Fernando Lázaro Freire JuniorFernando Lázaro Freire Junior

Pontifical Catholic University of Rio de Janeiro, PUC-Rio

OverviewOverview

The National Institute of Surface Engineering

1) Research2) Human resources3) Difusion of Knowledge4) Transfer of knowledge to the industrial sector

TheThe InstituteInstitute

TheThe starting starting pointpoint: 1987: 1987 – CNPq individual grants to support scientific collaboration betweenPUC-Rio (Van de Graaff Laboratory) and UFRGS (Ion Implantation Laboratory).

20012001 -First PROCAD (CAPES) grant joint the two teams and maintain the collaboration, now also involving one group from UNICAMP.

20022002 - CNPq network on Nanomaterials: coordinator Prof. Israel Baumvol

Besides the groups at PUC-Rio, UNICAMP and UFRGS, others groups were involved in the network: INPE and UFF.

20052005 – CNPq/MCT Network Rede Brasil Nano:

Nanostructured Coatings : coordinator Prof. Fernando Lázaro

2009 2009 – INCT National Institute of Science and Technology: Surface Enginnering

FromFrom 2000 2000 to 2009: more to 2009: more thanthan 50 50 jointjoint internationalinternational publicationspublications

exchangeexchange ofof studentsstudents andand pospos--docsdocs

interactioninteraction withwith industriesindustries

CoordinatorCoordinator: : Fernando Lázaro Freire Junior (PUC-Rio)

ExecutiveExecutive BoardBoard::Israel J. R. Baumvol (UCS)Lívio Amaral (UFRGS)Francisco Marques (UNICAMP)Amilton Sinatora (USP)Clodomiro Alves (UFRN)Vladimir Jesus Trava-Airoldi (INPE)Carlos Figueroa (UCS)

→ Director of graduate programs evaluation/CAPES

CoordinatorCoordinator: : Fernando Lázaro Freire Junior (PUC-Rio)

ExecutiveExecutive BoardBoard::Israel J. R. Baumvol (UCS)Pedro Grande (UFRGS)Francisco Marques (UNICAMP)Amilton Sinatora (USP)Clodomiro Alves (UFRN)Vladimir Jesus Trava-Airoldi (INPE)Carlos Figueroa (UCS)

twotwo presentialpresential meetings: Porto Alegre, meetings: Porto Alegre, MayMay 2009 2009 andand Ouro Preto, Ouro Preto, OctoberOctober 20102010

manymany discussionsdiscussions usingusing internetinternet

NanostructuredNanostructured Materials and Coatings Laboratory/Physics Department/PUCMaterials and Coatings Laboratory/Physics Department/PUC--Rio:Rio:Fernando Lázaro Freire Jr.Carlos Manuel Sanchez Tasayco

Thin Films Thin Films Laboratory Laboratory /Institute of Physics/UFF:/Institute of Physics/UFF:Dante Franceschini

Materials Materials and Sensors and Sensors Laboratory/INPE:Laboratory/INPE:Vladimir Jesus Trava-Airoldi

LaboratoriesLaboratories andand mainmain researchersresearchers

SurfaceSurface PhenomenaPhenomena LaboratoryLaboratory//DepartmentDepartment ofof MechanicalMechanical EngineeringEngineering/USP:/USP:Amilton SinatoraRoberto Martins de Souza

Photovoltaic Photovoltaic Research Research Laboratory/Institute of Physics/UNICAMP:Laboratory/Institute of Physics/UNICAMP:Francisco Marques

Thermo Thermo Mechanical Treatments Mechanical Treatments Laboratory/Laboratory/DepartmentDepartment ofof MaterialsMaterials//UNICAMP:UNICAMP:Paulo Roberto Mei

ZieglerZiegler--NattaNatta CatalysisCatalysis LaboratoryLaboratory//Institute of Chemistry/UFRGS Institute of Chemistry/UFRGS ::João H. Zimnoch dos Santos

Physical Physical Metallurgy Metallurgy Laboratory/Laboratory/DepartmentDepartment ofof MetallurgyMetallurgy EngineeringEngineering/UFRGS:/UFRGS:Carlos Fortis Kwietniewski

Ion Ion Implantation Implantation Laboratory/Institute of Physics/UFRGS:Laboratory/Institute of Physics/UFRGS:Pedro GrandeLivio AmaralGabriel Vieira SoaresFernando C. ZawislakPaulo Fernando FichtnerJohnny Ferraz Dias

Laboratory of Solid Surfaces and Laboratory of Solid Surfaces and InterfacesInterfaces//Institute of Physics/UFRGS:Institute of Physics/UFRGS:Cristiano KrugDaniel Eduardo Weibel

Nanofabrication Nanofabrication Laboratory Institute of Physics/UFRGS :Laboratory Institute of Physics/UFRGS :Marcos Z. Vasconcellos

Surface Engineering Laboratory/Materials Program/UCS:Surface Engineering Laboratory/Materials Program/UCS:Carlos FigueroaIsrael J. R. BaumvolCláudio Perottoni

Polymeric Materials Laboratory/Chemistry Department/UFSC:Polymeric Materials Laboratory/Chemistry Department/UFSC:Valdir Soldi

Plasma Plasma ProcessingProcessing LaboratoryLaboratory/ / DepartmentDepartment ofof MechanicalMechanical EngineeringEngineering/UFRN:/UFRN:Clodomiro Alves Jr.

Thin Films Laboratory/Physics Department/UDECSThin Films Laboratory/Physics Department/UDECS--Joinville:Joinville:Julio PurezaMonica de Mesquita Lacerda

EmergingEmerging GroupsGroups::

MaterialsMaterials LaboratoryLaboratory/Materials Program/University /Materials Program/University FeevaleFeevale -- Novo Hamburgo:Novo Hamburgo:Claudia Trindade Oliveira

SurfaceSurface EngineeringEngineering LaboratoryLaboratory//DepartmentDepartment ofof MechanicalMechanical EngineeringEngineering/UFPR:/UFPR:Ana Sofia C.M. de Oliveira

SurfacesSurfaces andand ThinThin FilmsFilms LaboratoryLaboratory//DepartmentDepartment ofof MetallurgyMetallurgy andand MaterialsMaterials EngineeringEngineering/UFRJ:/UFRJ:Sérgio de Souza Camargo Jr.Sérgio de Souza Camargo Jr.

NewNew membersmembers::

ObjectivesObjectives::

The The main objectives of main objectives of the the National Institute of Surface Engineering National Institute of Surface Engineering (INES) are:(INES) are:

-- investigation of physicalinvestigation of physical--chemical interactions of solid surfaces and interfaces:chemical interactions of solid surfaces and interfaces:1)1) Synthesis of thin films and interfaces by chemical and physical methods for Synthesis of thin films and interfaces by chemical and physical methods for

application in industrial productive system.application in industrial productive system.2)2) Investigation of properties of Investigation of properties of funcionalizedfuncionalized solid surfaces and interfaces.solid surfaces and interfaces.3)3) Development of specific metrology of near surface regions.Development of specific metrology of near surface regions.

-- applications applications of surface engineering and transfer of this knowledge to the industrial of surface engineering and transfer of this knowledge to the industrial productive productive system and to society.system and to society.

-- formation formation of high level human resources in surface engineering. of high level human resources in surface engineering.

GoalsGoals

Short and medium terms goals (2009-2011):

- to create a interative forum in the web. - to organize na international symposium on Surface Engineering in 2009.- to participate in the activities of the National Week of S&T.- to propose a Interinstitutional Program of Professionalizing Masters in Surface Engineering.

- to produce scientific knowledge relevant to the concerned area: -2 papers/main researcher/per year.

- to form graduate human resources.- to produce patents (2 per year).- to use human resources and innovative discoveries to stimulate new companies oftechnological basis.- to develop products and process for industries: automotive, gas & oil, metal-mechanic, microelectronics (CEITEC S.A.), etc.- organization of open lab days for high school students.- organization of workshops for managers, engineers and technician from industries.

√

√

√

√

1) 1) ResearchResearch

Publications in international indexed journalsPublications in international indexed journals:: 9191

Book Chapters: Book Chapters: 1 international and 1 national1 international and 1 national

Communications presented in International ConferencesCommunications presented in International Conferences: : 3030

Software: Software: 11

Patents: Patents: 1 international and 3 deposited at INPI1 international and 3 deposited at INPI

24 principal investigators

A complete list of publications can be found in the printed version of our annual report.

ScientificScientific productionproduction::

MW carbon nanotubes grown by spray pyrolysis decorated with nanoparticles (Ni, Co or Ag)

TEM HREMTEM HREM

silver nanoparticles

NanotechnologyNanotechnology::

work performed at PUC-Rio – MatMat ChemChem PhysPhys (submitted)

Characterization of nanoparticles through medium-energy ion scattering (MEIS):

We followed a quite general approach, where any nanoparticle geometry, inclusions, porous, inhomogeneities, and their corresponding areal and size distributions are accounted for.

To this end, we use the Monte Carlo method for the 3D-spacial integrations and determine the incoming-and outgoing-projectile paths numerically from the incident and scattering angles.

work performed at IF/UFRGS - JAPJAP 106 (2009) 1

gold nanoparticles adsorbed on a multilayeredfilm of weak polyelectrolyte

100 H+ keV MEIS experiment and simulation

KRISS (Korea Research Institute of Standard and Science), South Korea, implanted in May 2010, under the supervision of a brazilian researcher, thesoftware developed at Porto Alegre for MEIS characterization of nanostructures.

Cooperative research involving the groups at PUC-Rio and UFRGS: MEIS analysis ofnanotubes decorated with metallic nanoparticles

Silica-based solid sensors prepared by the sol-gel method

Development of solid pH sensors with potential application in the fabrication of intelligentplastics, i.e., packing plastics which may change color in the case of degradation of the food bythe alteration of pH or evolving of amines.

Incorporated content, visual color change and response time to ammonia gas for the synthesized solid sensors. RA = acid route; RNVA

= non-hydrolytic route; VA = alizarin red; AB = brilliant yellow; AC = acridine.

work performed at IQ/UFRGS - Sensor & Actuators B: Chemical (2010) (in print).

DLC DLC coatingscoatings::

Joint publication: Institute of Physics UNICAMP/ Department of Physics/PUC-Rio: Viana GA (UNICAMP), MotttaEF(UNICAMP), CostaMEHM (PUC-Rio), Freire Jr. FL (PUC-Rio) and Marques, Francisco das Chagas (UNICAMP), “Diamond-like carbon deposited by plasma techniques as a function of methane”. Diamond and Related Materials, 19 (2010) 756.

INES INES groupsgroups atat PUCPUC--RioRio, UNICAMP, UFF, UFRJ , UNICAMP, UFF, UFRJ andand INPE are INPE are internationalinternational referencesreferences in in thisthissubjectsubject: : basicbasic researchresearch → → transfertransfer to to thethe industryindustry: : productsproducts andand processes processes

work performed at INPE - Thin Solid Films 517 (2009) 5739

Bactericidal activity of DLC-TiO nanoparticles composites

Plasma Plasma surfacesurface treatmenttreatment::

UFRGS, UCS, UFRN, UNICAMP and USP have research acitivities on this subjetc.

Joint publication: Universidade of Caxias do Sul, Mechanical Engineering Department of USP andUNICAMP, Institute of Physics/UFRGS and Plasmar Tecnologia Ltda: M.V. Leite (USP), C.A. Figueroa (UCS), S. Corujeira Gallo (Plasmar), A.C. Rovani (UCS), R.L.O. Basso (UCS), P.R. Mei (UNICAMP), I.J.R. Baumvol (UFRGS, UCS),and A. Sinatora (USP), “Wear mechanisms and microstructure of pulsed plasma nitrided AISI H13 tool steel”Wear 269 (2010) 466.

PROCAD: UFRGS and UFRN

Effects of hydrogen on plasma oxidation of ferrous alloys

Plasma nitriding followed by post-oxidation is a good candidate as replacement for chromiunelectroplating and salt and gas-oxidation techniques due to enviromental-frendly aspects and surafceproperties:- hard and wear resistance nitriding layer + corrosion resistant and low friction oxide outermost layer.

- hematite free oxide layer, since it is porous and brittle.

work performed at UCS – ScriptaScripta MaterialliaMateriallia 62 (2010) 863.

2) Formation 2) Formation of of human resources:human resources:

. 23 Doctors (PhD)

. 21 Masters (Msc)

. dozens of Iniciação Cientifica fellows

degrees in PhysicsPhysics, , ChemistryChemistry, , MaterialsMaterials ScienceScience, , MechanicalMechanical EngineeringEngineering, , MaterialsMaterials EngineeringEngineering, , MicroelectronicsMicroelectronics, , PetroleumPetroleum EngineeringEngineering andand ChemicalChemical EngineeringEngineering..

A complete list of thesis and dissertations, can be found in the printed version of our annualreport.

FellowsFellows ofof INESINES

DT DT -- 3 (3 (MscMsc): 2 ): 2 UCS, 1 UFRN and 1 USPUCS, 1 UFRN and 1 USPDT DT -- 1 (pos1 (pos--doc): doc): 1 UNICAMP, 1 USP and 1 UFRGS1 UNICAMP, 1 USP and 1 UFRGSPosPos docdoc (PDJ(PDJ): ): 1 UNICAMP 1 UNICAMP andand 1 1 UFRGSUFRGS

CAPES: 6 CAPES: 6 fellowshipsfellowships ((MscMsc andand PhD)PhD)

How we selected the candidates?How we selected the candidates?

Call for proposals:Call for proposals:

The advisor must present:The advisor must present:-- CV Lattes of the candidate.CV Lattes of the candidate.-- Research project ( only 2 pages).Research project ( only 2 pages).-- fellowship level (DTfellowship level (DT--1, DT1, DT--2, DT2, DT--3 and PDJ).3 and PDJ).

Selection of the candidates was made by the Executive BoardSelection of the candidates was made by the Executive Board.

WeWe havehave nownow thethe CallCall for 2011: for 2011: namesnames mustmust bebe sendsend untiluntil DecemberDecember 2020

AtAt thethe momentmoment (CNPq):(CNPq):

FormerFormer studentsstudents::

Most of doctors stay in the Academy:

Many new positions at traditional and new Universities in the last few years.(it is not easy to find a pos-doc)

However, some students went to the industries that can be:

large ones, like Petrobras and Braskem

or small (spin-off): Plasmar Tecnologia (Caxias do Sul) and Clorovale Diamantes Indústria e Comércio S.A. (São José dos Campos)

SShorthort courses and talks for surface engineering diffusion and training for human resources courses and talks for surface engineering diffusion and training for human resources of the industry.of the industry.

Transfer of knowledge to the industrial sectorTransfer of knowledge to the industrial sector

Stand at Plastech industrial fair.

Training/Industrial Sector:Training/Industrial Sector:

At USP, at the Surface Phenomena Laboratory, the Institute offered two short courses and one workshop:

- Principles of Surface Texturing by Prof. Izhak Etsion (Technion), University of São Paulo. - Surface Finish Metrology, organized with the Center of Excelence of Taylor Hobson (United Kingdom),.- Tribological Challenges on the next generation of flex-fuel engined, at Mahle headquarters and at USP.

At UFRN, at Plasma Plasma ProcessingProcessing LaboratoryLaboratory, , short courses on vacuum technology and surface engeneering with technicians and engineering as audience.

- Diffusion of knowledge to the public in general using the web: www.engenhariadesuperficies.com.br

- Transfer of knowledge to the industrial sector.

- Open lab days for high school students.

- Participation in the activities of the National Week of Science and Technology.

- Organization of scientific meeting in Brazil:SimposiumSimposium at ICAM: at ICAM: “Protective Coatings: Surface Engineering” “Protective Coatings: Surface Engineering” at the International Conference on Advanced Materials. September 2009, Rio de Janeiro. Chairs: Fernando Lázaro Freire Jr, Y.W. Chung and Israel BaumvolBrazilBrazil--Argentina School on Argentina School on NanostructuredNanostructured CoatingsCoatings, December 2009, Rio de Janeiro. Organizer: Fenando Lázaro Freire Jr.

3) Transfer of knowledge to the society3) Transfer of knowledge to the society

Web: www.engenhariadesuperficies.com.brWeb: www.engenhariadesuperficies.com.br

Papers and patents, technical presentations, blog, videos, photos.

Web: how we reach the publicWeb: how we reach the public

Google search Google search first in the ranking for first in the ranking for

““engenhariaengenharia de de superfsuperfíciesícies””

EE--newsletternewslettermonthly monthly updateupdate

200 subscribers

academyindustrymedia

Twitter Twitter weekly update

2 respostas a Significativas mudanças no relacionamento com empresas: anotações1. Evando Mirra disse: 21/09/2010 às 11:18 pmCaro Amilton,Parabéns pelos comentários judiciosos e oportunos. Como você, sinto também que as coisas estão mudando sensivelmente e para melhor.É fato que existe um número cada vez maior de pessoas dedicadas à inovação nas empresas. Tenho participado frequentemente de bancas de doutorado em que um dos examinadores é pesquisador da indústria, corroborando o que você comenta a respeito da qualificação desses profissionais.E concordo plenamente com o papel decisivo das instituições nessa nova cultura: é fundamental que espaços como o Instituto Nacional de Engenharia de Superfícies sejam acionados nesse esforço. Um grande abraço, EvandoResponder2. Giuseppe Pintaude disse: 22/09/2010 às 11:11 pmAmilton,Recomendei seu texto no blog do PPGEM, após uma breve descrição de vivência recente no tema.Abraço, GiuseppeResponder

Open lab days for high school studentsOpen lab days for high school students

Organization of scientific meeting in Brazil:Organization of scientific meeting in Brazil:

Symposium at the IX Brazil-MRS Annual Meeting, Ouro Preto, , Ouro Preto, octoberoctober 2010: 2010: ProtectiveProtective CoatingsCoatings: : SurfaceSurface EngineeringEngineering, , Chairs: Fernando Lázaro Freire Jr and Carlos Figueroa

VII BrazilianVII Brazilian--German Workshop on Applied Surface ScienceGerman Workshop on Applied Surface Science, , BuziosBuzios, April 2011, , April 2011, Chairs: Fernando Lázaro Freire Jr.

2020thth InternationalInternational ConferenceConference onon IonIon BeamBeam AnalysisAnalysis, Itapema, , Itapema, AprilApril 2011, 2011, ChairsChairs: : Pedro Grande e Fernanda Pedro Grande e Fernanda StedileStedile..

4) Transfer of knowledge to the industrial sector4) Transfer of knowledge to the industrial sector

ABC/São José/Campinas Petrobras

Caxias do Sul Joinville

ContractsContracts withwith Petrobras:Petrobras:

PUC-Rio and UFRJ: Nanostructured Coatings (Network on Nanotecnology)

UFF: Characterization Center (Network on Corrosion)

UFRGS: Nanoparticles (Network on Nanotecnology)

R&D activities with Braskem (UFRGS), Frasle (UFRGS), Nanovetores (UFSC), Clorovale Diamantes (INPE) and Villares (USP).

3 deposited in INPI:1 UCS and 2 INPE

Spin-off company on plasma surface engineering: Plasmar Tecnologia (Caxias do Sul).

Some actions for 2011Some actions for 2011

Workshop on surface engineering at Vale (Tribology in the mining and mineral processing industries), February 2011.

3 short courses for human resources training on surface engineering at Simecs(Federation of the Metalworking Industries of Caxias do Federation of the Metalworking Industries of Caxias do SulSul) ) May, June and October 2011.

The National Institute of Surface Engineering

1) Research2) Human resources3) Difusion of Knowledge4) Transfer of knowledge to the industrial sector

Thank you for your attentionThank you for your attention