SEA-CSSJ-CMS Trilateral

Meeting on Clays 2010

Seville, Spain8-10 June 2010

ISBN: 978-1-61782-015-1

TABLE OF CONTENTS

LECTURES

CLAY SCIENCE: AN AREA OF INTERDISCIPLINARY RESEARCHS 1

Jose Serratosa

MOLECULAR SIMULATION AND THE NATURE OF THE CLAY-WATER INTERFACE 2

R. CyganCLAYS IN TEM 3

T. KogureCLAY-BASED NANOSTRUCTURED ECO-MATERIALS: FROM ENERGY STORAGE TO

BIOMEDICAL APPLICATIONS 4

E. Ruiz-Hilzky

CLAYS FOR A HEALTHY SOIL-WATER ENVIRONMENT 6

J. Cornejo

APPLICATION OF CHLORITE GEOTHERMOMETER TO LOW TEMPERATUREROCK

ALTERATION 8

A.Inoue

KINETIC STUDY ON INTERCALATION OF ORGANIC ANIONS IN LAYERED DOUBLE

HYDROXIDE USING QUARTZ CRYSTAL MICROBALANCE 9H. Hirahara, Y. Nilanai. S. Aisawa, E. Narila

EFFICIENT PHOTOCHEMICAL ENERGY TRANSFER REACTIONS IN CLAY-PORPHYRIN

COMPLEXES 11S. Takagi, Y. Ishida, S. Konno, D. Masui, T. Shimada, H. Tachibana, H. Inoue

TOPIC 1. STRUCTURAL FEATURES AND CRYSTAL CHEMISTRY

A SPECTRAL INVESTIGATION OF THERMALLY TREATED SAUDI Ni-EXCHANGED

MONTMORILLONITE 13M, Al-Qunaibil

SMECTITE FORMATION IN Fe-Mn-METALLIFEROUS SEDIMENTS COLLECTED IN THEHMS CHALLENGER EXPEDITION (1872-1876) 14

J. Cuadros, V. Dekov, X. Arroyo. F. Nielo

EFFECT OF ACID LEACHING ON THE STRUCTURE OF PALYGORSKITE AND SEPIOLITE 16

G. Chryssikos, G. Kacandes, V. Gionis

STRUCTURES OF THE PALYGORSKITE-SEPIOLITE GROUP MINERALS: COMMENTS ON

THE FORMATION OF THE POLYSOMES 18

S. GuggenheimSOLID-STATE NMR STUDIES ON ETHYLENE GLYCOL INTERCALATED KAOLINITE 19

D. Hirsemann, J. Senker, J. Breu

WATER UPTAKE CAPACITY OF BENTONITES 21

S. Kaujhold, R. Dohrmann

NEAR-INFRARED SPECTROSOPIC ANALYSIS OF ACID TREATED ORGANO-

MONTMORILLONITES 22

J. Madejovd, L. Jankovic, H. Pdlkovd

REPULSIVE INTERACTIONS IN AQUEOUS DIOCTAHEDRAL SWELLING CLAY MINERALSAT LOW IONIC STRENGTH 24

E. Paineau, I. Bihannic, C. Baravian, A. Philippe, P. Davidson, P. Levitz, L. Michat

SIMULTANEOUS RIETVELD REFINEMENT OF MULTI-DEVICE AND/OR MULTI-

SPECIMEN XRD DATA OF MIXED LAYERED STRUCTURES 26

K, Ufer, R. Kleeberg, J. Bergmcmn, R, Dohrmann

PREDICTING THE FORMATION OF PALYGORSKITE THROUGH THE SYNTHESIS

EXPERIMENT 28

IbrahimAl-Hawas

THE NH4 FOR K SUBSTITUTION IN MICAS SYNTHESIZED AT 200"C 29

M Bentabol, M, Ruiz Cruz

SYNCHRONOUS NEAR- AND MID INFRARED INVESTIGATION OF THE DEHYDRATION OF

SEPIOLITE 31V. Gionis, G. Kacandes, G. Chryssikos

PARTICLE SIZE AND SOLVENT EFFECTS ON INFRARED BAND POSITIONS OF LAYERMINERALS OBSERVED WITH POLARIZED ATR-FTIR 33

M. Tenorio Arvide, Y. Deng, J. Dixon

Al/Fe-, Al/Cu- AND Al/(Fe-Cu)-PILLARED CLAYS: STRUCTURAL FEATURES AT LOW

ATOMIC ACTIVE METAL RATIOS (AMR) 35

L. Galeano, A. Gil, M. Vicente

EVIDENCE FOR A HOFMANN-KLEMEN TYPE MECHANISM IN THE FORMATION OF Li-Al-RICH MICAS 37

M Gregorkiewitz, M. Roma, C. Aurisicchio, V. Balitsky, L. BalitskayaVOLUME FRACTION VERSUS ORDER IN NEMATIC FLUOROHECTORITE DISPERSIONS 39

E. Hansen, H, Hemmen, J. Fossum

FLOW INDUCED ORDERING IN NA-FLUOROHECTORITE DISPERSION 40

H. Hemmen, E. Hansen, E. Blindheim, J. Fossum

COMPUTATIONAL ELASTIC PROPERTIES OF MICAS 41

N. Hernandez-Haro, J. Ortega-Castro, C. Perez del Valle, C. Sainz-Diaz, A. Hemdndez-LagunaMOLECULAR DYNAMICS SIMULATIONS OF CLAY MINERAL-WATER/AQUEOUSSOLUTION SYSTEMS USING ATOM-ATOM POTENTIAL MODELS 42

K. Kawamura

STRUCTURAL HETEROGENEITY OF ALKYLAMMONIUM-EXCHANGED, SYNTHETICSWELLING FLUOROMICAS 44

Z. Klapyta

CATION MIGRATION IN CELADONITE AND CIS-VACANT ILLITE BY ELECTRON

RADIATION IN TEM 46T. Kogure, V. Drits

PORPHYRINS INTERCALATED IN Zn/Al, Mg/Al LAYERED DOUBLE HYDROXIDES:STRUCTURAL ARRANGEMENTAND PROPERTIES 48

P. Kovar, E. Kdfunkovd, M, PospiSil, K. Lang, M. Klementova, P. Bezdicka

CRYSTAL CHEMISTRY OF KEROLITE-STEVENSITE MIXED LAYERED MINERALS FROMTHE URAL REGION (RUSSIA) 50

V. Krnpskaya, L. Melchakova, M. Vigasina, G. Chyssikos, V. Gionis, L. Ogorodova, 1. Kiseleva

FLEXIBLE STRUCTURE OF SILICALITE (MFI) BY GAS ADSORPTION 52

K. Nakai, M, Hakuman. J. Kim, M. Yoshida, Y. Senda, K. Kato, M. Takata, H. Naono

NEW POROUS CLAY HETEROSTRUCTURES (PCH) FROM HIGH CHARGE-MICA TYPE

MATERIALS 54

C. Perdigon, D. Lee, C. Pesqnera, F. Gonzalez, B. Ortiz, C. Blanco

DEHYDRATION MECHANISM AND STRUCTURAL TRANSFORMATION OF

PALYGORSKITE 56T. Sakamoto, M. Jige, T. Ushirouchi

INTERFACIAL STRUCTURE OF MUSCOVITE/AQUEOUS NaCl SOLUTION STUDIED BY X-

RAY CTR SCATTERING AND MOLECULAR DYNAMICS SIMULATIONS 58H. Sakuma, T. Kondo, H. Nakao, K. Kawamura

ADSORPTION ON KAOLINS MODIFIED 60A. San Cristobal, R. Castello, C. Vizcayno

PREPARATION OF HOMOIONIC EXCHANGED SMECTITES IN BENTONITES: INFLUENCEOF VALENCE OF CATIONS AND INFLUENCE OF IMPURITIES ON THE EXCHANGEPROCEDURE 61

A. Steudel, K. Emmerich

DETERMINATION OF THE POINT OF ZERO CHARGE OF THE EDGES OF VARIOUS CLAYS 63M. Stirner, J. Breu

STUDY OF ANOMALOUS BEHAVIOUR IN DFT IR SPECTRA AND CALCULATEDBANDSTRUCTURE OBSERVED IN DIOCTAHEDRAL Fe3+, Ge4+ AND Ga3+ MICASSUBSTITUTED SERIES 65

V. Timdn, N. Hernandez Haw, J. Ortega, C. Sainz Diaz, D. Munoz, E. Escamilla, M. Cobian

NEW METHODS OF DATING HYDROCARBON GENERATION BASED ON K-Ar OF

DIAGENETIC ILLITE 67M. Szczerba, J, Srodon

TOPIC 2. MINERALOGY AND GEOLOGY

KEYNOTE: LOW GRADE METAMORPHISM IN POLYDEFORMED ROCKS OF AVALONIA

(ARISAIG GROUP, NOVA SCOTIA, CANADA) 68/. Abad, F. Nieto, G, Gutiirrez-Alonso, J, Murphy

STABLE ISOTOPE CONSTRAINTS ON THE ORIGIN OF KAOLIN DEPOSITS FROM

VARISCAN GRANITOIDS AND FELSITES, FROM SEDIMENTARY BASINS OF GALICIA (NWSPAIN) 70

N. Clauer, E. Galan, A. Fallick, J. Fernandez Caliani, P. Aparicio, M. Marquez, A. Miras

ANATOMY OF A METABENTONITE 72D. Eberl, A. Blum, M. Serravezza

KAOLINITISATION OF LOCALISED MUSCOVITE IN THE KGWAKGWE SHALE OF THETRANSVAAL SUPERGROUP, BOTSWANA 74

G. Ekosse

SEPIOLITE FROM ANATORIA TURKEY: IT'S MINING, MINERALOGYAND APPLICATIONS 76H. llahara, Y. Fukushima

CORRELATION OF LOWER PALEOZOIC K-BENTONITES: IMPLICATIONS FOR TECTONO-STRATIGRAPHIC CORRELATION IN EUROPE AND NORTH AMERICA 78

Warren HuffAMARGOSA VALLEY SEPIOLITE AND SAPONITE MINERALOGY AND MARKETS 80

W. Miles

VARIABILITY OF TRACE ELEMENTS IN SEPIOLITES FROM DIFFERENT SEDIMENTARY

ENVTRONMENTS(MADRID BASIN, SPAIN) 81

M. Pozo, M. Carretero, E. Galan

SYNTHESIS AND CHARACTERIZATION OF PHYLLOSILICATES IN MONTMORILLONITE -

STEVENSITE COMPOSITIONAL SERIES 83H. Yamada, K. Tamura, K. Morimoto, S. Yokoyama, T. Hatta

MINERALOGY, GEOCHEMISTRYAND GENESIS OF YENIDOGAN (SIVRIHISAR, TURKEY)SEPIOLITE AND RELATED MG-RICH MINERALS 85

M, Yeniyol

INTERLAYER AND OCTAHEDRAL SUBSTITUTIONS IN MESOZOIC GLAUCONITES AND

OTHER AUTHIGENIC GREEN MARINE CLAYS DURING DIAGENESIS OBSERVED BY XRD,SEM, TEM 86

A. Baldermami, G. GrathoffHYDROTHERMAL CLAYS AT THE FUTURO VEIN, MARTHA MINE SILVER EPITHERMAL

DEPOSIT, DESEADO MASSIF, PATAGONIA, ARGENTINA 88

B. Bauluz, A. Cedillo, I. Subias, G. Pdez, R. Ruiz, D. Guido

KAOL1NITE ILLITIZATION AT 300°C WITH INCREASING PRESSURE 90

M. Manlovani, A. Escudero, A, Becerro

MINERALOGYAND GEOCHEMISTRYOF BENTONITE ROCKS FROM THE SERRA DE

DENTRO, PORTO SANTO ISLAND, MADEIRA ARCHIPELAGO 92

F. Rocha, 1. Bobos

EVALUATION OF THERMOMETRY CAPACITY OF CLAY MINERALS: EXAMPLE OF THE

GULF COAST'S CHLORITES (TEXAS) 93F. Bourdelle, T. Parra, F. Moreau, C. Chopin, O. Beyssac

FIRST APPROACH TO THE CLAY MINERALOGY OF THE KAOLIN-RICH SEDIMENTARYDEPOSITS FROM THE WEALD FACIES IN THE IBERIAN RANGE (NE SPAIN) 95

A. Cedillo, B. Bauluz, A, Yuste, M. Mayayo, J. Gonzalez LopezCLASSIFICATION OF MONTMORILLONITES ACCORDING TO THEIR LAYER CHARGE:

SIGNIFICANCE AND APPLICATIONS 97

G. Christidis

BIOMINERALIZATION OF SEPIOLITE BY SILICIFIED NANOTUBE TEMPLATES IN

MIOCENE SEDIMENTS OF MADRID BASIN 995. Leguey, A. Ruiz, C. Balleslero.% J. Cuevas

GEOLOGY AND STRUCTURAL CONTROLS OF TWO KAOLIN OCCURRENCES FROM

LIMPOPO PROVINCE, SOUTH AFRICA 101

M. Diko, G. Ekosse, J. OgolaCOAL AND CLAY-MINERAL VERY LOW- TO LOW-TEMPERATURE INDICATORS,COMPARATIVE APPLICATION FROM DIAGENESIS TO GREEN- AND BLUESCHIST FACIES 102

Rafael Mdhlmann

GEOCHEMICAL "FINGERPRINTS" OF HISTORICAL BRICKS: A PILOT STUDY FROM

AUSTRIA 104

H. Frdschl, F. Ottner, F. Holawe, C. Mitterlehner, S. Hartinger

WEATHERING OF GLAUCONITE: EVIDENCE FROMTHE ABU TARTUR MINE, EGYPT 106B. Pestitschek, S. Gier

TOPOGRAPHY EFFECTS ON ALTERATION OF CLAY MINERALS 107M. Hajirasouli, S. Mahmoodi, H. Torabi

STUDY OF PALYGORSKITE TRANSFORMATION UNDER LONG TERM CULTIVATION AND

IRRIGATION IN A ARID REGION (KHUZESTAN, IRAN) 109

5. Jafari

FLUID ROCK INTERACTION PROCESSES IN FAULT-ZONES: CLAY MINERAL AND

GEOCHEMICAL EVIDENCE IN THE GUADIX-BAZA BASIN (BETIC CORDILLERA, SE

SPAIN) 110

J. Jimenez-Millan, F. Garcia-Tortosa, P. Alfaro, R. Jimenez-Espinosa

MINERALOGY OF THE CLAY GOUGES DEVELOPED IN SHEAR ZONES OF THE HIGH

TATRA MOUNTAINS, POLAND 112

A. Kuligiewicz, M. Skiba

ALLOPHANE AND PALAGONITE AS THE PRODUCT OF VOLCANIC GLASS ALTARETAION

OF DIFFERENT 113R, Molenko, E. Kuznetsova

A PALYGORSKITE-BEARING CLAY VEIN FROM THE FUTAMATA LANDSLIDE AREA IN

NORTHEASTERN HOKKAIDO, JAPAN 115H. Maeda, H. Naya, M. Kohno

MIDDLE MIOCENE IN PANAMA, WET OR DRY? 117

S. Moron, C, Monies, A. Cardona, C, Jaramillo, D. Fox

HOW TO CALCULATE MINERAL FORMULA FOR 2-MEMBERS DIOCTAHEDRAL MIXED

LAYERS FROM EDX-ANALYSIS BY TRANSMISSION ELECTRON MICROSCOPY: EXAMPLE

- FRIEDLAND CLAY 118

N. Lan, J. Kasbohm, H. Thao

METHODS TO CHARACTERIZE HISTORICAL BRICKSFROM VIENNA 120

F. Ottner, C, Mitterlehner, S. Hartinger

PROGRESSIVE STAGES OF HYDROTHERMAL ALTERATION OF PLAGIOCLASE TO

HALLOYSITE FROM LIMNOS ISLAND, GREECE 122

D. Papotilis, S. Komarneni, D. Panagiotaras

INFLUENCE OF PALEOENVIRONMENTAL CONDITIONS IN THE FORMATION OF

SEPIOLITE AND PALYGORSKITE IN THE BATALLONES DEPOSIT (MADRID BASIN, SPAIN) 123

M Pozo, J. Calvo, A. Moreno, J. Medina

FUNDAMENTAL PARTICLE CHARGE AND ITS SIGNIFICANCE 125

A. Pratikakis, G. Chrislidis, F. Villieras, L. Michol

TETRAHEDRAL ARSENIC (As+S) IN ANTIGORITE: GEOLOGICAL ORIGIN ANDIMPLICATIONS FOR GROUNDWATER QUALITY 127

P. Ryan, J. Moen, L. Corenthal, D. Chow, J. Kim

COMPOSITIONAL VARIATIONS OF INTERSTRATIFIED CHLORITE/SMECTITE

OCCURRING AS A VEIN-MINERAL FROM THE TODOROKI EPITHERMAL Au-AgDEPOSITS, HOKKAIDO, JAPAN 129

T. Yoneda, T. Watanabe, T. Sato

TOPIC 3. SOILS AND SEDIMENTS

KEYNOTE: STUDY ON CRYSTAL GROWTH AND CONTROL TO IMPROVE SOIL

FERTILITY IN WEST AFRICA 130

T, Halta, J-l. Sakagami, K. Hayashi, Y. Fujihara, S. Nemolo, T, Oya, N, Matsumoto, Y. Shinohara

EFFECTIVE CATION EXCHANGE CAPACITY (ECEC) AND CATION EXCHANGE CAPACITY

(CEC) OFA FULLER'S EARTH FROM GEORGIA 132

R. Ferrell, Lori Eversull

STRUCTURE OF NANOCRYSTALLINE PHYLLOMANGANATES PRODUCED BYFRESHWATER FUNGI 134

S. Grangeon, B, Lanson, N. Miyala, Y. Tani, A. Manceau

REASSESSING ATMOSPHERIC PALEO-pC02 WITH MONTE CARLO SIMULATIONS ANDCARBON ISOTOPE PROXIES IN HYDROXIDE SOIL MINERALS: A CASE FOR LOWERING

PALEO-ATMOSPHERIC C02 ESTIMATES BY FACTOR OF 10 136P. Schroeder, J. Austin

EXPERIMENTAL STUDY OF THE EFFECT OF SALINE ACIDIC CONDITIONS ON ILLITEDISSOLUTION 137

/. Bibi, B. Singh, E. Silvester

FIXATION OF K1", NH4+ AND Cs+ BY DIOCTAHEDRAL VERMICULITE 139M. Skiba

SOIL PALYGORSKITE FORMATION AND ITS ASSOCIATED MINERALS IN TWO

CONTRASTING CLIMATIC REGIMES 140

C. Bangira, Y. Deng, R. Loeppert, C. Hallmark, J. Dixon

DISSOLUTION OF KAOLINITE, ILLITE AND MONTMORILLONITE IN ACID-SALINE

SOLUTIONS 142/. Bibi, B. Singh, E. Silvester

CLAY MINERALS EVOLUTION IN A SOIL CLIMOBIOSEQUENCE OVER MICA-SCHIST

FROM SIERRA NEVADA MOUNTAINS (SPAIN) 144

J. Calero, V. Aranda, A. Callejas, J. Martin-Garcia, G. Delgaclo, R. Delgado

WEATHERINGOF A SMECTITE CLAY FROM A PERSPECTIVE ON ASSIMILATION OF

SOME TRACE METALS BY A PLANT GROWN UNDER A LABORATORY CONDITION 146

S. Chaudhuri, R. Weber, N. Clauer, J. Schneider

GEOLOGICAL, ENGINEERING OF EXPANSIVE SOILS OF WEST MAWHOOB AREA,DAKHLA OASIS, WESTERN DESERT, EGYPT 148

A. El-Shater, A. El-Sherif, H. El-Khashab, E. Abu Seif

REACTIVITY OF CA-BENTONITE IN THE PRESENCE OF LIME: A NMR AND TEM STUDY 150A-C. Gaillot, E. Pomakhina, D. Deneele, N. Maubec, G, Ouvrard

A LONG-TERM NATURAL ANALOGUE FOR RADIOACTIVE WASTE REPOSITORIES?

MINERALOGY AND CHEMISTRY OF A VOLKONSKOITE (CR-RICH SMECTITE) IN

TRAVERTINE DEPOSITS FROM CENTRAL JORDAN 151G. Gralhoff, H. Khouiy

PALYGORSKITE DISTRIBUTION AND GENESIS IN CENTRAL IRANIAN SOILS 153

5. Hojati, H. Khademi, A. Faz Cano

MICROMORPHOLOGY INVESTIGATION OF SEPIOLITE BEARING PETROCALCIC

HORIZONS FORMED FROM LACUSTRINE SEDIMENTS ON THE SOUTHERN HIGH PLAINS

OF TEXAS AND NEW MEXICO 154

Dusten Russell, Wayne Hudnall, B. Allen

DYNAMIC DEW POINT METHOD FOR MEASURING MOISTURE SORPTION ISOTHERMS 155

W. Likos

IMPORTANCE OF POROSITY IN THE ROCK WEATHERING PROCESSES. SOME

EXAMPLES 157E. Ballesteros, J. Talegon, H. Fernandez, A. Inigo

INFLUENCE OF SOIL IRON MINERALS ON THE FORMATION OF TRIHALOMETHANE 158/. Mulder, S. Huber, D. Maker, H. SchSler

K-Ar AGE VALUES OF BULK SOIL SAMPLES AND CLAY FRACTIONS: EFFECTS OF ACID

EXTRACTION AND IMPLICATIONS FOR THE ORIGIN OF MICACEOUS CLAY IN

SAVANNAH RIVER SITE SOILS 159

T. Naumann, W. Elliott, J. Wampler

TOPIC 4. ENVIRONMENT & ENERGY

KEYNOTE: EARTH ENGINEERING TECHNOLOGY LEARNT FROM LOW TEMPERATURE

PRESENT-DAY-SERPENTINIZATION 161T. Sato, S. Anraku, T. Yoneda

GRAPHENE-LIKE MATERIALS SUPPORTED ON CLAYS: EASY PREPARATION AND

APPLICATIONS 163P. Aranda, M, Darder, A. Gdmez-Aviles, E. Zatile, E. Ruiz-Hitzky

LAYERED DOUBLE HYDROXIDE / HUMIC ACID NANOCOMPOSITES AS PESTICIDES AND

HEAVY METALS ADSORBANTS 165

A. Khenifi, Z. Derriche, T. Alekseeva, P. Besse, V. Privot, C. Forano

SOIL CLAY MODIFICATION WITH SPERMINE AND ITS EFFECT ON THE BEHAVIOR OF

THE HERBICIDE FLUOMETURON 167

B. Gamiz, R, Celis, L. Cox, M. Hermosin, J. Cornejo

SYNTHESIS OF ORGANO-CLAYS WITH A NON-IONIC SURFACTANT 169

R. Guigan, M, Motelka-Hetno, L, Leforestier, S. Cadars

BEHAVIOURS OF CLAY MINERALS IN THE EXTRACTION OF ALBERTA OIL SANDS:

AQUEOUS VERSUS NON-AQUEOUS EXTRACTION PROCESSES 171A. Hooshiar, P. Uhllk, Q. Liu, D. Ivey, T. Etsell

A METHODOLOGICAL APPROACH TO FOLLOWTRACE ELEMENT MOBULIZATION IN

SOILS AFFECTED BY SPILLS. APPLICATION TO THE GUADIMAR SOILS (SW SPAIN) 172A. Romero, I. Gonzalez, I. Fernandez, E, Galdn

AMMONIUM CHLORIDE TRANSPORT THROUGH DIFFERENT NATURAL CLAY BARRIERS 174

A. Ruiz, I. De Solo, N. Jimenez, M Regadio, R. Fernandez, J. Cuevas

BASAL SPACINGS OF SMECTITE IN COMPACTED BENTONITE 176

M. Viliar, R. Gomez-Espina, L. Gutierrez-Nebot

ADSORPTION AND INTERCALATION OF CIPROFLOXACIN BY MONTMORILLONITE AND

RECTORITE IN AQUEOUS SOLUTION 178

C. Wang, Z. Li, W. Jiang, J. Jean

ADSORPTION OF THE HERBICIDE CLOPYRALID BY CHITOSAN-INTERCALATED

MONTMOTILLONITE 179

M. Adelino, R. Celis, G. Facenda, U. Bermosin, J. Cornejo

ALGERIAN BENTONITE AS ADSORBENT FOR THE REMOVAL OF HEAVY METAL IONS

FROM THE AQUEOUS SYSTEM: APPLICATION IN WASTEWATER TREATMENT 181

H. Assameur, F. Mohammed-Azizi, M. Boufalit

COMPARATIVE ASSESSMENT OF THE ADSORPTION OF PAHS ON CLAYS AND

INDUSTRIAL WASTES 182

F. Brum, R. Celis, I. Guzman, M. Real, J. Cornejo

ADSORPTION - INTERCALATION OF NAPHTALENE DERIVITES BY LAYERED DOUBLE

HYDROXIDES 184

E. Butenko, A. Kapusiin

MECHANISMS OF C02 INTERACTION WITH EXPANSIVE CLAY 186

V. Romanov, R. Cygan, B. Howard, E. Myshakin, G. Guthrie

REMOVAL OF PESTICIDES FROM WATER BY USE OF ORGANOHYDROTALCITE 187

D. Chaara, I. Pavlovic, F. Bruna, M. Ulibarri, K. Draoui, C. Barriga

UPTAKE OF ORANGE-10 BY CALCINED Mg/Al LAYERED DOUBLE HYDROXIDES 189

R. Exlremera, R. Perez, I. Pavlovic, M. Ulibarri, C. Barriga

KEY PROCESSES AFFECTING THE PORE WATER CHEMISTRY IN BENTONITES:

COMPARISON BETWEEN THE MX-80 AND FEBEX CLAYEY MATERIALS 191

A. Fernandez

CHLORITE FORMATION AT 90 °C BY DIFFUSION OF HYPERALKALINE FLUIDS

THROUGH COMPACTED BENTONITE 193

R. Fernandez, R. Garcia, R. Vigilde la Villa, J. Cuevas

THE INFLUENCE OF RAW MATERIALS IN COj EMISSIONS IN THE BRICK INDUSTRY. THE

CASE OF ANDALUSIA (SOUTHERN SPAIN) 195

E. Galan, I. Gonzalez, A. Miras, M. Vazquez

COMPARISON OF WELL-LOG DERIVED MINERAL QUANTITIES WITH XRD REULTS 197

A. Harrison, R. Ferrell

STUDIES ON ADSORPTION AND DIFFUSITIVITY OF PHENOL IN ANIONIC CLAYS 198

E. Butenko, A. Kapustin

ADSORPTION OF CADMIUM(II) FROM AQUEOUS SOLUTION ONTO SEPIOLITE 200

E. Padilla-Ortega, R. Leyva-Ramos, A. Jacob-Azuara, M. Berher-Mendoza, J. Mendoza-Barron, L. Fuenles-Rubio,A. Aragon-Pina

EFFECT OF MECHANICAL TREATMENTS IN THE ADSORPTION OF DIURON ON

MONTMORILLONITE AND SEPIOLITE 202

T. Undabeytia, M. dos Santos Afonso, R. Torres Sanchez, E. Morrillo, C. Maqueda

PHOTODEGRADATION OF ANIONIC DYE BY NON-TREATED ZN-AL LAYERED DOUBLE

HYDROXIDE IN AQUEOUS SOLUTION 203

K. Morimoto, K. Tamura, H. Yamada

APPLICATION OF NATURAL ATTENUATION PROCESS FOR WASTEWATER

CONTAMINATED WITH COPPER AND ZINC 205

H. Okamoto, K. Morimoto, S. Anraku, T, Sato, T. Yaneda

MACROSCOPIC AND SPECTROSCOPIC CHARACTERIZATION OF As(V) SORPTION BYBRUCITE AT HYPERALKALINE CONDITION 207

E. Opiso, J. Charnock, T. Sato, S. Anraku, C. Numako, T. Yoneda

UPTAKE OF PESTICIDES FLUOMETURON AND NICOSULFURON BY LAYERED DOUBLE

HYDROXIDE 209

R. Otero, M. Perez, C. Barriga, M. Ulibarri, I. Pavlovic, J. Fernandez

CATIONS ABSORPTION IN HIGH TECHNOLOGICAL LAYER SILICATES 211

E. Pavon, U. Castro, M. Alba, M. Orta, C. Pazos, M. Naranjo

PALYGORSKITE FROM MARRAKECH HIGH-ATLAS (MOROCCO): CHARACTERIZATION,FUNCTIONALIZATION AND PHOTOCATALYTIC ACTIVITY 213

I. Bouna, B. Rhouta, F, Maury, A. Jada, M-C. Lafont, M. Amjoud, F. Senocq, L. Daoudi, E. Zatile, P. Aranda, E.

Ruiz-Hitzky

ADSORPTION OF THE PESTICIDE METALAXYL ON PHYLLOSILICATE SURFACES BY

FIRST PRINCIPLE CALCULATIONS 215

S. Azarkan, C. Sainz-Diaz, M. Francisco-Marquez, K. Draoui

ADSORPTION OF HYDROPHOBIC ORGANIC COMPOUNDS ONTO A GEOSORBENT

MATERIAL 217

L. Scrcmo, S. Chiola, C. Belviso, F. Lelario, S. Fiore, S. BufoSODIUM AND CALCIUM / MAGNESIUM-MONTMORILLONITE: STRUCTURE, FORCES AND

SWELLING PROPERTIES 218

M. Segad, B. Jonsson, T. AKesson, U. Ohson, B. Cabane

HIGH PERFORMANCE NEW AMORPHOUS ALUMINUM-SILICATE ADSORBENT WATER

VAPOR AND CARBON DIOXIDE 220

T. Suemasu, M. Suzuki, K. Inukai, M. Maeda, K. Tsukimura

A COMPARATIVE STUDY OF THE USE OF AN ORGANOCLAY-BASED FORMULATION AND

A STANDARD COMMERCIAL FORMULATION OF THE HERBICIDE DIURON UNDER FIELD

CONDITIONS 222

C. Trigo, R. Celis, M. Hermosin, J. Cornejo

SLOW RELEASE FORMULATIONS OF THE HERBICIDE METRIBUZIN: BASED ON

PHOSPHATIDYLCHOLINE-MONTMORILLONITECOMPLEXES 223

T. Undabeytia, E. Redo, E. Morillo, C, MaquedaGEOCHEMISTRY OF THE FINE FRACTION OF SUPERFICIAL SEDIMENTS IN THE

OUTLET OF MEDJERDA RIVER (GULF OF TUNIS) 225

N. Zaaboub, W. Oueslati, S. Abdeljaoued, F. Huertas, A. Lopez-Galindo

EFFECT OF TEMPERATURE AND CATIONS ON THE SWELLING AND SHRINKING

BEHAVIOURS OF MONTMORILLONITE-CLAY 227

Y. Zheng, A. Zaoui, J. Shahrour

TOPIC 5. BIOLOGICAL ASPECTS & HEALTH

KEYNOTE: ADSORPTION OF PROTEINS ON SAPONITE 228

R. Schoonheydt, T. Szabo, C. Johnston

SYNTHESIS AND CELLULAR UPTAKE OF FLUORESCEINE INTERCALATED LAYERED

DOUBLE HYDOROXIDE 230

S, Aisawa, M. Tanaka, S. Takahashi, H, Hirahara, E. Narila

EVALUATION OF BENTONITES AS AN AMENDMENT IN POULTRY FEED

CONTAMINATED WITH HIGH-CONCENTRATION OF AFLATOXINS 232

A. Barrientos Velazquez, J. Fowler, R. Kakani, A. Haq, C. Bailey, M. Amide, Y. Deng, J. Dixon

ENZYME SUPPORTING PHOSPHOLIPID-SEPIOLITE HYBRIDS INCORPORATED IN

POLYMER MATRICES FOR BIOSENSOR AND BIOREACTOR APPLICATIONS 234

B. Wicklein, M. Darder, P. Aranda, E. Ruiz-Hitzky

ADSORPTION OF RADIO CESIUM BY PHARMACEUTICAL CLAY IN STOMACHMEDIUM

SIMULATED USING RADIOTRACER TECHNIQUE 236

F. Abaoui, A. Bouzidi, S. Hanini

AFLATOXIN CONTROL IN FEEDS AND FOODS WITH ADSORBENT SMECTITE CLAYS IN

BENTONITES 237

J, Dixon, A, Velazquez, M. Arvide, Y. Deng

FRUCTOSE-6-PHOSPHATE ALDOLASE LDH BASED BIOCATALYST FOR ALDOSE AND

CETOSE SYNTHESIS 239

C. Guerard-Helaine, B. Legeret, M. Lemaire, V. Privot, C. Forano

ADSORPTION OF OXALATE ON MONTMORILLONITE 241

M. Ramos, C. Johnston, F. Huertas

GOSSYPOL ADSORPTION BY UZBEKISTAN BENTONITES 243

V. Maksimov, 0. Veshkurova, D. Laird, G. Rahmatkariev, I. Salikhov

MICROBIOLOGICALASSESSEMENT OF SOME VOLCANIC MUDS FROM S. MIGUEL,

AZORES 244

A. Quintela, S. Almeida, D. Terroso, E. Ferreira da Silva, V. Forjaz, F. Rocha

PREPARATION AND CHARACTERIZATION OF POLYHYDROXYBUTYRATE

NANOCOMPOSITE MICROCAPSULES OBTAINED USING SMECTITIC CLAYS 246

M, Silva-Valenzuela, S. Wang, H. Wiebeck, F. Valenzuela-Diaz

CHARACTERIZATION OF SOUTH AMERICA SMECTITIC CLAYS AND THEER POTENTIAL

USE IN COSMETICS 248

A. Almeida, M. Silva-Valenzuela, A. Dantas, F. Valenzuela-Diaz

TOPIC 6. INDUSTRIALAND OTHER APPLICATIONS

KEYNOTE: LAYERED DOUBLE HYDROXIDES AND THEIR USE AS PRECURSORS OF

CERAMIC PIGMENTS 249

V. Rives

EXPLORING THE COMPETITIVE ADSORPTION OF STARCH AND PLASTICISERS IN THE

CLAY INTERLAYER AND ITS INFLUENCE ON THE BARRIER PROPERTIES OF STARCH

NANOCOMPOSITE PAPER COATINGS 251

K. Khairuddin, F. Clegg, C. Breen

ORGANOMODIFICATION OF CLAYS USING DIFFERENT SOLVENTS 252

F. Clegg, C. Breen

EFFICIENCY OF LIME TREATMENT ON MICASCHIST SOIL 253

L. Delavernhe, D. Deneele, A-C. Gaillol, G. Ouvrard

SEPIOLITE - SUPPORTED METALLIC NANOPARTICLES 255

Sadok Letaief, Sarah Grant, Yun Liu, Christian Detellier

ON THE SYNERGY BETWEEN SEPIOLITE AND CARBON NANOTUBES IN

BIONANOCOMPOSITES 256

F. Fernandas, E. Ruiz-Hitzky

PREPARATION AND CHARACTERIZATION OF POLYIMIDE/LAYERED DOUBLE

HYDROXIDE NANOHYBRIDS 258Jinhee Ahn, Chang-Sik Ha

THERMALLY MODIFIED CLAYS AS ADSORBENTS FOR INDUSTRIAL APPLICATIONS 259C. del Hoyo, R. Zapalera, V. Sanchez-Escribano, A. Queiniga

ADSORPTION OF CLUSTERS OF PHOTO-FUNCTIONAL DYES ONTO CLAY MINERALS

EXFOLIATED TO SINGLE LAYERS 260J. Kawamata

CLAYS IN THE GEOMETALLURGY OF COPPER MINING: EXAMPLES FROM CHILE 262

U. Kelm, M. A vendaiio, S. Helle, 0. Jerez, M. Pincheira

CHARACTERIZATION OF ORGANOCLAYS FOR COMPOSITES WITH NATURAL RUBBER 264

P. Komadel, L. Jankovic, J. Madejova, J. Hrachova

NANOTUBULAR KAOLINITE AS AN ADDITIVE FOR PREPARATION OF

POLYLACTIDE/CLAY COMPOSITES 266

J. Matusik, E, Stodolak, K. Bahranowski

INTERACTIONS BETWEEN LIME AND CLAY MINERALS - COUPLING BETWEEN THE

PHYSICOCHEMICAL AND GEOTECHNICAL ASPECTS 268

N, Maubec, D. Deneele, E. Pomakhina, M. Paris, G. Ouvrard

APPLYING ZETA POTENTIAL MEASUREMENTS TO CHARACTERIZE THE ADSORPTION

OF INORGANIC, ORGANIC, MICELLAR AND POLYMERIC CATIONS ONMONTMORILLONITE 269

D. Zadaka, A. Radian, Y. Mishael

PHOTOCHEMICAL REACTIONS IN COLLOIDAL MIXTURES OF EXFOLIATED CLAY AND

SEMICONDUCTOR NANOSHEETS 270T. Nakalo, Y. Yamada, M. Nakamura

LOTUS CERAMICS FROM KAOLIN CLAYS AND ITS CAPILLARY RISE ABILITY 272K. Okada, T. Isobe, Y. Kameshima, A. Nakajima, T. Kurala

POROUS MATERIALS FROM ACID LEACHED GROUND VERMICULITE 274J. Perez-Rodriguez, C. Maqueda, J. Subrt

MAYA BLUE ORIGINS TRACED WITH SYNCHROTRON RADIATION CLAY ANALYSIS 276M. Sdnchez del Rio, M. Sudrez, E. Garcia-Romero

POLYMER NANOCOMPOSITE USING A SECOND-STAGED ALKYLAMMONIUM-SERICITECOMPLEX 278

K. Tamura, T, Hatta, K. Morimoto, H. Yamada

CHARACTERIZATION OF HECTORITE SYNTHESISED WITH MICROWAVESANDDISPERSION IN PU 279

/. Vicente, P. Salagre, Y. Cesteros, F. Clegg, C. Breen

EFFECT OF SURFACTANT ON THE ELECTROKINETIC PROPERTIES OF NATURAL CLAY 281Z Kurt, S. Akbulut

ZEIN-CLAY BIO-HYBRID SYSTEMS AS FILLERS IN ALGINATE FILMS 282A. Alcantara, M. Darder, P. Aranda, E. Ruiz-H'ttzky

LIME-METAKAOLIN MORTARS WITH INCORPORATIONOF SEPIOLITE 284S. Andrejkovi?ovd, E. Ferraz, A. L. Velosa, F. Rocha

ECONOMIC EVALUATION OF SPENT BLEACHING CLAY RECYCLING USED IN

REREFINING OF WASTE LUBRICATING OIL IN SULAIMANI CILTY-IRAQ 286

B. Aziz, M. Abdullah

THE EFFECT OF (ORGAJNO) CLAY ADDITION ON THE PROPERTIES AND USES OF U.V.

POLYMERISED ACRYLATE SHAPE MEMORY POLYMERS 287

M. Barwood, F. Clegg, C. Breen, C. Hammond

SILICA/ALUMINA CLAY NANOCOMPOSITES AS HETEROGENEOUS ACID CATALYSTS 289

C. Be/ver, L. Molinero, M. Ladero, P. Aranda, E. Ruiz-Hitzky

STRUCTURE AND RHEOLOGY RELATIONSHIP OF ORGANOCLAY W/O

MACROEMULSIONFOR DRILLING FLUIDS 291

N. Cohaut, M. Khodja, R. Akkal, F. Bergaya

PALYGORSKITE CLAYS FROM BORSHHOVSKOE DEPOSIT (KALUGA REGION, RUSSIA):

COMPOSITION, CRYSTAL CHEMICAL PARTICULARITIES OF CLAY MINERALS AND

COLLOIDAL PROPERTIES 293

A, Bogrash, N. Malskova, S. Zakusin, V. Kmpskaya, B. Pokidko, V. Voloshin, 1. Krupnov

THE EFFECT OF CROSS-LINK TYPE, CROSS-LINK CONCENTRATIONAND INITIATION

METHOD ON THE SWELLING/ DESWELLING CAPABILITIES OF PNIPAM HYDROGELS IN

AQUEOUS AND ALCOHOLIC SOLUTIONS 295

V. Boyes, C. Sammon, C. Breen, S. Sabnis, J. Foulkes

NOVEL REACTIVE AMINO-COMPOUND: TRIS(HYDROXYMETHYL)AMINOMETHANECOVALENTLY GRAFTED ON KAOLINITE 296

E.H. de Faria, T.H. da Silva, U. Sallarelli, E. Nassar, K. Ciuffi, M. Vicente, R. Trujillano, A. Gil, S. Korili, P.

Calefi

CERAMIC PROPERTIES OF CLAYS FROM THE LITHOSTRATIGRAPHIC UNIT "ARGILAS

DE AVEIRO": A 3D MODEL VARIABILITY 298

J. Coroado, E. Ferraz, A. Amado, C. Gomes, F. Rocha

BUILDING REJECTS INCORPORATION ON RED CERAMICS 300

S. Cosin, G. Marlin-Cortes, N. Albanez, J. Di Rito, V. Kozievitch, F. Valenzuela-Diaz

SEPIOLITE-BASED NANOCOMPOSITEFOAMS 301

M. Darder, C. Matos, P. Aranda, E. Ruiz-Hitzky

REACTIVITY OF COMPACTED CLAYEY SOIL PERCOLATED WITH AN ALKALINE

SOLUTION 303

D. Deneele, 0, Cuisinier, V. Hallaire

MICROWAVE ASSISTED ACID TREATMENT OF SEPIOL1TE 304

F. Franco, J. Cecilia

SILICA-SEPIOLITE ORGANO-HETEROSTRUCTURES AND HETEROSTRUCTURES 306

A. Gomez-Aviles, P. Aranda, F. Fernandes, C. Belverand, E. Ruiz-Hitzky

DIOXIN IN BLEACHING EARTH: MASS BALANCE ISSUES 308

G. Goss, J. Hart, W. Moll, Y. Tondeur

PA6.6/Mg,Al/AD-LDH NANOCOMPOSITES OBTAINED BY SOLID STATE POLYMERIZATION 309

M Herrero, P. Benito, F. Labajos, V. Rives, Y. Zhu, G. Allen, J. Adams

EFFECTIVE AND SELECTIVE ADSORPTION OF ZINC ION ON A LAYEDED ALKALI

SILICATE FROM SEAWATER 311

Y, Ide, N. Ochi, M. Ogawa

EFFICIENT EXCITED ENERGY TRANSFER REACTION BETWEEN PORPHYRINS ON CLAY

SURFACE THE EFFECTS OF ADSORPTION CONDITIONS 313

Y. lshida, S. Takagi, D. Masui, T. Shimada, H. Tachibana, H. Inoue

AN EVALUATION OF CHILEAN CLAYS FOR INDUSTRIALS APPLICATIONS 315

S1. Meseguer, F. Pardo, M. Jordan, T, SanfeliuUPTAKE OF HEAVY METAL IONS FROM AQUEOUS SOLUTION BY Mg-AI LAYERED

DOUBLE HYDROXIDES INTERCALATED WITH ORGANIC ACID ANIONS, ITS KINETICS 317

T. Kameda, H. Takeuchi, T. Yoshioka

COMPETITIVE ADSORPTION OF POLYMER AND PLASTICIZER INTO THE CLAY

GALLERY 318

K. Khairuddin, F. Clegg, C, Breen

PREPARATION OF ZINC OXIDE - MONTMORILLONITE HYBRIDS 319

N. Khaorapapong, N. Khumcboo, M. Ogawa

MODIFICATION OF CALCINED CLAY FOR ARTIFICIAL GROWING MEDIA AND

PHYSICAL PROPERTIES 320

B. Kim, C, Park, G. Lee

INVESTIGATION OF DYES ADSORPTION BEHAVIOR ON THE CLAY SHEET -TOWARDS

EFFICIENT PHOTOCHEMICAL REACTION SYSTEM- 321

S. Konno, T. Shimada, H. Tachibana, D. Masui, S. Takagi, H. Inoue

PRELIMINARY RESULTS OF INVESTIGATIONS OF PHYSICAL AND CHEMICAL

CHARACTERISTICS OF CLAY IN THE CONTINENTAL PART OF MONTENEGRO 322

Nada Marstijepovic, Dragica Kovacevic

THE BOLE USED IN GILDED PLASTERWORK IN SALAO ARABE, PALACIO DA BOLSA

(OPORTO, PORTUGAL) 324

P. Mestre, F. Rocha, J. Coroado

LIQUID CRYSTAL PHASES OF CLAY MINERAL COLLOIDS AND ITS APPLICATION FOR

FABRICATING ANISOTROPIC GEL MATERIALS 325

N. Miyamoto, M. Shintate, Y. Kamachi, R. Motokawa

THE FORMATION OF MAYA BLUE MONITORED BY NEUTRON SCATTERING 327

C. Mondelli, M. Sanchez del Rio, A. Magazzu, M. Sudrez, E. Garcia-Romero, M. Gonzalez, P. Romano

NANOSPACE ENGINEERING IN METHYLVIOLOGEN MODIFIED HECTORITE-LIKE

LAYERED SILICATES WITH VARIED LAYERED CHARGE DENSITY FOR THE ADSORBENT

DESIGN 329

T. Okada, T. Matsutomo, M. Ogawa

SYNTHESIS AND MODIFICATION OF HYDROTALCITE FOR ENHANCED FLAME

RESISTANCE 331

F. Papini, C. Breen

INDONITE®: A MICROPOROUS SYNTHETIC CLAY-LIKE MATERIAL 332

M. Pa/el, P. Aranda, C. Belver, E. Ruiz-Hitzky

APPLICATION OF ULTRASOUNDS AND MICROWAVES TO OBTAIN MESOPOROUS

HECTORITES 334

T. Sanchez, P. Salagre, )'. Cesleros

RELEASE OF DRUGS INMOBILISED ON LDHs SUPORTED ON BIOPOLYMER 336

M. San Roman, M. Holgado, V. Rives

PHYSICAL, CHEMICAL AND GEOTECHNICAL PROPERTIES OF SPECIAL CLAYS DEPOSIT

FROM TAMAME DE SAYAGO (ZAMORA, SPAIN) 338

E. Manchado, C. Sdnchez-Rubio, M. Yenes, E. Garcia-Romero, M. Sudrez

ENHANCED TWO-PHOTON ABSORPTION CHARACTERISTICS OF POLY-CATIONIC DYES

BY HYBRIDIZING WITH CLAY MINERALS 339

Y. Suzuki, Y. Tenma, J. Kawamata

TWO-PHOTON ABSORPTION PROPERTIES OF CATIONIC PORPHYRIN-CLAY

COMPOSITES 341

Y, Tenma, Y, Suzuki, J. Kawamata

COBALT CONTAINING SAPONITES PREPARED BY A MICROWAVE-HYDROTHERMAL

METHOD 343

R, TrujiUano, E. Rico, M, Vicente, V. Rives

TEST AND CHARACTERIZATION OF RAW RESADIYE BENTONITE'S

ORGANOPHILICALLY MODIFIED PRODUCTS 345A. Vatansever, A. Sirkecioght, M. Koral S. Sarioglan, H. Yiizer

POLYSACCHARIDE/LAPONITE NANOCOMPOSITES THROUGH PRE-

FUNCTIONALIZATION WITH (3-AMINOPROPYL)TRIETHOXYSILANE 346

L. Bandeira, E. Nassar, K. Cm/ft, M. Vicente, R, Tmjillano, P. CaleflAPPLICATION POSSIBILITIES OF "BELCHATOW" CLAYS AS A RAW MATERIAL IN

FLOODBANKS' FIXING TECHNOLOGY 347

L. Wqjcik, P. Izak, A. StempkowskaCHITOSAN-CLAY BIONANOCOMPOSITES BASED ON MOROCCAN STEVENSITE 348

E. Zatile, P. Aranda, M. Darder, B, Rhouta, E. Ruiz-Hitzky

TOPIC 7. CLAYS IN EDUCATION PROGRAMS

KEYNOTE: INFRARED SPECTROSCOPY: PRINCIPLES AND APPLICATIONS IN THE STUDY

OF CLAY-ORGANIC INTERACTIONS 350

Giora Rytwo

CHARACTERIZATION OF EARTH BUILDING MATERIALS FROM ARCHAEOLOGICAL

SITES ON LA RIOJA AND AND CATAMARCA (ARGENTINA) 352

G, Spengler, M. Do Campo, J. Jimenez-MiUdn

PREPARATION OF LAYERED DOUBLE HYDROXIDE-ORGANIC INTERCALATION

COMPOUNDS BY SOLID-SOLID REACTIONS 354

K. Kuramoto, M. Ogawa

IMACS : AN INTERNATIONAL MASTER PROGRAMME ENTIRELY DEVOTED TO CLAYS 356

P. Patrier Mas, S. Petit, G. Christidis, E. Ferreira da Silva, F. Rocha, C. Blanchette, C. Detellier, A. Mexias

CLAYS IN UNDERGRADUATION AND POSTGRADUATION PROGRAMS: THE CASE OF THE

UNIVERSITY OF AVEIRO 358

F. Rocha

APPENDIX I: RECEIVED AFTER DEADLINE

CONTACT PRESSURE EFFECTS ON VIBRATIONAL BANDS OF KAOLINITE DURING

INFRARED SPECTROSCOPIC MEASUREMENTS IN A DIAMOND ATR CELL 360

F. Friedrkh. P. Weidler

Author Index