municipal solid waste. living in the material world for the most part, the earth is a closed system...
TRANSCRIPT
Living in the Material World
• For the most part, the Earth is a closed system with respect to materials
– Whatever “stuff” we’re going to have is already here
• The concept of “consumption” is really a misnomer
– We don’t really consume matter - we convert it
• Matter must therefore cycle throughout the Earth’s ecosystem
– At the atomic level
– At the molecular level
An example we’ve seen: Carbon
• Carbon in the atmosphere (in the form of CO2) is removed by plants through photosynthesis and converted to their tissue
• We make paper from some plants and use it as packaging
• When we dispose of the paper, we might compost it, causing it to be eaten by scavenging organisms
• The respiration of these organisms releases the carbon to the atmosphere in the form of CO2 or CH4 (depending on the nature of the decomposition)
“Use it up, wear it out, make do, or do without!”
• During World War II material conservation became a public focus as part of the war effort
– Rationing of materials
– “Victory Gardens”
– “Armstrong” starters
• This led to the “reduce, reuse, recycle” slogan of the 1970s
Definition
• Solid waste from residential, commercial, institutional, and industrial sources, not including such things as construction waste, automobile bodies, municipal sludge, combustion ash, and industrial process waste even though those wastes might also be disposed of in municipal waste landfills or incinerators.
• See http://www.epa.gov/epaoswer/osw/index.htm for current information on trends and technologies.
Life Cycle Assessment
• Consideration of the energy and material flows at every stage in the life cycle of a product so that new insights can be gained into the product’s contributions to overall environmental quality.
Source Reduction
• Reducing garbage at the source with Green Product Design strategies.
• Examples include product system life extension, material life extension, material selection, reduced material intensiveness, process management, efficient distribution, and various policy options.
Methods Labeling—inform consumers through the use of labels on
products about Green Products.
Recycling—collecting pre-used materials to be used as raw materials for a new product. Often, creating a new product with recycled material reduces the energy requirements for making the same product with virgin material.
Composting—containment and aerobic degradation of organic materials, yielding marketable soil amendment or mulch.
Methods (con’d)
Waste-to-Energy Combustion—the process of incinerating waste to generate useable energy, usually in the form of steam. Energy content of waste is a function of the type of waste.
Landfills—burying waste in sanitary landfills that contain the waste and allow for safe accumulation and/or decomposition.
Consideration of an Integrated Strategy
Synthetic Polymers
• Many of the structures in nature are constructed of polymers
• Polymers are chains of monomers - molecular structures which can be joined by covalent bonds
• In the 20th century chemists developed the ability to imitate natural polymers, using petroleum hydrocarbons as a starting point
• Today many of the tools and toys on which we depend are derived from petroleum in this way
– More recently non-petroleum starters have been used
The “Big Six”
• LDPE: Low Density Polyethylene (#4)
– E.g. Plastic bags, bubble wrap
• HDPE: High Density Polyethylene (#2)
– E.g. Milk jugs
• PVC: Polyvinyl chloride (#3)
– E.g. Plumbing pipes
• PS: Polystyrene (#6)
– Styrofoam insulation, drinking glasses
• PP: Polypropylene (#5)
– Bottle caps, automobile trim
• PET: Polyethylene Terephthalate (#1)
– Pop bottles, video tape
Pay-per-container: The Chester, NJ Model
• Recognized that cost was a driving factor• Also saw the importance of convenience• Adopted a system which permitted co-mingled recyclable
pickup once per week as part of base fee, and garbage pickup at $2 per 30-pound container (based on tipping fee)
• Results were astounding:– Recycled fraction: 9% → 42%– Participation: < 10% → 90%+
– In one month!• See NY Times article (July 14, 1992)
Energy Content of Waste
• High Heating Value = gross energy content, including energy contained in the vaporized water that is produced
• Low Heating Value = net energy content, not including energy in water vapor
Calculation of LHV• Most of the time, we lose the latent heat in the water vapor and the
heat possible from hydrogen (since when it burns it generates water vapor), thus we need to calculate LHV from HHV values
• The latent heat and heat lost from hydrogen is:
QL = 2440 kJ/kg (W kg+ 9H kg)
(Why do we multiply “H” by 9? Hint: consider molecular masses)
• To get LHV, take HHV and subtract QL
Environmental Impacts of Incineration
• Solids - bottom ash and fly ash
• Gases:
– dioxins and furans
– polychlorinated biphenyls (PCB)
– heavy metals
– polycyclic aromatic hydrocarbons (PAH)