msds nuvet 200 ec

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ATilVAC CH EMIC/IL CORPORAT'IOII NUVET 2OO EC MATERIAL SAFETY DATA SHEET I.@r LlDl1aluEledrioN PRODLTCT NAME: NUVET 200 EC CIIBMICAL NAME: Nor applicrblc (btend) GENERAL USB: Emulsifiable Concentrntc insecticittc PRODUCT DBSCRIPTION: Amber liquid llPA tlegistration Nrrmber: Not rcgistercrl in U.S. For Bxport Onl1,. MSDS No.: 332 2 Revision Date: 1.5 December, 2005 Pagc t of t0 AltlVAC |'{SDS No.: 3322 MANUF'ACTURER: AMVAC CITEMICAL CORPORA'I'ION 4100 E. \,trashington Blvd. l,os Angelcs, CA USA 90023-4406 Ph: J23-264-3910 liAX: 321-268-1028 EMBIICENCY TI,LI]PIIONB tr'UMBERS: ilTANIJFACTTIRBR: 323-264-391 0 TRANSPORTATION (24 ITOURS) CIIEl\lTReC: 800-424-9300 oTtrnR (24 nolitrs) r\MVAC: 323-264_3910 CONIPONI'N'T l)imr:tlryl 2,2-tliclrlorovi rrylphosphlte ( I)l)Vl,; [)i0lrlorvos) Inelt ingredients: lncluclcs the follor.ving compounrJs: I ,2-benzenedicarboxvl ic acid, dibutyl ester (Dibut1,l phthalate) Acelic arrhydride 20n,i, 80r'o 69.',|% 0.5% 62-73-1 84-'t4-2 I 08-24-7 Mixed nonionic/anioniq en4liifiers in solvenrs o QO/ _ a.r\ /O osltA HAZARDOUS CONTpoN0NTS (29 CFII. 1910. t200) coMpoNENT IIAZAB]) @ffi/#*r6ry,ffi ,ro-ro-r; cNS ncpression 5 0 mg/nrr 5.0 mglm' .-.-.--.-AsClig qdudrldC l0g:24-i\ 5nonr ;;.-;"* Corrosive : ru _ 5_-ppm Exposurc Limits g lrrs. TWA

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MSDS Pestisida Nuvet 200 EC

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Page 1: MSDS Nuvet 200 EC

ATilVAC CH EMIC/IL CORPORAT'IOIINUVET 2OO EC

MATERIAL SAFETY DATA SHEET

I.@r LlDl1aluEledrioNPRODLTCT NAME: NUVET 200 ECCIIBMICAL NAME: Nor applicrblc (btend)GENERAL USB: Emulsifiable Concentrntc insecticittcPRODUCT DBSCRIPTION: Amber liquidllPA tlegistration Nrrmber: Not rcgistercrl in U.S. For Bxport Onl1,.MSDS No.: 332 2Revision Date: 1.5 December, 2005

Pagc t of t0

AltlVAC |'{SDS No.: 3322

MANUF'ACTURER:AMVAC CITEMICAL CORPORA'I'ION4100 E. \,trashington Blvd.l,os Angelcs, CA USA 90023-4406Ph: J23-264-3910liAX: 321-268-1028

EMBIICENCY TI,LI]PIIONB tr'UMBERS:ilTANIJFACTTIRBR: 323-264-391 0TRANSPORTATION (24 ITOURS)

CIIEl\lTReC: 800-424-9300oTtrnR (24 nolitrs)

r\MVAC: 323-264_3910

CONIPONI'N'T

l)imr:tlryl 2,2-tliclrlorovi rrylphosphlte ( I)l)Vl,; [)i0lrlorvos)

Inelt ingredients:lncluclcs the follor.ving compounrJs:

I ,2-benzenedicarboxvl ic acid, dibutyl ester (Dibut1,lphthalate)Acelic arrhydride

20n,i,

80r'o

69.',|%

0.5%

62-73-1

84-'t4-2

I 08-24-7Mixed nonionic/anioniq en4liifiers in solvenrs o QO/_ a.r\ /O

osltA HAZARDOUS CONTpoN0NTS (29 CFII. 1910. t200) coMpoNENT IIAZAB])

@ffi/#*r6ry,ffi ,ro-ro-r; cNS ncpression 5 0mg/nrr 5.0 mglm' .-.-.--.-AsClig qdudrldC l0g:24-i\5nonr ;;.-;"* Corrosive: ru _ 5_-ppm

Exposurc Limits g lrrs. TWA

Page 2: MSDS Nuvet 200 EC

AMVAC CHEMICAL CORPORATION Psge 2 ol 10

AMVAC tISDS No.: 3322NUVET 2OO EC

Ynunt-*EMERGENCY OVEITVIEW:

DANGER! POISON! Poisonous if sivallorved, inhalecl or absorbei ilrrough skin and eyes.

Rapidly absorbed through skin. Repeated inhalation or skin contact ntay, withoutsymptoms, progressively increase susceptibility to Dichlorvos (DDVP) poisoning.

CAUTION! FLAMMABLE! Keep away from sources of ignition. CAUTION! WATERREAC'IIVE! TOXIC to fish! Do not contaminate bodies of water.

KEEP AWAY FROM CHII-DREN!

POIEI\ffir\L IIEALTI{ EFFECTS

ROUTE(S) OF ENffRY May be fatal if absorbed through thc eye or sl<in, is ingested or is inhalcd.

SIGNS OFACLffE OVEREXPOSURE: r\crrtc cholincstcr:rsc rlcprcssioo may bc cvirlcncccl bv

hcadache, nausca, vomiting, diarrhca, abdominal cramps, cxcessive sweating, salivalion and

tearing, constricted pupil.-, blurrccl vision, tightncss in chest, weakncss, musclc trvitchirrg and

confusion; irr extreme cases, unconsciousrrcss, convulsions, sevcre tespittt<;q'depression and

clcath may occur. It should also bc notcd that br:carrsc of thc prescncc oFthc othcr c()1nl)()lrcnts,

thc product may also havc thc following hcnltl.r hazards: in:iratin11 to thc skin and cvcs, mav causc

ctntral nervous system tlcprcsr;ion, ma)'catrsc skin scnsitization, amv causo harm to rn unlx;tntlrild, and rnny irtctcasc thc possiblc tisl< oI inrpnirccl lcttiliq'..

SIGNS OF CFIROMC OVEREXPOSURII: llcpe'atecl exlx)surcs to small closcs of Dl)V? ancl othcrorgan<lplrosplratcs nray lorvct thc cholinc"-tcrar-c to levtls tirr:rr: tlre alrovc svmpt()nrs of :rcrrtc()vcrcxp()i^urc lrc,rbscfvctl. Irr rtltlitiorr, llrr-'rc is cvitlcrrr:c tltrt cltrrlric cxp()surc t0 thc solvr:nt rnat'c,r, rs(: c('ntritl ilr:rv()us systcnr tlltnrtllc.

CARCINOGENICI'IY: lil)r\ untlcr its 19!X) proposcrl (iuirlclirrt's f<rr ()arcirrollcn ltisk r\sscs.rnrcrrt has

classificcl I)l)VI'!ls lravirrg "sulgcstivc cvirlcncc of carcinoecnir:ity, bLrt not sufficir:rrt t() lsscsshuman carcinogcn'ic potcntial." lAlt(l lists l)I)Vl) (l)ichlorvos) as

bcing possibly carcirrog<'rric to htrrnans ((irorrJr 213). CARII SI{O[[,D BE IXI]RCISED INI IAM)IING I)DVP N ND TTS I()TIMT]I/\I'IONS.

MBDICALCONDITIONSAGGRAVATED BYEXPOSURE: Prcexisting conditiors rvhlch loscrcholincstcrasc lcvcls incrcasc vulncrability to cht>lirrcstcrar-c dcprcssion,'l'hc"-c inclrrdc: (for plnsrna)gcnetic cholincstt:tasc dc6cicrrcy; rdvalccd livr:r tliscasc; chronic alcoholisrn; nr:rlntrtritirn;dennatomvositis; cxisting toxicity frrm exT)()i^urc to carbon disulfidc; benzalkonium salts, organicrncrcury compounds, ciguatoxins or solanincs; and (for ltl3C) hemolytic anemias.

Page 3: MSDS Nuvet 200 EC

\

4. FIRST AID MIIASUITES

DDVP IS A CI{OI,INESTERASE INI-III]If'OIT. A PI{\SICIAN STIOULD l]E CONIACI'ED IN ALL CASES OFEXPOSURE TO DDVP AND N'S FOiITTLA I'IONS.

CAUTION: Pcrsons atrcnding victim should avoid clircct contact with hcavih contaminatcd clothing ot vominrs.Rubber gkrvcs should bc wom bv the cmcrgcncy rcsJronrlcr or mc<.tic:rl pcrsrrnnci whilc washing thi pcsticiclc from skinand harr of tht cxposcd vicrirn.

E\T'S: Immcdiatcly flush thc cycs rvith copious amolrrlts of clcirr, cool nrnnir:g rvater tirr a miniurum o[: 15 minutcs. I]oldthecyrliclsaPartduringtlrcflushingtocnsurcrinsingofthccrrtircsurfaccofthccycs and lids u.ith watcr. Contact aphysician irnmcdiatcly. I f thcrc will bc a dclay in gcttirrg rne dical rttcntitxr, rinsc thc cves for at lcast alother I 5lr inutr:s.

INHAI-ATIO}.I:Rcmovc vi<:tim to frcsh air. If brcnthirrg has ceasctl, clcar the victim's ainvay nnd startrnouth-

ar:tificial rcspiration. If breathing is difFrcult, givc oxygcn. (lontact a physicinn immccliatcly.to-moutll

INGESTION:DO NOT induce vomiting. lf victim is consciorrs, adrninistcr xn I oz. glass of water containing 2 tbsp. activated

charcoal. l'Iave person lic on thr:ir left sidc to slorv down absorption of the ingested material. Ncvcr givc anvthing bvm()uth t() An unconscious lte rs()tl- (lontact a physician immcdiatclv.

SKIN: Imnrcdiatcly flush rrll affcctcll arcrts rvith largc afir()rrnts of ciclr rvirtcr ftrr at lcist 15 nrinutcs. I{cm1rvc

pl rysi<'i:rrr ir rrrrrctlirrtt.ly.

NOIETOPFTY$CIANS:'fhis is nn C)rgaoophttsphatc (Ol') lnsccticidc. l)o not rvait tirr laboratorv confirnation to trcar paticnrs with

strong clinical evidencc ofpoisorring. Contact your local poison control centet for further recornmendatioosregatding control of poisoning, emcrgency trcatment, aud other infonnation regatding the toxiciry of DD\?(Dichlorvos)' A possible method of treatorent is given bclorv. I)o Not handle the patient rvithout the foLlowingprotective equipmeot in place chemical resistlnt gloves and apron (prcfcrably nitrile). ltcmove contamiiatcd clothing anido notreusc without tlrorough. cleaning with cletctgent and hot watcr. f)ispose of heavilr. c()ntalninated clot-hirrg,including shocs, as a hazlrdous waste. Iistablish airway and oxyeenation. I lt Atropi.c s^ulf-ate is- the antidote ofcl.roicc against patasymPathetic !]ewous stimulation. If thcrc arc signs of parasymplthctic stimr:latiol, ,/\tropine

Sulfate should bc infccted at 10 minutc intcrvals in doscs of i to 2 milligrams u.rtil compl;rc atropinizarion hasoccurrcd. Pralidoxime chloride (2-P,'\tr'f cliloride) mav also bc uscd as an eftective antiiote i' a.'i.lition to and rvhilemaintaining full atropinizatiot. In adults, an initial rlose of I gmm of 2-PAIVI should be injcctecl, prcferably as anirrfusion, in250 cc of saline oveta 15 to 20 mimrte pcriocl. IFthis is notpractical,2l)r\M may bc r&rinistered slorvlyby intravcrious injection as a 59lo solution in rvatct over not lcss than 2 mirrutcs. Aftcr about an hour, a second doseof I sram of 2- PAM rvill be inclicatcd if muscle rvcakncss has not bcen tclicvcd. For infants and chiidrcn, thc dose of 2-

I)AM is 0.25 grirms..i\voi,l morphine, aminophyllinc, phcnothiazine, reserpinc, furoscmidc ancl ethacrvnicacid. clear chcst by postural drai'ngc. oxygcn administration nray bc neccssary.

Observe p^tient cofltinuously for 48 hours. Rcpeated exposure to cholinesterasc inhibitors may rvithoutwarning cause ptolongcd susccptibiliry to vcry small doses of anv cholinestcrasc inhibitor. All,,ru no furthercxposurc until time f<rr cholincsterasc tegencration has becn attaincd as detcrmincd by a |lood tcst. Ilathe andsharnpoo contnminatcd skin antl hait. If irrgcstccl, crnpty stonrach. Activatcd c6atcoal is trsctirl to tlrtl.rcr limitabsorption.

Page 4: MSDS Nuvet 200 EC

6. ACCIDBNTALRIILEASBIYIBASURIiS.-gon1't!

SMALL SPILL: Covcr with nonflanrmablc absr>rbctrt (clav, salrcl, oil city, kiny lincr, ctc..) to absorb the liquid. Srveepinto art opcn plastic tlrum. I)econtaminatc tlrc arcr rrrd cr.luipmcnt with clilutc ali<ali <>r amm6nia (iess than 570solution) antl clctctgcnt. FIush thc arc:r rvith watcr. i\bsotb arrd -srvccp into thc sarnc opcn plastic Jmm. Closethc dnrnr arrcl rlisposc oFas a hazardous \\'astc.

LAlt(;E SPILL: l)ikc thc spill to prcvcnt cotttitntirtatiorr of locul rvatcr s()urccs. SiJrlron thc maioritv of thc lirluitl i11t6clrrtrrts l'rrr ust: or dislrosal, dcpcndinll on thc circrrmstanccs. (,lcan thc arca as dcscribcci f<rr a snrall spill.

T.gaNpLtNG ANp STORAGE

FIANDLING: l)rcvcnt sl<in contact. I)o not breathe fumes. Wcar approl:riatc personal protcctive ccluipmenr(PPE, Scction 8). Wash thoroughlv aod chanse clothcs aftcr hanclling. Wash clothes .epnr"t"lv; do .,otrvash heavily contrminated clothint. Disposc of hcavily c()ntalninatecl clothing as a hazarclr>us rvaste.Kccp prtxluct rrrvay fronl frlod, clrirrk, c<>sntctic"-, ancl tobacco prorlucts. Scc prodr:ct labcl firr ororcdcttiicd harrdling proccclurcs.

of childrcn. Storc irr oriqinli containcr.

Ii. BXPOSU RIt CONTROLS/PE Ii.SONA I, PROT BCT'I ON

ENGINEEIUNGCOI\I.rIiOIS r\ wcll-vt:rrtilatctl arca is rcconrrncrrrlctl fot hanrlling NL]V;\NG) 200 I.l(1. Usc ofmcchanical or local cxbaust svstcm-s is rccomntclrclcrl. Scc labr:l ()r cont:lct vour distributr>r tbr r.norccomplctc instructions.

RESPIRATORY PITOTECTION: r\ NIOSI i/ivfSI L'\ approvr:d airlurili,ing rcspiraror ccluippccl rvith r>rganic vapgrcartriclgcs or canir-tcts is requircd g'hcn rnvonc is workinr *,itlr or ncar opcrl colltiin;rs of this piodrct. ,\nta;:jmtrrn usc oFcighr hours is rccommcrrclctl. llor crncrecncv arrrl otlrcr iondrtions q,hcrc. thc c,xPcisurc lintitnray l>c grcatlv cxccctlcrl, usc an al)llr()\'ctl positivc-prt:sstrrc, scl f'-corttainctl l;rcathint1 al)p:rratlls 6r pgsitiyc-l)rcssrtrc airlinc rvitlr atrxiliatv sc]f-contlirtt'cl rir strpplv. Scc l;rbcl ()r c()nt:tct vour,listribrrt<>. f,r. nr,r." cornpft:tcin s lrrrctiorr s.

SKIN PnOTECIION: I)rcvcttt:rkirt c.tttitct. (lh<:rnrcrl rcsistant glovc"-(prcfcr:rblv nitrilc), covcralls 'r iorrr-slccvccisllirr altrl 1t:tltt:r, rtrtl cht:tttir::t] rc'sislrurl shr,< s or llor,rs, art: ncc(-,ss:rrv t() l)r(.vcrrt skin (:(),)tlnrir):rrirl1. .\

risk oisIillrr11t'or slllrrslrirrll. l(ttrtovr: c()nt;ln);rr;rl((l r:lotlrirrt:ts s(xrn rls possilrlc. \\/lslr tii16.9rr:onl:rrnirr:rtttl clothing scparatt.lr, tionr ofltcr r.lotirrs. \\,cirr clr:rtrr clrithcs tlailr.. Wrrslr t,cl] *ith so.rp arrclrr':ttcr;ttitr harrrllirt!'this Ir,rrltrct. St'r'thc lal;tl tirr rrrort.sJ.(.'cill(: irrstrur:rir,rrs.

Page 5: MSDS Nuvet 200 EC

6.

[!BE FIEUTLN G M II,.\sURII:5.

FI-AMMABLD PROPERTIESFlash Point I 156 1t/65.5oO (Pensliv-l\'fartcns c,c.) '\utoisnitiort'['cmpcraturc: Not availablclilammablc l,imits: l,orvcr flammablc limit: not available

Uppcr flarnmablc limit: not availablc

. lilammability: 'l his is a nonflamnnblc liqtncl that will burn rvhcn hcatcd S',lltl?,'\ rating =1)

EXPLOSTVITYVapor-tirmixturcs <>f onc of thc (:()mp()ncr)ts);\cctic anhytlriclc, art: l<nt>rvtt trr bc cxplosivc rvlrcn thc ct>rnpt>uncl

is rvithin the tlarnmablc limits li--tcd abo.'e an<l thc tcmpcraturc is abovc the flaslrpoint.,\lsr>, a violent

cxgthcrmic rcrcti6n occurs rvlrcrr .\cctic arrhyrltidc rctcts rvitlt rvrtcr. ']'his hcat may bc sufficicnt trr i.O";r"

comltustiblc matcritls. r\cctjc :rnhvcl ridc is sc:nsitivc t() stxtic cl isclra rtlc.

HAZARDOUS COMBUSTION PRODI]CIS:T'his pr6dqct will crnit toxic furncs rvhcn llurncil, irrclucling carb<ttr nronrrxidc. \rapors of thc r:nbtrrtrcd

prgduct mry also bc hazarclous. (lorltact rvith thc fumcs and vapors shottld be avoidcd bv stavirrg upu'ind

and by wearing imperviotrs clothing and positivc prcssutc sclf-containecl brcathing aPParanrs.

DCTINGUISFIINGMEDIAFoam, dry chemical, carbon dioxide, watcr spray (fog). Usc rvatcr .x'ith caution as one of thc components.

Acctic anhydride, reacts with watcr.

FIRE FIGFITING INSTRUCITONS:l:ivacuatc rlonessr:fltial pcrsonncl from thc arca. Kccp upwincl. Wcar self-containcd btcathing apParatus

ancl inrpenious clothing, including glovcs antl cvc protection. Clcan all clothing bcfbrc rettse. Sevcrelv

contaminatcd clotl-ring cannot bc adcquatcly dccrxrt'lrninated, :rnd rmrst be disposbd as a hazarrlous waste.

Shower rvith -soap and water nftct contact with tlris procluct.

ACCI

GENERAL: l;',vncuatc pcrsolurcl antl tlroroughlv vcntilafc tlrc rrcr. Usc lrlt:titrirtc vcntilatiotr anrl rtpirronrirtte

pcrsonal protcctivc e<pipnrer.rt (l)l)l:,), Scction 8). l(ccp bysturtdcrs upwind ancl arvrtv tiom thc spill.