material safety data sheet page 1/5 according to 91/155 eec · reviewed on 15.12.2006 material...

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Printing date 15.12.2006Reviewed on 15.12.2006

Material Safety Data SheetAccording to 91/155 EEC

DR

1 Identification of the substance/preparation and of the company/undertaking

· Product details

· Trade name: MA 4500 blue / blau

· Manufacturer/Supplier:DOKUMENTAL GmbH & Co KG SchreibfarbenWoellnerstraße 26D-67065 LudwigshafenPhone + 49(0)621/5402321Fax + 49(0)621/5402391www. dokumental.de

· Further information obtainable from:Technical Service, Dr. B. PolzinTel.: +49-621-5402322Mobile +49-1726204412

· Information in case of emergency:GBK Gefahrgut Büro GmbH++49 (0) 6132 / 84463Ingelheim, Deutschland

* 2 Composition/information on ingredients

· Chemical characterizationMixture of the following substances, containing non-hazardous substances and colouring agents.

· Description: Mixture of substances listed below with nonhazardous additions.

· Dangerous components:

71-23-8 propan-1-ol Xi, F; R 11-41-67 50-100%

90506-69-7 Ethylhexyl phosphoric acid ester. C, Xn; R 22-34 ≤ 2,5%6786-83-0 C. I. Solvent Blue 4 Xn; R 22 ≤ 2,5%

52080-58-7 C. I. Solvent Violet 8 Xn, Xi, N; R 22-41-50/53 ≤ 2,5%· Additional information: For the wording of the listed risk phrases refer to section 16.

* 3 Hazards identification

· Hazard description:

Xi Irritant

· Information concerning particular hazards for human and environment:The product has to be labelled due to the calculation procedure of the "General Classificationguideline for preparations of the EU" in the latest valid version.Has a narcotizing effect.R 10 Flammable.R 41 Risk of serious damage to eyes.R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.R 67 Vapours may cause drowsiness and dizziness.

· Classification system:The classification is according to the latest editions of the EU-lists, and extended by company andliterature data.

4 First-aid measures

· After inhalation: Supply fresh air; consult doctor in case of complaints.· After skin contact: Generally the product does not irritate the skin.· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.· After swallowing: If symptoms persist consult doctor.

5 Fire-fighting measures

· Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.· For safety reasons unsuitable extinguishing agents:

WaterWater with full jet

· Protective equipment: No special measures required.

* 6 Accidental release measures

· Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.(Contd. on page 2)

EU

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Trade name: MA 4500 blue / blau

(Contd. of page 1)

DR

· Measures for environmental protection:Do not allow product to reach sewage system or any water course.Inform respective authorities in case of seepage into water course or sewage system.Do not allow to enter sewers/ surface or ground water.

· Measures for cleaning/collecting:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).Ensure adequate ventilation.Do not flush with water or aqueous cleansing agents

7 Handling and storage

· Handling:· Information for safe handling:

Ensure good ventilation/exhaustion at the workplace.Prevent formation of aerosols.

· Information about fire - and explosion protection:Keep ignition sources away - Do not smoke.Protect against electrostatic charges.

· Storage:· Requirements to be met by storerooms and receptacles: No special requirements.· Information about storage in one common storage facility: Not required.· Further information about storage conditions: Keep container tightly sealed.

8 Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.

· Ingredients with limit values that require monitoring at the workplace:The product does not contain any relevant quantities of materials with critical values that have tobe monitored at the workplace.

· Additional information: The lists valid during the making were used as basis.

· Personal protective equipment:· General protective and hygienic measures:

Immediately remove all soiled and contaminated clothingWash hands before breaks and at the end of work.Avoid contact with the eyes.

· Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case of intensive orlonger exposure use self-contained respiratory protective device.

· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ thepreparation.Due to missing tests no recommendation to the glove material can be given for the product/ thepreparation/ the chemical mixture.Selection of the glove material on consideration of the penetration times, rates of diffusion andthe degradation

· Material of glovesThe selection of the suitable gloves does not only depend on the material, but also on further marksof quality and varies from manufacturer to manufacturer. As the product is a preparation of severalsubstances, the resistance of the glove material can not be calculated in advance and has thereforeto be checked prior to the application.

· Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protective gloves and hasto be observed.

· Eye protection:

Tightly sealed goggles

* 9 Physical and chemical properties

· General Information

Form: FluidColour: According to product specificationOdour: Characteristic

(Contd. on page 3) EU

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(Contd. of page 2)

DR

· Change in conditionMelting point/Melting range: Undetermined.Boiling point/Boiling range: 96°C

· Flash point: 23°C

· Ignition temperature: 360°C

· Self-igniting: Product is not selfigniting.

· Danger of explosion: Product is not explosive. However, formation of explosive air/vapour mixtures are possible.

· Explosion limits:Lower: 2,1 Vol %Upper: 13,5 Vol %

· Vapour pressure at 20°C: 19 hPa

· Density at 20°C: 0,84 g/cm³

· Solubility in / Miscibility withwater: Not miscible or difficult to mix.

· Viscosity:Dynamic at 20°C: 4 mPas

· Solvent content:Organic solvents: 88,3 %

· Solids content: 9,2 %

10 Stability and reactivity

· Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.

· Dangerous reactions No dangerous reactions known.· Dangerous decomposition products: No dangerous decomposition products known.

* 11 Toxicological information

· Acute toxicity:

· LD/LC50 values relevant for classification:

52080-58-7 C. I. Solvent Violet 8

Oral LD50 700 mg/kg (Ratte)

· Primary irritant effect:· on the skin: No irritant effect.· on the eye: Strong irritant with the danger of severe eye injury.· Sensitization: No sensitizing effects known.· Additional toxicological information:

The product shows the following dangers according to the calculation method of the General EUClassification Guidelines for Preparations as issued in the latest version:Irritant

* 12 Ecological information

· Ecotoxical effects:· Remark: Harmful to fish· General notes:

Water hazard class 2 (German Regulation) (Self-assessment): hazardous for waterDo not allow product to reach ground water, water course or sewage system.Danger to drinking water if even small quantities leak into the ground.Harmful to aquatic organisms

13 Disposal considerations

· Product:· Recommendation

Must not be disposed together with household garbage. Do not allow product to reach sewage system.

· European waste catalogue

08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS,VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS

08 01 00 wastes from MFSU and removal of paint and varnish

08 01 13 sludges from paint or varnish containing organic solvents or other dangerous substances(Contd. on page 4)

EU

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(Contd. of page 3)

DR

· Uncleaned packaging:· Recommendation: Disposal must be made according to official regulations.

14 Transport information

· Land transport ADR/RID (cross-border)

· ADR/RID class: 3 (F1) Flammable liquids.· Danger code (Kemler): 30· UN-Number: 1263· Packaging group: III· Hazard label 3 · Description of goods: 1263 FARBE, (nicht viskos)

· Maritime transport IMDG:

· IMDG Class: 3 · UN Number: 1263· Label 3 · Packaging group: III· EMS Number: F-E,S-E· Marine pollutant: No· Proper shipping name: PAINT

· Air transport ICAO-TI and IATA-DGR:

· ICAO/IATA Class: 3 · UN/ID Number: 1263· Label 3 · Packaging group: III· Proper shipping name: PAINT

* 15 Regulatory information

· Labelling according to EU guidelines:The product has been classified and marked in accordance with EU Directives / Ordinance on HazardousMaterials.

· Code letter and hazard designation of product:

Xi Irritant

· Risk phrases:10 Flammable.41 Risk of serious damage to eyes.52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.67 Vapours may cause drowsiness and dizziness.

· Safety phrases:2 Keep out of the reach of children.26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.29/56 Do not empty into drains, dispose of this material and its container at hazardous or special

waste collection point.39 Wear eye/face protection.46 If swallowed, seek medical advice immediately and show this container or label.


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(Contd. of page 4)

DR

· National regulations:

· Technical instructions (air):

Class Share in %

NK 88,4

· Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.

16 Other informationThis information is based on our present knowledge. However, this shall not constitute a guaranteefor any specific product features and shall not establish a legally valid contractual relationship.

· * Data compared to the previous version altered. EU

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DR


· Product details

· Trade name: MA 4511 schwarz / black




2 Composition/information on ingredients




64-17-5 ethanol F; R 11 50-100%

107-98-2 1-Methoxy-2-propanol R 10 10-25%

90506-69-7 Ethylhexyl phosphoric acid ester. C, Xn; R 22-34 2,5-10%

8005-02-5 C. I. Solvent Black 7 Xn; R 48/20/21/22 ≤ 2,5%495-54-5 C. I. Solvent Orange 3 Xn, Xi, N; R 22-38-68-50/53 ≤ 2,5%

· Additional information: For the wording of the listed risk phrases refer to section 16.



Xn HarmfulF Highly flammable

· Information concerning particular hazards for human and environment:The product has to be labelled due to the calculation procedure of the "General Classificationguideline for preparations of the EU" in the latest valid version.R 11 Highly flammable.R 68 Possible risk of irreversible effects.R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.· Classification system:

The classification is according to the latest editions of the EU-lists, and extended by company andliterature data.


· After inhalation: Supply fresh air; consult doctor in case of complaints.· After skin contact: Generally the product does not irritate the skin.· After eye contact: Rinse opened eye for several minutes under running water.· After swallowing: If symptoms persist consult doctor.






· Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.(Contd. on page 2)

EU

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Trade name: MA 4511 schwarz / black

(Contd. of page 1)

DR

· Measures for environmental protection:Prevent seepage into sewage system, workpits and cellars.Inform respective authorities in case of seepage into water course or sewage system.Do not allow to enter sewers/ surface or ground water.

· Measures for cleaning/collecting:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).Dispose contaminated material as waste according to item 13.Ensure adequate ventilation.Do not flush with water or aqueous cleansing agents

* 7 Handling and storage




· Storage:· Requirements to be met by storerooms and receptacles: Store in a cool location.· Information about storage in one common storage facility: Not required.· Further information about storage conditions:

Keep container tightly sealed.Store in cool, dry conditions in well sealed receptacles.

* 8 Exposure controls/personal protection


· Ingredients with limit values that require monitoring at the workplace:

107-98-2 1-Methoxy-2-propanol (10-25%)

IOELV Short-term value: 568 mg/m³, 150 ppmLong-term value: 375 mg/m³, 100 ppmSkin



Keep away from foodstuffs, beverages and feed.Wash hands before breaks and at the end of work.



Protective gloves




· Eye protection:


EU(Contd. on page 3)

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(Contd. of page 2)

DR

9 Physical and chemical properties










· Density: Not determined.


· pH-value at 20°C: 5,5








· Acute toxicity:· Primary irritant effect:· on the skin: No irritant effect.· on the eye: No irritating effect.· Sensitization: No sensitizing effects known.· Additional toxicological information:

The product shows the following dangers according to the calculation method of the General EUClassification Guidelines for Preparations as issued in the latest version:



Water hazard class 2 (German Regulation) (Self-assessment): hazardous for waterDo not allow product to reach ground water, water course or sewage system.Danger to drinking water if even small quantities leak into the ground.Harmful to aquatic organisms



Must not be disposed together with household garbage. Do not allow product to reach sewage system.

· European waste catalogue



08 01 13 sludges from paint or varnish containing organic solvents or other dangerous substances(Contd. on page 4)

EU

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(Contd. of page 3)

DR




· ADR/RID class: 3 (F1) Flammable liquids.· Danger code (Kemler): 33· UN-Number: 1263· Packaging group: II· Hazard label 3 · Description of goods: 1263 FARBE, (Dampfdruck bei 50°C höchstens 110 kPa)


· IMDG Class: 3 · UN Number: 1263· Label 3 · Packaging group: II· EMS Number: F-E,S-E· Marine pollutant: No· Proper shipping name: PAINT


· ICAO/IATA Class: 3 · UN/ID Number: 1263· Label 3 · Packaging group: II· Proper shipping name: PAINT




Xn HarmfulF Highly flammable

· Hazard-determining components of labelling:C. I. Solvent Orange 3

· Risk phrases:11 Highly flammable.68 Possible risk of irreversible effects.52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

· Safety phrases:9 Keep container in a well-ventilated place.16 Keep away from sources of ignition - No smoking.36/37 Wear suitable protective clothing and gloves.61 Avoid release to the environment. Refer to special instructions/safety data sheets.



Class Share in %

NK 67,2(Contd. on page 5)

EU

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(Contd. of page 4)

DR

· Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.



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Printing date 10.12.2008Revision: 10.12.2008

Safety Data Sheetaccording to 1907/2006/EC, Article 31

D R

* 1 Identification of the substance/preparation and of the company/undertaking

· Product details

· Trade name: MA 4520 rot / red· Application of the substance / the preparation Permanent Marker Ink


· Further information obtainable from:Technical Service, Dr. B. PolzinTel.: +49-621-5402322Mobile +49-1726204412E-Mail: [email protected]




Xn Harmful

· Information concerning particular hazards for human and environment:The product has to be labelled due to the calculation procedure of the "GeneralClassification guideline for preparations of the EU" in the latest valid version.Has a narcotizing effect.R 10 Flammable.R 38 Irritating to skin.R 41 Risk of serious damage to eyes.R 68 Possible risk of irreversible effects.R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the

aquatic environment.· Classification system:

The classification is according to the latest editions of the EU-lists, and extendedby company and literature data.


· Chemical characterizationMixture of the following substances, containing non-hazardous substances andcolouring agents.


· Dangerous components:CAS: 71-23-8EINECS: 200-746-9

propan-1-olXi, F; R 11-41-67

50-100%

CAS: 26694-69-9EINECS: 247-906-4

C. I. Basic Red 1Xn; R 22

2,5-10%


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Trade name: MA 4520 rot / red

(Contd. of page 1)

D R

n-AlkylbenzolsulfonsäureC, Xn; R 22-35

≤ 2,5%

CAS: 495-54-5EINECS: 207-803-7

C. I. Solvent Orange 3Xn, Xi, N; R 22-38-68-50/53

≤ 2,5%

· Additional information:For the wording of the listed risk phrases refer to section 16.


· After inhalation:In case of unconsciousness place patient stably in side position for transportation.

· After skin contact:Immediately wash with water and soap and rinse thoroughly.Immediately rinse with water.

· After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.

· After swallowing: If symptoms persist consult doctor.






· Person-related safety precautions:Wear protective equipment. Keep unprotected persons away.

· Measures for environmental protection:Do not allow product to reach sewage system or any water course.Inform respective authorities in case of seepage into water course or sewage system.Do not allow to enter sewers/ surface or ground water.

· Measures for cleaning/collecting:Absorb with liquid-binding material (sand, diatomite, acid binders, universalbinders, sawdust).Dispose contaminated material as waste according to item 13.Ensure adequate ventilation.Do not flush with water or aqueous cleansing agents





· Storage:· Requirements to be met by storerooms and receptacles: No special requirements.· Information about storage in one common storage facility: Not required.


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(Contd. of page 2)

D R

· Further information about storage conditions: Keep container tightly sealed.

* 8 Exposure controls/personal protection

· Additional information about design of technical facilities:No further data; see item 7.

· Ingredients with limit values that require monitoring at the workplace:The product does not contain any relevant quantities of materials with criticalvalues that have to be monitored at the workplace.



Keep away from foodstuffs, beverages and feed.Immediately remove all soiled and contaminated clothingWash hands before breaks and at the end of work.Avoid contact with the skin.Avoid contact with the eyes and skin.

· Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case ofintensive or longer exposure use self-contained respiratory protective device.


Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/the preparation.Due to missing tests no recommendation to the glove material can be given for theproduct/ the preparation/ the chemical mixture.Selection of the glove material on consideration of the penetration times, rates ofdiffusion and the degradation

· Material of glovesThe selection of the suitable gloves does not only depend on the material, but alsoon further marks of quality and varies from manufacturer to manufacturer. As theproduct is a preparation of several substances, the resistance of the glove materialcan not be calculated in advance and has therefore to be checked prior to theapplication.

· Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protectivegloves and has to be observed.

· Eye protection:




Form: FluidColour: According to product specification


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(Contd. of page 3)

D R

Odour: Characteristic

Important information on protection ofhealth and environment, and on safety. Not applicable

Not applicable





· Danger of explosion: Product is not explosive. However,formation of explosive air/vapour mixturesare possible.











11 Toxicological information

· Acute toxicity:· Primary irritant effect:· on the skin: Irritant to skin and mucous membranes.· on the eye: Strong irritant with the danger of severe eye injury.· Sensitization: No sensitizing effects known.· Additional toxicological information:

The product shows the following dangers according to the calculation method of theGeneral EU Classification Guidelines for Preparations as issued in the latestversion:Irritant


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(Contd. of page 4)

D R



Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous forwaterDo not allow undiluted product or large quantities of it to reach ground water, watercourse or sewage system.Harmful to aquatic organisms



Must not be disposed together with household garbage. Do not allow product to reachsewage system.

· European waste catalogue08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF

COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTSAND PRINTING INKS


08 01 13 sludges from paint or varnish containing organic solvents or otherdangerous substances


* 14 Transport information


· ADR/RID class: 3 (F1) Flammable liquids.· Danger code (Kemler): 30· UN-Number: 1263· Packaging group: III· Hazard label 3 · Description of goods: 1263 FARBE, (nicht viskos)· Limited quantities (LQ) LQ7


· IMDG Class: 3 · UN Number: 1263· Label 3 · Packaging group: III· EMS Number: F-E,S-E· Marine pollutant: No


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(Contd. of page 5)

D R

· Proper shipping name: PAINT




· Labelling according to EU guidelines:The product has been classified and marked in accordance with EU Directives /Ordinance on Hazardous Materials.


Xn Harmful

· Hazard-determining components of labelling:C. I. Solvent Orange 3

· Risk phrases:10 Flammable.38 Irritating to skin.41 Risk of serious damage to eyes.68 Possible risk of irreversible effects.52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the

aquatic environment.

· Safety phrases:2 Keep out of the reach of children.26 In case of contact with eyes, rinse immediately with plenty of water and

seek medical advice.29/56 Do not empty into drains, dispose of this material and its container at

hazardous or special waste collection point.36/37/39 Wear suitable protective clothing, gloves and eye/face protection.46 If swallowed, seek medical advice immediately and show this container or

label.


· Technical instructions (air):Class Share in %

NK 50-100

· Waterhazard class:Water hazard class 1 (Self-assessment): slightly hazardous for water.


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(Contd. of page 6)

D R

16 Other informationThis information is based on our present knowledge. However, this shall notconstitute a guarantee for any specific product features and shall not establish alegally valid contractual relationship.

· Relevant R-phrases11 Highly flammable.22 Harmful if swallowed.35 Causes severe burns.38 Irritating to skin.41 Risk of serious damage to eyes.50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the

aquatic environment.67 Vapours may cause drowsiness and dizziness.68 Possible risk of irreversible effects.


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Printing date 10/08/2007Reviewed on 10/08/2007

Material Safety Data Sheetacc. to ISO/DIS 11014

DR

1 Identification of substance

· Product details

· Trade name: MA 4531 yellow-green / gelb-grün

· Article number: 2001810

· Manufacturer/Supplier:DOKUMENTAL GmbH & Co KG SchreibfarbenWoellnerstraße 26D-67065 LudwigshafenPhone + 49 (0)621/5402321Fax + 49 (0)621/5402391www. dokumental.de

· Information department:Technical Service, Dr. B. PolzinTel.: +49-621-5402322Mobile +49-1726204412E-Mail: [email protected]

· Emergency information:EMERGENCY Tel. No. for US and Canada:+1 800 535 5053 (INFOTRAC)All other countries001-352-323-3500 (INFOTRAC)

2 Composition/Data on components


· Description: Mixture of the substances listed below with nonhazardous additions.


71-23-8 propan-1-ol 50-100%

107-98-2 1-Methoxy-2-propanol 25-50%

94279-65-9 C. I. Solvent Yellow 146 2.5-10%

1328-51-4 C. I. Solvent Blue 38 ≤ 2.5%· Additional information: For the wording of the listed risk phrases refer to section 16.

3 Hazards identification


Irritant

· Information pertaining to particular dangers for man and environment:The product has to be labelled due to the calculation procedure of the "General Classificationguideline for preparations of the EU" in the latest valid version.Has a narcotizing effect.Flammable.Risk of serious damage to eyes.May cause sensitization by skin contact.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environmentVapours may cause drowsiness and dizziness

· Classification system:The classification was made according to the latest editions of international substances lists, andexpanded upon from company and literature data.

· NFPA ratings (scale 0 - 4)

23

0Health = 2Fire = 3Reactivity = 0

· HMIS-ratings (scale 0 - 4)

HEALTH

FIRE

REACTIVITY

2

3

0

Health = 2Fire = 3Reactivity = 0

USA(Contd. on page 2)

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Trade name: MA 4531 yellow-green / gelb-grün

(Contd. of page 1)

DR

4 First aid measures

· After inhalation:Supply fresh air and to be sure call for a doctor.In case of unconsciousness place patient stably in side position for transportation.

· After skin contact: Immediately wash with water and soap and rinse thoroughly.· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.· After swallowing: If symptoms persist consult doctor.

5 Fire fighting measures




6 Accidental release measures

· Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.· Measures for environmental protection:

Inform respective authorities in case of seepage into water course or sewage system.Do not allow to enter sewers/ surface or ground water.




Ensure good ventilation/exhaustion at the workplace.Prevent formation of aerosols.Not applicable

· Information about protection against explosions and fires:Keep ignition sources away - Do not smoke.Protect against electrostatic charges.

· Storage:· Requirements to be met by storerooms and receptacles: No special requirements.· Information about storage in one common storage facility: Not required.· Further information about storage conditions: Keep receptacle tightly sealed.

8 Exposure controls and personal protection

· Additional information about design of technical systems: No further data; see item 7.

· Components with limit values that require monitoring at the workplace:

71-23-8 propan-1-ol (50-100%)

PELREL

TLV

500 mg/m³, 200 ppmShort-term value: 625 mg/m³, 250 ppmLong-term value: 500 mg/m³, 200 ppmSkinShort-term value: (984) mg/m³, (400) ppmLong-term value: (492) NIC-246 mg/m³, (200) NIC-100 ppmNIC-A4


REL

TLV

Short-term value: 540 mg/m³, 150 ppmLong-term value: 360 mg/m³, 100 ppmShort-term value: 553 mg/m³, 150 ppmLong-term value: 369 mg/m³, 100 ppm

· Additional information: The lists that were valid during the creation were used as basis.


Immediately remove all soiled and contaminated clothing.Wash hands before breaks and at the end of work.Avoid contact with the eyes.

· Breathing equipment:In case of brief exposure or low pollution use respiratory filter device. In case of intensive orlonger exposure use respiratory protective device that is independent of circulating air.

(Contd. on page 3) USA

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(Contd. of page 2)

DR


Protective gloves




· Eye protection:




Form: FluidColor: According to product specificationOdor: Characteristic

· Change in conditionMelting point/Melting range: Undetermined.Boiling point/Boiling range: 96°C (205°F)

· Flash point: 23°C (73°F)

· Ignition temperature: 287.0°C (549°F)

· Auto igniting: Product is not selfigniting.

· Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are possible.

· Explosion limits:Lower: 1.7 Vol %Upper: 13.5 Vol %

· Vapor pressure at 20°C (68°F): 19.0 hPa (14 mm Hg)


· Solubility in / Miscibility withWater: Not miscible or difficult to mix.

· Viscosity:Dynamic at 20°C (68°F): 3 mPas

· Solvent content:Organic solvents: 87.8 %

· Solids content: 9.4 %



· Dangerous reactions No dangerous reactions known.· Dangerous products of decomposition: No dangerous decomposition products known.


· Acute toxicity:· Primary irritant effect:· on the skin: No irritant effect.


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(Contd. of page 3)

DR

· on the eye: Strong irritant with the danger of severe eye injury.· Sensitization: Sensitization possible through skin contact.· Additional toxicological information:

The product shows the following dangers according to internally approved calculation methods forpreparations:Irritant

12 Ecological information


Water hazard class 1 (Self-assessment): slightly hazardous for waterDo not allow undiluted product or large quantities of it to reach ground water, water course orsewage system.Harmful to aquatic organisms


· Product:· Recommendation:

Must not be disposed of together with household garbage. Do not allow product to reach sewagesystem.

· Uncleaned packagings:· Recommendation: Disposal must be made according to official regulations.


· DOT regulations:

· Hazard class: 3 · Identification number: UN1263· Packing group: III· Proper shipping name (technical name): PAINT· Label 3

· Land transport ADR/RID (cross-border):

· ADR/RID class: 3 (F1) Flammable liquids· Danger code (Kemler): 30· UN-Number: 1263· Packaging group: III· Description of goods: 1263 FARBE, (nicht viskos)


· IMDG Class: 3 · UN Number: 1263· Label 3 · Packaging group: III· EMS Number: F-E,S-E· Marine pollutant: No· Propper shipping name: PAINT


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(Contd. of page 4)

DR


· ICAO/IATA Class: 3 · UN/ID Number: 1263· Label 3 · Packaging group: III· Propper shipping name: PAINT

15 Regulations

· Sara

· Section 355 (extremely hazardous substances):

None of the ingredient is listed.

· Section 313 (Specific toxic chemical listings):

None of the ingredients is listed.

· TSCA (Toxic Substances Control Act):

71-23-8 propan-1-ol

· Proposition 65

· Chemicals known to cause cancer:


· Chemicals known to cause reproductive toxicity for females:


· Chemicals known to cause reproductive toxicity for males:


· Chemicals known to cause developmental toxicity:


· Cancerogenity categories

· EPA (Environmental Protection Agency)


· IARC (International Agency for Research on Cancer)


· NTP (National Toxicology Program)


· TLV (Threshold Limit Value established by ACGIH)


· MAK (German Maximum Workplace Concentration)


· NIOSH-Ca (National Institute for Occupational Safety and Health)


· OSHA-Ca (Occupational Safety & Health Administration)


· Product related hazard informations:The product has been classified and marked in accordance with directives on hazardous materials.

· Hazard symbols:

Irritant

· Hazard-determining components of labelling:C. I. Solvent Yellow 146

· Risk phrases:Flammable.Risk of serious damage to eyes.May cause sensitization by skin contact.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environmentVapours may cause drowsiness and dizziness

· Safety phrases:Avoid contact with skin.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable gloves and eye/face protection.Avoid release to the environment. Refer to special instructions/Safety data sheets


/6




(Contd. of page 5)

DR



Class Share in %

NK 50-100

· Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.


· * Data compared to the previous version altered. USA

/5



DR

* 1 Identification of substance

· Product details

· Trade name: MA 4541 violet / violett


· Information department:Technical Service, Dr. B. PolzinTel.: +49-621-5402322Mobile +49-1726204412






64-17-5 ethanol 50-100%

107-98-2 1-Methoxy-2-propanol 2.5-10%

110-25-8 Oleoylsarcosinic acid ≤ 2.5%509-34-2 C. I. Solvent Red 49 ≤ 2.5%




Highly flammable

· Information pertaining to particular dangers for man and environment:The product has to be labelled due to the calculation procedure of the "General Classificationguideline for preparations of the EU" in the latest valid version.Highly flammable.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment



03



HEALTH

FIRE

REACTIVITY

0

3

0





/5



Trade name: MA 4541 violet / violett

(Contd. of page 1)

DR







Prevent seepage into sewage system, workpits and cellars.Inform respective authorities in case of seepage into water course or sewage system.Do not allow to enter sewers/ surface or ground water.



· Handling:· Information for safe handling: Not applicable· Information about protection against explosions and fires:

Keep ignition sources away - Do not smoke.Protect against electrostatic charges.


Keep receptacle tightly sealed.Store in cool, dry conditions in well sealed receptacles.

* 8 Exposure controls and personal protection



64-17-5 ethanol (50-100%)

PELRELTLV

1900 mg/m³, 1000 ppm1900 mg/m³, 1000 ppm1880 mg/m³, 1000 ppm

107-98-2 1-Methoxy-2-propanol (2.5-10%)

REL

TLV



· Personal protective equipment:· General protective and hygienic measures: Wash hands before breaks and at the end of work.· Breathing equipment: Not required.· Protection of hands:

Protective gloves





/5




(Contd. of page 2)

DR

· Eye protection:





Important information on protection of healthand environment, and on safety. Not applicable

Not applicable





· Danger of explosion: Product is not explosive. However, formation ofexplosive air/vapor mixtures are possible.





· pH-value at 20°C (68°F): 5.8








· Acute toxicity:

· LD/LC50 values that are relevant for classification:

110-25-8 Oleoylsarcosinic acid

Oral LD50 9200 mg/kg (Ratte)

· Primary irritant effect:· on the skin: No irritant effect.· on the eye: No irritating effect.· Sensitization: No sensitizing effects known.



Water hazard class 1 (Self-assessment): slightly hazardous for waterDo not allow undiluted product or large quantities of it to reach ground water, water course orsewage system.


/5




(Contd. of page 3)

DR

Harmful to aquatic organisms






· DOT regulations:

· Hazard class: 3 · Identification number: UN1263· Packing group: II· Proper shipping name (technical name): PAINT· Label 3


· ADR/RID class: 3 (F1) Flammable liquids· Danger code (Kemler): 33· UN-Number: 1263· Packaging group: II· Description of goods: 1263 FARBE, (Dampfdruck bei 50°C höchstens 110 kPa)


· IMDG Class: 3 · UN Number: 1263· Label 3 · Packaging group: II· EMS Number: F-E,S-E· Marine pollutant: No· Propper shipping name: PAINT


· ICAO/IATA Class: 3 · UN/ID Number: 1263· Label 3 · Packaging group: II· Propper shipping name: PAINT

* 15 Regulations

· Sara




None of the ingredients is listed.(Contd. on page 5)

USA

/5




(Contd. of page 4)

DR


64-17-5 ethanol

509-34-2 C. I. Solvent Red 49

112-92-5 octadecan-1-ol

· Proposition 65








64-17-5 ethanol









64-17-5 ethanol A4


64-17-5 ethanol 5






· Hazard symbols:

Highly flammable

· Risk phrases:Highly flammable.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment

· Safety phrases:Keep container in a well-ventilated place.Keep away from sources of ignition - No smoking.Avoid contact with skin.Avoid release to the environment. Refer to special instructions/Safety data sheets



Class Share in %

NK 50-100




/5



DR


· Product details

· Trade name: MA 4550 brown / braun








71-23-8 propan-1-ol 50-100%






Irritant




23



HEALTH

FIRE

REACTIVITY

2

3

0


* 4 First aid measures


· After skin contact: Immediately wash with water and soap and rinse thoroughly.· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.


/5



Trade name: MA 4550 brown / braun

(Contd. of page 1)

DR


















71-23-8 propan-1-ol (50-100%)

PELREL

TLV



REL

TLV







Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ thepreparation.


/5




(Contd. of page 2)

DR

Due to missing tests no recommendation to the glove material can be given for the product/ thepreparation/ the chemical mixture.Selection of the glove material on consideration of the penetration times, rates of diffusion andthe degradation



· Eye protection:












· Density at 20°C (68°F): 0.850 g/cm³









· Acute toxicity:· Primary irritant effect:· on the skin: No irritant effect.· on the eye: Strong irritant with the danger of severe eye injury.· Sensitization: Sensitization possible through skin contact.· Additional toxicological information:



/5




(Contd. of page 3)

DR



Water hazard class 1 (Self-assessment): slightly hazardous for waterDo not allow undiluted product or large quantities of it to reach ground water, water course orsewage system.Harmful to aquatic organisms






· DOT regulations:









/5




(Contd. of page 4)

DR

* 15 Regulations

· Sara






71-23-8 propan-1-ol

· Proposition 65

























· Hazard symbols:

Irritant



· Safety phrases:Avoid contact with skin.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable gloves and eye/face protection.Avoid release to the environment. Refer to special instructions/Safety data sheets



Class Share in %

NK 50-100




/5



DR


· Product details

· Trade name: MA 4560 yellow / gelb








71-23-8 propan-1-ol 50-100%






Irritant




23



HEALTH

FIRE

REACTIVITY

2

3

0


* 4 First aid measures


· After skin contact: Immediately wash with water and soap and rinse thoroughly.· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.


/5



Trade name: MA 4560 yellow / gelb

(Contd. of page 1)

DR


















71-23-8 propan-1-ol (50-100%)

PELREL

TLV



REL

TLV







Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ thepreparation.


/5




(Contd. of page 2)

DR

Due to missing tests no recommendation to the glove material can be given for the product/ thepreparation/ the chemical mixture.Selection of the glove material on consideration of the penetration times, rates of diffusion andthe degradation



· Eye protection:












· Density at 20°C (68°F): 0.830 g/cm³


· Viscosity:Kinematic at 20°C (68°F): 3 s (DIN 53211/4)







· Acute toxicity:· Primary irritant effect:· on the skin: No irritant effect.· on the eye: Strong irritant with the danger of severe eye injury.· Sensitization: Sensitization possible through skin contact.· Additional toxicological information:



/5




(Contd. of page 3)

DR



Water hazard class 2 (Self-assessment): hazardous for waterDo not allow product to reach ground water, water course or sewage system.Danger to drinking water if even small quantities leak into the ground.Harmful to aquatic organisms






· DOT regulations:









/5




(Contd. of page 4)

DR

* 15 Regulations

· Sara






71-23-8 propan-1-ol

· Proposition 65

























· Hazard symbols:

Irritant



· Safety phrases:Avoid contact with skin and eyes.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable gloves and eye/face protection.Avoid release to the environment. Refer to special instructions/Safety data sheets



Class Share in %

NK 50-100

· Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water.



/4Printing date 24.07.2006

Reviewed on 24.07.2006Material Safety Data SheetAccording to 91/155 EEC

DR


· Product details

· Trade name: MA 4561 orange

· Manufacturer/Supplier:DOKUMENTAL GmbH & Co KG SchreibfarbenWoellnerstraße 26D-67065 LudwigshafenPhone + 49 (0) 6 21 /54 02 - 227Fax + 49 (0) 6 21 /54 02 394www. dokumental.de





· Description: Mixture of substances listed below with nonhazardous additions.· Dangerous components:

71-23-8 propan-1-ol Xi, F; R 11-41-67 50-100%107-98-2 1-Methoxy-2-propanol R 10 10-25%

84961-40-0 C.I. Solvent Orange 99 Xn; R 22 ≤ 2,5%94279-65-9 C. I. Solvent Yellow 146 Xi, N; R 36-51/53 ≤ 2,5%




Xi Irritant

· Information concerning particular hazards for human and environment:The product has to be labelled due to the calculation procedure of the "General Classificationguideline for preparations of the EU" in the latest valid version.Has a narcotizing effect.R 10 Flammable.R 41 Risk of serious damage to eyes.R 67 Vapours may cause drowsiness and dizziness.

· Classification system:The classification is according to the latest editions of the EU-lists, and extended by company andliterature data.








· Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.· Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.




Trade name: MA 4561 orange

(Contd. of page 1)

DR






· Storage:· Requirements to be met by storerooms and receptacles: No special requirements.· Information about storage in one common storage facility: Not required.· Further information about storage conditions: Keep container tightly sealed.

8 Exposure controls/personal protection


· Ingredients with limit values that require monitoring at the workplace:The product does not contain any relevant quantities of materials with critical values that have tobe monitored at the workplace.



Immediately remove all soiled and contaminated clothingWash hands before breaks and at the end of work.Avoid contact with the eyes.



Protective gloves




· Eye protection:





· Change in conditionMelting point/Melting range: Undetermined.





(Contd. of page 2)

DR

Boiling point/Boiling range: 96°C









· Viscosity:Kinematic at 20°C: 3 s (DIN 53211/4)







· Acute toxicity:· Primary irritant effect:· on the skin: No irritant effect.· on the eye: Strong irritant with the danger of severe eye injury.· Sensitization: No sensitizing effects known.· Additional toxicological information:

The product shows the following dangers according to the calculation method of the General EUClassification Guidelines for Preparations as issued in the latest version:Irritant


· General notes:Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for waterDo not allow undiluted product or large quantities of it to reach ground water, water course orsewage system.



Must not be disposed together with household garbage. Do not allow product to reach sewage system.· European waste catalogue


08 01 00 wastes from MFSU and removal of paint and varnish08 01 13 sludges from paint or varnish containing organic solvents or other dangerous substances






(Contd. of page 3)

DR



· ADR/RID class: 3 (F1) Flammable liquids.· Danger code (Kemler): 30· UN-Number: 1263· Packaging group: III· Hazard label 3 · Description of goods: 1263 FARBE, (nicht viskos)


· IMDG Class: 3 · UN Number: 1263· Label 3 · Packaging group: III· EMS Number: F-E,S-E· Marine pollutant: No· Proper shipping name: PAINT



15 Regulatory information



Xi Irritant

· Risk phrases:10 Flammable.41 Risk of serious damage to eyes.67 Vapours may cause drowsiness and dizziness.

· Safety phrases:23 Do not breathe vapour.26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.39 Wear eye/face protection.60 This material and its container must be disposed of as hazardous waste.


· Technical instructions (air):Class Share in %

NK 77,7

· Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.



/5



DR


· Product details

· Trade name: MA 4562 red- orange / rot- orange









71-23-8 propan-1-ol 25-50%




Irritant

· Information pertaining to particular dangers for man and environment:The product has to be labelled due to the calculation procedure of the "General Classificationguideline for preparations of the EU" in the latest valid version.Has a narcotizing effect.Flammable.Risk of serious damage to eyes.Vapours may cause drowsiness and dizziness



23



HEALTH

FIRE

REACTIVITY

2

3

0





· Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.(Contd. on page 2)

USA

/5



Trade name: MA 4562 red- orange / rot- orange

(Contd. of page 1)

DR

· For safety reasons unsuitable extinguishing agents:WaterWater with full jet



· Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.· Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.· Measures for cleaning/collecting:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).Ensure adequate ventilation.Do not flush with water or aqueous cleansing agents










REL

TLV


71-23-8 propan-1-ol (25-50%)

PELREL

TLV







Protective gloves




/5




(Contd. of page 2)

DR


· Eye protection:












· Density at 20°C (68°F): 0.840 g/cm³












· General notes:Water hazard class 1 (Self-assessment): slightly hazardous for waterDo not allow undiluted product or large quantities of it to reach ground water, water course orsewage system.


/5




(Contd. of page 3)

DR






· DOT regulations:








* 15 Regulations

· Sara






71-23-8 propan-1-ol(Contd. on page 5)

USA

/5




(Contd. of page 4)

DR

· Proposition 65

























· Hazard symbols:

Irritant

· Risk phrases:Flammable.Risk of serious damage to eyes.Vapours may cause drowsiness and dizziness

· Safety phrases:Do not breathe vapour.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear eye/face protection.This material and its container must be disposed of as hazardous waste.



Class Share in %

NK 50-100




/5



DR


· Product details

· Trade name: MA 4571 pink









71-23-8 propan-1-ol 50-100%


26694-69-9 C. I. Basic Red 1 ≤ 2.5%· Additional information: For the wording of the listed risk phrases refer to section 16.



Irritant

· Information pertaining to particular dangers for man and environment:The product has to be labelled due to the calculation procedure of the "General Classificationguideline for preparations of the EU" in the latest valid version.Has a narcotizing effect.Flammable.Risk of serious damage to eyes.Vapours may cause drowsiness and dizziness



23



HEALTH

FIRE

REACTIVITY

2

3

0



· After inhalation: Supply fresh air; consult doctor in case of complaints.· After skin contact: Generally the product does not irritate the skin.· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.


/5



Trade name: MA 4571 pink

(Contd. of page 1)

DR







· Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.· Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.· Measures for cleaning/collecting:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).Ensure adequate ventilation.Do not flush with water or aqueous cleansing agents









71-23-8 propan-1-ol (50-100%)

PELREL

TLV



REL

TLV







Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ thepreparation.Due to missing tests no recommendation to the glove material can be given for the product/ thepreparation/ the chemical mixture.


/5




(Contd. of page 2)

DR

Selection of the glove material on consideration of the penetration times, rates of diffusion andthe degradation



· Eye protection:






Not applicable


















The product shows the following dangers according to internally approved calculation methods forpreparations:


/5




(Contd. of page 3)

DR

Irritant








· DOT regulations:









/5




(Contd. of page 4)

DR

15 Regulations

· Sara






71-23-8 propan-1-ol

· Proposition 65

























· Hazard symbols:

Irritant

· Risk phrases:Flammable.Risk of serious damage to eyes.Vapours may cause drowsiness and dizziness

· Safety phrases:Do not breathe vapour.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear eye/face protection.This material and its container must be disposed of as hazardous waste.



Class Share in %

NK 50-100



USA

/5



DR


· Product details

· Trade name: MA 4580 torquoise / türkis









64-17-5 ethanol 50-100%


90506-69-7 Ethylhexyl phosphoric acid ester. ≤ 2.5%· Additional information: For the wording of the listed risk phrases refer to section 16.



Highly flammable

· Information pertaining to particular dangers for man and environment:The product has to be labelled due to the calculation procedure of the "General Classificationguideline for preparations of the EU" in the latest valid version.Highly flammable.



03



HEALTH

FIRE

REACTIVITY

0

3

0





/5



Trade name: MA 4580 torquoise / türkis

(Contd. of page 1)

DR







Prevent seepage into sewage system, workpits and cellars.Do not allow to enter sewers/ surface or ground water.



· Handling:· Information for safe handling: Not applicable· Information about protection against explosions and fires:

Keep ignition sources away - Do not smoke.Protect against electrostatic charges.


Keep receptacle tightly sealed.Store in cool, dry conditions in well sealed receptacles.




64-17-5 ethanol (50-100%)

PELRELTLV

1900 mg/m³, 1000 ppm1900 mg/m³, 1000 ppm1880 mg/m³, 1000 ppm


REL

TLV



· Personal protective equipment:· General protective and hygienic measures: Wash hands before breaks and at the end of work.· Breathing equipment: Not required.· Protection of hands:

Protective gloves





/5




(Contd. of page 2)

DR

· Eye protection:






Not applicable










· pH-value at 20°C (68°F): 4.8








· Acute toxicity:· Primary irritant effect:· on the skin: No irritant effect.· on the eye: No irritating effect.· Sensitization: No sensitizing effects known.




/5




(Contd. of page 3)

DR






· DOT regulations:

· Hazard class: 3 · Identification number: UN1263· Packing group: II· Proper shipping name (technical name): PAINT· Label 3


· ADR/RID class: 3 (F1) Flammable liquids· Danger code (Kemler): 33· UN-Number: 1263· Packaging group: II· Description of goods: 1263 FARBE, (Dampfdruck bei 50°C höchstens 110 kPa)


· IMDG Class: 3 · UN Number: 1263· Label 3 · Packaging group: II· EMS Number: F-E,S-E· Marine pollutant: No· Propper shipping name: PAINT


· ICAO/IATA Class: 3 · UN/ID Number: 1263· Label 3 · Packaging group: II· Propper shipping name: PAINT

15 Regulations

· Sara






64-17-5 ethanol(Contd. on page 5)

USA

/5




(Contd. of page 4)

DR

· Proposition 65








64-17-5 ethanol









64-17-5 ethanol A4


64-17-5 ethanol 5






· Hazard symbols:

Highly flammable

· Risk phrases:Highly flammable.

· Safety phrases:Keep container in a well-ventilated place.Keep away from sources of ignition - No smoking.Avoid contact with skin.This material and its container must be disposed of as hazardous waste.



Class Share in %

NK 50-100



USA

HMIS CODES H 2 F 3 R 0 PPE BX

Multichem Limited Premium Permanent Ink (PP120,PP140)

All Colours

Safety Data Sheet (Prepared according to 91/155/EEC)

Emergency Telephone Number (24Hrs) +44 7887 612787

1.0 Identification of the Substance / Preparation and of the company / undertaking 1.1 Product Name Premium Permanent Ink PP120 and PP140

1.2 Intended use Marking ink for use in writing instruments

1.3 Supplier / Manufacturer Address

Multichem Limited Tyne Mills Industrial Estate Hexham Northumberland England

1.4 24Hr Emergency Tel: Daytime Tel:

+44 7887 612787 +44 1434 606 085

Fax Number +44 1434 601 804

2.0 Composition / Information On Ingredients Contains: EINECS CAS Conc’n % Symbols R-phrases Propan-1-ol

(n-Propanol) 200-746-9 71-23-8 20 to 30% F Xi R11 R41-

R67 1-Methoxypropan-2-ol

(1-Methoxy-2-Propanol) 203-539-1 107-98-2 30 to 60% R10

Solvent Dyes* <13% Xn R20 R21 R33

Basic Dyes* <7% Xn N R.20.21.22.R33 R51.53

Note: The complete text of risk –R- phrases can be found in Section 15 and 16 *The chemical nature of the dyes used has been included as detailed in Article 15 of Directive 1999/45/EC

3.0 Hazards Identification 3.1 Preparation

Classification This preparation is dangerous under 67/548/EEC and 1999/45/EC regulations as amended. This preparation requires a Safety Data Sheet in accordance with 91/155/EC as amended. Additional information relating to health and environmental hazards can be found in Sections 11 and 12 of this Safety Data Sheet.

3.2 Danger Symbols: F Xi 3.3 Phrases –R– R11 R41 R67 R33 R52.53 3.4 Danger Identification HIGHLY FLAMMABLE. RISK OF SERIOUS DAMAGE TO EYES.

VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS. HARMFUL IF SWALLOWED. DANGER OF CUMULATIVE EFFECTS. HARMFUL TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT.

Data Sheet No: DS 42 Rev No: 02

Issue Date: 24/9/04 Page 1 of 6



4.0 First Aid Measures Route Effect First Aid 4.1 Skin Contact Will degrease skin - can

cause irritation Remove any contaminated clothing. Wash with soap & flowing water for 15 minutes. If irritation continues consult a physician.

4.2 Eye Contact May cause damage Irrigate with a suitable eye solution or water for ten minutes - obtain medical attention.

4.3 Inhalation Narcotic avoid inhalation Remove from exposure - in severe cases obtain medical attention. 4.4 Ingestion Harmful Give plenty to drink if ingestion is suspected. DO NOT induce

vomiting and consult a physician. 5.0 Fire-Fighting Measures 5.1 Hazard Low Flash Point - 15°C (Closed Cup)

Explosive Limits : Lower Limit 1.9% to 13.5% Upper Limit. 5.1 Extinguishing Media Alcohol resistant foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or

earth may be used for small fires only. Water may not be effective initially.

5.2 Media to avoid 5.3 Hazardous

Combustion Products Carbon Monoxide (CO) can form with incomplete combustion. Some Oxides of Nitrogen (NOX) and Sulphur (SOX) could be formed. Complete combustion will yield primarily Carbon Dioxide (CO2) and Water.

5.4 Protective Equipment Fire fighters should wear proper protective equipment and self-contained breathing apparatus with full face-piece

5.5 Additional Information Vapours may flow along surfaces to distant ignition sources and flash back. Closed containers exposed to heat may explode. Move exposed containers from fire area if it can be done without risk. Use water to keep fire-exposed containers cool.

6.0 Accidental Release Measures 6.1 Personal Precautions Avoid contact with skin and eyes. Ventilate contaminated area thoroughly. Do not breathe

vapour. Extinguish naked flames. Remove ignition sources. No smoking. Avoid sparks. Evacuate the area of all non-essential personnel. Shut off leaks, if possible without personal risk.

6.2 Environmental Precautions

Prevent contamination of soil and water. Prevent from spreading or entering into drains, ditches or rivers by using sand, earth, or other appropriate barriers.

6.3 Method of Clean Up Absorb or contain liquid with sand, earth or spill control material. Collect avoiding possible spark ignition and place in a labelled, sealable container for subsequent safe disposal. Put leaking containers in a labelled drum. Solvent is miscible with water. Flush contaminated area with plenty of water. Retain washings as contaminated waste. Refer to Sections 8.0 and 13.0 for additional information on Exposure and Disposal.

7.0 Handling and Storage 7.1 Handling Product is not intended nor should be allowed to maintain prolonged skin contact. Ensure

good ventilation or the provision of local exhaust ventilation where possible. Avoid contact with eyes, skin and clothing, avoid ingestion and inhalation. Avoid sources of Ignition.

7.2 Storage Keep away from direct sunlight and other sources of heat or ignition. Do not smoke in storage areas. Keep container tightly closed and in a well-ventilated place.

7.3 Product Transfer Low flash point, requires attention to equipment used in transport and use so as to avoid sparks and other sources of ignition. Take precautionary measures against static discharges. Earth all equipment. Avoid splash filling. Do not empty into drains. Multichem advise that their Cap-Off range of inks be stored for at least 24 hours at around 25°C and then agitated prior to assembly into markers or pen products.



8.0 Exposure Controls / Personal Protection 8.1 Exposure Limit Values Propan-1-ol

8hour TWA 200ppm (492mg/m3) (skin) STEL (15 mins) 250ppm (615mg/m3) (skin) (ACGIH 1999)

1-Methoxypropan-2-ol 8hour TWA 100ppm (369mg/m3) STEL (15 mins) 150ppm (553mg/m3) (ACGIH 1997). MAK 100ppm (375mg/m3)(1996)

8.2 Personal Protection Respiratory Protection Avoid inhalation of the vapours when the product in being used.

Local exhaust ventilation (LEV) should be used in conjunction with other control measures as a means of removing material incidentally released. Type approved RPE for organic vapours if required.

Hand Protection Protective Butyl gloves Eye Protection Safety goggles or face shield Skin Protection Overalls and anti static safety shoes Additional Do not permit smoking whilst product is used.

Keep away from children. 8.3 Environmental

Exposure See Section 12 for detailed information

9.0 Physical and Chemical Properties Odour Characteristic Odour of Propan-1-ol and 1-Methoxypropan-2-ol Appearance Coloured Liquid Volatility Approx 80% Volatile Solvents pH 4.0 to 9.0 Boiling Point / Range 96 to 122°C Flash Point 15°C Auto-ignition 270°C Explosive Properties This preparation is not considered explosive.

It will form explosive Vapour / Air Mixtures. Explosive Limits :

Lower Limit 1.9% to 13.5% Upper Limit. (Volume % in Air)

Oxidising Properties N/A Vapour Pressure 13.3mbar at 20°C Relative Density 0.92 (water = 1.0) Solubility Water Solubility – Solvents Miscible with Water

Fat Solubility - Partition Coefficient n-Octanol / Water – N/A Viscosity 5 – 9 cP Vapour Density Relative density of the vapour / air mixture at 20°C = 1.02

(Air = 1.0) Evaporation Rate N/A

10.0 Stability and Reactivity 10.1 Conditions to Avoid Considered a Stable Product. 10.2 Materials to Avoid Reacts with strong oxidants causing fire and explosion hazards.

Can also react with acid chlorides, acid anhydrides, aluminium and copper. It may attack some forms of plastic and rubber.

10.3 Hazardous May give of irritant / toxic fumes if involved in a fire. Primarily forms oxides of carbon during



Decomposition combustion.

11.0 Toxicological Information 11.1 Acute Effects Vapour inhalation Ataxia, Confusion, Dizziness, Drowsiness, Headache, Nausea, Weakness Skin De-fatting of Skin. Dry Skin

Note that dermal absorption of solvents could also contribute substantially to the total body burden.

Eyes Lacrimation, Redness, Pain, Blurred Vision Ingestion Abdominal Pain, Sore Throat, Drowsiness, Headache, Nausea 11.2 Target Organ Effects The preparation may cause Liver & Kidney damage if abused. 11.3 Sensitisation Allergic skin reaction / dermatitis could occur with misuse of this preparation. 12.0 Ecological Information 12.1 Ecotoxicity Propan-1-ol exhibits low acute toxicity to aquatic species.

The 96-hour LC50 value for the fathead minnow ranges from 4100-5000 ppm. The toxicity threshold values for bacteria (Pseudomonas putida), euglenoid (Entosiphon sulcatum) and green algae (Scenedesmus quadricauda) in cell multiplication inhibition tests were 2700, 38 and 3100 ppm, respectively.

1-Methoxypropan-2-ol Acute toxicity testing in fish, invertebrates, and algae indicate a very low order of toxicity with effect concentration exceeding 1,000 mg/L. Using an assessment factor of 100 for the fish 96 hour LC 50 of 20,800 mg/L, a PNEC of 208 mg/L was derived. Solvent Dyes and Basic Dyes Toxicity to Fish EC/LC50: 1-16mg/l Leuciscus idus Toxicity to Bacteria EC/LC50: 1 – 10 mg/l Modified Waste Test

12.2 Mobility Mobile liquid. Contains approx 80% volatile components. Solvents readily absorbed into soil. Non volatile content only slightly soluble in water. Dyes vary in solubility and some leaching into soil may occur from the non volatile fraction.

12.3 Persistance and Degradability

Solvents are readily biodegradable.

1-Methoxypropan-2-ol The half-life in air is estimated to be 3.1 hours due to direct reactions with photochemically generated hydroxyl radicals. It is readily biodegraded under aerobic conditions.

12.4 Bioaccumulative Potential

Propan-1-ol The log octanol/water partition coefficient for propanol is 0.25- 0.34. The calculated bio-concentration factor is 0.7. This indicates that it has low potential to bio-concentrate in aquatic organisms. 1-Methoxypropan-2-ol It is likely to partition to water compartments in the environment (surface water, groundwater) with small to negligible amounts remaining in other environmental compartments (air, soil, sediment, and fish). Solvent Dyes and Basic Dyes Some of the solvent dyes can contain copper or chromium (111) which can accumulate after breakdown of the dye complex.

12.5 Other Adverse Effects

13.0 Disposal Considerations Dispose of spilled material and containers in accordance with State and Local regulations for

hazardous or ‘Special’ waste. Consider recycling or incineration. State or Local regulations are complex and subject to change so should be consulted by the owner of the waste prior to disposal.

14.0 Transport Information UN No: 1993 Proper Shipping Name: Flammable Liquid n.o.s (Contains Propanol) ADR, IATA, IMDG

Hazard Class 3

Packing Group 2

15 Regulatory Information 15.1 Hazard Symbols F Xi

HIGHLY FLAMMABLE IRRITANT 15.2 -R-phrases R11 HIGHLY FLAMMABLE R22 HARMFUL IF SWALLOWED R41 RISK OF SERIOUS DAMAGE TO EYES R67 VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS R33 DANGER OF CUMULATIVE EFFECTS R52.53 HARMFUL TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN

THE AQUATIC ENVIRONMENT

15.3 -S-Phrases S(2) KEEP OUT OF THE REACH OF CHILDREN S7 KEEP CONTAINER TIGHTLY CLOSED S16 KEEP AWAY FROM SOURCES OF IGNITION – NO SMOKING S24/25 AVOID CONTACT WITH SKIN AND EYES S26 IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER

AND SEEK MEDICAL ADVICE S36/37/39 WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE / FACE PROTECTION S43 IN CASE OF FIRE USE FOAM, CO2, DRY CHEMICAL S60 THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF AS HAZARDOUS

MATERIAL





15.4 Contains Propan-1-ol

16 Other information 16.1 -R-Phrases R10 FLAMMABLE R20/21 HARMFUL BY INHALATION AND IN CONTACT WITH SKIN R20/21/22 HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED 16.2 Select Bibliography Regulation 67/548/EEC

Regulation 91/155/CE Regulation 1999/45/CE Regulation 2001/58/CE Regulation 2001/59/CE Regulation 2001/60/CE

16.3 The product conforms to the requirements of the Pencils & Graphics (Safety) Regulations in respect of toxic heavy

metals. 16.4 The product conforms to the requirements of the EN71 Part 3 Standard in respect of migration of certain elements. 16.5 The product conforms to the requirements of ASTM D-4236 in respect of toxicity. 16.6 HS Tariff No: 321590 10

16.7 The information contained herein does not constitute the user’s own assessment of workplace risk as required by other

health and safety legislation. The above information is provided in good faith and is based on our present knowledge. It shall not constitute a guarantee for any specific product feature and shall not establish a legally valid contractual arrangement.

material safety data sheet page 1/5 according to 91/155 eec · reviewed on 15.12.2006 material...

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