msds chemical injection

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© 2014 Baker Hughes Incorporated. All rights reserved. AQUASWEEP is a trademark of Baker Hughes Incorporated. Disclaimer of Liability: This information is provided for general information purposes only a nd is believed to be accurate as of the date hereof; however, Baker Hughes Incorporated and its afliates do not make any warranties or representations of any kind regarding the information and disclaim all express and implied warranties or representations to the fullest extent permissible by law, including those of merchantability, tness for a particular purpose or use, title, non-infringement, accuracy, correctness or completeness of the information provided herein. All information is furnished “as is” and without any license to distribute. The user agrees to assume all liabilities related to the use of or reliance on such information. BAKER HUGHES INCORPORATED AND ITS AFFILIATES SHALL NOT BE LIABLE FOR ANY DIRECT, INDIRECT, SPECIAL, PUNITIVE, EXEMPLARY OR CONSEQUENTIAL DAMAGES FROM ANY CAUSE WHATSOEVER INCLUDING BUT NOT LIMITED TO ITS NEGLIGENCE. 40960 BPPOCRW85838 05/2014 Applications    Subsea pipelines    Land-based pipelines  Offshore risers and related piping systems Features and benets    Residuals easily monitored Minimizes treatment costs   Excellent partition into water phase  Effective treatment in pipeline systems   Combination formula  Easier mixing with single point injection Minimizes inventory   Designed for discharge to open sea and treatable by filtration if necessary  Minimizes disposal costs   Filtration methodology available to lower residuals in environment ally sensitive areas  Meets the most rigid permit requirements for discharge to open sea   Good thermal stability  Effective at topside and subsea temperatures Application The AQUASWEEP  CRW85838 pipeline hydrostatic test cocktail is a water soluble blend of lming amines, a lming quaternary salt and an oxygen scavenger, formulated for a broad application in the oil and gas market. It is water soluble and oil dispersible. In addition to providing corrosion and fouling protection against carbon dioxide and organic acids, the cocktail can be used in the performance of hydrotesting pipelines during pre-commissionin g services and laying a pipeline in wet stagnant conditions. The AQUASWEEP CRW85838 inhibitor cocktail absorbs oxygen and inhibits the development of bacteria-related corrosion. This includes microbial-inu enced corrosion (MIC) caused by oxygen, sulfate reducing bacteria (SRB), or other bacteria in the hydrotest water or pre- existing bacteria in the pipeline. The inhibitor cocktail’s excellent partitioning into the water phase makes it particularly suitable for pipelines and other areas where water may gather. The product exhibits high lm persistency. The AQU ASWEEP CRW85838 hydrotest inhibitor cocktail should be applied via continuous injection into the hydrostatic test water while lling the pipeline at the following concentration for the expected time period of protection desired. T ypical dosing recommendation: Environmental data CEFAS Gold-rated with no product or substitution warning. ECOTOX reports available upon request. Materials compatibility Materials suitabili ty is based on analysis of test results obtained under specied laboratory conditions. All materials selection should be based on actual application. Testing results for materials will be made available on request. Safety and handling Before handling, storage or use, review the Safety Data Sheet (SDS) for guidance. AQUASWEEP CRW85838 Pipeline Hydrotest Inhibitor Cocktail Reduces risk of bacteria in pipeline hydrostatic testing and layup water Typical properties (may include other properties not listed below) Appearance Amber liquid Specic gravity at 20°C (68°F) ~1.04 Pour point ~-15°C (5°F) Viscosity at 38°C (100°F) ~16 cSt Flash point > 70°C (>158°F) pH ~ 7 Solubility: Brine Soluble  Water Soluble ~ ~ ~ ~ Time protection desired Recommended dosing rate  1 to 3 months 300 ppm  6 to 18 months 500 ppm  18 to 24 months 700 ppm OVERVIEW | bakerhughes.com

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Page 1: MSDS Chemical Injection

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© 2014 Baker Hughes Incorporated. All rights reserved.

AQUASWEEP is a trademark of Baker Hughes Incorporated.

Disclaimer of Liability: This information is provided for general information purposes only a nd is believed to be accurate as of the date hereof; however, Baker Hughes Incorporated and its affiliates do not make any warranties or representations of any kind regardingthe information and disclaim all express and implied warranties or representations to the fullest extent permissible by law, including those of merchantability, fitness for a particular purpose or use, title, non-infringement, accuracy, correctness or completeness of theinformation provided herein. All information is furnished “as is” and without any license to distribute. The user agrees to assume all liabilities related to the use of or reliance on such information. BAKER HUGHES INCORPORATED AND ITS AFFILIATES SHALL NOT BELIABLE FOR ANY DIRECT, INDIRECT, SPECIAL, PUNITIVE, EXEMPLARY OR CONSEQUENTIAL DAMAGES FROM ANY CAUSE WHATSOEVER INCLUDING BUT NOT LIMITED TO ITS NEGLIGENCE.

40960 BPPOCRW85838 05/2014

Applications

   Subsea pipelines

   Land-based pipelines

 Offshore risers and related

piping systems

Features and benefits

   Residuals easily monitored

–Minimizes treatment costs

  Excellent partition into water phase

 – Effective treatment in

pipeline systems

  Combination formula

 – Easier mixing with single

point injection

– Minimizes inventory

  Designed for discharge to open

sea and treatable by filtration

if necessary

 – Minimizes disposal costs

  Filtration methodology available to

lower residuals in environmentally

sensitive areas

 – Meets the most rigid permit

requirements for discharge to

open sea

  Good thermal stability

 – Effective at topside and subsea

temperatures

ApplicationThe AQUASWEEP™ CRW85838 pipeline

hydrostatic test cocktail is a water soluble

blend of filming amines, a filming quaternary

salt and an oxygen scavenger, formulated

for a broad application in the oil and gas

market. It is water soluble and oil dispersible.

In addition to providing corrosion and fouling

protection against carbon dioxide and

organic acids, the cocktail can be used in the

performance of hydrotesting pipelines during

pre-commissioning services and laying a

pipeline in wet stagnant conditions.

The AQUASWEEP CRW85838 inhibitor cocktail

absorbs oxygen and inhibits the development

of bacteria-related corrosion. This includes

microbial-influenced corrosion (MIC) caused

by oxygen, sulfate reducing bacteria (SRB), or

other bacteria in the hydrotest water or pre-

existing bacteria in the pipeline. The inhibitor

cocktail’s excellent partitioning into the water

phase makes it particularly suitable for pipelines

and other areas where water may gather. The

product exhibits high film persistency.

The AQUASWEEP CRW85838 hydrotest inhibitor

cocktail should be applied via continuous

injection into the hydrostatic test water while

filling the pipeline at the following concentration

for the expected time period of protection

desired. Typical dosing recommendation:

Environmental dataCEFAS Gold-rated with no product or

substitution warning. ECOTOX reports

available upon request.

Materials compatibility

Materials suitability is based on analysis of

test results obtained under specified laboratory

conditions. All materials selection should be based

on actual application. Testing results for materials

will be made available on request.

Safety and handlingBefore handling, storage or use, review the

Safety Data Sheet (SDS) for guidance.

AQUASWEEP CRW85838 Pipeline Hydrotest Inhibitor CocktailReduces risk of bacteria in pipeline hydrostatic testing and layup water

Typical properties(may include other properties not listed below)

Appearance Amber liquid

Specific gravityat 20°C (68°F)

~1.04

Pour point ~-15°C (5°F)

Viscosity at 38°C (100°F) ~16 cSt

Flash point > 70°C (>158°F)

pH ~ 7

Solubility: Brine Soluble

  Water Soluble

~

~

~

~

Time protection desired Recommended dosing rate

  1 to 3 months 300 ppm

  6 to 18 months 500 ppm

  18 to 24 months 700 ppm

OVERVIEW| bakerhughes .com

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEETCRW85838

SECTION 1: Identification of the substance/mixture and of thecompany/undertaking

1.1 Product identifier 

Product name : CRW85838

Product code : CRW85838

Product description : Corrosion Inhibitor 

Product type : Liquid.

1.2 Relevant identified uses of the substance or mixture and uses advised against

Not available.

1.3 Details of the supplier of the safety data sheet

Baker HughesKirkby Bank Road,Knowsley Industrial Park,Liverpool,L33 7SY, UK

Tel: +44 (0)151 545 3899Fax: +44 (0)151 547 3590

e-mail address of personresponsible for this SDS

: [email protected]

1.4 Emergency telephone number 

Supplier 

Telephone number : CHEMTREC Emergency Telephone within UK: 0203 318 0470

CHEMTREC Emergency Telephone outside UK: +44 203 318 0470

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Product definition : Mixture

Classification according to Directive 1999/45/EC [DPD]

The product is classified as dangerous according to Directive 1999/45/EC and its amendments.

Classification : Xn; R22Xi; R36

Human health hazards : Harmful if swallowed. Irritating to eyes.

See Section 16 for the full text of the R phrases or H statements declared above.

See Section 11 for more detailed information on health effects and symptoms.

Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Signal word : Danger 

Hazard statements : Harmful if swallowed.Causes skin irritation.Causes serious eye damage.

Precautionary statements

Prevention : Wear protective gloves. Wear eye or face protection. Do not eat, drink or smokewhen using this product. Wash hands thoroughly after handling.

Response : Not applicable.

Storage : Not applicable.

Disposal : Dispose of contents and container in accordance with all local, regional, national andinternational regulations.

Date of issue/Date of revision : 7 June 2011   1/11

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CRW85838 

SECTION 2: Hazards identification

2.2 Label elements

Regulation (EC) No. 1272/2008 [CLP]

Hazard symbol or symbols :

Indication of danger : Harmful

Risk phrases : R22- Harmful if swallowed.R36- Irritating to eyes.

Safety phrases : Not applicable.

Hazardous ingredients :

Supplemental labelelements

: Not applicable.

2.3 Other hazards

Substance meets thecriteria for PBT accordingto Regulation (EC) No.1207/2006, Annex XIII

Not applicable.

P: Not available. B: Not available. T: Not available.

Substance meets thecriteria for vPvB accordingto Regulation (EC) No.1207/2006, Annex XIII

Not applicable.

vP: Not available. vB: Not available.

Other hazards which donot result in classification

: Not available.

SECTION 3: Composition/information on ingredients

Substance/mixture : Mixture

Classification

Product/ingredientname

Identifiers % 67/548/EEC Regulation (EC) No.1272/2008 [CLP]

Type

ethoxylated amine /acid salt

- 10 - 30 Xn; R22 Acute Tox. 4, H302 [1]

ethanediol EC: 203-473-3CAS: 107-21-1Index: 603-027-00-1

10 - 30 Xn; R22 Acute Tox. 4, H302 [1] [2]

2-(2-butoxyethoxy)ethanol

EC: 203-961-6CAS: 112-34-5Index: 603-096-00-8

5 - 10 Xi; R36 Eye Irrit. 2, H319 [1] [2]

didecyldimethylammonium

chlorideEC: 230-525-2CAS: 7173-51-5Index: 612-131-00-6

1 - 5 Xn; R22C; R34

 Acute Tox. 3, H301Skin Corr. 1B, H314Eye Dam. 1, H318

[1]

See section 16 for the full text of the R-phrases declaredabove

See Section 16 for thefull text of the Hstatements declaredabove.

There are no additional ingredients present which, within the current knowledge of the supplier and in the

concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in thissection.

Type

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CRW85838 

SECTION 3: Composition/information on ingredients

[1] Substance classified with a health or environmental hazard[2] Substance with a workplace exposure limit[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1207/2006, Annex XIII[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1207/2006, Annex XIII

Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures4.1 Description of first aid measures

Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 15minutes. Get medical attention.

Inhalation : Move exposed person to fresh air. Keep person warm and at rest. If not breathing,if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid togive mouth-to-mouth resuscitation. If unconscious, place in recovery position andget medical attention immediately. Maintain an open airway. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed personmay need to be kept under medical surveillance for 48 hours.

Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing andshoes. Get medical attention if symptoms occur. Wash clothing before reuse.Clean shoes thoroughly before reuse.

Ingestion : Wash out mouth with water. If material has been swallowed and the exposedperson is conscious, give small quantities of water to drink. If vomiting occurs, thehead should be kept low so that vomit does not enter the lungs. Get medicalattention. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately.Maintain an open airway.

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Itmay be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

4.2 Most important symptoms and effects, both acute and delayed

Potential acute health effects

Eye contact : Irritating to eyes.

Inhalation : Exposure to decomposition products may cause a health hazard. Serious effectsmay be delayed following exposure.

Skin contact : May cause skin irritation.

Ingestion : Harmful if swallowed.

Over-exposure signs/symptoms

Eye contact :  Adverse symptoms may include the following:irritationwatering

rednessInhalation : No specific data.

Skin contact : No specific data.

Ingestion : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed

Notes to medical doctor : In case of inhalation of decomposition products in a fire, symptoms may be delayed.The exposed person may need to be kept under medical surveillance for 48 hours.

Specific treatments : Not available.

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CRW85838 

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable : Use dry chemical, CO2, water spray (fog) or foam.

Not suitable : Do not use water jet.

5.2 Special hazards arising from the substance or mixture

Special exposure hazards : Combustible liquid. In a fire or if heated, a pressure increase will occur and thecontainer may burst, with the risk of a subsequent explosion.

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitabletraining. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Hazardous thermaldecomposition products

: Decomposition products may include the following materials:carbon dioxidecarbon monoxidenitrogen oxidessulfur oxideshalogenated compoundsmetal oxide/oxides

5.3 Advice for fire-fighters

Special protectiveequipment for fire-fighters

: Fire-fighters should wear appropriate protective equipment and self-containedbreathing apparatus (SCBA) with a full face-piece operated in positive pressuremode.

Additional information : Not available.

SECTION 6: Accidental release measures

6.1 Personal precautions,protective equipment andemergency procedures

: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilt material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Avoid breathing vapour or mist.Provide adequate ventilation. Wear appropriate respirator when ventilation is

inadequate. Put on appropriate personal protective equipment (see Section 8).6.2 Environmentalprecautions

: If specialised clothing is required to deal with the spillage, take note of anyinformation in Section 8 on suitable and unsuitable materials. See also Section 8 for additional information on hygiene measures.

6.3 Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mopup if water-soluble. Alternatively, or if water-insoluble, absorb with an inert drymaterial and place in an appropriate waste disposal container. Use spark-proof toolsand explosion-proof equipment. Dispose of via a licensed waste disposal contractor.

Large spill : Stop leak if without risk. Move containers from spill area. Approach the releasefrom upwind. Prevent entry into sewers, water courses, basements or confinedareas. Wash spillages into an effluent treatment plant or proceed as follows.

Contain and collect spillage with non-combustible, absorbent material e.g. sand,earth, vermiculite or diatomaceous earth and place in container for disposalaccording to local regulations. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminatedabsorbent material may pose the same hazard as the spilt product.

6.4 Reference to other sections

: Note: see section 8 for personal protective equipment and section 13 for wastedisposal.

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CRW85838 

SECTION 7: Handling and storage

7.1 Precautions for safehandling

: Put on appropriate personal protective equipment (see Section 8). Eating, drinkingand smoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking andsmoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathingvapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spacesunless adequately ventilated. Keep in the original container or an approved

alternative made from a compatible material, kept tightly closed when not in use.Store and use away from heat, sparks, open flame or any other ignition source. Useexplosion-proof electrical (ventilating, lighting and material handling) equipment.Use non-sparking tools. Take precautionary measures against electrostaticdischarges. To avoid fire or explosion, dissipate static electricity during transfer byearthing and bonding containers and equipment before transferring material. Emptycontainers retain product residue and can be hazardous. Do not reuse container.

7.2 Conditions for safe storage, including any incompatibilities

Storage : Store in accordance with local regulations. Store in a segregated and approvedarea. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food anddrink. Eliminate all ignition sources. Separate from oxidizing materials. Keepcontainer tightly closed and sealed until ready for use. Containers that have been

opened must be carefully resealed and kept upright to prevent leakage. Do not storein unlabelled containers. Use appropriate containment to avoid environmentalcontamination.

Recommended Packagingmaterials

: Use original container.

7.3 Specific end use(s) : Corrosion Inhibitor 

Not available.

SECTION 8: Exposure controls/personal protection

8.1 Control parametersOccupational exposure limits

Product/ingredient name Exposure limit values

ethanediol EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbedthrough skin.TWA: 10 mg/m³ 8 hour(s). Form: Particulate

  STEL: 104 mg/m³ 15 minute(s). Form: Vapour   TWA: 52 mg/m³ 8 hour(s). Form: Vapour   STEL: 40 ppm 15 minute(s). Form: Vapour   TWA: 20 ppm 8 hour(s). Form: Vapour 

2-(2-butoxyethoxy)ethanol EH40/2005 WELs (United Kingdom (UK), 8/2007).TWA: 10 ppm 8 hour(s).

  STEL: 15 ppm 15 minute(s).  STEL: 15 mg/m³ 15 minute(s).  TWA: 10 mg/m³ 8 hour(s).

Recommended monitoringprocedures

: If this product contains ingredients with exposure limits, personal, workplaceatmosphere or biological monitoring may be required to determine the effectivenessof the ventilation or other control measures and/or the necessity to use respiratoryprotective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents andnational guidance documents for methods for the determination of hazardoussubstances.

8.2 Exposure controls

Occupational exposurecontrols : Use only with adequate ventilation. Use process enclosures, local exhaustventilation or other engineering controls to keep worker exposure to airbornecontaminants below any recommended or statutory limits. The engineering controlsalso need to keep gas, vapour or dust concentrations below any lower explosivelimits. Use explosion-proof ventilation equipment.

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CRW85838 

SECTION 8: Exposure controls/personal protection

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period.

 Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations andsafety showers are close to the workstation location.

Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection mustbe based on known or anticipated exposure levels, the hazards of the product andthe safe working limits of the selected respirator.

Hand protection : Chemical-resistant, impervious gloves complying with an approved standard shouldbe worn at all times when handling chemical products if a risk assessment indicatesthis is necessary.

Eye protection : Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts.

Skin protection :  Appropriate footwear and any additional skin protection measures should beselected based on the task being performed and the risks involved and should beapproved by a specialist before handling this product.

Environmental exposurecontrols

: Emissions from ventilation or work process equipment should be checked to ensurethey comply with the requirements of environmental protection legislation. In somecases, fume scrubbers, filters or engineering modifications to the process equipmentwill be necessary to reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state : Liquid.

Colour :  Amber.

Odour : Odourless.

Odour threshold : Not available.pH : 7.4

Boiling point : Not available.

Melting point/freezingpoint

: Not available.

Flammability (solid, gas) : May be combustible at high temperature.

Flash point : Closed cup: >70°C (>158°F) [PMCC]

Explosive properties : Not available.

Explosion limits : Not available.

Oxidising properties : Not available.

Vapour pressure : Not available.Density : Not available.

1.005 to 1.075 (16°C)Relative density :

Easily soluble in the following materials: cold water.Solubility :

Partition coefficient: n-octanol/water 

: Not available.

Viscosity : Kinematic (40°C): 15.7 cSt

Vapour density : Not available.

Evaporation rate (butylacetate = 1)

: Not available.

Decomposition

temperature

: Not available.

Auto-ignition temperature : Not available.

9.2 Other information

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CRW85838 

SECTION 9: Physical and chemical properties

Pour point : Not available.

SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability : The product is stable.10.3 Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid :  Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition.

10.5 Incompatiblematerials

: Reactive or incompatible with the following materials:oxidizing materials

10.6 Hazardousdecomposition products

: Under normal conditions of storage and use, hazardous decomposition productsshould not be produced.

SECTION 11: Toxicological information

Potential acute health effects

Inhalation : Exposure to decomposition products may cause a health hazard. Serious effectsmay be delayed following exposure.

Ingestion : Harmful if swallowed.

Skin contact : May cause skin irritation.

Eye contact : Irritating to eyes.

Acute toxicity

Product/ingredient name Result Species Dose Exposure

ethanediol LD50 Dermal Rabbit 9530 uL/kg -LD50 Oral Rat 4700 mg/kg -

2-(2-butoxyethoxy)ethanol LD50 Dermal Rabbit 2700 mg/kg -LD50 Oral Rat 4500 mg/kg -

didecyldimethylammoniumchloride

LD50 Dermal Rabbit 4177 mg/kg -

LD50 Oral Rat 84 mg/kg -LD50 Oral Rat 560 mg/kg -

General : No known significant effects or critical hazards.

Carcinogenicity : No known significant effects or critical hazards.

Mutagenicity : No known significant effects or critical hazards.

Teratogenicity : No known significant effects or critical hazards.

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.Inhalation : No specific data.

Ingestion : No specific data.

Skin contact : No specific data.

Eye contact :  Adverse symptoms may include the following:irritationwateringredness

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CRW85838 

SECTION 12: Ecological information

12.1 Toxicity : No known significant effects or critical hazards.

Aquatic ecotoxicity

Product/ingredient name Result Species Exposure

ethanediol Acute LC50 >18500 mg/L Fresh water Fish - Oncorhynchus mykiss 96 hours2-(2-butoxyethoxy)ethanol Acute LC50 1300000 ug/L Fresh water Fish - Lepomis macrochirus - 33

to 75 mm96 hours

didecyldimethylammoniumchloride  Acute EC50 0.026 mg/l Algae 96 hours

 Acute EC50 18 to 22 ppb Fresh water Daphnia - Daphnia magna - <20hours

48 hours

 Acute EC50 240 ug/L Fresh water Fish - Poecilia reticulata - 21 to28 days

96 hours

 Acute EC50 11 mg/l Micro-organism 3 hours Acute LC50 39 ug/L Marine water Crustaceans - Americamysis

bahia - Juvenile (Fledgling,Hatchling, Weanling)

48 hours

 Acute LC50 1 mg/l Fish 96 hoursChronic NOEC 0.01 mg/l Daphnia 21 daysChronic NOEC 0.032 mg/l Fish 34 days

Conclusion/Summary : Not available.12.2 Persistence and degradability

Product/ingredient name Test Result Dose Inoculum

didecyldimethylammonium chloride OECD 303 A 91 % - 50 days - -OECD 302 B302B InherentBiodegradability:Zahn-Wellens/EMPATest

87 to 94 % - 28days

- -

OECD 301 B 72 % - Readily -28 days

- -

Conclusion/Summary : Not available.Product/ingredient name Aquatic half-life Photolysis Biodegradabilitydidecyldimethylammonium chloride - - Readily

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential

Not available.

12.4 Mobility in soil : Not available.

12.5 Results of PBT and vPvB assessment

PBT : Not applicable.

P: Not available. B: Not available. T: Not available.

vPvB : Not applicable.

vP: Not available. vB: Not available.

12.6 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should beconsulted for any available use-specific information provided in the Exposure Scenario(s).

13.1 Waste treatment methods

Product

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CRW85838 

SECTION 13: Disposal considerationsMethods of disposal : The generation of waste should be avoided or minimised wherever possible. Empty

containers or liners may retain some product residues. This material and itscontainer must be disposed of in a safe way. Significant quantities of waste productresidues should not be disposed of via the foul sewer but processed in a suitableeffluent treatment plant. Dispose of surplus and non-recyclable products via alicensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmentalprotection and waste disposal legislation and any regional local authority

requirements. Avoid dispersal of spilt material and runoff and contact with soil,waterways, drains and sewers.

Hazardous waste : The classification of the product may meet the criteria for a hazardous waste.

Packaging

Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Emptycontainers or liners may retain some product residues. Waste packaging should berecycled. Incineration or landfill should only be considered when recycling is notfeasible.

13.2 Additional information

Special precautions : This material and its container must be disposed of in a safe way. Care should betaken when handling emptied containers that have not been cleaned or rinsed out.

Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

SECTION 14: Transport information

International transport regulations

Regulatoryinformation

14.1 UNnumber 

14.2 Proper shipping name 14.3 Transporthazard class(es)

14.4 PG* Label

ADR/RID Class Notregulated.

- -

ADN/ADNR Class Notregulated. - -

IMDG Class Notregulated.

- -

IATA Class Notregulated.

- -

PG* : Packing group

Regulatoryinformation

14.5Environmentalhazards

14.6 Special precautions for user Additionalinformation

ADR/RID Class No. - -

ADN/ADNR Class No. - -

IMDG Class No. - -

IATA Class No. - -

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Proper shipping name : Not available.

Ship type : Not available.

Pollution category : Not available.

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CRW85838 

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EU Regulation (EC) No. 1907/2006 (REACH)

Annex XIV - List of substances subject to authorisation

Substances of very high concern

None of the components are listed.

Annex XVII - Restrictions

on the manufacture,placing on the market anduse of certain dangeroussubstances, mixtures andarticles

: Not applicable.

Other EU regulations

Europe inventory : Not determined.

Black List Chemicals : Not listed

Priority List Chemicals : Listed

15.2 Chemical SafetyAssessment

: This product contains substances for which Chemical Safety Assessments are stillrequired.

SECTION 16: Other information

16.1 Revision comments : Not available.

Indicates information that has changed from previously issued version.

16.2 Abbreviations andacronyms

:  ATE = Acute Toxicity EstimateCLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.1272/2008]DNEL = Derived No Effect Level

EUH statement = CLP-specific Hazard statementPNEC = Predicted No Effect ConcentrationRRN = REACH Registration Number 

16.3 Key literaturereferences and sources for data

: Not available.

16.4 Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

 Acute Tox. 4, H302Skin Irrit. 2, H315Eye Dam. 1, H318

Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Classification Justification Acute Tox. 4, H302 Calculation methodSkin Irrit. 2, H315 Calculation methodEye Dam. 1, H318 Calculation method

16.5 Full text of abbreviatedH statements

: H301 Toxic if swallowed.H302 Harmful if swallowed.H314 Causes severe skin burns and eye damage.H315 Causes skin irritation.H318 Causes serious eye damage.H319 Causes serious eye irritation.

Full text of classifications[CLP/GHS]

:  Acute Tox. 3, H301 ACUTE TOXICITY: ORAL - Category 3 Acute Tox. 4, H302 ACUTE TOXICITY: ORAL - Category 4

Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2Skin Corr. 1B, H314 SKIN CORROSION/IRRITATION - Category 1BSkin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CRW85838 

SECTION 16: Other information

16.5 Full text of abbreviatedR phrases

: R22- Harmful if swallowed.R34- Causes burns.R36- Irritating to eyes.

Full text of classifications[DSD/DPD]

: C - CorrosiveXn - HarmfulXi - Irritant

16.6 Training advice : Not available.

16.7 Further information

Date of issue/ Date of revision

: 7 June 2011

Version : 1

Notice to reader 

This information relates only to the specific material designated and may not be valid for such material used incombination with any other materials or in any process. Such information is, to the best of the company'sknowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfyhimself as to the suitability of such information for his own particular use.

Date of issue/Date of revision : 7 June 2011   11/11