msds_jotun-baltoflake

Identification of the preparation and of the company

SAFETY DATA SHEETBaltoflake

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

1.

Emergency telephonenumber

Supplier/Manufacturer

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Product use Coatings: Solvent-borne.:

Label No. : 388

Jotun Paints (Europe) Ltd.Stather RoadFlixborough, ScunthorpeNorth LincolnshireDN15 8RREngland

Tel: +44 17 24 40 00 00 Fax: +44 17 24 40 01 [email protected]

BaltoflakeProduct name and/or code :

Contact National Poison Centre via Hospital or Registered Medical Practitioner

Hazards identificationThe product is classified as dangerous according to Directive 1999/45/EC and its amendments.

Flammable.Harmful by inhalation. Irritating to eyes and skin.

Harmful

2.

Composition/information on ingredients

Identifiers 67/548/EECProduct/ingredientname

styrene EC: 202-851-5CAS: 100-42-5Index: 601-026-00-0

25-35 R10Xn; R20Xi; R36/38

Flam. Liq. 3, H226Acute Tox. 4, H332Skin Irrit. 2, H315Eye Irrit. 2, H319

[1] [2] D

Naphtha (petroleum),hydrodesulfurizedheavy

EC: 265-185-4CAS: 64742-82-1Index: 649-330-00-2

<0,25 R10Xn; R65R66, R67N; R51/53

Flam. Liq. 3, H226STOT SE 3, H336Asp. Tox. 1, H304Aquatic Chronic 2,H411

[1] [2] H-P-4

See section 16 forthe full text of theR-phrases declaredabove

% TypeRegulation (EC) No.1272/2008 [CLP]

Classification

See Section 16 forthe full text of the Hstatementsdeclared above.

Substances presenting a health or environmental hazard within the meaning of the Dangerous SubstancesDirective 67/548/EEC.

Occupational exposure limits, if available, are listed in Section 8.

Type

[1] Substance classified with a health or environmental hazard[2] Substance with a workplace exposure limit[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII

Notes

3.

Date of issue : Page: 1/603.02.2011.

Baltoflake

If swallowed, seek medical advice immediately and show the container or label.Keep person warm and at rest. Do not induce vomiting.

Skin contact

Check for and remove any contact lenses. Immediately flush eyes with running waterfor at least 15 minutes, keeping eyelids open. Seek immediate medical attention.

Remove contaminated clothing and shoes. Wash skin thoroughly with soap andwater or use recognised skin cleanser. Do NOT use solvents or thinners.

4.First-aid measures

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing isirregular or if respiratory arrest occurs, provide artificial respiration or oxygen bytrained personnel.

Ingestion

Inhalation

Eye contact

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First-aid measures

General In all cases of doubt, or when symptoms persist, seek medical attention. Never giveanything by mouth to an unconscious person. If unconscious, place in recoveryposition and seek medical advice.

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Fire-fighting measures5.Recommended: alcohol-resistant foam, CO2, powders, water spray.Extinguishing media :

Recommendations : Fire will produce dense black smoke. Exposure to decomposition products maycause a health hazard. Appropriate breathing apparatus may be required.Cool closed containers exposed to fire with water. Do not release runoff from fire todrains or watercourses.

Extinguishing media not tobe used

: Do not use water jet.

Personal precautions Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist.Refer to protective measures listed in sections 7 and 8.

6. Accidental release measures:

:Spill Contain and collect spillage with non-combustible, absorbent material e.g. sand,earth, vermiculite or diatomaceous earth and place in container for disposalaccording to local regulations (see section 13). Preferably clean with a detergent.Avoid using solvents.

Note: see section 8 for personal protective equipment and section 13 for waste disposal.

Handling

Handling and storage7.Prevent the creation of flammable or explosive concentrations of vapours in air andavoid vapour concentrations higher than the occupational exposure limits.In addition, the product should only be used in areas from which all naked lights andother sources of ignition have been excluded. Electrical equipment should beprotected to the appropriate standard.To dissipate static electricity during transfer, earth drum and connect to receivingcontainer with bonding strap. Operators should wear antistatic footwear and clothingand floors should be of the conducting type.Keep away from heat, sparks and flame. No sparking tools should be used.Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray ormist arising from the application of this preparation. Avoid inhalation of dust fromsanding.Eating, drinking and smoking should be prohibited in areas where this material ishandled, stored and processed.Put on appropriate personal protective equipment (see Section 8).Never use pressure to empty. Container is not a pressure vessel.Always keep in containers made from the same material as the original one.Comply with the health and safety at work laws.Information on fire and explosion protectionVapours are heavier than air and may spread along floors. Vapours may formexplosive mixtures with air.

When operators, whether spraying or not, have to work inside the spray booth,ventilation is unlikely to be sufficient to control particulates and solvent vapour in allcases. In such circumstances they should wear a compressed air-fed respiratorduring the spraying process and until such time as the particulates and solventvapour concentration has fallen below the exposure limits.

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Baltoflake

Storage Store in accordance with local regulations.Notes on joint storageKeep away from: oxidising agents, strong alkalis, strong acids.Additional information on storage conditionsObserve label precautions. Store in a dry, cool and well-ventilated area. Keep awayfrom heat and direct sunlight. Keep away from sources of ignition. No smoking.Prevent unauthorised access. Containers that have been opened must be carefullyresealed and kept upright to prevent leakage.

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Engineering measures Provide adequate ventilation. Where reasonably practicable, this should be achievedby the use of local exhaust ventilation and good general extraction. If these are notsufficient to maintain concentrations of particulates and solvent vapours below theOEL, suitable respiratory protection must be worn.

8. Exposure controls/personal protection

Skin and body

Personal protective equipment

If workers are exposed to concentrations above the exposure limit, they must useappropriate, certified respirators. Use respiratory mask with charcoal and dust filterwhen spraying this product.(as filter combination A2-P2). In confined spaces, usecompressed-air or fresh-air respiratory equipment. When use of roller or brush,consider use of charcoalfilter.

Personnel should wear antistatic clothing made of natural fibres or of high-temperature-resistant synthetic fibres.

Use safety eyewear designed to protect against splash of liquids.Eyes

Respiratory system

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Occupational exposure limits

styrene EH40/2005 WELs (United Kingdom (UK), 8/2007).STEL: 1080 mg/m³ 15 minute(s).

STEL: 250 ppm 15 minute(s). TWA: 430 mg/m³ 8 hour(s). TWA: 100 ppm 8 hour(s).

Naphtha (petroleum), hydrodesulfurizedheavy

EH40-WEL (United Kingdom (UK), 1/2005).STEL: 850 mg/m³ 15 minute(s). Form: All forms

STEL: 150 ppm 15 minute(s). Form: All forms TWA: 566 mg/m³ 8 hour(s). Form: All forms TWA: 100 ppm 8 hour(s). Form: All forms

For prolonged or repeated handling, use the following type of gloves: gloves:polyvinyl alcohol or nitrile.

Barrier creams may help to protect the exposed areas of the skin but should not beapplied once exposure has occurred.

Hands

For right choice of glove materials, with focus on chemical resistance and time ofpenetration, seek advice by the supplier of chemical resistant gloves.

Ingredient name

The user must check that the final choice of type of glove selected for handling thisproduct is the most appropriate and takes into account the particular conditions ofuse, as included in the user's risk assessment.

Physical and chemical properties9.Physical state

Solubility

Liquid.

Insoluble in the following materials: cold water and hot water.

Characteristic.Odour

Various colours.Colour

Flash point Closed cup: 34°C (93,2°F)

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Density : 1.25 g/cm3

Explosion limits : 0.9 - 6.8%


Baltoflake

Stability and reactivityStable under recommended storage and handling conditions (see section 7).

Hazardous decomposition products: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen.

Keep away from the following materials to prevent strong exothermic reactions: oxidising agents, strong alkalis, strongacids.

10.

Toxicological information11.There is no data available on the preparation itself. The preparation has been assessed following the conventionalmethod of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. Seesections 2 and 15 for details.

Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result inadverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys,liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness,drowsiness and, in extreme cases, loss of consciousness.Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with thepreparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorptionthrough the skin.If splashed in the eyes, the liquid may cause irritation and reversible damage.Ingestion may cause nausea, diarrhea and vomiting.This takes into account, where known, delayed and immediate effects and also chronic effects of components fromshort-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.

Ecological information12.There is no data available on the preparation itself.Do not allow to enter drains or watercourses.

The preparation has been assessed following the conventional method of the Dangerous Preparations Directive1999/45/EC and is not classified as dangerous for the environment but contains a substance or substances dangerousfor the environment. See section 2 for details.

Ecological information

Product/ingredient name Aquatic half-life Photolysis BiodegradabilityNaphtha (petroleum),hydrodesulfurized heavy

- - Not readily

Aquatic ecotoxicity

Naphtha (petroleum), hydrodesulfurizedheavy

- Acute EC50 <10 mg/L Daphnia 48 hours

- Acute IC50 <10 mg/L Algae 72 hours- Acute LC50 <10 mg/L Fish 96 hours

Product/ingredient name Test SpeciesResult Exposure

Biodegradability

Disposal considerations13.Do not allow to enter drains or watercourses. Material and/or container must be disposed of as hazardous waste.

08 01 11* Waste paint and varnish containing organic solvents or other dangeroussubstances. If this product is mixed with other wastes, this code may no longer apply.If mixed with other wastes, the appropriate code should be assigned. For furtherinformation, contact your local waste authority.

European waste catalogue(EWC)

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14.

International transport regulations

Paint.Proper shipping name

Packing group III

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Transport information

1263UN Number :

Class 3:

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure thatpersons transporting the product know what to do in the event of an accident or spillage.


Baltoflake

Label :

Additional information

ADR / RID : Tunnel restriction code: (D/E)Hazard identification number: 30Special provisions: 640E

ADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable toreceptacles < 450 litre capacity).

Emergency schedules (EmS): F-E, S-EMarine pollutant: No.

:IMDG

IMDG: Viscous substance. Transport in accordance with paragraph 2.3.2.5(applicable to receptacles < 30 litre capacity).

Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.

Regulatory information

Harmful

15.

Safety phrases S23- Do not breathe vapour / spray.S51- Use only in well-ventilated areas.

R10- Flammable.R20- Harmful by inhalation.R36/38- Irritating to eyes and skin.

Hazard symbol or symbols

Risk phrases

EU regulations

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: The product is classified and labelled for supply in accordance with the Directive1999/45/EC as follows:

styreneContains

Industrial use : The information contained in this safety data sheet does not constitute the user’sown assessment of workplace risks, as required by other health and safetylegislation. The provisions of the national health and safety at work regulations applyto the use of this product at work.

R10- Flammable.R20- Harmful by inhalation.R65- Harmful: may cause lung damage if swallowed.R36/38- Irritating to eyes and skin.R66- Repeated exposure may cause skin dryness or cracking.R67- Vapours may cause drowsiness and dizziness.R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.

:Full text of abbreviated Rphrases

Full text of abbreviated Hstatements

: H226 Flammable liquid and vapour.H304 May be fatal if swallowed and enters airways.H315 Causes skin irritation.H319 Causes serious eye irritation.H332 Harmful if inhaled.H336 May cause drowsiness or dizziness.H411 Toxic to aquatic life with long lasting effects.

16. Other informationCEPE Classification : 1

Date of issue 03.02.2011.

Version

Notice to reader

2

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This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No 1907/2006.

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Indicates information that has changed from previously issued version.


Baltoflake

The information in this SDS is based on the present state of our knowledge and on current laws. The productis not to be used for purposes other than those specified under section 1 without first obtaining writtenhandling instructions. It is always the responsibility of the user to take all necessary steps to fulfil thedemands set out in the local rules and legislation. The information in this SDS is meant to be a description ofthe safety requirements for our product. It is not to be considered a guarantee of the product's properties.


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