material testing report mat9702 kw102-25/kw105-75mat9702 summary beaumont advanced processing...
TRANSCRIPT
Material Testing Report
MAT9702
KW102-25/KW105-75
Prepared for:
Stress Engineering Services
7030 Stress Engineering Way
Mason, OH 45040
USA
Prepared by:
Beaumont Advanced Processing
6100 West Ridge Rd
Erie, PA 16506
USA
Prepared on:
11 December, 2019
Report Created By:
David Schmidt
Materials Lab Engineer
11 December, 2019
© Beaumont Advanced Processing 2019. This report may not be reproduced.
Test results relate only to the item tested. Autodesk disclaims all warranties express or implied, including warranties of merchantability and fitness for a particular purpose. Beaumont Advanced Processing expressly disclaims all incidental and consequential damages that may arise from the use of this information.
Contents
Summary ......................................................................................................................... 4
Viscosity .......................................................................................................................... 8
Thermal conductivity ..................................................................................................... 14
Specific heat .................................................................................................................. 16
Pressure-Volume-Temperature ..................................................................................... 18
Mold verification ........................................................................................................... 21
Contact details .............................................................................................................. 25
mat9702 Summary
Beaumont Advanced Processing KW102-25/KW105-75 Page 4 of 25
Summary
Description
Family name BLENDS (PC+PBT, PC+ABS, ...)
Trade name KW102-25/KW105-75
Manufacturer KW Plastics
Family abbreviation PP+PE
Material structure Crystalline
Data source Beaumont Advanced Processing : pvT-Measured : mech-Supplemental
Date last modified 11-DEC-19
Date tested 09-DEC-19
Data status Confidential
Material ID 60702
Grade code mat9702
Supplier code CUSTOM
Fibers/fillers Unfilled
Recommended Processing
Mold surface temperature 52.00 °C
Melt temperature 218.00 °C
Mold temperature range (recommended)
Minimum 38.00 °C
Maximum 66.00 °C
Melt temperature range (recommended)
Minimum 204.00 °C
Maximum 232.00 °C
Absolute maximum melt temperature 246.00 °C
Ejection temperature 105.00 °C
Maximum shear stress 0.25 MPa
Maximum shear rate 100000 1/s
Maximum shear stress and maximum shear rate values have been supplemented with generic estimates.
mat9702 Summary
Beaumont Advanced Processing KW102-25/KW105-75 Page 5 of 25
Rheological Properties
Cross WLF Viscosity Model
n 0.3230
Tau 73923.0 Pa
D1 3.06675e+016 Pa-s
D2 153.15 K
D3 0 K/Pa
A1 35.313
A2 51.600 K
Juncture loss method coefficients
C1 0.04458 Pa^(1-c2)
C2 1.421
Transition temperature
Ttrans 120.00 °C
Moldflow Viscosity Index VI(240)157
mat9702 Summary
Beaumont Advanced Processing KW102-25/KW105-75 Page 6 of 25
Thermal Properties
Specific heat data
Temperature (T)
°C
Specific heat (Cp)
J/kg-°C
Heating/Cooling rate
°C/s
217.81 3167.3 -0.33
171.41 2914.3 -0.33
127.07 2702.4 -0.33
122.95 2696.1 -0.33
120.89 2888.9 -0.33
119.88 3798.3 -0.33
118.97 7223.1 -0.33
118.25 13292.0 -0.33
117.45 15787.0 -0.33
115.77 13749.0 -0.33
108.15 7034.8 -0.33
103.73 5110.6 -0.33
99.458 4306.7 -0.33
95.275 4047.0 -0.33
91.135 4023.6 -0.33
89.064 3901.1 -0.33
81.771 3245.2 -0.33
76.581 3041.6 -0.33
63.129 2665.6 -0.33
45.555 2273.0 -0.33
30.074 2048.6 -0.33
Thermal conductivity data
Temperature (T)
°C
Thermal conductivity
(k) W/m-°C
Heating/Cooling rate
°C/s
230.00 0.240 0.0
220.00 0.246 0.0
200.00 0.248 0.0
180.00 0.252 0.0
160.00 0.257 0.0
140.00 0.260 0.0
120.00 0.336 0.0
100.00 0.355 0.0
80.00 0.371 0.0
65.00 0.384 0.0
mat9702 Summary
Beaumont Advanced Processing KW102-25/KW105-75 Page 7 of 25
PVT Properties
Melt density 0.8272 g/cm3
Solid density 1.0353 g/cm3
2-domain Tait PVT model coefficients
b5 407.15 K
b6 1.270e-007 K/Pa
b1m 0.001139 m3/kg
b2m 8.325e-007 m3/kg-K
b3m 1.14920e+008 Pa
b4m 0.00509 1/K
b1s 0.001025 m3/kg
b2s 5.433e-007 m3/kg-K
b3s 2.32191e+008 Pa
b4s 0.003698 1/K
b7 0.000114 m3/kg
b8 0.064404 1/K
b9 1.158e-008 1/Pa
Mechanical Properties
Mechanical properties data Elastic modulus, 1st principal direction [E1] 1440 MPa
Elastic modulus, 2nd principal direction [E2] 1440 MPa
Poisson's ratio [v12] 0.3640
Poisson's ratio [v23] 0.3640
Shear modulus [G12] 526 MPa
Transversely isotropic coefficient of thermal expansion [CTE] data Alpha1 9.920e-005 1/°C
Alpha2 9.920e-005 1/°C
Mechanical and CTE data have not been tested for this material. The data has been supplemented with generic estimates for unfilled PP+PE.
Filler Properties
Filler data Description Weight %
mat9702 Viscosity
Beaumont Advanced Processing KW102-25/KW105-75 Page 8 of 25
Viscosity
Method: AMPL Test Method
Instrument: Arburg Allrounder 270S Injection Molding Machine
Test Specifications: Sample Form: Pellets
Pre-Processing: Not required
Moisture Level: Not measured
Capillary A: Length: 31.9693 mm
L/D: 15.98465
Die Entry Angle: 90 degrees
Capillary B: Length: 7.9731 mm
L/D: 3.98655
Die Entry Angle: 90 degrees
Barrel Diameter: 30 mm
Plastication Time: 20 sec
Dwell Time: 20 sec
Corrections: Bagley, Rabinowitsch and shear heating
Date Received: 25-NOV-19
Date Tested: 27-NOV-19
Operator’s Notes: Testing was performed per standard testing procedures. No anomalies were noted during testing.
mat9702 Viscosity
Beaumont Advanced Processing KW102-25/KW105-75 Page 9 of 25
Apparent Viscosity Data
Temperature
(°C)
Apparent Shear Rate
(sec-1)
Apparent Viscosity (Pa-s)
Die Diameter
(mm)
Die L/D (-)
194.7 64871 14.45 2.00 15.99
194.7 191 590.51 2.00 15.99
194.8 322 437.42 2.00 15.99
194.8 765 266.40 2.00 15.99
194.8 25538 27.07 2.00 15.99
195.8 1339 190.31 2.00 15.99
195.8 2592 126.75 2.00 15.99
197.0 12771 44.16 2.00 15.99
197.8 6465 70.70 2.00 15.99
203.7 195 551.34 2.00 15.99
203.8 316 421.07 2.00 15.99
204.8 772 250.21 2.00 15.99
204.8 25577 27.13 2.00 15.99
204.8 64813 14.49 2.00 15.99
205.8 1349 176.60 2.00 15.99
205.8 2570 119.73 2.00 15.99
207.0 12795 43.08 2.00 15.99
207.8 6474 67.63 2.00 15.99
213.7 198 495.97 2.00 15.99
214.7 25586 26.66 2.00 15.99
214.8 319 386.68 2.00 15.99
214.8 773 239.64 2.00 15.99
214.8 64538 14.54 2.00 15.99
215.8 1351 173.52 2.00 15.99
215.8 2584 117.63 2.00 15.99
216.4 12759 42.56 2.00 15.99
217.8 6470 66.41 2.00 15.99
223.8 196 456.96 2.00 15.99
224.7 323 352.27 2.00 15.99
224.7 64992 13.80 2.00 15.99
224.8 777 223.07 2.00 15.99
224.8 1338 164.05 2.00 15.99
224.8 25546 25.50 2.00 15.99
225.8 2588 111.27 2.00 15.99
226.3 12765 40.55 2.00 15.99
227.3 6465 63.24 2.00 15.99
201.0 191 768.15 2.00 3.99
201.0 322 579.96 2.00 3.99
201.0 765 368.62 2.00 3.99
202.0 1339 266.83 2.00 3.99
203.0 2592 178.90 2.00 3.99
203.0 25538 45.48 2.00 3.99
203.9 12771 68.45 2.00 3.99
203.9 64871 26.29 2.00 3.99
mat9702 Viscosity
Beaumont Advanced Processing KW102-25/KW105-75 Page 10 of 25
Temperature
(°C)
Apparent Shear Rate
(sec-1)
Apparent Viscosity (Pa-s)
Die Diameter
(mm)
Die L/D (-)
206.0 6465 103.99 2.00 3.99
213.9 1349 257.54 2.00 3.99
214.0 195 684.87 2.00 3.99
214.0 772 348.41 2.00 3.99
215.0 316 543.03 2.00 3.99
215.0 2570 178.68 2.00 3.99
216.0 12795 66.14 2.00 3.99
216.0 25577 43.16 2.00 3.99
216.0 64813 24.66 2.00 3.99
216.9 6474 101.85 2.00 3.99
223.9 773 317.78 2.00 3.99
225.0 319 476.31 2.00 3.99
225.0 1351 237.62 2.00 3.99
225.0 2584 165.88 2.00 3.99
225.9 25586 42.42 2.00 3.99
226.0 198 592.45 2.00 3.99
226.0 64538 24.58 2.00 3.99
226.7 12759 64.42 2.00 3.99
227.0 6470 97.12 2.00 3.99
235.0 323 443.38 2.00 3.99
235.0 777 296.17 2.00 3.99
235.0 1338 225.99 2.00 3.99
235.0 2588 157.29 2.00 3.99
236.9 12765 61.78 2.00 3.99
237.0 196 551.11 2.00 3.99
237.0 25546 40.54 2.00 3.99
237.0 64992 23.12 2.00 3.99
238.0 6465 92.60 2.00 3.99
mat9702 Viscosity
Beaumont Advanced Processing KW102-25/KW105-75 Page 11 of 25
Calculated Viscosity
Temperature
(°C)
Shear Rate (sec-1)
Calculated Viscosity
(Pa-s)
194.7 64871 12.74
194.7 191 500.01
194.8 322 379.16
194.8 765 229.80
194.8 25538 23.80
195.8 1339 162.26
195.8 2592 106.87
197.0 12771 37.42
197.8 6465 58.45
201.0 191 479.99
201.0 322 365.23
201.0 765 222.30
202.0 1339 157.26
203.0 2592 103.24
203.0 25538 22.96
203.7 195 466.60
203.8 316 362.50
203.9 64871 12.24
203.9 12771 36.28
204.8 64813 12.20
204.8 772 216.73
204.8 25577 22.76
205.8 1349 153.70
205.8 2570 102.47
206.0 6465 56.35
207.0 12795 35.76
207.8 6474 55.85
213.7 198 435.48
213.9 1349 147.77
214.0 195 437.37
214.0 772 206.78
214.7 25586 21.84
214.8 319 338.68
214.8 64538 11.74
214.8 773 205.83
215.0 2570 98.28
215.0 316 339.58
215.8 1351 146.38
215.8 2584 97.58
216.0 12795 34.44
216.0 25577 21.73
216.0 64813 11.65
mat9702 Viscosity
Beaumont Advanced Processing KW102-25/KW105-75 Page 12 of 25
Temperature
(°C)
Shear Rate (sec-1)
Calculated Viscosity
(Pa-s)
216.4 12759 34.45
216.9 6474 53.71
217.8 6470 53.53
223.8 196 410.69
223.9 773 196.72
224.7 64992 11.24
224.7 323 317.81
224.8 1338 141.24
224.8 777 195.37
224.8 25546 21.00
225.0 319 319.80
225.0 1351 140.30
225.0 2584 93.75
225.8 2588 93.35
225.9 25586 20.89
226.0 198 404.13
226.0 64538 11.24
226.3 12765 33.09
226.7 12759 33.06
227.0 6470 51.56
227.3 6465 51.53
235.0 323 300.64
235.0 777 186.11
235.0 1338 134.96
235.0 2588 89.83
236.9 12765 31.78
237.0 25546 20.07
237.0 196 379.68
237.0 64992 10.74
238.0 6465 49.42
mat9702 Viscosity
Beaumont Advanced Processing KW102-25/KW105-75 Page 13 of 25
Rheological Data
Cross WLF Viscosity Model
n 0.3230
Tau 73923.0 Pa
D1 3.06675e+016 Pa-s
D2 153.15 K
D3 0 K/Pa
A1 35.313
A2 51.600 K
Juncture loss method coefficients
C1 0.04458 Pa^(1-c2)
C2 1.421
1.0E+0
1.0E+1
1.0E+2
1.0E+3
1.0E+4
1.0E+1 1.0E+2 1.0E+3 1.0E+4 1.0E+5
Vis
cosi
ty (
Pa
-s)
Shear rate (1/s)
Viscosity vs shear rate
T = 204 °C T = 218 °C T = 232 °C
mat9702 Thermal conductivity
Beaumont Advanced Processing KW102-25/KW105-75 Page 14 of 25
Thermal conductivity
Method: ISO 22007-2, Plastics - Determination of thermal conductivity and thermal diffusivity - Part 2: Transient plane heat source (hot disc) method
Instrument: Hot Disk TPS 2500 S Thermal Constants Analyser
Test Specifications: Sample Form: 19 mm disks (2) machined from molded plaque
Pre-Processing: N/A
Moisture Level: DAM (Dry As Molded)
Sensor Specification Hot Disk 5465 3.189mm Kapton sensor
Measurement Time 10 sec
Heating Power 60 mW
Date Received: 25-NOV-19
Date Tested: 09-DEC-19
Operator’s Notes: Testing was performed per standard testing procedures. No anomalies were noted during testing.
mat9702 Thermal conductivity
Beaumont Advanced Processing KW102-25/KW105-75 Page 15 of 25
Thermal conductivity data
Temperature (T) °C
Thermal conductivity (k) W/m-°C
Heating/Cooling rate °C/s
230.00 0.240 0.0
220.00 0.246 0.0
200.00 0.248 0.0
180.00 0.252 0.0
160.00 0.257 0.0
140.00 0.260 0.0
120.00 0.336 0.0
100.00 0.355 0.0
80.00 0.371 0.0
65.00 0.384 0.0
0.00
0.10
0.20
0.30
0.40
0.50
0.60
0 50 100 150 200 250
Ther
mal
co
nd
uct
ivit
y, k
(W
/m-°
C)
Temperature (°C)
Thermal conductivity vs temperature
mat9702 Specific heat
Beaumont Advanced Processing KW102-25/KW105-75 Page 16 of 25
Specific heat
Method: ASTM E 1269, Standard Test Method for Determining Specific Heat Capacity by Differential Scanning Calorimetry ASTM D 3418, Standard Test Method for Transition Temperatures and Enthalpies of Fusion and Crystallization of Polymers by Differential Scanning Calorimetry
Instrument: TA Instruments Discovery Differential Scanning Calorimeter
Test Specifications: Sample Form: Pellets
Pre-Processing: Not required
Moisture Level: Not measured
Initial Temperature: 232°C
Final Temperature: 20°C
Cooling Rate: -20°C/min
Equilibrium Time: 3 min
Sample holder material: Aluminum
Sample holder volume: 40 µl
Sample holder mass: 53 mg (pan+lid)
Purge gas: 99.99% pure nitrogen
Purge gas flow rate: 50 ml/min
Date Received: 25-NOV-19
Date Tested: 10-DEC-19
Operator’s Notes: Testing was performed per standard testing procedures. No anomalies were noted during testing.
mat9702 Specific heat
Beaumont Advanced Processing KW102-25/KW105-75 Page 17 of 25
Specific heat data
Temperature (T)
°C
Specific heat (Cp)
J/kg-°C
Heating/Cooling
rate °C/s
217.81 3167.3 -0.33
171.41 2914.3 -0.33
127.07 2702.4 -0.33
122.95 2696.1 -0.33
120.89 2888.9 -0.33
119.88 3798.3 -0.33
118.97 7223.1 -0.33
118.25 13292.0 -0.33
117.45 15787.0 -0.33
115.77 13749.0 -0.33
108.15 7034.8 -0.33
103.73 5110.6 -0.33
99.458 4306.7 -0.33
95.275 4047.0 -0.33
91.135 4023.6 -0.33
89.064 3901.1 -0.33
81.771 3245.2 -0.33
76.581 3041.6 -0.33
63.129 2665.6 -0.33
45.555 2273.0 -0.33
30.074 2048.6 -0.33
Ttrans 120.00 °C
Ejection temperature 105.00 °C
0
2000
4000
6000
8000
10000
12000
14000
16000
18000
0 50 100 150 200 250
Spec
ific
hea
t, C
p (
J/kg
-°C
)
Temperature (°C)
Specific heat vs temperature
mat9702 Pressure-Volume-Temperature
Beaumont Advanced Processing KW102-25/KW105-75 Page 18 of 25
Pressure-Volume-Temperature
Method: High Pressure Indirect Dilatometry Instrument: Gnomix pvT Apparatus Test Specifications:
Sample Form: Molded Plaque
Pre-Processing: Not required
Scan type: Isothermal Cooling
Date Received: 25-NOV-19
Date Tested: 05-DEC-19
Operator’s Notes: Testing was performed per standard testing procedures. No anomalies were noted during testing.
mat9702 Pressure-Volume-Temperature
Beaumont Advanced Processing KW102-25/KW105-75 Page 19 of 25
pvT Experimental Data
Temperature (°C)
Pressure (MPa)
0MPa 50MPa 100MPa 150MPa 200MPa
38.19 0.9736 0.9609 0.9502 0.9413 0.9331
52.92 0.9819 0.9679 0.9563 0.9467 0.9380
67.48 0.9910 0.9753 0.9628 0.9525 0.9432
81.97 1.0020 0.9839 0.9702 0.9590 0.9487
96.14 1.0160 0.9951 0.9792 0.9663 0.9550
110.20 1.0340 1.0090 0.9901 0.9754 0.9626
124.40 1.0810 1.0340 1.0060 0.9868 0.9718
138.70 1.1430 1.1030 1.0510 1.0090 0.9853
153.10 1.1560 1.1140 1.0860 1.0540 1.0110
167.40 1.1670 1.1220 1.0930 1.0700 1.0510
181.70 1.1790 1.1310 1.1000 1.0760 1.0570
197.90 1.1930 1.1400 1.1070 1.0830 1.0620
207.80 1.2010 1.1460 1.1120 1.0870 1.0660
216.60 1.2090 1.1520 1.1170 1.0910 1.0700
230.80 1.2210 1.1580 1.1210 1.0950 1.0730
mat9702 Pressure-Volume-Temperature
Beaumont Advanced Processing KW102-25/KW105-75 Page 20 of 25
Melt density 0.8272 g/cm3
Solid density 1.0353 g/cm3
2-domain Tait PVT model coefficients
b5 407.15 K
b6 1.270e-007 K/Pa
b1m 0.001139 m3/kg
b2m 8.325e-007 m3/kg-K
b3m 1.14920e+008 Pa
b4m 0.00509 1/K
b1s 0.001025 m3/kg
b2s 5.433e-007 m3/kg-K
b3s 2.32191e+008 Pa
b4s 0.003698 1/K
b7 0.000114 m3/kg
b8 0.064404 1/K
b9 1.158e-008 1/Pa
0.88
0.93
0.98
1.03
1.08
1.13
1.18
1.23
1.28
20 70 120 170 220
Spec
ific
vo
lum
e (c
m^3
/g)
Temperature (°C)
Specific volume vs temperature
0 MPa 50 MPa 100 MPa 150 MPa 200 MPa
mat9702 Mold verification
Beaumont Advanced Processing KW102-25/KW105-75 Page 21 of 25
Mold verification
Method: AMPL Mold Verification Test Method (QOP-16-M)
Instrument: Krauss Maffei KM160-750CX Injection molding machine
Test Specifications: Sample Form: Pellets
Pre-Processing: Not required
Moisture Level: Not measured
Date Received: 25-NOV-19
Date Tested: 26-NOV-19
Operator’s Notes: Testing was performed per standard testing procedures. No anomalies were noted during testing.
mat9702 Mold verification
Beaumont Advanced Processing KW102-25/KW105-75 Page 22 of 25
1.5mm tag die
Experiment Number
Flow Rate (cc/sec)
Melt Temperature
Mold Temperature
Cyc0036 17.6 219.1 53.2
Cyc0046 45.3 220 53.2
0
10
20
30
40
50
60
70
80
0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8
Pre
ssu
re (M
Pa)
Time (s)
Cavity Pressure vs Time
Experimental data AMI2018R2 simulation
Part thickness : 1.5 mmFlow rate : 17.6 cc/secMelt temperature : 219.1 °CMold temperature : 53.2 °C
0
10
20
30
40
50
60
70
80
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
Pre
ssu
re (M
Pa)
Time (s)
Cavity Pressure vs Time
Experimental data AMI2018R2 simulation
Part thickness : 1.5 mmFlow rate : 45.3 cc/secMelt temperature : 220.0 °CMold temperature : 53.2 °C
mat9702 Mold verification
Beaumont Advanced Processing KW102-25/KW105-75 Page 23 of 25
2mm tag die
Experiment Number
Flow Rate (cc/sec)
Melt Temperature
Mold Temperature
Cyc0012 11.8 217.7 51.5
Cyc0021 45.4 218.3 54.8
0
5
10
15
20
25
30
35
40
45
0.0 0.5 1.0 1.5 2.0 2.5 3.0
Pre
ssu
re (M
Pa)
Time (s)
Cavity Pressure vs Time
Experimental data AMI2018R2 simulation
Part thickness : 2.0 mmFlow rate : 11.8 cc/secMelt temperature : 217.7 °CMold temperature : 51.5 °C
0
10
20
30
40
50
60
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
Pre
ssu
re (M
Pa)
Time (s)
Cavity Pressure vs Time
Experimental data AMI2018R2 simulation
Part thickness : 2.0 mmFlow rate : 45.4 cc/secMelt temperature : 218.3 °CMold temperature : 54.8 °C
mat9702 Mold verification
Beaumont Advanced Processing KW102-25/KW105-75 Page 24 of 25
3mm tag die
Experiment Number
Flow Rate (cc/sec)
Melt Temperature
Mold Temperature
Cyc0051 14 216.7 53.6
Cyc0063 71.2 218.4 54.7
0
2
4
6
8
10
12
14
16
18
20
0.0 0.5 1.0 1.5 2.0 2.5 3.0
Pre
ssu
re (M
Pa)
Time (s)
Cavity Pressure vs Time
Experimental data AMI2018R2 simulation
Part thickness : 3.0 mmFlow rate : 14.0 cc/secMelt temperature : 216.7 °CMold temperature : 53.6 °C
0
5
10
15
20
25
0.0 0.1 0.2 0.3 0.4 0.5 0.6
Pre
ssu
re (M
Pa)
Time (s)
Cavity Pressure vs Time
Experimental data AMI2018R2 simulation
Part thickness : 3.0 mmFlow rate : 71.2 cc/secMelt temperature : 218.4 °CMold temperature : 54.7 °C
Contact details
Beaumont Advanced Processing Page 25 of 25
Contact details
Beaumont Advanced Processing
6100 West Ridge Rd
Erie, PA 16506
USA
Phone: +1-814-899-6390
Fax: +1-814-899 7117
Email: [email protected]
Testing enquiries: [email protected]
Beaumont Advanced Processing website: www.bapmolding.com