lecture 11 matter and light astro161 – fall 2011 dr. matthias dietrich

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Lecture 11 Lecture 11 Matter and Matter and Light Light tro161 – Fall 2011 . Matthias Dietrich

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Page 1: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Lecture 11Lecture 11Matter and LightMatter and Light

Astro161 – Fall 2011Dr. Matthias Dietrich

Page 2: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Homework

The second home-work assignment is available after class today and it is also posted on the class web-site, as well as on Carmen. It will be due on Monday, Oct. 24th .

The home work has to be returned either in class

or as e-mail:

[email protected]

[email protected]

Page 3: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

some announcement

This Friday, October 21st, will be the second midterm.On Thursday, Oct. 20th, there will be a review session in the planetarium onthe 5th floor of Smith Lab at 5pm.

A practice test is posted, again on the class web-site and also on Carmen.

Page 4: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Oct. 03 Mon. doneOct. 04 Tue. doneOct. 05 Wed. doneOct. 11 Tue. doneOct. 12 Wed. doneOct. 13 Thu. doneOct. 17 Mon. @ 6:00 pmOct. 18 Tue. @ 6:00 pm

Smith Lab. 5th floor Planetarium

Roof NightsOct. 06 Thu. 8:00 pm doneOct. 19 Wed. 8:00 pm (Oct. 26)

Page 5: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Lecture 11Lecture 11Matter and LightMatter and Light

Page 6: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

6

In the late 17th and early 18th century experiments with prisms and slits – dispersion and diffraction – lead to thepicture that light can be described as a wave phenomenon.

Particle ? Wave ?Wave

Page 7: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Lecture 2: Light

Properties of Waves

• Light waves are characterized • by three numbers:

– wavelength, λ (size of the wave)

– frequency, f (number of waves/second)

– wave speed, c (the same for all wavelengths)• These are all related by:

c = λ f

• longer wavelength means smaller frequency

wavelength

Page 8: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich
Page 9: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

9

Wavelength (Å)

5000 10000 15000 200000

T = 6000 K

T = 10000 K

Hotter blackbodies:• emit more energy at all wavelengths• peak at shorter wavelengths

The Black Body Radiation Curve

Wien’s Law Stefan - Boltzmann

Page 10: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Lecture 2: Light

The Doppler Effect

• Shift in the observed wavelength when the source is moving relative to the observer.

• Examples:– Sound Waves (Siren or Train Horn)– Light Waves

• Amount of the shift and its sign depends on• relative speed of the source and observer• direction (towards or away)

Page 11: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Lecture 2: Light

The Doppler Effect for Light

• Amount of the shift depends upon the emitted wavelength (λem) and the relative speed v:

• If the motion is away from observer

• Wavelength gets longer = REDSHIFT

• If the motion is towards the observer• Wavelength gets shorter = BLUESHIFT

Page 12: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Way to Measure Speeds• Observe the wavelength (obs) of a source with a known

emitted wavelength (em)

• The difference is directly proportional to

the speed of the source, v:

(For v very small compared to the velocity c of light)

rest frame

observed

5050Å – 5007Å 5007Å= 0.0086 · cv = 2575 km/s

Page 13: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

13

Doppler Effect in Practice

• Used by astronomers to measure the speeds of objects towards or away from the Earth.

• Other Uses:• Traffic Radar Guns:

– Bounce microwaves or laser light of known wavelength off of cars, measure reflected wavelength: Doppler shift gives the car’s speed.

• Doppler Weather Radar:– Bounce microwaves off of clouds, measure speed and

direction of motion. Strength of the reflected signal gives the amount of rain or snow.

Page 14: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Lecture 2: Light

Doppler Effect and the Shifts of Wavelength

– shift to the red if the object is moving away– shift to the blue if the object is moving closer– a way to measure speeds at a distance e.g. how fast a star or galaxy moves away or how fast a car is moving

Analysis of Light

• Energy which is emitted• Temperature of a body, e.g. a star• Motion of an object along the line of sight

Page 15: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

First Ideas

• Greek philosophers

e.g. Democritus (~460 – ~370 BC)

‘Matter consists of tiny particles (Greek atomos)

which cannot be further divided and they have

already the properties of the matter they build.’

What is Matter ?

Page 16: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Ernest Rutherford (1910):Experiments to get an idea about the internal structure of atoms.

Most of the mass is concentrated in a compact nucleus smaller than 10-15 m and containing at least 99.98% of the mass which is surrounded by negatively charged electrons.

radioactivematerial

α-particles

Page 17: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Rutherford’s Model of an Atom

not in scale!

Page 18: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

This only a simple model to providea sort of picture of an atom.

Just to illustrate the size and emptiness of an atom imagine:

the size of the Sun is scaled down to the size of the nucleus of an atom (~10-15 m).

The electrons would move around the nucleus (~10-10 m) in a distance which would correspond to ~25x the distance of Pluto to the Sun.

But remember, this is only a picturewhich tries to visualize an atom.

Page 19: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

WRONG

Electrons don’t orbit around the nucleus like planets around the Sun.

Electrons, protons, and neutrons are not little particlesbut they have particle and wave properties like light.

Page 20: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich
Page 21: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

How do we know all this?

Particle acceleratorfor example CERNnear Geneva.

~9 km

Page 22: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Underground there are labs with huge detectors whichrecord the decay of particles which are created whenfor example protons or electrons collide head-on.

Page 23: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Whereas the gravitational force is always attractive, the electromagnetic force can be attractive or repulsive because charges come in two types (positive and negative):

– opposite charges attract

– like charges repel

Atomic Structure

Page 24: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

• Atomic Structure– Atoms are formed by the electromagnetic force

- +r

221

r

qqF

q1 q2

Coulomb Law

Atomic Structure

Page 25: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

• The atomic nucleus (size ~10–15 m) consists of two types of particles of nearly equal mass:– Protons (positive electric charge)

– Neutrons (no electric charge)

+

Atomic Structure

Page 26: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

• The atomic nucleus (size ~10 –15 m) consists of two types of particles of nearly equal mass:– Protons (positive electric charge)– Neutrons (no electric charge)

• The atomic nucleus is held together by the strong nuclear force, the strongest force in nature, but with a very short range.

Atomic Structure

Page 27: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

The Strong Nuclear Force

0

F

r

Electromagnetic repulsion

Strong nuclear attraction,a very short-range force

Page 28: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Principal Subatomic Particles

Name Size Mass Charge

Electron (e–)

Point? 9.1 × 10–31 kg (= 1 me)

–1

Proton (p+)

10–15 m 1836 me +1

Neutron (n)

10–15 m 1838 me 0

Photon -------- 0 0

-+

Page 29: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Important Atomic Nuclei

• Hydrogen (H)– 1p, 0n– Weight = 1

+

Page 30: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

• Hydrogen (H)– 1p, 0n– Weight = 1

• Deuterium (D)– 1p, 1n– “heavy hydrogen”– Weight = 2

+

+

the isotope of hydrogen

Important Atomic Nuclei

Page 31: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

• Helium (He)– 2p, 2n– Weight = 4

+

+

Important Atomic Nuclei

Page 32: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

• Carbon (C12)– 6p, 6n (common)– Weight = 12

+

+ +

+

+

+Other isotopes havedifferent numbers ofneutrons C13 (7n) C14 (8n)

Important Atomic Nuclei

Page 33: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

latest count – 116 elements

Page 34: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Atoms

+

+- -

Massive nucleus held together by strongnuclear force. Electrons “orbit”, held by electro-magnetic force.

number of electrons equals

number of protons

nucleus

cloud ofelectrons

Page 35: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Ions

+

+-

Ions are “charged”Atoms, i.e.number of e- number of p+

Here two protons and only one electron

positively charged ion

Page 36: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Molecules

Molecules are collections of atoms that “share” electrons. Molecules are held together weakly by the electromagnetic force.

H2

Page 37: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Hydrogen

Helium

Oxygen

Neon

Iron

Page 38: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Atomic Structure

• Electrons are allowed only in

certain orbits which have

specific energies.

• Electrons can change orbits by gaining or losing fixed amounts of energy.

• This can be done by absorbing or emitting a photon of the correct energy.

Niels Bohr (1885 – 1962) postulated:

Page 39: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

The Atomic Model by Niels Bohr

Electrons are allowed only on discrete orbits with specific energies.Transitions between the orbits require discrete excitation energies.

Balmer discovered thatfor hydrogen the wavelengths for specific transitions are given by

Page 40: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

40

Emission/De-excitation An electron drops to a lower-energy orbit, emitting a photon.

Before After

photon

Page 41: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

41

Absorption/Excitation A photon is absorbed, the electron goes to an excited state.

AfterBefore

photon

Page 43: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

43

PhotoionizationA high-energy photon can remove an electron from an atom.

AfterBefore

highenergyphoton

Page 44: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Cooling by Collisions• Since photons can carry away energy,

photon emission can cool a hot gas.– Temperature is a measure of average speed

of particles in the gas.

Page 45: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Hot GasFaster Average Speeds

Cool GasSlow Average Speeds

Page 46: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

46

Step 1: Two high-speed atoms

collide.

Page 47: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

47

Step 1: Two high-speed atoms

collide.

Step 2: Some ofcollision energy is

used to excite electrons.

Exchange of kinetic for

internal energy.

Page 48: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

48

Step 1: Two high-speed atoms

collide.

Step 2: Some ofcollision energy is

used to excite electrons.

Exchange of kinetic for

internal energy.

Step 3: Atomsde-excite, losing

energy to photons,which escape.

Page 49: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

• The net result of the collision is that the particles are moving slower (so average speed of gas particles and temperature decreases) and photons carry away energy.

• Energy is conserved, but converted from one form (gas kinetic energy) to another (photons).

Cooling by Collisions

Page 50: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Atomic Structure

• Energy levels (allowed orbits) are different for each ion. Depends on the following:– Primarily on number of electrons– Secondarily on number of protons– To a small extent on the number of neutrons

• Each element has a unique signature

(like a fingerprint)

Page 51: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Model Hydrogen Atom

UV

Visible

Infrared

Page 52: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Atomic Line Spectra

Hydrogen

Helium

Sodium

Mercury

Page 53: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

If atoms are densely crowded, energy levels

are perturbed by neighboring charges

Page 54: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

• If atoms are densely crowded, energy levels are perturbed by neighboring charges random shifts of energy levels random shifts of photon energies broadening of spectral lines

Atomic Structure

Page 55: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Low Pressure

Medium Pressure

High Pressure

Solid, Liquid, or Dense Gas

Page 56: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

• If atoms are densely crowded, energy levels are perturbed by neighboring charges random shifts of energy levels random shifts of photon energies broadening of spectral lines

• Solids, liquids, and very dense gases emit continuous spectra

Atomic Structure

Page 57: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

What can we learn from analyzing light ?

• Temperature (Kelvin Scale)– measures internal energy content.

• The size of an object (L = 4πR2 σT4)

• Kirchoff’s Rules of Spectroscopy

Page 58: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Kirchhoff’s Rules

Kirchhoff’s rules are a set of empirical guidelines that tell us what happens when light andmatter interact.

1 a hot dense object produces a

continuous spectrum

2 a cool diffuse gas in front of a hot source produces an absorption spectrum

3 a diffuse gas seen against a dark back-ground produces an emission-line spectrum

Page 59: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

HotContinuum

Source

Continuous Spectrum Emission-Line Spectrum

Absorption Spectrum

Cool, DiffuseGas Cloud

Page 60: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich
Page 61: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Absorption-Line Spectrum

• Light from a continuous spectrum through a vessel containing a cooler gas shows:– A continuous spectrum from the lamp crossed

by dark “absorption lines” at particular wavelengths.

– The wavelengths of the absorption lines exactly correspond to the wavelengths of emission lines seen when the gas is hot!

– Light is being absorbed by the atoms in the gas.

Page 62: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

Emission-Line Spectra

• 19th century: Chemists noticed that each element, heated into an incandescent gas in a flame, emitted unique emission lines.

• (Fraunhofer, Bunsen, Kirchoff)– Mapped out the emission-line spectra of

known atoms and molecules.– Used this as a tool to identify the

composition of unknown compounds.– They did not, however, understand how it

worked.

Page 63: Lecture 11 Matter and Light Astro161 – Fall 2011 Dr. Matthias Dietrich

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