-- - -- --

.

DAtE&Ei/rsBb:DATE1'IlBPARED:

MATERIAL SAFETY DATA SHEET (1/4)

SDSNo. 908019 PRODUCTNAME; BrOLher HL 720 TN 200.

1. CHEM I CAL PRODUCT AND .COMPANY I DENT I F r CA T ION

P10DUCt!Wm: BrOLher HI,. 720, TN 200 1LP2Q / 3C()'i-' Lf-.MANUFACtURE'SNAME

2. COMPOS IT ION/INFORMATION ON INGREDIENTS

hgredientsPolyesterPDJy~ropyleneOrganic picmentCarbonblack

CASNo.TradeSecret

9010-79-18005-02-5*1333-86-4

Proportionex by w1.)

> 84< 3< 5< 8

. OSHA PEL

Bot listedHot.Jisted.Hot Us leda. Smg/m'

ACGtHTLVROt li s tedNot lis tedNot listed

3. 5mg!111'

other tJmitsNOlleHoneNoneRone

t:[n the EuropeanInventory, Ihis material is regarded as mixtares made up lwoconstiluents ( CASNo. 101351-15-1 and CASNo. 65997-o4,-8).

3. HAZARD IDENTIFICATION

EMEAGENCr OVER-VIBW

Odorless black [lACpowde~

Nonflammable, but whensuspendedin air, is combustible_8 with most organLcpovders.

CARCrNDGEKICITY:CarboDbll0k js reclassified as a group 2B by lAIC, butL~ I inhalation test nsing a typical touer shovedno association betl~en toner

Ind ani~al tv~ors.

rOTENrlONWALTH BPFECrS

~YBS:S~lid or dusts maycause irrItation Dt corneal Injury.sKIN CONTAcr:EsSeht'alty nonirrItating 10 skin.

SKINABSORPTION:Skin absorption Is unlikelY due to Dhvsical DrDDetties.

INGESTION:Oral toxieity Is believed to he lov.INHALATION:MiniMal Irritation to respiratory track ~~y occur.

Pt!B ANDEXPLOSIoN

SENSITIVITYTO MECHAlHCALIMPACT~NoneSENSITIVITYTO STATICCHARGE;None

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DATEREVISED :DAtEUErABED:

MATERIAL SAFE~Y DATA SHEETCZ/4)

$OS No. 908019 nODucr NAMEi Brother HL 720. TN 200

-,

4, FIR S T A ID MEA SUR E 5

EYES:Plush eyes immediately with plenty of ~ater far " at least 15 aiautes.

SK[l{:PIU3hwltb plcnty DCnter. Use soap.

INGeSTION:No adverseelfects anticipated by this route of exposure jncidental 10

proper handUng, .

INHALATION:Removeto fresh &i~ It effects occu~ consult medical personnel.5. FIRE FIGHTING MEASURES

PLAWABLBPROPBRTlBS:

FLASHPOINt: No data av!ilable

P'lAMHABLRLIMITS1FL: Nodata availableUFL: Nodata Ivai labIe

EXTINGUISHINGMEDIA:Yater 10& ro~ CO,. dry chemical.

FIRE-FIGHTINGEQUIPHBNT:Wearlull bu~r gear including ~ positive pressure selC-

contained bre&thing apparatus in case of burning in large QUtDtities. .

6. ACCIDENTAL RELEASE MEASURES

Minimizethe release 01particula.tes. Wear personal prolectivr equipment.Donot use va.caumcleaner.After by lightly sPf(Ying with ,ater to prevent develop~enlor dust, spills should be sre~(

upar wll'edliP.ThCftresIduals un beremovedwith soapandwaCer.Preferred tll Qse the lIaterla.1

In a place, coverInsup the floor andsurroundIngI18.Uerslith suitable sheeu suchIS paper,

In I caseof belbg bDI lit to scrQb JhefLoar with yater. TheseUS~ shee1asbauld be wrappedUPill spills "andtransfer Into a.suitable container lor'disposd.GarmeDt,~ay be "&shedor dry cleaued. alt~r removal of loose tDner.

7. HANDL I NG AND STORAG'E

Avoid creating dUst. CleanUP a.11 spills proJlptly.

Inhalation and contact witb skjD or eyes should be avolde~

Provide general venlilatja~ Goodgeneral ventilation shauld be sufficient [or moSI

cond J t I on~.

Siore In a cool. well vcntilated place aw&y from flames and spark-producing

equipment ,

MaytDners be ~referred 10 use or to handle al fhe suitable place ~ithout concerneiug

abQu( smudges to ~hlcb are given rise by releasing th~

'-"'

'-

-,.

.~

......

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.

..»AtBnVrSEJ);DATi l'REPAiBD :

.,.MATE~IAL SAFETY DATA SHBET(3/4)

SDSNo. 908019 PRODUCTNAME: Brother HL 7ZP , TN ZOO

8. EXPOSURE CONTROLS/PERSONAL PROTE.CTION

RESPIRATORTPROTECtION:Far most conditions, no respira[ory protection snDuldbeneeded; however.111 ({usty umasDheres.useanapproveddust resDJtator.

SKINPROTECTION:No prec,utloDs shouldbeneededundernoraal use.

eYEI'ROT2CTION:Ho preel.ution:s shl:JU}d.be need.edmuler nOnlll( q:n:.

9. PHYS] CAL AND CREMI CAL PROPERT I ES

Al'1B.AllANt2::Black ClJle powderODOR:Noue' .BOILINGPOINT:N.A (not applicable)VJ\PPRESS:1(. A.vn «NSITY: N. A.SOL IN 1A1U.: Negligiblesr. GRAVITY:1.2MELTINGPOINT: No A.

pH: N.A.% VOLAnLB:N.A.

10. STAB ILITY AND REACTIVITY

STABILI'n':This is a. sta.ble product.

INCOMPATIBILItY: (SPECIAl JlATERIALSTOAVOID)None

HAZABDOVSDECOldl'DSITIONPi01>UCIS;c~ or HOx (by high heat and fire)

HAZARDOUSPOLYMBRIZATlON:Iill hot occur.

~ 11. TOXICOLOGICAL INFORMATION

-"

.. CARCINOGENICITY:

In 1~g6, the (ARCrevaluated carbonblack as a GROuP 28 carcinogen (possible humancarci~ogtq). Tbis evaluation is gIvCD 10 carbon bla~ tar _bich there is

Inadequate humanevideD~~ but sUfflcjeul animal eyidenc~ The latter is based upon

the developer of lung ~umorsin rat receiving chronic inbalafion exposures to Creecarbon blatk.~1 level that tndqce particle Dverlo~d 01 the luD~

Studies performed In Animal ~odel~ other than fats hav~ Dat demonstrated an .associationbetweencarbonblack and lung l~ors. Moreover. a two-year cancerbioassay using a typical toner preparatioD contaln!ng c~rbo~ black demonstrated noassociation between tODer exposur-t and tumor development in tats:

.~...

- -'II .:....

DATHKEVISBD ;DATI!PREPARED:

MATERIAL SAFETY DATA SHEET (4/4)

SDSNo. 908019 PRODUCTIW(E; Brother HL 720, TN 200

CHRONIC EFFECTS:In Ii study in rats QUfuhle> by r;hronic inblatioh expOSllre to a typical laDer,a mild io moderate degree of lung fibrosis was observed jn 92f of tbe rats in theconcentratlon(l6mglm') exposuregroup, and a mln1malto mlld degree ot fibrosis wasnoted in 22S of the anImals in tho lIIiddle (4mg/II") exposure group. But no pUlmonarychanges .,as repor ted In the IO'les f (lmg/II1') exposure group, tl1e most rei eYanl 1eve ItD potential human eXDosures.

12. ECOLOGICAL INFORMATION

None

-- 13. D I S POSAL CONS I DERAT IONS

IASTEDISPOSALMETHOD:Waste !IDSf be disposed 0 r in accordanceWith country ahdlocal envfronm~nfalcontrol regulations.

14. TRANSPORT INFORMATION

TRANSPOR!INFORMATION:This is Dot a hazardousproduct.UNNo.; ~DneallDcate~.

15. REGULATORY INFORMATION

. TSCA: All ch~mJcal 3ubstlnc~, in this pro~ucl COGPlY Yirh all 4pplic~ble rulesor orders uuder TSCA

16, OTHER INFORMATION

'-..-." NFPAk!tlDe: Health = I Flammability c 1 Reactivity B 0

REPl!JlENCES:IARC(1996) JAReMonographsa~ (be Evaluation or the Carclnoge~ic~Isk of Chemicalsto Huma1ls.Vol.65, Printing Precess aDdPrjnling fnIts. Carbon BJaekInd SomeNitroCompound~,tyon. PP.149-~61.

Jlllluhle, J. BellmanD. O.Crellizenberg, C.Da.seD.brock.ILErnsI. 1.XiIpper, J.C. MackeJ1%te.'P.Morro u: IlQhr, S. te.kellaka. and R.Werlllehtein (1991) Pulmonary Response to tonerapeDChronj~Inh~!ation ~osure in lafs. FundameD.taland ApP1iedTDxtCDlo!y11.pp. g8n-299.