managing livestock ammonia: a volatile, promiscuous fugitive in the atmosphere

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Managing Livestock Ammonia: A Volatile, Promiscuous, Fugitive in the Atmosphere? Jay Ham Department of Soil and Crop Sciences Colorado State University

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http://www.extension.org/67750 Livestock production is the largest source of atmospheric ammonia, accounting for over 50 % and 40 % of the national and global inventories, respectively. At beef feedlots for example, 40 to 60 percent of the fed nitrogen is lost to the atmosphere as ammonia. Once ammonia enters the atmosphere it can convert to an aerosol and travel long distances from the source. Most of this fugitive nitrogen is eventually deposited back to the ground when scavenged from the air by precipitation. Unfortunately, this unintentional nitrogen transport and fertilization is having a negative ecological impact on pristine ecosystems around the globe. Thus, it is not surprising that livestock ammonia is an area of growing public concern and regulatory debate. Perhaps nowhere is ammonia from livestock under greater scrutiny than along the Front Range of Colorado. Increased levels of atmospheric nitrogen deposition are having a negative impact on the ecology of Rocky Mountain National Park, a crown jewel of the National Park System. While studies suggest many different sources are contributing to nitrogen deposition in the park (e.g., urban, out of state sources), much attention has been directed to the beef feedlots and dairies that populate the plains just east of the mountains. The keynote address will briefly discuss ammonia emissions from livestock at global scales, with commentary on a new United Nations report "Our Nutrient World" that draws considerable attention to manure management and atmospheric ammonia. The remainder of the presentation will focus on Colorado's regional ammonia issue and what is being done to reduce ammonia loss from feedlots and dairies along the Front Range. New technologies for measuring ammonia and minimizing environmental impacts will be discussed.

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Page 1: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Managing Livestock Ammonia: A Volatile,

Promiscuous, Fugitive in the Atmosphere?

Jay Ham

Department of Soil and Crop SciencesColorado State University

Page 2: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Acknowledgements

Christina Williams, Joshua Stratton, Kira Shonkwiler

Co-PIs and Funding Agencies

CSU Department of Atmospheric Science

Members of RMNP Agric. Subcommittee

Cooperators and Industry Partners

Page 3: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Outline

The Global Nitrogen Cycle

Regional Ammonia– N deposition in Rocky

Mountain National Park– What is the contribution

from Livestock ? Farm Scale Solutions

– Measurement, Models, & BMPs

Page 4: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Part 1: The Global Nitrogen Cycle and Livestock Production

“a small leak will sink a great ship” - Benjamin Franklin

Page 5: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

A safe operating space for humanity

Rockström et al. 2009. Nature, 461, 472-475Galloway et al. 2008. Science, 320,www.ted.com/talks/johan_rockstrom_let_the_environment_guide_our_development.html

Nitrogen !

Page 6: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Erisman et al., 2008. Nature Geoscience

Page 7: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

“Globally around 80% of harvested nitrogen and phosphorus is consumed by livestock rather than directly by people, showing how global nutrient supply and pollution are dominated by humans’ choice to consume animal products.” Sutton et al., 2013.

United Nations Environment Programme (UNEP)http://www.gpa.unep.org/gpnm

Page 8: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Sutton et al., 2013. United Nations Environment Programme (UNEP)

Recommendations from “Our Nutrient World”

Page 9: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

promotion of the ‘ demitarian ’ option, which we define as a meal containing half the amount of meat or fish compared with the normal local amount …,

The Barsac Declaration

Demitarian

Page 10: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Global Nitrogen Fluxes and Livestock AmmoniaFluxes Tg N / yr

Nitrogen Fertilizer 120

Nitrogen Fixation 50-70

Crop and Grass Production 122

Crop and Grass for Livestock Production

100 (81%)

NH3 Emissions from Soils 15

NH3 Emissions from Livestock 22 (59.5 %)

Total NH3 from Agriculture 37

Sutton et al., 2013. United Nations Environment Programme (UNEP)

Page 11: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Got Beef ? Got Ammonia !

Retention of fed nitrogen in feedlot cattle is typically 13%

Most fed nitrogen is excreted in the urine and feces as urea

Up to 50% of fed N can be lost to the atmosphere as NH3

Page 12: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Map Courtesy of P.I. Coyne

9.5 million head * 0.31-0.37 lbs N excreted /day

= 2.7 to 3.5 million lbs N/day of excreted N

If 50% is lost to the atmosphere as NH3

1.4 to 1.7 million lbs. of ammonia/day

Page 13: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Satellite Data of NH3 OVER NORTH AMERICA (2009)

Data from Colette L. Heald, CSU

Page 14: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Part 2: Nitrogen deposition in Rocky Mountain National Park

A "perfect storm" is an expression that describes an event where a rare combination of circumstances will aggravate a situation drastically

http://en.wikipedia.org/wiki/Perfect_storm

Page 15: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere
Page 16: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Rocky Mountain National Park

Page 17: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

http://vista.cira.colostate.edu/improve/Education/education.htm

Page 18: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

NH3SOx NOx

Emissions

Gas-Particle Partitioning (aerosol formation)

NH3

H2SO4

HNO3

NH4+

SO42-

NO3-

Deposition

Dry Wet

Transport

NH3

(Slide by Luke Schiferl)

Page 19: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

http://vista.cira.colostate.edu/improve/Education/education.htm

Page 20: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Wet Deposition Sampling

Page 21: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Wet N Deposition in RMNP

Morris et al., 2012. Natural Resource Report NPS/NRSS/ARD/NRR—2012/562

Page 22: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

http://vista.cira.colostate.edu/improve/Education/education.htm

Page 23: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Colorado Ammonia Sources

Rocky Mountain National Park Initiative ‐ Nitrogen Deposition Reduction Contingency Plan. June 21, 2010

Page 24: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

NE Colorado CAFO Map

Page 25: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Malm, W. C., Collett, Jr., J. L., et al. (2009) The Rocky Mountain Airborne Nitrogen and Sulfur Study (RoMANS), final report to the National Park Service.

strategy taken for apportioning various aerosol species concentrations and deposition to source emissions is a weight-of-evidence approach, comparing and contrasting results from multiple analyses.

Page 26: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Wet Nitrogen Deposition

Page 27: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Part 3: Measurements, Modeling, and BMPs

“What gets measured gets managed “

- Peter Drucker

Page 28: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

CSU Livestock NH3 Research

Measurement of NH3 Emissions and Regional Conc. Patterns

Development of management BMPs

Modeling and Software Tools

New TechnologyFunding Sources:USDA, EPA, NRCS, and NSF

Page 29: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Best Management Practices to Reduce Livestock Ammonia

Impacts Feed Management

Change Manure Management

Meteorological Warning Systems

NH3 Measurement Technology

Page 30: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Blue – 13.5% CPRed – OscillatingGreen – 11.6% CP

Effect of Reduced Crude Protein Diet on Pen Surface NH3 Emissions

Diet

Galles K., Ham J., Westover E., Stratton J., Wagner J., Engle T., Bryant T.C. 2011. Influence of Reduced Nitrogen Diets on Ammonia Emissions from Cattle Feedlot Pens. Atmosphere. 2(4):655-670.

Page 31: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

New Measurement Technology

Identification of NH3 “Hot Spots”

Tracking and Trend Detection of NH3 emissions

Information for Decision Making

Meeting future regulatory requirements

Page 32: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Robotics for Managing Air Emissions of Ammonia at Livestock Operations

Ham et al., 2012.National Robotics Initiative (NSF/USDA-NIFA)

Goal: Develop a robotic air-quality management system for dairies and cattle feedlots that will help managers reduce ammonia emissions

Design new low-cost Laser for real-time NH3 monitoring

Laser Det.

Sample Gas

Develop a wireless NH3 sensor network

Design weather forecast retrieval system to predict NH3 emissions and transport in advance.

Page 33: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Conditional Passive Samplers

Page 34: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Conditional Passive Samplers

``

Linear Actcuator

Acrylic Tube

Cap

Spacer

Vertical Adapter

Radiello Diffusive Sampler

Foam

Acrylic Disc

Hall Effect Sensor

Control Cable

Spacer

Clevis

Clevis

PlungerMagnet

Hall Effect Cable

Arduino

Page 35: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Northern Colorado Dairy

Page 36: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Beef Feedlot NH3 Concentrations

Page 37: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

http://sensemake.rs/portfolio-item/air-quality-egg/

http://aircasting.org/http://aircasting.org/

Page 39: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Conclusions

Livestock NH3 is becoming a dominant global and regional environmental issue – and linkages between N pollution, livestock, and food choice will gain more attention over time.

Contact Information: [email protected]; 970-491-4112

Page 40: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Conclusions

The Front Range of Colorado and RMNP has emerged as a test case for how science, policy, and cooperation among stakeholders can address a regional NH3 issue.

Contact Information: [email protected]; 970-491-4112

Page 41: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Conclusions

New measurement technologies, IoT, and M2M communications will likely greatly help livestock managers reducer NH3 losses.

Contact Information: [email protected]; 970-491-4112

Page 42: Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

Questions ?

Contact Information: [email protected]; 970-491-4112