msds granofin pl liq

Safety Data Sheet according GB/T 16483-2008

Granofin PL liq (9)

Substance key: SXR060526 Revision Date: 28.05.2013

Version : 1 - 2 / CHI Date of printing : 06.08.2013

1) Chemical Product and Enterprise Logo

Trade name Granofin PL liq

Material number: 104824

Intended use of the product Industry sector: Leather processing industry

Type of use: Leather tanning and retanning

Identification of the company Clariant Produkte (Deutschland) GmbH Benzstrasse 11 70771 Leinfelden-Echterdingen Telephone no. : +49 711 90320

Information about the substance/preparation Corp Product Stewardship BU Leather Services E-mail: [email protected]

Emergency telephone number: +86 532-83889090 2) Hazard Summary

Main physical and chemical hazard information

GHS hazard class(es)

The product is classified and labelled in accordance with GHS regulation and the relevant national laws. Flammable liquids Category 3 Eye irritation Category 2A Skin sensitization Category 1 Carcinogenicity Category 2 Chronic aquatic toxicity Category 3

GHS labeling UN The product is classified and labelled in accordance with GHS regulation and the relevant national laws.

Symbols

Flame, Health Hazard, Exclamation mark

Signal word Warning

Hazard statements Flammable liquid and vapour. Causes eye irritation.


Granofin PL liq (9)



May cause an allergic skin reaction. Suspected of causing cancer. Harmful to aquatic life with long lasting effects.

Precautionary statements Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Use explosion-proof electrical/ventilating/lighting/.../ equipment. Take precautionary measures against static discharge. In case of fire: Use water spray for extinction. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Wash with plenty of soap and water. IF exposed or concerned: Get medical advice/ attention. Store locked up. Store in a well-ventilated place. Keep cool. Dispose of contents/container to an approved incineration plant.

Additional information No additional hazards are known except those derived from the labelling.

3) Ingredient/Composition information

Product type: Mixture

Chemical characterization aliphatic polyaldehyde, ca 50 % solution in water

Hazardous ingredients China:

Chemical name or generic name CAS-number Concentration or concentration scope

Formaldehyde 50-00-0 4 %

Acetaldehyde 75-07-0 3 %

Hazardous ingredients GHS:

Chemical name or generic name CAS-number Concentration or concentration scope

Formaldehyde 50-00-0 4 %

Acetaldehyde 75-07-0 3 %

4) First-aid Measures

General information Remove soiled or soaked clothing immediately

After inhalation Remove the casualty into fresh air and keep him calm.

After contact with skin In case of contact with skin wash off immediately with soap and water


Granofin PL liq (9)



After contact with eyes

In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice

After ingestion Rinse mouth thoroughly with water. When swallowed seek medical aid immediately and show the physician the packaging or the label of the packaging.

Advice to doctor

Symptoms No information available

Hazards No additional risks are known.

Treatment Treat symptomatically.

5) Fire Safety Measures

Suitable extinguishing media water spray jet foam carbon dioxide dry powder

Special hazards from the substance itself, its combustion products or from its vapours In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO) Carbon dioxide (CO2) Nitrogen oxides (NOx)

Special protective equipment for firefighting Use self-contained breathing apparatus

Further information Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations.

6) Leak Emergency Treatment

Personal precautions Wear personal protective equipment. Unprotected persons must be kept away. Keep away sources of ignition.

Environmental precautions Do not allow to enter drains or waterways

Methods for cleaning up/taking up Pick up with absorbent material (eg sand, sawdust). Rinse away rest with water When picked up, treat material as prescribed under heading "Disposal".

Additional information Information regarding personal protective measures see, chapter 8.

7) Operation, Disposal and Storage


Granofin PL liq (9)



Advice on safe handling

Use only in well ventilated areas.

Advice on protection against fire and explosion Keep away from sources of ignition - refrain from smoking. Take precautions against accumulation of electrostatic charge

Further information on storage conditions Protect from heat Container should not be closed air-tight.

Storage stability Storage temperature: 5 - 40 °C

8) Exposure Control and Individual Protection

Ingredients with occupational exposure limits to be monitored Formaldehyde CAS number : 50-00-0 Occupational exposure limits for hazardous agents in the workplace - Chemical hazardous agents. China. Occupational Exposure Limit for Hazardous Agents in the Workplace. Revision : : 2007-04-27 Maximum allowable concentration

Values: 0.5 mg/m3

Acetaldehyde CAS number : 75-07-0 Occupational exposure limits for hazardous agents in the workplace - Chemical hazardous agents. China. Occupational Exposure Limit for Hazardous Agents in the Workplace. Revision : : 2007-04-27 Maximum allowable concentration

Values: 45 mg/m3

General protective measures Avoid contact with eyes and skin Do not inhale vapours

Hygiene measures Remove soiled or soaked clothing immediately. Avoid contact of the substance.

Respiratory protection : If ventilation insufficient, use a respiratory protection apparatus

Hand protection : Butyl rubber gloves Observe the information of the glove manufacturers on permeability and breakthrough times and other workplace requirements

Eye protection : safety glasses

Body protection : protective clothing


Granofin PL liq (9)



9) Physical and Chemical Properties

Physical state/shape : Liquid

Color : slightly yellowish

Smell : slightly pungent

pH value : 6 - 7 (20 °C, 10 g/l)

Freezing point : < -10 °C

Boiling range : 90 - 99 °C

Sublimation point : not applicable

Flash point : 26 °C Method : DIN 51755 (closed cup)

Lower explosion limit : not tested.

Upper explosion limit : not tested.

Combustion number : not tested.

Vapour pressure : not tested.

Vapour density in relation to air :

not tested.

Density : approx. 1.2 g/cm3 (25 °C) Method : DIN 51757

Solubility in water : miscible

n-Octanol/water partition coefficient (log Pow) :

This property is not applicable for mixtures.

Ignition temperature : 430 °C Method : DIN 51794

Thermal decomposition : Method : DTA No decomposition upto 350 °C.

Evaporation rate : not tested.

Viscosity (dynamic) : not tested. 10) Stability and Reactvity

Chemical stability: Under normal conditions the product is stable.

Hazardous reactions When handled and stored appropriately no dangerous reactions are known

Conditions to be avoided not known

Incompatible substances not known


Granofin PL liq (9)



Dangerous decomposition products

Formaldehyde acetaldehyde

11) Toxicological Information

Acute oral toxicity : LD50 > 5,000 mg/kg (rat) Method : OECD 401

Acute inhalation toxicity : not tested.

Acute dermal toxicity : not tested.

Skin irritation or corrosion : non-irritant (rabbit) Method : OECD 404

Eye irritation or corrosion : irritant (rabbit eye) Method : OECD 405

Respiratory or skin allergies : not tested.

Germ cell mutation : not available

Carcinogenicity : not available

Reproductive toxicity : not available

Specific target organ toxicity - a one-time exposure (STOT - single exposure) :

Remarks: not tested.

Specific target organ toxicity - repeated exposure (STOT - repeated exposure) :

Remarks: not tested.

Repeated dose toxicity : not tested.

12) Ecological Information

Fish toxicity : LC50 10 - 100 mg/l (96 h, golden orfe)

Daphnia toxicity : not tested.

Algae toxicity : not tested.

Persistency and degradation (Biodegradability) :

45 % (10 d) not readily degradable Method : OECD 301 F

Potential biological accumulation :

not tested.

Dissolved Organic carbon (DOC) :

210 mg/g

Chemical oxygen demand (COD) :

480 mg/g

Biochemical oxygen demand (BOD5) :

not available


Granofin PL liq (9)



Bacteria toxicity : 100 - 1,000 mg/l

Method : fermentation tube test

Behaviour in environmental compartments No known data.

Remarks Product does not contain any organic bound Halogens which could lead to AOX-values.

13) Waste Disposal

Residual wastes In accordance with local authority regulations, take to special waste incineration plant

Contaminated container and package Disposal of wastes and containers in a safe manner.

14) Transport Information


Granofin PL liq (9)



IATA

Proper shipping name: Flammable liquid, n.o.s.

Class: 3 Packing group: III UN/ID number: UN 1993 Primary risk: 3 Remarks: Shipment permitted Hazard inducer(s): ACETALDEHYDE

Formaldehyde

IMDG


Class: 3 Packing group: III UN no.: UN 1993 Primary risk: 3 Remarks: Shipment permitted Hazard inducer(s): ACETALDEHYDE

Formaldehyde EmS: F-E S-E

ADR


Class: 3 Packing group: III UN no.: UN 1993 Primary risk: 3 Hazard no. : 30 Remarks: Shipment permitted Hazard inducer(s): ACETALDEHYDE Formaldehyde

RID


Class: 3 Packing group: III UN no.: UN 1993 Primary risk: 3 Hazard no. : 30 Remarks: Shipment permitted Hazard inducer(s): ACETALDEHYDE

Formaldehyde 15) Information on Laws and Regulations

Regulatory information China GB 13690-2009 : General rule for classification and hazard communication of chemicals. GB 20576 - 20599, GB 20601-20602: Safety rules for classification, precautionary labelling and precautionary statements of chemicals. Decree No. 591 of the State Council of the People’s Republic of China: Regulations on the Control over Safety of Hazardous Chemicals. GB 6944-2012: Classification and code of dangerous goods. GB 12268-2012: List of dangerous goods. GB 190-2009: Packing symbol of dangerous goods.


Granofin PL liq (9)



16) Other information

The data are based on the current state of our knowledge, and are intended to describe the product with regard to the requirements of safety. The data should not be taken to imply any guarantee of a particular or general specification. It is the responsibility of the user of the product to ensure to his satisfaction that the product is suitable for the intended purpose and method of use. We do not accept responsibility for any harm caused by the use of this information. In all cases, our general conditions of sale apply.

msds granofin pl liq

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