laser based sensor for detection of trace gases in the environment m. a. gondal, i. a. bakhtiari and...
TRANSCRIPT
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LASER BASED SENSOR FOR DETECTION OF TRACE GASES
IN THE ENVIRONMENT
M. A. Gondal, I. A. Bakhtiari and Z. H. YamaniLaser Research Laboratory & Physics Department
King Fahd University of Petroleum & Minerals
Gondal
Bakhtiari
Me!!
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Plan
1. Intro.: What is photoacoustic spectroscopy
2. Modifying the PA set up
3. Results for Ethylene
4. Future work
5. Conclusion
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Conventional Spectroscopy
Principal:Principal: Energy absorbed is determined by the difference (Io - I) / Io.
DetectorSampleLight Source
Io I
Introduction:What is photoacoustic spectroscopy
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Photoacoustic Spectroscopy (PA)
Principal: Principal: EnergyEnergy absorbed by the sample produces sound waves which are detected by sensitive microphone. The name PA is due to “Light Generated Sound”
Advantages:Advantages:Sample may be gaseous, liquid, solid opaque, powdered.Highly sensitive.
Light Source
Chopper Sample
Microphone
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LASER RADIATION
EXCITATION
HEAT
(VIBRATIONAL)(ELECTRONIC)EMISSION CHEM. REACTION
RADIATION EXPANSION PHASE TRANSITION
SOUND WAVES
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vent
Photoacoustic spectroscopy system using chopper for modulation
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Modifying the PA set up
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Stepping
Motor
P. Gauge
Valve
Vacuum Pump
Power Meter
Air FilterValve
LensTunable CO2 laser
Beam Splitter
Photoacoustic cell
MicrophoneGrating
`
Spectrum Analyzer
Newport micro stepping motor
grating controller
Variable Gain Low Noise Microphone
Amplifier
CO2 Laser Modulator. Variable
duty cycle (TTL)
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Resonant Photoacoustic Cell developed at KFUPM
G a s In le t G a s O u tle t
M icro p h o n eB u ffer V o lu m e
A co u stic F iltersW in d o w s
2122
,, ])()[(2
v
L
n
Rzmn
nmn z
R = 8 mm
L = 160 mm
It turns out that: 0,0,1 ~ 3400 Hz
Don’t worry about higher resonance frequencies, because they are beyond microphone response limit
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Noise Level with electronic Modulation
0
0.002
0.004
0.006
0.008
0.01
0.012
0.014
0.016
0.018
0.02
2000 2500 3000 3500 4000 4500 5000 5500 6000
Frequency (Hz)
PA
Sig
na
l (a
rb. U
nit
s)
Noise Level recorded with chopper
0
0.002
0.004
0.006
0.008
0.01
0.012
0.014
0.016
0.018
0.02
2000 2500 3000 3500 4000 4500 5000 5500 6000
Frequency (Hz)
PA
Sig
na
l In
tes
ity
(a
rb. u
nit
s)
Noise level in PA cell, filled
with pure nitrogen
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Results for Ethylene
1 3026 cm-1 CH2 stretch2 1623 cm-1 CC stretch3 1342 cm-1 CH2 scissor4 1023 cm-1 CH2 twist5 3103 cm-1 CH2 stretch6 1236 cm-1 CH2 rock7 949 cm-1 CH2 wag8 943 cm-1 CH2 wag9 3106 cm-1 CH2 stretch10 826 cm-1 CH2 rock11 2989 cm-1 CH2 stretch12 1444 cm-1 CH2 scissor
Fundamental frequenciesfor Ethylene (C2H4)
Molecular weight 28.05 amuFreezing point -169 CBoiling point -104 C
10.2 10.3 10.4 10.5 10.6 10.70
20
40
60
80
100
120
10.6
9610
.675
10.6
5310
.632
10.6
1110
.591
10.5
7110
.551
10.5
3210
.513
10.4
94
10.2
8910
.274
10.2
4710
.233
10.2
2
10.1
95
lase
r po
wer
(re
lativ
e)
wavelenght (m)
Spectral distribution of CO2 linesUse the 10 P(14) of CO2
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Time domain PA signal of C2H4
-40
-30
-20
-10
0
10
20
30
40
25487 25487.5 25488 25488.5 25489 25489.5 25490
Time (msec)
Am
plit
ud
e (a
rb. u
nit
)
FFT Spectra Ethlene with mechnical chopper
0
5
10
15
20
25
30
35
3000 3100 3200 3300 3400 3500 3600 3700
Frequency (Hz)
PA
Sig
na
l (a
rb. u
nit
s)
300 ppbV of ethylene under 1000 mbar of
nitrogen
Mechanical (chopper) Modulation
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FFT Spectra of Ethlene with electronic moduloation
0
10
20
30
40
50
60
70
80
90
2500 3500 4500
Frequency (Hz)
Sig
na
l in
ten
sit
y (
% f
ull
sc
ale
)
Time domain spectra using electronic modulation
-100
-80
-60
-40
-20
0
20
40
60
80
100
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5
Time (msec)
Am
pli
tu
de
(a
rb
. u
nit
s)
Electronic Modulation
300 ppbV of ethylene under 1000 mbar of
nitrogen
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Chopper Modulated Spectra of Ethylene
0
5
10
15
2800 3000 3200 3400Frequency (Hz)
PA
Sig
nal
(ar
b.
Un
its)
Spectra of Ethylene with Electronic Modulation
0
20
40
60
80
2800 3000 3200 3400Frequncy (Hz)
PA
Sig
nal
(ar
b.
Un
its)
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Calibration Curve for Ethylene
R2 = 0.9967
0
5
10
15
20
25
0 50 100 150 200 250 300 350
Concentration (ppbv)
PA
Sig
na
l In
ten
sit
y (
arb
. un
its
)
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PA Signal vs. Laser Power
R2 = 0.9979
0
2
4
6
8
10
12
14
16
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2
Laser Power (watt)
PA
Sig
na
l (arb
. Un
its
)
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1- SABIC funded project on detection of ozone.
2- Improve sensitivity.
3- Go out to the field
Future work
This is how the lab looks when we are
there!!!Domestically built CO2 laser
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1- The PA system is up and running with good dynamic range and sensitivity for the detection of C2H4.
2- We have a plan for future work, including detection of ozone.
3- We are open for ideas and need your support (esp. graduate students).
Conclusion
KFUPM is gratefully acknowledged for supporting this work
Thank you for your attention
.. بركاته و الله رحمة و عليكم السالم و
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Stepping
Motor
P. Gauge
Valve
Vacuum Pump
Power Meter
Air FilterValve
LensTunable CO2 laser
Beam Splitter
Photoacoustic cell
MicrophoneGrating
`
Spectrum Analyzer
Newport micro stepping motor
grating controller
Variable Gain Low Noise Microphone
Amplifier
CO2 Laser Modulator. Variable
duty cycle (TTL)