material safety data sheet - amazon s3 harmful: danger of serious damage to health by prolonged...

FixtechPtyLtd–POBox568,Southport,QLD

PH:+61(0)755301099,Fax:+61(0)755301322Email:[email protected]:www.fixtech.com.au

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MSDS: FixIt Grip MSDS Established: March 2012 MSDS Revised: an.01/06/2016

MATERIALSAFETYDATASHEET

FixItGrip–FMP100

1.1 Identificationofthesubstanceorpreparation: ProductName:FixItGrip–FMP1001.2 Useofsubstanceorpreparation: TimberAdhesive1.3 Companyundertakingidentification:

FixtechPtyLtd–FixtechMarineSolutionsUnit1/20Molendinar,Queensland4214Tel:+61755301099Fax:+61755301322Email:[email protected]

1.4 Emergencytelephone: +61755301099

HazardousIngredients CASNo.

Conc.In% Classification

DSD/DPDClassification

CLPNote

4,4’methylenediphenyldiisocyanate

101-68-8202-966-0

10%<C<25% Carc.Cat.3;R40Xn;R20-48/20Xi;R36/37/38

R42/43

Carc.2;H351AcuteTox.3;H331STOTSE2;H371EyeIrrit.2;H319STOTSE3;H335SkinIrrit.2;H315Resp.Sens.1;H334SkinSens.1;H317

(1)(2)

(1)ForR-phrasesandH-statementsinfull:seeheading16(2)SubstancewithaCommunityworkplaceexposurelimit

2.Composition/informationoningredients

1.Identification



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FixItGrip–FMP100

- ClassifieddangerousinaccordancewithDirectives67/548/EECand1999/45/EC- Irritatingtoeyes,respiratorysystemandskin- Limitedevidenceofacarcinogeniceffect- Maycausesensitisationbyinhalationandskincontact- Harmful:dangerofseriousdamagetohealthbyprolongedexposurethroughinhalation

4.1 General: -Incaseofdoubtorwithpersistingsymptoms,obtainmedicalattention

-Neverpassanythingthroughthemouthofanunconsciousperson4.2 Skincontact: -Donotapply(chemical)neutralizingagents -Washskinwithsoapandwater

-Donotusesolventsorthinners4.3 Eyecontact: -Irrigatewitheyewashsolutionorcleanwater,holdingtheeyelidsapart,foratleast10minutes -Donotapply(chemical)neutralizingagents -Seekmedicaladviceifirritationpersists4.4 Afteringestion: -Donotinducevomiting -Immediatelyafteringestion:givelotsofwatertodrink -Washmouthoutwithwaterandseekmedicalattention4.5 Inhalation -Removepatientfromexposure,keepwarmandatrest -Respiratoryproblems:consultadoctor/medicalservice

4.Firstaidmeasures

3.Hazardousidentification



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FixItGrip–FMP100

5.1 Instructions: Dilutetoxicgaseswithwaterspray5.2 Extinguishingmedia: Onlargefiresusedrychemical,carbondioxide,foamor waterspray.Onsmallfiresusecarbondioxide(CO2),dry chemicalorwaterspray.Watercanbeusedtocoolfire- exposedcontainers.5.3 Specialexposurehazards: Onburning:releaseoftoxicandcorrosivegases/vapours (nitrousvapours,carbonmonoxide-carbondioxide)Reacts slowlywithwater(moisture):releaseof(carbondioxide)5.4 ProtectiveEquipmentforFire-Fighters: -Gloves -Face-shield -Protectiveclothing -Heat/fireexposure:compressedair/oxygenapparatus

6.1 EnvironmentalPrecautions: -Donotallowtoenterdrains,sewers,orwatercourses -Damupthesolidspill -Absorbspillagesontosand,earthoranysuitableabsorbentmaterial6.2 Methodsforcleanup: -Scoopsolidspillintoclosingcontainers -Containersmustnotbesealedhermetically -Carefullycollectthespill/leftovers -Clean(treat)contaminatedsurfaceswithacetone -Washclothingandequipmentafterhandling Local,StateandFederallawsandregulationsmayapplytoreleasesanddisposalofwastematerial,aswellasthematerialusedinthecleanupofreleases.Youwillneedtodeterminetheapplicableregulations.

5.Firefightingmeasures

6.Accidentalreleasemeasures



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FixItGrip–FMP100

Note:Seesection8forPersonalProtectiveEquipment.7.1 Handling: -Keepawayfromnakedflames/heat -Observeverystricthygiene-avoidcontact -Keepcontainertightlyclosed -Donotdischargethewasteintothedrain7.2 Storage: -Storeinacool,dryplacewellventilatedplaceinoriginalcontainers -Storagetemperature+5°C-25°C. -Max.storagetime1year(s)7.3Specificuse(s): Seeinformationsuppliedbythemanufacturerfortheidentifieduse(s)

8.1 PersonalProtectiveEquipment: -Eyes: Useproperprotection–safetyglasses -Skin: Gloves,Polyethylene -Respiratory: Insufficientventilation:wearrespiratoryprotection -Skin: Protectiveclothing MeasuretheconcentrationintheairregularlyCarryoperationsintheopen/underlocal exhaust/ventilationorwithrespiratoryprotection8.2 Exposurelimitvalues: Occupationalexposure: IflimitvaluesareapplicableandavailablethesewillbelistedbelowIndicativeexposurelimit(TheNetherlands)Difenylmethaaan-4,4’-diisocyanaat Shorttimevalue 0.02ppm

0.21mg/m3

Timeweightedaverageexposurelimit 0.005ppm0.05mg/m3

7.Handlingandstorage

8.Exposurecontrols/personalprotection



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FixItGrip–FMP100Limitvalue(Belgium)

Difenylmethaan-4,4'-di-isocyanaat(MDI)

Shorttimevalue -ppm-mg/m3


TLV(USA)Methylenebisphenylisocyanate(MDI)

Shorttimevalue -ppmTimeweightedaverageexposurelimit 0.005mg/m3

TRGS900(Germany)4,4'-Methylen-diphenyldiisocyanat

Timeweightedaverageexposurelimit 0.05mg/m3

LimitValue(France)4,4'-Diisocyanatedediphénylméthane

Shorttimevalue 0.02(5min)ppm0.2(5min)mg/m3


LimitValue(UK)Isocyanates,all(as-NCO)

Shorttimevalue -(-NCO)ppmTimeweightedaverageexposurelimit -(-NCO)ppm

0.02(-NCO)mg/m3

8.2.1Samplingmethods:Productname Test Number Samplingmethod Remarks4,4-MethyleneBisphenyllsocyanate(MDI)(Isocyanates)

NIOSH 5521 Wetchemical

Isocyanates NIOSH 5521 WetChemical Isocyanates NIOSH 5522 WetChemical MethyleneBisphenylIsocyanate OSHA 47 Papi OSHA CSI



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FixItGrip–FMP100

9.1 Generalinformation: -PhysicalForm: Paste -Colour: Seeproductinformation -Odour: Characteristic -Density: Ca.1.1g/cm3 -Viscosity: 25s -Flashpoint: >165°C -Vapourdensity: >2Note:theaboveinformationisnotintendedforuseinpreparingproductspecifications

10.1 Conditionstoavoid: Possiblefirehazard: Heatsources10.2 Materialstoavoid: -(Strong)acids -(Strong)bases -Alcohols -Amines -Water/moisture10.3 Hazardousdecompositionproducts: Onburning:releaseoftoxicandcorrosive gases/vapours(nitrousvapours,carbonmonoxide- carbondioxide)Reactsslowlywithwater(moisture): releaseof(carbondioxide)

Conditionstoavoid: None11.1 Acutetoxicity:4,4’-methylenediphenyldiisocyanate LD50oral(rat) 9200mg/kgLD50dermal(rabbit) >10000mg/kg

9.PhysicalandChemicalProperties

10.Stabilityandreactivity

11.Toxilogicalinformation



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FixItGrip–FMP10011.2Chronictoxicity:

-Nocertaintyabouthumancarcinogenicproperties -Notlistedinmutagenicityclass(EC,MAK) -ContainsasubstanceofgroupC(MAK-PregnancyGroup)4,4’-methyldiphenyldiisocayanteECcarc.cat 3IARC-classification 3MAK–carcinogeniccategory 4MAK–pregnancygroup CCLPCarc.cat Category2FixItGrip–FMP100ECcarc.cat 311.3Acuteeffects/symptoms:Inhalation: -Dry/sorethroat -Coughing -Runnynose -Irritationoftherespiratorytract -IrritationofthenasalmucousmembranesSkincontact: -Tingling/irritationoftheskinEyecontact: -IrritationoftheeyetissueIngestion: -Irritationofthegastric/intestinalmucosa11.4Chroniceffects: -Prolongedexposure:dangerofdamagetohealththroughinhalation -NocumulativeeffectONCONTINUOUS/REPEATEDEXPOSURE/CONTACT: -Itching -Skinrash/inflammationFeelingofweakness -CoughingPossibleinflammationoftherespiratorytract -Respiratorydifficulties



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FixItGrip–FMP100

12.1 Ecotoxicity: 4,4’-methylenediphenyldiisocyanateLC50FishesSpecies Value Duration(h) RemarksBrachydanioRerio >=500mg/l 24hr EC50DaphniaSpecies Value Duration(h) RemarksDaphniaMagna >100mg/l 12.2 Mobility: -Volatileorganiccompounds(VOC) 0% -Solubilityin/reactionwithwater Literaturereports:insolubleinwater12.3 Persistenceanddegradability: -Biodegradabilityinwater:nodataavailable12.4 Bioaccumulativepotential: -Nobioaccumulationdataavailable12.5 ResultsofPBTassessment: -Notapplicable,basedonavailabledata

12.6 Otheradverseeffects: -Notdangerousfortheozonelayer(1999/45/EC)

13.1 Disposalmethods: -Removetoanauthorizedincineratorequippedwithanafterburnerandafluegasscrubber withenergyrecovery -Removewasteinaccordancewithlocaland/ornationalregulations -Donotdischargeintodrainsortheenvironment,disposetoanauthorisedcollectionpoint Stateorlocallawsmayimposeadditionalregulatoryrequirementsregardingdisposal

12.Effectsontheenvironment

13.Disposalconsiderations



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FixItGrip–FMP100

14.1 ClassificationofthesubstanceinaccordancewithUNrecommendations UNNumber : NotApplicable CLASS : -

PACKAGINGGROUP : -

14.2 ADR(transportbyroad) CLASS : Notsubject PACKAGINGGROUP : - CLASSIFICATIONCODE : -

DANGERLABELTANKS : -DANGERLABELPACKAGES : -PROPERSHIPPINGNAME : -

14.3 RID(transportbyrail) CLASS : Notsubject PACKAGINGGROUP : - CLASSIFICATIONCODE : -

DANGERLABELTANKS : -DANGERLABELPACKAGES : -PROPERSHIPPINGNAME : -

14.4 ADNR(transportbyinlandwaterways) CLASS : Notsubject PACKAGINGGROUP : - CLASSIFICATIONCODE : -

DANGERLABELTANKS : -DANGERLABELPACKAGES : -

14.5 IMDG(maritimetransport) CLASS : Notsubject SUBRISKS : - PACKAGINGGROUP : - MFAG : -

EMS : -MARINEPOLLUTANT : -

14.6 ICAO(airfreight) CLASS : NotSubject SUBRISKS : - PACKAGINGGROUP : -

14.Transportinformation



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FixItGrip–FMP100 PACKAGINGINSTRUCTIONSPASSENGERAIRCRAFT : -

PACKAGINGINSTRUCTIONSCARGOAIRCRAFT : - PROPERSHIPPINGNAME : -

HarmfulContains:4,4'-methylenediphenyldiisocyanateR-phrases36/37/38 Irritatingtoeyes,respiratorysystemandskin40 Limitedevidenceofcarcinogeniceffect42/43 Maycausesensitisationbyinhalationandskincontact48/20 Harmful:dangerofseriousdamagetohealthbyprolongedexposurethroughinhalationS-phrases(02) (Keepoutofreachofchildren)23 Donotbreathevapour36/37 Wearsuitableprotectiveclothingandgloves45 Incaseofaccidentorifyoufeelunwell,seekmedicaladviceimmediately(shoelabelwherepossible(63) (Incaseofaccidentbyinhalation:removecasualtytofreshairandkeepatrest)AdditionalrecommendationsContainsIsocyanates.Seeinformationsuppliedbythemanufacturer.-Personsalreadysensitivetodiisocyanatesmaydevelopallergicreactionswhenusingthisproduct-PersonssufferingfromAsthma,Eczemaorskinproblemsshouldavoidcontact,includingdermalcontactwiththisproduct-Thisproductshouldnotbeusedunderconditionsofpoorventilationunlessaprotectivemaskwithanappropriategasfilter,suitableforuseagainstorganicgasesandvapourswithaboilingpointhigherthan65°C

16.Regulatoryinformation



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FixItGrip–FMP100Thisdatacompletesthetechnicaldatasheetforuse,butdoesnotreplaceit.Thedatagivenhereisbasedon

currentknowledgeandexperience.Thepurposeofthissafetydatasheetistodescribetheproductsintermsoftheirsafetyrequirements.Thedatadoesnotsignifyanywarrantywithregardstotheproductsproperties.Compliancewiththeinstructionsinthissafetydatasheetdoesnotreleasetheuserfromtheobligationtotakeallmeasuresdictatedbycommonsense,regulationsandrecommendationsorwhicharenecessaryand/orusefulbasedontherealapplicablecircumstances.Fixtechdoesnotguaranteetheaccuracyorexhaustivenessoftheinformationprovided..AllintellectualpropertyrightstothissheetarethepropertyofFixtechanditsdistributionandreproductionarelimited.Waterhazardclass:Waterhazardclass1(Self-assessment):slightlyhazardousfordrinkingwater.



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FixItGrip–FMP100TheinformationprovidedonthisMSDSiscorrecttothebestofourknowledge,informationandbeliefatthedateofitspublication.Theinformationgiven

isdesignedonlyasaguideforsafehandling,use,processing,storage,transportation,disposalandreleaseandisnottobeconsideredasawarrantyorqualityspecification.Theinformationrelatesontothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedincombinationwithothermaterialorinanyprocess,unlessspecifiedinthetext.

material safety data sheet - amazon s3 harmful: danger of serious damage to health by prolonged...

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