lifecycle pollution prevention utilizing tomated, web...

Lifecycle Pollution tomated, Web-based hemicals, Products, M

George R. ThoCHEMICAL COMPLIA

Lifecycle Analysis and13th Green Chemistry &

College PJune 2

Prevention UtilizingAssessment of “Gree

Munitions & Processe

ompson, Ph.D.ANCE SYSTEMS, INC.

Green Metrics SessionEngineering Conference

Park, MD25, 2009

Pollution Preve

a. Modifying Production Pro

1. Reducing or Eliminating W

Pollution Prevention Act, 1990

2. Using Green Chemistry Pr

Green Chemistry–Theory and Practice, Anastas &

b. Promoting the Use of Non

c. Implementing Conservati

d. Reusing Materials

ention Priorities

ocesses

Waste at the Source a

rinciples b

& Warner

ntoxic, or Less Toxic Substances

on Techniques

Lifecycle

Design

NewConstituents

A L

T E

R N

A T

I V

E S

ManufacturingPrecursorMaterials

M

Design Manufacturin

[ScreeningTest Data

Requirements]

e Stages

FinishedManufactured

Product

Transport&

Storage

DisposalUsage

Emissions

g Handling/Usage Disposal

[ProductSpecific]

[ProductSpecific]

CAS# 302-0

HYDRAZINE

F2294

CM

PK22

ENVIRO

FIRE REACT

HEALTH

3 2

3-3 4-3-3EXP

7 1

69 5

4GROUND VEN

C

SPECIAL

hemical NameAS Registry NumberOT ID Numberazard Ratings (0-Minimal, 4-Severe)

Fire-Health (Short Term-Long Term)Reactivity-Environmental (Air-Water-Soil)

pecial Hazard IndicatorOXY (Oxidizer) EXP (Explosive)RAD (Radioactive) -W- (Water Reactive)

Reading the CCS SA

01-2 DOT# 2029

E

2 3

6. Year Received and Disposal Code7. Special Health Hazard Indicator

C (Carcinogen) T (Teratogen)M (Mutagen) N (Neurotoxin)

8. Recommended PPE(symbols not overprinted)

9. SAF-T-Storage Code

NTILATE WASH GLOVES CLOTHING

CARTRIDGE GOGGLES

8

AF-T-LABEL© – 1985

CCS Databases Published in 1990 / Handbook in 1995

Chemical

Referencectionary

Physical/Chemical Green

— — — /— — —

——

Health

—— — —

Safety

——— - ——

Ecological

———

Alternat—————————————

—

CS Relational Chemical and

Regulatory Product Munition— . . — . . — . . — . . — . . ———— ———

———— ———

—— / —

tives

( )

d Product Database (R–CP

R–CPD S

24 Years of Data Comp

75,000,000

260,000

>1,000,000

>10,000

10,000+

1,000

700

Data Ele

Chemica

Product

Manufac

Munition

Public D

Regulato

••••••••

Statistics

pilation – Ongoing Daily

ements

als

t MSDSs

cturers

ns (DoD/ UK / NATO)

Data Sources

ory Lists

Significance of each sub-score can be individ

HEALTHSCORE[people](0-100%)

SAFETYSCORE[people](0-100%)

FINALGREENGRADE

0 - 100%)

ECOLOGICALSCORE[planet](0-100%)

W

Rea

Chro

Acute

S

Product, Munition, Pro“Green” Sco

dually weighted “Endpoint” Criteria

LONG-TERM EFFECTS - SOGroundwater Mobility Facto

CERCLA RQ

TOXICITY-WATERFish LC50

Daphae LC50Green Algae EC50

(Solubility W-LC50) BC

LONG-TERM EFFECTS - WAEutrophication

Theoretical Oxygen Deman

LONG-TERM EFFECTS - AGlobal Warming PotentialOzone-Depleting Potential

SmogAcidification

TOXICITY - AIR(V.P. LC50) BCF

TOXICITY - SOIL(Koc O-LD50) BCF

14-day Worm LC50

PersistenceExposureToxicityLong-Term Effects



Water Score

Air Score

Soil Score

Explosivityactivity Score

nic Health Score

FLAMMABILITYFlash Point

Boiling Point

FlammabilityFire Score

Oral LD50Dermal LD50IDLHSTEL/CeilingInhalation LC50Skin IrritationEye IrritationOdor Threshold Value

e Health Score

Reproductive EffectsCarcinogenicityRfCRfDRadioactivitySensitizerNeurotoxicityTLV

RadioactivityOxidizerWater-ReactiveCorrosive

pecial Score

cess and Wastestreamring Process

“Green” Lifecycle(Within Each

Design Manufacturin

Design

NewConstituents

A L

T E

R N

A T

I V

E S

ManufacturingPrecursorMaterials

M

[ScreeningTest Data

Requirements]

Potential Products(GP–CAS)

Processes(G–PACS)

e Considerationsh/Across All)

ng Disposal

FinishedManufactured

Product

Transport&

Storage

DisposalUsage

Emissions

[ProductSpecific]

[ProductSpecific]

End Products(GP–CAS)

Wastestreams(G–WACS)

Handling/Usage

Ecological Score81.11

(33.34% AW) (65 Pass/Fail)

Health Score78.62

(33.34% AW) (65 Pass/Fail)

Safety Score91.18

(33.34% AW) (65 Pass/Fail)

Green” Grade Report Card

or Product IndexGP–CAS

Productomotive Antifreeze #1

Adjustable WeightPreferred

FINALGREENGRADE

83.63(100%)

Water Score: 82.01(33.34% AW)

Persistence: 74.97 (15% AW) Exposure: 54.46 (15% AW) Toxicity: 94.03 (35% AW) Long-Term Effects: 84.81 (35% AW)

Air Score: 89.57(33.33% AW)

Persistence: 60.49 (15% AW) Exposure: 96.62 (15% AW) Toxicity: 95 (35% AW) Long-Term Effects: 93.58 (35% AW)

Soil Score: 71.74(33.33% AW)

Persistence: 74.97 (15% AW) Exposure: 47.48 (15% AW)Toxicity: 100 (35% AW) Long-Term Effects: 52.5 (35% AW)

Acute Health Score: 89.59(50% AW)

Oral LD50: 97.65 (12.5% AW) Dermal LD50: 100 (15% AW) IDLH: 100 (25% AW) STEL/Ceiling: 70.98 (20% AW) Inhalation LC50: 100 (18% AW) Skin Irritation: 27.5 (3% AW)Eye Irritation: 52.5 (4.5% AW)Odor Threshold Value: 100 (2% AW)

Chronic Health Score: 67.65(50% AW)

Reproductive Effects: 100 (20% AW) Carcinogenicity: 76.25 (23% AW) RfC: 85.69 (4% AW) RfD: 85.5 (3% AW) Radioactivity: 100 (12% AW) Sensitizer: 100 (5% AW) Neurotoxicity: 5 (23% AW)TLV: 59.65 (10% AW)

Fire Score: 73.53(33.33% AW)

Flammability: 73.53 (100% AW)

Special Score: 100(33.34% AW)

Radioactivity: 100 (25% AW) Oxidizer: 100 (25% AW) Water-Reactive: 100 (25% AW) Corrosive: 100 (25% AW)

Reactivity Score: 100(33.33% AW)

Explosivity: 100 (100% AW)

GP–CAS ProducProcess “Gree

Process NameMSDS

Chem%Re-CalChem%

OverAssess

Y ADHESIVE 77ctured by 3M COMPANY

100 100 MOSGRE

RAL PURPOSE ADHESIVE SPRAYctured by CAMIE-CAMPBELL, INC.

100 100 2

A-1058ctured by LHB INDUSTRIES

100 100 3

PURPOSE SPRAY ON ADHESIVE MMM-A-8Actured by CONTACT INDUSTRIES, INC.

100 100 4

A-1058A ADHESIVE, PC-NAPCOctured by NATIONAL AEROSOL PRODUCTS CO.

GROW GROUP, INC.

100 100 5

PURPOSE SPRAY-ON ADHESIVEctured by CONTACT INDUSTRIES, INC.

100 100 6

A-1058A RUBBER ADHESIVEctured by LHB INDUSTRIES

100 100 7

RE RUBBER ADHESIVE, PART #532D800ctured by LHB INDUSTRIES

100 100 8

GSA ADHESIVEctured by CAMIE-CAMPBELL, INC.

100 100 9

PER 77 SPRAY ADHESIVEctured by 3M COMPANY

100 100 LEAGRE

ct Comparisonsenness” Analysis

Adjustable Weight List: Preferred

rallment

Green Grade(100%)

Ecological(33.34%)

(65 Pass/Fail)

Health(33.33%)

(65 Pass/Fail)

Safety(33.33%)

(65 Pass/Fail)R

STEEN

98.85 98.67 99.38 98.5

89.3 88.53 88.95 90.42

83.19 77.12 94.35 78.11

83.12 83.2 81.23 84.92

82.38 81.38 86.66 79.09

81.68 82.91 85.05 77.09

77.4 74.85 85.32 72.02

76.92 74.34 82.76 73.67

75.21 72.97 84.31 68.34

STEN

70.8 68.1 87.62 56.67

© 2009 Chemical Compliance Systems Inc All rig

G–PACS Ste

Process “Green

Process Name Chem%Overall

Assessment

OCESS 1 (Chemical of Concern)red by Chemical Compliance Systems, Inc.

100 MOST GRE

ompatibility) 2.35

ompatibility) 27.66

ompatibility) 4.28

ompatibility) 32.45

ompatibility) 10.43

ompatibility) 4.6

ompatibility) 10.29

ompatibility) 7.93

OCESS 2red by Chemical Compliance Systems, Inc.

100 LEAST GRE

p Evaluation

nness” AnalysisAdjustable Weight List: Preferred

Green Grade(100%)

Ecological(33.34%)

(65 Pass/Fail)

Health(33.33%)

(65 Pass/Fail)

Safety(33.33%)

(65 Pass/Fail)Reg

(L

EN 84.4 83.89 83.08 86.24

79.72 78.13 83.09 77.94

87.52 86.09 86.35 90.1

* 71.14 73.94 74.54 64.95

77.22 77.2 72.92 81.54

77.638 75.95 78.26 78.68

96.86 96.52 98.96 95.09

97.62 97.46 97.86 97.53

96.04 96.13 95.87 96.13

EN 81.3 81.62 79.47 82.82

© 2009 Chemical Compliance Systems, Inc. All righ

G–PACS AlternatiProcess “Green

Process Name Chem%Overall

Assessment

OCESS 1ured by Chemical Compliance Systems, Inc.

100 MOST GRE

ompatibility) 0

ompatibility) 0

ompatibility) 100

WATERCAS#: 7732-18-5Values) (Synonyms) (PHY. Property) (Alternative)

0

TOLUENECAS#: 108-88-3Values) (Synonyms) (PHY. Property) (Alternative)

59.79

POTASSIUM TERT-BUTOXIDECAS#: 865-47-4Values) (Synonyms) (PHY. Property) (Alternative)

40.21

ompatibility) 0

ompatibility) 0

ompatibility) 0

ompatibility) 0

ompatibility) 0

OCESS 2ured by Chemical Compliance Systems, Inc.

100 LEAST GRE

ive Chemicals [1]

© 2009 Chemical Compliance Systems, Inc. All righ

nness” AnalysisAdjustable Weight List: Preferred

tGreen Grade

(100%)

Ecological(33.34%)

(65 Pass/Fail)

Health(33.33%)

(65 Pass/Fail)

Safety(33.33%)

(65 Pass/Fail)Reg

(

EEN 84.4 83.89 83.08 86.24

N/A N/A N/A N/A

N/A N/A N/A N/A

71.14 73.94 74.54 64.95

N/A N/A N/A N/A

* 69.13 72.21 59.27 75

74.14 76.52 95.9 50

N/A N/A N/A N/A

N/A N/A N/A N/A

N/A N/A N/A N/A

N/A N/A N/A N/A

N/A N/A N/A N/A

EEN 81.3 81.62 79.47 82.82

G–PACS Alternaative Chemicals [3]

2 Alternative Chemical Con

hemical Generic Category

8 Abrasives

34 Absorbents

1555 Acids

304 Additives

3982 Alloys

1 Anticorrosives

13 Antidandruff Agents

15 Antifoaming Agents

104 Antimicrobials

48 Antioxidants

25 Antiperspirants

826 Antistatic Agents

90 Bases

68 Binders

Chemical Gener

199 Biologica

3 Bleachin

496 Botanica

76 Buffering

44 Chelating

207 Colorants

26 Denatura

36 Deodora

20 Dipilating

985 Emollien

112 Emulsion

269 Film-Form

245 Hair Dye

153 Humecta

nstituent Generic Categorie

ric Category

al Additives

g Agents

ls

g Agents

g Agents

s

ants

nts

g Agents

ts

n Stabilizers

mers

s

ants

Chemical Generic Category

407 Ionic Liquids

90 Opacifiers

43 Oral Care Agents

913 Oxidizing Agents

123 Preservatives

13 Propellants

28 Reducing Agents

649 Solvents

13 Solvents-Chloro

74 Solvents-FDA

141 Solvents-INCI

394 Surfactants

61 UV Absorbers

113 Viscosity Controlling Agents

Combined COC Ratings

AS # CHEMICALInventoQuant

-14-6 DINITROTOLUENE6-7 TNT0 NITROGLYCERIN

2-4 RDX92-1 LEAD2 DIBUTYLPHTHALATE

90-5 ALUMINUM70-0 NITROCELLULOSE8-7 NITROGUANIDINE02-0 NICKEL41-0 HMX79-1 POTASSIUM NITRATE-73-9 LEAD SALICYLATE98-9 AMMONIUM PERCHLORATE6-1 TRIACETIN4 STEARIC ACID

80-5 POTASSIUM SULFATE-15-1 CALCIUM SULFATE HEMIHYDRATE5-5 2-NITRODIPHENYLAMINE-72-2 METHYL DIPHENYLUREA21-3 SILICON44-0 CARBON89-6 IRON

s & Composite Rankings

ory tity

Regulatory Ranking Eco Health Safety

COMPORANKI

40 0 75 42 67 2240 83 74 62 33 252

25 50 75 57 50 25719 50 81 81 42 27366 8 77 42 100 29344 17 82 71 92 30537 75 82 75 50 3190 100 82 100 42 324

31 100 74 95 33 33380 25 82 51 100 33854 100 81 92 25 35249 75 73 99 67 36364 58 85 74 92 37358 100 81 98 58 39553 100 80 97 92 42268 100 82 92 92 43453 100 85 99 100 43771 100 100 85 83 43966 100 80 97 100 44363 100 80 100 100 443

100 100 82 92 75 44963 100 90 99 100 452

100 100 83 99 100 482

Multi-functional DoD Green Procurement Program Fulfillment Munition/Nonmunition P2 and Regulatory ComplianceMunition/Nonmunition Security

POLICY

By Demil OperationBy Specific Range & OperationFor Procurement—Hazard Acquisition ConstraintsSecurity Incident Prevention

OBJECTIVES/GOALS

By Level, Function, Product Type & Restricted ConstituentsWithin Permit ConstraintsBy Demil/Range Operation & RegulationStorage Requirements by Area & Function

TARGETS/REQUIREMENTS

Decrease/Increase Acquisition, Usage Releases, Exposures & CompliaSecurity Risks, Incidences, First Responder Analyses

ASPECTS/IMPACTS

No Hierarchical Data Calls“Broad Picture” of Operations, Processes, Areas & FunctionsIntegration of Munition, Nonmunition & Security Analyses & Compliance

MANAGEMENTPROGRAM

Definable by Area, Level, Function, Process, Operation & RegulationRESPONSIBILITIES

Periodic Interim Status Reports By & Across Module(s)Integrated Documentation & Validation

SCHEDULE

Simplified by Criteria, Pass/Fail ValuesOperation, Process & Area-Specific

TRAINING

Within Each ModuleDOCUMENTATION

Product & Constituent Data by Hazard, Area, Operation & ProcessImaged DocumentsDecreased Incidence Likelihood & Severity

EMERGENCYPREPAREDNESS

Within Each Module—Hazards & ComplianceMEASUREMENTS

Within Each ModuleRECORDKEEPING

Annual Executive Review & Interim Detailed ReportsNAGEMENT REVIEW

CS Module Integration Into

MACS–6Manufacturing

(NEW)

nce

e

C–HoSSChemical Secu

(NEW)

C–CASChemical Track

GP–CASGreen

Nonmunitions

Plasma ArcFeedrate

IncineratorFeedrate

MACS–1Demil

Risk ModuleDispersion

HRAHealth Risk

ERAEmission Risk

TRACSMunitions &

Waste

MACS–3TheoreticalCompliance

Analyses

MACS–2Ranges

G–MACSGreen Munitions

G–PACSProcesses

o Quantitative ISO 14001 EM

COCChemicalsof Concern

Conclu

hemical Lifecycle Pollution Prevent

cludes Product Design, ManufacturEnd-of-Life Segments

ased Upon 43 Objective Chemical EEndpoint Criteria–Flexible

dentifies Pollution Prevention Oppo

Quantitative Scores Facilitate ProducIncremental Improvements

ntegration With Green Engineering CLifecycle Analyses

usions

ion Analyses Can Now Be Automat

ring, Handling/Utilization &

Ecological, Health & Safety

ortunities in Each Lifecycle Segmen

ct & Process Comparisons—

Criteria Will Enhance

Dr. George

CHEMICAL COMPLIA706 Route 15 So

Lake Hopatcon973-663

georgethompsonwww.chem

r a remote demonstration, or m

Thompson

ANCE SYSTEMS, INC.outh, Suite 207ng, NJ [email protected]

more information, please conta