le châtelier’s principle example 2. nitrosyl chloride, nocl, can be prepared using the reaction:

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Le Châtelier’s Principle Example 2

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2NO (g) + Cl 2(g) Ý 2NOCl (g)

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Page 1: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

Le Châtelier’s Principle

Example 2

Page 2: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

Nitrosyl chloride, NOCl, can be prepared using the reaction:

Page 3: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g)

Page 4: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) DH = –77.2 kJ

Page 5: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) DH = –77.2 kJ

In order to obtain the highest possible yield of NOCl, one should use

Page 6: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) DH = –77.2 kJ

In order to obtain the highest possible yield of NOCl, one should use(high/low) ________ pressure

Page 7: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) DH = –77.2 kJ

In order to obtain the highest possible yield of NOCl, one should use(high/low) ________ pressure and (high/low)_______ temperature.

Page 8: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) DH = –77.2 kJ

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

Page 9: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) DH = –77.2 kJ

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

Page 10: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) DH = –77.2 kJ

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

Exothermic

Page 11: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) DH = –77.2 kJ

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

Exothermic

Heat term is on the right

Page 12: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) DH = –77.2 kJ

2NO(g) + Cl2(g) Ý 2NOCl(g) + 77.2 kJ

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

Heat term is on the right

Page 13: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) DH = –77.2 kJ

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

Page 14: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

Page 15: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

Page 16: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

Page 17: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

A high [NOCl]

Page 18: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

A high [NOCl]

Page 19: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

Page 20: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

3 molesof gas

Page 21: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

3 molesof gas

2 molesof gas

Page 22: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

3 molesof gas

2 molesof gas

If pressure is increased, the equilibrium will shift to the side with fewer moles of gas.

Page 23: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

3 molesof gas

2 molesof gas

If pressure is increased, the equilibrium will shift to the side with fewer moles of gas.

Page 24: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

3 molesof gas

2 molesof gas

If pressure is increased, the equilibrium will shift to the RIGHT.

Page 25: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

If pressure is increased, the equilibrium will shift to the RIGHT.

to produce a high yield of NOCl

Page 26: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

If pressure is increased, the equilibrium will shift to the RIGHT.

Page 27: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use (high/low) ________ pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

If pressure is increased, the equilibrium will shift to the RIGHT.

In order to achieve the maximum yield possible one should use HIGH PRESSURE.

Page 28: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

In order to achieve the maximum yield possible one should use HIGH PRESSURE.

Page 29: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

Should we use high or low temperature?

Page 30: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

Should we use high or low temperature?

to produce a high yield of NOCl

Page 31: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

According to Le Châtelier’s principle, a decrease in temperature will cause the equilibrium to shift toward the heat term.

Page 32: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

We are removing heat, so this reaction counteracts this stress by shifting toward the right, producing more heat.

Page 33: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

Using a low temperature

Page 34: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

Using a low temperature will cause this equilibrium to shift to the right,

Page 35: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and (high/low)_______ temperature.

We want the equilibrium to shift RIGHT

Using a low temperature will cause this equilibrium to shift to the right, producing a higher yield of the product NOCl.

Page 36: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and LOW temperature.

We want the equilibrium to shift RIGHT

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and LOW temperature.

Page 37: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and LOW temperature.

PE

Reaction Proceeds

Reactants

Products

Activation Energy

Page 38: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and LOW temperature.

PE

Reaction Proceeds

Reactants

Products

Activation EnergyIf the temperature is too low, the rate of the reaction will be very slow.

Page 39: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and LOW temperature.

A low temperature will produce a high yield of product,

Page 40: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and LOW temperature.

A low temperature will produce a high yield of product, but if it’s too low,

Page 41: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and LOW temperature.

A low temperature will produce a high yield of product, but if it’s too low, the rate of the reaction will be too slow to be practical.

Page 42: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and LOW temperature.

In an industrial process using this reaction, a low temperature would be used, but still high enough to maintain a reasonable reaction rate.

Page 43: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

2NO(g) + Cl2(g) Ý 2NOCl(g) + heat

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and LOW temperature.

In order to obtain the highest possible yield of NOCl, one should use HIGH pressure and LOW temperature.

Page 44: Le Châtelier’s Principle Example 2. Nitrosyl chloride, NOCl, can be prepared using the reaction:

The temperature should be high enough to maintain a reasonable reaction rate.

2NO(g) + Cl2(g) Ý 2NOCl(g) + heatIn order to obtain the highest possible yield of NOCl, one should use HIGH pressure and LOW temperature.