molecular orbitals. organic compounds are organised into groups according to similarities and...
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Molecular Orbitals
Organic compounds are organised into groups according to similarities and differences in their structure.
Groups of atoms within a molecule give the molecule specific characteristic properties.
These groups of atoms are known asFUNCTIONAL GROUPS.
Compounds containing only carbon and hydrogen.
Hydrocarbons
Sub-divisions.AlkanesAlkenesAlkynes
Cycloalkanes
Saturated
Alkanes
General formula CnH2n+2
All carbon atoms form 4 single covalent bonds
4 bonding pairs of electrons round each CThese pairs mutually repel and take up a TETRAHEDRAL
arrangement
CH H
H
H
Alkanes
Carbon atom Ground stateElectron arrangement 1s2 2s2 2p2
The 2p2 electrons occupy 2 of the 3 p orbital (Hund’s Rule)
2 unpaired electrons only 2 covalent bonds?
No! Methane = CH4 => 4 bonds
1s2 2p22s2
This is explained by the idea of Hybrid orbitals.
Hybrid orbitals are the result of ‘mixing’ orbitals to produce a new set of orbitals.
(Mathematical basis for this doing this is based on the SchrÖdinger wave equations – not needed at this level!)
Spectroscopic measurements show that all four bonds in methane are identical.
Alkanes
One of the 2s electron is promoted to the third p orbital.
This produces 4 Hybrid orbitals of equal energy containing single electrons.
This is known as sp3 hybridisation
Atom after hybridisation
sp3
Atom before hybridisation s
p
Alkanes
Atom after hybridisation
sp3
Atom before hybridisation s
p
Compare the shape of the p orbital for carbon with that of the sp3 orbital.The hybrid orbital is more directional in shape better overlap when forming bonds +
stronger bonds + forms 4 bonds.
Alkanes
For simplicity, the smaller lobe is often omitted from diagrams
Alkanes
Alkane - methane
H
C
H
H
H
sp3 hybrid orbital of carbon
1s orbital of hydrogen
CH
H
H
H
molecular orbitals of methane molecule
Overlap of a half-filled sp3 hybrid orbital with a half-filled 1s orbital of a hydrogen atom forms a new molecular orbital The shared pair of electrons are now under the influence of both nuclei.
The new molecular orbital lies along the axis joining the two nuclei and is known as a SIGMA (σ ) BOND.A sigma bond is formed by end-on overlap of atomic orbitals.
This model is consistent with the fact that all the bond angles in alkanes are 109.5° (the tetrahedral bond angle).
Alkanes
Alkane - ethanemolecular orbitals of ethane
molecule
CC
H HH H
HH
Bonding in alkenes
Alkenes unsaturated hydrocarbons molecules contain at least one carbon to carbon double bond. How is a double bond formed?
The explanation must fit the observed facts.
Bonding in alkenes How is a C = C bond formed?
The observed facts.
The ethene molecule is flat and all bond angles are 120°.
The C = C bond is shorter than the single bond.
The C=C bond strength is intermediate between a single and a triple bond but not twice as strong as a single bond.
There is restricted rotation around the C=C bond.
There are two isomers of but-2-ene which differ only in the position of the methyl groups. In one, they are on the same side of the double bond, while in the other they
are on opposite sides. (Stereoisomerism).
The two isomers of but-2-ene
C CH
HCH3
CH3
C CH H
CH3CH3Trans - isomer Cis - isomer
The formation of the C=C is explained by hybridisation.
Bonding in alkenes
The formation of the C=C involves sp2 hybridisation
Bonding in alkenes
Atom after hybridisationAtom uses the 2s orbital
andonly two of the 2p orbitals
Atom before hybridisation
1s2
2p22s2
1s2
p3 x sp2
hybrid orbitals
Unhybridised p orbital
sp2 hybridisationBonding in alkenes
On mathematically mixing these, three identical hybrid orbitals are obtained.
These lie in the same plane at 120° to each other and at 90° to the remaining p orbital
This is called sp2 hybridisationand
the new orbitals are called sp2 hybrid orbitals.
C
Three sp2 hybrid orbitals
unhybridised 2p orbital
H H
H H
SIGMA (σ ) BONDS
A sigma bond is formed by end-on overlap of atomic orbitals.
H H
H H
Unhybridised p orbitals are close enough to overlap aboveand below the plane of the sp2 bonds.
This produces a new molecular orbital between the 2 carbon atoms with lobes above and below the molecular plane.
This bond is called a pi (π) bond
This extra bond pulls the carbon atoms closer together – bond length shortens
Sideways overlap produces a weaker bond than the end-on overlap
C=C isn’t 2 x as strong as C-C
Resistance to rotation
π overlap is more effective when the p orbitals are parallelAny other position and the overlap is reduced – the bond will eventually be broken
The Bonding Continuum
The molecular orbital formed from overlapping atomic orbitals is symmetrical around a mid-point where the bonding electrons are most likely to be found.
Pure Covalent Bonds – Non -polar
Polar Covalent Bonds
When there is a large difference between the electronegativities of the two elements involved in the bond, the bonding molecular orbital will be asymmetrical.
Colour in Molecules
Colour in Molecules
Colour in Molecules
Colour in Molecules
Colour in MoleculesOrganic molecules contain bonding orbitals (s and p ) and non-bonding (lone pair) orbitals ( usuallydesignated with the letter n ). In addition they also have anti-bonding orbitals (s* and p*).
Colour in Molecules
Colour in Molecules
With increased possibilities for both bonding and antibonding orbitals in larger conjugated systems, the gap between the highest occupied (bonding) molecular orbital (HOMO) and the lowest unoccupied (antibonding) molecular orbital (LUMO) is decreasing.
Buta-1,3-diene, again, only absorbs in the UV region of the electromagnetic spectrum but molecules withlarger conjugated systems will absorb from the Visible spectrum and produce colours.
For example, lycopene which is responsible for the red colour in tomatoes.
Colour in Molecules
Colour in Molecules