may 22-2013 poster-bfn-techno-economic assessment and process modeling of steam processed...

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This research is funded by BioFuelNet Canada, a network focusing on the development of advanced biofuels and associated bioproducts. BioFuelNet is a member of the Networks of Centres of Excellence of Canada program. www.biofuelnet.ca Techno-economic assessment and process modeling of steam processed lignocellulosic biomass for pellet production– University of Alberta Abstract • Biomass utilization for energy has two key characteristics obstructing its large scale usage, higher transportation cost and low calorific value • This study is focused on the detailed techno-economic modelling of steam pretreatment reactor and pellet production equipment using Aspen Plus. • The heat input required for grinding of untreated biomass (1.31MJ/kg) was found to be higher than that for steam pretreated biomass (0.82 MJ/Kg). • The calorific value (HHV based) of untreated ground biomass, 18.61 MJ/kg, was lower than that of steam pretreated ground biomass, 21.16 MJ/kg, which further increased to 22.2 MJ/Kg after pelletization. • The net energy ratio of the pelletization process decreased from 4.07 (untreated pellet) to 2.41 (treated pellet) due to the addition of heat input in the form of steam. The energy input for steam pretreatment was 4.30 MJ/Kg. Goal • Biomass conversion to densified form like pellets helps in increasing energy density by seven times. • Pellets are currently produced through conventional process where biomass is dried, ground, fractionated and processed. However, steam pretreatment of biomass facilitates its breakdown, resulting in pellets with better characteristics. • Our aim in this project is to summarize all these studies available in a detailed literature review with special indication to those studies where steam pretreatment is used for pre-processing of biomass for pellet production. • Techno-economic model for cost assessment will be developed by ASPEN PLUS model. Variation of cost of production of pellets from steam treated crop residue pellets will be estimated using the Aspen plus model. Material • The unit operation developed in ASPEN PLUS uses Douglas Fir samples as reference. • Douglas Fir pieces were brought to the lab at UBC and debarked manually, split using a band saw, and then chipped and screened to an approximate size of 20 by 20 by 5 mm chips. • The white woodchips and bark samples were dried naturally in the laboratory environment to lower the moisture content from 50% to about 20% MC by spreading wood pieces on wire mesh trays in a stack in the lab. • The process of drying for the model has been replaced by commercial rotary drum dryer for economic benefit. • Steam treatments were carried out in a 1 liter treatment vessel in UBC Clean Energy Center. Approximately, 25 g of each sample of ground wood was fed to the preheated reactor whose body temperature was maintained at 220°C. • The saturated steam at 220°C, with a flow rate of 1 cm 3 /s from the 2 L boiler, was fed to the treatment vessel for treatment of the particles for 5 minutes. Based on the data Method - ASPEN Model Figure-1: Steam Pretreatment unit operation simulated in ASPEN PLUS Figure-2: Pelletization unit operation simulated in ASPEN PLUS • The major operation parameters of steam pretreatment are the reaction temperature (T) and the residence time (t). A severity index (log Ro) is used to represent the degree of steam pretreatment. • The unit operation of steam treatment developed in ASPEN PLUS consists of a heater unit representing the boiler unit and a yield reactor representing steam gun. • The pellet production unit consist of Dryer, grinder and a pelletizer unit chosen from the solids model library of ASPEN PLUS. • The net heat duty provided from the simulation for each unit operation was validated against the experimental data of relative energy consumption per unit operation. Model Description Conclusion Simulation Model Result Operation Experimental Energy Input MJ/Kg ASPEN model Energy Input MJ/Kg Steam treated Untreated Steam treated Untreated Steam Pretreatment 4.30 0.0 4.35 0.0 Drying 4.52 3.01 4.56 2.98 Size reduction 0.82 1.31 0.88 1.28 Pelletization 0.27 0.24 0.25 0.23 Total Energy Input 9.91 4.56 10.04 4.49 Total Energy Output 21.00 18.00 21.80 18.40 Energy Ratio 2.12 3.95 2.17 4.10 Wet Biomass Steam pretreatment (0.49+0.73) kg Input Energy=1.88 MJ ( Electricity and steam) Drying Efficiency=85% (0.49+0.08) kg Input Energy=1.97 MJ (Flue gas from NG burning and electricity) 1 (0.5+0.5) kg 14 MJ Solids 0.01 kg Waste steam 0.063 MJ Water 0.65 kg Flue gas 0.2 MJ Grinding (0.47+0.06)kg Input Energy=0.36 MJ Steam treated Pellet Input Energy 0.13 MJ 0.43 kg dry 9.46 MJ Figure-3: ASPEN PLUS model of steam treatment representing mass and heat balance Techno-Economic Result Steam Treated Pellet Untreated Pellet Capacity (tons) 45000 45000 Total Energy (GJ) 990000 810000 Price of Pellet ($/tonne) 223 179 Price of Pellet ($/GJ) 10.14 9.96 • The analysis of the techno-economic model suggest that the cost of pellet produced increases with steam pretreatment due to increased capital and operating cost of steam generation and steam pretreatment unit. • Result Analysis of $/GJ of energy output show that the cost of pellet produced from steam pretreatment is similar to regular pellet since steam pretreatment significantly increases the calorific value of pellet compared to untreated pellet. • From the ASPEN PLUS model and Techno-Economic model, result shows increased cost of pellet produced from steam pretreatment occurs due to the increase capital cost and operating cost of steam gun. • The steam gun used for the techno-economic model process only 240 tons of raw biomass per day. • The increase in capacity will give significant scale of economics to the process reducing the capital cost and the operating cost of production. • The ASPEN PLUS model is progress to identify the effect of scale in cost of production is in progress. The final goal is Project Team University of Alberta team: Amit Kumar (PI) Sonia Ghatora (PDF) S M Hassan Shahrukh (RAsst) Acknowledgement Platform Western Project SEES 59 Table-1: The model validation data and compared net energy ratio of the ASPEN PLUS model with experimental data Table-2: Comparison of economic parameters of Steam treated pellet vs Untreated Pellet Dryer University of British Columbia team: Shahab Sokhansanj Linoj Kumar Bahman Ghiasi The authors are grateful for partial financial support from University of Alberta

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Page 1: May 22-2013 Poster-BFN-Techno-economic assessment and process modeling of steam processed lignocellulosic biomass for pellet production– University of  Alberta

This research is funded by BioFuelNet Canada, a network focusing on the development of advanced biofuels and associated bioproducts. BioFuelNet is a member of the Networks of Centres of Excellence of Canada program. www.biofuelnet.ca

Techno-economic assessment and process modeling of steam processed lignocellulosic biomass for pellet production– University of Alberta

Abstract• Biomass utilization for energy has two key characteristics obstructing its large

scale usage, higher transportation cost and low calorific value• This study is focused on the detailed techno-economic modelling of steam

pretreatment reactor and pellet production equipment using Aspen Plus. • The heat input required for grinding of untreated biomass (1.31MJ/kg) was found

to be higher than that for steam pretreated biomass (0.82 MJ/Kg). • The calorific value (HHV based) of untreated ground biomass, 18.61 MJ/kg, was

lower than that of steam pretreated ground biomass, 21.16 MJ/kg, which further increased to 22.2 MJ/Kg after pelletization.

• The net energy ratio of the pelletization process decreased from 4.07 (untreated pellet) to 2.41 (treated pellet) due to the addition of heat input in the form of steam. The energy input for steam pretreatment was 4.30 MJ/Kg.

Goal• Biomass conversion to densified form like pellets helps in increasing energy density

by seven times. • Pellets are currently produced through conventional process where biomass is

dried, ground, fractionated and processed. However, steam pretreatment of biomass facilitates its breakdown, resulting in pellets with better characteristics.

• Our aim in this project is to summarize all these studies available in a detailed literature review with special indication to those studies where steam pretreatment is used for pre-processing of biomass for pellet production.

• Techno-economic model for cost assessment will be developed by ASPEN PLUS model. Variation of cost of production of pellets from steam treated crop residue pellets will be estimated using the Aspen plus model.

Material• The unit operation developed in ASPEN PLUS uses Douglas Fir samples as

reference.• Douglas Fir pieces were brought to the lab at UBC and debarked manually, split

using a band saw, and then chipped and screened to an approximate size of 20 by 20 by 5 mm chips.

• The white woodchips and bark samples were dried naturally in the laboratory environment to lower the moisture content from 50% to about 20% MC by spreading wood pieces on wire mesh trays in a stack in the lab.

• The process of drying for the model has been replaced by commercial rotary drum dryer for economic benefit.

• Steam treatments were carried out in a 1 liter treatment vessel in UBC Clean Energy Center. Approximately, 25 g of each sample of ground wood was fed to the preheated reactor whose body temperature was maintained at 220°C.

• The saturated steam at 220°C, with a flow rate of 1 cm3/s from the 2 L boiler, was fed to the treatment vessel for treatment of the particles for 5 minutes. Based on the data of this experiment ASPEN PLUS model is developed.

 

Method - ASPEN Model

Figure-1: Steam Pretreatment unit operation simulated in ASPEN PLUS

Figure-2: Pelletization unit operation simulated in ASPEN PLUS

• The major operation parameters of steam pretreatment are the reaction temperature (T) and the residence time (t). A severity index (log Ro) is used to represent the degree of steam pretreatment.

• The unit operation of steam treatment developed in ASPEN PLUS consists of a heater unit representing the boiler unit and a yield reactor representing steam gun.

• The pellet production unit consist of Dryer, grinder and a pelletizer unit chosen from the solids model library of ASPEN PLUS.

• The net heat duty provided from the simulation for each unit operation was validated against the experimental data of relative energy consumption per unit operation. 

Model Description

Conclusion

Simulation Model Result

OperationExperimental Energy Input MJ/Kg ASPEN model Energy Input MJ/Kg

Steam treated Untreated Steam treated Untreated

Steam Pretreatment 4.30 0.0 4.35 0.0

Drying 4.52 3.01 4.56 2.98

Size reduction 0.82 1.31 0.88 1.28

Pelletization 0.27 0.24 0.25 0.23

Total Energy Input 9.91 4.56 10.04 4.49

Total Energy Output 21.00 18.00 21.80 18.40

Energy Ratio 2.12 3.95 2.17 4.10

Wet Biomass

Steam pretreatment (0.49+0.73) kg

Input Energy=1.88 MJ ( Electricity and steam)

Drying Efficiency=85%(0.49+0.08) kg

Input Energy=1.97 MJ(Flue gas from NG burning and

electricity)

1 (0.5+0.5) kg

14 MJ

Solids 0.01 kgWaste steam0.063 MJ

Water 0.65 kg Flue gas 0.2 MJ

Grinding(0.47+0.06)kg

Input Energy=0.36 MJ

Steam treated Pellet

Input Energy 0.13 MJ

0.43 kg dry

9.46 MJ

Figure-3: ASPEN PLUS model of steam treatment representing mass and heat balance

Techno-Economic Result

Steam Treated Pellet Untreated Pellet

Capacity (tons) 45000 45000

Total Energy (GJ) 990000 810000

Price of Pellet ($/tonne) 223 179

Price of Pellet ($/GJ) 10.14 9.96

• The analysis of the techno-economic model suggest that the cost of pellet produced increases with steam pretreatment due to increased capital and operating cost of steam generation and steam pretreatment unit.

• Result Analysis of $/GJ of energy output show that the cost of pellet produced from steam pretreatment is similar to regular pellet since steam pretreatment significantly increases the calorific value of pellet compared to untreated pellet.

• From the ASPEN PLUS model and Techno-Economic model, result shows increased cost of pellet produced from steam pretreatment occurs due to the increase capital cost and operating cost of steam gun.

• The steam gun used for the techno-economic model process only 240 tons of raw biomass per day.

• The increase in capacity will give significant scale of economics to the process reducing the capital cost and the operating cost of production.

• The ASPEN PLUS model is progress to identify the effect of scale in cost of production is in progress. The final goal is to identify the point of production capacity of pellet which will be lower in production for steam treated pellet than regular pellet.

 

Project TeamUniversity of Alberta team:

Amit Kumar (PI) Sonia Ghatora (PDF) S M Hassan Shahrukh (RAsst)

Acknowledgement

Platform Western ProjectSEES 59

Table-1: The model validation data and compared net energy ratio of the ASPEN PLUS model with experimental data

Table-2: Comparison of economic parameters of Steam treated pellet vs Untreated Pellet

Dryer

University of British Columbia team:

Shahab Sokhansanj Linoj Kumar Bahman Ghiasi

The authors are grateful for partial financial support from University of Alberta