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Lab Name:WADSWORTH/ALERT Contract:6S-D1-OOS5MW20BF

74-87-3-———----Chloromethane74-83-9---————Bromome thane75-01-4———————Vinvl Chloride75-00-3———————Chloroe thane75-09-2———————Methvlene Chloride67-64-1-------—Acetone75-15-0———————Carbon Disulfide75-35-4———————1 , 1-Dichloroethene75-34-3-—-———-1,1-Dichloroethane540-59-0——————1,2-Dichloroethene (total)67-66-3———————Chloroform107-06-2 ——— ——1,2-Dichloroe thane78-93-3 ——————— 2-Butanone71-55-6— ———— -1,1, l-Trichloroethane56-23-5-—————Carbon Tetrachloride75-27-4-————--Bromodichloromethane78-87-5-——-----1,2-Dichloropropane10061-01-5---——cis-1,3-Dichloropropene79-01-6———————Trichloroethene124-48-l--------Dibromochloromet h ane79-00-5 ——— ———1,1,2-Tri chloroe thane71-43-2———————Benz e n e10061-02-6-———-trans-1.3-Dichloropropene75-25-2---———-Bromoform108-10-1 —————— 4-Methvl-2-Pentanone591-78-6- — ———— 2-Hexanone127-18-4 ————— -Tetra c hloroethene79-34-5——————-1.1.2.2-Tetrachloroethane108-88-3 — —— -—Toluene108-90-7- —————Chlorobenzene100-41-4- —————— Ethyl benzene100-42-5 ——— - — Stvrene1330-20-7—————Xylene (total)

i120. ! U120.120.!U120120120.!U120.!U28120.!U160120.!U120. !U120. !U110120.!U120.!U120. ,'U120. !'

2100.!120. !U120. !U120. !U120. !U120. |U120. !120. !'120. !120. !U120.!U120.!U120. !U120.!U120

Lab Code:WADS Case No.:87376 SAS No.: SDG No.:EQB-l

Matrix: (soil/water) WATER Lab Sample ID:42"770101

Sample wt/vol: 5.00 (g/ml) ML Lab File ID: VOL99S4

Level: (low/med) LOW Date Received: 1/30/92

% Moisture: not dec. Date Analyzed: 2/07/92

GC Column:DB624 ID: 0.53 (mm) Dilution Factor: 12.5

Soil Extract Volume:0 (uL) Soil Aliquot Volume:0 (uL

CONCENTRATION UN ITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

ftR307l*6l 000145

VOLATILE .ORGANICS A.sAi-it'SIS DATA -Si.^-•*. ." '-' ''• '""TENTATIVELY IDENTIFIED COMPOUNDS | ^

! MW/OBFLab Name:WADSWORTH/ALERT Contract : 68-D1-QQ85 ! J "• '

)Lab Code:WADS Case No.:S7376 SAS No.: SDG No.:EQB-l

Matrix: (soil/water) WATER Lab Sample 10:42770101

Sample wt/vol: 5.00 (g/ml) ML Lab File ID: VOL9984


% Moisture: not dec. 0 Date Analyzed: 2/07/92


Soil Extract Volume: 0.00 (uL) Soil Aliquot Volume: O.OO(uL)

CONCENTRATION UNITS:Number TICs Found: 0 (ug/L or ug/Kg) UG/L_

CAS NUMBER

1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

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AMOUNT=AREA * REF AMNT/(REF AREA * RESP FACT)Resp. fac. from Library Entry

No Name1 BROMOCHLOROMETHANE2 1; 4-DIFLUOROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE10 CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1,2-DICHLOROETHANE16 2-BUTANONE17 1,1,1-TRICHLOROETHANE18 CARBON TETRACHLORIDE19 VINYL ACETATEO BROMODICHLOROMETHANE21 1,2-DICHLOROPROPANE22 CIS-1,3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMQCHLOROMETHANE25 1,1,2-TRICHLOROETHANE26 BENZENE27 TRANS-1;3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1, 1, 2,2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES38 TOLUENE-0839 BROMOFLUOROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1,3-DICHLOROBENZENE44 1,2-DICHLOROBENZENE5 i,4-DICHLOROBENZENE

'46 AC ROLE IN47 ACRYLONITRILE 000148

43 TRICHLOROFLUOROMETHANE49 DICHLORODIFLUOROMETHANE50 CIS-1;2-DICHLOROETHENE

No m/z Scan Tims Ref RRT Meth Area(Hght) Amount JLTot1 128 299 6:22 1 l.OOO A BV 19753. 250. OOO NG 10.292 114 402 8:34 2 l.OOO A BB 75170. 25O. OOO NG 1O. 293 117 664 14: O9 3 l.OOO A BB 63956. 25O. 000 NG 10.294 NOT FOUND5 NOT FOUND6 NOT FOUND7 NOT FOUND8 NOT FOUND9 NOT FOUND10 76 131 2: 47 1 0. 438 A BB 50. 0. 181 NG 0. 01II 96 118 2:31 1 0.395 A BV 1185. 11.390 NG O. 4712 63 219 4:40 1 0.732 A BB 35. 0.156 NG 0.0113 NOT FOUND14 83 314 6:41 1 1. O5O A BB 35. O. 127 NG 0.0115 NOT FOUND16 43 294 6:16 1 O. 983 A*BB 81. 1.210 NG 0.0517 97 322 6:52 2 0.801 A BB 11031. 45.387 NG 1.8718 NOT FOUND19 43 239 5:06 2 0.595 A BB 68. 0.192 NG 0.0120 NOT FOUND21 NOT FOUND22 NOT FOUND23 13O 419 8:56 2 1.O42 A BV 11OO93. 853.179 NG 35.1124 NOT FOUND25 NOT FOUND26 NOT FOUND27 NOT FOUND28 NOT FOUND29 43 531 11:19 3 O. 8OO A BB 1222. 5.529 NG O. 2330 NOT FOUND31 164 586 12:29 3 O. 883 A BB 115. 0.897 NG 0.0432 NOT FOUND33 NOT FOUND34 112 668 14:14 3 1.006 A BB 39. 0.161 NG 0. Ol35 NOT FOUND36 NOT FOUND37 106 695 14:48 3 1.O47 A BB 152. 1.082 NG O. O438 98 531 11:19 3 O. 80O A BV 65937. 242.773 NG 9.9939 95 782 16:40 3 1.178 A BB 55917. 222.479 NG 9.1540 65 353 7:31 1 1.181 A BB 54532. 230.452 NG 9.4841 NOT FOUND42 NOT FOUND43 146 888 18:55 3 1.337 A BB 210. 0.653 NG O. 0344 146 934 19:54 3 1.4O7 A BB 54. O. 176 NG 0. Ol45 146 9O1 19:12 3 1.357 A BB 229. 0.664 NG 0.0346 NOT FOUND47 NOT FOUND48 NOT FOUND49 85 46 0:59 1 O. 154 A BB 34. 0.369 NG 0.0250 96 278 5:55 1 0.930 A BV 5986. 63.604 NG 2.62

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Lab Code: WADS Case No.:S73~6 SAS No.: SDG N'o.:EQB-l

Matrix: (soil/water) WATER ' Lab Sample ID:42~6410i

Sample wt/vol: 5.00 (g/ml) ML Lab F i l e ID: VOE19S3




Soil Extract Volume: 0.00 (uL) Soil Aliquot Volume: O.OOfuL

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L_ Q

74-87-3--—-———Chloromethane74-83-9 — --•-----Bromomethane75-01-4———————Vinyl Chloride75-00-3—-------Chloroethane75-09-2———————Methylene Chloride67-64-1---------Acetone75-15-0———————Carbon Disulfide75-35-4 ——————— 1, 1-Dichloroethene75-34-3———————1,1-Dichloroe thane540-59-0-—————1,2-Dichloroethene (total67-66-3-- —— —— -Chloroform107-06-2 —————— 1,2-Dichloroethane78-93-3-- — - ——— 2-Butanone71-55-6———————1, 1 . 1-Tr ichloroe thane56-23-5 —— -———Carbon Tetrachloride75-2T-4-------—Bromodi chloromethane78-S"-5—— —— - — 1,2-Dichloropropane10061-01-5 ————— cis-1 . 3-Dich_loropropene79-01-6———————Trichloroethene124-48-l--------Dibromochloromethane79-00-5 ———— ---1,1,2-T r i c h 1o r o e tha n e71-43-2--—---—Benzene10061-02-6————trans-1,3-Dichloropropene75-25-2-------—Bromoform108-10-1 ————— -4-Me thyl-2-Pentanone591-"S-6 —————— 2-Hexanone12 7-IS-4 — •————Te t. r a c h 1 o r o e_t h e n e _9-34-5----- — --1.1.1 , 2 ,2 -Te t r.ach 1 o r oe t hane108-88-3 — —————To l.uen.e .„._,_108-90-" ———_——Chlor100-41-4---———Ethyl benzene100-42-5 —————— S t y r e n eJ.3 3 0-2 Q-7—————x.vle n e J J o t a 1 )

14. ! u14. U14 . i U14 . ! U14 . ! U52. !_14. !U39

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000158

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Lab Code:WADS Case No.:873"6 SAS No.: SDG No.:EQB-l

Matrix: (soil/water) WATER Lab Sample ID:42"64lOl

Sample wt/vol: 5.00 (g/ml) ML Lab File ID: VOE1983






CAS NUMBER

1 .2.3.4.5.6.7.8.9.10.11 .12.13.14.15.16.17.18.19.20.21.i "i23 .24.25.26.i"** > *

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*i10'JNT=AREA * REF A«NT/(R£F AREA * RESP FACT)Resp, fac, from Library Entry ,

No Name1 BRQMOCHLOROMETHANE2 1,4-DIFLUOROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE10 CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1,2-DICHLQROETHANE16 2-BUTANONE17 1,1,1-TRICHLOROETHANE18 CARBON TETRACHLORIDE19 VINYL ACETATE20 BROMODICHLOROMETHANE21 1,2-DICHLOROPROPANE22 CIS-1,3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1,1,2-TRICHLOROETHANE26 BENZENE27 TRANS-1,3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES38 TOLUENE-D839 BROMOFLUOROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1,3-DICHLOROBENZENE44 1,2-DICHLOROBENZENE45 1,4-DICHLQROBENZENE46 ACROLEIN47 ACRYLONITPILE

000161

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No m/z Scan Time Ref RRT Meth Area(Hght) Amount XTot1 128 304 6:35 1 1.000 A BB 137062. 250.000 NG 8.022 114 409 8:52 2 1.000 A BB 497404. 250.000 NG 8.023 117 675 14:37 3 1.000 A BB 443793. 250.000 NG 8.024 NOT FOUND5 NOT FOUND6 NOT FOUND7 NOT-FOUND8 84 164 3: 33 1 0. 539 A BB 4293. 5. 563 NG O. 189 43 128 2:46 1 0.421 A BB 57252. 181.731 NG 5.8310 NOT FOUND11 96 123 2:40 1 O. 405 A BB 93598. 135.783 NG 4.3612 63 225 4:52 1 0.740 A BB 19271. 11.626 NG 0.3713 NOT FOUND14 NOT FOUND15 NOT FOUND16 43 293 6:21 1 0.964 A BB 2757. 5.142 NG 0.1617 97 327 7:05 2 O. 80O A BB 62959O. 727.011 NG 23.3218 117 327 7:05 2 0.800 A BB 93452. a- 397 NG 3.4619 NOT FOUND VJfWtf t~>T20 NOT FOUND J .-21 NOT FOUND ' # I22 NOT FOUND23 130 426 9:14 2 1.042 A BB 399591. 452.451 NG 14.5124 NOT FOUND5 97 589 12:46 2 1.440 A BB 1845. 2.270 NG 0.076 NOT FOUND7 NOT FOUND28 NOT FOUND29 43 54O 11:42 3 O. 8OO A BB 6611. 5.773 NG 0.1930 43 621 13:27 3 0. 92O A BB 971. 1.071 NG 0.0331 NOT FOUND32 S3 821 17:47 3 1.216 A BB 1994. 1.303 NG O. 0433 92 545 11:48 3 0.807 A BB 453. 0.370 NG 0.0134 NOT FOUND35 NOT FOUND36 NOT FOUND37 106 706 15:18 3 1.046 A BB 522. 0.524 NG 0.0238 98 540 11:42 3 0. SOO A BB 504444. 248.317 NG 7.9739 95 796 17:15 3 1.179 A BB 402946. 239.361 NG 7.684O 65 360 7: 4S 1 1. 184 A BB 228998. 235.925 NG 7.5741 NOT FOUND42 NOT FOUND43 146 905 19:36 3 1.341 A BB 1125. 0.634 NG 0.0244 146 951 20: 36 3 1. 409 A BB 812. 0. 487 NG O. O245 146 915 19:49 3 1.356 A BB 1527. 0.832 NG 0.0346 NOT FOUND47 NOT FOUND48 NOT FOUND49 NOT FOUND50 96 233 6:03 1 0.931 A BB 2659. 3.420 NG 0. 11

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MW21BFLab Name:WADSWORTH/ALERT Contract:6S-D1-OOS5

Lab Code:WADS Case No.:ST3~6 SAS No.: SDG N'o.:EQB-l

Matrix: (soil/water) WATER : Lab Sample ID:42~6S101

Sample wt/vol: 5.00 (g/ml) ML Lab File ID: VOE19S4






74-8"-3---------Chloromethane74-83-9 — —————Bromome thane75-01-4 ————— -—Vinyl Chloride75-00-3--——----Chloroethane75-09-2 ———————Methylene Chloride67-64-1-—----—Acetone75-15-0———————Carbon Disulfide75-35-4---------1,1-Dichloroethene75-34-3 — — — ——1, 1-Dichloroethane540-59-0 ———— — 1.2-Dichloroethene (total)67-66-3———————Chloro form107-06-2 ————— —1, 2-D ichloroe thane78-93-3 ———— - — 2-Butanone71-55-6 ——————— 1, 1. 1-Trichloroethane56-23-5———-—-Carbon Tetrachloride75-2T-4---------Bromodichloromethane8-8"-5--- — ---- i. 2-Dichloropropane10061-01-5—————cis-1.3-Dichloropropene79-01 -6-——————Trichloro e thene124-48-1----—--Dibromochloromethane79-00-5 ——— ———1,1,2-Trichloroethane71-43-2 ——— - —— -Benzene10061-02-6——-—trans-1, 3-Dichloropropene75-25-2-,——-——Bromoforrn108-10-1-—————4-Methvl-2-Pentanone591-"S-6 — —— - — 2-HexanoneJ. 27-18-4——— — - T e t r a c h 1 o r o e_t_h e n e79-34-5 ————— ——1 , 1,2, 2-Tetrachloroethane108-38-3——————Toluene ____________108-90-" ———— ---Chlo robe nz e n e_ __100-41-4——————Ethvl ben z e_ne..100-42-5 —————— St y.re ne_._. _1330-2Q--—————Xylene JJtot_a 1.)

830. !U830. '.'830. I830. !830.!U410. !8302800210830.!U830.!U830. !U290. !

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TENTATIVELY IDENTIFIED COMPOUNDSMW21BF

Lab Name:WADSWORTH/ALERT Contract:6S-D1-OOS5

Lab Code:WADS Case No.:87376 SAS No.: SDG Xo.:EQB-l

M a t r i x : (soil/water) WATER Lab Sample ID:42~6S101

Sample wt/vol: 5.00 (g/ml) ML Lab File ID: VOE19S4




Soil Extract Volume: 0.00 (uL) Soil Aliquot Volume: 0.00(uL


CAS NUMBER

1.2.3.4.5.6.1 .8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.•> - f28.29.30.

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Data: VOE1984. TI02/06/92 11:35:00Sample: 42768101, MW21BF> 6OUL/5MLConds. : 510000Formula: Instrument: 5100 Weight: 0. 004ubmitted by: Analyst: RQ Acct. No. :

AMOUNT=AREA * REF AMNT/<REF AREA * RESP FACT)Resp. fac. from Library Entry

No Name1 BROMOCHLOROMETHANE2 1, 4-DIFLUOROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE1O CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1,2-DICHLOROETHANE16 2-BUTANONE17 1,1, 1-TRICHLOROETHANE18 CARBON TETRACHLORIDE19 VINYL ACETATE20 BROMODICHLOROMETHANE21 1,2-DICHLOROPROPANE22 CIS-11 3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMQCHLOROMETHANE25 1,1, 2-TRICHLOROETHANE26 BENZENE27 TRANS-1, 3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES38 TOLUENE-D839 BROMOFLUOROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1,3-DICHLOROBENZENE44 1,2-DICHLOROBENZENE45 1,4-DICHLOROBENZENE46 ACROLEIN47 ACRYLONITRILE

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fX" -•!"-• , -;No Name48 TRICHLOROFLUCROMETHANE49 DICHLORODIFLUOROMETHANE50 CIS-1,2-DICHLOR OETHENE

No m/z Scan Time Ref RRT Meth Area(Hght) Amount %Tot7. 577. 577. 57

4 NOT FOUND5 NOT FOUND6 NOT FOUND7 NOT FOUND8 NOT FOUND9 43 127 2: 45 1 0. 418 A BB 7759. 24. 616 NG O. 7410 NOT FOUND11 96 123 2: 4O 1 O. 4O5 A BB 114478. 165.989 NG 5.0212 63 225 4:52 1 0. 74O A BB 21221. 12.796 NG 0.3913 NOT FOUND14 NOT FOUND15 62 366 7: 56 1 1. 2O4 A BB 1101. 1.154 NG 0.0316 43 293 6: 21 1 0. 964 A BB 9442. 17. 599 NG 0. 5317 97 327 7:05 2 0. 80O A BB 716830. 809.481 NG 24.5018 117 327 7:05 2 0.800 A BB 105959. >*< 637 NG 3.6219 43 242 5:15 2 0.592 A BB 483. - tf? 0.286 NG O. 0120 NOT FOUND ^ |L'1'21 NOT FOUND22 75 519 11:15 2 1.269 A BB 415. 0.369 NG 0.0123 13O 426 9:14 2 1. O42 A BB 528798. 585.536 NG 17.7224 129 623 13:30 2 1.523 A BB 713. 0.566 NG 0.0225 97 590 12:47 2 1.443 A BB 3229. 3.886 NG 0.1226 78 361 7: 49 2 O. 883 A BB 494. 0. 250 NG 0. 0127 NOT FOUND28 173 759 16:27 2 1.856 A BB 3035. il 2. 951 NG 0.0929 43 541 11:43 3 0. 8O1 A BB 17471. ||npt><'833 NG 0.4530 43 622 13:29 3 0.921 A BB 8408. V u& 9.016 NG 0.2731 164 595 12:53 3 0.881 A BB 761. M/ l. 055 NG 0.0332 83 821 17:47 3 1.216 A BB 1O763. * 6.839 NG 0.2133 92 546 11:50 3 0.809 A BB 944. 0.749 NG 0.0234 112 677 14: 4O 3 1. OO.3 A BB 1842. 0.986 NG O. 0335 106 7O7 15:19 3 1.047 A BB 2214. 2.943 NG 0.0936 1O4 747 16:11 3 1.107 A BB 1336. 0.783 NG 0.0237 1O6 707 15:19 3 1.047 A BB 2214. 2.161 NG 0.0738 98 54O 11:42 3 0. 8OO A BB 523464. 250.522 NG 7.5839 95 796 17:15 3 1.179 A BB 425027. 245.465 NG 7.4340 65 360 7:48 1 1.184 A BB 235311. 242.305 NG 7.3341 NOT FOUND42 106 745 16:08 3 1.104 A BB 1368. 1.269 NG 0.0443 146 905 19:36 3 1.341 A BB 4O92. 2.241 NG 0.0744 146 951 2O: 36 3 1. 4O9 A BB 3497. 2. O38 NG 0.0645 146 915 19:49 3 1.356 A BB 4710. 2.495 NG 0.0846 NOT FOUND47 53 186 4: 02 1 0. 612 A BB 4080. 19. 679 NG 0. 6048 NOT FOUND49 NOT FOUND5O 96 283 6: 08 1 0. 931 A BB 3196. 4. 1O9 NG 0. 12

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9:14SAMPLE: 42768101, MW21BF, 601COHDS.: 510000GC TEMP:

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j.-vv >.., i, ANALYSIS C.MA SHbET

W21BFBV'Lab Name:WADSWORTH/ALERT Contract:6S-D1-OOS5

Lab Code:WADS Case Xo.:S~3~6 SAS No.: SDG Xo.:EQB-1

Matrix: (soil/water) WATER ' .Lab Sample ID:42"69101

Sample wt/vol: 5.00 (g/ml) ML Lab F i l e ID: VOE1992

Level: (low/med) LOW _ Date Received: 1/30/92





4-8~- 3---------Chloromethane74-S3-9---------Bromome thane75-01-4———————Vinyl Chloride75-00-3- —— — ---Chloroe thane5-09-2 — — ———Methylene Chloride

67-64-1---------Ace tone75-15-0---------Carbon Disulfide'5-35-4 ——— —— — 1 , 1 -Dich loroethene5-34-3---------1,1-Dichloroethane

540-59-0 ———— —— 1,2-Dichloroethene (total)

1000.!U1000.!U1000.!U1000. !U1000. ', U1000. !U1000. !U25001000.!U1000.IU

67-66-3---------Chlorofp rm 1000. !U1Q7-Q6-2— - ———— 1 , 2-D ichloroe thane 1000. !U78-93-3 — -- ——— 2-Butanone71-55-6---------I ,1,1-Trichloroe thane

1000.!U16000.!

56-23-5------——Carbon Tetrachloride 1000. ', U75-27-4---------Bromodichloromethane looo. IL*S-S~-5---------l,2-Dichloropropane 1000 I V

10061-01-5------Cis-1.3-Dichloropropene 1000. JL*^9-01-6-——————Tr ichloroe t hene 10000 f

124-48-1--------Dibromochloromethane 1000.!U79-00-5————-1,1,2-Trichloroethane 1000. IUl-43-2---------Benzene 1000

10061-02-6------trans-1.3-Dichloropropene 1000.!U'5-25-2---------Bromoforin 1000.108-10-1 ——— -——4-Methvl-2-Pentanone looo.;L591-"S-6----——2-Hexanone looo.:u127-18-4------—Tetrachloroethene 1000.IU'9-34-5---------1,1.2.2-Tetrachloroethane 1000. !U108-SS-3-----——To 1uene 1000. !U10S-90-"—.— -_Tjr_7C]Ll_o_ro_b en_ze ne_ 1000. |U100-41-4 — — - --rJLLhy.1 b e.n.z e n_e100-42-5- —— - —— Stvrene

10001000

1330-20-"-————Xylene (total) 1000.!U

RR307506FORM I VGA ' .-5/P-O

TENTATIVELY IDENTIFIED COMPOUNDS'


Lab Code:WADS Case Xo.:S~3"6 SAS Xo.: SDG Xo.:EQB-l

M a t r i x : (soil/water) WATER Lab Sample ID:42"69101

Sample wt/vol: 5.00 (g/ml) ML Lab F i l e ID: VOE1992





COXCEXTRATION UXITS:Number TICs Found: 0 (ug/L or ug/Kg) UG/L_

CAS NUMBER

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mula: -- Instrument. 5100 Weight: 0.004If'.. &>r- i t ted by Analyst: RQ Acct. No. :

AMCL;NT=AREA * P.EF AMNT/(PEF AREA * RE3P FACT)Fesp. fac. from Library Entry

No Name1 BROMOCHLOROMETHANE2 1,4-DIFLUOROBENZENE3 CHLOROEENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANES METHYLENE CHLORIDE9 ACETONE10 CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1,2-DICHLOROETHAME16 2-BUTANQNE17 1,1,1-TRICHLOROETHANEIS CARBON TETRACHLORIDE19 VINYL ACETATE0 BROMODICHLOROMETHANE1 1/2-DICHLOROPRQPANE

22 CIS-1,3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1,1,2-TRICHLOROETHANE26 BENZENE27 TRANS-1,3-DICHLOROPROPENE28 BROMOFORM2? 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2,2-TETRACHLQROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLEENZENE36 STYRENE37 XYLENES38 TOLUENE-OS3= v BROMOFLUCROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 I, 3-DICHLGROBENZENE

1, 2-DICHLQRCSENZENE1, 4-DICHLQR05ENZENEACROLEINACRYLONITRILE

ftR307509 000133

"43 TRICHLORCFLUORQMETHANE^- DICHLORODIFLUORONETHANE50 CIS-1,2-DICHLORQETHENE

No m/z Scan Time Ref RP.T Math Area(Hght) Amount ''.Tot1 128. 304 6.35 1 l.OOO A BB 131522. 25G, OOO NG 8.192 114 409 8:52 2 1.000 A BB 468955. 250.000 NG 8. 193 117 675 14:37 3 1.000 A BB 443687. 250.000 NG 8.194 NOT FOUND5 NOT FOUND6 NOT FOUND7 NOT FOUND8 84 164 3:33 1 0.539 A BB 1637. , jo)--1 ' 2.211 NG 0.079 43 129 2:48 1 0.424 A BB 5714. \r LST'902 NG 0.6210 NOT FOUND11 96 125 2:42 1 0.411 A BB 83751. 126.615 NG 4.1512 63 225 4: 52 1 0. 740 A BB 15517. 9. 756 NG 0. 3213 NOT FOUND14 NOT FOUND15 NOT FOUND16 43 292 6:20 1 0.961 A BB 995. 1.934 NG 0.0617 97 326 7:04 2 0.797 A BB 644165. 788.966 NG 25.8618 117 326 7:04 2 0.797 A BB 95723. >tT. 224 NG 3.8419 NOT FOUND20 NOT FOUND21 NOT FOUND22 NOT FOUND23 130 426 9:14 2 1.042 A BB 432253. 519.125 NG 17.0224 NOT FOUND25 97 590 12:47 2 1.443 A BB 1231. 1.607 NG 0.0526 78 360 7: 48 2 0. 88O A BB 497. 0. 273 NG 0. 0127 NOT FOUND28 NOT FOUND29 43 540 11:42 3 0.800 A BB 3389. 2.960 NG 0.1030 NOT FOUND31 NOT FOUND32 NOT FOUND33 92 545 11:48 3 0. 8O7 A BB 1244. 1.015 NG 0.0334 112 677 14: 4O 3 1.003 A BB 2894. 1.594 NG 0.0535 NOT FOUND36 NOT FOUND37 NOT FOUND38 98 540 11:42 3 0.800 A BB 486932. 239.753 NG 7.8637 95 796 17:15 3 1.179 A BB 400727. 238.100 NG 7.8040 65 359 7:47 1 1.181 A BB 211532. 227.110 NG 7.4441 NOT FOUND42 NOT FOUND43 146 9O5 19:36 3 1.341 A BB 427. 0.241 NG O. 0144 NOT FOUND45 146 915 19:49 3 1.356 A BB 1020. 0.556 NG 0.0246 NOT FOUND47 NOT FOUND4S NOT FOUND4° NOT FQUND50 96 283 6: OS 1 C. 931 A BB 2244. 3.008 NG 0.10

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ANALYSIS. _ -.7 -\ SHEET

TRPBL1Lab Name:WADSWORTH/ALERT Contract:6S-D1-OOS5

Lab Code: WADS Case No.:S~3~6 SAS No.: SDG No.:EQB-l

Matrix: (soil/water) WATER Lab Sample ID:42~6il01

Sample wt/vol: 5.00 (g/ml) ML Lab F i l e ID: VOL99S2


% Moisture: not dec. 0 Date Analyzed: 2/0"/92




74-87-3---------Chloromethane74-83-9---—----Bromomethane75-01-4- —————— Vinyl Chloride

-Chloroethane75-09-2 — —————Methylene Chloride67-64-1-------—Acetone75-15-0------ — -Carbon Pisu1f ide

•1 ,1-Dichloroethene75-34-3---------1,1-Dichloroethane540-59-0 — ————1,2-Dichloroethene (total67-66-3-- — ———Chloroform107-06-2- — --- — 1,2-Dichloroethane78-93-3 ————— --2-Bu t an o n e71-55-6———————1,1, 1-Trichloroethane

•Carbon Tetrachloride75-27-4---------Bromodichloromethane78-87-5---------1 ,2-Di c h.l_o_r o_2.i"J2JLa_n.e_1006l-Ol-5------cis-l.3-Dichloropropene79-01-6-------- -Trichloroet he ne_124-4S-l--------Dibromochloromethane79-00-5 — —— -——1.1,2-Trichloroethane1-43-2-- — - ——— Benzene

10061-02-6------trans- 1_., 3-Dichloropropene•Bromof orm

108-10-1-————4-Methyl-2-Pentanone591-"S-6——--—2-Hexanone12~- 18-4--------Te t r_a_ch 1 oroejt hene'9-34-5---------1..,1., 2.2-TetrachIoroethane10S-8S-3--———Toluene

>-90-~--------Chlorobenzene100-41-4--- — -—Et hy 1 be n z ene__. ... ____100-42-5--- ———— Stvrene.1330-20-~- —— ---Xylen e _ ( t o t a 1.

10. Ui o . : u10. ! u1 0 . ! U10. i U

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VOLATILE oRG.\:v.---.y ANALYSIS DAT* SHEETTENTATIVELY IDENTIFIED COMFvw.'DS

TRPBL1Lab Name:WADSWORTH/ALERT Contract:6S-D1-OOS5

Lab Code:WADS Case No.:S~3~6 SAS No.: SDG No.:EQB-1

Matrix: (soil/water) WATER Lab Sample ID:42"61101



% Moisture: not dec. 0 Date Analyzed: 2/0~"/92



CONCENTRATION UNITS:Number TICs Found: 0 (ug/L or ug/Kg] UG/L_

CAS NUMBER

1 .2.3.4.5 .6.1 .8.9.10.11 .12.13.14.15.16.I ~ _18.19.20.-21 .22 .23 .24.25 .26.•> -28.29 .30.

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Daca. VOL9982. TI02/07/92 1:54.00Sample: 42761101, TRPBL1, 5MLConds. : FINN52Formula: VOC Instrument: FINN52 Weight: 0 000Submitted by. WADS Analyst: JP Acct. No. 6SD10008

AMOUNT-AREA * REF AMNT/(REF AREA * P.ESP FACT)Resp. fac. from Library Entry

No Name1 BROMOCHLOROMETHANE2 1,4-DIFLUOROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE1O CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1/2-DICHLOROETHANE16 2-BUTANONE17 1.1,1-TRICHLOROETHANE18 CARBON TETRACHLORIDE19 VINYL ACETATE2O BRQMODICHLOROMETHANE21 1,2-DICHLQROPROPANE22 CIS-1*3-DICHLQRQPROPENE23 TRICHLOROETHENE24 DIBROMQCHLOROMETHANE25 1,1,2-TRICHLOROETHANE26 BENZENE27 TRANS-li3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2,2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES38 TOLUENE-0839 BROMOFLUORQBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE fTOTAL)43 1,3-DICHLOROBENZENE44 1,2-DICHLOROEENZENE45 1,4-DICHLOROBENZENE46 ACROLEIN47 ACRYLONITRILE

O

000404AR3G7520

43 TRICHLOROFLUOROMETHANE49 DICHLORODIFLUOROMETHANE50 CIS-1, 2-DICHLOROETHENE

No m/z Scan Tims Ref RRT Meth Area(Hght) Amount XTot1 128 299 6:22 1 1.000 A BB 22738. 250.000 NG 16.382 114 402 8:34 2 l.OOO A BB 84413. 25O. 000 NG 16.383 117 664 14:09 3 1.000 A BV 72561. 250.000 NG 16.384 NOT FOUND5 NOT FOUND6 NOT FOUND7 NOT FOUND8 84 158 3:22 1 0.528 A BV 491. 4.493 NG 0.299 43 124 2:39 1 0.415 A BB 1466. 32.521 NG 2.1310 NOT FOUND11 NOT FOUND12 NOT FOUND13 NOT FOUND14 NOT FOUND15 NOT FOUND16 43 287 6:07 1 0.960 A BB 40. 0.519 NG 0.0317 97 322 6:52 2 0.801 A BB 34. 0.125 NG O. 0118 NOT FOUND19 NOT FOUND2O NOT FOUND21 63 437 9:19 2 1.087 A BB 44. 0.334 NG 0.0222 NOT FOUND23 NOT FOUND24 NOT FOUND25 NOT FOUND26 78 353 7:31 2 0.878 A BB 8O. 0.283 NG 0. O227 NOT FOUND28 NOT FOUND29 43 531 11:19 3 0.800 A BB 1678. 6.691 NG 0.4430 NOT FOUND31 164 588 12:32 3 O. 886 A BB 74. 0.509 NG 0.0332 NOT FOUND33 91 536 11:25 3 0.807 A BB 227. 0.692 NG 0.0534 NOT FOUND35 NOT FOUND36 NOT FOUND37 NOT FOUND38 98 532 11:20 3 0.801 A BB 76380. 247.870 NG 16.2439 95 783 16:41 3 1.179 A BB 68488. 240.179 NG 15.7440 65 353 7:31 1 1.181 A BB 65844. 241.723 NG 15.8441 NOT FOUND42 NOT FOUND43 146 901 19:12 3 1.357 A BB 206. 0.564 NG 0.0444 NOT FOUND45 NOT FOUND46 NOT FOUND47 NOT FOUND48 NOT FOUND4? NOT FOUND50 NOT FOUND

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- •• •-—••• - "-1" ' ••• ••" ••'•' « •. f ^. - t i i ••. j*r»Ti — -° m "tl •" •« Lp UJ

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SR307523

COCO

VOLATILE STANDARDS DATA

4ftSR30752U

.OLATILE ORGAN'ICS INITIAL CALIBRATION" DATA

Lab Name:WADSWORTH/ALERT ' Contract:6S-D1-OOS5

ab Code:WADS Case No.:S"3~6 SAS No.: SDG Xo.:EQB-l

Instrument ID:510000 - " C a l i b r a t i o n Date(s): 2/05/92 2/05/92

Heated Purge: (Y/X) X Calibration Times:

GC Coiumn:DB624 ID: 0.53 (mm)

LAB FILE ID: RRF 10 =VOE196;RRF50 =VOE1966 RRF 1 00=VOE1 96;

jCOMPOUND ! RRF 10

)— — — — — — — — — — — — — — — — — — — — — — — — — — — — | — — — — — —

CHLOROMETHANE 2.268BROMOMETHAXE * 1.931VINYL CHLORIDE * 1 .890CHLOROETHANE 1 . 206METHYLEN'E CHLORIDE 1.455ACETONE 0.784CARBON DISULFIDE 3.7591 , 1-DICHLOROETHENE * 1.3451 . 1-DI CHLOROETHANE * 3.0231 . 2-DICHLOROETHENE (TOTAL) ! 0.000CHLOROFORM * 2.629kl. 2-D I CHLOROETHANE * 1.594'2-BUTANONE ! 1.052! 1 , 1 . 1-TR I CHLOROETHANE * 0.483CARBON TETRACHLORIDE * 0.423IBROMODICHLOROMETHANE * 0.5941.2-DICHLOROPROPANE ! 0.504

1CIS-1 .3-DICHLOROPROPENE * 0.837TRICHLOROETHENE * 0.463,'DIBROMOCHLOROMETHANE * 0.5561.1. 2 -TR I CHLOROETHANE * 0.39"

! BENZENE *' 0.963TRANS-1 , 3-DICHLOROPROPENE * 0.154BROMOFORM * 0.4374-METKYL-2-PENTANONE ! 0.6422-HEXAXOXE ! 0.462TETRACHLOROETHENE * 0.379

, 1 . 1 .2.2-TETRACHLOROETHANE * 0.852TOLUENE * 0.6 "51CHLOROBEXZEXE * 1.040ETHYLBEXZEXE "' * 0.411! STYREXE * 0.8"6'XYLEXE (TOTAL) * 1.0S3

TOLUEXE-DS 1.129IBROMOFLUOROBEXZEXE * 0.9561 . 2-DICHLOROETHAXE-D4 1 . 6^4

i

\

,)

RRF20

1.-621.4351.4400.9111.4820.5523.5471 . 2572. 8240.0002.6971.6310.9610.4280.4210.6080.4970.8680.4490.5950.4070.9"!0. 1650.4940.6"0.4620.3950.921O.'OO1 .0510.4200.9241 . i2~

1 . 1"S0.9S91 .65'

RRF2CRRF2C

RRF50

1 .8681.6201 .6200.8971.4420.5093.9931 .3853.1171 .4102.9481.S210.9090.4850.4710.-160.5701.0510.5120.7620.4831 .0900. 1980.6460.6690.4-40.4360.9950.-531 . 14S0.4611 .0-80.6~1

1 .0980.9-41 .664

) =VOE1<)0=VOElf

RRF100

1.6SO1 . 1451.3890.5951.5310.4434.0431 . 3483.0540.0003.022i.-is0.9350.4890.4930.7140.5421 .0190.4990.7540.4781 .0590.2060.6260.6SS0.5120.4310.9850 . "561 .0680 . 4 5 S1.0121 . 143

1 .09"0.9591 . 5"!

364>62

RRF200

1 .6620.9851 .3280.5111 .4570.38-3.9601 . 1S62. 8460.0002.7661.7190.8"30.4460.4710.5840.4-50.6940.43-0.5""0.4190 . ' S 50. 1940.50"0.5"0.4240.39-O."200.6220.-420.413O.-QO0. "68

0."30.6-31.53"

RRF

1 .8481 .4231 .5330.8241.4730.5353.8601 .3042.9*31 .4102.8121 .69"0.9460.4660.4560.6430.5180.8940.4720.6490.43-0.9-40. 1830.5420.6510.46"0.4080.8950.-Q11 .0100.4330.9180.958

1.0550.9101.615

f

RSD

13 .426.4 *14.8 »33.72.4

28. 65.36.2 i4.4 »0.05.9 *5.2 *7. 15.9 *7.0 *

10.3 i-.3

16.2 i6.8 *

15.5 *9.3 *

12.2 =*12.3 »16.6 *6.8 '6."6. 1 >

12.6 *S.O *

15.4 >5 . ~ *

15.8 *23.2 *= = = = =15.314 . 6 >3.5

Compound* wi t h required minimum RRF and maximum '''RSD valuesAil other compounds must meet a minimum RRF of 0.010.

HR307525

VOLATILE ORGAXICS INITIAL CALIBRATION" DATA

Lab XauiK : WADSWORTH/ALERT Con t rac t : 6S-D 1-OOS5

Lab Code:WADS Case No.:S~376 SAS Xo.: SDG Xo.:EOB-i

Instrument ID:FIXX52 Calibration Date(s): 2/06/92 2/06/92

Heated Purge: (Y/N) X Calibration Times: l_>?$ L> 2 ^/f , * ('• i ) ^ •* '/ ••*-/«, • i ' /^>J " J

GC Column:DB624 ID: 0.53 (mm)

ILAB FILE I D : R R F 1 0 = V O L 9 9 6 3 R R F 2 0 =VOL99621RRF50 =VOL9959 RRF100=VOL9961 RRF200=VOL9960

1

! COMPOUND

! CHLOROMETHANE! BROMOMETHANE1 VINYL CHLORIDE! CHLOROETHANE1METHYLENE CHLORIDE! ACETONE! CARBON DISULFIDE! 1 , 1-DICHLOROETHENE! 1 . 1-D I CHLOROETHANE! 1 . 2-D I CHLOROETHENE ( TOTAL! CHLOROFORM! 1 , 2-D I CHLOROETHANE! 2-BUTANONE! 1 , 1 , 1-TR I CHLOROETHANE! CARBON TETRACHLORIDE! BROMOD I CHLOROMETHANE! 1 . 2-DICHLOROPROPANE1CIS-1 . 3-DICHLOROPROPENEiTRICHLOROETHENE! DIBROMOCHLOROMETHANE1 1 , 1 . 2-TR I CHLOROETHANE1 BENZENEITRANS-1 . 3-DICHLOROPROPENE! BROMOFORM! 4-METHYL-2-PENTANONE! 2-HEXANOXE! TETRACHLOROETHEXE1 1 . 1 . 2 . 2-TETRACHLOROETHANE! TOLUENE1CHLOROBENZEXEiETHYLBEXZEXE! STYREXEIXYLEXE ( iOTAL )1

ITOLUENE-DS! BROMOFLUOR03EXZEXE! 1 .2-DICHLOROETHAXE-D4

**

**

) |**

***

*******

*****^*

= = =

X

RRF 10

1 .0191 .6410.9501. 1321 . 1630.7873.7521.5473.3091.3964.2133.5961 . 1850.9471 . 1540.9400.4571 .0000.5240.9890.410'0.9"00. 2250.97-1.0480.-920.59"0.9561 .2351 . 1290.4151 .0500.634

0.959O.S2S2.92"

i

1

RRF20 1

11

1

1

1

041

1«

3101000000000100

_011010

001

.859!

.124!

.554!

.357!

.586!

.782!

.425!

."9!

.-21!

.542!

. 140!

.681 !

. 159!

.910!

.072!

.890!

.441!

.951 !

.460!

.903!

.380!

.936!

. 196!

.905!

.035!

.-68!

.590 1

.944!

.259!

.053!

.414!

.069!

.593!

. 9-9 !

.913!

.393!

RRF50

1 .5521 .9"21 .3031 .2201.3750.4734.4471.5643. 1011.4533.5233.0580.6960.8251 .0140.8090.3960.8350.4090.8040.3220.85"0. 1840 . "710 . "230. 5410.49"0.-S41.1140.9410.3630.9650.555

1 .09"0.93"2.935

RRF100

1.3521.9531.2431.3111.4380.5784.6861.6593.4191 .5913.7353.2"!0.8580.9541 . 1480.9270.444i .0030.4660.9-80.3840.9830. 2201 .0810.8440.6630. 5360.96'1 . 1610.9930. 386i .09"0.630

0.9431 .0132.8"0

4 i

RRF

1 .i .1 .1 .1 .0.4.1 .3 .1 .3 .3.0.0.1 .0.0.1 .0.1 .0.1 .0.1 .0.0.0.1 .1 .1 .0.1 .0.

1 .1 .•%J .

200!

08-;"21 !003!178!3-3!474!698!-37!203!456!845!407!685!936!202!974!458!055 !498!1 1 1 !392!02-;234!290!"55!595 1564!013!250!056!410!3-0!-64!_ _ — '

019!t -o 1- 0 |

010!tI

1

RRF 1

1.3-4!1 .883!1.211!1 .240!1.387!0.619!4.402!1 .65"!3.35111.488!3.891 !3.403!0.91"!0.914!1.118!0.908!0.439!0. 969!0.4-1!0.95"!0.3-3;0.955;0.212!1 .005!0.882!0.6-3!0.55"!0.934!1 .204!1.034!0.398!1 . 110!0.635!

0.999!1.005!2.92-1

11

RSD

25.110.520 . 27 . 5

11.025 .4S,"6.2". 15. 2

33!5.86."6.95.88.69. 2

~S.S6."9 . 9

19.41 " . 216.1-.49.55.36.9•? ™"

13.812.4— — — — -

6.216.9_L^

*

**

i***ii******ii

***#**i

1* Compounds wi:h required minimum RRF and maximum \.RSD values.

""All other compounds must meet a minimum RRF of 0.010. Pf"")*

AR307526FORM VI VOA 3/90

fiR307527

Quantitation Report File: VJ&1966

Data: VOE1966. TI02/O5/92 20:09:OOSample: VSTDO50, 250NG VOL STD, 5MLConds. : 51OOOOFormula: Instrument: 5100 Weight: 0. 004Submitted by: Analyst: RQ Acct. No.:


No Name1 BROMOCHLOROMETHANE2 1,4-DIFLUOROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE10 CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1,2-DICHLOROETHANE16 2-BUTANONE17 1,1,1-TRICHLOROETHANE18 CARBON TETRACHLORIDE19 VINYL ACETATE20 BROMODICHLOROMETHANE21 1,2-DICHLOROPROPANE22 CIS-1, 3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1,1,2-TRICHLORDETHANE26 BENZENE27 TRANS-1,3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES38 TOLUENE-D839 BROMOFLUOROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1,3-DICHLOROBENZENE44 1,2-DICHLOROBENZENE45 1,4-DICHLOROBENZENE46 ACROLEIN47 ACRYLONITRILE

OQG-,11AR307528

No Name48 TRICHLOROFLUOROMETHANE49 DICHLORODIFLUOROMETHANE50 CIS-1,2-DICHLOROETHENE

No m/z Scan Time Ref RRT Meth Area(Hght) Amount XTot1 128 303 6:34 1 1.000 A BB 140081. 250.000 NG 1.922 114 4O8 8: 5O 2 l.OOO A BB 489890. 25O. OOO NG 1.923 117 675 14:37 3 1.000 A BB 481916. 25O. 000 NG 1.924 50 61 1:19 1 0.201 A BB 261609. 250.000 NG 1.925 94 75 1:37 1 0.248 A BB 226951. 250.000 NG 1.926 62 64 1:23 1 0.211 A BB 226980. 250.000 NG 1.927 64 75 1:37 1 0.248 A VB 125670. 250.000 NG 1.928 84 164 3:33 1 0.541 A BB 201980. 250.000 NG 1.929 43 129 2:48 1 0.426 A BB 71346. 250.000 NG 1.9210 76 138 2:59 1 0.455 A BB 559412. 250.000 NG 1.9211 96 124 2:41 1 0. 4O9 A BB 193974. 250. OOO NG 1.9212 63 224 4:51 1 0.739 A BB 436571. 250.000 NG 1.9213 96 185 4:00 1 0.611 A BB 197496. 250.000 NG 1.9214 83 319 6:55 1 1.053 A BB 412915. 250.000 NG 1.9215 62 366 7:56 1 1.208 A BB 255070. 250.000 NG 1.9216 43 292 6:20 1 0.964 A BV 127298. 250.000 NG 1.9217 97 326 7: O4 2 O. 799 A BB 237754. 250.000 NG 1.9218 117 341 7:23 2 O. 836 A BB 230733. 250.000 NG 1.9219 43 242 5:15 2 0.593 A BB 297852. 250.000 NG 1.9220 83 476 10:19 2 1.167 A BB 35O60O. 250.000 NG 1.9221 63 444 9:37 2 1.088 A BB 279216. 250.000 NG 1.9222 75 519 11:15 2 1.272 A BB 51485O. 405. OOO NG 3.1223 130 426 9:14 2 1.044 A BB 250592. 250.000 NG 1.9224 129 622 13:29 2 1.525 A BB 373514. 250.000 NG 1.9225 97 589 12:46 2 1.444 A BB 236641. 250.000 NG 1.9226 78 366 7:48 2 O. 882 A BB 533988. 250.000 NG 1.9227 75 575 12:27 2 1.409 A BB 97224. 95.000 NG 0.7328 173 759 16:27 2 1. 86O A BB 316576. 25O. 000 NG 1.9229 43 540 11:42 3 0. 8OO A BB 322448. 25O. OOO NG 1.9230 43 621 13:27 3 0.920 A BB 228261. 250.000 NG 1.9231 164 595 12:53 3 0.881 A BB 210133. 250.000 NG 1.9232 83 821 17:47 3 1.216 A BB 479744. 250.000 NG 1.9233 92 545 11:48 3 0.807 A BB 362729. 250.000 NG 1.9234 112 677 14:40 3 1. OQ3 A BB 553381. 250.000 NG 1.9235 1O6 694 15: O2 3 1. O28 A BV 222338. 250.000 NG 1.9236 104 746 16:10 3 1.105 A BB 519541. 250.000 NG 1.9237 106 7O7 15:19 3 1. O47 A VB 613040. 5OO. OOO NG 3.8538 98 54O 11:42 3 O. 8OO A BB 52917O. 25O. OOO NG 1.9239 95 795 17:13 3 1.178 A BB 469155. 250.000 NG 1.9240 65 359 7:47 1 1.185 A BB 233109. 250.000 NG 1.9241 63 514 11:08 2 1.260 A BB 13775. 250.000 NG 1.9242 106 744 16:07 3 1.102 A BB 323467. 250.000 NG 1.9243 146 904 19:35 3 1.339 A BV 594678. 250.000 NG 1.9244 146 951 20:36 3 1. 4O9 A BB 569355. 250.000 NG 1.9245 146 915 19:49 3 1.356 A VB 619663. 250.000 NG 1.9246 56 115 2:29 1 0. 38O A BB 28315. 500.000 NG 3.8547 53 186 4:02 1 0.614 A BB 108055. 500. OOO NG 3.8548 NOT FOUND49 85 51 1:06 1 0.168 A BB 188472. 250.000 NG 1.9250 96 282 6:07 1 0.931 A BB 214488. 250.000 NG 1.92

AR307529

<s>

-vl C<• • i2ro »s

cn—1 O'l OJM o to

5

flR 307 5 30

Quantitation Report File: VOE1962

^ ^ kC on d^ PForm^ ^ ^ e^. . u _

Data: VOE1962. TIO2/05/92 17:47:00Sample: VSTD20O, 1000NG VOL STD, 5ML

: 51OOOOormula: Instrument: 5100 Weight: 0. OO4

Submitted by: Analyst: RQ Acct. No. :

AMOUNT=AREA * REF AMNT/CREF AREA # RESP FACT)Resp. fac. from Library Entry

No Name1 BROMOCHLOROMETHANE2 1,4-DIFLUOROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE1O CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1,2-DICHLOROETHANE16 2-BUTANONE17 1,1,1-TRICHLOROETHANE18 CARBON TETRACHLORIDE19 VINYL ACETATE20 B R OMODIC HLOR OMETHANE21 1,2-DICHLOROPROPANE22 CIS-1, 3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1,1, 2-TRICHLOROETHANE26 BENZENE27 TRANS-1, 3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANONE3O 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES38 TOLUENE-D839 BROMOFLUOROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1,3-DICHLOROBENZENE44 1,2-DICHLOROBENZENE45 1,4-DICHLOROBENZENE46 ACROLEIN47 ACRYLONITRILE

BR30753I


No m/z Scan Time Ref RRT Meth Area(Hght) Amount XTot1 128 305 6:36 1 l.OOO A BB 190726. 250.000 NG 0.592 114 4O9 8:52 2 l.OOO A BB 7743OO. 25O. 000 NG 0.593 117 675 14:37 3 l.OOO A BB 708719. 250.000 NG 0.594 5O 65 1:24 1 0.213 A BB 1267750. 889. 8OO NG 2.115 94 79 1:43 1 0.259 A BB 751365. 6O7. 894 NG 1.446 62 68 1:28 1 0.223 A BB 1013340. 819.745 NG 1.957 64 80 1:44 1 0.262 A VB 390016. 569.847 NG 1.358 84 167 3:37 1 0.548 A BB 1111510. 1010. 44O NG 2.409 43 136 2: 57 1 0. 446 A BB 295519. 760. 545 NG 1. 811O 76 142 3:05 1 0.466 A BB 3020830. 991.525 NG 2.3511 96 127 2:45 1 O. 416 A BB 904764. 856.449 NG 2.0312 63 227 4: 55 1 0. 744 A BB 2171O30. 913. 104 NG 2. 1713 96 188 4: 04 1 O. 616 A BB 1O8202O. 1005. 97O NG 2. 3914 83 32O 6:56 1 1.049 A BB 211O53O. 938.516 NG 2.2315 62 367 7:57 1 1.203 A BB 1311590. 944.172 NG 2.2416 43 296 6: 25 1 0. 970 A BB 666013. 960. 660 NG 2. 2817 97 327 7:05 2 0.800 A BB 1382140. 919.504 NG 2.1818 117 342 7:25 2 0.836 A BB 1459500. 1000.510 NG 2.3719 43 245 5: 18 2 0. 599 A BB 1952570. 1036. 890 NG 2. 462O 83 477 1O: 20 2 1.166 A BB 18O9270. 816.250 NG 1.9421 63 445 9:38 2 1.088 A BB 1471350. 833.500 NG 1.9822 75 52O 11:16 2 1.271 A BB 214839O. 1069.240 NG 2.5423 13O 426 9: 14 2 1. O42 A BB 1353O1O. 854. O12 NG 2. O324 129 623 13:30 2 1.523 A BB 1788260. 757.277 NG 1.80,25 97 590 12:47 2 1.443 A BB 1297230. 867.076 NG 2.066 78 361 7:49 2 0.883 A BB 2432270. 720.463 NG 1.7127 75 575 12:27 2 1.406 A BB 600802. 371.425 NG 0.8828 173 759 16:27 2 1.856 A BB 1570580. 784.714 NG 1.8629 43 542 11:45 3 0.803 A BB 16364OO. 862.716 NG 2.0530 43 622 13:29 3 0.921 A BB 12O1300. 894.663 NG 2.1231 164 595 12:53 3 0.881 A BB 1125050. 91O. 160 NG 2.1632 83 821 17:47 3 1.216 A BB 2O41970. 723.566 NG 1.7233 92 546 11:50 3 0.809 A BB 1761990. 825.770 NG 1.9634 112 678 14:41 3 1.004 ABB 2102280. 645. 812 NG 1.5335 106 695 15:03 3 1.030 A BV 1170030. 894.587 NG 2.1236 104 747 16:11 3 1.107 A BB 1983600. 649.043 NG 1.5437 106 708 15:20 3 1.049 A VB 2176870. 1207. 290 NG 2.8738 98 54O 11:42 3 0. 8OO A BB 219O890. 7O3. 826 NG 1.6739 95 796 17:15 3 1.179 A BB 19O6480. 690.805 NG 1.644O 65 36O 7:48 1 1. ISO A BB 117267O. 923.691 NG 2.1941 63 514 11:08 2 1.257 A BB 191985. 2204. 47O NG 5.2342 106 745 16:08 3 1.104 A BB 1519170. 798.388 NG 1.8943 146 906 19:38 3 1.342 A BV 2072290. 592.391 NG 1.4144 146 952 2O: 38 3 1.41O A BB 2019530. 602.983 NG 1.4345 146 916 19:51 3 1.357 A VB 2042530. 560.341 NG 1.3346 56 121 2:37 1 0.397 A BB 103420. 1341.300 NG 3.1847 53 192 4: 10 1 O. 63O A BB 554774. 1885. 430 NG 4. 4748 1O1 98 2: 07 1 0. 321 A BB 143OS3O. 270. 874 NG 0. 6449 85 57 1: 14 1 0. 187 A BB 937134. 912.984 NG 2. 1750 96 284 6:09 1 0.931 A BB 1147770. 982.566 NG 2.33

OGG215AR3Q7S32

RR307533

iil'ui'Mi ',/!:!::•: I. 'iM:.::i. T !!i : : ; ; i , ' i : ; i : i / ' : i ' i ; ! i . i i i : l i i n i : CM:I!iiiiur,|:i:i i! : '»'!:! T;:/ I. CK!'. IliOU M' W.\L iii'nX. !!i|'ll...d; m:' ii ii' i. !>:;ii:n:iI" i: •(• ill >,: 1, ill: '.'. n 'i I; r i, ir IKII 1;: !|i!, liKii!:i ul:i in:. I; 1; ii :l i; ,| .M'l \\\ 1,1,1 !i I;: l:! !i!

:;i TGL'jii'Nii;:pi' ';:i"!i,,:::iP!:iiM:!:i'i;i:iii:Miii:

• ii;:T'H'"'i..i;ni;:i'.i;!:!!i:h!i;:

IMO ii ii ir ii'•N 1:1 Tl:l I! I!!!"IL [I Ullilll" I..:,JOI;I iiirili; 7l"li•'Mi1 i!i!!i:iHi..,i"'p;;i;;:i [n.jjni^cii'iiiin'i

-h. iCD

cocn '

•MCO

BR307536

Gu«.-' :. : . ««ian *Upoft File: VOE1964

Data: VOE1964. TI02/05/92 18:59:OOSample: VSTDO2O, 100NG VOL STD, 5MLConds. : 51OOOOFormula: Instrument: 5100 Weight: 0.004Submitted by: Analyst: RQ Acct. No.:

AMOUNT^AREA * REF AMNT/(REF AREA * RESP FACT)Resp. fac. from Library Entry

No Name1 BROMOCHLOROMETHANE2 1, 4-DIFLUOROBEIMZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE10 CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1,2-DICHLQROETHANE16 2-BUTANONE17 1,1,1-TRICHLOROETHANE18 CARBON TETRACHLORIDE19 VINYL ACETATE2O BROMODICHLOROMETHANE21 1,2-DICHLOROPRaPANE22 CIS-1.3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1,1,2-TRICHLOROETHANE26 BENZENE27 TRANS-1,3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES38 TOLUENE-DS39 BROMOFLUOROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1,3-DICHLOROBENZENE44 1,2-DICHLOROBENZENE45 1,4-DICHLOROBENZENE46 ACROLEIN47 ACRYLONITRILE

AR3Q7537


No m/z Scan Time Ref RRT Meth Area(Hght) Amount XTot1 128 3O3 6:34 1 l.OOO A BB 176966. 25O. OOO NG 4.732 114 4OS 8: SO 2 l.OOO A BB 6369O8. 25O. OOO NG 4.733 117 674 14:36 3 1.000 A BB 563970. 250.000 NG 4.734 SO 6O 1:18 1 0.198 A BB 124744. 94.361 NG 1.795 94 75 1:37 1 0.248 A BB 101544. 88.543 NG 1.676 62 65 1:24 1 0.215 A BB 101941. 88.877 NG 1.687 64 76 1:39 1 0.251 A VB 64463. 101. 51O NG 1.928 84 16S 3:34 1 O. 545 A BB 1O4936. 1O2. 812 NG 1.949 43 128 2: 46 1 0. 422 A BB 39090. 108. 424 NG 2. 0510 76 138 2:59 1 0. 455 A BB 251064. 88.814 NG 1.6811 96 124 2:41 1 0.409 A BB 890O8. 90.806 NG 1.7212 63 224 4:51 1 0.739 A BB 199923. 90.622 NG 1.7113 96 185 4:00 1 0.611 A BB 93179. 93.366 NG 1.7714 83 319 6:55 1 1.053 A BB 190942. 91.510 NG 1.7315 62 366 7:56 1 1.208 ABB 115465. 89. 582 NG 1.6916 43 292 6: 20 1 0. 964 A BB 68026. 105. 751 NG 2. 0017 97 326 7:04 2 O. 799 A BB 109049. 88.198 NG 1.6718 117 34O 7:22 2 0.833 A BB 1O7138. 89.289 NG 1.6919 43 241 5:13 2 0.591 A BB 99331. 64.128 NG 1.2120 83 476 10:19 2 1.167 A BB 154958. 84.989 NG 1.6121 63 444 9:37 2 1.088 ABB 126537. 87. 144 NG 1.6522 75 518 11:13 2 1.270 A BB 221023. 133.731 NG 2.5323 13O 425 9:12 2 1. O42 A BB 114437. 87.813 NG 1.6624 129 622 13:29 2 1.525 A BB 151607. 78.050 NG 1.4825 97 588 12:44 2 1.441 A BB 103810. 84.355 NG 1. 6O26 78 36O 7:48 2 0.882 A BB 2474O3. 89.091 NG 1.6927 75 574 12:26 2 1.407 A BB 42142. 31.673 NG 0. 6O28 173 758 16:25 2 1.858 A BB 125941. 76.498 NG 1.4529 43 540 11:42 3 0.801 A BB 152826. 101.250 NG 1.9230 43 621 13:27 3 0.921 ABB 104132. 97. 456 NG 1.8431 164 594 12:52 3 0.881 A BB 89043. 90.523 NG 1.7132 83 82O 17:46 3 1.217 A BB 207835. 92.547 NG 1.7533 92 545 11:48 3 0.809 A BB 157887. 92.986 NG 1.7634 112 677 14:40 3 1. OQ4 A BB 23720O. 91.569 NG 1.7335 1O6 693 15:01 3 1.028 A BV 94695. 90.985 NG 1.7236 104 746 16:10 3 1. 1O7 A BB 208527. 85.743 NG 1.6237 106 706 15:18 3 1.047 A VB 254163. 177.137 NG 3.3538 98 539 11:41 3 0-8OO A BB 265694. 107.261 NG 2. O339 95 795 17:13 3 1.180 ABB 223138. 101. 604 NG 1.9240 65 358 7:45 1 1.182 A BB 117318. 99.595 NG 1.8841 63 513 11:07 2 1.257 A BB 15336. 214.083 NG 4.0542 106 743 16:06 3 1.102 A BB 132025. 87.193 NG 1.6543 146 904 19:35 3 1.341 A BV 242718. 87.192 NG 1.6544 146 95O 2O:35 3 1.409 A BB 237111. 88.966 NG 1.6845 146 914 19:48 3 1.356 A VB 255504. 88.084 NG 1.6746 56 115 2:29 1 0.380 A BB 6637. 92.772 NG 1.7547 53 186 4: O2 1 0.614 A BB 50383. 184.545 NG 3.4948 101 96 2: 05 1 0. 317 A BB 197753. 40. 348 NG 0. 7649 85 51 1:06 1 0.168 A BB 96945. 101.791 NG 1.93

1. 75

AR307538

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Quanti «tion Report File: VG'O965

Data: VOE1965.TI02/05/92 19:34:00Sample: VSTDO1O, 50NG VOL STD, 5MLConds.: 51OOOOormula: Instrument: 5100 Weight: 0. 005ubmitted by: Analyst: RQ Acct. No.:


No Name1 BROMOCHLOROMETHANE2 1,4-DIFLUOROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE10 CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1,2-DICHLOROETHANE16 2-BUTANONE17 1,1,1-TRICHLOROETHANE18 CARBON TETRACHLORIDE19 VINYL ACETATE20 BROMODICHLOROMETHANE21 1,2-DICHLOROPROPANE22 CIS-1, 3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1,1, 2-TRICHLOROETHANE26 BENZENE27 TRANS-1, 3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES38 TOLUENE-0839 BROMQFLUOROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1,3-DICHLOROBENZENE44 1,2-DICHLOROBENZENE145 1,4-DICHLOROBENZENE46 ACROLEIN47 ACRYLONITRILE

AR3075i*0 000223


No m/z Scan Time Ref RRT Meth Area(Hght) Amount XTot1 128 3O3 6:34 1 1.000 A BB 154584. 250.000 NG 7.902 114 408 8:50 2 l.OOO A BB 543334. 250.000 NG 7.903 117 674 14:36 3 1.000 A BB 494897. 250.000 NG 7.904 50 60 1:18 1 0.198 A BB 70112. 60.715 NG 1.925 94 76 1:39 1 0.251 A BB 59695. 59.588 NG 1.886 62 64 1:23 1 0.211 A BB 58422. 58.310 NG 1.847 64 76 1:39 1 0.251 A VB 37292. 67.226 NG 2.138 84 163 3:32 1 0.538 A BB 44995. 50.467 NG 1.609 43 127 2: 45 1 0. 419 A BB 24232. 76. 944 NG 2. 4310 76 138 2:59 1 0.455 A BB 116227. 47.069 NG 1.4911 96 123 2:40 1 0.406 A BB 41588. 48.571 NG 1.5412 63 224 4: 51 1 0. 739 A BB 93475. 48. 506 NG 1. 5313 96 184 3: 59 1 0. 607 A BB 41668. 47. 797 NG 1. 5114 83 318 6:53 1 1.050 A BB 81273. 44.590 NG 1.4115 62 365 7:54 1 1.205 A BB 49296. 43.783 NG 1. 3816 43 291 6:18 1 0.960 A BB 32521. 57.876 NG 1.8317 97 325 7: O2 2 0.797 A BB 52471. 49.746 NG 1.5718 117 340 7:22 2 0.833 A BB 46017. 44.955 NG 1.4219 43 241 5: 13 2 0. 591 A BB 104359. 78. 977 NG 2. 5020 83 476 1O: 19 21. 167 A BB 64545. 41. 498 NG 1. 3121 63 444 9:37 2 1.088 A BB 54756\ 44.204 NG 1.4022 75 518 11:13 2 1.270 A BB 90940. 64.500 NO 2.0423 130 425 9:12 2 1.042 A BB 5O271. 45.219 NG 1.4324 129 621 13:27 2 1.522 A BB 60394. 36.447 NG 1.1525 97 588 12:44 2 1.441 A BB 43161. 41.112NG 1.3026 78 ' 36O 7:48 2 0.882 A BB 104656. 44.178 NG 1.4027 75 574 12:26 2 1.407 A BB 16743. 14.751 NG O. 4728 173 758 16:25 2 1.858 A BB 47520. 33.835 NG 1.0729 43 540 11:42 3 0.801 ABB 63504. 47. 944 NG 1.5230 43 621 13:27 3 0.921 A BB 45757. 48.800 NG 1.5431 164 594 12: 52 3 0. 881 A BB 37469. 43. 408 NG 1. 3732 83 820 17:46 3 1.217 A BB 84323. 42.789 NG 1.3533 92 545 11:48 3 0.809 A BB 66766. 44.809 NG 1.4234 112 676 14:39 3 1.003 A BB 102954. 45.291 NG 1.4335 106 693 15:01 3 1.028 A BB 40664. 44.524 NG 1.4136 104 746 16:10 3 1.107 A BB 86665. 40.609 NG 1.2837 1O6 7O6 15:18 3 1. O47 A BB 107234. 85.167 NG 2.6938 98 539 11:41 3 O. 80O A BB 111755. 51.413 NG 1.6339 95 795 17:13 3 1.180 A BB 94653. 49.115 NG 1.5540 65 358 7:45 1 1.182 A BB 50818. 49.387 NG 1.5641 63 513 11:07 2 1.257 A BB 875. 14.318 NG 0.4542 106 743 16:06 3 1.102 A BB 55507. 41.775 NG 1.3243 146 904 19:35 3 1.341 A BV 107749. 44.109 NG 1.3944 146 95O 2O: 35 3 1.409 A BB 1O8864. 46.548 NG 1.4745 146 914 19:48 3 1.356 A VB 113577. 44.620 NG 1.4146 56 115 2:29 1 0.380 A BB 9639. 154.241 NG 4.8847 53 185 4:00 1 O. 611 A BB 23004. 96.459 NG 3.0548 101 96 2:05 1 0.317 A VB 92738. 21.661 NG 0.6849 85 50 1:05 1 0.165 A BB 50293. 60.453 NG 1.9150 96 282 6:07 1 0.931 A BB 42691. 45.091 NG 1.43

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Quantitation Report File; VOL9v*:9

Data: VOL9959.TI02/06/92 10:59:00Sample: VSTD050, 25ONG VOL STD, 5MLConds. : FINN52Formula: VOC Instrument: FINN52 Weight: 0.000Submitted by: WADS Analyst: JP Acct. No.: 68D10008

AMOUNT=AREA * REF AMNT/CREF AREA * RESP FACT)Resp. fac. from Library Entry

No Name1 BROMOCHLOROMETHANE2 1,4-DIFLUOROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE10 CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1,2-DICHLOROETHANE16 2-BUTANONE17 1,1,1-TRICHLOROETHANE18 CARBON TETRACHLORIDE19 VINYL ACETATE20 BROMODICHLOROMETHANE21 1,2-DICHLOROPROPANE22 CIS-1, 3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1,1,2-TRICHLOROETHANE26 BENZENE27 TRANS-1,3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES38 TOLUENE-D839 BROMOFLUOROBENZENE40 1, 2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1, 3-D ICHLOROBENZENE44 1, 2-DICHLOROBENZENE45 1, 4-DICHLOROBENZENE46 ACROLEIN47 ACRYLONITRILE 000228

AR3Q75l*3

No Name48 TRICHLOROFLUOROMETHANE49 DICHLORODIFLUOROMETHANE50 CIS-1,2-DICHLORQETHENE

No m/z Scan Tims Ref RRT Math Area(Hght) Amount XTot1 128 .299 6:22 1 1.000 A BB 27612. 250. OOO NG 1.892 114 4O3 S:35 2 l.OOO A BB 102103. 25O. 000 NG 1.892 117 665 14:10 3 1.000 A BE 81227. 250.000 NG 1.894 50 53 1:08 1 0.177 A BB 42861. 250.000 NG 1.895 94 70 1:29 1 0.234 A BB 54459. 250.000 NG 1.896 62 58 1:14 1 0. 194 A BV 35979. 250.000 NG 1.897 64 71 1:31 1 0.237 A BB 33674. 250.000 NG 1.898 84 157 3:21 1 0.525 A BB 37971. 250.000 NG 1.899 43 123 2:37 1 0.411 A BB 13056. 250.000 NG 1.891O 76 130 2:46 1 0.435 A BB 122788. 25O. OOO NG 1.8911 96 118 2:31 1 0.395 A BB 43197. 250.000 NG 1.8912 63 221 4:43 1 0.739 A BB 85619. 250.000 NG 1.8913 96 180 3:50 1 0. 6O2 A BB 40120. 250.000 NG 1.8914 83 315 6:43 1 1.054 A BB 97277. 250.000 NG 1.8915 62 360 7:40 1 1.204 A BV 84444. 250.000 NG 1.8916 43 289 6:09 1 0.967 A BB 19206. 25O. 000 NG 1.8917 97 322 6:52 2 0.799 A BB 84223. 250. OOO NG 1.8918 117 337 7:11 2 0.836 A BB 103581. 250.000 NG 1.8919 43 241 5:08 2 0.598 A BB 128181. 250. OOO NG 1.8920 S3 469 10:00 2 1.164 A BB 82603. 250.000 NG 1.8921 63 437 9:19 2 1.084 A BV 4O435. 250.000 NG 1.8922 75 511 10:53 2 1.268 A BV 85215. 405.000 NG 3.0623 130 420 8:57 2 1.042 A BB 41791. 250.000 NG 1.8924 129 612 13:02 2 1.519 A BB 82065. 250.000 NG 1.8925 97 580 12:21 2 1.439 A BB 32892. 250.000 NG 1.8926 78 356 7:35 2 0,883 A BB 87545. 250. OOO NG 1.8927 75 567 12:05 2 1.407 A BV 18755. 95.000 NG 0.7228 173 746 15:54 2 1.851 A BB 78689. 250.000 NG 1.8929 43 533 11:21 3 0.802 A BB 59130. 250. OOO NG 1.8930 43 613 13:04 3 0.922 A BB 43977. 250.000 NG 1.8931 164 587 12:30 3 0.883 A BB 40355. 250.000 NG 1.8932 83 807 17:12 3 1.214 A BV 63654. 250.000 NG 1.8933 91 538 11:28 3 0.809 A BV 90499. 250.000 NG 1.8934 112 667 14:13 3 1.003 A BB 76444. 250.000 NG 1.8935 106 684 14:34 3 1.029 A BB 29508. 250.000 NG 1.8936 1O4 735 15: 4O 3 1.105 A BB 78373. 250.000 NG 1.8937 106 696 14:50 3 1.047 A VB 89257. 5OO. 000 NG 3.7738 98 532 11:20 3 0. 8OO A BV 89131. 250.000 NG 1.8939 95 783 16:41 3 1.177 A BB 80209. 250.000 NG 1.8940 65 354 7:33 1 1.184 A BB 81028. 250. OOO NG 1.8941 63 507 10:48 2 1.258 A BB 4742. 250.000 NG 1.8942 106 733 15:37 3 1.102 A BB 45077. 250.000 NG 1.8943 146 89O 18:58 3 1.338 A BV 100163. 250.000 NG 1.8944 146 935 19:55 3 1, 4O6 A BB 97330. 25O. 000 NG 1.8945 146 90O 19:10 3 1.353 A V3 109847. 250. OOO NG 1.8946 56 110 2:21 1 0.368 A BB 8252. 50O. 000 NG 3.7747 53 181 3:51. 1 0.605 A BB 12515. 500.000 NG 3.7748 101 89 1:54 1 0.298 A BB 156082. 250.000 NG 1.894? 85 46 0:5? 1 0.154 A BB 41619. 250.000 NG 1.8950 96 279 5:57 1 0.933 A BB 36878. 250.000 NG 1.89

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Quantitation Report File. VQL9960

Data: VOL996O.TI02/06/92 11:42:00Sample: VSTD200, 1000NG VOL STD, 5MLonds. : FINN52ormula: VQC Instrument: FINN52 Weight: 0. 000L'.mitted by: WADS Analyst: JP Acct. No. : 68D1OOO8

AMOUNT=AREA * REF AMNT/CREF AREA * RESP FACT)Resp. fac. from Library Entry

fMo Name1 BROMOCHLOROMETHANE2 1,4-DIFLUOROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE10 CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1,2-DICHLOROETHANE ,16 2-BUTANONE17 1,1,1-TRICHLOROETHANE18 CARBON TETRACHLORIDE19 VINYL ACETATE20 BROMODICHLOROMETHANE21 1,2-DICHLOROPROPANE22 CIS-1,3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1,1,2-TRICHLOROETHANE26 BENZENE27 TRANS-1,3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLQROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLSENZENE36 STYRENE37 XYLENES38 TOLUENE-0339 BROMOFLUOROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1,S-DICHLORQBENZENE

1,2-DICHLOROBENZENE45 1,4-DICHLOROBENZENE46 ACROLEIN47 ACRYLONITRILE


No m/z Scan Tims Ref RRT Meth Area(Hght) Amount XTot1 128 301 6:25 1 1.000 A BV 27537. 250.000 NG 0.432 114 403 8:35 2 1.000 A BV 100976 25O. 000 NG 0.433 117 665 14:10 3 1.000 A BB 95361. 250.000 NG 0.434 50 54 1:09 1 O. 179 A BB 119728. 700.256 NG 1.215 94 70 1:29 1 0.233 A BB 189541. 872.487 NG 1.516 62 58 1:14 1 0.193 A BV 110478. 769.757 NG 1.337 64 72 1:32 v 1 0.239 A VB 129704. 965.570 NG 1.678 84 159 3:23 1 0.528 A BB 151192. 998.151 NG 1.729 43 129 2:45 1 0.429 A BB 52158. 1001.460 NG 1.7310 76 129 2:45 1 0.429 A BB 517427. 1056.370 NG 1.8211 96 117 2:30 1 0.389 A BB 191381. 1110.630 NG 1.9212 63 222 4:44 1 0.738 A BB 352807. 1032.980 NG 1.7813 96 181 3:51 1 0.601 A BB 160364. 10O1.990 NG 1.7314 83 317 6:45 1 1.053 A BB 423493. 1091. 33O NG 1.8815 62 361 7:41 1 1.199 A BB 375250. 1113.970 NG 1.9216 43 292 6:13 1 0.970 A BB 75421. 984.411 NG 1.7017 97 323 6:53 2 0.801 A BB 377939. 1134.350 NG 1.9618 117 338 7:12 2 0.839 A BB 485548. 1184.980 NG 2.0419 43 242 5:09 2 0.600 A BB 531384. 1047.960 NG 1.8120 83 469 10: OO 2 1.164 A BB 393598. 12O4. 53O NG 2.0821 63 437 9:19 2 1.084 A BV 185113. 1157.270 NG 2.0022 75 512 10:54 2 1.270 A BB 426174. 2048.060 NG 3.5323 130 420 8:57 2 1.042 A BB 201088. 1216.360 NG 2.1024 129 613 13:04 2 1.521 A BB 448566. 1381.740 NG 2.3825 97 580 12:21 2 1.439 A BB 158191. 1215.760 NG 2.1026 78 356 7:35 2 0.883 A BB 414922. 1198.100 NG 2.0727 75 566 12: O4 2 1.404 A BB 94569. 484.376 NG 0.8428 173 746 15:54 2 1.851 A BB 521037. 1673.830 NG 2.8929 43 534 11:2.3 3 0.803 A BB 287816. 1036.520 NG 1.7930 43 613 13:04 3 0.922 A BB 226902. 1098.700 NG 1.9031 164 587 12:30 3 0.883 A BB 215268. 1135.930 NG 1.9632 83 807 17:12 3 1.214 A BB 388202. 1298.680 NG 2.2433 91 538 11:28 3 0. 8O9 A BB 476697. 1121.680 NG 1.9334 112 667 14:13 3 1.OQ3 A BB 402754. 1121.930 NG 1.9435 1O6 684 14:34 3 1.029 A BV 156519. 1129.510 NG 1.9536 104 735 15:40 3 1.105 A BB 522720. 1420.270 NG 2.4537 106 697 14:51 3 1.048 A VB 579677. 2765,940 NG 4.773S 98 532 11:20 3 0. 8OO A BB 388646. 928.530 NG 1.6039 95 783 16:41 3 1.177 A BB 487660. 1294.680 NG 2.2340 65 355 7:34 1 1.179 A BB 331570. 1025.790 NG 1.7741 63 5O7 10:48 2 1.258 A BB 21236. 1132. 02O NG 1.9542 1O6 733 15:37 3 1.1O2 A BB 291412. 1376.640 NG 2.3743 146 890 18:58 3 1.338 A BV 681698. 1449. 29O NG 2. SO44 146 935 19: 55 3 1. 406 A BB 653058. 1428. 820 NG 2. 4645 146 900 19:10 3 1.353 A VB 759926. 1473.170 NG 2.5446 56 113 2:24 1 0.375 A BB 32583. 1979.580 NG 3.4147 53 184 3:55 1 0.611 A BB 51310. 2055.470 NG 3.5548 101 89 1:54 1 C. 296 A BB 970029. 1557.950 NG 2.6949 85 46 0:5? 1 0. 153 A BB 115572. 696. 123 NG 1.2050 96 28O 5:58 1 O. 930 A BB 153895. 1046.120 NG 1.8O

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Quantitation Report File; VOL9961

Data: VOL9961.TIO2/O6/92 12:21:00Sample: VSTD100, 500NG VOL STD, 5MLConds. : FINN52Formula: VOC Instrument: FINN52 Weight: 0. 000Submitted by: WADS Analyst: JP Acct. No.: 68D10008


No Name1 BROMOCHLOROMETHANE2 1,4-DIFLUOROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE10 CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1,2-DICHLOROETHANE16 2-BUTANONE17 1,1,1-TRICHLOROETHANEIS CARBON TETRACHLORIDE19 VINYL ACETATE20 BROMODICHLOROMETHANE21 1,2-DICHLOROPROPANE22 CIS-1,3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1,1,2-TRICHLOROETHANE26 BENZENE27 TRANS-1,3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES38 TOLUENE-DS39 BROMOFLUOROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1,3-DICHLOROBENZENE44 1,2-DICHLOROBENZENE45 1,4-DICHLOROBENZENE46 ACROLEIN47 ACR YLOIMI TR ILE

il

AR3Q75I*9


No m/'z Scan Time Ref RRT Meth Area(Hght) Amount 7.Tot1 12S 300 6:23 1 1.000 A BD 30651. 250.000 NG 0.872 114 403 8:35 2 1.000 A BB 108927. 250. OOO NO 0.873 117 665 14:10 3 1.000 A BB 100139. 250.000 NG 0.874 50 54 1:09 1 0.180 A BB 82879. 435.486 NG 1.515 94 70 1:29 1 0.233 A BB 120004. 496.271 NG 1.726 62 58 1:14 1 0.193 A BV 76211. 477.050 NG 1.667 64 71 1:31 1 0.237 A BB 80347. 537.368 NG 1.87S 84 158 3:22 1 0.527 A BB 38136. 522.743 NG 1.829 43 127 2:42 1 0.423 A BB 35446. 611.444 NG 2.1210 76 130 2:46 1 0.433 A BB 287281. 526.922 NG 1.8311 96 117 2:30 1 0.390 A BB 101716. 530.308 NG 1.8412 63 221 4:43 1 0.737 A BB 209577. 551.275 NG 1.9113 96 ISO 3:50 1 0.600 A BB 97529. 547.473 NG 1.9014 83 316 6:44 1 1.053 A BB 228993. 530.156 NG 1.8415 62 361 7:41 1 1.203 A BB 200541. 534.845 NG 1.8616 43 291 6:12 1 0.970 A BB 52628. 617.114 NG 2.1417 97 323 6: 53 2 O. 8O1 A BB 2O7774. 578. O96 NG 2. 0118 117 337 7:11 2 0.836 A BB 250188. 566.013 NG 1.9719 43 241 5:03 2 0.598 A BB 339704. 621.039 NG 2.1620 83 469 10:00 2 1.164 A BB 202OO9. 573.082 NG 1.9921 63 437 9:19 2 1.084 A BB 96677. 560.275 NG 1.9522 75 512 10: 54 2 1. 270 A BB 218520. 973. 484 NG 3. 3823 130 420 8:57 2 1.042 A BB 101475. 569.004 NG 1.9824 129 613 13:04 2 1.521 A BB 213029. 608.309 NG 2.11-25 97 581 12:23 2 1.442 A BB 83722. 596.469 NG 2.0726 78 356 7:35 2 0.883 A BB 214182. 573.315 NG 1.9927 75 567 12:05 2 1.407 A BB 47880. 227.337 NG 0.7928 173 747 15:55 2 1.854 A BB 235483. 701.272 NG 2.4429 43 534 11:23 3 0. 8O3 A BB 169005. 579.603 NG 2. Ol30 43 613 13:04 3 0.922 A BB 133777. 616.366 NG 2.1431 164 587 12:30 3 0.883 A BB 107275. 539.061 NG 1.8732 83 807 17:12 3 1.214 A BB 19374S. 617.234 NG 2.1433 91 538 11:28 3 0.809 A BB 232522. 521.028 NG 1.8134 112 667 14:13 3 1.OO.3 A BB 198919. 527.679 NG 1.8335 106 684 14:34 3 1.029 A BB 77291. 531.154 NG 1.8436 104 736 15:41 3 1.1O7 A BB 219732. 568.543 NG 1.9737 106 697 14:51 3 1.048 A VB 247726. 1125.630 NG 3.913B 98 532 11:20 3 0.800 A BB 188868. 429.704 NG 1.4939 95 783 16:41 3 1.177 A BB 203833. 515.335 NG 1.7940 65 354 7:33 1 1.180 A BB 175963. 489.076 NG 1.7041 63 508 1O: 49 2 1.261 A BB 8916. 440.605 NG 1.5342 106 733 15:37 3 1.102 A BV 126156. 567.533 NG 1.9743 146 89O 18:53 3 1.338 A BV 3O1169. 6O9. 736 NG 2.1244 146 935 19:55 3 1.406 A BB 286875. 597.703 NG 2.0845 146 901 19: 12 3 1. 355 A VB 324486. 599. 027 NG 2. 0846 56 112 2:23 1 0.373 A BB 21024. 1147.540 NG 3.9947 53 182 3:53 1 0.607 A BB 36561. 1315.810 NG 4.5748 101 39 1:54 1 0.297 A BB 481397. 694.615 NG 2.4149 85 47 1:00 1 0.157 A BB 76326. 413.025 NG 1.4350 96 279 5: 57 1 0. 930 A BB 86983. 531. 204 NG 1. 84

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Quant.-.-i •:, ion Report File: VOL9962

Data: VOL9962. TI02/06/92 12: 55: 00Sample: VSTDC20, 100NG VOL STD, 5MLConds.: FINN52ormula: VOC Instrument: FINN52 Weight: 0.000

Submitted by: WADS Analyst: JP Acct. No.: 68D10008

Ar1CL'NT=AREA * REF AMNT/(REF AREA * RESP FACT)Rssp. fac. from Library Entry

No Name1 BROMOCHLOROMETHANE2 1,4-DIFLUOROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANES METHYLENE CHLORIDE9 ACETONE10 CARBON DISULFIDE11 1, 1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1, 2-DICHLDROETHANE16 2-BUTANONE17 1,1, 1-TRICHLOROETHANE18 CARBON TETRACHLORIDE19 VINYL ACETATE20 BROMODICHLOROMETHANE21 1,2-DICHLOROPROPANE22 CIS-1,3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1,1,2-TRICHLOROETHANE26 BENZENE27 TRANS-i, 3-DICHLOROPROPENE2S BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES33 TOLUENE-DS39 BROMOFLUOROBENZENE40 1, 2-DICHLDROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1,3-DICHLOROBENZENE44 1, 2-DICHLOROEENZENE45 1, 4-DICHLOROBENZENE46 ACROLEIN47 ACRYLONITRILE

AR307552

No Name43 TRICHLOROFLUOROMETHANE49 DICHLORODIFLUOROMETHANE5O CIS-1, 2-DICHLOROETHENE

No m/z Scan Time Ref RRT Meth Area(Hght) Amount 7.Tot1 128 299 6:22 1 1.000 A BB 24552. 250. OOQ NG 3.912 114 402 8:34 2 1.000 A BB 94180. 250.000 NG 3.913 117 664 14:09 3 1.000 A BB 75361. 250.000 NG 3.914 50 55 1:10 1 0.184 A B3 18260. 119.781 NG 1.875 94 70 1:29 1 O. 234 A BB 20863. 107.713 NG 1.686 62 58 1:14 1 0.194 A BB 15261. 119.258 NG 1.867 64 72 1:32 1 0.241 A BB 13325. 111.256 NG 1.743 84 159 3:23 1 0.532 A BB 15571. 115.295 NG 1.809 43 126 2:41 1 0.421 A BB 7682. 165.424 NG 2.5810 76 132 2:49 1 0.441 A BB 43457. 99.508 NG 1.5511 96 118 2:31 1 Q. 395 A BB 17467. 113.688 NG 1.7812 63 221 4:43 1 0.739 A BB 36540. 119.992 NG 1.8713 96 ISO 3:50 1 0.602 A BB 15145. 106.134 NG 1.6614 83 315 6:43 1 1.054 A BB 40660. 117.520 NG 1.8415 62 361 7:41 1 1. 2O7 A BB 36146. 12O. 350 NG 1.8816 43 291 6:12 1 0.973 A BB 11378. 166.565 NG 2.6017 97 322 6:52 2 0.801 A BB 34268. 11O. 275 NG 1.7218 117 337 7:11 2 0.838 A BB 40391. 105.688 NG 1.6519 43 241 5: OS 2 0.600 A BB 55530. 117.415 NG 1.8320 83 469 10: OO 2 1.167 A BB 33537. 110.041 NG 1.7221 63 436 9:17 2 1.085 A BB 16611. 111.340 NG 1.7422 75 511 10:53 2 1.271 A BV 35817. 184.547 NG 2.8823 130 420 8:57 2 1.045 A BB 17315. 112.294 NG 1.7524 129 612 13:02 2 1.522 A BB 34031. 112.394 NG 1.7625 97 579 12: 2O 2 1.440 A BB' 14316. 117.963 NG 1.8426 78 356 7:35 2 0.886 A BB 35244. 109.112 NG 1.7027 75 566 12:04 2 1.408 A BB 7383. 40.544 NG 0.6328 173 746 15:54 2 1.856 A BV 34094. 117.430 NG 1.8329 43 533 11:21 3 0.803 A BB 31208. 142.219 NG 2.2230 43 612 13:02 3 0.922 A BB 23148. 141.837 NG 2.2231 164 586 12:29 3 0.883 A BV 17771. 118.661 NG 1.8532 83 807 17:12 3 1.215 A BV 28447. 120.422 NG 1.8833 91 537 11:26 3 0.809 A BB 37964. 113.039 NG 1.7734 112 667 14:13 3 1.0Q5 A BV 31738. 111.874 NG 1.7535 106 683 14:33 3 1.029 A BB 12487. 114.026 NG 1.7836 1O4 735 15:40 3 1.107 A BB 32211. 110.747 NG 1.7337 106 696 14:50 3 1.048 A W 36405. 219.807 NG 3.4338 98 531 11:19 3 0.800 A BB 29519. 89.241 NG 1.3939 95 733 16:41 3 1.179 A BV 27514. 92.432 NG 1.4440 65 353 7:31 1 1.181 A BB 28416. 98.601 NG 1.5441 63 509 10:51 2 1.266 A BB 1074. 61.381 NG 0.9642 106 732 15:36 3 1.102 A BB 17884. 106.906 NG 1.6743 146 890 IS: 58 3 1.340 A BV 39302. 1O5. 731 NG 1.6544 146 935 19:55 3 1. 4O8 A BV 4O461. 112.017 NG 1.7545 146 900 19:10 3 1.355 A VB 44562. 109.314 NG 1.7146 56 112 2:23 1 0.375 A BB 2747. 187.218 NG 2.9247 53 181 3: 51 1 0. 605 A BV 5175. 232. 510 NG 3. 6348 101 90 1:55 1 0.301 A BB 60690. 109.324 NG 1.7149 85 46 0:5? 1 0.154 A BB 16735. 113.057 NG 1.7750 96 279 5:57 1 0.933 A BV 14301. 109.027 NG 1.70

O

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AR307553

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Quantitation Report File: VOL'

Data. VOL9963. TI02/06/92 13:23:00Sample: VSTD01O, SONG VOL STD, 5MLConds. : FINN52Formula: VOC Instrument: FINN52 Weight: 0. 000Submitted by: WADS Analyst: JP Acct. No.: 68D10008

AMOUNT=AREA * REF AMNT/(REF AREA * RESP FACT)Resp, fac. from Library Entry

No Name1 BROMOCHLOROMETHANE2 1,4-DIFLUOROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE10 CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1,2-DICHLOROETHANE16 2-BUTANONE17 1,1,1-TRICHLOROETHANE18 CARBON TETRACHLORIDE19 VINYL ACETATE2O BROMODICHLOROMETHANE21 1,2-DICHLOROPROPANE22 CIS-1,3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1,1,2-TRICHLOROETHANE26 BENZENE27 TRANS-1,3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES38 TOLUENE-D839 BROMOFLUOROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1,3-DICHLOROBENZENE44 1,2-DICHLORDBENZENE45 1,4-DICHLOROBENZENE46 ACROLEIN47 ACRYLONITRILE

AR307555 000238


No m/z Scan Time Ref RRT Meth Area(Hght) Amount 7.Tot1 128 300 6:23 1 l.OOO A BB 23011. 250. OOO NG 7.212 114 403 8:35 2 l.OOO A BV 88485. 250. OOO NG 7.213 117 665 14:10 3 1.000 A BB 75591. 250, OOO NG 7.214 50 55 1:10 1 0.183 A B3 4689. 32.823 NG O. 955 94 71 1:31 1 0.237 A BB 7551. 41.595 NG 1.2O6 62 59 1:15 1 0.197 A BB 4370. 36.437 NG 1.057 64 71 1:31 1 0.237 A BB 5210. 46.414 NG 1.348 84 159 3:23 1 0. 53O A BB 5351. 42.275 NG 1.229 43 124 2:39 1 0.413 A BV 3621. 83.206 NG 2.4010 76 130 2:46 1 0.433 A BB 17267. 42.186 NG 1.2211 96 118 2:31 1 0.393 A BB 7118. 49.436 NG 1.4212 63 221 4:43 1 0.737 A BB 15228. 53.357 NG 1.5413 96 183 3:54 1 0.610 A BB 6426. 48. O49 NG 1.3814 83 316 6:44 1 1.053 A BB 19390. 59.798 NG 1.7215 62 361 7:41 1 1.203 A BB 16549. 58.793 NG 1.6916 43 29O 6:11 1 0.967 A BB 5453. 85.177 NG 2.4617 97 322 6:52 2 O. 799 A BB 16764. 57.421 NG 1.6618 117 338 7:12 2 0.839 A BB 20420. 56.871 NG 1.6419 43 24O 5:07 2 0.596 A BB 27087. 60.961 NG 1.7620 83 469 10:00 2 1.164 A BB 16641. 58.115 NG 1.6821 63 437 9:19 2 1.084 A BB 8089. 57.711 NG 1.6622 75 512 10:54 2 1.270 A BB 17694. 97.036 NG 2.8023 130 420 8:57 2 1.042 A BV 9265. 63.954 NG 1.8424 129 612 13:02 2 1.519 A BB 17495. 61.499 NG 1.7725 97 580 12:21 2 1.439 A BB 7250. 63.585 NG 1.8326 78 356 7:35 2 0.883 A BB 17159. 56.542 NG 1.6327 75 566 12:04 2 1.404 A BB 3986. 23.298 NG 0.6728 173 746 15:54 2 1.851 A BB 17297. 63.411 NG 1.8329 43 533 11:21 3 0. 8O2 A BB 15847. 71.996 NG 2. O830 43 613 13:04 3 0.922 A BB 11974. 73.148 NG 2.1131 164 587 12:30 3 0.883 A BB 9O24. 60.072 NG 1.7332 83 807 17:12 3 1.214 A BB 14451. 6O. 988 NG 1.7633 91 537 11:26 3 0.808 A BB 18672. 55.428 NG 1.6O34 112 667 14:13 3 1.0Q3 A BB 17067. 59.977 NG 1.7335 106 684 14:34 3 1.029 A BB 6267. 57.053 NG 1.6436 104 735 15: 4O 3 1.105 A BB 15877. 54.422 NG 1.5737 106 696 14: SO 3 1.047 A BB 17915. 1O7. 838 NG 3.1138 98 532 11: 2O 3 0.800 A BB 14497. 43.694 NG 1.2639 95 783 16:41 3 1.177 A BB 12520. 41.934 NG 1.2140 65 354 7:33 1 1.180 A BB 13472. 49.877 NG 1.4441 63 5O6 10:47 2 1.256 A BB 738. 44.893 NG 1.2942 106 732 15:36 3 1.101 A BB 9580. 57.096 NG 1.6543 146 89O 18:58 3 1.338 A BV 20959. 56.213 NG 1.6244 146 935 19:55 3 1. 4O6 A BV 18783. 51.842 NG 1.4945 146 900 19:10 3 1.353 A VV 23337. 57.073 NG 1.6546 56 110 2:21 1 0.367 A BB 1160. 84.375 NG 2.4347 53 182 3: 53 1 O. 6O7 A BV 1945. 93. 242 NG 2. 694S 101 89 1:54 1 0.297 A BB 23828. 45.798 NG 1.3249 85 46 0:59 1 0.153 A BV 5387. 38.830 NG 1.1250 96 279 5:57 1 0.930 A BB 6609. 53.762 NG 1.55

AR307556

"AVOLATILE CONTINUING CALIBRATION' CHECK

Lab Name : WADSWORTH/ALERT Con t rac C : 6S-D 1 -OOS5

Lab Code: WADS Case NTo.:S"3"6 SAS No.: SDG Xo.:EQB-l

Instrument 10:510000 Calibration Date: 2/06/92 Time:0903

Lab F i l e ID:VOE19SO Init. Calib. Date(s): 2/05/92 2/05/92

Heated Purge: (Y/N) N Init. Calib. Times://</?


COMPOUND

ChloromethaneBromome thaneVinvl ChlorideChloroethaneMethvlene ChlorideAce toneCarbon Disulfide1 . 1-D ichloroe thene1 , 1-D ichloroe thane1 . 2-Dichloroethene (total)Chloroform1 , 2-D ichloroe thane2-Butanone1 , 1 , 1-Tri chloroethaneCarbon Tet rachlor ideBromodi chlorome thane1.2-Dichloropropanecis-1 , 3-DichloropropeneTr i chloroe theneDibromoch lorome t hane1.1. 2-TrichloroethaneBenzenetr an s-1. 3-DichloropropeneBromof orm4-Methvl-2-Pentanone2-HexanoneTetrachloroethene1,1.2. 2-TetrachloroethaneTo lueneChlorobenzeneEthy IbenzeneStvreneXvlene ( total )

Toluene-dSBromof luorobenzene1 . 2-Dichloroethane-d4

i

RRF

111010312121000000000000000001000

101

.848

.423

.533

.824

.473

.535

.860

.304

.9-3

.410

.812

.69"

.946

.466

.456

.643

.518

.894

.472

.649

.437

.9-4

. 183

.542

.651

.467

.408

.895

.701

.010

.433

.918

.958

.055

.910

.615

I 1

JRRF50 'l

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i i.1 o.1 1.1

3202522147384085750"!25-023368-747409-8435435615496895444619408971173505645511395862691023412935590

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<lAll other compounds must meet a minimum

FORM VTT VGA 3 -'90

~AVOLATILE CONTINUING CALIBRATION CHECK

Lab Name:WADSWORTH/ALERT Con tract:6S-D1-0085

Lab Code:WADS Case Xo.:S"3~6 SAS No.: SDG No.:EQB-l

Instrument ID:FIXN52 Calibration Date: 2/06/92 Time:2319

Lab F i l e ID:VOL99SO I n i t . Calib. Date(s): 2/06/92 2/06/92

Heated Purge: (V/X) X Init. Calib. Times:


1

! COMPOUNDt _ _ _ _ ___ _ _ _1 Ch lorome thaneiBromomethane[Vinyl Chloride! ChloroethaneiMethvlene Chloride! Acetone,'Carbon Disulfide! 1 , 1-Dichloroethene! 1, 1-Dichloroethane! 1 , 2-Dichloroethene (total)! Chloroform1 1 . 2-D ichloroe thane! 2-Butanone! 1 . 1 , 1-Trichloroethane,'Carbon Te t rachloride1 Bromodi chlorome thane1 1.2-Dichloropropane! cis-1 , 3-Dichloropropene1 Tr ichloroe thene1 Dibromoch lorome thane! 1,1,2-TrichioroethaneiBenzene! trans-1 ,3-Dichloropropene1 Bromof orm! 4-Methvl-2-Pentanone! 2-HexanoneiTetrach loroethene1 1 . 1.2.2-TetrachloroethaneiToluene,'Chlorobenzene1 Ethvlbenzene! Stvrene i ...iXvlene (total )1

,'Toluene-dSiBromofluorobenzene1 1 , 2-Dichioroe t hane-d4ii

RRF

1 .3741.SS31.2111.2401.3870.6194.4021.6573.3511.48S3.891

• 3.4030.9170.9141.1180.9080.4390.9690.4710.9570.3780.9550.2121.0050.8820.6730.55"0.9341.2041.0340.3981.1100.635

0.9991 .0052.92"

1 MIX 1RRF50 1 RRF 1-._____ ' — _ 1

0.930! !1.849JO. 100!1.04310. 100!1.159! !1.202! !0.496! 13.490! !1.31610. 100!2.83910.200!1.2161 !3.49810. 200 !3. 147!0. 100!0.847! !O.SOS10. 100!1.03210. 100!0.83410.200!0.390! 10.87910.200!0.42910.300!0.89610. 100!0.35710. 100!0.83810.500!0.20210.100!0.89710. 100!0.864! !0.597! !0.501 10.200!0.87810.500!1.131 [0.400!0.947!0.500!0.367!0. 10010.9"-, '0.300!0.5-810.300!

— _ ) _ _ __, __ _ 1

1.062! !0.98210.200!2.995! 1

1 1I , _., '

1 MAX°oD ! ~,D— — — — — — i — _— _32.3!1.8125.0

13.9!25.06.5!

13.3!19.9!20.?!20.6125.015.3J25.018.3!10. 1 ! 25.07.5!25.07.6!

11. 6! 25.07.7125.08.1125.0

11.2!9.3125.08.9!25.06. 4! 25.05. 6J25. 0

12.3125.04.7J25.010. 7! 25.02.0!

11.3!10.1125.06.0125.06. 1 ! 25.0S. 4125.0-.8125.0

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1|

All other compounds must meet a minimum

FORM VII VGA ,- ''Q0

~AVOLATIi.F CONTINUING CALIBRATION CHECK

Lab Name :WADSWORTH/ALERT Con t rac t : 6S-D 1 -0085

Lab Code:WADS Case No.:S"376 SAS No.: SDG No.: EQB-1

Instrument ID:FINN52 Calibration Date: 2/0"/92 Time:121"

Lab File ID:VOL9999 Init. Calib. Date(s): 2/06/92 2/06/92

Heated Purge: (Y/N) X Init. Calib. Times: J S""" J <f/c-^~i , 3-! ~i


1

1 COMPOUND,-===--==-===============-===1 Chloromethane! Bromomethaneivinvl Chloride! ChloroethaneiMethvlene Chloride! AcetoneICarbon Disulfide! 1, 1-Dichloroethene! 1 , 1-D ichloroe thane! 1 , 2-Dichloroethene (total)'.Chloroform! 1 , 2-D ichloroe thane! 2-Butanone! 1 , 1 . 1-Trichlo roe thaneICarbon Tet rachlor ide! Bromodi chlorome thane1 1 , 2-Dichloropropane! cis-1 , 3-DichloropropeneiTrichloroetheneiDibromoch lorome thane! 1 , 1 ,2-TrichloroethaneiBenzene!trans-l,3-Dichloropropene! Bromof orm! 4-Methvl-2-Pentanone1 2-HexanoneiTetrach loroethene1 1 . 1 . 2 , 2-Tetrachloroe thane'.TolueneiChlorobenzene! Ethvlbenzene! StvreneiXvlene (total)j = = = = = = = = = = = = = = = = = = = = = = = = = = = =!To luene-dSiBromofluorobenzene! 1.2-Dichloroethane-d4!

RRF

1.3-41.SS31.2111.2401.3870.6194.4021.6573.3511.4883.8913.4030.9170.9141. 1180.9080.4390.9690.4710.9570.3780.9550.2121.0050.8820.6"30.5570.9341 .2041.0340.3981.1100.635

0.9991.0052.92-

! MIX !RRF50 1 RRF !

1.355! !1.77510. 100!1 .24510. 100!1.177!1.401! !0.423! !4.1-8! !1.40010. 100!3.25710.200!1.398! 13.63310.200!3.06210. 100!0.805! 10.82310.100!1.01510. 100!0.831 10.200!0.391! !0.87510.200!0.38610.300!0.80510.100!0.33810. 100!0.91010.500!0. 19510. 100!0.790!0.100!0.-36! !0.53S! !0.449! 0.200!0.83310.500!1.091 10.400!0.93310.500!0.35410. 100!0.93310.300!0.55410.300!

1.035! !0.961 10.200!2.9-8! !

I 1I 1

! MAXl%D 1 ~D 1

1.4!5. -',25.0!2.8125.0!5.11 !1.01 1

31.-! !5.1! 115.5125.0!2.8! 25.016.0! !6.6125.0!10.0! 25.0!12.2! !10.0125.0!9.2125.0!8.5125.0!

10.9!9.7125.0!

18.0125.0115.9125.0!10.6125.0!4. -125.0!8.0125.0!

21.4125.0!16.6! !20.1!19.4125.0!10.8125.0!9.4125.0!9.8125.0!

11 . 1! 25.0!15.9125.0!1 2. S 125.0!

-_ I M -_ 1

3.6! !4.4:25.0!1 - 1 i

i ii i

All other compounds must meet a minimum

FORM VII VGA

flR307560

Report File. VQE1980

. TI02/06/92 9. 03: 00Sample: VSTDO5O, 250NG VOL STD, 5MLConds. : 510OOOFormula: Instrument: 5100 Weight: 0.004Submitted by Analyst: RQ Acct. No. :


No Name1 BROMOCHLOROMETHANE2 1, 4-DIFLUOROBENZENE3 CHLOROBEN2ENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE1O CARBON DISULFIDE11 1 , 1 -D I CHLOROETHENE12 1, 1-DICHLOROETHANE13 1,2-DICHLOROETHENE <TOTAL>14 CHLOROFORM15 1 , 2-D I CHLOROETHANE16 2-BUTANONE17 1,1, 1-TR I CHLOROETHANE13 CARBON TETRACHLORIDE19 VINYL ACETATE2O BROMOD I CHLOROMETHANE21 1,2-DICHLOROPROPANE22 CIS-1, 3-DICHLDROPROPENE23 TR I CHLOROETHENE24 DIBROMOCHLOROMETHANE25 1, 1, 2-TR I CHLOROETHANE26 BENZENE27 TRANS-1, 3-DICHLOROPROPENE23 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES38 TOLUENE-0839 BROMOFLUOROBENZENE40 1, 2-DICHLORQETHAME-D441 2-CHLORQETHYL VINYL ETHER42 XYLENE (TOTAL)43 1, 3-D I CHLOROBENZENE44 1, 2-DICHLOROBENZENE45 1, 4-DICHLOROBEN2ENE46 ACROLEIN47 ACRYLONITRILE

AR30756I


No m/z Scan Time Ref RRT Meth AreaCHght) Amount XToti 128 303 6:34 1 l.OOO A BB 190495. 250.000 NG 1.892 114 4O8 8: 5O 2 1.000 A BB 71346O. 250.000 NG 1.893 117 674 14:36 3 l.OOO A BB 646482. 25O. 000 NG 1.894 50 59 1:17 1 0.195 A BB 251456. 250.000 NG 1.895 94 75 1:37 1 0.248 A BB 238485. 25O. 000 NG 1.896 62 63 1:22 1 0.208 A BB 231321. 250.000 NG 1.897 64 75 1:37 1 0.248 A VB 140569. 250.000 NG 1.898 84 163 3:32 1 0.538 A BB 268129. 250.000 NG 1.899 43 128 2:46 1 0.422 A BB 109463. 250.000 NG 1.8910 76 135 2:55 1 0.446 A BB 775582. 250.000 NG 1.8911 96 122 2:39 1 0.403 A BB 239513. 250.000 NG 1.8912 63 225 4:52 1 0.743 A BB 575937. 250.000 NG 1.8913 96 185 4:00 1 0.611 A BB 260688. 250,000 NG 1.8914 83 319 6:55 1 1.053 A BB 528480. 25O. 000 NG 1.8915 62 366 7:56 1 1.208 A BB 331413. 250.000 NG 1.8916 43 292 6:20 1 0.964 A VB 186317. 250.000 NG 1.8917 97 326 7:04 2 0.799 A BB 310540. 250. OOO NG 1.8918 117 341 7:23 2 0.836 A BB 310585. 250.000 NG 1.8919 43 242 5:15 2 0.593 A BB 592278. 250.000 NG 1.892O 83 476 1O: 19 2 1.167 A BB 438580. 250.000 NG 1.8921 63 444 9:37 2 1. O88 A BB 353793. 250.000 NG 1.8922 75 519 11:15 2 1.272 A BB 638585. 405.000 NG 3.0623 130 425 9:12 2 1.042 A BB 316697. 25O. 000 NG 1.8924 129 622 13:29 2 1.525 A BB 441484. 250.000 NG 1.8925 97 589 12:46 2 1.444 A BB 291417. 250.000 NG 1.8926 78 360 7:48 2 0.882 A BB 692910. 250.000 NG 1.8927 75 574 12:26 2 1.407 A BV 123617. 95.000 NG 0.7228 173 758 16:25 2 1.858 A BB 360622. 250.000 NG 1.8929 43 54O 11:42 3 0. 8O1 A VB 417035. 25O. 000 NG 1.8930 43 621 13:27 3 0.921 A BB 33O170. 250.000 NG 1.8931 164 594 12:52 3 0.881 A BB 255472. 25O. OOO NG 1.8932 83 820 17:46 3 1.217 A BB 557214. 25O. OOO NG 1.8933 92 545 11:48 3 0.809 A BB 446478. 250.000 NG 1.8934 112 677 14:40 3 1.0Q4 A BB 661216. 250.000 NG 1.8935 106 693 15: Ol 3 1.028 A BB 266396. 250.000 NG 1.8936 104 746 16:10 3 1.107 A BB 604279. 250.000 NG 1.8937 106 7O6 15:18 3 1.047 A VB 725527. 500.000 NG 3.7738 98 539 11:41 3 0.800 A BB 739816. 250.000 NG 1.8939 95 795 17:13 3 1.180 A BB 613069. 250.000 NG 1.8940 65 359 7:47 1 1.185 A BB 33726O. 250.000 NG 1.8941 63 513 11:07 2 1.257 A BB 43548. 25O. OOO NG 1.8942 106 743 16:06 3 1.102 A BB 381558. 250.000 NG 1.8943 146 903 19:34 3 1.340 A BV 646512. 250.000 NG 1.8944 146 949 20:34 3 1.408 A BB 607490. 250.000 NG 1.8945 146 914 19:48 3 1.356 A VB 668268. 250.000 NG 1.8946 56 115 2:29 1 0. 38O A BB 28597. 500.000 NG 3.7747 53 186 4: O2 i 0.614 A BB 144006. 500.000 NG 3.7748 101 94 '2:02 1 0.310 A BB 487192. 250.000 NCJ 1.8949 85 50 1:05 1 0.165 A S3 124133. 25O. 000 NG 1.8950 96 282 6:07 1 0.931 A BB 270110. 250.000 NG 1.89

flR307S62 ::;;~"

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AR307563

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Quant-, ration Report File. VOL9980

Data: VOL9980.TIO2/06/92 23:19:OOSample: VSTD05O, 250NG VOL STD, 5MLonds. : FINN52ormula: VOC Instrument: FINN52 Weight: 0.000

Submitted by: WADS Analyst: JP Acct. No.: 68D100O8

Af!OUNT=AREA * REF AMNT/CREF AREA * RESP FACT)Re = p. fac. from Library Entry

No Name1 BROMOCHLOROMETHANE2 1,4-DIFLUOROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE10 CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1,2-DICHLOROETHANE16 2-BUTANONE17 1,1,1-TRICHLOROETHANE18 CARBON TETRACHLORIDE19 VINYL ACETATE20 BROMODICHLOROMETHANE21 1,2-DICHLOROPROPANE22 CIS-1,3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1,1,2-TRICHLOROETHANE26 BENZENE27 TRANS-1, 3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES38 TOLUENE-DS39 BROMOFLUOROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1,3-DICHLOROBENZENE44 1,2-DICHLOROBENZENE45 1,4-DICHLOROBENZENE46 ACROLEIN47 ACRYLONITRILE

No Name48 TRICHLORQFLUOROMETHANE49 DICHLORODIFLUOROMETHANE50 CIS-1,2-DICHLOROETHENE

No m/z Scan Time Ref RRT Meth Area(Hght) Amount XTot1 128 300 6:23 1 l.OOO A BV 23259. 250. OOO NG 1.892 114 4O2 8:34 2 l.OOO A BB 86725. 250. OOO NG 1.893 117 664 14: O9 3 l.OOO A BB 74735. 250.000 NG 1.894 50 55 1:10 1 0.183 A VB 21631. 250.000 NG 1.895 94 70 1:29 1 0.233 A BB 43003. 250.000 NG 1.896 62 58 1:14 1 0.193 A BB 24265. 250.000 NG 1.897 64 71 1:31 1 0.237 A VB 26947. 250.000 NG 1.898 84 157 3:21 1 0.523 A BB 27946. 250.000 NG 1.899 43 125 2:40 1 0.417 A BB 11528. 250.000 NG 1.8910 76 131 2:47 1 0.437 A BB 81185. 25O. 000 NG 1.8911 96 118 2:31 1 0.393 A BB 3O616. 25O. 000 NG 1.8912 63 221 4:43 1 0.737 A BB 66026. 250.000 NG 1.8913 96 181 3:51 1 0.603 A BB 28293. 230.000 NG 1.8914 83 316 6:44 1 1.053 A BB 81369. 250.000 NG 1.8915 62 360 7:40 1 1.200 A BB 73197. 250.000 NG 1.8916 43 290 6:11 1 0.967 A BB 19700. 250.000 NG 1.8917 97 322 6: 52 2 0. 801 A BB 7O104. 25O. OOO NO 1. 8918 117 337 7:11 2 0.838 A BB 89514. 250.000 NG 1.8919 43 240 5:07 2 0.597 A BB 102083. 25O. 000 NG 1.892O 83 468 9:58 2 1.164 A BB 72325. 25O. OOO NG 1.8921 63 437 9:19 2 1.087 A BB 33848. 250.000 NG 1.8922 75 511 10:53 2 1.271 A BB 76273. 405.000 NG 3.0623 130 419 8:56 2 1.042 A BV . 37219. 250.000 NG 1.8924 129 612 13:02 2 1.522 A BB 77692. 250.000 NG 1.8925 97 579 12:20 2 1.440 A BB 30986. 250.000 NG 1.8926 78 355 7:34 2 0.883 A BB 72652. 25O. 000 NG 1.8927 75 566 12:04 2 1.408 A BV 17478. 95.000 NG 0.7228 173 746 15:54 2 1.856 A BB 77817. 250.000 NG 1. 8929 43 533 11:21 3 O. 8O3 A BB 64564. 25O. OOO NG 1.8930 43 612 13:02 3 O. 922 A BB 44639. 25O. OOO NG 1.8931 164 586 12:29 3 0.883 A BB 37441. 25O. 000 NG 1.8932 83 807 17:12 3 1.215 A BV 65612. 25O. 000 NG 1.8933 91 537 11:26 3 0.809 A BB 84505. 250.000 NG 1.8934 112 666 14:11 3 1.0Q3 A BV 70743. 250.000 NG 1.8935 106 683 14:33 3 1.029 A BB 27456. 250. OOO NG 1.8936 104 734 15:38 3 1.105 A BV 72984. 250.000 NG 1.8937 106 696 14:50 3 1.048 A BB 82068. 5OO. OOO NG 3.7738 98 532 11:20 3 0.801 A SB 79344. 250.000 NG 1.8939 95 782 16: 4O 3 1.178 A BB 73423. 250.000 NG 1.8940 65 354 7:33 1 1.180 A BB 69658. 250.000 NG 1.8941 63 506 10:47 2 1.259 A BB 4514. 250.000 NG 1.8942 106 732 15:36 3 1.102 A BV 43227. 250.000 NG 1.8943 146 889 18:56 3 1.339 A BV 93998. 250.000 NG 1.8944 146 934 19:54 3 1.407 A BB 89706. 250. OOO NG 1.8945 146 900 19:10 3 1.355 A VB 100752. 250.000 NG 1.8946 56 111 2:22 1 O. 370 A BB 6323. 5OO. OOO NG 3.7747 53 181 3:51 1 0. 6O3 A BB 10552. 5OO. OOO NG 3.7748 101 89 1:54 1 0.297 A BB 132689. 250.000 NG 1.8949 85 46 0:59 1 0.153 A BB 27107. 250.000 NG 1.8950 96 280 5:58 1 0.933 A BB 27705. 250.000 NG 1.89

AR307565 OGO-.4S

'" "'"»' Vv$wt'" •

TO O Ij'l CD 33> O X> K'l H-,

AR307566

•L.Quantitation Report File: VOL*099

Data: VOL9999.TI02/07/92 12:17:00Sample: VSTD050, 250NG VOL STD, 5MLConds.: FINN52Formula: VOC Instrument: FINN52 Weight: 0.000Submitted by: WADS Analyst: JP Acct. No. : 68D10008

AMOUNT=AREA * REF AMNT/<REF AREA * RESP FACT)Resp, fac. from Library Entry

No Name1 BROMOCHLOROMETHANE2 1,4-DIFLUOROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE1O CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1,2-DICHLOROETHANE16 2-BUTANONE17 1,1,1-TRICHLOROETHANEIS CARBON TETRACHLORIDE19 VINYL ACETATE20 BROMODICHLOROMETHANE21 1,2-DICHLOROPROPANE22 CIS-1,3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1,1,2-TRICHLORQETHANE26 BENZENE27 TRANS-1,3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES33 TOLUENE-D839 BROMOFLUOROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1. 3-DICHLOROBENZENE44 1, 2-DICHLOROBENZENE45 1, 4-DICHLOROBENZENE46 ACROLEIN47 ACRYLONITRILE

8R307567


No m/z Scan Time Ref RRT Math Area(Hght) Amount XTot1 128 300 6:23 1 l.OOO A BB 3O571. 250.000 NG 1.892 114 403 8:35 2 l.OOO A BB 114178. 25O. OOO NG 1.893 117 665 14:10 3 1.000 A BB 96397. 250.000 NG 1.894 50 54 1:0? 1 0.180 A BB 41412. 250. OOO NG 1.895 94 70 1:29 1 0.233 A BB 54274. 25O. 000 NG 1.896 62 59 1:15 1 0.197 A BB 38076. 250.000 NG 1.897 64 72 1:32 1 0.240 A VB 35982. 250.000 NG 1.89S 84 158 3:22 1 0.527 A BB 42839. 250.000 NG 1.899 43 124 2:39 1 0.413 A BB 12924. 250.000 NG 1.8910 76 131 2:47 1 0.437 A BB 127728. 250.000 NG 1.8911 96 119 2:32 1 0.397 A BB 42801. 250.000 NG 1.8912 63 221 4:43 1 0.737 A BB 99572. 250.000 NG 1.8913 96 180 3:50 1 0. 60O A BB 4273O. 25O. 000 NG 1.8914 83 316 6:44 1 1.053 A BB 111068. 25O. OOO NG 1.8915 62 361 7:41 1 1.203 A BB 93600. 250.000 NG 1.8916 43 29O 6:11 1 0.967 A BB 24624. 250.000 NG 1.8917 97 323 6:53 2 0.801 A BB 93984. 250.000 NG 1.8918 117 337 7:11 2 0.836 A BB 115914. 250.000 NG 1.8919 43 241 5:08 2 0.598 A BB 160264. 250.000 NG 1.8920 S3 469 10: OO 2 1.164 A BV 94918. 25O. 000 NG 1.8921 63 437 9:19 2 1.084 A BB 44599. 250.000 NG 1.8922 75 511 10:53 2 1.268 A BB 99897. 405.000 NG 3.0623 130 420 8:57 2 1.042 A BB 44057. 250.000 NG 1.8924 129 612 13:02 2 1.519 A BB 91922. 250.000 NG 1.895 97 580 12:21 2 1.439 A BB 38574. 250.000 NG 1.89

'26 78 356 7:35 2 0.883 A BB 103860. 250.000 NG 1.8927 75 567 12:05 2 1.407 A BB 22212. 95.000 NG 0.7228 173 746 15:54 2 1.851 A BB 90202. 250.000 NG 1.8929 43 533 11:21 3 0. 8O2 A BB 70914. 25O. 000 NG 1.8930 43 613 13:04 3 0.922 A BB 51892. 250.000 NG 1.8931 164 587 12:30 3 0.883 A BV 43316. 25O. OOO NG 1.8932 83 807 17:12 3 1.214 A BV 80272. 250.000 NG 1.8933 91 538 11:28 3 0.809 A BB 105147. 250.000 NG 1.8934 112 667 14:13 3 1.003 A BB 89903. 250.000 NG 1.8935 106 684 14:34 3 1.029 A BV 34129. 250.000 NG 1.8936 104 735 15:40 3 1.105 A BB 89912. 250.000 NG 1.8937 106 696 14:50 3 1.047 A VB 103O81. 500.000 NG 3.7738 98 532 11: 2O 3 0. 800 A BB 99758. 250.000 NG 1.8939 95 783 16:41 3 1.177 A BB 92672. 250.000 NG 1.8940 65 354 7:33 1 1.180 A BB 91026. 250. OOO NG 1.8941 63 5O7 10:48 2 1.258 A BB 6120. 250.000 NG 1.8942 106 733 15:37 3 1.102 A BV 53369. 250.000 NG 1.8943 146 890 18:58 3 1.338 A BV 123833. 250.000 NG 1.8944 146 935 19:55 3 1.406 A BB 118160. 250.000 NG 1.8945 146 900 19:10 3 1.353 A VB 133623. 250.000 NG 1.8946 56 111 2:22 1 0.370 A BB 8324. 50O. 000 NG 3.7747 53 181 3: 51 1 0. 603 A BB 16967. 500. OOO NG 3. 7748 101 89 1:54 1 0.297 A BB 153142. 250.000 NG 1.894<? 85 47 1:00 1 0.157 A BB 39474. 250.000 NG 1.8950 96 280 5:58 1 0.933 A BB 41166. 250.000 NG 1.89

000 515R307568

Mass List Data'; B'Ffc_J5i£ # 177 Base m/ : : 9502/05/92 16:50:00 + 3' 50 Cali' EFB951E # 2 RIC: 125184.Sample: SONG INJECTION OF BFBConds. : 51 0000*U76 to #178 Averaged - 4*160 XI. 00

36 0, 00 0 00 O, Minima Min inten: 0.221 » 0 Maxima

Mass y. RA ;: RIC Inten. Mass 7. RA 7. RIC Inten.

36.00? S 1.01 0.23 290. 175.00 S 5.38 1.23 1542.37.OO? S 5.64 1.29 1616. 176.00 S 71.21 16.31 20416.36.00? S 5.27 1.21 1512. 177.00 S 4.94 1.13 1416.3=?. 00? S 2.01 0.46 577. 207.00 S 0.21 0.05 60.40.00? S 0.05 0.01 14. 221.00 S 0.35 0.08 1O1.41. 00? S 0. 36 0. 08 104.43. OO? S 0. 25 0. 06 73.45.OO? S 1. O4 0.24 297.47. 00? S 2. 75 0. 63 788.48. 00? S 0. 27 0. 06 78.49. OO? S 3. 65 0. 84 1O46.50. 00? S 18. 42 4. 22 5280.51.00? S 5.50 1.26 1578.55.00? S 0.48 0.11 139.56.00? S 1.75 0.40 502.57.00? S 2.86 0.66 821.6O. OO? S 1. 1O 0.25 314.61. OO? S 2.69 0.62 771.62. 00? S 3. 33 0. 76 956.63. 00? S 2. 51 0. 57 719.67. 00? S 0. 52 0. 12 148.68.00? S 8.47 1.94 2428.69.00 S 7.66 1.75 2196.70.00 S 1.06 0.24 305.71. 00 S 0. 15 0. 03 43.72. OO S 0. 27 O. 06 76.73.0O S 5.56 1.27 1594.74.00 S 11.29 2.58 3236.75.0O S 38.56 8.83 11056.76. 00 S 3. 40 0. 78 975.77. OO S 1. 31 0. 30 377.78. 00 S 0. 55 0. 13 157.79.00 S 1.76 0.40 505.80. OO S 0. 64 0. 15 184.81. 00 S 2. O3 O. 47 583.82. 00 S 0. 64 0. 15 184.87. 00 S 5. 11 1. 17 1466.88. 00 S 5. 62 1. 29 , 1610.92. 00 S 2. 17 0. 50 623.93. 00 S 3. 25 0. 74 932.94. OO S 8. 52 1. 95 2444.95. 00 S 100. 00 22. 90 23672.96. OO S 7. 45 1. 71 2136.97. 00 S O. 52 0. 12 148.105, 00 S 0. 23 0. 05 67.119. 00 S 0. 27 0. 06 77.131. 00 S 0. 78 0. IB 225.135. 00 S 0. 51 0. 12 145.147. 00 S 0. 55 0. 13 157.174. 00 S 74. 00 16. 95 21216.

&R3Q7569

VOLATILE RAW QC DATA

SR307570

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'ass Cii-i • JA:-i . Jp -s >--*••-"• - Data: BFBS51E # 1/7I2/O3/92 16:3O:OO * 3: 5O Call: BFB831E # 2 RIC: 125184.Samp 1 e: SD*J& JXJJ&CTJonJ Of- APSConds.: 31OOOO#176 to #173 Averaged - #160 XI. 00

36 0. 00 0. 00 0. Minima Min inten: 0.221 # 0 Maxima

Mass 7. RA 7. RIC Inten. Mass X RA X RIC Inten.

S 1.01 0.23 290. 175. OO S 5.38 1.23 1542.S 5. 64 1. 29 1616. 176. 00 S 71. 21 16. 31 20416.S 5.27 1.21 1512. 177. OO S 4.94 1.13 1416.S 2. 01 0. 46 577. 2O7. 00 S 0. 21 0. 05 60.S 0. 05 0. 01 14. 221. 00 S 0. 35 0. 08 101.S 0. 37 0. 08 105.S 0. 23 0. 06 73.S 1. 04 0. 24 297.S 2. 75 O. 63 788.S 0. 27 0. 06 78.S 3. 65 0. 84 1046.S 18. 42 4. 22 528O.S 5. 30 1. 26 1578.S 0. 48 0. 11 139.S 1. 73 0. 40 502.S 2. 86 O. 66 821.S 1. 10 0. 23 314.S 2. 69 O. 62 772.S 3. 33 O. 76 956.S 2. 51 0. 57 719.S 0. 52 0. 12 148.S 8. 47 1. 94 2428.S 7. 66 1. 73 2196.S 1. 06 0. 24 303.S O. 13 0. 03 43.S 0. 27 0. 06 76.S 5. 57 1. 27 1396.S 11. 29 2. S3 3236.S 38. 36 3. 83 11036.S 3. 4O 0. 78 973.S 1. 31 0. 30 377.S 0. 55 0. 13 137.S 1. 76 0. 4O 503.S 0. 64 0. 13 184.S 2. 03 0. 47 583.S 0. 64 0. 13 184.S 5. 11 1. 17 1466.S 5. 62 1. 29 1610.S 2. 17 0. 30 623.S 3. 25 0. 74 932.S 8. 52 1. 95 2444.S 100. 00 22. 90 28672.S 7. 45 1. 71 2136.S 0. 52 0. 12 148.S O. 23 0. 03 67.S 0. 27 0. 06 77.S 0. 78 0. 18 225.S 0. 31 0. 12 145. GG0254S 0. 35 0. 13 157.S 74. 00 16. 95 21216.

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36 0. 00 0. 00 0 Minima Min inten: 0.177 # 0 Maxima

Mass 7. RA 7. RIC In ten.

36. 00? S 1. 95 0. 45 54?.37.0O? S 7.71 1.78 2168.38. 00? S 6. 75 1. 55 1S9S.39. OO? S 3. 46 0. 80 973.41.00? S 0.32 0.07 89.43, 00? S 0. 43 0. 10 120.45. 00? S 0. 76 0. 18 215.47. 00? S 2. 83 0. 65 797.46. 00? S 0. 68 0. 16 190.49. 00? S 4. 54 1. 05 1278.50. 00? S 22. 33 5. 16 6296.51.00? S 6.46 1.49 1818.55. 00? S O. 37 0. O9 105.56.00? S 1.34 0.31 376.57. 00? S 3. 04 0. 70 855.60.00? S 1.09 0.25 306.61. 00? S 3. 15 0. 73 886.62. 00? S 3. 96 0. 91 1114.63. 00? S 2. 97 0. 68 835.67.00? S O. 82 0.19 231.68. 00? S 9. 27 2. 14 2608.69. 00 S 9. 51 2. 19 2676.70. 00 S 1. 31 0. 30 368.71.00 S 0.24 0.06 68.72. 00 S 0. 28 0. 06 78.73. OO S 5. 65 1. 30 1588.74.00 S 12.86 2.96 3616.75.00 S 42.04 9.68 11824.76. 00 S 3. 74 0. 86 1O52.77. 00 S 1. SO 0. 35 423.78. 00 S 0. 25 0. 06 .70.79. 00 S 2. 22 0. 51 625.80. 00 S 0. 37 0. 09 104.81. 00 S 2. 37 0. 55 668.82. 00 S 0. 91 0. 21 256.87. 00 S 4. 86 1. 12 1368.88.OO S 5.46 1.26 1536.92. OO S 2. 14 0. 49 6O3.<93. OO S 3. 51 0. 81 987.94. 00 S 8. 86 2. 04 2492.95. OO S 100. 00 23. 03 28128.96. 00 S 7. 44 1. 71 2092.97. 00 S O. 25 0. 06 71.174. OO S 64.62 14. SS 18176.175.00 S 4.72 1.09 1328.176. OO S 60. 30 13 89 1696O.177.00 S 4.24 0.98 1194.

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36 0.00 0.00 0. Minima Min inten: 0239 # C Maxima

Mass % RA ". RIC Inten. Mass f. RA 7. RIC Inten.

36.00? S 2.15 0.39 256. 123.00 S 0.05 0.01 6.37. 00? S 17. 27 3. 12 2056. 125. 00 S 0. 04 0. 01 5.38. 00? S 13. 00 2. 35 1548. 128. 00 S 0. 29 0. 05 35.39. 00? S 2. 47 0. 45 294. 129. 00 S 0. 29 0. 05 35.47. 00? S 0. 17 0. 03 20. 130. 00 S 0. 30 0, 05 36.48. 00? S 1. 74 0. 31 2O7. 131. OO S 0. 12 0. 02 14.49.00? S 10.08 1.82 1200. 132.00 S 0.05 0.01 6.50. 00? S 38. 51 a. 97 4584. 133. 00 S 0. 06 0. 01 7.51. 00? S 10. 47 1. 89 1246. 135. 00 S 0. 15 0. 03 18.52. 00? S 0. 20 0. 04 24. 137. 00 S 0. 3O 0. 05 36.54. 00? S 0. 08 0. 01 9. 140. 00 S 0. 06 0. 01 7.55. 00? S 0. 29 0. 05 35. 141. 00 S 1. 88 0. 34 224.56. 00? S 2. 17 0. 39 258. 142. 00 S 0. 23 0. 04 27.57. OO? S 5. 5O 1. 00 655. 143. 00 S 2. 04 0. 37 243.60.00? S 0.15 0.03 18. 145.00 S 0.13 0.02 15.61. OO? S 6.49 1.17 772. 146. OO S 0.46 0.08 55.62.00? S 7.83 1.42 932. 147.00 S 0.18 0.03 22.63. 00? S 6. 00 1. 09 714. 148. 00 S O. 22 0. 04 26.64. 00? S 0. 42 0. 08 50. 149. 00 S 0. 13 0. 02 15.67.00? S 0.23 0.04 27. 153.00 S 0.10 0.02 12.68. 00? S 16. 28 2. 95 1938. 154. 00 S 0. 05 0. 01 6.69.00 S 14.97 2.71 1782. 155.00 S 0.23 0.04 27.70. OO S 1.16 0.21 138. 159.00 S 0.06 0.01 7.73.00 S 1.10 0.20 131. 161.00 S 0.09 0.02 11.74. 00 S 23. 89 4. 32 2844. 165. 00 S 0. 05 0. 01 6.75. 00 S 39: 72 7. 19 4728. 171. 00 S 0. 06 0. 01 7.76. 00 S 4. 05 0. 73 482. 173. 00 S 0. 55 0. 10 66.78. 00 S 0. 50 0. 09 60. 174. 00 S 72. 72 13. 16 3656.79.00 S 9.07 1.64 1080. 175.00 S 5.54 1.00 660.80.00 S 3.03 0.55 361. 176.00 S 71.10 12.86 3464.SI. 00 S 9.26 1.67 11.02. 177.00 S 5.21 0.94 620.32. 00 S 1. 97 0. 36 235. 178. 00 S 0. OS 0. 02 10.33. 00 S 0. 17 0. 03 20. 184. 00 S 0. 06 0. 01 7.37.00 S 2.31 0.42 275. 190.00 S 0. O5 O. 01 6.88. 00 S 2. 29 0. 41 273. 193. 00 S 0. 08 0. 02 10.92. 00 S 4. 19 0. 76 499. 207. 00 S 0. 24 0. 04 23.93.00 S 6.18 1.12 736. 212.00 S 0.05 0.01 6.94.00 S 15.37 2.78 1830. 221.00 S 0.10 0.02 12.95.00 S 100.00 13.09 11904. 239.00 S 0.04 0.01 5.96. 00 S 6. 56 1. 19 781.97. 00 S 0. 16 0. 03 19.101. 00 S 0. 05 0. 01 6.102. 00 S 0. 04 0. 01 5.111. 00 S 0. 14 0. 03 17113. 00 S 0. 10 0. 02 12.115. 00 S 0. 13 0. 02 15.116. 00 S 0. 53 0. 10 63.117. 00 S 0. 93 0. 13 117i 13. 00 S 0. 53 0. 10 63.119. OO S O. S9 0. 16 106.

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36 0.00 0,00 0 Minima Min inten: s.237 # Q Maxima

Mass 7. RA 7. RIC Inten. Mass '/. RA '/. RIC Inten.

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57.00- S 5.40 0.90 465. 138.00 S 0. OS 0.01 7.62.00- S 4.10 0.69 353. 139. OO S O. 15 O. 03 13.63.00- S 5.36 0.90 461. 141.00 S 2.28 0.38 196.64. OO- S 0.33 0.05 28. 142.00 S 0.09 0.02 8.67.00- S 0.36 0.06 31. 143.00 S 2.18 0.37 188.66.OO- S 15.57 2.60 1340. 144.00 S 0.07 0.01 6.69. 00 S ' 16. 08 2. 69 1384. 145. 00 S 0. 12 0. 02 10.70.00 S 1.67 0.28 144. 147.00 S 0.21 0.03 18.72.00 S 0.39 0.07 34. 148.00 S 0.19 0.03 16.73.00 S 5.03 0.84 433. 149.00 S 0.14 0.02 12.74.00 S 25.19 4.21 2168. 150.00 S 0.13 0. O2 11.75. 00 S 60. 69 10. 15 5224. 152. 00 S 0. 07 0. 01 6.76.00 S 4.53 0.76 390. . 153.00 S 0.07 0.01 6.78.00 S 0.53 0.09 46. 155.00 S 0.14 0.02 12.79.00 S 10.44 1.75 899. 157.00 S 0.23 0.04 20.80. OO S 3.61 0.60 311. 159.00 S 0.07 0.01 6.SI. 00 S 10.49 1.75 9O3. 161.00 S 0.07 0.01 6.82. 00 S 2. 74 0. 46 236. 165. 00 S 0. 09 0. 02 8.83.00 S 0.15 0.03 ,13. 169.00 S 0.07 0.01 6.85. OO S 0.08 0.01 7. 172. OO S 0. OS 0.01 7.36. 00 S 0. 21 0. 03 IS. 173. 00 S 0, 55 0. 09 47.87. OO S 3.09 0.52 266. 174.00 S 85.13 14.24 7328.88. OO S 2. 2O 0. 37 189. 175. 00 S 5. 79 0. 97 498.93.00 S 2.76 0.46 238. 176.00 S 83.92 14.04 7224.94.OO S 15.47 2.59 1332. 177.00 S 6.33 1.06 545.95.00 S 100.00 16.73 8608. 181.00 S 0.08 0.01 7.96.00 S 7.60 1.27 654. 182.00 S 0.08 0.01 7.97. 00 S, 0. 22 0. 04 19. 185. 00 S 0. 12 0. 02 10.99.00 S 0.16 0.03 14. 187.00 S 0.19 0.03 16.100. 00 S 0. 07 0. 01 6. 223. 00 S 0. 07 0. 01 6.104. OO S 0. 30 0. 05 26. 224. 00 S 0. 07 0. 01 6.106. 00 S 0. 28 0. 05 24. 225. 00 S 0. 07 0. 01 6.107. OO S 0. 29 0. O5 25.108. 00 S 0. 14 0, 02 12.111. 00 S 0. 26 0. 04 22.112.00 S 0.21 0.03 18.113. 00 S 0. 07 0. 01 6.114.00 S 0.07 0.01 6.

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36 0.00 0.00 0. Minima Min inten:238 # 0 Maxima

Mass 7. RA 7, RIC Inten. Mass 7. RA

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VBLK1Lab Name:WADSWORTH/ALERT Concract:6S-D1-OOS5

Lab Code:WADS Case No.:S~3~6 " SA'S Xo. : SDG Xo.:EQB-l

Matrix: (soil/water) WATER Lab Sample ID:VBLK1

Sample wt/vol: 5.00 (g/ml) ML Lab Fi l e ID: VOE196'

Level: (low/med) LOW Date Received: / /



Soil Extract Volume: 0.00 (uL) Soil Aliquot Volume: O.OOtuL

CONCENTRATION UNITS:CAS XO. COMPOUND (ug/L or ug/Kg) UG/L_ Q

74-87-3---------Chloromethane74-83-9---------Bromometnane75-01-4--- ———— Vinyl Chloride75-00-3---------Chloroethane75-09-2 ———————Methyl e.ne Chlor i.de_67-64-1---------Ace tone75-1 5-0- — - —-—Carbon Pisu1f ide'5-35-4---------I,1-Pi chlor o e t hener5-34-3 ——————— 1. l-Dichloroethane_540-59-0---—---1,2-Dichloroechene (total6T-66-3- — - — —^Chloroform107-06-2 —— ——— -1. 2-D ichloroe thane73-93-3 ————— — 2-Butanone______________71-55-6---------1,1.1-Trichloroethane56-23-5---------Carbon Tetrachloride'5-2 "-4---------Brorno_dJ_g..hlorprne t han e_' S-87-5 ---------i,2-Pich Ipropropane10061-01-5- —- —cis-1.3-DichIoropropene79-01-6-------- -Trichloroe t_he_n.e _.._____124-43-1------—Dibr o mochloromethane"79-00-5-— —— ——1.1.2 - Tr i_c h 1 o r o e t *ian e_7 1-4.3 -2------ ---Benzene . . .1006 1-02-6-----,- tr_ans- 1 , 3-D i ch lor opropene"5-25-2--------Bromoform _______.108-10-1--- —— --4-Me Lb yj[-J -Pen t a none

2-Hex_a.none1 2"-18-4--------Te trachloroethene'9-34-5--------!.,.! , 2 . 2-Te t rach loroe t hane108-88-3 —— ———— Toluene _ .__.10S-90-"- ———— -Chlorobenzene.100-41-4 —— —— — Ethyl be n z_e.ne_100-42-5--———-Stvrene1330-20-"———-—Xvlene (total)

10 . I U10 . ! U10 . I U10 . ! U10. ! U

1 0 . ! U10. ! U10 . ! Ui 0 . ! U10. ! U10. !U_10 . i U10. ;y_i o. i u10.; u1010. iu_10.! ui o.! u1010.; ui o.: ui o. i u10. I U10. ! u10 . ! u10. I U10 . ! L*10. ! u10. ! u10.: u

SR3G7586I VGA H n w U / w U U .1 /QO

TENTATIVELY IDENTIFIED COMPOUNDSVBLkl


Lab Code:WADS Case No.:S~3~6 SAS No.: SDG No.:EQB-l

Matrix: (soil/water) WATER Lab Sample ID:V3LKi

Sample wt/vol: 5.00 (g/ml) ML Lab F i l e ID: VOE196~


ljo Moisture: not dec. 0 Date Analyzed: 2/05/92

GC Column:DB624 ID: 0.53 (mm) D i l u t i o n Factor: 1.00

Soil Extract Volume: 0.00 (uL) Soil Aliquot Volume: O.OCXuL


CAS NUMBER

1 .•>t-m *

3.4 _5 .6.7

8.9 <10.11 .12.13.14.15.16.17.18.19.20.21.2 ~>23.24.25.26.T "7

28.29.30.

COMPOUND NAME RT EXT . CONC . Q

————— i———— \

1

Ill

'•> -.--

FORM I VOA-TIC H R U / U U I ;,/9QAR3Q7587

s *

Si

CO -_.« Gjl-ft. ®Si

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-J CO••KiSi

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000 70flR307588

. u.ar- •" r.a r: on " L p.', .- '• •: '. : " VU'r,: "*O • ; . .

Data: VOE1967. TI02/05/92 20:44:00Sample: VBLK1, 5MLConds.: 510000Formula: Instrument: 5100 Weight: 0.004Submitted by: Analyst: RQ Acct. No.:

AMOUNT=AREA # REF AUNT/(REF AREA * RESP FACT)Resp. fac. from Library Entry

No Name1 BROMOCHLOROMETHANE2 1,4-DIFLUOROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE10 CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1,2-DIC HLOROETHANE16 2-BUTANONE17 Ii1,1-TRICHLOROETHANE18 CARBON TETRACHLORIDE19 VINYL ACETATE20 BROMODICHLOROMETHANE21 1,2-DICHLOROPROPANE22 CIS-l,3-DICHLOROPROPENE23 TRIC HLOROETHENE24 DIBROMOCHLOROMETHANE25 1, 1, 2-TRICHLOROETHANE26 BENZENE27 TRANS-1, 3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2,2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES38 TOLUENE-D839 BROMOFLUOROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1,3-DICHLOROBENZENE44 1,2-DICHLOROBENZENE45 1,4-DICHLOROBENZENE46 ACROLEIN47 ACRYLONITRILE OOO,

flR307589

No Name , .48 TRICHLOROFLUORQMETHANE49 DICHLORODIFLUOROMETHANE50 CIS-1,2-DICHLOROETHENE

No m/z Scan Time Ref RRT Meth Area(Hght) Amount X.Tot1 128 3O3 6:34 1 1.000 A BB 132404. 250.000 NG 15.942 114 408 8: 5O 2 l.OOO A BB 475635. 250.000 NG 15.943 117 674 14:36 3 1.000 A BB 432154. 250.000 NG 15.944 NOT FOUND5 NOT FOUND6 NOT FOUND7 NOT FOUND8 NOT FOUND9 43 127 2:45 1 0.419 A BB 8486. 31.459 NG 2.0110 NOT FOUND11 NOT FOUND12 NOT FOUND13 NOT FOUND14 NOT FOUND L>15 NOT FOUND } jf^16 43 292 6:20 1 0.964 A BB 8891. pB 473 NG 1. 1817 NOT FOUND18 NOT FOUND19 43 241 5: 13 2 0. 591 A BB 671. 0. 580 NG O. 042O NOT FOUND21 NOT FOUND22 NOT FOUND23 NOT FOUND24 NOT FOUND25 NOT FOUND26 NOT FOUND27 NOT FOUND ,.;L28 NOT FOUND29 43 54O 11:42 3 0. SOI A BB 13711. 1/11/854 NG O. 7630 43 621 13:27 3 0-921 A BB 9184. U ii. 217 NG 0.7131 NOT FOUND32 83 82O 17:46 3 1.217 A BB 3186. 1.851 NG 0.1233 NOT FOUND34 112 676 14:39 3 1.003 A BB 554. 0.279 NG 0.0235 NOT FOUND36 NOT FOUND37 106 7O6 15:18 3 1.047 A BB 965. O. 878 NG O. 0638 98 539 11:41 3 0. SOO A BB 493125. 259.798 NG 16.5639 95 795 17:13 3 1.1SO A BB 402450. 239.149 NG 15.2440 65 358 7:45 1 1.182 A BB 210671. 239.036 NG 15.2441 NOT FOUND42 NOT FOUND43 146 904 19:35 3 1.341 A BB 3087. 1.447 NG 0.0944 146 95O 2O:35 3 1.4O9 A BB 2122. 1.039 NG 0. O745 146 914 19:48 3 1.356 A BB 4091. 1.841 NG 0.1246 NOT FOUND47 NOT FOUND48 NOT FOUND49 NOT FOUND50 NOT FOUND

•?

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VOLATILE ORvJ... ' •- - " J,^S I 0. ••.•"> .-. 5i.£ET

VBLK2Lab N'ame : WADSWORTH/ALERT Con t rac t : 6S-D i-0035

Lab Code:WADS Case N'o.:S~3~6 SAS No.: SDG N'o.:EQB-l



Level: (Low/med) LOW Date Received: / /


GC Column:DB624 ID: 0.53 (mm) . D i l u t i o n Factor: 1.00

Soil Extract Volume: 0.00 (uL) Soil Aliquot Volume: O. O O t u L

CONCENTRATION UNITS:CAS NO. COMPOUND 1ug/L or ug/Kg) UG/L_ Q

74-ST-3---------Chloromethane'4-S3-9---------Bromomethane75-01-4 —— ———— Vinyl Chloride75-00-3- — ————Chloroethane'5-09-2 ———— --—Methvlene Chloride67-64- i---------Acetone75-15-0- ——————Carbon Disulfide75-35-4---------1.1-Dichloroethene'5-34-3-- — — ——1,1-Dichloroethane540-59-0——————1. 2-D ichloroe thene (total67-66-3 ——————Chloroform1Q7-Q6-2-————--1.2-Dichloroethaner8-93-3— - —— - — 2-Butanone71-55-6---------1 . 1 , 1-Trichloroetha n e_56-23-5---------Carbon Tet rachloride75-2"-4---------Bromodichlorome thane'8-S"-5---------l , 2-D ic_h loropropanel006l-Ol-5------cis-l.3-Dichloropropene79-OI-6---------Trichloroethene124-48-1--------Dibromochloromethane79-00-5--- ——— —1.1,2-Tric h1 or oethanel-43-2---------Benzene

lOQ61-02-6------trans-i.3-Dichloropropene'5-25-2---------Bromoform

_i08-10-1 — — - —— 4-Me t hvj 2.z£e_n t anone59i-"S-6-- ———— -2-Hexanone ______!2"-lS-4--------Tetrachloroethene'9-34-5-- ——— — -1 . 1... 2 ,2-TetrachloroethaneIPS-S3-3-----——Toluene108-90-"-———---ChlorobenzenelOO-4l-4--------Ethylbenzene100-42-5----—--Stvrene1330-20-" — -- —— Xvlene_ ( t a t a 1.)

t.10 . | U10 . ! U10. ! U10 . ! U10 . I U10. ! U1010 . ! U10. ! u10. ! U10 . ! U10 . ! U10 . ! U10 . ! U10 . ! U10 . ! U10.; u10. |u_i o.; ui o. i u10.! u10. ILL10.! u10.; u10. i u10 . ! U10 . ! u10. ! U10.; u10. |u_ro. : u10.; u10

OOOiVo

QR307593

VOLATILE ORGAN'1 CSAN-.LYS.iS DATA an;TENTATIVELY IDENTIFIED COMPOUNDS

VBLK2Lab Name : WADSWORTH/ALERT Con t ra.ct : 6S-D1-OOS5

Lab Code:WADS Case N"o.:S"3"6 SAS No.: SDG No.:EQE-l



Level: (low/met!) LOW Date Received: / /



Soil Extract Volume: 0.00 (uL ) Soil A l i q u o t Volume: O . O O f u L

CONCENTRAT I ON UN ITS:Number TICs Found: 0 (ug/L or ug/Kg) UG/L_

CAS NUMBER

1 .2.3 .4 .5 .6.—8.9.10.11 .i i1 mm* •

13.14.15.16.1".18.19.20.21 .•> •)23.24.25.26.•> -28.29.30.

COMPOUND NAME

_

RT EXT. CONC. 0

OOOiTS

FORM , VOA-T,r fl R 3 0 7 5 9 I*

-S- fO.. ,£>tO '3'3

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fiR307595

O Om m• • CC' '*. Si I/ •" -• —

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Data: VQE19S2. TI02/06/92 10.25:00Sample: VBLK2, 5l"iLConds. : 510000Formula: Instrument: 5100 Weight: 0,004Submitted by: Analyst: RQ Acct. No. •

AMOUNT=AREA * REF AMNT/(P£F AREA * RESP FACT)Rssp. fac from Library Entry

No Name1 BRQMOCHLQRGMETHANE2 1, 4-DIFLUQRDBENZENE3 CHLOROEEN2ENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE1O CARBON DISULFIDE11 1, 1-DICHLOROETHENE12 1, 1-DICHLOROETHANE13 1, 2-DICHLQROETHENE (TOTAL)14 CHLOROFORM15 1, 2-DICHLOROETHANE16 2-BUTANONE17 1, 1, 1-TRICHLOROETHANE18 CARBON TETRACHLQRIDE19 VINYL ACETATE2O BROMODICHLOROMETHANE21 1,2-DICHLQROPROPANE22 CIS-1,3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1,1,2-TRICHLORQETHANE26 BENZENE'27 TRANS-1, 3-DICHLQROPRaPENE28 BRQMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLQROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES33 TOLUENE-0839 BROMOFLUOROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLORCETHYL VINYL ETHER42 XYLENE (TOTAL)&3 1,3-DICHLOROSENZENE•14 1, 2-DICHLORQBENZENE45 1,4-DICHLQROBENZENE46 ACROLEIN47 ACRYLONITRILE

SR307596

Me Name " v' "" " • • •'43 TRICHLOROFLUOROMETHANE4? DICHLORODIFLUOROMETHANE50 CIS-1,2-DICHLOROETHENE

No m/z Scan Time Ref RRT Meth Area(Hght) Amount XToti 128 303 6:34 1 1.000 A EB 155305. 250.000 NG 16,822 114 403 8:50 2 1,000 A BB 553521, 250.000 NG 16.323 117 675 14:37 3 1.000 A BB 494477. 250.000 NG 16,824 NOT FOUND5 NOT FOUND6 NOT FOUND7 NOT FOUNDS NOT FOUND9 NOT FOUND10 NOT FOUND11 NOT FOUND12 NOT FOUND13 NOT FOUND14 NOT FOUND15 NOT FOUND16 43 292 6:20 1 0.964 A BB 5089. 8.376 NG 0.5617 NOT FOUNDIS NOT FOUND19 NOT FOUND20 NOT FOUND21 NOT FOUND22 NOT FOUND23 NOT FOUND24 NOT FOUND25 NOT FOUND26 NOT FOUND27 NOT FOUND23 NOT FOUND29 43 540 11:42 3 0. SOO A BB 5695. 4,463 NG 0.3030 NOT FOUND31 NOT FOUND32 NOT FOUND33 NOT FOUND34 NOT FOUND35 NOT FOUND36 NOT FOUND37 NOT FOUND33 98 539 11.41 3 0.799 A BB 563094. 248.776 NG 16.7439 95 796 17:15 3 1.179 A BB ,453184. 241.611 NG 16.2540 65 35S 7:45 1 1.132 A BB 256623. 233.329 NG 15.7041 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND45 NOT FOUND46 NOT FOUND47 NOT FOUND43 NOT FOUND4? NOT POUND50 NOT FOUND

<l

00"V_> A. f

8R3Q7S97

A.V/.LVS I S ' DATA SHEET

VBLK3Lab Name:WADSWORTH/ALERT Contract:68-D1-0085


Matrix: (soil/water) WATER Lab Sample ID:V3LK3







4-8"-3---------Chloromethane74-S3-9---------Bromomethane75-01-4---------Vinyl Chloride'5-00-3————--Chloroethane•5-09-2--———--Methvlene Chloride67-64-1---------Acetone75-15-0---------Carbon Pisu1f ide'5-35-4--- - - --— 1 , 1-Dichloroethene"5-34-3--------- 1 ,1-Dichloroethane540-59-0--------1.2-Dichloroethene (total )67-66-3---------Chloroform10"-06-2 — — --—1.2-Dichloroethane78-93-3- ———— - — 2-Butanone71-55-6--------- 1 , 1 , 1-Trichloroethane56-23-5---------Carbon Tetrachloride75-27-4---------Bromodichloromethane8-S7-5--------- I ,2-D i ch i oropropane10061-0 1-5----- r ij_ LjjLrJLL?jQj-P L 0£!_o_p.e ner9-01-6--- — —.—Trichloroethene124-4S- 1--------Di b r omochIorome thane'9-00-5- —— — —— 1, 1 .2-Trichloroethane1-43-2 ---------B e nzene

10061-02-6------t r an s- 1.3-Dichloropropene5-25-2---------Bromoform10S-10-1--————4-Methyl-2-Pentanone591-"S-6--------2-Hexanone12"-IS-4- — — — -Tetrachloroethene9-34-5 — - —— -—1,1,2 . 2-Tetrachloroethane10S-8S-3- ——— —-Toluene __.._..__„10S-90-"--- -.- -.- -Ch loroben z. e n. e__100-41-4--------Ethv'benzene100-42-5 — -- — --_3 U"re_n_e _1330-20------——Xvlene ( t o t a l )

10. ! U10. 1 U10. ! U10. ! U10. I U10 . ! U10, ! u10 . i U10. ! u10. ! u10. U10. ! u10. ! u10. !U_10. i U10,1010. |y_10. I Ui o.; u10. ! u10. ! u10. ! u10 . ! U10. ! u10. ! u10.; u10. ! u10. U10. ;y_10.: uio.it:10.; u

OGG^SO

AR307598FORM I VOA M n O U / J U 3/00

'VOLATILE ORGANIC a ......i. s D.VFA SHEETTENTATIVELY IDENTIFIED COMPOUNDS

VBLK3Lab Name : WADSWORTH/ALERT Con t rac t : 68-D 1 -OOS5

Lab Code:WADS Case No.:S~3~<5 SAS No.: SDG No.:EQB-l




°J Moisture: not dec. 0 Date Analyzed: 2/0~/92


Soil Extract Volume: 0.00 ( uL ) Soil Aliquot Volume: O . O O t u L

CONCENTRAT I ON UN ITS:Number TICs Found: 0 ( ug/L or ug/Kg) UG/L_

CAS NUMBER

1 .2.3 .4 .5 .6.-

8.9.10.11 .12.13.14.15 .16.1".18.19.20 .21 .22 .23 .24.25.26.-> -28.29 .30.

COMPOUND NAME

,

RT EXT. CONC. Q :

——— 21)— II;

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l

1

1

1

OOOiSI

AR307599

<lFORM I VOA-TIC H U U U f v/ 3/00

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flR307600

. .- r r. •- . ,- . . . , - , , . .... .

Data: VOL9981, TI02/07/92 l-21'OOSample: VBLK.3, 5MLConds. : FINN52Formula: VOC Instrument: FINN52 Weight: 0. 000Submitted by WADS Analyst: JP Acct. No. : 68D10008

A?10UNT-AREA * REF AMNT/CREF AREA * RESP FACT)Resp. fac. from Library Entry

No Name1 BROMOCHLOROMETHANE2 1,4-DIFLUOROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE10 CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLORQETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1,2-DICHLOROETHANE16 2-BUTANONE17 1,1, 1-TRICHLOROETHANE18 CARBON TETRACHLORIDE19 VINYL ACETATE20 BROMODICHLQROMETHANE21 1,2-DICHLOROPROPANE22 CIS-1,3-DICHLORQPRQPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1,1,2-TRICHLOROETHANE26 BENZENE27 TRANS-1/3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANQNE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES38 TOLUENE-D339 BROMOFLUOROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLORCETHYL VINYL ETHER42 XYLENE (TOTAL)43 1,3-DICHLGROEENZENE44 1, 2-DICHLQROBENZEN'E45 1, 4-DICHLQRQBENZENE40 ACROLEIN47 ACRYLDNITRILE

OGOA-3J

AR30760I

N o Name . • . . . , _ - - . • r48 TRICHLGROFLUOROMETHANE49 DICHLORODIFLUOROMETHANE50 CIS-1,2-DICHLOROETHENE

m/z Scan Time Ref RRT Meth Area(Hght) Amount 7.Tot128 299 6:22 1 1,000 A BB 22668. 250.000 NG 16.81114 403 3:35 2 1.000 A BB 79363. 250. OOO NG 16.81117 664 14:09 3 1.000 A BB 62091. 25O. QOO NG 16.81NOT FOUNDNOT FOUND

6 NOT FOUND7 NOT FOUND3 NOT FOUND9 43 123 2: 44 1 0. 428 A VB 242. 5. 385 NG 0. 3610 NOT FOUND11 NOT FOUND12 NOT FOUND13 NOT FOUND14 NOT FOUND15 NOT FOUND16 43 291 6: 12 1 0. 973 A BB 272. 3. 542 NG 0. 2417 NOT FOUND18 NOT FOUND19 NOT FOUND2O NOT FOUND21 NOT FOUND22 NOT FOUND23 NOT FOUND24 NOT FOUND25 NOT FOUND26 NOT FOUND27 NOT FOUND23 NOT FOUND29 43 533 11:21 3 0.803 A BB 1366. 6.366 NG 0.4330 43 612 13:02 3 0.922 A BB 36. 0.243 NG 0.0231 NOT FOUND32 NOT FOUND33 91 539 11:29 3 0.812 A BB 72. 0.256 NG 0.0234 112 668 14:14 3 1. OQ6 A BB 63. 0.268 NG 0.0235 NOT FOUND36 NOT FOUND37 NOT FOUND33 93 532 1 1: 2O 3 O. 801 A BB 67402. 255.618 NG 17. 1939 95 782 16:40 3 1.178 A BV 58023. 237.793 NG 15.9940 65 354 7:33 1 1.134 A BB 61929. 228. O55 NG 15.3341 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND45 NOT FOUND46 NOT FOUND47 NOT FOUND43 101 92 1:53 1 0.308 A BB 41. 0.079 NG 0.0149 NOT FOUNDSO NOT FOUND

ftR307602

i .A • •

\u!.tA'. r.Lt ORG-AMCS ANALYSIS DATA SHEET

VBLK4Lab Name:WADSWORTH/ALERT Con tract:6S-D1-0085

Lab Code:WADS Case No.:8"3~6 SAS No.: SDG No.:EQB-l


Sample wt/vol: 5.00 (g/ml! ML Lab F i l e ID: VOL1001




Soil Extract Volume: 0.00 (uL) Soil Aliquot Volume: 0.00(uL


"4-87-3—-—-——Chloromethane'4-83-9---------Bromomethane•5-01-4---------Vinvl Chloride75-00-3 — --————Chloroe t hane"5-09-2-————--Methvlene Chloride67-64-1---------Ace tone75-15-0-——————Carbon Disulfide'5-35-4————--1.1-Dichloroethene75-34-3------——1 , l-Dichloroet_hane540-59-0—---—-1,2-Dichioroethene (total)67-66-3---------Chlorofo rm1Q7-Q6-2--------1,2-Dichloroethane"8-93-3 — - — — —2-Butanone' 1-55-6---------1.1,1-Trichloroe thane56-23-5---------Carbon Tetrachlor ide'5-2"-4---------BromodichloromethaneS-S"-5---------l,2-Dichloropropane10061-0l-5------cis-l.3-Dichloropropene'9-01-6 ———— —— -Tr ichloroe thene124-48-1--------Dibromochloromethane'9-00-5-- — ————1.1.2-Trichloroethane1-43-2—-—--—Benzene

10061-02-6------trans-l,3-Dichloropropene'5-25-2---------BromoForm108-10-1 — ——— — 4-Methyl-2-Pentanone591-"S-6--——--2-Hexanone12"-IS-4--------Tetrachloroethem'9-34-5-------—1.1.2.2-Tetrachloroethane108-88-3 -- ——— —Toluene108-90-"--————-Chlorobenzene100-11-4---- — --Ethyl benzene100--12-5- -------Stvrene1330-20-~- ————Xvl e ne _(,t o t a 1 )

1010101010101010101010,101010101010101010101010101010.10101010101010

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VOLAi'iLt ORGANICS A.V.-.LVS 1 S DATA Sil'.r"-. .':_____TENTATIVELY IDENTIFIED COMPOUNDS

! VBLK4Lab Name:WADSWORTH/ALERT Contract:6S-D1-0085 i ___

Lab Code:WADS Case No. :8~3~6 SAS No.: SDG No.:EQB-l

M a t r i x : (soil/water) WATER Lab Sample ID:VBLK4

Sample wt/vol: 5.00 (g/ml) ML Lab F i l e ID: VOL1001


% Moisture:" not dec. 0 Date Analyzed: 2/0~/92




CAS NUMBER

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Data: VOL1001 TI02/07/92 13: 34: 00Sample: VBLK4, 5MLConds. : FINN52Formula: VOC Instrument: FINN52 Weight: 0. 000Submitted by WADS Analyst: JP Acct. No.. 68D10008

AnOUNT=AR£A * REF AMNT/CREF AREA * RESP FACT)Resp. fac. from Library Entry

No Name1 BROMOCHLOROMETHANE2 1, 4-DIFLUQROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE10 CARBON DISULFIDE11 1, 1-DICHLOROETHENE12 1, 1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1, 2-DICHLOROETHANE16 2-BUTANONE17 1,1, 1-TR ICHLOROETHANE13 CARBON TETRACHLORIDE19 VINYL ACETATE20 BROMOD I CHLOROMETHANE21 1,2-DICHLOROPROPANE22 CIS-1, 3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1, 1, 2-TR I CHLOROETHANE26 BENZENE27 TRANS-1, 3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES33 TOLUENE-D839 BROMOFLUOROBENZENE4O 1, 2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1, 3-DICHLOROBENZENE44 1, 2-DICHLOROBENZENE45 i, 4-DICHLOROBENZENE46 ACROLEIN47 ACRYLONITRILE :' VV

AR3Q7606

No Name48 TRICHLOROFLUOROMETHANE49 DICHLOR.ODIFLUOROMETHANE50 CIS-1,2-DICHLOROETHENE

No m/z Scan Time Ref RRT Meth Area(Hght) Amount ".Tot1 128 299 6:22 1 1.000 A BV 27672. 250,000 NG 17,022 114 4O2 8:34 2 1.000 A BB 107432. 25O. OOQ NG 17.023 117 664 14.09 3 1,000 A BB 8505O. 250,000 NG 17.024 NOT FOUND5 NOT FOUND6 NOT FOUND7 NOT FOUND8 NOT FOUND9 43 131 2:47 1 0.438 A BB 138. 2.949 NG 0.2010 NOT FOUND11 NOT FOUND12 NOT FOUND13 NOT FOUND14 NOT FOUND15 NOT FOUND16 43 291 6: 12 1 0. 973 A BB 277. 3. 107 NG 0. 2117 NOT FOUND18 NOT FOUND19 NOT FOUND20 NOT FOUND21 NOT FOUND22 NOT FOUND23 NOT FOUND24 NOT FOUND25 NOT FOUND26 NOT FOUND27 NOT FOUND28 NOT FOUND29 43 532 11:20 3 0.301 A BB 1284. 5.131 NG 0.353O NOT FOUND31 NOT FOUND32 NOT FOUND33 NOT FOUND34 NOT FOUND35 NOT FOUND36 NOT FOUND37 NOT FOUND3S 98 532 11:2O 3 0.801 A BB SS278. 250.746 NG 17.0739 95 783 16:41 3 1.179 A BB 76642. 234.339 NG 15.9540 65 353 7:31 1 1.181 A BB 73444. 222.841 NG 15.1741 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND45 NOT FOUND46 NOT FOUND47 NOT FOUND43 NOT FOUND49 NOT FOUND50 NOT FOUND

AR307607

..VHLE ORGAN ICS ANALYSIS DATA SHEL

MW21AWMSLab Name:WADSWORTH/ALERT " Contract:68-D1-0085

Lab Code:WADS Case No.:S"3'6 SAS No.: SDG No.:EQB-l

Matrix: (soil/water) WATER Lab Sample 10:42764





Soil Extract Volume: 0.00 (uL) Soil Aliquot Volume: O.OOfuL


•4-87-3--—-----Chloromethane74-83-9---------Bromomethane75-01-4——------Vinyl Chloride75-00-3 — - ————Chloroethane75-09-2-——————Methylene Chloride67-64-l---------Acetone'5-15-0--- — ----Carbon Pisu1f ide75-35-4 ————— -—1 , 1-D ichloroe thene75-34-3---------1 ,1-Dichloroethane540-59-0 —— — ——1,2-Dichloroethene (total67-66-3---------Chloroform107-06-2--————i,2-Dichloroethane78-93-3- —— ——— 2-Butanon.e71-55-6 —— -————1.1, 1-Tr ichloroe thane56-23-5-----—--Carbon Tetrachloride75-27-4---------Bromodich1oromethane78-S7-5---------1,2-Dichloropropane10061-01-5 — ----cis-1.3-Dich1o ropropene79-01-6 ——————Tr ichloroe thene124-48-l--------Dibromochloromethane79-00-5-——————1.1,2-Tr ichloroe thane1-43-2------—-Benzene

10061-02-6——-—trans-1.3-Dichloropropene.75-25-2———————Bromoform _____108-10-1 —————— 4-Methy 1-2-Pentanone591-"8-6 ————— — 2-Hexanon e____________12"-l8-4--------Tetrachloroethene79-34-5---- — ---1 ,1,2.2-Tetrachloroe thane108-88-3 ——— ——--Toluene_____108-90-"-———•-—:Chloro b_enz e n_e_100-41-4 ——— -—Ethyl b e n z e n e_.100-42-5--------Stvrene1330-20-" ————— Xylene ( tqtaj ) . . _____

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Data: VOL999O. TI02/07/92 6: 24: 00Sample: 42764101, MWZ1AWMS, 3. 5ML/5MLConds.: FINN52Formula: VOC Instrument: FINN52 Weight: 0.000Submitted by: WADS Analyst: JP Acct. No.: 68D10008

AMOUNT=AREA * REF AMNT/(REF AREA * RE3P FACT)Resp. fac. from Library Entry

No Name1 BROMOCHLOROMETHANE2 1,4-DIFLUOROBENZENE3 CHLOROBENZENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACETONE10 CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE (TOTAL)14 CHLOROFORM15 1, 2-DICHLOROETHANE16 2-BUTANONE17 1,1, 1-TRICHLOROETHANE18 CARBON TETRACHLORIDE19 VINYL ACETATE20 BROMODICHLOROMETHANE21 1,2-DICHLOROPROPANE22 CIS-1,3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1,1,2-TRICHLOROETHANE26 BENZENE27 TRANS-1,3-DICHLOROPROPENE28 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES38 TOLUENE-0839 BROMOFLUOROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLOROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1,3-DICHLOROBENZENE44 1,2-DrCHLQRCEENZENE45 1,4-DICHLOROBENZENE46 ACROLEIN47 ACRYLONITRILE . , „,

flR3076IO

43 TRICHLOROFLUOROMETHANE "~r" "49 DICHLORODIFLUOROMETHANE50 CIS-1,2-DICHLOROETHENE

No m/z Scan Time Ref RRT Meth Area(Hght) Amount X.Tot1 128 299 6:22 1 1.000 A BV 22408. 250.000 NG 7.502 114 403 8:35 2 1.000 A BB 80761. 250,000 NG 7.503 117 664 14:09 3 1.000 A BV 70932. 250.000 NG 7.504 NOT FOUND5 NOT FOUND6 NOT FOUND7 NOT FOUND8 NOT FOUND9 NOT FOUND10 NOT FOUND11 96 118 2:31 1 0.395 A BB 34094. 288.972 NG 8.6712 63 222 4:44 1 0.742 A BB . 1625. 6.387 NG 0. 1913 NOT FOUND14 NOT FOUND15 62 360 7:40 1 1.204 A VB 172. 0.610 NG 0.0216 43 294 6:16 1 0.983 A BB 138. 1.818 NG 0.0517 97 322 6: 52 2 0. 799 A BB 120066. 459. 789 NG 13. 7918 NOT FOUND19 43 244 5:12 2 0.605 A BB 86. 0.226 NG 0.0120 NOT FOUND21 NOT FOUND22 NOT FOUND23 130 419 8: 56 2 1, O4O A BV 76957. 555. 094 NG 16. 6524 NOT FOUND25 97 58O 12:21 2 1.439 A BB 143. 1.239 NG 0.0426 78 355 7:34 2 0.881 A BB 54648. 201.936 NG 6.0627 NOT FOUND28 NOT FOUND29 43 532 11:20 3 0.801 A BV 1269. 5.177 NG 0.1630 NOT FOUND31 164 588 12:32 3 0.886 A BB 41. 0.288 NG 0.0132 NOT FOUND33 91 537 11:26 3 0.809 A BB 61735. 192.429 NG 5.7734 112 667 14:13 3 1.OO5 A BB 53930. 200. 8O2 NG 6. O235 NOT FOUND36 NOT FOUND37 NOT FOUND38 98 532 11:20 3 0.801 A BB 69658. 231.249 NG 6.9339 95 783 16:41 3 1.179 A BV 60493. 217.015 NG 6.5140 65 354 7:33 1 1.184 A BV 58621. 218.382 NG 6.5541 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND45 146 900 19:10 3 1.355 A BB 57. 0.149 NG 0.0046 NOT FOUND47 NOT FOUND48 NOT FOUND49 NOT FOUND50 96 279 5: 57 1 0. 933 A BB 366. " 3. 428 NG 0. 10

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MW21AWMSDLab Name:WADSWORTH/ALERT Contract:68-D1-0085 __._____.___


Matrix: (soil/water) WATER Lab Sample ID:42~64



% Moisture: not dec. 0 Date Analyzed: 2/0~/92

GC Column:DB624 ID: 0.53 (mm) Dilu t i o n Factor: 1.43

Soil Extract Volume: 0.00 (uL) - Soil Aliquot Volume: O.OO(uL)

CONCENTRATION UN ITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L_ .Q

74-87-3---------Chloromethane74-83-9- ——-----Bromome thane75-01-4-- ——— —— Vinvl Chloride75-00-3-—------Chloroethaner5-09-2 —— ------Methvlene Chlpr ide67-64-1 — -------Acetone75-15-0———————Carbon Disulfide75-35-4----——--1,1-Dichloroethene"5-34-3-- — - — —1,1-Dichloroethane540-59-0 —————— 1.2-Dichloroethene ( total67-66-3---------C hi proform107-06-2- —— — —1.2-Dichloroethane8-93-3 — ————— -2-Butanone

' 1-55-6---------1,1,1-Trichloroethane56-23-5---------Carbon Tetrachlorider5-2"-4—----—-Bromodichloromethane' 3-87-5---------1,2-D i ch1o r o p ropane10061-01-5------cis-1. 3-Dichloropropene79-01-6————-—Tr ichloroe thene124-48-l--------Dibromochloromethane79-OQ-5---- — ---1, 1,2-Trichloroethane7 1-43-2---------Ben z ene10061-02-6—-—-trans-1.3-Dichloropropene'5-25-2---------Bromoform08-10-1 ———— — 4-.Methvl-2-Pentanone591-"S-6 ——— ——— 2-Hexanone127-18-4 — ------Tet'ra ch J p. r .oe_t_h e n e_________79-34-5---------1,1 .2,2-Tet rachloroethane108-3S-3 ——————TolueneIPS-90-"——————Ch 1 Q,rp_b e n_z ene.__100-41-4- ———— — Ethyl benzene100-42-5- ——— —— Stvrene1330-20-"——----Xylene (total)

141414141 46114

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No Name1 BROMOCHLOROMETHANE2 1,4-DIFLUOROBENZENE3 CHLOROBEN2ENE-D54 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANES METHYLENE CHLORIDE9 ACETONE10 CARBON DISULFIDE11 1,1-DICHLOROETHENE12 1,1-DICHLOROETHANE13 1,2-DICHLOROETHENE <TOTAL)14 CHLOROFORM15 1,2-DICHLOROETHANE16 2-BUTANONE17 1,1,1-TRICHLOROETHANE18 CARBON TETRACHLORIDE19 VINYL ACETATE20 BROMODICHLOROMETHANE21 1,2-DICHLOROPROPANE22 CIS-1>3-DICHLOROPROPENE23 TRICHLOROETHENE24 DIBROMOCHLOROMETHANE25 1, 1, 2-TRICHLOROETHANE26 BENZENE27 TRANS-1, 3-DICHLOROPROPENE29 BROMOFORM29 4-METHYL-2-PENTANONE30 2-HEXANONE31 TETRACHLOROETHENE32 1,1,2, 2-TETRACHLOROETHANE33 TOLUENE34 CHLOROBENZENE35 ETHYLBENZENE36 STYRENE37 XYLENES3S TOLUENE-DS39 BROMOFLUOROBENZENE40 1,2-DICHLOROETHANE-D441 2-CHLDROETHYL VINYL ETHER42 XYLENE (TOTAL)43 1,3-DICHLOROBENZENE44 1,2-DICHLOR03ENZENE45 1,4-DICHLOROBENZENE46 ACROLEIN47 ACRYLONITRILE

AR3076IU

' «i •.•••No Name48 TRICHLOROFLUOROMETHANE49 DICHLORODIFLUOROMETHANE50 CIS-1,2-DICHLQRQETHENE

No m/z Scan Time Ref RRT Meth Area(Hght) Amount %Tot1 128 299 6:22 1 1.000 A BB 20710. 250.000 NG 6.612 114 403 8:35 2 1.000 A BV 78595. 250.000 NG 6.613 117 664 14:09 3 1.000 A BB 67191. 250.000 NG 6.614 50 53 1:03 10 177 A BB 37. 0.480 NG 0.015 NOT FOUND6 NOT FOUND7 NOT FOUND3 84 157 3:21 1 O. 525 A BB 71. 0.713 NG 0.029 43 125 2:40 1 0.418 A BV 8788. 214.032 NG 5.6510 76 130 2: 46 1 0. 435 A BB 48. 0. 166 NG 0. 0011 96 118 2:31 1 0.395 A BB 38354. 351.729 NG 9.2912 63 220 4:41 1 0.736 A BB 1503. 6.391 NG 0.1713 NOT FOUND14 NOT FOUND15 NOT FOUND16 43 290 6: 11 1 0. 97O A BB 2O5. 2.922 NG 0.0817 97 322 6:52 2 O. 799 A BB 121151. 476.728 NG 12.60IS NOT FOUND19 43 232 4: 57 2 0. 576 A BB 128. 0. 346 NG 0. 012O NOT FOUND21 63 435 9:16 2 1.079 A BB 34. 0.277 NG 0.0122 NOT FOUND23 13O 419 3:56 2 1.04O A BB 80314. 595.277 NG 15.7324 NOT FOUND25 97 578 12:19 2 1.434 A BB 95. 0.846 NG 0.0226 78 355 7: 34 2 0. 881 A BB 62468. 237. 193 NG 6. 2727 NOT FOUND28 NOT FOUND29 43 532 11:20 3 0.301 A BB 2046. 8.812 NG 0.2330 43 611 13:01 3 0.920 A BB 59. 0.368 NG 0.0131 164 586 12:29 3 0.883 A BB 168. 1.248 NG 0.0332 NOT FOUND33 91 537 11:26 3 0.809 A BB 68732. 226.165 NG 5.9834 112 666 14:11 3 1.0Q3 A BB 60291. 236.986 NG 6.2635 NOT FOUND36 NOT FOUND37 NOT FOUND38 98 532 11:20 3 0.801 A BS -.8777. 241.036 NG 6.3739 95 782 16:40 3 1.178 A BB 56766. 214.983 NG 5.6840 65 353 7:31 1 1.181 A BB 53821. 216.937 NG 5.7341 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND45 NOT FOUND46 NOT FOUND47 NOT FOUND48 NOT FOUND49 NOT FOUND50 96 280 5: 58 1 0. 936 A BB 158. 1. 601 NG 0. 04

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(Signature)/'Cooler/Safe/Other

SvAtrShipper No.

YES N01 ) Were custody seals on the outside of the coder?...................-.....-................;......................... Q CD

If YES, how many and where? Quantity | Location _____ •<l/ i> _________Were signature and date correct?...........................................-........................................... L_] CH

2) Were custody papers included inside the cooler?...................™,.................................-............ -0 M

3) Were custody papers properly filled out (ink, signed, match labels)?........................................ -___" __]

4) Did you sign the custody papers in the appropriate place?..........-............................................ -c-r I — I

5) Shipper's packing slip attached to this form?.............................. _ ........................................... ~~td I — I

6) Was packing material used?....................................................-... _ ........................................... -S- I — IIf YES, what type? ______________ x -i d-frl-JO _______

7) Were samples chilled?.............................................................-.......— ......IT............................... CU (U

8) Were all the bottles sealed in separate plastic bags?....................— ......................................... — Q- LJ

9) Did all bottles arrive in good condition (unbroken)?................. ........ ........ ................................. -Q- LJ

10) Were all bottle labels complete (No., date, signed, analysis, preservatives)?.........-............. ~~Q- LJ

1 1 ) Did all bottle labels and tags agree with custody papers?....... ................................................ -Q- Q

12) Were correct bottles used for the tests indicated?......— ..——...—— ................ ...... .............. • LJ - LJ

1 3) Were all VOA bottles checked for the presence of air bubbles?—— .......... ....... .................... -Q- L_

1 4) Was a sufficient amount of sample sent in each bottle?......... ................................................. '"Q LJ

15) Sample received by Fed Ex/UPS/Ciient drop-off /Other _________________

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Paul C. Rizzo Associates, Inc.SIGti

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