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1. Product and Company Identification Company Name: Mavidon® Medical Products Telephone: 561-585-2227 Address: 1820 2ed Avenue North Transportation Emergency: Infotrac Lake Worth, FL 33461 1-800-535-5053 Outside the US1-352-323-5000 USA (collect calls accepted) Substance Name: Collodion USP E-mail: CS@MAVIDON.COM Product: MD0002 Contact Person: Special End Use: Medical Skin Coating Emergency Contact:

2. Hazards Identification

Health Environmental Physical Acute

Toxicity: Acute Oral Toxicity Category 4 Acute Inhalation Toxicity Category 4

Acute Toxicity:

NA Fire: Flammable liquid and vapor Category 2

Skin / Eye Irritation:

Skin Irritant Category 2 Eye Irritant Category 2A

Chronic Toxicity:

NA

STOT-SE Specific Target Organ Toxicity Single Exposure Category 3 (CNS)

Signal word: Danger

Hazard Statements/Category Precautionary Statements: -Highly Flammable Liquid and Vapor -Harmful if Swallowed -Harmful if Inhaled -Causes Skin and Eye Irritation -May cause drowsiness or dizziness

- Keep away for heat, sparks and open flames. -Keep container tightly closed. -Use explosion proof ventilating / lighting equipment. -Use only non-sparking tools. -Take precautionary measures against static discharge. -Wash hands thoroughly after handing. -Do not eat, drink or smoke when using this product. -Avoid breathing vapors. -Use only outdoors or in a well ventilated area. -Wear protective gloves and face protection.

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Symbols: Response: Rinse mouth. If swallowed: Call poison control (1-800-535-5053-INFOTRAC) if you feel unwell. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call poison control (1-800-535-5053-INFOTRAC) if you feel unwell. If on skin: Wash with plenty of water. When dried may be pealed off. Use acetone or collodion remover to facilitate removal. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash it before use. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: get medical attention. Storage: Store in a well ventilated place. Keep container tightly closed. Store in Approved Flammable Cabinet. Store locked up. Keep cool.

3. Composition/Information on Ingredients

Chemical Name Cas # ENCIS # Reach Registered Concentration % Weight

Ethyl Ether (a,b) 60-29-7 200-467-2 Yes 65-75 Ethanol (denatured) 64-17-5 200-578-6 Yes 20-30

Nitrocellulose, colloided, granular

(d)

9004-70-0 603-037-01-3 NA 3-7

4. First Aid Measures Inhalation: Move from the exposed area immediately, supply artificial respiration

if necessary. If symptoms persist seek medical attention. Skin Contact: If still liquid wipe of with disposable towel. Once dried, nitrocellulose

film can be removed by pealing off. Use acetone or collodion remover to help with removal if needed.

Eye Contact: Rinse cautiously with water for several minutes. Remove contact lens, if present and easy to do. Continue rinsing. (P305+P351+P338) If eye irritation persists get medical attention. (P337+P313)

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Ingestion: If swallowed, drink two glasses of water to dilute. DO NOT INDUCE VOMITING. Never give anything by mouth to an unconscious person.

Notes for Doctor:

There are no antidotes for this material, treatment is based on symptoms.

5. Fire Fighting Measures

Extinguishing Media:

In case of fire: Use Dry Chemical or CO2 for extinguishing. (P370+P378) For surrounding fire such as dry chemical for small fire, use carbon dioxide, water fog and dry chemical.

Special Hazards:

Closed containers can explode due to buildup of pressure when exposed to extreme heat. Do not use direct stream of water on pool fires as product may re-ignite on water surface. Caution - Material is extremely flammable!

Hazardous Combustion

Products:

Smoke, fumes, hydrocarbons and oxides of carbon.

6. Accidental Release Measures

Personal Protection Equipment:

Wear protective gloves/eye protection/face protection. (P280) If misting occurs, use appropriate respiratory protection.

Non Emergency Personnel:

Leave the immediate area; prevent smoking or open flames, turnoff all electrical equipment without generating sparks. Use natural ventilation (open doors or window) avoid sparks and ignition sources.

Emergency Responders:

Carefully ventilate the area avoid sparks and ignition sources. Firefighters must wear full face piece self - contained breathing apparatus in positive pressure mode. Do not use solid stream of water since stream will scatter and spread fire. Fine water spray can be used to keep fire - exposed containers cool.

Environmental Precautions:

Keep away for heat, sparks and open flames.

Methods & Materials for Containment/Cleanup:

Flush the area with water, ventilate with large volumes of outside air, avoid generating sparks, heat or flames.

Other information: Keep away from heat, sparks and flames. Reference to other: Sections:

See section 7 for safe handling precautions and personal protective equipment.

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7. Handling and Storage

Precautions for Safe Handling:

Store in tightly closed containers. Store in a well ventilated area. Store in approved Flammable Liquid cabinet. Keep room temperature 28ºC (82º F) or below. (P403+P235)

Protective Measures: Keep in room temperature 28ºC (82º F) or below and dry areas. Fire Prevention: Keep away from flames and hot surfaces-No Smoking (P210) Aerosol & Dust Generation Prevention:

None applicable

Handling considerations:

Keep container tightly closed. (P233) Ground/bond container and receiving equipment. (P240) Use Proper air purification system to remove fumes, or Use explosion proof electrical/ventilating/lighting equipment. (P241) Use only non sparking tools. (P242) Take precautionary measures against static discharge. (P243)

Safe Storage: Store in original labeled container. Keep in room temperature 28ºC (82º F) or below and in dry areas.

General Hazards: Product is extremely flammable. Products of combustion include: smoke, fumes, hydrocarbons and oxides of carbon. Vapors may cause a flash fire or ignite explosively. Vapors may travel a considerable distance to a source of ignition and flash back.

8. Exposure Controls/Personal Protection

Exposure Controls: Follow all manufactures instructions. Engineering Controls:

Use in well ventilated area, assess atmosphere for potential flammable levels.

Safety Equipment: Safety eye bath nearby. Eye and Face Protection:

Splash goggles with side shields.

Skin Protection: Neoprene or rubber gloves with cuffs. Respiratory Protection:

If misting occurs, use appropriate respiratory protection.

Thermal Hazards: Vapors may cause a flash fire or ignite explosively. Vapors may travel a considerable distance to a source of ignition and flash back.

Environmental Exposure Controls:

Non applicable

Occupations Exposure limits

Ethyl Ether 1200/1210 mg/m3 OSHA PEL/ACGIH TLV Ethanol (denatured) 1900/1900 mg/m3 OSHA PEL/ACGIH TLV

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9. Physical and Chemical Properties Component Collodion UPS Appearance Viscous Colorless Liquid

Odor Ether Odor Odor Threshold ND

PH ND Melting Point/Freezing Point ND

Initial Boiling Point: ºC / ºF 36.1/97 Evaporation Rate Slower Than Ether

Flash point Closed Cup: ºC / ºF -45/-49

Upper/Lower Flammability/Explosive 1.90 % / 36.0 %

Vapor Pressure: 70º F 442 mm Hg

Vapor Density (Air =1) >1 Specific Gravity (H2O= 1 @ 20º C) 0.770

Density ND Solubility In Water Slight

Auto-Ignition Temperature ND

Decomposition Temperature ND

Flammability (solid, gas) ND

Relative Density ND

Viscosity ND

Partition coefficient: n-octanol/water ND

10. Stability and Reactivity

Reactivity: Stable at ambient temperature and pressure. Chemical Stability: Considered stable and under normal ambient temperatures. Possibility of Hazardous Reactions:

Reactive with oxidizing materials and strong acids.

Conditions to Avoid:

Extreme temperatures, open flames, sparks or hot surface.

Incompatible Materials: Reactive with oxidizing materials and strong acids. Hazardous Decomposition Products:

In case of fire: smoke, fumes, hydrocarbons and oxides of carbon.

Storage: Store in original labeled container. Store in approved Flammable Liquid cabinet. Keep in cool and dry areas.

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11. Toxicological Information

Routes of exposure: Oral, dermal, inhalation and eye. Acute Toxicity: Dizziness and drowsiness. Skin Corrosion/Irritation:

May Cause Drying and Cracking

Serious Eye Damage: Irritating to eyes.

Respiratory or Skin Sensitization:

Non applicable

Germ Cell Mutagenicity:

Non applicable

Carcinogenicity: NTP Carcinogen: No, IARC Monographs: No, OSHA Regulated No

Reproductive Toxicity: Not determined STOT Single Exposure: Causes CNS depression. STOT Repeated Exposure:

Not determined

Aspiration Hazard: Not determined Hazardous Components CAS #/ENICS# LD 50 of

ingredients (Specify Species and route)

LC 50 of ingredients (Specify Species)

Ethyl Ether (a,b) 60-29-7/200-467-2 1215 mg / kg Oral-rat

6500 ppm / 99M inhalation – mouse

Ethanol (denatured) 64-17-5/200-578-6 7060/mg/kg Oral-rat

20000 ppm / 10 H inhalation – rat

Nitrocellulose, colloided, granular (d)

9004-70-0/603-037-01-3 >5000 mg/kg Oral rat

Not established

12. Ecological Information

Toxicity: No data available Persistence and Degradability:

No data available

Bioaccumulative Potential:

No data available

Mobility in Soil: No data available Results of PBT/vPvB Assessment:

No data available

Other Adverse effects: No data available

13. Disposal Considerations Waste Treatment Methods:

Dispose of contents/container in accordance with local/regional/national/international regulations. (P501)

14. Transport Information

Air: Nitrocellulose, solution flammable, Class 3, Packaging Group

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II, UN 2059

Land: Nitrocellulose, solution flammable, Class 3, Packaging Group II, UN 2059

Sea: Nitrocellulose, solution flammable, Class 3, Packaging Group II, UN 2059

Notes Label: Flammable Liquid Transportation information provided is for reference only. Client is urged to consult DOT, IMDG, IATA, EU, United Nations, TDG, and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes, packaging materials and methods of shipping.

15. Regulatory Information

Risk Phrases: R1, 3, 11, 12, 19, 22, 66, 67 Safety Phrases: S9, 16, 29, 33 TSCA (USA - Toxic Substance Control Act)

All components of this product are listed on the U.S. Toxic Substances Control Act Chemical Inventory (TSCA Inventory) or are exempted from listing because a Low Volume or Polymer Exemption has been granted in accordance with 40 CFR 723.50.

SARA TITLE III (USA - Superfund Amendments and Reauthorization Act)

311/312 Hazard Categories: Immediate health, fire hazard 313 Reportable Ingredients: None

CERCLA (USA - Comprehensive Response Compensation and Liability Act)

(a) The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) has notification requirements for releases or spills to the environment of the Reportable Quantity (RQ for this mixture > 24,000 lbs) or greater amounts, according to 40 CFR 302.

California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986

There are no reportable chemicals present known to the state of California to cause cancer or reproductive toxicity.

CPR (Canadian Controlled Products Regulations)

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. WHMIS Classification: B2

IDL (Canadian Ingredient Disclosure List)

Components of this product identified by CAS number and listed on the Canadian Ingredient Disclosure List are shown in Section 2.

DSL / NDSL (Canadian Domestic Substances List / Non-Domestic Substances List)

Components of this product identified by CAS number are listed on the DSL or NDSL, or are otherwise in compliance with the New Substances Notification (NSN) regulations. Only ingredients classified as "hazardous" are listed in Section 2 unless otherwise indicate

EINECS (European Inventory of Existing Commercial Chemical Substances

Components of this product identified by CAS numbers are on the European Inventory of Existing Commercial Chemical Substances.

WGK Water Quality Index: 1 VbK Index: A I

16. Other Information

To the best of our knowledge, the information contained herein is accurate. However, Mavidon® Medical Products assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. NO WARRANTY, EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS OR OTHERWISE IS MADE. In no event shall Mavidon® Medical Products or any of its subsidiaries be liable for any special, incidental or consequential damages.

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Creation Date: 8/03/2012 Replaces 9/09/2011