materials aspects and application of superconductivityjuly 9, 2015 materials aspects aud...
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July 9, 2015 Materials Aspects aud Applications Superconductivity
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Materials Aspects and
Application of Superconductivity July 9, 2015
School of Environmental Science and Engineering
Toshihiko Maeda, Professor
Materials Science and Device Technology
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Contents
Self introduction
Brief introduction to Superconductivity
Materials Aspects
Application
On-going R&D
Brief introduction to superconductivity
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Electrical Resistance (Resistivity)
Ohm's law: V=RI ♠ V: voltage, I: current, R: resistance ♠ R depends on amount of material.
R=ρL/S ♠ ρ: resistivity, L: length, S: cross-section ♠ ρ is material constant.
Joule heat (energy) ♠ W=I2R
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battery
S
L
Magnetic force lines
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What is superconductivity?
In some materials, electrical resistance is absolutely zero below a certain temperature. This phenomenon is called "superconductivity" and this characteristic temperature is called "critical temperature" or "superconductivity transition temperature" (Tc).
Tc is very low in our normal sense (its present world record at ambient pressure is 133 K (-140˚C)), however, if Tc is higher than 77 K (-196˚C), we can use cheap liquid nitrogen instead of too expensive liquid helium (4.2 K) for cooling. July 9, 2015 Materials Aspects aud
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1911: discovered by H. K. Onnes (Leiden Univ., Netherland)
Resistivity of metals ♠ decreases as temperature (T) lowers.
At absolute zero (0 K, -273˚C), does it go down to zero or diverge to infinity? ♠ Using highly pure metal (mercury; Hg) and
liquid helium (liq. He), Onnes measured temperature-dependence of resistivity, and then, discovered "Superconductivity".
♠ Hg is liquid at room-temperature, so Hg is easily vaporized. By re-condensation, highly pure Hg can be obtained.
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Characterics (on the standpoint of Physics) Characteristics of superconductivity is not only
"zero resistance" but also •••♠ zero Joule loss: energy saving
Perfect Diamagnetism: type I superconductor♠ exclude magnetic flux♠ In type II, this is "imperfect".
Quantum Vortex Josephson Effect
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Type I Superconductor ≠ Perfect conductor
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cooling
room-temperature
H=0
perfect conductor
superconductor
B = 0normal state superconducting state by London
∂B∂t
= 0
∂B∂t
= 0
Superconductor ≠ Perfect conductor
Maxwell's equations
♠ D=ε0E+P=εrε0E=εE, B=µ0H+M=µrµ0H=µH
We can conclude that "superconducting state" and "normal state" are different phases from each other. July 9, 2015 Materials Aspects aud
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€
∇ • D = ρ
∇ × E = −∂B∂t
∇ • B = 0
∇ × H = −∂D∂t
+ J
Why superconductivity: Application
Zero-resistance♠ very strong electromagnet (NMR, MRI ••••)♠ energy storage (SMES; superconducting magnetic energy storage)
Diamagnetism♠ magnetic shielding
Quantum Vortex ♠ highly sensitive magnetic sensor (SQUID etc.)
Josephson effect♠ highly sensitive magnetic sensor (SQUID etc.)
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3 critical parameters
Critical temperature (Tc)
Critical field (Hc1, Hc2)
Critical current (Jc) ♠ the most important parameter for
practical application
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Brief History of Superconductivity
1908: Liquid Helium 1911: discovery of Superconductivity (Hg, Sn, Pb) 1933: Meissner effect 1935: London equation 1935-37: Type II Superconductor 1954: Nb3Sn (18.5 K) 1960: GL theory 1961: Quantum Vortex 1961: NbTi (9.8 K) 1957: BCS theory 1962: Josephson effect 1974: Nb3Ge (23.2 K) 1986: discovery of High-Temperature Superconductivity
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Increasing Tc: HTSC
Materials Aspects
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Element superconductors
Many elements exhibit superconductivity at 1 atm. ♠ Hg, Pb, Sn, Nb, ••• (30 elements) ♠ Under high-pressure, much more!)
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Other (Compound) superconductors
Alloys: NbTi etc. Intermetallic compounds: Nb3Sn, Nb3Al etc. Organic compounds: (TMTSF)2PF6 etc. Sulfides: PbMo6S8 etc. Oxides (Cuprates: high-temperature superconductors)
♠ SrTiO3, Ba(Pb,Bi)O3 etc. ♠ (La,Ba)Cu2O4
♠ YBa2Cu3O7 ♠ Bi2Sr2Can-1CunO2n+4, Tl2Ba2Can-1CunO2n+4 etc. ♠ Fe-based Oxides (Arsenides): new comers
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Conventional Superconductors
At present, superconductors used for practical application are NbTi (bcc) and Nb3Ti only.
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Nb3Sn: A15 structure
YBa2Cu3Oz
The first material having Tc higher than 77 K (Tc≈90 K for z≈7; quite sensitive on z value).
The structure is oxygen-deficient triple perovskite.
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Perovskite structure
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Ionic crystal with chemical formula of ABO3. Many functional oxides with 3d transition metals. The most famous one is (probably) BaTiO3 in
which TiO6 octahedron is slightly distorted.
Examples of Application
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Labo. application
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High-field magnet SQUID NMR
Medical application (MRI)
Magnetic Resonance Inspection
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Transportation (MAGLEV)
Magnetically Levitation Train
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Apr. 21, 2015: World record: 603 km/h
Large scale application
LHC: Large hadron collider (CERN)♠ Nobel prize in 2013♠ Japanese suppliers contribute a lot.
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On going R&D
Superconducting power cable
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1st generation wire: Ag-sheathed Bi2Sr2Ca2Cu3O10: powder sintering
2nd generation wire (epitaxial thin film)
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PLD apparatus
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0
2
4
6
0 10 20 30 40 50 60 70 80
Inte
nsity
/ 10
4 cps
2θ/degree
CuKα
NiO
(200
)
(001
) (002
)
(003
)
(004
)
(005
) (006
)
(007
)
(008
)
(009
)
PLD-YBCO/(100) NiO single crystal
XRD profile of YBCO film
Tsub=680˚C
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Pole figure
α
β
0˚
90˚
180˚
270˚α=90˚
α=0˚
YBCO (102)
NiO <100>
NiO <010>
CuKα2θ=27.56˚α: 15~90˚β: 0~360˚
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0
200
400
600
800
1000
1200
0 90 180 270 360β/degree
Inte
nsity
/ cp
s
CuKαPLD-YBCO/NiO(100) single crystal
YBCO (102)・2θ=27.56˚・α=34˚
FWHM=1.9˚
β-scan profile
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Temperature dependence of resistivity
0
50
100
150
200
250
300
0 50 100 150 200 250 300
Resi
stiv
ity, ρ
/(µΩ
•cm
)
Temperature, T/K
I=0.01 mA
0
20
40
60
80
100
88 90 92
PLD-YBCO/(100) NiO single crystal
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I-V characterics at 77 K
0
5
10
15
20
25
30
35
0 0.2 0.4 0.6 0.8 1 1.2 1.4
Volta
ge, V
/µV
Current, I/A
PLD-YBCO/(100) NiO single crystal
1 µVcorresponding to: ♦ Ic*= 60.7 A for 10 mm width ♦ Jc = 3.3 MA/cm2
Temperature: 77.3 Kthickness: 180 nmwidth: 173 µmlength: 0.69 mm
Ic=1.05 A
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Cross sectional HRSEM images of fractured surface for PLD-YBCO/NiO structure
180 nmYBCOYBCO
NiONiO
YBCOYBCO
NiONiO
200 nm1 µm
(taken by Kyoto Univ.)
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TEM image of interface structure ofPLD-YBCO/(100) NiO single crystal
100 nm
YBCO
NiO
Materials Aspects aud Applications Superconductivity
Summary
Superconductivity
♠ hopeful
♠ interesting
♠ cute
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That's all !!
Thank you for your attention !!
Submit your report at the beginning of next lecture.
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