manikannan raaiyan, m. sc., m. phil., ph. d. (org. chem...

Application for Assistant/Associate Professor in Chemistry (Organic Chemistry)

Dear Sir/MadamGreetings from Dr Manikannan Ramaiyan

I now looking Assistant/Associate Professor in Chemistry (Organic Chemistry), I did Ph. D in Organic chemistry from Madurai Kamaraj University, Madurai, India, under the guidance of Prof. Dr. Shanmugam Muthusubramanian, after completed my Ph. D, joined as a Research Associate in the same lab (2009-2010). From February 2010 to August 2011, worked as a Postdoctoral Research Associate with Prof. Dr. Yuhlong Oliver Su, National Chi Nan University, Taiwan, then Joined as a Senior Postdoctoral Research Associate with Prof. Dr. Jiri Kulhanek & Dr. Filip Bureš, University of Pardubice, Pardubice, Czech Republic from Aug 2012 to Mar 2015. I taught to under graduate, masters and master of philosophy students about Organic Chemistry, heterocyclic chemistry, NMR, Uv-Visible, FT-IR spectroscopy etc. Experience in conducting under-graduate and graduate level laboratory work in synthetic organic chemistry and Organometallic Chemistry. Experience in guiding junior researchers, Ph. D. students, and project assistants.

I have excellent experience in synthesized a library of pharmaceuticals industrial important heterocycles compounds like Benzoxazine, Pyrazole, poly substituted Pyridine, selenadiazoles, and thiadiazoles and screened their biological activities like antimicrobial, antifungal and anti-tubercular (TB) activity also have a research experience in Organic Synthesis, purifications, Spectroscopic techniques and Organic materials Characterisations and Synthesis of Derived Porphyrin and Porphyrin Dendrimers Macrocycle Molucules. Strengthening of Research and Development of this research group, Tutor for Undergraduate, postgraduate and Ph. D study programmes. I deal with techniques like NMR (Bruker 300 MHz), GC-Mass, FT-Infrared UV-Vis (Microwave Synthesizer (Biotage/CEM), and CHNS elemental analyser. Synthesis of heterocyclic based Organic (materials, push-pull chromophores for nonlinear optics (NLO) properties, organic light-emitting devices (OLEDs), OTFTs, organic field-effect transistor (OFET), photodynamic therapy (PDT) Dye-sensitised solar cells (DSSCs) and photovoltaic device (PV).

My Research focus with Synthetic Organic, Medicinal & Material Chemistry:My research interests include the development of new synthetic methodology, heterocyclic chemistry, bioorganic and medicinal chemistry.

Kindly find my CV enclosed, for your ready reference. I am available to take interview whenever needed for you to find my abilities, interests and disabilities. Please do let me know once you received my mail, your thoughts and inputs. Looking forward to hear from you.

Yours sincerely,

Manikannan Ramaiyan

1/14 Manikannan Ramaiyan

MANIKANNAN RAMAIYAN, M. Sc., M. Phil., Ph. D.

167, Middle Street, Periyanarkunam, Chidamabram TK, Cuddalore Dist. Tamilnadu, Pin-608704, India.

[email protected] : [email protected]

+917598405589: +919790219917https://www.linkedin.com/profile/view?id=53571611&trk=nav_responsive_tab_profile

CAREER SUMMARY

Synthetic organic and Organic material chemist experience in the academic research

Laboratory. Evaluated and developed new synthetic methodology. Synthesized a library of

pharmaceuticals industrial important heterocycles compounds and screened their biological

activities like antimicrobial, antifungal and anti-tubercular (TB) activity. Synthesis of

Organic Material (dyes) based with heterocyclic and aryl push-pull chromophores and studies

of the OLEDs, OTFTs, OFET, DSSCs, photovoltaic device PV and DFT calculation.

Strengthening of research and development of the research group, Tutor for undergraduate,

postgraduate and Ph. D. study programmes. Have a broad knowledge of state-of-the-art

technology and technique, analytical equipment and systems

SCIENTIFIC CONTRIBUTIONArticles 26 (First Author 9); Lectures delivered 3; Oral Presentation 1; Posters 13; Conferences and Workshops participated 11. Co-Guide for Masters and Master of Philosophy Students-7.

EDUCATION

Feb-2005-Sep. 2008 Ph.D. (Doctor of Philosophy) in Organic Chemistry (Awarded on 7th Aug-2009) Madurai Kamaraj University, Madurai-21, India, Synthesis of derived heterocyclic systems Mentor; Prof. Dr. Shanmugam Muthusubramanian, 2003-2005 M. Phil. (Master of Philosophy in Chemistry): First Class (63%) Madurai Kamaraj University, Tamilnadu, India, Synthesis, characterization and biological activity of metal

complexes having (2-{[2-(2-benzoyl-4- chloroanilino)2-hydrox-yethenyl]amino}-5-chlorophenyl)(phenyl)methanone ligand.

Mentor: Dr. D. Chellappa 1999-2002 M. Sc. (Master of Science in Chemistry): First Class (63%) Govt. Arts College, Bharathiar University, Ooty.


mailto:[email protected]

Thesis title: Studies on the physico-chemical characters of Reservoirs in Nilgiris, Tamilnadu. Mentor: Prof. P. Elangkumaran

1996-1999 B. Sc. (Bachelor of Science in Chemistry); First Class (71.39%) Govt. Arts College, Bharathiar University, Coimbatore.

WORK EXPERIENCES

01/08/2012 to 31/03/2015 Postdoctoral Research Associate, ESF Project, University of Pardubice, Pardubice, Czech Republic, Europe.Synthesis and study of D-p-A chromophores, NLO Materials , push-pull type organic chromophores, : Strengthening of Research and Development , Tutorial in Undergraduate, postgraduate and Ph. D study programmes.

Mentors: Prof. Jiri Kulhanek & Dr. Filip Bureš

06/05/2013 to 20/06/2013: Visiting Scientist, Physics and Materials Science, Electrical Engineering Department , Institute of electronics, Technical University of Czestochowa, Częstochowa, PL-42201, Poland, from Characterization of NLO materials and DFT calculation.

Mentor; Prof. Dr. Iwan Kityk

18/02/2010 to 31/07/2011: Postdoctoral Research Associate, National Chi Nan University, Taiwan, 54561, Synthesis of Derived Porphyrin and porphyrin Dendrimers Macrocycle Molucules and their Electrochemical Characteriza-tion. Guidance for researchers and master students.

Mentor; Prof. Dr. Yuhlong Oliver Su , President,

08/08/2009 to 15/02/2010. Research Associate, Department of Organic Chemistry, School of Chemistry, Madurai Kamaraj University, India,. Synthesis of heterocyclic compounds and their biological studies. Co-guidance for master students and research scholars. NMR, GC-MS, UV-Vis, IR spectroscopy, microwave reactor running and maintenance,. Liquid nitrogen filling and NMR spectra taken for outside sample.

Mentor; Prof. Dr. Shanmugam Muthusubramanian,

01/08/2008 to 31/08/2009: Tutorial Assistant at School of Chemistry, Madurai Kamaraj Uni-versity, India. Examination duty, NMR maintenance, Liquid ni-trogen filling, Organic Lab in-charge.

01/08/2001 to 30/04/2003: Teacher at Vivekananda Science and Technology Tutorial Cen-ter. Taking Chemistry, Physics, and Biology classes for Higher Secondary school students and coaching, counseling


for state level Engineering and Medical, Entrance examina-tions.

AWARDS/FELLOWSHIPS Visiting Scientist awarded from European Union Social Fund (ESF), May 2013 to June

2013. Senior Researcher (Post-Doctoral Research Associate fellowship) awarded from Euro-

pean Union Social Fund (ESF), The Ministry of Education, Youth and Sports of the Czech Republic, Project CZ.1.07/2.3.00/30.0021, 2012- 2015.

Post-Doctoral Research Associate fellowship, National Science Council (NSC), Project; NSC 100-2811-M-260-001. Taiwan, 2010-2011.

University Stipendiary Research fellowship (USRF) awarded from Madurai Kamaraj University, Madurai, 625021, Tamilnadu, India. 2005-2008

Co-Guide for Masters and Master of Philosophy

Thesis title:

1. Microwave assisted synthesis of 1-(2,4-dinitrophenyl)-3-aryl-1h-4-pyrazolyl (1-phenyl-1h-1,2,3,4-tetrazol-5-yl) sulfides using vilsmeier’s reagent, P. VINAYAGAM, M. Sc., May 2008. Reg. No: A643026. Ph. D student at Department of Biotechnology, Indian Institute of Technology, Chennai, India.

2. Synthesis and characterization of 1-(2,4-dinitrophenyl)-3-(aryl)-4-[(aryl)sulfanyl]-1h-pyrazoles using vilsmeier’s reagent under microwave irradiation, R. VENKATESAN, M.Phil., Reg. No: M743025, July 2008. Ph. D., Student at Department of Chemistry, National Institute of Technology, Trichy, India

3. Nicotinonitriles by multicomponent synthesis , C. SATHISH KUMAR, M.Phil., Reg. No. M843017, July 2009. Teacher at Madurai, India.

4. Synthesis of 5-(benzothiazol-2-yl)-2-methoxy-4,6-diarylnicotinonitrile, S. KALADEVI, M.Phil., Reg. No. M843009, July 2009. Ph. D., Student at Department of Organic Chemistry, School of Chemistry, Madurai Kamaraj University, India.

5. New heterocycles from 1-aryl-2-[(1-phenyl-1h-1,2,3,4-tetrazol-5-yl)sulfanyl]-1-ethanones, S. MANOJVEER, M.Sc., Reg. No: A743014, May 2009. Ph. D., Student at School of Chemistry, Hyderabad Central University, Hyderabad, India.

6. Synthesis and characterization of 5-(5-methyl-1,3,4-thiadiazolesulfanyl)-4-aryl-1,2,3-selenadiazoles, M. SHANMUGARAJA, M. Sc., Reg. No: A743024, May 2009. . Ph. D., Student at School of Chemistry Hyderabad central University, Hyderabad, India.

7. Synthesis and characterization of 5-(1h-1,3-benzimidazol-2-ylsulfanyl)-2-methoxy-4,6-diarylnicotinonitriles, A. B. SURESH KUMAR, M. Sc., Reg. No: A743029. Chemist at Chennai

VISITED COUNTRIES


Taiwan (ROC), Germany, Czech Republic, Poland, Netherland, Italy, Turkey, Hungary.

INTERNATIONAL JOURNAL REVIEWERSHIP

International Journal of Biological Macromolecules Asian Pacific Journal of Tropical Biomedicine Journal of Surfactants and Detergents Protein & Peptide Letters Bioprocess and Biosystems Engineering Bioorganic Chemistry BioMed Research International Applied Microbiology and Biotechnology Journal of Photochemistry and Photobiology B: Biology

INSTRUMENTS HANDLED

Bruker 300 MHz NMR spectrometers and very much familiar with two-dimensional NMR spectroscopy techniques in order to elucidate the complex organic structures.

GC-MS (Finnigan Trace GC-MS)/ Agilent,Agilent 8453 UV-Visible spectrophotometer) JASCO FT-Infrared Microwave Synthesizer (Biotage/CEM). CHNS elemental analyser (Perkin-Elmer) using acetanilide as standard

COMPUTER SKILLS Aware of MS Office, Chemdraw, ACD Lab, Hyperchem and computer-based literature research technique Reaxys and Sci-finder.

TEACHING AND LABORATORY EXPERIENCE STUDENTS

I taught to under graduate, masters and master of philosophy students about Organic Chemistry, heterocyclic chemistry, NMR, Uv-Visible, FT-IR spectroscopy etc. Experience in conducting under-graduate and graduate level laboratory work in synthetic organic chemistry and Organometallic Chemistry. Experience in guiding junior researchers, Ph. D. students, and project assistants.

PERSONAL INFORMATION Nationality: : Indian Date of Birth : 24/01/1977Sex : MaleMarital Status : Married to Kanimozhi Ramakrishnan, Ph. D.,

Department of Biophysics, University of Cologne, Germany.

Languages (read, write & speak): English, Tamil;

RESEARCH PUBLICATIONS (Nos 26). See the link for full paper; https://upce.academia.edu/ManikannanRamaiyan;https://www.researchgate.net/profile/Manikannan_Ramaiyan


https://www.researchgate.net/profile/Manikannan_Ramaiyan

https://upce.academia.edu/ManikannanRamaiyan

1. Dicyanobenzene and dicyanopyrazine derived X shaped charge-transfer chromophores: Comparative and structure-property relationship study. L. Dokládalová, F. Bureš, W. Kuznik, I. V. Kityk, T. Mikysek, N. Almonasy, M. Ramaiyan, Z. Padělková, J. Kulhánek and M. Ludwig. Organic & Biomolecular Chemistry 2014, 12, 5517–5527. IF: 3.57

2. Synthesis and characterization of Push-pull molecules bearing tetraflurobenzene central acceptor modified with two peripheral hexyloxy and dihexylamino donors. Manikannan RAMAIYAN, Jiří KULHÁNEK and Filip BUREŠ. Sci. Pap. Univ. Pardubice, Ser. A 20 (2014) 249-261.

3. Spectral, electrochemical and calculated properties of quadrupolar chromophores based on tetrafluorobenzene. Falko PIPPIG, Tomáš MIKYSEK, Manikannan RAMAIYAN, Oldřich PYTELA, Jiří KULHÁNEK, Karel VYTŘAS, Numan ALMONASY and Filip BUREŠ. Sci. Pap. Univ. Pardubice, Ser. A 20 (2014) 221–228.

4. Synthesis of highly substituted n-hydroxy piperidine via intramoecular reductive cyc-lization of 1-keto-5-ketoxime. Muthupandi Nagaraj, Muthusamy Boominathan, Ra-maiyan Manikannan, Shanmugam Muthusubramanian and Nattamai Bhuvanesh. Synthetic Communications, 2013, 43, 930-940. IF: 1.06

5. Synthesis and characterization of 5-(5-methyl-1,3,4-thiadiazolesulfanyl)-4-aryl-1,2,3-selenadiazoles. R. Manikannan, M. Shanmugaraja, S. Manojveer and S. Muthusub-ramanian. Journal of Chemical Sciences, 2012, 124, 463-468. IF: 1.18

6. Synthesis of 1-(2,4-dinitrophenyl)-3-aryl-4-(arylsulfanyl)-1H-pyrazoles by Vilsmeier reaction of 2,4-dinitrophenylhydrazones of phenacyl aryl sulfides. R. Manikannan, R. Venkatesan and S. Muthusubramanian, Indian Journal of Chemistry, 2011, 50B, 1611-1618. IF: 0.69

7. Synthesis and Conformational Features of 4-(Cyclohexylsulfanyl)-1-(2,4-dinitrophenyl)-3-aryl-1H-pyrazole. R. Manikannan, R. Venkatesan and S. Muthusub-ramanian. Synthetic Communications, 2011, 13, 1916 – 1928. IF: 1.06

8. Ring and side chain formylated pyrazoles from acetophenone azines and Vilsmeier’s reagent. R. Manikannan and S. Muthusubramanian. Journal of Heterocyclic Chem-istry, 2011, 48(3), 671-677. IF: 1.12

9. Pyrazole derivatives from azines of substituted phenacyl aryl/cyclcohexylsulfides and study their antitubercular activity. R. Manikannan, R. Venkatesan, S. Muthusub-ramanian, P. Yogeeswari and D. Sriram. Bioorganic and Medicinal Chemistry Letters, 2010, 20, 6920–6924. IF: 2.65

10. Selective one-pot multicomponent synthesis and antitubercular evaluation of 5-(aryl/cyclohexylsulfanyl)-2-alkoxy-4,6-diarylnicotinonitriles, R. Manikannan, S. Muthusubramanian, P. Yogeeswari and D. Sriram. Bioorganic and Medicinal Chem-istry Letters, 2010, 20, 3352-3355. IF: 2.65

11. Synthesis and biological activity of 6-alkyl\chlorine-3-4-(6-alkyl\chlorine-2H-benzo[e][1,3]oxazin-3(4H)-yl)phenyl)-3,4-dihydro-2H-benzo[e][1,3]oxazines. R. Manikannan and S. Muthusubramanian. Indian Journal of Chemistry, Section B. 2010, 49B, 1083-1087. IF: 0.69

12. Chemoselective reaction of formalin with 2-(5-subsitituted aryl-2-hydroxyben-zylamino)phenols: Synthesis of 6-substituted 3-(2-hydroxyphenyl)-3,4-dihydro-2H-benzo[e][1,3]oxazines. R. Manikannan and S. Muthusubramanian. Journal of Hetero-cyclic Chemistry, 2008, 45, 1207-1210. . IF: 1.12


Acta Crystalographica E, IF: 0.35

13. 4-(2-Hydroxyphenyl)-3,5-dithiaheptanedioic acid. K. Ravichandran, R. Manikannan, S. Muthusubramanian, P. Ramesh and M. N. Ponnuswamy. Acta Cryst. (2013). E69, o893.

14. Chain and ring motifs in (E)-3-(4-Methoxyphenyl)-3-[3-(4-methoxyphenyl)-1H-1-pyrazolyl]-2-propenal. V. Susindran, S. Athimoolam, S. Asath Bahadur, R. Manikan-nan and S. Muthusubramanian. Acta Cryst. (2013). E69, o594–o595.

15. 1-(2,4-Dinitrophenyl)-3-phenyl-4-phenylsulfanyl-1H-pyrazole,. V. Susindran, S. Ath-imoolam, S. Asath Bahadur, R. Manikannan and S. Muthusubramanian. Acta Cryst. (2012). E68, o2845.

16. (E)-3-(4-Bromophenyl)-3-[3-(4-bromophenyl)-1H-pyrazol-1-yl]prop-2-enal. P. Ramesh, Ramaiyan Manikannan, S. Muthusubramanian, K. Ravichandran and M. N. PonnuswamyActa Cryst. 2010, E66, o279.

17. (E)-3-Phenyl-3-(3-phenyl-1H-1-pyrazolyl)-2-propenal.V. Susindran, S. Athimoolam, S. Asath Bahadur, B. Sridhar, R. Manikannan, S. Muthusubramanian. Acta Cryst, 2010, E66, o577.

18. E)-3-(4-Chlorophenyl)-3-[3-(4-Chlorophenyl)-1H-1-pyrazolyl]-2-propenal. V. Susindran, S. Athimoolam, S. Asath Bahadur*, R. Manikannan and S. Muthusubramanian. Acta Cryst. 2010, E66, o2594-o2595.

19. 3,3’-(p-phenylene)bis (3,4-dihydro-2H-1,3-benzoxazine). Sekaran Ranjith, Sundar Thenmozhi, Ramaiyan Manikannan, Shanmugam Muthusubramanian and Arunach-alathevar Subbiahpandi. Acta Cryst. 2009, E65, o581.

20. 3-(4-Chlorophenyl)-1-[(E)-1-(4-chlorophenyl)-2-(4-methylphenylsulfanyl)-ethenyl]-4-(4-methylphenylsulfanyl)-1H pyrazole. P. Ramesh, Ramaiyan Manikannan,S. Muthusubramanian, S. S. Sundaresan and M. N. Ponnuswamy, Acta Cryst. 2009, E65, o2881–o2882.

21. P. Ramesh, A. Subbiahpandi, Ramaiyan Manikannan, S. Muthusubramanian and M. N. Ponnuswamy*, 3-(Cyclohexylsulfanyl)-2-(4-methylphenyl)-5,7-dinitro-1H-indole. Acta Cryst. 2008, E64, o1890.

22. 1-[(E)-2-Formyl-1-(4-methylphenyl)-ethenyl]-3-(4-methylphenyl)pyrazole-4-Carbalde-hyde. P. Ramesh, A. Subbiahpandi, Ramaiyan Manikannan, S. Muthusubramanian and M. N. Ponnuswamy, Acta Cryst. 2008, E64, o1889.

23. 4-[(4-Chlorophenyl)sulfanyl]-1-(E)-2-[(4-chlorophenyl)sulfanyl]-1-phenyl-1-ethenyl-3-phenyl-1H-pyrazole. P. Ramesh, A. Subbiahpandi, Ramaiyan Manikannan, S. Muthusubramanian and M. N. Ponnuswamy, Acta Cryst. 2008, E64, o2054-o2055.

24. 4-(Cyclohexylsulfanyl)-1-[(E)-2-(cyclohexylsulfanyl)-1-phenyl-1-ethenyl]-3-phenyl-1H-pyrazole. P. Ramesh, A. Subbiahpandi, Ramaiyan Manikannan, S. Muthusub-ramanian and M. N. Ponnuswamy, Acta Cryst. 2008, E64, o2132-o2133.

25. 1-(2,4-Dinitrophenyl)-3-(4-methylphenyl)-4-phenylsulfanyl-1H-pyrazole. P. Ramesh, Ramaiyan Venkatesan, Ramaiyan Manikannan, S. Muthusubramanian and M. N. Ponnuswamy, Acta Cryst. 2008, E64, o2093.

26. (E)-3-(4-Methylphenyl)-3-[3-(4-methylphenyl)-1H-1-pyrazolyl]-2-propenal. P. Ramesh, A. Subbiahpandi, Ramaiyan Manikannan, S. Muthusubramanian and M. N. Ponnuswamy. Acta Cryst. 2008, E64, o2243.


COMMUNICATED AND PREPARATION

1. Synthesis and Properties of Push–Pull Chromophores Based on Pyrrolo[3,4-c]pyrrole-1,4-diones. Under preparation.

2. Synthesis and Properties of Push–Pull Chromophores of 4,7- π-substituted 2,1,3-ben-zothiadiazole. Under preparation.

3. Synthesis and NLO Properties of Push–Pull Chromophores Based on Thiophene-3,4-dinitrothiophene. Under preparation.

4. Synthesis and NLO Properties of Push–Pull Chromophores Based on Thiophene-3,4-dicarbonitrile. Under preparation.

5. One-pot multicomponent synthesis of 6-substituted 3-[(1R)-1-phenylethyl]-3,4-di-hydro-2H-1,3-benzoxazines and their biological activity. R. Manikannan, K. Thiru-mavalavan, M. Karuppaiya and S. Muthusubramanian (Submitted to Medicinal Chemistry Research).

6. Nicotinonitriles by multicomponent synthesis and studies their anti-tubercular activ-ity. Under preparation.

7. Synthesis of 2-((5-substituted-2-hydroxyphenyl)[(2-oxoethyl)sulfanyl]methylsulfanyl)acetaldehyde; Reaction of C-(2-hydroxyaryl)-N-aryl imines with thioglycollic acid. Under preparation.

8. Synthesis and NLO Properties of Push–Pull Chromophores Based on imiadazole. Un-der preparation.

LECTURES DELIVERED

1. Synthesis of derived heterocyclic systems and study of their biological activities, European Union postdoc lecture at Faculty of Chemical Technology, University of Pardubice, Pardubice, Czech Republic, on 5th April 2013.

2. International scientific fellowship with Czestochowa University of Technology, European Union postdoc lecture at Faculty of Chemical Technology, University of Pardubice, Pardubice, Czech Republic, on 21st November 2013.

3. Synthesis and Properties of Push–Pull Chromophores Based on Thiophene and Bis-pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione. Colloquium of (post)doctoral students at Faculty of Chemical Technology, University of Pardubice, Pardubice, Czech Republic, on 12th February 2014.

ORAL PRESENTATION1. Solventless reaction of lead tetraacetate with N-2-hydroxyaryl imines.

R. Manikannan, V. Sridharan and S. Muthusubramanian, Recent Advances in Chemistry, Annamalai University, Chidambaram, India, March 10-11, 2006.

CONFERENCE PROCEEDINGS


1. Synthesis and Properties of Push–Pull Chromophores based on Thiophen, Benzene, Benzo-thiadiazole, Imidazole, and Diketopyrrolopyrrole (DPP) Derivatives, R. Manik-annan, J. Kulhánek, F. Bures, Final Postdoc. Workshop, 11th February 2015, Univer-sity of Pardubice, Pardubice, Czech Republic.

2. Synthesis and Properties of Push–Pull Chromophores Based on Pyrrolo[3,4-c]pyrrole-1,4-diones. Ramaiyan Manikannan, Jiri Kulhánek, Bures Filip, IDMS 2014 - Interna-tional Days of Materials Science 2014, 16th September and 17 th September 2014, University Pardubice, Pardubice, Czech Republic, Europe.

3. Synthesis and properties of push–pull–push chromophores based on 3,4-dinitro-thiophene. Ramaiyan Manikannan, Jiří Kulhánek, ICOS20 (20th International Confer-ence on Organic Synthesis), 29th June – 4th July 2014 Budapest, Hungary, Europe.

4. Synthesis and Properties of Push–Pull Chromophores Based on Thiophene-3,4-dicar-bonitrile. Ramaiyan Manikannan, Jiří Kulhánek. 44th IUPAC Word Chemistry Con-gress, August 11th – August 16th, 2013, Istanbul, Turkey.

5. Crystal and molecular structure of 3-(4-Chlorophenyl)-1-(E)-1-(4-chlorophenyl)-2-[(4-chlorophenyl)sulfanyl]-1-ethenyl-4-[(4-chlorophenyl)sulfanyl]-1H-pyrazole. S. Pandia-rajan, B. Ravikumar, M. Rekha Devi, Ramaiyan Manikannan, S. Muthusubramanian. 14th National Seminar on Crystal Growth, NSCG- XIV 10-12, March 2010. Organized by School of Advanced Sciences, VIT University, Vellore – 14, India.

6. Product selective one-pot multicomponent synthesis of 5-(benzo[d]thiazol-2-ylthio)-2-methoxy-4,6-diarylnicotinonitriles. Ramaiyan Manikannan, Selvam Kaladevi and Shanmugam Muthusubramanian. National Seminar on Recent Trends (RTC-3) in Chemistry, Department of Chemistry, Jayaraj Annapackiam for women college, Per-iyakulam, Tamilnadu, India February, 26-27, 2009.

7. Crystal structure of 3-[4-(3,4-dihydro-2H-1,3-benzoxazine-3-yl)phenyl]-3,4-dihydro-2H-1,3-benzoxazine. S. Ranjith, R. Manikannan and A. Subbiah Pandi. 38th National Seminar on Crystallography (38NSC-2009), Department of Studies in Geology, Uni-versity of Mysore, Mysore, Karnataka, India, 13th February-2009.

8. Pyrazole derivatives from substituted acetophenone azines. Ramaiyan Manikannan and Shanmugam Muthusubramanian, National Conference on Recent Advances in Chemical Research, Department of Chemistry, University College of Science, Os-mania University, Hyderabad, February, 6-7, 2009.

9. Product selective one-pot multicomponent synthesis of 5-(4,5-dihydrothiazol-2-yl-thio)-2-methoxy-4,6-diarylnicotininitriles. Ramaiyan Manikannan, Chinnayan Sathish kumar and Shanmugam Muthusubramanian. National Conference on Recent Ad-vances in Chemical Research, Department of Chemistry, University College of Sci-ence, Osmania University, Hyderabad, February, 6-7, 2009.

10. Synthesis of 4-(Cyclohexylsulfanyl)-1,3-diaryl-1H-pyrazoles Using Vilsmeier’s Re-agent. R. Manikannan, R. Venkatesan and S. Muthusubramanian, 10th anniversary of CRSI National Symposium in Chemistry, Indian Institute of Science, Bangalore, Feb-ruary, 1-3, 2008.

11. Synthesis of 6-alkyl/aryl-3-(4-(6-alkyl/aryl-2H-benzo[e][1,3]oxazin-3(4H)-yl)phenyl)-3,4-dihydro-2H-benzo[e][1,3]oxazine from 2-({4-[(2-hydroxy-5-substituted benzyl)amino]anilino}methyl)-4-alkyl/aryl benzenol and formalin. R. Manikannan and S. Muthusubramanian, National Seminar on Current Developments in Chemistry, Bharathiar University, Coimbatore, January 18-19, 2007.


12. Reaction of formalin with 2-(5-alkyl\aryl-2-hydroxybenzylamino)phenols. R. Manikannan and S. Muthusubramanian, National Conference in Chemistry, Central College, Bangalore, September 27-29, 2006.

13. Synthesis, characterization and biological activity of metal complexes having (2-{[2-(2-benzoyl-4-chloroanilino)-2-hydroxyethenyl]amino}-5-chlorophenyl) (phenyl)methanone ligand.R. Manikannan, S. Meenalochcani and D. Chellappa, Re-gional symposium on current research trends in Chemistry at Kongunadu Arts and Science College, Coimbatore, India. 10th September 2004.

CONFERENCES AND WORKSHOPS PARTICIPATED

1. International seminar 2014, “2014 – 2020: a New Challenge for Coordinators of the European Projects” University of Pardubice, Pardubice, Czech Republic, May 13 – 14, 2014.

2. IOCB Invited Lecture Series Topic: Organotrifluoroborates, Novel Organoboron Re-agents and Reactivities by Prof. Gary A. Molander (Department of Chemistry, Univer-sity of Pennsylvania, Philadelphia, Pennsylvania, USA) at Institute of Organic Chem-istry and Biochemistry, Academy of Sciences of the Czech Republic Flemingovo nam. 2, 166 10 Prague 6, Czech Republic. March 11th 2014.

3. SERC School on Green Chemistry Application, Research Activities and Recent Trends, at School of Chemistry, Madurai Kamaraj University, Madurai, Tamilnadu, India, 625021. December 14th to 27th, 2009.

4. Patent awareness workshop at School of Chemistry, Madurai Kamaraj University, Madurai, Tamilnadu, India, 625021, December 4th 2009.

5. Lecture-Workshop programme on Synthetic and Structural Chemistry (SASC 2009), Department of Chemistry, Annamalai Univeristy, Chidambaram, India, 21st and 22nd

March 2009.

6. One day seminar on Recent Trends in Green Chemistry (RTGC-09), Department of Chemistry, Thiagarajar College of Engineering, Madurai, India, 20th February 2009.

7. National Organic Symposium Trust fourth J-NOST conference for Research Scholars, School of Chemistry, Madurai Kamaraj University, Madurai, India, December 6-9, 2008.

8. National Seminar on Frontiers in Natural Products Chemistry, School of Chemistry, Madurai Kamaraj University, Madurai, India, March, 20-21, 200

9. National Workshop on NMR Spectroscopy - Theory and Applications, School of Chem-istry, Madurai Kamaraj University, Madurai, India, March 2008.

10. National Workshop on One and Two Dimensional NMR Spectroscopy - Theory and Ap-plications, School of Chemistry, Madurai Kamaraj University, Madurai, India, February 2007.

11. National Workshop on Green Chemistry, School of Chemistry, Madurai Kamaraj Uni-versity, Madurai, India, July 2005.

Prof. Dr. Jiri Kulhanek,Vice-Rector for ResearchStudentska 573,

Prof. Dr.Muthusubramanian Shanmugam Chair Person, HOD, Department of Organic Chemistry,


Department of organic materials, Institute of Organic Chemistry and Technology, Faculty of Chemical Technology,University of Pardubice, Pardubice53210, Czech Republic, EuropeEmail: [email protected]: +420 46 603 7016 (7019)

School of Chemistry, Madurai Kamaraj University,Madurai - 625021, Tamilnadu, India.E-mail: [email protected] : +91-452-2458246Fax: +91-452-2459845

Senior Prof. Dr. Subbu Perumal,Department of Organic Chemistry, School of Chemistry, Madurai Kamaraj University,Madurai - 625021, Tamilnadu, India.E-mail: [email protected] : +91-452-2458246Fax: +91-452-2459845

Dr. P. R. Murugesan, MBBS, MS, DNB, M.Ch., DNB, Professor and HeadChief Cardio-thoracic & Vascular Surgen,Thoracoscopy, Minimal Invasive Cardiac Surgery & ECMO, Transplant SpecialistDept. Of Cardio-thoracic & Vascular SurgeryP.S.G. Institute of Medical Sciences & Research, Peelamedu, Coimbatore-641004,E-mail : [email protected] 0422-2623501

Prof. Dr. Alagusundaram Ponnusamy,Department of Organic Chemistry, School of Chemistry, Madurai Kamaraj University,Madurai - 625021, Tamilnadu, India. E-mail: [email protected] : +91-452-2458246.Fax: +91-452-2459845

REFERENCES

SUMMARY OF RESEARCH WORKS


mailto:E-mail%20:%[email protected]

Organic Material Synthesis

My current research work focused on Synthesis and Properties of Push–Pull Chromophores Based on Porphyrin, Pyrazine, Benzene, Ferrocene, Thiophene, diketopyrrolopyrrole and benzothiadiazole based heterocyclic and aryl push-pull chromophores for nonlinear optics (NLO) properties, organic light-emitting diodes OLEDs, OTFTs, organic field-effect transistor (OFET), photodynamic therapy (PDT) Dye-sensitised solar cells (DSSCs) photovoltaic device (PV) and DFT calculation.

Push-pull chromophores enjoy widespread application in material chemistry as optoelectronic and optical data storage devices, organic light-emitting diodes (OLED), organic-inorganic hybrid materials, functional polymers etc. We have been reported the Pyrazine, Benzene, Thiophene, diketopyrrolopyrrole, benzothiadiazole, porphyrin and imidazole based chromophores as an acceptor moiety, a systematically enlarged -conjugated spacer and methoxy and N,N-dimethylamino groups as donors and nitro, cyano groups as acceptor.

Scheme 1. Synthesis of (D-π-D or D-π-A ) and D–π-A–π-D or A–π-D–π-A) push-pull chromophores

Synthetic Organic Chemistry and Medicinal Chemistry

In my doctoral research in my thesis 1st part , I have synthesized a series of 1,3-benzoxazine and bis-benzoxazines derivatives from the corresponding para subsitituted phenols, respective primary amines and formaldehyde under microwave irradiation as well as conventional method, and multi-step approach by benign green chemical protocols and studies their antimicrobial activities.

In 2nd part of my doctoral thesis deals with synthesis of pyrazole and pyridine derivatives and study their antitubercular activity. The antimycobacterial activity of the isomeric compounds has been tested against Mycobacterium tuberculosis (MTB). Pyrazole, pyrrole, indole and pyridine derivates were synthesized from simple substituted acteopheone via multi step process.

In my research associate research carrier I have synthesized the libraries of

heterocyclic compounds pyridine with S-linked heterocyclic molecules like benzimidazole,

benzthiazole, benzoxazole, dihydrothiazole, imidazole, tetrazole, 5-methyl-1,3,4-thiadiazole

(15-20,24 and 26) from their corresponding ketones with arylaldehyde and malononitrile in


sodium hydroxide in methanol/ethanol by one-pot multicomponent reaction and studies their

antitubercular activity.

Attempted many reactions in my research laboratory, like Fisher Indole synthesis,

Piloty pyrrole synthesis, Friedlander reaction and synthesis of some novel chalcones.

In my Master of Philosophy work I have synthesized, characterized Cu, Zn, Mn, Ni,

Fe and Co complexes having (2-{[2-(2-benzoyl-4-chloroanilino)-2-hydroxyethenyl]amino}-

5-chlorophenyl)(phenyl) methanone ligand and their biological activity studies.

Statement of teaching interests:


I am very much interest on Basic Organic Chemistry, Inorganic Chemistry, Physical Chemistry and Natural Product Chemistry Organic Chemistry:

Structural theory of organic chemistry, Nomenclature of organic chemistry, Stereochemistry, Ba-sic mechanisms of organic reactions, Reactions various groups of organic compounds, Name re-actions, Rearrangements and Reagents.

Spectroscopy:

Basic of NMR spectroscopy and their application, Basic of Uv-Visible spectroscopy and their application Basic of FT-IR spectroscopy, Basic of GC-MS spectroscopy Basic of Chromatography and their applications (Paper, HPLC, TLC, Column)

Heterocyclic Chemistry

Synthesis of different heterocyclic compounds and their pharmaceutical applications

Organic Materials and their applications

Synthesis and Properties of Push–Pull Chromophores . And study their nonlinear optics (NLO) properties, organic light-emitting diodes OLEDs, OTFTs, organic field-effect transistor (OFET), photodynamic therapy (PDT) Dye-sensitised solar cells (DSSCs) and photovoltaic device (PV).


manikannan raaiyan, m. sc., m. phil., ph. d. (org. chem...

Documents