likely cause: hydrogen combustionlikely source of hydrogen identified in close proximity to...
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Likely Cause: Hydrogen Combustion
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Hydrogen Combustion
H2 + ½ O2 H2O +Energy Ignition Source
H2 Flammability Limit: 4% in air H2 Detonation Limit: 18% in air
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Hydrogen Production via Copper Corrosion
Electrochemical Reaction Anode: Corroding Cathode: Protected from Corrosion
Cu+2
H
e- Copper (Cu)
e-
H
H+ H+
H2
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Beach Schematic
Air
Sand and Water Wire
Corrosion Zone: H2 Buildup
H2
O2
H2O
O2 Diffusion Zone
H2 + ½ O2 H2O +Energy
Combustion Zone
Sand and Air
H2
H2
O2
O2
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Cable End Differences
Up-Slope End: Corroded End Near Event: No Corrosion
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Hydrogen Flame Properties
Very low ignition energy
Flames not visible
Flames radiate very little heat
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Observations & Conclusions
No flames observed
No burns
No explosive residues
Methane levels below or near detection
Likely source of hydrogen identified in close proximity to explosion
Flammable hydrogen levels detected in beach sand : Values up to approximately 5% of air pressure
Conclusion:
All of the above consistent with a hydrogen combustion.
Removal of wire and aeration of sand make future combustion unlikely.
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GSO Participants
Prof. Arthur Spivack
Prof. John King
Prof. Brian Heikes
Justine Sauvage
Kira Homola
Dennis Graham