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r LDEPARTMENT OF Ir) ATMOSPHERIC SCIENCES UNIVERSITY OF WASHINGTON 0 SCIENTIFIC REPORT OFFICE OF NAVAL RESEARCH Contract N00014-67-A-0103-0007 NR 307-252 AN ANALYSIS OF CARBON DIOXIDE IN THE APRTIC ATMOSPHERE NEAR BARROW, ALASKA 2 1961 TO 1967 by JOHN J. KELLEY, JR. 69 . -- PRIL 1969 1 2 :--:...-\d [ . j.A

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Page 1: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

r

LDEPARTMENT OF

Ir) ATMOSPHERIC SCIENCESUNIVERSITY OF WASHINGTON

0

SCIENTIFIC REPORT

OFFICE OF NAVAL RESEARCH

Contract N00014-67-A-0103-0007NR 307-252

AN ANALYSIS OF CARBON DIOXIDE IN THE APRTICATMOSPHERE NEAR BARROW, ALASKA

2 1961 TO 1967

by

JOHN J. KELLEY, JR.

69

. -- PRIL 1969

1 2 :--:...-\d

[ . j.A

Page 2: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

AN ANALYSIS OF CARBON DIOXIDE

IN THE ARCTIC ATMOSPHERE

NEAR BARROW, ALASKA

1961 TO 1967

Final Report

by

John J. Kelley, Jr.

University of Washington

REPRODUCTION IN WHOLE OR IN PART IS -PERMITTED FOR ANY PURPOSE OF THE

UNITED STATES GOVERNMENT

Page 3: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

The North Meadow Lake Research Field

Station near Barrow, Alaska. August 1965.

Page 4: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

ABSTRACT

The results of the measurements of carbon dioxide in

air at Barrow, Alaska, are presented. Reference gas com-

parison data are tabulated, and methods of calculations

are discussed. The average daily concentrations of

atmospheric carbon dioxide are tabulated for the period

10 July 1961 to 15 September 1967. The diurnal variations

of carbon dioxide during this period are also presented.

Page 5: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

TABLE OF CONTEIMS

Page

List of Figures........................................................ i

List of Tables ..................................................... iii

Preface..............................................................

I Introductlon.................................................. 2

II Reference Gas Comparisons...................................... 2

III Recorder Scale Factors ......................................... 5

A. Definition.............................................. 5

B. Standard Computation for ThreeMuitually Compared Tanks.................................5

C. Determination of Index Differences........................6

D. Weighted Average Recorder ScaleFactors................................................ 7

IV Summ~ary of Recorder Scale Factors..............................7

V Index Values of Reference Gases................................8

VI Combined Scripps and Barrow Index

Values of Working Reference Gases........................8

VII Corapailfoot of Sczippa and BarrowIndex Values of Working ReferenceGases................................................ 9

VIII Index Valuea of Air.......................................... 10

A. Computation of Index Values.............................10

B. Manometric Concentration Scale..........................1U

Page 6: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

Page

IX Monthly Average Index of CarbonDioxide ................................................ 12

X Monthly Average Index of CarbonDioxide, Manometric ConcentrationScale .................................................. 12

XI Twelve Month Running Mean Concentraticnof Carbon Dioxide ....................................... 12

XII Values c'i Table 9 and 9a Referredto a Constant Datum ..................................... 13

XIII The Diurnal Variation of CO2 .. ... .. . .. .. .. .. .. .. .. .. .. .. .. . .. . .14

Tables ............................................................. 15

References........................................................ 163

Appendix 1........................................................ 164

Appendix 2........................................................ 166

Page 7: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

r

LIST OF FIGUPES

Figure 1 Map of Point Barrow vicinity showing the atmos-

pheric chemistry site near the ocean beach and the

North Meadow Lake field station.

Figure 2 Mutual Camparison Method for Tank Standardization.

Figure 3 Recorder Scale Factors (RSF'a) Adjusted to Standard

Barometric Pressure Versus Calendar Dates, Period

1-11, Arctic Ocean Beach Site.

Figure 4 Recorder Scale Factors (RSF's) Adjusted to Standard

Barometric Pressure Versus Calendar Dates, Period

13-14, Arctic Ocean Beach Site.

Figure 5 Recorder Scale Factors (RSF's) Adjusted to Standard

Barometric Pressure Versus Calendar Dates, Period 15,

Arctic Ocean Beaca Site.

Figure 6 Recorder Scale Factors (RSF's) Adjusted to Standard

Barometric Pressure Versus Calendar Dates, Period

1-4, North Meadow Lake.

Figure 7 Recorder Scale Factors (RSF's) Adjusted to Standard

Barometric Pressure Versus Calendar lates, Period

4-10, North Meadow Lake.

Page 8: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

Figure 8 Pecorder Scale Factors (PSF's) Adjusted to

Standard Barometric Pressure Versus Calendar

Pates. Period 10-17, North Mendow 'Lake.

Figure 9 Differences Between Index Values (ppm) Obtained

from Measurements at Barrow and Scripps, 1961-1963.

Figure 10 Differences Between Index Values (nnm) Obtained

from Measurements at North Meadow Lake and Scripps,

1965-1967.

Figure 11. Daily Average Concentration of CO, ]q61-1963.

Figure 12 Daily Average Concentration of Cn, 19f65-1067.

firure 13 T.elve-Month Punninp Mean of the Concentration of

Atmospheric CO 2 Near Barrow, A]aska.

Figure 14 "onthiv Average Concentration of CO 2 Near Barrow,

Alaska Peferred to a Constant Datun (.lanunrv ])~f).

rigure 15 Averape Diurnal Variation of cno, " ear Barrow, Alaslk,

1961-1Q67.

- tt -

Page 9: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

IT ST OF TABLES

Table 1 Refer,nce (as Comparisons - Barrov

Table In Rcf._rence Gas Comparisons - nlvcrsJtv of Vanshinpton

Table 2 Recorder Scale Factors - Barrow, Alaska

Table 2a Recorder Scale Factors - niver.,itv of W4aqhinrton

Table 3 Surunarv of Recorder Scale Factors, 1961-1063

Table 3a Summary of Recorder Scale Factors - ,Iutunl

Comparison Miethod, 1962-1963

Table 3b Summary of Pecorder S cale Factors - Mxuttal

Comrarison "ethod. 1965-1n67

Table 3c .ummarv of Recorder Scale Factors - Slldinp.

Pecorder Scale ractor ;, Barrow Alask' Carboti

Dioxide rroject

Table 4 Index Values of Vorkinp Reference Cases

Table 5 Combined Scripns and Barrow Index Values of

,orkinp. Peference Cases

Table 6 Comparison of Scrinis and Barrow Index Values

of Working Reference e

Table 7 Indices of Air With Continuous A nalvzer, 1961-163

Table 7a Indices of Air With Continuous Analvzer, 1965-1067

Table 8 onthlv Index of Carbon Dioxide (ann) at Barrow,

Alaska, 1961-1963

- iii -

Page 10: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

Table 8a Monthly hiaex of Carbon Dioxide (pm) at Barrow,

Alaska, 1965-1967

Table 9 m .thlv Index of Carbon Dioxide (rpm) at Barrow,

Alaska - M3nometric Concentration Scale, 1961-1963

Table 9a Monthly Index of Carbon Dioxide (rpm) at Barrow,

Alamkq - Mfanometric Concentration Scale, 1q65-1967

Table 10 Twelve Month Running Mean Concentration of

Atmospheric Carbon Dioxide at Barrow, Alaqka

Tahle 11 Values of Tables 9, 9a Peferred to a Constant Datum

(January 1960)

Table 12 Dliurnal Variation of Carbon Dioxide, Barro-, Alaqkp

1961-1963

Ta le 12c Diurnal Variation of Carbon Dioxide, ,larrow, Aaq.a,

1965-1967

Table 12b Averace Diurnal Variation of CaTrbon Dioxide,

1961-1967

- iv -

Page 11: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

PREFACE

This eport presents a summary of measurements of the concentration

of carbon dioxide near Barrow, Alaska, and at the North Meadow Lake field

station of the Arctic Research Laboratory, Barrow, Alaska.

This work was supported under a contract from the Office of Naval

Research (ONR 477(24)) with the Department of Atmospheric Sciences,

UTniversity of Washington. The analytical program was conducted cooperatively

with Dr. C. D. Keeling's (The Scripps Instzution of Oceanography, La

Jolla, Califarnla) atmospheric csrba--, diox-Th pogra. at Mauna Loa,

Hawaii, and the South Pole Sv' on, Ant, .

The carbon dioxide t rogi -. ,t ,-' j nitiated and maintained

from July 1961 to -ugust j J, . J. Pelilcy, .r. Operation of the carbon

dioxide i yzer was ;.ti:e . J. Unpt:r frDt September 1962 to March

I -i, ., rp . v-£1. lc: " 9t:. , t. Strzoschein.

T .- ca-- Q .-n dioxie prt:,.x.c at the N.-t, 14eadow Lake field station

, .* t..&.: , f, -iVer 1, Ja *.', !'o5 to September 1965, by

~2~> Ja.'.Y >r. : , pte!W- ik!: ". r 5 i,:" i.C0.U. , , and by W. wald from

c~r~ ~rI tob the U i of it ' o'.v 'Septe--ie 1967.

~?of ! ,:i - At4C Pe'ieaf-C. i ro Dr. M. C. Brewer

. -J.js .alf h.je ;'c-id, i u:u e :';.m.e to the project.

I

Page 12: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

I. INTRODUCTION

This report presents the final results of a program to measure the con-

centration of carbon dioxide in the atmosphere at Barrow, Alaska from

July 1961 to October 1963, and at the North Meadow lAke field station

of t>':e Arctic Research Laboratory, Barrow, Alaska from January 1965

to September 1967. The location of each site is shown in Figure 1.

Daily average values of the concentration of CO2 in the surface air

are computed from da.a derived from original strip chart records of a

continucus recording infrared gas analyzer installed at the station.

All relevant data and computations for the years ln6l through 1967

are contained in this report. The experimental method is described

in a Technical Report by Kellev (1964). Interpretation of the data

will be published in a scientific journal.

All data in this retort are final values. The procedure for

computation follows that used at the Scripps Institution of Oceanogranhv,

La Jolla, California as described in Research Rerorts I throuph VIII*.

II. REFERENCE ZA5 COITARISONS - TABLE 1, Ia

This table lists, in chronological order, both the observed scale

differences which were used to calibrate the gas analyzer, and their

conversion into index values proportional to CO2 concentration. The

*Coples of these reports may he obtained from Dr. Charles D. Keelinp,

S.T.O., La Jolla, California.

-2

Page 13: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

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Page 14: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

calibrations of the analyzer consisted of repeastd comparisons of pairs

of specially prepared gas mixtures of CO2 in nitrogen obtained from the

Scripps Institution of Oceanography. These reference gas mixtures were

stored in stainless steel cylinders called "tanks."

Under normal operating conditions ten comparisons were obtained by

alternately passing one gar of the pair, and then the other, through

the infrared analyzer for five minutes at the same flow rate employed

in the air measurements (normally 0.5 liters per minute), As soon as

one series of trn comparisons was run, one or both tanks were replaced

and another pair of tanks compared. This process was repeated, as a

rule, three times during the life of a "working reference" tank: at

the beginning of use, when the gas pressure was half depleted, and at

400 p.s.i., before return of the cylinder to Scripps for final calibration.

The scale difference between two successive traces, in recorder chart

ordinates, was read with a straightedge scale (30 divisions to the inch)

by drawing parallel straight lines through each of the traces belonging

to the reference gases. The successior of individual scale differences

for each tank pair was entered on data sheets. The calibrations described

served to establish the recorder sensitivity of the infrared gas analyzer.

They were also used to determine the index values of reference gases

known as "working references," used in connection with air m e-Irementa.

The general method used by the Scripps Institution for tank standardization

(Figure 2) was modified somewhat a& Barrow during the period covered

by the report. Initially, two reference gases were compared with air

every 30 minutes. Fro= 1962 to the end of the program in 1967, three

reference gases were employed. Two of the reference gases were used

-3-

Page 15: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

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Page 16: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

as comparison standards. The third reference gas was ranked as a

"working reference" and compared with air every 30 minutes. The "working

reference" was compared directly to the comparison standards, primary

and span (high or low), in the absence of a suitable secondary reference

at Barrow.

In Table 1, tanks related to each calibration run are identified by

tank numbers. They are listed in columns 1 and 2. Column 1 lists the

number of the standard tank; column 2 lists the number of the tank with

which it is compared. The average observed scale difference for each

tank pair is listed in column 3. A positive number indicates that the

compared tank, for that particular comparison, has a higher scale reading,

and consequently a higher C02 concentration than the standard; a negative

number indicates the reverse. The number of comparisons (not always

10) which entered into each average scale difference is listed in column 4.

The recorder sensitivity, determined by comparisons of the primary

and secondary standards, is expressed by a "recorder scale factor" listed

in column 5. The computed index differences, each with the same sign

as the corresponding scale difference, and the index value of the compared

tank, in terms of a prescribed, or "assigned" value of the standard tank,

are listed in columns 6 and 7.

Weighted average recorder scale factors, column 5, are copied from

column 7 of table 2. Index differences, column 6, were computed bv -

formula given in Section III-D.

- 4-

Page 17: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

The computed index values, column 7, are the algebraic sums of the

index values of the standard tanks listed in column 1 and the index

differences of column 6. The index values of the standard tanks are those

listed in column 7 of Table 6. In the case of the primary tanks designated

as I and Ihs or ILS in Figure 2, they depend solely on the measurements

made at Scripps.

The data listed in Table 1 are for the period 2 January 1965 to

18 September 1967 at the North Meadow Lake field station. The data in

Table la are for the period 1 April 1964 to 14 June 1967 at the University

of Washington. The data for reference gas comparisons at the Arctic

Ocean beach site from 6 January 1962 to 21 August 1963 are given in

Report 2 (Kelley, 1966).

The scale differences entered in column 3 of Table 1 and la are

copied from original entries on the reference gas data sheets.

III.RECORDER SCALE FACTORS - TABLE 2, 2a

A. Definition

The Recorder Scale Factor, RSF, is defined as the index difference

between two reference gases divided by the number of scale divisions

(30 div. to the inch) between the recorder chart traces for each reference

gas recorded in units. Ten divisions on the scale were equal to one unit.

The index of a reference gas tank is defined as a provisional CO2

concentration, or mixing ratio, in ppm based on the initial analysis of the

tank.

B. Standard Computation for Three Mutually Compared Tanks

Columns I through 4, except values with asterisks explained below, and

the last entry in column 4 for each calibration day, list selected data

- 5-

Page 18: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

copied directly from the corresponding columns of Table 1. These data are

employed, as shown below, to obtain daily RSF's.

The following format has been adapted from the Scripps (SIO Reports

1-8) scheme for tank standardizations, where the standard tank index

values have been assigned the symbols A and B , and the compared tank,

without such assignment, the symbol X:

Standard Compared Observed Scale No. ofTank No. Tank No. Difference Comparisons

A X IXI- (A] aB X [X)- (BI bA B [YI* (a or b)*

[i I (IxI - (A]) - (IX) - (B)) ((B] - A])

The asterisk on [Ylindicates the calculated value, and the brackets

indicate index values. The number of comparisons assigned to tY] is "a"

or "b", whichever is smaller. The observed scale differences were taken

from the averages of the individual chart scale differences (Table 1).

The observed comparisons and calculated values of any group of three

tanks, A, B, and X are set off in the table by boxes.

C. Determination of Index Differences

Index differences shown in Tables 2 and 2a, column 5, were obtained

from index values of the standard tanks as follows:

Tank Numbers Index Values Difference

11589 vs 18206 314.59 - 310.70 3.8911589 vs 18207 314.59 - 312.7d 1.8118206 vs 18208 314.59 - 312.40 2.1911589 vs 10071 -314.59 + 339.00 24.41

-6-

L _______

Page 19: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

The index values of separate tanks are obtained from Table 4.

D. Weighted Average Recorder Scale Factors

Column 6 presents RSF's computed according to the definition given

in section III-A. Column 7 presents the weighted average values of the

recorder scale factors for each calibration day. The index differences

in column 6 of Table 1 are computed by the formula:

Computed Index - (Observed Scale Difference)(Weighted Average RSF)Difference

IV. SU44ARY OF RECORDER SCALE FACTORS - TABLES 3. 3a. 3b. 3c

Values of RSF's are assembled in chronological order in column

5 of Table 3 for Periods I through 11, 10 July 1961 to 16 December 1961.

A graph for the data from Period I through Period 11 is shown in Figure 3.

During these periods, breaks in continuity were extreme due to the

development of a method for determining a standard operating method for

infrared analysis at the Arctic Ocean beach site. Each break is charac-

terized by a change in the span control on the infrared analyzer. There-

fore, discrete periods of relatively constant recorder scale factors are

created between span changes.

During periods 12 to 15, from 6 January 1962 to 21 August 1963,

(Table 3a) a constant recorder span setting was used and a mutual comparisrr

method of tank standardization was set up. These data are 9rhown In

Figures 4 and 5.

Table 3b presents a sumnary of recorder scale factors for the period

2 January 1965 to 18 September 1967 at the North Meadow Lake field station.

-7-

Page 20: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

4.5.II

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1961

Figure 3 Recorder Scale Factors (RSF's) Adjusted to StandardBarometric Pressure Versus Calendar Dates, Period

1-11, Arctic Ocean Beach Site.

Page 21: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

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Page 22: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

The data are derived by means of the mutual comparison method. Discon-

tinuities in the recorder scale factors occurred at vArious times during the

period of analysis at North Meadow Lake. Table 3c provides daily

recorder scale factors for the periods where discontinuities occur.

The data in Table 3c were produced by drawing a line between the end

point of the average RSF curve for one period to the starting point of

the average RSF curve of the next period. Daily RSF's were recorded and

defined as sliding recorder scale factors. The recorder scale factors

adjusted for pressure barometric for the period 2 January 1965 to 18

September 1967 are shown in Figures 6, 7, and 8.

All recorder scale factors were adjusted to a standard barometric

pressure of 30.00 inches of mercury (1015.9 mb). The following formula

was used:

Adjusted Recorder (Weighted Average RSF)(Observed Barometric Pressure)Scale Factor 30.00 inches of mercury

V. INDEX VALUES OF REFERENCE GASES - TABLE 4

This table presents the index values of all reference gases usedU

in the Arctic field program and at the University of Washington. All

of the analyses were performed at the Scripps Institution of Oceanography.

VI. COMBINED SCRIPPI AND BARJ'.OW INDEX VALUESOF WORKING REFERUNCE GASES - TABLE 5

This table sunnarizes the index values of all working reference

gases used at the North Meadow Lake field station from 1965 to 1967.

The data for working reference gases for 1961 to 1963 are given in Report

2, Table 7 (Kellev, 1966).

-8-

Page 23: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

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Page 24: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

Entries in columns 2 and 3 are the numbers of comrarlsons and wel%'hted

averepe index values based on measurements at Scripps prior to and after

Use. These data are taken from Table 4.

Tntries in columns 4 and 5 are the numbers of comparisons and weirhted

average index values based on measurements at the North Meadov. Lake

fieldl sr.-ton near Barrow, Alask-a.

flntries in columns 6 and 7 list the total number cf conarIF~on- and

veighted averape Index values based on all measuremients at S crinrs and

ait Parro-.

".T1. C(,'TARTrON OF SCRTPPS A'-D Bj~PR' P!TW\'V.ALtrr. OF "ORVINr RVFTrTrN'CTr CAsy-S -- TAV.Lr F.

This tahie rrvsents the results of all analvsis of Pnrrol-' reference

tais uqed In the di.'conarison i0, Air durinp lnf.5 to l167. 7 t is

Cir--Criqon forZ the years 1On'1 to 1"63l is Plven In 'ePnnrt 2, rTable P

0. ellev, 196A). The tablle cornares the results of the analysqes rade

ait the Fcrinps Tnstittlon of Oceanorranmhv iwith those r-ade at Tarrow.

Fhie total numher of indices and comnarisons sqhoi.'n in columnsq 2 and 3 arc

tal~en fret' the coluns headed cumulative runs Pand cumuantive Index< of

Table 4. The numb+er of cornarisons -ind reference tank indices In colur-r-

4 and 5 are conierl fror. columrns 4 and 5 of Table 5. E'ntrie-s in column

0 ire the di fferences bietwyeen index values in nartsz nor mill1ion I'v volume-l

C()2 obtAined froT- meastiremerits at PBarrov- and 5Qcrinns, aind represent

tho Indey. denarturo fror- qcrinns values. Thoev da.tA arp neotted in rl-uuro 0

for tiie nerio(I 1061 -19~63, and rifure 10 for thei Period 1I %5-l%(7.

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Page 25: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

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Page 26: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

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Page 27: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

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Page 28: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

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Page 29: LDEPARTMENT Ir) ATMOSPHERIC SCIENCES · r ldepartment of ir) atmospheric sciences university of washington 0 scientific report office of naval research contract n00014-67-a-0103-0007

VIII. INDEX VALUES OF AIR - TABLE 71 7a

A. Computation of Index Values

These tables contain all daily CO2 values at the Arctic Ocean

beach site and the North Meadow Lake field station for the period

1961-1967. Column 1 lists the calendar date of the analysis. Column 2

shows the observed daily average scale difference between the air trace

and the working reference gas trace. Column 3 lists the total number

of comparisons for the day. A full day consists of forty-eight half-

hour comparisons. Column 4 records the average barometric pressure for

the day. These values are obtained from the original carbon dioxide

daily data sheets. All of the data for the years 1961 to 1963, Table 7,

were processed manually. All of the data from 1965 to the termination

of the program in 1967 were precessed with the aid of an IBM 7094

computer. The Fortran 4 format is given in Appendix 2.

The observed scale difference in column 2 was adjusted to a standard

barometric pressure of 30.00 inches of mercury (1015.9 mb) by the

formula:

Adjusted Scale , Observed Scale x 30.00 inches of HgDifference Difference Average pressure for the day

and this adjusted scale difference is recorded in column 5.

Column 6 lists the RSF's to be used in converting scale uifferences

to index units. These are based on values listed in Tables 3, 3a, 3b,

and 3c which have been adjusted to standard atmospheric pressure.

The computed index difference in column 7 is obtained by:

Computed Index Difference = RSF X Adjusted Scale Difference

- 10-

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The working reference tank used in the comparison with air is listed

in column 8, its index in column 9. These data are taken from Table 5.

The daily average index values in column 10 are the algebraic sme of the

entries in columns 7 and 9.

In several instances reference tank changes were made during the

day. In these cases the daily index was computed by first computing

an air index for all of the observations with one tank in use, and doing

the same for the data taken with the replacement tank. These data are

reported separately in column 10. The daily index is taken as the average

of the two separate index values.

B. Manometric Concentration Scale

Throughout this report, the CO2 data have been reported in terms of

an index scale. It was established provisionally at Scripps in 1959

that the true concentration in parts per million by volume is related to

the ,.[dex scale by:

Manometric Concentration - (C - 311.51) 1.2186 + 311.51

wh.ere C 1 r the 1 'nucx value.

This equation is based on the absolute calibration of primary and

span reference gases by means of a mercury manometer. It is possible

that future manometric calibrations may result in further adjustment of

the index scale. The intercept value (311.51) is believed to be correct

within 1 ppm; the slope value (1.2186) within 0.03.

- 11 -

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U

This equation has been used to report atmospheric CO2 concentrations

in the reports and journal contributions listed in Appendix 1.

Column 11 lists the manometric concentration of the index values

reported in column 10 in ppm CO2 by volume dry air. The data are shown

graphically in Figure 11 for the period 1961-1963, and Figure 12 for

the period 1965-1967.

IX. MONTHLY AVERAGE INDEX OFCARBON DIOXIDE - TABLE 8. Ba

This table presents the monthly average index of atmospheric CO2

at Barrow, Alaska for the years 1961-1963 (Table 8), and 1965-1967

(Table 8a). Columns 2, 5, and 8 list the number of days for which air

index values are quoted in Tables 7 and 7a. Columns 3, 6, and 9 list

the monthly carbon dioxide index values.

X. MONTHLY AVERAGE INDEX OF CARBON DIOXIDE,MANOMETRIC CONCENTRATION SCALE - TABLE 9. 9a

The data in Tables 9 and 9a are the manometric indices in ppm

CO2 for index values quoted in Tables 8 and 8a.

The averages of the monthly values for each year are given in

columns 3, 6. and 9.

XI. TWELVE MONTH RUNNING MEAN CONCENTRATION

OF CARBON DIOXIDE - TABLE 10

A twelve-month running mean concentration of CO2 was calculated to

smooth out the seasonal variation in CO2. Concentrations for CO2

are presented for the period 1962 to 1967. Means are plotted in Figure

13 versus the sixth month of the appropriate 12-month interval. Least

squares regression lines were fitted to the data for the periods 1962-

1963 and 1965-1967. Equations for each regression line were determined as

- 12 -

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3 5 --- 1 1T I

1961

315 ""320 L

305

3o0 L L J L_. _ _ J 1 _ _

JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC325-

F 315'°z I

0 305 }

L 300J4N FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC

32.0 , ,____ _ q

C)300

JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC

Fu 1 i C o C 1 -

320 ':

315 "

310 " .. " >'

305K

300 - LJAN FEB MAR APR MAY JUN JUL AuG SEP OCT NOV DEC;

F'igure 11 Daily Average Concentration of CO2 1961-1963.

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S1965

315 " -I .*. o

- i

310 I

305 -

<x _L ___ _ ._L 1 I I I 1 1 1 L

JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DECE 325 . .-.,,

Q ,-: r . 1966

z0

315-L-I ,- - , ., .--

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C

0 Q________.

_ _

3oo Lr II I I i i LJAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC

r -- -'"-." ".' - - • - I 1967

U0 .. -

315

305 - --

300 _l. - L I i IJAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC

Figure 12 Daly Average Concentration of CO2 1965-1967.

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4-

nix-brr of m % . ln &ayue.- frc:T- t' Ie f i:tlt a m X 0.

s';,- tr i ht line for trt puio i9 2-1Th3 tr at.. a rat,- of

icc,., cf CC, in tht hrt.-:tc atupher( oi 0.02f. pur. per Manth. The

&:ra.'-.t line for the per'o, 19£4-i96 in.-liatea a rist c0 lncrease of

ct2 3f 'V. r,5t, ppm pe" tzont . 7 veig,;t@, Avf-¢n.st .--f th two rites

t Irre-,Ae JE CC... in th~e Arctic striosneve If ~CSp. mcr 'th

X1, VAi'S OF TAbLt 9 P Nl. 9a TO.....F . . '1" TA L-?! A 11

ThI.F. table .ises t .I? avs->t& 'trlLione ?tc i':,ea 9 and

~ai~ 'L . A -4!jMr C 1--st c~8Ll rtch ct~c: . h! concen-

0.!. 0%: f. 't r,. O'e t . h,2 e e - t~c rrtc' nrea increased --At

,,- cf C. ppT. p.ez , 'h (;.Ob ppm per month rate of increase

it, ba;ed o.r, the ohserva~cin *t Ha.na Ly- by Pales and Keeling (1965)

.nt Aint; ct by brcwt, _rid Keelina (1965), and by the rate given in

02 - for t;,e Arctic.

Co,4 wuste averages appear in column 5. Column 6 lists the departure

cl these averages frcm the annual meat, value of 314.69. The monthly

average concentration of CO 2 near Barrow, Alaska referred to a constant

datum (1960) is shown in Figure 14.

-13-

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0

cc

:3 *

C-

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-u c

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rI

XIII. T1;'£ DIURNAL VARIATION OF CO2 - TAI'TYr 12, 12a, 13c

The diurnal variation of C0 2 was calculntpd from the half-hourly

ob.ervations recorded on the oripinal carbon dioxide data sheets.

The ieturnal variations are based on hourly air indices by findinp, the

average index for each hour of the day for each month.

rPiure 15 and Table 12c show the averape diurnal variation of

CO, for each month based on the data for CO 2 from 1961 to 1967.

- 14 -

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321 -Tm-

~J

320- JANUARY

319

322

FEBRUARY

322

321 MARCH

322 --

321 APRIL

324 'E 323 -------.

MAYMI

z 321 -

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33 -z0 311

310

, AUGUST /312

SEPTEMBER310 --

316 , L

31 5- OCTOBER

318

i NOVEMBER

DECEMBER

318__._____•____,_,__'_______ i i i i . i j

C 2 4 6 8 10 12 14 16 18 20 22 24

TIME (hour of day)Figure 15 Average Diurnal Variation of CO2 Near Barrow, Alaska,

1961-1967.

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-4 V4 p4 -4 p4 v-4 -4 P-4 P4 p4 r4 4 P4 p4 p4 p4 -4 -4 p4 p4 0p4 p4 -4 -4

14 41V-4 I ~0 r'O

0 fIV4P % r400-400% 4en 4 -440 O0 %cm0

pV4

14t4M M% OOp404 4 M %Z4NNc 0% e 4 n I~

0 C%0 0 00 0 0 FO 0C0 0' P4 0' -' 24 -0 fA -4 0% P4 0' N% N

'.49

415

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NNNN N N " N -4 P4 P-4 N NNtqNNNNNN N N N N N N N e4 N

I N C4 N N N N N N N N N N N N4 N4 N N " N

UM %M LM N NNNN N M N7 kN NW N' N N % -N A N ) N N

N (4 C4 C4 C4 N1 N4 C4 q N 4 (44 e4 C4 N 4 . % N 4 0 1 C4 N C- C

W~ ~ N4 N N4 N4 N N 4 N-N N N- N N4 N4 N4 N N4 N N N N4 N4 NN

N r'4 N4 N4 N- N1 N4 N N N N N4 N4 N N N N~ q N N1 N4 N* N N4

C4 ~ ~~~~ N1 N4 -4 N N1 N4 NI N4 (4 " C1 C4 C4 C44 N N .4 4 N

9 4 4 ;; . 44 4C4 44 C 0 C44 :0; 44P- C4C4 " -4C* . .N C4 , - C -Z ,4-l N C,'C- N, C.," '

m - "c ne nmI nme nClr p ,mI)n Mr

1-4 C1 4C 40 - 40 1 A I V Qe l q"0

0 0000 0 000 -4- 4 4 4 -.- 4 4 NN N 4.) r4 C-

44

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.4 4 4 4 4 4 4 4 N 4 4 4 -4 4 4 c4 ' .4 0 ~4 N c4

-4 -4 -4 -4 4 -4-4 -4 -4 -4 -4- 4 -f 44-44 -4 -4 4 -4 4-4 -4 -4

-4-4 4 r4 4 -4-4- 4-4-4 -4 -4 -4 -4 -4 4 -4 4 -4 -1 -4 4-4 -

0-4 n 6A-t 4 0 00%00 00 ).0 00 000CW00 lk M

4 4 _") 4.) 4 4 C 14 4" 4")4 4.') .; C;)4)4 43 .C ") 4") 8 6) 4.' " 4 ' 4

9 -4- 4-4 4-.4 -4 4 -4 -4 -4- 4 4 -4 -4 -- 44-4 -44-4 -4 4 -4

'4

V aV! 1 '9 o D.' . ll . C 0:00 000000-rn-rIf!A'O V!0

4) N 0oC '). 4 N4 N4 P-4 r -4 4 - 4 -4 if)0'4 N .4

U') 4/' tn IT IT 4.4.41 IT4 'T Is Is.4.I4IT4.4IT4V4.-1 if') U') U'Mv4- 4- 4-4 4-4-4r-4 - 4 -4 -I 44 4 -4 -4 4 4 -444 4 -4 -4

-F4

*,4 N M % r, 0 O 0 - C1 en Lr %D - 0 ON0 4C14 n c

4 4 -4.4 4 --4-f -1 -4 r% C-4C-4 (-4

0f 0 0 0 00 0 0 -4 -4 -. 44 4-,-4 (N- MN N CN 4

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O~ CN (4N N I~ N N C4 N NCI ( C4 0N N N NNN

-4 4 A 4 -4 P.4 -4-4 -4-4 -4 .- 4 4 -4 1-4 4 A 4 .q 4 -4 -4

1-4

0' 0' 0'04 0'000 00% Go C) 0 Go. 0, 0 0 0 0' 0' C. 0V' C: 0' 0'. 0:

t - -4 -44-4 -4 4-4 -4-4 -4 -4 -4 -4 -4-4 -4 -4 -4-4

CO nMMMM r nMMM le

-4 -4-4 .4 -4 14 -4 -4 -4-4A-4 4-4 -4 -4 -4 -4 4 -4-4 -4 -4 -4 -4

'0-' C.4 . in0 '0. Go ms 0 - "r".4 in XO') r-. O a% - CO H O MI V

-4 - -4 4-4~ -4 4~4-4 14 -1 -4 -4 -4 -4 -4 -4 -1- 4 -

-414 A - 4 1- 4 - - 4C0t

15

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IL C4 N ('4 C-4 ClN N4 N CN C4 r4 0 4 C4 N N 4 C4 N " 04 C4 C4

-4t4 N N "0U r-4 04 CN C4 C-OCN C4 N, "'f CN 4 4 "t C4N

N N 4 N l N N . .N NNNNN N N N N Nm nm00ne nc"f nr me ,enf nmmmc

N1 N1 N N1 " N4 C4 N4 N N4 C N 4. C NN N N1 C1 N Nj N1 Nq N e

I - a 01%( % 0%'0-r- P r 1, D 0 0%-rl(r- f.

eq C (NN N .NNN.N.NN.NN.

0' O~~ 0% 0% OC000O 0% 0% 0% 0 0% 0% C%0 0:0% 0% 0% N0% 0 00 C 0 ON 0% 0% 0% 0 0% m% Ch 0 ON 0 0 0% *%-- 4 -4~ N N N N (4 CN r4 .-4 .4-4 .4 N .-4 .-4 -4 N .4 .-4 N .-4 -4

4f ca

t-

-4 1.4 -4 .4..4 -4 Pb4 . -4 4 ~N N eq

-a

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-4 M 0v- 0 0%- 0 -4 r4 4-4 C40 4% .- 4 -4-4 -

; (*4 C 4 C i N4 C4 N N N4 C4 N N 4 N4 C4 e4 C N N NC4N C4 NCN4 N N1 . . N . . . . . N N N N N . . . .

r4 "l C4 (4 (%1 C C4 04 "l t4 .l . . N C14 C4 "l C4 C-4 ( CN C4 C4

fn . " N Cq(nC' -4 4 -40 N - NN-Cl.4r- C4 N I N q M N T

N, N4 N 4 N N1 N4 N N- N N4 N NI N4 N N4 N NI C4 N% N' N N(Nnecn M (1)V) en mcn M m en m m m r) m m m cn m l% en

0 - 4Q 14a 7%(0O 0000 A N 1 z -

PN N4 N N4 N N4 N4 N4 N4 N4 N C N4 N: N4 N N NNN 40' 4 C4 C-4 C4 r4 C14 " "C " C4 'C 4 (C C-C4 04 V4 C C4

N , N N N 4 N N N r,~ -N ~ ~ ~ ~ ~ c N, N N NNNNN9N l C! N!

N C N N 6 C; C; C; :; C; N ; N ; N N C; 8N S N N ; ; NNC4 C4~ Clr ClrVe Cq C4 C4~ C C "ClA C C4 " C4 C%4 N "N C4~

en It~ tm Cl i l co cs 0 1.N-1 C14 m -. U 'D C-- 0' 0'C 0~ .4 C -4 m 4

14 ~ ~ 00 0 00 00 00 0 0 01 -- -0 -0 0 00 0 -4 4C I 1

'U160

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9-4,

C4 ~ ~ 9 61% C4 14 4% NO N4 Nr %n -4 1 1 NN N% - N1 %a V

O . -4 -4 44- -- 4 4 - -4 - - - - - ---m nmc )e n ne nc - nine n( ne

0r-

M MMMM M MM M MMMM M MM M M

0 '0 QM 0 0. 0 0 0 '0 P-1 -. 0 r4 '0 i' C4 c-4 c-4 C40 M

al 0 .1 Co .1 M . (4NNNNNNC

II0 161

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0' 00 cy O0 % 0, I 000 , O C'. 0% CA 0% 00 00 CI 0'0 CN47 0 0

en fn1( en fl ml ml en 4-* fn1 Cl en An en ml ml ml en mI m l el el

11: 1" r OC ) I'- %0 1 11 0 ' C-. P 0% 9 -. ! C 0 0' O% 0: 01 0'

r- I'C l IC l .r1 P, r- r- r- r, r- Cl r- r- r- r. r- (I

Z l- ~- ~- ~C -4 pl -4 -4 -N -4 -1 t - 4 -4 -4. -l 4 0 -t 4

ClC C l lil~ C l lC Cl el Cl (1' Cl C lCC Cl n l C (1

4 .) -4- - 4 --4 r4.44 -10C00 700 0% ONON 01 4 -4C4

W- 1(2 -- , 4 -4 -4-4 ;- 4 4-4 -.4 .4 4 .-4 .-4 -4 -4 -4 .-4 '4 '4.-4 -4

CC 0% (N, ClJ M4 40 C. U%.l' 7 (1n ('21( en4 M (M- CIA M%0 C-. e r-

06

0

'0 c 0- '.t r- C3 -. c0 ' C 0- 0- 0 c3 CA 0 '.0 . G4 .7 - C)

;m oe ooolo co o o o c o-4-Z4- 4 4- 1- -4 0 0 CY, N'01 NJN(N(DiC 0% a(CJ((-

P,- c44r 4 44 ;4 3r 44rC- ,C4C4C4C4 ..- - - - - -4C- 1 - I Q CAA

rn e c i -

v.-4 .4 r4 .4 r.4 '.4 v-4 -4 4i - 4 - 4 r-4 ~4 .4 .4 A. '.4 '.4 r4 ,. 4 .-4 ,C*4 ~C4 " , ' C,4A Alt1 ( C i4 C "1( r4 .C C C4 C4 cA "I C,4 c,4 c,4

<1 W 1 C, 00 CO . ON CO f CID(' C, Cl (I cl Cl (1 ( a l a l Cl Cl a

TZ -4 1' 41 -' l- ( t 4 4 4 - 40 -4 4~( C.4 -4 _4 -4 -j -4 .-

C.) 11 .- 4-m.-4. An--4-4.4.In47-4 4.. -4.4-4 A AN CI -'-'C.4

M3 C.) 'C en r-) M C- Ml n' C-'(2 C,) M 0 C. en . j,~ t '0 M. M. el' C-.C

~~~~L 00'C CQ.00 C0 0 0'C 0

QI. 3 '~ - ( C, C.4 " -4 -. -LI -.0 C-. -220 0. r C4 C4 -zt

-IG

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REMMENCES

1. Brown, C.W., and C.D. Keeling, The concentr tion of atmosphe,:ic

carbon dioxide in Antarctica, .. Gftovhys. Res., 70, 6077-6086,

1965.

2. Kelley, J.J., Jr., Analysis of carbon dioxide in the Arctit. ti-osphere,

at Point Barrow, Alaska, Tecchnical Repor.t, Office o aval

Research Contract 477(24), University of Washington, 1964.

3. Kelley, J.J., Jr., Analysis of carbon dioxide in the Arctic

atmosphere at Barrow, Alaska during 1961-1962-1963, Technical

Report No._2, Office of Naval Research, Contract 477(24),

University of Waehington, 1966.

4. Pales, J.C. and C.D. Keeling, The concentration of atmospheric

carbon dioxide in the Hawaiian Islands, .J. Geophys. Res., 70

6053-6076, 1965.

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APPENDIX 1

The following is a list of publications and reports based on the

atmspheric carbon dioxide program in the Arctic and at the University

of Washington.

1. Kelley, J.J., Jr., An Analysis of Carbon Dioxide in the Arctic

Atmosphere at Barrow, Alaska, 'mechnical RePort, University of

Washington, Department of Atmospheric Sciences, ONR 477(24),

1964.

2. Felley, J.J., Jr. and D.F. Weaver, Carbon Dioxide and Ozone in

the Arctic Atmosphere, Proceedings of the 16th Alaskan Scienice

Conference, AAAS, 1965.

3. Kelley, J.J., Jr. and E. LaChapelle, Atmospheric CarL-on Dioxide

Variations on Mt. Olympus, J. Geophys. Res, Vol. 71, No. 8,

1966.

4. Kelley, J.J., Jr., An Analysis of Carbon Dioxide in the Arctic.

Atmosrhere, Report 2, Technical Report, ONR 477(24), Department

of Atmospheric Sciences, University of Washington, Seattle

Washington.

5. Kelley, J.J., Jr., Carbon Dioxide in the Surface Waters of Puget

Sound, FinalRetport, prepared under Contract Nonr 477(24),

Department of Atmoepheric Sciences, University of Washington,

Seattle, 1966.

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i

6. Kelley, J.J., Jr. and S.M. Podge, Measurements of the Chemlcal

Constitution of the Atmosphere at the Blue Glacier Field Station,

Mount O1)wpus, Washington, Summer, 1966, Scientific Report,

Department of Atmoshperic Sciences, University of Washington,

Seattle, 1967.

7. Kelley, J.J., Ji., Carbon Dioxide and Ozone Studies in the Arctic

Atmosphere, Proc. of the ONR-AINA Arctic Drifting Stations

SyMposium, 1967.

8. KeIley, J.J., jr., D. Weaver, and B. Smith, The Variation of Carbon

Dioxide under the Snow in the Arctic, ECOLOGY, 49(2),

pp 358-361, 1968.

9. Kelley, J.J., Jr., Carbon Dioxide in the Sea Water under the Arctic

Ice, NATURE, Vol 218, No 5144, pp 862-864, June, 196S.

10. Kelley, J.J., Jr., Atmospheric Trace Gases and Suspended Particulate

Matter on Mt. Olympus, Olympic National Park, Washington,

J. Geophys. Res. (in press), 1968.

11. Kelley, J.J., Jr., Observations of Carbon Dioxide In the Atmosphere

over the Western Urited States, J. Geophys. Res. (in press),

1968.

12. Kelley, J.J., Jr., Equilibrium Partial Pressure of CO2 in the

Kara, Barnts, and Norwegian Seas, Progrfss Report, AINA-ONR,

ConLract 401, Department of Atmospheric Sciences, Universitv of

Waehington, Seattle, 1968.

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APPENDIX 2

FORTRAN 4 COMPUTER PROGRAM

This program is designed for use on the IBM 7094 computer. Data

for CO2 from five sources of air are entered into the program for each

half hour interval. The CO2 index for each half hour interval is

computed. Wind direction, wind speed, barometric pressure, and ambient

air tempe'ature are logged in the data output. A summary of the dat.

is given for each day as follows:

Number of half hourly observaticns

Recorder Scale Factor

Mean Index 1

Mean Index 2

Mean Index 3

Mean Index 4

Mean Index 5

Mean Index all levels

Mean barometric pressure

Mean temperature, OC

Location of levels I through 5

INSTRUCTIONS FOR KEYPUNCHING DATA

1. The first data card has the form: three blank spaces, then

the data of the day's run, e.g.:

17 March 1965

Other data may also be placed on this card and will be reproduced in the

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heading of the output just as printed on the card.

2. The second card contains the chart nual'er (3 spaces), reference

tank nwu.ner (6 spaces), and the index (8 spaces)

For example, if chart number 12, reference tank, 11633, and the

tank 1.,dex, 310.68, are the data, then the card reads as follows:

0120116330310.680

3. Data Cards: There must be a total of forty-eight cards;

i.e., one for each half hour of data even if data are missing for part

of the time. The pressure, temperature, wind direction, and wind

speed data mist start on the first card. All data must start on the half-

hour and alternate from there. For example:

Wind WindTime Ll L2 L3 L4 L5 Press. TeDir. Ied

0030 2.93 7.82 10.63 15.72 2.93 130 13 1.029 00100 2.83 7.89 11.01 15.47 2.83 - - -

Cards read:

002.93007.82010.63015.72002.9310.29032.1300 .002.83007.89011.01015.47002.8399.99

4. Missing Data:

a) If more than one of the index values are missing, punch 99.99

in the first five columns. Then skip to column 31 and punch in the wind,

temperature and pressure data on the half hour.

b) If only one of the index values is missing, substitute an average

value for the missing index value.

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c) if the pressure, temperature, and wind observations are missing

for a particular half hour, punch 99.99 in columns 31-35.

S. Program For'mat;

The Fortian-4 program and a specimen of the arrangement of the

data for one day are given.

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$JOB 3,5,6000 2002650$FORMS OUI PROGRAM,141326$MxCUTE IBJOB$IBJOB GO,MAPsmrrTC co'rwiC CARBON DIOXIDE INDEX PROGRAM-SUMMER 5 LEVEL VERSION(REVISED)

DIMENSION S (5,4B),AI(5,48) ,Kr(48),SDA(48),T(24),P(24),IWD(24) tIws1(24)

1 FORMAT(13,16,F8.3)2 FORMAT(SF6.2,F5.2,T4.0,213)10 FORMAT(1H1,4OX,38H DAILY C/.RBON DIOXIDE AIR INDEX VALLES/53X,15H B

1ARROW, ALASKA/48X,26H NORTH MEADOW LAKE STATION/I11 FORMAT(83H

12 FORNAT(19X,15H CHAPT N'UMBER =13,15%.,18H REFERENCE GAS W c16,8X,S8HlINDEX zF9.3/)

13 FORMAT(6H AST,10X,2L&H HALF HOURLY SCALE DIFF..,19X,23H HALF HOU1Y INrE:X, AIR,13X,35H WIND DIR SPEED PRESSURE TEMlP/IOX,3Hl 1.,24X,3H 2.14X,3H 3.,4X,3H 4.,4X,3H !.,SX,3H 1.,7X,3H 2.,7X,3H 3.,7X,33H 4 .,,7X,SH 5.,4X,33H DEGREES 101. BARS C.)

14 FORMAT(2X,14,1X,F7.2,F7.2,F7.2,F7.2,F7.2,4XF8.3,2X,re.3,2X,r8.3,21X,FS.3,2X,F8.3,SX,13,6X,13X.X,F7.4,3X,F5.0)

15 FORHAT(2H I*,16H DATA MISSING)16 FORMATUf/3H0 NUMBER OF HALF HOURLY OBSERVATIONS:FL4.0/26HO RECORDE

1R SCALE FACTOR vF?.3/1640 MEAN INDEX 1 v FB.3/16H0 MEAN INDEX 2 =F82.3/1640 MEAN INDEX 3 a F8.3/16H0 MEANi INDEX 4 a F8.3/16H0 MEAN INDEX3 5 = F8.3/28HO MEAN INDEX AT ALL LEVELS z F8.3/17H0 MEAN PRESSURE zF47.1,10H MILLIBARS/20H0 MEAN TEMPERATURE :F5.0,19H DEGREES CENTIGRA5DE/16H0 L1=16.0 METERS/ISHO L2*1.O METERS/iSHO L3*0.5 ML7ERS/16H06L420.25 KETERS/17H0 L5=0.125 METERS)

17 FORMAT(2H 14,16H DATA NISSING,77X,13,6X,13,4X,F7.4,3X,r5.0)18 FORNAT(1H,114X,7H PAGE 2)

RSF=1 .7201(1:0DO 50 J=1,48MJ~JiF(moD(mj,2))51,52,51

51 1(1:1(+30KT(J )::KK1=KI,+70GO TO 50

52 KT(J):K.50 CONTINUE200 ITR=0

READ(5,11)READ(5,1) ICNIRT,WRGDO 75 J=1,48

J 1=JIF(MOD(J,2 ) )76 ,77,76

76 X2=K1-ITR

IYTR:ITR+ 1GO TO 75

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77 IED52 S(,)I15

75 CONTINUEDO 99 J-1,48SDA(J)a-O.ODO 99 1:1,5

99 AM(,3)ZO.OAVvO .0AV2=.0OAV 3=0.0AV4O0.0AV=MDINCO.0DO 100 J=1,48A=SD(1,J)iF(A-99. 99)101,100,101

101 DIN:DIN+1.OAV1&AVl+SD(l,J)AV2.AV2+SD(24,J)AV3=AV3+SD(3 ,J)AVL=AYA4+SD( is,J)AV5=AV5+SD(5 ,J)

100 CONTINUEAVI=AV1/DINAV2=AV2/DINAV3=AV3IDINAV4=AVI4/DINAVS=AVS/DINAV =0.0DO 102 J=1,48A=SD(,J)IF(A-99.99)103 ,102,103

103 S:0.0DO 104 I=1,5AI(I,3)=WRG+(SD(I,J)*RSF)

104 S=StSD(I,J)

AV=AV+SDA(J')102 CONTINUE

AV=AV/DINAV1:WRG+(AV1*RSF)AV2=WRG+(AV2*RSF)AV3=WRG+(AV3*Rsr)AVis:WRG+(AV4*Rsr)AV5=WRG+(AV5*RSF)Av=WdRG+(CAV*RSF)DO 105 I=1,24T(I)=0.556*(T(I)-32.0)IF(P(I-15.00316.316,317

316 P(I)=P(I)/10.J)GO TO 105

317 F(I)=(33.864*P(I))/1000.O105 CONTINUE

PA0 .0TA=0.0DIT=0.0DO 125 1=1.24

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AzP(I)IF(A-99. 99).'26 ,125,126

126 IYITtDIT+1. 0PANPA4P( I)TAmTA+T(I)

125 CONTINUEPAx(PA*1000. )IDITTARtTA/DTWRITE(6 ,10)WRITE(6 ,11)WRTTE(6,12) 1CNIRTWRGWRITE(6,13)KlzODO 150 Tnl,49AnSD(1,J)IF(A-99 .99)151,152,151

152 JimJIF(MOD(J1,2))155 ,156,155

155 K12X1+1BzP(K1)ir(B-g9. 99)157,156,157

157 WRITE(6,17) KT(J),IWD(K1),TWS(KI),P(K1),T(Kl)GO TO 150

155 WRITE(6,15) Kr(J)GO TO 150

151 J1 aJIF(MOD(J1,2) )153,1S4,153

153 Kl=1I1+l

1AI(2,J),AI(3,J),AI(4,J),AI(5,J),IWD(K1),IWS(K1),P(K1),T(K1)GO TO 150

154 WRITE(6 ,14) KT(J),SD(1,J),SD(2,J) ,SD(3,J),SD(4,J),SD(5,J),AI(1,J),

150 CONTINUEWRITE(6,18)WRIM6,11)WRITE(6,16) DIN,RSF,AV1,AV2,AV3,AV4,AV5,AV,PA,TAGO TO 200EN])

SENTRY COTM$ DATA

I PAY 19671.280100670311.71C002.9300"1.82010.6301S.72002.9310.29032.1300130 2.83007.89011.01015.47002.8399.99002 .96007 .75011. 26015. 30002. 9610. 2qo32 140011002.93007.50011.05015.18002.9399.99003 .08007 .61009 .02015 .72003 .0810. 29032. 140011002. 90007 .75010 .96016 .17002-.9099 .99002. B9008 .09010 .75016 .78002. t~91O. 2903] .1500100 2.89008.20010.87017.39002.8999.99002 .83008. 57008. 57017. 88002.89310 .28031. 140011002.93008.87011. 23017.93002.9399.99002.94008.91011. 35018.29002.9410.28031.14U009002.88009.21011. 13018. 54002.8899.99002.90008.66011. 21019.23002.9010.28032.140008

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DOCUMENT CONTROL DATA - R & 0

UN I VLPS ITV OF WASH1,M UNC SSI OIL

AN A:AALYSIS OF CAFO,' DIOXIDE 1A~ ME ARCTIC ,1OSPiIEE A4EA'1 BAPPIt' j"LASKA1961 TO 1967

* OISCO-P 1-9 VC? TES Ip 01 o'*Po-t -d -l. diiie)

SCIE1NTIFIC REPOPT*~~ ~ ~ AwTo48(- " ,odl ntil at..

JOHN' J. KELLEY, JR.

0 11PORT OArIF IS. TO'AL NO 00 IIIIACO S

APRIL 1969 172 4B.CON YAC* oft rM.N1 NO 0. oGNATOWS RE(PORT NVVS~~l

rJOO04-67-A0103-J007 SCIENTIFIC REPORT #3L. "FlOjOc T .40

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01S UPPLEMCNI4A'* NOTIgS 12 SPONSORING -LITARY ACTVITYfOFFICE nr UI\'iAL rESEP"CI, C)DE 4~15ARCTIC PPOflA11'-!A"SHIJ(TON, D, C. 2 22 5

The results of the measurements of carbon dioxide in air At Barrow, AM~are presented. Reference gas comparison data are tabulated, and methods 0.-calculations are discussed. The average daily concentrAtions of atfnosnohericcarbon dioxide Are tabulated for the period 1r) July 1961 to 15 September 1-9(7The diurnal variations of carbon dioxide durinn this neriod Are also nresc-nt .

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