SUPPLEMENT Fonn 4400-122 A
Boring Number P - 3 u 5 Use-only as an attachment to Form 4400-12 22. Page 2 of 2
Sample
Z 5 -1 Qi
U
m
Soil/Rock Description
And Geologic Origin For
Each Major Unil
a J ? Q
a u. D o iz
U cn
Soil Properties
2 u a o
16
•17
h i s
-19
-20
-21.
-22
-23
-24
-25
-26
-27
12' - 17' WELL GRADED SAND WITH GRAVEL brown, medium with trace rounded gravel,(continued) grinding on rock fragments weathered surface of bedrock, moist
bedrock, fractured, weathered chips, wet
22' - 25' competent bedrock, no discussable fractures, wet
6" fracture, rods "dropped" through faster large amounts of steady water and pressure Tar @ 27', tar droplets present in water
Afrom cuttings f END OF BORING @ 27.5'
HSA Refusal @ 17', Change to 6" Air Rotary
Slate ofWisconsin Departmeni of Namral Resources „ -n „ , , j / , , , rn
Route To: Watershed/Wastewater U Remediation/Redevelopment I
Waste Management D MONITORING WELL CONSTRUCTION Other D Form 4400-113A Rev. 7-98
Facility/Project Name
Fonner Marinette MGP Site (1549)
Local Grid Location of Well
148612.26 IN jl. ^!,^- 805734.08 f, ^ W^
Well Name
P-305 Facility License, Permit or Moniloring No. Local Grid Origin
o
Lat.
(estimated: • ) or
Long.
Well Location •
or
Wis, Unique Well No, DNR Well Number
Facilily ID St. Plane ft.N, ft.E, S / C / N 238000047
Type of Well
Well Code 12/p2
Section Location of Waste/Source
1/4 of 1/4 of Sec
Dale Well Installed
06/22,/2004
, T. .N .R. D E
_D W
Distance from Waste/ Source ft.
Enf Slds, Apply
Location of Well Relative to Waste/Source u D Upgradient s D Sidegradieni
d D Downgradient n D Nol Known
Gov, Lot Number
Well Installed By: (Person's Name and Firm)
Boart Lonsjvear
586,96 ft. MSL A. Protective pipe, top elevalion _
B. Well casing, lop elevation _
C. Land surface elevation _
D. Surface seal, bottom 584.5 ft. MSL or L l . ft.
586.96 ft. MSL
587.0 ft. MSL
12,
13.
14
15
16
17
u s e s classification of soil near screen:
GP D GMD G C D GWD S W H SP El S M D SC D M L D MHD CL D CH D Bedrock K
Sieve analysis attached? D Yes D No
Drilling method used: Rotary D 5 0
Hollow Stem Auger S 4 1 Air rotary Other Kl
Drilling fluid used: Water D 0 2 Air D 0 1
Drilling Mud D 0 3 None D 9 9
Drilling additives used? D Yes S No
DpRrrihe
Source of water (attach analysis, if required):
E. Bentoniie seal, top
F. Fine sand, lop
G. Filler pack, top
H. Screen joint, lop
I. Well bottom
ft. MSL or
ft. MSL or
584.5 fl, MSLor 2.5 ^
565,0 ft. MSL or ^2.0 ft.
560.0 ft. MSL or 27.0 ft.
J. Filler pack, bottom 559.5 f, M ^ I nr 27.5 ft
K. Borehole, bottom 559.5 ft M,S1 or 27.5 ft
L. Borehole, diameter "-' in.
M, C D , well casing 2,33 jn
N. l.D, well casini; 2.07 j^i.
1, Cap and lock?
-2, Prolective cover pipe:
a. Inside diameter:
b. Length:
c. Material:
Yes D No
8.0 in.
1 . ft, 0 4
LStLiStt.
•:-j:
d. Additional protection?
If yes, describe:
Steel D
Other B _ _
D Yes E) No
' 3. Surface seal: Bentoniie D
Concrete K
_ Other D
30 0 1
' 4 . Material between well casing and protective pipe:
Benionite D Sand Other Kl
• 5, Annular space seal: a, Granular/Chipped Benionite K
b Lbs/gal mud weight. . . Bentonite-sand slurry D
c Lbs/gal mud weight. . . Bentonite slurry D
d % Bentoniie . . , Benionile-cement grout D
e Ft' volume added forany of the above
f How installed: Tremie D
Tremie pumped D
Gravity S
6, Bentonite seal: a. Benionite granules K
b. D 1/4 in. D3/8in . D 1/2 in. Bentoniie chips D
c Other D
, 7, Fine sand material: Manufacturer, product name & mesh size
30
3 3
3 5
3 1
5 0
0 1
0 2
0 8
3 3
3 2
b. Volume added ft' 8, Filter pack material: Manufacturer, product name & mesh size
a Red Flint
b. Volume added ft'
9, Well casing: Flush threaded PVC schedule 40 B 2 3
Flush threaded PVC schedule 80 D 2 4
Other D _ _
• 10, Screen material:
a. Screen Type:
PVC
Factory cut B 11
Continuous slot D 0 1
Other D Boart Longvear b. Manufacturer _
c. Slot size:
d. Slotted length:
11, Backfill material (below filter pack):
0,010
l A . ft. None D 1 4
Other Kl
1 hereby certify thai the information on this form is irue and correct lo the besl of my knowledge. Signaiure ure ^ Firm Natural Resource Technology. Inc.
23713 W. Paul Road, Unit D Pewaukee. Wl 53072 Tel: (262)523-9000 Fa.x: (262)523-9001
Please coinpleie both Forms 4400-1 13A and 4400-1 13B anci rerum them to the appropnaie DNR office and bureau. Compleiion of these rcport.s is required by chs. 160. 281. 283. 289 291, 292. 293. 295. and 299. Wis. Stats., and ch. NR 141. Wis. Adm. Code. In accordance with chs. 281. 289. 291. 292. 293. 295. and 299. 'iVis. Slats., failure lo file these forms may resull in a forleiiurc of between SIO and S25.000. or imprisonment for up to one year, dependini; on the program and conduci involved. Personally identifiable infon-naiion on these fonl i.s noi inlended lo be used for any oihcr purpose. NOTE: Sec the instructions for more mfomtaiion. includinL' where the compleied forms should be seni.
Natural Resource Technoloiiv
MONITORING WELL DEVELOPMENT
N R r
Facility/Project Name
Former Marinette MGP Site (1549) County
Marinette Well Name
P-305 Facility License, Pennit or Monitoring Number Slate Unique Well Number Well Number
1. Can this well be purged dry?
2. Well development method:
surged with bailer and bailed
surged with bailer and pumped
surged with block and bailed
surged with block and pumped
surged with block, bailed, and pumped
compressed air
bailed only
pumped only
pumped slowly
other
3 Time spent developing well
4. Depth of well (from top of well casing)
5. Inside diameter of well
6 Volume of water in filter pack and well casing
7 Volume of water removed from well
8. Volume of water added (if any)
9. Source of water added
10. Analysis performed on water added?
(If yes, attach results)
D Yes 0 No
D 4 1
D 6 I
D 42
D 62
D 70
D 20
D 1 0
B 5 I
D 50
D Wl
62 min.
26.6 ft.
2 .07 in.
gal.
50 .0 gal.
gal.
D Yes D No
Before Development After Development 11. Depth to Water
(from top of well casing)
Date b.
Time
7.19 ft.
7/6/2004
M a.m. 08:30 D p.m.
12. Sediment in well bottom
13. Water clarity Clear H 1 0
Turbid D 1 5
(Describe)
inches
7.37 ft.
7 / 6 / 2 0 0 4
El a.m. 0 9 : 3 2 D p.m.
inches
Clear IS 2 0
Turbid 0 2 5
(Describe)
Fill in if drilling fluids were used and well is at solid waste facility:
mg/I 14. Total suspended solids
15. COD mg/1
mg/I
mg/1
16. Well developed by: Person's Name and Firm
Jody Barbeau
Natural Resource Technology, Inc. 17. Additional comments on development:
Facility Address or Owner/Responsible Party Address
NpniP Shirley Scharff
Firm Wisconsin Public Service Corporation
.Street 700 N. Adaois St. PO Box 19002
ri,v/s;tn,e./7ip- Green Bay, WI 54307
1 hereby certiiy that the above information is true and correct to the best of my knowledge.
.lon.n.r.- J ^ ^ / / ? ^ - a - - ^ Jody Barbeau
Pnri.N.mP Jody Bafbeau
Firm- Natural Resource Technology, Inc.
1 einplale: NRT WELL DEVELOPMENT - Projeci 1549G1NT.GPJ
. APPENDIX B
JANUARY 2005 SURVEY DATA
Appendix B November 2004 Groundwater Quality Update • 1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS #.- 02-38-000047
Field Survey Completed by Wisconsin Public Service Corporation Survey Group Horizontal Datum is Marinette County Coordinates Vertical Datum is NGVDSS
Field Survey Conducted on January 21, 2005.
Location ID MW3R MW307R MW308 MW310 MW311 P305
Northing 148447.37 148820.08 148611.73 148714.51 148612.58 148612.26
Easting 805728.41 805551.00 805727.28 805639.53 805565.06 805734.08
Grd. Elev. 585.68 585.07 586.94 585.90 585.60 586.96
T/Casing 585.68 585.07 586.94 585.90 585.60 586.96
T/PVC 585.50 584.70 586.62 585.50 585.20 586.96
1549GWQualityDataNovember04 App B - Survey Data Page 1 of 1 s NMURAL
APPENDIX C
LABORATORY ANALYTICAL REPORTS
/ x « ( ace Analytical REVISED 1241 Bellevue Street, Suite 9
Green Bay, Wl 54302
920-469-2436, Fax: 920-469-8827
Analytical Report Number: 853784
Client: NATURAL RESOURCE TECHNOLOGY, INC.
Project Name: WPSC - MARINETTE
Project Number: 1549
Lab Contact: Tom Trainor
Lab Sample Number Field ID
853784-001 MW-302
853784-002 MW-303
853784-003 MW-304
853784-004 MW-305
853784-005 MW-306
853784-006 MW-307R
853784-007 MW-308
853784-008 MW-310
853784-009 MW-1
853784-010 MW-311
B53784-011 MW-3R
853784-013 MW-5
853784-014 P-302
853784-015 P-303
853784-017 P-305
853784-018 QC-1
853784-019 QC-2
853784-020 TRIP BLANK
Collect ion Matrix Date
WATER 11/22/04
WATER 11/22/04
WATER 11/22/04
WATER 11/22/04
WATER 11/22/04
WATER 11/22/04
WATER 11/22/04
WATER 11/22/04
WATER 11/22/04
WATER 11/22/04
WATER 11/22/04
WATER 11/22/04
WATER 11/22/04
WATER 11/22/04
WATER 11/22/04
WATER 11/22/04
WATER 11/22/04
WATER 11/22/04
I certify that the data contained In this Final Report has been generated and reviewed In accordance with approved methods and Laboratory Standard Operating Procedure. Exceptions, If any, are discussed in the accompanying sample comments. Release of this f inal report is authorized by Laboratory management, as is verif ied by the fo l lowing signature. This report shall not be reproduced, except in ful l , without the wri t ten consent of Pace Analytical Services, Inc. The sample results relate only to the analytes of Interest tested.
y ] d 4 y < ^ ^ 1'?-o5~ Approval Signature Date
En Chem A Division of Pace Analytical Services, Inc.
Client: NATURAL RESOURCE TECHNOLOGY, INC
Project Name : WPSC - MARINETTE
Project Number : 1549
Analytical Report Number: 853784 1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collection Date : 11/22/04 Report Date : 12/07/04
Field ID :
I N O R G A N I C S
Test
MW-302
Result LOD LOQ EQL Dll. Units
Lab Sample Number : 853784-001
Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 + N 0 2
Sulfate
920
130
250
< 0.063
52
17
0.14
8.3
0.063
0.36
55
0.48
28
0.21
1.2
ug/L
ug/L
mg/L
mg/L
mg/L
11/30/04
11/30/04
12/01/04
12/07/04
11/24/04
SW846 6010B
SW846 601 OB
EPA 310.2
EPA 353.2
EPA 300.0
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
PVOC
Analyte Result LOD LOQ EQL Dll. Units Code Anl Date
Prep Date: 11/24/04
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trlfluorotoluene
0.61
< 0.40
4.6
8.6
< 0.36
< 0.36
4.4
1.8
99
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
Q
Q
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 503OB
SW846 5030B
SW846 5030B
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846M8021
SW846 M8021
SW846 M8021
SW845 M8021
M E T H A N E
Analyte
Methane
P A H / PNA
Analyte
Result
220
Result
LOD
LOD
LOQ
LOQ
EQL
10
EQL
Dil .
1
Dll .
Units
ug/L
Units
Code Anl Date
12/01/04
Code Anl Date
Prep Date: 12/01/04
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 11/24/04
Prep Method Anl Method
1 -Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Diben2(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
< 4.0
< 4.5
5.3
27
45
70
80
45
42
47
59
13
110
4.9
39
13
22
78
0
0
0
4.0
4.5
3.9
3.9
3.5
3.9
3.6
3.6
4.1
3.9
3.3
4.4
6.6
4.4
3.4
4.5
4.1
3.3
13
15
13
13
12
13
12
12
14
13
11
15
22
15
11
15
14
11
200
200
200
200
200
200
200
200
200
200
200
200
400
200
200
200
200
200
200
200
200
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
% Recov
% Recov
Q
* '
Q*
D
Q
• Q
D
D
D
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
12/01/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 35IOC
SW846 35IOC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C.-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem Analytical Report Number: 853784 A Division of Pace Analytical Services, Inc.
C l i en t : NATURAL RESOURCE TECHNOLOGY, INC.
Project Name : WPSC - MARINETTE
Pro jec t Number : 1549
Field ID : MW-303
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collect ion Date ; 11/22/04
Report Da te : 12/07/04
Lab Sample Number : 853784-002
I N O R G A N I C S
Test Result LOD LOQ EQL Dll. Units Code Anl Date Prep Mett iod Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03- i -N02
Sulfate
8900
1300
600
0.063
24
17
0.14
17
0.063
0.36
55
0.48
56
0.21
1.2
ug/L
ug/L
mg/L
mg/L
mg/L
11/30/04
11/30/04
12/01/04
12/07/04
11/24/04
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
P V O C
Analyte Result LOD LOQ EQL DiL Units Code Anl Date
Prep Date: 11/24/04
Prep Method Anl Method
1,2,4-Trimethylben2ene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trifluorotoluene
1 -Methylnaphthalene
2-l\/lethylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indenod ,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
0.39
0.40
0.14
0.40
0.36
0.36
036
0.74
99
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW84B
SW846
5030B
5030B
5030B
5030B
5030B
5030B
5030B
5030B
5030B
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846M8021
SW846 M8021
SW846 M8021
SW846 M8021
METHANE
Analyte
Methane
PAH/ PNA
Analyte
Result
850
Result
LOD
LOD
LOQ
LOQ
EQL
50
EQL
Dil.
5
Dil.
Units
ug/L
Units
Code
Code
Anl Date
12/01/04
Anl Date
Prep Date: 12/01/04
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 11/24/04
Prep Method Anl Method
0.020
0.023
0.46
0.060
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.032
0.022
0.017
0.032
0.020
0.035
88
61
62
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.017
0.022
0.017
0.022
0.020
0.016
0.067
0.076
0.065
0.065
0.059
0.066
0.061
0.060
0.069
0.065
0.055
0.074
0.055
0.073
0.057
0.075
0.068
0.054
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
% Recov
%Recov
%Recov
11/29/04
11/29/04
11/29/04
Q 11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
Q 11/29/04
11/29/04
11/29/04
Q 11/29/04
11/29/04
Q 11/29/04
11/29/04
11/29/04
11/29/04
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 35IOC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 35IOC
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 351 OC
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
B270C-SIM
8270C-SIM
8270C-SIM
S270C-SIM
8270C-SIM
8270C-S1M
8270C-SIM
8270C-S1M
8270G-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem Analytical Report Number: 853784 A Division of Pace Analytical Services, Inc.
Client: NATURAL RESOURCE TECHNOLOGY, INC.
Project Name : WPSC - MARINETTE
Project Number: 1549
Field ID : MW-304
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collection Date : 11/22/04
Report Date : 12/07/04
Lab Sample Number: 853784-003
INORGANICS
Test Result LOD LOQ EQL Dll. Units Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 -(• N02
Sulfate
190
250
220
0.064
490
17
0.14
8.3
0.063
3.6
55
0.48
28
0.21
12
ug/L
ug/L
mg/L
mg/L
0 mg/L
Q
11/30/04
11/30/04
12/01/04
12/07/04
11/30/04
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 6010B
SW846 601OB
EPA 310.2
-EPA 353.2 •
EPA 300.0
PVOC
Analyte Result LOD LOQ EQL Dil. Units
Prep Date: 11/24/04
Code Anl Date Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m -i- p
a.a,a-Trifluorotoluene
1.8
0.73
29
5.9
< 0.36
5.1
4.0
4.6
98
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
0
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846M8021
SW845M8021
SW846M8021
SW846 M8021
SW846M8021
SW846M8021
SW846 M8021
SW846 M8021
SW846M8021
M E T H A N E
Analyte
Methane
P A H / P N A
Analyte
Result
33
Result
LOD
LOD
LOQ
LOQ
EQL
10
EQL
Dil.
1
Dil.
Units
ug/L
Units
Code
Code
An l Date
12/01/04
Anl Date
Prep Date: 12/01/04
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 11/24/04
Prep Method Anl Method
1 -Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
< • <
< < < < < < < < < < < <
< <
2.5
2.3
1.9
1.9
1.8
2.0
1.8
1.8
2.1
1.9
1.6
2.2
1.7
2.2
1.7
27
2.0
1.6
0
0
0
2.0
2.3
1.9
1.9
1.8
2.0
1.8
1.8
2.1
1.9
1.6
2.2
1.7
2.2
1.7
2.2
2.0
1.6
6.7
7.6
6.5
6.5
5.9
6.6
6.1
6.0
6.9
6.5
5.5
7.4
5.5
7.3
5.7
7.5
6.8
5.4
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
ug/L Q 11/30/04
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov D
%Recov D
%Recov D
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11 /30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
SW846 3510C
SW846 3510C
SW846 35IOC
SW846 3510C
SW846 3510C
SW846 3510C
SW845 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 35IOC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
8270C-SIIV1
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SiM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SIIVI
8270C-SIM
8270C-SIM
En Chem A Division of Pace Analytical Services, Inc.
C l ient : NATURAL RESOURCE TECHNOLOGY, INC
Project Name : WPSC - MARINETTE
Project Number : 1549
Field ID : MW-305
Analytical Report Number: 853784 1241 Bellevue Street Green Bay, Wl 54302 920^69-2436
Matrix Type: WATER
Collection Date : 11/22/04
Report Date : 12/07/04
Lab Sample Number : 853784-004
I N O R G A N I C S
Test Result LOD LOQ EQL Dil. Units Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 + N02
Sulfate
26
0.45
270
4.3
34
17
0.14
8.3
0.063
0.36
55
0.46
28
0.21
1.2
ug/L
ug/L
mg/L
mg/L
mg/L
Q
Q
11/30/04
11/30/04
12/01/04
12/07/04
11/24/04
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 601 OB
SW846 601 OB
EPA 310.2
EPA 353.2
EPA 300.0
PVOC
Analyte Result LOD LOQ EQL Dil. Units
Prep Date: 11/24/04
Code Anl Date Prep Method Anl Method
1,2,4-Trimethylben2ene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a.a.a-Trlfluorotoluene
< < < < < < < <
0.39
0 4 0
0.14
0.40
0.36
0.36
036
0.74
100
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
M8D21 M8021 M8021 M8021 M8021 M8021 M8021 M8021 M8021
M E T H A N E
Analyte
Methane
P A H / PNA
Analyte
Result
< 10
Result
LOD
LOD
LOQ
LOQ
EQL
10
EQL
Dil.
1
Dil.
Units
ug/L
Units
Code
Code
Anl Date
12/01/04
Anl Date
Prep Date: 12/01/04
Prep Method Anl Method
SWB46M8015 SW846M8015
Prep Date: 11/24/04
Prep Method An l Method
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo{k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
< < < < < < < < < < < <
< < < < <
0.020
0.023
0.019
0 019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.018
0.022
0.017
0.022
0020
0.016
56
40
58
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.022
0.020
0.016
0.066
0.076
0.065
0.064
0.059
0.065
0.060
0.060
0.069
0.064
0.055
0.073
0.055
0.073
0.057
0.075
0.068
0.054
1 ug/L
1 ug/L
•ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
ug/L Q 11/29/04
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%ReGOV
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
SW846 3510C
SW846 3510C
SW846 3510C
SW846 35100
SW846 351 OC
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 35100
SW846 351 OC
SW846 351 OO
SW846 3510C
SW846 351 OC
SW846 3510O
SW846 351 OO
SW846 35100
SW846 35100
SW846 35100
SW846 351 OC
SW846 3510C
SW846 3510C
6270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
8270C-SIM
8270C-S1M
8270C-SIM
8270C-SIM
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
5270C-SIM
En Chem A Division of Pace Analytical Sen/ices, Inc.
C l i en t : NATURAL RESOURCE TECHNOLOGY, INC
Project Name : WPSC - MARINETTE
Project Number : 1549
Analytical Report Number: 853784 1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collection Date : 11/22/04
Report Date : 12/07/04
Field ID :
INORGANICS
Test
MW-306
Result LOD LOQ EQL Dil. Units
Lab Sample Number : 853784-005
Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 -i- N02
Sulfate
4500
390
350
< 0.063
9.8
17
0.14
8.3
0.063
0.36
55
0.48
28
0.21
1.2
ug/L
ug/L
mg/L
mg/L
mg/L
11/30/04
11/30/04
12/01/04
12/07/04
11/24/04
SW846 601 OB
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
PVOC
Analyte Result LOD LOQ EQL Dll. Units Code Anl Date
Prep Date: 11/24/04
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trlfluorotoluene
5.5
< 0 4 0
0.20
0.41
< 0.36
< 0.36
2.3
< 0.74
100
0.39
0 40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
Q
Q
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
SW846 503OB
SW846 5030B
SW846 5030B
SW846 5030B
SW846 503OB
SW846 5030B
SW846 503OB
SW846 5030B
SW846 503OB
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
METHANE
Analyte
Methane
PAH/ PNA
Analyte
Result
43
Result
LOD
LOD
LOQ
LOQ
EQL
10
EQL
DiL
1
Dil.
Units
ug/L
Units
Code
Code
Anl Date
12/01/04
Anl Date
Prep Date: 12/01/04
Prep Method An l Method
SW846 M8015 SW846 M8015
Prep Date: 11/24/04
Prep Method Anl Method
1 -Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno{1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nltrobenzene-d5 •
2-Fluorobiphenyl
Terphenyl-d14
<
< < < < < < < < <
<
<
1.8
0.023
0.18
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.035
0.031
0.017
0.37
0.020
0.24
82
59
61
0.10
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.022
0.020
0.016
0.33 5 ug/L
0.076
0.065
0.064
0.059
0.065
0.060
0.060
0.069
0.064
0.055
0.073
0.055
0.073
0.057
0.075
0.068
0.054
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
D
* *
• 0
0
*
12/01/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
SW846 351 OC
SW846 351 OC
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 351 OC
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem A Division of Pace Analytical Services, Inc.
Client: NATURAL RESOURCE TECHNOLOGY, INC
Project Name : WPSC - MARINETTE
Project Number: 1549
Analytical Report Number: 853784 1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER Collection Date : 11/22/04
Report Date : 12/07/04
Field ID :
I N O R G A N I C S
Test
MW-307R
Result LOD LOQ EQL Dil. Units
Lab Sample Number : 853784-006
Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N 0 3 + N02
Sulfate
20000
2300
650
< 0.063
5.3
17
0.14
17
0.063
0.36
55
0.48
56
0.21
1.2
1
1
2
1
1
ug/L
ug/L
mg/L
mg/L
mg/L
11/30/04
11/30/04
12/01/04
12/07/04
11/24/04
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
PVOC
Analyte Result LOD LOQ EQL Dll. Units Code Anl Date
Prep Date: 11/24/04
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a.a-Trifluorotoluene
<
< < < < <
0.69
0.40
0.61
0.40
0.36
0.36
0.36
0.74
100
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
Q 11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
M E T H A N E
Analyte
Methane
P A H / P N A
Analyte
Result
4100
Result
LOD
LOD
LOQ
LOQ
EQL
500
EQL
Dil .
50
Dil .
Units
ug/L
Units
Code
Code
Anl Date
12/01/04
Anl Date
Prep Date: 12/01/04
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 11/24/04
Prep Method Anl Method
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
6.0
0.84
7.4
0.25
1.0
0.50
0.31
0.18
0.15
0.17
0.34
0.053
1.8
2.5
0.14
3.2
4.8
1.6
91
60
56
0.50
0.57
0.48
0.019
0.44
0.49
0.018
0.018
0.021
0.019
0.016
0.022
0.41
0.54
0.017
0.56
0.51
0.41
1.7
1.9
1.6
0.064
1.5
1.5
0.060
0.060
0.069
0.064
0.055
0.073
1.4
1.8
0.057
1.9
1.7
1.4
25
25
25
1
25
25
1
1
1
1
1
1
25
25
1
25
25
25
1
1
1
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
D
QD
D
QD
QD
* •
•
Q-
D
D
• D
D
D
12/01/04
• 12/01/04
12/01/04
11/30/04
12/01/04
12/01/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
12/01/04
12/01/04
11/30/04
12/01/04
12/01/04
12/01/04
11/30/04
11/30/04
11/30/04
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 35IOC
SW846 35IOC
SW846 351 OC
SW846 3510C
SW846 35IOC
SW846 351 OC
SW846 3510C
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
82700-SIM
8270C-SIM
e270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem A Division of Pace Analytical Services, Inc.
C l i en t : NATURAL RESOURCE TECHNOLOGY, INC
Project Name : WPSC - MARINETTE
Project Number : 1549
Analytical Report Number: 853784 1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collection Date : 11/22/04
Report D a t e : 12/07/04
Field ID :
I N O R G A N I C S
Test
MW-308
Result LOD LOQ EQL Dil . Units
Lab Sample N u m b e r : 853784-007
Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 + N02
Sulfate
710
1500
590
0.063
25
17
0.14
17
0.063
0.36
55
0.48
56
0.21
1.2
ug/L
ug/L
mg/L
mg/L
mg/L
11/30/04
11/30/04
12/01/04
12/07/04
11/24/04
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 5010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
PVOC
Analyte Result LOD LOQ EQL Dil . Units Code Anl Date
Prep Date: 11/24/04
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Tnmethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Tritluorotoluene
<
< < <
<
0.90
0.40
0.61
0.40
0.36
0.36
1.0
0.74
99
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1,2
1.2
2.5
1 ug/L
1 ug/L
1 ug/L
1 ug/L
1 ug/L
1 ug/L
1 ug/L
1 ug/L
1 %Recov
Q
Q
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846M8021
SW846M8021
SW846 M8021
SW846 M8021
SW846M8021
SW846M8021
SW846M8021
SW846 l\/I8Q21
M E T H A N E
Analyte
Methane
P A H / PNA
Analyte
Result
2100
Result
LOD
LOD
LOQ
LOQ
EQL
200
EQL
Dil.
20
DIL
Units
ug/L
Units
Code
Code
Anl Date
12/01/04
Anl Date
Prep Date: 12/01/04
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 11/24/04
Prep Method Anl Method
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghl)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(l,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
<
< < < < < < < < < < <
<
18
2.3
11
3.6
1.8
2.0
1.8
1.8
2.1
1.9
1.6
2.2
1.6
2.2
1.7
2.2
11
1.6
0
0
0
2.0
2.3
1.9
1.9
1.8
2.0
1.8
1.8
2.1
1.9
1,6
2.2
1.6
2.2
1.7
2.2
2.0
1-6
6.6
7.6
6.6
6.4
5.9
6.5
6.0
6.0
6.9
6.4
5.5
7.3
5.5
7.3
5.7
7.5
6.8
5.4
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
Q
Q
* •
*
*
D
D
D
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SWB46 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem Analytical Report Number: 853784 A Division of Pace Analytical Services, Inc.
Cl ient : NATURAL RESOURCE TECHNOLOGY, INC.
Project Name : WPSC - MARINETTE
Project Number : 1549
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collection Date : 11/22/04
Report Date : 12/07/04
Field ID :
I N O R G A N I C S
Test
MW-310
Result LOD LOQ EQL DIL Units
Lab Sample Number : 853784-008
Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 + N02
Sulfate
28000
2200
400
0.063
49
17
0.14
8.3
0.063
0.36
55
0.48
28
0.21
1.2
ug/L
ug/L
mg/L
mg/L
mg/L
11/30/04
11/30/04
12/01/04
12/07/04
11/24/04
SW846 6010B
SW846 601 OB
EPA 310.2
EPA 353.2
EPA 300.0
SW846 60108
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
P V O C Prep Date: 11/24/04
Analyte
1,2,4-Trimethylben2ene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m -i- p
a,a,a-Trifiuorotoluene
<
< < < <
Result
0.46
0.40
0.68
0.89
0.36
0.36
0.36
0.74
100
LOD
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
LOQ EQL Dil. Units
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
Code
Q
Q
Anl Date
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
Prep Method
SW846 5030B
SW846 5030B
SWB46 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
Anl Method
SW846 M8021
SW846M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846M8021
SW846 M8021
SW846 M8021
SW846 M8021
M E T H A N E
Analyte
Methane
P A H / PNA
Analyte
Result
170
Result
LOD
LOD
LOQ
LOQ
EQL
10
EQL
Dil.
1
Dil.
Units
ug/L
Units
Code
Code
Anl Date
12/01/04
Anl Date
Prep Date: 12/01/04
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 11/24/04
Prep Method Anl Method
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz{a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-FlLorobiphenyl
Terphenyl-d14
4.4
1.3
5.2
0.067
0.70
0.051
< 0.018
< 0.018
< 0.021
< 0.019
0.035
< 0.022
0.37
1.9
< 0.017
5.4
3.0
0.39
72
52
46
0.40
0.45
0.39
0.019
0.35
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.44
0.017
0.45
0.41
0.016
1.3
1.5
1.3
0.064
1.2
0.065
0.060
0.060
0.069
0.064
0.055
0.073
0.055
1.5
0.057
1.5
1.4
0.054
20
20
20
1
20
1
1
1
1
1
1
1
1
20
1
20
20
1
1
1
1
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
D
QD
D
QD
Q
* • Q
*
D
* D
D
12/01/04
12/01/04
12/01/04
11/30/04
12/01/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
12/01/04
11/30/04
12/01/04
12/01/04
11/30/04
11/30/04
11/30/04
11/30/04
SW846 35100
SW846 35100
SW846 35100
SW846 35100
SW846 35100
SW846 35100
SW846 35100
SW846 35100
SW846 35100
SW846 35100
SW846 35IOC
SW846 35100
SW846 3510C
SW846 35100
SW846 35100
SW846 35100
SW846 35100
SW846 35100
SW846 35100
SW846 3510C
SW845 3510O
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SIM
B270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem A Division of Pace Analytical Services, Inc.
Client : NATURAL RESOURCE TECHNOLOGY, INC
Project Name : WPSC - MARINETTE
Project Number : 1549
Analytical Report Number: 853784 1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collection Date : 11/22/04
Report Date : 12/07/04
Field ID :
I N O R G A N I C S
Test
MW-1
Result LOD LOQ EQL Dil. Units
Lab Sample Number : 853784-009
Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 -i- N02
Sulfate
11000
810
590
< 0.063
5.0
170
0.14
17
0.063
0.36
550
0.48
56
0.21
1.2
10
1 .
2
1
1
ug/L
ug/L
mg/L
mg/L
mg/L
11/30/04
11/29/04
12/01/04
12/07/04
11/24/04
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 6010B
SW846 60108
EPA 310.2
EPA 353.2
EPA 300.0
P V O C
Analyte
1 -Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2.3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
Result LOD LOQ EQL Dil. Units
Prep Date: 11/24/04
Code Anl Date Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trifluorotoluene
< < < < < < < <
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
100
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846 M8021
SW846M8021
SW846 M8021
SW846M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
M E T H A N E
Analyte
Methane
P A H / PNA
Analyte
Result
3200
Result
LOD
LOD
LOQ
LOQ
EQL
250
EQL
Dil .
25
Dil .
Units
ug/L
Units
Code
Code
Anl Date
12/01/04
Anl Date
Prep Date: 12/01/04
Prep Method Anl Method
SW846 M8015 SW846 M8015
Prep Date: 11/24/04
Prep Method Anl Method
< <
< < < < < < < < < < < <
< <
0.020
0.023
0.022
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.14
0.020
0.016
73
53
48
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.022
0.020
0.016
0.066
0.076
0.065
0.064
0.059
0.065
0.060
0.060
0.069
0.064
0.055
0.073
0.055
0.073
0.057
0.075
0.068
0.054
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
11/29/04
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
351 OC
351 OC
351 OC
351 OC
3510C
351 OC
351 OC
35 IOC
351 OC
3510C
351 OC
3510C
3510C
3510C
3510C
3510C
351 OC
3510C
3510C
3510C
3510C
82700-SIM
82700-SIM
82700-SIM
8270C-SIM
82700-SIM
82700-SIM
82700-SIM
82700-SIM
82700-SIM
8270C-SIM
8270C-SIM
82700-SIM
82700-SIM
8270C-SIM
8270C-SIM
82700-SIM
82700-SIM
82700-SIM
8270C-SIM
8270C-SIM
82700-SIM
Pace Analytical Services, Inc.
Analytical Report Number: 853784
Cl ien t : NATURAL RESOURCE TECHNOLOGY, IN
Project Name : WPSC - MARINETTE
Project N u m b e r : 1549
Field ID : MW-311
REVISED
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collection Date : 11/22/04
Report Date : 06/09/05
Lab Sample Number : 853784-010
INORGANICS
Test Result LOD LOQ EQL Dil. Units Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 + N02
Sulfate
1200
3000
1100
0.083
13
17
0.14
42
0.063
0.36
55
0.48
140
0.21
1.2
1 ug/L
1 ug/L
5 mg/L
1 mg/L
1 mg/L
11/30/04
11/30/04
12/01/04
12/07/04
11/24/04
SW846 6010B
SW846 601QB
EPA 310.2
EPA 353.2
EPA 300.0
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
PVOC
Analyte Result LOD LOQ EQL Dil. Units Code Anl Date
Prep Date: 11/24/04
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trifluorotoluene
1-Methylnaphthalene
2-Methyln3phthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzp(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
150
57
580
1200
< 9.0
19
310
510
99
9.8
9.9
3.4
10
9.0
8.9
9.0
19
33
33
11
33
30
30
30
62
25
25
25
25
25
25
25
25
1
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
K 11/24/04
K 11/24/04
K 11/24/04
K 11/24/04
K 11/24/04
QK 11/24/04
K 11/24/04
K 11/24/04
11/24/04
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
50308
5030B
5030B
5030B
5030B
5030B
5030B
50308
5030B
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
METHANE
Analyte
Methane
PAH/ P N A
Analyte
Result
1300
Result
LOD
LOD
LOQ
LOQ
EQL
100
EQL
Dil.
10
Dll.
Units
ug/L
Units
Code
Code
Anl Date
12/01/04
Anl Date
Prep Date: 12/01/04
Prep Method Anl Method
SW846M8015 SWe46M8015
Prep Date: 11/24/04
Prep Method Anl Method
350 250
330 280
< 240 240
3.7 1.9
9.9 1.8
< 2.0 2.0
< 1.8 1.8
< 1.8 1.8
< 2.1 2.1
< 1.9 1.9
< 1.6 1.6
< 2.2 2.2
3.9 1.6
36 2.2
< 1.7 1.7
3200 280
32 2,0
3.7 1.6
0
0
0
830
940
810
6.4
5.9
6.5
6.0
6.0
6.9
6.4
5.5
7.3
5.5
7.3
5.7
930
6.8
5.4
12500
12500
12500
100
100
100
100
100
100
100
100
100
100
100
100
12500
100
100
100
100
100
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
% Recov
%Recov
%Recov
QD 12/01/04
QD 12/01/04
D 12/01/04
Q 11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
Q 11/30/04
11/30/04
11/30/04
D 12/01/04
11/30/04
Q 11/30/04
D 11/30/04
D 11/30/04
D 11/30/04
SW846 351 OC
SW845 351 OC
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW845 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 35IOC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 35IOC
SW846 3510C
SW846 3510C
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem A Division of Pace Analytical Services. Inc.
Cl ient : NATURAL RESOURCE TECHNOLOGY, INC
Project Name : WPSC - MARINETTE
Project Number : 1549
Analytical Report Number: 853784 1241 Bellevue Street Green Bay, Wl 54302 920-459-2436
Matrix Type : WATER
Collect ion Date : 11/22/04
Report Date: 12/07/04
Field ID :
I N O R G A N I C S
Test
MW-3R
Result LOD LOQ EQL Dll. Units
Lab Sample Number : 853784-011
Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 + N02
Sulfate
1100
1200
850
0.80
290
17
0.14
17
0.063
3.6
55
0.48
56
0.21
12
1 ug/L
1 ug/L
2 mg/L
1 mg/L
10 mg/L
11/30/04
11/30/04
12/01/04
12/07/04
11/24/04
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
P V O C
Analyte
P A H / PNA
Analyte
Result LOD LOQ EQL Oil. Units
Prep Date: 11/24/04
Code Anl Date Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trifluorotoluene
< < < < < < < <
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
99
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
SW846 5030B
SW846 5030B
SW846 503OB
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846 M8021
SW846M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
M E T H A N E
Analyte
Methane
Result
35
LOD LOQ EQL
10
DiL
1
Units
ug/L
Code Anl Date
12/01/04
Prep Date: 12/01/04
Prep Method Anl Method
SW846M8015 SW846M8015
Result LOD LOQ EQL Dil. Units Code Anl Date
Prep Date: 11/24/04
Prep Method Anl Method
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
0.18
0.051
14
0.28
0.15
< 0.020
< 0.018
< 0.018
< 0.021
< 0.019
< 0.016
< 0.022
0.15
2.4
< 0.017
< 1.1
0.049
0.093
97
61
64
0.020
0.023
0.97
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
1.1
0.017
1.1
0.020
0.016
0.066
0.076
3.2
0.064
0.059
0.065
0.060
0.060
0.069
0.064
0.055
0.073
0.055
3.6 ;
0.057
3.7 ;
0.068
0.054
ug/L
ug/L
50 ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
50 ug/L
ug/L
JO ug/L
ug/L
ug/L
%Recov
%Recov
% Recov
Q
D
* "
*
QD
• D
Q
11/30/04
11/30/04
12/01/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
12/01/04
11/30/04
12/01/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 35IOC
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem Analytical Report Number: 853784 A Division of Pace Analytical Services, Inc.
C l i en t : NATUFIAL RESOURCE TECHNOLOGY, INC.
Project Name : WPSC - MARINETTE
Project N u m b e r : 1549
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix T y p e : WATER
Collection Date : 11/22/04
Report Date : 12/07/04
Field ID :
I N O R G A N I C S
Test
MW-5
Result LOD LOQ EQL DiL Units
Lab Sample Number : 853784-013
Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 + N02
Sulfate
18
480
270
2.7
66
17
0.14
8.3
0.063
0.36
55
0.48
28
0.21
1.2
ug/L
ug/L
mg/L
mg/L
mg/L
11/30/04
11/30/04
12/01/04
12/07/04
11/24/04
SW846 60108 SW845 6010B
SW846 601 OB SW846 601 OB
EPA 310.2
EPA 353.2
EPA 300.0
EPA 310.2
EPA 353.2
EPA 300.0
PVOC
Analyte Result LOD LOQ EQL Dil. Units
Prep Date: 11/24/04
Code Anl Date Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trifluorotoluene
0.39
0.40
0.73
0.63
0.36
0,36
0.36
0.74
100
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW845 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846M8021
SW846 M8021
SW846 M8021
SW846 M8021
M E T H A N E
Analyte
Methane
P A H / PNA
Analyte
Result
< 10
Result
LOD
LOD
LOQ
LOQ
EQL
10
EQL
Dil.
1
Dil.
Units
ug/L
Units
Code
Code
Anl Date
12/01/04
Anl Date
Prep Date: 12/01/04
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 11/24/04
Prep Method Anl Method
1-Methylnaphthalene
2-Methylnaphfhalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Diben2(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
< < < < <
c
< < <:
<
0.087
0.085
0.060
0.019
0.018
0.020
0.018
0.018
0.022
0.022
0.025
0.022
0.016
0.022
0.017
1.4
0.027
0.016
71
55
103
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.015
0.022
0.017
0.089
0,020
0.016
0.066
0.076
0.065
0.064
0.059
0.065
0.060
0.060
0.069
0.064
0.055
0.073
0.055
0.073
0.057
0.30
0.068
0.054
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
I ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
0
Q
Q
0
D
Q
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
12/01/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 35IOC
SW846 35100
SW846 3510C
SW846 3510C
SW846 35100
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
a270C-SIM
8270C-SIM
8270C-SIM
En Chem Analytical Report Number: 853784 A Division of Pace Analytical Services, Inc.
Client: NATURAL RESOURCE TECHNOLOGY, INC. Project Name : WPSC - MARINETTE
Project Number: 1549
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER Collection Date : 11/22/04
Report Date: 12/07/04 Field ID :
I N O R G A N I C S
Test
P-302
Result LOD LOQ EQL Dil. Units
Lab Sample Number : 853784-014
Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N 0 3 + N02
Sulfate
6600
230
260
0.063
30
17
0.14
8.3
0.063
0.36
55
0 4 8
28
0.21
1.2
ug/L
ug/L
mg/L
mg/L
mg/L
0
11/30/04
11/30/04
12/01/04
12/07/04
11/24/04
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
PVOC
Analyte Result LOD LOQ EQL Dil. Units Code Anl Date
Prep Date: 11/24/04
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a.a,a-Trifluorotoluene
< < < < < < < <
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
100
0.39
0 4 0
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
% Recov
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
SW846 5030B
SW846 5030B
SW846 5030B
SW846 50308
SW846 50308
SW846 50308
SW846 50308
SW846 50308
SW846 5030B
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
M E T H A N E
Analyte
Methane
PAH/ PNA
Analyte
Result
< 10
Result
LOD
LOD
LOQ
LOQ
EQL
10
EQL
Dll.
1
Dil.
Units
ug/L
Units
Code
Code
Anl Date
12/01/04
Anl Date
Prep Date: 12/01/04
Prep Method Anl Method
SW846 M8015 SW846 M8015
Prep Date: 11/24/04
Prep Method Anl Method
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo{b)fluoranthene
Benzo(ghi)perylene
Benzo{k)fluoranthene
Chrysene
Diben2(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2.3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
< < < < < < < < < < < < < < < < < <
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.022
0.020
0.016
72
58
91
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.022
0.020
0.016
0.066
0.076
0.065
0.064
0.059
0.065
0.060
0.060
0.069
0.064
0.055
0.073
0.055
0.073
0.057
0.075
0.068
0.054
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
% Recov
% Recov
1 %Recov
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
B270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem Analytical Report Number: 853784 A Division of Pace Analytical Services, Inc.
Client : NATURAL RESOURCE TECHNOLOGY, INC Project Name : WPSC - MARINETTE
Project Number: 1549
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collection Date : 11/22/04
Report Date: 12/07/04 Field I D : P-303
I N O R G A N I C S
Test
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 + N02
Sulfate
P V O C
Analyte
1,2,4-Trimethylt3enzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trifluorotoluene
M E T H A N E
Analyte
Methane
P A H / PNA
Analyte
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)3nthracene
Benzo{a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Diben2(a,h)anthracene
Fluoranthene
Fluorene
lndeno(l,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
Result
40
3.8
200
0.26
670
Result
< 0.39
< 0.40
< 0.14
< 0.40
< 0.36
< 0.36
< 0.36
< 0.74
100
Result
< 10
Result
< 0.020
< 0.023
< 0.019
0.027
< 0.018
0.050
0.041
0.026
0.023
0.030
0.039
< 0.022
0.071
< 0.022 ,
0.019
< 0.022
0.044
0.067
62
54
82
LOD
17
0.14
8.3
0.063
7.2
LOD
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
LOD
LOD
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.022
0020
0.016
LOQ EQL
55
0.48
28
0.21
24
LOQ EQL
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
Dil. Units
1 ug/L
1 ug/L
1 mg/L
1 mg/L
20 mg/L
Dll. Units
1 ug/L
t ug/L
1 ug/L
1 ug/L
1 ug/L
1 ug/L
ug/L
1 ug/L
1 %Recov
LOQ EQL Dil . Units
10 ug/L
LOQ EQL Dil . Units
0.066
0.076
0.065
0.064
0.059
0.065
O.O60
0.060
0.069
0.064
0.055
0.073
0.055
0.073
0.057
0.075
0.066
0.054
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
( ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
Lab Sample Number : 853784-015
Code
Q
Code
Code
Code
Q
Q
Q
0
Q
Q
0
Q
Q
Anl Date
11/30/04
11/30/04
12/01/04
12/07/04
11/24/04
Anl Date
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
11/24/04
Anl Date
12/01/04
Anl Date
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
Prep Method
SW846 601 OB
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
Anl Method
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
Prep Date: 11/24/04
Prep Method
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
Anl Method
SW846 IVI8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SWa46 M8021
Prep Date: 12/01/04
Prep Method
SW846M8015
Anl Method
SW846M8015
Prep Date: 11/24/04
Prep Method
SW84e3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 3510C
SW846 35IOC
SW846 3510C
SW846 3510C
SW846 3510C
Anl Method
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
3270C-SIM
82700-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
82700-SIM
8270C-S1M
82700-SIM
82700-SIM
En Chem Analytical Report Number: 853784 A Division of Pace Analytical Services, Inc.
Client: NATURAL RESOURCE TECHNOLOGY, INC.
Project Name : WPSC - MARINETTE
Project Number : 1549
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER Collection Date : 11/22/04
Report Date : 12/07/04 Field ID : P-305
I N O R G A N I C S
Test
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N 0 3 + N02
Sulfate
P V O C
Analyte
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trifluorotoluene
M E T H A N E
Analyte
Methane
P A H / PNA
Analyte
1 -Methylnaphtha lene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Ben20(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2.3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
< < < < < < < <
< <
< < < < < < < < < < < <
< <
Result
4700
1700
720
0.22
76
Result
0.39
0.40
0.14
0.40
0.35
0.36
0.36
0.74
100
Result
38
Result
0.020
0.023
0.051
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.025
0.020
0.016
95
76
94
LOD
17
0.14
17
0.063
0.36
LOD
0.39
0.40
0.14
0.40
0.35
0.35
0.36
0.74
LOD
LOD
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.022
0.020
0.016
LOQ EQL
55
0.48
56
0.21
1.2
LOQ EQL
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
LOQ EQL
10
LOQ EQL
0.066
0.076
0.065
0.064
0.059
0.065
0.060
0.060
0.069
0.064
0.055
0.073
0.055
0.073
0.057
0.075
0.068
0.054
Dil. Units
1 ug/L
1 ug/L
2 mg/L
1 mg/L
1 mg/L
Dil. Units
1 ug/L
ug/L
1 ug/L
1 ug/L
1. ug/L
1 ug/L
1 ug/L
1 ug/L
1 %Recov
Dil. Units
1 ug/L
Dil. Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
Lab Sample Number : 853784-017
Code Anl Date
11/30/04
11/30/04
12/01/04
12/07/04
11/24/04
Code Anl Date
11/25/04
11/25/04
11/25/04
11/25/04
11/25/04
11/25/04
11/25/04
11/25/04
11/25/04
Code Anl Date
12/01/04
Code Anl Date
11/30/04
11/30/04
Q 11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
Q 11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
Prep Method
SW846 6010B
SW846 60108
EPA 310.2
EPA 353.2
EPA 300.0
Anl Method
SW846 601 OB
SW846 601 OB
EPA 310.2
EPA 353.2
EPA 300.0
Prep Date: 11/25/04
Prep Method
SW846 5030B
SW846 5030B
SW846 5030B
SW846 50308
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
Anl Method
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
Prep Date: 12/01/04
Prep Method
SW846M8015
Anl Method
SW846M8015
Prep Date: 11/29/04
Prep Method
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 35IOC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 35IOC
SW846 351 OC
SW846 35IOC
SW846 35IOC
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 35100
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
Anl Method
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
82700-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SIM
En Chem A Division of Pace Analytical Services, Inc.
Cl ient : NATURAL RESOURCE TECHNOLOGY, INC
Project Name : WPSC - MARINETTE
Project Number : 1549
Analytical Report Number: 853784 1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collection Date : 11/22/04
Report Date : 12/07/04
Field ID :
INORGANICS
Test
QC-1
Result LOD LOQ EQL Dil. Units
Lab Sample Number : 853784-018
Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 + N02
Sulfate
4500
390
350
0.063
9.7
17
0.14
8.3
0.063
0.36
55
0.48
28
0.21
1.2
ug/L
ug/L
mg/L
mg/L
mg/L
11/29/04
11/29/04
12/01/04
12/07/04
11/24/04
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
P V O C
Analyte
1 -Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Ben2o(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-dS
2-Fluorobiphenyl
Terphenyl-d14
Result LOD LOQ EQL Dil. Units Code Anl Date
Prep Date: 11/25/04
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trifluorotoluene
<
< < <
<
4.2
0.40
0.15
0.40
0.36
0.35
1.8
0.74
100
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
11/25/04
11/25/04
ug/L Q 11/25/04
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
11/25/04
11/25/04
11/25/04
11/25/04
11/25/04
11/25/04
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846M8021
SW846M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
M E T H A N E
Analyte
Methane
P A H / PNA
Analyte
Result
50
Result
LOD
LOD
LOQ
LOQ
EQL
10
EQL
Dil.
1
Dil.
Units
ug/L
Units
Code
Code
Anl Date
12/01/04
Anl Date
Prep Date: 12/01/04
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 11/29/04
Prep Method Anl Method
0.54
0.023
0.080
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.037
0.022
0.017
0.11
0.020
0.24
88
70
88
0.040
0.023
0.019
0.019
0.018
0.020
0.018
0,018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.022
0.020
0.016
0.13
0.076
0.065
0.064
0.059
0.065
0.060
0.060
0.069
0.064
0.055
0.073
0.055
0.073
0.057
0.075
0.068
0.054
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
% Recov
%Recov
%Recov
D 12/02/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
Q 11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
11/30/04
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 35100
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SWe46 3510C
SW846 35100
SW846 3510C
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
a270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
6270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem A Division of Pace Analytical Services, Inc.
C l ien t : NATURAL RESOURCE TECHNOLOGY, INC
Project Name : WPSC - MARINETTE
Project Number : 1549
Field ID : QC-2
Analytical Report Number: 853784 1241 Bellevue Street Green Bay, W l 54302 920-469-2436
Matrix Type : WATER
Collection Date : 11/22/04
Report Date : 12/07/04
Lab Sample Number : 853784-019
INORGANICS
Test Result LOD LOQ EQL DiL Units Code Anl Date Prep Method Ant Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 + N02
Sulfate
1400 17
680 0.14
410 8.3
0.063 0.063
93 1.8
55
0.48
28
0.21
6.0
ug/L
ug/L
mg/L
mg/L
mg/L
11/29/04
11/29/04
12/01/04
12/07/04
11/24/04
SW846 60108
SW846 601 OB
EPA 310.2
EPA 353.2
EPA 300.0
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
PVOC
Analyte Result LOD LOQ EQL Dll. Uni ts Code Anl Date
Prep Date: 11/25/04
Prep Method A n l Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trifluorotoluene
0.39
0.40
0.15
0.40
0.36
0 3 6
0.36
0.74
100
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
7oRecov
11/25/04
11/25/04
Q 11/25/04
11/25/04
11/25/04
11/25/04
11/25/04
11/25/04
11/25/04
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
5030B
5030B
5030B
5030B
5030B
5030B
5030B
5030B
5030B
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
M8021
M8021
M8021
M8021
M8021
M8021
M8021
M8021
M8021
METHANE
Analyte Result LOD LOQ EQL DiL Uni ts
Prep Date: 12/01/04
Code Anl Date Prep Method A n l Method
Methane 10 10 ug/L 12/01/04 SW846M8015 SW846M8015
PAH/ PNA
Analyte Result LOD LOQ EQL Dll. Uni ts Code Anl Date
Prep Date: 11/29/04
Prep Method A n l Method
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Ben20(ghi)perylene
Benzo(k)fiuoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
< < < < < < < < < < < < < < <
< <
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.026
0.020
0.016
85
66
91
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.022
0.020
0.016
0.066
0.076
0.065
0.064
0.059
0.065
0.060
0.060
0.069
0.064
0.055
0,073
0.055
0.073
0.057
0.075
0.068
0.054
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
12/01/04
12/01/04
12/01/04
12/01/04
12/01/04
12/01/04
12/01/04
12/01/04
12/01/04
12/01/04
12/01/04
12/01/04
12/01/04
12/01/04
12/01/04
ug/L Q 12/01/04
ug/L
ug/L
VoRecov
%Recov
%Recov
12/01/04
12/01/04
12/01/04
12/01/04
12/01/04
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem A Division of Pace Analytical Services, Inc.
Client : NATURAL RESOURCE TECHNOLOGY, INC
Project Name : WPSC - MARINETTE
Project Number: 1549
Field ID : TRIP BLANK
Analytical Report Number: 853784 1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collection Date : 11/22/04
Report Date : 12/07/04
Lab Sample Number: 853784-020
PVOC
Analyte
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m -i- p
a,a,a-Trifluorotoluene
< < < < < < < <
Result
0.39
0.40
0.14
0.40
0.36
0.35
0.36
0.74
100
LOD
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
LOQ EQL Dil . Units Code Anl Date
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
11/25/04
11/25/04
11/25/04
11/25/04
11/25/04
11/25/04
11/25/04
11/25/04
11/25/04
Prep Date: 11/25/04
Prep Method
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
Anl Method
SW846 M8021
SW846 M8021
SW846M8021
SW848 M8021
SW846M8021
SW846M8021
SW846 M8021
SW846 M8021
SW846 M8021
Qualifier Codes
Flag Applies To Explanation
Inorganic
B
B
C
D
E
Inorganic
Organic
All
All
Inorganic
E
F
F
H
HF
J
J
K
K
L
M
N
0
P
0
Organic
Inorganic
Organic
All
Inorganic
Inorganic
Organic
Inorganic
Organic
All
Organic
All
Organic
Organic
All
Organic
U
V
w X
& -< 1
2
3
4
5
6
7
All
All
All
All
All
All
All
Inorganic
Inorganic
Inorganic
Inorganic
Inorganic
Inorganic
Inorganic
Analyte is detected in the method blank. Method blank criteria is evaluated to the laboratory method detection limit. Additionally, method blank acceptance may be based on project specific criteria or determined from analyte concentrations in the sample and are evaluated on a sample by sample basis.
The analyte has been detected between the method detection limit and the reporting limit.
Analyte is present in the method blank. Method blank criteria is evaluated to the laboratory method detection limit. Additionally, method blank acceptance may be based on project specific criteria or determined from analyte concentrations in the sample and are evaluated on a sample by sample basis.
Elevated detection limit.
Analyte value from diluted analysis or surrogate result not applicable due to sample dilution.
Estimated concentration due to matrix interferences. During the metals analysis the serial dilution failed to meet the estatilished control limits of 0-10%. The sample concentration is greater than 50 times the IDL for analysis done on the ICP or 100 times the IDL for analysis done on the ICP-MS. The result was flagged with the E qualifier to indicate that a physical interference was observed.
Analyte concentration exceeds calibration range.
Due to potential interferences for this analysis by Inductively Coupled Plasma techniques (SW-846 Method 6010), this analyte has been confirmed by and reported from an alternate method.
Surrogate results outside control criteria
Preservation, extraction or analysis performed past holding time.
This test is considered a field parameter, and the recommended holding time is 15 minutes from collection. The analysis was performed in the laboratory beyond the recommended holding time.
The analyte has been detected between the method detection limit and the reporting limit.
Concentration detected is greater than the method detection limit but less than the reporting limit.
Sample received unpreserved. Sample was either preserved at the time of receipt or at the time of sample preparation.
Detection limit may be elevated due to the presence of an unrequested analyte.
Elevated detection limit due to low sample volume.
Sample pH was greater than 2
Spiked sample recovery not within control limits.
Sample received overweight.
The relative percent difference between the two columns for detected concentrations was greater than 40%.
The analyte has been detected between the limit of detection (LOD) and limit of quantitation (LOQ). The results are qualified due to the uncertainty of analyte concentrations within this range.
The relative percent difference between quantitation and confirmation columns exceeds internal quality control criteria. Because the result is unconfirmed, it has been reported as a non-detect with an elevated detection limit.
The analyte was not detected at or above the reporting limit.
Sample received with headspace.
A second aliquot of sample was analyzed from a container with headspace.
See Sample Narrative.
Laboratory Control Spike recovery not within control limits.
Precision not within control limits.
The analyte was not detected at or above the reporting limit.
Dissolved analyte or filtered analyte greater than total analyte; analyses passed QC based on precision criteria.
Dissolved analyte or filtered analyte greater than total analyte; analyses failed QC based on precision criteria.
BOD result is estimated due to the BOD blank exceeding the allowable oxygen depletion.
BOD duplicate precision not within control limits. Due to the 48 hour holding time for this test, it is not practical to reanalyze and try to correct the deficiency.
BOD result is estimated due to insufficient oxygen depletion. Due to the 48 hour holding time for this test, it is not practical to reanalyze and try to correct the deficiency.
BOD laboratory control sample not within control limits. Due to the 48 hour holding time for this test, it is not practical to reanalyze and try to correct the deficiency.
BOD result is estimated due to complete oxygen depletion. Due to the 48 hour holding time for this test, it is not practical tc reanalyze and try to correct the deficiency.
En Chem Analysis Summary by Laboratory A Division of Pace Analytical Services, Inc.
1241 Bellevue Street Green Bay, Wl 54302
1090 Kennedy Avenue Kimberly.WI 54136
Test Group Name
ALKALINITY AS CAC03
IRON - DISSOLVED
MANGANESE - DISSOLVED
METHANE
NITROGEN, N03-1-N02
PAH/ PNA
PVOC
SULFATE
OJ U l OJ
00
o o
G
G
G
G
G
G
G
G
CD t n w CD 4 ^
8 ro
G
G
G
G
G
G
G
G
0 0 O l OJ
CD 4 ^
O o OJ
G
G
G
G
G
G
G
G
0 0 O l OJ
0 0
6 o
G
G
G
G
G
G
G
G
00 O l OJ
o o c n
G
G
G
G
G
G
G
G
OO
a OO
o o CJJ
G
G
G
G
G
G
G
G
OO O l OJ
o o - 4
G
G
G
G
G
G
G
G
OJ O l OJ • > !
2 o o CD
G
G
G
G
G
G
G
G
0 3 O l OJ
00
§ CD
G
G
G
G
G
G
G
G
CD cn CO - CO
o o
G
G
G
G
G
G
G
G
O l OJ --J CO
o
G
G
G
G
G
G
G
G
0 0 O l OJ -v/ 00
o OJ
G
G
G
G
G
G
G
G
OJ O l OJ
00
o
G
G
G
G
G
G
G
G
0 0 c n CO - ^ I 0 0
CD
cn
G
G
G
G
G
G
G
G
OJ cn CO - , 1 CO
o
G
G
G
G
G
G
G
G
CD t n CJ
c a 4 ^
o CD
G
G
G
G
G
G
G
G
0 0 cn
CO
OJ
o CD
G
G
G
G
G
G
G
G
00 cn CO - v i 05
o o
G
Wisconsin Certification
G-
K =
S =
'C =
- En Chem Green Bay
= En Chem Kimberly
= En Chem Superior
405132750 / DATCP: 105 000444
445134030
Not Applicable
= Subcontracted Analysis
Batch No. ^ ^ S ? ^ " / Project Name or ID I S n !
En Chem, Inc. Cooler Receipt Log
Temps: { ' ^ t ^ No. of Coolers: /
A. Receipt Phase: Date cooler was opened: j ' g ^ S C J n Bv: ( S ^
1: Were samples received on ice? (Must be < 6 C ) (.YES NO ' NA
2. Was there a Temperature Blank? YES
3: Were custody seals present and Intact on cooler? (Record on COC) YES
4: Are COC documents present? ./<YES
5: Does this Project require quick turn around analysis? YES
6; Is there any sub-work? YES
7: Are there any short hold time tests? YES
8: Are any samples nearing expiration of hold-time? (Within 2 days) YES
9: Do any samples need (o be Filtered or Preserved in the lab? YES
B. Check-in Phase: Date samples were Checked-in: \ \ ' ' ^ ^ ' C i ' ^ By: { ^ ^
Contacted by/Who_
Contacted by/Who_
1: Were all sample containers listed on the COC received and intact?..
2: Sign the COC as received by En Chem. Completed
3: Do sample labels match the COC?
4: Completed pH check on preserved samples {This statement does noi apply to water VOC, O&G, TOC, ORG, Total Rec. Phenolii
5: Do samples have correct chemical preservation? /^.YES (This statement does not apply to water VOC, O&G, TOC, DRO, Total Rec. Phenolic
6: Are dissolved parameters field filtered?
7: Are sample volumes adequate for tests requested?
8: Are VOC samples free of bubbles >6mm :
9: Enter samples into logbook. Completed :(YES,
10; Place laboratory sample number on all containers and COC. Completed <YES
11: Complete Laboratory Tracking Sheet (LTS). Completed YES
12: Start Nonconformance form ' .YES
13: Initiate Subcontracting procedure. Completed ,/ YES
14: Check laboratory sample number on all containers and COC.
Short Hold-time tests:
7 7 ^ES
o(723A^iQ>
24 Hours or less Coliform Corrosivity = pH Dissolved Oxygen Hexavalent Chromium HPC Ferrous Iron Eh Odor Residual Chlorine Sulfite
48 Hours BOD Color Nitrite or Nitrate Ortho Phosphorus Surfactants Turbidity En Core Preservation Power stop preservation
7 days A«h
^--"Aqueous Extr^ctable Organics- ALL "" " ^ Flashpoint - ^
Free Liquids Sulfide TDS TSS Total Solids TVS TVSS Unpreserved VOC's
Footnotes 1 Notify proper lab group immediately. 2 Complete nonconformance memo.
Rev. 2/05/04, At tachment to 1-REC-5. Subject to Q A Audit . Rev iewed by/date_ fvf iiliili
p:/everyone/forms/samplereceiving/cri.doc
(Please Prim Legibly) Company Name-. < V s V i / V ^ \ V -~<-> t jVc ' - V c A ^ ^ j ' \ i i cj-J
W c ^ - j ^ " U -c Branch or Localion: V
Project Conlaci: ~ ^ 0 M ' \ b u > ^ V ' - " ' ^
^ ^ v - <; - \ V « V i Telephone:
Project Number: * S n \
Project Nama: ^ ^ ^ ^ ' ^ ' • - ^ ^ V ' ^ • - ' V-^ ^ ^
Projeci Stale; W T
Sampled By (Priril) :
P 0 # :
. - J o J ^ ^ l > ^ . y V l , ^ ' ^
Data Package Options - (please circle il requested)
Sample Results Only (no QC)
EPA Level II (Subject to Surcharge)
EPA Level 111 (Subject to Surcharge)
EPA Level IV (Subject to Surcharge)
LftBORATORY ID (Lab Use Only) FIELD ID
Regulalory Program
UST RCRA SDWA NPDES
CERCLA
EN CHEM INC.
C3 1241 BeUevue St., Suite 9 Gieen Bay, Wl S4302
920-469-2436 Fax 920-469-8827
...clttntiitryfor llil environnieiit.
CHAIN OF CUSTODY N° 130183 /
Page_
Quote #:_
Mail Report To: ,: 'sL.cN^u... UJ-A^ •Preservallon Coiles
A=None B=HCL C=H2S04 D=HN03 E=EnCote F=Melhanol G=NaOH , v i v--, - _ , H^Soillum BIsullale Solullon USoilluni Thiosulfale JjOlher / Company: A / - v V ' ^ ^ ' ^ ' V - i . >agt- '- '^ V<..V-., i i^
FILTERED? (YES/MO) / r V / f J / ^ / \ < . i - / f ^
PRESERVATION (CODE)' / P ^ / f \
Malrlx Coiles
COLLECTION
OATE
(V,U- " V X \ \ \ i , . i - i V-~
j v ^ o ^ J i o » 7
OOi Od(p
O o l
06^
OlO
o n
Cy^\jj - v ^ ^
{ ^ \ . j - - ^ o l ^
\ ' LX^
f - ) ^ ' 1>0 ft
/s*~j • " i l o
fS-lUJ - ^
- f ° ^ ~ - » ^ j Y \ u / - S l l PftTC-
w \_-l • u y
TIME
>1
oa
i\i Ui-\
V b ^ 1
-h^x
y
X >
^
> >
>>
>
. : ] ^
>
>
>
>
>
>
T Y
>
^
y
-t >
: ) ^ ^ Y ^^
N
T^
^
>
VL
)^
Y_
7
^
• ^
Y
r >
>-
f ^t-
^
<
^
^
>
T-
>
>
Yi.
>
^
Y
y^/t/g> I^3M^,(iP }LArvh& /l
r i-506hJ^ . ( ^ M- 3 R , ^ ^ ^
nnn7^-*-l- in: " T ^ (P f ^ ( j A / \ K ^ M rtAM / ^ l l / l ' i / ' ^ ^ l ^ j ^ Rush Turnaround Time Requested (TAT) - Prelim
(Rush TAT subject to approval/surcharge)
Date Needed:
Transmit Prelim Rusti Results by (circle);
Phone Fax E-Mail
Ptioiie #:
Fax#:
E-Mail Address:
Samples on HOLD are subject to special pr ic ing and release o l l iabil i ty
Dale/Time; ua ien ime: , \ ^ _ '
14'. CO ll'-^ Date/Time:
Relinquished By; Date/Time;
Relinquished By; Date/Time;
Relinquished By; Date/time:
IDats/Tjme:
EuuW 11^1 iw En Chem Project No.
Sample Receipt Temp, :e lp l Ten
Received By: Date/Time: Sample (Wel/Metali
Receipt Ter
Receipt pH
Received By: Date/Time: 'Lot L;usloily..S<
Received By; Date/Time;
Cooler Custoay.Se(r i—-. ,
Present / l^ot P r e s e n t , - ^
Intact/Not Intact Vetsion 4.0; 07/03
(Please Print Legibly)
Company Name: / ^ ' ^ W v 4 \ > - t . > , u v < . ^ T c L ^ - , » ] a ^ V
Branch or Locat ion :^ & U ^ i * ^ / ^ ' - * - , \ ^ ' ^
Project Contact:
Telephone: " ^ U V " ^ W - N x ^ a V t
Project Number;
Projeci Name:
Projeci Slate; _
AS^M^Llll ^^)^^v'^oLV\-c.
W l
Sampled By (Print)
P 0 # ;
."SoJ^^W^ < I ^ ^
Data Package Options - (please circle if requested)
Sample Results Only (no QC)
EPA Level II (Subject to Surcharge)
EPA Level IM (Subject lo Surcharge)
EPA Level IV (Subject to Surcharge)
LABORATORY ID (Lab Use Only) FIELD ID
Regulalory Pmqram
UST RCRA SOWA NPDES
CERCLA
EN CHEM INC.
3 1241 Bellevue St., Suite 9 Green Bay, WI 54302
920-469-2436 Fax 920-469-8827
/ L ^ /
i lry for lite t'liviroiiweiif. 1_ Z .
CHAIN OF CUSTODY N? 130 184 'PreserDalion Codes
A=None B=HCL C=H2S04 D=HN03 E=EnCore F=Melh3nol H=So(lium Bisulfate Solution l-Sodium Thiosullale J=Dther
FILTERED? (YES/NO) / ^
PRESERVATION (CODE)-
G^NaOH
Quote #:
Mail Report To: WoVc... Cu.y.w
V /TTi 7 A/ / / ^ / 7J
• / • l ^ / j _ cvs:
Company: /^>^\ '>>^^^ ^^»-^ " - "^^<- •> '>^ ,^^a ^ 1
Address:
' ^ i ^ i ^ ^ ^ ' ^ ^ i v ^ ' P - ? - \ > o > T -
Invoice To:
IVIatrli Codes
W=Waler S=Soil A=Alr
C^Charcoal B=Blola
SbSludge
CpUECTipN
DATE ] TIME
t ^ ^ - b \ ^ - p L X -
0 ( ^
^yj^-r^^^^oTT
o n ! ?- ^'iS"
h^ o
30>HO
-e
on 090_
Qo~\
Q c - X
: ^ ^ ' ^ ' ^ ' ^
\ ^
\ \ \ . ^ ,
^ -
MATRIX
"t
'4 K ^ . / ^ ^ , ^
y
y-^ Company: A / K V - ' - ' ^ V y . . > ' - > - " X , V , „ , \ . v , - J
Address: " '^ i* t ^ \ > a - J i - ^
Mail Invoice To; ^ - V ^ . C'w J - W
< /
X
. ^ ' ^
%.
-<
K
K
- ^
r ^
1^
Y.
)<
K
^ CLIENT COMMENTS
7<
y^
<.
"K~
X
X .
Y L
1
X
>
A
_ ) ^
-i-
^
vc
A
(o- ^ ^ 5 - ^ S d d A k o i'ulJuoJ
:M
LAB COMMENTS (Lab Use Only)
3.^e^M/(Li?
-V-_^Ji6nl6ji^BL^.
^ ^ ' g / * Olie P - ^ o ^ T h ^ h t ^
M(:^i//0i/-
i^7% Rush Turnaround Time Requested (TAT) - Prelim
(Rush TAT subject to approval/surcharge)
Date Needed: ^ ' R
Transmit Prelim Rush Results by (circle):
Phone Fax E-Mail
Phone #:
Fax »:
E-Mail Address:
Samples on HOLD are subject to special pr ic ing and release of l iabil i ty
. Dale/ l ime: ^_^
elinquished By:
RelinquishecfBy:
Date/Time:
Dale/Time;
Relinquished By; Date/Time:
Relinquished By: Dale/Time:
Received By; Dale/Time:
Received By;
Received By:
Dale/Time;
Dale/Time:
En Chem Projeci No.
Sample Receipt Temp.
Sample Receipt pH (WeVMelalsJ. J ^
Cooler Cusj j
Present / Not Present
Intact / Not Intact Version fl.O: 07/03
ace Analytical m\SE\) 1241 Bellevue Street, Suite 9 Green Bay, Wl 54302
920-469-2436, Fax: 920-469-8827
Analytical Report Number: 858276
Client: NATUFtAL RESOURCE TECHNOLOGY
Project Name: WPSC - MARINETTE
Project Number: 1549
Lab Contact: Tom Trainor
Lab Sample Number
858276-001
858276-002
858276-003
858276-004
858276-005
858276-006
858276-007
858276-008
858276-009
858276-010
858276-011
858276-012
858276-013
858276-014
858276-015
858276-016
858276-017
858276-018
858276-019
Field ID
MW-302
MW-303
MW-304
MW-305
MW-306
MW-307R
MW-308
MW-310
MW-1
MW-311
MW-3R
MW-5
P-302
P-303
P-304
P-305
QC-1
QC-2
TRIP BLANK
Collection Matrix Date
WATER 04/14/05
WATER 04/14/05
WATER 04/14/05
WATER 04/14/05
WATER 04/13/05
WATER 04/13/05
WATER 04/13/05
WATER 04/13/05
WATER 04/13/05
WATER 04/13/05
WATER 04/14/05
WATER 04/14/05
WATER 04/14/05
WATER 04/14/05
WATER 04/14/05
WATER 04/14/05
WATER
WATER
WATER 04/13/05
I certify that the data contained in this Final Report has been generated and reviewed in accordance with approved methods and Laboratory Standard Operating Procedure. Exceptions, If any, are discussed in the accompanying sample comments. Release of this fmal report is authorized by Laboratory management, as is verified by the following signature. This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. The sample results relate only to the analytes of interest tested.
( ^ ^>v^^
Approval Signature
/ l / b l ^ t y ^ I'J-'or-Date
En Chem Analytical Report Number: 858276 A Division of Pace Analytical Services, Inc.
Client: NATURAL RESOURCE TECHNOLOGY
Project Name : WPSC - MARINETTE
Project Number: 1549
1241 Bellevue Street Green Bay, Wl 54302 920^69-2436
Matrix Type : WATER Collection Date : 04/14/05
Report Date : 04/29/05 Field ID :
INORGANICS
Test
MW-302
Result LOD LOQ EQL Dil. Units
Lab Sample Number : 858276-001
Code Anl Date Prep Method An l Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 -i- N02
Sulfate
1100
160
380
< 0.061
160
17
0.14
6.3
0.061
4.2
55
0.48
21
0.20
14
1
1
1
1
5
ug/L
ug/L
mg/L
mg/L
mg/L
04/23/05
04/23/05
04/25/05
04/18/05
04/18/05
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW856 6010B
SW856 6010B
EPA 310.2
EPA 353.2
EPA 300.0
PVOC
Analyte Result LOD LOQ EQL Dil. Units Code Anl Date
Prep Date: 04/19/05
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m -i p
a.a,a-Trifluorotoluene
< <
< < < <
0.39
0.40
4.9
0.57
0.36
0.36
0.36
0.74
103
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0,46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
Q
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
SW846 50308
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
METHANE
Analyte
Methane
P A H / PNA
Analyte
Result
40
Result
LOD
LOD
LOQ
LOQ
EQL
10
EQL
Dil.
1
Dil.
Units
ug/L
Units
Code Anl Date
04/25/05
Code Anl Date
Prep Date: 04/25/05
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 04/18/05
Prep Method Anl Method
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
< 0.40
< 0.45
0.40
1.2
0.96
2.5
3.0
2.3
2.0
1.9
1.9
0.62
3.5
< 0.44
1.8
< 0.45
1.2
3.0
0
0
0
0 4 0
0.45
0.39
0.39
0.35
0.39
0.36
0.36
0.41
0.39
0.33
0.44
0.33
0.44
0.34
0.45
0.41
0.33
1.3
1.5
1.3
1.3
1.2
1.3
1.2
1.2
1.4
1.3
1.1
1.5
1.1
1.5
1.1
1.5
1.4
1.1
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
Q
Q
Q
Q
Q
D
D
D
04/27/05
04/27/05
04/27/05
04/27/05
04/27/05
04/27/05
04/27/05
04/27/05
04/27/05
04/27/05
04/27/05
04/27/05
04/27/05
04/27/05
04/27/05
04/27/05
04/27/05
04/27/05
04/27/05
04/27/05
04/27/05
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 351 OC
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
B270C-SIM
8270C-SIM
e270C-SIM
8270C-SIM
8270C-SIM
a270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
B270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem Analytical Report Number: 858276 A Division of Pace Analytical Services, Inc.
Cl ient : NATURAL RESOURCE TECHNOLOGY
Project Name : WPSC - MARINETTE
Project N u m b e r : 1549
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collection Date : 04/14/05
Report Date : 04/29/05
Fie ld ID
I N O R G A N I C S
Test
MW-303
Result LOD LOQ EQL DIL Units
Lab Sample Number : 858276-002
Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N 0 3 + N02
Sulfate
8300
920
400
0.43
67
17
0.14
6.3
0.061
0.83
55
0.48
21
0.20
2.8
ug/L
ug/L
mg/L
mg/L
mg/L
04/23/05
04/23/05
04/25/05
04/18/05
04/18/05
SW846 6O10B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW856 6010B
SW856 6010B
EPA 310.2
EPA 353.2
EPA 300.0
PVOC
Analyte Result LOD LOQ EQL Dil. Units Code Anl Date
Prep Date: 04/19/05
Prep Method Anl Method
1,2,4-Thmethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trifluorotoluene
< <
< < < <
0.39
0:40
1.5
0.53
0.36
0.36
0.36
0.74
103
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
Q
04/19/05
04/19/05
04/19/05
04/19705
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 MB021
SW846 M8021
SW846 M8021
M E T H A N E
Analyte
Methane
PAH/ P N A
Analyte
Result
480
Result
LOD
LOD
LOQ
LOQ
EQL
50
EQL
Dil .
5
DiL
Units
ug/L
Units
Code
Code
Anl Date
04/25/05
Anl Date
Prep Date: 04/25/05
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 04/18/05
Prep Method Anl Method
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
0.053
0.058
0.26
0.068
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.017
0.022
0.017
0.18
0.020
0.020
45
51
80
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0,022
0.020
0.016
0.066
0.076
0.065
0.064
0.059
0.065
0.060
0.060
0.069
0.064
0.055
0.073
0.055
0.073
0.057
0.075
0.068
0.054
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
Q 04/19/05
Q 04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
Q 04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
Q 04/19/05
04/19/05
04/19/05
04/19/06
SW846 3510C
SW846 3510C
SW846 3510C
SW845 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW845 3510C
SW846 35IOC
SW846 3510C
SW845 3510C
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
a270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem Analytical Report Number: 858276 A Division of Pace Analytical Services, Inc.
Client: NATURAL RESOURCE TECHNOLOGY
Project Name : WPSC - MARINETTE
Project Number : 1549
Field ID : MW-304
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collection Date : 04/14/05
Report Date: 04/29/05
Lab Sample Number : 858276-003
INORGANICS
Test
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 ^ N02
Sulfate
Result LOD LOQ EQL Dil. Units Code Anl Date Prep Method Anl Method
280
320
490
0.58
630
17
0.14
6.3
0.061
8.3
55
0.48
21
0.20
28
ug/L
ug/L
mg/L
mg/L
0 mg/L
04/23/05
04/23/05
04/25/05
04/18/05
04/18/05
SW846 6010B SW856 6010B
SW846 601 OB SW856 601 OB
EPA 310.2 EPA 310.2
EPA 353.2 EPA 353.2
EPA 300.0 EPA 300.0
PVOC
Analyte
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o Xylenes, m -i- p
a,a,a-Trifluorotoluene
PAH/ PNA
Analyte
Result LOD LOQ EQL Dil. Unite Code Anl Date
Prep Date: 04/19/05
Prep Method Anl Method
e <
e <
< < < < <
0.39
0.40
1.1
0.40
0.36
0.36
0.36
0.74
103
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846 M8021
SW846 MB021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
M E T H A N E
Analyte
Methane
Result
< 10
LOD LOQ EQL
10
Dil.
1
Unite
ug/L
Code Anl Date
04/25/05
Prep Date: 04/25/05
Prep Method Anl Method
SW846M8015 SW845M8015
Result LOD LOQ EQL Dll. Unite Code Anl Date
Prep Date: 04/18/05
Prep Method Anl Method
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
0.12
< 0.023
< 0.019
< 0.019
0.027
0.020
0.023
0.036
0.026
0.028
0.025
< 0.022
0.041
< 0.022
0.021
0.060
< 0.020
0.031
64
52
83
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.022
0.020
0.016
0.066
0.076
0.065
0.064
0.059
0.065
0.060
0.060
0.069
0.064
0.055
0.073
0.055
0.073
0.057
0.075
0.068
0.054
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
Q
Q
Q
Q
Q
Q
Q
0
Q
Q
Q
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem Analytical Report Number: 858276 A Division of Pace Analytical Services, Inc.
C l ien t : NATURAL RESOURCE TECHNOLOGY
Project Name : WPSC - MARINETTE
Project Number : 1549
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collection Date : 04/14/05
Report Date: 04/29/05
Field ID :
INORGANICS
Test
MW-305
Result LOD LOQ EQL Dil. Units
Lab Sample Number: 858276-004
Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 + N02
Sulfate
61
8.1
260
6.6
47
17
0.14
6.3
0.31
0.83
55
0.48
21
1.0
2.8
1 ug/L
1 ug/L
1 mg/L
5 mg/L
1 mg/L
04/23/05 SW846 6010B SW856 6010B
04/23/05 SW846 6010B SW856 6010B
04/25/05 EPA 310.2 EPA 310.2
04/18/05 EPA 353.2 EPA 353.2
04/18/05 EPA 300.0 EPA 300.0
P V O C
Analyte
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a.h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nltrobenzen6-d5
2-Fluorobiphenyl
Terphenyl-d14
Result LOD LOQ EQL Dll. Unite Code Anl Date
Prep Date: 04/19/05
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trifluorotoluene
< < < < < < < <
0,39
0,40
0.14
0.40
0.36
0.36
0.36
0.74
104
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46 ~
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 50306
SW846M8021
SW846M8021
SW846M8021
SW846M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
METHANE
Analyte
Methane
P A H / PNA
Analyte
Result
< 10
Result
LOD
LOD
LOQ
LOQ
EQL
10
EQL
Dil.
1
DIL
Unite
ug/L
Unite
Code
Code
Anl Date
04/25/05
Anl Date
Prep Date: 04/25/05
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 04/18/05
Prep Method Anl Method
0.025
0.036
0.019
0.35
0.098
0.24
0.20
0.24
0.24
0.21
0.21
0.071
0.21
0.022
0.19
0.098
0.10
0.32
66
60
76
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.022
0.020
0.016
0.066
0.076
0.065
0.064
0.059
0.065
0.060
0.060
0.069
0.064
0.055
0.073
0.055
0.073
0.057
0.075
0.068
0.054
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
Q 04/19/05
Q 04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
Q 04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
SW846 3610C
SW846 3510C
SW846 35IOC
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 35IOC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW848 3510C
SW846 35IOC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW845 351 OC
8270C-SIM
8270C-SIM
8270C-SIM
B270C-SIM
B270C-SIM
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
a270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem Analytical Report Number: 858276 A Division of Pace Analytical Services, Inc.
C l ien t : NATUFIAL RESOURCE TECHNOLOGY
Project Name : WPSC - MARINETTE
Project Number : 1549
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collect ion Date : 04/13/05
Report Date : 04/29/05
Field ID :
I N O R G A N I C S
Test
MW-306
Result LOD LOQ EQL Dil. Unite
Lab Sample Number : 858276-005
Code Anl Date Prep Method Anl Method
Iron -Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 + N02
Sulfate
4500
650
380
< 0.061
100
17
0.14
32
0.061
4.2
55
0.48
110
0.20
14
1
1
5
1
5
ug/L
ug/L
mg/L
mg/L
mg/L
04/27/05
04/27/05
04/25/05
04/18/05
04/18/05
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
P V O C
Analyte Result LOD LOQ EQL Dll. Unite Code Anl Date
Prep Date: 04/20/05
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m -i- p
a,a,a-Trifluorotoluene
300
75
< 0.34
350
< 0.90
13
300
390
104
0.98
0.99
0.34
1.0
0.90
0.89
0.90
1.9
3.3
3.3
1.1
3.3
3.0
3.0
3.0
6.2
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
1
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
% Recov
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846M8021
SW846M8021
SW846 M8021
SW846 M8021
M E T H A N E
Analyte
Methane
P A H / PNA
Analyte
Result
110
Result
LOD
LOD
LOQ
LOQ
EQL
10
EQL
Dil.
1
Dil.
Unite
ug/L
Unite
Code
Code
Anl Date
04/25/05
Anl Date
Prep Date: 04/25/05
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 04/18/05
Prep Method Anl Method
1 -Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
7.4
0.46
0.67
0.082
0.022
< 0.020
< 0.018
< 0.018
< 0.021
< 0.019
< 0.017
< 0.022
0.12
0.17
< 0.017
410
0.050 •
0.23
89
65
71
0.020
0.023
0.020
0.020
0.018
0.020
0.018
0.018
0.021
0.019
0.017
0.022
0.017
0.022
0.017
45
0.021
0.016
0.067
0.076
0.065
0.065
0.059
0.066
0.061
0.060
0.069
0.065
0.055
0.074
0.055
0.073
0.057
150 ;
0.069
0.055
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
?000 ug/L
ug/L
ug/L
%Recov
%Recov
% Recov
E
E
Q
D
Q
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/20/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 35IOC
SW846 3510C
8270C-SIM
8270C-SIIVI
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem A Division of Pace Analytical Services, Inc.
Client: NATURAL RESOURCE TECHNOLOGY Project Name ; WPSC - MARINETTE
Project Number: 1549
Analytical Report Number: 858276 1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type: WATER
Collection Date: 04/13/05 Report Date: 04/29/05
Field ID :
INORGANICS
Test
MW-307R
Result LOD LOQ EQL Dil . Unite
Lab Sample Number : 858276-006
Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N 0 3 + N02
Sulfate
28000
2900
710
< 0.061
12
17
0.14
32
0.061
0.83
55
0.48
110
0.20
2.8
1
1
5
1
1
ug/L
ug/L
mg/L
mg/L
mg/L
04/27/05
04/27/05
04/25/05
04/16/05
04/18/05
SW846 60108
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 601 OB
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
PVOC
Analyte Result LOD LOQ EQL Dil. Unite Code Anl Date
Prep Date: 04/20/05
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m •»- p
a,a,a-Trifluorotoluene
< <
< < < < <
0.39
0.40
0.57
0.40
0.36
0.36
0.36
0.74
103
0.39
0.40
0.14
0 4 0
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
SW846 5030B
SW846 5O30B
SW846 5O30B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
METHANE
Analyte
Methane
P A H / P N A
Analyte
Result
4200
Result
LOD
LOD
LOQ
LOQ
EQL
250
EQL
Dil .
25
Dil .
Unite
ug/L
Unite
Code
Code
Anl Date
04/25/05
Anl Date
Prep Date: 04/25/05
Prep Method Anl Method
SW845M8015 SW846M8015
Prep Date: 04/18/05
Prep Method Anl Method
1 -Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno( 1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
2.1
< 0.23
3.4
< 0.20
0.55
< 0.20
< 0.18
< 0.18
< 0.21
< 0:19
< 0.17
< 0.22
0.53
0.90
< 0.17
0.48
1.1
0.51
0.0
0.0
0.0
0.20
0.23
0.20
0.20
0.18
0.20
0.18
0.18
0.21
0.19
0.17
0.22
0.17
0.22
0.17
0.23
0.21
0.16
0.67
0.76
0.65
0.65
0.59
0.66
0.61
0.60
0.69
0.65
0.55
0.74
0.55
0.73
0.57
0.75
0.69
0.55
10 10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
Q
Q
Q
Q
D
D
D
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SWB46 351 OC
SWB46 3510C
SW846 351 OC
SW846 351 OC
SW846 3510C
SW846 3510C
8270C-SIM
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8Z70C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
8270C-S1M
8270C-SIM
8270C-SIM
En Chem Analytical Report Number: 858276 A Division of Pace Analytical Services, Inc.
C l ien t : NATURAL FIESOURCE TECHNOLOGY
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Project Name : WPSC - MARINETTE
Project Number : 1549
Matrix Type : WATER
Collection Date : 04/13/05
Report Date: 04/29/05
Field ID :
INORGANICS
Test
MW-308
Result LOD LOQ EQL Dil. Unite
Lab Sample Number : 858276-007
Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen,.N03 + N02
Sulfate
350 17
1500 0.14
540 32
< 0.061 O.061
14 0.83
55
0.48
110
0.20
2.8
1 ug/L
1 ug/L
5 mg/L
1 mg/L
1 mg/L
04/27/05
04/27/05
04/25/05
04/18/05
04/18/05
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0 •
PVOC
Analyte Result LOD LOQ EQL Dil . Unite Code Anl Date
Prep Date: 04/20/05
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trifluorotoluene
1 -Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)nuoranthene
Benzo(ghi) perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
1.4 0.39
< 0.40 0.40
0.33 0.14
0.71 0.40
< 0.36 0.36
< 0.36 0.36
0.76 0.36
< 0.74 0.74
102
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
04/20/05
04/20/05
Q 04/20/05
Q 04/20/05
04/20/05
04/20/05
Q 04/20/05
04/20/05
04/20/05
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
5030B
5030B
5030B
5030B
5030B
5030B
5030B
5030B
5030B
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
M8021
M8021
M8021
M8021
M8021
M8021
M8021
M8021
M8021
METHANE
Analyte
Methane
PAH/ PNA
Analyte
Result
660
Result
LOD
LOD
LOQ
LOQ
EQL
50
EQL
Dil.
5
Dil.
Unite
ug/L
Unite
Code
Code
Anl Date
04/25/05
Anl Date
Prep Date: 04/25/05
Prep Method Anl Method
SW846M8015 SW846 M8015
Prep Date: 04/18/05
Prep Method Anl Method
21
2.3
19
2.3
2.0
2.0
1.8
1.8
2.1
2.0
1.7
2.2
1.7
2.2
1.7
12
3.7
1.7
0
0
0
2.0
2.3
2.0
2.0
1.8
2.0
1.8
1.8
2.1
2.0
1.7
2.2
1.7
2.2
1.7
2.3
2.1
1.7
6.8
7.7
6.6
6.6
6.0
6.7
6.2
6.1
7.0
6.6
5.6
7.5
5.6
7.4
5.8
7.6
6.9
5.5
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
04/20/05
04/20/05
04/20/05
Q 04/20/05
Q 04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
Q 04/20/05
04/20/05
D 04/20/05
D 04/20/05
D 04/20/05
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 35IOC
SW846 35IOC
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 35IOC
SW846 35IOC
SW846 35IOC
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SII\/1
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem Analytical Report Number: 858276 A Division of Pace Analytical Services, Inc.
Client: NATURAL RESOURCE TECHNOLOGY Project Name : WPSC - MARINETTE
Project Number: 1549
Field ID: MW-310
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER Collection Date : 04/13/05
Report Date : 04/29/05
Lab Sample Number : 858276-008
INORGANICS
Test Result LOD LOQ EQL Dil. Unite Code Anl Date Prep Method Anl Method
Iron - Dissolved Manganese - Dissolved Alkalinity as CaC03 Nitrogen, N03 + N02 Sulfate
21000
1500
370
0.061 32
17 0.14 32 0.061
0.83
55
0.48
110 0.20 2.8
ug/L ug/L mg/L mg/L mg/L
04/27/05 04/27/05 04/25/05 04/18/05 04/18/05
SW846 6010B SW846 6010B EPA 310.2 EPA 353.2 EPA 300.0
SW846 6010B SW846 6010B EPA 310.2 EPA 353.2 EPA 300.0
PVOC
Analyte Result LOD LOQ EQL Dil. Unite Code Anl Date
Prep Date: 04/20/05
Prep Method Anl Method
1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene
Benzene Ethylbenzene Methyl-tert-butyl-ether
Toluene Xylene, o Xylenes, m + p a,a,a-Trifluorotoluene
< < < < < < < <
0.39 0.40 0.14
0.40 0.36 0.36 0.36 0.74 103
0.39 0.40 0.14 0.40
0.36 0.36 0.36 0.74
1.3 1.3
0.46 1.3 1.2 1.2 1.2 2.5
ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L
% Recov
04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05
SW846 5030B SW846 5030B
SW846 5030B SW846 5030B SW846 5030B
SW846 5030B SW846 5030B SW846 5030B SW846 5030B
SW846 M8021 SW846 M8021 SW846 M8021 SW846 M8021 SW846 M8021 SW846 M8021 SW846 M8021 SW846 M8021 SW846 M8021
METHANE
Analyte
Methane
PAH/ PNA
Analyte
Result
34
Result
LOD
LOD
LOQ
LOQ
EQL
10
EQL
Dil.
1
Dil.
Unite
ug/L
Unite
Code
Code
Anl Date
04/25/05
Anl Date
Prep Date: 04/25/05
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 04/18/05
Prep Method Anl Method
1 -Methylnaphthalene 2-Methylnaphthalene Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene
Benzo(a)pyrene Benzo(b)fluoranthene Benzo(ghi)perylene
Benzo(k)fluoranthene Chrysene Dibenz(a,h)anthracene Fluoranthene Fluorene lndeno(1,2,3-cd)pyrene
Naphthalene Phenanthrene Pyrene Nitrobenzene-d5 2-Fluorobiphenyl Terphenyl-d14
3.4
0.46
5.3
0.39
1.3
0.40
0.37
0.36
0.42
0.39
0.33
0.44
0.41
1.6
0.34
3.7
2.8
046
0
0
0
0.40
0.46
0.39
0.39
0.36
0.40
0.37
0.36
0.42
0.39
0.33
0.44
0.33
0.44
0.34
0.45
0.41
0.33
1.3
1.5
1.3
1.3
1.2
1.3
1.2
1.2
1.4
1.3
1.1
1.5
1.1
1.5
1.1
1.5
1.4
1.1
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
ug/L ug/L
ug/L ug/L ug/L
ug/L ug/L ug/L ug/L ug/L
ug/L ug/L ug/L ug/L ug/L ug/L
ug/L ug/L %Recov %Recov %Recov
04/19/05 04/19/05
04/19/05 04/19/05 04/19/05 04/19/05 04/19/05 04/19/05 04/19/05
04/19/05
04/19/05
04/19/05
Q 04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
O 04/19/05
D 04/19/05
D 04/19/05
D 04/19/05
SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW845 3510C SW846 351 OC SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C
8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM B270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-S1M 8270C-SIM
En Chem Analytical Report Number: 858276 A Division of Pace Analytical Sen/ices, Inc.
C l i e n t : NATURAL RESOURCE TECHNOLOGY
Project Name : WPSC - MARINETTE
Project N u m b e r : 1549
Field ID : MW-1
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collect ion Date : 04/13/05
Report Date : 04/29/05
Lab Sample Number : 858276-009
I N O R G A N I C S
Test Result LOD LOQ EQL Dil. Unite Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 + N02
Sulfate
12000
1300
540
0.061
20
17
0.14
32
0.061
0.83
55
0.48
110
0.20
2.8
ug/L
ug/L
mg/L
mg/L
mg/L
04/27/05
04/27/05
04/25/05
04/18/05
04/18/05
SW346 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 60108
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
P V O C
Analyte Result LOD LOQ EQL Dil. Unite Code Anl Date
Prep Date; 04/20/05
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m • p
a,a,a-Trifluorotoluene
1 -Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
103
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846 M8021
SW846 M8021
SWB46 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
METHANE
Analyte
Methane
PAH/ PNA
Analyte
Result
5300
Result
LOD
LOD
LOQ
LOQ
EQL
500
EQL
Dil.
50
Dil.
Unite
ug/L
Unite
Code
Code
Anl Date
04/25/05
Anl Date
Prep Date: 04/25/05
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 04/18/05
Prep Method Anl Method
0.020
0.023
0.042
0.020
0.018
0.020
0.018
0.018
0.021
0.020
0.017
0.022
' 0.017
0.022
0.017
0.055
0.021
0.017
84
65
84
0.020
0.023
0.020
0.020
0.018
0.020
0.018
0.018
0.021
0.020
0.017
0.022
0.017
0.022
0.017
0.023
0.021
0.017
0.068
0.077
0.066
0.066
0.060
0.067
0.062
0.061
0.070
0.066
0.056
0.075
0.056
0.074
0.058
0.076
0.059
0.055
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
04/19/05
04/19/05
Q 04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
Q 04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SWB46
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
35 IOC
351 OC
3510C
351 OC
351 OC
351 OC
351 OC
351 OC
351 OC
351 OC
35 IOC
351 OC
351 OC
351 OC
351 OC
351 OC
351 OC
351 OC
351 OC
3510C
3510C
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIIVI
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIIVI
8270C-SIM
Pace Analytical Services, Inc.
Analytical Report Number: 858276
Client: NATURAL RESOURCE TECHNOLOGY
Project Name : WPSC - MARINETTE
Project Number: 1549 REVISED
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collection Date: 04/13/05
Report Date : 06/09/05
Field ID :
I N O R G A N I C S
Test
MW-311
Result LOD LOQ EQL Dil . Unite
Lab Sample Number : 858276-010
Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N 0 3 -i- N02
Sulfate
2700
2700
690
< 0.061
28
17
0.14
32
0.051
0.83
55
0.48
110
0.20
2.8
1
1
5
1
1
ug/L
ug/L
mg/L
mg/L
mg/L
04/27/05
04/27/05
04/25/05
04/18/05
04/18/05
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
PVOC
Analyte Result LOD LOQ EQL DiL Unite Code Anl Date
Prep Date: 04/20/05
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trifluorotoluene
88
22
260
700
< 0.72
15
170
190
102
0.78
0.79
0.28
0.80
0.72
0.71
0.72
1.5
2.6
2.6
0.92
2.7
2.4
2.4
2.4
4.9
2
2
2
2
2
2
2
2 .
1
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
SW846 5030B
SW846 5Q30B
SWB46 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846 M8021
SW846 M8021
.SW846M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846M8021
SW846 M8021
METHANE
Analyte
Methane
P A H / P N A
Analyte
Result
1200
Result
LOD
LOD
LOQ
LOQ
EQL
100
EQL
Dil .
10
Dil.
Unite
ug/L
Unite
Code
Code
Anl Date
04/25/05
An l Date
Prep Date: 04/25/05
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 04/18/05
Prep Method Anl Method
1 -Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)nuoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
170
240
170
4.6
15
< 3.9
< 3.6
< 3.6
< 4.1
< 3.9
< 3.3
< 4.4
3.8
37
< 3.4
2000
33
5.1
0
0
0
160
4.5
160
3.9
3.5
3,9
3.6
3.6
4.1
3.9
3.3
4.4
3.3
4.4
3.4
180
4.1
3,3
530
15
520
13
12
13
12
12
14
13
11
15
11
15
11
600
14
11
8000
200
8000
200
200
200
200
200
200
200
200
200
200
200
200
8000
200
200
200
200
200
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
QD
E
QD
Q
Q
D
Q
D
D
D
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
SW846 3510C
SW846 3510C
SW846 35IOC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 35IOC
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
B270C-SIM
B270C-SIM
8270C-SIIV!
8270C-S1M
En Chem Analytical Report Number: 858276 A Division of Pace Analytical Services, Inc.
C l ien t : NATURAL RESOURCE TECHNOLOGY
Project Name : WPSC - MARINETTE
Project Number : 1549
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix T y p e : WATER
Col lect ion Date : 04/13/05
Report Date : 04/29/05
Field ID :
INORGANICS
Test
MW-2R
Result LOD LOQ EQL Dil. Unite
Lab Sample Number : 858276-010
Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 + N02
Sulfate
2700
2700
690
0.061
28
17
0.14
32
0.061
0.83
55
0.48
110
0.20
2.B
1 ug/L
1 ug/L
5 mg/L
1 mg/L
1 mg/L
04/27/05
04/27/05
04/25/05
04/18/05
04/18/05
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.O
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
P V O C
Analyte Result LOD LOQ EQL Dil. Unite Code Anl Date
Prep Date: 04/20/05
Prep Method Anl Method
1,2,4-Trimelhylben2ene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ethei
Toluene
Xylene, o Xylenes, m •<• p
a,a,a-Trifluorotoluene
1 -Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nltrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
8B
22
260
700
< o:72
15
170
190
102
0.78
0.79
0.28
0.80
0.72
0.71
0.72
1.5
2.6
2.6
0.92
2.7
2.4
2.4
2.4
4.9
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846M8021
SW846 M8021
SW846MB021
SW845 M8021
SW846 M8021
SW846M8021
SW846 MB021
SW846M8021
METHANE
Analyte
Methane
PAH/PNA
Analyte
Result
1200
Result
LOD
LOD
LOQ
LOQ
EQL
100
EQL
Dil.
10
Dil.
Unite
ug/L
Unite
Code
Code
Anl Date
04/25/05
Anl Date
Prep Date: 04/25/05
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 04/18/05
Prep Method Anl Method
170
240
170
4.6
15
< 3.9
< 3.6
< 3.6
< 4.1
< 3.9
< 3.3
< 4.4
3.8
37
160
4.5
160
3.9
3.5
3.9
3.6
3.6
4.1
3.9
3.3
4 4
3.3
4.4
< 3.4 3.4
2000 180
33 4.1
5.1 3.3
0
0
0
530
15
520
13
12
13
12
12
14
13
11
15
11
15
11
600
14
11
8000
200
8000
200
200
200
200
200
200
200
200
200
200
200
200
8000
200
200
200
200
200
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov %Recov
QD
E
QD
Q
Q
D
D
D
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
SW846 3510C
SW846 35IOC
SW846 35IOC
SWB46 3510C
SWB46 3510C
SWB46 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
B270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem Analytical Report Number: 858276 A Division of Pace Analytical Services, Inc.
Client: NATURAL RESOURCE TECHNOLOGY Project Name : WPSC - MARINETTE
Project Number: 1549
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER Collection Date : 04/14/05
Report Date : 04/29/05
Field ID :
INORGANICS
Test
MW-3R
Result LOD LOQ EQL Dil. Unite
Lab Sample Number : 858276-011
Code Anl Date Prep Method Anl Method
Iron - Dissolved Manganese - Dissolved Alkalinity as CaC03 Nitrogen, N03 + N02 Sulfate
17
21
400
6.4
280
17
0.14
6.3
0.31
8.3
55
0.48
21
1.0
28
1
1
1
5
10
ug/L
ug/L
mg/L
mg/L
mg/L
04/27/05
04/27/05
04/25/05
04/18/05
04/18/05
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846e010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
PVOC
Analyte
1 -Methylnaphthalene 2-Methylnaphthalene Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(ghi)perylene Ben2o(k)fluoranthene Chrysene Dibenz(a,h)anthracene Fluoranthene Fluorene lndeno(1,2,3-cd)pyrene Naphthalene Phenanthrene
Pyrene Nitrobenzene-d5 2-Fluorobiphenyl Terphenyl-d14
Result LOD LOQ EQL Dil. Unite Code Anl Date
Prep Date: 04/20/05
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trifluorotoluene
< < < < < < < <
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
103
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1-2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846M8021
METHANE
Analyte
Methane
PAH/ PNA
Analyte
Result
< 10
Result
LOD
LOD
LOQ
LOQ
EQL
10
EQL
Dil.
1
Dil.
Unite
ug/L
Unite
Code
Code
Anl Date
04/25/05
Anl Date
Prep Date: 04/25/05
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 04/18/05
Prep Method Anl Method
0.020 0.023 0.019
0.019 0.018 0.020 0.018
0.018 0.021 0.019 0.016
0,022
0.016 0.022 0.017
0.022
0.020
0.016 87 66
98
0.020 0.023 0.019 0.019 0.018 0.020 0.018 0.018 0.021 0.019 0.016 0.022 0.016 0.022 0.017 0.022 0.020 0.016
0.066
0.076
0.065
0.064
0.059
0.065
0.060
0.060
0.069
0.064
0.055
0.073
0.055
0.073
0.057
0.075
0.068
0.054
ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L
ug/L ug/L ug/L
ug/L ug/L
ug/L ug/L ug/L %Recov %Recov %Recov
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
SW846 351 OC SW846 3510C SW846 3510C SW846 3510C SWB46 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 351 OC SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C
8270C-S1M 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-S1M 8270C-S;M
8270C-S1M 8270C-S1M 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM
En Chem Analytical Report Number: 858276 A Division of Pace Analytical Services, Inc.
Client: NATURAL RESOURCE TECHNOLOGY
Project Name : WPSC - MARINETTE
Project Number : 1549
Field ID : MW-5
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type: WATER
Collection Date : 04/14/05
Report Date : 04/29/05
Lab Sample Number: 858276-012
INORGANICS
Test Result LOD LOQ EQL Dil. Unite Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 + N02
Sulfate
< 17
420
300
2.9
38
17
0.14
6.3
0.061
0.83
55
0.48
21
0.20
2.8
ug/L
ug/L
mg/L
mg/L
mg/L
04/27/05
04/27/05
04/25/05
04/18/05
04/18/05
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 601 OB
SW846 601 OB
EPA 310.2
EPA 353.2
EPA 300.0
PVOC
Analyte
PAH/ PNA
Analyte
Result LOD LOQ EQL Dil. Unite Code Anl Date
Prep Date: 04/20/05
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m -i- p
a,a,a-Trifluorotoluene
< < < < < < < <
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
103
0.39
0.40
0.14
D.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
% Recov
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
METHANE
Analyte
Methane
Resul t
< 10
LOD LOQ EQL
10
Dil.
1
Unite
ug/L
Code Anl Date
04/25/05
Prep Date: 04/25/05
Prep Method A n l Method
SW846M8015 SW846M8015
Result LOD LOQ EQL Dil. Units Code Anl Date
Prep Date: 04/18/05
Prep Method Anl Method
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
< < < < < < < < < < < < < < < < < <
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.01 B
0.022
0.016
0.022
0.017
0.022
0.020
0.016
64
52
87
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.022
0.020
0.016
0.066
0.076
0.065
0.064
0.059
0.065
0.060
0.060
0.069
0.064
0.055
0.073
0.055
0.073
0.057
0.075
0.068
0.054
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 35IOC
SW846 3510C
SW846 35IOC
SW846 3510C
SW846 35IOC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 351 OC
SW846 35IOC
SW846 35IOC
SW846 3510C
SW846 3510C
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIIV1
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
En Chem Analytical Report Number: 858276 A Division of Pace Analytical Services, Inc.
C l i e n t : NATURAL RESOURCE TECHNOLOGY
Project Name : WPSC - MARINETTE
Project N u m b e r : 1549
Fie ld ID : P-302
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collection Date : 04/14/05
Report Date : 04/29/05
Lab Sample Number : 858276-013
INORGANICS
Test Result LOD LOQ EQL Dil. Unite Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N03 -i- N02
Sulfate
6300
230
250
< 0.061
30
17
0.14
6.3
0.061
0.83
55
0.48
21
0.20
2.8
ug/L
ug/L
mg/L
mg/L
mg/L
04/27/05
04/27/05
04/25/05
04/18/05
04/18/05
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.O
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
P V O C
Analyte Result LOD LOQ EQL Di l . Unite Code Anl Date
Prep Date: 04/20/05
Prep Methtod Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m -t p
a,a,a-Trifluorotoluene
< < < < < < < <
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
103
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
1 ug/L
1 ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846M8021
SW846 M8021
SW846 M8021
SW846 M8021
METHANE
Analyte
Methane
PAH/ PNA
Analyte
Result
17
Result
LOD
LOD
LOQ
LOQ
EQL
10
EQL
Dil.
1
Dil.
Unite
ug/L
Unite
Code Anl Date
04/25/05
Code Anl Date
Prep Date: 04/25/05
Prep Method Anl Method
SW846M8015 SW846M8015
Prep Date: 04/18/05
Prep Method Anl Method
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-dS
2-Fluorobiphenyl
Terphenyl-d14
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.022
0.020
0.016
90
70
95
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.022
0.020
0.016
0.066
0.076
0.065
0.064
0.059
0.065
0.060
0.060
0.069
0.064
0.055
0073
0,055
0.073
0.057
0.075
0.068
0.054
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L .
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
SW846
35 IOC
3510C
351 OC
3510C
3510C
351 OC
35 IOC
3510C
3510C
35 IOC
35 IOC
35 IOC
35 IOC
3510C
351 OC
35 IOC
3510C
351 OC
3510C
351 OC
3510C
e270C-SIIVI
8270C-SIM
8270C-SIM
8270C-SIM
S 2 7 0 C - S ; M
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8276C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIIW
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
En Chem Analytical Report Number: 858276 A Division of Pace Analytical Services, Inc.
C l i en t : NATUFWL RESOURCE TECHNOLOGY
Project Name : WPSC - MARINETTE
Project Number : 1549
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Col lect ion Date : 04/14/05
Report Date : 04/29/05
Field ID :
INORGANICS
Test
P-303
Result LOD LOQ EQL Dil . Unite
Lab Sample Number : 858276-014
Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity as CaC03
Nitrogen, N 0 3 + N02
Sulfate
33
34
190
0.18
680
17
0.14
6.3
0.061
17
55
0.48
21
0.20
56 "
1
1
1
1
20
ug/L
ug/L
mg/L
mg/L
mg/L
Q
Q
04/27/05
04/27/05
04/25/05
04/18/05
04/18/05
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
P V O C
Analyte
P A H / P N A
Analyte
Result LOD LOQ EQL Dil. Unite Code Anl Date
Prep Date: 04/20/05
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m • p
a,a,a-Trifluorotoluene
< < < < < < < <
0,39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
103
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1-2 .
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1 ug/L
ug/L
%Recov
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SWB46 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
METHANE
Analyte
Methane
Result
< 10
LOD LOQ EQL
10
Dil .
1
Unite
ug/L
Code Anl Date
04/25/05
Prep Date: 04/25/05
Prep Method Anl Method
SW846M8015 SW846M8015
Result LOD LOQ EQL Dll. Unite Code Anl Date
Prep Date: 04/18/05
Prep Method Anl Method
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
< < < < < < < < < < < <
< < < <
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.027
0.022
0.017
0.022
0.020
0.027
95
69
93
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.022
0.020
0.016
0.066
0.076
0.065
0.064
0.059
0.065
0.060
0.060
0.069
0.064
0.055
0.073
0.055
0.073
0.057
0.075
0.068
0.054
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
ug/L Q 04/19/05
ug/L
ug/L
ug/L
ug/L
04/19/05
04/19/05
04/19/05
04/19/05
ug/L Q 04/19/05
%Recov
%Recov
%Recov
04/19/05
04/19/05
04/19/05
SW846 3510C
SW846 3510C
SW846 3510C
SW846 35IOC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 35IOC
SW846 35IOC
SW846 35IOC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 35IOC
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIWI
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIIV1
8270C-SIM
En Chem A Division of Pace Analytical Services, Inc.
Analytical Report Number: 858276
Client: NATURAL RESOURCE TECHNOLOGY
Project Name : WPSC Project Number: 1549
Field ID: P-304
PVOC
Analyte
1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene
Benzene Ethylbenzene Methyl-tert-butyl-ether
Toluene Xylene, o Xylenes, m • p a,a,a-Trifluorotoluene
PAH/ PNA
Analyte
1-Methylnaphthalene
2-Methylnaphthalene Acenaphthene Acenaphthylene
Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(ghi)perylene Benzo(k)fluoranthene
Chrysene Dibenz(a,h)anthracene
Fluoranthene Fluorene lndeno(1,2,3-cd)pyrene
Naphthalene Phenanthrene Pyrene Nitrobenzene-d5 2-Fluorobiphenyl
Terphenyl-d14
- MARINE 1 1 b
< < < < < < < <
< < < < < < < < < < < < < < < < < <
Result
0.39 0.40 0.14
0.40
0.36
o:36
0.36
0.74
104
Result
0.15
0.17
0.15
0.15
0.13
0.15
0.14
0.14
0.16
0.15
0.12
0.17
0.12
0.16
0.13
0.17
0.15
0.12
94
51
88
LOD
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
LOD
0.15
0.17
0.15
0.15
0.13
0.15
0.14
0.14
0.16
0.15
0.12
0.17
0.12
0.16
0.13
0.17
0.15
0.12
LOQ EQL Dil.
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
LOQ EQL Dil.
0.50
0.57
0.49
0.49
0.45
0.49
0.46
0.45
0.52
0.49
0.41
0.56
0.42
0.55
0.43
0.56
0.51
0.41
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1241 Bellevue Street Green Bay, Wl 64302 920469-2436
Matrix Type: WATER
Collection Date : 04/14/05 Report Date: 04/29/05
Lab Sample
Unite Code
ug/L ug/L ug/L ug/L ug/L ug/L ug/L
ug/L %Recov
Unite Code
ug/L
ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L %Recov
%Recov %Recov
Anl Date
04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/06 04/20/05
Anl Date
04/20/05
04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05
04/20/05 04/20/05 04/20/05 04/20/05
.04/20/05 04/20/05 04/20/05
f^umber: 858276-015
Prep Date: 04/20/05
Prep Method
SW846 5030B
SW846 5030B SW846 5030B SW846 5030B SW846 5030B SW846 5030B SW845 5030B SW846 5030B SW846 5030B
Anl Method
SW846 M8021 SW846M8021 SW846 M8021 SW846 M8021 SW846 M8021 SW846M8021 SW846 M8021 SW846 M8021 SW846 M8021
Prep Date: 04/18/05
Prep Method
SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW845 351 OC SW846 3510C SW846 3510C SW846 351 OC SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 351 OC SW846 3510C
Anl Method
8270C-SIM 8270C-SIM 8270C-SIM 8270C-S1M 8270C-S1M 8270C-S1M 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM
8270C-SIM 8270C-SIM e270C-SIM 8270C-SIM 8270C-S1M 8270C-S1M
8270C-SIM 8270C-SIM
8270C-SIM 8270C-S1M
En Chem Analytical Report Number: 858276 A Division of Pace Analytical Services, Inc.
Client: NATURAL RESOURCE TECHNOLOGY
Project Name : WPSC - MARINETTE
Project Number : 1549
Field ID : P-305
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type: WATER
Collection Date : 04/14/05
Report Date : 04/29/05
Lab Sample Number : 858276-016
INORGANICS
Test Result LOD LOQ EQL Dil. Unite Code Anl Date Prep Method Anl Method
Iron - Dissolved
Manganese - Dissolved
Alkalinity, as CaC03
Nitrogen, N03 + N02
Sulfate
6200
1800
690
0,11
150
17
0.14
32
0.061
4.2
55
048
110
0.20
14
1 ug/L
1 ug/L
5 . mg/L
1 mg/L
5 mg/L
04/27/05
04/27/05
04/25/05
04/18/05
04/19/05
SW846 6010B
SW846 6Q10B
EPA 310.2
EPA 353.2
EPA 300.0
SW846 6010B
SW846 6010B
EPA 310.2
EPA 353.2
EPA 300.0
PVOC
Analyte Result LOD LOQ EQL Dil. Unite Code Anl Date
Prep Date: 04/19/05
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trifluorotoluene
< < < < < < < <
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
101
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.45
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
METHANE
Analyte Result LOD LOQ EQL Dil. Unite
Prep Date: 04/25/05
Code Anl Date Prep Method Anl Method
Methane 54 10 ug/L 04/25/05 SW846M8015 SW846M8015
PAH/ PNA
Analyte Result LOD LOQ EQL Dil. Unite Code Anl Date
Prep Date: 04/18/05
Prep Method Anl Method
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
< < < < < < < < < < < <
< <
< <
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.016
0.021
0.019
0.016
0.022
0.018
0.022
0.017
0.026
0.020
0.016
102
78
84
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.022
0.020
0.016
0.066
0.076
0.065
0.064
0.059
0.065
0.060
0.060
0.069
0.064
0.055
0.073
0.055
0.073
0.057
0.075
0.068
0.054
1 ug/L
1 ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
ug/L Q 04/19/05
ug/L
ug/L
04/19/05
04/19/05
ug/L Q 04/19/05
ug/L
ug/L
%Recov
%Recov
%Recov
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
8270C-SIM
8270C-SIM
B270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem A Division of Pace Analytical Services, Inc.
Client: NATURAL RESOURCE TECHNOLOGY
Project Name : WPSC - MARINETTE
Project Number: 1549
Field ID: QC-1
Analytical Report Number: 858276 1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collection Date :
Report Date : 04/29/05
Lab Sample Number : 858276-017
PVOC
Analyte Result LOD LOQ EQL Dil. Unite Code Anl Date
Prep Date: 04/19/05
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzere
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m + p
a,a,a-Trifluorotoluene
< <
< < < < <
0.39
0.40
0.80
0.40
0.36
0.36
0.36
0.74
100
0.39
0.40
0.14
040
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.6
1 ug/L
ug/L
t ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 5030B
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846M8021
PAH/ PNA
Analyte Result LOD LOQ EQL Dil. Unite Code Anl Date
Prep Date: 04/19/05
Prep Method Anl Method
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a.h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
3.0
< 0.45
5.5
< 0.39
1-2
< 0.39
< 0.36
< 0.36
< 0.41
< 0.39
< 0.33
< 0.44
0.56
1.2
< 0.34
0.55
2.1
0.59
0
0
0
0.40
0.45
0.39
0.39
0.35
0.39
0.36
0.36
0.41
0.39
0.33
0.44
0.33
0.44
0.34
0.45
041
0.33
1.3
1.5
1.3
1.3
1.2
1.3
1.2
1.2
14
1.3
1.1
1.5
1.1
1.5
1.1
1.5
14
1.1
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
%Recov
%Recov
Q
Q
Q
Q
D
D
D
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/06
04/20/05
04/20/05
04/20/05
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
8270C-S1M
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
En Chem Analytical Report Number: 858276 A Division of Pace Analytical Services, Inc.
Client: NATURAL RESOURCE TECHNOLOGY
Project Name : WPSC - MARINETTE
Project Number: 1549
Field ID : QC-2
1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type : WATER
Collection Date :
Report Date : 04/29/05
Lab Sample Number : B58276-018
PVOC
Analyte Result LOD LOQ EQL Dil. Unite Code Anl Date
Prep Date: 04/19/05
Prep Method Anl Method
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Benzene
Ethylbenzene
Methyl-tert-butyl-ether
Toluene
Xylene, o
Xylenes, m -i- p
a,a,a-Trifluorotoluene
< < < < < < < <
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
100
0.39
0.40
0.14
0.40
0.36
0.36
0.36
0.74
1.3
1.3
0.46
1.3
1.2
1.2
1.2
2.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recov
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
04/19/05
SW846 5O30B
SW846 5O30B
SW846 5O30B
SW846 5030B
SW846 5030B
SW846 5O30B
SW846 5030B
SW846 5O30B
SW846 5030B
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
SW846 M8021
PAH/ PNA
Analyte Result LOD LOQ EQL Dil. Unite Code Anl Date
Prep Date: 04/19/05
Prep Method Anl Method
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghl)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Nltrobenzene-d5
2-Fluorobiphenyl
Terpheriyl-d14
< < < < < < < < < < < < < < <
< <
0,020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.034
0.020
0.016
106
79
106
0.020
0.023
0.019
0.019
0.018
0.020
0.018
0.018
0.021
0.019
0.016
0.022
0.016
0.022
0.017
0.022
0.020
0.016
0.066
0.076
0.065
0.064
0.059
0.065
0.060
0.060
0.069
0.054
0.055
0.073
0.055
0.073
0.057
0.075
0.068
0.054
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
ug/L Q 04/20/05
ug/L
ug/L
%Recov
%Recov
% Recov
04/20/05
04/20/05
04/20/05
04/20/05
04/20/05
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 35IOC
SW846 3510C
SW846 3510C
SW846 35IOC
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 3510C
SW846 3510C
SW846 351 OC
SW846 35IOC
SW846 3510C
SW846 351 OC
SW846 3510C
SW846 3510C
SW846 35IOC
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-SIM
8270C-S1M
8270C-S1M
8270C-S1M
8270C-SIM
En Chem A Division of Pace Analytical Services, Inc.
Analytical Report
Client: NATURAL RESOURCE TECHNOLOGY
Project Name: WPSC Project Number: 1549
MARINbl I t
Field ID: TRIP BLANK
PVOC
Analyte
1,2,4-Trimethylbenzene 1,3.5-Trimethylbenzene Benzene
Ethylbenzene Methyl-tert-butyl-ether Toluene
Xylene, o Xylenes, m + p a,a,a-Trifluorotoluene
< < < < < < < <
Result
0.39 0.40 0,14
0.40 0.36 0.36 0.36 0.74
101
LOD
0.39 0.40 0.14
0.40 0.36 0.36 0.36 0.74
LOQ
1.3 1.3
0.46 1.3 1.2 1.2 1.2 2.5
EQL
Number: 858276 1241 Bellevue Street Green Bay, Wl 54302 920-469-2436
Matrix Type: WATER Collection Date : 04/13/05
Report Date: 04/29/05 Lab Sample Number: 858276-019
3il. Unite Code Anl Date
ug/L 04/19/05 ug/L 04/19/05 ug/L 04/19/05 ug/L 04/19/05 ug/L 04/19/05
ug/L 04/19/05 ug/L 04/19/05 ug/L 04/19/05 %Recov 04/19/05
Prep Date: 04/19/05
Prep Method
SW846 5030B SW846 5030B SW846 5030B SW846 5030B SW846 503OB SW846 5030B SW846 5030B SW846 5030B
SW846 5030B
Anl Method
SW846 M8021 SW846 M8021 SW846 M8021 SW846 M8021 SW346 M8021 SW846 M8021 SW846 M8021 SW846 M8021 SW846 MB021
B
B
C
D
E
Inorganic
Organic
All
All
Inorganic
Qualifier Codes Flag Applies To Explanation ' A Inorganic Analyte is detected in the method blank. Method blank criteria is evaluated to the laboratory method detection limit. Additionally,
method blank acceptance may be based on project specific criteria or detemnined from analyte concentrations in the sample and are evaluated on a sample by sample basis.
The analyte has been detected between the method detection limit and the reporting limit.
Analyte is present in the method blank. Method blank criteria is evaluated to the laboratory method detection limit. Additionally, method blank acceptance may be based on project specific criteria or determined from analyte concentrations in the sample and are evaluated on a sample by sample basis.
Elevated detection limit.
Analyte value from diluted analysis or surrogate result not applicable due to sample dilution.
Estimated concentration due to matrix interferences. During the metals analysis the serial dilution failed to meet the established control limits of 0-10%. The sample concentration is greater than 50 times the IDL for analysis done on the ICP or 100 times the IDL for analysis done on the ICP-MS. The result was flagged with the E qualifier to indicate that a physical interi'erence was observed.
Analyte concentration exceeds calibration range.
Due to potential interferences for this analysis by Inductively Coupled Plasma techniques (SW-846 Method 6010), this analyte has been confirmed by and reported from an alternate method.
Surrogate results outside control criteria.
The result is estimated because the concentration is less than the lowest calibration standard concentration utilized in the initial calibration. The method detection limit is less than the reporting limit specified for this project.
Preservation, extraction or analysis performed past holding time.
This test is considered a field parameter, and the recommended holding time is 15 minutes from collection. The analysis was performed in the laboratory beyond the recommended holding time.
Concentration detected equal to or greater than the method detection limit but less than the reporting limit.
Sample received unpreserved. Sample was either preserved at the time of receipt or at the time of sample preparation.
Detection limit may be elevated due to the presence of an unrequested analyte.
Elevated detection limit due to low sample volume.
Sample pH was greater than 2
Spiked sample recovery not within control limits.
Sample received overweight.
The relative percent difference between the two columns for detected concentrations was greater than 40%.
The analyte has been detected between the limit of detection (LOD) and limit of quantitation (LOQ). The results are qualified due to the uncertainty of analyte concentrations within this range.
Organic The relative percent difference between quantitation and confirmation columns exceeds internal quality control criteria. Because the result is unconfirmed, it has been reported as a non-detect with an elevated detection limit.
Inadequate sample volume received to perform the method required MS/MSD.
The analyte was not detected at or above the reporting limit.
Sample received with headspace.
A second aliquot of sample was analyzed from a container with headspace.
See Sample Narrative,
Laboratory Control Spike recovery not within control limits.
Precision not within control limits.
The analyte was not detected at or above the reporting limit.
Dissolved analyte or filtered analyte greater than total analyte: analyses passed QC based on precision criteria.
Dissolved analyte or filtered analyte greater than total analyte: analyses failed QC based on precision criteria.
BOD result is estimated due to the BOD blank exceeding the allowable oxygen depletion.
BOD duplicate precision not within control limits. Due to the 48 hour holding time for this test, it is not practical to reanalyze and try to correct the deficiency.
BOD result is estimated due to insufficient oxygen depletion. Due to the 48 hour holding time for this test, it is not practical to reanalyze and try to correct the deficiency.
BOD laboratory control sample not within control limits. Due to the 48 hour holding time for this test, it is not practical to reanalyze and try to correct the deficiency. BOD result is estimated due to complete oxygen depletion. Due to the 48 hour holding time for this test, it is not practical to reanalyze and try to correct the deficiency.
E
F
F
G
H
HF
J
K
K
L
M
N
0
P
Q
Organic
Inorganic
Organic
All
All
Inorganic
All
Inorganic
Organic
All
Organic
All
Organic
Organic
All
T
U
V
W
X
& • < 1
2
3
4
5
6
7
All
All
All
All
All
All
All
All
Inorganic
Inorganic
Inorganic
Inorganic
Inorganic
Inorganic
Inorganic
En Chem Analysis Summary by Laboratory A Division of Pace Analytical Services, Inc.
1241 Bellevue Street Green Bay, Wl 54302
1090 Kennedy Avenue Kimberly, Wl 54136
Test Group Name
ALKALINITY AS CAC03
IRON - DISSOLVED
MANGANESE - DISSOLVED
METHANE
NITROGEN, N03 + N02
PAH/PNA
PVOC
SULFATE
CD O l OD N) - 4
O O
G
G
G
G
G
G
G
G
OD
CD
o o r o
G
G
G
G
G
G
G
G
0 0 cn 0 0 ro - J a> o
s G
G
G
G
G
G
G
G
0 0 cjy 0 0 r o
a o
s G
G
G
G
G
G
G
G
0 0 O l 0 0 r o
o o cn
G
G
G
G
G
G
G
G
0 0 CJl 0 0 r o • v j cn
6
G
G
G
G
G
G
G
G
0 0 CJI OO ro ~ o
3 G
G
G
G
G
G
G
G
00 CJl 0 0 NJ
a o o 00
G
G
G
G
G
G
G
G
0 0 cn 0 3 r o - C3)
8 CD
G
G
G
G
G
G
G
G
0 0 cn 0 0 ro
C31
o o
G
G
G
G
G
G
G
G
CO cn 00 r o - .J
o
G
G
G
G
G
G G
G
0 0 O l ca M
o
ro
G
G
G
G
G
G
G
G
0 0 cn 0 0 r o
o
OJ
G
G
G
G
G
G
G
G
0 0 cn 0 0 ro - J cn o
G
G
G
. G
G
G
G
G
0 0 cn 0 0 ro - cn o
cn
G
G
0 0 cn 00
ro
cn o
cn
G
G
G
G
G
G
G
G
CO cn 0 0 ro - - J ro o
G
G
03 cn 00 ro - -1 t n o
00
G
G
CD cn cn t o
cn o
CD
G
Wisconsin Certificafion
G = En Chem Green Bay
K = En Chem Kimberly
S = En Chem Superior
C = Subcontracted Analysis
1 = Other Pace Lab Analysis
405132750 / DATCP: 105-444
445134030
Not Applicable
r.r-D'.-^i / En Chem, Inc. Cooler Receipt Log
Batch N o . _ 2 ^ Z I I J = l _ _ Project Name or I p tAJ P S C - ' / l / l . X l r / V l X r t i g No. of Coolers: ^ Temps
A. Receipt Phase: Date cooler was opened: A ' l 5 > ' 0 ^ Bv: l\f)
1: Were samples received on ice? (Must be < 6 C ) ( ^ H ^ '^^^
2. Was there a Temperature Blank? YES / ' ^ ° ~ )
3: Were custody seals present and intact on cooler? (Record on COC) YES / ^ )
4: Are COC documents present? / ^ ^ J "^^^
5: Does this Project require quick tum around analysis? YES K ? ^
6: Is there any sub-work? : YES / f K ) \
7: Are there any short hold time tests? / * ^ ^ ^ ^ °
8: Are any samples nearing expiration of hold-time? (Within 2 days) YES' / ^
9: Do any samples need to be Filtered or Preserved in the lab? YES^
B. Check-in Phase: Date samples were Checked-in: n ] ! D ~ O Z P Bv: n r /
1: Were all sample containers listed on the COC received and intact? / f ^ ^'-'^
2: Sign the COC as received by En Chem. Completed .>ljiS} NO
3: Do sample labels match the COC? . V ^ NO^
4: Completed pH check on preserved samples f ^ ^ '^*-*
(This statement does not apply to water VOC, O&G, TOC, DRO, Total Rec. PhenoHcS)^^ 5: Do samples have correct chemical preservation? " ^ 3 NO^
(This statement does not apply to water VOC, O&G, TOC, DRO, Total Rec. P h e n o i i c s ^ 6: Are dissolved parameters field filtered? YES N O '
7: Are sample volumes adequate for tests requested? • / ' ^ ^ ^ ^ ^
8: Are VOC samples free of bubbles >6mm YgS/ NO^
9: Enter samples into logbook. Completed - r ^ ^ '*"^
10: Place laboratory sample number on all containers and COC. Completed / ^ § ^ ' ^ ^
11: Complete Laboratory Tracking Sheet (LTS). Completed YES NO
12: Start Nonconformance form YES NO
13: Initiate Subcontracting procedure. Completed j . YES NO
14: Check laboratory sample number on all containers and COC L X / ( i /O ' / Y E S ^ NO
Short Hold-t ime teste:
24 Hours or less Coliform Corrosivity = pH Dissolved Oxygen Hexavalent Chromium HPC Ferrous Iron Eh Odor Residual Chlorine Sulfite
Rev . 2 /05/04, A t tachment to 1-REC-5. Subject to QA Audi t . Reviewed by/date
M i
NA
Contacted by/Who_
Contacted by/Who_
NA
NA
NA
NA
NA
24 Hours or less Coliform Corrosivity = pH Dissolved Oxygen Hexavalent Chromium HPC Ferrous Iron Eh Odor Residual Chlorine Sulfite
48 Hours BOD Color Nitrite or Nitrate Ortho Phosphorus Surfactants Turbidity En Core Preservation Power stop preservation
7 days Ash
l-lashpoint Free Liquids Sulfide TDS TSS Total Solids TVS TVSS Unpreserved VOC's
Footnotes 1 Notify proper lab group immediately. 2 Complete nonconformance memo.
j - f 'j/irAr
p:/everyone/forms/samplereceiving/cri.doc
(Please Piifit Legibly) __ Company Name: ;VV^ i. i - • ' ! g^j.ov.^v' '- ' g c ' - • , . / " j " / r - -
Branch or Localion: \ ' ' ^ ^ - • - ^ ' - , L- | ,
Projeci Contact : i ^ j y \l<-:\.,:\ Telephone: X >./ I - 1 ) 1 - / I " 3
Project Number: I S ' ' ' '
Project Name:
Project State:
. , f ^ c - ^ , „ , , H.
U />
Sampled By (Print)
PO/f:
3,J/rs...\.,..^ v .j. , ri-'-^'-"
Data Package Options - (please circle if requested) Sample Results Only (no QC) EPA Level II (Subject to Surcharge) EPA Level III (Subject to Surcharge) EPA Level IV (Subject lo Surcharge)
LABORATORY 10 (Lal) IJse Oiily)' FIELD ID
Regulatory Prporam
UST RCRA SDWA NPDES CERCLA
y<' ^ J :HEM #
« ^ INC. ..chemistry for the environment.
J S J ^
,1S0 [XI 1241 Bellevue St . , Sui te 9 ~ Green Bay, WI 5 4 3 0 2
9 2 0 - 4 6 9 - 2 4 3 6 F a s 9 2 0 - 4 6 9 . 8 8 2 7
• 7 -
CHAIN OF CUSTODY Page_
I ":- 111133 Quote #:.
'Preservallon Codes A^None B^HCL C=H2S04 D=HN03 E EnCore H^Sodium BisuKalfl Solullon l-Sodium ThiosuKate J^OIher
' ' Mail Heport To: l l e l v , c c - ~ C ^ v . ) ' l \
' / FILTERED? (YES/NO) / T j ^ / ^ A " / ^ - / C / f t
PRESERVATION (CODE)' / f J / i ^ / f ^ / Y
Company: A ' C - U . V - - ' ^ ^'^'^ ' ^ ^ > - . -^" j ' '
/ A d d r e s s : ^ ' ^ - ^ t ' ^ ^ - ' < ' - - ' ^ 1 - ^ ^ . . ^ ^ - • ' - b
Matrix Codes
W^Water S=Soll A=Air
C=Charcaal B=Biola
Sl Sludge
COLLECTION DATE! TIME
MATRIX
W t J . . - ' i 1 1 \ ^ 1 . •S V o ?-">-
Company: A/ V T
1 ./ / I /
"- '.. ' \ X i j .J
' /
/ cHy Invoice To; ^ - ^ V. r ^ 1.
/ J ^ / X ) / Address:
%7 ' ^ / / 'O^y'' '^^'' Invoice To:
f... y.\^
-<^ CLIENT COMMENTS .LAB COMMENTS '(|.ati'Uieqn|y|-
M y iM jQj i - \ ^
.hOZ ^^^y^£L _DD i - -\oM
M i X >
i ^ . _DD l -Jc- , M i 6Z>ii -OS 3 oV. '/v:^?^ / i h lUl -i o l \K fe im. £v^U_Ji f^ ^
^ 2 1
li'/a. ^ L..y " i I 0 icL?
>
V
V V
Ml /^-\\.J \ ^Ull (9io
4B=m Avy^ :^ f t r»^t .o- .g/y : M ^ _aAi i l - . B l
\ ' ) / • - ^ . w • b ML Gik
X X
;<
^^/> Y
y y
V >c
J L
X
X k
>
X J L
A--^
X
X >
X
X K X
X • > !
-K -X
X
X
J<_ X
X >r A'
X
J^ X
K
y
A /
i l i<_ / .
A
X
X
y X %
BiaaWll2S)4tf^o^^i Mi^
- ^ ^ \ ? Rush Turnaround Time Requested (TAT) - Prelim
(Rush TAT subject to approval/surcharge)
Date Needed: .. ^ ^
Rejlpt^yished By:' _j Date/Time:
Transmit Prelim Rush Results by (circle):
Phone Fax E-Mail
Phone #:
F a x > : •.. -•
/
Rpii^&liit^d By; ^-^ V-^S^-
RelinqtiishM"Byl."-"
Dgte/Time:
Mai
E-Mail Address;
Relii1( uiShei
Samples on HOLD are subject to pial p r i c i n ^ n d release ot liability
Relinquished By:
^ J - t : ^
Date/Time;
I 9 ^ • ' \ Date/Time:
Date/Time:
Received By:
/ 2 -Reeeiyed By:
I Date/Time
Y y ( I A O . ^
lyi
V/ Date/Time
' /S>.f J rM'O Retiivea'Byi'' / T ' / Date/Time
R6 j^ ib fec rBy ! | l ' ^ ^ " * ^^ H Date/Time
Received By: Date/Time
En qheiii Proigct fjq
g3rp|3|e F|ecelpt Tefpp
^aniplg Receipt pft
loojer Custpay Se Coojpr Cust^py S^al
presepj / (Jpi Pr fs 'gpf^T?
iQtac) / Mo{ Intact '
^ ^ ^ g ^ ^ ^ _ ^ ^ ^ _ Vcr!^^^^7/03 ^ ^ ^ ^ ^ ^ ^ ^
(Please Print Legibly)
Company Name: Z ^ ' ' ^ ' ' ' ^ ' ^ ' ) X o ' ^ « . t , k . i . \ o ^ ; ^ )
Branch or Location: v.^-5;:
Project Contact: ^ - ^ - . " S ^ w ^ - ^ V i V '
Telephone: C U V T I "^ - - ^ \ Q " ^
Project Number: \ - ^ M ^ ^ ? ^ ^ ^ A n ^ ^ U c ^ V - ^ C
Project Name
Project Stale: V^ Sl
Sampled By (Print)
PO# :
:=>oJSV>^^\^^- ,'?^i..'':i Tby'-V^N
Data Package Opt ions • (please circle il requested)
Sample Results Only (no QC)
EPA Level II (Subject to Surcharge)
EPA Level ill (Subject to Surcharge)
EPA Level IV (Subject to Surcharge)
UBORATORY ID (Lab Use Only)
_fl.ll M m m M
FIELD 10
P-1.0-X
?-^-> ? ^ t -T» t , ^ &.c.~]
Regulalory Pronram
UST RCRA SDWA NPDES
CERCLA
EM GHEM ••- • y I N C .
1 3 - 1241 BeUevue St., Suite 9 Green Bay, WI 54302
920-469-2436 Fax 920-469-8827
...citemistty for iht environment.
CHAIN OF CUSTODY N? 111134 •Preservation Codes
A:^None B=HCL C=H2S04 D=HN03 E^EnCore F=Metlianol H=Sodium Bisulfate Solullon hSoillum Tliiosulfale J=Olher
FILTERED? (YES/NO) / j ^ / / v " y p / < ^ / f J / ^
PRESERVATION (CODE)' / Q , / ^ / \ / >
G=HaOH
i ^ .o f • 2 . Page.
Quote #:
Ivlail Report To: I ? . L V - c.tC'v C^v . J .
Company:A^ A " " - " ^ K - > a < ^ ^ ' ^ T C - C U . Q I
A d d r e s s : ^ " ^ " ^ ' ^ ^ - ^ - ^ ^ • ' ^ ^ - ^ - • ^ \ >
Matrix CDdes
U/=lValer S=Soil AsAir
CsCharcoal B=Blota
SkSludge
COLLECTION
OATE
m/dL m mfM.
a< Tv>^ ^K .
TIME
ma
MATRIX
V/J -t A X. X--%-7<
A
i r j < -:2^
- ^
A
A ^
A
K
JL
? -X
K
- ^
X
K
l-Ujukzir^, ^7.^KA1^"^. U H D M I ^
l l d O i V L l X f e
I 3
'3 fHI)Mf^" vT
w
Tt
Rush Turnaround Time Requested (TAT) - Prelim ^ 'Rpllnq
(Rush TAT subject to approval/surcharge) ' - ^
Date Needed:
Transmit Prelim Rush Results by (circle):
Ptione Fax E-Mail
Phone #:
Fax #:
E-Mail Address:
^ Date/Time Date/Time:
S\\j^Q> TJaTe/Time
i Date/Time:
Date/Time: A-\^-m \50[)
Date/Time:
Samples on HOLD are subject to special pr ic ing and release of l iabil i ty
Relinquished By: Date/Time: Date/Time:
En Chem Project No.
Sample Receipt Temp.
Eoi Sample Receipt pH (WeVMutals) ft 1 /
Cooler Custody Seal
Pr"T"n*TTJrit PrTTgnT
Intact / Not Intact Vflrslon 4.0: 07/03
t3y/iy/:^i305 I D I S J )iZ\iZblbr/\^ TAWATER PAGE 01/18
TestAmerica ANALYTICAL TESTING CORPORATION
WDNR No. 128053530 602 COMMEKCEDWVE . WATEKTOWN, VW S30W 920-26J-JI660 FAX 920-261-8120
ANALYTICAL REPORT
Ms. Rebecca Caudill NATURAL RESOURCE TECH, 23713 W. Paul Road Pewaukee, WI 53072
INC 09/19/2005
Job No: 05.0300!
Page 1 of 6
The following samples were received by TestAmerica for analysis
1549 WPSC Marinette
Sample Number
612713 612714 612715 612716 612717 612716 612719 612720 512721 612722 612723 612724 612725 612726 612727 612728 612729 612730 612731 612732
Sai
MW-30 6 MW-311 MW-307R MW-1 MW-310 P-305 MW-308 P-303 MW-3R MW-5 MW-303 MW-304 MW-305 MW-302 P-302 QC-1 QC-2 MW-801 PZ-801 MW-806
Sample Description Date Taken
04/13/2005 04/13/2005 04/13/2005 04/13/2005 04/13/2005 04/13/2005 04/13/2005 04/14/2005 04/14/2005 04/14/2005 04/14/2005 04/14/2005 04/14/2005 04/14/2005 04/14/2005 04/14/2005 04/14/2005 04/13/2005 04/13/2005 04/13/2005
Date Received
04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15
/2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005
Karen R. Wenta Inorganic Operations Manager
www.ifsiainerlcalnc.cofn
TeslAmerici An*lyilc»l Testing Corporaiion | TestAmerica Drilling Coiporsllon | TcjtAinrriea Air Emisjion Corporation
ay/iy/liUUb It).-53 9202518120 TAWATER PAGE 02/10
TesUtoerica ANALYTICAL TESTING CORPORATION
WDNR No, 128053530 602 COMMERCE DRIVE • WATERTOWN. Wl 53094 92O-261-]660 • FAX 9 2 0 - 2 6 ) - 8 1 2 0
ANALYTICAL REPORT
Ms. Rebecca Caudill NATURAL RESOURCE TECH, INC 23713 W. Paul Road Pewaukee, WI 53072
09/19/2005
Job No: 05.0300!
Page 2 of 6
The following samples were received by TestAmerica for analysis
1549 WPSC Marinette
Sample Number Sample Description
MW-807 612734 PZ-802 612735 PZ-803 612736 QC-1 4/13
Date Taken
04/13/2005 04/13/2005 04/13/2005 04/13/2005
Date Received
04/15/2005 04/15/2005 04/15/2005 04/15/2005
www.tesumtrletlnc.cora TtistAmcrlcj Annlyllcul Testing Corporation j TcjiAmcrIca Drilling Corpor»tlo« | TesiAmerlcj Air Emission Corporitlon
09/19/2005 15:53 9202B18120 TAWATER PAGE 0 3 / 1 0
TestAmerica WDNRNo. J28053530 ANALYTICAL TESTING CORPORATION 602 CoMMERCT DRIVE • WATERTOWN, W [ 53094 • 920-261-1660 • FAX 920-261-8120
NATURAL RESOURCE TECH, INC 09/19/2005 Job No: 05.03008 Page 3 of 5
KEY TO DATA FLAGS The attached sample(s) may have a result flag shown on the report. The following are the result flag definitions:
h = fi.nalyzed/e:-:tracted past hold time B = Blank is contaminated C = Standard outside of control limits D = Diluted for analysis E = TCLP extraction outside of method required temperature range F = Sample filtered in lab G = Received past hold time H = Late eluting hydrocarbons present I = Improperly handled sample J = Estimated concentration L = Common lab solvent M = Matri.x interference P = Improperly preserved sample Q = Result confirmed via re-analysis S = Sediment present T = Does not match typical pattern W = BOD re-set due to missed dilution X - Unidentified compound(s) present z = Internal standard outside limits * = See Case Narrative
KEY TO ANALYST INITIALS
The attached sample(s) may have been analyzed by another certified laboratory. If a number appears in the Analyst Initials field, the following are the appropriate certifications (if the lab code does not appear below, that means that certification is not required for the work performed):
Certification Number Lab Code
OOS 013 020 030 070 090 130 149 148 300 400 510 700
WDNR - 999766900 WDNR - 999917160; ILNELAC - 100261 WDNR - 999447680 ILNELAC - 100230; WDNR - 998294430 lA - 007; ILNELAC - 000663; MDH - 019-999-319; WDNR - 999917270 ILNELAC 200006; WDNR - 399031270 WDNR - 632021390 WDNR - 721026460 WDNR - 399017190 ELNELAC - 87358; lA - 131; MDH - 047-999-345; WDNR - 998020430 WDNR - 113133790 WDNR - 241249360 WDNR - 113289110
TestAmerica Watertown Certifications: ,WI DNR - 123053530; IL NELAC - 100453; lA DNR - 294; MN DoH - 055-999-366; ND DoH R-046; AR DEQ - 88-0809
unless sub-contracted (see above), volatiles analyses (including VOC, PVOC, GRO, BTEX and TPH Gasoline) performed by TestAmerica Watertown at 1101 Industrial Drive, Units 9&10. All other analyses performed at 602 Commerce Drive, Watertown WI 53094.
Results reported between the Method Detection Limic (MDL) and Limit of Quantitation (LOQ) are less certain than results at or above the LOQ.
Tor questions regarding this report, please contact Dan Milews)cy or Warren Topel.
www.u j iamer ica inc .com
TestAuitr lcS Ana)yiic»l T t t i l n j Corporation | T«slAincrica Drill ing Corporailon j TcsiAmerlca Air Emission Corporailon
09/19/2005 15:53 9202618120 TAWATER PAGE 04/10
TestAmerica ANALYTICAL TESTING CORPORATION
WDNRNo. 1280535J0 602 COMMERCE DRIVE • WATERTOWN, Wl 53094 • 920-26M66O • FAX 920-26i~e:20
ANALYTICAL REPORT
Ms. Rebecca Caudill NATURAL RESOURCE TECH, INC 23713 W. Paul Road Pewaukee, WI 53072
Job Description: 1549 WPSC Marinette Marinette, WI Rec'd on ice
09/19/2005 Job No: 05.03008 Account No: 52450 Purchase Order: Page 4 of 6
6:2113
Cyanide,
6127H
Cyanlda,
612115
Cyanide,
612716
Cyanide,
612717
Cyanide,
612716
Cyanide,
612719
Cyanide,
612720
Cyanide,
Paraaecar
MM-306
available
MW-311
availabls
MW-307R
available
MW-1
available
MW-olO
available
P-30S
available
Mn-306
available
P-303
available
Date Prap/Run
R e s u l t s Uni ta MDI, LOQ Methofl Analyzed Analys t Batch
Data/Time Taken; 0 4 / 1 3 / 2 0 0 5 13 :30
<0.0050 roO/L 0 .0050 EPA 1677 0</21/2005 090 52
Date/Time Token: 04 /13 /2005 13 ;50
<0.0050 mg/L 0.0050 ZP?. 1677 04 /21 /2005 090 52
Dacs/Tima Taken: 04 /13 /2005 H ; 2 2
<0.0050 mg/L 0.0050 EPa. 1677 01 /26 /2005 090 53
Date/Time Taken: 0« /13 /200S 15 :30
<D.0050 mg/L 0.0050 EPA 1677 04 /26 /2005 090 53
Date/Time Taken: 04 /13 /2005 16:07
0 , 0 0 5 1 m<3/L 0.0050 EfA 1677 04 /26 /2005 Q90 S3
Dace/Time Taken: 04 /13 /2005 16 :45
<0.OnS0 mg/L O.OOSO EPA 1677 04 /26 /2005 0?0 53
Date/Time Taken: 04 /13 /2005 16:40
<O.O0S0 mg/L 0.0050 EPA 1677 04 /26 /2005 090 S3
Date/Time Taken: 04 /14 /200S 07 :30
<0 .0050 mg/ l 0.0050 EPA 1677 01 /26 /2005 090 54
www.tesiamcrtcalnc.coin
TejlAmerica Ani ly i l ca l Tesi ine Corpora i lon | TejtATntrlc» Drilling Corporation | Tes iAmc i i c j Air EmlsJlcn Corpor«Oon
09/19/2005 15:53 9202618120 TAWATER PAGE 05/10
Test^toerica ANAUVTICAL TESTING CORPORATION
WDNR No. 128053530 602 COMMERCE DIOVE • W.JITEKTOWN. W I 53094 • 920-261-1660 • FAX 920-2S1-8120
ANALYTICAL REPORT
Ms. Rebecca C a u d i l l NATURAL RESOURCE TECH, INC 23713 W. Paul Road .Pewaukee, WI 53072
Job D e s c r i p t i o n : 1549 WPSC Mar ine t t e M a r i n e t t e , WI Rec'd on ice
09/19/2005 Job No: 05.03008 Account No: 52450 Purchase Order: Page 5 of 6
612721
Cyanide,
612722
Cyanide,
612723
Cyanide,
612721
Cyanide,
6127J5
Cyanide,
612726
Cyanide,
612727
Cyanide,
612728
Cyanide,
Parameter
NW-3R
available
MW-5
available
MW-303
availflbls
W-304
available
MW-30S
a-»ailoble
KM-30J
available
P-302
available
QC-1
available
Date Prap/Run
R e s u l t s Uni ta MDL LOQ M e t h o d Analyzaa A n a l y s t Batch
Cote/Txms Taken; 04 /14 /2005 07;36
<0.0050 ros/L 0 .0050 EPA 1577 04/29/2005 090 54
Data/'Time Tsksn ; 04 /14 /2005 0S;15
<0.0050 mg/L 0.0050 EPA 1677 04/28/2005 050 51
Date/Time Taken: 04 /14 /2005 09;06
<0.0050 mg/L 0.0050 EPA 1677 04/26/2005 090 54
Date/Time Taken; 04 /14 /2005 09;OS
0.0076 mg/L 0.0050 EPA 1677 04/2S/200S 090 54
Pa te /Time Tak«n: 04 /14 /2005 09:45
fO.OOSO mg/L 0 .0030 EPA 1677 04/26/2005 090 54
Date/Time Takan; 04 /14 /2005 10:15
O.OOSO mg/L O.OOSO EPA 1677 04/29/2005 090 54
Date/Time Taken: 04 / l ( i /2005 10:16
<0.OOS0 mg/L O.OOSO EPA 1677 04/28/2005 090 5<l
Date/Tlrae Taken: 04 /14/2005 UNKNOVW
<0.0050 mg/L 0.0050 EPA 16?7 04/26/2005 090 54
www.iesn incr lca lnc .com
Tts tAmcrlca Analytical Te j l lng Corporiitloii | TestAmerica Dii l l ing Corporai lon | TeciAracrlet Air Emijjlon Corporntlon
09/19/2005 15:53 9202618120 TAWATER PAGE 05/10
Test/toerica ANALYTICAL TESTING CORPORATION
WDNRNo. 128053530 602 COMMERCE DRIVE • WATERTOWN. w i 53094 • 920-Z6I-166O • FA.K 920-26I-8120
ANALYTICAL REPORT
Ms. Rebecca Caudill NATURAL RESOURCE TECH, INC 23713 W. Paul Road Pewaukee, WI 53072
Job Description; 1549 WPSC Marinette Marinette, WI Rec'd on ice
09/19/2005 Job No: 05.0300B Account No: 52450 Purchase Order: Page 6 of 6
612729
Cyanide,
612730
Cyanide,
612731
Cyanide,
612732
Cyanide,
612733
Cyanide,
612734
Cyanide,
612735
Cyanide,
612736
Cyanide,
7arams usr
QC-2
available
MW-BOl
available
PZ-801
fli7ailablc
KH-e06
available
Mn-eo7
available
e2-802
available
e2-803
available
OC-1 4/13
available
Date Prcp/Run
R e s u l t s U n i t s MPL LOQ M a t h o d .Analyzed A n a l y s t Batch
Date /Time Taken: 04 /14 /2005 UNKNOWN
<0.0050 EVCI/L 0 .0050 EPA. 1677 0 1 / 2 8 / 2 0 0 5 090 S4
Data /Time Token: 04 /13/2005 09 :00
0.0097 mg/L 0.0050 EPA 1677 0 4 / 2 7 / 2 0 0 5 09Q 55
Date /Time t a k e n : 04 /13 /2005 0 3 : 0 5
<0.OOSO mj/L 0.0050 EPA 1677 0 4 / 2 7 / 2 0 0 5 090 55
Date /Time Takan; 04 /13 /2005 08 :35
0.0064 mg/L 0.0050 EPA 1677 0 4 / 2 7 / 2 0 0 5 090 SS
Date /Time Taken: 04 /13 /2005 10:18
<0.0050 mg/L O.OOSO EPA 1677 0 4 / 2 7 / 2 0 0 5 090 55
Date /Time Taken; 04 /13 /2005 09 :40
<0.0050 mg/L O.OOSO EPA 1677 0 4 / 2 7 / 2 0 0 5 090 55
Date/Time Taken; 04 /13 /2005 10 :20
<0.0050 nig/L O.OOSO EPA 1677 0 4 / 2 7 / 2 0 0 5 090 55
Data/Time Taken; 04 /13/2005 UNKKOMtl
0 .0066 mg/L 0.0050 EPA 1677 0 4 / 2 7 / 2 0 0 5 090 SS
www.icsl9merlc3lnc.cam
T t s l A m t r i c a Analy t ica l TesUng Corporation | TestAmerica Dri l l ing Corporaiion | TcsiAmcrica Air Emission Corporation
Testiimerica *^m3m8*
I N C O n F O R A T
Watertown Division 602 Commerce Drive Watertown, Wl 53094
Phone 920-261-1660 or 800-833-7036 Fax 920-261-8120
m n / /^(ifg/ctr Client Name,
Address: ^ 3 - ^ J ^ ^ . / g j / C /
/C^Ko/c^o t f
To assist us in using the proper analytical methods, is this work being conducted for regulatory purposes?
Compliance Monitoring
Client #:
City/State/Zip Code:
Project Manager:
Telephone Number:
Sampler Name: (Print Name)
Sampler Signature:
x ^ : ^ / . / ^ . KJ/ Jf7r / \ . cSc»Kvy/ Y /
Project Name: W / f f l S - / l A a r r ^ C T n ^ ^
Project #: / S ^
^^•:U.2^'^t^- ?crQ^
site/Location ID: / H p ^ y ^ . ^ M j ^ f i L
Report To:
Invoice To:
Quote #:
State: I 'AJ C
PO#:
7 Matrix Preservation & # of Containers QC Deliverables
None Level 2 (Batch QC)
Level 3 Level 4
Other:
REMARKS
TAT Standard Rush (surcharges may apply)
Date Needed:
Fax Results: Y N
SAMPLE ID -£.
o
u> o E (0
o
il 3 13 •
in ,
w C: ^ ^
>^>^^^^y~' £ ^ i!!!^ T ^ >-
pft"?-- iBf:jS^±=;ftd. m<.0-3i MU'- J ^ a ^
1250. ^ X /^Z ^ X
ytii/t/-r t£lo_ •K X. Ml&llM. A J 2 ^ § _
l(fi1r
M X .is. 21 *;
M l ^ ' ^ ^ im
Mo ^ X A ?o.?
Special Instructions cm c 1 <jay :H .k
: ^ < a / ^ ^ j f ^ / / fr-/4:yM
Relinquished By: U M ^ Relinquished By:
Received By: u t ^ Received By:
Received By:
LABORATORY COMMENTS:
inlt Lab temp; <Q)iKJ
Red Lab Temp:
Custody Seals: r N Bottles Supplied by Test Am*
Method of Shiprtient:,/
#V//S/o^