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25 th May 2018 Prague MSAR® Technology - Emulsion Fuel for Power Generation, Marine Bunkers & Refinery Uses

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Page 1: MSAR® Technology - Emulsion Fuel for Power Generation ... MB BBTC 2018.pdf · low CAPEX, short cycle, upgrading solutions for HFO pool How it works: Tiny droplets of extra-viscous

25th May 2018Prague

MSAR® Technology - Emulsion Fuel for Power Generation, Marine Bunkers & Refinery Uses

Page 2: MSAR® Technology - Emulsion Fuel for Power Generation ... MB BBTC 2018.pdf · low CAPEX, short cycle, upgrading solutions for HFO pool How it works: Tiny droplets of extra-viscous

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• Quadrise is the supplier of proprietary, proven MSAR® technology.

• A low viscosity “synthetic HFO” is produced by blending heavy residue streams without adding cutter, improving refinery margins.

• The technology and fuel are proven and verified at commercial scale.

• MSAR® emulsion fuels are used as direct substitutes for HFO in power and marine applications, and potentially refinery refuelling.

• Economic and environmental benefits for producer and consumer.

• IP is developed and protected jointly with Akzo Nobel and MSAR® projects are being developed with major global companies.

• QFI plc is listed on the London Stock Exchange (AIM companies).

= Multiphase Superfine Atomised Residue

Introduction to Quadrise

Industry participants:

Page 3: MSAR® Technology - Emulsion Fuel for Power Generation ... MB BBTC 2018.pdf · low CAPEX, short cycle, upgrading solutions for HFO pool How it works: Tiny droplets of extra-viscous

Quadrise licenses, operates & provides MSAR® technology, additives & services to

produce a stable ‘Oil-in-Water’ emulsion fuel

Delivers HFO consumers tangible cost savings & environmental benefits

MSAR® provides refiners with low CAPEX, short cycle, upgrading

solutions for HFO pool

How it works: Tiny droplets of extra-viscous heavy hydrocarbons are dispersed in water using proprietary processes and additives

Key benefits: ✓ Refinery yield improvement✓ Water & chemicals replace cutters✓ Blend ‘incompatible’ residue streams✓ Simple, low risk implementation

Key benefits: ✓ Stable, lower cost fuel

synthetic HFO ✓ Enhanced combustion &

lower emissions (NOx, PM)

Overview

MSAR® stands for Multiphase Superfine Atomised Residue

Quadrise technology adds value to refineries and fuel oil consumers

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Page 4: MSAR® Technology - Emulsion Fuel for Power Generation ... MB BBTC 2018.pdf · low CAPEX, short cycle, upgrading solutions for HFO pool How it works: Tiny droplets of extra-viscous

MSAR® Technology

Solid, viscous residues

✓ Refinery residue streams from VR to SDA pitch.

✓ Petchem reaction residues✓ 1,000 – 100,000,000 cSt @ 100°C

Crude

“Semi-complex” Refinery

Premium fuels

Residues

Bitumen

Fuel Oil

Fuel Oil Market

Water & Additives

2

3

1

MSAR®Unit

“Plug & Play” Refinery Technology

Water ~29%~70%

Additives <1%

✓ Can be derived from utility, waste or stripped sour water sources

Oil residues are taken direct from refinery rundown lines and cooled to achieve the required viscosity (~200-1000cSt @ 100-200oC typically) for the colloid mill.

Water, together with proprietary additives, is added to the residue in a high-speed colloid mill under pressure.

The mixture is processed in the mill and cooled to provide a highly stable oil-in-water fuel oil equivalent (~200cSt at 50oC) that can be run down to existing fuel oil tanks.

1 2 3

The blending hardware is based on proven asphalt emulsion systems.100 units+ worldwide

4

Page 5: MSAR® Technology - Emulsion Fuel for Power Generation ... MB BBTC 2018.pdf · low CAPEX, short cycle, upgrading solutions for HFO pool How it works: Tiny droplets of extra-viscous

Project Timeline

ScopingRefinery residue

stream identified.

Conceptual design and feasibility study.

Pilot Testing

Pilot testing at QRF*, additive

formulation optimized based on end-use application and product specs.

FEED

Scope developed and a design prepared for

implementation. Quadrise provide client training and

experience.

EPC

Implementation/ integration of

MSAR® project in modular, scalable,

containerised units.

OperationsOngoing support from Quadrise to

maintain optimum performance.

5

1-2 months 3-4 months 6-12 months

*QRF = Quadrise Research Facility MSAR® installation at Cepsa San Roque Refinery

A 6KBPD MSAR® project costs ~$5m and is

implemented within 12 months.

Page 6: MSAR® Technology - Emulsion Fuel for Power Generation ... MB BBTC 2018.pdf · low CAPEX, short cycle, upgrading solutions for HFO pool How it works: Tiny droplets of extra-viscous

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vs. HFO (RMG)

Water• MSAR® contains ~30% water, resulting in a

reduced calorific value compared to HFO.• Typically 50% more fuel required (factored

into economics).• Water along with micro droplet size

enhances the combustion process.

Density• MSAR® density is higher as residue based.

Viscosity• MSAR® Viscosity is lower as it is a function

of the water in the bulk phase.

Sulphur• Like HFO, MSAR® contains sulphur as a

function of the residue.

Characteristic LimitCategory

ISO-F-ISO Test Method

RMG 380 Reference Marine Grade

Density at 15°c, kg/m³ max. 991,0 ISO 3675 / ISO 12185 1050,0

Kinematic Vicosity at 50°c, mm² max. 380,0 ISO 3104 180,0*

Flash Point °c min. 60 ISO 2719 60

Pour Point (upper)

Winter Quality °c max. 30 ISO 3016 N/A

Summer Quality °c max. 30 ISO 3016 N/A

Carbon Residue, % (m/m) max. 18 ISO 10370 20

Ash, % (m/m) max. 0,15 ISO 6245 0,3

Water, % (v/v) max. 0,5 ISO 3733 33,0

Sulfur, % (m/m) max. 3,5 ISO 14597 / 8754 3,5

Acid number, mg KOH/g max. 2,5 2,5

Hydrogen Sulfide, mg/kg max. 2,0 IP 570 Part A 2,0

Vanadium, mg/kg max. 350 ISO 14597 / IP 501 350

Sodium, mg/kg max. 100 ISO 14597 / IP 501 100

Total Sediment Potential, % (m/m) max. 0,10 ISO 10307-2 N/A

Aluminium plus Silicon, mg/kg max. 80 ISO 10478 15

Used lubricating oil (ULO) max*

Zinc, mg/kg 15 IP 501/IP 470 N/A

Phosphorus, mg/kg 15 IP 501/IP 470 N/A

Calcium, mg/kg 30 IP 501/IP 470 N/A

* = at 100s -1

N/A = Not

relevant for

emulsion fuel

* The fuel shall be considered free of ULO if one or more

elements Zn, P and Ca are below or at the specified limits.

All three elements shall exceed the same limits before a

fuel shall be deemed to contain ULO.

Comparison of ISO8217:2010 marine residual fuel (RMG) versus MSAR®

Page 7: MSAR® Technology - Emulsion Fuel for Power Generation ... MB BBTC 2018.pdf · low CAPEX, short cycle, upgrading solutions for HFO pool How it works: Tiny droplets of extra-viscous

An additional 20% of higher value fuel can be sold by the refinery at the market rate vs HFO value

Refinery output

Refinery output

HFO

Traditional refinery process An MSAR® refinery

High value fuels used to dilute HFO

Residual fuels

Water & <1% chemicals

Every barrel of high value premium fuel used to create HFO is lost margin to the refinery

Value is created via a significant refinery yield shift due to upgrading cutter from the fuel oil pool to the distillate pool.

50%

20%

30% 70% 30%

MSAR®

High valuetransport fuels

HFO example60% residue 40% diluent

70% residue 30% water &

chemicals

* Price of MSAR® < HFO on a per unit of energy basis

Economic drivers for MSAR®

7

Page 8: MSAR® Technology - Emulsion Fuel for Power Generation ... MB BBTC 2018.pdf · low CAPEX, short cycle, upgrading solutions for HFO pool How it works: Tiny droplets of extra-viscous

MSAR® production per MSAR® Unit = 1000 mt/d 350,000mt/yr MSAR® % Resid in MSAR® = 70% = 245,000mt/yr Residue feed

Market Prices (USD/MT) Gasoil, 0.1wt% S = 632 HFO 3.5%S = 262 at refinery gate Gasoil / Fuel Oil spread = $370/mt

Refinery Fuel Oil Blend Assumed $/mt Viscosity, cSt@50°C wt % mt/yr Shell V50 Comments

Heavy Fuel Oil, 3.5wt% S 262 380 100% 410,620 33.0 Mitsui futures. MED FOB. 2020

made from… Cutter Stock (LCO) 537 6.5 40% 165,620 17.1 85% Market gasoil value assumed

and… Refinery Residue 77 250,000 60% 245,000 43.7 Netback value (HFO & LCO $/t and blend ratio)

Step 1… Derive the value of the residue per ton on a netback Basis, i.e. value of HFO less the cost of distillates (LCO)

MSAR® Blend Economics $/mt Ratio (wt%) $/mt of MSAR®

Refinery Residue 77 x 70% = 54

OPEX (Water 29%, Additives <1%, etc) 35 x 30% = 35

MSAR® Cost of Production (variable cost basis) = 89

Step 3… Adjust MSAR® value for lower NCV and compare HFO fuel savings on a “like for like” energy basis

Assumptions: HFO NCV = 40.8 GJ/mt Resid NCV (GJ/mt) = 39.5 GJ/mt therefore… MSAR® NCV = 27.11 GJ/mt

Cost of MSAR® on HFO basis = 40.8 / 27.1 x $89/mt = $133/mt HFO MSAR® cost normalised for NCV (HFO equiv.)

Margin for MSAR® vs HFO (normalised for NCV) = 262 - 133 = $129/mt HFO Step 4… Calculate MSAR® Margin (to be shared)

($129/mt HFO x 27.1 / 40.8) = $86/mt MSAR® x 350,000mt/yr MSAR® = $30 million/yr 49% Discount vs HFO. ($/mt to be shared)

Generic Refinery Economics; Vacuum residue cut with LCO for 380cSt HFO vs Quadrise MSAR®

Step 2… Calculate the cost of MSAR®/t = (Residue

+ water + additives)

- typical range $25/mt (Power) - $35/mt

(Marine)

Refinery economics (2H 18 example)

8

Step 3… Adjust for lower calorific value and compare savings “like for like” vs HFO.

MSAR vs HFO = [ HFO value – distillate savings + additive costs ] x Net Calorific Value Adjustment

Step 2… Calculate the cost of MSAR® (residue + water + additives)

Step 1… Derive the value of the residue per ton, based on value of HFO less the cost of distillates (LCO)

Step 4… MSAR® value to be shared, (assumed 50% to refinery)…

Page 9: MSAR® Technology - Emulsion Fuel for Power Generation ... MB BBTC 2018.pdf · low CAPEX, short cycle, upgrading solutions for HFO pool How it works: Tiny droplets of extra-viscous

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• Positive for QFI and the MSAR® fuel solution:

• Wider distillate – fuel oil ‘spreads’ create even stronger economics.

• High margins combined with low CAPEX, <$5million for 6KBPD MSAR®, and quick implementation, <12mths, result in <2 year payback providing low risk, short cycle projects.

• MSAR® is compatible with ECGS (“scrubber”) so positive for End Users with EGCS as it enables affordable compliance with environmental standards.

• MSAR® can be both a permanent or interim solution based on other upgrading projects.

Impact of MEPC 2020 on MSAR® Economics

Courtesy of S&P Global Platts

Page 10: MSAR® Technology - Emulsion Fuel for Power Generation ... MB BBTC 2018.pdf · low CAPEX, short cycle, upgrading solutions for HFO pool How it works: Tiny droplets of extra-viscous

✓MSAR® is stored & transported at ambient temperatures (>25oC)

1. Energy Savings

2. Efficient Combustion

✓Complete Carbon burnout = lower dust emissions = less Black Carbon

With MSAR®: Tiny droplets of residue are dispersed in water

5-10 micron droplets

4. Lower CO2 Impact✓Considerable CO₂ emission savings of 6%

CO₂ using EGCS vs. <0.5%S fuel.

Economic & Environmental Benefits

10

BURNING HFO:

MSAR®:

Source: Concawe Report 1/13R (EU Refineries) 2013

3. Lower NOx Emissions✓Water reduces the combustion temperature

= >20% lower NOx emitted

Page 11: MSAR® Technology - Emulsion Fuel for Power Generation ... MB BBTC 2018.pdf · low CAPEX, short cycle, upgrading solutions for HFO pool How it works: Tiny droplets of extra-viscous

Cepsa MSAR® Installation• 6 KBPD MSAR® system installed at the CEPSA 240 KBPD Gibraltar San Roque Refinery for Marine & Power

• Quadrise responsible for MSAR® system installation, commissioning, operations & quality control

• MSAR® system designed to supply Marine or Power end users, installed in 9 months for <$5m

• Processing visbreaker residue from a wide range of sweet and sour opportunity crudes

• Proven, reliable, 24/7, continuous operation

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Page 12: MSAR® Technology - Emulsion Fuel for Power Generation ... MB BBTC 2018.pdf · low CAPEX, short cycle, upgrading solutions for HFO pool How it works: Tiny droplets of extra-viscous

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Our Focus on HFO Applications

• MSAR® is proven in Wärtsilä 4-stroke diesel engines.

• JDA with Maersk commenced in 2008 to demonstrate MSAR® use in large 2-stoke diesel propulsion engines.

• Successful laboratory and land-based tests (2009-2013) leading to sea-borne 2014 “Proof of Concept” vessel tests.

• “Operational LONO Trial” with Cepsa & Maersk 2016/17.

• Interim LONO received from Wärtsilä for Flex Engine Types.

Diesel Engines (Marine & Power)• Significant worldwide emulsion fuel boiler experience.

• Experience applied to MSAR® improvements.

• >60 million tons emulsion fuel fired: 50MWth to 770MWe

Plus Cement Kilns,Fired Heaters etc…

Steam Boilers (Power & Utilities)

Page 13: MSAR® Technology - Emulsion Fuel for Power Generation ... MB BBTC 2018.pdf · low CAPEX, short cycle, upgrading solutions for HFO pool How it works: Tiny droplets of extra-viscous

Global Applications Summary

Marine

• Term supply options with bunker buyers to further improve scrubber economics.

• OEM (MAN & Wärtsilä) approvals for MSAR® use alongside scrubbers.

Complementary Solutions

• Refinery heaters and boilers.

• National Oil Company synergies to provide MSAR® for Marine & Power.

• Selected upstream & petrochemical residue opportunities.

Power

• Opportunities for KSA PowerGensupply 400-500KBPD HFO.

• MoA signed with JGC Corporation to develop MSAR® projects in Japan and elsewhere.

• Supply into Middle East, Asia etc.

• Potential funding of emissions control equipment.

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Page 14: MSAR® Technology - Emulsion Fuel for Power Generation ... MB BBTC 2018.pdf · low CAPEX, short cycle, upgrading solutions for HFO pool How it works: Tiny droplets of extra-viscous

25th May 2018Prague

MSAR® - Emulsion Fuel for Power Generation, Marine Bunkers & Refinery Uses

Thank you / Děkuji- questions welcome!

Further info available:

www.quadrisefuels.com or [email protected]