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THIRD EDITION FORENSIC SCIENCE An Introduction RICHARD SAFERSTEIN Taken from: Forensic Science: An Introduction, Second Edition Forensic Science: From the Crime Scene to the Crime Lab, Third Edition Criminalistics: An Introduction to Forensic Science, Eleventh Edition by Richard Saferstein

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THIRD EDITION

FORENSIC SCIENCE An Introduction

RICHARD SAFERSTEIN

Taken from:

Forensic Science: An Introduction, Second Edition

Forensic Science: From the Crime Scene to the Crime Lab, Third Edition

Criminalistics: An Introduction to Forensic Science, Eleventh Editionby Richard Saferstein

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ISBN 10: 1-269-92520-2 (HS Binding)ISBN 13: 978-1-269-92520-4 (HS Binding) PearsonSchool.com/Advanced

Cover Art: Courtesy of Photodisc/Getty Images.

Taken from:Forensic Science: An Introduction, Second Editionby Richard SafersteinCopyright © 2011 by Pearson Education, Inc.Published by Pearson Prentice HallUpper Saddle River, New Jersey 07458

Forensic Science: From the Crime Scene to the Crime Lab, Third Editionby Richard SafersteinCopyright © 2015 by Pearson Education, Inc.Published by Pearson Education, Inc.Upper Saddle River, New Jersey 07458

Criminalistics: An Introduction to Forensic Science, Eleventh Editionby Richard SafersteinCopyright © 2014 by Pearson Education, Inc.Published by Pearson Education, Inc.Upper Saddle River, New Jersey 07458

Copyright © 2016 by Pearson, Inc.All rights reserved.

This copyright covers material written expressly for this volume by the editor/s as well as the compilation itself. It does not cover the individual selections herein that first appeared elsewhere. Permission to reprint these has been obtained by Pearson Learning Solutions for this edition only. Further reproduction by any means, electronic or mechanical, including photocopying and recording, or by any information storage or retrieval system, must be arranged with the individual copyright holders noted.

All trademarks, service marks, registered trademarks, and registered service marks are the property of their respective owners and are used herein for identification purposes only.

Pearson, Inc., 501 Boylston Street, Suite 900, Boston, MA 02116A Pearson Education Companywww.pearsoned.com

Printed in the United States of America

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To my wife, Gail, pillar of my life

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ContentsPreface . . . . . . . . . . . . . . . . . . . . . . . . . xiAcknowledgments . . . . . . . . . . . . . . . . xiiAbout the Author . . . . . . . . . . . . . . . . .xiii

Handbook of Forensic Services—FBI . . xivNext Generation Science Standards

Overview . . . . . . . . . . . . . . . . . . . . . xv

˜Chapter 1

Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Definition and Scope of Forensic Science . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4History and Development of Forensic Science . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6Crime Laboratories . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14The Functions of the Forensic Scientist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24Exploring Forensic Science on the Internet. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44Endnotes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45

˜Chapter 2

The Crime Scene. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46Physical Evidence and the Crime Scene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48Preserving and Recording the Crime Scene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49Dealing with Physical Evidence . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56Ensuring Crime-Scene Safety. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70Quick Lab: Crime-Scene Sketch . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75

˜Chapter 3

Physical Evidence. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76Common Types of Physical Evidence . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 78The Examination of Physical Evidence. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80The Significance of Physical Evidence . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85Forensic Databases . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101Endnotes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103

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˜Chapter 4

Death Investigation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .104Role of the Forensic Pathologist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 106Role of the Forensic Anthropologist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 123Role of the Forensic Entomologist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 136Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 140

˜Chapter 5

Properties of Matter and the Analysis of Glass . . . . . . . . . . . . . . . . . . . . . . . . . . . . .142

Properties of Matter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144The Nature of Matter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147Theory of Light . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 152Physical Properties of Matter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 156Forensic Analysis of Glass . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 176Quick Lab: Glass and Density . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 177Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 178Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 180Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 182Endnotes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183

˜Chapter 6

Drugs. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .184Drug Dependence . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 187Types of Drugs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191Drug-Control Laws . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208Forensic Drug Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 211Collection and Preservation of Drug Evidence . . . . . . . . . . . . . . . . . . . . . . . . . . 233

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 234Quick Lab: Chromatography . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 235Quick Lab: Drug Screening Test . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 236Quick Lab: What Is the White Powder? . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 237Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 238Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 240Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 242Endnotes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 243

Contents v

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Chapter 7

Forensic Toxicology . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .244The Role of Forensic Toxicology . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 246Toxicology of Alcohol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 247Testing for Intoxication . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 253The Analysis of Blood for Alcohol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 261Alcohol and the Law . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 263The Role of the Toxicologist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 266

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 282Quick Lab: pH Test. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 283Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 284Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 286Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 288Endnotes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 291

˜Chapter 8

The Microscope . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .292Basics of the Microscope. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 294The Compound Microscope. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 296The Comparison Microscope . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 299The Stereoscopic Microscope . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 301The Polarizing Microscope . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 303The Microspectrophotometer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 304The Scanning Electron Microscope (SEM) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 307

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 314Quick Lab: Focusing the Microscope . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 315Quick Lab: Creating Wet-Mount Slides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 316Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 317Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 319Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 320

˜Chapter 9

Forensic Serology. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .322The Nature of Blood . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 325Immunoassay Techniques . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 329Forensic Characterization of Bloodstains . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 333Principles of Heredity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 338Forensic Characterization of Semen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 342Collection of Rape Evidence . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 346

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 352Quick Lab: Blood Typing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 353Quick Lab: Luminol Test . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 354Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 355Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 357Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 360Endnotes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 361

vi Contents

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˜Chapter 10

DNA: The Indispensable Forensic Science Tool . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .362

Understanding DNA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 364Replication of DNA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 369DNA Typing with Tandem Repeats . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 374Polymerase Chain Reaction (PCR) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 382Short Tandem Repeats (STRs) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 384Mitochondrial DNA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 392The Combined DNA Index System (CODIS) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 395Collection and Preservation of Biological Evidence for DNA Analysis . . . . . . . . 395

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 404Quick Lab: Buccal Swab . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 406Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 408Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 408Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 412Endnotes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 413

˜Chapter 11

Crime-Scene Reconstruction: Bloodstain Pattern Analysis . . . . . . . . . . . . . .414

Crime-Scene Reconstruction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 416General Features of Bloodstain Formation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 419Impact Bloodstain Spatter Patterns . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 423More Bloodstain Spatter Patterns. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 427Other Bloodstain Patterns. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 432

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 442Quick Lab: Blood Drop Analysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 444Quick Lab: Blood Spatter Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 445Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 446Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 449Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 450

˜Chapter 12

Trace Evidence I: Hairs and Fibers. . . .454Forensic Examination of Hair. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 456Forensic Examination of Fibers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 467

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 482Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 483Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 485Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 488Endnotes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 489

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˜Chapter 13

Trace Evidence II: Metals, Paint, and Soil . . . . . . . . . . . . . . . . . . . . . . . . . .490

Forensic Analysis of Trace Elements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 492Forensic Examination of Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 501Forensic Analysis of Soil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 513

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 522Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 523Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 524Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 525Endnotes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 527

˜Chapter 14

Forensic Aspects of Fire Investigation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .528

Forensic Investigation of Arson. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 530The Chemistry of Fire . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 530Searching the Fire Scene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 540Collection and Preservation of Arson Evidence . . . . . . . . . . . . . . . . . . . . . . . . . 543Analysis of Flammable Residues . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 545

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 550Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 551Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 553Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 555Endnotes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 557

Chapter 15

Forensic Investigation of Explosions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .558

Explosions and Explosives. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 560Collection and Analysis of Evidence of Explosives . . . . . . . . . . . . . . . . . . . . . . . 568

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 576Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 577Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 579Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 580Endnote . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 581

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˜Chapter 16

Fingerprints . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .582History of Fingerprinting. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 584Fundamental Principles of Fingerprints. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 587Classification of Fingerprints. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 593Automated Fingerprint Identification Systems . . . . . . . . . . . . . . . . . . . . . . . . . . 594Methods of Detecting Fingerprints. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 599Preservation of Developed Prints . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 607Digital Imaging for Fingerprint Enhancement . . . . . . . . . . . . . . . . . . . . . . . . . . . 609

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 612Quick Lab: Fingerprinting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 613Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 614Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 616Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 618Endnotes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 619

˜Chapter 17

Firearms, Tool Marks, and Other Impressions . . . . . . . . . . . . . . . . . . . . . . . . .620

Bullet and Cartridge Comparisons . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 622Automated Firearms Search Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 631Gunpowder Residues . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 635Primer Residues on the Hands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 639Serial Number Restoration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 645Collection and Preservation of Firearms Evidence . . . . . . . . . . . . . . . . . . . . . . . 646Tool Marks. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 648Other Impressions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 651

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 660Quick Lab: Toolmarks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 661Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 662Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 664Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 665Endnotes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 669

˜Chapter 18

Document Examination . . . . . . . . . . . . . . . . . . . . . . . .670The Document Examiner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 672Handwriting Comparisons . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 672Typescript Comparisons . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 679Alterations, Erasures, and Obliterations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 681Other Document Problems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 688

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 692Quick Lab: Handwriting Comparison . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 693Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 694

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Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 696Laboratory Experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 697Endnotes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 699

˜Chapter 19

Computer Forensics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .700From Input to Output: How Does the Computer Work? . . . . . . . . . . . . . . . . . . 703Putting It All Together . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 706Storing and Retrieving Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 707Processing the Electronic Crime Scene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 710Analysis of Electronic Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 715Forensic Analysis of Internet Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 722Forensic Investigation of Internet Communications . . . . . . . . . . . . . . . . . . . . . . 725

Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 730Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 732Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 734Endnotes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 735

˜Chapter 20

Mobile Device Forensics . . . . . . . . . . . . . . . . . . . . . .736The Mobile Device Neighborhood: What Makes a Mobile Device “Mobile”? . . . . 738Forensic Challenges: Mobile Devices as Small Computers—Sort Of . . . . . . . . . . . 740Extracting Useful Data: The Differences in Various Types of Mobile Devices . . . . . . . 743Mobile Device Architecture: What Is Inside the Device and What Is It

Used For?. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 745Analyzing Mobile Devices: Finding Forensically Valuable Artifacts . . . . . . . . . . . . 747Hybrid Crime Assessment: Fitting the Mobile Device into the Digital

Forensic Investigation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 749Chapter Review. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 752Review Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 753Application and Critical Thinking. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 755Further References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 755

˜Chapter 21

Careers in Forensic Science . . . . . . . . . . . . . . . .756Disciplines in Forensic Science. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 758College Courses in Forensic Science . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 763

Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 767Photo Credits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 786

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Preface xi

PrefaceThe level of sophistication that forensic science has brought to criminal investigations is awesome. But one cannot lose sight of the fact that, once all the drama of a forensic science case is put aside, what remains is an academic subject emphasizing science and technology. It is to this end that this third edition of Forensic Science: An Introduction is dedicated.

This high school edition follows the tradition, philosophy, and objectives of my introductory college text, Criminalistics: An Introduction to Forensic Science, which is in its eleventh edition. In creating this introductory text, every chapter of the college text was examined to improve the clarity of the narrative. This improvement has been accomplished by presenting the science of forensics in a straightforward and student-friendly format. Topics have been rearranged to better integrate scientific methodology with actual forensic application. The reader is offered the option of delving into the more difficult technical aspects of the book by going into the “Inside the Science” features in some chapters, an option that can be bypassed without detracting from a basic comprehension of the subject of forensic science.

Only the most relevant scientific and technological concepts are presented to the reader, so that the subject is not watered down with superfluous discussions that are of no real significance to current forensic science practices. It is the author’s belief that, by learning in an interactive environment using the Internet, the reader will be a more motivated and active participant in the learning process. The text is accompanied by a companion website that provides additional exercises, text information, and MyCrimeLab: WebExtras. The latter serve to expand the coverage of the book through video presen-tations and MyCrimeLab: WebExtras that enhance the reader’s understanding of the subject’s more difficult concepts.

One of the constants of forensic science is how frequently its applications become front-page news. Whether the story is sniper shootings or the tragic consequences of the terrorist attacks of 9/11/01, forensic science is at the forefront of the public response. In order to merge theory with practice, a significant number of actual forensic Case Files are included in the text. The intent is for all the case illustrations to capture the interest of the reader and to move forensic science from the domain of the abstract into the real world of criminal investigation.

Within and at the end of each chapter, the student will encounter Quick Reviews and a Chapter Summary that recap all of the major points of the chapter. The end-of-chapter summary is followed by review questions, as well as application and critical thinking exercises designed to have the reader fur-ther explore the chapter’s content and its significance. Most chapters also include Laboratory Experi-ments, which have students apply the Next Generation Science Standards to a crime-scene activity. In some chapters, virtual crime scene exercises enable the reader to move through various types of crime scenes while identifying and collecting physical evidence.

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xii Acknowledgments

AcknowledgmentsI am most appreciative of the contribution that Lieutenant Andrew (Drew) Donofrio of New Jersey’s Bergen County Prosecutor’s Office made to Forensic Science. I was fortunate to find in Drew a contrib-utor who not only possesses extraordinary skill, knowledge, and hands-on experience with computer forensics, but who was able to combine those attributes with sophisticated communication skills. Like-wise, I was fortunate to have Dr. Peter Stephenson contribute to this book on the subject of mobile forensics. He brings skills as a cybercriminologist, author, and educator in digital forensics.

Sarah A. Skorupsky-Borg, MSFS, invested an extraordinary amount of time and effort in prepar-ing an accompanying supplement to this text: Basic Laboratory Exercises for Forensic Science. Her skills and tenacity in carrying out this task are acknowledged and greatly appreciated.

Many people provided assistance and advice in the preparation of this book. Many faculty mem-bers, colleagues, and friends have read and commented on various portions of the text. I would like to acknowledge the contributions of Anita Wonder, Robert J. Phillips, Norman H. Reeves, Jeffrey C. Kercheval, Robert Thompson, Roger Ely, Jose R. Almirall, Michael Malone, Ronald Welsh, Ken Rad-will, David Pauly, Jan Johnson, Natalie Borgan, Dr. Barbara Needell, Robin D. Williams, Peter Diac-zuk, and Jacqueline E. Joseph. I’m appreciative of the contributions, reviews, and comments that Dr. Claus Speth, Dr. Mark Taff, Dr. Elizabeth Laposata, Thomas P. Mauriello, and Michelle D. Miranda provided during the preparation of Chapter 4, “Death Investigation.”

I’m appreciative of the efforts of Brenda Wolpa and Jill Christman in preparing chapter experi-ments that support the Next Generation Science Standards.

Thanks to the reviewers of the third edition for their feedback: Debbie Allen, Maury High School; Jennifer Bisch, St. Joseph’s Academy; Tommy Decker, Thomas Jefferson High School; Aimee Fydyuk, Hillsboro High School; Terry Howerton, Atkins High School; Derrick Leach, Mid-East Career and Technology; Keith Miessau, Lake Mary High School; Scott Rubins, New Rochelle High School; and Brenda Wolpa, Salpointe Catholic High School. The following reviewers for the second edition pro-vided insightful and helpful critiques of the manuscript: Kate Allender, Redmond High School; Jill Christman, Canyon Del Oro High School; Charles Fanning, La Habra High School; John Gomola, Sterling Heights High School; Lance Goodlock, Sturgis High School; Dorothy Harris, Quince Orchard High School; Christine Leventhal, Darien High School; Christal Lippencott, Parker High School; Mary Monte, Eastern Technical High School; Kim McNamara, Oak Lawn Community High School; Randy Neider, Reading High School; Stephanie Niedermeyer, Wayne Memorial High School; Baokhanh Paton, Granby Memorial High School; and Jay Phillips, Westside High School.

I also thank the following reviewers of the first edition: Craig Anderson, Galt High School; Mar-garet Barthel, Ph.D., Freedom High School; Thomas J. Costello, High Point Regional High School; Thomas Donley, The Hotchkiss School; Shelly Duk, Walled Lake Central High School; Mark Feil, Glasgow High School; Myra Frank, Marjory Stoneman Douglas High School; Jim Hurley, Waverly-Shell Rock Community Schools; Lisa Kiann, River Valley High School; Mary Monte, Eastern Techni-cal High School; Mary J. Monte, Woodlawn High School; Kevin Mugridge, Bishop Timon St. Jude High School; Barbara Olsen, Rocky Hill High School; Bruce Parce, Albert Einstein High School; Tod Suttle, Mayfair Middle/High School; Danielle DuChesne Thompson, Mariner High School; and Penny Wolkow, Oakland Mills High School.

The assistance and research efforts of Pamela Cook, Gonul Turhan, and Michelle Tetreault were invaluable and are an integral part of this text. The transformation of Criminalistics from a college text into this edition is the result in large part of the editorial skills of John Haley, who reorganized substan-tial portions of the text and rewrote end-of-chapter questions.

Finally, I am grateful to those law enforcement agencies, government agencies, private individuals, and equipment manufacturers cited in the text for contributing their photographs and illustrations.

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About the Author xiii

About the AuthorRichard Saferstein, Ph.D., retired in 1991 after serving twenty-one years as the Chief Forensic Sci-entist of the New Jersey State Police Laboratory, one of the largest crime laboratories in the United States. He currently acts as a consultant for attorneys and the media in the area of forensic science. During the O. J. Simpson criminal trial, Dr. Saferstein provided extensive commentary on forensic aspects of the case for the Rivera Live show, the E! television network, ABC radio, and various radio talk shows. Dr. Saferstein holds degrees from the City College of New York and earned his doctorate degree in chemistry in 1970 from the City University of New York. From 1972 to 1991, he taught an introductory forensic science course in the criminal justice programs at The College of New Jersey and Ocean County College. These teaching experiences played an influential role in Dr. Saferstein’s authorship in 1977 of the widely used introductory textbook Criminalistics: An Introduction to Foren-sic Science, currently in its eleventh edition. Saferstein’s basic philosophy in writing Criminalistics is to make forensic science understandable and meaningful to the nonscience reader while giving the reader an appreciation for the scientific principles that underlie the subject.

Dr. Saferstein has authored or co-authored more than forty-four technical papers covering a variety of forensic topics. Dr. Saferstein has authored Basic Laboratory Exercises for Forensic Science (Prentice Hall, 2011) and co-authored Lab Manual for Criminalistics (Prentice Hall, 2015). He has also edited two editions of the widely used professional reference books Forensic Science Handbook, Volume 1 (Prentice Hall, 2002), Forensic Science Handbook, Volume 2 (Prentice Hall, 2005), and Forensic Science Handbook, Volume 3 (Prentice Hall, 2009). Dr. Saferstein is a member of the American Chemical Society, the American Academy of Forensic Sciences, the Canadian Society of Forensic Scientists, the International Association for Identification, the Northeastern Association of Forensic Scientists, and the Society of Forensic Toxicologists.

In 2006, Dr. Saferstein received the American Academy of Forensic Sciences Paul L. Kirk award for distinguished service and contributions to the field of criminalistics.

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xiv Handbook of Forensic Services—FBI

Handbook of Forensic Services—FBIThe Handbook of Forensic Services provides guidance and procedures for the safe and efficient methods of collecting, preserving, packaging, and shipping evidence, and describes the forensic examinations performed by the FBI’s Laboratory Division and Operational Technology Division.

The contents of the Handbook are to be found by the reader on either the iPhone app entitled “FBI Handbook” or the Android app entitled “Handbook of Forensic Services.” The handbook can also be found online: www.fbi.gov/about-us/lab/handbook-of-forensic-services-pdf.

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Next Generation Science Standards Overview xv

Next Generation Science Standards* OverviewThe Next Generation Science Standards (NGSS) provide an important opportunity to improve not only science education but also student achievement. Based on the Framework for K–12 Science Edu-cation, the NGSS are intended to reflect a new vision for American science Education

The forensic science course, being an integrated science, is not intended to directly address specific NGSS expectations. However, it incorporates the science and engineering practices and crosscutting concepts from the Framework for K–12 Science Education, which are the foundation for the NGSS standards.

The Framework identifies seven crosscutting concepts and eight science and engineering practices. The seven crosscutting concepts bridge disciplinary boundaries, uniting core ideas throughout the fields of science and engineering. The seven crosscutting concepts are as follows.

1. Patterns—Observed patterns of forms and events guide organization and classification, and they prompt questions about relationships and the factors that influence them.

2. Cause and effect: Mechanism and explanation—Events have causes, sometimes simple, sometimes multifaceted. A major activity of science is investigating and explaining causal relationships and the mechanisms by which they are mediated. Such mechanisms can then be tested across given contexts and used to predict and explain events in new contexts.

3. Scale, proportion, and quantity—In considering phenomena, it is critical to recognize what is rel-evant at different measures of size, time, and energy and to recognize how changes in scale, propor-tion, or quantity affect a system’s structure or performance.

4. Systems and system models—Defining the system under study—specifying its boundaries and making explicit a model of that system—provides tools for understanding and testing ideas that are applicable throughout science and engineering.

5. Energy and matter: Flows, cycles, and conservation—Tracking fluxes of energy and matter into, out of, and within systems helps one understand the systems’ possibilities and limitations.

6. Structure and function—The way in which an object or living thing is shaped and its substructure determine many of its properties and functions.

7. Stability and change—For natural and built systems alike, conditions of stability and determinants of rates of change or evolution of a system are critical elements of study.

The eight practices of science and engineering identified as essential for all students to learn are listed below:

1. Asking questions (for science) and defining problems (for engineering) 2. Developing and using models 3. Planning and carrying out investigations 4. Analyzing and interpreting data 5. Using mathematics and computational thinking 6. Constructing explanations (for science) and designing solutions (for engineering) 7. Engaging in argument from evidence 8. Obtaining, evaluating, and communicating information

*Next Generation Science Standards is a registered trademark of Achieve. Neither Achieve nor the lead states and partners that developed the Next Generation Science Standards was involved in the production of, and does not endorse, this product.

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Welcome...to the exciting third edition of Forensic Science: An Introduction. Richard Saferstein has carefully adapt-ed and updated his classic Criminalistics: An Introduction to Forensic Science text to create a comprehen-sive program designed specifically for high school students and teachers.

Accessible Text and Motivational 4-Color PresentationThe layout and design

make learning forensic sci-ence even more motivating and exciting.

Students live in a visual world, and the functional use of full color conveys forensic science to today’s students. Over 150 full-color photos and illustra-tions motivate students to read.

Chapter OpenersEach chapter opens with a real-life case study and stunning visual that captures students’ interest and brings content to life. Learning Objectives help students focus on the key takeaways for that chapter. National Science Education Stan-dards align with the chapter content and highlight the multidisciplinary nature of forensic science.

154 Chapter 5

is transmitted by the glass. Likewise, one can determine the color of an opaque object by observing its ability to absorb some of the component colors of light while reflecting others back to the eye. Color is thus a visual indication that objects absorb certain portions of visible light and transmit or reflect others. Sci-entists have long recognized this phenomenon and have learned to characterize different chemical substances by the type and quantity of light they absorb. This has important applications for the identification and classification of forensic evidence.

The Electromagnetic Spectrum Visible light is only a small part of a large family of radiation waves known as the electromagnetic spectrum (see Fig-ure 5–5). All electromagnetic waves travel at the speed of light (c) and are distin-guishable from one another only by their different wavelengths or frequencies. Hence, the only property that distinguishes X-rays from radio waves is the differ-ent frequencies the two types of waves possess.

Visible light

Gamma rays

High frequency Low frequency

Short wavelengthEnergy increases

Long wavelength

X rays Ultraviolet Infrared Microwaves Radio waves

FIGURE 5–5 The electromagnetic spectrum.

X-rayThe high-energy, short-wavelength form of electromagnetic radiation

laserAn acronym for light ampli�cation by stimulated emission of radiation; light that has all its waves pulsating in unison

visible lightColored light ranging from red to violet in the electromagnetic spectrum

electromagnetic spectrumThe entire range of radiation from the most energetic cosmic rays to the least energetic radio waves

Similarly, the range of colors that make up the visible spectrum can be cor-related with frequency. For instance, the lowest frequencies of visible light are red; waves with a lower frequency fall into the invisible infrared (IR) region. The highest frequencies of visible light are violet; waves with a higher frequency extend into the invisible ultraviolet (UV) region. No definite boundaries exist be-tween any colors or regions of the electromagnetic spectrum; instead, each region is composed of a continuous range of frequencies, each blending into the other.

Ordinarily, light in any region of the electromagnetic spectrum is a collection of waves possessing a range of wavelengths. Under normal circumstances, this light comprises waves that are all out of step with each other (incoherent light). However, scientists can produce light that has all its waves pulsating in unison (see Figure 5–6). This is called a laser (light amplification by stimulated emission of radiation). Light in this form is very intense and can be focused on a very small area. Laser beams can be focused to pinpoints that are so intense that they can zap microscopic holes in a diamond.

Properties of Matter and the Analysis of Glass 155

˜Light as a ParticleAs long as electromagnetic radiation is moving through space, its behavior can be described as that of a continuous wave. However, once radiation is absorbed by a substance, the model of light as a stream of discrete particles must be invoked to describe its behavior. Here, light is depicted as consisting of energy particles that are known as photons. Each photon has a definite amount of energy associated with its behavior. This energy is related to the frequency of light, as shown by Equation (5–2):

E = hf

where E specifies the energy of the photon, f is the frequency of radiation, and h is a universal constant called Planck’s constant. As shown by Equation (5–2), the energy of a photon is directly proportional to its frequency. Therefore, the photons of ultraviolet light will be more energetic than the photons of visible or infrared light, and exposure to the more energetic photons of X-rays presents more danger to human health than exposure to the photons of radio waves.

Just as a substance can absorb visible light to produce color, many of the invisible radiations of the electromagnetic spectrum are likewise absorbed. This absorption phenomenon is the basis for spectrophotometry, an analytical tech-nique that measures the quantity of radiation that a particular material absorbs as a function of wavelength or frequency. We will examine spectrophotometry in more detail when we discuss the forensic analysis of drugs in Chapter 6.

Coherent radiation

Incoherent radiation

FIGURE 5–6 Coherent and incoherent radiation.

photonA discrete particle of electromagnetic radiation

EQUATION 5–2

Properties of Matter and the Analysis of Glass5

Key Termsamorphous solidatomBecke linebirefringenceCelsius scalechemical propertycompoundconcentric fracturecrystalline soliddensitydispersionelectromagnetic spectrumelement

Fahrenheit scalefrequencygasintensive propertylaminated glasslaserliquidmassmatterperiodic tablephasephotonphysical property

physical stateradial fracturerefractionrefractive indexsolidsublimationtempered glassvisible lightwavelengthweightX-ray

Learning ObjectivesAfter studying this chapter you should be able to:

● De�ne and distinguish the physi-cal and chemical properties of matter

● Understand how to use the basic units of the metric system

● De�ne and distinguish elements and compounds

● Contrast the differences between a solid, liquid, and gas

● Understand the differences between the wave and particle theories of light

● Understand and explain the dispersion of light through a prism

● Describe the electromagnetic spectrum

● De�ne and understand the properties of density and refrac-tive index

● List and explain forensic methods for comparing glass fragments

● Understand how to examine glass fractures to determine the direction of impact for a projectile

National Science Content Standards

Scienti�c Inquiry

The Lindbergh Baby CaseOn the evening of March 1, 1932, a kidnapper crept up his homemade ladder and stole the baby of Charles and Anne Lindbergh directly from the second-�oor nursery of their house in Hopewell, New Jersey. The only evidence of his coming was a ransom note, the ladder, a chisel, and the tragic absence of the infant. A couple of months later, though the $50,000 ransom had been paid, the baby turned up dead in the woods a mile away. There was no additional sign of the killer. Fortunately, when �nally studied by wood technologist Arthur Koehler, the abandoned ladder yielded some important investigative clues.

By studying the types of wood used and the cut-ter marks on the wood, Koehler ascertained where the materials might have come from and what speci�c equipment was used to create them. Koehler traced the wood from a South Carolina mill to a lumberyard in the Bronx, New York. Unfortunately the trail went cold, as the lumberyard did not keep sales records of purchases. The break in the case came in 1934, when Bruno Richard Hauptmann paid for gasoline with a bill that matched a serial number on the ransom money. Koehler showed that microscopic markings on the wood were made by a tool in Hauptmann’s possession. Ultimately, handwriting analysis of the ransom note clearly showed it to be writ-ten by Hauptmann.

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Dimensional Illustrations The full-color art program helps students better understand key forensics concepts.

Open and Accessible DesignDesign elements bring the course content to life and provide visual cues to guide student reading.

Key TermsForensic-specific vocabulary is highlighted in the text and defined in the margins.

496 Chapter 13

animation graphically showed that the bullet wounds were completely consistent with Kennedy’s and Connally’s positions at the time of shooting, and that by fol-lowing the bullet’s trajectory backward they could be found to have originated from a narrow cone including only a few windows of the sixth floor of the Texas School Book Depository.

˜Atomic StructureTo understand the principle behind neutron activation analysis, one must �rst understand the fundamental structure of the atom. Each atom is composed of elementary particles that are collectively known as subatomic particles. �e most important subatomic particles are the proton, electron, and neutron.

�e properties of the proton, neutron, and electron are summarized in the following table:

Particle Symbol Relative Mass Electrical Charge

Proton P 1 +Neutron n 1 0Electron e 1/1837 –

As you can see, the masses of the proton and neutron are each about 1,837 times the mass of an electron. �e proton has a positive electrical charge; the electron has a negative charge equal in magnitude to that of the proton; and the neutron is a neutral particle with neither a positive nor a negative charge.

A popular descriptive model of the atom, and the one that will be adopted for the purpose of this discussion, pictures an atom as consisting of electrons orbiting a central nucleus composed of protons and neutrons—an image that is analogous to our solar system, in which the planets revolve around the sun (see Figure 13–4).1 To maintain a zero net electrical charge, the number of protons in the nucleus must always equal the number of electrons in orbit around the nucleus.

FIGURE 13-4 A popular model of the atom likens the electrons to planets orbiting the “sun” of the nucleus. Courtesy Getty Images - Stone Allstock

nucleusThe core of an atom, consisting of protons and neutrons

protonA positively-charged particle that is one of the basic structures in the nucleus of an atom

electronA negatively-charged particle that is one of the fundamental struc-tural units of the atom

neutronA particle with no elec-trical charge that is one of the basic structures in the nucleus of an atom

Trace Evidence II: Metals, Paint, and Soil 497

With this knowledge, we can describe the atomic structure of the elements. For example, hydrogen has a nucleus consisting of one proton and no neu-trons, and it has one orbiting electron. Helium has a nucleus comprising two protons and two neutrons, with two electrons in orbit around the nucleus (see Figure 13–5).

FIGURE 13–5 The atomic structures of hydrogen and helium.

1P

Hydrogen

2P2n

Helium

atomic numberThe number of protons in the nucleus of an atom

Hydrogen Deuterium Tritium

1P 1P1n

1P2n

FIGURE 13–6 Isotopes of hydrogen.

�e behavior and properties that distinguish one element from another must be related to the di�erences in the atomic structure of each element. One such distinction is that each element possesses a di�erent number of protons. �is number is called the atomic number of the element. As we look back at the periodic table on page 150, we see that the elements are numbered consecutively. �ose numbers represent the atomic number or number of protons associated with each element. An element is therefore a collection of atoms that all have the same number of protons. �us, each atom of hydrogen has one and only one proton, each atom of helium has 2 protons, each atom of silver has 47 protons, and each atom of lead has 82 protons in its nucleus.

˜Isotopes and RadioactivityAlthough the atoms of a single element must have the same number of protons, nothing prevents them from having di�erent numbers of neutrons. �e total number of protons and neutrons in a nucleus is known as the atomic mass num-ber. Atoms with the same number of protons but di�ering solely in the number of neutrons are called isotopes.

For example, hydrogen consists of three isotopes: ordinary hydrogen, which has one proton and no neutrons in its nucleus, and two other isotopes called deuterium and tritium. Deuterium (or heavy hydrogen) also has one proton, but contains one neutron as well. Tritium has one proton and two neutrons in its nucleus.

�erefore, all the isotopes of hydrogen have an atomic number of 1 but di�er in their atomic mass numbers. Hydrogen has an atomic mass of 1, deuterium a mass of 2, and tritium a mass of 3. �e atomic structures of these isotopes are shown in Figure 13–6.

atomic massThe sum of the number of protons and neu-trons in the nucleus of an atom

isotopeAn atom differing from another atom of the same element in the number of neutrons it has in its nucleus

Eclosion:Adult FlyEmerges

LarvaStage III

LarvaStage III

Postfeeding

Puparium

Early

Late

Oviposition

Egg

Eclosion:MaggotEmerges

LarvaStage I

LarvaStage II

Hydrogen Deuterium Tritium

1P 1P1n

1P2n

FIGURE 13–6Isotopes of hydrogen.

in their atomic mass numbers. Hydrogen has an atomic mass of 1, deuterium a mass of 2, and tritium a mass of 3. �e atomic structures of these isotopes are shown in Figuigure 13–6e 13–6.

same element in the number of neutrhas in its nucleus

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Engaging Case FilesLinked to the chapter material, the Case File feature boxes provide stu-dents with quick and pertinent facts about real forensic cases.

Quick LabsInquiry is at the heart of science, and it’s no exception here. In-text Quick Labs are hands-on activities that allow students to apply and experience key forensic concepts.

Physical Evidence 93

Case F

iles

A 53-year-old man was walking his dog in the early morning hours. He was struck and killed by an unknown vehicle and later found lying in the roadway. No witnesses were present, and the police had no leads regarding the suspect vehicle. A gold me-tallic painted plastic fragment recovered from the scene and the victim’s clothing were submitted to the Virginia Department of Forensic Science for analysis.

The victim’s clothing was scraped, and several minute gold metallic paint particles were recovered. Most of these particles contained only topcoats, whereas one minute particle contained two primer layers and a limited amount of colorcoat. The color of the primer surface layer was similar to that typically associated with some Fords. Subsequent spectral searches in the Paint Data Query (PDQ) database indicated that the paint most likely origi-nated from a 1990 or newer Ford.

The most discriminating aspect of this paint was the unusual-looking gold metal-lic topcoat color. A search of automotive repaint books yielded only one color that closely matched the paint recovered in the

case. The color, Aztec Gold Metallic, was determined to have been used only on 1997 Ford Mustangs.

The results of the examination were relayed via telephone to the investigat-ing detective. The investigating detective quickly determined that only 11,000 1997 Ford Mustangs were produced in Aztec Gold Metallic. Only two of these vehicles were registered, and had been previously stopped, in the jurisdiction of the offense. Ninety minutes after the make, model, and year information was relayed to the investigator, he called back to say he had located a suspect vehicle. Molding from the vehicle and known paint samples were submitted for comparison. Subsequent laboratory comparisons showed that the painted plastic piece recovered from the scene could be physically �tted together with the molding, and paint recovered from the victim’s clothing was consistent with paint samples taken from the suspect vehicle.

Source: Brenda Christy, Virginia Depart-ment of Forensic Science

Aztec Gold Metallic Hit and Run

Physical Evidence 93

Quick Lab: Luminol TestMaterials:

Luminol (powder needs to be mixed with water)Spray bottleSimulated bloodPiece of wood or flooringUV light source

Procedure:Apply some blood to the wood/flooring. Than try to completely clean it, as if you were trying to cover up a crime. If the teacher does not have the luminol mixed for you, follow instructions on how to mix it. Using the spray bottle, apply some luminol to the wood/flooring that you cleaned. Keep the room dark for this step. You may shine the UV light on the area where you sprayed the luminol; this may help if you do not see a reaction right away.

Follow-Up Questions: 1. Did you observe any reaction when the room was dark? When

you shined the UV light on the wood/�ooring? If so, what did you observe?

2. How does luminol detect bloodstains?

3. What is luminescence?

354 Chapter 9

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Application and Critical ThinkingEach chapter contains many activities designed to encourage application of critical thinking skills as they pertain to everyday life.

Chapter Review and AssessmentEach chapter provides a point-by-point summary of key concepts, with explana-tions that reinforce the materials covered.

Application and Critical Thinking 1. Indicate the phase of growth of each of the following hairs:

a. the root is club-shapedb. the hair has a follicular tagc. the root bulb is �ame-shapedd. the root is elongated

2. A criminalist studying a dyed sample hair notices that the dyed color ends about 1.5 centimeters from the tip of the hair. Approximately how many weeks before the examination was the hair dyed? Explain your answer.

3. Following are descriptions of several hairs; based on these descriptions, indi-cate the likely race of the person from whom the hair originated.a. evenly distributed, �ne pigmentationb. continuous medullationc. dense, uneven pigmentationd. wavy with a round cross-section

4. Criminalist Pete Evett is collecting �ber evidence from a murder scene. He no-tices �bers on the victim’s shirt and trousers, so he places both of these items of clothing in a plastic bag. He also sees �bers on a sheet near the victim, so he balls up the sheet and places it in separate plastic bag. Noticing �bers adhering to the windowsill from which the attacker gained entrance, Pete carefully removes them with his �ngers and places them in a regular envelope. What mistakes, if any, did Pete make while collecting this evidence?

5. For each of the following human hair samples, indicate the medulla pattern present.

A. ____________________

B. ____________________

C. ____________________

D. ____________________

E. ____________________

F. ____________________

G. ____________________

H. ____________________

I. ____________________

Trace Evidence I: Hairs and Fibers 485

Courtesy Richard Saferstein, Ph.D.

Each chapter provides a point-by-point summary of key concepts, with explana-tions that reinforce the materials covered. Chapter Review

● Trace elements are small quantities of elements present in concentrations of less than 1 percent. �ey provide “invisible” markers that may establish the source of a material or provide additional points for comparison.

● �e three most important subatomic particles are the proton, neutron, and electron. �e proton has a positive electrical charge, the neutron has no electrical charge, and the electron has a negative electrical charge.

● Atomic number indicates the number of protons in the nucleus of an atom. Atomic mass refers to the total number of protons and neutrons in a nucleus.

● An isotope is an atom di�ering from other atoms of the same element in the number of neutrons in its nucleus.

● Radioactivity is the emission of high-energy subatomic particles that accompanies the spontaneous disintegration of the nuclei of unstable isotopes. �e three types of radiation are alpha particle rays, beta particle rays, and gamma rays.

● In neutron activation analysis, a sample is bombarded with neutrons and the energy of the gamma rays emitted by the activated isotopes is measured. �e gamma rays of each element are associated with characteristic energy values that helps identify the speci�c element that produces them.

● Paint spread onto a surface dries into a hard �lm that is best described as consisting of pigments and additives suspended in the binder.

● Questioned and known paint specimens are best compared side by side under a stereoscopic microscope for color, surface texture, and color layer sequence.

● Pyrolysis gas chromatography and infrared spectrophotometry are used to distinguish most paint binder formulations.

● Emission spectroscopy and inductively coupled plasma are techniques avail-able for determining the elemental composition of paint pigments.

● PDQ (Paint Data Query) is a computerized database that allows an analyst to obtain information on paints related to automobile make, model, and year.

● A side-by-side visual comparison of the color and texture of soil specimens provides a way to distinguish soils that originate from di�erent locations.

● Minerals are naturally occurring crystalline solids found in soil. �eir physi-cal properties—for example, color, geometric shape, density, and refractive index or birefringence—are useful for characterizing soils.

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New to This Edition •New, enhanced, and current Case Files feature that links the content to real-world crime cases. •New chapters on Death Investigation and Mobile Device Forensics. •New end-of-chapter Laboratory Experiments that support Next Generation Science Standards. •New photo program.

Student and Teacher SupplementsBasic Laboratory Exercises for Forensic Science (Available for purchase, ISBN: 1-323-01928-6)The Basic Laboratory Exercises workbook brings the real world of forensic science into the classroomwith hands-on activities from fingerprinting to bloodstain analysis, and from forensic entomology toforensic anthropology.

MyCrimeLab with Pearson eTextThis is an online supplement that offers book-specific learning objectives, chapter summaries, flashcards, WebExtras, practice tests, and more to aid student learning and comprehension. In addition, the teacher resources for Forensic Science, 3e, are also included in this online supple-ment. These include the Annotated Teacher’s Edition, videos, PowerPoints, and testing files.Access to MyCrimeLab with Pearson eText is provided upon adoption. See below for teacher and student access information.

Preview and Adoption AccessUpon textbook purchase, students and teachers are granted access to MyCrimeLab with Pearson eText. High school teachers can obtain preview or adoption access for MyCrimeLab in one of the following ways:

Preview Access • Teachers can request preview access by visiting PearsonSchool.com/Access_Request. Select Initial

Access then using Option 2, select your discipline and title from the drop-down menu and com-plete the online form. Preview Access information will be sent to the teacher via e-mail.

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Adoption Access • With the purchase of a textbook program that offers a media resource, a Pearson Adoption Access

Card, with student and teacher codes and a complete Instructor’s Manual, will be delivered with your textbook purchase. ISBN: 978-0-13-354087-1

• Ask your sales representative for an Adoption Access Code Card/Instructor Manual package. ISBN: 978-0-13-354087-1

OR

• Visit PearsonSchool.com/Access_Request. Select Initial Access then using Option 3, select your discipline and title from the drop-down menu and complete the online form. Access information will be sent to the teacher via e-mail.

Students, ask your teacher for access.

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