model of a heavy metal adsorption system using the s-layer ... · presented at the 2011 comsol...

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Presented at the 2011 COMSOL Conference in Boston Model of a Heavy Metal Adsorption System Using the S-Layer of Bacillus sphaericus Juan Pablo Orjuela Urban and Regional Sustainability Group Universidad de los Andes Bogota - Colombia

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Page 1: Model of a Heavy Metal Adsorption System Using the S-Layer ... · Presented at the 2011 COMSOL Conference in Boston Model of a Heavy Metal Adsorption System Using the S-Layer of Bacillus

Presented at the 2011 COMSOL Conference in Boston Model of a Heavy Metal Adsorption System Using the S-Layer of Bacillus sphaericus

Juan Pablo Orjuela

Urban and Regional Sustainability Group Universidad de los Andes

Bogota - Colombia

Page 2: Model of a Heavy Metal Adsorption System Using the S-Layer ... · Presented at the 2011 COMSOL Conference in Boston Model of a Heavy Metal Adsorption System Using the S-Layer of Bacillus

Heavy metals and water

Page 3: Model of a Heavy Metal Adsorption System Using the S-Layer ... · Presented at the 2011 COMSOL Conference in Boston Model of a Heavy Metal Adsorption System Using the S-Layer of Bacillus

Bacillus sphaericus

Page 4: Model of a Heavy Metal Adsorption System Using the S-Layer ... · Presented at the 2011 COMSOL Conference in Boston Model of a Heavy Metal Adsorption System Using the S-Layer of Bacillus

Tunjuelito meets Bacillus sphaericus

Page 5: Model of a Heavy Metal Adsorption System Using the S-Layer ... · Presented at the 2011 COMSOL Conference in Boston Model of a Heavy Metal Adsorption System Using the S-Layer of Bacillus

Let’s model this!

• Single porosity model

• Langmuir’s Isotherm

Page 6: Model of a Heavy Metal Adsorption System Using the S-Layer ... · Presented at the 2011 COMSOL Conference in Boston Model of a Heavy Metal Adsorption System Using the S-Layer of Bacillus

Use of COMSOL Multiphysics

• 2D • Mass transfer module • Chemical Species Transport / chpm

Page 7: Model of a Heavy Metal Adsorption System Using the S-Layer ... · Presented at the 2011 COMSOL Conference in Boston Model of a Heavy Metal Adsorption System Using the S-Layer of Bacillus

Global parameters

• Experimental: – Langmuir – Time for saturation – Density – Porosity – Initial concentrations

• Literature: – Dm – E – Km

Page 8: Model of a Heavy Metal Adsorption System Using the S-Layer ... · Presented at the 2011 COMSOL Conference in Boston Model of a Heavy Metal Adsorption System Using the S-Layer of Bacillus

Geometry

Page 9: Model of a Heavy Metal Adsorption System Using the S-Layer ... · Presented at the 2011 COMSOL Conference in Boston Model of a Heavy Metal Adsorption System Using the S-Layer of Bacillus

Species transport in porous media

Page 10: Model of a Heavy Metal Adsorption System Using the S-Layer ... · Presented at the 2011 COMSOL Conference in Boston Model of a Heavy Metal Adsorption System Using the S-Layer of Bacillus

Results

Page 11: Model of a Heavy Metal Adsorption System Using the S-Layer ... · Presented at the 2011 COMSOL Conference in Boston Model of a Heavy Metal Adsorption System Using the S-Layer of Bacillus

Results II

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Page 12: Model of a Heavy Metal Adsorption System Using the S-Layer ... · Presented at the 2011 COMSOL Conference in Boston Model of a Heavy Metal Adsorption System Using the S-Layer of Bacillus

Results II

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0 1000 2000 3000 4000

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g/l)

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Page 13: Model of a Heavy Metal Adsorption System Using the S-Layer ... · Presented at the 2011 COMSOL Conference in Boston Model of a Heavy Metal Adsorption System Using the S-Layer of Bacillus

Conclusions

• The model shows some really good preliminary results

• 1-D analysis is a good option

• Particle size has a greater effect than inflow speed

• Relationship between surface area and diffusivity coefficient ?

• Scale-up?

Page 14: Model of a Heavy Metal Adsorption System Using the S-Layer ... · Presented at the 2011 COMSOL Conference in Boston Model of a Heavy Metal Adsorption System Using the S-Layer of Bacillus

Acknowledgements

• Civil and Environmental Engineering Department • Urban and Regional Sustainability Group • Chemical Engineering Department • Biology Department • Nathalia Flórez • Andrea García • Andrés Gonzalez

Page 15: Model of a Heavy Metal Adsorption System Using the S-Layer ... · Presented at the 2011 COMSOL Conference in Boston Model of a Heavy Metal Adsorption System Using the S-Layer of Bacillus

THANK YOU! Juan Pablo Orjuela [email protected]