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ff 863 July 85
ENGINEERING AND INDUSTRIAL EXPERIMENT STATION
College of Engineering
University of Florida
Gainesville
https://ntrs.nasa.gov/search.jsp?R=19670003665 2020-01-03T17:51:35+00:00Z
A STUDY OF GAS SOLUBILITIES AND TRANSPORT PROPERTIES IN FUEL CELL ELECTROLYTES
Reeearch Grant NGR 10-005-022
Second Semi-Annuel Report
Period Covered: March 1, 1966 - August 31, 1966
Prepared For National Aeronautics and Space Administration
Washington, D . C .
October 7 , 1966
Robert D. Walker, Jr. Principal Investigator
ENGINEERING AND INDUSTRIAL EXPERIMENT STATION
College of Engineering tlniveraity of Florida_ Gaiserrvf 11s , Florida
TABLE OF CONTENTS
LIST OF TAB.S ..................................... LIST OF FIGURES ......................... ......... ABQ.. ...........................................
2 . PHYSICAL PROPERTY MEASUREMENTS FOR POTASSIUM HYDROXIDE SOLUTIONS ........................... 2.1 Materials .................................. 2.2 Density Measurements.. .................... 2.3 Vapor Pressure Measurements ...............
3 . GAS SOLUBILITY IN AQUEOUS KOH SOLUTIONS ........ 3.1 Current Experimental Method ............... 3.2 Solubility of O2 in KOH a t 2 5 O C ...........
4 . THE DIFFUSIVITY OF OXYGEN AND HYDROGEN IN KOH SOLUTIONS .................................
4.1 Experimental .............................. 4.2 Results and Discussion ....................
Notation ................................... 5 . FUTURE PLANS ................................... 6. LITERATURE CITED ...............................
iii
1
3
5
5
5
8
11
11
14
17
17
21
23
24
25
LIST OF TABLES
Table - 1
2
3
4
5
Page
The Effect of KOH Solutions on the Volume of Glass 6 Pycnometers..........,,.,........,...,..,~........
Experimental Measurements for Density of KOH 7 Solutions at 1 Atm, Pressure..~b.....b...,.,......
Vapor Pressure of Aqueous Potassium Hydroxide 9 Solutions....... ..................................
0 Solubility of O2 in KOH at 25 C .................... 14
Comparison of Experimental Results w i t h Values 22 from Literature...............,...,..........,....
ii
LIST OF FIGURES
Figure Page
1 Vapor Pressure of KOH Solutions ................... 10
2 Dissolved Gas Stripper and Concentrator. .......... 13
3 Solubility of Oxygen in Aqueous KOH Solutions ..... 15
4 Schematic Diagram of the Steady'State Diaphragm 18 Diffusion Cell ...................................
iii
ABSTRACT
Work during t h e f i r s t year of t h e g ran t has been concentrated i n
t h r e e a reas : (1) measurement of t h e dens i ty and t h e vapor p re s su re of
KOH s o l u t i o n s , (2 ) development of a method of concent ra t ing d isso lved
gases be fo re a n a l y s i s , and (3) p e r f e c t i o n of a s teady s t a t e diaphragm
ce l l f o r r a p i d measurement of d i f f u s i v i t i e s .
Dens i t ies of KOH so lu t ions up t o about 52 w t . per cent KOH and
0 150 C have been made us ing two techniques.
a b l e from o the r sources is s a t i s f a c t o r y .
explored f o r measurements a t higher temperatures and KOH concent ra t ions .
Agreement with da t a a v a i l -
A modified technique is being
Vapor pressures over KOH s o l u t i o n s have been measured f o r KOH con-
c e n t r a t i o n s up t o about 53 w t . per cent and up t o two atmospheres.
F a i r l y s a t i s f a c t o r y agreement with da t a r epor t ed i n t h e l i t e r a t u r e has
been obta ined , but t h e method used does not appear t o be s u i t a b l e f o r
measurements a t very h igh KOH concent ra t ions and temperatures . Other
techniques a r e being explored.
A method f o r concentrat ing d isso lved gases before a n a l y s i s has
been pe r fec t ed and a few measurements of t h e s o l u b i l i t y of oxygen i n
KOH s o l u t i o n s a t 25 C have been made. These agree q u i t e we l l wi th
ear l ie r da t a a t low KOH concent ra t ions and l i e c l o s e t o a s t r a i g h t
l i n e on a semi-log p l o t of Solubility versus KOH concent ra t ion .
b i l i t y da t a f o r 50 C a l s o g ive a l i n e a r semi-log s o l u b i l i t y versus
0
Solu-
0
concen t r a t ion p l o t . The l i n e s f o r t h e two t,emperatures are p a r a l l e l ,
and t h e s o l u b i l i t y of oxygen in KOH s o l u t i o n s a t 5OoC i s about t h ree -
f o u r t h s a s l a r g e a s t h e s o l u b i l i t y a t 25'C.
2
A new steady state diaphragm cell method has been perfected for
measuring diffusivities. It is capable of yielding reasonably accurate
results rapidly but has not been used to measure the diffusivity of
oxygen or hydrogen so far betause of'the unavailability of accurate
solubility data,
the diffusivity of several hydrocarbons'and C02 i n water, data for which
were available from other workers.
sults was good.
The adequacy of the method was shown by determining
Agreement with earlier reported re-
1. INTRODUCTION
The pauci ty of da t a on the s o l u b i l i t y and d i f f u s i v i t y of gases i n f u e l
c e l l e l e c t r o l y t e s has se r ious ly hindered e s t ima t ion of l i m i t i n g c u r r e n t denei-
t i e s a t f u e l c e l l e l ec t rodes , and i t ’ h a s f u r t h e r i n t e r f e r e d with s t u d i e s
of e l e c t r o d e k i n e t i c s . The p r i n c i p a l work dur ing t h e f i r s t year of th is
grant has been d i r e c t e d toward providing t h i s information.
those da t a which were a v a i l a b l e i n t h e l i t e r a t u r e have been assembled and
To th i e end
c o r r e l a t e d , and methods o f
e l e c t r o l y t e concent ra t ions
d a t a on pe r t inen t phys ica l
a b l e over t h e e n t i r e range
measiirPment which appear t o be s u i t a b l e a t high
and high temperatures have been devised. Since
p rope r t i e s of t h e KOH-H 0 system were not a v a i l -
of concent ra t ion and temperature, it has been
2
necessary t o make many of these measurements.
E a r l i e r work by Gubbins and Walker (Ij showed t h a t boch t h e s o l u b i l i t y
and d i f f u s i v i t y of oxygen i n aqueous KOH s o l u t i o n s decreased sharply as t h e
KOH concent ra t ion increased . I t became c l e a r from t h i s work t h a t accu ra t e
s o l u b i l i t y da t a a t high KOH concent ra t ions would r e q u i r e modi f ica t ion of t h e
techniques used i n t h e e a r l i e r work. Moreover, Tobias ( 2 ) has observed t h a t
d i f f u s i o n may not be t h e r a t e - l i m i t i n g process i n t h e e l e c t r o r e d u c t i o n of
oxygen i n concentrated KOH so lu t ions . Thus, t h e e lec t rochemica l method used
ear l ier f o r de te rmina t ion of the d i f f u s i v i t y of oxygen i n KOH s o l u t i o n s i s
not s u i t a b l e f o r measurements a t high KOH concen t r a t ions .
Another procedure f o r determining gas s o l u b i l i t i e s , e s p e c i a l l y s u i t a b l e
f o r low s o l u b i l i t i e s , has been developed, and a new method f o r measuring gas
d i f f u s i v i t i e s has been devised and t e s t e d . These a r e descr ibed i n d e t a i l i n
t h e appropr i a t e s ec t ions of t h i s r e p o r t , and pe r t inen t da t a a r e presented .
The experimental methods which have been followed i n measuring c e r t a i n physi-
cal properties of t h e KOH-H-0 system a r e a l s o d iscussed , as wel l as d i f f i c u l t i e s L
3
and l i m i t a t i o n s of technique which have been encountered. Pe r t inen t phys ica l
property da t a a r e presented i n both t a b u l a r and graph form.
It appears t h a t t h e pr inc ipa l experimental d i f f i c u l t i e s in t h e meaeure-
ment of gas s o l u b i l i t y and d i f f u s i v i t y have now been overcome, and it i e
expected t h a t t hese da t a can be generated a t a r e l a t i v e l y r a p i d r a t e during
t h e second year of t h e g r a n t .
2 . PHYSICAL PROPERTY MEASUREMENTS FOR POTASSIUM HYDROXIDE SOLUTIONS
2.1 Mate r i a l s
The potassium hydroxide used was Merck reagent grade, and con-
t a ined approximately 1.2% of potassium carbonate . Solu t ione were stand-
a rd ized p e r i o d i c a l l y , and both hydroxide and carbonate con ten t s were
determined. The f i g u r e s given f o r weight percent KOH i n t h e following
sections do not inc lude t h e carbonate impuri ty . The carbonate conten t
of t h e s o l u t i o n s used w a s genera l ly i n t h e range 1.0 t o 1.3% of t o t a l
d i sso lved s o l i d s .
So f a r no a t t e m p t has been made t o f u r t h e r pu r i fy t h e potas-
sium hydroxide s o l u t i o n s . However, f o r c e r t a i n of t h e property measure-
ments tes t determinat ions w i l l be c a r r i e d out i n which carbonate- f ree
s o l u t i o n s w i l l be used.
us ing ion-exchange r e s i n s as descr ibed by Davies and Nancollas (3).
Carbonate removal w i l l probably be e f f e c t e d
2 . 2 Density Measurements
Experimental dens i ty measurements have been made f o r KOH con-
0 . c e n t r a t i o n s i n t h e range 0-52 w t . % f o r temperatures up t o 150 C . Two
d i f f e r e n t measuring procedures have. been used:
a) a Westphal balance method
b ) a pycnometer method
The procedure f o r method ( a ) has been descr ibed i n a previous r e p o r t (4);
dens i ty de te rmina t ions a t temperatures up t o 70 C have been made using
t h i s procedure.
0
I n procedure (b) a g l a s s pycnometer of t h e Lipkin type w a s
used (5). The method was based upon t h e assumption t h a t t h e r a t e of
5
6
corrosion of the glass by KOH would not be so rapid as to invalidate
the results, provided that the pycnometer was frequently recalibrated,
Pycnometers were calibrated using pure distilled mercury.
The purity of the mercury was checked by determining its density at
2SoC, Before a determination the pycnometer was weighed with mercury
at three different levels in the capillary arms, the pycnometer beiag
equilibrated in an oil bath controlled to +0.02°C. The pycnometer
was then cleaned, filled with the sample KOH solution, equilibrated
in the oil bath, and then cooled and reweighed. Finally the pycnometer
was recalibrated using mercury, to check for any possible volume change
due to corrosion. 0 At temperatures up to 90 C no significant changes in volume
were found for the pycnometers before and after a measurement. At the
higher temperatures, however, measurable volume changes occurred dur-
ing an experiment. Table 1 shows measured volumes before and after a
density determination, Since the average of the two calibrations is
.used in calculating the density, the results suggest that the error
due t o volume changes during an experiment should not be greater than
about 3 parts in 10,000,
TABLE 1
THE EFFECT OF KOH SOLUTIONS ON THE VOLUME OF GLASS PYCNOMETERS I I1 111
Temperature no0c llO°C 150°C
Wt % KOH 43.99 52.60 52.60
Pycnometer volume before measurement 5.080 m1.5.038 ml. 5.048
Pycnometer volume after measurement 5.083 5,041 5.056
7
The density measurements are given in Table 2, and are com-
pared with densities reported by the Solvay Process Division of Allied
Chemical Corporation (6). The latter measurements were made using a
hydrometer.
TABLE 2
EXPERIMENTAL MEASUREMENTS FOR DENSITY OF KOH SOLUTIONS AT 1 ATM. PRESSURE
Temperature
3OoC 30 30 30 30
50 50 50 50 50
70 70 70 70 70 70
90 90 90 90 90
110 110 110
150
Wt % KOH
4.40 8.66 17.47 27.08 32.07
4.40 8.66 17.47 27.08 32.07
4.40 8.66 17.47 27.08 32.07 44.02
6.57 10.60 17.32 30.77 44.02
32.40 43.99 52.60
52.60
Method
a a a a a
a a a a a
a a a a a b
b b b b b
b b b
b
Mea s ur e d Dens i ty
1.035 g./ml 1.071 1.159 1.261 1.310
1.026 1.062 1.150 1.250 1.300
1.014 1.049 1.138 1.241 1.289 1.418
1.023 1.055 1.124 1.258 1.398
1.261 1.389 1.492
1.472
Solvay - Values ( 6 )
1.034 g,/ml 1.074 1.. 158 1.253 1.305
1.027 1.065 1.147 1.242 1.294
1.018 1.056 1.137 1.232 1.283 1.413
1.029 1.064 1.126 1.258 1.401
1.265" 1.387" 1.479*
* Extrapolated values
a
2.3 Vapor Pressure Measurements
Experimental vapor pressure measurements have been made for
KOH concentrations in the range 0-53.9 wt, % for vapor pressures up t o
2 atm. (temperatures up to 170 C ) . 0 The measurements were made by a
static isoteniscope method which has been described in detail in a
previous report ( 3 ) .
Table 3 shows the results obtained together with values from
International Critical Tables (denoted "Lit." in Table 3 ) . The experi-
mental results are plotted in Figure 1 as log p vs. T. Results
obtained at constant wt. % KOH fall almost on a straight line when
plotted in this way; the linearity appears to improve somewhat at
higher concentrations of KOH.
For most of the results in Table 3 the agreement between
experimental and literature values is moderately good (within a few
percent). However the measurements of low vapor pressures reported
here are generally several mm, below the literature values, and it
seems likely that a consistent experimental error occurred in the
experimental measurements at low pressures. Also, the measarenents
of vapor pressures above one atmosphere for 53.9 wt. X KOH solutions
were not in agreement with measurements for lower temperatures at
this concentration, and appear to be in error.
In view of the rather poor precision shown by the vapor
pressure results, other methods of determining vapor pressures are
being examined. The static method used to date has the advantage
of simplicity, but has serious deficiencies when used for mixtures,
and does not seem capable of yielding the desired accuracy.
9
do m W d VI
rl m 0 .;r I
2
.--IN
W * + P J
. .
* m N u * m a O o h * d m m m Q . . . . . . . . . . . . . . . .
N 000 uJ
0
03 0
m
U d
'0 a U a rl d 0 a a h U X w
m m m m
0 0 W h
. . . h m w d N m
*
" I
FIGURE 1
i
I
' ,
3 . GAS SOLUBILITY IN AQUEOUS KOH SOLUTIONS
Up t o the present t ime, a l l work has been d i r e c t e d towards measur-
ing t h e s o l u b i l i t y of oxygen i n KOH s o l u t i o n s a t va r ious concent ra t ions
and temperatures.
s tud ied as soon as t h e s o l u b i l i t y of oxygen has been determined.
The s o l u b i l i t y of hydrogen i n KOH s o l u t i o n s w i l l be
As noted e a r l i e r , Gubbins and Walker (1) had a l ready found t h a t
t h e sharp decrease i n oxygen s o l u b i l i t y a t inc reas ing KOH concentra-
t i o n would soon lead t o inaccura te s o l u b i l i t y measurements with t h e
method then i n use.
gas s t r ipped from t h e s o l u t i o n by a stream of helium, has been descr ibed
This method, which involved chromatography of t h e
i n d e t a i l by Gubbins, Carden, and Walker ( 7 ) .
t o be sound provided t h a t a means could be devised €or s t r i p p i n g l a r g e r
volumes of s a t u r a t e d s o l u t i o n of t h e d isso lved gas and concent ra t ing
t h e s t r i p p e d gas i n a manner which would permit i t s r a p i d in t roduc t ion
i n t o t h e chromatograph. This proved t o be a much more d i f f i c u l t and
time-consuming t a s k than had been a n t i c i p a t e d , but i t appears t h a t a
s u i t a b l e technique has now been per fec ted ; t h i s i s discussed below and
new da ta presented.
The b a s i c method appeared
3.1 Current Experimental -Method
The p r i x i p a l d i f f i c u l t y with t h e o r i g i n a l procedure was that
t h e a r e a of t h e peak recorded f o r oxygen w a s too small t o measure
accu ra t e ly when t h e s o l u b i l i t y decreased t o only a few per cent of t h e
s o l u b i l i t y i n water ,
Af te r t e s t i n g numerous approaches, a s a t i s f a c t o r y technique
f o r s t r i p p i n g and concentrat ing d isso lved gases w a s developed, and it
11
12
is shown schemat ica l ly i n Figure 2 . The s a t u r a t o r (not shown) i s
i d e n t i c a l w i th t h a t descr ibed i n an e a r l i e r paper ( 7 ) , a s is t h e
chromatograph.
The following procedure is used i n making a measurement:
Solenoid va lves 1 and 2 are s e t t o permit helium c a r r i e r gas t o flow
d i rec t ly through t o t h e sample column of t h e chromatograph, and t h e
carrier helium f lowra te is ad jus t ed t o t h e d e s i r e d va lue . Solenoid
valves 3 and 4 a r e set t o permit s t r i p p i n g helium t o flow through
t h e system as shown i n F igure 2.
t i o n e d ae shown i n F igure 2 , and t h e s t r i p p i n g helium f lowra te
Liquid n i t rogen ba ths a r e pos i -
ad jus t ed t o t h e des i r ed va lue (gene ra l ly about 30 ml/min.).
S t r i p p i n g helium passes f i r s t through an adso rp t ion
column a t t h e temperature o f l i q u i d n i t rogen f o r removal o f a l l
adsorbable impur i t i e s . It then flows t o t h e s t r i p p i n g c e l l , which
is merely an enlarged v e r s i o n of t h e one descr ibed i n r e f e r e n c e 7 .
S a t u r a t e d KOH s o l u t i o n from the s a t u r a t o r i s i n j e c t e d i n any d e s i r e d
amount a t t h e i n j e c t i o n p o r t . The f r i t t e d g l a s s d i s c produces smal l
bubbles which r a p i d l y s t r i p d isso lved gases from t h e s o l u t i o n i n the
S t r ipp ing ce l l . The s t r i p p i n g helium, now conta in ing t h e s t r i p p e d
gas and water vapor, is f i r s t d r i e d by pass ing through a column of
D r i e r i t e (necessary because the molecular sieve used i n t h e chromato-
graph adsorbs water vapor i r r e v e r s i b l y ) , then i t flows through Solenoid
va lve 3 t o t h e concen t r a to r , where t h e s t r i p p e d gases are adsorbed.
S t r i p p i n g helium passes on through Solenoid va lve 4 and t h e l i q u i d
n i t r o g e n t r a p from which i t is vented t o t h e atmosphere.
d 0 z zi 8 u
u
“I I G m 2
0 ,, J
c v)
I- e a J z 0 l- o LLI
-
After t h e i n j e c t e d s o l u t i o n has been s t r i p p e d f o r t h e des i r ed
time (usua l ly about 5 min.), valves 3 and 4 a r e set t o s t o p the flow of
s t r i p p i n g helium and t o connect t o va lves 1 and 2 , The l i q u i d n i t rogen
ba th i s removed from t h e concent ra tor and rep laced by a ba th of b o i l i n g
water f o r a s p e c i f i e d per iod (usua l ly 5 min , ) , which causes e s s e n t i a l l y
complete desorp t ion of t h e adsorbed gases . Valves 1 and 2 are then set
t o d i r e c t t h e flow of carrier helium through t h e concen t r a to r , and t h e
desorbed gas sample i s then swept i n t o t h e chromatograph where t h e amount
of d isso lved gas i n t h e in j ec t ed sample of s o l u t i o n is measured i n t h e
manner descr ibed i n r e fe rence 7 .
3.2 S o l u b i l i t y of 0, i n KOH a t 25OC
The experimental technique descr ibed i n t h e previous s e c t i o n
was per fec ted too l a t e t o p e r m i t many measurements. However, a few
s o l u b i l i t y da t a a t 2 5 O C were obtained and these a r e given i n Table 4.
These d a t a , along wi th those reported e a r l i e r by Gubbins and Walker (l),
and Geffcken (8), a r e shown i n F igure 3, where log S i s p l o t t e d versus
.w t . per cent KOH.
TABLE .4 SOLUBILITY OF O2 IN KOH AT 25OC
(New L . d a t a )
Wt / KOH S X ~ O ~
6 . 5 10.2 17.6 43.99
0.788 g.mole/ l . 0.588 0.300 0.044
It may be seen t h a t t h e new data l i e along a s t r a i g h t l i n e which i s a f a i r l y
good average of t h e e a r l i e r data repor ted except f o r t h e high KOH concent ra t ion
15
1. 0 0- 8
0 6 6
0.2 I Oa 0 8 0"
LL. 0-0 6
> t- 7 0.04 4 - m 3 -I 0
0.0 2
0.0 I
__
FIGURE 3
0GUBBlNS AND W A L K E R AT 25" C kSHOOR AT 25" C AGEFFCKEN AT 25" C WUBBINS AND WALKER AT 50" C
25" c
1
IO 20 30 40
W T % KOH
50
16
values of Gubbins and Walker (1 ) which were suspected of being inaccura t e ,
It a l s o seems worth noting t h a t t he da t a of Knaster and Apel'baum (9) for
the s o l u b i l i t y of oxygen i n KOH so lu t ions a t 2loC f a l l f a i r l y c l o s e t o t h e
l i n e of Figure 3 up t o a KOH concent ra t ion of about 30 w t . per c e n t ,
Ale0 p l o t t e d on Figure 3 a r e the data of Gubbine and Walker (1)
f o r t h e s o l u b i l i t y of oxygen i n KOH a t SO°C.
t o a s t r a i g h t l i n e on t h e semi-log p l o t which is p a r a l l e l t o t he 2SoC l i n e
and d isp laced towards lower s o l u b i l i t i e s . The r a t i o of t h c s o l u b i l i t y a t
50°C t o the s o l u b i l i t y a t 25OC appears t o be r e l a t i v e l y constant a t about
0.75 over t he KOH concent ra t ion range s tud ied .
These da t a , too, l i e c l o s e
A ques t ion may a r i s e a s t o why t h e e a r l i e r da ta of Gubbins and Walker
f o r s o l u b i l i t y of oxygen i n KOH a t 25OC and high KOH concent ra t ions s c a t t e r
more than those f o r s o l u b i l i t y a t 5OoC even though t h e s o l u b i l i t y a t 5OoC
i s l e s s than t h e s o l u b i l i t y a t 25'C and low s o l u b i l i t y i s judged t o be a
p r i n c i p a l d i f f i c u l t y i n making accura te measurements a t high KOH concen-
t r a t i o n s . Frankly, i t does not appear t h a t s u f f i c i e n t da t a are a v a i l a b l e
t o s u b s t a n t i a t e any conclusions.
4. THE DIFFUSIVITY OF OXYGEN AND HYDROGEN I N KOH SOLUTIONS
Methods f o r determining t h e d i f f u s i o n c o e f f i c i e n t s of oxygen
and hydrogen i n KOH s o l u t i o n s t h a t have been considered inc lude e l e c t r o -
chemical methods and diaphragm c e l l methods.
r i e d ou t t o d a t e have cons is ted of t h e development of a new s t e a d y - s t a t e
diaphragm c e l l technique.
Experimental s t u d i e s car-
The commonly used diaphragm c e l l procedure ( 1 0 , l l ) is attrac-
t i v e because of i t s s i m p l i c i t y , and the method is capable of g iv ing
q u i t e accu ra t e r e s u l t s . A drawback of t h e method is t h e cons iderable
t i m e , u sua l ly 2-3 days, requi red t o o b t a i n a measurement. Experimental
s t u d i e s of t h e d i f f u s i o n of d i sso lved gases by t h e diaphragm ce l l method
involve a d d i t i o n a l d i f f i c u l t i e s i n t h e f i l l i n g of t h e c e l l and subse-
quent a n a l y s i s of t h e so lu t ions (12). Analyses of t h e r equ i r ed accuracy
are p a r t i c u l a r l y d i f f i c u l t t o o b t a i n when t h e gases a r e very spar ingly
so lub le , as i s t h e case i n the present work.
A more rap id and accura te measurement procedure has been
developed i n which t h e diaphragm c e l l i s operated i n s teady s t a t e . I n
o rde r t o tes t t h e procedure, measurements of t h e d i f f u s i o n c o e f f i c i e n t s
of carbon d ioxide and of s eve ra l s a t u r a t e d hydrocarbon gases i n water
have been made; t hese systems were chosen t o test t h e method s i n c e
va lues of d i f f u s i o n c o e f f i c i e n t s are a v a i l a b l e i n t h e l i t e r a t u r e (15),
and t h e gases r e a d i l y lend themselves t o a n a l y s i s by gas chromatography.
4 . 1 Experimental
The diaphragm cel l (Figure 4) w a s opera ted h o r i z o n t a l l y , wi th
a gas space above t h e l i q u i d i n each compartment. A g l a s s diaphragm
having a diameter of 9 cm. and a mean pore s i z e of about 5 p was used,
1 7
.j
aJ
u M 0 U
v1 (d CJ
18
19
and t h e c e l l compartments had a volume of approximately 350 m l . The c e l l
was f i l l e d wi th s o l u t i o n under vacuum, and t h e l a s t t r a c e s of a i r removed
from t h e diaphragm i n t h e following manner (11): The s o l u t i o n t o be
s tud ied and t h e c e l l were connected wi th a s topcock and each evacuated
about 20 min. with t h e stopcock c losed . The stopcock was opened and t h e
vapor pressure of t h e s o l u t i o n caused f i l l i n g of t h e c e l l s .
upper compartment was almost f i l l e d with l i q u i d , t he l a s t traces of gas
contained i n t h e f r i t were removed by varying t h e pressure d i f f e r e n t i a l
t o r a i s e and lower t h e l i q u i d l e v e l i n the upper compartment. When no
f u r t h e r bubbles appeared i n the l i q u i d the f r i t was assumed t o be f i l l e d ,
The s o l u t e gas under study w a s passed slowly and cont inuously through t h e
l i q u i d i n one of t h e compartments, keeping t h e concent ra t ion of d i sso lved
gas c l o s e t o the s a t u r a t i o n va lue . A stream of helium was passed through
the l i q u i d contained i n the o ther compartment, thus removing d i f fused
s o l u t e gas from s o l u t i o n and keeping t h e concent ra t ion i n t h i s compartment
c l o s e t o zero . The f low-rates of both gas streams were con t ro l l ed by very
f i n e meter ing va lves , SI and S
before en te r ing the c e l l . Both t h e diaphragm c e l l and p r e s a t u r a t o r s were
kept i n a water ba th con t ro l l ed t o O.0loC,
were used; gas f lowra tes g r e a t l y i n excess of t h i s va lue were found t o g ive
r ise t o pressure f l u c t u a t i o n s between t h e two compartments.
When t h e
and t h e gases were p re sa tu ra t ed with water 2 ’
G a s f lowra tes of about 30 ml./min.
The concent ra t ion of d i f fused gas i n t h e helium stream leaving
t h e c e l l was determined by gas chromatography. A hydrogen flame i o n i z a t i o n
d e t e c t o r was used t o determine hydrocarbon gases , and f o r measurements of
carbon dioxide a hot-wire de tec tor was used. Af te r t h e s t e a d y - s t a t e condi-
t i o n had been achieved (usua l ly between 1 and 2 hours) t h e helium gas flow-
23
rate was determined using a soap bubble meter, and a sample of the gae
stream of known volume was trapped between the valves S
three-way solenoid valves S
and S 4 5' The
S6, S were then so adjusted a8 to 4' s5' 7
pass the sample to the gas chromatograph.
samples of the liquid from each of the cell compartments were removed
using a syringe and analysed for dissolved gas by gas chromatography.
No measurable concentration of dissolved gas was found in samples taken
from the helium side of the cell.
At the end of the experiment
The diffusional resistance provided by liquid in the diaphragm
may be considered equivalent to that of a cylinder of stagnant liquid
of length L and cross-sectional area A, the volume of the liquid being
equal to the volume of liquid contained in the frit.
the total flowrate of diffusing material will be
At steady state
where y = A/L is a cell constant.
.the quasi-stationary cell constant /3 using 0.lN potassium chloride.
cell was completely filled with liquid and operated vertically, the
liquids in each compartment being stirred with magnetic stirring bars.
The procedure used was identical to that described by Robinson and
Stokes (14). The quasi-stationary cell constant thus obtained is related
to the steady state cell constant by
The cell was calibrated by obtaining
The
P ' A (L++ (L+L) "1 v2 v1 v2
21
so that determinations of p and the volumes of the cell compartments
were sufficient to determine 7 . The cell constant was checked at fre-
quent intervals; when not in use the diaphragm was filled with a aolu-
tion containing 1 p.p.m, copper sulphate to prevent changes in the cell
calibration due to the formation of algae.
Clearly, at high KOH concentrations and high temperatures a
porous g lass diaphragm will be unsuitable.
investigated at the present time and it appears that one or more of these
will prove satisfactory.
Other materials are being
The gases used were obtained from the Matheson Company. The
minimum purities were methane and ethane 99.0%; propane and butane 99.5%;
carbon dioxide 99.99%.
4.2 Results and Discussion
Measurements of the diffusion coefficients of methane, ethane,
propane, butane and carbon dioxide in water have been made. Table 5
compares the results obtained with values from the literature. The
results reported are the mean values for about 5 measurements in each
case; the values of precision shown.are the standard deviations of the
arithemetic mean.
by Witherspoon and Saraf (15) were obtained by the capillary cell method,
and those of Unver and Himmelblau (16) were made by studying gas adsorp-
tion using a liquid jet. Several other workers have stirdied the diffusion
of carbon dioxide in water (13), and at 25 C report values of D ranging
from 1.74 to 1.92 x l o m 5 cm. sec. . At 4OoC Ringbom (17) has reported
a value of 2.75 x 10 cm. sec. for carbon dioxide diffusing in water.
In view of the difficulties involved in making experimental determinations
Literature values of diffusion coefficients reported
0
2 -1
-5 2 -1
22
of the diffueion coefficient for sparingly soluble gasee (13), the agreement
ehown in Table 5 appears to be quite good.
In eummary, the principal advantage of the steady-etate method
over procedures previously described is the speed with which measuremente
may be made. For the cell used in this work a single measurement took
about 2 hours. The steady state procedure is simpler and requires much lese
handling of liquids containing dissolved gases than the conventional dia-
phragm cell method. Since a measurement is not made until a steady state
is reached, the possibility of adsorption of the diffusing gas on the
diaphragm is not a problem, as it may be in the unsteady state diaphragm
cell procedure.
TABLE 5
COMPARISOK OF EXPERIMENTAL RESULTS WITH VALUES FROM LITERATURE
Temperature Experimental Value Literature Value - Gas OC D x 105, cm.2, sec. -' D x lo5, em.2, sec." Reference
25.0 1.99 2 0.06 40.0 2.36 ,+ 0.05
cH4
25.0 1.53 ,+ 0.03 ''2H6 40.0 2.02 - + 0.10, 25.0 1.27 ,+ 0.04
1.63 + 0.09 40.0 C3H8
- 25.0 0.97 t 0.04 25.0 1.89 2 0.10 40.0 2.81 ,+ 0.10 60.0 4.15 2 0.24
'qH1O
c02
1.89
2.34
1.52
1.88
1.22
1.53
0.97
1.85
2.90
4.05
16
16
16
16
16
16
16
17 17
17
A = area of cylinder of stagnant liquid having resistance to
c = concentration of dissolved gas, g,mole.cm.
diffusion equal to that of the diaphragm, cm,2 -3
- 3 = saturation concentration of diesolved gas, g.mole.cm. cO
2 -1 D = diffusion coefficient, cm. sec.
L length of cylinder of stagnant liquid having resistance to diffusion equal to that of diaphragm, and area A, cm.
-1 N = total flowrate of diffusing gas, g.mole.sec,
3 V1,Vz = volumes of cell compartments, cm.
p cell constant for diaphragm cell operated using conventional quasistationary procedure, cm. - 2
y = steady-state cell constant, cm.
23
5. FUTURE PLANS
Since t h e experimental methods which have been used f o r both dens i ty
and vapor p re s su re measurements a r e proving u n s a t i s f a c t o r y for h igh KOH
concent ra t ions and high temperatures, new techniques a r e being explored.
A s i l v e r plummet has been procured f o r use with t h e Westphal balance,
and it is expected t h a t dens i ty measurefients of adequate accuracy can be
made with t h i s equipment.
Two new techniques for measuring vapor p re s su re a r e being cons idered .
These are ( l ) , a s t a t i c method i n which t h e weight change of a KOH sample
i s measured when t h e vapor pressure of water around it is v a r i e d , and (Z),
a dynamic method i n which t h e dewpoint of an i n e r t gas i s measured when
i t i s i n equ i l ib r ium wi th a KOH s o l u t i o n of known concen t r a t ion and t e m -
pe ra tu re .
A t h i r d graduate s tudent i s being assigned t o these t a s k s , and i t
i s expected t h a t t hese phys ica l p roper ty da t a w i l l be a v a i l a b l e be fo re
t h e end of t h e next r epor t ing per iod .
The newly developed method f o r determining gas s o l u b i l i t y w i l l be
f u r t h e r appl ied t o a study of oxygen d i s s o l u t i o n i n KOH s o l u t i o n s up to
s a t u r a t e d KOH and 200°C.
i n KOH s o l u t i o n s w i l l be defer red u n t i l t h e d a t a f o r oxygen are complete.
Determinations of t h e s o l u b i l i t y of hydrogen
Since measurements of the d i f f u s i v i t y r e q u i r e a knowledge of t h e
s o l u b i l i t y of t h e gas a t t h e KOH concen t r a t ion and temperature i n ques-
t i o n , l i t t l e a d d i t i o n a l work on t h e d i f f u s i v i t y i s planned u n t i l most of
t h e s o l u b i l i t y da t a a r e i n hand. A t t h a t t i m e , e f f o r t s w i l l be concen-
t r a t e d on t h e de te rmina t ion of t h e d i f f u s i v i t y of both hydrogen and oxy-
gen i n KOH s o l u t i o n s using the s teady s t a t e diaphragm method descr ibed i n
c h i s r e p o r i .
24
6 . LITERATURE CITED
1.
2 .
3.
4.
5 .
6.
7 .
8.
9 .
10.
11.
12.
13.
14.
15.
16.
1 7 .
Gubbins, K. E. and Walker, R . D . , J . Electrochem. SOC., 112, 469 (1965).
Tobias, C . W . , P r i v a t e Communication
Davies, C. W. and Nancollas, G . H . , Nature, 165, 237 (1950).
F i r s t Semi-Annual Report, Grant NGR 10-005-022, March, 1966.
Lipkin, M . R . , Davison, J . A . , Harvey, W. T, and Kurtz, S. S., Ind. Eng. Chem., Anal. Ed., l6, 55 (1944).
Solvay Technical and Engineering Se rv ice , B u l l e t i n NO. 15, 1960.
Gubbins, K. E . , Carden, S. N., and Walker, R. D . , J, Gas Chromatog., 3, 98 (1965).
Geffcken, G . , Z . Physik. Chem., 49, 257 (1904).
Knaster, M. B . , and Apel'baum, L. A , , Russian J . Phys. Chem., - 38, 120 (1964).
Northrup, J . H . and Anson, M. L . , J, Gen. Phys io l . , 12, 543 (1929).
Gordon, A . R . , Ann. New York Acad. S c i . , 46, 285 (1945).
Gubbins, K. E . , Bhatia, K. K . , and Walker, R . D . , A.1.Ch.E. Journa l , l2, 548 (1966).
Himmelblau, D. M . , Chem. Rev., 64, 527 (1964).
Robinson, R. A . and Stokes, R . H . , E l e c t r o l y t i c Solutions, Academic Press, New York, 1955.
Witherspoon, P . A . and S a r a f , D. N . , J . Phys. Chem., 69, 3752 (1965).
Unver, A . A . and Himmelblau, D. M . , J . Chem. Eng. Data, 9, 428 (1964).
Ringbom, A . , Z . Anorg. Allgem. Chem., 238, 94 (1938).
2.5