malcolm pirnie inc - july 1996 monthly progress report ... · august 9, 1996 mr. pablo n. valentin...

MALCOUVtPIRNIE MALCOLM PIRNIE, INC.

ENVIRONMENTAL ENGINEERS, SCIENTISTS & PLANNERSv .Lfx I? jxv^ ijJIj^A^^t^

August 9, 1996

Mr. Pablo N. ValentinRemedial Project ManagerOffice of SuperfundU.S. Environmental Protection Agency77 West Jackson BoulevardChicago, IL 60604-3590

Re: July 1996 Monthly Progress Report for theLemberger Landfill RD/RA - Operable Unit 1

Dear Mr. Valentin:

Please find enclosed two (2) copies of the subject Monthly Progress Report for theLemberger Landfill (LL) RD/RA activities in accordance with Paragraph 29 of the ConsentDecree.

The Monthly Progress Report for the Lemberger Transport and Recycling (LTR) RD/RAactivities will be submitted under separate cover by the LSRG's LTR constructionadministration contractor.

Please call if you have any questions.

Very truly yours,

MALCOLM PIRNIE, INC.

William M. Mahlum, Jr., P.E.Project Manager/Associate

Enclosure

c: D. B. Clark, Foley & Lardner, w/encl.G. A. Edelstein, WDNR, w/encl. (2 copies)J. B. Huffinan, WDNR, w/encl.LSRG Technical Committee, w/encl.A. Becker, Foley & Lardner, w/encl.T. A. Ritter, w/encl.S. C. Schwarz, w/encl.R. W. Arko, w/encl.M.A. Mclaughlin, w/encl

\lembergr\monthrpt\jul96mpr. let

5500 WAYZATA BOULEVARD MINNEAPOLIS, MN 55416-1262 612-591-1394 FAX 612-591-9881

RECYCLED PAPER

MALCOLM PIRNIE, INC. Date: August 9, 1996

LLMONTHLY PROGRESS REPORT

Remedial Design and Remedial ActionLemberger Landfill Site

Operable Unit 1Lemberger Site Remediation Group

Reporting Period: July 1 through July 31, 1996

Estimated Percent Complete:

Conceptual RD/RA Memorandum 100%Work Plan 100%Predesign Activities 100%Design 100%Construction Quality Assurance Plan 100%Construction 95%

Summary of Progress:

• Construction of the clay barrier lay was completed.

• The two 8-hour and 14-day performance testing of the groundwater treatment system wascompleted.

• Construction work on the treatment facility and storage tank building continued. Constructionis complete, except for installation of exhaust fans and louvers.

• Restoration and landscaping continued along the raw water pipeline routes.

• The LSRG selected RMT to operate and maintain the Lemberger Sites Closure Systems andGroundwater Treatment System.

• Additional laboratory and field SOPs for the pre-startup sampling of ground water and surfacewater were submitted to the WDNR for review by LSRG's pre-startup sampling contractor.

Summary of Physical Testing and Analyses Completed:

• Influent and effluent testing results from the groundwater treatment system performance testingis attached.

Summary of Changes to RD/RA Work Plan:

• None.

2049 -1-

Summary of Outside Contacts:

• Certain landowners in the area were contacted regarding on-going construction.

Areas of Concern:

• The pre-startup groundwater sampling have been delayed. These delays may impact theschedule for startup of full-time operation of the ground water treatment system.

• Construction activities have been delayed due to weather.

Action Taken to Resolve Areas of Concern:

• LSRG's pre-startup sampling contractor is working with the USEPA and WDNR to gainapproval of the analytical and field SOPs and to conduct the pre-startup sampling in mid-August.

• We are working with the construction contractor to reschedule activities in an effort to minimizedelays in completion of the construction.

Key Personnel Changes:

• None.

Activities Planned for Next Month:

• Site restoration and landscaping will continue.

• All construction work is expected to be substantially complete by the end of the month.

• Prefmal Inspection is scheduled for August 27.

• The pre-startup groundwater and surface water sampling are expected to be completed.

• Training of the O&M operator for the groundwater treatment system is expected to becompleted.

• Preparation of the O&M Plan Addenda by the O&M contractor is expected to begin.

• Startup of the groundwater treatment system is expected after October 1, 1996

Respectfully submitted,

MALCOLM PIRNIE, INC.

William M. Mahlum, Jr., P.E.Project Coordinator

\lembergr\monthrpt\lljul96.mpr

2049 -2-

Page -1

Volatile Organic Compounds Analysis ReportWater Analysis by SW-846 Method 8021

CLIENT ED:HESID:

DATE SAMPLED:DATE RECEIVED:

DATE ANALYZED:

AERATION TEST-16040030307/11/9607/11/9607/12/96

Surrogate Recoveries1,4-DICHLOROBUTANE: 88%

COMPOUNDHall Detector

1,1,1-TRICHLOROETHANE1.U-TRICHLOROETHANE

REPORTLOD LOQ CONC.(ug/L) (ug/L) (ug/L) FLAGS

0.290.15

0.910.47

OJ1<LOD

Y

FLAGS : B - analyte found in blank above LOD (Limit of Detection)Y - Compound Concentration Value between LOD and LOQ (Limit of Quantitation)E - concentration exceeds the calibration rangeD - concentration determined from a diluted analysis

S I ervices/ Inc.525 SCIENCE DRI\£ MADISON. WISCONSIN 53711

HES,Inc.

SVERDRUPLemberger Landfill Project

Sample Number 60700303Sample ID: Aeration Test-1Date Received: 07/12/96

Assay

AntimonyArsenicCadmiumLeadSeleniumMercuryAluminumBerylliumChromiumCopperIronNickelSilverZinc

Cyanide

ChlorideHardness

•*- Total PhosphateTotal Suspended SolidsPH

DateAnalyzed

7/16/967/15/967/16/967/16/967/16/967/16/967/17/967/17/967/17/967/17/967/17/967/17/967/17/967/17/96

7/12/96

7/16/967/17/967/19/967/16/967/16/96

Units

UG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/L

UG/L

MG/LMG/LMG/LMG/L

PH

Result

<5.01.0<1.0<1.0<2.0<0.133.4<0.2<4.0<3.8375<7.9<5.25.1

<2.5

17.5390

0.01117.07.93

"Y" = Value between LOD and LOQMetals results are reported to the current IDL

Phone 608-232-3300 Fax 608-233-0502

IBSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

SAMPLE NO,

Lab Name: HES, Inc. . Contract:

Lab Code: Case No.: SVDP SAS No.:

Matrix: (soil/water) WATER

Sample wt/vol: 1000 (g/mL) ML

Level: (low/med) LOW

% Moisture: decanted: (Y/N)

Concentrated Extract Volume: 1000 (uL)

Injection Volume: l.O(uL)

GPC Cleanup: (Y/N) N pH:

GAS NO. COMPOUND

AERATION

SDG No.: 700303

Lab Sample ID: 60700303

Lab File ID: 1F014

Date Received: 07/12/96

Date Extracted: 07/12/96

Date Analyzed: 07/19/96

Dilution Factor: 1.0

CONCENTRATION UNITS:(ug/L or ug/Kg) UG/L

62-75-9—————•——N-Nitrosodimethylamine______108-95-2——————Phenol____________________111-44-4——————bis (2-Chloroethyl) Ether_____95-57-8———————2-Chlorophenol____________541-73-1——————1,3-Dichlorobenzene________106-46-7——————1,4-Dichlorobenzene________95-50-1———————1,2-Dichlorobenzene__________108-60-1——————bis (2-Chloroisopropyl) ether_____621-64-7——————N-Nitroso-Di-n-Propylamine__67-72-1———————Hexachloroethane__________9 8-95-3———————Nitrobenzene______________78-59-1———————Isophorone________________88-75-5———————2-Nitrophenol_____________105-67-9——————2,4-Dimethylphenol_________111-91-1——————bis (2-Chloroethoxy) Methane__120-83-2——————2,4-Dichlorophenol_______12 0-82-1——————1,2,4-Trichlorobenzene_____91-20-3———————Naphthalene____________87-68-3———————Hexachlorobutadiene________59-50-7———————4-Chloro-3-Methylphenol_____77-47-4———————Hexachlorocyclopentadiene___88-06-2———————2,4,6-Trichlorophenol_______91-58-7———————2-Chloronaphthalene________131-11-3——————Dimethylphthalate_________208-96-8——————Acenaphthylene____________606-20-2——————2,6-Dinitrotoluene_________83-32-9———————Acenaphthene______________51-28-5———————2,4-Dinitrophenol_________100-02-7——————4-Nitrophenol_____________121-14-2——————2,4-Dinitrotoluene_________

101010101010101010101010101010101010101010101010101010505010

Q

uuuuuuuuuuuuuuuuuuuuuuuuuuuuuu

FORM I SV-1 OLM03.0

SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

Lab Name: HES, Inc. Contract:

Lab Code: Case No.: SVDP SAS No.:

Matrix: (soil/water) WATER

Sample wt/vol: 1000 (g/mL) ML

Level: (low/med) LOW

% Moisture: decanted: (Y/N)

Concentrated Extract Volume: 1000 (uL)

Injection Volume: l.O(uL)

GPC Cleanup: (Y/N) N pH:

GAS NO. COMPOUND

AERATION

SDG No.: 700303

Lab Sample ID: 60700303

Lab File ID: 1FO14

Date Received: 07/12/96

Date Extracted: 07/12/96

Date Analyzed: 07/19/96

Dilution Factor: 1.0

CONCENTRATION UNITS:(ug/L or ug/Kg) UG/L

84-66-2———————Diethylphthalate_________7005-72-3—————4-Chlorophenyl-phenylether_86-73-7———————Fluorene__________________________534-52-1——————4,6-Dinitro-2-methylphenol_86-30-6———————N-Nitrosodiphenylamine (1)~122-66-7——————1,2-Diphenylhydrazine___~101-55-3——————4-Bromophenyl-phenylether_118-74-1——————Hexachlorobenzene____________87-86-5———————Pentachlorophenol_____________85-01-8———————Phenanthrene___________120-12-7——————Anthracene_____________84-74-2———————Di-n-Butylphthalate________206-44-0——————Fluoranthene____________92-87-5———————Benzidine______________129-00-0——————Pyrene_________________85-68-7———————Butylbenzylphthalate_______91-94-1———————3,3'-Dichlorobenzidine_____56-55-3———————Benzo (a) Anthracene________218-01-9——————Chrysene________________117-81-7——————bis (2-Ethylhexyl) Phthalate117-84-0——————Di-n-Octyl Phthalate_____~205-99-2——————Benzo (b) Fluoranthene_____207-08-9——————Benzo(k)Fluoranthene_____50-32-8———————Benzo (a) Pyrene__________193-39-5——————Indeno (1,2,3-cd) Pyrene___53-70-3———————Dibenzja,h)Anthracene____191-24-2——————Benzo (gf h, i) Perylene_____

10101050101010105010101010501010201010]

10101010101010

uuuuuuuuuuuuuuuuuuuJuuuuuuu

(1) - Cannot be a rated from Diphenylamine

FORM I SV-2 OLM03.0

1730 Strand Associates, Inc91 OW.Wingra DriveMadison, Wl 53715

(608) 251-4843

Wisconsin DNR Certified Lab No. 113138410

Laboratory Results ReportThursday, July 18,1996

Tina Shipley Purchase Order or Job No.: 5038H. E. S. Inc.525 Science DriveMadison, Wl 53711 Samples Received On: 7/12/96 at 1310

Samples received on ice? Yes

Sample 4455 Aeration Test 1No.

Biochemical Oxygen DemandNitrogen, Ammonia

Sample From 7/11/96 EndingTaken: to 7/11/96 at:

<2

<0.20

1700 (Grab)

mg/Lmg/L

Comments:None.

horized for Release Date

Attachments;

STRANDASSOCIATES INC

ORGANIC ANALYSIS DATA SHEET PESTICIDE / PCB'S

Laboratory Name: HES, Inc.Client: SverdrupMatrix: WATER

Date Received: 7/12/96Date Extracted/Prepared: 7/15/96Date Analyzed: 7/17/96

Client Sample NameAERATION TEST 1

Laboratory Sample Name60700303

GPC Cleanup: NOConcentration: LOWMoisture: 0.00 %Moist C. F.: 1.000

GAS Number Compound Resultsjig/L

DilutionFactor

319-84-6 Alpha-BHC < 0.05358-89-9 Gamma-BHC (Lindane) < 0.05376-44-8 Heptachlor < 0.053

959-98-8 Endosulfan I < 0.05360-57-1 Dieldrin < 0.1172-20-8 Endrin < 0.1172-54-8 4,4'-DDD < 0.1150-29-3 4,4'-DDT < 0.11

319-85-7 Beta-BHC < 0.053319-86-8 Delta-BHC < 0.053309-00-2 Aldrin < 0.053

1024-57-3 H. Epoxide < 0.05356641-38-4 Gamma-cnlordane < 0.05356534-02-2 Alpha-chlordane < 0.053

72-55-9 4,4'-DDE < 0.1133213-65-9 Endosulfan II < 0.117421-93-4 Endrin Aldehyde < 0.111031-07-8 Endosulfan Sulfate < 0.118001-35-2 Toxaphene < 5.3

N.A. Aroclor 1016 < 1.1N.A. Aroclor 1221 < 2.1N.A. Aroclor 1232 < 1.1N.A. Aroclor 1242 < 1.1N.A. Aroclor 1248 < 1.1N.A. Aroclor 1254 < 1.1N.A. Aroclor 1260 < 1.1

N.A. = Not Available V = Volume of sample extracted (L)Vm = Volume of extract injected on megabore (ul)T = Volume of total extract (ml)

V: 0.950 Vm: 2.00 T: 10.0

HES, Inc.Sample Analysis Report

Method: 624 GC/MS

CLIENT NAMECLIENT ID

HES IDDATE SAMPLED

DATE RECEIVEDDATE ANALYZED

SVERDRUPAERATION TEST6070030307/11/9607/12/9607/12/96

FILE NAME: 607CA109.D

COMPOUND

C010 ChloromethaneC01S BromomethaneC020 Vinyl ChlorideC025 ChloroethaneC290 TrichlorofluoromethaoeC392 AcroleinC030 Methylene ChlorideC045 1,1-DlchloroetheneC396 AcrylonitrileC050 1,1-DichloroethaneC055 tram 1,2-DlchloroetheneC060 ChloroformC065 1,2-DichloroethaneCHS 1,1,1-TrichloroethaneC120 Carbon TetrachlorideC130 BromodichloromethaneC140 1,2-DichloropropaneC17S 2-Chloroethyl Vinyl EtherC143 cii-l,3-DichloropropeneC150 TrichloroetheneC165 BenzeneC155 DibromochloromethaneC172 Trans-l,3-DichloropropeneC160 l,U-TrichloroethaneC220 TetrachloroetheneC230 TolueneC235 ChlorobenzeneC240 EthylbenzeneC180 BromoformC225 1,1.2,2-TetrachloroethaneC422 1,3-DlchlorobenzeneC426 1,4-DlchlorobenzeneC430 1,2-Dichlorobenzene

REPORTMDL LOQ CONC.ug/L ug/L ug/L QUALIFIER

0.80.50.70.70.476.00.70.832.00.71.01.10.90.70.90.80.98.20.31.00.60.80.21.10.80.30.80.90.80.80.60.60.8

2.51.62.22.21.3

241.82.22.5

101.82.23.23.52.92.22.92.52.926.11.03.21.92.50.63.52.51.02.52.92.52.51.91.92.5

<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL<MDL

Y: Concentration between the MDL and LOQ.E: Concentration above ICAL range.B: Compound present in the-associated blank.D: Concentration determined from a diluted analysis

Page -1


CLIENT IDHESID

DATE SAMPLEDDATE RECEIVED

DATE ANALYZED

2nd RUN: AERATION TEST-16040030107/12/9607/15/96 1,4-DICHLOROBUTANE:07/15/96

Surrogate Recoveries111%


1,1,1-TRICHLOROETHANE1,U-TRICHLOROETHANE


0.290.15

0.910.47

<LOD<LOD

FLAGS : B - analyte found in blank above LOD (Limit of Detection)Y - Compound Concentration Value between LOD and LOQ (Limit of Quantitadon)E - concentration exceeds the calibration rangeD - concentration determined from a diluted analysis

Page - 2


CLIENT ID: PLANT EFFLUENT, DAY 1HESID: 60700474

DATE SAMPLED: 07/167%DATE RECEIVED: 07/18/96

DATE ANALYZED: 07/18/96

Surrogate Recoveries1,4-DICHLOROBUTANE:

FLUOROBENZENE:97%91%

COMPOUNDPID Detector

METHYL-TERT-BUTYL-ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETA-& PARA-XYLENEORTHO-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENE1,3,5-TRIMETHYLBENZENETERT-BUTYLBENZENE1A4-TRIMETHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE


0.280.150.140.130.180.160.310.130.170.160.180.160.190.130.180.180.200.35

0.880.480.440.410.570.500.980.410.540.510.560.510.620.400.580.570.641.1

0.74<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD

0.19<LOD<LOD<LOD<LOD

Y

B(0.15)Y

FLAGS : B - analyte found in blank above LOD (Limit of Detection)Y • Compound Conoentration Value between LOD and LOQ (Limit of Quantitation)E - concentration exceeds the calibration rangeD - concentration determined from a diluted analyin

Page -1


CLIENT ID: PLANT EFFLUENT, DAY 1HESD): 60700474

DATE SAMPLED: 07/16/96 Surrogate RecoveriesDATE RECEIVED: 07/18/96

DATE ANALYZED: 07/18/961,4-DICHLOROBUTANE:



DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORIDEBROMOMETHANECHLOROETHANETRICHLOROFLUOROMETHANE1,1-DICHLOROETHENEMETHYLENE CHLORIDETRANS-U-DICHLOROETHENE1,1-DICHLOROETHANE2,2-DICHLOROPROPANECIS-U-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1,1,1-TRICHLOROETHANE1,1-DICHLOROPROPENECARBON TETRACHLORIDEU-DICHLOROETHANETRICHLOROETHENE1,2-DICHLOROPROPANEBROMODICHLOROMETHANEDIBROMOMETHANECIS 1J-DICHLOROPROPENETRANS IJ-DICHLOROPROPENEl.U-TRICHLOROETHANE13-DICHLOROPROPANEDIBROMOCHLOROMETHANEU-DIBROMOETHANECHLOROBENZENEU,U-TETRACHLOROETHANEBROMOFORMUA2-TETRACHLOROETHANE1A3-TRICHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENE1J-DICHLOROBENZENE1,4-DICHLOROBENZENE . .U-DICHLOROBENZENEU-DIBROMO-3-CHLOROPROPANEU,4-TRICHLOROBENZENEHEXACHLOROBUTADIENE1,23-TRICHLOROBENZENE


0310.230.190.420.260.460.410.270310350.260.170.180.220.290.260.320.130.160.200.320.290.130.100.150350.480.300.130.210.470.260.160.220.200.230.230.260.260.470.180.270.25

0.990.750.6213

0.821.513

0.851.01.1

0.840.530.560.700.910.831.0

0.410.520.651.0

0.920.410.330.471.11.5

0.970.410.671.5

0.840.500.710.630.730.720.820.821.5

0.590.860.78

<LOD0.76

<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD

0.4S<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD

B(0.39)

Y

FLAGS: B-analyte found in blank above LOD (Limit of Detection)Y • Compound Concentration Value between LOD and LOQ (Limit of Quantitation)E - oonoeotntioo exoeedi the calibration rangeD - concentration determined from a diluted analyiii

Page-1



DATE SAMPLED: 07/17/96DATE RECEIVED: 07/18/96


Sitrmonti* Recoveries1,4-DICHLORC«UTANE:


COMPOUNDHallDetoctor

DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORIDEBROMOMETHANECHLOROETHANETRICHLOROFLUOROMETHANE1,1-DICHLOROETHENEMETHYLENE CHLORIDETRANS-IJ-DICHLOROETHENE1,1-DICHLOROETHANEW-DICHLOROPROPANECIS-14-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1,1,1-TRICHLOROETHANE1,1-DICHLOROPROPENECARBON TETRACHLORIDE1,2-DICHLOROETHANETRICHLOROETHENEU-DICHLOROPROPANEBROMODICHLOROMETHANEDIBROMOMETHANECIS 13-DICHLOROPROPENETRANS 13-DICHLOROPROPENEI.IO-TRICHLOROETHANE1J-DICHLOROPROPANEDIBROMOCHLOROMETHANEU-DIBROMOETHANECHLOROBENZENE1,1,10-TETRACHLOROETHANEBROMOFORM1.1JJ-TETRACHLOROETHANE1,23-TRICHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENE13-DICHLOROBENZENE1,4-DICHLOROBENZENE1,2-DICHLOROBENZENE1.2-DIBROMO-3-CHLOROPROPANE1A4-TRICHLOROBENZENEHEXACHLOROBUTADIENE1.2J-TR1CHLOROBENZENE

REPORTLOD LOQ CONC.

(ug/L) (ug/L) (ug/L) FLAGS

0.310.230.190.420.260.460.410.2703103S0.260.170.180^20^90^60320.130.16OJ200320.290.130.100.150330.480300.130.210.470^60.160^20^00.230^30260^60.470.180.27025

0.990.750.6213

0.821.513

0.851.01.1

0.840.530.560.700.910.831.0

0.410.520.651.0

0.920.410.330.471.11.5

0.970.410.671.5

0.840.500.710.630.730.720.820.821.5

0.590.860.78

<LOD0.55

<LOD<LOD<LOD<LOD<LOD<LOD<LOD

0.44<LOD

0^2<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOO<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD

B(0.39)Y

Y

Y

FLAGS: B-Mwlyte found in bbdk above LOD (Limit of Detection)Y - Compound Coooeatntioo Value betweea IOD md LOQ (Limit of QuMtitatioa)E • concentration emeedi the o«libr»tkx> rangeD • ooooeutratioodetennined from » diluted mtlyiii

Page-2


CLIENT ID:HESID:


DATE ANALYZED:

PLANT EFFLUENT, DAY 26070047507/17/96 Surrogate RcCOYCHCS07/18/9607/18/96

1.4-DICHLOROBUTANE:FLUOROBENZENE:

103%90%


METHYL-TERT-BUTYL-ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETA- * PARA-XYLENEORTHO-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENE133-TRIMETHYLBENZENETERT-BUTYLBENZENE1,2,4-TRIMETHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE

REPORTLOD LOQ CONC.(ug/L) (US/L) (u«/L) FLAGS

0.280.150.140.130.180.160.310.130.170.160.180.160.190.130.180.180.200.35

0.880.480.440.410.570.500.980.410.540.510.560.510.620.400.580.570.641.1

<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD

OJO<LOD<LOD<LOD<LOD

B(0.1J)Y

FLAGS: B-«ndyte food mbUnkibove LOD (Limit of Detection)V . Compound Concentration Vitoe between LOD «td LOQ (Limit of QutntiUtion)E - concentration exooedi the o*libntioa rangeD • oonoenlration determiaad from • diluted uilyiii

Page -1


CLIENT ID:HESID:


DATE ANALYZED:

WATER TREATMENT PLANT, DAY 36070053707/18/96 Surrogate Recoveries07/19/9607/20/96

1,4-DICHLOROBUTANE:FLUOROBENZENE:

97%104H


DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORmEBROMOMETHANECHLOROETHANETRICHLOROFLUOROMETHANEU-DICHLOROETHENEMETHYLENE CHLORIDETRANS-U-DICHLOROETHENE1,1-DICHLOROETHANE2,2-DICHLOROPROPANECIS-U-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1,1,1-TRICHLOROETHANE1,1-DICHLOROPROPENECARBON TETRACHLORIDEU-DICHLOROETHANETR1CHLOROETHENEU-DICHLOROPROPANEBROMODICHLOROMETHANED1BROMOMETHANECIS 1J-DICHLOROPROPENETRANS 13-DICHLOROPROPENE1,U-TRICHLOROETHANEU-DICHLOROPROPANEDIBROMOCHLOROMETHANE1,2-DIBROMOETHANECHLOROBENZENE1.1,1 0-TETRACHLOROETHANEBROMOFORM1.1A2-TETRACHLOROETHANEU3-TRICHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENE13-DICHLOROBENZENE1,4-DICHLOROBENZENEU-DICHLOROBENZENE1.2-DIBROMO-3-CHLOROPROPANE1A4-TRICHLOROBENZENEHEXACHLOROBUTADIENE1A3-TRICHLOROBENZENE

REPORTLOD LOQ CONC.(ug/L) (ug/L) (ug/L)

0.310.230.190.420.260.460.410.270.310.350.260.170.180.220.290.260.320.130.160.200.320.290.130.100.1S0350.480.300.130.210.470^60.160720.200230.230.26Q260.470.180.270^5

0.990.750.6213

0.821.513

0.851.01.1

0.840.530.560.700.910.831.0

0.410.520.651.0

0.920.410.330.471.11.5

0.970.410.671.5

0.840.500.710.630.730.720.820.821.5

0.590.860.78

<LOD0.43

<LOD<LOD<LOD<LOD

0.71<LOD<LOD

0.61<LOD

0.74<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD

FLAGS

B(0.43)Y

Y

Y

FLAGS: B - twlyte found in blank above LOD aimit of Detection)Y - Compound Concentration Vtlne between LOD nd LOQ (Limit of Quirtititioo)E - oonoentntioo exoeedi the o«libntion rangeD - oonoentntion determined from • diluted toalyni

Page-2


CLIENT ID: WATER TREATMENT PLANT, DAY 3HESID: 60700537

DATE SAMPLED: 07/18/96DATE RECEIVED : 07/19/96 1,4-DICHLOROBUTANE:

DATE ANALYZED: 07/20/96 FLUOROBENZENE:97%104%


METHYL-TERT-BUTYL-ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETA- A PARA-XYLENEORTHO-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENE1,3,5-TRIMETHYLBENZENETERT-BUTYLBENZENEU,4-TRIMETHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE

REPORTLOD LOQ CONC.


0.280.150.140.130.180.160.310.130.170.160.180.160.190.130.180.180.200.35

0.880.480.440.410.570.500.980.410.540.510.560.510.620.400.580.570.641.1

<LOD<LOD<LOD

0.24<LOD<LOD<LOD

0.16<LOD<LOD<LOD<LOD<LOD


Y

Y

B(0.1J)Y

FLAGS: B-uuJyte found in blank above LOD (LJmh of Detection)Y - Compound Concentration Value between LOD and LOQ (Limit of Quantitation)E - concentration exoeedb the calibration rangeD - concentration determined from a diluted anatyiii

Page -1


CLIENT ID: PLANT EFFLUENT,DAY4HESID: 60700540




FLUOROBENZENE:94%99*


DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORIDEBROMOMETHANECHLOROETHANETRICHLOROFLUOROMETHANE1,1-DICHLOROETHENEMETHYLENE CHLORIDETRANS-U-DICHLOROETHENE1,1-DICHLOROETHANE2,2-DICHLOROPROPANECIS-U-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1,1,1-TRICHLOROETHANE1,1-DICHLOROPROPENECARBON TETRACHLORIDEU-DICHLOROETHANETRICHLOROETHENEU-DICHLOROPROPANEBROMODICHLOROMETHANEDIBROMOMETHANECIS 13-DICHLOROPROPENETRANS 13-DICHLOROPROPENE1.U-TRICHLOROETHANE13-DICHLOROPROPANEDIBROMOCHLOROMETHANEU-DIBROMOETHANECHLOROBENZENE1,1,10-TETRACHLOROETHANEBROMOFORM1.1A2-TETRACHLOROETHANEU3-TRICHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENE13-DICHLOROBENZENE1,4-DICHLOROBENZENEU-DICHLOROBENZENEU-DIBROMO-3-CHLOROPROPANE1A4-TRICHLOROBENZENEHEXACHLOROBUTADIENE1,23-TRICHLOROBENZENE

REPORTLOD LOQ CONC.


0.310.230.190.420.260.460.410.270.310.350.260.170.180.220.290.260.320.130.160.200.320.290.130.100.150350.480300.130.210.470.260.160.220.200.230.230.260.260.470.180.270.25

0.990.750.621.3

0.821.513

0.851.01.1

0.840.530.560.700.910.831.0

0.410.520.651.0

0.920.410.330.471.11.5

0.970.410.671.5

0.840.500.710.630.730.720.820.821.5

0.590.860.78

<LOD0.58

<LOD<LOD<LOD<LOD<LOD

032<LOD

0.73<LOD

0.82<LOD<LOD

0.48<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD

Y

B(0.59)Y

Y

Y

FLAGS: B-analyte found m blank above LOD (Limit of Detection)Y - Compound Concentration Value between LOD and LOQ (Limit of Quantitation)E - concentration exceedi the calibration rangeD • concentration determined from a diluted analyiii

Page - 2


CLIENT ID:HESID:


DATE ANALYZED:

PLANT EFFLUENTJIAY46070054007/19/9607/23/9607/24/96

Surrogate Recoveries1.4-DICHLOROBUTANE:



METHYL-TERT-BUTYL-ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETA- A PARA-XYLENEORTHO-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENEU.5-TRIMETHYLBENZENETERT-BUTYLBENZENE1A4-TRIMETHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE


0.280.150.140.130.180.160.310.130.170.160.180.160.190.130.180.180.200.35

0.880.480.440.410.570.500.980.410.540.510.560.510.620.400.580.570.641.1

<LOD<LOD<LOD

0.22<LOD<LOD<LOD


0.22<LOD<LOD<LOD<LOO

Y

Y

B(0.16)Y

FLAGS : B • tnalyte found in blank above LOD (Limit of Detection)Y - Compound Concentration Value between LOD and LOQ (Limit of QuanUtation)E - concentration exceeds the calibration rangeD - concentration determined from a diluted analytii

Page -1


CLIENT ID:HESID:


DATE ANALYZED:

PLANT EFFLUENTJ>AY 56070054307/20/9607/23/9607/24/96




DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORIDEBROMOMETHANECHLOROETHANETRICHLOROFLUOROMETHANE1,1-DICHLOROETHENEMETHYLENE CHLORIDETRANS-U-DICHLOROETHENE1,1-DICHLOROETHANE2,2-DICHLOROPROPANECIS-U-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1,1,1-TRICHLOROETHANE1,1-DICHLOROPROPENECARBON TETRACHLORIDEU-DICHLOROETHANETRICHLOROETHENEU-DICHLOROPROPANEBROMODICHLOROMETHANEDIBROMOMETHANECIS 13-DICHLOROPROPENETRANS 13-DICHLOROPROPENE1,1,2-TRICHLOROETHANEU-DICHLOROPROPANEDIBROMOCHLOROMETHANEU-DIBROMOETHANECHLOROBENZENE1,1,U-TETRACHLOROETHANEBROMOFORM1.U.2-TETRACHLOROETHANEU3-TRICHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENEU-DICHLOROBENZENE1,4-DICHLOROBENZENEU-DICHLOROBENZENEU-DIBROMO-3-CHLOROPROPANEU,4-TRICHLOROBENZENEHEXACHLOROBUTADIENE1,23-TRICHLOROBENZENE

REPORTLOD LOQ CONC.

(ug/L) (ufe/L) (ug/L) FLAGS

0.310.230.190.420.260.460.410.270.310.350.260.170.180.220.290.260.320.130.160.200.320.290.130.100.150.350.480.300.130.210.470.260.160.220.200.230.230.260.260.470.180270.25

0.990.750.621.3

0.821.51.3

0.851.01.1

0.840.530.560.700.910.831.0

0.410.520.651.0

0.920.410.330.471.11.5

0.970.410.671.5

0.840.500.710.630.730.720.820.821.5

0.590.860.78

<LOD0.52


0.30<LOD

0.62<LOD

0.76<LOD<LOD036

<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD•«LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD

Y

B(0.59)Y

Y

Y

FLAGS: B-analyte found in blank above LOD (Limit of Detection)Y - Compound Concentration Value between LOD and LOQ (Limit of Quantiution)E - concentration exceedt the calibration rangeD - concentration determined from a diluted analyiu

Page - 2


CLIENT ID:HESO):


DATE ANALYZED:

PLANT EFFLUENT4)AY 56070054307/20/9607/23/9601/24/96

Surrogate Recoveries1,4-D1CHLOROBUTANE:



METHYL-TERT-BUTYL-ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETA- A PARA-XYLENEORTHO-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENE1,3,5-TRIMETHYLBENZENETERT-BUTYLBENZENEU.4-TRIMETHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE

REPORTLOD LOQ CONC.


0.280.150.140.130.180.160.310.130.170.160.180.160.190.130.180.180.200.35

0.880.480.440.410.570.500.980.410.540.510.560.510.620.400.580.570.641.1

<LOD<LOD

0.140.42

<LOD<LOD

0.430.25



Y

YY

B(0.16)Y

FLAGS : B - analyte found in blank above LOD (Limit of Detection)Y - Compound Conoeattation Value between LOD and LOQ (Limit of QuaaliUtion)E - concentration exoeedi the calibration rangeD - concentration determined from a diluted anaryiu

Page -1


CLIENT ID:HESID:


DATE ANALYZED:

PLANT EFFLUEPOVDAY 66070054407/21/9607/23/9607/24/96




DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORIDEBROMOMETHANECHLOROETHANETRICHLOROFLUOROMETHANE1,1-DICHLOROETHENEMETHYLENE CHLORIDETRANS-1.2-DICHLOROETHENE1,1-DICHLOROETHANE2,2-DICHLOROPROPANECIS-U-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1,1,1-TRlCHLOROETHANE1,1-DICHLOROPROPENECARBON TETRACHLORIDEU-DICHLOROETHANETRICHLOROETHENEU-DICHLOROPROPANEBROMODICHLOROMETHANEDIBROMOMETHANECIS 13-DICHLOROPROPENETRANS 1J-DICHLOROPROPENEl.U-TRICHLOROETHANEU-DICHLOROPROPANEDIBROMOCHLOROMETHANE1,2-DIBROMOETHANECHLOROBENZENE1,1,1,2-TETRACHLOROETHANEBROMOFORM1,1,2,2-TETRACHLOROETHANE1,2,3-TRICHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENE1J-DICHLOROBENZENE1,4-DICHLOROBENZENEU-DICHLOROBENZENEU-DIBROMO-3-CHLOROPROPANEU.4-TRICHLOROBENZENEHEXACHLOROBUTADIENE1,23-TRlCHLOROBENZENE

REPORTLOD LOQ CONC.


0.310.230.190.420.260.460.410.270.310.350.260.170.180.220.290.260.320.130.160.200.320.290.130.100.150.350.480.300.130.210.470.260.160.220.200.230.230.260.260.470.180.270.25

0.990.750.621.3

0.821.51.3

0.851.01.1

0.840.530.560.700.910.831.0

0.410.520.651.0

0.920.410.330.471.11.5

0.970.410.671.5

0.840.500.710.630.730.720.820.821.5

0.590.860.78

<LOD0.53


030<LOD

O.S2<LOD

0.67<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD

. <LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD

Y

B(0.59)Y

Y

FLAGS : B • tnjjyte found in blank «bove LOD (Limit of Detection)Y - Compound Concentration Viloe between LOD «nd LOQ (Limit of QumtiUtion)E - concentralion exceedi the calibration rangeD - concentration determined from • diluted uulyiu

Page - 2


CLIENT ID: PLANT EFFLUENT,DAY 6HESED: 60700544






METHYL-TERT-BUTYL-ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETA- A PARA-XYLENEORTHO-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENEU.S-TRIMETHYLBENZENETERT-BUTYLBENZENE1,2,4-TRIMETHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE

REPORTLOD LOQ CONC.(ug/L) (vg/L) (ug/L) FLAGS

0.280.150.140.130.180.160310.130.170.160.180.160.190.130.180.180.200.35

0.880.480.440.410.570.500.980.410.540.510.560.510.620.400.580.570.641.1

<LOD<LOD<LOD

0.28<LOD<LOD<LOD


0.28<LOO<LOD<LOD<LOD

Y

Y

B(0.16)Y

FLAGS : B - analyte found in blink above LOD (Limit of Detection)Y - Compound Conoentntion Value between LOD and LOQ (Limit of Quantitttion)E - Conoentntion exoeedi the calibration rangeD - concentration determined from a diluted anaJyiii

Page -1



DATE SAMPLED: 07/22/9607/23/9607/24/96

DATE RECEIVED:DATE ANALYZED:




DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORIDEBROMOMETHANECHLOROETHANETRICHLOROFLUOROMETHANE1,1-DICHLOROETHENEMETHYLENE CHLORIDETRANS-U-DICHLOROETHENE1,1-DICHLOROETHANE2,2-DICHLOROPROPANECIS-14-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1,1,1-TRICHLOROETHANE1,1-DICHLOROPROPENECARBON TETRACHLORIDEU-DICHLOROETHANETRICHLOROETHENEU-DICHLOROPROPANEBROMODICHLOROMETHANEDIBROMOMETHANECIS 13-DICHLOROPROPENETRANS 1,3-DICHLOROPROPENE1,1,2-TRICHLOROETHANEM-DICHLOROPROPANEDIBROMOCHLOROMETHANEU-DIBROMOETHANECHLOROBENZENE1,1,1,2-TETRACHLOROETHANEBROMOFORM1,1^2-TETRACHLOROETHANEU3-TRICHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENEU-DICHLOROBENZENE1,4-DICHLOROBENZENE1,2-DICHLOROBENZENEU-DIBROMO-3-CHLOROPROPANE1A4-TRICHLOROBENZENEHEXACHLOROBUTADIENE1^3-TRICHLOROBENZENE


0.310.230.190.420.260.460.410.270.310.350.260.170.180.220.290.260.320.130.160.200.320.290.130.100.150.350.480.300.130.210.470.260.160.220.200.230.230.260.260.470.180.270.25

0.990.750.621.3

0.821.513

0.851.01.1

0.840.530.560.700.910.831.0

0.410.520.651.0

0.920.410.330.471.11.5

0.970.410.671.5

0.840.500.710.630.730.720.820.821.5

0.590.860.78

<LOD0.46


0.33<LOD

0.72<LOD

0.93<LOD<LOD

0-34<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD

Y

B(0.59)Y

Y

Y

FLAGS: B-«ulyle found in bUnk above LOD (Limit of Detection)Y - Compound Concentration Value between LOD and LOQ (LimH of QumtiUtion)E - concentration exoeedi the calibration rangeD - concentration determined from • diluted tiulyiU

Page - 2


CLIENT ID: PLANT EFFLUENT.DAY7HESID: 60700541





COMPOUNDFID Detector

METHYL-TERT-BUTYL-ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETA- & PARA-XYLENEORTHO-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENE1J,5-TRIMETHYLBENZENETERT-BUTYLBENZENEU.4-TRIMETHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE

REPORTLOD LOQ CONC.


0.280.150.140.130.180.160.310.130.170.160.180.160.190.130.180.180.200.35

0.880.480.440.410.570.500.980.410.540.510.560.510.620.400.580.570.641.1

<LOD<LOD<LOD

0.32<LOD<LOD

0.310.20


033<LOD<LOD<LOD<LOD

Y

YY

B(0.16)Y

FLAGS : B - analyte found in blank above LOD (Limit of Detection)Y - Compound Concentration Value between LOD and LOQ (Limit of Quantitation)E - concentration exceed* the calibration rangeD - concentration determined from a diluted analyiii

Page -1

Volatfle Organic Compounds Analysis ReportWater Analysis by SW-846 Method 8021

CLIENT ID: PLANT INFLUENT,DAY 8HESID: 60700557


DATE ANALYZED: 07/247%

Surroeate Recoveries1,4-DICHLOROBUTANE:



DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORIDEBROMOMETHANECHLOROETHANETRICHLOROFLUOROMETHANE1.1-DICHLOROETHENEMETHYLENE CHLORIDETRANS-1,2-DICHLOROETHENE1,1-DICHLOROETHANE2J-DICHLOROPROPANECIS-U-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1,1,1-TRICHLOROETHANE1,1-DICHLOROPROPENECARBON TETRACHLORIDEU-DICHLOROETHANETRICHLOROETHENE1,2-DICHLOROPROPANEBROMODICHLOROMETHANEDIBROMOMETHANECIS 13-DICHLOROPROPENETRANS 1,3-DICHLOROPROPENE1,U-TRICHLOROETHANE13-DICHLOROPROPANEDIBROMOCHLOROMETHANEU-DIBROMOETHANECHLOROBENZENE1,1,1 a-TETRACHLOROETHANEBROMOFORMUA2-TETRACHLOROETHANE14,3-TRICHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENEM-DICHLOROBENZENE1,4-DICHLOROBENZENE1,2-DICHLOROBENZENEU-DIBROMO-3-CHLOROPROPANE14,4-TRICHLOROBENZENEHEXACHLOROBUTADIENE1A3-TRICHLOROBENZENE


0.310.230.190.420.260.460.410.270.310.350.260.170.180.220.570.260.320.130.160.200.320.290.130.100.150.350.480.300.130210.470.260.160.220.200.230.230.260.260.470.180.270.25

0.990.750.621.3

0.821.51.3

0.851.01.1

0.840.530.560.701.80.831.0

0.410.520.651.0

0.920.410.330.471.11.5

0.970.410.671.5

0.840.500.710.630.730.720.820.821.5

0.590.860.78

<LODOJ4

<LOD<LOD

23<LOD

2.70.31

<LOD17

<LOD11

<LOD<LOD

49<LOD<LOD

0.173.8

<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD

y

B(0.59)Y

Y

FLAGS : B - uuUyte found in blank •bow LOD (Limit of Detection)Y - Compound ConoentnUion Vahie between LOD and LOQ (Limh of Quanlitition)E - concentration exoeedi the calibration rangeD - concentration determined from * diluted malyiis

Page - 2


CLIENT ID: PLANT INFLUENT J)AY 8HESED: 60700557






METHYL-TERT-BUTYL-ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETA- A PARA-XYLENEORTHO-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENEU^-TRIMETHYLBENZENETERT-BUTYLBENZENE1,2,4-TRIMETHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE


0.280.150.140.130.180.160.310.130.170.160.180.160.190.130.180.180.200.35

0.880.480.440.410.570.500.980.410.540.510.560.510.620.400.580.570.641.1



B(0.16)Y

FLAGS : B - analyte found in blank above LOD (Limit of Detention)Y - Compound Concentration Value between LOD and LOQ (Limit of Quantitation)E - concentration exoeedi the calibration rangeD - concentration determined from a diluted analyiii

Page -1


CLIENT ID:HESID:


DATE ANALYZED:

PLANT EFFLUENTJDAY 86070055807/23/9607/24/9607/24/96




DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORIDEBROMOMETHANECHLOROETHANETRICHLOROFLUOROMETHANE1,1-DICHLOROETHENEMETHYLENE CHLORIDETRANS-10-DICHLOROETHENE1,1-DICHLOROETHANE2J-DICHLOROPROPANECIS-10-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1,1,1-TRICHLOROETHANE1,1-DICHLOROPROPENECARBON TETRACHLORIDEU-DICHLOROETHANETR1CHLOROETHENEU-DICHLOROPROPANEBROMODICHLOROMETHANEDIBROMOMETHANECIS 13-DICHLOROPROPENETRANS 13-DICHLOROPROPENE1,1,2-TRICHLOROETHANE13-DICHLOROPROPANEDIBROMOCHLOROMETHANE1,2-DIBROMOETHANECHLOROBENZENE1,1,1,2-TETRACHLOROETHANEBROMOFORM1.1A2-TETRACHLOROETHANE1,23-TRICHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENE13-DICHLOROBENZENE1,4-DICHLOROBENZENEU-DICHLOROBENZENEU-DIBROMOh3-CHLOROPROPANE1,2,4-TRICHLOROBENZENEHEXACHLOROBUTADIENE1,23-TRICHLOROBENZENE

REPORTLOD L.OQ CONC.(ug/L) (ug/L) (ug/L) FLAGS

0.310.230.190.420.260.460.410.270.310.350.260.170.180.220.290.260320.130.160.200320.290.130.100.150.350.480.300.130.210.470.260.160.220.200.230.230.260.260.470.180.270.25

0.990.750.6213

0.821.513

0.851.01.1

0.840.530.560.700.910.831.0

0.410.520.651.0

0.920.410.330.471.11.5

0.970.410.671.5

0.840.500.710.630.730.720.820.821.5

0.590.860.78

<LOD039


0.45<LOD


Y

B(O.S9)

Y

Y

FLAGS: B - nalyte found in blink above LOD (Limit of Detection)Y - Compound Conoenlntioo Value between LOD and LOQ (Limit of Qtuntiution)E - oonoentradon exceeds tin oilibntioo nogeD - conoentration detennined firom • diluted tnalyiii

Page - 2


CLIENT ID:HESffi:


DATE ANALYZED:

PLANT EFFLUENT.DAY 86070055807/23/9607124/9607/24/96




METHYL-TERT-BUTYL-ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETA- A PARA-XYLENEORTHO-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENE1,3,5-TRIMETHYLBENZENETERT-BUTYLBENZENE1A4-TRIMETHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE


0.280.150.140.130.180.160.310.130.170.160.180.160.190.130.180.180.20OJ5

0.880.480.440.410.570.500.980.410.540.510.560.510.620.400.580.570.641.1



B(0.16)Y

FLAGS : B - analyte found in blank above LOD (Limit of Detection)Y - Compound Concentration Value between LOD and LOQ (Limit of Quantitation)E - concentration exceeds the calibration rangeD - concentration determined from a diluted analyiii

Page -1








DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORIDEBROMOMETHANECHLOROETHANETRICHLOROFLUOROMETHANE1,1-DlCHLOROETHENEMETHYLENE CHLORIDETRANS-IJ-DICHLOROETHENE1,1-DICHLOROETHANE2,2-DICHLOROPROPANECIS-10-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1,1,1-TRICHLOROETHANE1,1-DICHLOROPROPENECARBON TETRACHLORIDEU-DICHLOROETHANETRICHLOROETHENEU-DICHLOROPROPANEBROMODICHLOROMETHANEDIBROMOMETHANECIS 1J-DICHLOROPROPENETRANS 13-DICHLOROPROPENE1,1,2-TRICHLOROETHANE1,3-DICHLOROPROPANEDIBROMOCHLOROMETHANEU-DIBROMOETHANECHLOROBENZENEU.U-TETRACHLOROETHANEBROMOFORM1,1,2,2-TETRACHLOROETHANE1A3-TRJCHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENE1J-DICHLOROBENZENE1,4-DICHLOROBENZENE1,2-DICHLOROBENZENEl^-DIBROMO-3-CHLOROPROPANEU,4-TRICHLOROBENZENEHEXACHLOROBUTADIENEUJ-TRICHLOROBENZENE

REPORTLOD LOQ CONC.

(ugrt,) (ug/L) (ug/L) FLAGS

0.310.230.190.420.260.460.410.270.310.350.260.170.180.22

_ 0.290.260.320.130.160.200.320.290.130.100.150.350.480.300.130.210.470.260.160.220.200.230.230.260.260.470.180.270.25

0.990.750.6213

0.821.51.3

0.851.01.1

0.840.530.560.700.910.831.0

0.410.520.651.0

0.920.410.330.471.11.5

0.970.410.671.5

0.840.500.710.630.730.720.820.821.5

0.590.860.78

<LOD0.47


0.49<LOD


FLAGS: B-analyte found in blank above LOD (Limit of Detection)Y - Compound Conoentration Value between LOD and LOQ (Limit of Quantitation)E - concentration exaeedi the calibration rangeD - concentration determined from a diluted analytii

Y

B(0.33)

Y

7j H IS E 0 t7 g rrn V ' ; 'JlJ; AUG 02 19961

| tr • ; - • - . . - • • • •

Page - 2


CLIENT ID: PLANT EFFLUENT, DA Y 9HESID: 60700619




FLUOROBENZENE:9JS100%


METHYL-TERT-BUTYL-ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETA- & PARA-XYLENEORTHQ-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENEU.5-TRIMETHYLBENZENETERT-BUTYLBENZENE1A4-TRIMETHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE

REPORTLOD LOQ CONC.(ug/L) (ug/L) (ug/L)

0.280.150.140.130.180.160.310.130.170.160.180.160.190.130.180.180.200.35

0.880.480.440.410.570.500.980.410.540.510.560.510.620.400.580.570.641.1



FLAGS

B(0.27)Y

FLAGS: B - analyte found in blank above LOD (Limit of Detection)Y - Compound Concentration Value between LOD and LOQ (Limit of Quadtitatiom)E - concentration exoeedi the calibration rangeD - concentration determined from a diluted analyni

OiSi J* (S 1?| AUG

(I0

V

2

1!

199ft"!.:

SVERDSL?

Page-1


CLIENT ID: PLANT EFFLUENT.DAY10HESID: 60700704


DATE ANALYZED: 07/27196




DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORIDEBROMOMETHANECHLOROETHANETRICHLOROFLUOROMETHANE1,1-DICHLOROETHENEMETHYLENE CHLORIDETRANS-1.2-DICHLOROETHENE1,1-DICHLOROETHANE24-DICHLOROPROPANECIS-U-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1,1,1-TRICHLOROETHANE1,1-DICHLOROPROPENECARBON TETRACHLORIDEU-DICHLOROETHANETRICHLOROETHENE1J-DICHLOROPROPANEBROMODICHLOROMETHANEDIBROMOMETHANECIS 13-DICHLOROPROPENETRANS 1,3-DICHLOROPROPENEl.U-TRICHLOROETHANEIJ-DICHLOROPROPANEDIBROMOCHLOROMETHANE1J-DIBROMOETHANECHLOROBENZENEU.U-TETRACHLOROETHANEBROMOFORMUA2-TETRACHLOROETHANE1A3-TRICHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENEU-DICHLOROBENZENE1,4-DICHLOROBENZENE1,2-DICHLOROBENZENEU-DIBROMO-3-CHLOROPROPANE1A4-TRICHLOROBENZENEHEXACHLOROBUTADIENE1A3-TRICHLOROBENZENE

REPORTLOD LOQ CONC(ug/L) (UJ&) (ug/L) FLAGS

0.310.230.190.420.260.460.410.270.310350.260.170.180.220.290.260.320.130.160.200.320.290.130.100.150.350.480.300.130.210.470.260.160.220.200.230.230.260.260.470.180.270.25

0.990.750.621.3

0.821.51.3

0.851.01.1

0.840.530.560.700.910.831.0

0.410.520.651.0

0.920.410.330.471.11.5

0.970.410.671.5

0.840.500.710.630.730.720.820.821.5

0.590.860.78

<LOD0.59


0.44<LOD


Y

8(0.33)

Y

Y

f~ i —

' • : * ( I.FLAGS: B - anatyte foond in blaiUc above LOD (Limit of Detection)

Y - Compound Concentration Value between LOD and LOQ (Limit of Quantitation)E - concentration exceed* the calibration rangeD • concentration determined from a diluted anarytia 02

Page - 2








METHYL-TERT-BUTYL-ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETA- & PARA-XYLENEORTHO-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENE1,3,5-TRIMETHYLBENZENETERT-BUTYLBENZENE1,2,4-TRIMETHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE

REPORTLOD LOQ CONC.

(ug/L) (ugVL) (ug/L) FLAGS

0.280.150.140.130.180.160.310.130.170.160.180.160.190.130.180.180.200.35

0.880.480.440.410.570.500.980.410.540.510.560.510.620.400.580.570.641.1


OJO<LOD<LOD<LOD<LOD

Y

B(0.27)Y

FLAGS : B - tntlyte found in blank above LOD (Limit of Detection)Y - Compound Concentration Value between LOD «od LOQ (Limit of QumliUtion)E - conoentntion exoeedi the calibration rangeD - concentration determined from • diluted analytii

AUBUg

Page-1




DATE ANALYZED: 07/31/961.4-DICHLOROBUTANE:

FLUOROBENZENE:95H101%


DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORIDEBROMOMETHANECHLOROETHANETRICHLOROFLUOROMETHANE1,1-DICHLOROETHENEMETHYLENE CHLORIDETRANS-10-DICHLOROETHENEU-DICHLOROETHANE2O-DICHLOROPROPANECIS-1.2-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1,1,1-TRICHLOROETHANE1,1-DICHLOROPROPENECARBON TETRACHLORTOE1,2-DICHLOROETHANETRICHLOROETHENE1,2-DICHLOROPROPANEBROMODICHLOROMETHANEDIBROMOMETHANECIS 13-DICHLOROPROPENETRANS 13-DICHLOROPROPENEUJ-TRICHLOROETHANE13-DICHLOROPROPANEDIBROMOCHLOROMETHANE1,2-DIBROMOETHANECHLOROBENZENE1,1,10-TETRACHLOROETHANEBROMOFORM14A2-TETRACHLOROETHANE1A3-TRICHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENE13-DICHLOROBENZENE1,44>ICHLOROBENZENE1,2-DICHLOROBENZENBU-DIBROMO-3-CHLOROPROPANEU,4-TRICHLOROBENZENBHEXACHLOROBUTADIENE1,23-TRlCHLOROBENZENE


0.310.230.190.420.260.460.410^7OJ10350.260.170.18OJ220^90^60320.130.160.200320.290.130.100.1 50350.4S0300.130210.470.260.160.220.200^30^30^60^60.470.180.270^5

0.990.750.6213

0.821.513

0.851.01.1

0.840.530.560.700.910.831.0

0.410.520.651.0

0.920.410330.471.11.5

0.970.410.671.5

0.840.500.710.630.730.720.820.821.5

0.590.860.78

<LOD036


0.40<LOD


B(0.44)Y

B(0.44)

Y

Y

FLAGS: B-Mwlyta found in bUnk above LOD (Limit of Detection)Y - Coopoond Concentration Value between LOD nd LOQ (LimhofQMrtiUtioo)E - oofXMatrationexceedi the oalibntioo rangeD - oonoentntion determined from •diluted vudyiii

Page - 2






FLUOROBENZENE:93H101H


METHYL-TERT-BUTYL-ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETA- A PARA-XYLENEORTHO-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENE1,3,5-TRIMETHYLBENZENETERT-BUTYLBENZENE10.4-TRIMETHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE

REPORTLOD LOQ CONC.

(ug/L) (ug/L) (ugfl,) FLAGS

0.280.150.140.130.180.160310.130.170.160.180.160.190.130.180.180.200.35

0.880.480.440.410.570.500.980.410.540.510.560.510.620.400.580.570.641.1



B(0.17)Y

FLAGS: B • analyte found in bbnk above LOD (Limit of Detection)Y • Compound Concentration Vttoe between LOD «nd LOQ (Limit of QumtiUtion)E - concentration exoeedt the calibration rangeD - concentration determined from* diluted natyiii

Page -1


CLIENT ID: PLANT INFLUENT, DAY 12HESID: 60700956






DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORIDEBROMOMETHANECHLOROETHANETRICHLOROFLUOROMETHANE1,1-DICHLOROETHENEMETHYLENE CHLORIDETRANS-14-DICHLOROETHENE1,1-DlCHLOROETHANE2,2-DICHLOROPROPANECIS-U-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1,1,1-TRICHLOROETHANE1,1-DICHLOROPROPENECARBON TETRACHLORIDEU-DICHLOROETHANETRICHLOROETHENEU-DICHLOROPROPANEBROMODICHLOROMETHANEDIBROMOMETHANECIS 1J-DICHLOROPROPENETRANS 13-DICHLOROPROPENEl.U-TRICHLOROETHANE13-DICHLOROPROPANEDIBROMOCHLOROMETHANE1,2-DIBROMOETHANECHLOROBENZENE1,1,10-TETRACHLOROETHANEBROMOFORMl,Ua-TETRACHLOROETHANE1A3-TRICHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENE13-DICHLOROBENZENE1,4-DICHLOROBENZENE14-DICHLOROBENZENEU-DIBROM03-CHLOROPROPANEU.4-TRICHLOROBENZENEHEXACHLOROBUTADIENE1A3-TRICHLOROBENZENE

REPORTLOD LOQ CONC.(ug/L) (ug/L) (u«/L) FLAGS

0.620.470.390.830.510.920.810.540.63'0.710.520330.350.440.570.520.630.260.330.410.640.580.260.210.300.700.960.610260.420.940.530.310.440.400.460.450.520.520.930.370.540.49

2.01.51.22.61.62.92.61.72.0121.71.11.11.41.81.72.00.821.01.32.01.8

0.830.660.94223.11.9

0.82133.01.7

0.991.41.31.51.41.61.63.01.21.71.6

<LOD<LOD<LOD<LOD

2.S<LOD

5.00.55

<LOD19

<LOD13

<LOD<LOD

50<LOD<LOD<LOD

3.9<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD

oB(0.44) D

DDDDD

B(0.44)YDDDDDDDDDDDDDDDDODDDDDDDDDDDDDDDDDDD

FLAGS: B • mtyte found in btak above LOD (Limit of Detection)Y - Confound Concentration Vitae between LOD md LOQ (Limit of QuaatiUtion)E - concentration exceeds the calibration rangeD - oonBentralion determined from • diluted amlyiit

Page - 2


CLIENT ID: PLANT INFLUENT, DAY 12HESID: 60700956






METHYL-TERT-BUTYLr ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETA- & PARA-XYLENEORTHO-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENE1J.S-TRIMETHYLBENZENETERT-BUTYLBENZENE1A4-TRIMETHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE

REPORTLOD LOQ CONC(ug/L) (ug/L) (ug/L)

0.550300.280.260360320.620.260.340320350320390.250360360.400.70

1.80.%0.880.821.11.02.00.831.11.01.11.01.2

0.80\21.11322



FLAGS

DDDDDDDDDDDDD

B<0.17)YDDDDO

FLAGS: B - malyte found in blank above LOD (Limit of Detection)Y - Compound Concentration Value between LOD and LOQ (Limit of Quantitation)E - concentration exceeds the calibration rangeD - oonoentntion determined from • diluted analyiit

Page -1


CLIENT ID : PLANT EFFLUENT, DAY 12HESID: 60700954



Surrooale Recoveries1,4-DICHLOROBUTANE:



DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORIDEBROMOMETHANECHLOROETHANETRICHLOROFLUOROMETHANE1.1-DICHLOROETHENEMETHYLENE CHLORIDETRANS-1,2-DICHLOROETHENE1,1-DICHLOROETHANE24-DICHLOROPROPANECIS-1.2-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1,1,1-TRICHLOROETHANEU-DICHLOROPROPENECARBON TETRACHLORIDElO-DICHLOROETHANETRICHLOROETHENE1O-DICHLOROPROPANEBROMODICHLOROMETHANEDIBROMOMETHANECIS 13-DICHLOROPROPENETRANS 13-DICHLOROPROPENEl.U-TRICHLOROETHANE1J-DICHLOROPROPANEDIBROMOCHLOROMETHANE1,2-DIBROMOETHANECHLOROBENZENE1,1,10-TETRACHLOROETHANEBROMOFORMUA2-TETRACHLOROETHANE1,23-TRICHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENE13-DICHLOROBENZENE1,4-DICHLOROBENZENE1,2-DICHLOROBENZENE1,2-DIBROMO-J-CHLOROPROPANEU.4-TRICHLOROBENZENEHEXACHLOROBUTADIENE1A3-TRICHLOROBENZENE

REPORTLOD LOQ CONC.

(ve/L) (ug/L) (ug/L) FLAGS

0.310.230.190.420.260.460.410.270310350.260.170.180.220290260320.130.160.200320.290.130.100.150350.480300.130.210.470.260.160.220.200230230260260.470.18

' 0.270.25

0.990.750.6213

0.821.513

0.851.01.1

0.840.530.560.700.910.831.0

0.410.520.651.0

0.920.410330.471.11.5

0.970.410.671.5

0.840.500.710.630.730.720.820.821.5

0.590.860.78

<LOD0.47


0.42<LOD


B(0.44)Y

B(0.44)

Y

Y

FLAGS: B-aoalytefoond in blank above LOD (Limit of Deteotion)Y - Compoond Coooertrrtion Value between LOD and LOQ (Limit of QnantiUtion)E - ooooenfntion exceeds the calibration rangeD - ooooeotration determined from a dilated analyiii

Page - 2





Suiromite Recoveries1,4-DICHLOROBUTANE:



METHYL-TERT-BUTYL-ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETAr * PARA-XYLENEORTHO-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENE13,5-TRIMETHYLBENZENETERT-BUTYLBENZENE10,4-TRIMETHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE

REPORTLOD LOQ CONC(ug/L) (ug/L) (ug/L) FLAGS

0.280.150.140.130.180.160310.130.170.160.180.160.190.130.180.180.20035

0.880.480.440.410.570.500.980.410.540.510.560.510.620.400.580.570.641.1

<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOO<LOD<LOD<LOD<LOD


B(0.17)Y

FLAGS: B • nulyto foond in blank above LOD (Limit of Detection)Y - Compound Concentration Value between LOD and LOQ (Limit of QnmtiUtion)E - concentration exoeedi the calibration rangeD - oonoentratioa determined from • diluted *n*lyiii

Page-1


CLIENT H): PLANT EFFLUENT, DAY 13HESID: 60700955


DATE ANALYZED: 07/31/961.4-DICHLOROBUTANE:

FLUOROBENZENE:94%99H


DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORIDEBROMOMETHANECHLOROETHANETRICHLOROFLUOROMETHANE1,1-DICHLOROETHENEMETHYLENE CHLORIDETRANS-1.2-DICHLOROETHENE1,1-DICHLOROETHANE2,2-DICHLOROPROPANECIS-U-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1,1,1-TRICHLOROETHANEU-DICHLOROPROPENECARBON TETRACHLORIDE14-DICHLOROETHANETRICHLOROETHENE1,2-DlCHLOROPROPANEBROMODICHLOROMETHANEDIBROMOMETHANECIS 13-DICHLOROPROPENETRANS 13-DICHLOROPROPENE1.U-TRICHLOROETHANE13-DICHLOROPROPANEDIBROMOCHLOROMETHANEU-DIBROMOETHANECHLOROBENZENE1,1,1 4-TETRACHLOROETHANEBROMOFORM1,1A2-TETRACHLOROETHANE1A3-TRICHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENE13-DICHLOROBENZENE1,4-DICHLOROBENZENEL2-DICHLOROBENZENE1.2-DIBROMO3-CHLOROPROPANE1J.4-TRICHLOROBENZENEHEXACHLOROBUTADIENEU3-TRICHLOROBENZENE

REPORTLOD LOQ CONC

(ug/L) (UB/L) (ua/L) FLAGS

0.310.230.190.420.260.460.410.270310350.260.170.180.220.290.260320.130.160.200320.290.130.100.150350.480300.130.210.470.260.160.220.200.230730260260.470.18021025

0.990.750.6213

0.821.513

0.851.01.1

0.840.530.560.700.910.831.0

0.410.520.651.0

0.920.410330.471.11.5

0.970.410.671.5

0.840.500.710.630.730.720.820.821.5

0.590.860.78

<LOD0.60


0.51<LOD


B(0.44)Y

BC0.44)

Y

FLAGS: B - imtyte found in blink «bovB LOD (Unit of Detection)Y • Compound Concentration Vdne between LOD tod LOQ (Limit of Qu«n»it«tion)E - ooooeotntjoa exoeedi the calibration rangeD - concentration detennined from • diluted analyni

Page-2


CLIENT ED: PLANT EFFLUENT, DAY 13HESED: 60700955



Surrogate Recoveries1.4-D1CHLOROBUTANE:

FLUOROBENZENE:94*99H


METHYL-TERT-BUTYL-ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETA- A PARA-XYLENEORTHO-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENEM3-TRIMETHYLBENZENETERT-BUTYLBENZENEU.4-TRIMETHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE

REPORTLOD LOQ CONC


0.280.1 50.140.130.180.160310.130.170.160.180.160.190.130.180.180.200.35

0.880.480.440.410.570.500.980.410.540.510.560.510.620.400.580.570.641.1



y

B«U7)Y

FLAGS : B - anatyte found in blank above LOD (Limit of Deteotion)Y - Compound Conoentration Value between LOD and LOQ (Limit of Quanlitation)E - oonoentration exceed* the calibration rangeD - concentration dettmined from a diluted analyrif

Page -1


CLIENT ID: PLANT EFFLUENTJUY 14HESID: 60700962





DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORIDEBROMOMETHANECHLOROETHANETRICHLOROFLUOROMETHANE1,1-DICHLOROETHENEMETHYLENE CHLORIDETRANS-IJ-DICHLOROETHENE1,1-DICHLOROETHANE2,2-DICHLOROPROPANECIS-1.2-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1.1,1-TRICHLOROETHANE1,1-DICHLOROPROPENECARBON TETRACHLORJDE1,2-DICHLOROETHANETRICHLOROETHENE1,2-DICHLOROPROPANEBROMODICHLOROMETHANEDIBROMOMETHANECIS 13-DICHLOROPROPENETRANS 13-DICHLOROPROPENE1.U-TRICHLOROETHANE1J-DICHLOROPROPANEDIBROMOCHLOROMETHANE1,2-DIBROMOETHANECHLOROBENZENEU.U-TETRACHLOROETHANEBROMOFORMUA2-TETRACHLOROETHANE1A3-TRICHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENE13-DICHLOROBENZENE1,4-DICHLOROBENZENE1,2-DICHLOROBENZENE1.2-DIBROMO4-CHLOROPROPANE1O.4-TRICHLOROBENZENEHEXACHLOROBUTADIENEU3-TRICHLOROBENZENE

REPORTLOD LOQ CONC(ug/L) (ug/L) (ug/L) FLAGS

0310.230.190.420.260.460.410.270310350.260.170.180.220.290.260320.130.160.200320.290.130.100.150350.480300.130.210.470260.160.220.200.230.230.260^60.470.180.270^5

•0.990.750.6213

0.821.513

0.851.01.1

0.840.530.560.700.910.831.0

0.410.520.651.0

0.920.410.330.471.11.5

0.970.410.671.5

0.840.500.710.630.730.720.820.821.5

0.590.860.78

<LOD1.8



B(0.44)

B(0.44)

Y

FLAGS: B-iMlyte found in MM* above LOD (Limit of Detection)Y • Compound Concentration Vihw between LOD and LOQ (Limit of Quratitation)E - concentration exceed* the calibration rangeD - concentration determined from • diluted malyitf

Page - 2


CLIENT ID: PLANT EFFLUENTJUY 14HESID: 60700962



SurroBftte Recoveries1.4-DICHLOROBUTANE:


COMPOUNDPQ} Detector

METHYL-TERT-BUTYL-ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETA- A PARA-XYLENEORTHO-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENE1,3,5-TRIMETHYLBENZENETERT-BUTYLBENZENEU.4-TR1METHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE

REPORTLOD LOQ CONC.(ug/L) (ug/L) (UR/L) FLAGS

0.280.150.140.130.180.16OJ10.130.170.160.180.160.190.130.180.180.200.35

0.880.480.440.410.570.500.980.410.540.510.560.510.620.400.580.570.641.1



B(0.17)Y

FLAGS: B-«ulyt« found in bUnk«boveUDD (Limit of Detection)Y - Compound Concentration Vahie between LOD and LOQ (Limit of QuantiUtion)E - concentration exoeedi the calibration rangeD - concentration determined from • dilated analyni

Page -1


CLIENT ID: PLANT INFLUENTJDAY15HESBD: 60700964






DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORIDEBROMOMETHANKCHLOROETHANETRICHLOROFLUOROMETHANEU-DICHLOROETHENEMETHYLENE CHLORIDETRANS-1.2-DICHLOROETHENE1,1-DICHLOROETHANEW-DICHLOROPROPANECIS-10-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1,1,1-TRICHLOROETHANE1,1-DICHLOROPROPENECARBON TETRACHLORIDE1,2-DICHLOROETHANETRICHLOROETHENE1,2-DICHLOROPROPANEBROMODICHLOROMETHANEDIBROMOMETHANECIS 13-DICHLOROPROPENETRANS 1J-DICHLOROPROPENE1,14-TRICHLOROETHANE13-DICHLOROPROPANEDIBROMOCHLOROMETHANEU-DIBROMOETHANECHLOROBENZENE1,1,1,2-TETRACHLOROETHANEBROMOFORM1,1A2-TETRACHLOROETHANE1A3-TRICHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENE1J-DICHLOROBENZENE1,4-DICHLOROBENZENE1,2-DICHLOROBENZENE1.2-DIBROMO3-CHLOROPROPANE1O.4-TRICHLOROBENZENEHEXACHLOROBUTADIENE1A3-TRICHLOROBENZENE


0.620.470390.830.510.920.81O.S40.630.710.520.330.350.440.570.520.630.260330.410.640.580.260.210300.700.960.610.260.420.940.530.310.440.400.460.450.520.520.930.370.540.49

2.01.51.22.61.62.92.61.72.02.21.71.11.11.41.81.72.00.821.0132.01.8

0.830.660.942.23.11.9

0.821.33.01.7

0.991.4131.51.41.61.63.0121.71.6

<LOD2.0

<LOD<LOD

2.5<LOD

3.013

<LOD20

<LOD13

<LOD<LOD

53<LOD<LOD<LOD

4.0<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD<LOD

DB(0.44) D

DDDDD

B(0.«4)YDDDD0DDDDDDDDODDDDDDDDDDDDDDDDDDDDDD

FLAGS: B-«Ml)to found in blank ibova LOD (Limit of Detection)Y - Compound Concentration Vilne between LOD and LOQ (Limit of QunHitation)E - ooooentntion exceeds the calibration rangeD - concentration determined froma diluted Mialyni

Page - 2


CLIENT ID: PLANT INFLUENTJDAY15HESID: 60700964



Surrogate Recoveries1,4-D1CHLOROBUTANE:



METHYL-TERT-BUTYL-ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETA- A PARA-XYLENEORTHO-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENE1,3,5-TRIMETHYLBENZENETERT-BUTYLBENZENEU.4-TRIMETHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE


0.550300.280.260360.320.620.260.340320.350.320.390.250360360.400.70

1.80.960.880.821.11.02.0

0.831.11.01.11.01.2

0.80121.11322



DDDDDDDDDDDDD

B(0.17)YDDDDD

FLAGS: B-uulyte found in blank above LOD (Limit of Detection)Y - Compound Concentration Value between LOD and LOQ (Limit of Quantitation)E - concentration exceeds the calibration rangeD - concentration determined from a diluted analyiii

Page -1


CLIENT ID: PLANT EFFLUENT JJAY15HESID: 60700963





DICHLORODIFLUOROMETHANECHLOROMETHANEVINYL CHLORIDEBROMOMETHANECHLOROETHANETRICHLOROFLUOROMETHANE1,1-DICHLOROETHENEMETHYLENE CHLORIDETRANS-l^-DICHLOROETHENE1,1-DICHLOROETHANE2,2-DICHLOROPROPANEC1S-1.2-DICHLOROETHENECHLOROFORMBROMOCHLOROMETHANE1,1,1-TRICHLOROETHANE1,1-DICHLOROPROPENECARBON TETRACHLORIDEU-DICHLOROETHANETRICHLOROETHENE1,2-DICHLOROPROPANEBROMODICHLOROMETHANEDIBROMOMETHANECIS 13-DICHLOROPROPENETRANS 13-DICHLOROPROPENE1,1,2-TRlCHLOROETHANE13-DICHLOROPROPANEDIBROMOCHLOROMETHANE1,2-DIBROMOETHANECHLOROBENZENE1,1,1,2-TETRACHLOROETHANEBROMOFORM1,1A2-TETRACHLOROETHANEU3-TRICHLOROPROPANEBROMOBENZENE2-CHLOROTOLUENE4-CHLOROTOLUENE13-DICHLOROBENZENE1,4-DICHLOROBENZENEU-DICHLOROBENZENE1.2-DIBROMO-3-CHLOROPROPANEU,4-TRICHLOROBENZENEHEXACHLOROBUTADIENE1,23-TRICHLOROBENZENE


0.310.230.190.420.260.460.410.270310350.260.170.180.220.290260.320.130.160.200.320.290.130.100.150.350.480.300.130.210.470.260.160.220.200.230.230.260.260.470.180.270.25

0.990.750.6213

0.82U13

0.851.01.1

0.840.530.560.700.910.831.0

0.410.520.651.0

0.920.410330.471.11.5

0.970.410.671.5

0.840.500.710.630.730.720.820.821.5

0.590.860.78

<LOD13



B(0.44)

B(0.44)

Y

FLAGS: B-malyto found in Mat* above LOD (Limit of Detection)Y - Compound Concentration Value between LOD tad LOQ (Limit of Quanthation)E - concentration exceeds the calibration rangeD - oonoentrationdetenmaedfroniadUutedanalyn*

Page - 2


CLIENT ID: PLANT EFFLDENT,DAY 15HESID: 60700963




FLUOROBENZENE:93%


MBTHYL-TERT-BUTYL-ETHERISOPROPYL ETHERBENZENETOLUENETETRACHLOROETHENEETHYLBENZENEMETA- A PARA-XYLENEORTHO-XYLENESTYRENEISOPROPYLBENZENEN-PROPYLBENZENE1,3,5-TRIMETHYLBENZENETERT-BUTYLBENZENE1A4-TRIMETHYLBENZENESEC-BUTYLBENZENEP-ISOPROPYLTOLUENEN-BUTYLBENZENENAPHTHALENE

REPORTLOD LOQ CONC.


0.280.150.140.130.180.160.310.130.170.160.180.160.190.130.180.18020035

'

0.880.480.440.410.570.500.980.410.540.510.560.510.620.400.580.570.641.1



Y

B(0.17)Y

FLAGS: B - anatyte {band in blank above LOD (Limit of Detection)Y - Compound Concentration Value between LOD and LOQ (Limit of Quantitation)E - concentration exceeds the calibration rangeD - concentration determined from a diluted analysis

malcolm pirnie inc - july 1996 monthly progress report ... · august 9, 1996 mr. pablo n. valentin...

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