landfill investigation and waste characterization
TRANSCRIPT
462m SDMS DocID 000234913
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LANDFILL INVESTIGATION AND
WASTE CHARACTERIZATION
TROY MILLS LANDFILL
TROY NEW HAMPSHIRE
Prepared for
TROY MILLS INC Troy New Hampshire
Prepared by
NORMANDEAU ASSOCIATES INC Bedford New Hampshire
R-457
April 1984
TABLE OF CONTENTS
PAGE
FIGURES ii
TABLES ii
ABBREVIATIONS AND SYMBOLS iv
PLATES v
10 INTRODUCTION 1
20 SAFETY PLAN 3
30 MAGNETIC SURVEY 4
40 TEST PIT EXCAVATION 6 41 WORK PLAN 6 42 FIELD WORK 8
50 RESULTS 10 51 GENERAL 10 52 OBSERVED QUANTITY AND CHARACTER OF DRUMS 14 53 CHARACTER OF WASTES 16
60 DISCUSSION 22 61 EXISTING SITUATION 22 62 SITE HYDROLOGY 22 63 GEOLOGIC CONDITIONS 22 64 POTENTIAL FOR GROUND WATER CONTAMINATION 34
70 CONCLUSIONS 40
80 RECOMMENDED PLAN 41
APPENDICES
APPENDIX A Site Safety Plan APPENDIX B Work Plan APPENDIX C Magnetic Survey Report APPENDIX D Laboratory Analyses APPENDIX E Plates
FIGURES
PAGE
30-1 Delineated area of magnetic source material Troy Mills Landfill Troy New Hampshire
62-1 Ground water elevation Troy Mills Landfill and vicinity Troy New Hampshire 33
TABLES
41-1 Randomly selected excavation sites
52-1 Drum log for excavations on November 17 21 and 23 1983 12
52-2 Contents and condition of excavated drums 15
53-1 Sample log for waste samples obtained on November 17 21 and 23 1983 17
53-2 Summary of analytical results for waste samples obtained on November 17 21 and 23 1983 19
61-1 Analyses of Water Samples Collected from Monitor Well Ml 23
61-2 Analyses of Water Samples Collected from Monitor Well M2 24
61-3 Analyses of Water Samples Collected from Monitor Well M3 25
61-4 Analyses of Water Samples Collected from Monitor Well M4 26
61-5 Analyses of Water Samples Collected from Monitor Well M5 (upgradient well) 27
61-6 Analyses of Water Samples Collected from Monitor Well M6 28
iii
61-7 Analyses of Water Samples Collected from Monitor Well M7 29
61-8 Analyses of Water Samples Collected from Surface Water Station A (leachate seep) 30
61-9 Analyses of Water Samples Collected from Surface Water Station B (upstream) 31
61-10 Analyses of Water Samples Collected from Surface Water Station C (downstream) 32
64-1 Physical properties of phthalate esters 35
64-2 Physical properties of ethylbenzene and toluene 39
iv
ABBREVIATIONS AND SYMBOLS
EBP benzyl butyl phthalate degC degrees Celsius Ca circa D volume occupied by one drum DEHP di (2-ethylhexyl) phthalate DOP di-n-octyl phthalate E east eg exempli gratia (for example) EPA US Environmental Protection Agency HNU HNU Systems Inc photo-ionization detector LEL lower explosive limit LPP level of personnel protection MCL maximum contaminant level mg1 milligrams per liter ug1 micrograms per liter MSA Mine Safety Appliances Inc N north also number of steel drums NAI Normandeau Associates Inc OS over sample OVA Foxboro Century Organic Vapor Analyzer P estimated packing density of drums PPM parts per million RAI Resource Analysts Inc RCRA Resource Conservation and Recovery Act S south SCBA Self contained breathing apparatus SNARL EPA suggested no adverse response level T trace Troy Troy Mills Inc TVO total volatile organics V estimated volume of drum burial area VOC volatile organic compounds W west gt greater than lt less than
PLATES
Plate 10-1 Troy Mills Landfill with a backhoe excavation in progress in a former drum burial area
Plate 20-1 NAI field investigation team preparing for Level B activities during the drum excavation task Troy Mills Landfill
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
Plate 20-3 NAI field investigation team member undergoing personal decontamination at the hot line Troy Mills Landfill
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
Plate 53-3 Pigmentsludge deposits interbedded with soil layers in Excavation 8A Troy Mills Landfill
VI
10 INTRODUCTION
As a part of a phased program to investigate potential ground
and surface water contamination associated with the Troy Mills Inc
landfill Normandeau Associates Inc (NAI) has completed a waste
characterization at portions of the landfill that were formerly used for
the disposal of steel drums containing wastes (See Plate 10-1 for site
overview) The objectives of this phase of study included
1 Delineation of the horizontal extent of the drum burial area
2 Estimate ofthe number of drums
3 Characterization of the physical condition of the drums
4 Assessment of the contents of the drums and
5 Assessment of potential for ground water contamination
6 Development of a remedial action plan for the site
The work involved developing and implementing an extensive
site safety program conducting a magnetometer survey digging a series
of test pits on randomly selected sites laboratory analyses of selected
samples of soil and waste and formulation of a remedial action plan for
the site
The Troy Mills landfill is roughly eight acres in total area
and divided into two main sections One section is currently being
operated as a solid waste (non-hazardous) disposal area for fabric
scraps and trimmings as well as other non-hazardous materials such as
wood and broken tools The solid waste landfill covers about six acres
of the site An estimated three acres presently contain deposits of
solid waste and about three acres are being prepared for future
disposal A closed former steel drum burial area is the second section
occupying about two acres of the site The drum burial area is now
covered with soil and a light cover crop of grasses The drum burial
area received wastes between 1968 and 1978 The disposed drums are
reported to have contained various materials including waste
plasticisers pigments and organic solvents
Previous site investigations by NAI have included site
reconnaissance studies test pitting water quality analyses (NAI report
of August 12 1981) geophysical (seismic refraction and electrical
resistivity) investigations (NAI report of December 1981) installation
of a ground water monitoring system (4 wells) and sampling and analyses
of ground and surface water samples (NAI report of July 1982) A water
budget analysis was performed to assess the leachate generation
potential of the site (NAI report of September 1982) Concurrent with
the study of the drum burial area additional seismic refraction lines
were conducted and three additional ground water monitoring wells were
installed to further assess leachates from the solid waste
(non-hazardous) portion of the site
Laboratory Analyses were conducted by Resource Analysts Inc
(RAI) We also wish to acknowledge the assistance and cooperation
provided by the management and personnel of Troy Mills especially
Messrs Barrett Ripley and Carl Patten
20 SAFETY PLAN
A Bureau of Hazardous Waste approved safety plan for on-site
activities was developed for the waste characterization phase of work
because of the potential for encountering hazardous materials The
safety plan is presented in Appendix A of this report It assesses the
overall degree of hazard identifies specific potential hazardous
situations and presents guidelines for personnel protection and action
levels as required The plan was made available to all field personnel
during the field work
The magnetic and topographic surveys were considered to be low
hazard activities with a prescribed level of personnel protection (LPP)
of C or D depending on the results of air monitoring Level C proshy
tection involves wearing a full face respirator with organic vapor dust
combo cartridge Tyvek suit over work clothes rubber safety boots and
gloves Level D protection requires cotton coveralls or other work
clothes safety shoes safety glasses and possibly a Tyvek suit
During the drum excavation and sampling task which was
determined to be moderately hazardous Level B protection was preshy
scribed Level B protection requires that personnel wear SCBA (self
contained breathing apparatus) chemical resistance Tyvek suit steel-
toed rubber boots and gloves Plate 20-1 shows NAI personnel on the
site preparing for Level B activities Plates 20-2 and 20-3 show
personnel decontamination equipment and the hot line during the drum
excavation task
30 MAGNETIC SURVEY
To delineate the landfill area underlain by steel drums a
high resolution magnetic investigation was conducted by John F Kick
PhD consulting geophysicist The magnetic method was chosen over
other search methods because ferromagnetic substances (drums) were the
target objects and the majority of Troy Mills other wastes are
non-magnetic (largely fabric scraps) Dr Kicks report is presented in
Appendix C
Eighteen parallel rows of magnetic field measurements were
made along north-south lines The measurements were made at 10-foot
intervals along the rows This work resulted in a detailed contour plot
of the magnetic anomaly (Figure 1 in Appendix C) The source materials
which cause the magnetic anomalies do not usually directly underlie the
peak of the anomaly A shift is caused by the inclination of the
earths magnetic field and by dipolar effects Figure 30-1 shows NAls
delineation of probable source areas for the magnetic anomaly and
peripheral areas which may contain some magnetic source material The
plotted source area is generally the area between the peak of the
magnetic anomaly northward to the zero anomaly contour This is to
compensate for a southward shift of the peak of the magnetic anomaly
from the center of the source deposit The complex geometry of the
anomaly necessitated much interpolation between peaks and ridges
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40 TEST PIT EXCAVATION
41 WORK PLAN
A series of test pits were excavated in the Troy landfill for
observation and sampling More specifically the purpose of the
excavation was to estimate the number and distribution of drums buried
in the landfill determine the condition of the drums (full empty
crushed rusted leaking etc) identify types of buried and drummed
waste and verify the results of the magnetometer survey A stratified
random sampling method was used to choose 10 locations within the
delineated area of magnetic source material This insured that
excavations were distributed randomly across the landfill and that the
resulting data could be evaluated with a level of statistical
reliability Excavations were also selected in areas on either side of
the anomaly which were considered free of buried magnetic material and
also where drums were visible at the landfill surface
The following procedure was used in choosing the locations for
the random excavations The center of the delineated area of magnetic
source material was used as a base line The base line was drawn onto a
map of the source material (Figure 30-1) and then divided into ten
60-foot long segments Using a random numbers table a point-distance
was located on each segment (designated the random station) and a
line drawn at that point perpendicular to the base line segment Again
using a random numbers table a point-distance (designated the random
offset) measured along the perpendicular line located the point of
excavation The grid coordinates for each excavation were graphically
determined from the grid overlay and then field-located from the
surveyed grid intersections Grid coordinates and selection data are
presented in Table 41-1
It was judged that 10 excavations in the delineated area of
magnetic source material and two excavations out of the area would be
sufficient to characterize the site would produce statistically valid
TABLE 41-1 RANDOMLY SELECTED EXCAVATION SITES TROY MILLS LANDFILL TROY NEW HAMPSHIRE
BASELINE RANDOM RANDOM EXCAVATION GRID SEGMENT STATION OFFSET
NUMBER COORDINATE (FEET) fFEET) (FEET)
1 7E+15 65N 0-60 26 16
2 9E+5 13S 60-120 110 9
3 8E+0 31S 120-180 140 7
4 4E+5 48S 180-240 230 26
5 3E+8 45S 240-300 254 20
6 OE+8 45S 300-360 394 50
7 2W+15 24N 360-420 465 14
8 5W+6 42N 420-480 518 20
9 6V+14 74N 480-540 548 7
10 8W+5110N 540-600 611 31
Locations are plotted on Map in Figure 30-1
data and could be expected to be completed within a scheduled 2-3 day
work period
42 FIELD WORK
Test pit excavation was conducted in two phases On the first
day each of the 10 random locations (Excavation 1 through 10 Figure
30-1) was probed to a depth of 2 feet using hand shovels On the
second and third days excavation was conducted using a combination of
hand shovelling and power backhoe The NAI field investigation team
consisted of six members Four of the team members were equipped to
work at Level B for work in and near the actual test pit excavation
(See Plate 42-1) The other two team members spent much of their time
with personnel and equipment decontamination and refilling compressed
air bottles at the hot line Mr Timothy W Drew an engineer of the
New Hampshire Bureau of Hazardous Waste Management was present during
most probing and excavation work Mr Robert Lynch an experienced
Level B equipment operator of Jet-Line Services Inc operated a power
backhoe which was provided by Troy Mills Inc
An average excavation size using the backhoe was approximately
7-feet wide and 10-feet long Excavation continued downward until drums
were encountered or to a minimum depth of five feet Drums were careshy
fully uncovered and fully described A total of 17 samples were
obtained from uncontainerized wastes (solids dried sludges pigments
stained soil) and where possible from drums using EPA sampling methods
and protocols All of the excavations were backfilled upon completion
of this task
Each sample consisted of one filled 8-ounce glass jar sealed
with a Teflon-lined lid Samples were submitted to Resource Analysts
Inc (RAI) Laboratory in Hampton Falls NH for priority pollutant
analysis
Air monitoring was conducted during each excavation using a
Foxboro Century Flame lonization Organic Vapor Analyzer (OVA) an HNU
Systems photo-ionization detector (HNU) and an MSA combined oxygen and
explosimeter High explosimeter measurements were considered cause for
an immediate halt in exploratory work in the interest of personnel
safety
10
50 RESULTS
51 GENERAL
On November 17 1983 Excavations 1 through 10 were initiated
using hand shovels to a depth of approximately two feet A total of
two buried drums were discovered Excavation 13 was completed and a
third partially buried drum uncovered On November 21 1983
Excavations 1 through 9 were completed and on November 23 1983
Excavations 7A 8A 10 11 12 and 14 were completed An additional
42 drums were uncovered on the last two days of excavation
Excavation Locations Seventeen test pit excavations were
completed at locations which are shown on Figure 30-1 Two pits were
excavated at three of the locations Noteworthy aspects of the
excavation operation are
Excavations 1 through 10 were randomly located in the area of delineated magnetic source material (on-anomaly)
One excavation connected Excavations 4 and 5 This was done because of the proximity of Excavations 4 and 5
Excavation 7A was located immediately adjacent to Excavation 7 Excavation 7 was located on the boundary line of the anomaly and proceeded in a southerly direction off the area of delineated magnetic source material (off-anomaly) Excavation 7A was initiated in the opposite direction (north on-anomaly)
Excavation 8A was initiated one foot north of Excavation 8 after the latter was abandoned due to the detection of a potentially explosive drum
Excavations 11 and 12 were selected off-anomaly to the north and south (respectively) in areas considered to be free of buried magnetic material (drums)
Excavation 13 involved minor hand shovelling necessary to uncover a partially buried drum located on the periphery of the anomaly at the east end of the landfill
11
Excavation 14 was a surface scrape which extended from an exposed drum found to the south of the magnetic anomaly northward toward the anomaly
The details of each excavation are presented in Table 52-1
Drum Locations The excavation results support the
interpretation of the magnetometer survey with buried drums as the
source of the magnetic anomaly With the exception of a few strands of
wire found in Excavation 1 ferromagnetic materials other than drums
were not encountered during the test pit excavations
Drums were foundin 9 of the 10 excavations located in the
area of delineated magnetic source material (See Plate 51-1) No drums
were found in Excavations 11 and 12 located out of the area of
delineated magnetic source materials The location point for Excavation
7 was on the boundary of the anomaly Excavation 7 which proceeded
south away from the area of source materials was free of drums
Excavation 7A proceeding north toward the area of magnetic source
materials uncovered 6 drums Excavation 14 located just out of the
delineated area to the south produced unexpected results Five drums
were uncovered just under the surface in an area with low positive to
slightly negative total magnetic field values It is possible that
Excavation 14 was improperly located in the field If adjusted just 20
feet to the east it would be well into the delineated area It is also
possible that a negative dipole derived from the mass of material to the
southeast is cancelling positive readings at this location
Fill Material and Vegetation Cover and fill material was
predominantly fine to medium sand with an occasional boulder Till with
a siltclay component was also used as a cover particularly at
Excavations 6 and 7A This material was densely compacted and difficult
to dig through Excavations 7 11 and 12 each extending to a minimum
depth of 5 feet were characterized by uniform silt and fine to medium
sand and traces of dark discoloration Excavation 12 was located in
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1- laquo 3 = C 3 or cu ogt tn Q -shy
E L n CD J-gt o o gt gt s o ---shyDior 3 3
mdash Tgt o cr cr mdash mdash CU 0)
o a CD -a OLJ U CU
N CU COT 4JT3 poundmdash 0gt U V
raquoT3 mdash agt OJ gtgtcu laquo c c
T3 O
C
C
Zlshyo ui u- Li ^ ^~bullgt lt LJ
lAXvOX
VO X ^ X
Xcjltshy
lA x
CM
O x
3shy
_ X
r^5 X
_ X
CM X
mdash c^ C3 O
c a bullbull o c c
mdash 4J O I I 4J
01 JJ 4J 1C laquo
3 t- C raquoJ O L (D CU C mdash o a~o mdash o
i i
C J J W CO II) O W IT OC N 03 = OJJ C O I- -= C O
I I
o o
ON X mdash
CMr-raquo
00 Orshy
X CO
vo ro O C 5) JJ Jshy I- I gtJZ-00 s a o
LJ CO eo UTJ a- I I O C X J O gtZ 1 re O
i CM
LA
LJ
O mdash c imdash LJ lt a gt y lt 2
ltCO O
O^mdash
laquoshy rmdash
CM Tmdash
n rmdash
_^jshymdash CO
LJ
j ^ |
52
14
what appeared to be natural materials although its location on the
cleared and leveled landfill tend to contradict this possibility
Most of the landfill is vegetated by a thin layer of grasses
sedges mosses and annual herbaceous species The northeast corner of
the landfill is unvegetated and cover material appears to have been more
recently applied This section is elevated 4 to 6 feet above the rest
of the landfill and appears to have received a second newer layer of
waste A 4-foot thick layer of carpet waste was encountered in
Excavation 1 but not in other excavations This section is adjacent to
the newer active landfill The landfill area just west of the access
road crossing (near Excavations 7A 8 and 8A) was also unvegetated due
to relatively recent grading operations
Ground Water The landfill appears well drained as ground
water was not encountered during any of the excavations Excavated
overburden was damp from the recent heavy rain but intergranular macro
pore spaces were free of water
OBSERVED QUANTITY AND CHARACTER OF DRUMS
A total of 45 drums were observed buried in the landfill
Table 52-1 presents a drum log describing each excavation and the
observed drums Data on the contents and condition of drums is
summarized in Table 52-2
Of the total drums observed 15 (33) were crushed flat
Although these could possibly still contain small amounts of waste they
are probably considered empty under RCRA guidelines Thirty (67) of
the total drums discovered were uncrushed and capable of containing
waste Seven (88) of the 8 drums sampled contained liquid or sludge
waste material Thus at least 7 (23) of the uncrushed drums contained
some liquid or sludge waste
15
en C Cl
bullo gtraquormdash
c mdash a
o c re bull mdash c
~ o mdashbull 4Jmdash
10 0 mdash
gt O
ro CO
fcshy0
c
C
vgt 3 0
1 rea
-gt
mdash
3 o T3
lt-O
C j C
CB 3 TJ ii i- 3 mdashQCOa
ifl u bull c c
t_ o
mdash shyO
mdash
L re N
co
t-O
mdash
mdash lfl
V) O
CO N CO pound re
0 mdash
^1 10
ltP O C raquo
CM reO
o f shyi O
mdash mdash 3 - D
c 1
CD bulllaquo
mdash3
D mdash
1 C
Q CO
CD Ifl 4-gt CO
Q
CM
r-
Ul
Q Ul gt EC Ul CJ CO o t5bullpound
z O mdash
C Ci o^
O Cbulla 3v iC MW5 CO 4J3 u CS- Ifl CBC J C O - U
gt Cgt Omdash Oi O
U- 0) Ifl bullgt-gt 1 W C
to lt-gtT3 gtmdash
0) gt shyJ 0)
C OltJ bull O T 3 C D C P
133mdash 4J bull ifl tshy Vgt~ V a O V4JJ
C o
C mdash
O Ifl
3 fc 0)
i-
c
U) re gt
ai C mdash
C mdash
CO gt c o
bull to y 3 cc Q
ltbull-CB
1 4Jin
bullD reCD jCJJC TJCD mdashbullD bull mdash
CD 0t- u iflo ifl
0 C ^-
CB laquo
3 ltbull-
0)^shy
C
0 Cgt O
1 O CTl C
T3 1 mdash CB O
mdash CB mdash in J o 3 tfl C ^ CO 0 gtltgtshy
O gtgtc 01
CO 3 1- mdash C Cregtmdash laquo
TJ W TJ mdash i re traquo-
shyU mdash
O Q
COCO^^
mdash ^
mdash gt C 0gt mdashO ~ bull
Ul
o auO
CCUl
mdash K o tO Ul Q
mdash OT30Jj c mdash4Jt- Jpound O Wre c i re03 gt
lt~i- laquo o ai
0 ) 3 gt O ^crc Ifl - CO -^mdash
3 mdash Q iflmdash 1- O 3 3
O V O ltraquo-o laquoTJ
gt
T3 - o
gtgtmdash J-gtmdash
Dmdash
6-o
09 bull mdash gtpoundbulllt-gt
re a
Ul X t5
Cpound O Z
fl) mdash^ C B gttflOl3T3T3l_ 3 Q)O mdash mdash
tn mdash
shyD CB
mdash mdash
mdash tt
CO C T3 poundi mdash JCmdash re
^ C O C X CB ^ - S - C C O mdash re O Q DW4shy
re shyu O 1
O Ul X EC Ul mdash
x a^s ox
CO
^) Z
J
1-o t-Ul X r-u 0
o j c gt T3 i -gt c tu mdash c u r e mdash
- C D mdash T3 - C M mdashbullOJJQmdash re3inecrec u c r e o mdash lt~ bullz c~4J O CX t ^Jw o r e -gtgtOgtgtshy3 c j t shy re mdash mdash ret- i o Qmdash gtgtpoundgt a
i reraquo CD 0) bullbull Ifl t-
Q ) t ) O pound O ^ laquo gt - Ow re re ro re re -gt Q mdashc 5 shyu a j-gt D t- raquomdash mdashCB C re C CO 3Q mdash O mdash O U
Htshy ae cu coo)
1 O i i
shya shyo j CD C bullgt o mdash c o c o coco mdash plusmngt o ~a v c en CD
mdash C O
raquoCJ 3C c re amp- ogtCD J o 3 CC C I-Omdash 3gt O
3
O ro
Ul X 1mdash
u O
Ul o r-Z Ul
gtV~ omdash Dlshy ^mdash mdash wre3 i cc
mdash cr bull gtJJ mdash C mdashi QIgtJ^re a shyJQI- o 0mdash
O bullO 3laquo laquo
jjmdash ureoO mdash O N 0)rc3recomdash4Jt-4JpoundmdashC C mdashmdash mdash u
1
shya 0 -
mdash gtgt re-raquo-gt CUD laquo E CD
^ J-1
CJ eoc
4JCB CO
mdash O
C 1- C mdash O C B C B C E J mdash J ltshy shyo cn o o c o r e c shyU -gtO OJC D ifl roc
T3 3 I U 3 laquo-
Ifl CD 1 W ^J 4 J 4 J c -aiflj jc
CB C r e O C B lt-gt -Jgtcoraquo C C -WE O O ) ~ O O O mdash O
Ul O
c ui =gt z
o
1-CC Ul Q
Q z ^ Ul
2 gt Ul O
o Cpound
^ CO
Ul Q ^
z o
(O U S Q
Slt
t5 lt
Z5O
1mdash z ui
Qa Ul
CD 0-1
u m O_J
O2^ltUl
O CC Ul Q
VOCO
CNlA |3
VO ^
CJ |CO |
CJ CMI3 f~ rojO VO rolo
^
ymdash3 CC
roCM
ro O ICNj
ro rolvO ro ro
ro A
rolvO r-jO
00 C3N
ec a m
r3
CO
3 a ty r-
cc Q
(M CM
to z
m 3 c O
u _i co
U-O
O 3-IObull - I c y
fshy lt- ICO r- r-ICM O U lfN ro -mdashla1 f~ laquo- ]CO bull- -ICM O O J|O O
c U) CO
mdashbullre re
mdash re
mdash i ltC c tz
j lt
i lt
5 0 0 G O o o o o z bullU 4J J h- J shyJ tmdash tmdash
^33
J3 3
O 3
Q 3
_Cr(bull
shyC 3 t)
CC IP y
C2 zgt c J
1mdash O 5
53
16
The condition of the uncrushed drums was highly variable with
only 4 (13) rusted and decomposed to the point of structural weakness
These drums were found in Excavation 10 at the far west end of the
landfill which is believed to be the oldest section (See Plate 52-1)
Interestingly two almost new looking drums were also found in
Excavation 10 at a greater depth than the four rusted drums The
remaining 26 drums were observed to be generally intact and structurally
sound Some were dented partially crushed or rusty
CHARACTER OF WASTES
Air Monitoring An OVA and HNU were used to monitor the air
for concentrations of organic vapors during each excavation Above
background instrument readings indicative of contamination were
regularly recorded when monitoring the air just above or inside of
drums A general contamination of the ambient air in the workspace was
noted only during Excavation 8A where above background readings of +13
in the excavation pit and of +6 above the excavation pit were recorded
Explosimeter readings were obtained from three drums -- 10 lower
explosive limit (LEL) from drum sample 10A 20 LEL from drum sample 6B
and 100 LEL from a drum in Excavation 8 Instrument readings are
presented in Table 52-1 and Table 53-1
Visual Observations The following types of waste were
observed during the excavations
fabric waste (carpet waste)
crushed drums
drummed waste - liquid sludge and solid
uncontainerized dried sludges and pigments
stained soils
Fabric waste scraps of synthetic non-woven fabrics5 heavy
carpet-like fabric and backing material were found only in Excavation
17
CM
CO LJ fmdash O z
laquo 4J
u TO 4-gt
c bullmdash
k bull mdash E mdash 3 3 i-^ O
mdash TJ --raquo co co 4J
E CO O U L U
E 3 c T3
C O a o
is
CO c to 3
U
TO
E O t_ U_
o o
1 ltmdash c
mdash tmdash TO 4J bull C TO 0 O o c u 3 TO
t_ 0) 0 4J
U)
mdashOTOgt
Cw bull aco jc
N 4J a
mdash L Q) re co T E
CO
bullo gt egt mdash c mdash bull o ^^73 C E gtO O mdash 3 J-gtmdash N 4J L 3 mdash 1--C gttTC bull
CX 01C JJ TO O mdash
TO trt mdash t- E mdash 3 JJ a O Q
C I 0 X E mdash C mdash CO
mdash o laquo (D-O mdash O O bullbull B Ol o -cmdash e oic f~ to a (gt TD mdash
E 1- Cpoundmdash 3 O O CO P m T1
L u
T3 CO
lto sshy0 O CA W
laquoT3 O CO 0 C J= CO tlaquo Q bull 3 O Ol 1- C o mdash 3 E a
3 E E i- to
Z L
mdash bull mdash O 4-3 Cl Q
bullD 0) CO T5 N CO mdash C -P 1 0 U TO O mdash 4J Cfc
mdash U) c shybullgt O w C O Q (5 4J 0
3 -J bull U)
5 gt TO_ U
bull gt pound mdash 3 mdash L ro TD
JJ-D - CO TO laquo QO
C 0
^ 0) T3 mdash O
r to 3
O O L L
0
01 TO gt bull
tshy mdash OT3 mdash
CD O C N U) O mdash
TO O CO mdash C C
bull^ ~ CO TO TO gt U iJ
mdash C W to O
5 c c 4J 3 CO X LJ
^ bull bull0 laquolt- ej
TO CJ CO mdash C JJ
z u to mdash T3 4J ai TO CD C laquo bull c c ugt o cr 0) bull mdash CO mdash O bull gt JC TO ^ mdash Q CO O JJ O Q bull- CO to mdash to c Z CC O il mdash 4J gt
mdash Omdash O1O CD mdash U) TO C X mdash O CO C L mdash Cvv O W pound G CO C C
O gtgtgt C C mdash CO C TO CO 3 E mdash -J laquo 1- bullgt CO 0 to
bullo CO
cshyo bull
ugt C CO TO c w 4J-Q co e a c
mdash re TO in E to
Q
JJ c bullo
a LJ co E bull LJLJ
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ax
z o mdash1mdash Q
mdasha o CO LJ a LJ ~J
s CO
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bullmdash
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gtgt3 TO CT L mdash Olmdash 1 O CD mdash 3 a CT cshy re 3 a c- o
^j C CO E Ol
bullmdash CL
bull CO 01 D 3
U
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bullmdash av^ CO 4J IA TO 5
T3 CO C
bullD
mdash mdash O CO
3 CT
bullmdash ^
bulla CO L
4J
C CO o 3
(A C TO
Imdash
03
ai_ 3 a bullo bull mdash 05 3 O) 00
mdash mdash C c gtgt G CO
O O
bullo^ = c a 0)
E C O umdash u a L_ bull OlCD mdash
4J mdash
u) obulla o u) amp 5 c -a 7 O C mdash o mdash _ i- (0
CO E laquoJ
C
a
bulla c bull o bull
c bullQ CO
3 01
CT mdash mdash a mdash -v
t- Ol CC-D 0) 3
CJ raquo
x^ CO
bullo 3
lt) bull_
gtraquomdash CO O 1- Ui O)
bulla ^ c mdash mdash mdash TO co in
s^
COOlbullo3
U) mdash
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mdash TO
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c mdash
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03 shyogt
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o z
CO d _l O LJ LJ _J hmdash J C- LJ XZampS LJ mdash
Q mdash
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I 1 1 i
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o ltDpound 15 t-
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1mdash 3E LJ
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rshyC5 Z
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mdash s Cu a
gt 0
Q
mdash
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o
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CO o
o
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a mdash o o T~
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A
to 2T
f ro
CO X
O
Q
O O
Q
mdash O o o rmdash A
CO X
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CO X
o o ^
1
f
CO
o
to X
00
to X
CO
to X
CO
if
LJ
CO lt
LJ CM 51 r-rmdash
tmdash CM CM ^_ CM
CO CM ^x
CM (M CO CM
Q -
-^ ^ -
--
^ shy-
1
gtZLJ lt O C3 o-s - shy laquo raquo laquo S laquo 5 2 LJ Z
ui o -1 LJ
i mdash lt sectco z 1
ltT -^
bull~
lt
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deg
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^
lt 1
sect
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CO 1
CC
18
bull -a gtgt CD
CO S jj
0 0
CO O
bullo CD jJ
bullo z 3 O L
E 3
CD 1-gt o CO
jpound cshy x mdash o mdash
- 0 1 mdash bshy
4J 1 CO
Z u
CO mdash T3 CD CD
co E C mdash z bullD 73 4J O JZ = CD ltshyO C CD
CD 4J laquomdash C
bullO Qmdash U N ET3 bull mdash 0 Cmdash i- L re mdash oltmdash o
O 1 f-u gt Z 03 shy3 mdash CD
O O tshyo
O (Q C N O mdash shy
o agt O 4-raquo bull z in jz 3 CO 4-gt
gt Q ltshy 0
CD JZ N w Oshy- O
laquo ^ mdash 13 mdash m
mdash in 3
z s_ mdash
laquo
laquo CO T3 0 bull E in 3 3 1-L ^3
-TJ
re 3 O L
CD U -D SshyCD CO CO N 0) mdash 0-E S GO CD CO L
i
CO UJ gtmdash
z laquo w mdash ffl JZ CO 4-gt 4J JZ
4_) t_ mdash bull
cz QJ co jZ C C mdash 4J
re (uS a z z
OX) mdash a) O W E
Z O O JZ bull CL V E
C (~ mdash r re O CD
obullz
-J VI O 4J z re o gt o jt o 5
mdash tshy Q mdash CO 0 Q) mdash j j a C5 E U3
mdash CO mdash 4JCO CO E
CO
JZ 0 3 mdash t_
E Ot3 O L
bull
C 3 3 U L
E OT3 O LshyU
Z JZ 0 0 gt 0 o c 3)
T3
1 I
bullz o mdashfmdash Q
mdashfV
O CO LJ O
LJ _J Q y
CO
C CO
mdash mdash 0 10
bullc bull CD 0) C 4-gt mdash w CO CO 4-1 to
gtJ CD Sshymdash CD Q-O L- gt
CD 4^
~mdash
^
^ bull
bullD 4J C C CO CD
E -3 Ol CD mdash - a bullc cu mdash 4J mdash CO
v^4-gt C 0)E01 Q
agt 3 ^ j3
D CD bullbullbull lpound mdash ltn
t
bullabullmdash 3 CT _
mdash
O
mdash a
bulla
co (0
T3 0) C
a 4J UJ
jpound O CO
bull 05 4J CO CO
^s^
^gtc CD E C)
a c CD 0
3 O c a
O CO vgt gt
O CO co j
3 a CO
O CO
i
COK-IOLJ LJ laquoJ ^ i 1 i
O rmdash 1 1
C-ld to o z
XZS9 jj mdash a
E
i UJ bull~ CO CO
c V
co in
bullo
1mdash bullz LJ s
o Q bull
3)
~
ro
^
r-i
4
O o CM
1
O
1 o ro
Ol c
13
CD
Ct
gtgt imdash CO
tmdash CO (U
bullz ~ CO CO CO O
0 o ^^
X X o 0 O O Ttrade 1
O
|
C CO a
^ gtO
ashyf
o o A O
o T3 ffi
bulla 03 3 C
C o o 1
lt
LJ tshy
o
a
CM
^~
laquobullgt CM
-
fshy
ltshy
fO CM
-
flCM
rlaquoshy
^
3 3D- cr CD ltu CD U C Z CO 0) jZ N 4J Z
C 0)
0)u z
CD n oL Q
a CD ltO pound2 o mdash s CO 00
O o _
CD C ZE
3
E O CO CD ti O
sshy laquo a ^3 ^ T3 SEE C re re c a z gt c
LJ a
clt
-J LJ
z 2 lt o O
1 1 lt o
CC ^
lt^(V
E I I i I I
L lt 13 O 00 CO
CO Z 05 CO Ch ~ rmdash
19
c o C M O - L bull O C M bullmdash co ujn iiupeo CM
CM h- fO i- X
bull k_ c _Jlaquo _Jo
laquok ro
mn i LJOJ 140 CM
3-
bull CM
m CM
tshy r- ro CM
CV
sshy = sO r sshy~ - 2
CM ^ ~ ~ mdash rs
a
2
ou tz S S o w S S o | ^
O gt atshy
mdash o r gtgtlt_
CM 1
m raquo
rmdash r- i- o o o r^ CZ LJ
auazuaq |ua oCO
laquo o PO laquo
o J
o bull
O ~S 5
LJ
O apiJO|L|3 au3|Aq5auj H- r-
J 0
CO
Z
0
a 5 ausni oa O O O J ^ O O r o r~ If o ^rO VO ^ f~ VO deg-
- ^ bull rshy
O o
ro
LJ ^ CM 3 lf kmdash o Tmdash shy
O 1
_J-i
5
O aueu3aojoiuoiu-i i L 1mdash
lts
o o bull
^J mdashZ
0 0 0 0
0 O
^UJ g sauaiJx CO O CM
^ mdashS W
^^ S
5 Tmdash
bullft S
LJ =CO ^CltLJ3Z
^|
i IjJ
ltrshy UJ
LJ ^
shy _jo gt
auazuaq o o
mdashshy
o L-
ia O
pound3 bull
mdash O
lt
lt 3U BL|3 3OJ O I U ^ P mdash l l p^
C N
poundC M- CM 1 3 1mdash H|
W _J
aua iXquaojomoi ja bull LJ mdash mdash O
Q _JZ lt lt C _J to
a)e | eu3Ljd | X ^ O O mdash Umdash 1 p
ooCM
o o OJ
VO
o o O raquo
vO
o o
CM laquo
~
IshyOishy
bull r
bullO
O C 3
E V_ () gt- mdash1 mdash _l lt ~
lt gt
z n o pound
o o
DlllllH 34B 1 eH-gtM -|A3nq lAzuaq
oOCM
o O O
CMrmdash
o O O
ro laquomdash
o (O
o O
CO
CM
o O r~
gtO
o O
(O
mdashV^
rgtE
C
o Jj
o C
C bullc
o i
ltshy
1-o
i-O OCC -J C S O
hmdash gt-poundi ltc bull ^ ro
sects
lt 2
mdash
hlaquo
J
3 4 C J cI^JLJU
( iJxsn iXuia-2 ) s j q
o o C
laquo C
o o
M laquo
O f ro
o o o o
O O O laquo ^
M O O r- LA
o o o
O t ^
O e o
o r
O laquo
O
o ~
i
o o
A O laquo
C M
o o O
( M ^
o o O
C^ 0
laquo C
i raquo
~gto
E c
lt O 1- O bull
CMi
M s ja i cu^dcrj^ ^ 0CM^
0 bull-
ro
J u- e
u-J
_u ^C3 lt1 CJ1 mdash1 lt
=lt r r
lt= - - J L - N O K S c C z -
^
20
1 (See Plate 53-1) This is the predominant waste material currently
being disposed of in the active landfill
Crushed drums were distributed throughout the original
landfill and were found in Excavations 2 4 4-5 7A 8A and 14 Some
drums such as those found under the road in Excavation 7A may have
been crushed by heavy equipment operating in the landfill Others like
those found at depth in sandy fill in Excavation 2 appear to have been
crushed before burial Drummed liquid and sludge wastes are also
distributed throughout the landfill (See Plate 53-2) They were found
in Excavations 1 4 5 6 8 and 10 These wastes are discussed below
One sealed drum was openedand found filled with refuse -- paper cups
towels paint covered rags etc One open and partially crushed drum
contained a dark granular solid waste This material was sampled
(Sample 10B) and found to be nonhazardous
Small deposits of dried pigmentsludge were found in
Excavations 3 4 6 9 and 13 Discernible layers of pigmentsludge and
stained soils were present in Excavations 7A 8 and 8A (See Plate
53-3) Of particular note was a 2 to 4-inch thick layer of
grey-colored dried sludge found at Excavations 7A and 8 All of these
wastes were sampled and the results are discussed below
Laboratory Analyses
Laboratory analyses were performed on 10 selected samples
obtained from both containerized (drummed) and uncontainerized wastes
Samples were analysed for 3 metals and 87 priority pollutants including
11 acid compounds 45 baseneutral compounds and 31 volatile organic
compounds Table 5-4 summarizes the analytical results and the
laboratory data sheets are presented in Appendix D
Of the 45 priority pollutant baseneutral compounds only 4
were identified in the samples that were analyzed Baseneutral
21
compounds and particularly phthalates were the most prevalent
chemicals and also were reported in the greatest concentrations The
highest levels of naphthalene (1200 ppm) bis (2-ethylhexyl) phthalate
(110000 ppm) and di-n-octyl phthalate (6200 ppm) were found in sample
4A a translucent red liquid obtained from a drum The highest
concentration of benzyl butyl phthalate (13000 ppm) was found in sample
6B a clear liquid and pink sludgepigment obtained from a drum
A total of 8 volatile organic compounds were identified The
highest levels of benzene (100 ppm) xylenes (19000 ppm) and
ethylbenzene (5300 ppm) were found in sample 5A a clear liquid
purple-grey sludge obtained from a drum Toluene was found in highest
concentration (12000 ppm) in sample 1A a purple-grey thick opaque
liquid obtained from a drum Methylene chloride (13 ppm) was
identified in greatest concentration in sample 8A-C a purple stained
soil and powdery waste Sample 10A a purple liquid obtained from a
drum was the only sample found to contain 1-1 dichloroethane (2000
ppm) Finally trace levels of trichloroethylene (sample 10A) and
111-trichloroethane (sample IB) were also reported
Samples were tested for three metals - cadmium zinc and
chromium The highest concentrations of cadmium (2200 ppm) and zinc
(5700 ppm) were found in sample 4A a translucent red liquid obtained
from a drum The highest level of chromium (52 ppm) was reported in
sample 5A a clear liquidpurple-grey sludge obtained from a drum
22
60 DISCUSSION
61 EXISTING SITUATION
Under existing conditions relatively small quantities of
volatile organic compounds (VOC) are indicated to be leaking from wastes
buried on the landfill site To date ground and surface water
monitoring results indicate relatively low concentrations of VOC in the
ground water and below detection limits in the adjacent brook (See
Tables 61-1 to 61-10) The results indicate that no potential health
risks from VOC and other constituents currently under observation are
being caused by the landfill operation to down stream surface water
users It would be prudent for Troy Mills to continue to monitor the
quality of Rockwood Brook upstream and downstream for VOC and on the
basis of waste analyses (previous section) to monitor ground and
surface water points for toxic metals and baseneutral compounds
62 SITE HYDROLOGY
An analysis of the hydrology of the landfill site was
performed in 1982 (NAI report of September 1982) The subwatershed that
contains the landfill site is (about 44 acres) a small fraction of the
watershed area that contributes to Rockwood Brook above surface water
sampling point C (about 1650 acres see Figure 62-1) This indicates
that most of the flow of the brook at point C (about 97) is contributed
by upstream watershed areas Thus leachate discharging into Rockwood
Brook from the landfill site can be expected to be diluted by over 30
times its volume This factor and the volatilization which naturally
occurs results in parameters detected in the Troy Mills monitoring
wells often becoming undetectable when they enter the brook
f 5
Geologic conditions which were defined in the NAI report of
July 1982 indicate that permeable deposits of sand and gravel overlie
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27
TABLE 61-5 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M5 (UPGRADIENT WELL)
Parameter Date Sampled 11-22-83
Specific conductance
pH2 81
Dissolved iron mg1 036
Dissolved manganese mg1 010
Chloride mg1 10
Phenolics mg1
3
023
Identified volatile organics
None identified ND
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (yg1)
28
TABLE 61-6 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M6
Parameter
Specific conductance
PH2
Dissolved iron mg1
Dissolved manganese mg1
Chloride mg1
Phenolies mg1
Identified volatile organics
11-dichloroethane tetrachloroethylene 111-trichloroethane
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vg1)
Date Sampled 11-22-83
152
lt002
29
6
0002
27 trace 140
29
TABLE 61-7 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M7
Parameter Date Sampled 11-22-83
1 47 Specific conductance
pH2 62
Dissolved iron mg1 002
Dissolved manganese mg1 0026
Chloride mg1 gt2
Phenolics mg1 0070
3 Identified volatile organics
111-trichloroethane 5
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vig1)
30
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34
glacial till and bedrock The sand and gravel deposits form a permeable
conduit through which leachate from the waste burial areas migrates
The permeable deposits lie in the area north of monitoring well M-l (See
Figure 62-1) In general the water saturated thickness of the sand
and gravel in the vicinity of the north-south access road is 6 to 12
feet
64 POTENTIAL FOR GROUND WATER CONTAMINATION
641 Estimated Quantity of Drums
The test pit excavation and sampling in the drum burial area
indicates a potential source of ground water contamination for the
future Many of the drums encountered were in fair to good condition
and contained liquid wastes An estimate of the number of drums in the
deposit was made with the following assumptions
1 The complex magnetic anomaly was simplified into a geometric solid 600 feet long 40 feet wide and 10 feet deep with a volume (V) of 240000 cubic feet
2 Each steel drum (D) occupies 105 cubic feet (including voids)
3 The density of packing (P) was assumed to be 50 of the packing that can be achieved with perfect cubic packing
THEN
N = estimated number of steel drums
N = (VD) (P)
N = (240000105) (05)
N = 11429 drums
The results of the drum excavation work provides a basis for
estimating the potential for specific types of chemical loading In
general three main classes of chemical substances were identified in
35
the drums The chemical substances included baseneutral extractable
organic compounds (mostly phthalates and lesser amounts of naphthalene)
volatile organic chemicals and metals
642 Phthalates
The phthalate esters found in the drums include
bis (2-ethylhexyl) phthalate ^0^3 benzyl butyl phthalate di-n-octyl phthalate Jd~7
Bis (2-ethylhexyl) phthalate was found in the highest
concentration at 110000 ppm (11 percent) Benzyl butyl phthalate is at
the second highest concentration 13000 ppm (13 percent)
Characteristics of those phthalates found are presented in Table 64-1
TABLE 64-1 PHYSICAL PROPERTIES OF PHTHALATE ESTERSshy
di-n-octyl bis (2-ethylhexyl) butyl benzyl DOP DEHP BBP
ALTERNATE o-Benzenedishy di (2-ethylhexyl) benzyl butyl NAMES carboxylic phthalate phthalate
Molecular Weight 3910 3910 312
Melting Point -25degC -50degC -35degC
Boiling Point 220degC 386 9degC 377degC
Vapor Pressure-mdash lt02 torr (150degC) lt001 torr (20degC)
Not
2xlO~7torr (20degC) Available
Solubility 3 rngfc (25degC) 04 mgfc (25degC)
58
13 rngH 48
Log octanolwater 92 873 58 partition coefficient 53 48
Versar Inc 1979 Water-Related Fate of 129 Priority Pollutants Volume II Prepared for US Environmental Protection Agency PBSO-20438 December
bullbullOther names listed in Versar 1979 vMore than one value has been calculatedreported
36
Bis (2-ethylhexyl) phthalate is the most well-studied of the
phthalate esters though the information on phthalate esters as a group
is limited The three phthalates identified at the Troy Mills site have
relatively low solubilities and are readily adsorbed onto suspended
particulates Microbial degradation is effective under aerobic
conditions bur is generally slower under anaerobic conditions
(nonexistent for bis (2-ethylhexyl) phthalate)
The above characteristics are important for two reasons One
the extent and nature of contaminant migration from the site are
dependent upon the physical characteristics Second the treatment
(clean-up) alternatives for contaminated ground water or soil can be
estimated from the characteristics
From the available information it appears that the phthalates
present at the Troy Mills site would be relatively immobile due to their
low solubilities and high adsorption rates The presence of toluene and
methylene chloride at the site however may increase the phthalates rate
of migration
It is important to note that none of the phthalates have been
found to be present in the monitoring wells nor in the surface water
sampled probably due to the low solubility and high adsorption rate
37
643 Napthalene u K r
Naphthalene has also been found in significant quantities in
the sampled drums Naphthalene is a polycyclic aromatic hydrocarbon and
has the following properties
Molecular Weight 12819
Melting Point 8055
Vapor Pressure (20degC) 00492 torr
Solubility in Water (25degC) 344 mgfc
317 mgfc
Log octanolwater partition coefficient 337
Versar 1979
Naphthalene has mid-range adsorption rates and solubility It is
therefore inferred that there would be some adsorption to soils in a
ground water environment It is important to note that naphthalene has
not been detected to date at the monitoring wells or the surface water
sampling locations This is expected to be a result of adsorption on
the soils
644 Volatile Organic Compounds
Volatile organic compounds tend to migrate readily within
soils and ground water They are therefore considered a threat to
surrounding ground and surface waters if they are released in sufficient
quantities
Volatile organic compounds were detected in samples from six
steel drums The total volatile organic (TVO) concentrations in the
38
wastes ranged from 9 ppm to 30100 ppm and averaged 8570 ppm In order
to determine the potential for future contamination by volatile organic
compounds an estimate of waste quantity based on information from the
drum excavation program was made It was assumed that 7000 steel drums
in the deposit are 60 full of liquid waste with an average TVO
concentration of 8570 ppm The computed volume of liquid waste is
231000 gallons with an average TVO concentration of 8570 ppm This is
equivalent to about 1980 gallons of pure TVO
Two of the volatile organic compounds that have been most
prevalent in the existing ground water monitoring system are
111-trichloroethane and ethylbenzene The EPA suggested no adverse
response level (SNARL) for 111-trichloroethane is 330 ugpound for
1 day of exposure and 35 jigd for exposure over a life-time in
drinking water
In general ethylbenzene is a prevalent chemical in the
environment Sources include commercial (eg petroleum and petroleum
by-products) motor vehicle exhaust and cigarette smoke An intake of
16 mgday (1 mgfc) has been calculated as an acceptable rate to
protect from toxic effects Carcinogenic effects have not been
identified to date The physical properties of ethylbenzene are
presented in Table 64-2 The principal mechanism for removal of
ethylbenzene from water is volatilization In addition to
volatilization adsorption may also be an important removal mechanism
based on the log octanolwater coefficient This factor is important in
evaluating the migration of ethylbenzene from the disposal site
Toluene which was also identified in waste and ground water
samples exhibits properties similar to ethylbenzene in that it
volatilizes easily Toluene which is also referred to as methylbenzene
is distinguished from benzene by the substitution of a methyl group for
one hydrogen atom Physical properties of it are presented in Table
39
64-2 The EPA suggested no adverse response level (SNARL) for toluene
is 1 mgpound in drinking water with a maximum exposure time of ten
days
TABLE 64-2 PHYSICAL PROPERTIES OF ETHYLBENZENE AND TOLUENE
ETHYLBENZENE TOLUENE
Molecular Weight 10616 9213
Melting Point -949degC -950degC
Boiling Point 1362degC 1106degC
Vapor Pressure at 20degC 7 torr 287 torr
Solubility in water at 20degC 152 mg2 5348 mgd
Log OctanolWater Partition Coefficient 315 269
645 Metals
One liquid sample contained high concentrations of cadmium
(2200 mgd) and zinc (5700 mgd) indicating that the waste deposit is
also a potential source of certain toxic metals Tests for these metals
have not been made to-date in ground or surface water samples It would
be prudent to add toxic metals such as cadmium chromium lead and
mercury to the list of parameters that are being monitored to further
characterize the quality of adjacent ground and surface waters US
EPA and New Hampshire drinking water standards for these metals are
cadmium 01 mgd chromium 05 mgpound lead 05 mgd mercury 002
mgd Although zinc is not considered a highly toxic metal the
US EPA has set a secondary drinking water maximum contaminant level of
5 mgd on this metal
40
70 CONCLUSIONS
The following conclusions were drawn during this
investigation
1 A steep-gradient irregular-shaped magnetic anomaly is present under closed and covered portions of the south part of the Troy Mills landfill
2 The magnetic anomaly is caused mostly by an irregular-shaped accumulation of disposed steel drums
3 In a randomly conducted sampling of drums in the source area for the magnetic anomaly 16 of the drums contained liquid andor sludge 33 were crushed flat and 51 were not sampled because there were no accessible openings
4 Laboratory analyses indicate that the random waste sampling contained significant concentrations of several volatile organic chemicals several baseneutral priority pollutants and high levels of cadmium and zinc
5 Observed concentrations of volatile organics at the monitoring wells are relatively low Because of their potential for migration in the ground water continued monitoring of volatile organics will be required
6 Volatile organic chemicals have not been detected in Rockwood Brook to-date Because of the presence of low levels of volatile organics in the ground water they should be monitored in the brook on a regular basis to confirm the lack of impact
7 The presence of high concentrations of cadmium and zinc in one of the waste samples indicates that trace metals should be monitored periodically
8 The presence of baseneutral extractable compounds (phthalates and naphthalene) in all of the analyzed waste samples indicates that these compounds should be monitored periodically
9 The phthalates are not expected to migrate freely because they have low solubilities and are readily adsorbed onto soil particles
10 If elevated concentrations of volatile organic compounds trace metals or baseneutral extractable compounds should occur in the monitoring system (wells and brook) in the future a need for site remedial actions to mitigate the potential for downgradient ground and surface water contamination could develop
~
80
41
RECOMMENDED PLAN
Based on the preceding conclusions it is recommended that the
following plan be implemented by Troy Mills Inc
1 Continue monitoring ground and surface water quality at the Troy Mills Inc landfill sampling on a quarterly basis with sample collections during April July October and January
2 To confirm the absence of the landfills impact on Rockwood Brook test samples for volatile organic compounds by GCMS from surface Stations B (upstream) and C (downstream) on the April and October samplings
3 To determine if trace metals are present in downgradient ground waters conduct analyses for cadmium chromium lead mercury and zinc on samples from all monitoring points during the April sampling and on subsequent sampling rounds if necessary
4 To confirm the continued absence of baseneutral extractable compounds in downgradient ground and surface waters conduct analyses for baseneutral extractable compounds on samples from monitoring wells M 2 and 3 and surface Station C (downstream) on the April sampling and on subsequent sampling rounds if necessary
5 If a sudden rise in concentrations toward unacceptable levels should occur in the monitoring system (wells and brook) additional monitoring rounds at a monthly interval should be conducted to confirm the rise in concentrations
6 If elevated concentrations persist and are verified by the additional monitoring remedial alternatives will be defined to mitigate the potential for downgradient ground and surface water contamination
Respectfully submitted NORMANDEAU ASSOCIATES INC
Dennis R Sasseville Project Manager
Donald H Bruehl f laquo | APG Senior Hydrogeologist -^ - - AIPG Certificate No 2272 ^ -v^
^^Z-^^
APPENDIX A
SITE SAFETY PLAN
GENERAL SAFETY PLAH FOR
TROT MILLS LANDFILL TROY MEW HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
Prepared by
NORMANDEAU ASSOCIATES INC Bedford New Hampshire
R-457
November 1983
TABLE OF COHTENTS
PAGE
SECTION 1 BACKGROUND INFORMATION 2
Identification 2 Personnel 2 Site Description 3 Project Description 5
SECTION 2 HAZARD EVALUATION 6
Overall Degree of Hazard 6 Specific Hazards 8 Necessary LPP 8
SECTION 3 FIRST AID FOR EXPOSURE 10
SECTION 4 OPERATIONS SAFETY PLAN 11
General Personnel Protection GuidelinesAction Levels 11 Site Reconnaissance 13 Task 1 - Magnetic Survey Topographic Survey 14 Task 2 - Drum excavation and Sampling 15
SECTION 5 EMERGENCY INFORMATION 16
Emergency Telephone Numbers 16 Route to Hospital 16 Contingency Plan 17
APPENDICES 18
A - LEVELS OF PERSONNEL PROTECTION 18 B - DECONTAMINATION PROCEDURES 23 C - PERSONNEL AND RESPONSIBILITIES 25 D - PERSONNEL CASUALTY 26 E - GUIDELINES FOR SITE OPERATIONS 27
GENERAL SAFETY PLAN FOR
TROY MILLS LANDFILL TROY NEraquo HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
The following is a Safety Plan for on-site activities performed
during the Investigation of the Troy Mills Landfill being conducted by
Normandeau Associates Inc (NAI) of Bedford New Hampshire
The document is intended to be an in house working guideline
for personnel trained and experienced in hazardous waste field work and
not a treatise on safety Familiarity with standard equipment and proshy
cedures is expected Where possible non-site specific information has
been appended
All NAI employees subcontractors and visitors will be required
to follow this safety procedure plan and to report to either NAIs proshy
ject manager (P M) on site coordinator (OSC) or safety officer (SO) on
issues relating to safety
SECTION 1
BACKGROUND INFORMATION
IDENTIFICATION
Site Name Trey Mills Landfill NAI-ID No 457
Trey Mills Inc Troy NH 03465
AddressLocation At the south end of the dirt road about 15 miles
south of Troy NH between Rockwood Brook and the
old Boston and Maine Railroad grade
County Cheshire Phone 603-242-7711
PERSONNEL
Brook Dupee Bureau Hazardous Waste 603-271-4611
State Contact John Regan Bureau Solid Waste 603-271-4586
Dan Allen WSPCC 603-271-2755
EPA Contact
Other Contacts
Client Contacts Barrett F Ripley (Vice President)
NAI Personnel - (472-5191)
Project Manager - Dennis Sasseville
On Site Coordinators - Alton Stone
Safety Officer - Elizabeth Gross (Phoenix Safety)
Technical Director - Don Bruehl
Other - Douglas DeNatale Steve Ransom
SITE DESCRIPTION
Type of Facility Company (on-site) landfill
RCRA Status Generator Disposer
Size About 15 acres BuildingsStructures None
Surrounding Land Use N Forested
(one mile radius) E Abandoned Railroad
Forest RuralResidential
S Forested
W Forested Mountain side
Unusual Features or Terrain None
Site Activities - Troy Mills manufactures textiles carpets and related
products Since 1968 waste materials including
drummed wastes have been landfilled on company proshy
perty Drums mostmany of which may be emptycrushed
are buried in an inactive section of the landfill
The active section is currently accepting waste
which is considered to be non hazardous
Specific - Improper disposal of hazardous waste
Problems - Leachate seep
Contamination of ground water
Hazardous WastesMaterials On-5ite
Wastes - Uncured foam rubber latex sludge
SBR rubber silicone defoamer potassium oleate soap
calcium carbonate and feldspar filters zinc oxide
and sulpher salt cure system
- Vinyl plastisol sludge
PVC dispersion resin DOP and DOA plasticiser
calcium carbonate filler organic pigments AZO
dicarbcnamid blowing agent zinc salts expoxidized
soybean oil cadmLum-bariin-zinc stabilizer Varsol
MEK prints and topcoats sludges
PVC acrylic resins organic and inorganic pigments
MEK solvent toluene silicate fillers
Industrial solvents and chemicals
11 -dichlorethane 12-dichlorothane
111-trichloroethane trichlorethylene tetrachshy
lorethene methylene chloride toluene benzene
ethylbenzene benzidine 33-dichlorobenzidine aeroshy
lein acrylonitrile napthalene benzoperylene dibenshy
zoanthrasene idenopyrene
Pesticides
There is a possibility for low levels of pesticides
to be on site These would include Chlorodane
heptachlor expoxide toxaphene aldrin alpha BHC
beta BHC 4-4-DDT endosulphan 1 heptachlor
PROJECT DESCRIPTION
Purpose Tb characterize ground water conditions at the site and to
characterize wastes buried on site
Specific Tasks
Site Reconnaisance
Task 1 - Magnetometer SurveyTopographic Survey
Task 2 - Excavation for inspection of drums
SECTION 2
HAZARD EVALUATION
Overall Degree of Hazard - Moderate
Task Hazard Proposed LPP
Site Reconnaissance Low Level C
Task 1 MagnetometerTopographic Surveys Low Level CD
Task 2 Drum ExcavationSampling Moderate Level B
Conpany records have indicated that a variety of industrial
and potentially hazardous wastes including drummed wastes
were disposed of on site Several of the subtances are
trade name materials or industrial process materials and it
is difficult to determine the specific chemical composition
Hazard is dependent upon concentration of material state of
material (solid sludge drummed liquid) and degree of
decomposition
Many of the materials - SBR rubber silicone defoamer
potassium oleate soap calcium carbonate and feldspar
fillers zinc oxide and sulpher salts plasticiser
calcium carbonate filler organicinorganic pigments AZO
dicarbonamid blowing agent epoxidized soy bean oil
cadmiura-bariun-zinc stabilizer - probably do not represent
a significant hazard to an inspection team if they are
bound into a sludge or solid Personnel are not likely
to injest or come into a prolonged high concentration
contact with these materials In powdered or dust conshy
ditions the materials are more hazardous due to the inhashy
lation of contaminated particulates
MEK (TLV-200ppm) toluene (TLV-100ppm) and Varsol
(turpentine thinner composition unknown) are volatile
organics which require respiratory protection and contact
protection
Depending upon state and decomposition PVC resins could
be a source of vinyl chloride monomer (VCM-a carcinogen)
requiring respiratory protection VCM is not adequately
filtered by air purifying respirators
Results from ground water sampling showed low levels of
industrial chemicals (PPB range) At these low conshy
centrations the chemicals do not represent a significant
hazard However the low concentrations in ground water indishy
cate the possibility of higher concentrations in the waste
materials
Industrial chemicals - napthalene (TLV-10 ppm) peryshy
lene anthrocene and pyrene which are hazardous
through inhalation or absorbtion Furthermore as
double benzene ring chemicals they are potential
carcinogens
Results from ground water sampling indicated possible
low levels (parts per trillion) of several pesticides
- chlorodane heptachlor epoxide toxaphene eldrin
Alpha BHC Beta BHC 4-4-DDT endosulphan These were
tentatively identified during a first analytical run
but not confirmed during a second run laboratory
review (GCA Bedford Mass) determined that the
material was actually a complex of highly degraded
heavy organics derived from the industrial waste The
presence of pesticides in industrial textile waste is
unlikely
Specific Hazards
1) Inhalation of organic vapors
Excavation of buried material and sampling of drums could
initiate high vapor concentrations
2) Fire and explosion
Many of the solvents are flammable liquids and volatile
Excavation of material and sampling of drums should
proceed cautiously in order to avoid rupturing shocking
or sparking of drums and material
3) Inhalation of contaminated dustparticulates
Excavation of buried material may result in a release of
particulates
4) Contact contamination
Excavation and sampling of wastes could possibly result in
contact with contaminated waste and soils necessitating
protective clothing
Necessary LPP
Site Reconnaissance - Level C The site has been visited on numerous
occassions by the state and private personnel Use of an HNU (102 ev
probe)- has not indicated significant vapor concentrations Significant
odors during dry weather or other hazards have not been noted
Sections of the landfill are currently active and adverse effects to
personnel have not been noted Level C - (tyveks rubber safety boots
organic vapor cartridges) is sufficient
Task 1 MagnetometerTopographic Survey - Level CD LPP will depend
upon the results of the Site Recon Significant vapor concentrations
or likelihood of particulates will necessitate an upgrade in the LPP
Otherwise Level D (work clothes safety boots boot wash) is sufficient
Task 2 Excavation and Sampling of Buried Drums - Level B The potenshy
tial for encountering significant concentrations of hazardous
materials during this task is moderately high Full Level B - (SCBA
chemical resistant tyveks hoods rubber safety boots rubber gloves)
will provide necessary respiratory and contactsplash protection
The use of the hooded yellow tyveck and the taping of ankleboots
wristsgloves and face maskhood junctions will provide complete conshy
tact protection
10
SECTION 3
FIRST AID FOR EXPOSURE
INHALATION OF VAPORSPARTICUIATES
Symptoms - eyenosethroat irritation nausea dizziness headache weakness fatigue lightheadedness drowsiness Loss of coordination confusion vomiting cramps (These sympshytoms are similar for most organic vapors particularly solvents)
Treatment Mild Exposure - Bring victim to fresh air Rinse eyes and throat if
irritated Heavy Exposure - (victim vomits very dizzy groggy faints etc)
Bring victim to fresh air Evacuate to hospital Prepare to administer CPR
Victim should be monitored for 48 hours in case of a delayed reaction
CONTACT EXPOSURE
Symptoms - Itching burning redness of skin Severe contact exposure for certain solvents will progress to CNS (central nervous system) symptoms similar to those for inhalation
Treatment - Remove contaminated clothing flush with water dry and banshydage Monitor victim for CNS symptoms for at least 48 hours
FIRST AIDSAFETY EQUIPMENT
The following equipment will be stationed at the Hotline or when appropriate down range
- Fully equipped first aid kit - Oxygen bottlekit - Nine (9) Ib chemical fire extinguisher - Eyewash bottle or other pressurized water filled container
11
SECTION 4
OPERATIONS SAFETY PLAN
This section outlines the specifics of safety procedures to be
used during each phase of the operations Safety procedures may be
upgraded or downgraded during site activities pending monitored changes
in the working environment All changes will be in line with the
General Level of Personnel Protection GuidelinesAction Levels for the
Troy Mills Landfill On-Site Investigation as described below
General Personnel Protection GuidelinesAction Levels
An in depth review of levels of personnel protection (LPP) is
presented in Appendix A
Level B (SCBA cotton coveralls or work clothes yellow tyveks (chemical resistant) steel toed rubber boots or work boots with disposhysible over boots and gloves)
Vapor concentrations (as measured on an OVA or HNU 117 EV Probe) greater than 5 ppm above background
- Oxygen deficient atmospheres less than 195
Specific actions (ie excavationsampling of drums) which could initiate a sudden moderate or high concentration of vapor
Level C (full face respirator organic vapor dust combo cartridge tyveks over work clothscoverails rubber safety boots gloves)
Vapor concentrations above an established clean zone backshyground level
During conditions (natural or personnel induced) which result in high levels of dust (visable above background atmospheric concentrations of particulates)
Level C activities require continual air monitoring
12
Level D (cotton coveralls or other work clothes safety shoes and safety glasses when down range Tyveks may also be needed)
Support areas and downrange areas where a higher LPP has not been deemed necessary
Continual air monitoring in downrange areas
Explosive Atmospheres
- 20 LEL (lower explosive limit) as recorded by an explosishymeter Secure and evacuate the work area
Oxygen Deficient Atmospheres
- Less than 195 (by volume) oxygen atmosphere requires upgrading the level of Personnel Protection to Level B
Task Specific Safety Plans
Levels of Personnel Protection indicated for specific tasks below are those which are anticipated to be used Changes in site conshyditions and results of air monitoring may indicate the upgrade downgrade of the LPP
13
Site Reconnaissance (SR) Date Sept 21 1983
Purpose To review on-site conditions and determine LPP necessary for further tasks To evaluate safety hazards Preliminary planning of future tasks
LPP - Initially Level C Updowngrade as necessary
Equipment - OVA HNU (102 ev probe)
Hotline - End of access road Upwind if possible
Command PostFirst Aid - Behind Hotline
Decontamination - Boot wash
Operations
Three man team Two persons advance in front with instrushyments Third person at distance as backup
Team methodically sweeps (criss cross) the proposed work areas with instruments
Specific points of interest (leachate seeps etc) are closely checked
All information is loggedsketch mapped
Upgraded LPP as necessary
14
Task 1 - Magnetic Survey Topographic Survey Date Week of October 3 1983
Purpose - Determine the location(s) and extent of buried drums Provide topographic information for site base map
LPP - Level CD
Hotline - End of access road (upwind if possible)
Decontamination - Boot wash
Operations - SO or other NAI personnel will perform a brief safety sweep of the work area
- Work team will then proceed downrange at the appropriate LPP Using the magnetometer the team will systematically criss cross -the work area
Task 2 - Drum Excavation and Sampling Date Week of November 14 1983
Purpose - Excavationsampling of buried drums in order to characterize the condition of the drums and the nature of the wastes conshytained in the drums and buried in the landfill
Msthod - Backhoe and hand labor will be used to uncover the drums in specified locations Samples will be obtained from spillage or leakage around the drums and of contaninated soil Selected drums which have accessible and openable bungs may be opened and sampled Drums will not be moved or staged Clean drums will be available to receive any significant spillage during the opening and sampling
Specific Hazards - Inhalation of organic vapors - Fire and explosion of drummed waste - Contact with contaminated waste or soil
LPP - Full Level B protection Backhoe operator at Level B Backshyhoe equipped with splash shield and without teeth on bucket
Hotline - At the end of the access road Upwind if possible
Decontamination - Procedures will essentially follow those as outlined by the EPA for Level B work Due to the inaccessibility of the site a field shower will not be available See Appendix B
Safety Equipment - OVA HNU eyewash fire extinguisher oxygen kit first aid kit metal detector non sparking implements
15
Operations - The cover soil is very sandy and the drums appear to be buried close to the surface which should facilitate excavation
- Minimum of 4 man team (exclusive of backhoe operator) Two or three man downrange team for digging and sampling One or two men in supportbackup at hotline
- Personnel will hand dig several small holes to approximately one (1) foot depth in each Location area If drums are not encountered the backhoe will scrape off soil to that depth
- Excavation will proceed alternating hand and backhoe methods At depths below four (4) feet the sides of the pit must be angled back to less than 45deg
- Prior to opening a closed drum the backhoe will nudgebump the drum to check for shock sensitive material An alternate method will be to attach a length of rope to the drum and from a distance pull on the rope to jog the drum
mdash Backhoe The backhoe operator will work at Level B utilizing air supplied from a large cylinder attached to the backhoe The backhoe will also be equipped with a splash shield A scraping bucket without teeth will be used
Prior to backhoe excavation at each location the area where the backhoe will be stationed will be checked for drums which could be ruptured by the backhoe feet
f Excavation areas will be checked for drums utilizing hand excavations or a metal detector prior to removing material by machine
16
SECTION 5
EMERGENCY INFORMATION
Emergency Telephone Numbers
If calling one of these numbers please state NAME LOCATION
and type of PROBLEM
Local Emergency Support
Fire Department (Troy 242-7759) For all emergencies use
Ambulance 352-1100 Mutual Aid (Keene) 352-1100
Police Department (Troy 242-7992)
Hospital 352-4111 (Cheshire Hospital in Keene)
Town Clerk 242-3845 State Agencies
NH Bureau of Hazardous Waste Management 271-4608
NH Water Supply and Pollution Control Commission 271-3503
NH Fire Marshall Office 271-3336
NH State Police (24-Hour Dispatch) 1-800-852-3411
Other
US EPA (24-Hour Hotline) 617-223-7265
Poison Center Mary Hitchcock Hospital 1-800-562-8236
Route to Hospital
- Follow dirt access road to Bowkerville Road - Left on Bowkerville Road to Rt 12 - Left (north) on Rt 12 through Troy to Keene NH - At major junction of Rts 9 10 101 and 12 go straight through
into Keene - At common go half-way around and go right on Court Street - Hospital is at 580 Court Street
17
Contingency Plan
Signal - five (5) one second blasts of auto or air horn Action - All personnel immediately excavate dovmrange areas and
report to Hotline for instructions
Personnel Unexplained Fire (if small) Accident (serious) Collapse of Personnel
Evacuate area Emergency ^ ^Evacuation Evacuate Area
First Aid
Estimate Explosion Level B (for Potential Contact Outside Help evcavation)
Evacuate Victim i If
Level B Prepare for Transportation
1 First AidCPR Use extinguisher Transport
Contact Outside Help Notify Coup any Have Proper Information Personnel (see below) 1
Transport
Call Fire Dept (if necessary)
For Hospital Victim
- Name and Phone of family physician
- Description of Incident chemicals involved symptoms nature of injury proposed treatment and plan of transportation
18
APPENDIX A
LEVELS OF PERSONNEL PROTECTION
Because of the possible dangers of exposure to toxic or harmshyful chemicals protective equipment must be worn during work on hazardous waste sites Levels of Personnel Protection (LPP) describe respiratory clothing and other equipment necessary for protecting personnel against expected hazards
The descriptions below are for full dress at a given LPP where hazards are expected to be at a maximum for which the given LPP is conshysidered adequate Depending on site conditions and work activities the clothing and dress requirements of a given LPP are commonly modified
LEVEL A
1 Personal Protection Equipment
Positive Pressure SCBA (MSHANIOSH approved) Operated in the positive pressure mode
Totally Encapsulating Suit (boots and gloves attached)
Gloves - Inner (tight fitting and chemical resistant)
- Boots - Chemical - protective steel toe and shank Depending on suit boot construction worn over suit boot
- Gloves shy Outer chemical-resistanttion worn over suit gloves May bchemical-resistant gloves worn insid
Dependinge replaced withe suit glo
on s
ves
uit construcshy tight-fitting
- Underwear shy Cotton long-John type
- Hard Hat (under suit)
- Disposable protective suitover encapsulating suit)
gloves and boots (Worn under or
- Coveralls (under suit)
- 2-way Radio Communications
Optional
19
2 Criteria for Use
A The type and concentration of toxic substances are known and require the highest level of combined protection to the respirashytory tract skin and eyes These conditions would be
1 Atmospheres which are immediately dangerous to life and health (IDLH)
a IDLHs can be found in the NIOSHOSHAs Pocket Guide to Chemical Hazards andor other references
2 Known atmospheres or potential situations that would effect the skin or eyes or could be absorbed into the body through these surfaces in toxic quantities
a Potential situations are those where vapors may be generated or splashing may occur through site activities
b Standard reference books should be consulted to obtain concentrations hazardous to skin eyes or mucous memshybranes
3 Oxygen deficient atmospheres with above conditions
3 At sites where the type andor potential concentration of toxic substances are unknown
1 Unless circumstances strongly indicate otherwise the site should be presumed to present hazards to the respiratory system skin and eyes Level A protection would provide the highest level of protection for the initial entry team
a Such circumstances might be
1 Environmental measurements contiguous to the site
2 Reliable accurate historical data
3 Open unconfined areas
4 Minimal probability of vapors presence or splashing with cutaneous effecting substances
2 Enclosed areas such as buildings railroad cars ships holds etc
20
LEVEL B
1 Personal Protective Equipment
Positive Pressure SCBA (MSHANIOSH approved) operated in the positive pressure mode
- Hooded chemical-resistant suit
Gloves - Outer chemical-protective
Gloves - Inner tight-fitting chemical-resistant
Boots - Outer (chemical-protective heavy rubber disposables)
Boots - Inner (chemical-protective steel toe and shank)
2-way Radio Communications
Hard Hat
Face Shield
2 Criteria for Use
A The type and concentration of hazardous substances are known and require the highest degree of respiratory protective but a lower level of skin protection
1 Atmospheres which are immediately dangerous to life and health (IDLH) Type and concentration of vapors in air do not present a hazard to the small unprotected areas of the body
2 Atmospheres with concentrations of known substances greater than protection factors associated with full-face air-purifying respirators with appropriate cartridges
3 Atmospheres with less than 195 oxygen
B When a determination is made that potential exposure to the body parts not protected by a fully encapsulated suit (primarily neck ears etc) is highly unlikely
1 Known absence of cutaneous or percutaneous hazards
2 Activities performed preclude splashing of individuals
C Level B protection is recommended as the lowest level of protecshytion for initial entries until the hazards have been further identified and defined by monitoring sampling and other reliable methods of analysis and personnel protection equipment commensurate with these findings utilized
21
LEVEL C
1 Personal Protective Equipment
Full-face or half-face air purifying respirator (MSHANIOSH approved)
Chemical-resistant clothing
Gloves - Outer (chemical-protective)
Gloves - Inner (tight-fitting chemical-resistant type (or woven liners)
Hard Hat (face shield optional)
Boots - Outer (chemical-protective heavy rubber throw aways)
Boots - Inner (chemical-protective steel toe and shank)
2-way radio comnunications
Safety glasses required with half-face respirator
2 Criteria for Use
A Site known to contain potentially hazardous materials exceeding
1 Air concentrations requiring a protection factor no greater than that afforded by a full-face mask
2 Harmful levels to unprotected body areas (face neck etc)
3 Well-documented reliable history of site and patterns of prior entry
C No evidence to suspect acute or chronic toxicity to exposed personnel
D Continuous air or personnel monitoring should occur while wearing Level C protection
22
LEVEL D
1 Person Protective Equipment
Chemical resistant aprons
BootsShoes - Safety or chemical-resistant steel toed boots
Boots - Outer (chemical-protective heavy rubber throw-away)
Half-face respirators immediately available
Safety glasses or safety goggles
Gloves
2 Criteria for Use
a No indication of airborne health hazards present
b No gross indications above background on the photoionizer andor organic vapor analyzer
c Continuous air or personnel monitoring should occur while wearing Level D protection
23
APPENDIX B
DECONTAMIHATION PROCEDURES
Depending upon activities and location on site it may be
necessary for personnel to decontaminate prior to leaving the conshy
taminated zone Procedures described below are typical for Level C
operations
Upon exiting downrange (contaminated) areas all personnel are
required to decontaminate by means of the following procedure
1 Place equipment in the Drop Zone at the Hotline
2 Enter the Decontamination Station
Boot Wash Walk through wash tub and scrub boots then rinse boots in second tube
Glove Wash In two pan wash scrub over gloves rinse set out to dry
2 Remove tyvek - if leaving the contamination reduction zone (CRZ) and proceed to clean zones
3 Dispose of heavily contaminated clothing and under gloves
4 Remove respirator
5 Use disposable gloves to clean equipment
6 Use a two bucket (washrinse) to decon respirators at the end of the working day or if they become heavily contami nated
The procedures for a typical Level B Decontamination are
outlined on the following page
TANK CHANGE 9
CONTAMINATION REDUCTION
ZONE
OUTER GLOVE REMOVAL
EXCLUSION ZONE
TAPE REMOVAL
BOOT COVER
GLOVE WASH
(bull)mdashQ-G--copyshySOOT COVEH SCOT COVES 4
REMOVAL GLOVE RINSE
SUITSAFETY BOOT WASH
SU1TSC8A78OOTGLOVE RINSE
SAFETY BOOT 10 REMOVAL
SCSA BACKPACK REMOVAL
SPLASH SUIT 12 REMOVAL
INNER GLOVE WASH
INNER GLOVE RINSE
FACE PIECE REMOVAL
INNER GLOVE 16 I REMOVAL
INNER CLOTHING REMOVAL
FIEUJ 19 REDRESS WASH
SEGREGATED EQUIPMENT
OROP
mdash -HOTLINE-shy
DECONTAMINATION LAYOUT LEVEL B PROTECTION
FIGURE A2-1
CONTAMINATION CONTROLLING
SUPPORT ZONE
25
APPENDIX C
PERSOHNEL AND RESPONSIBILITIES
Project Manager (PM)
Overall responsibility for all Project activates budget
schedule investigative operations safety personnel
On Site Coordinator (OSC)
Responsibility for activities at the site Primary responshy
sibilities include
1) Interfacing with the client state EPA media or other groups
2) Reviewing technical operations
3) Reviewing site safety in particular information supplied by the Site Safety Officer
4) Enforcing site safety and compliance with the Safety Plan
5) Directing Emergency Contingency operations
Safety Officer (SO)
Responsibility for directing the safety of operations and impleshy
menting the Safety Plan Specific responsibilities include
1 Assuring that appropriate personnel protective equipment is available and properly utilized by all site personnel
2 Assuring that personnel are aware of the provisions of this plan are instructed in the work practices necessary to ensure safety and in planned procedures for dealing with emergencies
3 Assuring that personnel are aware of the potential hazards associated with site operations
4 Supervising the monitoring of safety performance by all pershysonnel to ensure that required work practices are employed
26
APPENDIX D
PERSOHHEL CASUALTY
Personnel casualty would most likely result from either chemical
contamination heat-related problems physical injury from accidents
(ie falling lacerations etc) in performing the work or a comshy
bination of one or more of the above The appropriate action depends on
the type of injury involved with the priority being to assist the
casualty as soon as possible without endangering other personnel
Riysical and heat-related injuries can and should be treated
immediately with appropriate first-aid measures and follow-up medical
attention if necessary The injured worker(s) shall immediately move
out of the hot zone or if necessary be moved out by fellow workers as
soon as possible The OSC and Safety Officer shall be notified immeshy
diately and shall recommend further measures as needed
Chemical-related injuries require a much more cautious approach
so as to keep casualties to a minimum If a worker injured by chemical
ejqgtosure is able he shall notify the nearest co-worker and leave the hot
zone immediately- The co-worker shall ensure that the OSC and Safety
Officer are immediately informed and shall accompany the casualty from
the hot zone to the decontamination zone The OSC and Safety Officer
shall determine the appropriate measure
27
APPENDIX E
GUIDELINES FOR SITE OPERATIONS
In order to deal with the potential dangers of exposure and conshy
tamination of a hazardous waste site three zones are delineated
according to the degree of hazard The three zones are 1) Downrange
or Contamination Zone 2 Contamination Reduction Zone (CRZ) 3) Support
or Clean Zone
Downrange or Contamination Zone
The Contamination Zone is the active work area of the site which
encortpasses the areas where there is a potential for exposure and in
which investigative activities will occur (drilling sampling etc)
Within the Contamination Zone the designated level of hazard will be
established necessitating the utilization of personnel protective
equipment
Hot spots are those areas Downrange where observations instrushy
ment readings or specific activities indicate a high probability of
closure or contamination and may require an upgrade in the LPP in the
vicinity of the Hot Spot
Contamination Reduction Zone
The CRZ is an area between the Downrange and Support Zones where
decontamination of equipment and personnel occurs
28
Personnel entering the CRZ shall wear protective clothing and
carry the respiratory protection required for entry within the
Contamination Zone
Personnel working within the CRZ shall remain cognizant of the
CRZ in order to be prepared for any need to increase their level of proshy
tection within the CRZ
A decontamination station will be located at the outer perimeter
of the CRZ All personnel who have been within the Hot lane shall pass
through a decontamination procedure prior to re-entering the Support
Zone
Support or Clean Zone
The Support Zone is the outer area and may be considered to be
clear of contamination potential The command post will be located
within the Support Zone
a) The Command Post will serve as the OSCs headquarters and
will be equipped with
1 Communications
2 Safety Plans
3 First Aid Supplies
4 Analytical Equipment
5 Safety Equipment
APPENDIX B
WORK PLAN
WORK PLAN FOR
TROY MILLS LANDFILL TROY NEW HAMPSHIRE
DRUM EXCAVATION AND SAMPLING
Prepared by
NORHANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
1933
WORX PLAN FOR
TKOt MILLS LANDFILL TROT NEW HAMPSHIRE
DRUM EXCAVATION AHD SAMPLING
DATS November 16-18 1983
PURPOSE
To determine the condition of drums (ie erroty or full
crushed rusted leaking etc) buried in the Troy Mills Landfill To
obtain representative samples toward identifying the types of materials
buried in the landfill This information will be used in the detershy
mination of the level of remedial action needed at the site
METHOD
Using the results of the magnetometer survey the (10) points
have been randomly chosen across the area where the buried drans are
expected to be found Each point is central to an Excavation Location
-- an area four (4) to six (6) feet in diameter which will be excavated
in order to characterize the condition of the drams and to obtain waste
sarples
Preliminary observations have indicated that many of the drums
may be buried within 1-2 feet of the surface Therefore the investigashy
tion will proceed in two phases
Phase 1 mdash Hand Excavation By digging several small holes in
each Location personnel will determine if drums are located within
about one to two feet of the surface If drums are encountered the
excavation will proceed by hand uncovering the dnris for evaluation and
sampling Where drums are not encountered near the surface excavation
at this location will be postponed until Phase 2
Phase 2 mdash HandBackhoe Excavation After all Locations have
been attempted during Phase 1 those Locations in which drums were not
encountered wall be further excavated using a combination of hand
backhoe digging
It is expected that one to two days will be necessary to
cor^piete each phase Depending upon the results of Phase 1 it may not
be necessary to iroleraent Phase 2
Spare drums will be on hand for containerizing any significant
spillage resulting from sampling efforts Excavation locations will be
identified with marked stakes and the holes will be backfilled at the
conclusion of the investigation
SPECIFICS
Excavation Locations (Holes)
Number of proposed excavations is ten (10)
Locations of excavations are presented in Appendix A
Hole Size mdash It is expected that a hole from four (4) feet to six (6) feet in diameter at the bottom (depth at which drums are encountered) will be sufficient to characterize the drums at each Location Deeper excavations will require increasingly large top diameters
Hole Depth -- Holes will be excavated to a maximum depth of six (6) feet Due to the sandy cover material the excavation of deeper holes is probably impractical from both safety and efficiency stand points
If after attempting excavation at each of t-ie 10 proposed
1ocatiors irums are not encountered within six (6) fet of the surf ice
in enough locations to characterize the site excavations nay be
attempted to depths greater than six (6) feet if scil stability permits
or a new set of sampling locations may be chosen
(Excavations to depths greater than six (6) feet require a
significant increase in work The sides of the hole crust be graded back
to less than 45deg in order to insure the safety of investigatorysampling
personnel It may also be necessary to employ bracing bulkheads etc
for trench support)
Excavation Identification
Proposed excavation Locations have been consecutively numbered
from 1 to 10 beginning at the east end of the landfill They will be
marked with numbered stakes
Excavation Methods
Phase 1 mdash Within each Location personnel will dig a nunber of
small holes - about one (1) foot in depth - to probe for drums If
druns are encountered they will continue to excavate until the drur3
are sufficiently uncovered for characterization
Phase 2 mdash After hand probing the Location with snail holes
the backhoe will remove cover material to the one (1) foot depth The
Location will then be probed to a two (2) foot depth before removing
further material Excavation will proceed alternating handprobing and
backhoe excavation until drums are encountered or the maximum six (6)
foot depth is reached
If excavations to depths greater than six (6) feet are undershy
taken they will proceed using the above method
Santnlea
Due to the effort involved in excavating and because conshycentrated waste samples are not expected to undergo rapid degradation it is considered expedient to obtain all readily available samples (exclusive of closed drum samples -- see belcw) These can then be submitted for laboratory characterization as determined by need and budget restrictions
An attempt will be trade to secure at least one sample froa each excavation in order to help characterize the distrishybution of waste materials across the site An attempt will also be made to secure samples of observably difshyferent materials
Sample Types and Mediums - Solid liquid and sludge samples are possible Samples will be obtained from in order of preference -- 1) leakage uncontainerized waste or contaminated soil 2) waste contained in open conshytainers - drum already has a hole or no top or other access point 3) sealed containers
The opening of closed containers will be considered if it is decided that it has not been possible to obtain a sufshyficient number of representative samples from the other mediums
Each sample will consist of two (2) 8-oz jars (with teflon-lids) filled about 23 full One jar will be for organic analysis and the other for inorganic analysis
Sanole Identification - Samples will be identified with a number corresponding to the Excavation Location and a letter Example if three samples were obtained from Location 2 they would be samples 2A 23 and 2C and Samples 2Ad 23d and 2Cd for duplicates
Sampling Methods and Volumes - 11 mm hollow glass tubing trowels disposable scoops will be available to obtain samples Samples tools will be disposed of or deconshytaminated between each sample
Drum Samples - If necessary an attempt will be cude to obtain samples from sealed drums Oily o^und non-rusted drums will be considered Bunjs rust be xn suitable conshydition -jo that the dram cm be openoi withrut cvis ing dainai -ind ca-i be resell od to pr-jvcrt l V-i 30
There wil l be no staging or movement of drums in order to faci l i tate sampling Only drums with accessible bungs will be considered for sampling
Procedure for Drum Sampling
1) Excavate around top of drum
2) Monitor air in the adjacent area
3) Chec for shock sensitive - Loop rope around top of drum stand at a distance give drum several hard jogs by pulling on the rope An alternative nethod is to lightly jog the drum with the backhoe bucket
4) If the drum is not upright place a catch basin under the bung
5) Open drum with bung wrench
6) Monitor the air atin bung
7) Sample drum -- liquids insert glass tube the fu l l length into the drum in order to obtain a column of the materials in the drum Solids use scoop to dig out material through the bung or use a sampling trowel
3) Reseal the dram
Spill Control
The possibility exists during the sampling and excavation for a
drum to be ruptured or otherwise have spillage Clean drums wil l be on
hand to receive significant spillage resulting frora sampling or excavashy
tion They will not be used for clean up of widespread uncontainerized
waste or existing leakage
Personnel
The work team will require four (4) persons (exclusive of the
backhoe opera tor) Trie downrange team will consist of three (3) persons
-- two (2) for d igg ing and sampl ing and on ( 1 ) for logging air moni shy
toring and photographing One (1) person will be at the hotline in
support mdash as safety backup person to fill air bottles to deconshy
taminate samoles to assist in decontamination of personnel
Documentation Logging
The following information will be recorded at each location
nmber of drums uncovered and the condition (crushed empty rusted
sealed etc) of each drum evidence of spillage or contaminated soil
labels on uncovered drums samples (time drum ID type description)
periodic air monitoring information depth at which specific events
occur or drums are buried soil condition presence of ground water
In addition photographs will be taken of specific events or
items of importance during each excavation and of each sampling incishy
dent The time description of subject photographer excavation
location and photo number will be logged for each photograph
Analytical Laboratories and Schedule
RAI Hampton NH
Initial schedule
Ten samples for GCrns for organic priority pollutants Samples may also be submitted for inorganic anlaysis or volatile organic analysis depending upon waste materials observed during the excavation
APPENDIX A
TABLE A-1 EXCAVATION LOCATIONS
EXCAVATION BASELINE RANDOM RANDOM
NUMBER GRID COORD SEGMENT STATIOH OFFSET
1 7E+1 565N 0- 60 26 (25) 16
2 9E+5 13S 60-120 50 (110) 9
3 8E+0 31S 120-180 20 (140) 7
4 4E+5 483 180-240 50 (230) 25
5 3E+3 45S 240-300 14 (254) 20
6 OE+6 5S 300-360 34 ( 334) 50
7 2W1 5 24N 360-420 45 (-155) 14
8 5W+6 42N 420-480 38 (518) 20
9 6W+1474N 480-540 8 (543) 7
10 8W 5 11011 540-600 11 (611) 31
Locations are plotted on Map A-1
Method of Choice A stratified random sampling method was used to choose 10 Excavation Locations within the magnetic anomaly
The axis of the magnetic anomaly was used as a base line and divided into ten 60 foot long segments Using a randora nirnbers table a distance along each secpent was chosen (Random Station) and a line drawn at that point perpendicular to the base line Again using a random numbers table a distance was located along each perpendicular line by measuring inward from the line denoting the edge of Area A (Random Offset) The Grid Coordinates for each of the Excavation Locations were graphically determined from the grid overlay (this overlay has been surveyed and intersections field located)
It was judged that 10 excavation locations within the magnetic zone and two outside of the zone would be sufficient to characterize the area would produce statistically valid iati and coli be expected to be co~letod within 2-3 days work period
to
80
cu0
cgtc
APPENDIX C
MAGNETIC INVESTIGATION TROY MILLS INC LANDFILL SITE
TROY NEW HAMPSHIRE
For
NORMANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
By
JOHN F KICK PhD GEOPHYSICIST
Box 6 Dunstable Massachusetts 01827
(617) 649-6650
Noverber 19S3
MAGNETIC INVESTIGATION
TROY MILLS INC LANDFILL SITE
TROY NEK HAMPSHIRE
INTRODUCTION
A high resolution ragnetic investigation was completed on the Troy
Mills Inc landfill site in Troy New Hampshire by John F Kick
Consulting Geophysicist The purpose of the investigation was to
delineate the extent of buried steel drums under closed portions of the
Troy Mills landfill The information is needed as a part of a study of
the landfill that is being conducted by Normandeau Associates Inc
FIELDKORK
Magnetometer measurements of total field intensity were made over an
area that was reported to contain buried steel drums and adjacent
landfilled areas that contained unknown waste materials The area of
investigation included capped and grassed closed areas along the south
margin of the landfill site and adjacent areas The fieldwork was
performed during October of 1983
Eighteen parallel rows of measurements were conducted along north-
south lines (using magnetic compass directions) A spacing of 20-feet
was used between rows and magnetometer measurements were made at 10-foot
intervals along the rows Greater intervals between measurements were
used at the ends of the rows and in periferal areas with low magnetic
-JF Kick 01shy
field gradients
A series of magnetic field measurements were made at an adjacent
base station throughout the survey to torn the basis for a daily
variation curve The base station was located at a site with typical low-
gradient background magnetic field intensity measurements
MAGNETIC SEARCH METHOD
Theory Magnetic search methods involve the detection and
measurement of anomalies in the Earths magnetic field caused by the
presence of materials with contrasting magnetic susceptibility Iron and
steel objects generally have very high magnetic susceptibility contrasts
with usual surrounding materials and therefore produce magnetic
anomalies The amplitude shape and detectable distance of the anomaly
depend mostly on the particular susceptibility contrast and size of the
object Magnetic anomalies are measured in units called gammas The
normal magnetic field in this area is over 50000 gammas A 5-inch
screwdriver will produce an anomaly of 5 to 10 gammas at a depth of 5
feet and an anomaly of 1 gamma at a depth of 10 feet A 1 ton automobile
will produce an anomaly of 40 gammas at a depth of 30 feet and an anomaly
of 1 gamma at a depth of 100 feet The magnitude of an anomaly caused by
a single steel drum will vary with its condition (new heavily rusted
etc) Tests using a single light weight (somewhat rusted) drum on the
surface with the magnetic detector at a height of of 12 feet produced an
anomaly in the range of 40 to 50 gammas
Total magnetic intensity disturbances or anomalies are almost always
asymmetrical sometimes appear complex even from simple sources and
usually exhibit the combined magnetic effects of several sources which
can produce a given anomaly The apparent complexity of such anomalies
is a result of several relatively simple functions of magnetic dipole
-JF Kick 02shy
behavior Reasonable assumptions about the geology and buried source
conbined with an understanding of magnetic dipole behavior can usually
lead to a satisfactory qualitative interpretation More detailed
interpretations nay require modeling studies
Instrumentation Field equipment on this project included a EGampG
Geometries Memory-Mag G-856 proton precession magnetmeter The
instrument has a resolution of +01 gamma The magnetic field detector
is separate from the rest of the instrument and is mounted on an 8-foot
staff to provide measurements that are a constant height above land
surface
Magnetic Data Analysis For the purposes of data reduction and
anomaly delineation it was assumed that base station total field
intensity measurements were typical background values for the site
Measurements made at frequent intervals at the base station were used to
prepare a diurnal variation curve for the site Anoraly values were
obtained by subtracting background values from the base station curve
from measurements collected in the area of investigation
RESULTS
The reduced results are presented in the form of a magnetic anomaly
contour map (Figure 1) and two profiles across the area of investigation
(Figures 2 and 3) The map and profiles show that very steep magnetic
field gradients and large departures form background occur in an
irregular shaped band that is about 460 feet long and ranges from about
30 to about 200 feet in width The magnitude of the anomaly is such that
a significant deposit of ferromagnetic materials (such as steel drums) is
indicated
In using the plotted magnetic results it should be noted that the
greatest concentrations of ferromagnetic materials probably do not
-JF Kick 03shy
directly underlie the peak magnetic anomalies A shift is caused by the
inclination of the Earths magnetic field and by the dipolar nature of
ferromagnetic deposits The inclination of the Earths field is about 76shy
degrees northward in the vicinity of Troy The dipolar effect is induced
by the Earths field and results in negative anomalies immediately north
of large positive anomalies
Magnetic Anomaly Map The magnetic anomaly map (Figure 1) indicates
10 positive peaks of varying size shape and intensity Associated
negative anomalies of a broader and less intense nature lie immediately
north of the belt of positive anomalies The configuration of the
anomalous area is indicative of lense-shaped and cigar-shaped bodies of
ferromagnetic materials Steep-sloped anomalies are indicative of very
shallow source materials The thickness of the ferromagnetic deposit
cannot be easily determined on the basis of intensity and size of
anomalous peaks because a small mass of iron or steel at the surface can
duplicate the anomaly caused by a much larger mass at depth The
ferromagnetic source materials can generally be expected to lie north of
the positive peak of anomalies and south of the adjacent negative
anomaly Modeling can provide the best approximations of the depth and
density of the ferromagnetic source materials The outer boundaries of
the source materials can be expected to overlap the positive peak and
negative anomaly somewhat depending on the depth and configuration of
the deposit
For illustration purposes two north-south rows that were profiled
are discussed below
Magnetic Anomaly Along Row 9-East Two strong positive magnetic
anomalies (3645 and 2436 gammas) and adjacent negative anomalies were
profiled along Row 9-East (Figure 2) The approximate centers of the
ferromagnetic deposits are believed to underlie stations 50 north and 75
feet south of the base line The rounded shape of the north positive
-JF Kick
anoraly nay indicate somewhat deeper burial of the ferromagnetic deposit
Magnetic Anomaly Alone Row 7-West Figure 3 shows the most intense
positive magnetic anomaly (4470 gammas) that was detected on this
project The steepeness of the slopes is indicative of very shallow
source materials An uneven burial pattern is suggested by the two-
peaked positive anoraly The negative anomaly south of the two peaks is
unusual and may be related to another positive anomaly to the southeast
(along Rows 5 and 6 20 feet north of the base line) The centers of the
sources of the positive anomalies are probably approximately 80 and 120
feet north of the base line along Row 7-West
-JF Kick 05shy
DISTANCE FROM BASE LINE(FEET)
CO
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6a
CO
LU CD
o cr CD o lt
i-mdash LU Lu 2 Q lt2 Z
lt ltr
CsJ
LU aIDCD Li_
SVWWV9 N A1VWONV
s
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0 O o
SVWWV9 NI A1VWONV
t o H
X
D 8 j~ 00
UJ UJ en UJ u UJ
o ui o CC
CO
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UI o
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0020
UJ U
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ro 8 LU
CC ID egt LL
APPENDIX D
LABORATORY ANALYSES
RAI
Resource Analysts Incorporated Box 4778 Hampton H 03842
(603) 92^7777
TO PO 830318
Mr Doug DeNatale Date Received 12-2-83 Kormandeau Associates 25 Nashua Road Lab Number 2887 Bedford NH 03102 J
Date Reported 1-3-84
IDENTIFICATION
SAMPLE DESIGNATION PARAMETER
Volatile Organics Analyses by EPA Method 624
Acid and BaseNeutral Extractable Compounds Analyzed by EPA Method 625
Metals Analyzed by Standard Methods 303A
Please see attachments for all results
Results expressed in mgL unless otherwise designated lt = Less Than
ClarkeFosterVan K o u w e i b r h 1 ANALYST DIRECTOR
METHODS Standard Methods (or the Examination ol Water and Waitewaler 15th Edition or other EPA approved mtlhodologiei unless otherwise designated
Phys ica l descr ip t ion of sample
LiquidSludop
Saiple workup
Volitile f ract ion Methannl F-1-rarMrm CSVJ Rdfi-Smm
Semivolatile f ra ictio0onication Extraction fSW 846-3540^ Inorganic f rac t on Acid Digestion (SW 84h-iOS(V)
ACS3 COMPOUNDS
rr t CAS CAS
(71 A) tt-Ot-2 i^t TT i^MoroprvrfgtOi (73B) 30-32-1
(23 A) J9-JO-7 ^bull^^ lof o^^ft^crt gto (7 OB) 205-M-2
(2 A) 13-37 -J 2- chlorophenol (75B) 207-01-
(3 A) 120-13-2 2raquo^icMoroorgtenol (748) 211-01-9
(MA) 103-47-9 2-dimethv lohenol (77 B) 201-94-1
(37A) U-73-3 2- niiroDhenol (7IB) 120-12-7
(MA) 100-02-7 raquo-niiroprienol (7raquoB) lraquol-2raquo-2
(raquoA) Jl-21-3 2 - in i tr opheno 1 (106) raquoi-73-7
(40 A) 33-J7-l k4-dinnro-2-mlaquothylplaquogtergtol (I IB) 15-01-1
(4A) I7-U-3 (xntictiloroorraquonol (I2B) J3-70-3
USA) 101-93-2 pxmol (I3B) 193-39-J
(14 B) 179-00-0 RASENEUTOAL COMPOUNDS
( I B ) 13-32- raquocmlaquophtgtgtefgtlaquo
(36) 92-173 benzidine (2V) 107-02-S
( I B ) I20-I2-I l2t-tricMorobenzlaquonlt (3V) 10713-1
OB) 111-71-1 he laquo laquoch 1 or o benz erve (laquoV) 71-A3-2
(176) 47-72-1 hetraquocWoroltthlaquone (4V) X-23-5
U S B ) 111-- bu(7-cloroetrivl)ether (7V) 101- 90-7
(7CB) 9 I -3J -7 2-Chlororuprthraquolene (10V) 107-04-2
(73B) 95-50-1 l2-diCMoroblaquonzene ( I 1 V ) 7|3j^
( K B ) XI-73-1 13-didilorobtnzene (13V) 7J-3-3
(27B) 104-M7 1tmdash djcMorobenzene dkV) 79-00-3
C2IS) 9i9i-l 33-dictgtloroblaquoazidinr ( I JV) laquo-3-J
(33B) 12I -U-7 2gt-dinicrotoluer (14V) 7J-00-3 (KB) 4O4-7C-7 24-dinitrotoluene (UV) 110-73-1 (J7B) 122-A4-7 1J -diprienv lhydrraquo z irf (23V) lt7 tt 3
(MB) Z0-fc-0 UuorraquonThelaquo (2raquoV) 7J-35-
(W551 700J77-3 -ctilorophenyl prlaquonyl ether (JOV) 1M-40-3
( raquo I 6 ) 10I-J3-3 raquo-6romoprgtefgtyl prtenyl ether (32V) 71-17-3
(raquo7B) 33132-9 bU (2-cMorobopropyl) ether (33V) 10041-02-4
(raquoJ6) i l l -91- l bu (2-laquo^loroeTho)ry) methane 10041-01-03
(B) D-U) hexraquopoundj1|orobutaltlicne (31 V) 100--
(33B) 77-raquo7- heiKCtilorocycIopentadicrve (WV) 7J-CT-2
OB) 7IJraquo-I traquoo oh or or (raquo3V) 7raquo-17-3
(J3B) gtl-20-3 nphthraquolene (UV) 7raquo-I3-9
(546) n-tj) nitrobenzene (7V) 7J-2J-7
(426) U-Xl-4 bullJ -n itr o tod iphenyU mi ne (UV) 75-27-J
(OR) 421-W-7 N-oitrcnodipropYlirrUne ^raquoraquoV) 73-49-k
(446) I 1 7 J I - 7 bu (2-eltr^lheryl) phtfaUte 8200 (3ov) 73-71-1
(476) 13-U7 benzyl buryl phttwlite (51V) 124-kt-l
( U B I M-71-2 di-fl-utgtl pMhUre (13V) 177-II-
( lraquo6) 117-1 -0 dj-n-octvl prithlaquoUte (UV) 101-IS-3
(7CB) W-44-2 dielhvlphtraquollaquo (17V) 79-OI-t
( 7 | B ) I 3 I - I I - J dj^laquorTvipnthraquoUtr (UV) 7J-OI- (776) H-J5-5 bnro(raquogtnthrraquocefvr
Iab I D N o 2SS-10
C l ien t ID 1A64223
RASENEUTRAL COMPOUNDS
bfzoltraquogtprrene
benzoltb)flucrraquornNene
benio(llaquo)fluorraquonthene
chryiene
bullcenaDhthvien
raquontnrraquoctne
benzoltghi)perrlefgte
Iluorene
phergtraquonthrmlaquo
dibenzoltraquoMaithrraquocenraquo
indeno(123-cd)pvrene
prrene
VOLATHES
(frolein
bullcrvlooitrdf
benien
orbon Temchloide
CMorobeniene
1 7-dJchlorolaquothnr
111-trieftloroethine
ll-ltJichloroetrufle ll7-triCilorigtetMrlaquor
l127-tetrraquocMorothfllaquo
chloroethlaquo-e
7-dMoroeThraquo|virgtvl eirwshy
chloroform
11-didMoro^tfwnr
trinj- 1 2-dictMorolaquoirgtene
1 7-ltlicMoroproplaquorve
trini- 1 3-ltJichloroorcrpeoe
cu-lJ-lieMorocT oo eashy
rthy Uveniene
methrlene chloridf
chloromethine
bromome thraquone
bro mod iCTi lore met Mrgt
(Juorotr ichloromthraquor
di cMlor od 1 f 1 uore ngtet hj^gt
chloreltJbnjmomethne
te tr ten 1 or oet rx-r
laquouene 12000
tncMeroethe^e
Cidrr ium Chromiutr 10
All results are expressed as ucg veicht as received Nc ertrv denotes -0r ~ ^ 1 i rt
P h y s i c a l d e s c r i p t i o n of
SoilSludge
sample
Sanple workup
Vol i t i le f ract ion p^r Exf- rar r ion fST7Semivola t i le f rac t ion So^h^Pt Fgtr f ra r f ion
846-SOTO^ (SWRdfi-^SiO1)
Inorganic fract ion Ar id nio-psrirm
AOD COMPOUNDS
m CAS (2i A) tt-04-2 2raquot- Wichlorophenol
(22 A) J1-50-7 p-cfi I or o-n-cre laquoo 1
(2A) 13-57-1 2- ctiloroprienol
O iA) 120-13-2 2raquo^icMoroprnol
(gtraquoA) 103-47-1 2f 4mdash^imetSv Ip^enol
(37 A) U-73-3 7mdash Ti j oprtenol
(JraquoA) 100-07-7 mdash mdasho i Br opr^e no 1
JJ1A) 31-21-3 if mdash4 irtiTroprienol
(40A) J34-32-1 4 T4-4initrogtmdash 7 nte tny Ipnenol
(4A) f y _H 5 plaquontchlaroorwnol
(43A) J 01-95-7 prienol
rV ipoundNEUTRAlaquo- COMPOUNDS
( I B ) raquoJ-32-raquo
(3B) 17-17-5
( IB) 170-12-1
(IB) 1I1-7I-I
(17B) 4777-1
( I t B ) 111--
(20B) 11-31-7
(236) 15-50-1
(245) 51-73-1
(77B) 104-4-7
(285) 11-14-1
(336) 121-142
(34B) 404-70-2
(J7B) 127-M7
O1B) 2O4--0
(406) 7003-72-3
(416) 101-35-3 lt raquo 2 6 gt 3H3I32-1 ltraquo36) 111-11-1 (57B) S7-U-3
(336) 77 -raquo7-
(36) 71-31-1
(33B) 11-20-3
pound34 6 1 n-i33 (UB) tt-30-4
(436) CI-44-7
(4461 117-11-7
(47B) U-417
( U B I 14-747
(U6) I17_t-0
(7CS) l-laquo2
(7 I B ) t J U t l - gt
(7761 54-55-3
CT-~- i_i w i Miirn 0
resul ts
b^TMdint
1 2 t-o- icn lorobenl ergtlaquo
SeTraquochloroblaquorierraquoe
hrxchlorolaquotSlaquone
bu(2-chloroethv|gtether
2 -lt3M or onraquo ph ti1 ene
1 2-ltJictilorotgtmzcne
13-dicWorotxerzene
1 4-djch 1 or otxn z ergte
33-ditfgtlorolgtlaquoniidirraquo
24-dinitrotoloene
2 4-dtnitro toluene
U-dlpoenylfiydrraquoiilaquo
(luoranthene
raquo-cfJorophenyl poenyl ether
Mx-omopfieflyl phenyl ether
bis (2-cMorooopropyt) ether
bu (2-ctilorcxtSorv) meiSkte
hezkOilorobutadicne
hei acM or ocyc1 ofMn udi cne
oo prior one
nphthlene
nurotxniene N -ni tro Kxd ipoenyU mi ne
N-rutrowxhpropYUmJrw
bu (2-thylherl)(gthlaquoiraquoUtraquo
blaquoniyl buryl phtfraquolaquoUte
dt-^t-^xjrvl pfttfuiLitY
dj-n-octyl pitflaquoLitraquo
dirthvl phtruUtt
OArriett^vt prraquoT^Lraquot
bnzoltklaquonihnicer
22 Chronium
ire ev^rescei as uc ^ ^i-~ht-
Lab 1U N o 28B-1
C l i en t I D 1 R R 7 A A R
RASpoundNEbTRAL COMPOUNDS
benroltb)fluorraquorgtthfflf
benzoraquollt)fluor intone
ltrylaquo-gte
bullcenioithylen
raquomtirraquoenlaquo
ben z oltxh i)per v lene
lloorene
poentnthrrne
dibnzo(4h)laquonthricrne
mdeno(I23-rt)pvre-ie
pyrene
VOLATU-Ei
bullcrelem
bullcrvlonio-Ue
benzene
caj-bon traquotrraquochloraquo-idr
Ctilorobernene
l2-diehlongtethne
iii-tnctltiorotKraquor Trace 1 T 1 -4)Ctilorampe^hArw
l f 1 ^-tric^i lor oefvtrve
l t l 22-teTrtclloroetl^Ane
ehloroethraquone
2-chloroltthr|viw| ttrve-
Chloroform
1 1 -ltSicMorot^nr
trinraquo-l2-dictiloroetrne
12-d^loropOStn
trinil3^ichloroproone
eis-lJ-diChloroprooene
rrhylberuene Tarce methrlene ehlor tat Trace
Ct1 or o m e t Kirgte
bromometKtrte
bro mod i rfi lor o rrgte t Mne
Uuorotrlchloromethraquo^e
OJ CJ lor od 1 f 1 uoro met hraquone
chJorodibromometKATgte
laquotrlaquociloroethrrx
toluene 9
tricolor otheir
fsw
T9
Sifi-TOSO)
(73B)
(7IB)
(75B)
(7(B)
(77 B)
(71 B)
(71B)
(SOB)
( t lB)
(I2B)
U3B)
(M B)
(7V)
(3V)
(4V)
(4V)
(7V)
(10V)
(11V)
(13V)
(14V)
(13V)
(14V)
(11V)
(23V)
(21V)
(30V)
(32V)
(33V)
(34V)
ltlaquoV)
( raquo J V )
(44 V)
f raquo 7 V )
(UV)
(V)
000 (30V)
Tlfl 151V)
(15V)
^00 (14V)
(17V)
(UVgt
-1 ZINT
CAS 30-32-J
205-11-7
207-01-1
211-01-1
201-14-1
120-12-7
111-24-2
14-73-7
13-01 -laquo
33-70-3
113-31-5
121-00-0
107-07-t
107-13-1
71-43-7
34-23-3
101-W-7
107-04-7
71-35-t
75-3-3
7^-00-5
71-34-5
75-00-3
110-73-1
(7-14-3
73-35-4
154-40-5
71-17-5
10041-07-6
10041-01-05
100-4I-
73-OT-2
74-17-3
74-13-1
73-25-2
75-27-4
73-41-4
75-71-1
174-41-1
127-U- IOUIS-) 71-01- 75-OI-
130
Lab ID Mo 2887-4
Phys i ca l d e s c r i p t i o n of sample C l i en t ID 4A5760
Liquid Sample was predominantlv a hvrlrnrarhnn bl pnd
Sanple workup Voli t i le f ract ion PEG Extraction (SW 846-5030) Scrnivola t ile f rac t ion Sonication Extraction (SW 846-3550) Inorganic f rac t ion Acid Digestion (SW 846-3050)
AC3D CS3U POUNDS 5AipoundNEUTlUgtJ- COMPOUNDS
ri CAS PPraquo CASf
(210 U-04-2 2raquot- tricMorophrnol (7)6) raquo-32-l braquoniolttVyre
[EM 51-50-7 ^-cti 1 or raquo-m-lt rlaquo laquoo 1 (7raquoB) 203-M-2 biMo(b)(luorinth^f
2 A) raquo5-57-J 2- cfiloropheryjl (7 3 B) 20701 benro(ilt) floor in tlaquo^e
(31 A) 120J3-2 2raquo-ltJicWoro(ygtlaquotx)l (74B) 2II-OI- chryve^e
(MA) 105-47- 2l-dimlaquothvloSrrgtol (77 B) 20Uraquot-J bullcwrioMhylene
(57A) u-73-3 2- ruTroohrgtol (TIB) 120-12-7 raquontnncergte
(34 A) 100-02-7 -oitrophenol (7gtB) lraquol-2raquo-2 benio(ghi)cgtrrylngtlaquo
(3Agt 51- 21-3 2 -4 initropherwl (SOB) tt-73-7 fluorme
(tOA) 53-37-l t-dinitro-2-mlaquothy lpNlaquoxil (II B) 15-01-4 pheAinthrrnlaquo
(A) I7-U-5 tgtentraquochlQroiywnol (I2B) 53-70-3 dibenplusmnoltraquoh)fcnthrraquocrne UJJ 101-55-2 rfwtwl (I3B) lraquo3-3raquo-3 indenol 1 23-cd)vrtie
(UB) I2raquo^X3-0 pyrer BASENEUTOAL COMPOUNDS
VOLATO-ES (161 I3-32- raquoclaquonraquophttgtngtf
(5B) 12-17 -J btniidir (2V) gt 07 -07-1 bullcrolem
(IB) 120-17-1 l^^iricfvleroboMux (3V) 107-13-1 bullcrvlonit Jlaquo (raquoBI IIS-7t| SeraquoChlorotgtlaquoterlaquo (raquoV) 7IJ3-7 benient
(I7S) 4772-1 heLCMorolaquothinc (tV) J-23-5 crtgton wtrraquocMoidf (UB) I11-U-I bll(2lttllorolaquot^w gtetNer (7V) 101-W-7 ltAtoroxniergtlaquo
(203) Jl-31-7 2 -etvl or onlaquo ph traquo I en e (IOV) 107-04-2 1 2-ltlicMorolaquoTKlaquone
(25B) raquo5-30-l 1 2-dichlorobenzene ( 1 1 V ) 71-JJ-t llI-trichlorolaquotNlaquoe (2 B) 31-73-1 l3-ltlichoroblaquonzenlaquo (13V) 7J-3A-) 1 1-6 1 cM or Of t (Mr
(77B) I04-M7 I -di CM oro ben z eoe ( I k V ) rraquo-oo-j l12-niichlorolaquotfvirraquolaquo
(2IB) raquol-raquo-l )J-dichlcroblaquorLiidinr (IJV) rgt-3laquo-3 J122-tetrraquochlcrolaquoTrie
(33B) 12I-Ilaquo 2 2-dinia-otoluer (UV) 73-00-3 Ctgtloroltthne U4B) laquoJ-70-7 2 t-dtnitrotoluene (1raquoV) HO-73-1 2-ltJilorocthv|vL-v| etrveshy
(J7B) 127-M7 14-dip^wnylhydraiine (23V) C7-U^-3 Ctilorofcrm
(JraquoBJ 2Ot-ugt-0 CJuarlLnthefe (2raquoV) 7J-33- 11 -ltlicMorcxil^nr
(mei TOCJ-77-3 -chJorophcnyl phenyl laquoKr (xgtvraquo lK-^0-3 tnjM-l^-diC^lofCKtl^nf
( M B I IOI-J5-3 -6romophnyl phenyl ether (32V) 7I-J7-3 12-dicMoroprosaA
(raquo2B) 3M3I32) bU (2-cMarobopropyU rtNer (3JV) ICXU 1-07-4 trraquoni- 1 3-ltjictgtloroBoor^f
(OB) t l l f l - 1 bi5 (2-cMoroetfxgtrv) meihtrw lOOt 1-01-03 cu-O-dichloroprose- (32B) D-U-3 hrxaetilorobutadierw (UV) 100-laquol-raquo rthylbenien 1^00
(33B) 77^7- he i kcMor ocyc 1 openudi crw (UV) 7J-OT-2 rrveThvlerw chlof idf
(36) 7I-gtraquo| oop^troo (raquoJV) 7raquoJ7-3 CtgtlorBmethne
(338) raquo|20-3 nraquopfitfillaquofx 1200 (wv) 7raquo-l3-raquo bromorrgtlaquothne
(34B) nraquo3) nitrobenzene (raquo7V) 73-23-2
(CBI U-Xl-4 N -fl i iro lod iphen yU mi nr (UV) 7J-27- bro mod i cti lor o mT bull- (OR) 42l^-7 N-^itrolaquoodipropylmlrlte (raquoraquoV) 73-traquo-laquo tl uor o tr i cfi lor o mlaquoT itr (UB) I I 7 J I - 7 bn (^thylheraquoy|) phttilaquoUtT 110000 (XIV) 75-71J QJ ct )or oltJ 1 f 1 uoro rrgtei ^bull gte U76) U-U7 blaquonzyl buryl pttTfKUie 12000 ( j i v ) m-i-i ctil or od ib ro mo met h xnf (UB) M-7i2 d i -n -bo TV 1 ft thlaquo U tlaquo (13V) 127-11- te trraquo cfl lor ot hlaquoTgtf (OBI 117-4J-0 dj -n -oc t y1 Jgth fflaquo U re 6 200 tuv) iom-3 tolucie ^70
(7CB) u-u- djrthyl phtJMlire (17V) 7raquo-OI-4 irictilarcraquo^lt-ir (715) 1 3 1 - 1 1 - 5 oVnrrhyl pMtfaUte (UV) 75-OI- v i M v l CMor idr
(T76I 5-55-3 blaquorgtzo( Unihrlaquocme Xylenes 1SOO
Cad- iurn 2 2 on Chromium - - Z I N C ^ ~ P r
Ai results arc expressed as ugc weight as received Xo entry denotes not detects
Lab ID No 2887-3 5A 57709 Phys ica l d e s c r i p t i o n of sample Cl ien t ID
LiquidSludge Liquid appeared to be a hvdrnc-Arhnn blonrl
Sample workup
Vol i t i l e f r ac t ion Methanol Extraction fSW 846-5030^ Semivolatile fract ion Sonicatlon Extraction fSW 84 f i_3550gt) Inorganic f rac t ion Acid nic-psr-inn fSW 846-30501
ACS3 COMPOUNDS BASENEUTRAL COMPOUNDS
f f t CAS CAS (2IA) tt-04-2 (738) JO-32-J DCftZ OTamp p V^^^ff
(22 A) 3laquo9-50-7 p-cttl or o-m-cre laquoo 1 (7VB) 205-99-2 p^^izot oil lyor 4-^ t ^ltf ^^
(2 A) raquo5-37-l 2- CJiloroprieno (75B) 207-01-9 blaquonioltllt)flultxtn^it
(31A) 120-13-2 2raquo-dictgtlcr8tgtrfX)l (74B) 211-01-9 Chryeolaquo
(3 A) 103-47-9 2 -d irrgtet hv Ipherto1 (77B) 201-94-1 laquocnphthyle^
(37 A) 11-73-5 2- rutrop^enol (7IB) 120-12-7 bull^thrjc c^
(MA) 100-02-7 -flitroprlaquorv3l (79B) 91-2-2 bcnroltKhi)pefraquoler
(79A) 31-21-3 2 -d in itr eoricno 1 (IOB) 14-73-7 tluoren
(40 A) 33-37-l 4-d in itr raquo-2 -met hy Iphtnol ( I IB) 13-01-1 poltrtAOthrvTgt^
(44 A) 17-14-3 plaquon1 CM or o^eno I (I2B) 33-70-3 dib^fi-o( 4(K)Aji thirl c c^f (43A) 101-93-7 prwnol (S3B) 193-39-3 indcnotlIJ-ctflsvfie
(SB) 129-00-0 pyrene ftASENEUTRAL COMPOUNDS
( I D )
(5B) 92-X7-3 b^zidrw (2V) 107-02-1 bullcrolrm
(IB) 120-17-1 1 2 fc-Tr ICJ caro blaquoni crw (3V) 107-13-1 bullcrvlonitrij
(93) 1IU7I1 Seraquochlcrotgttniegtlaquo (4V) 71J3-2 blaquonienlaquo inn (17B) 4777-1 hexat^lorcwthgine (4V) H-23-5 carbon ttTricllixidf
( I I B ) 111-wJ bll(2-lt3^1oroltt^w)ether (7V) 101-90-7 ciloroblaquonzene
(20B) 91-31-7 2-ctdo-ont she Ime (10V) 107-04-2 12-dieftloroerane (25B) 95-50-1 l2-dilorobenzene ( 1 1 V ) 71-35-4 11 1 -tricMorotn-laquo
(2ampSI 51-73-1 13-dicMo-obenxerw (13V) 73-3-3 1 1 -d i CM orcxt M-
(77 B) I04-H-7 1 -di ci 1 or o benI erw (UV) 79-00-3 llJ-WiChlorolaquoflaquonlaquo
(2J6) 91-90-1 SS-dKJilorotxniidinc (13V) rraquo-3laquo-3 l122-tetrlaquocftlorelaquoTrne
(35B) 12| |k-2 2fc-dintrotoluene (14V) 73-00-3 diloroeth^e
(gt4B1 404-20-2 24-diniTrotoluenlaquo (19V) 110-73-1 2-cMortxfthv|vL-raquo trlaquoshy
(37B) 122-447 12-diphenylhydriin (23V) 47-44-3 cMoroform
(J9B) 204-U-0 Ouormntherve (29V) 73-33-i ll-diCMorolaquot^nf
(fcOB) 7005-77-3 k-cMarophfy| prlaquonyl etScr (gtOV) 134-40-3 trraquonraquo- 1 2 -dicMoroc t Nenf
(raquo I6) 101-35) raquo-6romoprny| phenyl rther (32V) 71-17-3 12-diChloropostn
(raquo2B) JH3IO2-9 bU (2-ltplusmnlaronopropyl) rthrr (J3V) 10041-02-4 trni-l)-diirMoroxtgtOpnf
(OB) I I 1 - 9 I - I bu (Z-chloroethxjrv) metSampnlaquo 10041-01-05 CU-D-djcMoroproOf-W
(32B) 17 -U -3 hiraquocfilarobutraquodiergtlt (3JV) 100-4U rttyligtlaquonitrgtlaquo 5300 (33B) 77-raquo7-raquo hrxicftl or ocrclopei tidier (UV) 75-09-2 nxthylenf ctilor ifif
lt3B) 71-391 ao prior or (raquo3V) 7raquo-17-3 rtloromrtha^r
(356) 91-20-3 nlaquoprithienraquo Trace (44V) 7raquo1Jraquo bromltmlaquoth^
(MB) n-93) ft i vo b^nz c^^ (raquo7V) 73-23-2
(425) U-30-4 ^bullf i^OftOOL^ri^ny lArrunf (UV) 73-27- bro mod i cgt lor o i~ t gt
U3amp1 Ul-4-7 N i itr CrtoO ip ro py 1 laquo ml r (raquo9V) 73-49-k U uor o IT 1 et loront Mrgt (UB) II7-1I-7 bu (2-Ihythlaquoryl)prtfUtr 59J300 (30V) 73-71-1 dj ci kr olt11 f 1 uoro rrrt (Nrgtraquo
(47 B) L3-41-7 txniyl burvl phthlaquoUtr ( 3 1 V ) I2-1-1 ch1 or od i b ro mo mi IMP r
(UBI U-71- 0-A-fcurl BMMliw (13V) 127-ll-i rt tr t cM or of tNr
Uraquo6) 117-li-O di-n-oCTv| pnttlaquoUfr 6000 (UV) lOt-II-3 toluenf 5700 (7CB) U-447 djrthvl p^tfvilirt (17V) 79-01-4 WiCMoroth^e ( 7 J B I U l - l l - 3 d^M^vl prttgtraquoUW (UV) 73-01- vinv t cMor 10 (77 Bgt H-35-) brto(raquollaquonthncrTraquo Xylenes 19000
Caen 1U~ 1 Chromium =2 Z I N C
All results are expressed as up g weight as received No errrv ripn^t-plt
Lab 1Lgt No 2887-5
rhyr i r n l d e s c r i p t i o n o f sample C l i e n t in 6857710
LiquidSludge
Sample workup Vol i t i l e f r a c t i o n PEG Extraction (SW 846-5030) Semivolat i le fr action Sonication Extraction (SW 846-3550) Inorganic f rac t ionAcid Digestion (SW 846-3030)
AOD COMPOUNDS BAStNELTTRAL COMPOUNDS
rr i CASI CAS (21 A) tt-04-7 (736) 30-32-1 bntoltraquogtprrene
(23A) 3-9-50-7 p~lt1 or o-m-c rraquo1 (78) 205-99-2 ben to( Sgt )1 1 uor raquon I he-gtf
(7raquoA) 93-37J 2- etilorophenol (73B) 207-01-9 beriioltk)(luortntrgt^f
(3 IA) 170J3-2 2raquo-dicMoroprnol (7(B) 2II-OI-9 eifVMTie
(3 A) 03-(7-9 24-4mlaquoThvlDheno| (77B) 20l-9(-i bullceraoMhyler
(37 A) tt-73-5 2- rue-oorienol (718) 1 20- 2-7 laquoflthrraquocene
(3 A) IOO-02-7 ^Mtroprwnol (7fB) 191-24-2 beraquoMoltsrM)plaquovllaquox
(39 A) 3I-71-5 2-4 ini tr ophero1 (tOamp) K-7J-7 tluwtrie
((OA) 33-37l (-lt iMtro-2-methylphenol (tlB) D-01-J phenATithrene
(4A) I7-44-J pentichlorophenol (128) J3-70-3 dilwnioltraquoh)laquonthrraquoceif
(OA) IOI-95-2 prwnol U38) 193-39-3 indeno(123-cd)vcne
(MB) 129-00-0 pyrergtlaquo 6 ASENEUTILW- COMPOUNDS
VOLATH-tS ( I B ) 13-32-9 ftCYTNA pO IT H I raquolt
(38) 92-17- o^nzioinc (7V) 107-02-1 aero le in
( IB) 120-I2-I l2k-o-i(3iloroblaquontergtlaquo (3V) 107-13-1 laquocrvlono-U
OB) Jl l-7fc | he I raquocti 1 or o blaquonI enlaquo (V) 71-43-2 Oltf2 tO^
(17B) (772-I he uc^i 1 or of t h ne ((V) 34-23-3 CJU JOO Tt TTlCfllo^ iCpound
( I I S ) bu(2-rfilcroethv|)ether (7V) 10J-90-7 laquoWoroblaquonzeoe III-44-4
(KB) 9I-51-7 2ltfMoronlaquoohttvraquolwe (10V) 107^)4-2 1 t2^ojo^loroetfft^c (2JB) 95-50-I 1 2 -dichlorotgtlaquorlene (11V) 71-55-4 1 1 1 -trichloroeihtr (251 541-73-I 13-dchlorotxniene (13V) 73-J4-3 1 1 -dieMoreeraquohraquorlaquo
(77Bgt 04-lgt4-7 1 mdash djcMorobenlene (IkV) 79-OO-3 t12-tricriloroeflaquofgte (2gtB) raquolraquo-l 33-didMoroblaquonjidirlaquo (13V) 79-34-3 1122-tetrcnicroeir^ne (33B) 12 I I 4 -2 Z4-diniiroioluerlte (1(Vgt 73-00-3 e^loroetruuie (KB) (04-7C2 2 (-dinitro toluene (19V) 110-73-4 2ltJilorolaquotr(v|vLnraquolnhlaquo (175) 122-447 12-dipr-enylfiydrmiine (23V) (7-44-3 chloroform
(J1B) 704JJ-O Huor^thrr (29V) 73-33-4 lI-ltJicMoroltthcne
(OBgt 7003-77-3 -ctJoroprienvl phenyl ether (JOV) 134-40-3 irirraquo-12-dictila-olaquotrlaquone
( raquo I B ) IOJ 33-3 -6ogtmoprienyl phenyl ether (32V) 7I-I7-3 l7^lichlorepreoine (laquo2BI 3H3raquoO2raquo bit (2-chlororaquoopfT5pyO ether (3JV) 10041-02-4 trint-l3-ltJicnloroBlt-ooee (OB) 111-11-1 bis (2-cMcroetro(v) metSuvr 100(1-01-03 CU-lJ-itflloropOO-^
(376) t7-U-3 hraquoz raquoch1 or o bu tlaquodi ene (J1V) )00-1- erhylberuer 1400 (33B) 77 -gt7- hei tchl or ocyc1 open traquodi ene (raquoV) 73-09-2 methylene chloriCf OB) 7raquo-3raquo-l BO prior one (raquo3V) 74J7-J eMorametrutne (33B) raquol-raquo-3 naphtfalene 100 (UV) 74-13-9 bro rrvome t hrgt (3iB) n-raquo3-3 niireblaquor)iergte (raquo7V) 7J23-2 (CB) U-XH N -01 ITo tod 4gthenyU rru rr (UV) 75-27-4 bro mod i ch lor o rrx t f4Ugt ((36) 42IO4-7 N-nnroodipropYlraquomlrlaquo (raquolaquoV) 73-4t-4 JJuorotr lchloronvlaquoiMftlaquo (Uol U7-1I-7 ba (2-etrylNraquoYl) phtt^Ure 100000 (30V) 75-71 -raquo dj cftlcr od U 1 vraquooro rri NUT
(47 Bl 13-44-7 t^niyl butvl phthiUte 13000 (31V) 124-41-1 chlorodibromorrwt^r
lt U E gt ) U-71-2 d-ojjurvl phtf^Ure (13V) 127-11-4 tr trbullcti loro rirr
laquoraquo6gt 11704-0 dl-fl-OCTvl pfltMUM (UV) 10t-ll-3 toluene fiin (TtS) raquo-laquo djrthvl phttuliTr (17V) 79-01-4 tricolor oethenr lt 7 | o l 131 -11 -1 (UV) v i n v i chlcwidr dimrlKyl rrftlaquoUTraquo 75-OI-J
(T75I J4-35-J blaquoTMOlt^trrlaquocr^ gtylenes 1200
Cadr ium 3 Chromium 21 ZINC 150
All results are expressed as ugg weight as received y0 entry denotes not detect
Iah I D No 2887-2
Physical descr ip t ion of sample
Strained Soil
Sample workup
Voli t i le f rac t ion PFG Extraction (^W 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-3540) Inorganic fract ion Acid Digestion (SW 846-3050)
ACS) COMPOUNDS
rn CAS Tft CASf
(21 A) tt-04-2 (73B) 50-32-4
U2A) 71-50-7 P-ch 1 or o-m-cre laquoo 1 (7k 8) 205-11-2
(2 A) raquo3-37-l 2- chloroprraquoeno| (75B) 207-01-1
(3IA) 120-13-2 2raquo-4ichlorophenol (74B) 21UOI-1
(3 A) 103-47-1 24-dimethvlphenol (77 B) 201-14-1
(57A) U-75-3 2- njtroDhenol C7I5) 120-12-7
(MA) 100-02-7 a-flitrophenol (71B) |1l-2raquo-2
(51A) 51-21-5 2 -d in i tr o phetio 1 (SOB) K-73-7
(40 A) 53-57-l raquo 4-dinitro-2-methy lprnol (tlB) 15-01-1
(4 A) 17-14-3 plaquoitraquochloroorlaquonol (I2B) 53-70-3
(43A) IOt-13-2 prlaquonol (13B) m-31-3 (MB) 121-00-0
BJ KSENCLmLAL COMPOUNDS
(IB)
(3B) 12-17-3 bcnzidine (2V) 107-07-1
(IB) 120-17-1 1 2 k- tr i ch 1 oro benr ene (3V) 107-13-1
(IB) I1U7I-1 he it raquocM or o boiz ergte (raquoV) 7I-J3-7
(12B) 47-77-1 he traquoch 1 or oet hlaquo ne (4V) 54-23-3
(116) 111-- buC-cJiloroethv|gtether (7V) 101- W-7
(20B) 11-31-7 2 -ltft 1 or on ph ttvraquo 1 laquon e (10V1 107-04-2
(23B) 15-30-1 1 2 -dictilorobeni ene (11V) 71-55-4
(25) VI-73-1 1 3 -ltJ i ci 1 or o blaquoiz ene (13V) 73-3-3
(77 B) 104-M7 llaquo-dchloroblaquoMeoe (HV) n-00-3
(2IB) 11-lk-l 33-dicMorotxTLtidinr (15V) n-3raquo-3 (33B) 12I-U-2 2 ltgt -4 in i tr ot o luene (14V) 75-00-3
(MB) 464-20-2 2 4-d initrotoluene (11V) 1 10-7 3-1
(J7B) 122-447 1 2-diprieny Ihydrti ine (23V) 47-44-3
(316) 2O4-UO Ouorraquonthene (21V) 73-33Jshy
(WB) 7t)03-77-3 ^-cJJorophenyl prienyl ether (JXgtV) 154-40-3
(MB) 101-33-3 -6romopriefgtyl prienyl ether (32V) 71-J7-3
(raquo2B) 3431-32-1 bit (2-chloroboproprO ether (33V) 10041-07-4
(OB) I1U1I- I bu (2-ltMoroethorv) methane 10041-01-03
(52B) r-u-3 hexachlorobutadiene (J1V) 100-l-raquo
(33B) 77-47- he z raquoctlt lor ocycloqenud i crte (MV) 75-01-2
OB) 71-31-1 ao prior one (raquo3V) 7raquo-17-3
(33B) 11-20-3 nlaquopntrlaquollaquone (UV) 7raquo-13-1
(MB) n-13-3 nitrobenzene (raquo7V) 73-23-2
(UB) U-30-4 N-nnroiodiprienyUmine (UV) 75-27-k
(436) Ol-U-7 N-nitrModiproOYlmJne (raquo1V) 73-41-
(UB) 117-117 bu (2-laquothylheiry) phtrlaquolte 8800 (50V) 75-71-1
( 4 7 B ) L3-U7 blaquoniyl buryl phthaUte 30 (31V) 12I-H-1
(UB) U-7U-2 di-o-burvl phtrMUte U3V) I27-I1-
(416) II7-U-0 dj-n-oCTvl pritntUtr 1200 (raquo4V) IOUI1-3
17CB) U-44-2 djetiTi phrtultrt (raquo7V) 71-01-4
( 7 I B I 1 3 1 - 1 1 - 3 dimnfTraquo| prThraquoUtr (UV) 73-01-
(776) H-35-3 berMolta^thrCF^
Cl ien t ID 8 A - S 7 4 6 1
RASENEUTRAL COMPOUNDS
benzofbtfluor^tMe
benzodclfluorintoent
Ctiryiene
cenoithylene
raquonthrraquoctne
benzoltKhilpervlefgte
floor ene
prlaquofnnthrene
ltlibenplusmno(4h)knthricrnlaquo
inogtno(123-rt)pvrrne
pyrene
VCX-ATIIE5
bullcrolem
bullcrvlomn-U
benzene
carbon tetrtchloridf
chlorobenzene
1 2-oUchloroethAnf
lll-trichloroethlaquone
ll-dcfioroethrraquo
1 1 2-tricilorolaquothraquorw
1122-tetrichloroeTtvin
chloroethre
J-ctiloroethv|vinv| etrgte
chloroform
11 -denier oethene
trinraquo- 1 2 -4 cMor oe t hens
12-dcMoroprooine
^Lns~ I f 3-4ic^ lo^opf oo^^^
Cli-l 3-dicMoroprooe^e
rttiylbenzene
methylene cnlonfle
Ch 1 or o me t hane
bromome thane
Trace
bro mod i cMor 0 me t hane
(Juorotrlchlorome thane
chlorodibromometKinf
tetracnloroethervp
toluenetr icMoroel he-if
Trace
CacTiiun Chromium ZINC f
All resxil ts are exprp^spr i K-i
Phys ica l de sc r ip t ion of sample
Strained Soil
Sample workup Vol i t i le f ract ion PEG Extraction (SU 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-5340) Inorganic fract ion Acid Digestion CSV 846-3050)
ACE) C30laquo POUNDS
m CA5i CASraquo (2i A tt-C-2 (73B) JO- 52-1
(22 A) J1-JO-7 p-ch 1 or raquowTv-cre 101 (7raquoB) 203-raquoraquo2
(2 A) raquo)57-J 2- chlorophenol (73B) 20701-
(31 A) I25J3-2 2k-4icttlltroptlaquonol (7tB) 211-01-1
(3A) IO)-7-raquo 2-dimlaquothvlpNrnol (77 B) 20l-raquoi-
(37 A) u-rj-j 7- niTTOphenol (TIB) 120-11-7
(MA) 100-02-7 -rtropN-rraquol (7raquoB) lraquol-2-2
(JraquoA) JI-21-) 2-d initroprietys 1 (IOB) U-73-7
(MA) 53-37-l Udinnro-2-mlaquothylphenol (UB) I5-OI-J
(Agt I7-U-3 pentichlcropwnol (126) 33-70-3
laquo)Agt 10l-raquo)-2 phenol (I3B) IJ3-31-3
(MB) 12raquo-00-0 AASCVflCUTRAl COMPOUNDS
( I B ) I3-32- bullcnraquophtber
(56) raquo2-17) bnzidirlaquo (2Vgt 107-02-1
(IB) 120-12-1 l2btrilt7tlorotgteizegtlaquo (3V) 107-13-1
traquoB) IIraquo-7fc | heikcMeroblaquonzergte (V) 7l-3-2
( I 2 B ) 4772-1 he ueft 1 or olaquot hraquo rgte (tV) laquo-23-3
( i ts) III-- biraquo(2-cMoroethv Dethrr (7V) 101-W-7
(20Bgt 1I-3I-7 2-cMoroflaquophthlene (10V) 107-Ofc-2
(2)6) raquo5-50-l l2-dchlorotgtlaquonzefgte (11V) 71-33-4
(28) 3l-7)-| 1 3-didMoroblaquonrenlaquo (13V) 73-3-3
(27B) 10t--7 l-diclorolgtmzerlaquo (iV) rraquo-00)
(216) raquoI raquoltbull- 33-dichloroblaquoMidiflaquo (13V) 79-31-
(356gt 2I- l-2 21-dinitrotoloen (UV1 73-00-3
(UB) laquogt- 20-2 2 (-dinitroto luenlaquo (HV) 110-7J-J
(376) 122-W-7 14 -dipheny Ihydrzire (23V) lt7-M-3
(396) 2O--0 tJuoruMSene (2raquoV) 7J-35- (OB) 7003-77-3 -c^lvophenyl pNrnyl ethlaquor (30V) 1H-W-)
(MB) 101-33-3 bull-bromopriefiyl prienyl ether (32V) 7t-t7-3
ltraquo25) 3HJI-32-1 bU (2-cMoroaopropyl) rthrr (33V1 10ltX 1-02 -6
(06) l l t - t l - l bis (2-cftloroetSorv) metwne 100lt]-01-03
(32B) C7U-3 heraquoraquochlorobutidierx (31V) 1 00-41-
(3361 77-7-raquo hexiOilorocycloptfiudlerve (raquoV) 73-0raquo-2
(56) 71-51-1 no ph or one (raquo3V) 7raquo-17-3
(3)6) raquol-raquo-3 rwiphtfalme (UV) 7raquoJ3-raquo
1361
LUB)
H-133
14-30-4
nitrobenzene
^ ri i iy o too ipf^^ y LA r^i rtf ^ 7V) (UV)
73-23-2
73-27-
(436) t21--7 M^TI iff frfcO^ip ropy Ift mJf^ (gtraquoV) 73-4raquo-raquo (UB) I17J1-7 bu (2-rThyiruMcyDpMtvUtr 570 (jov) 73-71-1 ( U B ) U-41-7 blaquonzyl buryl phthlaquoLite (31V) l2k-raquo-l ( U B I U-7I-2 di-n-burvl pitftALtTe (raquo)V) 127-lt-fc
(OB) 117- -0 dJ-fraquo-oCTvl phlJ^Ute (UV) IOt-It-3
(7CB) 14 -W- 2 djelftvl phtfalitt (17V) Tt-01- ( 7 I B I 1 J I - I 1 - ) duTNnhylphttsraquoUw ltUV) 75-01-
(77BI X-))O lgtmrlaquoigtmhrraquoctf
Cadmium f iQ Chromium 15 ZINC
Tab ID No oo -
Cl ient ID 8A-A-64220
fcASENEUTTRAL COMPOUNDi
blaquofuo(raquo)pyrrtgte
bfizo(b)(loortAth^e
benzo(k)f|ulaquoin1herf
Ctiryiene
cenDraquoMrwlene
fcftT^rict^t
D^flZCT (fftl)pC^ V Itf^p
(luorene
phen^threne
diiwnztKthlanthricene
indlaquono( 1 23-lttf)pvrene
oyrene
VOCATtLES
bullcrolem
bullcrvlooitriJe
bervteoe
carbon WTTicMoridf
chlorobenze^e
12-djcMoroetfane
1 1 1 -tricolor ex tKraquon
1 1 -dicMarcx t hrlaquo
1 1 2-triChlorothraquorw
1 122 -laquotrraquocM or o-hraquorgt
cMoroettu^e
2-cMorlaquothv|vuy| rseshy
chlexeform
ll-dchloroctfgtn
tri^iraquo l 2laquoflic^ loTo^i rgtcnt
12-dicWoroproptrs
Winl-l3-dicMoropfooene
Cu-lJ-djChleroprooe^
rrtiylfrenzene
methylene ctiloride 0 64
cMorometHAne
bromomlaquothlaquone
bnsmoform
bro mod i eti lor e me t Nine
0 uor o tr 1 cMor e rrgtlaquo t Nnlaquo
dj di tor olaquol If 1 uoro mraquoi Nrraquo
chlorodibromonveiKme
re tr a en 1 or or fxrvr
toluene
D-ieWoroefwne
entry denotes not detect All results are expressed as ugg weight as received Xo
Lab 1) No 2887-8
Physical descr ipt ion of sample
Sf-rs inpH 9 n i l
Sample workup
Vol iCi le f ract ion PEG Extraction (SW 846-5030)
Scmivolat i le f ract ion Soxhlet Extraction (SW 846-3540) Inorganic fraction Acid Digestion (SW 846-3050)
ACD O3MPOUNDS
m CAS fPraquo CASf pi A) tt-Ot-2 Zraquot- tritilorophrgtol (73B) 30-32-1
ft M -3o-7 p-cMorraquo-m-crTraquool (7kB) 205-raquo-2
(2 A) raquoS-37-l 2- cMorop^erxgtl J73B) 207-OI-raquo
(31 A) 120-13-2 l^ictiloropix)l ^7tB) JII-01-
(3 A) |03-7-raquo 21^-dimeThvlphenol (77B) 20t-raquot-l
(J7A) tl-73-3 2- rutropwnol (71 B) 120-12-7
(MA) 100-02-7 -MO-opwnol lt7raquoB) lraquol-2-2
fJraquoA) 3I-2J-3 2-dinitrop^laquoTgtoI ((OB) U-7J7
(laquogtA) J34-37-1 lt-dinitrfr-2-methylpwrxgtl (I IB) I 3-0 1-1 (raquoAI 17-1 3 pcmacMcroptonol (S2B) J3-70-J UJA) IOI-raquo5-2 phenol (IJB) MJ-39-J
(tBgt 12raquo-00-0 RASEfZUTRAL COMPOUNDS
( IB) 13-32-f raquocertaprithene
(3B) J2-17-3 twnndinc (2V) 107J2-J (IB) 170-I2- lr2k-triOilorobenzerlaquo (3V) 107-13-1 (raquoB) I11-7I-I hei bulllt1 ore blaquont ergtlaquo (raquoV) 7l-3-2 (1B) 47-72-I he ucft 1 or oe t h n (tV) 3-23-3 (116) |II_wJ bu(2-ctiIarothvI)laquotNer (7V) 101-90-7
(20B) raquoI-JI7 2 -cW or orvraquo ph tf I ene (10V) I07-Ofc-2 (23B) J3-30-I l2-lt5ictiloroblaquonzeoe (11V) 71-3J- (245) 3I-7J-I 13-dic^lorotxenzenc (13V) 7J-3-3 (27B) 104-K-7 1 mdash diC^lorobtnrerve ( lraquoV) 7^-OO-5 (21 B) raquo|raquo| 33^icftlorobenzidifv (I3V) rgt-j-3 (33B) I 2 I - U - 2 2ltgt-dinin-o1olvraquorgte (UV1 75-00-3
(J4B) 404-JO-2 21-dinitrotoluerve (1raquoV) 110-73-1
(37B) I22-W7 1 2 -d ipheny Ihydra z ine (23V) C7-14-3
(318) 2O4-W-0 tJuortnihrne lt29V) 75-3J- (kOBt 700J-77-J ^-tfMoropheTgtyl p^enyl ether (30V) 1J4-W-3
( raquo I B ) IOI03-J raquo-6romopfgtenyl phenyl ether (32V) 7I-I7-J
(06) 3H3raquo-)2-raquo bU (2-tfilerobopropyO ether (3)V) 10041-02-i
(OB) lll|| bii (2-cMoroethoxv) methane 10041-01-03
(37B) PUt) hxzraquocMorobutadienlaquo (J1V) 100-raquol-raquo
(JJB) T7^7U heztctilarocrclotMnttdicrgte (V) 7gt-0raquo-2 OB) 7l-3raquo-l BO ph or one (raquo3V) 7raquo-17-J
(338) raquo|20-3 rlaquopritrilaquolene (UV) raquo-laquo-raquo
(3iBl n-raquo3) nitrobenzene (raquo7V) 75-23-2
(CB) li-X)-t N -n i tr o tod ipheny U mi nr (UV) 73-27-fc
(06) CI-U7 N^iitroiodipropYUmlr ^raquo1V) 73-H-fc (UB) 117JI-7 bu (2-ethYlNerrl)pM^Utr 12000 (JOV) 75-71-1 (47 B) L3-U7 llaquoniyl buryl pht^UTe 2 800 ( 3 I V ) 2laquo-raquo-I (UB) raquo-7i2 di-o-ourvl pritfwiUrr (I3V) 127-lt-i (196) 117-14 3 dj-n-ocryl pritfiiUrr (UV) IOUIS-3
(TCB) J4-W-2 djnhYl phtfalitt (17V) 7t-01-lt (716 ) 1 3 1 - 1 1 ) damnhYl pMtuUTT (UV) 73-01- (77 Bl 3 33-3 frlaquon z olt raquo klaquom h rraquo c prgte
Cadmium T^ Chromiurn T Z T N C 100
Client ID 8A-C64221
BASENEUTRAL COtPOUNOS
bnzo(t)pyrrrie
benzobXluoriflthei blaquorizoltVHluorraquontrraquone
chryiene
bullcenphthylene
tnthneene
benzoltRM)perylene
fluorene
prienlaquonthcTTgte ditgtmplusmnolt4hluithrraquoctnf
indenof 1 23-cd)pvrf ne
pyrer
VOUATILES
bullcrolein raquocrvlonnrile benzene cmrbort Tetrichloride
chlorobenieoe 1 2-oUchloroethirie
11 1 -tricolor oethne ll-dvchlorolaquollMr 1 1 2-w icMoroethAoe l122-tetrieMoroeihilaquonlaquo
chloroetKvne JltJilorothvlvmv| ethe chloroform
11-dicMoroethent
trani- 1 2 -dicti lorolt t hene
1 J^JictiloroproBfVf
trim- 1 3-4ietiloroproperie
Cil-IJ-dicMoropfoOerie
rrhyUxrmene
methylene criloride
chlorornethine
bromome thne
007
13
tluorotr l^VoromlaquotNraquorgtt
da ch lor od 1 1 1 ooro frvet hraquone
chlorodibromometlvinf
te trraquocnloroeT rrrr
tricMoroetSmr
All results are expressed as us2 weight as receixred No entrv denotes not detect i
Phys ica l descr ip t ion of sample
SoilCake
Sample workup
vol i t i le fract ion ^FP FvfrarfMnn (ltU Rif i mdash Smrn
Semivolatile fraction Soxhlet Extraction (SW 846-3540^ Inorganic fraction Acid Digestion (SW 846-1050)
AC23 COMPOUNDS
rrt CAS CAS
(21 A) 11-04-2 2raquo4- trieMorophenol (738) 50mdash 3-4
122 A) J1-30-7 p-ctil or raquo-nvltrlaquo laquoo 1 (7laquoB) 205-11-2
12 A) 13-37-4 2- etilorophenol (75B) 207-01-1
(31 A) 120-13-2 2raquo-diclorophlaquoTgtol (74B) 211-01-1
(34A) 103-471 24-dmlaquothylphrnol (77 B) 201-14-4
(57 A) U-73-3 2- rutrop^nol (7raquoB) 120-12-7
(54 A) 100 -02-7 bull i tro p^c 01 (71B) 111-24-2
(J9M 31213 Z o trt i tr o poc^oI (MB) U-73-7
(40 A) 334-32-1 T^Hjinitrfr2^rt^T ny tp^gt^noi ( t lB) 13^)1-4
(44A) 17-44-3 pcnttchlaroprwnol (S2B) 33-70-3ltOA) IOt-IJ-2 pTUfNOl (136) 113-31-3
ftASENtUTRAL COMPOUNDS (MB) 121-00-0
(IB)
(56) 12-473 Iwnndine (2V) 107-02-1(IB) I20-IJ-I 1 2 4-tr icJi lorobeniervr (3V) 107-13-1(IB) 11 1-711 hexkcMarobcnzeM (4V) 71-43-2(126) 47-72-1 hexch)eroeihlaquone (4V) 54-23-J( I I S ) 111-4- bu(2-eMorlaquothv|)laquothr (7V) 101-10-7
(208) 11-51-7 2-c^laronraquophtfgtlene (IOV) 107-04-2(23B) 1J-30-I 1 2-dichloroblaquonime (11V) 71-35-4(2651 341-73-1 gt3-ltiictitaroblaquonxcnc (13V) 73-54-3
(27 B) 104-47 l4-dicMorotKmrerlaquo (14V) 71-OO-3
(21 Bgt 11-14) 33-4ichlaroblaquon2idine (15V) 71-34-3
(338) 121-14-2 24-dinitrotoluene (14V1 73-OO-3(J4Bgt 4O4-20-2 24-dinitretoluenc (11V) 110-73-4(37B) 122-447 lraquo2-dip^nylhydrraquoxirlaquo (23V) 47-44-)(MB) ro--0 Uuaranthene (21V) 73-33-4(406) 7003-72-3 4-ltUorepfraquonyl phenvl rtSer (30V) IH-40-J( raquo I 6 ) 101-333 4-6romoprlaquonyl pflaquony| ether (32V) 71-17-3
(OB) 3H3I-J21 bll (2-cti|orobopfrgtpyO ether (33V) 10041-02-4
(OB) I11-1I-I bis (2-cMaroethoxv) methane 10041-0103
(57B) P-44-) hczw^lorobundiene (J4V) 100-41-4
(JJ6I 77-47-4 htTicMarocyclojxrtadien (44 V) 75-01-2
(346) 71-31-1 aophoroo ( raquo ) V ) 74-47-3
(33B) raquo|203 r^pn thA Icr^ (44V) 7 -raquobull J-
(546) n-i3) H i frovCftZfl^^ (raquo7V) 73-23-2
142B) 14-30-4 S -n i tr o laquood ipheny Lt mi nc (44V) 73-27-4
(43 B) 421-447 N^iitrotodtpropyUmlne (41V) 73-41-4(MB) 117-41-7 bu (2-raquoThylhlaquolaquoyl)pMtgtlaquoUtr 52000 (30V) 73-71-4(4B ) 13-447 (xniyl bviryl ptithiUre 6700 (3 lV) 12raquo-l-l(UB) 147U- di-n-burvl pMhUre (I3V) 127-11-4laquoampgt 117-4J-0 ltjj-n-octyl phtfaUtr (UV) 101-11-)
(7CB) U-44-2 djrthyl pht)raquolraquort ( I7V) 71-01-4( 7 I B I 131-11 ) dimrthyl phttgtUTe (UV) 73-01-
(T76) H-33O tgtnzoUtlaquoftthncmr
Cadmium l i r^ Chromiurn 2 0 ZINC 140
All results are expressed as ugg weight as received
Lab ID No 2887-6
Cl ien t I D 8AD64219
Dd20( amp py(re
blaquonio(bHluorraquoflthegtlaquo
berzo(Mf luorampnThene
chryraquoefgte
ftctnAoMhy(ergte
raquonthncene
benioltK(M)plaquovlene
(Juorene
picnintfirtTX
dihwvioltraquoh)laquonThrraquocene
mdeno(l23-rt)pvrraquone
pyrene
raquocrolein
raquocrvloourUf
benzene
carbon laquoTrraquochlofifle
chlorobenieo
l24JcMarolaquotlxine
lll-trichlcroltthlaquorlaquo
-ltJicMorigtnKraquorgtlaquo
l12-trichlorolaquot^nlt
1 1 22-tetrcftloroetrvtnlaquo
^tloroeThAne
2^^1orolaquothvlvuiivt ethe
etila-oform
ll^liailoroltN^
trtni-12-dichlcxolaquoTfgtene
12-ditfiloropropine
trtni-l3-ltjicti|orocltX)t^f
cu-l3-djcMoroprooe^f
rttiylbtnztTve
methvlene cWoride
ciloromnM^f
Dco^^oroct^A^^
bromofarm
bromodicJiloromltlfraquon
tluorotrlctiloromttNir
diOilorodKloororfvrir^Ar
ct^lorodraquobrofTorrgttKAne
wtricnlorampctNrr
toluene
trirfilorolaquoThfif
v i n v CMor ilt3^
No-entry denotes not detect
ih i n N O 2887-9
Phys ica l d-asc r ip t ion of sample Cl ient ID 10A64222
Linnir l ShtHcp
Sample workup Volitile f rac t ion PEG Extraction (SW 846-^030^ Semivolatile fract ion Sonication Extraction (SW 846-3-540 Inorganic f ract ion Acid Digestion (SW 846-3050)
AOD COM POUNDS BAStNELTTRAL CXLPCXJNDS
rrt CAS CAS
(21 AJ U-Ot-7 Z4- trichloropSeno (73B) 30-J2-
(22 A) 55-30-7 p-ctilarraquo-m-erelaquoo1 (7kB) 205-raquoraquo-2 ben r olt b) 1 uor ifl t Ne~gtf
(2AJ raquo3-37-i 2- ctilorophenol (75B) 207-0raquoraquo benzoltllt)floofraquontslaquor
(31A) 120-13-2 2raquo-ltJictilcroooenol (76) 211-01 9 ctiryjene
(3A) I03-47- 2k-dimethylphenol (77 B) 20t-raquo4-i bullceruphthv lerraquoe
(37A) U-73-3 Zmdash Ajtropheooi (7SB) 120-12-7 fcntftricene
(34 A) 100-02-7 w^ i ff o phe rgto 1 (7raquoB) Iraquol-2-2 ben z o( Rh i )per v 1 me
(31A1 51-21-3 Z^ - d iA iV opheno1 (SOB) U-7J-7 Iluorene
(MA) 3X-37-I T v-4iAiv omdash laquo mdash fl^et ny Ipoenoi (I1B) 13-01-1 poeftraquonthrene
(4 Al 17-14-5 p^ntBCfllGrOprlC 1 Vol |I2B) 33-70-3 dilgtenioltraquoh)laquontwraquocenr
USA) IOl-raquo5-2 phenol (13fi) U3-31-3 indeno(l73-cd)oraquorrie
(MB) I2raquo-OO-0 pyrene RASENCimiAL COMPOUNDS
VCH-ATUL5 ( I B ) 13-32- raquoclaquonraquophtflaquorgte
(58) 12-I7-J benzidire (2V) 107-02-1 bullcrolem
(IB) 120-J7-I 1 2k-tr icnlorobenzene (3V) 107-13-1 acrvlonitr UP
(IB) 11U7I-I heKicMorobtnzme (raquoV) 7I-A3-2 benzene
(176) 4772-1 hexcftla-oethtgte (4V) J4-23-5 campr~toon TeTrscftlo itit
(116) III-- bii(2-lttilorolaquothv iVether (7V) lOt-W-7 chlocobenieo
(2C5gt raquol-3l-7 2-cM oroolaquo ptittu lene (10V) I07-O4-2 1 2-dicrtloreetranr
(23B) raquo5-30-l 12-dichlarobenime ( 1 I V ) 71-33-4 11 1 -tricMoroethr
(24 B) 31-73-1 1 3-ltl icJgt lor obcn i ene (13V) 73-3^-3 1 1 -dicMoroeth^i
(27B) 104-^4-7 1 4-dich lorobenzergte ( t k V ) n-00-3 11 2-tncfiloroetvlaquorie
(215) 91901 33-didMoroblaquozidinr (I3V) rraquo-3k-3 l122-tetrraquoOMo-oethne
(335) 121-I-2 2-dinitrotoluergte (ItV) 73JW-3 chloroethjin
(3461 (0420-2 24-dinitrotoluene (19V) 110-73-1 2-cMoroethraquo|vuiv| trgteshy
(37 B1 122-44-7 12-diphenylhydrnine (23V) 47-44-3 ctiloroform
(316) 204- Jgt tluarmrnhene lt2V) 73-35-4 1 1 -^iCMoroeThe^f
(C6) 7003-77-3 -chlorophenyl poenyl ether (gtOV) 154-40-5 trraquonraquo-l2-dicrloroltthene
(bull16) 101-35-3 raquo-6romophenyl phenyl ether (32V) 7I-I7-3 l2^ipoundMoroproBirgte
(raquo26) 3H3I-32- bit (2-cMarobopropvt) ether (33V) 1 004 1-02 -4 trmni-l^-dictilwoproom
(OB) l l l - raquo l - l bis (2-cMeroethoxv) methane 1004 1-0 1-05 cu-13-laquoicMoroprooe^e
(J2BI D-U-3 rraquolaquoeftlorobutraquodilaquooe (JJV) IOOJM- rttylbenzene
(336) 77 -raquo7- hezactilarocyclooentadiene (WV) 75-OT-2 methylene cniorifle
(56) 7raquo-3raquo-l ao ph or one (raquo5V) 7raquoJ7-3 eMoromeirune
(33B) JI-20-3 nraquophtMlene (UV) 7raquoJ3-raquo bromomethAftf
1X6) n-raquov) nitrobtnxerw (raquo7V) 7J-25-2
(CB1 14-30-4 J -ltii TT o vxJ ipheny U rru rraquo ^UV) 75-27- bro mod i cfilor o me t r)e
(CB) 47I-U-7 N-nnrotodipropylraquomJne (tV) 75-4raquo- 11 uor o tr i cMor o me t htgte (US) V17-1I-7 bu (2-eifrrlhryl)praquogtttilaquoUMshy 69 000 (30V) 75-71-1 di cti tor odl1 1 van m^i rajgtr
(476) U-U-7 benzyl buryl phihiUte 890 (31V) 12laquo-kraquo-l cMorodbremof^etNrr (US) U-7I-2 di-n-burvl prittuUre (13V) 127-lt- Uraquo6gt 117-t-0 dJ-laquo-ocTvl phttviUre (UV) IOLtS-3 Wluenr
(75) u-w djrrhylphtnltt ( i rv) 71-01-4
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All results are expressed as ugg weight as received No en
APPENDIX E
PLATES
I I I I I I I I I i Plate 10-1 Troy Mills Landfill with a backhoe excavation
in progress in a former drum burial area
I I I
I I I I I I I I
I I Plate 20-1 NAI field investigation team preparing for
Level B activities during the drum excavation task Troy Mills Landfill
I I I
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
I I I I I I I I
I I Plate 20-3 NAI field investigation team member undergoing
personal decontamination at the hot line Troy Mills Landfill
I 1 I
I I I I I I
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
1
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
I
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
I I I
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
I I I I I I I I I I I 1 I Plate 53-3 Pigmentsludge deposits interbedded with
soil layers in Excavation 8A Troy Mills
I Landfill
1
TABLE OF CONTENTS
PAGE
FIGURES ii
TABLES ii
ABBREVIATIONS AND SYMBOLS iv
PLATES v
10 INTRODUCTION 1
20 SAFETY PLAN 3
30 MAGNETIC SURVEY 4
40 TEST PIT EXCAVATION 6 41 WORK PLAN 6 42 FIELD WORK 8
50 RESULTS 10 51 GENERAL 10 52 OBSERVED QUANTITY AND CHARACTER OF DRUMS 14 53 CHARACTER OF WASTES 16
60 DISCUSSION 22 61 EXISTING SITUATION 22 62 SITE HYDROLOGY 22 63 GEOLOGIC CONDITIONS 22 64 POTENTIAL FOR GROUND WATER CONTAMINATION 34
70 CONCLUSIONS 40
80 RECOMMENDED PLAN 41
APPENDICES
APPENDIX A Site Safety Plan APPENDIX B Work Plan APPENDIX C Magnetic Survey Report APPENDIX D Laboratory Analyses APPENDIX E Plates
FIGURES
PAGE
30-1 Delineated area of magnetic source material Troy Mills Landfill Troy New Hampshire
62-1 Ground water elevation Troy Mills Landfill and vicinity Troy New Hampshire 33
TABLES
41-1 Randomly selected excavation sites
52-1 Drum log for excavations on November 17 21 and 23 1983 12
52-2 Contents and condition of excavated drums 15
53-1 Sample log for waste samples obtained on November 17 21 and 23 1983 17
53-2 Summary of analytical results for waste samples obtained on November 17 21 and 23 1983 19
61-1 Analyses of Water Samples Collected from Monitor Well Ml 23
61-2 Analyses of Water Samples Collected from Monitor Well M2 24
61-3 Analyses of Water Samples Collected from Monitor Well M3 25
61-4 Analyses of Water Samples Collected from Monitor Well M4 26
61-5 Analyses of Water Samples Collected from Monitor Well M5 (upgradient well) 27
61-6 Analyses of Water Samples Collected from Monitor Well M6 28
iii
61-7 Analyses of Water Samples Collected from Monitor Well M7 29
61-8 Analyses of Water Samples Collected from Surface Water Station A (leachate seep) 30
61-9 Analyses of Water Samples Collected from Surface Water Station B (upstream) 31
61-10 Analyses of Water Samples Collected from Surface Water Station C (downstream) 32
64-1 Physical properties of phthalate esters 35
64-2 Physical properties of ethylbenzene and toluene 39
iv
ABBREVIATIONS AND SYMBOLS
EBP benzyl butyl phthalate degC degrees Celsius Ca circa D volume occupied by one drum DEHP di (2-ethylhexyl) phthalate DOP di-n-octyl phthalate E east eg exempli gratia (for example) EPA US Environmental Protection Agency HNU HNU Systems Inc photo-ionization detector LEL lower explosive limit LPP level of personnel protection MCL maximum contaminant level mg1 milligrams per liter ug1 micrograms per liter MSA Mine Safety Appliances Inc N north also number of steel drums NAI Normandeau Associates Inc OS over sample OVA Foxboro Century Organic Vapor Analyzer P estimated packing density of drums PPM parts per million RAI Resource Analysts Inc RCRA Resource Conservation and Recovery Act S south SCBA Self contained breathing apparatus SNARL EPA suggested no adverse response level T trace Troy Troy Mills Inc TVO total volatile organics V estimated volume of drum burial area VOC volatile organic compounds W west gt greater than lt less than
PLATES
Plate 10-1 Troy Mills Landfill with a backhoe excavation in progress in a former drum burial area
Plate 20-1 NAI field investigation team preparing for Level B activities during the drum excavation task Troy Mills Landfill
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
Plate 20-3 NAI field investigation team member undergoing personal decontamination at the hot line Troy Mills Landfill
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
Plate 53-3 Pigmentsludge deposits interbedded with soil layers in Excavation 8A Troy Mills Landfill
VI
10 INTRODUCTION
As a part of a phased program to investigate potential ground
and surface water contamination associated with the Troy Mills Inc
landfill Normandeau Associates Inc (NAI) has completed a waste
characterization at portions of the landfill that were formerly used for
the disposal of steel drums containing wastes (See Plate 10-1 for site
overview) The objectives of this phase of study included
1 Delineation of the horizontal extent of the drum burial area
2 Estimate ofthe number of drums
3 Characterization of the physical condition of the drums
4 Assessment of the contents of the drums and
5 Assessment of potential for ground water contamination
6 Development of a remedial action plan for the site
The work involved developing and implementing an extensive
site safety program conducting a magnetometer survey digging a series
of test pits on randomly selected sites laboratory analyses of selected
samples of soil and waste and formulation of a remedial action plan for
the site
The Troy Mills landfill is roughly eight acres in total area
and divided into two main sections One section is currently being
operated as a solid waste (non-hazardous) disposal area for fabric
scraps and trimmings as well as other non-hazardous materials such as
wood and broken tools The solid waste landfill covers about six acres
of the site An estimated three acres presently contain deposits of
solid waste and about three acres are being prepared for future
disposal A closed former steel drum burial area is the second section
occupying about two acres of the site The drum burial area is now
covered with soil and a light cover crop of grasses The drum burial
area received wastes between 1968 and 1978 The disposed drums are
reported to have contained various materials including waste
plasticisers pigments and organic solvents
Previous site investigations by NAI have included site
reconnaissance studies test pitting water quality analyses (NAI report
of August 12 1981) geophysical (seismic refraction and electrical
resistivity) investigations (NAI report of December 1981) installation
of a ground water monitoring system (4 wells) and sampling and analyses
of ground and surface water samples (NAI report of July 1982) A water
budget analysis was performed to assess the leachate generation
potential of the site (NAI report of September 1982) Concurrent with
the study of the drum burial area additional seismic refraction lines
were conducted and three additional ground water monitoring wells were
installed to further assess leachates from the solid waste
(non-hazardous) portion of the site
Laboratory Analyses were conducted by Resource Analysts Inc
(RAI) We also wish to acknowledge the assistance and cooperation
provided by the management and personnel of Troy Mills especially
Messrs Barrett Ripley and Carl Patten
20 SAFETY PLAN
A Bureau of Hazardous Waste approved safety plan for on-site
activities was developed for the waste characterization phase of work
because of the potential for encountering hazardous materials The
safety plan is presented in Appendix A of this report It assesses the
overall degree of hazard identifies specific potential hazardous
situations and presents guidelines for personnel protection and action
levels as required The plan was made available to all field personnel
during the field work
The magnetic and topographic surveys were considered to be low
hazard activities with a prescribed level of personnel protection (LPP)
of C or D depending on the results of air monitoring Level C proshy
tection involves wearing a full face respirator with organic vapor dust
combo cartridge Tyvek suit over work clothes rubber safety boots and
gloves Level D protection requires cotton coveralls or other work
clothes safety shoes safety glasses and possibly a Tyvek suit
During the drum excavation and sampling task which was
determined to be moderately hazardous Level B protection was preshy
scribed Level B protection requires that personnel wear SCBA (self
contained breathing apparatus) chemical resistance Tyvek suit steel-
toed rubber boots and gloves Plate 20-1 shows NAI personnel on the
site preparing for Level B activities Plates 20-2 and 20-3 show
personnel decontamination equipment and the hot line during the drum
excavation task
30 MAGNETIC SURVEY
To delineate the landfill area underlain by steel drums a
high resolution magnetic investigation was conducted by John F Kick
PhD consulting geophysicist The magnetic method was chosen over
other search methods because ferromagnetic substances (drums) were the
target objects and the majority of Troy Mills other wastes are
non-magnetic (largely fabric scraps) Dr Kicks report is presented in
Appendix C
Eighteen parallel rows of magnetic field measurements were
made along north-south lines The measurements were made at 10-foot
intervals along the rows This work resulted in a detailed contour plot
of the magnetic anomaly (Figure 1 in Appendix C) The source materials
which cause the magnetic anomalies do not usually directly underlie the
peak of the anomaly A shift is caused by the inclination of the
earths magnetic field and by dipolar effects Figure 30-1 shows NAls
delineation of probable source areas for the magnetic anomaly and
peripheral areas which may contain some magnetic source material The
plotted source area is generally the area between the peak of the
magnetic anomaly northward to the zero anomaly contour This is to
compensate for a southward shift of the peak of the magnetic anomaly
from the center of the source deposit The complex geometry of the
anomaly necessitated much interpolation between peaks and ridges
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40 TEST PIT EXCAVATION
41 WORK PLAN
A series of test pits were excavated in the Troy landfill for
observation and sampling More specifically the purpose of the
excavation was to estimate the number and distribution of drums buried
in the landfill determine the condition of the drums (full empty
crushed rusted leaking etc) identify types of buried and drummed
waste and verify the results of the magnetometer survey A stratified
random sampling method was used to choose 10 locations within the
delineated area of magnetic source material This insured that
excavations were distributed randomly across the landfill and that the
resulting data could be evaluated with a level of statistical
reliability Excavations were also selected in areas on either side of
the anomaly which were considered free of buried magnetic material and
also where drums were visible at the landfill surface
The following procedure was used in choosing the locations for
the random excavations The center of the delineated area of magnetic
source material was used as a base line The base line was drawn onto a
map of the source material (Figure 30-1) and then divided into ten
60-foot long segments Using a random numbers table a point-distance
was located on each segment (designated the random station) and a
line drawn at that point perpendicular to the base line segment Again
using a random numbers table a point-distance (designated the random
offset) measured along the perpendicular line located the point of
excavation The grid coordinates for each excavation were graphically
determined from the grid overlay and then field-located from the
surveyed grid intersections Grid coordinates and selection data are
presented in Table 41-1
It was judged that 10 excavations in the delineated area of
magnetic source material and two excavations out of the area would be
sufficient to characterize the site would produce statistically valid
TABLE 41-1 RANDOMLY SELECTED EXCAVATION SITES TROY MILLS LANDFILL TROY NEW HAMPSHIRE
BASELINE RANDOM RANDOM EXCAVATION GRID SEGMENT STATION OFFSET
NUMBER COORDINATE (FEET) fFEET) (FEET)
1 7E+15 65N 0-60 26 16
2 9E+5 13S 60-120 110 9
3 8E+0 31S 120-180 140 7
4 4E+5 48S 180-240 230 26
5 3E+8 45S 240-300 254 20
6 OE+8 45S 300-360 394 50
7 2W+15 24N 360-420 465 14
8 5W+6 42N 420-480 518 20
9 6V+14 74N 480-540 548 7
10 8W+5110N 540-600 611 31
Locations are plotted on Map in Figure 30-1
data and could be expected to be completed within a scheduled 2-3 day
work period
42 FIELD WORK
Test pit excavation was conducted in two phases On the first
day each of the 10 random locations (Excavation 1 through 10 Figure
30-1) was probed to a depth of 2 feet using hand shovels On the
second and third days excavation was conducted using a combination of
hand shovelling and power backhoe The NAI field investigation team
consisted of six members Four of the team members were equipped to
work at Level B for work in and near the actual test pit excavation
(See Plate 42-1) The other two team members spent much of their time
with personnel and equipment decontamination and refilling compressed
air bottles at the hot line Mr Timothy W Drew an engineer of the
New Hampshire Bureau of Hazardous Waste Management was present during
most probing and excavation work Mr Robert Lynch an experienced
Level B equipment operator of Jet-Line Services Inc operated a power
backhoe which was provided by Troy Mills Inc
An average excavation size using the backhoe was approximately
7-feet wide and 10-feet long Excavation continued downward until drums
were encountered or to a minimum depth of five feet Drums were careshy
fully uncovered and fully described A total of 17 samples were
obtained from uncontainerized wastes (solids dried sludges pigments
stained soil) and where possible from drums using EPA sampling methods
and protocols All of the excavations were backfilled upon completion
of this task
Each sample consisted of one filled 8-ounce glass jar sealed
with a Teflon-lined lid Samples were submitted to Resource Analysts
Inc (RAI) Laboratory in Hampton Falls NH for priority pollutant
analysis
Air monitoring was conducted during each excavation using a
Foxboro Century Flame lonization Organic Vapor Analyzer (OVA) an HNU
Systems photo-ionization detector (HNU) and an MSA combined oxygen and
explosimeter High explosimeter measurements were considered cause for
an immediate halt in exploratory work in the interest of personnel
safety
10
50 RESULTS
51 GENERAL
On November 17 1983 Excavations 1 through 10 were initiated
using hand shovels to a depth of approximately two feet A total of
two buried drums were discovered Excavation 13 was completed and a
third partially buried drum uncovered On November 21 1983
Excavations 1 through 9 were completed and on November 23 1983
Excavations 7A 8A 10 11 12 and 14 were completed An additional
42 drums were uncovered on the last two days of excavation
Excavation Locations Seventeen test pit excavations were
completed at locations which are shown on Figure 30-1 Two pits were
excavated at three of the locations Noteworthy aspects of the
excavation operation are
Excavations 1 through 10 were randomly located in the area of delineated magnetic source material (on-anomaly)
One excavation connected Excavations 4 and 5 This was done because of the proximity of Excavations 4 and 5
Excavation 7A was located immediately adjacent to Excavation 7 Excavation 7 was located on the boundary line of the anomaly and proceeded in a southerly direction off the area of delineated magnetic source material (off-anomaly) Excavation 7A was initiated in the opposite direction (north on-anomaly)
Excavation 8A was initiated one foot north of Excavation 8 after the latter was abandoned due to the detection of a potentially explosive drum
Excavations 11 and 12 were selected off-anomaly to the north and south (respectively) in areas considered to be free of buried magnetic material (drums)
Excavation 13 involved minor hand shovelling necessary to uncover a partially buried drum located on the periphery of the anomaly at the east end of the landfill
11
Excavation 14 was a surface scrape which extended from an exposed drum found to the south of the magnetic anomaly northward toward the anomaly
The details of each excavation are presented in Table 52-1
Drum Locations The excavation results support the
interpretation of the magnetometer survey with buried drums as the
source of the magnetic anomaly With the exception of a few strands of
wire found in Excavation 1 ferromagnetic materials other than drums
were not encountered during the test pit excavations
Drums were foundin 9 of the 10 excavations located in the
area of delineated magnetic source material (See Plate 51-1) No drums
were found in Excavations 11 and 12 located out of the area of
delineated magnetic source materials The location point for Excavation
7 was on the boundary of the anomaly Excavation 7 which proceeded
south away from the area of source materials was free of drums
Excavation 7A proceeding north toward the area of magnetic source
materials uncovered 6 drums Excavation 14 located just out of the
delineated area to the south produced unexpected results Five drums
were uncovered just under the surface in an area with low positive to
slightly negative total magnetic field values It is possible that
Excavation 14 was improperly located in the field If adjusted just 20
feet to the east it would be well into the delineated area It is also
possible that a negative dipole derived from the mass of material to the
southeast is cancelling positive readings at this location
Fill Material and Vegetation Cover and fill material was
predominantly fine to medium sand with an occasional boulder Till with
a siltclay component was also used as a cover particularly at
Excavations 6 and 7A This material was densely compacted and difficult
to dig through Excavations 7 11 and 12 each extending to a minimum
depth of 5 feet were characterized by uniform silt and fine to medium
sand and traces of dark discoloration Excavation 12 was located in
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CO T3 0 4J Q) - C 0 mdash CO gt mdash E O w mdash
O 01shyC CU O O CD aw
CD O CO u- sshy amdash
re lt c eo cc c CD mdash CD 1- ltshy C C_ C re c co o - O X X CO CO3 gt CO 3 gt to E O O co O co CO 3 jt w O cfl 0) eo
cr LJ
LJ-J u mdash j CO 0amp5
a O 1 O
Q
1 1 i l
CD Dl bulla
CO _ mdash O D o
O ^ (A
ZX mdash Ld
O
en 3 10 O a
LJa a
Q 1 1 O
Q
+
O
X
_
mdash
o o I
gtgt O
h~Z
-^ 3
o0
mdash i-
1A 1
a a co agt C
LJ
sectK
Z= tM O 0 to bullo
X
mdashshyo
CD O
o mdash _ o
E umdash 3 E eo sshy
ltr-toZmdash
mdash s
0shy c
^
^ gt o
D o
a-rmdash
1
Q-
0 0oo r-V
tO 0
= mdash
O
tO 0
= mdash
O
Q O
O r-i O NO
1
awi
i mdash _ 3
Imdash I O
bullO C
1- 3 gt 0) bullo sshy co w
bullO CJ ID O X E C CU tt) bullw^ T3
w agt u C pound -gt
a a CO CD
mdash L 4J CD o gt
T3 gt C CO UJtt
2 mdash1 LJ Z) d CO 1 1
COO
~
lt O
~ I 1 1 I
Dl C 10 3 -D
lt - T J O
Dl C
1gt Omdash O bulllaquo Xl- i s o cu
Q lt3 toz cshy
mdash W f
r-B O c
mdashgtgt3 01O O u
W ID CO bullgt C -O mdash 4-gt 4-gt C
O -x mdash1 CO o CU c c co
1
OZ ZO o mdash Ol-
LJ -
L
0
1
C- bull 14 u- o laquoc~
bull mdash u bullDT3 O laquoccce tshy ^ D
l_ Cshy CCO O 0 0-0 Qmdash
CJ I- r-CM
1 1
U-Qshy
bull bullbull ^
O t_ 0 Q
-LJ
raquol
a o iT o c o
U) c
c u CD O
I I I CU c
Q) CJ CU W a ltshyon J2 o l- E E gt QCO CD O
I I I
ID JJ CU ES
J-gt imdash O Q Z CO w t --shy O mdash O 3 O laquoshy ^ c
_ICO a 0 0 0
^ sect5oa I-Q
CO X u_ y o- o=gtLJt-a
3shy
^
1
1
VO
m
1
i
1
t
_
3 lta i- U) 0 0
a
lA
lAbull
0 O
JI E oj3 gt E re mdash O X X co Qj
C 1 O
W 3
U L CO O
4J CO
0mdash CCD gt j ti --shy c JJ 4J
1- laquo 3 = C 3 or cu ogt tn Q -shy
E L n CD J-gt o o gt gt s o ---shyDior 3 3
mdash Tgt o cr cr mdash mdash CU 0)
o a CD -a OLJ U CU
N CU COT 4JT3 poundmdash 0gt U V
raquoT3 mdash agt OJ gtgtcu laquo c c
T3 O
C
C
Zlshyo ui u- Li ^ ^~bullgt lt LJ
lAXvOX
VO X ^ X
Xcjltshy
lA x
CM
O x
3shy
_ X
r^5 X
_ X
CM X
mdash c^ C3 O
c a bullbull o c c
mdash 4J O I I 4J
01 JJ 4J 1C laquo
3 t- C raquoJ O L (D CU C mdash o a~o mdash o
i i
C J J W CO II) O W IT OC N 03 = OJJ C O I- -= C O
I I
o o
ON X mdash
CMr-raquo
00 Orshy
X CO
vo ro O C 5) JJ Jshy I- I gtJZ-00 s a o
LJ CO eo UTJ a- I I O C X J O gtZ 1 re O
i CM
LA
LJ
O mdash c imdash LJ lt a gt y lt 2
ltCO O
O^mdash
laquoshy rmdash
CM Tmdash
n rmdash
_^jshymdash CO
LJ
j ^ |
52
14
what appeared to be natural materials although its location on the
cleared and leveled landfill tend to contradict this possibility
Most of the landfill is vegetated by a thin layer of grasses
sedges mosses and annual herbaceous species The northeast corner of
the landfill is unvegetated and cover material appears to have been more
recently applied This section is elevated 4 to 6 feet above the rest
of the landfill and appears to have received a second newer layer of
waste A 4-foot thick layer of carpet waste was encountered in
Excavation 1 but not in other excavations This section is adjacent to
the newer active landfill The landfill area just west of the access
road crossing (near Excavations 7A 8 and 8A) was also unvegetated due
to relatively recent grading operations
Ground Water The landfill appears well drained as ground
water was not encountered during any of the excavations Excavated
overburden was damp from the recent heavy rain but intergranular macro
pore spaces were free of water
OBSERVED QUANTITY AND CHARACTER OF DRUMS
A total of 45 drums were observed buried in the landfill
Table 52-1 presents a drum log describing each excavation and the
observed drums Data on the contents and condition of drums is
summarized in Table 52-2
Of the total drums observed 15 (33) were crushed flat
Although these could possibly still contain small amounts of waste they
are probably considered empty under RCRA guidelines Thirty (67) of
the total drums discovered were uncrushed and capable of containing
waste Seven (88) of the 8 drums sampled contained liquid or sludge
waste material Thus at least 7 (23) of the uncrushed drums contained
some liquid or sludge waste
15
en C Cl
bullo gtraquormdash
c mdash a
o c re bull mdash c
~ o mdashbull 4Jmdash
10 0 mdash
gt O
ro CO
fcshy0
c
C
vgt 3 0
1 rea
-gt
mdash
3 o T3
lt-O
C j C
CB 3 TJ ii i- 3 mdashQCOa
ifl u bull c c
t_ o
mdash shyO
mdash
L re N
co
t-O
mdash
mdash lfl
V) O
CO N CO pound re
0 mdash
^1 10
ltP O C raquo
CM reO
o f shyi O
mdash mdash 3 - D
c 1
CD bulllaquo
mdash3
D mdash
1 C
Q CO
CD Ifl 4-gt CO
Q
CM
r-
Ul
Q Ul gt EC Ul CJ CO o t5bullpound
z O mdash
C Ci o^
O Cbulla 3v iC MW5 CO 4J3 u CS- Ifl CBC J C O - U
gt Cgt Omdash Oi O
U- 0) Ifl bullgt-gt 1 W C
to lt-gtT3 gtmdash
0) gt shyJ 0)
C OltJ bull O T 3 C D C P
133mdash 4J bull ifl tshy Vgt~ V a O V4JJ
C o
C mdash
O Ifl
3 fc 0)
i-
c
U) re gt
ai C mdash
C mdash
CO gt c o
bull to y 3 cc Q
ltbull-CB
1 4Jin
bullD reCD jCJJC TJCD mdashbullD bull mdash
CD 0t- u iflo ifl
0 C ^-
CB laquo
3 ltbull-
0)^shy
C
0 Cgt O
1 O CTl C
T3 1 mdash CB O
mdash CB mdash in J o 3 tfl C ^ CO 0 gtltgtshy
O gtgtc 01
CO 3 1- mdash C Cregtmdash laquo
TJ W TJ mdash i re traquo-
shyU mdash
O Q
COCO^^
mdash ^
mdash gt C 0gt mdashO ~ bull
Ul
o auO
CCUl
mdash K o tO Ul Q
mdash OT30Jj c mdash4Jt- Jpound O Wre c i re03 gt
lt~i- laquo o ai
0 ) 3 gt O ^crc Ifl - CO -^mdash
3 mdash Q iflmdash 1- O 3 3
O V O ltraquo-o laquoTJ
gt
T3 - o
gtgtmdash J-gtmdash
Dmdash
6-o
09 bull mdash gtpoundbulllt-gt
re a
Ul X t5
Cpound O Z
fl) mdash^ C B gttflOl3T3T3l_ 3 Q)O mdash mdash
tn mdash
shyD CB
mdash mdash
mdash tt
CO C T3 poundi mdash JCmdash re
^ C O C X CB ^ - S - C C O mdash re O Q DW4shy
re shyu O 1
O Ul X EC Ul mdash
x a^s ox
CO
^) Z
J
1-o t-Ul X r-u 0
o j c gt T3 i -gt c tu mdash c u r e mdash
- C D mdash T3 - C M mdashbullOJJQmdash re3inecrec u c r e o mdash lt~ bullz c~4J O CX t ^Jw o r e -gtgtOgtgtshy3 c j t shy re mdash mdash ret- i o Qmdash gtgtpoundgt a
i reraquo CD 0) bullbull Ifl t-
Q ) t ) O pound O ^ laquo gt - Ow re re ro re re -gt Q mdashc 5 shyu a j-gt D t- raquomdash mdashCB C re C CO 3Q mdash O mdash O U
Htshy ae cu coo)
1 O i i
shya shyo j CD C bullgt o mdash c o c o coco mdash plusmngt o ~a v c en CD
mdash C O
raquoCJ 3C c re amp- ogtCD J o 3 CC C I-Omdash 3gt O
3
O ro
Ul X 1mdash
u O
Ul o r-Z Ul
gtV~ omdash Dlshy ^mdash mdash wre3 i cc
mdash cr bull gtJJ mdash C mdashi QIgtJ^re a shyJQI- o 0mdash
O bullO 3laquo laquo
jjmdash ureoO mdash O N 0)rc3recomdash4Jt-4JpoundmdashC C mdashmdash mdash u
1
shya 0 -
mdash gtgt re-raquo-gt CUD laquo E CD
^ J-1
CJ eoc
4JCB CO
mdash O
C 1- C mdash O C B C B C E J mdash J ltshy shyo cn o o c o r e c shyU -gtO OJC D ifl roc
T3 3 I U 3 laquo-
Ifl CD 1 W ^J 4 J 4 J c -aiflj jc
CB C r e O C B lt-gt -Jgtcoraquo C C -WE O O ) ~ O O O mdash O
Ul O
c ui =gt z
o
1-CC Ul Q
Q z ^ Ul
2 gt Ul O
o Cpound
^ CO
Ul Q ^
z o
(O U S Q
Slt
t5 lt
Z5O
1mdash z ui
Qa Ul
CD 0-1
u m O_J
O2^ltUl
O CC Ul Q
VOCO
CNlA |3
VO ^
CJ |CO |
CJ CMI3 f~ rojO VO rolo
^
ymdash3 CC
roCM
ro O ICNj
ro rolvO ro ro
ro A
rolvO r-jO
00 C3N
ec a m
r3
CO
3 a ty r-
cc Q
(M CM
to z
m 3 c O
u _i co
U-O
O 3-IObull - I c y
fshy lt- ICO r- r-ICM O U lfN ro -mdashla1 f~ laquo- ]CO bull- -ICM O O J|O O
c U) CO
mdashbullre re
mdash re
mdash i ltC c tz
j lt
i lt
5 0 0 G O o o o o z bullU 4J J h- J shyJ tmdash tmdash
^33
J3 3
O 3
Q 3
_Cr(bull
shyC 3 t)
CC IP y
C2 zgt c J
1mdash O 5
53
16
The condition of the uncrushed drums was highly variable with
only 4 (13) rusted and decomposed to the point of structural weakness
These drums were found in Excavation 10 at the far west end of the
landfill which is believed to be the oldest section (See Plate 52-1)
Interestingly two almost new looking drums were also found in
Excavation 10 at a greater depth than the four rusted drums The
remaining 26 drums were observed to be generally intact and structurally
sound Some were dented partially crushed or rusty
CHARACTER OF WASTES
Air Monitoring An OVA and HNU were used to monitor the air
for concentrations of organic vapors during each excavation Above
background instrument readings indicative of contamination were
regularly recorded when monitoring the air just above or inside of
drums A general contamination of the ambient air in the workspace was
noted only during Excavation 8A where above background readings of +13
in the excavation pit and of +6 above the excavation pit were recorded
Explosimeter readings were obtained from three drums -- 10 lower
explosive limit (LEL) from drum sample 10A 20 LEL from drum sample 6B
and 100 LEL from a drum in Excavation 8 Instrument readings are
presented in Table 52-1 and Table 53-1
Visual Observations The following types of waste were
observed during the excavations
fabric waste (carpet waste)
crushed drums
drummed waste - liquid sludge and solid
uncontainerized dried sludges and pigments
stained soils
Fabric waste scraps of synthetic non-woven fabrics5 heavy
carpet-like fabric and backing material were found only in Excavation
17
CM
CO LJ fmdash O z
laquo 4J
u TO 4-gt
c bullmdash
k bull mdash E mdash 3 3 i-^ O
mdash TJ --raquo co co 4J
E CO O U L U
E 3 c T3
C O a o
is
CO c to 3
U
TO
E O t_ U_
o o
1 ltmdash c
mdash tmdash TO 4J bull C TO 0 O o c u 3 TO
t_ 0) 0 4J
U)
mdashOTOgt
Cw bull aco jc
N 4J a
mdash L Q) re co T E
CO
bullo gt egt mdash c mdash bull o ^^73 C E gtO O mdash 3 J-gtmdash N 4J L 3 mdash 1--C gttTC bull
CX 01C JJ TO O mdash
TO trt mdash t- E mdash 3 JJ a O Q
C I 0 X E mdash C mdash CO
mdash o laquo (D-O mdash O O bullbull B Ol o -cmdash e oic f~ to a (gt TD mdash
E 1- Cpoundmdash 3 O O CO P m T1
L u
T3 CO
lto sshy0 O CA W
laquoT3 O CO 0 C J= CO tlaquo Q bull 3 O Ol 1- C o mdash 3 E a
3 E E i- to
Z L
mdash bull mdash O 4-3 Cl Q
bullD 0) CO T5 N CO mdash C -P 1 0 U TO O mdash 4J Cfc
mdash U) c shybullgt O w C O Q (5 4J 0
3 -J bull U)
5 gt TO_ U
bull gt pound mdash 3 mdash L ro TD
JJ-D - CO TO laquo QO
C 0
^ 0) T3 mdash O
r to 3
O O L L
0
01 TO gt bull
tshy mdash OT3 mdash
CD O C N U) O mdash
TO O CO mdash C C
bull^ ~ CO TO TO gt U iJ
mdash C W to O
5 c c 4J 3 CO X LJ
^ bull bull0 laquolt- ej
TO CJ CO mdash C JJ
z u to mdash T3 4J ai TO CD C laquo bull c c ugt o cr 0) bull mdash CO mdash O bull gt JC TO ^ mdash Q CO O JJ O Q bull- CO to mdash to c Z CC O il mdash 4J gt
mdash Omdash O1O CD mdash U) TO C X mdash O CO C L mdash Cvv O W pound G CO C C
O gtgtgt C C mdash CO C TO CO 3 E mdash -J laquo 1- bullgt CO 0 to
bullo CO
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ugt C CO TO c w 4J-Q co e a c
mdash re TO in E to
Q
JJ c bullo
a LJ co E bull LJLJ
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ax
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mdasha o CO LJ a LJ ~J
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^j C CO E Ol
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bull CO 01 D 3
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bullmdash av^ CO 4J IA TO 5
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03
ai_ 3 a bullo bull mdash 05 3 O) 00
mdash mdash C c gtgt G CO
O O
bullo^ = c a 0)
E C O umdash u a L_ bull OlCD mdash
4J mdash
u) obulla o u) amp 5 c -a 7 O C mdash o mdash _ i- (0
CO E laquoJ
C
a
bulla c bull o bull
c bullQ CO
3 01
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t- Ol CC-D 0) 3
CJ raquo
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bullo 3
lt) bull_
gtraquomdash CO O 1- Ui O)
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mdash TO
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tmdash CM CM ^_ CM
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18
bull -a gtgt CD
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4J 1 CO
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co E C mdash z bullD 73 4J O JZ = CD ltshyO C CD
CD 4J laquomdash C
bullO Qmdash U N ET3 bull mdash 0 Cmdash i- L re mdash oltmdash o
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O O tshyo
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gt Q ltshy 0
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re 3 O L
CD U -D SshyCD CO CO N 0) mdash 0-E S GO CD CO L
i
CO UJ gtmdash
z laquo w mdash ffl JZ CO 4-gt 4J JZ
4_) t_ mdash bull
cz QJ co jZ C C mdash 4J
re (uS a z z
OX) mdash a) O W E
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C (~ mdash r re O CD
obullz
-J VI O 4J z re o gt o jt o 5
mdash tshy Q mdash CO 0 Q) mdash j j a C5 E U3
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CO
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bullc bull CD 0) C 4-gt mdash w CO CO 4-1 to
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13
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CO Z 05 CO Ch ~ rmdash
19
c o C M O - L bull O C M bullmdash co ujn iiupeo CM
CM h- fO i- X
bull k_ c _Jlaquo _Jo
laquok ro
mn i LJOJ 140 CM
3-
bull CM
m CM
tshy r- ro CM
CV
sshy = sO r sshy~ - 2
CM ^ ~ ~ mdash rs
a
2
ou tz S S o w S S o | ^
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mdash o r gtgtlt_
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m raquo
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mdash O
lt
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Q _JZ lt lt C _J to
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o O O
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o (O
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o O r~
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mdashV^
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o Jj
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o i
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hmdash gt-poundi ltc bull ^ ro
sects
lt 2
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20
1 (See Plate 53-1) This is the predominant waste material currently
being disposed of in the active landfill
Crushed drums were distributed throughout the original
landfill and were found in Excavations 2 4 4-5 7A 8A and 14 Some
drums such as those found under the road in Excavation 7A may have
been crushed by heavy equipment operating in the landfill Others like
those found at depth in sandy fill in Excavation 2 appear to have been
crushed before burial Drummed liquid and sludge wastes are also
distributed throughout the landfill (See Plate 53-2) They were found
in Excavations 1 4 5 6 8 and 10 These wastes are discussed below
One sealed drum was openedand found filled with refuse -- paper cups
towels paint covered rags etc One open and partially crushed drum
contained a dark granular solid waste This material was sampled
(Sample 10B) and found to be nonhazardous
Small deposits of dried pigmentsludge were found in
Excavations 3 4 6 9 and 13 Discernible layers of pigmentsludge and
stained soils were present in Excavations 7A 8 and 8A (See Plate
53-3) Of particular note was a 2 to 4-inch thick layer of
grey-colored dried sludge found at Excavations 7A and 8 All of these
wastes were sampled and the results are discussed below
Laboratory Analyses
Laboratory analyses were performed on 10 selected samples
obtained from both containerized (drummed) and uncontainerized wastes
Samples were analysed for 3 metals and 87 priority pollutants including
11 acid compounds 45 baseneutral compounds and 31 volatile organic
compounds Table 5-4 summarizes the analytical results and the
laboratory data sheets are presented in Appendix D
Of the 45 priority pollutant baseneutral compounds only 4
were identified in the samples that were analyzed Baseneutral
21
compounds and particularly phthalates were the most prevalent
chemicals and also were reported in the greatest concentrations The
highest levels of naphthalene (1200 ppm) bis (2-ethylhexyl) phthalate
(110000 ppm) and di-n-octyl phthalate (6200 ppm) were found in sample
4A a translucent red liquid obtained from a drum The highest
concentration of benzyl butyl phthalate (13000 ppm) was found in sample
6B a clear liquid and pink sludgepigment obtained from a drum
A total of 8 volatile organic compounds were identified The
highest levels of benzene (100 ppm) xylenes (19000 ppm) and
ethylbenzene (5300 ppm) were found in sample 5A a clear liquid
purple-grey sludge obtained from a drum Toluene was found in highest
concentration (12000 ppm) in sample 1A a purple-grey thick opaque
liquid obtained from a drum Methylene chloride (13 ppm) was
identified in greatest concentration in sample 8A-C a purple stained
soil and powdery waste Sample 10A a purple liquid obtained from a
drum was the only sample found to contain 1-1 dichloroethane (2000
ppm) Finally trace levels of trichloroethylene (sample 10A) and
111-trichloroethane (sample IB) were also reported
Samples were tested for three metals - cadmium zinc and
chromium The highest concentrations of cadmium (2200 ppm) and zinc
(5700 ppm) were found in sample 4A a translucent red liquid obtained
from a drum The highest level of chromium (52 ppm) was reported in
sample 5A a clear liquidpurple-grey sludge obtained from a drum
22
60 DISCUSSION
61 EXISTING SITUATION
Under existing conditions relatively small quantities of
volatile organic compounds (VOC) are indicated to be leaking from wastes
buried on the landfill site To date ground and surface water
monitoring results indicate relatively low concentrations of VOC in the
ground water and below detection limits in the adjacent brook (See
Tables 61-1 to 61-10) The results indicate that no potential health
risks from VOC and other constituents currently under observation are
being caused by the landfill operation to down stream surface water
users It would be prudent for Troy Mills to continue to monitor the
quality of Rockwood Brook upstream and downstream for VOC and on the
basis of waste analyses (previous section) to monitor ground and
surface water points for toxic metals and baseneutral compounds
62 SITE HYDROLOGY
An analysis of the hydrology of the landfill site was
performed in 1982 (NAI report of September 1982) The subwatershed that
contains the landfill site is (about 44 acres) a small fraction of the
watershed area that contributes to Rockwood Brook above surface water
sampling point C (about 1650 acres see Figure 62-1) This indicates
that most of the flow of the brook at point C (about 97) is contributed
by upstream watershed areas Thus leachate discharging into Rockwood
Brook from the landfill site can be expected to be diluted by over 30
times its volume This factor and the volatilization which naturally
occurs results in parameters detected in the Troy Mills monitoring
wells often becoming undetectable when they enter the brook
f 5
Geologic conditions which were defined in the NAI report of
July 1982 indicate that permeable deposits of sand and gravel overlie
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27
TABLE 61-5 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M5 (UPGRADIENT WELL)
Parameter Date Sampled 11-22-83
Specific conductance
pH2 81
Dissolved iron mg1 036
Dissolved manganese mg1 010
Chloride mg1 10
Phenolics mg1
3
023
Identified volatile organics
None identified ND
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (yg1)
28
TABLE 61-6 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M6
Parameter
Specific conductance
PH2
Dissolved iron mg1
Dissolved manganese mg1
Chloride mg1
Phenolies mg1
Identified volatile organics
11-dichloroethane tetrachloroethylene 111-trichloroethane
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vg1)
Date Sampled 11-22-83
152
lt002
29
6
0002
27 trace 140
29
TABLE 61-7 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M7
Parameter Date Sampled 11-22-83
1 47 Specific conductance
pH2 62
Dissolved iron mg1 002
Dissolved manganese mg1 0026
Chloride mg1 gt2
Phenolics mg1 0070
3 Identified volatile organics
111-trichloroethane 5
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vig1)
30
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34
glacial till and bedrock The sand and gravel deposits form a permeable
conduit through which leachate from the waste burial areas migrates
The permeable deposits lie in the area north of monitoring well M-l (See
Figure 62-1) In general the water saturated thickness of the sand
and gravel in the vicinity of the north-south access road is 6 to 12
feet
64 POTENTIAL FOR GROUND WATER CONTAMINATION
641 Estimated Quantity of Drums
The test pit excavation and sampling in the drum burial area
indicates a potential source of ground water contamination for the
future Many of the drums encountered were in fair to good condition
and contained liquid wastes An estimate of the number of drums in the
deposit was made with the following assumptions
1 The complex magnetic anomaly was simplified into a geometric solid 600 feet long 40 feet wide and 10 feet deep with a volume (V) of 240000 cubic feet
2 Each steel drum (D) occupies 105 cubic feet (including voids)
3 The density of packing (P) was assumed to be 50 of the packing that can be achieved with perfect cubic packing
THEN
N = estimated number of steel drums
N = (VD) (P)
N = (240000105) (05)
N = 11429 drums
The results of the drum excavation work provides a basis for
estimating the potential for specific types of chemical loading In
general three main classes of chemical substances were identified in
35
the drums The chemical substances included baseneutral extractable
organic compounds (mostly phthalates and lesser amounts of naphthalene)
volatile organic chemicals and metals
642 Phthalates
The phthalate esters found in the drums include
bis (2-ethylhexyl) phthalate ^0^3 benzyl butyl phthalate di-n-octyl phthalate Jd~7
Bis (2-ethylhexyl) phthalate was found in the highest
concentration at 110000 ppm (11 percent) Benzyl butyl phthalate is at
the second highest concentration 13000 ppm (13 percent)
Characteristics of those phthalates found are presented in Table 64-1
TABLE 64-1 PHYSICAL PROPERTIES OF PHTHALATE ESTERSshy
di-n-octyl bis (2-ethylhexyl) butyl benzyl DOP DEHP BBP
ALTERNATE o-Benzenedishy di (2-ethylhexyl) benzyl butyl NAMES carboxylic phthalate phthalate
Molecular Weight 3910 3910 312
Melting Point -25degC -50degC -35degC
Boiling Point 220degC 386 9degC 377degC
Vapor Pressure-mdash lt02 torr (150degC) lt001 torr (20degC)
Not
2xlO~7torr (20degC) Available
Solubility 3 rngfc (25degC) 04 mgfc (25degC)
58
13 rngH 48
Log octanolwater 92 873 58 partition coefficient 53 48
Versar Inc 1979 Water-Related Fate of 129 Priority Pollutants Volume II Prepared for US Environmental Protection Agency PBSO-20438 December
bullbullOther names listed in Versar 1979 vMore than one value has been calculatedreported
36
Bis (2-ethylhexyl) phthalate is the most well-studied of the
phthalate esters though the information on phthalate esters as a group
is limited The three phthalates identified at the Troy Mills site have
relatively low solubilities and are readily adsorbed onto suspended
particulates Microbial degradation is effective under aerobic
conditions bur is generally slower under anaerobic conditions
(nonexistent for bis (2-ethylhexyl) phthalate)
The above characteristics are important for two reasons One
the extent and nature of contaminant migration from the site are
dependent upon the physical characteristics Second the treatment
(clean-up) alternatives for contaminated ground water or soil can be
estimated from the characteristics
From the available information it appears that the phthalates
present at the Troy Mills site would be relatively immobile due to their
low solubilities and high adsorption rates The presence of toluene and
methylene chloride at the site however may increase the phthalates rate
of migration
It is important to note that none of the phthalates have been
found to be present in the monitoring wells nor in the surface water
sampled probably due to the low solubility and high adsorption rate
37
643 Napthalene u K r
Naphthalene has also been found in significant quantities in
the sampled drums Naphthalene is a polycyclic aromatic hydrocarbon and
has the following properties
Molecular Weight 12819
Melting Point 8055
Vapor Pressure (20degC) 00492 torr
Solubility in Water (25degC) 344 mgfc
317 mgfc
Log octanolwater partition coefficient 337
Versar 1979
Naphthalene has mid-range adsorption rates and solubility It is
therefore inferred that there would be some adsorption to soils in a
ground water environment It is important to note that naphthalene has
not been detected to date at the monitoring wells or the surface water
sampling locations This is expected to be a result of adsorption on
the soils
644 Volatile Organic Compounds
Volatile organic compounds tend to migrate readily within
soils and ground water They are therefore considered a threat to
surrounding ground and surface waters if they are released in sufficient
quantities
Volatile organic compounds were detected in samples from six
steel drums The total volatile organic (TVO) concentrations in the
38
wastes ranged from 9 ppm to 30100 ppm and averaged 8570 ppm In order
to determine the potential for future contamination by volatile organic
compounds an estimate of waste quantity based on information from the
drum excavation program was made It was assumed that 7000 steel drums
in the deposit are 60 full of liquid waste with an average TVO
concentration of 8570 ppm The computed volume of liquid waste is
231000 gallons with an average TVO concentration of 8570 ppm This is
equivalent to about 1980 gallons of pure TVO
Two of the volatile organic compounds that have been most
prevalent in the existing ground water monitoring system are
111-trichloroethane and ethylbenzene The EPA suggested no adverse
response level (SNARL) for 111-trichloroethane is 330 ugpound for
1 day of exposure and 35 jigd for exposure over a life-time in
drinking water
In general ethylbenzene is a prevalent chemical in the
environment Sources include commercial (eg petroleum and petroleum
by-products) motor vehicle exhaust and cigarette smoke An intake of
16 mgday (1 mgfc) has been calculated as an acceptable rate to
protect from toxic effects Carcinogenic effects have not been
identified to date The physical properties of ethylbenzene are
presented in Table 64-2 The principal mechanism for removal of
ethylbenzene from water is volatilization In addition to
volatilization adsorption may also be an important removal mechanism
based on the log octanolwater coefficient This factor is important in
evaluating the migration of ethylbenzene from the disposal site
Toluene which was also identified in waste and ground water
samples exhibits properties similar to ethylbenzene in that it
volatilizes easily Toluene which is also referred to as methylbenzene
is distinguished from benzene by the substitution of a methyl group for
one hydrogen atom Physical properties of it are presented in Table
39
64-2 The EPA suggested no adverse response level (SNARL) for toluene
is 1 mgpound in drinking water with a maximum exposure time of ten
days
TABLE 64-2 PHYSICAL PROPERTIES OF ETHYLBENZENE AND TOLUENE
ETHYLBENZENE TOLUENE
Molecular Weight 10616 9213
Melting Point -949degC -950degC
Boiling Point 1362degC 1106degC
Vapor Pressure at 20degC 7 torr 287 torr
Solubility in water at 20degC 152 mg2 5348 mgd
Log OctanolWater Partition Coefficient 315 269
645 Metals
One liquid sample contained high concentrations of cadmium
(2200 mgd) and zinc (5700 mgd) indicating that the waste deposit is
also a potential source of certain toxic metals Tests for these metals
have not been made to-date in ground or surface water samples It would
be prudent to add toxic metals such as cadmium chromium lead and
mercury to the list of parameters that are being monitored to further
characterize the quality of adjacent ground and surface waters US
EPA and New Hampshire drinking water standards for these metals are
cadmium 01 mgd chromium 05 mgpound lead 05 mgd mercury 002
mgd Although zinc is not considered a highly toxic metal the
US EPA has set a secondary drinking water maximum contaminant level of
5 mgd on this metal
40
70 CONCLUSIONS
The following conclusions were drawn during this
investigation
1 A steep-gradient irregular-shaped magnetic anomaly is present under closed and covered portions of the south part of the Troy Mills landfill
2 The magnetic anomaly is caused mostly by an irregular-shaped accumulation of disposed steel drums
3 In a randomly conducted sampling of drums in the source area for the magnetic anomaly 16 of the drums contained liquid andor sludge 33 were crushed flat and 51 were not sampled because there were no accessible openings
4 Laboratory analyses indicate that the random waste sampling contained significant concentrations of several volatile organic chemicals several baseneutral priority pollutants and high levels of cadmium and zinc
5 Observed concentrations of volatile organics at the monitoring wells are relatively low Because of their potential for migration in the ground water continued monitoring of volatile organics will be required
6 Volatile organic chemicals have not been detected in Rockwood Brook to-date Because of the presence of low levels of volatile organics in the ground water they should be monitored in the brook on a regular basis to confirm the lack of impact
7 The presence of high concentrations of cadmium and zinc in one of the waste samples indicates that trace metals should be monitored periodically
8 The presence of baseneutral extractable compounds (phthalates and naphthalene) in all of the analyzed waste samples indicates that these compounds should be monitored periodically
9 The phthalates are not expected to migrate freely because they have low solubilities and are readily adsorbed onto soil particles
10 If elevated concentrations of volatile organic compounds trace metals or baseneutral extractable compounds should occur in the monitoring system (wells and brook) in the future a need for site remedial actions to mitigate the potential for downgradient ground and surface water contamination could develop
~
80
41
RECOMMENDED PLAN
Based on the preceding conclusions it is recommended that the
following plan be implemented by Troy Mills Inc
1 Continue monitoring ground and surface water quality at the Troy Mills Inc landfill sampling on a quarterly basis with sample collections during April July October and January
2 To confirm the absence of the landfills impact on Rockwood Brook test samples for volatile organic compounds by GCMS from surface Stations B (upstream) and C (downstream) on the April and October samplings
3 To determine if trace metals are present in downgradient ground waters conduct analyses for cadmium chromium lead mercury and zinc on samples from all monitoring points during the April sampling and on subsequent sampling rounds if necessary
4 To confirm the continued absence of baseneutral extractable compounds in downgradient ground and surface waters conduct analyses for baseneutral extractable compounds on samples from monitoring wells M 2 and 3 and surface Station C (downstream) on the April sampling and on subsequent sampling rounds if necessary
5 If a sudden rise in concentrations toward unacceptable levels should occur in the monitoring system (wells and brook) additional monitoring rounds at a monthly interval should be conducted to confirm the rise in concentrations
6 If elevated concentrations persist and are verified by the additional monitoring remedial alternatives will be defined to mitigate the potential for downgradient ground and surface water contamination
Respectfully submitted NORMANDEAU ASSOCIATES INC
Dennis R Sasseville Project Manager
Donald H Bruehl f laquo | APG Senior Hydrogeologist -^ - - AIPG Certificate No 2272 ^ -v^
^^Z-^^
APPENDIX A
SITE SAFETY PLAN
GENERAL SAFETY PLAH FOR
TROT MILLS LANDFILL TROY MEW HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
Prepared by
NORMANDEAU ASSOCIATES INC Bedford New Hampshire
R-457
November 1983
TABLE OF COHTENTS
PAGE
SECTION 1 BACKGROUND INFORMATION 2
Identification 2 Personnel 2 Site Description 3 Project Description 5
SECTION 2 HAZARD EVALUATION 6
Overall Degree of Hazard 6 Specific Hazards 8 Necessary LPP 8
SECTION 3 FIRST AID FOR EXPOSURE 10
SECTION 4 OPERATIONS SAFETY PLAN 11
General Personnel Protection GuidelinesAction Levels 11 Site Reconnaissance 13 Task 1 - Magnetic Survey Topographic Survey 14 Task 2 - Drum excavation and Sampling 15
SECTION 5 EMERGENCY INFORMATION 16
Emergency Telephone Numbers 16 Route to Hospital 16 Contingency Plan 17
APPENDICES 18
A - LEVELS OF PERSONNEL PROTECTION 18 B - DECONTAMINATION PROCEDURES 23 C - PERSONNEL AND RESPONSIBILITIES 25 D - PERSONNEL CASUALTY 26 E - GUIDELINES FOR SITE OPERATIONS 27
GENERAL SAFETY PLAN FOR
TROY MILLS LANDFILL TROY NEraquo HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
The following is a Safety Plan for on-site activities performed
during the Investigation of the Troy Mills Landfill being conducted by
Normandeau Associates Inc (NAI) of Bedford New Hampshire
The document is intended to be an in house working guideline
for personnel trained and experienced in hazardous waste field work and
not a treatise on safety Familiarity with standard equipment and proshy
cedures is expected Where possible non-site specific information has
been appended
All NAI employees subcontractors and visitors will be required
to follow this safety procedure plan and to report to either NAIs proshy
ject manager (P M) on site coordinator (OSC) or safety officer (SO) on
issues relating to safety
SECTION 1
BACKGROUND INFORMATION
IDENTIFICATION
Site Name Trey Mills Landfill NAI-ID No 457
Trey Mills Inc Troy NH 03465
AddressLocation At the south end of the dirt road about 15 miles
south of Troy NH between Rockwood Brook and the
old Boston and Maine Railroad grade
County Cheshire Phone 603-242-7711
PERSONNEL
Brook Dupee Bureau Hazardous Waste 603-271-4611
State Contact John Regan Bureau Solid Waste 603-271-4586
Dan Allen WSPCC 603-271-2755
EPA Contact
Other Contacts
Client Contacts Barrett F Ripley (Vice President)
NAI Personnel - (472-5191)
Project Manager - Dennis Sasseville
On Site Coordinators - Alton Stone
Safety Officer - Elizabeth Gross (Phoenix Safety)
Technical Director - Don Bruehl
Other - Douglas DeNatale Steve Ransom
SITE DESCRIPTION
Type of Facility Company (on-site) landfill
RCRA Status Generator Disposer
Size About 15 acres BuildingsStructures None
Surrounding Land Use N Forested
(one mile radius) E Abandoned Railroad
Forest RuralResidential
S Forested
W Forested Mountain side
Unusual Features or Terrain None
Site Activities - Troy Mills manufactures textiles carpets and related
products Since 1968 waste materials including
drummed wastes have been landfilled on company proshy
perty Drums mostmany of which may be emptycrushed
are buried in an inactive section of the landfill
The active section is currently accepting waste
which is considered to be non hazardous
Specific - Improper disposal of hazardous waste
Problems - Leachate seep
Contamination of ground water
Hazardous WastesMaterials On-5ite
Wastes - Uncured foam rubber latex sludge
SBR rubber silicone defoamer potassium oleate soap
calcium carbonate and feldspar filters zinc oxide
and sulpher salt cure system
- Vinyl plastisol sludge
PVC dispersion resin DOP and DOA plasticiser
calcium carbonate filler organic pigments AZO
dicarbcnamid blowing agent zinc salts expoxidized
soybean oil cadmLum-bariin-zinc stabilizer Varsol
MEK prints and topcoats sludges
PVC acrylic resins organic and inorganic pigments
MEK solvent toluene silicate fillers
Industrial solvents and chemicals
11 -dichlorethane 12-dichlorothane
111-trichloroethane trichlorethylene tetrachshy
lorethene methylene chloride toluene benzene
ethylbenzene benzidine 33-dichlorobenzidine aeroshy
lein acrylonitrile napthalene benzoperylene dibenshy
zoanthrasene idenopyrene
Pesticides
There is a possibility for low levels of pesticides
to be on site These would include Chlorodane
heptachlor expoxide toxaphene aldrin alpha BHC
beta BHC 4-4-DDT endosulphan 1 heptachlor
PROJECT DESCRIPTION
Purpose Tb characterize ground water conditions at the site and to
characterize wastes buried on site
Specific Tasks
Site Reconnaisance
Task 1 - Magnetometer SurveyTopographic Survey
Task 2 - Excavation for inspection of drums
SECTION 2
HAZARD EVALUATION
Overall Degree of Hazard - Moderate
Task Hazard Proposed LPP
Site Reconnaissance Low Level C
Task 1 MagnetometerTopographic Surveys Low Level CD
Task 2 Drum ExcavationSampling Moderate Level B
Conpany records have indicated that a variety of industrial
and potentially hazardous wastes including drummed wastes
were disposed of on site Several of the subtances are
trade name materials or industrial process materials and it
is difficult to determine the specific chemical composition
Hazard is dependent upon concentration of material state of
material (solid sludge drummed liquid) and degree of
decomposition
Many of the materials - SBR rubber silicone defoamer
potassium oleate soap calcium carbonate and feldspar
fillers zinc oxide and sulpher salts plasticiser
calcium carbonate filler organicinorganic pigments AZO
dicarbonamid blowing agent epoxidized soy bean oil
cadmiura-bariun-zinc stabilizer - probably do not represent
a significant hazard to an inspection team if they are
bound into a sludge or solid Personnel are not likely
to injest or come into a prolonged high concentration
contact with these materials In powdered or dust conshy
ditions the materials are more hazardous due to the inhashy
lation of contaminated particulates
MEK (TLV-200ppm) toluene (TLV-100ppm) and Varsol
(turpentine thinner composition unknown) are volatile
organics which require respiratory protection and contact
protection
Depending upon state and decomposition PVC resins could
be a source of vinyl chloride monomer (VCM-a carcinogen)
requiring respiratory protection VCM is not adequately
filtered by air purifying respirators
Results from ground water sampling showed low levels of
industrial chemicals (PPB range) At these low conshy
centrations the chemicals do not represent a significant
hazard However the low concentrations in ground water indishy
cate the possibility of higher concentrations in the waste
materials
Industrial chemicals - napthalene (TLV-10 ppm) peryshy
lene anthrocene and pyrene which are hazardous
through inhalation or absorbtion Furthermore as
double benzene ring chemicals they are potential
carcinogens
Results from ground water sampling indicated possible
low levels (parts per trillion) of several pesticides
- chlorodane heptachlor epoxide toxaphene eldrin
Alpha BHC Beta BHC 4-4-DDT endosulphan These were
tentatively identified during a first analytical run
but not confirmed during a second run laboratory
review (GCA Bedford Mass) determined that the
material was actually a complex of highly degraded
heavy organics derived from the industrial waste The
presence of pesticides in industrial textile waste is
unlikely
Specific Hazards
1) Inhalation of organic vapors
Excavation of buried material and sampling of drums could
initiate high vapor concentrations
2) Fire and explosion
Many of the solvents are flammable liquids and volatile
Excavation of material and sampling of drums should
proceed cautiously in order to avoid rupturing shocking
or sparking of drums and material
3) Inhalation of contaminated dustparticulates
Excavation of buried material may result in a release of
particulates
4) Contact contamination
Excavation and sampling of wastes could possibly result in
contact with contaminated waste and soils necessitating
protective clothing
Necessary LPP
Site Reconnaissance - Level C The site has been visited on numerous
occassions by the state and private personnel Use of an HNU (102 ev
probe)- has not indicated significant vapor concentrations Significant
odors during dry weather or other hazards have not been noted
Sections of the landfill are currently active and adverse effects to
personnel have not been noted Level C - (tyveks rubber safety boots
organic vapor cartridges) is sufficient
Task 1 MagnetometerTopographic Survey - Level CD LPP will depend
upon the results of the Site Recon Significant vapor concentrations
or likelihood of particulates will necessitate an upgrade in the LPP
Otherwise Level D (work clothes safety boots boot wash) is sufficient
Task 2 Excavation and Sampling of Buried Drums - Level B The potenshy
tial for encountering significant concentrations of hazardous
materials during this task is moderately high Full Level B - (SCBA
chemical resistant tyveks hoods rubber safety boots rubber gloves)
will provide necessary respiratory and contactsplash protection
The use of the hooded yellow tyveck and the taping of ankleboots
wristsgloves and face maskhood junctions will provide complete conshy
tact protection
10
SECTION 3
FIRST AID FOR EXPOSURE
INHALATION OF VAPORSPARTICUIATES
Symptoms - eyenosethroat irritation nausea dizziness headache weakness fatigue lightheadedness drowsiness Loss of coordination confusion vomiting cramps (These sympshytoms are similar for most organic vapors particularly solvents)
Treatment Mild Exposure - Bring victim to fresh air Rinse eyes and throat if
irritated Heavy Exposure - (victim vomits very dizzy groggy faints etc)
Bring victim to fresh air Evacuate to hospital Prepare to administer CPR
Victim should be monitored for 48 hours in case of a delayed reaction
CONTACT EXPOSURE
Symptoms - Itching burning redness of skin Severe contact exposure for certain solvents will progress to CNS (central nervous system) symptoms similar to those for inhalation
Treatment - Remove contaminated clothing flush with water dry and banshydage Monitor victim for CNS symptoms for at least 48 hours
FIRST AIDSAFETY EQUIPMENT
The following equipment will be stationed at the Hotline or when appropriate down range
- Fully equipped first aid kit - Oxygen bottlekit - Nine (9) Ib chemical fire extinguisher - Eyewash bottle or other pressurized water filled container
11
SECTION 4
OPERATIONS SAFETY PLAN
This section outlines the specifics of safety procedures to be
used during each phase of the operations Safety procedures may be
upgraded or downgraded during site activities pending monitored changes
in the working environment All changes will be in line with the
General Level of Personnel Protection GuidelinesAction Levels for the
Troy Mills Landfill On-Site Investigation as described below
General Personnel Protection GuidelinesAction Levels
An in depth review of levels of personnel protection (LPP) is
presented in Appendix A
Level B (SCBA cotton coveralls or work clothes yellow tyveks (chemical resistant) steel toed rubber boots or work boots with disposhysible over boots and gloves)
Vapor concentrations (as measured on an OVA or HNU 117 EV Probe) greater than 5 ppm above background
- Oxygen deficient atmospheres less than 195
Specific actions (ie excavationsampling of drums) which could initiate a sudden moderate or high concentration of vapor
Level C (full face respirator organic vapor dust combo cartridge tyveks over work clothscoverails rubber safety boots gloves)
Vapor concentrations above an established clean zone backshyground level
During conditions (natural or personnel induced) which result in high levels of dust (visable above background atmospheric concentrations of particulates)
Level C activities require continual air monitoring
12
Level D (cotton coveralls or other work clothes safety shoes and safety glasses when down range Tyveks may also be needed)
Support areas and downrange areas where a higher LPP has not been deemed necessary
Continual air monitoring in downrange areas
Explosive Atmospheres
- 20 LEL (lower explosive limit) as recorded by an explosishymeter Secure and evacuate the work area
Oxygen Deficient Atmospheres
- Less than 195 (by volume) oxygen atmosphere requires upgrading the level of Personnel Protection to Level B
Task Specific Safety Plans
Levels of Personnel Protection indicated for specific tasks below are those which are anticipated to be used Changes in site conshyditions and results of air monitoring may indicate the upgrade downgrade of the LPP
13
Site Reconnaissance (SR) Date Sept 21 1983
Purpose To review on-site conditions and determine LPP necessary for further tasks To evaluate safety hazards Preliminary planning of future tasks
LPP - Initially Level C Updowngrade as necessary
Equipment - OVA HNU (102 ev probe)
Hotline - End of access road Upwind if possible
Command PostFirst Aid - Behind Hotline
Decontamination - Boot wash
Operations
Three man team Two persons advance in front with instrushyments Third person at distance as backup
Team methodically sweeps (criss cross) the proposed work areas with instruments
Specific points of interest (leachate seeps etc) are closely checked
All information is loggedsketch mapped
Upgraded LPP as necessary
14
Task 1 - Magnetic Survey Topographic Survey Date Week of October 3 1983
Purpose - Determine the location(s) and extent of buried drums Provide topographic information for site base map
LPP - Level CD
Hotline - End of access road (upwind if possible)
Decontamination - Boot wash
Operations - SO or other NAI personnel will perform a brief safety sweep of the work area
- Work team will then proceed downrange at the appropriate LPP Using the magnetometer the team will systematically criss cross -the work area
Task 2 - Drum Excavation and Sampling Date Week of November 14 1983
Purpose - Excavationsampling of buried drums in order to characterize the condition of the drums and the nature of the wastes conshytained in the drums and buried in the landfill
Msthod - Backhoe and hand labor will be used to uncover the drums in specified locations Samples will be obtained from spillage or leakage around the drums and of contaninated soil Selected drums which have accessible and openable bungs may be opened and sampled Drums will not be moved or staged Clean drums will be available to receive any significant spillage during the opening and sampling
Specific Hazards - Inhalation of organic vapors - Fire and explosion of drummed waste - Contact with contaminated waste or soil
LPP - Full Level B protection Backhoe operator at Level B Backshyhoe equipped with splash shield and without teeth on bucket
Hotline - At the end of the access road Upwind if possible
Decontamination - Procedures will essentially follow those as outlined by the EPA for Level B work Due to the inaccessibility of the site a field shower will not be available See Appendix B
Safety Equipment - OVA HNU eyewash fire extinguisher oxygen kit first aid kit metal detector non sparking implements
15
Operations - The cover soil is very sandy and the drums appear to be buried close to the surface which should facilitate excavation
- Minimum of 4 man team (exclusive of backhoe operator) Two or three man downrange team for digging and sampling One or two men in supportbackup at hotline
- Personnel will hand dig several small holes to approximately one (1) foot depth in each Location area If drums are not encountered the backhoe will scrape off soil to that depth
- Excavation will proceed alternating hand and backhoe methods At depths below four (4) feet the sides of the pit must be angled back to less than 45deg
- Prior to opening a closed drum the backhoe will nudgebump the drum to check for shock sensitive material An alternate method will be to attach a length of rope to the drum and from a distance pull on the rope to jog the drum
mdash Backhoe The backhoe operator will work at Level B utilizing air supplied from a large cylinder attached to the backhoe The backhoe will also be equipped with a splash shield A scraping bucket without teeth will be used
Prior to backhoe excavation at each location the area where the backhoe will be stationed will be checked for drums which could be ruptured by the backhoe feet
f Excavation areas will be checked for drums utilizing hand excavations or a metal detector prior to removing material by machine
16
SECTION 5
EMERGENCY INFORMATION
Emergency Telephone Numbers
If calling one of these numbers please state NAME LOCATION
and type of PROBLEM
Local Emergency Support
Fire Department (Troy 242-7759) For all emergencies use
Ambulance 352-1100 Mutual Aid (Keene) 352-1100
Police Department (Troy 242-7992)
Hospital 352-4111 (Cheshire Hospital in Keene)
Town Clerk 242-3845 State Agencies
NH Bureau of Hazardous Waste Management 271-4608
NH Water Supply and Pollution Control Commission 271-3503
NH Fire Marshall Office 271-3336
NH State Police (24-Hour Dispatch) 1-800-852-3411
Other
US EPA (24-Hour Hotline) 617-223-7265
Poison Center Mary Hitchcock Hospital 1-800-562-8236
Route to Hospital
- Follow dirt access road to Bowkerville Road - Left on Bowkerville Road to Rt 12 - Left (north) on Rt 12 through Troy to Keene NH - At major junction of Rts 9 10 101 and 12 go straight through
into Keene - At common go half-way around and go right on Court Street - Hospital is at 580 Court Street
17
Contingency Plan
Signal - five (5) one second blasts of auto or air horn Action - All personnel immediately excavate dovmrange areas and
report to Hotline for instructions
Personnel Unexplained Fire (if small) Accident (serious) Collapse of Personnel
Evacuate area Emergency ^ ^Evacuation Evacuate Area
First Aid
Estimate Explosion Level B (for Potential Contact Outside Help evcavation)
Evacuate Victim i If
Level B Prepare for Transportation
1 First AidCPR Use extinguisher Transport
Contact Outside Help Notify Coup any Have Proper Information Personnel (see below) 1
Transport
Call Fire Dept (if necessary)
For Hospital Victim
- Name and Phone of family physician
- Description of Incident chemicals involved symptoms nature of injury proposed treatment and plan of transportation
18
APPENDIX A
LEVELS OF PERSONNEL PROTECTION
Because of the possible dangers of exposure to toxic or harmshyful chemicals protective equipment must be worn during work on hazardous waste sites Levels of Personnel Protection (LPP) describe respiratory clothing and other equipment necessary for protecting personnel against expected hazards
The descriptions below are for full dress at a given LPP where hazards are expected to be at a maximum for which the given LPP is conshysidered adequate Depending on site conditions and work activities the clothing and dress requirements of a given LPP are commonly modified
LEVEL A
1 Personal Protection Equipment
Positive Pressure SCBA (MSHANIOSH approved) Operated in the positive pressure mode
Totally Encapsulating Suit (boots and gloves attached)
Gloves - Inner (tight fitting and chemical resistant)
- Boots - Chemical - protective steel toe and shank Depending on suit boot construction worn over suit boot
- Gloves shy Outer chemical-resistanttion worn over suit gloves May bchemical-resistant gloves worn insid
Dependinge replaced withe suit glo
on s
ves
uit construcshy tight-fitting
- Underwear shy Cotton long-John type
- Hard Hat (under suit)
- Disposable protective suitover encapsulating suit)
gloves and boots (Worn under or
- Coveralls (under suit)
- 2-way Radio Communications
Optional
19
2 Criteria for Use
A The type and concentration of toxic substances are known and require the highest level of combined protection to the respirashytory tract skin and eyes These conditions would be
1 Atmospheres which are immediately dangerous to life and health (IDLH)
a IDLHs can be found in the NIOSHOSHAs Pocket Guide to Chemical Hazards andor other references
2 Known atmospheres or potential situations that would effect the skin or eyes or could be absorbed into the body through these surfaces in toxic quantities
a Potential situations are those where vapors may be generated or splashing may occur through site activities
b Standard reference books should be consulted to obtain concentrations hazardous to skin eyes or mucous memshybranes
3 Oxygen deficient atmospheres with above conditions
3 At sites where the type andor potential concentration of toxic substances are unknown
1 Unless circumstances strongly indicate otherwise the site should be presumed to present hazards to the respiratory system skin and eyes Level A protection would provide the highest level of protection for the initial entry team
a Such circumstances might be
1 Environmental measurements contiguous to the site
2 Reliable accurate historical data
3 Open unconfined areas
4 Minimal probability of vapors presence or splashing with cutaneous effecting substances
2 Enclosed areas such as buildings railroad cars ships holds etc
20
LEVEL B
1 Personal Protective Equipment
Positive Pressure SCBA (MSHANIOSH approved) operated in the positive pressure mode
- Hooded chemical-resistant suit
Gloves - Outer chemical-protective
Gloves - Inner tight-fitting chemical-resistant
Boots - Outer (chemical-protective heavy rubber disposables)
Boots - Inner (chemical-protective steel toe and shank)
2-way Radio Communications
Hard Hat
Face Shield
2 Criteria for Use
A The type and concentration of hazardous substances are known and require the highest degree of respiratory protective but a lower level of skin protection
1 Atmospheres which are immediately dangerous to life and health (IDLH) Type and concentration of vapors in air do not present a hazard to the small unprotected areas of the body
2 Atmospheres with concentrations of known substances greater than protection factors associated with full-face air-purifying respirators with appropriate cartridges
3 Atmospheres with less than 195 oxygen
B When a determination is made that potential exposure to the body parts not protected by a fully encapsulated suit (primarily neck ears etc) is highly unlikely
1 Known absence of cutaneous or percutaneous hazards
2 Activities performed preclude splashing of individuals
C Level B protection is recommended as the lowest level of protecshytion for initial entries until the hazards have been further identified and defined by monitoring sampling and other reliable methods of analysis and personnel protection equipment commensurate with these findings utilized
21
LEVEL C
1 Personal Protective Equipment
Full-face or half-face air purifying respirator (MSHANIOSH approved)
Chemical-resistant clothing
Gloves - Outer (chemical-protective)
Gloves - Inner (tight-fitting chemical-resistant type (or woven liners)
Hard Hat (face shield optional)
Boots - Outer (chemical-protective heavy rubber throw aways)
Boots - Inner (chemical-protective steel toe and shank)
2-way radio comnunications
Safety glasses required with half-face respirator
2 Criteria for Use
A Site known to contain potentially hazardous materials exceeding
1 Air concentrations requiring a protection factor no greater than that afforded by a full-face mask
2 Harmful levels to unprotected body areas (face neck etc)
3 Well-documented reliable history of site and patterns of prior entry
C No evidence to suspect acute or chronic toxicity to exposed personnel
D Continuous air or personnel monitoring should occur while wearing Level C protection
22
LEVEL D
1 Person Protective Equipment
Chemical resistant aprons
BootsShoes - Safety or chemical-resistant steel toed boots
Boots - Outer (chemical-protective heavy rubber throw-away)
Half-face respirators immediately available
Safety glasses or safety goggles
Gloves
2 Criteria for Use
a No indication of airborne health hazards present
b No gross indications above background on the photoionizer andor organic vapor analyzer
c Continuous air or personnel monitoring should occur while wearing Level D protection
23
APPENDIX B
DECONTAMIHATION PROCEDURES
Depending upon activities and location on site it may be
necessary for personnel to decontaminate prior to leaving the conshy
taminated zone Procedures described below are typical for Level C
operations
Upon exiting downrange (contaminated) areas all personnel are
required to decontaminate by means of the following procedure
1 Place equipment in the Drop Zone at the Hotline
2 Enter the Decontamination Station
Boot Wash Walk through wash tub and scrub boots then rinse boots in second tube
Glove Wash In two pan wash scrub over gloves rinse set out to dry
2 Remove tyvek - if leaving the contamination reduction zone (CRZ) and proceed to clean zones
3 Dispose of heavily contaminated clothing and under gloves
4 Remove respirator
5 Use disposable gloves to clean equipment
6 Use a two bucket (washrinse) to decon respirators at the end of the working day or if they become heavily contami nated
The procedures for a typical Level B Decontamination are
outlined on the following page
TANK CHANGE 9
CONTAMINATION REDUCTION
ZONE
OUTER GLOVE REMOVAL
EXCLUSION ZONE
TAPE REMOVAL
BOOT COVER
GLOVE WASH
(bull)mdashQ-G--copyshySOOT COVEH SCOT COVES 4
REMOVAL GLOVE RINSE
SUITSAFETY BOOT WASH
SU1TSC8A78OOTGLOVE RINSE
SAFETY BOOT 10 REMOVAL
SCSA BACKPACK REMOVAL
SPLASH SUIT 12 REMOVAL
INNER GLOVE WASH
INNER GLOVE RINSE
FACE PIECE REMOVAL
INNER GLOVE 16 I REMOVAL
INNER CLOTHING REMOVAL
FIEUJ 19 REDRESS WASH
SEGREGATED EQUIPMENT
OROP
mdash -HOTLINE-shy
DECONTAMINATION LAYOUT LEVEL B PROTECTION
FIGURE A2-1
CONTAMINATION CONTROLLING
SUPPORT ZONE
25
APPENDIX C
PERSOHNEL AND RESPONSIBILITIES
Project Manager (PM)
Overall responsibility for all Project activates budget
schedule investigative operations safety personnel
On Site Coordinator (OSC)
Responsibility for activities at the site Primary responshy
sibilities include
1) Interfacing with the client state EPA media or other groups
2) Reviewing technical operations
3) Reviewing site safety in particular information supplied by the Site Safety Officer
4) Enforcing site safety and compliance with the Safety Plan
5) Directing Emergency Contingency operations
Safety Officer (SO)
Responsibility for directing the safety of operations and impleshy
menting the Safety Plan Specific responsibilities include
1 Assuring that appropriate personnel protective equipment is available and properly utilized by all site personnel
2 Assuring that personnel are aware of the provisions of this plan are instructed in the work practices necessary to ensure safety and in planned procedures for dealing with emergencies
3 Assuring that personnel are aware of the potential hazards associated with site operations
4 Supervising the monitoring of safety performance by all pershysonnel to ensure that required work practices are employed
26
APPENDIX D
PERSOHHEL CASUALTY
Personnel casualty would most likely result from either chemical
contamination heat-related problems physical injury from accidents
(ie falling lacerations etc) in performing the work or a comshy
bination of one or more of the above The appropriate action depends on
the type of injury involved with the priority being to assist the
casualty as soon as possible without endangering other personnel
Riysical and heat-related injuries can and should be treated
immediately with appropriate first-aid measures and follow-up medical
attention if necessary The injured worker(s) shall immediately move
out of the hot zone or if necessary be moved out by fellow workers as
soon as possible The OSC and Safety Officer shall be notified immeshy
diately and shall recommend further measures as needed
Chemical-related injuries require a much more cautious approach
so as to keep casualties to a minimum If a worker injured by chemical
ejqgtosure is able he shall notify the nearest co-worker and leave the hot
zone immediately- The co-worker shall ensure that the OSC and Safety
Officer are immediately informed and shall accompany the casualty from
the hot zone to the decontamination zone The OSC and Safety Officer
shall determine the appropriate measure
27
APPENDIX E
GUIDELINES FOR SITE OPERATIONS
In order to deal with the potential dangers of exposure and conshy
tamination of a hazardous waste site three zones are delineated
according to the degree of hazard The three zones are 1) Downrange
or Contamination Zone 2 Contamination Reduction Zone (CRZ) 3) Support
or Clean Zone
Downrange or Contamination Zone
The Contamination Zone is the active work area of the site which
encortpasses the areas where there is a potential for exposure and in
which investigative activities will occur (drilling sampling etc)
Within the Contamination Zone the designated level of hazard will be
established necessitating the utilization of personnel protective
equipment
Hot spots are those areas Downrange where observations instrushy
ment readings or specific activities indicate a high probability of
closure or contamination and may require an upgrade in the LPP in the
vicinity of the Hot Spot
Contamination Reduction Zone
The CRZ is an area between the Downrange and Support Zones where
decontamination of equipment and personnel occurs
28
Personnel entering the CRZ shall wear protective clothing and
carry the respiratory protection required for entry within the
Contamination Zone
Personnel working within the CRZ shall remain cognizant of the
CRZ in order to be prepared for any need to increase their level of proshy
tection within the CRZ
A decontamination station will be located at the outer perimeter
of the CRZ All personnel who have been within the Hot lane shall pass
through a decontamination procedure prior to re-entering the Support
Zone
Support or Clean Zone
The Support Zone is the outer area and may be considered to be
clear of contamination potential The command post will be located
within the Support Zone
a) The Command Post will serve as the OSCs headquarters and
will be equipped with
1 Communications
2 Safety Plans
3 First Aid Supplies
4 Analytical Equipment
5 Safety Equipment
APPENDIX B
WORK PLAN
WORK PLAN FOR
TROY MILLS LANDFILL TROY NEW HAMPSHIRE
DRUM EXCAVATION AND SAMPLING
Prepared by
NORHANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
1933
WORX PLAN FOR
TKOt MILLS LANDFILL TROT NEW HAMPSHIRE
DRUM EXCAVATION AHD SAMPLING
DATS November 16-18 1983
PURPOSE
To determine the condition of drums (ie erroty or full
crushed rusted leaking etc) buried in the Troy Mills Landfill To
obtain representative samples toward identifying the types of materials
buried in the landfill This information will be used in the detershy
mination of the level of remedial action needed at the site
METHOD
Using the results of the magnetometer survey the (10) points
have been randomly chosen across the area where the buried drans are
expected to be found Each point is central to an Excavation Location
-- an area four (4) to six (6) feet in diameter which will be excavated
in order to characterize the condition of the drams and to obtain waste
sarples
Preliminary observations have indicated that many of the drums
may be buried within 1-2 feet of the surface Therefore the investigashy
tion will proceed in two phases
Phase 1 mdash Hand Excavation By digging several small holes in
each Location personnel will determine if drums are located within
about one to two feet of the surface If drums are encountered the
excavation will proceed by hand uncovering the dnris for evaluation and
sampling Where drums are not encountered near the surface excavation
at this location will be postponed until Phase 2
Phase 2 mdash HandBackhoe Excavation After all Locations have
been attempted during Phase 1 those Locations in which drums were not
encountered wall be further excavated using a combination of hand
backhoe digging
It is expected that one to two days will be necessary to
cor^piete each phase Depending upon the results of Phase 1 it may not
be necessary to iroleraent Phase 2
Spare drums will be on hand for containerizing any significant
spillage resulting from sampling efforts Excavation locations will be
identified with marked stakes and the holes will be backfilled at the
conclusion of the investigation
SPECIFICS
Excavation Locations (Holes)
Number of proposed excavations is ten (10)
Locations of excavations are presented in Appendix A
Hole Size mdash It is expected that a hole from four (4) feet to six (6) feet in diameter at the bottom (depth at which drums are encountered) will be sufficient to characterize the drums at each Location Deeper excavations will require increasingly large top diameters
Hole Depth -- Holes will be excavated to a maximum depth of six (6) feet Due to the sandy cover material the excavation of deeper holes is probably impractical from both safety and efficiency stand points
If after attempting excavation at each of t-ie 10 proposed
1ocatiors irums are not encountered within six (6) fet of the surf ice
in enough locations to characterize the site excavations nay be
attempted to depths greater than six (6) feet if scil stability permits
or a new set of sampling locations may be chosen
(Excavations to depths greater than six (6) feet require a
significant increase in work The sides of the hole crust be graded back
to less than 45deg in order to insure the safety of investigatorysampling
personnel It may also be necessary to employ bracing bulkheads etc
for trench support)
Excavation Identification
Proposed excavation Locations have been consecutively numbered
from 1 to 10 beginning at the east end of the landfill They will be
marked with numbered stakes
Excavation Methods
Phase 1 mdash Within each Location personnel will dig a nunber of
small holes - about one (1) foot in depth - to probe for drums If
druns are encountered they will continue to excavate until the drur3
are sufficiently uncovered for characterization
Phase 2 mdash After hand probing the Location with snail holes
the backhoe will remove cover material to the one (1) foot depth The
Location will then be probed to a two (2) foot depth before removing
further material Excavation will proceed alternating handprobing and
backhoe excavation until drums are encountered or the maximum six (6)
foot depth is reached
If excavations to depths greater than six (6) feet are undershy
taken they will proceed using the above method
Santnlea
Due to the effort involved in excavating and because conshycentrated waste samples are not expected to undergo rapid degradation it is considered expedient to obtain all readily available samples (exclusive of closed drum samples -- see belcw) These can then be submitted for laboratory characterization as determined by need and budget restrictions
An attempt will be trade to secure at least one sample froa each excavation in order to help characterize the distrishybution of waste materials across the site An attempt will also be made to secure samples of observably difshyferent materials
Sample Types and Mediums - Solid liquid and sludge samples are possible Samples will be obtained from in order of preference -- 1) leakage uncontainerized waste or contaminated soil 2) waste contained in open conshytainers - drum already has a hole or no top or other access point 3) sealed containers
The opening of closed containers will be considered if it is decided that it has not been possible to obtain a sufshyficient number of representative samples from the other mediums
Each sample will consist of two (2) 8-oz jars (with teflon-lids) filled about 23 full One jar will be for organic analysis and the other for inorganic analysis
Sanole Identification - Samples will be identified with a number corresponding to the Excavation Location and a letter Example if three samples were obtained from Location 2 they would be samples 2A 23 and 2C and Samples 2Ad 23d and 2Cd for duplicates
Sampling Methods and Volumes - 11 mm hollow glass tubing trowels disposable scoops will be available to obtain samples Samples tools will be disposed of or deconshytaminated between each sample
Drum Samples - If necessary an attempt will be cude to obtain samples from sealed drums Oily o^und non-rusted drums will be considered Bunjs rust be xn suitable conshydition -jo that the dram cm be openoi withrut cvis ing dainai -ind ca-i be resell od to pr-jvcrt l V-i 30
There wil l be no staging or movement of drums in order to faci l i tate sampling Only drums with accessible bungs will be considered for sampling
Procedure for Drum Sampling
1) Excavate around top of drum
2) Monitor air in the adjacent area
3) Chec for shock sensitive - Loop rope around top of drum stand at a distance give drum several hard jogs by pulling on the rope An alternative nethod is to lightly jog the drum with the backhoe bucket
4) If the drum is not upright place a catch basin under the bung
5) Open drum with bung wrench
6) Monitor the air atin bung
7) Sample drum -- liquids insert glass tube the fu l l length into the drum in order to obtain a column of the materials in the drum Solids use scoop to dig out material through the bung or use a sampling trowel
3) Reseal the dram
Spill Control
The possibility exists during the sampling and excavation for a
drum to be ruptured or otherwise have spillage Clean drums wil l be on
hand to receive significant spillage resulting frora sampling or excavashy
tion They will not be used for clean up of widespread uncontainerized
waste or existing leakage
Personnel
The work team will require four (4) persons (exclusive of the
backhoe opera tor) Trie downrange team will consist of three (3) persons
-- two (2) for d igg ing and sampl ing and on ( 1 ) for logging air moni shy
toring and photographing One (1) person will be at the hotline in
support mdash as safety backup person to fill air bottles to deconshy
taminate samoles to assist in decontamination of personnel
Documentation Logging
The following information will be recorded at each location
nmber of drums uncovered and the condition (crushed empty rusted
sealed etc) of each drum evidence of spillage or contaminated soil
labels on uncovered drums samples (time drum ID type description)
periodic air monitoring information depth at which specific events
occur or drums are buried soil condition presence of ground water
In addition photographs will be taken of specific events or
items of importance during each excavation and of each sampling incishy
dent The time description of subject photographer excavation
location and photo number will be logged for each photograph
Analytical Laboratories and Schedule
RAI Hampton NH
Initial schedule
Ten samples for GCrns for organic priority pollutants Samples may also be submitted for inorganic anlaysis or volatile organic analysis depending upon waste materials observed during the excavation
APPENDIX A
TABLE A-1 EXCAVATION LOCATIONS
EXCAVATION BASELINE RANDOM RANDOM
NUMBER GRID COORD SEGMENT STATIOH OFFSET
1 7E+1 565N 0- 60 26 (25) 16
2 9E+5 13S 60-120 50 (110) 9
3 8E+0 31S 120-180 20 (140) 7
4 4E+5 483 180-240 50 (230) 25
5 3E+3 45S 240-300 14 (254) 20
6 OE+6 5S 300-360 34 ( 334) 50
7 2W1 5 24N 360-420 45 (-155) 14
8 5W+6 42N 420-480 38 (518) 20
9 6W+1474N 480-540 8 (543) 7
10 8W 5 11011 540-600 11 (611) 31
Locations are plotted on Map A-1
Method of Choice A stratified random sampling method was used to choose 10 Excavation Locations within the magnetic anomaly
The axis of the magnetic anomaly was used as a base line and divided into ten 60 foot long segments Using a randora nirnbers table a distance along each secpent was chosen (Random Station) and a line drawn at that point perpendicular to the base line Again using a random numbers table a distance was located along each perpendicular line by measuring inward from the line denoting the edge of Area A (Random Offset) The Grid Coordinates for each of the Excavation Locations were graphically determined from the grid overlay (this overlay has been surveyed and intersections field located)
It was judged that 10 excavation locations within the magnetic zone and two outside of the zone would be sufficient to characterize the area would produce statistically valid iati and coli be expected to be co~letod within 2-3 days work period
to
80
cu0
cgtc
APPENDIX C
MAGNETIC INVESTIGATION TROY MILLS INC LANDFILL SITE
TROY NEW HAMPSHIRE
For
NORMANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
By
JOHN F KICK PhD GEOPHYSICIST
Box 6 Dunstable Massachusetts 01827
(617) 649-6650
Noverber 19S3
MAGNETIC INVESTIGATION
TROY MILLS INC LANDFILL SITE
TROY NEK HAMPSHIRE
INTRODUCTION
A high resolution ragnetic investigation was completed on the Troy
Mills Inc landfill site in Troy New Hampshire by John F Kick
Consulting Geophysicist The purpose of the investigation was to
delineate the extent of buried steel drums under closed portions of the
Troy Mills landfill The information is needed as a part of a study of
the landfill that is being conducted by Normandeau Associates Inc
FIELDKORK
Magnetometer measurements of total field intensity were made over an
area that was reported to contain buried steel drums and adjacent
landfilled areas that contained unknown waste materials The area of
investigation included capped and grassed closed areas along the south
margin of the landfill site and adjacent areas The fieldwork was
performed during October of 1983
Eighteen parallel rows of measurements were conducted along north-
south lines (using magnetic compass directions) A spacing of 20-feet
was used between rows and magnetometer measurements were made at 10-foot
intervals along the rows Greater intervals between measurements were
used at the ends of the rows and in periferal areas with low magnetic
-JF Kick 01shy
field gradients
A series of magnetic field measurements were made at an adjacent
base station throughout the survey to torn the basis for a daily
variation curve The base station was located at a site with typical low-
gradient background magnetic field intensity measurements
MAGNETIC SEARCH METHOD
Theory Magnetic search methods involve the detection and
measurement of anomalies in the Earths magnetic field caused by the
presence of materials with contrasting magnetic susceptibility Iron and
steel objects generally have very high magnetic susceptibility contrasts
with usual surrounding materials and therefore produce magnetic
anomalies The amplitude shape and detectable distance of the anomaly
depend mostly on the particular susceptibility contrast and size of the
object Magnetic anomalies are measured in units called gammas The
normal magnetic field in this area is over 50000 gammas A 5-inch
screwdriver will produce an anomaly of 5 to 10 gammas at a depth of 5
feet and an anomaly of 1 gamma at a depth of 10 feet A 1 ton automobile
will produce an anomaly of 40 gammas at a depth of 30 feet and an anomaly
of 1 gamma at a depth of 100 feet The magnitude of an anomaly caused by
a single steel drum will vary with its condition (new heavily rusted
etc) Tests using a single light weight (somewhat rusted) drum on the
surface with the magnetic detector at a height of of 12 feet produced an
anomaly in the range of 40 to 50 gammas
Total magnetic intensity disturbances or anomalies are almost always
asymmetrical sometimes appear complex even from simple sources and
usually exhibit the combined magnetic effects of several sources which
can produce a given anomaly The apparent complexity of such anomalies
is a result of several relatively simple functions of magnetic dipole
-JF Kick 02shy
behavior Reasonable assumptions about the geology and buried source
conbined with an understanding of magnetic dipole behavior can usually
lead to a satisfactory qualitative interpretation More detailed
interpretations nay require modeling studies
Instrumentation Field equipment on this project included a EGampG
Geometries Memory-Mag G-856 proton precession magnetmeter The
instrument has a resolution of +01 gamma The magnetic field detector
is separate from the rest of the instrument and is mounted on an 8-foot
staff to provide measurements that are a constant height above land
surface
Magnetic Data Analysis For the purposes of data reduction and
anomaly delineation it was assumed that base station total field
intensity measurements were typical background values for the site
Measurements made at frequent intervals at the base station were used to
prepare a diurnal variation curve for the site Anoraly values were
obtained by subtracting background values from the base station curve
from measurements collected in the area of investigation
RESULTS
The reduced results are presented in the form of a magnetic anomaly
contour map (Figure 1) and two profiles across the area of investigation
(Figures 2 and 3) The map and profiles show that very steep magnetic
field gradients and large departures form background occur in an
irregular shaped band that is about 460 feet long and ranges from about
30 to about 200 feet in width The magnitude of the anomaly is such that
a significant deposit of ferromagnetic materials (such as steel drums) is
indicated
In using the plotted magnetic results it should be noted that the
greatest concentrations of ferromagnetic materials probably do not
-JF Kick 03shy
directly underlie the peak magnetic anomalies A shift is caused by the
inclination of the Earths magnetic field and by the dipolar nature of
ferromagnetic deposits The inclination of the Earths field is about 76shy
degrees northward in the vicinity of Troy The dipolar effect is induced
by the Earths field and results in negative anomalies immediately north
of large positive anomalies
Magnetic Anomaly Map The magnetic anomaly map (Figure 1) indicates
10 positive peaks of varying size shape and intensity Associated
negative anomalies of a broader and less intense nature lie immediately
north of the belt of positive anomalies The configuration of the
anomalous area is indicative of lense-shaped and cigar-shaped bodies of
ferromagnetic materials Steep-sloped anomalies are indicative of very
shallow source materials The thickness of the ferromagnetic deposit
cannot be easily determined on the basis of intensity and size of
anomalous peaks because a small mass of iron or steel at the surface can
duplicate the anomaly caused by a much larger mass at depth The
ferromagnetic source materials can generally be expected to lie north of
the positive peak of anomalies and south of the adjacent negative
anomaly Modeling can provide the best approximations of the depth and
density of the ferromagnetic source materials The outer boundaries of
the source materials can be expected to overlap the positive peak and
negative anomaly somewhat depending on the depth and configuration of
the deposit
For illustration purposes two north-south rows that were profiled
are discussed below
Magnetic Anomaly Along Row 9-East Two strong positive magnetic
anomalies (3645 and 2436 gammas) and adjacent negative anomalies were
profiled along Row 9-East (Figure 2) The approximate centers of the
ferromagnetic deposits are believed to underlie stations 50 north and 75
feet south of the base line The rounded shape of the north positive
-JF Kick
anoraly nay indicate somewhat deeper burial of the ferromagnetic deposit
Magnetic Anomaly Alone Row 7-West Figure 3 shows the most intense
positive magnetic anomaly (4470 gammas) that was detected on this
project The steepeness of the slopes is indicative of very shallow
source materials An uneven burial pattern is suggested by the two-
peaked positive anoraly The negative anomaly south of the two peaks is
unusual and may be related to another positive anomaly to the southeast
(along Rows 5 and 6 20 feet north of the base line) The centers of the
sources of the positive anomalies are probably approximately 80 and 120
feet north of the base line along Row 7-West
-JF Kick 05shy
DISTANCE FROM BASE LINE(FEET)
CO
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i-mdash LU Lu 2 Q lt2 Z
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SVWWV9 N A1VWONV
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t o H
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UJ UJ en UJ u UJ
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APPENDIX D
LABORATORY ANALYSES
RAI
Resource Analysts Incorporated Box 4778 Hampton H 03842
(603) 92^7777
TO PO 830318
Mr Doug DeNatale Date Received 12-2-83 Kormandeau Associates 25 Nashua Road Lab Number 2887 Bedford NH 03102 J
Date Reported 1-3-84
IDENTIFICATION
SAMPLE DESIGNATION PARAMETER
Volatile Organics Analyses by EPA Method 624
Acid and BaseNeutral Extractable Compounds Analyzed by EPA Method 625
Metals Analyzed by Standard Methods 303A
Please see attachments for all results
Results expressed in mgL unless otherwise designated lt = Less Than
ClarkeFosterVan K o u w e i b r h 1 ANALYST DIRECTOR
METHODS Standard Methods (or the Examination ol Water and Waitewaler 15th Edition or other EPA approved mtlhodologiei unless otherwise designated
Phys ica l descr ip t ion of sample
LiquidSludop
Saiple workup
Volitile f ract ion Methannl F-1-rarMrm CSVJ Rdfi-Smm
Semivolatile f ra ictio0onication Extraction fSW 846-3540^ Inorganic f rac t on Acid Digestion (SW 84h-iOS(V)
ACS3 COMPOUNDS
rr t CAS CAS
(71 A) tt-Ot-2 i^t TT i^MoroprvrfgtOi (73B) 30-32-1
(23 A) J9-JO-7 ^bull^^ lof o^^ft^crt gto (7 OB) 205-M-2
(2 A) 13-37 -J 2- chlorophenol (75B) 207-01-
(3 A) 120-13-2 2raquo^icMoroorgtenol (748) 211-01-9
(MA) 103-47-9 2-dimethv lohenol (77 B) 201-94-1
(37A) U-73-3 2- niiroDhenol (7IB) 120-12-7
(MA) 100-02-7 raquo-niiroprienol (7raquoB) lraquol-2raquo-2
(raquoA) Jl-21-3 2 - in i tr opheno 1 (106) raquoi-73-7
(40 A) 33-J7-l k4-dinnro-2-mlaquothylplaquogtergtol (I IB) 15-01-1
(4A) I7-U-3 (xntictiloroorraquonol (I2B) J3-70-3
USA) 101-93-2 pxmol (I3B) 193-39-J
(14 B) 179-00-0 RASENEUTOAL COMPOUNDS
( I B ) 13-32- raquocmlaquophtgtgtefgtlaquo
(36) 92-173 benzidine (2V) 107-02-S
( I B ) I20-I2-I l2t-tricMorobenzlaquonlt (3V) 10713-1
OB) 111-71-1 he laquo laquoch 1 or o benz erve (laquoV) 71-A3-2
(176) 47-72-1 hetraquocWoroltthlaquone (4V) X-23-5
U S B ) 111-- bu(7-cloroetrivl)ether (7V) 101- 90-7
(7CB) 9 I -3J -7 2-Chlororuprthraquolene (10V) 107-04-2
(73B) 95-50-1 l2-diCMoroblaquonzene ( I 1 V ) 7|3j^
( K B ) XI-73-1 13-didilorobtnzene (13V) 7J-3-3
(27B) 104-M7 1tmdash djcMorobenzene dkV) 79-00-3
C2IS) 9i9i-l 33-dictgtloroblaquoazidinr ( I JV) laquo-3-J
(33B) 12I -U-7 2gt-dinicrotoluer (14V) 7J-00-3 (KB) 4O4-7C-7 24-dinitrotoluene (UV) 110-73-1 (J7B) 122-A4-7 1J -diprienv lhydrraquo z irf (23V) lt7 tt 3
(MB) Z0-fc-0 UuorraquonThelaquo (2raquoV) 7J-35-
(W551 700J77-3 -ctilorophenyl prlaquonyl ether (JOV) 1M-40-3
( raquo I 6 ) 10I-J3-3 raquo-6romoprgtefgtyl prtenyl ether (32V) 71-17-3
(raquo7B) 33132-9 bU (2-cMorobopropyl) ether (33V) 10041-02-4
(raquoJ6) i l l -91- l bu (2-laquo^loroeTho)ry) methane 10041-01-03
(B) D-U) hexraquopoundj1|orobutaltlicne (31 V) 100--
(33B) 77-raquo7- heiKCtilorocycIopentadicrve (WV) 7J-CT-2
OB) 7IJraquo-I traquoo oh or or (raquo3V) 7raquo-17-3
(J3B) gtl-20-3 nphthraquolene (UV) 7raquo-I3-9
(546) n-tj) nitrobenzene (7V) 7J-2J-7
(426) U-Xl-4 bullJ -n itr o tod iphenyU mi ne (UV) 75-27-J
(OR) 421-W-7 N-oitrcnodipropYlirrUne ^raquoraquoV) 73-49-k
(446) I 1 7 J I - 7 bu (2-eltr^lheryl) phtfaUte 8200 (3ov) 73-71-1
(476) 13-U7 benzyl buryl phttwlite (51V) 124-kt-l
( U B I M-71-2 di-fl-utgtl pMhUre (13V) 177-II-
( lraquo6) 117-1 -0 dj-n-octvl prithlaquoUte (UV) 101-IS-3
(7CB) W-44-2 dielhvlphtraquollaquo (17V) 79-OI-t
( 7 | B ) I 3 I - I I - J dj^laquorTvipnthraquoUtr (UV) 7J-OI- (776) H-J5-5 bnro(raquogtnthrraquocefvr
Iab I D N o 2SS-10
C l ien t ID 1A64223
RASENEUTRAL COMPOUNDS
bfzoltraquogtprrene
benzoltb)flucrraquornNene
benio(llaquo)fluorraquonthene
chryiene
bullcenaDhthvien
raquontnrraquoctne
benzoltghi)perrlefgte
Iluorene
phergtraquonthrmlaquo
dibenzoltraquoMaithrraquocenraquo
indeno(123-cd)pvrene
prrene
VOLATHES
(frolein
bullcrvlooitrdf
benien
orbon Temchloide
CMorobeniene
1 7-dJchlorolaquothnr
111-trieftloroethine
ll-ltJichloroetrufle ll7-triCilorigtetMrlaquor
l127-tetrraquocMorothfllaquo
chloroethlaquo-e
7-dMoroeThraquo|virgtvl eirwshy
chloroform
11-didMoro^tfwnr
trinj- 1 2-dictMorolaquoirgtene
1 7-ltlicMoroproplaquorve
trini- 1 3-ltJichloroorcrpeoe
cu-lJ-lieMorocT oo eashy
rthy Uveniene
methrlene chloridf
chloromethine
bromome thraquone
bro mod iCTi lore met Mrgt
(Juorotr ichloromthraquor
di cMlor od 1 f 1 uore ngtet hj^gt
chloreltJbnjmomethne
te tr ten 1 or oet rx-r
laquouene 12000
tncMeroethe^e
Cidrr ium Chromiutr 10
All results are expressed as ucg veicht as received Nc ertrv denotes -0r ~ ^ 1 i rt
P h y s i c a l d e s c r i p t i o n of
SoilSludge
sample
Sanple workup
Vol i t i le f ract ion p^r Exf- rar r ion fST7Semivola t i le f rac t ion So^h^Pt Fgtr f ra r f ion
846-SOTO^ (SWRdfi-^SiO1)
Inorganic fract ion Ar id nio-psrirm
AOD COMPOUNDS
m CAS (2i A) tt-04-2 2raquot- Wichlorophenol
(22 A) J1-50-7 p-cfi I or o-n-cre laquoo 1
(2A) 13-57-1 2- ctiloroprienol
O iA) 120-13-2 2raquo^icMoroprnol
(gtraquoA) 103-47-1 2f 4mdash^imetSv Ip^enol
(37 A) U-73-3 7mdash Ti j oprtenol
(JraquoA) 100-07-7 mdash mdasho i Br opr^e no 1
JJ1A) 31-21-3 if mdash4 irtiTroprienol
(40A) J34-32-1 4 T4-4initrogtmdash 7 nte tny Ipnenol
(4A) f y _H 5 plaquontchlaroorwnol
(43A) J 01-95-7 prienol
rV ipoundNEUTRAlaquo- COMPOUNDS
( I B ) raquoJ-32-raquo
(3B) 17-17-5
( IB) 170-12-1
(IB) 1I1-7I-I
(17B) 4777-1
( I t B ) 111--
(20B) 11-31-7
(236) 15-50-1
(245) 51-73-1
(77B) 104-4-7
(285) 11-14-1
(336) 121-142
(34B) 404-70-2
(J7B) 127-M7
O1B) 2O4--0
(406) 7003-72-3
(416) 101-35-3 lt raquo 2 6 gt 3H3I32-1 ltraquo36) 111-11-1 (57B) S7-U-3
(336) 77 -raquo7-
(36) 71-31-1
(33B) 11-20-3
pound34 6 1 n-i33 (UB) tt-30-4
(436) CI-44-7
(4461 117-11-7
(47B) U-417
( U B I 14-747
(U6) I17_t-0
(7CS) l-laquo2
(7 I B ) t J U t l - gt
(7761 54-55-3
CT-~- i_i w i Miirn 0
resul ts
b^TMdint
1 2 t-o- icn lorobenl ergtlaquo
SeTraquochloroblaquorierraquoe
hrxchlorolaquotSlaquone
bu(2-chloroethv|gtether
2 -lt3M or onraquo ph ti1 ene
1 2-ltJictilorotgtmzcne
13-dicWorotxerzene
1 4-djch 1 or otxn z ergte
33-ditfgtlorolgtlaquoniidirraquo
24-dinitrotoloene
2 4-dtnitro toluene
U-dlpoenylfiydrraquoiilaquo
(luoranthene
raquo-cfJorophenyl poenyl ether
Mx-omopfieflyl phenyl ether
bis (2-cMorooopropyt) ether
bu (2-ctilorcxtSorv) meiSkte
hezkOilorobutadicne
hei acM or ocyc1 ofMn udi cne
oo prior one
nphthlene
nurotxniene N -ni tro Kxd ipoenyU mi ne
N-rutrowxhpropYUmJrw
bu (2-thylherl)(gthlaquoiraquoUtraquo
blaquoniyl buryl phtfraquolaquoUte
dt-^t-^xjrvl pfttfuiLitY
dj-n-octyl pitflaquoLitraquo
dirthvl phtruUtt
OArriett^vt prraquoT^Lraquot
bnzoltklaquonihnicer
22 Chronium
ire ev^rescei as uc ^ ^i-~ht-
Lab 1U N o 28B-1
C l i en t I D 1 R R 7 A A R
RASpoundNEbTRAL COMPOUNDS
benroltb)fluorraquorgtthfflf
benzoraquollt)fluor intone
ltrylaquo-gte
bullcenioithylen
raquomtirraquoenlaquo
ben z oltxh i)per v lene
lloorene
poentnthrrne
dibnzo(4h)laquonthricrne
mdeno(I23-rt)pvre-ie
pyrene
VOLATU-Ei
bullcrelem
bullcrvlonio-Ue
benzene
caj-bon traquotrraquochloraquo-idr
Ctilorobernene
l2-diehlongtethne
iii-tnctltiorotKraquor Trace 1 T 1 -4)Ctilorampe^hArw
l f 1 ^-tric^i lor oefvtrve
l t l 22-teTrtclloroetl^Ane
ehloroethraquone
2-chloroltthr|viw| ttrve-
Chloroform
1 1 -ltSicMorot^nr
trinraquo-l2-dictiloroetrne
12-d^loropOStn
trinil3^ichloroproone
eis-lJ-diChloroprooene
rrhylberuene Tarce methrlene ehlor tat Trace
Ct1 or o m e t Kirgte
bromometKtrte
bro mod i rfi lor o rrgte t Mne
Uuorotrlchloromethraquo^e
OJ CJ lor od 1 f 1 uoro met hraquone
chJorodibromometKATgte
laquotrlaquociloroethrrx
toluene 9
tricolor otheir
fsw
T9
Sifi-TOSO)
(73B)
(7IB)
(75B)
(7(B)
(77 B)
(71 B)
(71B)
(SOB)
( t lB)
(I2B)
U3B)
(M B)
(7V)
(3V)
(4V)
(4V)
(7V)
(10V)
(11V)
(13V)
(14V)
(13V)
(14V)
(11V)
(23V)
(21V)
(30V)
(32V)
(33V)
(34V)
ltlaquoV)
( raquo J V )
(44 V)
f raquo 7 V )
(UV)
(V)
000 (30V)
Tlfl 151V)
(15V)
^00 (14V)
(17V)
(UVgt
-1 ZINT
CAS 30-32-J
205-11-7
207-01-1
211-01-1
201-14-1
120-12-7
111-24-2
14-73-7
13-01 -laquo
33-70-3
113-31-5
121-00-0
107-07-t
107-13-1
71-43-7
34-23-3
101-W-7
107-04-7
71-35-t
75-3-3
7^-00-5
71-34-5
75-00-3
110-73-1
(7-14-3
73-35-4
154-40-5
71-17-5
10041-07-6
10041-01-05
100-4I-
73-OT-2
74-17-3
74-13-1
73-25-2
75-27-4
73-41-4
75-71-1
174-41-1
127-U- IOUIS-) 71-01- 75-OI-
130
Lab ID Mo 2887-4
Phys i ca l d e s c r i p t i o n of sample C l i en t ID 4A5760
Liquid Sample was predominantlv a hvrlrnrarhnn bl pnd
Sanple workup Voli t i le f ract ion PEG Extraction (SW 846-5030) Scrnivola t ile f rac t ion Sonication Extraction (SW 846-3550) Inorganic f rac t ion Acid Digestion (SW 846-3050)
AC3D CS3U POUNDS 5AipoundNEUTlUgtJ- COMPOUNDS
ri CAS PPraquo CASf
(210 U-04-2 2raquot- tricMorophrnol (7)6) raquo-32-l braquoniolttVyre
[EM 51-50-7 ^-cti 1 or raquo-m-lt rlaquo laquoo 1 (7raquoB) 203-M-2 biMo(b)(luorinth^f
2 A) raquo5-57-J 2- cfiloropheryjl (7 3 B) 20701 benro(ilt) floor in tlaquo^e
(31 A) 120J3-2 2raquo-ltJicWoro(ygtlaquotx)l (74B) 2II-OI- chryve^e
(MA) 105-47- 2l-dimlaquothvloSrrgtol (77 B) 20Uraquot-J bullcwrioMhylene
(57A) u-73-3 2- ruTroohrgtol (TIB) 120-12-7 raquontnncergte
(34 A) 100-02-7 -oitrophenol (7gtB) lraquol-2raquo-2 benio(ghi)cgtrrylngtlaquo
(3Agt 51- 21-3 2 -4 initropherwl (SOB) tt-73-7 fluorme
(tOA) 53-37-l t-dinitro-2-mlaquothy lpNlaquoxil (II B) 15-01-4 pheAinthrrnlaquo
(A) I7-U-5 tgtentraquochlQroiywnol (I2B) 53-70-3 dibenplusmnoltraquoh)fcnthrraquocrne UJJ 101-55-2 rfwtwl (I3B) lraquo3-3raquo-3 indenol 1 23-cd)vrtie
(UB) I2raquo^X3-0 pyrer BASENEUTOAL COMPOUNDS
VOLATO-ES (161 I3-32- raquoclaquonraquophttgtngtf
(5B) 12-17 -J btniidir (2V) gt 07 -07-1 bullcrolem
(IB) 120-17-1 l^^iricfvleroboMux (3V) 107-13-1 bullcrvlonit Jlaquo (raquoBI IIS-7t| SeraquoChlorotgtlaquoterlaquo (raquoV) 7IJ3-7 benient
(I7S) 4772-1 heLCMorolaquothinc (tV) J-23-5 crtgton wtrraquocMoidf (UB) I11-U-I bll(2lttllorolaquot^w gtetNer (7V) 101-W-7 ltAtoroxniergtlaquo
(203) Jl-31-7 2 -etvl or onlaquo ph traquo I en e (IOV) 107-04-2 1 2-ltlicMorolaquoTKlaquone
(25B) raquo5-30-l 1 2-dichlorobenzene ( 1 1 V ) 71-JJ-t llI-trichlorolaquotNlaquoe (2 B) 31-73-1 l3-ltlichoroblaquonzenlaquo (13V) 7J-3A-) 1 1-6 1 cM or Of t (Mr
(77B) I04-M7 I -di CM oro ben z eoe ( I k V ) rraquo-oo-j l12-niichlorolaquotfvirraquolaquo
(2IB) raquol-raquo-l )J-dichlcroblaquorLiidinr (IJV) rgt-3laquo-3 J122-tetrraquochlcrolaquoTrie
(33B) 12I-Ilaquo 2 2-dinia-otoluer (UV) 73-00-3 Ctgtloroltthne U4B) laquoJ-70-7 2 t-dtnitrotoluene (1raquoV) HO-73-1 2-ltJilorocthv|vL-v| etrveshy
(J7B) 127-M7 14-dip^wnylhydraiine (23V) C7-U^-3 Ctilorofcrm
(JraquoBJ 2Ot-ugt-0 CJuarlLnthefe (2raquoV) 7J-33- 11 -ltlicMorcxil^nr
(mei TOCJ-77-3 -chJorophcnyl phenyl laquoKr (xgtvraquo lK-^0-3 tnjM-l^-diC^lofCKtl^nf
( M B I IOI-J5-3 -6romophnyl phenyl ether (32V) 7I-J7-3 12-dicMoroprosaA
(raquo2B) 3M3I32) bU (2-cMarobopropyU rtNer (3JV) ICXU 1-07-4 trraquoni- 1 3-ltjictgtloroBoor^f
(OB) t l l f l - 1 bi5 (2-cMoroetfxgtrv) meihtrw lOOt 1-01-03 cu-O-dichloroprose- (32B) D-U-3 hrxaetilorobutadierw (UV) 100-laquol-raquo rthylbenien 1^00
(33B) 77^7- he i kcMor ocyc 1 openudi crw (UV) 7J-OT-2 rrveThvlerw chlof idf
(36) 7I-gtraquo| oop^troo (raquoJV) 7raquoJ7-3 CtgtlorBmethne
(338) raquo|20-3 nraquopfitfillaquofx 1200 (wv) 7raquo-l3-raquo bromorrgtlaquothne
(34B) nraquo3) nitrobenzene (raquo7V) 73-23-2
(CBI U-Xl-4 N -fl i iro lod iphen yU mi nr (UV) 7J-27- bro mod i cti lor o mT bull- (OR) 42l^-7 N-^itrolaquoodipropylmlrlte (raquoraquoV) 73-traquo-laquo tl uor o tr i cfi lor o mlaquoT itr (UB) I I 7 J I - 7 bn (^thylheraquoy|) phttilaquoUtT 110000 (XIV) 75-71J QJ ct )or oltJ 1 f 1 uoro rrgtei ^bull gte U76) U-U7 blaquonzyl buryl pttTfKUie 12000 ( j i v ) m-i-i ctil or od ib ro mo met h xnf (UB) M-7i2 d i -n -bo TV 1 ft thlaquo U tlaquo (13V) 127-11- te trraquo cfl lor ot hlaquoTgtf (OBI 117-4J-0 dj -n -oc t y1 Jgth fflaquo U re 6 200 tuv) iom-3 tolucie ^70
(7CB) u-u- djrthyl phtJMlire (17V) 7raquo-OI-4 irictilarcraquo^lt-ir (715) 1 3 1 - 1 1 - 5 oVnrrhyl pMtfaUte (UV) 75-OI- v i M v l CMor idr
(T76I 5-55-3 blaquorgtzo( Unihrlaquocme Xylenes 1SOO
Cad- iurn 2 2 on Chromium - - Z I N C ^ ~ P r
Ai results arc expressed as ugc weight as received Xo entry denotes not detects
Lab ID No 2887-3 5A 57709 Phys ica l d e s c r i p t i o n of sample Cl ien t ID
LiquidSludge Liquid appeared to be a hvdrnc-Arhnn blonrl
Sample workup
Vol i t i l e f r ac t ion Methanol Extraction fSW 846-5030^ Semivolatile fract ion Sonicatlon Extraction fSW 84 f i_3550gt) Inorganic f rac t ion Acid nic-psr-inn fSW 846-30501
ACS3 COMPOUNDS BASENEUTRAL COMPOUNDS
f f t CAS CAS (2IA) tt-04-2 (738) JO-32-J DCftZ OTamp p V^^^ff
(22 A) 3laquo9-50-7 p-cttl or o-m-cre laquoo 1 (7VB) 205-99-2 p^^izot oil lyor 4-^ t ^ltf ^^
(2 A) raquo5-37-l 2- CJiloroprieno (75B) 207-01-9 blaquonioltllt)flultxtn^it
(31A) 120-13-2 2raquo-dictgtlcr8tgtrfX)l (74B) 211-01-9 Chryeolaquo
(3 A) 103-47-9 2 -d irrgtet hv Ipherto1 (77B) 201-94-1 laquocnphthyle^
(37 A) 11-73-5 2- rutrop^enol (7IB) 120-12-7 bull^thrjc c^
(MA) 100-02-7 -flitroprlaquorv3l (79B) 91-2-2 bcnroltKhi)pefraquoler
(79A) 31-21-3 2 -d in itr eoricno 1 (IOB) 14-73-7 tluoren
(40 A) 33-37-l 4-d in itr raquo-2 -met hy Iphtnol ( I IB) 13-01-1 poltrtAOthrvTgt^
(44 A) 17-14-3 plaquon1 CM or o^eno I (I2B) 33-70-3 dib^fi-o( 4(K)Aji thirl c c^f (43A) 101-93-7 prwnol (S3B) 193-39-3 indcnotlIJ-ctflsvfie
(SB) 129-00-0 pyrene ftASENEUTRAL COMPOUNDS
( I D )
(5B) 92-X7-3 b^zidrw (2V) 107-02-1 bullcrolrm
(IB) 120-17-1 1 2 fc-Tr ICJ caro blaquoni crw (3V) 107-13-1 bullcrvlonitrij
(93) 1IU7I1 Seraquochlcrotgttniegtlaquo (4V) 71J3-2 blaquonienlaquo inn (17B) 4777-1 hexat^lorcwthgine (4V) H-23-5 carbon ttTricllixidf
( I I B ) 111-wJ bll(2-lt3^1oroltt^w)ether (7V) 101-90-7 ciloroblaquonzene
(20B) 91-31-7 2-ctdo-ont she Ime (10V) 107-04-2 12-dieftloroerane (25B) 95-50-1 l2-dilorobenzene ( 1 1 V ) 71-35-4 11 1 -tricMorotn-laquo
(2ampSI 51-73-1 13-dicMo-obenxerw (13V) 73-3-3 1 1 -d i CM orcxt M-
(77 B) I04-H-7 1 -di ci 1 or o benI erw (UV) 79-00-3 llJ-WiChlorolaquoflaquonlaquo
(2J6) 91-90-1 SS-dKJilorotxniidinc (13V) rraquo-3laquo-3 l122-tetrlaquocftlorelaquoTrne
(35B) 12| |k-2 2fc-dintrotoluene (14V) 73-00-3 diloroeth^e
(gt4B1 404-20-2 24-diniTrotoluenlaquo (19V) 110-73-1 2-cMortxfthv|vL-raquo trlaquoshy
(37B) 122-447 12-diphenylhydriin (23V) 47-44-3 cMoroform
(J9B) 204-U-0 Ouormntherve (29V) 73-33-i ll-diCMorolaquot^nf
(fcOB) 7005-77-3 k-cMarophfy| prlaquonyl etScr (gtOV) 134-40-3 trraquonraquo- 1 2 -dicMoroc t Nenf
(raquo I6) 101-35) raquo-6romoprny| phenyl rther (32V) 71-17-3 12-diChloropostn
(raquo2B) JH3IO2-9 bU (2-ltplusmnlaronopropyl) rthrr (J3V) 10041-02-4 trni-l)-diirMoroxtgtOpnf
(OB) I I 1 - 9 I - I bu (Z-chloroethxjrv) metSampnlaquo 10041-01-05 CU-D-djcMoroproOf-W
(32B) 17 -U -3 hiraquocfilarobutraquodiergtlt (3JV) 100-4U rttyligtlaquonitrgtlaquo 5300 (33B) 77-raquo7-raquo hrxicftl or ocrclopei tidier (UV) 75-09-2 nxthylenf ctilor ifif
lt3B) 71-391 ao prior or (raquo3V) 7raquo-17-3 rtloromrtha^r
(356) 91-20-3 nlaquoprithienraquo Trace (44V) 7raquo1Jraquo bromltmlaquoth^
(MB) n-93) ft i vo b^nz c^^ (raquo7V) 73-23-2
(425) U-30-4 ^bullf i^OftOOL^ri^ny lArrunf (UV) 73-27- bro mod i cgt lor o i~ t gt
U3amp1 Ul-4-7 N i itr CrtoO ip ro py 1 laquo ml r (raquo9V) 73-49-k U uor o IT 1 et loront Mrgt (UB) II7-1I-7 bu (2-Ihythlaquoryl)prtfUtr 59J300 (30V) 73-71-1 dj ci kr olt11 f 1 uoro rrrt (Nrgtraquo
(47 B) L3-41-7 txniyl burvl phthlaquoUtr ( 3 1 V ) I2-1-1 ch1 or od i b ro mo mi IMP r
(UBI U-71- 0-A-fcurl BMMliw (13V) 127-ll-i rt tr t cM or of tNr
Uraquo6) 117-li-O di-n-oCTv| pnttlaquoUfr 6000 (UV) lOt-II-3 toluenf 5700 (7CB) U-447 djrthvl p^tfvilirt (17V) 79-01-4 WiCMoroth^e ( 7 J B I U l - l l - 3 d^M^vl prttgtraquoUW (UV) 73-01- vinv t cMor 10 (77 Bgt H-35-) brto(raquollaquonthncrTraquo Xylenes 19000
Caen 1U~ 1 Chromium =2 Z I N C
All results are expressed as up g weight as received No errrv ripn^t-plt
Lab 1Lgt No 2887-5
rhyr i r n l d e s c r i p t i o n o f sample C l i e n t in 6857710
LiquidSludge
Sample workup Vol i t i l e f r a c t i o n PEG Extraction (SW 846-5030) Semivolat i le fr action Sonication Extraction (SW 846-3550) Inorganic f rac t ionAcid Digestion (SW 846-3030)
AOD COMPOUNDS BAStNELTTRAL COMPOUNDS
rr i CASI CAS (21 A) tt-04-7 (736) 30-32-1 bntoltraquogtprrene
(23A) 3-9-50-7 p~lt1 or o-m-c rraquo1 (78) 205-99-2 ben to( Sgt )1 1 uor raquon I he-gtf
(7raquoA) 93-37J 2- etilorophenol (73B) 207-01-9 beriioltk)(luortntrgt^f
(3 IA) 170J3-2 2raquo-dicMoroprnol (7(B) 2II-OI-9 eifVMTie
(3 A) 03-(7-9 24-4mlaquoThvlDheno| (77B) 20l-9(-i bullceraoMhyler
(37 A) tt-73-5 2- rue-oorienol (718) 1 20- 2-7 laquoflthrraquocene
(3 A) IOO-02-7 ^Mtroprwnol (7fB) 191-24-2 beraquoMoltsrM)plaquovllaquox
(39 A) 3I-71-5 2-4 ini tr ophero1 (tOamp) K-7J-7 tluwtrie
((OA) 33-37l (-lt iMtro-2-methylphenol (tlB) D-01-J phenATithrene
(4A) I7-44-J pentichlorophenol (128) J3-70-3 dilwnioltraquoh)laquonthrraquoceif
(OA) IOI-95-2 prwnol U38) 193-39-3 indeno(123-cd)vcne
(MB) 129-00-0 pyrergtlaquo 6 ASENEUTILW- COMPOUNDS
VOLATH-tS ( I B ) 13-32-9 ftCYTNA pO IT H I raquolt
(38) 92-17- o^nzioinc (7V) 107-02-1 aero le in
( IB) 120-I2-I l2k-o-i(3iloroblaquontergtlaquo (3V) 107-13-1 laquocrvlono-U
OB) Jl l-7fc | he I raquocti 1 or o blaquonI enlaquo (V) 71-43-2 Oltf2 tO^
(17B) (772-I he uc^i 1 or of t h ne ((V) 34-23-3 CJU JOO Tt TTlCfllo^ iCpound
( I I S ) bu(2-rfilcroethv|)ether (7V) 10J-90-7 laquoWoroblaquonzeoe III-44-4
(KB) 9I-51-7 2ltfMoronlaquoohttvraquolwe (10V) 107^)4-2 1 t2^ojo^loroetfft^c (2JB) 95-50-I 1 2 -dichlorotgtlaquorlene (11V) 71-55-4 1 1 1 -trichloroeihtr (251 541-73-I 13-dchlorotxniene (13V) 73-J4-3 1 1 -dieMoreeraquohraquorlaquo
(77Bgt 04-lgt4-7 1 mdash djcMorobenlene (IkV) 79-OO-3 t12-tricriloroeflaquofgte (2gtB) raquolraquo-l 33-didMoroblaquonjidirlaquo (13V) 79-34-3 1122-tetrcnicroeir^ne (33B) 12 I I 4 -2 Z4-diniiroioluerlte (1(Vgt 73-00-3 e^loroetruuie (KB) (04-7C2 2 (-dinitro toluene (19V) 110-73-4 2ltJilorolaquotr(v|vLnraquolnhlaquo (175) 122-447 12-dipr-enylfiydrmiine (23V) (7-44-3 chloroform
(J1B) 704JJ-O Huor^thrr (29V) 73-33-4 lI-ltJicMoroltthcne
(OBgt 7003-77-3 -ctJoroprienvl phenyl ether (JOV) 134-40-3 irirraquo-12-dictila-olaquotrlaquone
( raquo I B ) IOJ 33-3 -6ogtmoprienyl phenyl ether (32V) 7I-I7-3 l7^lichlorepreoine (laquo2BI 3H3raquoO2raquo bit (2-chlororaquoopfT5pyO ether (3JV) 10041-02-4 trint-l3-ltJicnloroBlt-ooee (OB) 111-11-1 bis (2-cMcroetro(v) metSuvr 100(1-01-03 CU-lJ-itflloropOO-^
(376) t7-U-3 hraquoz raquoch1 or o bu tlaquodi ene (J1V) )00-1- erhylberuer 1400 (33B) 77 -gt7- hei tchl or ocyc1 open traquodi ene (raquoV) 73-09-2 methylene chloriCf OB) 7raquo-3raquo-l BO prior one (raquo3V) 74J7-J eMorametrutne (33B) raquol-raquo-3 naphtfalene 100 (UV) 74-13-9 bro rrvome t hrgt (3iB) n-raquo3-3 niireblaquor)iergte (raquo7V) 7J23-2 (CB) U-XH N -01 ITo tod 4gthenyU rru rr (UV) 75-27-4 bro mod i ch lor o rrx t f4Ugt ((36) 42IO4-7 N-nnroodipropYlraquomlrlaquo (raquolaquoV) 73-4t-4 JJuorotr lchloronvlaquoiMftlaquo (Uol U7-1I-7 ba (2-etrylNraquoYl) phtt^Ure 100000 (30V) 75-71 -raquo dj cftlcr od U 1 vraquooro rri NUT
(47 Bl 13-44-7 t^niyl butvl phthiUte 13000 (31V) 124-41-1 chlorodibromorrwt^r
lt U E gt ) U-71-2 d-ojjurvl phtf^Ure (13V) 127-11-4 tr trbullcti loro rirr
laquoraquo6gt 11704-0 dl-fl-OCTvl pfltMUM (UV) 10t-ll-3 toluene fiin (TtS) raquo-laquo djrthvl phttuliTr (17V) 79-01-4 tricolor oethenr lt 7 | o l 131 -11 -1 (UV) v i n v i chlcwidr dimrlKyl rrftlaquoUTraquo 75-OI-J
(T75I J4-35-J blaquoTMOlt^trrlaquocr^ gtylenes 1200
Cadr ium 3 Chromium 21 ZINC 150
All results are expressed as ugg weight as received y0 entry denotes not detect
Iah I D No 2887-2
Physical descr ip t ion of sample
Strained Soil
Sample workup
Voli t i le f rac t ion PFG Extraction (^W 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-3540) Inorganic fract ion Acid Digestion (SW 846-3050)
ACS) COMPOUNDS
rn CAS Tft CASf
(21 A) tt-04-2 (73B) 50-32-4
U2A) 71-50-7 P-ch 1 or o-m-cre laquoo 1 (7k 8) 205-11-2
(2 A) raquo3-37-l 2- chloroprraquoeno| (75B) 207-01-1
(3IA) 120-13-2 2raquo-4ichlorophenol (74B) 21UOI-1
(3 A) 103-47-1 24-dimethvlphenol (77 B) 201-14-1
(57A) U-75-3 2- njtroDhenol C7I5) 120-12-7
(MA) 100-02-7 a-flitrophenol (71B) |1l-2raquo-2
(51A) 51-21-5 2 -d in i tr o phetio 1 (SOB) K-73-7
(40 A) 53-57-l raquo 4-dinitro-2-methy lprnol (tlB) 15-01-1
(4 A) 17-14-3 plaquoitraquochloroorlaquonol (I2B) 53-70-3
(43A) IOt-13-2 prlaquonol (13B) m-31-3 (MB) 121-00-0
BJ KSENCLmLAL COMPOUNDS
(IB)
(3B) 12-17-3 bcnzidine (2V) 107-07-1
(IB) 120-17-1 1 2 k- tr i ch 1 oro benr ene (3V) 107-13-1
(IB) I1U7I-1 he it raquocM or o boiz ergte (raquoV) 7I-J3-7
(12B) 47-77-1 he traquoch 1 or oet hlaquo ne (4V) 54-23-3
(116) 111-- buC-cJiloroethv|gtether (7V) 101- W-7
(20B) 11-31-7 2 -ltft 1 or on ph ttvraquo 1 laquon e (10V1 107-04-2
(23B) 15-30-1 1 2 -dictilorobeni ene (11V) 71-55-4
(25) VI-73-1 1 3 -ltJ i ci 1 or o blaquoiz ene (13V) 73-3-3
(77 B) 104-M7 llaquo-dchloroblaquoMeoe (HV) n-00-3
(2IB) 11-lk-l 33-dicMorotxTLtidinr (15V) n-3raquo-3 (33B) 12I-U-2 2 ltgt -4 in i tr ot o luene (14V) 75-00-3
(MB) 464-20-2 2 4-d initrotoluene (11V) 1 10-7 3-1
(J7B) 122-447 1 2-diprieny Ihydrti ine (23V) 47-44-3
(316) 2O4-UO Ouorraquonthene (21V) 73-33Jshy
(WB) 7t)03-77-3 ^-cJJorophenyl prienyl ether (JXgtV) 154-40-3
(MB) 101-33-3 -6romopriefgtyl prienyl ether (32V) 71-J7-3
(raquo2B) 3431-32-1 bit (2-chloroboproprO ether (33V) 10041-07-4
(OB) I1U1I- I bu (2-ltMoroethorv) methane 10041-01-03
(52B) r-u-3 hexachlorobutadiene (J1V) 100-l-raquo
(33B) 77-47- he z raquoctlt lor ocycloqenud i crte (MV) 75-01-2
OB) 71-31-1 ao prior one (raquo3V) 7raquo-17-3
(33B) 11-20-3 nlaquopntrlaquollaquone (UV) 7raquo-13-1
(MB) n-13-3 nitrobenzene (raquo7V) 73-23-2
(UB) U-30-4 N-nnroiodiprienyUmine (UV) 75-27-k
(436) Ol-U-7 N-nitrModiproOYlmJne (raquo1V) 73-41-
(UB) 117-117 bu (2-laquothylheiry) phtrlaquolte 8800 (50V) 75-71-1
( 4 7 B ) L3-U7 blaquoniyl buryl phthaUte 30 (31V) 12I-H-1
(UB) U-7U-2 di-o-burvl phtrMUte U3V) I27-I1-
(416) II7-U-0 dj-n-oCTvl pritntUtr 1200 (raquo4V) IOUI1-3
17CB) U-44-2 djetiTi phrtultrt (raquo7V) 71-01-4
( 7 I B I 1 3 1 - 1 1 - 3 dimnfTraquo| prThraquoUtr (UV) 73-01-
(776) H-35-3 berMolta^thrCF^
Cl ien t ID 8 A - S 7 4 6 1
RASENEUTRAL COMPOUNDS
benzofbtfluor^tMe
benzodclfluorintoent
Ctiryiene
cenoithylene
raquonthrraquoctne
benzoltKhilpervlefgte
floor ene
prlaquofnnthrene
ltlibenplusmno(4h)knthricrnlaquo
inogtno(123-rt)pvrrne
pyrene
VCX-ATIIE5
bullcrolem
bullcrvlomn-U
benzene
carbon tetrtchloridf
chlorobenzene
1 2-oUchloroethAnf
lll-trichloroethlaquone
ll-dcfioroethrraquo
1 1 2-tricilorolaquothraquorw
1122-tetrichloroeTtvin
chloroethre
J-ctiloroethv|vinv| etrgte
chloroform
11 -denier oethene
trinraquo- 1 2 -4 cMor oe t hens
12-dcMoroprooine
^Lns~ I f 3-4ic^ lo^opf oo^^^
Cli-l 3-dicMoroprooe^e
rttiylbenzene
methylene cnlonfle
Ch 1 or o me t hane
bromome thane
Trace
bro mod i cMor 0 me t hane
(Juorotrlchlorome thane
chlorodibromometKinf
tetracnloroethervp
toluenetr icMoroel he-if
Trace
CacTiiun Chromium ZINC f
All resxil ts are exprp^spr i K-i
Phys ica l de sc r ip t ion of sample
Strained Soil
Sample workup Vol i t i le f ract ion PEG Extraction (SU 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-5340) Inorganic fract ion Acid Digestion CSV 846-3050)
ACE) C30laquo POUNDS
m CA5i CASraquo (2i A tt-C-2 (73B) JO- 52-1
(22 A) J1-JO-7 p-ch 1 or raquowTv-cre 101 (7raquoB) 203-raquoraquo2
(2 A) raquo)57-J 2- chlorophenol (73B) 20701-
(31 A) I25J3-2 2k-4icttlltroptlaquonol (7tB) 211-01-1
(3A) IO)-7-raquo 2-dimlaquothvlpNrnol (77 B) 20l-raquoi-
(37 A) u-rj-j 7- niTTOphenol (TIB) 120-11-7
(MA) 100-02-7 -rtropN-rraquol (7raquoB) lraquol-2-2
(JraquoA) JI-21-) 2-d initroprietys 1 (IOB) U-73-7
(MA) 53-37-l Udinnro-2-mlaquothylphenol (UB) I5-OI-J
(Agt I7-U-3 pentichlcropwnol (126) 33-70-3
laquo)Agt 10l-raquo)-2 phenol (I3B) IJ3-31-3
(MB) 12raquo-00-0 AASCVflCUTRAl COMPOUNDS
( I B ) I3-32- bullcnraquophtber
(56) raquo2-17) bnzidirlaquo (2Vgt 107-02-1
(IB) 120-12-1 l2btrilt7tlorotgteizegtlaquo (3V) 107-13-1
traquoB) IIraquo-7fc | heikcMeroblaquonzergte (V) 7l-3-2
( I 2 B ) 4772-1 he ueft 1 or olaquot hraquo rgte (tV) laquo-23-3
( i ts) III-- biraquo(2-cMoroethv Dethrr (7V) 101-W-7
(20Bgt 1I-3I-7 2-cMoroflaquophthlene (10V) 107-Ofc-2
(2)6) raquo5-50-l l2-dchlorotgtlaquonzefgte (11V) 71-33-4
(28) 3l-7)-| 1 3-didMoroblaquonrenlaquo (13V) 73-3-3
(27B) 10t--7 l-diclorolgtmzerlaquo (iV) rraquo-00)
(216) raquoI raquoltbull- 33-dichloroblaquoMidiflaquo (13V) 79-31-
(356gt 2I- l-2 21-dinitrotoloen (UV1 73-00-3
(UB) laquogt- 20-2 2 (-dinitroto luenlaquo (HV) 110-7J-J
(376) 122-W-7 14 -dipheny Ihydrzire (23V) lt7-M-3
(396) 2O--0 tJuoruMSene (2raquoV) 7J-35- (OB) 7003-77-3 -c^lvophenyl pNrnyl ethlaquor (30V) 1H-W-)
(MB) 101-33-3 bull-bromopriefiyl prienyl ether (32V) 7t-t7-3
ltraquo25) 3HJI-32-1 bU (2-cMoroaopropyl) rthrr (33V1 10ltX 1-02 -6
(06) l l t - t l - l bis (2-cftloroetSorv) metwne 100lt]-01-03
(32B) C7U-3 heraquoraquochlorobutidierx (31V) 1 00-41-
(3361 77-7-raquo hexiOilorocycloptfiudlerve (raquoV) 73-0raquo-2
(56) 71-51-1 no ph or one (raquo3V) 7raquo-17-3
(3)6) raquol-raquo-3 rwiphtfalme (UV) 7raquoJ3-raquo
1361
LUB)
H-133
14-30-4
nitrobenzene
^ ri i iy o too ipf^^ y LA r^i rtf ^ 7V) (UV)
73-23-2
73-27-
(436) t21--7 M^TI iff frfcO^ip ropy Ift mJf^ (gtraquoV) 73-4raquo-raquo (UB) I17J1-7 bu (2-rThyiruMcyDpMtvUtr 570 (jov) 73-71-1 ( U B ) U-41-7 blaquonzyl buryl phthlaquoLite (31V) l2k-raquo-l ( U B I U-7I-2 di-n-burvl pitftALtTe (raquo)V) 127-lt-fc
(OB) 117- -0 dJ-fraquo-oCTvl phlJ^Ute (UV) IOt-It-3
(7CB) 14 -W- 2 djelftvl phtfalitt (17V) Tt-01- ( 7 I B I 1 J I - I 1 - ) duTNnhylphttsraquoUw ltUV) 75-01-
(77BI X-))O lgtmrlaquoigtmhrraquoctf
Cadmium f iQ Chromium 15 ZINC
Tab ID No oo -
Cl ient ID 8A-A-64220
fcASENEUTTRAL COMPOUNDi
blaquofuo(raquo)pyrrtgte
bfizo(b)(loortAth^e
benzo(k)f|ulaquoin1herf
Ctiryiene
cenDraquoMrwlene
fcftT^rict^t
D^flZCT (fftl)pC^ V Itf^p
(luorene
phen^threne
diiwnztKthlanthricene
indlaquono( 1 23-lttf)pvrene
oyrene
VOCATtLES
bullcrolem
bullcrvlooitriJe
bervteoe
carbon WTTicMoridf
chlorobenze^e
12-djcMoroetfane
1 1 1 -tricolor ex tKraquon
1 1 -dicMarcx t hrlaquo
1 1 2-triChlorothraquorw
1 122 -laquotrraquocM or o-hraquorgt
cMoroettu^e
2-cMorlaquothv|vuy| rseshy
chlexeform
ll-dchloroctfgtn
tri^iraquo l 2laquoflic^ loTo^i rgtcnt
12-dicWoroproptrs
Winl-l3-dicMoropfooene
Cu-lJ-djChleroprooe^
rrtiylfrenzene
methylene ctiloride 0 64
cMorometHAne
bromomlaquothlaquone
bnsmoform
bro mod i eti lor e me t Nine
0 uor o tr 1 cMor e rrgtlaquo t Nnlaquo
dj di tor olaquol If 1 uoro mraquoi Nrraquo
chlorodibromonveiKme
re tr a en 1 or or fxrvr
toluene
D-ieWoroefwne
entry denotes not detect All results are expressed as ugg weight as received Xo
Lab 1) No 2887-8
Physical descr ipt ion of sample
Sf-rs inpH 9 n i l
Sample workup
Vol iCi le f ract ion PEG Extraction (SW 846-5030)
Scmivolat i le f ract ion Soxhlet Extraction (SW 846-3540) Inorganic fraction Acid Digestion (SW 846-3050)
ACD O3MPOUNDS
m CAS fPraquo CASf pi A) tt-Ot-2 Zraquot- tritilorophrgtol (73B) 30-32-1
ft M -3o-7 p-cMorraquo-m-crTraquool (7kB) 205-raquo-2
(2 A) raquoS-37-l 2- cMorop^erxgtl J73B) 207-OI-raquo
(31 A) 120-13-2 l^ictiloropix)l ^7tB) JII-01-
(3 A) |03-7-raquo 21^-dimeThvlphenol (77B) 20t-raquot-l
(J7A) tl-73-3 2- rutropwnol (71 B) 120-12-7
(MA) 100-02-7 -MO-opwnol lt7raquoB) lraquol-2-2
fJraquoA) 3I-2J-3 2-dinitrop^laquoTgtoI ((OB) U-7J7
(laquogtA) J34-37-1 lt-dinitrfr-2-methylpwrxgtl (I IB) I 3-0 1-1 (raquoAI 17-1 3 pcmacMcroptonol (S2B) J3-70-J UJA) IOI-raquo5-2 phenol (IJB) MJ-39-J
(tBgt 12raquo-00-0 RASEfZUTRAL COMPOUNDS
( IB) 13-32-f raquocertaprithene
(3B) J2-17-3 twnndinc (2V) 107J2-J (IB) 170-I2- lr2k-triOilorobenzerlaquo (3V) 107-13-1 (raquoB) I11-7I-I hei bulllt1 ore blaquont ergtlaquo (raquoV) 7l-3-2 (1B) 47-72-I he ucft 1 or oe t h n (tV) 3-23-3 (116) |II_wJ bu(2-ctiIarothvI)laquotNer (7V) 101-90-7
(20B) raquoI-JI7 2 -cW or orvraquo ph tf I ene (10V) I07-Ofc-2 (23B) J3-30-I l2-lt5ictiloroblaquonzeoe (11V) 71-3J- (245) 3I-7J-I 13-dic^lorotxenzenc (13V) 7J-3-3 (27B) 104-K-7 1 mdash diC^lorobtnrerve ( lraquoV) 7^-OO-5 (21 B) raquo|raquo| 33^icftlorobenzidifv (I3V) rgt-j-3 (33B) I 2 I - U - 2 2ltgt-dinin-o1olvraquorgte (UV1 75-00-3
(J4B) 404-JO-2 21-dinitrotoluerve (1raquoV) 110-73-1
(37B) I22-W7 1 2 -d ipheny Ihydra z ine (23V) C7-14-3
(318) 2O4-W-0 tJuortnihrne lt29V) 75-3J- (kOBt 700J-77-J ^-tfMoropheTgtyl p^enyl ether (30V) 1J4-W-3
( raquo I B ) IOI03-J raquo-6romopfgtenyl phenyl ether (32V) 7I-I7-J
(06) 3H3raquo-)2-raquo bU (2-tfilerobopropyO ether (3)V) 10041-02-i
(OB) lll|| bii (2-cMoroethoxv) methane 10041-01-03
(37B) PUt) hxzraquocMorobutadienlaquo (J1V) 100-raquol-raquo
(JJB) T7^7U heztctilarocrclotMnttdicrgte (V) 7gt-0raquo-2 OB) 7l-3raquo-l BO ph or one (raquo3V) 7raquo-17-J
(338) raquo|20-3 rlaquopritrilaquolene (UV) raquo-laquo-raquo
(3iBl n-raquo3) nitrobenzene (raquo7V) 75-23-2
(CB) li-X)-t N -n i tr o tod ipheny U mi nr (UV) 73-27-fc
(06) CI-U7 N^iitroiodipropYUmlr ^raquo1V) 73-H-fc (UB) 117JI-7 bu (2-ethYlNerrl)pM^Utr 12000 (JOV) 75-71-1 (47 B) L3-U7 llaquoniyl buryl pht^UTe 2 800 ( 3 I V ) 2laquo-raquo-I (UB) raquo-7i2 di-o-ourvl pritfwiUrr (I3V) 127-lt-i (196) 117-14 3 dj-n-ocryl pritfiiUrr (UV) IOUIS-3
(TCB) J4-W-2 djnhYl phtfalitt (17V) 7t-01-lt (716 ) 1 3 1 - 1 1 ) damnhYl pMtuUTT (UV) 73-01- (77 Bl 3 33-3 frlaquon z olt raquo klaquom h rraquo c prgte
Cadmium T^ Chromiurn T Z T N C 100
Client ID 8A-C64221
BASENEUTRAL COtPOUNOS
bnzo(t)pyrrrie
benzobXluoriflthei blaquorizoltVHluorraquontrraquone
chryiene
bullcenphthylene
tnthneene
benzoltRM)perylene
fluorene
prienlaquonthcTTgte ditgtmplusmnolt4hluithrraquoctnf
indenof 1 23-cd)pvrf ne
pyrer
VOUATILES
bullcrolein raquocrvlonnrile benzene cmrbort Tetrichloride
chlorobenieoe 1 2-oUchloroethirie
11 1 -tricolor oethne ll-dvchlorolaquollMr 1 1 2-w icMoroethAoe l122-tetrieMoroeihilaquonlaquo
chloroetKvne JltJilorothvlvmv| ethe chloroform
11-dicMoroethent
trani- 1 2 -dicti lorolt t hene
1 J^JictiloroproBfVf
trim- 1 3-4ietiloroproperie
Cil-IJ-dicMoropfoOerie
rrhyUxrmene
methylene criloride
chlorornethine
bromome thne
007
13
tluorotr l^VoromlaquotNraquorgtt
da ch lor od 1 1 1 ooro frvet hraquone
chlorodibromometlvinf
te trraquocnloroeT rrrr
tricMoroetSmr
All results are expressed as us2 weight as receixred No entrv denotes not detect i
Phys ica l descr ip t ion of sample
SoilCake
Sample workup
vol i t i le fract ion ^FP FvfrarfMnn (ltU Rif i mdash Smrn
Semivolatile fraction Soxhlet Extraction (SW 846-3540^ Inorganic fraction Acid Digestion (SW 846-1050)
AC23 COMPOUNDS
rrt CAS CAS
(21 A) 11-04-2 2raquo4- trieMorophenol (738) 50mdash 3-4
122 A) J1-30-7 p-ctil or raquo-nvltrlaquo laquoo 1 (7laquoB) 205-11-2
12 A) 13-37-4 2- etilorophenol (75B) 207-01-1
(31 A) 120-13-2 2raquo-diclorophlaquoTgtol (74B) 211-01-1
(34A) 103-471 24-dmlaquothylphrnol (77 B) 201-14-4
(57 A) U-73-3 2- rutrop^nol (7raquoB) 120-12-7
(54 A) 100 -02-7 bull i tro p^c 01 (71B) 111-24-2
(J9M 31213 Z o trt i tr o poc^oI (MB) U-73-7
(40 A) 334-32-1 T^Hjinitrfr2^rt^T ny tp^gt^noi ( t lB) 13^)1-4
(44A) 17-44-3 pcnttchlaroprwnol (S2B) 33-70-3ltOA) IOt-IJ-2 pTUfNOl (136) 113-31-3
ftASENtUTRAL COMPOUNDS (MB) 121-00-0
(IB)
(56) 12-473 Iwnndine (2V) 107-02-1(IB) I20-IJ-I 1 2 4-tr icJi lorobeniervr (3V) 107-13-1(IB) 11 1-711 hexkcMarobcnzeM (4V) 71-43-2(126) 47-72-1 hexch)eroeihlaquone (4V) 54-23-J( I I S ) 111-4- bu(2-eMorlaquothv|)laquothr (7V) 101-10-7
(208) 11-51-7 2-c^laronraquophtfgtlene (IOV) 107-04-2(23B) 1J-30-I 1 2-dichloroblaquonime (11V) 71-35-4(2651 341-73-1 gt3-ltiictitaroblaquonxcnc (13V) 73-54-3
(27 B) 104-47 l4-dicMorotKmrerlaquo (14V) 71-OO-3
(21 Bgt 11-14) 33-4ichlaroblaquon2idine (15V) 71-34-3
(338) 121-14-2 24-dinitrotoluene (14V1 73-OO-3(J4Bgt 4O4-20-2 24-dinitretoluenc (11V) 110-73-4(37B) 122-447 lraquo2-dip^nylhydrraquoxirlaquo (23V) 47-44-)(MB) ro--0 Uuaranthene (21V) 73-33-4(406) 7003-72-3 4-ltUorepfraquonyl phenvl rtSer (30V) IH-40-J( raquo I 6 ) 101-333 4-6romoprlaquonyl pflaquony| ether (32V) 71-17-3
(OB) 3H3I-J21 bll (2-cti|orobopfrgtpyO ether (33V) 10041-02-4
(OB) I11-1I-I bis (2-cMaroethoxv) methane 10041-0103
(57B) P-44-) hczw^lorobundiene (J4V) 100-41-4
(JJ6I 77-47-4 htTicMarocyclojxrtadien (44 V) 75-01-2
(346) 71-31-1 aophoroo ( raquo ) V ) 74-47-3
(33B) raquo|203 r^pn thA Icr^ (44V) 7 -raquobull J-
(546) n-i3) H i frovCftZfl^^ (raquo7V) 73-23-2
142B) 14-30-4 S -n i tr o laquood ipheny Lt mi nc (44V) 73-27-4
(43 B) 421-447 N^iitrotodtpropyUmlne (41V) 73-41-4(MB) 117-41-7 bu (2-raquoThylhlaquolaquoyl)pMtgtlaquoUtr 52000 (30V) 73-71-4(4B ) 13-447 (xniyl bviryl ptithiUre 6700 (3 lV) 12raquo-l-l(UB) 147U- di-n-burvl pMhUre (I3V) 127-11-4laquoampgt 117-4J-0 ltjj-n-octyl phtfaUtr (UV) 101-11-)
(7CB) U-44-2 djrthyl pht)raquolraquort ( I7V) 71-01-4( 7 I B I 131-11 ) dimrthyl phttgtUTe (UV) 73-01-
(T76) H-33O tgtnzoUtlaquoftthncmr
Cadmium l i r^ Chromiurn 2 0 ZINC 140
All results are expressed as ugg weight as received
Lab ID No 2887-6
Cl ien t I D 8AD64219
Dd20( amp py(re
blaquonio(bHluorraquoflthegtlaquo
berzo(Mf luorampnThene
chryraquoefgte
ftctnAoMhy(ergte
raquonthncene
benioltK(M)plaquovlene
(Juorene
picnintfirtTX
dihwvioltraquoh)laquonThrraquocene
mdeno(l23-rt)pvrraquone
pyrene
raquocrolein
raquocrvloourUf
benzene
carbon laquoTrraquochlofifle
chlorobenieo
l24JcMarolaquotlxine
lll-trichlcroltthlaquorlaquo
-ltJicMorigtnKraquorgtlaquo
l12-trichlorolaquot^nlt
1 1 22-tetrcftloroetrvtnlaquo
^tloroeThAne
2^^1orolaquothvlvuiivt ethe
etila-oform
ll^liailoroltN^
trtni-12-dichlcxolaquoTfgtene
12-ditfiloropropine
trtni-l3-ltjicti|orocltX)t^f
cu-l3-djcMoroprooe^f
rttiylbtnztTve
methvlene cWoride
ciloromnM^f
Dco^^oroct^A^^
bromofarm
bromodicJiloromltlfraquon
tluorotrlctiloromttNir
diOilorodKloororfvrir^Ar
ct^lorodraquobrofTorrgttKAne
wtricnlorampctNrr
toluene
trirfilorolaquoThfif
v i n v CMor ilt3^
No-entry denotes not detect
ih i n N O 2887-9
Phys ica l d-asc r ip t ion of sample Cl ient ID 10A64222
Linnir l ShtHcp
Sample workup Volitile f rac t ion PEG Extraction (SW 846-^030^ Semivolatile fract ion Sonication Extraction (SW 846-3-540 Inorganic f ract ion Acid Digestion (SW 846-3050)
AOD COM POUNDS BAStNELTTRAL CXLPCXJNDS
rrt CAS CAS
(21 AJ U-Ot-7 Z4- trichloropSeno (73B) 30-J2-
(22 A) 55-30-7 p-ctilarraquo-m-erelaquoo1 (7kB) 205-raquoraquo-2 ben r olt b) 1 uor ifl t Ne~gtf
(2AJ raquo3-37-i 2- ctilorophenol (75B) 207-0raquoraquo benzoltllt)floofraquontslaquor
(31A) 120-13-2 2raquo-ltJictilcroooenol (76) 211-01 9 ctiryjene
(3A) I03-47- 2k-dimethylphenol (77 B) 20t-raquo4-i bullceruphthv lerraquoe
(37A) U-73-3 Zmdash Ajtropheooi (7SB) 120-12-7 fcntftricene
(34 A) 100-02-7 w^ i ff o phe rgto 1 (7raquoB) Iraquol-2-2 ben z o( Rh i )per v 1 me
(31A1 51-21-3 Z^ - d iA iV opheno1 (SOB) U-7J-7 Iluorene
(MA) 3X-37-I T v-4iAiv omdash laquo mdash fl^et ny Ipoenoi (I1B) 13-01-1 poeftraquonthrene
(4 Al 17-14-5 p^ntBCfllGrOprlC 1 Vol |I2B) 33-70-3 dilgtenioltraquoh)laquontwraquocenr
USA) IOl-raquo5-2 phenol (13fi) U3-31-3 indeno(l73-cd)oraquorrie
(MB) I2raquo-OO-0 pyrene RASENCimiAL COMPOUNDS
VCH-ATUL5 ( I B ) 13-32- raquoclaquonraquophtflaquorgte
(58) 12-I7-J benzidire (2V) 107-02-1 bullcrolem
(IB) 120-J7-I 1 2k-tr icnlorobenzene (3V) 107-13-1 acrvlonitr UP
(IB) 11U7I-I heKicMorobtnzme (raquoV) 7I-A3-2 benzene
(176) 4772-1 hexcftla-oethtgte (4V) J4-23-5 campr~toon TeTrscftlo itit
(116) III-- bii(2-lttilorolaquothv iVether (7V) lOt-W-7 chlocobenieo
(2C5gt raquol-3l-7 2-cM oroolaquo ptittu lene (10V) I07-O4-2 1 2-dicrtloreetranr
(23B) raquo5-30-l 12-dichlarobenime ( 1 I V ) 71-33-4 11 1 -tricMoroethr
(24 B) 31-73-1 1 3-ltl icJgt lor obcn i ene (13V) 73-3^-3 1 1 -dicMoroeth^i
(27B) 104-^4-7 1 4-dich lorobenzergte ( t k V ) n-00-3 11 2-tncfiloroetvlaquorie
(215) 91901 33-didMoroblaquozidinr (I3V) rraquo-3k-3 l122-tetrraquoOMo-oethne
(335) 121-I-2 2-dinitrotoluergte (ItV) 73JW-3 chloroethjin
(3461 (0420-2 24-dinitrotoluene (19V) 110-73-1 2-cMoroethraquo|vuiv| trgteshy
(37 B1 122-44-7 12-diphenylhydrnine (23V) 47-44-3 ctiloroform
(316) 204- Jgt tluarmrnhene lt2V) 73-35-4 1 1 -^iCMoroeThe^f
(C6) 7003-77-3 -chlorophenyl poenyl ether (gtOV) 154-40-5 trraquonraquo-l2-dicrloroltthene
(bull16) 101-35-3 raquo-6romophenyl phenyl ether (32V) 7I-I7-3 l2^ipoundMoroproBirgte
(raquo26) 3H3I-32- bit (2-cMarobopropvt) ether (33V) 1 004 1-02 -4 trmni-l^-dictilwoproom
(OB) l l l - raquo l - l bis (2-cMeroethoxv) methane 1004 1-0 1-05 cu-13-laquoicMoroprooe^e
(J2BI D-U-3 rraquolaquoeftlorobutraquodilaquooe (JJV) IOOJM- rttylbenzene
(336) 77 -raquo7- hezactilarocyclooentadiene (WV) 75-OT-2 methylene cniorifle
(56) 7raquo-3raquo-l ao ph or one (raquo5V) 7raquoJ7-3 eMoromeirune
(33B) JI-20-3 nraquophtMlene (UV) 7raquoJ3-raquo bromomethAftf
1X6) n-raquov) nitrobtnxerw (raquo7V) 7J-25-2
(CB1 14-30-4 J -ltii TT o vxJ ipheny U rru rraquo ^UV) 75-27- bro mod i cfilor o me t r)e
(CB) 47I-U-7 N-nnrotodipropylraquomJne (tV) 75-4raquo- 11 uor o tr i cMor o me t htgte (US) V17-1I-7 bu (2-eifrrlhryl)praquogtttilaquoUMshy 69 000 (30V) 75-71-1 di cti tor odl1 1 van m^i rajgtr
(476) U-U-7 benzyl buryl phihiUte 890 (31V) 12laquo-kraquo-l cMorodbremof^etNrr (US) U-7I-2 di-n-burvl prittuUre (13V) 127-lt- Uraquo6gt 117-t-0 dJ-laquo-ocTvl phttviUre (UV) IOLtS-3 Wluenr
(75) u-w djrrhylphtnltt ( i rv) 71-01-4
(715) t J I - l l - 3 dimnhrl pfthUte (UVI 73-01- viny l CMcriOr
(779) J4-35-3 0laquoMo(UnthrraquoCflaquoe
C a d m i u m 130 Chromium 20 ZINC 170
o nnn Z-UUU
^0(^ Trace
All results are expressed as ugg weight as received No en
APPENDIX E
PLATES
I I I I I I I I I i Plate 10-1 Troy Mills Landfill with a backhoe excavation
in progress in a former drum burial area
I I I
I I I I I I I I
I I Plate 20-1 NAI field investigation team preparing for
Level B activities during the drum excavation task Troy Mills Landfill
I I I
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
I I I I I I I I
I I Plate 20-3 NAI field investigation team member undergoing
personal decontamination at the hot line Troy Mills Landfill
I 1 I
I I I I I I
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
1
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
I
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
I I I
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
I I I I I I I I I I I 1 I Plate 53-3 Pigmentsludge deposits interbedded with
soil layers in Excavation 8A Troy Mills
I Landfill
1
FIGURES
PAGE
30-1 Delineated area of magnetic source material Troy Mills Landfill Troy New Hampshire
62-1 Ground water elevation Troy Mills Landfill and vicinity Troy New Hampshire 33
TABLES
41-1 Randomly selected excavation sites
52-1 Drum log for excavations on November 17 21 and 23 1983 12
52-2 Contents and condition of excavated drums 15
53-1 Sample log for waste samples obtained on November 17 21 and 23 1983 17
53-2 Summary of analytical results for waste samples obtained on November 17 21 and 23 1983 19
61-1 Analyses of Water Samples Collected from Monitor Well Ml 23
61-2 Analyses of Water Samples Collected from Monitor Well M2 24
61-3 Analyses of Water Samples Collected from Monitor Well M3 25
61-4 Analyses of Water Samples Collected from Monitor Well M4 26
61-5 Analyses of Water Samples Collected from Monitor Well M5 (upgradient well) 27
61-6 Analyses of Water Samples Collected from Monitor Well M6 28
iii
61-7 Analyses of Water Samples Collected from Monitor Well M7 29
61-8 Analyses of Water Samples Collected from Surface Water Station A (leachate seep) 30
61-9 Analyses of Water Samples Collected from Surface Water Station B (upstream) 31
61-10 Analyses of Water Samples Collected from Surface Water Station C (downstream) 32
64-1 Physical properties of phthalate esters 35
64-2 Physical properties of ethylbenzene and toluene 39
iv
ABBREVIATIONS AND SYMBOLS
EBP benzyl butyl phthalate degC degrees Celsius Ca circa D volume occupied by one drum DEHP di (2-ethylhexyl) phthalate DOP di-n-octyl phthalate E east eg exempli gratia (for example) EPA US Environmental Protection Agency HNU HNU Systems Inc photo-ionization detector LEL lower explosive limit LPP level of personnel protection MCL maximum contaminant level mg1 milligrams per liter ug1 micrograms per liter MSA Mine Safety Appliances Inc N north also number of steel drums NAI Normandeau Associates Inc OS over sample OVA Foxboro Century Organic Vapor Analyzer P estimated packing density of drums PPM parts per million RAI Resource Analysts Inc RCRA Resource Conservation and Recovery Act S south SCBA Self contained breathing apparatus SNARL EPA suggested no adverse response level T trace Troy Troy Mills Inc TVO total volatile organics V estimated volume of drum burial area VOC volatile organic compounds W west gt greater than lt less than
PLATES
Plate 10-1 Troy Mills Landfill with a backhoe excavation in progress in a former drum burial area
Plate 20-1 NAI field investigation team preparing for Level B activities during the drum excavation task Troy Mills Landfill
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
Plate 20-3 NAI field investigation team member undergoing personal decontamination at the hot line Troy Mills Landfill
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
Plate 53-3 Pigmentsludge deposits interbedded with soil layers in Excavation 8A Troy Mills Landfill
VI
10 INTRODUCTION
As a part of a phased program to investigate potential ground
and surface water contamination associated with the Troy Mills Inc
landfill Normandeau Associates Inc (NAI) has completed a waste
characterization at portions of the landfill that were formerly used for
the disposal of steel drums containing wastes (See Plate 10-1 for site
overview) The objectives of this phase of study included
1 Delineation of the horizontal extent of the drum burial area
2 Estimate ofthe number of drums
3 Characterization of the physical condition of the drums
4 Assessment of the contents of the drums and
5 Assessment of potential for ground water contamination
6 Development of a remedial action plan for the site
The work involved developing and implementing an extensive
site safety program conducting a magnetometer survey digging a series
of test pits on randomly selected sites laboratory analyses of selected
samples of soil and waste and formulation of a remedial action plan for
the site
The Troy Mills landfill is roughly eight acres in total area
and divided into two main sections One section is currently being
operated as a solid waste (non-hazardous) disposal area for fabric
scraps and trimmings as well as other non-hazardous materials such as
wood and broken tools The solid waste landfill covers about six acres
of the site An estimated three acres presently contain deposits of
solid waste and about three acres are being prepared for future
disposal A closed former steel drum burial area is the second section
occupying about two acres of the site The drum burial area is now
covered with soil and a light cover crop of grasses The drum burial
area received wastes between 1968 and 1978 The disposed drums are
reported to have contained various materials including waste
plasticisers pigments and organic solvents
Previous site investigations by NAI have included site
reconnaissance studies test pitting water quality analyses (NAI report
of August 12 1981) geophysical (seismic refraction and electrical
resistivity) investigations (NAI report of December 1981) installation
of a ground water monitoring system (4 wells) and sampling and analyses
of ground and surface water samples (NAI report of July 1982) A water
budget analysis was performed to assess the leachate generation
potential of the site (NAI report of September 1982) Concurrent with
the study of the drum burial area additional seismic refraction lines
were conducted and three additional ground water monitoring wells were
installed to further assess leachates from the solid waste
(non-hazardous) portion of the site
Laboratory Analyses were conducted by Resource Analysts Inc
(RAI) We also wish to acknowledge the assistance and cooperation
provided by the management and personnel of Troy Mills especially
Messrs Barrett Ripley and Carl Patten
20 SAFETY PLAN
A Bureau of Hazardous Waste approved safety plan for on-site
activities was developed for the waste characterization phase of work
because of the potential for encountering hazardous materials The
safety plan is presented in Appendix A of this report It assesses the
overall degree of hazard identifies specific potential hazardous
situations and presents guidelines for personnel protection and action
levels as required The plan was made available to all field personnel
during the field work
The magnetic and topographic surveys were considered to be low
hazard activities with a prescribed level of personnel protection (LPP)
of C or D depending on the results of air monitoring Level C proshy
tection involves wearing a full face respirator with organic vapor dust
combo cartridge Tyvek suit over work clothes rubber safety boots and
gloves Level D protection requires cotton coveralls or other work
clothes safety shoes safety glasses and possibly a Tyvek suit
During the drum excavation and sampling task which was
determined to be moderately hazardous Level B protection was preshy
scribed Level B protection requires that personnel wear SCBA (self
contained breathing apparatus) chemical resistance Tyvek suit steel-
toed rubber boots and gloves Plate 20-1 shows NAI personnel on the
site preparing for Level B activities Plates 20-2 and 20-3 show
personnel decontamination equipment and the hot line during the drum
excavation task
30 MAGNETIC SURVEY
To delineate the landfill area underlain by steel drums a
high resolution magnetic investigation was conducted by John F Kick
PhD consulting geophysicist The magnetic method was chosen over
other search methods because ferromagnetic substances (drums) were the
target objects and the majority of Troy Mills other wastes are
non-magnetic (largely fabric scraps) Dr Kicks report is presented in
Appendix C
Eighteen parallel rows of magnetic field measurements were
made along north-south lines The measurements were made at 10-foot
intervals along the rows This work resulted in a detailed contour plot
of the magnetic anomaly (Figure 1 in Appendix C) The source materials
which cause the magnetic anomalies do not usually directly underlie the
peak of the anomaly A shift is caused by the inclination of the
earths magnetic field and by dipolar effects Figure 30-1 shows NAls
delineation of probable source areas for the magnetic anomaly and
peripheral areas which may contain some magnetic source material The
plotted source area is generally the area between the peak of the
magnetic anomaly northward to the zero anomaly contour This is to
compensate for a southward shift of the peak of the magnetic anomaly
from the center of the source deposit The complex geometry of the
anomaly necessitated much interpolation between peaks and ridges
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40 TEST PIT EXCAVATION
41 WORK PLAN
A series of test pits were excavated in the Troy landfill for
observation and sampling More specifically the purpose of the
excavation was to estimate the number and distribution of drums buried
in the landfill determine the condition of the drums (full empty
crushed rusted leaking etc) identify types of buried and drummed
waste and verify the results of the magnetometer survey A stratified
random sampling method was used to choose 10 locations within the
delineated area of magnetic source material This insured that
excavations were distributed randomly across the landfill and that the
resulting data could be evaluated with a level of statistical
reliability Excavations were also selected in areas on either side of
the anomaly which were considered free of buried magnetic material and
also where drums were visible at the landfill surface
The following procedure was used in choosing the locations for
the random excavations The center of the delineated area of magnetic
source material was used as a base line The base line was drawn onto a
map of the source material (Figure 30-1) and then divided into ten
60-foot long segments Using a random numbers table a point-distance
was located on each segment (designated the random station) and a
line drawn at that point perpendicular to the base line segment Again
using a random numbers table a point-distance (designated the random
offset) measured along the perpendicular line located the point of
excavation The grid coordinates for each excavation were graphically
determined from the grid overlay and then field-located from the
surveyed grid intersections Grid coordinates and selection data are
presented in Table 41-1
It was judged that 10 excavations in the delineated area of
magnetic source material and two excavations out of the area would be
sufficient to characterize the site would produce statistically valid
TABLE 41-1 RANDOMLY SELECTED EXCAVATION SITES TROY MILLS LANDFILL TROY NEW HAMPSHIRE
BASELINE RANDOM RANDOM EXCAVATION GRID SEGMENT STATION OFFSET
NUMBER COORDINATE (FEET) fFEET) (FEET)
1 7E+15 65N 0-60 26 16
2 9E+5 13S 60-120 110 9
3 8E+0 31S 120-180 140 7
4 4E+5 48S 180-240 230 26
5 3E+8 45S 240-300 254 20
6 OE+8 45S 300-360 394 50
7 2W+15 24N 360-420 465 14
8 5W+6 42N 420-480 518 20
9 6V+14 74N 480-540 548 7
10 8W+5110N 540-600 611 31
Locations are plotted on Map in Figure 30-1
data and could be expected to be completed within a scheduled 2-3 day
work period
42 FIELD WORK
Test pit excavation was conducted in two phases On the first
day each of the 10 random locations (Excavation 1 through 10 Figure
30-1) was probed to a depth of 2 feet using hand shovels On the
second and third days excavation was conducted using a combination of
hand shovelling and power backhoe The NAI field investigation team
consisted of six members Four of the team members were equipped to
work at Level B for work in and near the actual test pit excavation
(See Plate 42-1) The other two team members spent much of their time
with personnel and equipment decontamination and refilling compressed
air bottles at the hot line Mr Timothy W Drew an engineer of the
New Hampshire Bureau of Hazardous Waste Management was present during
most probing and excavation work Mr Robert Lynch an experienced
Level B equipment operator of Jet-Line Services Inc operated a power
backhoe which was provided by Troy Mills Inc
An average excavation size using the backhoe was approximately
7-feet wide and 10-feet long Excavation continued downward until drums
were encountered or to a minimum depth of five feet Drums were careshy
fully uncovered and fully described A total of 17 samples were
obtained from uncontainerized wastes (solids dried sludges pigments
stained soil) and where possible from drums using EPA sampling methods
and protocols All of the excavations were backfilled upon completion
of this task
Each sample consisted of one filled 8-ounce glass jar sealed
with a Teflon-lined lid Samples were submitted to Resource Analysts
Inc (RAI) Laboratory in Hampton Falls NH for priority pollutant
analysis
Air monitoring was conducted during each excavation using a
Foxboro Century Flame lonization Organic Vapor Analyzer (OVA) an HNU
Systems photo-ionization detector (HNU) and an MSA combined oxygen and
explosimeter High explosimeter measurements were considered cause for
an immediate halt in exploratory work in the interest of personnel
safety
10
50 RESULTS
51 GENERAL
On November 17 1983 Excavations 1 through 10 were initiated
using hand shovels to a depth of approximately two feet A total of
two buried drums were discovered Excavation 13 was completed and a
third partially buried drum uncovered On November 21 1983
Excavations 1 through 9 were completed and on November 23 1983
Excavations 7A 8A 10 11 12 and 14 were completed An additional
42 drums were uncovered on the last two days of excavation
Excavation Locations Seventeen test pit excavations were
completed at locations which are shown on Figure 30-1 Two pits were
excavated at three of the locations Noteworthy aspects of the
excavation operation are
Excavations 1 through 10 were randomly located in the area of delineated magnetic source material (on-anomaly)
One excavation connected Excavations 4 and 5 This was done because of the proximity of Excavations 4 and 5
Excavation 7A was located immediately adjacent to Excavation 7 Excavation 7 was located on the boundary line of the anomaly and proceeded in a southerly direction off the area of delineated magnetic source material (off-anomaly) Excavation 7A was initiated in the opposite direction (north on-anomaly)
Excavation 8A was initiated one foot north of Excavation 8 after the latter was abandoned due to the detection of a potentially explosive drum
Excavations 11 and 12 were selected off-anomaly to the north and south (respectively) in areas considered to be free of buried magnetic material (drums)
Excavation 13 involved minor hand shovelling necessary to uncover a partially buried drum located on the periphery of the anomaly at the east end of the landfill
11
Excavation 14 was a surface scrape which extended from an exposed drum found to the south of the magnetic anomaly northward toward the anomaly
The details of each excavation are presented in Table 52-1
Drum Locations The excavation results support the
interpretation of the magnetometer survey with buried drums as the
source of the magnetic anomaly With the exception of a few strands of
wire found in Excavation 1 ferromagnetic materials other than drums
were not encountered during the test pit excavations
Drums were foundin 9 of the 10 excavations located in the
area of delineated magnetic source material (See Plate 51-1) No drums
were found in Excavations 11 and 12 located out of the area of
delineated magnetic source materials The location point for Excavation
7 was on the boundary of the anomaly Excavation 7 which proceeded
south away from the area of source materials was free of drums
Excavation 7A proceeding north toward the area of magnetic source
materials uncovered 6 drums Excavation 14 located just out of the
delineated area to the south produced unexpected results Five drums
were uncovered just under the surface in an area with low positive to
slightly negative total magnetic field values It is possible that
Excavation 14 was improperly located in the field If adjusted just 20
feet to the east it would be well into the delineated area It is also
possible that a negative dipole derived from the mass of material to the
southeast is cancelling positive readings at this location
Fill Material and Vegetation Cover and fill material was
predominantly fine to medium sand with an occasional boulder Till with
a siltclay component was also used as a cover particularly at
Excavations 6 and 7A This material was densely compacted and difficult
to dig through Excavations 7 11 and 12 each extending to a minimum
depth of 5 feet were characterized by uniform silt and fine to medium
sand and traces of dark discoloration Excavation 12 was located in
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mdash c-Omdash
^
^V f-
mdash U
fc ^ aa L 1_ ou C- C
1
w
0
X L
raquo( CC-mdash
LJ
O
lA
_
0 1
^v U
Oi
laquo-O n
mdash
Z o to
ltr s _3 OK
CVJ CM ro
raquo~
j CM VO
ro bull-CM
ro 1 VO laquomdash
z o
r-Q
I C
o X UJ
poundo| s~a
a CM CVI CVJ fO lA CM 1 lA lt-
a o
o mdash LJ o raquomdash L
lt ^^ gt lt UJ C N X mdash _ in
o X o X CO
f)XCOXr-
X CM
bull-X ot^
ro X ^y X O rmdash
rXlAXOv
CM X
00 X
CM V
ro X ~
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lAX roX o
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o
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lt 5 rmdash fl ro ^ -~
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lt gt- CO
X
0 O
13
E
23
eo ETC CU
gt i- Nlt (_ mdash
E O i-
lt~o ON dgt
N Q) mdash
i-tt) gtOO
bullDC
gt 0) C
T3 O
-D C CD
tgt
-U mdash mdash
C5
E 33
E-0 gtgts-O CD mdash T3 1- N JO ( =
0 0 U - O C5 t- t-ushy ro L jj bull
3 C 0 gtgt cnmdash 4J mdash
bullD CD bull C E E
I t -
lt Q 0)eo i c
lt mdash
mdash L
aagt E C CO mdash
CO i-W CO
bull obullDmdash 0
gtgt mdash
re bull E bulllt-gt
gtgt mdash
CD bull E-0
L W O lt tu en i-fgt c O Q
gtgt0 3 O mdash 4-gt i C
CD X -o eo E 0
w co CD bullO 4J COmdash ^ C d)CO O ^E 1 O W
co eo 4J bull
bull C CU ^ O ^
C O W
c eo Qeo mdash eo
t-JJ 0 E
o mdash c mdash
eo w
D C c eo CD laquo)
CO T3 0 4J Q) - C 0 mdash CO gt mdash E O w mdash
O 01shyC CU O O CD aw
CD O CO u- sshy amdash
re lt c eo cc c CD mdash CD 1- ltshy C C_ C re c co o - O X X CO CO3 gt CO 3 gt to E O O co O co CO 3 jt w O cfl 0) eo
cr LJ
LJ-J u mdash j CO 0amp5
a O 1 O
Q
1 1 i l
CD Dl bulla
CO _ mdash O D o
O ^ (A
ZX mdash Ld
O
en 3 10 O a
LJa a
Q 1 1 O
Q
+
O
X
_
mdash
o o I
gtgt O
h~Z
-^ 3
o0
mdash i-
1A 1
a a co agt C
LJ
sectK
Z= tM O 0 to bullo
X
mdashshyo
CD O
o mdash _ o
E umdash 3 E eo sshy
ltr-toZmdash
mdash s
0shy c
^
^ gt o
D o
a-rmdash
1
Q-
0 0oo r-V
tO 0
= mdash
O
tO 0
= mdash
O
Q O
O r-i O NO
1
awi
i mdash _ 3
Imdash I O
bullO C
1- 3 gt 0) bullo sshy co w
bullO CJ ID O X E C CU tt) bullw^ T3
w agt u C pound -gt
a a CO CD
mdash L 4J CD o gt
T3 gt C CO UJtt
2 mdash1 LJ Z) d CO 1 1
COO
~
lt O
~ I 1 1 I
Dl C 10 3 -D
lt - T J O
Dl C
1gt Omdash O bulllaquo Xl- i s o cu
Q lt3 toz cshy
mdash W f
r-B O c
mdashgtgt3 01O O u
W ID CO bullgt C -O mdash 4-gt 4-gt C
O -x mdash1 CO o CU c c co
1
OZ ZO o mdash Ol-
LJ -
L
0
1
C- bull 14 u- o laquoc~
bull mdash u bullDT3 O laquoccce tshy ^ D
l_ Cshy CCO O 0 0-0 Qmdash
CJ I- r-CM
1 1
U-Qshy
bull bullbull ^
O t_ 0 Q
-LJ
raquol
a o iT o c o
U) c
c u CD O
I I I CU c
Q) CJ CU W a ltshyon J2 o l- E E gt QCO CD O
I I I
ID JJ CU ES
J-gt imdash O Q Z CO w t --shy O mdash O 3 O laquoshy ^ c
_ICO a 0 0 0
^ sect5oa I-Q
CO X u_ y o- o=gtLJt-a
3shy
^
1
1
VO
m
1
i
1
t
_
3 lta i- U) 0 0
a
lA
lAbull
0 O
JI E oj3 gt E re mdash O X X co Qj
C 1 O
W 3
U L CO O
4J CO
0mdash CCD gt j ti --shy c JJ 4J
1- laquo 3 = C 3 or cu ogt tn Q -shy
E L n CD J-gt o o gt gt s o ---shyDior 3 3
mdash Tgt o cr cr mdash mdash CU 0)
o a CD -a OLJ U CU
N CU COT 4JT3 poundmdash 0gt U V
raquoT3 mdash agt OJ gtgtcu laquo c c
T3 O
C
C
Zlshyo ui u- Li ^ ^~bullgt lt LJ
lAXvOX
VO X ^ X
Xcjltshy
lA x
CM
O x
3shy
_ X
r^5 X
_ X
CM X
mdash c^ C3 O
c a bullbull o c c
mdash 4J O I I 4J
01 JJ 4J 1C laquo
3 t- C raquoJ O L (D CU C mdash o a~o mdash o
i i
C J J W CO II) O W IT OC N 03 = OJJ C O I- -= C O
I I
o o
ON X mdash
CMr-raquo
00 Orshy
X CO
vo ro O C 5) JJ Jshy I- I gtJZ-00 s a o
LJ CO eo UTJ a- I I O C X J O gtZ 1 re O
i CM
LA
LJ
O mdash c imdash LJ lt a gt y lt 2
ltCO O
O^mdash
laquoshy rmdash
CM Tmdash
n rmdash
_^jshymdash CO
LJ
j ^ |
52
14
what appeared to be natural materials although its location on the
cleared and leveled landfill tend to contradict this possibility
Most of the landfill is vegetated by a thin layer of grasses
sedges mosses and annual herbaceous species The northeast corner of
the landfill is unvegetated and cover material appears to have been more
recently applied This section is elevated 4 to 6 feet above the rest
of the landfill and appears to have received a second newer layer of
waste A 4-foot thick layer of carpet waste was encountered in
Excavation 1 but not in other excavations This section is adjacent to
the newer active landfill The landfill area just west of the access
road crossing (near Excavations 7A 8 and 8A) was also unvegetated due
to relatively recent grading operations
Ground Water The landfill appears well drained as ground
water was not encountered during any of the excavations Excavated
overburden was damp from the recent heavy rain but intergranular macro
pore spaces were free of water
OBSERVED QUANTITY AND CHARACTER OF DRUMS
A total of 45 drums were observed buried in the landfill
Table 52-1 presents a drum log describing each excavation and the
observed drums Data on the contents and condition of drums is
summarized in Table 52-2
Of the total drums observed 15 (33) were crushed flat
Although these could possibly still contain small amounts of waste they
are probably considered empty under RCRA guidelines Thirty (67) of
the total drums discovered were uncrushed and capable of containing
waste Seven (88) of the 8 drums sampled contained liquid or sludge
waste material Thus at least 7 (23) of the uncrushed drums contained
some liquid or sludge waste
15
en C Cl
bullo gtraquormdash
c mdash a
o c re bull mdash c
~ o mdashbull 4Jmdash
10 0 mdash
gt O
ro CO
fcshy0
c
C
vgt 3 0
1 rea
-gt
mdash
3 o T3
lt-O
C j C
CB 3 TJ ii i- 3 mdashQCOa
ifl u bull c c
t_ o
mdash shyO
mdash
L re N
co
t-O
mdash
mdash lfl
V) O
CO N CO pound re
0 mdash
^1 10
ltP O C raquo
CM reO
o f shyi O
mdash mdash 3 - D
c 1
CD bulllaquo
mdash3
D mdash
1 C
Q CO
CD Ifl 4-gt CO
Q
CM
r-
Ul
Q Ul gt EC Ul CJ CO o t5bullpound
z O mdash
C Ci o^
O Cbulla 3v iC MW5 CO 4J3 u CS- Ifl CBC J C O - U
gt Cgt Omdash Oi O
U- 0) Ifl bullgt-gt 1 W C
to lt-gtT3 gtmdash
0) gt shyJ 0)
C OltJ bull O T 3 C D C P
133mdash 4J bull ifl tshy Vgt~ V a O V4JJ
C o
C mdash
O Ifl
3 fc 0)
i-
c
U) re gt
ai C mdash
C mdash
CO gt c o
bull to y 3 cc Q
ltbull-CB
1 4Jin
bullD reCD jCJJC TJCD mdashbullD bull mdash
CD 0t- u iflo ifl
0 C ^-
CB laquo
3 ltbull-
0)^shy
C
0 Cgt O
1 O CTl C
T3 1 mdash CB O
mdash CB mdash in J o 3 tfl C ^ CO 0 gtltgtshy
O gtgtc 01
CO 3 1- mdash C Cregtmdash laquo
TJ W TJ mdash i re traquo-
shyU mdash
O Q
COCO^^
mdash ^
mdash gt C 0gt mdashO ~ bull
Ul
o auO
CCUl
mdash K o tO Ul Q
mdash OT30Jj c mdash4Jt- Jpound O Wre c i re03 gt
lt~i- laquo o ai
0 ) 3 gt O ^crc Ifl - CO -^mdash
3 mdash Q iflmdash 1- O 3 3
O V O ltraquo-o laquoTJ
gt
T3 - o
gtgtmdash J-gtmdash
Dmdash
6-o
09 bull mdash gtpoundbulllt-gt
re a
Ul X t5
Cpound O Z
fl) mdash^ C B gttflOl3T3T3l_ 3 Q)O mdash mdash
tn mdash
shyD CB
mdash mdash
mdash tt
CO C T3 poundi mdash JCmdash re
^ C O C X CB ^ - S - C C O mdash re O Q DW4shy
re shyu O 1
O Ul X EC Ul mdash
x a^s ox
CO
^) Z
J
1-o t-Ul X r-u 0
o j c gt T3 i -gt c tu mdash c u r e mdash
- C D mdash T3 - C M mdashbullOJJQmdash re3inecrec u c r e o mdash lt~ bullz c~4J O CX t ^Jw o r e -gtgtOgtgtshy3 c j t shy re mdash mdash ret- i o Qmdash gtgtpoundgt a
i reraquo CD 0) bullbull Ifl t-
Q ) t ) O pound O ^ laquo gt - Ow re re ro re re -gt Q mdashc 5 shyu a j-gt D t- raquomdash mdashCB C re C CO 3Q mdash O mdash O U
Htshy ae cu coo)
1 O i i
shya shyo j CD C bullgt o mdash c o c o coco mdash plusmngt o ~a v c en CD
mdash C O
raquoCJ 3C c re amp- ogtCD J o 3 CC C I-Omdash 3gt O
3
O ro
Ul X 1mdash
u O
Ul o r-Z Ul
gtV~ omdash Dlshy ^mdash mdash wre3 i cc
mdash cr bull gtJJ mdash C mdashi QIgtJ^re a shyJQI- o 0mdash
O bullO 3laquo laquo
jjmdash ureoO mdash O N 0)rc3recomdash4Jt-4JpoundmdashC C mdashmdash mdash u
1
shya 0 -
mdash gtgt re-raquo-gt CUD laquo E CD
^ J-1
CJ eoc
4JCB CO
mdash O
C 1- C mdash O C B C B C E J mdash J ltshy shyo cn o o c o r e c shyU -gtO OJC D ifl roc
T3 3 I U 3 laquo-
Ifl CD 1 W ^J 4 J 4 J c -aiflj jc
CB C r e O C B lt-gt -Jgtcoraquo C C -WE O O ) ~ O O O mdash O
Ul O
c ui =gt z
o
1-CC Ul Q
Q z ^ Ul
2 gt Ul O
o Cpound
^ CO
Ul Q ^
z o
(O U S Q
Slt
t5 lt
Z5O
1mdash z ui
Qa Ul
CD 0-1
u m O_J
O2^ltUl
O CC Ul Q
VOCO
CNlA |3
VO ^
CJ |CO |
CJ CMI3 f~ rojO VO rolo
^
ymdash3 CC
roCM
ro O ICNj
ro rolvO ro ro
ro A
rolvO r-jO
00 C3N
ec a m
r3
CO
3 a ty r-
cc Q
(M CM
to z
m 3 c O
u _i co
U-O
O 3-IObull - I c y
fshy lt- ICO r- r-ICM O U lfN ro -mdashla1 f~ laquo- ]CO bull- -ICM O O J|O O
c U) CO
mdashbullre re
mdash re
mdash i ltC c tz
j lt
i lt
5 0 0 G O o o o o z bullU 4J J h- J shyJ tmdash tmdash
^33
J3 3
O 3
Q 3
_Cr(bull
shyC 3 t)
CC IP y
C2 zgt c J
1mdash O 5
53
16
The condition of the uncrushed drums was highly variable with
only 4 (13) rusted and decomposed to the point of structural weakness
These drums were found in Excavation 10 at the far west end of the
landfill which is believed to be the oldest section (See Plate 52-1)
Interestingly two almost new looking drums were also found in
Excavation 10 at a greater depth than the four rusted drums The
remaining 26 drums were observed to be generally intact and structurally
sound Some were dented partially crushed or rusty
CHARACTER OF WASTES
Air Monitoring An OVA and HNU were used to monitor the air
for concentrations of organic vapors during each excavation Above
background instrument readings indicative of contamination were
regularly recorded when monitoring the air just above or inside of
drums A general contamination of the ambient air in the workspace was
noted only during Excavation 8A where above background readings of +13
in the excavation pit and of +6 above the excavation pit were recorded
Explosimeter readings were obtained from three drums -- 10 lower
explosive limit (LEL) from drum sample 10A 20 LEL from drum sample 6B
and 100 LEL from a drum in Excavation 8 Instrument readings are
presented in Table 52-1 and Table 53-1
Visual Observations The following types of waste were
observed during the excavations
fabric waste (carpet waste)
crushed drums
drummed waste - liquid sludge and solid
uncontainerized dried sludges and pigments
stained soils
Fabric waste scraps of synthetic non-woven fabrics5 heavy
carpet-like fabric and backing material were found only in Excavation
17
CM
CO LJ fmdash O z
laquo 4J
u TO 4-gt
c bullmdash
k bull mdash E mdash 3 3 i-^ O
mdash TJ --raquo co co 4J
E CO O U L U
E 3 c T3
C O a o
is
CO c to 3
U
TO
E O t_ U_
o o
1 ltmdash c
mdash tmdash TO 4J bull C TO 0 O o c u 3 TO
t_ 0) 0 4J
U)
mdashOTOgt
Cw bull aco jc
N 4J a
mdash L Q) re co T E
CO
bullo gt egt mdash c mdash bull o ^^73 C E gtO O mdash 3 J-gtmdash N 4J L 3 mdash 1--C gttTC bull
CX 01C JJ TO O mdash
TO trt mdash t- E mdash 3 JJ a O Q
C I 0 X E mdash C mdash CO
mdash o laquo (D-O mdash O O bullbull B Ol o -cmdash e oic f~ to a (gt TD mdash
E 1- Cpoundmdash 3 O O CO P m T1
L u
T3 CO
lto sshy0 O CA W
laquoT3 O CO 0 C J= CO tlaquo Q bull 3 O Ol 1- C o mdash 3 E a
3 E E i- to
Z L
mdash bull mdash O 4-3 Cl Q
bullD 0) CO T5 N CO mdash C -P 1 0 U TO O mdash 4J Cfc
mdash U) c shybullgt O w C O Q (5 4J 0
3 -J bull U)
5 gt TO_ U
bull gt pound mdash 3 mdash L ro TD
JJ-D - CO TO laquo QO
C 0
^ 0) T3 mdash O
r to 3
O O L L
0
01 TO gt bull
tshy mdash OT3 mdash
CD O C N U) O mdash
TO O CO mdash C C
bull^ ~ CO TO TO gt U iJ
mdash C W to O
5 c c 4J 3 CO X LJ
^ bull bull0 laquolt- ej
TO CJ CO mdash C JJ
z u to mdash T3 4J ai TO CD C laquo bull c c ugt o cr 0) bull mdash CO mdash O bull gt JC TO ^ mdash Q CO O JJ O Q bull- CO to mdash to c Z CC O il mdash 4J gt
mdash Omdash O1O CD mdash U) TO C X mdash O CO C L mdash Cvv O W pound G CO C C
O gtgtgt C C mdash CO C TO CO 3 E mdash -J laquo 1- bullgt CO 0 to
bullo CO
cshyo bull
ugt C CO TO c w 4J-Q co e a c
mdash re TO in E to
Q
JJ c bullo
a LJ co E bull LJLJ
O mdash zx ZQ
ax
z o mdash1mdash Q
mdasha o CO LJ a LJ ~J
s CO
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bullmdash
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bullO bullmdash
gtgt3 TO CT L mdash Olmdash 1 O CD mdash 3 a CT cshy re 3 a c- o
^j C CO E Ol
bullmdash CL
bull CO 01 D 3
U
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bullmdash av^ CO 4J IA TO 5
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bullD
mdash mdash O CO
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bullmdash ^
bulla CO L
4J
C CO o 3
(A C TO
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03
ai_ 3 a bullo bull mdash 05 3 O) 00
mdash mdash C c gtgt G CO
O O
bullo^ = c a 0)
E C O umdash u a L_ bull OlCD mdash
4J mdash
u) obulla o u) amp 5 c -a 7 O C mdash o mdash _ i- (0
CO E laquoJ
C
a
bulla c bull o bull
c bullQ CO
3 01
CT mdash mdash a mdash -v
t- Ol CC-D 0) 3
CJ raquo
x^ CO
bullo 3
lt) bull_
gtraquomdash CO O 1- Ui O)
bulla ^ c mdash mdash mdash TO co in
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mdash TO
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CO X
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LJ
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tmdash CM CM ^_ CM
CO CM ^x
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18
bull -a gtgt CD
CO S jj
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bullo z 3 O L
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CD 1-gt o CO
jpound cshy x mdash o mdash
- 0 1 mdash bshy
4J 1 CO
Z u
CO mdash T3 CD CD
co E C mdash z bullD 73 4J O JZ = CD ltshyO C CD
CD 4J laquomdash C
bullO Qmdash U N ET3 bull mdash 0 Cmdash i- L re mdash oltmdash o
O 1 f-u gt Z 03 shy3 mdash CD
O O tshyo
O (Q C N O mdash shy
o agt O 4-raquo bull z in jz 3 CO 4-gt
gt Q ltshy 0
CD JZ N w Oshy- O
laquo ^ mdash 13 mdash m
mdash in 3
z s_ mdash
laquo
laquo CO T3 0 bull E in 3 3 1-L ^3
-TJ
re 3 O L
CD U -D SshyCD CO CO N 0) mdash 0-E S GO CD CO L
i
CO UJ gtmdash
z laquo w mdash ffl JZ CO 4-gt 4J JZ
4_) t_ mdash bull
cz QJ co jZ C C mdash 4J
re (uS a z z
OX) mdash a) O W E
Z O O JZ bull CL V E
C (~ mdash r re O CD
obullz
-J VI O 4J z re o gt o jt o 5
mdash tshy Q mdash CO 0 Q) mdash j j a C5 E U3
mdash CO mdash 4JCO CO E
CO
JZ 0 3 mdash t_
E Ot3 O L
bull
C 3 3 U L
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1 I
bullz o mdashfmdash Q
mdashfV
O CO LJ O
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mdash mdash 0 10
bullc bull CD 0) C 4-gt mdash w CO CO 4-1 to
gtJ CD Sshymdash CD Q-O L- gt
CD 4^
~mdash
^
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bullD 4J C C CO CD
E -3 Ol CD mdash - a bullc cu mdash 4J mdash CO
v^4-gt C 0)E01 Q
agt 3 ^ j3
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t
bullabullmdash 3 CT _
mdash
O
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bulla
co (0
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a 4J UJ
jpound O CO
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3 a CO
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i
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O rmdash 1 1
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E
i UJ bull~ CO CO
c V
co in
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1mdash bullz LJ s
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3)
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ro
^
r-i
4
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1
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13
CD
Ct
gtgt imdash CO
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bullz ~ CO CO CO O
0 o ^^
X X o 0 O O Ttrade 1
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|
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^ gtO
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o T3 ffi
bulla 03 3 C
C o o 1
lt
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a
CM
^~
laquobullgt CM
-
fshy
ltshy
fO CM
-
flCM
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^
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C 0)
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a CD ltO pound2 o mdash s CO 00
O o _
CD C ZE
3
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LJ a
clt
-J LJ
z 2 lt o O
1 1 lt o
CC ^
lt^(V
E I I i I I
L lt 13 O 00 CO
CO Z 05 CO Ch ~ rmdash
19
c o C M O - L bull O C M bullmdash co ujn iiupeo CM
CM h- fO i- X
bull k_ c _Jlaquo _Jo
laquok ro
mn i LJOJ 140 CM
3-
bull CM
m CM
tshy r- ro CM
CV
sshy = sO r sshy~ - 2
CM ^ ~ ~ mdash rs
a
2
ou tz S S o w S S o | ^
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mdash o r gtgtlt_
CM 1
m raquo
rmdash r- i- o o o r^ CZ LJ
auazuaq |ua oCO
laquo o PO laquo
o J
o bull
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20
1 (See Plate 53-1) This is the predominant waste material currently
being disposed of in the active landfill
Crushed drums were distributed throughout the original
landfill and were found in Excavations 2 4 4-5 7A 8A and 14 Some
drums such as those found under the road in Excavation 7A may have
been crushed by heavy equipment operating in the landfill Others like
those found at depth in sandy fill in Excavation 2 appear to have been
crushed before burial Drummed liquid and sludge wastes are also
distributed throughout the landfill (See Plate 53-2) They were found
in Excavations 1 4 5 6 8 and 10 These wastes are discussed below
One sealed drum was openedand found filled with refuse -- paper cups
towels paint covered rags etc One open and partially crushed drum
contained a dark granular solid waste This material was sampled
(Sample 10B) and found to be nonhazardous
Small deposits of dried pigmentsludge were found in
Excavations 3 4 6 9 and 13 Discernible layers of pigmentsludge and
stained soils were present in Excavations 7A 8 and 8A (See Plate
53-3) Of particular note was a 2 to 4-inch thick layer of
grey-colored dried sludge found at Excavations 7A and 8 All of these
wastes were sampled and the results are discussed below
Laboratory Analyses
Laboratory analyses were performed on 10 selected samples
obtained from both containerized (drummed) and uncontainerized wastes
Samples were analysed for 3 metals and 87 priority pollutants including
11 acid compounds 45 baseneutral compounds and 31 volatile organic
compounds Table 5-4 summarizes the analytical results and the
laboratory data sheets are presented in Appendix D
Of the 45 priority pollutant baseneutral compounds only 4
were identified in the samples that were analyzed Baseneutral
21
compounds and particularly phthalates were the most prevalent
chemicals and also were reported in the greatest concentrations The
highest levels of naphthalene (1200 ppm) bis (2-ethylhexyl) phthalate
(110000 ppm) and di-n-octyl phthalate (6200 ppm) were found in sample
4A a translucent red liquid obtained from a drum The highest
concentration of benzyl butyl phthalate (13000 ppm) was found in sample
6B a clear liquid and pink sludgepigment obtained from a drum
A total of 8 volatile organic compounds were identified The
highest levels of benzene (100 ppm) xylenes (19000 ppm) and
ethylbenzene (5300 ppm) were found in sample 5A a clear liquid
purple-grey sludge obtained from a drum Toluene was found in highest
concentration (12000 ppm) in sample 1A a purple-grey thick opaque
liquid obtained from a drum Methylene chloride (13 ppm) was
identified in greatest concentration in sample 8A-C a purple stained
soil and powdery waste Sample 10A a purple liquid obtained from a
drum was the only sample found to contain 1-1 dichloroethane (2000
ppm) Finally trace levels of trichloroethylene (sample 10A) and
111-trichloroethane (sample IB) were also reported
Samples were tested for three metals - cadmium zinc and
chromium The highest concentrations of cadmium (2200 ppm) and zinc
(5700 ppm) were found in sample 4A a translucent red liquid obtained
from a drum The highest level of chromium (52 ppm) was reported in
sample 5A a clear liquidpurple-grey sludge obtained from a drum
22
60 DISCUSSION
61 EXISTING SITUATION
Under existing conditions relatively small quantities of
volatile organic compounds (VOC) are indicated to be leaking from wastes
buried on the landfill site To date ground and surface water
monitoring results indicate relatively low concentrations of VOC in the
ground water and below detection limits in the adjacent brook (See
Tables 61-1 to 61-10) The results indicate that no potential health
risks from VOC and other constituents currently under observation are
being caused by the landfill operation to down stream surface water
users It would be prudent for Troy Mills to continue to monitor the
quality of Rockwood Brook upstream and downstream for VOC and on the
basis of waste analyses (previous section) to monitor ground and
surface water points for toxic metals and baseneutral compounds
62 SITE HYDROLOGY
An analysis of the hydrology of the landfill site was
performed in 1982 (NAI report of September 1982) The subwatershed that
contains the landfill site is (about 44 acres) a small fraction of the
watershed area that contributes to Rockwood Brook above surface water
sampling point C (about 1650 acres see Figure 62-1) This indicates
that most of the flow of the brook at point C (about 97) is contributed
by upstream watershed areas Thus leachate discharging into Rockwood
Brook from the landfill site can be expected to be diluted by over 30
times its volume This factor and the volatilization which naturally
occurs results in parameters detected in the Troy Mills monitoring
wells often becoming undetectable when they enter the brook
f 5
Geologic conditions which were defined in the NAI report of
July 1982 indicate that permeable deposits of sand and gravel overlie
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27
TABLE 61-5 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M5 (UPGRADIENT WELL)
Parameter Date Sampled 11-22-83
Specific conductance
pH2 81
Dissolved iron mg1 036
Dissolved manganese mg1 010
Chloride mg1 10
Phenolics mg1
3
023
Identified volatile organics
None identified ND
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (yg1)
28
TABLE 61-6 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M6
Parameter
Specific conductance
PH2
Dissolved iron mg1
Dissolved manganese mg1
Chloride mg1
Phenolies mg1
Identified volatile organics
11-dichloroethane tetrachloroethylene 111-trichloroethane
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vg1)
Date Sampled 11-22-83
152
lt002
29
6
0002
27 trace 140
29
TABLE 61-7 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M7
Parameter Date Sampled 11-22-83
1 47 Specific conductance
pH2 62
Dissolved iron mg1 002
Dissolved manganese mg1 0026
Chloride mg1 gt2
Phenolics mg1 0070
3 Identified volatile organics
111-trichloroethane 5
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vig1)
30
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34
glacial till and bedrock The sand and gravel deposits form a permeable
conduit through which leachate from the waste burial areas migrates
The permeable deposits lie in the area north of monitoring well M-l (See
Figure 62-1) In general the water saturated thickness of the sand
and gravel in the vicinity of the north-south access road is 6 to 12
feet
64 POTENTIAL FOR GROUND WATER CONTAMINATION
641 Estimated Quantity of Drums
The test pit excavation and sampling in the drum burial area
indicates a potential source of ground water contamination for the
future Many of the drums encountered were in fair to good condition
and contained liquid wastes An estimate of the number of drums in the
deposit was made with the following assumptions
1 The complex magnetic anomaly was simplified into a geometric solid 600 feet long 40 feet wide and 10 feet deep with a volume (V) of 240000 cubic feet
2 Each steel drum (D) occupies 105 cubic feet (including voids)
3 The density of packing (P) was assumed to be 50 of the packing that can be achieved with perfect cubic packing
THEN
N = estimated number of steel drums
N = (VD) (P)
N = (240000105) (05)
N = 11429 drums
The results of the drum excavation work provides a basis for
estimating the potential for specific types of chemical loading In
general three main classes of chemical substances were identified in
35
the drums The chemical substances included baseneutral extractable
organic compounds (mostly phthalates and lesser amounts of naphthalene)
volatile organic chemicals and metals
642 Phthalates
The phthalate esters found in the drums include
bis (2-ethylhexyl) phthalate ^0^3 benzyl butyl phthalate di-n-octyl phthalate Jd~7
Bis (2-ethylhexyl) phthalate was found in the highest
concentration at 110000 ppm (11 percent) Benzyl butyl phthalate is at
the second highest concentration 13000 ppm (13 percent)
Characteristics of those phthalates found are presented in Table 64-1
TABLE 64-1 PHYSICAL PROPERTIES OF PHTHALATE ESTERSshy
di-n-octyl bis (2-ethylhexyl) butyl benzyl DOP DEHP BBP
ALTERNATE o-Benzenedishy di (2-ethylhexyl) benzyl butyl NAMES carboxylic phthalate phthalate
Molecular Weight 3910 3910 312
Melting Point -25degC -50degC -35degC
Boiling Point 220degC 386 9degC 377degC
Vapor Pressure-mdash lt02 torr (150degC) lt001 torr (20degC)
Not
2xlO~7torr (20degC) Available
Solubility 3 rngfc (25degC) 04 mgfc (25degC)
58
13 rngH 48
Log octanolwater 92 873 58 partition coefficient 53 48
Versar Inc 1979 Water-Related Fate of 129 Priority Pollutants Volume II Prepared for US Environmental Protection Agency PBSO-20438 December
bullbullOther names listed in Versar 1979 vMore than one value has been calculatedreported
36
Bis (2-ethylhexyl) phthalate is the most well-studied of the
phthalate esters though the information on phthalate esters as a group
is limited The three phthalates identified at the Troy Mills site have
relatively low solubilities and are readily adsorbed onto suspended
particulates Microbial degradation is effective under aerobic
conditions bur is generally slower under anaerobic conditions
(nonexistent for bis (2-ethylhexyl) phthalate)
The above characteristics are important for two reasons One
the extent and nature of contaminant migration from the site are
dependent upon the physical characteristics Second the treatment
(clean-up) alternatives for contaminated ground water or soil can be
estimated from the characteristics
From the available information it appears that the phthalates
present at the Troy Mills site would be relatively immobile due to their
low solubilities and high adsorption rates The presence of toluene and
methylene chloride at the site however may increase the phthalates rate
of migration
It is important to note that none of the phthalates have been
found to be present in the monitoring wells nor in the surface water
sampled probably due to the low solubility and high adsorption rate
37
643 Napthalene u K r
Naphthalene has also been found in significant quantities in
the sampled drums Naphthalene is a polycyclic aromatic hydrocarbon and
has the following properties
Molecular Weight 12819
Melting Point 8055
Vapor Pressure (20degC) 00492 torr
Solubility in Water (25degC) 344 mgfc
317 mgfc
Log octanolwater partition coefficient 337
Versar 1979
Naphthalene has mid-range adsorption rates and solubility It is
therefore inferred that there would be some adsorption to soils in a
ground water environment It is important to note that naphthalene has
not been detected to date at the monitoring wells or the surface water
sampling locations This is expected to be a result of adsorption on
the soils
644 Volatile Organic Compounds
Volatile organic compounds tend to migrate readily within
soils and ground water They are therefore considered a threat to
surrounding ground and surface waters if they are released in sufficient
quantities
Volatile organic compounds were detected in samples from six
steel drums The total volatile organic (TVO) concentrations in the
38
wastes ranged from 9 ppm to 30100 ppm and averaged 8570 ppm In order
to determine the potential for future contamination by volatile organic
compounds an estimate of waste quantity based on information from the
drum excavation program was made It was assumed that 7000 steel drums
in the deposit are 60 full of liquid waste with an average TVO
concentration of 8570 ppm The computed volume of liquid waste is
231000 gallons with an average TVO concentration of 8570 ppm This is
equivalent to about 1980 gallons of pure TVO
Two of the volatile organic compounds that have been most
prevalent in the existing ground water monitoring system are
111-trichloroethane and ethylbenzene The EPA suggested no adverse
response level (SNARL) for 111-trichloroethane is 330 ugpound for
1 day of exposure and 35 jigd for exposure over a life-time in
drinking water
In general ethylbenzene is a prevalent chemical in the
environment Sources include commercial (eg petroleum and petroleum
by-products) motor vehicle exhaust and cigarette smoke An intake of
16 mgday (1 mgfc) has been calculated as an acceptable rate to
protect from toxic effects Carcinogenic effects have not been
identified to date The physical properties of ethylbenzene are
presented in Table 64-2 The principal mechanism for removal of
ethylbenzene from water is volatilization In addition to
volatilization adsorption may also be an important removal mechanism
based on the log octanolwater coefficient This factor is important in
evaluating the migration of ethylbenzene from the disposal site
Toluene which was also identified in waste and ground water
samples exhibits properties similar to ethylbenzene in that it
volatilizes easily Toluene which is also referred to as methylbenzene
is distinguished from benzene by the substitution of a methyl group for
one hydrogen atom Physical properties of it are presented in Table
39
64-2 The EPA suggested no adverse response level (SNARL) for toluene
is 1 mgpound in drinking water with a maximum exposure time of ten
days
TABLE 64-2 PHYSICAL PROPERTIES OF ETHYLBENZENE AND TOLUENE
ETHYLBENZENE TOLUENE
Molecular Weight 10616 9213
Melting Point -949degC -950degC
Boiling Point 1362degC 1106degC
Vapor Pressure at 20degC 7 torr 287 torr
Solubility in water at 20degC 152 mg2 5348 mgd
Log OctanolWater Partition Coefficient 315 269
645 Metals
One liquid sample contained high concentrations of cadmium
(2200 mgd) and zinc (5700 mgd) indicating that the waste deposit is
also a potential source of certain toxic metals Tests for these metals
have not been made to-date in ground or surface water samples It would
be prudent to add toxic metals such as cadmium chromium lead and
mercury to the list of parameters that are being monitored to further
characterize the quality of adjacent ground and surface waters US
EPA and New Hampshire drinking water standards for these metals are
cadmium 01 mgd chromium 05 mgpound lead 05 mgd mercury 002
mgd Although zinc is not considered a highly toxic metal the
US EPA has set a secondary drinking water maximum contaminant level of
5 mgd on this metal
40
70 CONCLUSIONS
The following conclusions were drawn during this
investigation
1 A steep-gradient irregular-shaped magnetic anomaly is present under closed and covered portions of the south part of the Troy Mills landfill
2 The magnetic anomaly is caused mostly by an irregular-shaped accumulation of disposed steel drums
3 In a randomly conducted sampling of drums in the source area for the magnetic anomaly 16 of the drums contained liquid andor sludge 33 were crushed flat and 51 were not sampled because there were no accessible openings
4 Laboratory analyses indicate that the random waste sampling contained significant concentrations of several volatile organic chemicals several baseneutral priority pollutants and high levels of cadmium and zinc
5 Observed concentrations of volatile organics at the monitoring wells are relatively low Because of their potential for migration in the ground water continued monitoring of volatile organics will be required
6 Volatile organic chemicals have not been detected in Rockwood Brook to-date Because of the presence of low levels of volatile organics in the ground water they should be monitored in the brook on a regular basis to confirm the lack of impact
7 The presence of high concentrations of cadmium and zinc in one of the waste samples indicates that trace metals should be monitored periodically
8 The presence of baseneutral extractable compounds (phthalates and naphthalene) in all of the analyzed waste samples indicates that these compounds should be monitored periodically
9 The phthalates are not expected to migrate freely because they have low solubilities and are readily adsorbed onto soil particles
10 If elevated concentrations of volatile organic compounds trace metals or baseneutral extractable compounds should occur in the monitoring system (wells and brook) in the future a need for site remedial actions to mitigate the potential for downgradient ground and surface water contamination could develop
~
80
41
RECOMMENDED PLAN
Based on the preceding conclusions it is recommended that the
following plan be implemented by Troy Mills Inc
1 Continue monitoring ground and surface water quality at the Troy Mills Inc landfill sampling on a quarterly basis with sample collections during April July October and January
2 To confirm the absence of the landfills impact on Rockwood Brook test samples for volatile organic compounds by GCMS from surface Stations B (upstream) and C (downstream) on the April and October samplings
3 To determine if trace metals are present in downgradient ground waters conduct analyses for cadmium chromium lead mercury and zinc on samples from all monitoring points during the April sampling and on subsequent sampling rounds if necessary
4 To confirm the continued absence of baseneutral extractable compounds in downgradient ground and surface waters conduct analyses for baseneutral extractable compounds on samples from monitoring wells M 2 and 3 and surface Station C (downstream) on the April sampling and on subsequent sampling rounds if necessary
5 If a sudden rise in concentrations toward unacceptable levels should occur in the monitoring system (wells and brook) additional monitoring rounds at a monthly interval should be conducted to confirm the rise in concentrations
6 If elevated concentrations persist and are verified by the additional monitoring remedial alternatives will be defined to mitigate the potential for downgradient ground and surface water contamination
Respectfully submitted NORMANDEAU ASSOCIATES INC
Dennis R Sasseville Project Manager
Donald H Bruehl f laquo | APG Senior Hydrogeologist -^ - - AIPG Certificate No 2272 ^ -v^
^^Z-^^
APPENDIX A
SITE SAFETY PLAN
GENERAL SAFETY PLAH FOR
TROT MILLS LANDFILL TROY MEW HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
Prepared by
NORMANDEAU ASSOCIATES INC Bedford New Hampshire
R-457
November 1983
TABLE OF COHTENTS
PAGE
SECTION 1 BACKGROUND INFORMATION 2
Identification 2 Personnel 2 Site Description 3 Project Description 5
SECTION 2 HAZARD EVALUATION 6
Overall Degree of Hazard 6 Specific Hazards 8 Necessary LPP 8
SECTION 3 FIRST AID FOR EXPOSURE 10
SECTION 4 OPERATIONS SAFETY PLAN 11
General Personnel Protection GuidelinesAction Levels 11 Site Reconnaissance 13 Task 1 - Magnetic Survey Topographic Survey 14 Task 2 - Drum excavation and Sampling 15
SECTION 5 EMERGENCY INFORMATION 16
Emergency Telephone Numbers 16 Route to Hospital 16 Contingency Plan 17
APPENDICES 18
A - LEVELS OF PERSONNEL PROTECTION 18 B - DECONTAMINATION PROCEDURES 23 C - PERSONNEL AND RESPONSIBILITIES 25 D - PERSONNEL CASUALTY 26 E - GUIDELINES FOR SITE OPERATIONS 27
GENERAL SAFETY PLAN FOR
TROY MILLS LANDFILL TROY NEraquo HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
The following is a Safety Plan for on-site activities performed
during the Investigation of the Troy Mills Landfill being conducted by
Normandeau Associates Inc (NAI) of Bedford New Hampshire
The document is intended to be an in house working guideline
for personnel trained and experienced in hazardous waste field work and
not a treatise on safety Familiarity with standard equipment and proshy
cedures is expected Where possible non-site specific information has
been appended
All NAI employees subcontractors and visitors will be required
to follow this safety procedure plan and to report to either NAIs proshy
ject manager (P M) on site coordinator (OSC) or safety officer (SO) on
issues relating to safety
SECTION 1
BACKGROUND INFORMATION
IDENTIFICATION
Site Name Trey Mills Landfill NAI-ID No 457
Trey Mills Inc Troy NH 03465
AddressLocation At the south end of the dirt road about 15 miles
south of Troy NH between Rockwood Brook and the
old Boston and Maine Railroad grade
County Cheshire Phone 603-242-7711
PERSONNEL
Brook Dupee Bureau Hazardous Waste 603-271-4611
State Contact John Regan Bureau Solid Waste 603-271-4586
Dan Allen WSPCC 603-271-2755
EPA Contact
Other Contacts
Client Contacts Barrett F Ripley (Vice President)
NAI Personnel - (472-5191)
Project Manager - Dennis Sasseville
On Site Coordinators - Alton Stone
Safety Officer - Elizabeth Gross (Phoenix Safety)
Technical Director - Don Bruehl
Other - Douglas DeNatale Steve Ransom
SITE DESCRIPTION
Type of Facility Company (on-site) landfill
RCRA Status Generator Disposer
Size About 15 acres BuildingsStructures None
Surrounding Land Use N Forested
(one mile radius) E Abandoned Railroad
Forest RuralResidential
S Forested
W Forested Mountain side
Unusual Features or Terrain None
Site Activities - Troy Mills manufactures textiles carpets and related
products Since 1968 waste materials including
drummed wastes have been landfilled on company proshy
perty Drums mostmany of which may be emptycrushed
are buried in an inactive section of the landfill
The active section is currently accepting waste
which is considered to be non hazardous
Specific - Improper disposal of hazardous waste
Problems - Leachate seep
Contamination of ground water
Hazardous WastesMaterials On-5ite
Wastes - Uncured foam rubber latex sludge
SBR rubber silicone defoamer potassium oleate soap
calcium carbonate and feldspar filters zinc oxide
and sulpher salt cure system
- Vinyl plastisol sludge
PVC dispersion resin DOP and DOA plasticiser
calcium carbonate filler organic pigments AZO
dicarbcnamid blowing agent zinc salts expoxidized
soybean oil cadmLum-bariin-zinc stabilizer Varsol
MEK prints and topcoats sludges
PVC acrylic resins organic and inorganic pigments
MEK solvent toluene silicate fillers
Industrial solvents and chemicals
11 -dichlorethane 12-dichlorothane
111-trichloroethane trichlorethylene tetrachshy
lorethene methylene chloride toluene benzene
ethylbenzene benzidine 33-dichlorobenzidine aeroshy
lein acrylonitrile napthalene benzoperylene dibenshy
zoanthrasene idenopyrene
Pesticides
There is a possibility for low levels of pesticides
to be on site These would include Chlorodane
heptachlor expoxide toxaphene aldrin alpha BHC
beta BHC 4-4-DDT endosulphan 1 heptachlor
PROJECT DESCRIPTION
Purpose Tb characterize ground water conditions at the site and to
characterize wastes buried on site
Specific Tasks
Site Reconnaisance
Task 1 - Magnetometer SurveyTopographic Survey
Task 2 - Excavation for inspection of drums
SECTION 2
HAZARD EVALUATION
Overall Degree of Hazard - Moderate
Task Hazard Proposed LPP
Site Reconnaissance Low Level C
Task 1 MagnetometerTopographic Surveys Low Level CD
Task 2 Drum ExcavationSampling Moderate Level B
Conpany records have indicated that a variety of industrial
and potentially hazardous wastes including drummed wastes
were disposed of on site Several of the subtances are
trade name materials or industrial process materials and it
is difficult to determine the specific chemical composition
Hazard is dependent upon concentration of material state of
material (solid sludge drummed liquid) and degree of
decomposition
Many of the materials - SBR rubber silicone defoamer
potassium oleate soap calcium carbonate and feldspar
fillers zinc oxide and sulpher salts plasticiser
calcium carbonate filler organicinorganic pigments AZO
dicarbonamid blowing agent epoxidized soy bean oil
cadmiura-bariun-zinc stabilizer - probably do not represent
a significant hazard to an inspection team if they are
bound into a sludge or solid Personnel are not likely
to injest or come into a prolonged high concentration
contact with these materials In powdered or dust conshy
ditions the materials are more hazardous due to the inhashy
lation of contaminated particulates
MEK (TLV-200ppm) toluene (TLV-100ppm) and Varsol
(turpentine thinner composition unknown) are volatile
organics which require respiratory protection and contact
protection
Depending upon state and decomposition PVC resins could
be a source of vinyl chloride monomer (VCM-a carcinogen)
requiring respiratory protection VCM is not adequately
filtered by air purifying respirators
Results from ground water sampling showed low levels of
industrial chemicals (PPB range) At these low conshy
centrations the chemicals do not represent a significant
hazard However the low concentrations in ground water indishy
cate the possibility of higher concentrations in the waste
materials
Industrial chemicals - napthalene (TLV-10 ppm) peryshy
lene anthrocene and pyrene which are hazardous
through inhalation or absorbtion Furthermore as
double benzene ring chemicals they are potential
carcinogens
Results from ground water sampling indicated possible
low levels (parts per trillion) of several pesticides
- chlorodane heptachlor epoxide toxaphene eldrin
Alpha BHC Beta BHC 4-4-DDT endosulphan These were
tentatively identified during a first analytical run
but not confirmed during a second run laboratory
review (GCA Bedford Mass) determined that the
material was actually a complex of highly degraded
heavy organics derived from the industrial waste The
presence of pesticides in industrial textile waste is
unlikely
Specific Hazards
1) Inhalation of organic vapors
Excavation of buried material and sampling of drums could
initiate high vapor concentrations
2) Fire and explosion
Many of the solvents are flammable liquids and volatile
Excavation of material and sampling of drums should
proceed cautiously in order to avoid rupturing shocking
or sparking of drums and material
3) Inhalation of contaminated dustparticulates
Excavation of buried material may result in a release of
particulates
4) Contact contamination
Excavation and sampling of wastes could possibly result in
contact with contaminated waste and soils necessitating
protective clothing
Necessary LPP
Site Reconnaissance - Level C The site has been visited on numerous
occassions by the state and private personnel Use of an HNU (102 ev
probe)- has not indicated significant vapor concentrations Significant
odors during dry weather or other hazards have not been noted
Sections of the landfill are currently active and adverse effects to
personnel have not been noted Level C - (tyveks rubber safety boots
organic vapor cartridges) is sufficient
Task 1 MagnetometerTopographic Survey - Level CD LPP will depend
upon the results of the Site Recon Significant vapor concentrations
or likelihood of particulates will necessitate an upgrade in the LPP
Otherwise Level D (work clothes safety boots boot wash) is sufficient
Task 2 Excavation and Sampling of Buried Drums - Level B The potenshy
tial for encountering significant concentrations of hazardous
materials during this task is moderately high Full Level B - (SCBA
chemical resistant tyveks hoods rubber safety boots rubber gloves)
will provide necessary respiratory and contactsplash protection
The use of the hooded yellow tyveck and the taping of ankleboots
wristsgloves and face maskhood junctions will provide complete conshy
tact protection
10
SECTION 3
FIRST AID FOR EXPOSURE
INHALATION OF VAPORSPARTICUIATES
Symptoms - eyenosethroat irritation nausea dizziness headache weakness fatigue lightheadedness drowsiness Loss of coordination confusion vomiting cramps (These sympshytoms are similar for most organic vapors particularly solvents)
Treatment Mild Exposure - Bring victim to fresh air Rinse eyes and throat if
irritated Heavy Exposure - (victim vomits very dizzy groggy faints etc)
Bring victim to fresh air Evacuate to hospital Prepare to administer CPR
Victim should be monitored for 48 hours in case of a delayed reaction
CONTACT EXPOSURE
Symptoms - Itching burning redness of skin Severe contact exposure for certain solvents will progress to CNS (central nervous system) symptoms similar to those for inhalation
Treatment - Remove contaminated clothing flush with water dry and banshydage Monitor victim for CNS symptoms for at least 48 hours
FIRST AIDSAFETY EQUIPMENT
The following equipment will be stationed at the Hotline or when appropriate down range
- Fully equipped first aid kit - Oxygen bottlekit - Nine (9) Ib chemical fire extinguisher - Eyewash bottle or other pressurized water filled container
11
SECTION 4
OPERATIONS SAFETY PLAN
This section outlines the specifics of safety procedures to be
used during each phase of the operations Safety procedures may be
upgraded or downgraded during site activities pending monitored changes
in the working environment All changes will be in line with the
General Level of Personnel Protection GuidelinesAction Levels for the
Troy Mills Landfill On-Site Investigation as described below
General Personnel Protection GuidelinesAction Levels
An in depth review of levels of personnel protection (LPP) is
presented in Appendix A
Level B (SCBA cotton coveralls or work clothes yellow tyveks (chemical resistant) steel toed rubber boots or work boots with disposhysible over boots and gloves)
Vapor concentrations (as measured on an OVA or HNU 117 EV Probe) greater than 5 ppm above background
- Oxygen deficient atmospheres less than 195
Specific actions (ie excavationsampling of drums) which could initiate a sudden moderate or high concentration of vapor
Level C (full face respirator organic vapor dust combo cartridge tyveks over work clothscoverails rubber safety boots gloves)
Vapor concentrations above an established clean zone backshyground level
During conditions (natural or personnel induced) which result in high levels of dust (visable above background atmospheric concentrations of particulates)
Level C activities require continual air monitoring
12
Level D (cotton coveralls or other work clothes safety shoes and safety glasses when down range Tyveks may also be needed)
Support areas and downrange areas where a higher LPP has not been deemed necessary
Continual air monitoring in downrange areas
Explosive Atmospheres
- 20 LEL (lower explosive limit) as recorded by an explosishymeter Secure and evacuate the work area
Oxygen Deficient Atmospheres
- Less than 195 (by volume) oxygen atmosphere requires upgrading the level of Personnel Protection to Level B
Task Specific Safety Plans
Levels of Personnel Protection indicated for specific tasks below are those which are anticipated to be used Changes in site conshyditions and results of air monitoring may indicate the upgrade downgrade of the LPP
13
Site Reconnaissance (SR) Date Sept 21 1983
Purpose To review on-site conditions and determine LPP necessary for further tasks To evaluate safety hazards Preliminary planning of future tasks
LPP - Initially Level C Updowngrade as necessary
Equipment - OVA HNU (102 ev probe)
Hotline - End of access road Upwind if possible
Command PostFirst Aid - Behind Hotline
Decontamination - Boot wash
Operations
Three man team Two persons advance in front with instrushyments Third person at distance as backup
Team methodically sweeps (criss cross) the proposed work areas with instruments
Specific points of interest (leachate seeps etc) are closely checked
All information is loggedsketch mapped
Upgraded LPP as necessary
14
Task 1 - Magnetic Survey Topographic Survey Date Week of October 3 1983
Purpose - Determine the location(s) and extent of buried drums Provide topographic information for site base map
LPP - Level CD
Hotline - End of access road (upwind if possible)
Decontamination - Boot wash
Operations - SO or other NAI personnel will perform a brief safety sweep of the work area
- Work team will then proceed downrange at the appropriate LPP Using the magnetometer the team will systematically criss cross -the work area
Task 2 - Drum Excavation and Sampling Date Week of November 14 1983
Purpose - Excavationsampling of buried drums in order to characterize the condition of the drums and the nature of the wastes conshytained in the drums and buried in the landfill
Msthod - Backhoe and hand labor will be used to uncover the drums in specified locations Samples will be obtained from spillage or leakage around the drums and of contaninated soil Selected drums which have accessible and openable bungs may be opened and sampled Drums will not be moved or staged Clean drums will be available to receive any significant spillage during the opening and sampling
Specific Hazards - Inhalation of organic vapors - Fire and explosion of drummed waste - Contact with contaminated waste or soil
LPP - Full Level B protection Backhoe operator at Level B Backshyhoe equipped with splash shield and without teeth on bucket
Hotline - At the end of the access road Upwind if possible
Decontamination - Procedures will essentially follow those as outlined by the EPA for Level B work Due to the inaccessibility of the site a field shower will not be available See Appendix B
Safety Equipment - OVA HNU eyewash fire extinguisher oxygen kit first aid kit metal detector non sparking implements
15
Operations - The cover soil is very sandy and the drums appear to be buried close to the surface which should facilitate excavation
- Minimum of 4 man team (exclusive of backhoe operator) Two or three man downrange team for digging and sampling One or two men in supportbackup at hotline
- Personnel will hand dig several small holes to approximately one (1) foot depth in each Location area If drums are not encountered the backhoe will scrape off soil to that depth
- Excavation will proceed alternating hand and backhoe methods At depths below four (4) feet the sides of the pit must be angled back to less than 45deg
- Prior to opening a closed drum the backhoe will nudgebump the drum to check for shock sensitive material An alternate method will be to attach a length of rope to the drum and from a distance pull on the rope to jog the drum
mdash Backhoe The backhoe operator will work at Level B utilizing air supplied from a large cylinder attached to the backhoe The backhoe will also be equipped with a splash shield A scraping bucket without teeth will be used
Prior to backhoe excavation at each location the area where the backhoe will be stationed will be checked for drums which could be ruptured by the backhoe feet
f Excavation areas will be checked for drums utilizing hand excavations or a metal detector prior to removing material by machine
16
SECTION 5
EMERGENCY INFORMATION
Emergency Telephone Numbers
If calling one of these numbers please state NAME LOCATION
and type of PROBLEM
Local Emergency Support
Fire Department (Troy 242-7759) For all emergencies use
Ambulance 352-1100 Mutual Aid (Keene) 352-1100
Police Department (Troy 242-7992)
Hospital 352-4111 (Cheshire Hospital in Keene)
Town Clerk 242-3845 State Agencies
NH Bureau of Hazardous Waste Management 271-4608
NH Water Supply and Pollution Control Commission 271-3503
NH Fire Marshall Office 271-3336
NH State Police (24-Hour Dispatch) 1-800-852-3411
Other
US EPA (24-Hour Hotline) 617-223-7265
Poison Center Mary Hitchcock Hospital 1-800-562-8236
Route to Hospital
- Follow dirt access road to Bowkerville Road - Left on Bowkerville Road to Rt 12 - Left (north) on Rt 12 through Troy to Keene NH - At major junction of Rts 9 10 101 and 12 go straight through
into Keene - At common go half-way around and go right on Court Street - Hospital is at 580 Court Street
17
Contingency Plan
Signal - five (5) one second blasts of auto or air horn Action - All personnel immediately excavate dovmrange areas and
report to Hotline for instructions
Personnel Unexplained Fire (if small) Accident (serious) Collapse of Personnel
Evacuate area Emergency ^ ^Evacuation Evacuate Area
First Aid
Estimate Explosion Level B (for Potential Contact Outside Help evcavation)
Evacuate Victim i If
Level B Prepare for Transportation
1 First AidCPR Use extinguisher Transport
Contact Outside Help Notify Coup any Have Proper Information Personnel (see below) 1
Transport
Call Fire Dept (if necessary)
For Hospital Victim
- Name and Phone of family physician
- Description of Incident chemicals involved symptoms nature of injury proposed treatment and plan of transportation
18
APPENDIX A
LEVELS OF PERSONNEL PROTECTION
Because of the possible dangers of exposure to toxic or harmshyful chemicals protective equipment must be worn during work on hazardous waste sites Levels of Personnel Protection (LPP) describe respiratory clothing and other equipment necessary for protecting personnel against expected hazards
The descriptions below are for full dress at a given LPP where hazards are expected to be at a maximum for which the given LPP is conshysidered adequate Depending on site conditions and work activities the clothing and dress requirements of a given LPP are commonly modified
LEVEL A
1 Personal Protection Equipment
Positive Pressure SCBA (MSHANIOSH approved) Operated in the positive pressure mode
Totally Encapsulating Suit (boots and gloves attached)
Gloves - Inner (tight fitting and chemical resistant)
- Boots - Chemical - protective steel toe and shank Depending on suit boot construction worn over suit boot
- Gloves shy Outer chemical-resistanttion worn over suit gloves May bchemical-resistant gloves worn insid
Dependinge replaced withe suit glo
on s
ves
uit construcshy tight-fitting
- Underwear shy Cotton long-John type
- Hard Hat (under suit)
- Disposable protective suitover encapsulating suit)
gloves and boots (Worn under or
- Coveralls (under suit)
- 2-way Radio Communications
Optional
19
2 Criteria for Use
A The type and concentration of toxic substances are known and require the highest level of combined protection to the respirashytory tract skin and eyes These conditions would be
1 Atmospheres which are immediately dangerous to life and health (IDLH)
a IDLHs can be found in the NIOSHOSHAs Pocket Guide to Chemical Hazards andor other references
2 Known atmospheres or potential situations that would effect the skin or eyes or could be absorbed into the body through these surfaces in toxic quantities
a Potential situations are those where vapors may be generated or splashing may occur through site activities
b Standard reference books should be consulted to obtain concentrations hazardous to skin eyes or mucous memshybranes
3 Oxygen deficient atmospheres with above conditions
3 At sites where the type andor potential concentration of toxic substances are unknown
1 Unless circumstances strongly indicate otherwise the site should be presumed to present hazards to the respiratory system skin and eyes Level A protection would provide the highest level of protection for the initial entry team
a Such circumstances might be
1 Environmental measurements contiguous to the site
2 Reliable accurate historical data
3 Open unconfined areas
4 Minimal probability of vapors presence or splashing with cutaneous effecting substances
2 Enclosed areas such as buildings railroad cars ships holds etc
20
LEVEL B
1 Personal Protective Equipment
Positive Pressure SCBA (MSHANIOSH approved) operated in the positive pressure mode
- Hooded chemical-resistant suit
Gloves - Outer chemical-protective
Gloves - Inner tight-fitting chemical-resistant
Boots - Outer (chemical-protective heavy rubber disposables)
Boots - Inner (chemical-protective steel toe and shank)
2-way Radio Communications
Hard Hat
Face Shield
2 Criteria for Use
A The type and concentration of hazardous substances are known and require the highest degree of respiratory protective but a lower level of skin protection
1 Atmospheres which are immediately dangerous to life and health (IDLH) Type and concentration of vapors in air do not present a hazard to the small unprotected areas of the body
2 Atmospheres with concentrations of known substances greater than protection factors associated with full-face air-purifying respirators with appropriate cartridges
3 Atmospheres with less than 195 oxygen
B When a determination is made that potential exposure to the body parts not protected by a fully encapsulated suit (primarily neck ears etc) is highly unlikely
1 Known absence of cutaneous or percutaneous hazards
2 Activities performed preclude splashing of individuals
C Level B protection is recommended as the lowest level of protecshytion for initial entries until the hazards have been further identified and defined by monitoring sampling and other reliable methods of analysis and personnel protection equipment commensurate with these findings utilized
21
LEVEL C
1 Personal Protective Equipment
Full-face or half-face air purifying respirator (MSHANIOSH approved)
Chemical-resistant clothing
Gloves - Outer (chemical-protective)
Gloves - Inner (tight-fitting chemical-resistant type (or woven liners)
Hard Hat (face shield optional)
Boots - Outer (chemical-protective heavy rubber throw aways)
Boots - Inner (chemical-protective steel toe and shank)
2-way radio comnunications
Safety glasses required with half-face respirator
2 Criteria for Use
A Site known to contain potentially hazardous materials exceeding
1 Air concentrations requiring a protection factor no greater than that afforded by a full-face mask
2 Harmful levels to unprotected body areas (face neck etc)
3 Well-documented reliable history of site and patterns of prior entry
C No evidence to suspect acute or chronic toxicity to exposed personnel
D Continuous air or personnel monitoring should occur while wearing Level C protection
22
LEVEL D
1 Person Protective Equipment
Chemical resistant aprons
BootsShoes - Safety or chemical-resistant steel toed boots
Boots - Outer (chemical-protective heavy rubber throw-away)
Half-face respirators immediately available
Safety glasses or safety goggles
Gloves
2 Criteria for Use
a No indication of airborne health hazards present
b No gross indications above background on the photoionizer andor organic vapor analyzer
c Continuous air or personnel monitoring should occur while wearing Level D protection
23
APPENDIX B
DECONTAMIHATION PROCEDURES
Depending upon activities and location on site it may be
necessary for personnel to decontaminate prior to leaving the conshy
taminated zone Procedures described below are typical for Level C
operations
Upon exiting downrange (contaminated) areas all personnel are
required to decontaminate by means of the following procedure
1 Place equipment in the Drop Zone at the Hotline
2 Enter the Decontamination Station
Boot Wash Walk through wash tub and scrub boots then rinse boots in second tube
Glove Wash In two pan wash scrub over gloves rinse set out to dry
2 Remove tyvek - if leaving the contamination reduction zone (CRZ) and proceed to clean zones
3 Dispose of heavily contaminated clothing and under gloves
4 Remove respirator
5 Use disposable gloves to clean equipment
6 Use a two bucket (washrinse) to decon respirators at the end of the working day or if they become heavily contami nated
The procedures for a typical Level B Decontamination are
outlined on the following page
TANK CHANGE 9
CONTAMINATION REDUCTION
ZONE
OUTER GLOVE REMOVAL
EXCLUSION ZONE
TAPE REMOVAL
BOOT COVER
GLOVE WASH
(bull)mdashQ-G--copyshySOOT COVEH SCOT COVES 4
REMOVAL GLOVE RINSE
SUITSAFETY BOOT WASH
SU1TSC8A78OOTGLOVE RINSE
SAFETY BOOT 10 REMOVAL
SCSA BACKPACK REMOVAL
SPLASH SUIT 12 REMOVAL
INNER GLOVE WASH
INNER GLOVE RINSE
FACE PIECE REMOVAL
INNER GLOVE 16 I REMOVAL
INNER CLOTHING REMOVAL
FIEUJ 19 REDRESS WASH
SEGREGATED EQUIPMENT
OROP
mdash -HOTLINE-shy
DECONTAMINATION LAYOUT LEVEL B PROTECTION
FIGURE A2-1
CONTAMINATION CONTROLLING
SUPPORT ZONE
25
APPENDIX C
PERSOHNEL AND RESPONSIBILITIES
Project Manager (PM)
Overall responsibility for all Project activates budget
schedule investigative operations safety personnel
On Site Coordinator (OSC)
Responsibility for activities at the site Primary responshy
sibilities include
1) Interfacing with the client state EPA media or other groups
2) Reviewing technical operations
3) Reviewing site safety in particular information supplied by the Site Safety Officer
4) Enforcing site safety and compliance with the Safety Plan
5) Directing Emergency Contingency operations
Safety Officer (SO)
Responsibility for directing the safety of operations and impleshy
menting the Safety Plan Specific responsibilities include
1 Assuring that appropriate personnel protective equipment is available and properly utilized by all site personnel
2 Assuring that personnel are aware of the provisions of this plan are instructed in the work practices necessary to ensure safety and in planned procedures for dealing with emergencies
3 Assuring that personnel are aware of the potential hazards associated with site operations
4 Supervising the monitoring of safety performance by all pershysonnel to ensure that required work practices are employed
26
APPENDIX D
PERSOHHEL CASUALTY
Personnel casualty would most likely result from either chemical
contamination heat-related problems physical injury from accidents
(ie falling lacerations etc) in performing the work or a comshy
bination of one or more of the above The appropriate action depends on
the type of injury involved with the priority being to assist the
casualty as soon as possible without endangering other personnel
Riysical and heat-related injuries can and should be treated
immediately with appropriate first-aid measures and follow-up medical
attention if necessary The injured worker(s) shall immediately move
out of the hot zone or if necessary be moved out by fellow workers as
soon as possible The OSC and Safety Officer shall be notified immeshy
diately and shall recommend further measures as needed
Chemical-related injuries require a much more cautious approach
so as to keep casualties to a minimum If a worker injured by chemical
ejqgtosure is able he shall notify the nearest co-worker and leave the hot
zone immediately- The co-worker shall ensure that the OSC and Safety
Officer are immediately informed and shall accompany the casualty from
the hot zone to the decontamination zone The OSC and Safety Officer
shall determine the appropriate measure
27
APPENDIX E
GUIDELINES FOR SITE OPERATIONS
In order to deal with the potential dangers of exposure and conshy
tamination of a hazardous waste site three zones are delineated
according to the degree of hazard The three zones are 1) Downrange
or Contamination Zone 2 Contamination Reduction Zone (CRZ) 3) Support
or Clean Zone
Downrange or Contamination Zone
The Contamination Zone is the active work area of the site which
encortpasses the areas where there is a potential for exposure and in
which investigative activities will occur (drilling sampling etc)
Within the Contamination Zone the designated level of hazard will be
established necessitating the utilization of personnel protective
equipment
Hot spots are those areas Downrange where observations instrushy
ment readings or specific activities indicate a high probability of
closure or contamination and may require an upgrade in the LPP in the
vicinity of the Hot Spot
Contamination Reduction Zone
The CRZ is an area between the Downrange and Support Zones where
decontamination of equipment and personnel occurs
28
Personnel entering the CRZ shall wear protective clothing and
carry the respiratory protection required for entry within the
Contamination Zone
Personnel working within the CRZ shall remain cognizant of the
CRZ in order to be prepared for any need to increase their level of proshy
tection within the CRZ
A decontamination station will be located at the outer perimeter
of the CRZ All personnel who have been within the Hot lane shall pass
through a decontamination procedure prior to re-entering the Support
Zone
Support or Clean Zone
The Support Zone is the outer area and may be considered to be
clear of contamination potential The command post will be located
within the Support Zone
a) The Command Post will serve as the OSCs headquarters and
will be equipped with
1 Communications
2 Safety Plans
3 First Aid Supplies
4 Analytical Equipment
5 Safety Equipment
APPENDIX B
WORK PLAN
WORK PLAN FOR
TROY MILLS LANDFILL TROY NEW HAMPSHIRE
DRUM EXCAVATION AND SAMPLING
Prepared by
NORHANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
1933
WORX PLAN FOR
TKOt MILLS LANDFILL TROT NEW HAMPSHIRE
DRUM EXCAVATION AHD SAMPLING
DATS November 16-18 1983
PURPOSE
To determine the condition of drums (ie erroty or full
crushed rusted leaking etc) buried in the Troy Mills Landfill To
obtain representative samples toward identifying the types of materials
buried in the landfill This information will be used in the detershy
mination of the level of remedial action needed at the site
METHOD
Using the results of the magnetometer survey the (10) points
have been randomly chosen across the area where the buried drans are
expected to be found Each point is central to an Excavation Location
-- an area four (4) to six (6) feet in diameter which will be excavated
in order to characterize the condition of the drams and to obtain waste
sarples
Preliminary observations have indicated that many of the drums
may be buried within 1-2 feet of the surface Therefore the investigashy
tion will proceed in two phases
Phase 1 mdash Hand Excavation By digging several small holes in
each Location personnel will determine if drums are located within
about one to two feet of the surface If drums are encountered the
excavation will proceed by hand uncovering the dnris for evaluation and
sampling Where drums are not encountered near the surface excavation
at this location will be postponed until Phase 2
Phase 2 mdash HandBackhoe Excavation After all Locations have
been attempted during Phase 1 those Locations in which drums were not
encountered wall be further excavated using a combination of hand
backhoe digging
It is expected that one to two days will be necessary to
cor^piete each phase Depending upon the results of Phase 1 it may not
be necessary to iroleraent Phase 2
Spare drums will be on hand for containerizing any significant
spillage resulting from sampling efforts Excavation locations will be
identified with marked stakes and the holes will be backfilled at the
conclusion of the investigation
SPECIFICS
Excavation Locations (Holes)
Number of proposed excavations is ten (10)
Locations of excavations are presented in Appendix A
Hole Size mdash It is expected that a hole from four (4) feet to six (6) feet in diameter at the bottom (depth at which drums are encountered) will be sufficient to characterize the drums at each Location Deeper excavations will require increasingly large top diameters
Hole Depth -- Holes will be excavated to a maximum depth of six (6) feet Due to the sandy cover material the excavation of deeper holes is probably impractical from both safety and efficiency stand points
If after attempting excavation at each of t-ie 10 proposed
1ocatiors irums are not encountered within six (6) fet of the surf ice
in enough locations to characterize the site excavations nay be
attempted to depths greater than six (6) feet if scil stability permits
or a new set of sampling locations may be chosen
(Excavations to depths greater than six (6) feet require a
significant increase in work The sides of the hole crust be graded back
to less than 45deg in order to insure the safety of investigatorysampling
personnel It may also be necessary to employ bracing bulkheads etc
for trench support)
Excavation Identification
Proposed excavation Locations have been consecutively numbered
from 1 to 10 beginning at the east end of the landfill They will be
marked with numbered stakes
Excavation Methods
Phase 1 mdash Within each Location personnel will dig a nunber of
small holes - about one (1) foot in depth - to probe for drums If
druns are encountered they will continue to excavate until the drur3
are sufficiently uncovered for characterization
Phase 2 mdash After hand probing the Location with snail holes
the backhoe will remove cover material to the one (1) foot depth The
Location will then be probed to a two (2) foot depth before removing
further material Excavation will proceed alternating handprobing and
backhoe excavation until drums are encountered or the maximum six (6)
foot depth is reached
If excavations to depths greater than six (6) feet are undershy
taken they will proceed using the above method
Santnlea
Due to the effort involved in excavating and because conshycentrated waste samples are not expected to undergo rapid degradation it is considered expedient to obtain all readily available samples (exclusive of closed drum samples -- see belcw) These can then be submitted for laboratory characterization as determined by need and budget restrictions
An attempt will be trade to secure at least one sample froa each excavation in order to help characterize the distrishybution of waste materials across the site An attempt will also be made to secure samples of observably difshyferent materials
Sample Types and Mediums - Solid liquid and sludge samples are possible Samples will be obtained from in order of preference -- 1) leakage uncontainerized waste or contaminated soil 2) waste contained in open conshytainers - drum already has a hole or no top or other access point 3) sealed containers
The opening of closed containers will be considered if it is decided that it has not been possible to obtain a sufshyficient number of representative samples from the other mediums
Each sample will consist of two (2) 8-oz jars (with teflon-lids) filled about 23 full One jar will be for organic analysis and the other for inorganic analysis
Sanole Identification - Samples will be identified with a number corresponding to the Excavation Location and a letter Example if three samples were obtained from Location 2 they would be samples 2A 23 and 2C and Samples 2Ad 23d and 2Cd for duplicates
Sampling Methods and Volumes - 11 mm hollow glass tubing trowels disposable scoops will be available to obtain samples Samples tools will be disposed of or deconshytaminated between each sample
Drum Samples - If necessary an attempt will be cude to obtain samples from sealed drums Oily o^und non-rusted drums will be considered Bunjs rust be xn suitable conshydition -jo that the dram cm be openoi withrut cvis ing dainai -ind ca-i be resell od to pr-jvcrt l V-i 30
There wil l be no staging or movement of drums in order to faci l i tate sampling Only drums with accessible bungs will be considered for sampling
Procedure for Drum Sampling
1) Excavate around top of drum
2) Monitor air in the adjacent area
3) Chec for shock sensitive - Loop rope around top of drum stand at a distance give drum several hard jogs by pulling on the rope An alternative nethod is to lightly jog the drum with the backhoe bucket
4) If the drum is not upright place a catch basin under the bung
5) Open drum with bung wrench
6) Monitor the air atin bung
7) Sample drum -- liquids insert glass tube the fu l l length into the drum in order to obtain a column of the materials in the drum Solids use scoop to dig out material through the bung or use a sampling trowel
3) Reseal the dram
Spill Control
The possibility exists during the sampling and excavation for a
drum to be ruptured or otherwise have spillage Clean drums wil l be on
hand to receive significant spillage resulting frora sampling or excavashy
tion They will not be used for clean up of widespread uncontainerized
waste or existing leakage
Personnel
The work team will require four (4) persons (exclusive of the
backhoe opera tor) Trie downrange team will consist of three (3) persons
-- two (2) for d igg ing and sampl ing and on ( 1 ) for logging air moni shy
toring and photographing One (1) person will be at the hotline in
support mdash as safety backup person to fill air bottles to deconshy
taminate samoles to assist in decontamination of personnel
Documentation Logging
The following information will be recorded at each location
nmber of drums uncovered and the condition (crushed empty rusted
sealed etc) of each drum evidence of spillage or contaminated soil
labels on uncovered drums samples (time drum ID type description)
periodic air monitoring information depth at which specific events
occur or drums are buried soil condition presence of ground water
In addition photographs will be taken of specific events or
items of importance during each excavation and of each sampling incishy
dent The time description of subject photographer excavation
location and photo number will be logged for each photograph
Analytical Laboratories and Schedule
RAI Hampton NH
Initial schedule
Ten samples for GCrns for organic priority pollutants Samples may also be submitted for inorganic anlaysis or volatile organic analysis depending upon waste materials observed during the excavation
APPENDIX A
TABLE A-1 EXCAVATION LOCATIONS
EXCAVATION BASELINE RANDOM RANDOM
NUMBER GRID COORD SEGMENT STATIOH OFFSET
1 7E+1 565N 0- 60 26 (25) 16
2 9E+5 13S 60-120 50 (110) 9
3 8E+0 31S 120-180 20 (140) 7
4 4E+5 483 180-240 50 (230) 25
5 3E+3 45S 240-300 14 (254) 20
6 OE+6 5S 300-360 34 ( 334) 50
7 2W1 5 24N 360-420 45 (-155) 14
8 5W+6 42N 420-480 38 (518) 20
9 6W+1474N 480-540 8 (543) 7
10 8W 5 11011 540-600 11 (611) 31
Locations are plotted on Map A-1
Method of Choice A stratified random sampling method was used to choose 10 Excavation Locations within the magnetic anomaly
The axis of the magnetic anomaly was used as a base line and divided into ten 60 foot long segments Using a randora nirnbers table a distance along each secpent was chosen (Random Station) and a line drawn at that point perpendicular to the base line Again using a random numbers table a distance was located along each perpendicular line by measuring inward from the line denoting the edge of Area A (Random Offset) The Grid Coordinates for each of the Excavation Locations were graphically determined from the grid overlay (this overlay has been surveyed and intersections field located)
It was judged that 10 excavation locations within the magnetic zone and two outside of the zone would be sufficient to characterize the area would produce statistically valid iati and coli be expected to be co~letod within 2-3 days work period
to
80
cu0
cgtc
APPENDIX C
MAGNETIC INVESTIGATION TROY MILLS INC LANDFILL SITE
TROY NEW HAMPSHIRE
For
NORMANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
By
JOHN F KICK PhD GEOPHYSICIST
Box 6 Dunstable Massachusetts 01827
(617) 649-6650
Noverber 19S3
MAGNETIC INVESTIGATION
TROY MILLS INC LANDFILL SITE
TROY NEK HAMPSHIRE
INTRODUCTION
A high resolution ragnetic investigation was completed on the Troy
Mills Inc landfill site in Troy New Hampshire by John F Kick
Consulting Geophysicist The purpose of the investigation was to
delineate the extent of buried steel drums under closed portions of the
Troy Mills landfill The information is needed as a part of a study of
the landfill that is being conducted by Normandeau Associates Inc
FIELDKORK
Magnetometer measurements of total field intensity were made over an
area that was reported to contain buried steel drums and adjacent
landfilled areas that contained unknown waste materials The area of
investigation included capped and grassed closed areas along the south
margin of the landfill site and adjacent areas The fieldwork was
performed during October of 1983
Eighteen parallel rows of measurements were conducted along north-
south lines (using magnetic compass directions) A spacing of 20-feet
was used between rows and magnetometer measurements were made at 10-foot
intervals along the rows Greater intervals between measurements were
used at the ends of the rows and in periferal areas with low magnetic
-JF Kick 01shy
field gradients
A series of magnetic field measurements were made at an adjacent
base station throughout the survey to torn the basis for a daily
variation curve The base station was located at a site with typical low-
gradient background magnetic field intensity measurements
MAGNETIC SEARCH METHOD
Theory Magnetic search methods involve the detection and
measurement of anomalies in the Earths magnetic field caused by the
presence of materials with contrasting magnetic susceptibility Iron and
steel objects generally have very high magnetic susceptibility contrasts
with usual surrounding materials and therefore produce magnetic
anomalies The amplitude shape and detectable distance of the anomaly
depend mostly on the particular susceptibility contrast and size of the
object Magnetic anomalies are measured in units called gammas The
normal magnetic field in this area is over 50000 gammas A 5-inch
screwdriver will produce an anomaly of 5 to 10 gammas at a depth of 5
feet and an anomaly of 1 gamma at a depth of 10 feet A 1 ton automobile
will produce an anomaly of 40 gammas at a depth of 30 feet and an anomaly
of 1 gamma at a depth of 100 feet The magnitude of an anomaly caused by
a single steel drum will vary with its condition (new heavily rusted
etc) Tests using a single light weight (somewhat rusted) drum on the
surface with the magnetic detector at a height of of 12 feet produced an
anomaly in the range of 40 to 50 gammas
Total magnetic intensity disturbances or anomalies are almost always
asymmetrical sometimes appear complex even from simple sources and
usually exhibit the combined magnetic effects of several sources which
can produce a given anomaly The apparent complexity of such anomalies
is a result of several relatively simple functions of magnetic dipole
-JF Kick 02shy
behavior Reasonable assumptions about the geology and buried source
conbined with an understanding of magnetic dipole behavior can usually
lead to a satisfactory qualitative interpretation More detailed
interpretations nay require modeling studies
Instrumentation Field equipment on this project included a EGampG
Geometries Memory-Mag G-856 proton precession magnetmeter The
instrument has a resolution of +01 gamma The magnetic field detector
is separate from the rest of the instrument and is mounted on an 8-foot
staff to provide measurements that are a constant height above land
surface
Magnetic Data Analysis For the purposes of data reduction and
anomaly delineation it was assumed that base station total field
intensity measurements were typical background values for the site
Measurements made at frequent intervals at the base station were used to
prepare a diurnal variation curve for the site Anoraly values were
obtained by subtracting background values from the base station curve
from measurements collected in the area of investigation
RESULTS
The reduced results are presented in the form of a magnetic anomaly
contour map (Figure 1) and two profiles across the area of investigation
(Figures 2 and 3) The map and profiles show that very steep magnetic
field gradients and large departures form background occur in an
irregular shaped band that is about 460 feet long and ranges from about
30 to about 200 feet in width The magnitude of the anomaly is such that
a significant deposit of ferromagnetic materials (such as steel drums) is
indicated
In using the plotted magnetic results it should be noted that the
greatest concentrations of ferromagnetic materials probably do not
-JF Kick 03shy
directly underlie the peak magnetic anomalies A shift is caused by the
inclination of the Earths magnetic field and by the dipolar nature of
ferromagnetic deposits The inclination of the Earths field is about 76shy
degrees northward in the vicinity of Troy The dipolar effect is induced
by the Earths field and results in negative anomalies immediately north
of large positive anomalies
Magnetic Anomaly Map The magnetic anomaly map (Figure 1) indicates
10 positive peaks of varying size shape and intensity Associated
negative anomalies of a broader and less intense nature lie immediately
north of the belt of positive anomalies The configuration of the
anomalous area is indicative of lense-shaped and cigar-shaped bodies of
ferromagnetic materials Steep-sloped anomalies are indicative of very
shallow source materials The thickness of the ferromagnetic deposit
cannot be easily determined on the basis of intensity and size of
anomalous peaks because a small mass of iron or steel at the surface can
duplicate the anomaly caused by a much larger mass at depth The
ferromagnetic source materials can generally be expected to lie north of
the positive peak of anomalies and south of the adjacent negative
anomaly Modeling can provide the best approximations of the depth and
density of the ferromagnetic source materials The outer boundaries of
the source materials can be expected to overlap the positive peak and
negative anomaly somewhat depending on the depth and configuration of
the deposit
For illustration purposes two north-south rows that were profiled
are discussed below
Magnetic Anomaly Along Row 9-East Two strong positive magnetic
anomalies (3645 and 2436 gammas) and adjacent negative anomalies were
profiled along Row 9-East (Figure 2) The approximate centers of the
ferromagnetic deposits are believed to underlie stations 50 north and 75
feet south of the base line The rounded shape of the north positive
-JF Kick
anoraly nay indicate somewhat deeper burial of the ferromagnetic deposit
Magnetic Anomaly Alone Row 7-West Figure 3 shows the most intense
positive magnetic anomaly (4470 gammas) that was detected on this
project The steepeness of the slopes is indicative of very shallow
source materials An uneven burial pattern is suggested by the two-
peaked positive anoraly The negative anomaly south of the two peaks is
unusual and may be related to another positive anomaly to the southeast
(along Rows 5 and 6 20 feet north of the base line) The centers of the
sources of the positive anomalies are probably approximately 80 and 120
feet north of the base line along Row 7-West
-JF Kick 05shy
DISTANCE FROM BASE LINE(FEET)
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APPENDIX D
LABORATORY ANALYSES
RAI
Resource Analysts Incorporated Box 4778 Hampton H 03842
(603) 92^7777
TO PO 830318
Mr Doug DeNatale Date Received 12-2-83 Kormandeau Associates 25 Nashua Road Lab Number 2887 Bedford NH 03102 J
Date Reported 1-3-84
IDENTIFICATION
SAMPLE DESIGNATION PARAMETER
Volatile Organics Analyses by EPA Method 624
Acid and BaseNeutral Extractable Compounds Analyzed by EPA Method 625
Metals Analyzed by Standard Methods 303A
Please see attachments for all results
Results expressed in mgL unless otherwise designated lt = Less Than
ClarkeFosterVan K o u w e i b r h 1 ANALYST DIRECTOR
METHODS Standard Methods (or the Examination ol Water and Waitewaler 15th Edition or other EPA approved mtlhodologiei unless otherwise designated
Phys ica l descr ip t ion of sample
LiquidSludop
Saiple workup
Volitile f ract ion Methannl F-1-rarMrm CSVJ Rdfi-Smm
Semivolatile f ra ictio0onication Extraction fSW 846-3540^ Inorganic f rac t on Acid Digestion (SW 84h-iOS(V)
ACS3 COMPOUNDS
rr t CAS CAS
(71 A) tt-Ot-2 i^t TT i^MoroprvrfgtOi (73B) 30-32-1
(23 A) J9-JO-7 ^bull^^ lof o^^ft^crt gto (7 OB) 205-M-2
(2 A) 13-37 -J 2- chlorophenol (75B) 207-01-
(3 A) 120-13-2 2raquo^icMoroorgtenol (748) 211-01-9
(MA) 103-47-9 2-dimethv lohenol (77 B) 201-94-1
(37A) U-73-3 2- niiroDhenol (7IB) 120-12-7
(MA) 100-02-7 raquo-niiroprienol (7raquoB) lraquol-2raquo-2
(raquoA) Jl-21-3 2 - in i tr opheno 1 (106) raquoi-73-7
(40 A) 33-J7-l k4-dinnro-2-mlaquothylplaquogtergtol (I IB) 15-01-1
(4A) I7-U-3 (xntictiloroorraquonol (I2B) J3-70-3
USA) 101-93-2 pxmol (I3B) 193-39-J
(14 B) 179-00-0 RASENEUTOAL COMPOUNDS
( I B ) 13-32- raquocmlaquophtgtgtefgtlaquo
(36) 92-173 benzidine (2V) 107-02-S
( I B ) I20-I2-I l2t-tricMorobenzlaquonlt (3V) 10713-1
OB) 111-71-1 he laquo laquoch 1 or o benz erve (laquoV) 71-A3-2
(176) 47-72-1 hetraquocWoroltthlaquone (4V) X-23-5
U S B ) 111-- bu(7-cloroetrivl)ether (7V) 101- 90-7
(7CB) 9 I -3J -7 2-Chlororuprthraquolene (10V) 107-04-2
(73B) 95-50-1 l2-diCMoroblaquonzene ( I 1 V ) 7|3j^
( K B ) XI-73-1 13-didilorobtnzene (13V) 7J-3-3
(27B) 104-M7 1tmdash djcMorobenzene dkV) 79-00-3
C2IS) 9i9i-l 33-dictgtloroblaquoazidinr ( I JV) laquo-3-J
(33B) 12I -U-7 2gt-dinicrotoluer (14V) 7J-00-3 (KB) 4O4-7C-7 24-dinitrotoluene (UV) 110-73-1 (J7B) 122-A4-7 1J -diprienv lhydrraquo z irf (23V) lt7 tt 3
(MB) Z0-fc-0 UuorraquonThelaquo (2raquoV) 7J-35-
(W551 700J77-3 -ctilorophenyl prlaquonyl ether (JOV) 1M-40-3
( raquo I 6 ) 10I-J3-3 raquo-6romoprgtefgtyl prtenyl ether (32V) 71-17-3
(raquo7B) 33132-9 bU (2-cMorobopropyl) ether (33V) 10041-02-4
(raquoJ6) i l l -91- l bu (2-laquo^loroeTho)ry) methane 10041-01-03
(B) D-U) hexraquopoundj1|orobutaltlicne (31 V) 100--
(33B) 77-raquo7- heiKCtilorocycIopentadicrve (WV) 7J-CT-2
OB) 7IJraquo-I traquoo oh or or (raquo3V) 7raquo-17-3
(J3B) gtl-20-3 nphthraquolene (UV) 7raquo-I3-9
(546) n-tj) nitrobenzene (7V) 7J-2J-7
(426) U-Xl-4 bullJ -n itr o tod iphenyU mi ne (UV) 75-27-J
(OR) 421-W-7 N-oitrcnodipropYlirrUne ^raquoraquoV) 73-49-k
(446) I 1 7 J I - 7 bu (2-eltr^lheryl) phtfaUte 8200 (3ov) 73-71-1
(476) 13-U7 benzyl buryl phttwlite (51V) 124-kt-l
( U B I M-71-2 di-fl-utgtl pMhUre (13V) 177-II-
( lraquo6) 117-1 -0 dj-n-octvl prithlaquoUte (UV) 101-IS-3
(7CB) W-44-2 dielhvlphtraquollaquo (17V) 79-OI-t
( 7 | B ) I 3 I - I I - J dj^laquorTvipnthraquoUtr (UV) 7J-OI- (776) H-J5-5 bnro(raquogtnthrraquocefvr
Iab I D N o 2SS-10
C l ien t ID 1A64223
RASENEUTRAL COMPOUNDS
bfzoltraquogtprrene
benzoltb)flucrraquornNene
benio(llaquo)fluorraquonthene
chryiene
bullcenaDhthvien
raquontnrraquoctne
benzoltghi)perrlefgte
Iluorene
phergtraquonthrmlaquo
dibenzoltraquoMaithrraquocenraquo
indeno(123-cd)pvrene
prrene
VOLATHES
(frolein
bullcrvlooitrdf
benien
orbon Temchloide
CMorobeniene
1 7-dJchlorolaquothnr
111-trieftloroethine
ll-ltJichloroetrufle ll7-triCilorigtetMrlaquor
l127-tetrraquocMorothfllaquo
chloroethlaquo-e
7-dMoroeThraquo|virgtvl eirwshy
chloroform
11-didMoro^tfwnr
trinj- 1 2-dictMorolaquoirgtene
1 7-ltlicMoroproplaquorve
trini- 1 3-ltJichloroorcrpeoe
cu-lJ-lieMorocT oo eashy
rthy Uveniene
methrlene chloridf
chloromethine
bromome thraquone
bro mod iCTi lore met Mrgt
(Juorotr ichloromthraquor
di cMlor od 1 f 1 uore ngtet hj^gt
chloreltJbnjmomethne
te tr ten 1 or oet rx-r
laquouene 12000
tncMeroethe^e
Cidrr ium Chromiutr 10
All results are expressed as ucg veicht as received Nc ertrv denotes -0r ~ ^ 1 i rt
P h y s i c a l d e s c r i p t i o n of
SoilSludge
sample
Sanple workup
Vol i t i le f ract ion p^r Exf- rar r ion fST7Semivola t i le f rac t ion So^h^Pt Fgtr f ra r f ion
846-SOTO^ (SWRdfi-^SiO1)
Inorganic fract ion Ar id nio-psrirm
AOD COMPOUNDS
m CAS (2i A) tt-04-2 2raquot- Wichlorophenol
(22 A) J1-50-7 p-cfi I or o-n-cre laquoo 1
(2A) 13-57-1 2- ctiloroprienol
O iA) 120-13-2 2raquo^icMoroprnol
(gtraquoA) 103-47-1 2f 4mdash^imetSv Ip^enol
(37 A) U-73-3 7mdash Ti j oprtenol
(JraquoA) 100-07-7 mdash mdasho i Br opr^e no 1
JJ1A) 31-21-3 if mdash4 irtiTroprienol
(40A) J34-32-1 4 T4-4initrogtmdash 7 nte tny Ipnenol
(4A) f y _H 5 plaquontchlaroorwnol
(43A) J 01-95-7 prienol
rV ipoundNEUTRAlaquo- COMPOUNDS
( I B ) raquoJ-32-raquo
(3B) 17-17-5
( IB) 170-12-1
(IB) 1I1-7I-I
(17B) 4777-1
( I t B ) 111--
(20B) 11-31-7
(236) 15-50-1
(245) 51-73-1
(77B) 104-4-7
(285) 11-14-1
(336) 121-142
(34B) 404-70-2
(J7B) 127-M7
O1B) 2O4--0
(406) 7003-72-3
(416) 101-35-3 lt raquo 2 6 gt 3H3I32-1 ltraquo36) 111-11-1 (57B) S7-U-3
(336) 77 -raquo7-
(36) 71-31-1
(33B) 11-20-3
pound34 6 1 n-i33 (UB) tt-30-4
(436) CI-44-7
(4461 117-11-7
(47B) U-417
( U B I 14-747
(U6) I17_t-0
(7CS) l-laquo2
(7 I B ) t J U t l - gt
(7761 54-55-3
CT-~- i_i w i Miirn 0
resul ts
b^TMdint
1 2 t-o- icn lorobenl ergtlaquo
SeTraquochloroblaquorierraquoe
hrxchlorolaquotSlaquone
bu(2-chloroethv|gtether
2 -lt3M or onraquo ph ti1 ene
1 2-ltJictilorotgtmzcne
13-dicWorotxerzene
1 4-djch 1 or otxn z ergte
33-ditfgtlorolgtlaquoniidirraquo
24-dinitrotoloene
2 4-dtnitro toluene
U-dlpoenylfiydrraquoiilaquo
(luoranthene
raquo-cfJorophenyl poenyl ether
Mx-omopfieflyl phenyl ether
bis (2-cMorooopropyt) ether
bu (2-ctilorcxtSorv) meiSkte
hezkOilorobutadicne
hei acM or ocyc1 ofMn udi cne
oo prior one
nphthlene
nurotxniene N -ni tro Kxd ipoenyU mi ne
N-rutrowxhpropYUmJrw
bu (2-thylherl)(gthlaquoiraquoUtraquo
blaquoniyl buryl phtfraquolaquoUte
dt-^t-^xjrvl pfttfuiLitY
dj-n-octyl pitflaquoLitraquo
dirthvl phtruUtt
OArriett^vt prraquoT^Lraquot
bnzoltklaquonihnicer
22 Chronium
ire ev^rescei as uc ^ ^i-~ht-
Lab 1U N o 28B-1
C l i en t I D 1 R R 7 A A R
RASpoundNEbTRAL COMPOUNDS
benroltb)fluorraquorgtthfflf
benzoraquollt)fluor intone
ltrylaquo-gte
bullcenioithylen
raquomtirraquoenlaquo
ben z oltxh i)per v lene
lloorene
poentnthrrne
dibnzo(4h)laquonthricrne
mdeno(I23-rt)pvre-ie
pyrene
VOLATU-Ei
bullcrelem
bullcrvlonio-Ue
benzene
caj-bon traquotrraquochloraquo-idr
Ctilorobernene
l2-diehlongtethne
iii-tnctltiorotKraquor Trace 1 T 1 -4)Ctilorampe^hArw
l f 1 ^-tric^i lor oefvtrve
l t l 22-teTrtclloroetl^Ane
ehloroethraquone
2-chloroltthr|viw| ttrve-
Chloroform
1 1 -ltSicMorot^nr
trinraquo-l2-dictiloroetrne
12-d^loropOStn
trinil3^ichloroproone
eis-lJ-diChloroprooene
rrhylberuene Tarce methrlene ehlor tat Trace
Ct1 or o m e t Kirgte
bromometKtrte
bro mod i rfi lor o rrgte t Mne
Uuorotrlchloromethraquo^e
OJ CJ lor od 1 f 1 uoro met hraquone
chJorodibromometKATgte
laquotrlaquociloroethrrx
toluene 9
tricolor otheir
fsw
T9
Sifi-TOSO)
(73B)
(7IB)
(75B)
(7(B)
(77 B)
(71 B)
(71B)
(SOB)
( t lB)
(I2B)
U3B)
(M B)
(7V)
(3V)
(4V)
(4V)
(7V)
(10V)
(11V)
(13V)
(14V)
(13V)
(14V)
(11V)
(23V)
(21V)
(30V)
(32V)
(33V)
(34V)
ltlaquoV)
( raquo J V )
(44 V)
f raquo 7 V )
(UV)
(V)
000 (30V)
Tlfl 151V)
(15V)
^00 (14V)
(17V)
(UVgt
-1 ZINT
CAS 30-32-J
205-11-7
207-01-1
211-01-1
201-14-1
120-12-7
111-24-2
14-73-7
13-01 -laquo
33-70-3
113-31-5
121-00-0
107-07-t
107-13-1
71-43-7
34-23-3
101-W-7
107-04-7
71-35-t
75-3-3
7^-00-5
71-34-5
75-00-3
110-73-1
(7-14-3
73-35-4
154-40-5
71-17-5
10041-07-6
10041-01-05
100-4I-
73-OT-2
74-17-3
74-13-1
73-25-2
75-27-4
73-41-4
75-71-1
174-41-1
127-U- IOUIS-) 71-01- 75-OI-
130
Lab ID Mo 2887-4
Phys i ca l d e s c r i p t i o n of sample C l i en t ID 4A5760
Liquid Sample was predominantlv a hvrlrnrarhnn bl pnd
Sanple workup Voli t i le f ract ion PEG Extraction (SW 846-5030) Scrnivola t ile f rac t ion Sonication Extraction (SW 846-3550) Inorganic f rac t ion Acid Digestion (SW 846-3050)
AC3D CS3U POUNDS 5AipoundNEUTlUgtJ- COMPOUNDS
ri CAS PPraquo CASf
(210 U-04-2 2raquot- tricMorophrnol (7)6) raquo-32-l braquoniolttVyre
[EM 51-50-7 ^-cti 1 or raquo-m-lt rlaquo laquoo 1 (7raquoB) 203-M-2 biMo(b)(luorinth^f
2 A) raquo5-57-J 2- cfiloropheryjl (7 3 B) 20701 benro(ilt) floor in tlaquo^e
(31 A) 120J3-2 2raquo-ltJicWoro(ygtlaquotx)l (74B) 2II-OI- chryve^e
(MA) 105-47- 2l-dimlaquothvloSrrgtol (77 B) 20Uraquot-J bullcwrioMhylene
(57A) u-73-3 2- ruTroohrgtol (TIB) 120-12-7 raquontnncergte
(34 A) 100-02-7 -oitrophenol (7gtB) lraquol-2raquo-2 benio(ghi)cgtrrylngtlaquo
(3Agt 51- 21-3 2 -4 initropherwl (SOB) tt-73-7 fluorme
(tOA) 53-37-l t-dinitro-2-mlaquothy lpNlaquoxil (II B) 15-01-4 pheAinthrrnlaquo
(A) I7-U-5 tgtentraquochlQroiywnol (I2B) 53-70-3 dibenplusmnoltraquoh)fcnthrraquocrne UJJ 101-55-2 rfwtwl (I3B) lraquo3-3raquo-3 indenol 1 23-cd)vrtie
(UB) I2raquo^X3-0 pyrer BASENEUTOAL COMPOUNDS
VOLATO-ES (161 I3-32- raquoclaquonraquophttgtngtf
(5B) 12-17 -J btniidir (2V) gt 07 -07-1 bullcrolem
(IB) 120-17-1 l^^iricfvleroboMux (3V) 107-13-1 bullcrvlonit Jlaquo (raquoBI IIS-7t| SeraquoChlorotgtlaquoterlaquo (raquoV) 7IJ3-7 benient
(I7S) 4772-1 heLCMorolaquothinc (tV) J-23-5 crtgton wtrraquocMoidf (UB) I11-U-I bll(2lttllorolaquot^w gtetNer (7V) 101-W-7 ltAtoroxniergtlaquo
(203) Jl-31-7 2 -etvl or onlaquo ph traquo I en e (IOV) 107-04-2 1 2-ltlicMorolaquoTKlaquone
(25B) raquo5-30-l 1 2-dichlorobenzene ( 1 1 V ) 71-JJ-t llI-trichlorolaquotNlaquoe (2 B) 31-73-1 l3-ltlichoroblaquonzenlaquo (13V) 7J-3A-) 1 1-6 1 cM or Of t (Mr
(77B) I04-M7 I -di CM oro ben z eoe ( I k V ) rraquo-oo-j l12-niichlorolaquotfvirraquolaquo
(2IB) raquol-raquo-l )J-dichlcroblaquorLiidinr (IJV) rgt-3laquo-3 J122-tetrraquochlcrolaquoTrie
(33B) 12I-Ilaquo 2 2-dinia-otoluer (UV) 73-00-3 Ctgtloroltthne U4B) laquoJ-70-7 2 t-dtnitrotoluene (1raquoV) HO-73-1 2-ltJilorocthv|vL-v| etrveshy
(J7B) 127-M7 14-dip^wnylhydraiine (23V) C7-U^-3 Ctilorofcrm
(JraquoBJ 2Ot-ugt-0 CJuarlLnthefe (2raquoV) 7J-33- 11 -ltlicMorcxil^nr
(mei TOCJ-77-3 -chJorophcnyl phenyl laquoKr (xgtvraquo lK-^0-3 tnjM-l^-diC^lofCKtl^nf
( M B I IOI-J5-3 -6romophnyl phenyl ether (32V) 7I-J7-3 12-dicMoroprosaA
(raquo2B) 3M3I32) bU (2-cMarobopropyU rtNer (3JV) ICXU 1-07-4 trraquoni- 1 3-ltjictgtloroBoor^f
(OB) t l l f l - 1 bi5 (2-cMoroetfxgtrv) meihtrw lOOt 1-01-03 cu-O-dichloroprose- (32B) D-U-3 hrxaetilorobutadierw (UV) 100-laquol-raquo rthylbenien 1^00
(33B) 77^7- he i kcMor ocyc 1 openudi crw (UV) 7J-OT-2 rrveThvlerw chlof idf
(36) 7I-gtraquo| oop^troo (raquoJV) 7raquoJ7-3 CtgtlorBmethne
(338) raquo|20-3 nraquopfitfillaquofx 1200 (wv) 7raquo-l3-raquo bromorrgtlaquothne
(34B) nraquo3) nitrobenzene (raquo7V) 73-23-2
(CBI U-Xl-4 N -fl i iro lod iphen yU mi nr (UV) 7J-27- bro mod i cti lor o mT bull- (OR) 42l^-7 N-^itrolaquoodipropylmlrlte (raquoraquoV) 73-traquo-laquo tl uor o tr i cfi lor o mlaquoT itr (UB) I I 7 J I - 7 bn (^thylheraquoy|) phttilaquoUtT 110000 (XIV) 75-71J QJ ct )or oltJ 1 f 1 uoro rrgtei ^bull gte U76) U-U7 blaquonzyl buryl pttTfKUie 12000 ( j i v ) m-i-i ctil or od ib ro mo met h xnf (UB) M-7i2 d i -n -bo TV 1 ft thlaquo U tlaquo (13V) 127-11- te trraquo cfl lor ot hlaquoTgtf (OBI 117-4J-0 dj -n -oc t y1 Jgth fflaquo U re 6 200 tuv) iom-3 tolucie ^70
(7CB) u-u- djrthyl phtJMlire (17V) 7raquo-OI-4 irictilarcraquo^lt-ir (715) 1 3 1 - 1 1 - 5 oVnrrhyl pMtfaUte (UV) 75-OI- v i M v l CMor idr
(T76I 5-55-3 blaquorgtzo( Unihrlaquocme Xylenes 1SOO
Cad- iurn 2 2 on Chromium - - Z I N C ^ ~ P r
Ai results arc expressed as ugc weight as received Xo entry denotes not detects
Lab ID No 2887-3 5A 57709 Phys ica l d e s c r i p t i o n of sample Cl ien t ID
LiquidSludge Liquid appeared to be a hvdrnc-Arhnn blonrl
Sample workup
Vol i t i l e f r ac t ion Methanol Extraction fSW 846-5030^ Semivolatile fract ion Sonicatlon Extraction fSW 84 f i_3550gt) Inorganic f rac t ion Acid nic-psr-inn fSW 846-30501
ACS3 COMPOUNDS BASENEUTRAL COMPOUNDS
f f t CAS CAS (2IA) tt-04-2 (738) JO-32-J DCftZ OTamp p V^^^ff
(22 A) 3laquo9-50-7 p-cttl or o-m-cre laquoo 1 (7VB) 205-99-2 p^^izot oil lyor 4-^ t ^ltf ^^
(2 A) raquo5-37-l 2- CJiloroprieno (75B) 207-01-9 blaquonioltllt)flultxtn^it
(31A) 120-13-2 2raquo-dictgtlcr8tgtrfX)l (74B) 211-01-9 Chryeolaquo
(3 A) 103-47-9 2 -d irrgtet hv Ipherto1 (77B) 201-94-1 laquocnphthyle^
(37 A) 11-73-5 2- rutrop^enol (7IB) 120-12-7 bull^thrjc c^
(MA) 100-02-7 -flitroprlaquorv3l (79B) 91-2-2 bcnroltKhi)pefraquoler
(79A) 31-21-3 2 -d in itr eoricno 1 (IOB) 14-73-7 tluoren
(40 A) 33-37-l 4-d in itr raquo-2 -met hy Iphtnol ( I IB) 13-01-1 poltrtAOthrvTgt^
(44 A) 17-14-3 plaquon1 CM or o^eno I (I2B) 33-70-3 dib^fi-o( 4(K)Aji thirl c c^f (43A) 101-93-7 prwnol (S3B) 193-39-3 indcnotlIJ-ctflsvfie
(SB) 129-00-0 pyrene ftASENEUTRAL COMPOUNDS
( I D )
(5B) 92-X7-3 b^zidrw (2V) 107-02-1 bullcrolrm
(IB) 120-17-1 1 2 fc-Tr ICJ caro blaquoni crw (3V) 107-13-1 bullcrvlonitrij
(93) 1IU7I1 Seraquochlcrotgttniegtlaquo (4V) 71J3-2 blaquonienlaquo inn (17B) 4777-1 hexat^lorcwthgine (4V) H-23-5 carbon ttTricllixidf
( I I B ) 111-wJ bll(2-lt3^1oroltt^w)ether (7V) 101-90-7 ciloroblaquonzene
(20B) 91-31-7 2-ctdo-ont she Ime (10V) 107-04-2 12-dieftloroerane (25B) 95-50-1 l2-dilorobenzene ( 1 1 V ) 71-35-4 11 1 -tricMorotn-laquo
(2ampSI 51-73-1 13-dicMo-obenxerw (13V) 73-3-3 1 1 -d i CM orcxt M-
(77 B) I04-H-7 1 -di ci 1 or o benI erw (UV) 79-00-3 llJ-WiChlorolaquoflaquonlaquo
(2J6) 91-90-1 SS-dKJilorotxniidinc (13V) rraquo-3laquo-3 l122-tetrlaquocftlorelaquoTrne
(35B) 12| |k-2 2fc-dintrotoluene (14V) 73-00-3 diloroeth^e
(gt4B1 404-20-2 24-diniTrotoluenlaquo (19V) 110-73-1 2-cMortxfthv|vL-raquo trlaquoshy
(37B) 122-447 12-diphenylhydriin (23V) 47-44-3 cMoroform
(J9B) 204-U-0 Ouormntherve (29V) 73-33-i ll-diCMorolaquot^nf
(fcOB) 7005-77-3 k-cMarophfy| prlaquonyl etScr (gtOV) 134-40-3 trraquonraquo- 1 2 -dicMoroc t Nenf
(raquo I6) 101-35) raquo-6romoprny| phenyl rther (32V) 71-17-3 12-diChloropostn
(raquo2B) JH3IO2-9 bU (2-ltplusmnlaronopropyl) rthrr (J3V) 10041-02-4 trni-l)-diirMoroxtgtOpnf
(OB) I I 1 - 9 I - I bu (Z-chloroethxjrv) metSampnlaquo 10041-01-05 CU-D-djcMoroproOf-W
(32B) 17 -U -3 hiraquocfilarobutraquodiergtlt (3JV) 100-4U rttyligtlaquonitrgtlaquo 5300 (33B) 77-raquo7-raquo hrxicftl or ocrclopei tidier (UV) 75-09-2 nxthylenf ctilor ifif
lt3B) 71-391 ao prior or (raquo3V) 7raquo-17-3 rtloromrtha^r
(356) 91-20-3 nlaquoprithienraquo Trace (44V) 7raquo1Jraquo bromltmlaquoth^
(MB) n-93) ft i vo b^nz c^^ (raquo7V) 73-23-2
(425) U-30-4 ^bullf i^OftOOL^ri^ny lArrunf (UV) 73-27- bro mod i cgt lor o i~ t gt
U3amp1 Ul-4-7 N i itr CrtoO ip ro py 1 laquo ml r (raquo9V) 73-49-k U uor o IT 1 et loront Mrgt (UB) II7-1I-7 bu (2-Ihythlaquoryl)prtfUtr 59J300 (30V) 73-71-1 dj ci kr olt11 f 1 uoro rrrt (Nrgtraquo
(47 B) L3-41-7 txniyl burvl phthlaquoUtr ( 3 1 V ) I2-1-1 ch1 or od i b ro mo mi IMP r
(UBI U-71- 0-A-fcurl BMMliw (13V) 127-ll-i rt tr t cM or of tNr
Uraquo6) 117-li-O di-n-oCTv| pnttlaquoUfr 6000 (UV) lOt-II-3 toluenf 5700 (7CB) U-447 djrthvl p^tfvilirt (17V) 79-01-4 WiCMoroth^e ( 7 J B I U l - l l - 3 d^M^vl prttgtraquoUW (UV) 73-01- vinv t cMor 10 (77 Bgt H-35-) brto(raquollaquonthncrTraquo Xylenes 19000
Caen 1U~ 1 Chromium =2 Z I N C
All results are expressed as up g weight as received No errrv ripn^t-plt
Lab 1Lgt No 2887-5
rhyr i r n l d e s c r i p t i o n o f sample C l i e n t in 6857710
LiquidSludge
Sample workup Vol i t i l e f r a c t i o n PEG Extraction (SW 846-5030) Semivolat i le fr action Sonication Extraction (SW 846-3550) Inorganic f rac t ionAcid Digestion (SW 846-3030)
AOD COMPOUNDS BAStNELTTRAL COMPOUNDS
rr i CASI CAS (21 A) tt-04-7 (736) 30-32-1 bntoltraquogtprrene
(23A) 3-9-50-7 p~lt1 or o-m-c rraquo1 (78) 205-99-2 ben to( Sgt )1 1 uor raquon I he-gtf
(7raquoA) 93-37J 2- etilorophenol (73B) 207-01-9 beriioltk)(luortntrgt^f
(3 IA) 170J3-2 2raquo-dicMoroprnol (7(B) 2II-OI-9 eifVMTie
(3 A) 03-(7-9 24-4mlaquoThvlDheno| (77B) 20l-9(-i bullceraoMhyler
(37 A) tt-73-5 2- rue-oorienol (718) 1 20- 2-7 laquoflthrraquocene
(3 A) IOO-02-7 ^Mtroprwnol (7fB) 191-24-2 beraquoMoltsrM)plaquovllaquox
(39 A) 3I-71-5 2-4 ini tr ophero1 (tOamp) K-7J-7 tluwtrie
((OA) 33-37l (-lt iMtro-2-methylphenol (tlB) D-01-J phenATithrene
(4A) I7-44-J pentichlorophenol (128) J3-70-3 dilwnioltraquoh)laquonthrraquoceif
(OA) IOI-95-2 prwnol U38) 193-39-3 indeno(123-cd)vcne
(MB) 129-00-0 pyrergtlaquo 6 ASENEUTILW- COMPOUNDS
VOLATH-tS ( I B ) 13-32-9 ftCYTNA pO IT H I raquolt
(38) 92-17- o^nzioinc (7V) 107-02-1 aero le in
( IB) 120-I2-I l2k-o-i(3iloroblaquontergtlaquo (3V) 107-13-1 laquocrvlono-U
OB) Jl l-7fc | he I raquocti 1 or o blaquonI enlaquo (V) 71-43-2 Oltf2 tO^
(17B) (772-I he uc^i 1 or of t h ne ((V) 34-23-3 CJU JOO Tt TTlCfllo^ iCpound
( I I S ) bu(2-rfilcroethv|)ether (7V) 10J-90-7 laquoWoroblaquonzeoe III-44-4
(KB) 9I-51-7 2ltfMoronlaquoohttvraquolwe (10V) 107^)4-2 1 t2^ojo^loroetfft^c (2JB) 95-50-I 1 2 -dichlorotgtlaquorlene (11V) 71-55-4 1 1 1 -trichloroeihtr (251 541-73-I 13-dchlorotxniene (13V) 73-J4-3 1 1 -dieMoreeraquohraquorlaquo
(77Bgt 04-lgt4-7 1 mdash djcMorobenlene (IkV) 79-OO-3 t12-tricriloroeflaquofgte (2gtB) raquolraquo-l 33-didMoroblaquonjidirlaquo (13V) 79-34-3 1122-tetrcnicroeir^ne (33B) 12 I I 4 -2 Z4-diniiroioluerlte (1(Vgt 73-00-3 e^loroetruuie (KB) (04-7C2 2 (-dinitro toluene (19V) 110-73-4 2ltJilorolaquotr(v|vLnraquolnhlaquo (175) 122-447 12-dipr-enylfiydrmiine (23V) (7-44-3 chloroform
(J1B) 704JJ-O Huor^thrr (29V) 73-33-4 lI-ltJicMoroltthcne
(OBgt 7003-77-3 -ctJoroprienvl phenyl ether (JOV) 134-40-3 irirraquo-12-dictila-olaquotrlaquone
( raquo I B ) IOJ 33-3 -6ogtmoprienyl phenyl ether (32V) 7I-I7-3 l7^lichlorepreoine (laquo2BI 3H3raquoO2raquo bit (2-chlororaquoopfT5pyO ether (3JV) 10041-02-4 trint-l3-ltJicnloroBlt-ooee (OB) 111-11-1 bis (2-cMcroetro(v) metSuvr 100(1-01-03 CU-lJ-itflloropOO-^
(376) t7-U-3 hraquoz raquoch1 or o bu tlaquodi ene (J1V) )00-1- erhylberuer 1400 (33B) 77 -gt7- hei tchl or ocyc1 open traquodi ene (raquoV) 73-09-2 methylene chloriCf OB) 7raquo-3raquo-l BO prior one (raquo3V) 74J7-J eMorametrutne (33B) raquol-raquo-3 naphtfalene 100 (UV) 74-13-9 bro rrvome t hrgt (3iB) n-raquo3-3 niireblaquor)iergte (raquo7V) 7J23-2 (CB) U-XH N -01 ITo tod 4gthenyU rru rr (UV) 75-27-4 bro mod i ch lor o rrx t f4Ugt ((36) 42IO4-7 N-nnroodipropYlraquomlrlaquo (raquolaquoV) 73-4t-4 JJuorotr lchloronvlaquoiMftlaquo (Uol U7-1I-7 ba (2-etrylNraquoYl) phtt^Ure 100000 (30V) 75-71 -raquo dj cftlcr od U 1 vraquooro rri NUT
(47 Bl 13-44-7 t^niyl butvl phthiUte 13000 (31V) 124-41-1 chlorodibromorrwt^r
lt U E gt ) U-71-2 d-ojjurvl phtf^Ure (13V) 127-11-4 tr trbullcti loro rirr
laquoraquo6gt 11704-0 dl-fl-OCTvl pfltMUM (UV) 10t-ll-3 toluene fiin (TtS) raquo-laquo djrthvl phttuliTr (17V) 79-01-4 tricolor oethenr lt 7 | o l 131 -11 -1 (UV) v i n v i chlcwidr dimrlKyl rrftlaquoUTraquo 75-OI-J
(T75I J4-35-J blaquoTMOlt^trrlaquocr^ gtylenes 1200
Cadr ium 3 Chromium 21 ZINC 150
All results are expressed as ugg weight as received y0 entry denotes not detect
Iah I D No 2887-2
Physical descr ip t ion of sample
Strained Soil
Sample workup
Voli t i le f rac t ion PFG Extraction (^W 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-3540) Inorganic fract ion Acid Digestion (SW 846-3050)
ACS) COMPOUNDS
rn CAS Tft CASf
(21 A) tt-04-2 (73B) 50-32-4
U2A) 71-50-7 P-ch 1 or o-m-cre laquoo 1 (7k 8) 205-11-2
(2 A) raquo3-37-l 2- chloroprraquoeno| (75B) 207-01-1
(3IA) 120-13-2 2raquo-4ichlorophenol (74B) 21UOI-1
(3 A) 103-47-1 24-dimethvlphenol (77 B) 201-14-1
(57A) U-75-3 2- njtroDhenol C7I5) 120-12-7
(MA) 100-02-7 a-flitrophenol (71B) |1l-2raquo-2
(51A) 51-21-5 2 -d in i tr o phetio 1 (SOB) K-73-7
(40 A) 53-57-l raquo 4-dinitro-2-methy lprnol (tlB) 15-01-1
(4 A) 17-14-3 plaquoitraquochloroorlaquonol (I2B) 53-70-3
(43A) IOt-13-2 prlaquonol (13B) m-31-3 (MB) 121-00-0
BJ KSENCLmLAL COMPOUNDS
(IB)
(3B) 12-17-3 bcnzidine (2V) 107-07-1
(IB) 120-17-1 1 2 k- tr i ch 1 oro benr ene (3V) 107-13-1
(IB) I1U7I-1 he it raquocM or o boiz ergte (raquoV) 7I-J3-7
(12B) 47-77-1 he traquoch 1 or oet hlaquo ne (4V) 54-23-3
(116) 111-- buC-cJiloroethv|gtether (7V) 101- W-7
(20B) 11-31-7 2 -ltft 1 or on ph ttvraquo 1 laquon e (10V1 107-04-2
(23B) 15-30-1 1 2 -dictilorobeni ene (11V) 71-55-4
(25) VI-73-1 1 3 -ltJ i ci 1 or o blaquoiz ene (13V) 73-3-3
(77 B) 104-M7 llaquo-dchloroblaquoMeoe (HV) n-00-3
(2IB) 11-lk-l 33-dicMorotxTLtidinr (15V) n-3raquo-3 (33B) 12I-U-2 2 ltgt -4 in i tr ot o luene (14V) 75-00-3
(MB) 464-20-2 2 4-d initrotoluene (11V) 1 10-7 3-1
(J7B) 122-447 1 2-diprieny Ihydrti ine (23V) 47-44-3
(316) 2O4-UO Ouorraquonthene (21V) 73-33Jshy
(WB) 7t)03-77-3 ^-cJJorophenyl prienyl ether (JXgtV) 154-40-3
(MB) 101-33-3 -6romopriefgtyl prienyl ether (32V) 71-J7-3
(raquo2B) 3431-32-1 bit (2-chloroboproprO ether (33V) 10041-07-4
(OB) I1U1I- I bu (2-ltMoroethorv) methane 10041-01-03
(52B) r-u-3 hexachlorobutadiene (J1V) 100-l-raquo
(33B) 77-47- he z raquoctlt lor ocycloqenud i crte (MV) 75-01-2
OB) 71-31-1 ao prior one (raquo3V) 7raquo-17-3
(33B) 11-20-3 nlaquopntrlaquollaquone (UV) 7raquo-13-1
(MB) n-13-3 nitrobenzene (raquo7V) 73-23-2
(UB) U-30-4 N-nnroiodiprienyUmine (UV) 75-27-k
(436) Ol-U-7 N-nitrModiproOYlmJne (raquo1V) 73-41-
(UB) 117-117 bu (2-laquothylheiry) phtrlaquolte 8800 (50V) 75-71-1
( 4 7 B ) L3-U7 blaquoniyl buryl phthaUte 30 (31V) 12I-H-1
(UB) U-7U-2 di-o-burvl phtrMUte U3V) I27-I1-
(416) II7-U-0 dj-n-oCTvl pritntUtr 1200 (raquo4V) IOUI1-3
17CB) U-44-2 djetiTi phrtultrt (raquo7V) 71-01-4
( 7 I B I 1 3 1 - 1 1 - 3 dimnfTraquo| prThraquoUtr (UV) 73-01-
(776) H-35-3 berMolta^thrCF^
Cl ien t ID 8 A - S 7 4 6 1
RASENEUTRAL COMPOUNDS
benzofbtfluor^tMe
benzodclfluorintoent
Ctiryiene
cenoithylene
raquonthrraquoctne
benzoltKhilpervlefgte
floor ene
prlaquofnnthrene
ltlibenplusmno(4h)knthricrnlaquo
inogtno(123-rt)pvrrne
pyrene
VCX-ATIIE5
bullcrolem
bullcrvlomn-U
benzene
carbon tetrtchloridf
chlorobenzene
1 2-oUchloroethAnf
lll-trichloroethlaquone
ll-dcfioroethrraquo
1 1 2-tricilorolaquothraquorw
1122-tetrichloroeTtvin
chloroethre
J-ctiloroethv|vinv| etrgte
chloroform
11 -denier oethene
trinraquo- 1 2 -4 cMor oe t hens
12-dcMoroprooine
^Lns~ I f 3-4ic^ lo^opf oo^^^
Cli-l 3-dicMoroprooe^e
rttiylbenzene
methylene cnlonfle
Ch 1 or o me t hane
bromome thane
Trace
bro mod i cMor 0 me t hane
(Juorotrlchlorome thane
chlorodibromometKinf
tetracnloroethervp
toluenetr icMoroel he-if
Trace
CacTiiun Chromium ZINC f
All resxil ts are exprp^spr i K-i
Phys ica l de sc r ip t ion of sample
Strained Soil
Sample workup Vol i t i le f ract ion PEG Extraction (SU 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-5340) Inorganic fract ion Acid Digestion CSV 846-3050)
ACE) C30laquo POUNDS
m CA5i CASraquo (2i A tt-C-2 (73B) JO- 52-1
(22 A) J1-JO-7 p-ch 1 or raquowTv-cre 101 (7raquoB) 203-raquoraquo2
(2 A) raquo)57-J 2- chlorophenol (73B) 20701-
(31 A) I25J3-2 2k-4icttlltroptlaquonol (7tB) 211-01-1
(3A) IO)-7-raquo 2-dimlaquothvlpNrnol (77 B) 20l-raquoi-
(37 A) u-rj-j 7- niTTOphenol (TIB) 120-11-7
(MA) 100-02-7 -rtropN-rraquol (7raquoB) lraquol-2-2
(JraquoA) JI-21-) 2-d initroprietys 1 (IOB) U-73-7
(MA) 53-37-l Udinnro-2-mlaquothylphenol (UB) I5-OI-J
(Agt I7-U-3 pentichlcropwnol (126) 33-70-3
laquo)Agt 10l-raquo)-2 phenol (I3B) IJ3-31-3
(MB) 12raquo-00-0 AASCVflCUTRAl COMPOUNDS
( I B ) I3-32- bullcnraquophtber
(56) raquo2-17) bnzidirlaquo (2Vgt 107-02-1
(IB) 120-12-1 l2btrilt7tlorotgteizegtlaquo (3V) 107-13-1
traquoB) IIraquo-7fc | heikcMeroblaquonzergte (V) 7l-3-2
( I 2 B ) 4772-1 he ueft 1 or olaquot hraquo rgte (tV) laquo-23-3
( i ts) III-- biraquo(2-cMoroethv Dethrr (7V) 101-W-7
(20Bgt 1I-3I-7 2-cMoroflaquophthlene (10V) 107-Ofc-2
(2)6) raquo5-50-l l2-dchlorotgtlaquonzefgte (11V) 71-33-4
(28) 3l-7)-| 1 3-didMoroblaquonrenlaquo (13V) 73-3-3
(27B) 10t--7 l-diclorolgtmzerlaquo (iV) rraquo-00)
(216) raquoI raquoltbull- 33-dichloroblaquoMidiflaquo (13V) 79-31-
(356gt 2I- l-2 21-dinitrotoloen (UV1 73-00-3
(UB) laquogt- 20-2 2 (-dinitroto luenlaquo (HV) 110-7J-J
(376) 122-W-7 14 -dipheny Ihydrzire (23V) lt7-M-3
(396) 2O--0 tJuoruMSene (2raquoV) 7J-35- (OB) 7003-77-3 -c^lvophenyl pNrnyl ethlaquor (30V) 1H-W-)
(MB) 101-33-3 bull-bromopriefiyl prienyl ether (32V) 7t-t7-3
ltraquo25) 3HJI-32-1 bU (2-cMoroaopropyl) rthrr (33V1 10ltX 1-02 -6
(06) l l t - t l - l bis (2-cftloroetSorv) metwne 100lt]-01-03
(32B) C7U-3 heraquoraquochlorobutidierx (31V) 1 00-41-
(3361 77-7-raquo hexiOilorocycloptfiudlerve (raquoV) 73-0raquo-2
(56) 71-51-1 no ph or one (raquo3V) 7raquo-17-3
(3)6) raquol-raquo-3 rwiphtfalme (UV) 7raquoJ3-raquo
1361
LUB)
H-133
14-30-4
nitrobenzene
^ ri i iy o too ipf^^ y LA r^i rtf ^ 7V) (UV)
73-23-2
73-27-
(436) t21--7 M^TI iff frfcO^ip ropy Ift mJf^ (gtraquoV) 73-4raquo-raquo (UB) I17J1-7 bu (2-rThyiruMcyDpMtvUtr 570 (jov) 73-71-1 ( U B ) U-41-7 blaquonzyl buryl phthlaquoLite (31V) l2k-raquo-l ( U B I U-7I-2 di-n-burvl pitftALtTe (raquo)V) 127-lt-fc
(OB) 117- -0 dJ-fraquo-oCTvl phlJ^Ute (UV) IOt-It-3
(7CB) 14 -W- 2 djelftvl phtfalitt (17V) Tt-01- ( 7 I B I 1 J I - I 1 - ) duTNnhylphttsraquoUw ltUV) 75-01-
(77BI X-))O lgtmrlaquoigtmhrraquoctf
Cadmium f iQ Chromium 15 ZINC
Tab ID No oo -
Cl ient ID 8A-A-64220
fcASENEUTTRAL COMPOUNDi
blaquofuo(raquo)pyrrtgte
bfizo(b)(loortAth^e
benzo(k)f|ulaquoin1herf
Ctiryiene
cenDraquoMrwlene
fcftT^rict^t
D^flZCT (fftl)pC^ V Itf^p
(luorene
phen^threne
diiwnztKthlanthricene
indlaquono( 1 23-lttf)pvrene
oyrene
VOCATtLES
bullcrolem
bullcrvlooitriJe
bervteoe
carbon WTTicMoridf
chlorobenze^e
12-djcMoroetfane
1 1 1 -tricolor ex tKraquon
1 1 -dicMarcx t hrlaquo
1 1 2-triChlorothraquorw
1 122 -laquotrraquocM or o-hraquorgt
cMoroettu^e
2-cMorlaquothv|vuy| rseshy
chlexeform
ll-dchloroctfgtn
tri^iraquo l 2laquoflic^ loTo^i rgtcnt
12-dicWoroproptrs
Winl-l3-dicMoropfooene
Cu-lJ-djChleroprooe^
rrtiylfrenzene
methylene ctiloride 0 64
cMorometHAne
bromomlaquothlaquone
bnsmoform
bro mod i eti lor e me t Nine
0 uor o tr 1 cMor e rrgtlaquo t Nnlaquo
dj di tor olaquol If 1 uoro mraquoi Nrraquo
chlorodibromonveiKme
re tr a en 1 or or fxrvr
toluene
D-ieWoroefwne
entry denotes not detect All results are expressed as ugg weight as received Xo
Lab 1) No 2887-8
Physical descr ipt ion of sample
Sf-rs inpH 9 n i l
Sample workup
Vol iCi le f ract ion PEG Extraction (SW 846-5030)
Scmivolat i le f ract ion Soxhlet Extraction (SW 846-3540) Inorganic fraction Acid Digestion (SW 846-3050)
ACD O3MPOUNDS
m CAS fPraquo CASf pi A) tt-Ot-2 Zraquot- tritilorophrgtol (73B) 30-32-1
ft M -3o-7 p-cMorraquo-m-crTraquool (7kB) 205-raquo-2
(2 A) raquoS-37-l 2- cMorop^erxgtl J73B) 207-OI-raquo
(31 A) 120-13-2 l^ictiloropix)l ^7tB) JII-01-
(3 A) |03-7-raquo 21^-dimeThvlphenol (77B) 20t-raquot-l
(J7A) tl-73-3 2- rutropwnol (71 B) 120-12-7
(MA) 100-02-7 -MO-opwnol lt7raquoB) lraquol-2-2
fJraquoA) 3I-2J-3 2-dinitrop^laquoTgtoI ((OB) U-7J7
(laquogtA) J34-37-1 lt-dinitrfr-2-methylpwrxgtl (I IB) I 3-0 1-1 (raquoAI 17-1 3 pcmacMcroptonol (S2B) J3-70-J UJA) IOI-raquo5-2 phenol (IJB) MJ-39-J
(tBgt 12raquo-00-0 RASEfZUTRAL COMPOUNDS
( IB) 13-32-f raquocertaprithene
(3B) J2-17-3 twnndinc (2V) 107J2-J (IB) 170-I2- lr2k-triOilorobenzerlaquo (3V) 107-13-1 (raquoB) I11-7I-I hei bulllt1 ore blaquont ergtlaquo (raquoV) 7l-3-2 (1B) 47-72-I he ucft 1 or oe t h n (tV) 3-23-3 (116) |II_wJ bu(2-ctiIarothvI)laquotNer (7V) 101-90-7
(20B) raquoI-JI7 2 -cW or orvraquo ph tf I ene (10V) I07-Ofc-2 (23B) J3-30-I l2-lt5ictiloroblaquonzeoe (11V) 71-3J- (245) 3I-7J-I 13-dic^lorotxenzenc (13V) 7J-3-3 (27B) 104-K-7 1 mdash diC^lorobtnrerve ( lraquoV) 7^-OO-5 (21 B) raquo|raquo| 33^icftlorobenzidifv (I3V) rgt-j-3 (33B) I 2 I - U - 2 2ltgt-dinin-o1olvraquorgte (UV1 75-00-3
(J4B) 404-JO-2 21-dinitrotoluerve (1raquoV) 110-73-1
(37B) I22-W7 1 2 -d ipheny Ihydra z ine (23V) C7-14-3
(318) 2O4-W-0 tJuortnihrne lt29V) 75-3J- (kOBt 700J-77-J ^-tfMoropheTgtyl p^enyl ether (30V) 1J4-W-3
( raquo I B ) IOI03-J raquo-6romopfgtenyl phenyl ether (32V) 7I-I7-J
(06) 3H3raquo-)2-raquo bU (2-tfilerobopropyO ether (3)V) 10041-02-i
(OB) lll|| bii (2-cMoroethoxv) methane 10041-01-03
(37B) PUt) hxzraquocMorobutadienlaquo (J1V) 100-raquol-raquo
(JJB) T7^7U heztctilarocrclotMnttdicrgte (V) 7gt-0raquo-2 OB) 7l-3raquo-l BO ph or one (raquo3V) 7raquo-17-J
(338) raquo|20-3 rlaquopritrilaquolene (UV) raquo-laquo-raquo
(3iBl n-raquo3) nitrobenzene (raquo7V) 75-23-2
(CB) li-X)-t N -n i tr o tod ipheny U mi nr (UV) 73-27-fc
(06) CI-U7 N^iitroiodipropYUmlr ^raquo1V) 73-H-fc (UB) 117JI-7 bu (2-ethYlNerrl)pM^Utr 12000 (JOV) 75-71-1 (47 B) L3-U7 llaquoniyl buryl pht^UTe 2 800 ( 3 I V ) 2laquo-raquo-I (UB) raquo-7i2 di-o-ourvl pritfwiUrr (I3V) 127-lt-i (196) 117-14 3 dj-n-ocryl pritfiiUrr (UV) IOUIS-3
(TCB) J4-W-2 djnhYl phtfalitt (17V) 7t-01-lt (716 ) 1 3 1 - 1 1 ) damnhYl pMtuUTT (UV) 73-01- (77 Bl 3 33-3 frlaquon z olt raquo klaquom h rraquo c prgte
Cadmium T^ Chromiurn T Z T N C 100
Client ID 8A-C64221
BASENEUTRAL COtPOUNOS
bnzo(t)pyrrrie
benzobXluoriflthei blaquorizoltVHluorraquontrraquone
chryiene
bullcenphthylene
tnthneene
benzoltRM)perylene
fluorene
prienlaquonthcTTgte ditgtmplusmnolt4hluithrraquoctnf
indenof 1 23-cd)pvrf ne
pyrer
VOUATILES
bullcrolein raquocrvlonnrile benzene cmrbort Tetrichloride
chlorobenieoe 1 2-oUchloroethirie
11 1 -tricolor oethne ll-dvchlorolaquollMr 1 1 2-w icMoroethAoe l122-tetrieMoroeihilaquonlaquo
chloroetKvne JltJilorothvlvmv| ethe chloroform
11-dicMoroethent
trani- 1 2 -dicti lorolt t hene
1 J^JictiloroproBfVf
trim- 1 3-4ietiloroproperie
Cil-IJ-dicMoropfoOerie
rrhyUxrmene
methylene criloride
chlorornethine
bromome thne
007
13
tluorotr l^VoromlaquotNraquorgtt
da ch lor od 1 1 1 ooro frvet hraquone
chlorodibromometlvinf
te trraquocnloroeT rrrr
tricMoroetSmr
All results are expressed as us2 weight as receixred No entrv denotes not detect i
Phys ica l descr ip t ion of sample
SoilCake
Sample workup
vol i t i le fract ion ^FP FvfrarfMnn (ltU Rif i mdash Smrn
Semivolatile fraction Soxhlet Extraction (SW 846-3540^ Inorganic fraction Acid Digestion (SW 846-1050)
AC23 COMPOUNDS
rrt CAS CAS
(21 A) 11-04-2 2raquo4- trieMorophenol (738) 50mdash 3-4
122 A) J1-30-7 p-ctil or raquo-nvltrlaquo laquoo 1 (7laquoB) 205-11-2
12 A) 13-37-4 2- etilorophenol (75B) 207-01-1
(31 A) 120-13-2 2raquo-diclorophlaquoTgtol (74B) 211-01-1
(34A) 103-471 24-dmlaquothylphrnol (77 B) 201-14-4
(57 A) U-73-3 2- rutrop^nol (7raquoB) 120-12-7
(54 A) 100 -02-7 bull i tro p^c 01 (71B) 111-24-2
(J9M 31213 Z o trt i tr o poc^oI (MB) U-73-7
(40 A) 334-32-1 T^Hjinitrfr2^rt^T ny tp^gt^noi ( t lB) 13^)1-4
(44A) 17-44-3 pcnttchlaroprwnol (S2B) 33-70-3ltOA) IOt-IJ-2 pTUfNOl (136) 113-31-3
ftASENtUTRAL COMPOUNDS (MB) 121-00-0
(IB)
(56) 12-473 Iwnndine (2V) 107-02-1(IB) I20-IJ-I 1 2 4-tr icJi lorobeniervr (3V) 107-13-1(IB) 11 1-711 hexkcMarobcnzeM (4V) 71-43-2(126) 47-72-1 hexch)eroeihlaquone (4V) 54-23-J( I I S ) 111-4- bu(2-eMorlaquothv|)laquothr (7V) 101-10-7
(208) 11-51-7 2-c^laronraquophtfgtlene (IOV) 107-04-2(23B) 1J-30-I 1 2-dichloroblaquonime (11V) 71-35-4(2651 341-73-1 gt3-ltiictitaroblaquonxcnc (13V) 73-54-3
(27 B) 104-47 l4-dicMorotKmrerlaquo (14V) 71-OO-3
(21 Bgt 11-14) 33-4ichlaroblaquon2idine (15V) 71-34-3
(338) 121-14-2 24-dinitrotoluene (14V1 73-OO-3(J4Bgt 4O4-20-2 24-dinitretoluenc (11V) 110-73-4(37B) 122-447 lraquo2-dip^nylhydrraquoxirlaquo (23V) 47-44-)(MB) ro--0 Uuaranthene (21V) 73-33-4(406) 7003-72-3 4-ltUorepfraquonyl phenvl rtSer (30V) IH-40-J( raquo I 6 ) 101-333 4-6romoprlaquonyl pflaquony| ether (32V) 71-17-3
(OB) 3H3I-J21 bll (2-cti|orobopfrgtpyO ether (33V) 10041-02-4
(OB) I11-1I-I bis (2-cMaroethoxv) methane 10041-0103
(57B) P-44-) hczw^lorobundiene (J4V) 100-41-4
(JJ6I 77-47-4 htTicMarocyclojxrtadien (44 V) 75-01-2
(346) 71-31-1 aophoroo ( raquo ) V ) 74-47-3
(33B) raquo|203 r^pn thA Icr^ (44V) 7 -raquobull J-
(546) n-i3) H i frovCftZfl^^ (raquo7V) 73-23-2
142B) 14-30-4 S -n i tr o laquood ipheny Lt mi nc (44V) 73-27-4
(43 B) 421-447 N^iitrotodtpropyUmlne (41V) 73-41-4(MB) 117-41-7 bu (2-raquoThylhlaquolaquoyl)pMtgtlaquoUtr 52000 (30V) 73-71-4(4B ) 13-447 (xniyl bviryl ptithiUre 6700 (3 lV) 12raquo-l-l(UB) 147U- di-n-burvl pMhUre (I3V) 127-11-4laquoampgt 117-4J-0 ltjj-n-octyl phtfaUtr (UV) 101-11-)
(7CB) U-44-2 djrthyl pht)raquolraquort ( I7V) 71-01-4( 7 I B I 131-11 ) dimrthyl phttgtUTe (UV) 73-01-
(T76) H-33O tgtnzoUtlaquoftthncmr
Cadmium l i r^ Chromiurn 2 0 ZINC 140
All results are expressed as ugg weight as received
Lab ID No 2887-6
Cl ien t I D 8AD64219
Dd20( amp py(re
blaquonio(bHluorraquoflthegtlaquo
berzo(Mf luorampnThene
chryraquoefgte
ftctnAoMhy(ergte
raquonthncene
benioltK(M)plaquovlene
(Juorene
picnintfirtTX
dihwvioltraquoh)laquonThrraquocene
mdeno(l23-rt)pvrraquone
pyrene
raquocrolein
raquocrvloourUf
benzene
carbon laquoTrraquochlofifle
chlorobenieo
l24JcMarolaquotlxine
lll-trichlcroltthlaquorlaquo
-ltJicMorigtnKraquorgtlaquo
l12-trichlorolaquot^nlt
1 1 22-tetrcftloroetrvtnlaquo
^tloroeThAne
2^^1orolaquothvlvuiivt ethe
etila-oform
ll^liailoroltN^
trtni-12-dichlcxolaquoTfgtene
12-ditfiloropropine
trtni-l3-ltjicti|orocltX)t^f
cu-l3-djcMoroprooe^f
rttiylbtnztTve
methvlene cWoride
ciloromnM^f
Dco^^oroct^A^^
bromofarm
bromodicJiloromltlfraquon
tluorotrlctiloromttNir
diOilorodKloororfvrir^Ar
ct^lorodraquobrofTorrgttKAne
wtricnlorampctNrr
toluene
trirfilorolaquoThfif
v i n v CMor ilt3^
No-entry denotes not detect
ih i n N O 2887-9
Phys ica l d-asc r ip t ion of sample Cl ient ID 10A64222
Linnir l ShtHcp
Sample workup Volitile f rac t ion PEG Extraction (SW 846-^030^ Semivolatile fract ion Sonication Extraction (SW 846-3-540 Inorganic f ract ion Acid Digestion (SW 846-3050)
AOD COM POUNDS BAStNELTTRAL CXLPCXJNDS
rrt CAS CAS
(21 AJ U-Ot-7 Z4- trichloropSeno (73B) 30-J2-
(22 A) 55-30-7 p-ctilarraquo-m-erelaquoo1 (7kB) 205-raquoraquo-2 ben r olt b) 1 uor ifl t Ne~gtf
(2AJ raquo3-37-i 2- ctilorophenol (75B) 207-0raquoraquo benzoltllt)floofraquontslaquor
(31A) 120-13-2 2raquo-ltJictilcroooenol (76) 211-01 9 ctiryjene
(3A) I03-47- 2k-dimethylphenol (77 B) 20t-raquo4-i bullceruphthv lerraquoe
(37A) U-73-3 Zmdash Ajtropheooi (7SB) 120-12-7 fcntftricene
(34 A) 100-02-7 w^ i ff o phe rgto 1 (7raquoB) Iraquol-2-2 ben z o( Rh i )per v 1 me
(31A1 51-21-3 Z^ - d iA iV opheno1 (SOB) U-7J-7 Iluorene
(MA) 3X-37-I T v-4iAiv omdash laquo mdash fl^et ny Ipoenoi (I1B) 13-01-1 poeftraquonthrene
(4 Al 17-14-5 p^ntBCfllGrOprlC 1 Vol |I2B) 33-70-3 dilgtenioltraquoh)laquontwraquocenr
USA) IOl-raquo5-2 phenol (13fi) U3-31-3 indeno(l73-cd)oraquorrie
(MB) I2raquo-OO-0 pyrene RASENCimiAL COMPOUNDS
VCH-ATUL5 ( I B ) 13-32- raquoclaquonraquophtflaquorgte
(58) 12-I7-J benzidire (2V) 107-02-1 bullcrolem
(IB) 120-J7-I 1 2k-tr icnlorobenzene (3V) 107-13-1 acrvlonitr UP
(IB) 11U7I-I heKicMorobtnzme (raquoV) 7I-A3-2 benzene
(176) 4772-1 hexcftla-oethtgte (4V) J4-23-5 campr~toon TeTrscftlo itit
(116) III-- bii(2-lttilorolaquothv iVether (7V) lOt-W-7 chlocobenieo
(2C5gt raquol-3l-7 2-cM oroolaquo ptittu lene (10V) I07-O4-2 1 2-dicrtloreetranr
(23B) raquo5-30-l 12-dichlarobenime ( 1 I V ) 71-33-4 11 1 -tricMoroethr
(24 B) 31-73-1 1 3-ltl icJgt lor obcn i ene (13V) 73-3^-3 1 1 -dicMoroeth^i
(27B) 104-^4-7 1 4-dich lorobenzergte ( t k V ) n-00-3 11 2-tncfiloroetvlaquorie
(215) 91901 33-didMoroblaquozidinr (I3V) rraquo-3k-3 l122-tetrraquoOMo-oethne
(335) 121-I-2 2-dinitrotoluergte (ItV) 73JW-3 chloroethjin
(3461 (0420-2 24-dinitrotoluene (19V) 110-73-1 2-cMoroethraquo|vuiv| trgteshy
(37 B1 122-44-7 12-diphenylhydrnine (23V) 47-44-3 ctiloroform
(316) 204- Jgt tluarmrnhene lt2V) 73-35-4 1 1 -^iCMoroeThe^f
(C6) 7003-77-3 -chlorophenyl poenyl ether (gtOV) 154-40-5 trraquonraquo-l2-dicrloroltthene
(bull16) 101-35-3 raquo-6romophenyl phenyl ether (32V) 7I-I7-3 l2^ipoundMoroproBirgte
(raquo26) 3H3I-32- bit (2-cMarobopropvt) ether (33V) 1 004 1-02 -4 trmni-l^-dictilwoproom
(OB) l l l - raquo l - l bis (2-cMeroethoxv) methane 1004 1-0 1-05 cu-13-laquoicMoroprooe^e
(J2BI D-U-3 rraquolaquoeftlorobutraquodilaquooe (JJV) IOOJM- rttylbenzene
(336) 77 -raquo7- hezactilarocyclooentadiene (WV) 75-OT-2 methylene cniorifle
(56) 7raquo-3raquo-l ao ph or one (raquo5V) 7raquoJ7-3 eMoromeirune
(33B) JI-20-3 nraquophtMlene (UV) 7raquoJ3-raquo bromomethAftf
1X6) n-raquov) nitrobtnxerw (raquo7V) 7J-25-2
(CB1 14-30-4 J -ltii TT o vxJ ipheny U rru rraquo ^UV) 75-27- bro mod i cfilor o me t r)e
(CB) 47I-U-7 N-nnrotodipropylraquomJne (tV) 75-4raquo- 11 uor o tr i cMor o me t htgte (US) V17-1I-7 bu (2-eifrrlhryl)praquogtttilaquoUMshy 69 000 (30V) 75-71-1 di cti tor odl1 1 van m^i rajgtr
(476) U-U-7 benzyl buryl phihiUte 890 (31V) 12laquo-kraquo-l cMorodbremof^etNrr (US) U-7I-2 di-n-burvl prittuUre (13V) 127-lt- Uraquo6gt 117-t-0 dJ-laquo-ocTvl phttviUre (UV) IOLtS-3 Wluenr
(75) u-w djrrhylphtnltt ( i rv) 71-01-4
(715) t J I - l l - 3 dimnhrl pfthUte (UVI 73-01- viny l CMcriOr
(779) J4-35-3 0laquoMo(UnthrraquoCflaquoe
C a d m i u m 130 Chromium 20 ZINC 170
o nnn Z-UUU
^0(^ Trace
All results are expressed as ugg weight as received No en
APPENDIX E
PLATES
I I I I I I I I I i Plate 10-1 Troy Mills Landfill with a backhoe excavation
in progress in a former drum burial area
I I I
I I I I I I I I
I I Plate 20-1 NAI field investigation team preparing for
Level B activities during the drum excavation task Troy Mills Landfill
I I I
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
I I I I I I I I
I I Plate 20-3 NAI field investigation team member undergoing
personal decontamination at the hot line Troy Mills Landfill
I 1 I
I I I I I I
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
1
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
I
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
I I I
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
I I I I I I I I I I I 1 I Plate 53-3 Pigmentsludge deposits interbedded with
soil layers in Excavation 8A Troy Mills
I Landfill
1
61-7 Analyses of Water Samples Collected from Monitor Well M7 29
61-8 Analyses of Water Samples Collected from Surface Water Station A (leachate seep) 30
61-9 Analyses of Water Samples Collected from Surface Water Station B (upstream) 31
61-10 Analyses of Water Samples Collected from Surface Water Station C (downstream) 32
64-1 Physical properties of phthalate esters 35
64-2 Physical properties of ethylbenzene and toluene 39
iv
ABBREVIATIONS AND SYMBOLS
EBP benzyl butyl phthalate degC degrees Celsius Ca circa D volume occupied by one drum DEHP di (2-ethylhexyl) phthalate DOP di-n-octyl phthalate E east eg exempli gratia (for example) EPA US Environmental Protection Agency HNU HNU Systems Inc photo-ionization detector LEL lower explosive limit LPP level of personnel protection MCL maximum contaminant level mg1 milligrams per liter ug1 micrograms per liter MSA Mine Safety Appliances Inc N north also number of steel drums NAI Normandeau Associates Inc OS over sample OVA Foxboro Century Organic Vapor Analyzer P estimated packing density of drums PPM parts per million RAI Resource Analysts Inc RCRA Resource Conservation and Recovery Act S south SCBA Self contained breathing apparatus SNARL EPA suggested no adverse response level T trace Troy Troy Mills Inc TVO total volatile organics V estimated volume of drum burial area VOC volatile organic compounds W west gt greater than lt less than
PLATES
Plate 10-1 Troy Mills Landfill with a backhoe excavation in progress in a former drum burial area
Plate 20-1 NAI field investigation team preparing for Level B activities during the drum excavation task Troy Mills Landfill
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
Plate 20-3 NAI field investigation team member undergoing personal decontamination at the hot line Troy Mills Landfill
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
Plate 53-3 Pigmentsludge deposits interbedded with soil layers in Excavation 8A Troy Mills Landfill
VI
10 INTRODUCTION
As a part of a phased program to investigate potential ground
and surface water contamination associated with the Troy Mills Inc
landfill Normandeau Associates Inc (NAI) has completed a waste
characterization at portions of the landfill that were formerly used for
the disposal of steel drums containing wastes (See Plate 10-1 for site
overview) The objectives of this phase of study included
1 Delineation of the horizontal extent of the drum burial area
2 Estimate ofthe number of drums
3 Characterization of the physical condition of the drums
4 Assessment of the contents of the drums and
5 Assessment of potential for ground water contamination
6 Development of a remedial action plan for the site
The work involved developing and implementing an extensive
site safety program conducting a magnetometer survey digging a series
of test pits on randomly selected sites laboratory analyses of selected
samples of soil and waste and formulation of a remedial action plan for
the site
The Troy Mills landfill is roughly eight acres in total area
and divided into two main sections One section is currently being
operated as a solid waste (non-hazardous) disposal area for fabric
scraps and trimmings as well as other non-hazardous materials such as
wood and broken tools The solid waste landfill covers about six acres
of the site An estimated three acres presently contain deposits of
solid waste and about three acres are being prepared for future
disposal A closed former steel drum burial area is the second section
occupying about two acres of the site The drum burial area is now
covered with soil and a light cover crop of grasses The drum burial
area received wastes between 1968 and 1978 The disposed drums are
reported to have contained various materials including waste
plasticisers pigments and organic solvents
Previous site investigations by NAI have included site
reconnaissance studies test pitting water quality analyses (NAI report
of August 12 1981) geophysical (seismic refraction and electrical
resistivity) investigations (NAI report of December 1981) installation
of a ground water monitoring system (4 wells) and sampling and analyses
of ground and surface water samples (NAI report of July 1982) A water
budget analysis was performed to assess the leachate generation
potential of the site (NAI report of September 1982) Concurrent with
the study of the drum burial area additional seismic refraction lines
were conducted and three additional ground water monitoring wells were
installed to further assess leachates from the solid waste
(non-hazardous) portion of the site
Laboratory Analyses were conducted by Resource Analysts Inc
(RAI) We also wish to acknowledge the assistance and cooperation
provided by the management and personnel of Troy Mills especially
Messrs Barrett Ripley and Carl Patten
20 SAFETY PLAN
A Bureau of Hazardous Waste approved safety plan for on-site
activities was developed for the waste characterization phase of work
because of the potential for encountering hazardous materials The
safety plan is presented in Appendix A of this report It assesses the
overall degree of hazard identifies specific potential hazardous
situations and presents guidelines for personnel protection and action
levels as required The plan was made available to all field personnel
during the field work
The magnetic and topographic surveys were considered to be low
hazard activities with a prescribed level of personnel protection (LPP)
of C or D depending on the results of air monitoring Level C proshy
tection involves wearing a full face respirator with organic vapor dust
combo cartridge Tyvek suit over work clothes rubber safety boots and
gloves Level D protection requires cotton coveralls or other work
clothes safety shoes safety glasses and possibly a Tyvek suit
During the drum excavation and sampling task which was
determined to be moderately hazardous Level B protection was preshy
scribed Level B protection requires that personnel wear SCBA (self
contained breathing apparatus) chemical resistance Tyvek suit steel-
toed rubber boots and gloves Plate 20-1 shows NAI personnel on the
site preparing for Level B activities Plates 20-2 and 20-3 show
personnel decontamination equipment and the hot line during the drum
excavation task
30 MAGNETIC SURVEY
To delineate the landfill area underlain by steel drums a
high resolution magnetic investigation was conducted by John F Kick
PhD consulting geophysicist The magnetic method was chosen over
other search methods because ferromagnetic substances (drums) were the
target objects and the majority of Troy Mills other wastes are
non-magnetic (largely fabric scraps) Dr Kicks report is presented in
Appendix C
Eighteen parallel rows of magnetic field measurements were
made along north-south lines The measurements were made at 10-foot
intervals along the rows This work resulted in a detailed contour plot
of the magnetic anomaly (Figure 1 in Appendix C) The source materials
which cause the magnetic anomalies do not usually directly underlie the
peak of the anomaly A shift is caused by the inclination of the
earths magnetic field and by dipolar effects Figure 30-1 shows NAls
delineation of probable source areas for the magnetic anomaly and
peripheral areas which may contain some magnetic source material The
plotted source area is generally the area between the peak of the
magnetic anomaly northward to the zero anomaly contour This is to
compensate for a southward shift of the peak of the magnetic anomaly
from the center of the source deposit The complex geometry of the
anomaly necessitated much interpolation between peaks and ridges
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40 TEST PIT EXCAVATION
41 WORK PLAN
A series of test pits were excavated in the Troy landfill for
observation and sampling More specifically the purpose of the
excavation was to estimate the number and distribution of drums buried
in the landfill determine the condition of the drums (full empty
crushed rusted leaking etc) identify types of buried and drummed
waste and verify the results of the magnetometer survey A stratified
random sampling method was used to choose 10 locations within the
delineated area of magnetic source material This insured that
excavations were distributed randomly across the landfill and that the
resulting data could be evaluated with a level of statistical
reliability Excavations were also selected in areas on either side of
the anomaly which were considered free of buried magnetic material and
also where drums were visible at the landfill surface
The following procedure was used in choosing the locations for
the random excavations The center of the delineated area of magnetic
source material was used as a base line The base line was drawn onto a
map of the source material (Figure 30-1) and then divided into ten
60-foot long segments Using a random numbers table a point-distance
was located on each segment (designated the random station) and a
line drawn at that point perpendicular to the base line segment Again
using a random numbers table a point-distance (designated the random
offset) measured along the perpendicular line located the point of
excavation The grid coordinates for each excavation were graphically
determined from the grid overlay and then field-located from the
surveyed grid intersections Grid coordinates and selection data are
presented in Table 41-1
It was judged that 10 excavations in the delineated area of
magnetic source material and two excavations out of the area would be
sufficient to characterize the site would produce statistically valid
TABLE 41-1 RANDOMLY SELECTED EXCAVATION SITES TROY MILLS LANDFILL TROY NEW HAMPSHIRE
BASELINE RANDOM RANDOM EXCAVATION GRID SEGMENT STATION OFFSET
NUMBER COORDINATE (FEET) fFEET) (FEET)
1 7E+15 65N 0-60 26 16
2 9E+5 13S 60-120 110 9
3 8E+0 31S 120-180 140 7
4 4E+5 48S 180-240 230 26
5 3E+8 45S 240-300 254 20
6 OE+8 45S 300-360 394 50
7 2W+15 24N 360-420 465 14
8 5W+6 42N 420-480 518 20
9 6V+14 74N 480-540 548 7
10 8W+5110N 540-600 611 31
Locations are plotted on Map in Figure 30-1
data and could be expected to be completed within a scheduled 2-3 day
work period
42 FIELD WORK
Test pit excavation was conducted in two phases On the first
day each of the 10 random locations (Excavation 1 through 10 Figure
30-1) was probed to a depth of 2 feet using hand shovels On the
second and third days excavation was conducted using a combination of
hand shovelling and power backhoe The NAI field investigation team
consisted of six members Four of the team members were equipped to
work at Level B for work in and near the actual test pit excavation
(See Plate 42-1) The other two team members spent much of their time
with personnel and equipment decontamination and refilling compressed
air bottles at the hot line Mr Timothy W Drew an engineer of the
New Hampshire Bureau of Hazardous Waste Management was present during
most probing and excavation work Mr Robert Lynch an experienced
Level B equipment operator of Jet-Line Services Inc operated a power
backhoe which was provided by Troy Mills Inc
An average excavation size using the backhoe was approximately
7-feet wide and 10-feet long Excavation continued downward until drums
were encountered or to a minimum depth of five feet Drums were careshy
fully uncovered and fully described A total of 17 samples were
obtained from uncontainerized wastes (solids dried sludges pigments
stained soil) and where possible from drums using EPA sampling methods
and protocols All of the excavations were backfilled upon completion
of this task
Each sample consisted of one filled 8-ounce glass jar sealed
with a Teflon-lined lid Samples were submitted to Resource Analysts
Inc (RAI) Laboratory in Hampton Falls NH for priority pollutant
analysis
Air monitoring was conducted during each excavation using a
Foxboro Century Flame lonization Organic Vapor Analyzer (OVA) an HNU
Systems photo-ionization detector (HNU) and an MSA combined oxygen and
explosimeter High explosimeter measurements were considered cause for
an immediate halt in exploratory work in the interest of personnel
safety
10
50 RESULTS
51 GENERAL
On November 17 1983 Excavations 1 through 10 were initiated
using hand shovels to a depth of approximately two feet A total of
two buried drums were discovered Excavation 13 was completed and a
third partially buried drum uncovered On November 21 1983
Excavations 1 through 9 were completed and on November 23 1983
Excavations 7A 8A 10 11 12 and 14 were completed An additional
42 drums were uncovered on the last two days of excavation
Excavation Locations Seventeen test pit excavations were
completed at locations which are shown on Figure 30-1 Two pits were
excavated at three of the locations Noteworthy aspects of the
excavation operation are
Excavations 1 through 10 were randomly located in the area of delineated magnetic source material (on-anomaly)
One excavation connected Excavations 4 and 5 This was done because of the proximity of Excavations 4 and 5
Excavation 7A was located immediately adjacent to Excavation 7 Excavation 7 was located on the boundary line of the anomaly and proceeded in a southerly direction off the area of delineated magnetic source material (off-anomaly) Excavation 7A was initiated in the opposite direction (north on-anomaly)
Excavation 8A was initiated one foot north of Excavation 8 after the latter was abandoned due to the detection of a potentially explosive drum
Excavations 11 and 12 were selected off-anomaly to the north and south (respectively) in areas considered to be free of buried magnetic material (drums)
Excavation 13 involved minor hand shovelling necessary to uncover a partially buried drum located on the periphery of the anomaly at the east end of the landfill
11
Excavation 14 was a surface scrape which extended from an exposed drum found to the south of the magnetic anomaly northward toward the anomaly
The details of each excavation are presented in Table 52-1
Drum Locations The excavation results support the
interpretation of the magnetometer survey with buried drums as the
source of the magnetic anomaly With the exception of a few strands of
wire found in Excavation 1 ferromagnetic materials other than drums
were not encountered during the test pit excavations
Drums were foundin 9 of the 10 excavations located in the
area of delineated magnetic source material (See Plate 51-1) No drums
were found in Excavations 11 and 12 located out of the area of
delineated magnetic source materials The location point for Excavation
7 was on the boundary of the anomaly Excavation 7 which proceeded
south away from the area of source materials was free of drums
Excavation 7A proceeding north toward the area of magnetic source
materials uncovered 6 drums Excavation 14 located just out of the
delineated area to the south produced unexpected results Five drums
were uncovered just under the surface in an area with low positive to
slightly negative total magnetic field values It is possible that
Excavation 14 was improperly located in the field If adjusted just 20
feet to the east it would be well into the delineated area It is also
possible that a negative dipole derived from the mass of material to the
southeast is cancelling positive readings at this location
Fill Material and Vegetation Cover and fill material was
predominantly fine to medium sand with an occasional boulder Till with
a siltclay component was also used as a cover particularly at
Excavations 6 and 7A This material was densely compacted and difficult
to dig through Excavations 7 11 and 12 each extending to a minimum
depth of 5 feet were characterized by uniform silt and fine to medium
sand and traces of dark discoloration Excavation 12 was located in
to a s
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X a s ar e gt Emdash COC i O O
mdash gt shyc laquo- O raquo bull t- mdash CO
X c - gt c c i shy r e w O t r e
mdash re X i- - z ^E l - IC C3O
Z cJ Xt E J r mdash o in trade re ^ cc U pound -gt
^ mdashJ O ^ 11 CSLJ - gt ^ c olt- c umdash C CT-3 O B 3= mdashmdash z - ^r mdash c = s J
mdash laquo f j 3 -3mdash O
pound mdash z = J 3 3 S O laquo
s re -re mdashmdash ~mdash gt
cO t 3 r e C - ^ laquo gtC ltshy O gt mdash Z CD o c re mdash rei 3 u
O C S li = i U) x^shy mdash x x r z r e JO w L J C ^ 3 i
mdashi
a
IS shyJmdash _jii) OS
aa I i
a 1 1
a 1 1 O
a
z CC w ^ 1raquo oo o o
CM o o
zx
o
ltamdashZLraquo
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Q a mdash mdash
o rmdash IA
i 0
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lA r~ r~
a mdash o CO
amdashoCOttrade
Q o o
laquobull
O
o o 1mdash
i ia o o lA
i
Z mdash m
CO CO
h_
0^zmdash
^
S c-c_ 1_
0 a mdash mdash 0
o O ro mdash 1
O O
0o CM1
a mdash
O O
Q
O O
1
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oO-
Q o o
lA 1
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o o
1
WO
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Q O
lA 1
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CM O lA
v o3- V
CM
CM r ~ CM
mdash =^ a
S 5^ 0lt r ~ ~
1 1 1 a- lA
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1 mdash a z ZO o mdash Ui-
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a laquo
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mdash K ^
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cs shyo L ^ t-oshy0 ~ CMr-
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laquof~
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bull- t-
^ LL ^
K f- Ci bull-bull
shy shyU LJ LJ
rr shyo laquot- t_
O ^~ O c
CM Q
mdash c-Omdash
^
^V f-
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fc ^ aa L 1_ ou C- C
1
w
0
X L
raquo( CC-mdash
LJ
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Z o to
ltr s _3 OK
CVJ CM ro
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j CM VO
ro bull-CM
ro 1 VO laquomdash
z o
r-Q
I C
o X UJ
poundo| s~a
a CM CVI CVJ fO lA CM 1 lA lt-
a o
o mdash LJ o raquomdash L
lt ^^ gt lt UJ C N X mdash _ in
o X o X CO
f)XCOXr-
X CM
bull-X ot^
ro X ^y X O rmdash
rXlAXOv
CM X
00 X
CM V
ro X ~
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lAX roX o
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o
r-X
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z C o
lt a
lt 5 rmdash fl ro ^ -~
I O C- 83 ^ ~
lt gt- CO
X
0 O
13
E
23
eo ETC CU
gt i- Nlt (_ mdash
E O i-
lt~o ON dgt
N Q) mdash
i-tt) gtOO
bullDC
gt 0) C
T3 O
-D C CD
tgt
-U mdash mdash
C5
E 33
E-0 gtgts-O CD mdash T3 1- N JO ( =
0 0 U - O C5 t- t-ushy ro L jj bull
3 C 0 gtgt cnmdash 4J mdash
bullD CD bull C E E
I t -
lt Q 0)eo i c
lt mdash
mdash L
aagt E C CO mdash
CO i-W CO
bull obullDmdash 0
gtgt mdash
re bull E bulllt-gt
gtgt mdash
CD bull E-0
L W O lt tu en i-fgt c O Q
gtgt0 3 O mdash 4-gt i C
CD X -o eo E 0
w co CD bullO 4J COmdash ^ C d)CO O ^E 1 O W
co eo 4J bull
bull C CU ^ O ^
C O W
c eo Qeo mdash eo
t-JJ 0 E
o mdash c mdash
eo w
D C c eo CD laquo)
CO T3 0 4J Q) - C 0 mdash CO gt mdash E O w mdash
O 01shyC CU O O CD aw
CD O CO u- sshy amdash
re lt c eo cc c CD mdash CD 1- ltshy C C_ C re c co o - O X X CO CO3 gt CO 3 gt to E O O co O co CO 3 jt w O cfl 0) eo
cr LJ
LJ-J u mdash j CO 0amp5
a O 1 O
Q
1 1 i l
CD Dl bulla
CO _ mdash O D o
O ^ (A
ZX mdash Ld
O
en 3 10 O a
LJa a
Q 1 1 O
Q
+
O
X
_
mdash
o o I
gtgt O
h~Z
-^ 3
o0
mdash i-
1A 1
a a co agt C
LJ
sectK
Z= tM O 0 to bullo
X
mdashshyo
CD O
o mdash _ o
E umdash 3 E eo sshy
ltr-toZmdash
mdash s
0shy c
^
^ gt o
D o
a-rmdash
1
Q-
0 0oo r-V
tO 0
= mdash
O
tO 0
= mdash
O
Q O
O r-i O NO
1
awi
i mdash _ 3
Imdash I O
bullO C
1- 3 gt 0) bullo sshy co w
bullO CJ ID O X E C CU tt) bullw^ T3
w agt u C pound -gt
a a CO CD
mdash L 4J CD o gt
T3 gt C CO UJtt
2 mdash1 LJ Z) d CO 1 1
COO
~
lt O
~ I 1 1 I
Dl C 10 3 -D
lt - T J O
Dl C
1gt Omdash O bulllaquo Xl- i s o cu
Q lt3 toz cshy
mdash W f
r-B O c
mdashgtgt3 01O O u
W ID CO bullgt C -O mdash 4-gt 4-gt C
O -x mdash1 CO o CU c c co
1
OZ ZO o mdash Ol-
LJ -
L
0
1
C- bull 14 u- o laquoc~
bull mdash u bullDT3 O laquoccce tshy ^ D
l_ Cshy CCO O 0 0-0 Qmdash
CJ I- r-CM
1 1
U-Qshy
bull bullbull ^
O t_ 0 Q
-LJ
raquol
a o iT o c o
U) c
c u CD O
I I I CU c
Q) CJ CU W a ltshyon J2 o l- E E gt QCO CD O
I I I
ID JJ CU ES
J-gt imdash O Q Z CO w t --shy O mdash O 3 O laquoshy ^ c
_ICO a 0 0 0
^ sect5oa I-Q
CO X u_ y o- o=gtLJt-a
3shy
^
1
1
VO
m
1
i
1
t
_
3 lta i- U) 0 0
a
lA
lAbull
0 O
JI E oj3 gt E re mdash O X X co Qj
C 1 O
W 3
U L CO O
4J CO
0mdash CCD gt j ti --shy c JJ 4J
1- laquo 3 = C 3 or cu ogt tn Q -shy
E L n CD J-gt o o gt gt s o ---shyDior 3 3
mdash Tgt o cr cr mdash mdash CU 0)
o a CD -a OLJ U CU
N CU COT 4JT3 poundmdash 0gt U V
raquoT3 mdash agt OJ gtgtcu laquo c c
T3 O
C
C
Zlshyo ui u- Li ^ ^~bullgt lt LJ
lAXvOX
VO X ^ X
Xcjltshy
lA x
CM
O x
3shy
_ X
r^5 X
_ X
CM X
mdash c^ C3 O
c a bullbull o c c
mdash 4J O I I 4J
01 JJ 4J 1C laquo
3 t- C raquoJ O L (D CU C mdash o a~o mdash o
i i
C J J W CO II) O W IT OC N 03 = OJJ C O I- -= C O
I I
o o
ON X mdash
CMr-raquo
00 Orshy
X CO
vo ro O C 5) JJ Jshy I- I gtJZ-00 s a o
LJ CO eo UTJ a- I I O C X J O gtZ 1 re O
i CM
LA
LJ
O mdash c imdash LJ lt a gt y lt 2
ltCO O
O^mdash
laquoshy rmdash
CM Tmdash
n rmdash
_^jshymdash CO
LJ
j ^ |
52
14
what appeared to be natural materials although its location on the
cleared and leveled landfill tend to contradict this possibility
Most of the landfill is vegetated by a thin layer of grasses
sedges mosses and annual herbaceous species The northeast corner of
the landfill is unvegetated and cover material appears to have been more
recently applied This section is elevated 4 to 6 feet above the rest
of the landfill and appears to have received a second newer layer of
waste A 4-foot thick layer of carpet waste was encountered in
Excavation 1 but not in other excavations This section is adjacent to
the newer active landfill The landfill area just west of the access
road crossing (near Excavations 7A 8 and 8A) was also unvegetated due
to relatively recent grading operations
Ground Water The landfill appears well drained as ground
water was not encountered during any of the excavations Excavated
overburden was damp from the recent heavy rain but intergranular macro
pore spaces were free of water
OBSERVED QUANTITY AND CHARACTER OF DRUMS
A total of 45 drums were observed buried in the landfill
Table 52-1 presents a drum log describing each excavation and the
observed drums Data on the contents and condition of drums is
summarized in Table 52-2
Of the total drums observed 15 (33) were crushed flat
Although these could possibly still contain small amounts of waste they
are probably considered empty under RCRA guidelines Thirty (67) of
the total drums discovered were uncrushed and capable of containing
waste Seven (88) of the 8 drums sampled contained liquid or sludge
waste material Thus at least 7 (23) of the uncrushed drums contained
some liquid or sludge waste
15
en C Cl
bullo gtraquormdash
c mdash a
o c re bull mdash c
~ o mdashbull 4Jmdash
10 0 mdash
gt O
ro CO
fcshy0
c
C
vgt 3 0
1 rea
-gt
mdash
3 o T3
lt-O
C j C
CB 3 TJ ii i- 3 mdashQCOa
ifl u bull c c
t_ o
mdash shyO
mdash
L re N
co
t-O
mdash
mdash lfl
V) O
CO N CO pound re
0 mdash
^1 10
ltP O C raquo
CM reO
o f shyi O
mdash mdash 3 - D
c 1
CD bulllaquo
mdash3
D mdash
1 C
Q CO
CD Ifl 4-gt CO
Q
CM
r-
Ul
Q Ul gt EC Ul CJ CO o t5bullpound
z O mdash
C Ci o^
O Cbulla 3v iC MW5 CO 4J3 u CS- Ifl CBC J C O - U
gt Cgt Omdash Oi O
U- 0) Ifl bullgt-gt 1 W C
to lt-gtT3 gtmdash
0) gt shyJ 0)
C OltJ bull O T 3 C D C P
133mdash 4J bull ifl tshy Vgt~ V a O V4JJ
C o
C mdash
O Ifl
3 fc 0)
i-
c
U) re gt
ai C mdash
C mdash
CO gt c o
bull to y 3 cc Q
ltbull-CB
1 4Jin
bullD reCD jCJJC TJCD mdashbullD bull mdash
CD 0t- u iflo ifl
0 C ^-
CB laquo
3 ltbull-
0)^shy
C
0 Cgt O
1 O CTl C
T3 1 mdash CB O
mdash CB mdash in J o 3 tfl C ^ CO 0 gtltgtshy
O gtgtc 01
CO 3 1- mdash C Cregtmdash laquo
TJ W TJ mdash i re traquo-
shyU mdash
O Q
COCO^^
mdash ^
mdash gt C 0gt mdashO ~ bull
Ul
o auO
CCUl
mdash K o tO Ul Q
mdash OT30Jj c mdash4Jt- Jpound O Wre c i re03 gt
lt~i- laquo o ai
0 ) 3 gt O ^crc Ifl - CO -^mdash
3 mdash Q iflmdash 1- O 3 3
O V O ltraquo-o laquoTJ
gt
T3 - o
gtgtmdash J-gtmdash
Dmdash
6-o
09 bull mdash gtpoundbulllt-gt
re a
Ul X t5
Cpound O Z
fl) mdash^ C B gttflOl3T3T3l_ 3 Q)O mdash mdash
tn mdash
shyD CB
mdash mdash
mdash tt
CO C T3 poundi mdash JCmdash re
^ C O C X CB ^ - S - C C O mdash re O Q DW4shy
re shyu O 1
O Ul X EC Ul mdash
x a^s ox
CO
^) Z
J
1-o t-Ul X r-u 0
o j c gt T3 i -gt c tu mdash c u r e mdash
- C D mdash T3 - C M mdashbullOJJQmdash re3inecrec u c r e o mdash lt~ bullz c~4J O CX t ^Jw o r e -gtgtOgtgtshy3 c j t shy re mdash mdash ret- i o Qmdash gtgtpoundgt a
i reraquo CD 0) bullbull Ifl t-
Q ) t ) O pound O ^ laquo gt - Ow re re ro re re -gt Q mdashc 5 shyu a j-gt D t- raquomdash mdashCB C re C CO 3Q mdash O mdash O U
Htshy ae cu coo)
1 O i i
shya shyo j CD C bullgt o mdash c o c o coco mdash plusmngt o ~a v c en CD
mdash C O
raquoCJ 3C c re amp- ogtCD J o 3 CC C I-Omdash 3gt O
3
O ro
Ul X 1mdash
u O
Ul o r-Z Ul
gtV~ omdash Dlshy ^mdash mdash wre3 i cc
mdash cr bull gtJJ mdash C mdashi QIgtJ^re a shyJQI- o 0mdash
O bullO 3laquo laquo
jjmdash ureoO mdash O N 0)rc3recomdash4Jt-4JpoundmdashC C mdashmdash mdash u
1
shya 0 -
mdash gtgt re-raquo-gt CUD laquo E CD
^ J-1
CJ eoc
4JCB CO
mdash O
C 1- C mdash O C B C B C E J mdash J ltshy shyo cn o o c o r e c shyU -gtO OJC D ifl roc
T3 3 I U 3 laquo-
Ifl CD 1 W ^J 4 J 4 J c -aiflj jc
CB C r e O C B lt-gt -Jgtcoraquo C C -WE O O ) ~ O O O mdash O
Ul O
c ui =gt z
o
1-CC Ul Q
Q z ^ Ul
2 gt Ul O
o Cpound
^ CO
Ul Q ^
z o
(O U S Q
Slt
t5 lt
Z5O
1mdash z ui
Qa Ul
CD 0-1
u m O_J
O2^ltUl
O CC Ul Q
VOCO
CNlA |3
VO ^
CJ |CO |
CJ CMI3 f~ rojO VO rolo
^
ymdash3 CC
roCM
ro O ICNj
ro rolvO ro ro
ro A
rolvO r-jO
00 C3N
ec a m
r3
CO
3 a ty r-
cc Q
(M CM
to z
m 3 c O
u _i co
U-O
O 3-IObull - I c y
fshy lt- ICO r- r-ICM O U lfN ro -mdashla1 f~ laquo- ]CO bull- -ICM O O J|O O
c U) CO
mdashbullre re
mdash re
mdash i ltC c tz
j lt
i lt
5 0 0 G O o o o o z bullU 4J J h- J shyJ tmdash tmdash
^33
J3 3
O 3
Q 3
_Cr(bull
shyC 3 t)
CC IP y
C2 zgt c J
1mdash O 5
53
16
The condition of the uncrushed drums was highly variable with
only 4 (13) rusted and decomposed to the point of structural weakness
These drums were found in Excavation 10 at the far west end of the
landfill which is believed to be the oldest section (See Plate 52-1)
Interestingly two almost new looking drums were also found in
Excavation 10 at a greater depth than the four rusted drums The
remaining 26 drums were observed to be generally intact and structurally
sound Some were dented partially crushed or rusty
CHARACTER OF WASTES
Air Monitoring An OVA and HNU were used to monitor the air
for concentrations of organic vapors during each excavation Above
background instrument readings indicative of contamination were
regularly recorded when monitoring the air just above or inside of
drums A general contamination of the ambient air in the workspace was
noted only during Excavation 8A where above background readings of +13
in the excavation pit and of +6 above the excavation pit were recorded
Explosimeter readings were obtained from three drums -- 10 lower
explosive limit (LEL) from drum sample 10A 20 LEL from drum sample 6B
and 100 LEL from a drum in Excavation 8 Instrument readings are
presented in Table 52-1 and Table 53-1
Visual Observations The following types of waste were
observed during the excavations
fabric waste (carpet waste)
crushed drums
drummed waste - liquid sludge and solid
uncontainerized dried sludges and pigments
stained soils
Fabric waste scraps of synthetic non-woven fabrics5 heavy
carpet-like fabric and backing material were found only in Excavation
17
CM
CO LJ fmdash O z
laquo 4J
u TO 4-gt
c bullmdash
k bull mdash E mdash 3 3 i-^ O
mdash TJ --raquo co co 4J
E CO O U L U
E 3 c T3
C O a o
is
CO c to 3
U
TO
E O t_ U_
o o
1 ltmdash c
mdash tmdash TO 4J bull C TO 0 O o c u 3 TO
t_ 0) 0 4J
U)
mdashOTOgt
Cw bull aco jc
N 4J a
mdash L Q) re co T E
CO
bullo gt egt mdash c mdash bull o ^^73 C E gtO O mdash 3 J-gtmdash N 4J L 3 mdash 1--C gttTC bull
CX 01C JJ TO O mdash
TO trt mdash t- E mdash 3 JJ a O Q
C I 0 X E mdash C mdash CO
mdash o laquo (D-O mdash O O bullbull B Ol o -cmdash e oic f~ to a (gt TD mdash
E 1- Cpoundmdash 3 O O CO P m T1
L u
T3 CO
lto sshy0 O CA W
laquoT3 O CO 0 C J= CO tlaquo Q bull 3 O Ol 1- C o mdash 3 E a
3 E E i- to
Z L
mdash bull mdash O 4-3 Cl Q
bullD 0) CO T5 N CO mdash C -P 1 0 U TO O mdash 4J Cfc
mdash U) c shybullgt O w C O Q (5 4J 0
3 -J bull U)
5 gt TO_ U
bull gt pound mdash 3 mdash L ro TD
JJ-D - CO TO laquo QO
C 0
^ 0) T3 mdash O
r to 3
O O L L
0
01 TO gt bull
tshy mdash OT3 mdash
CD O C N U) O mdash
TO O CO mdash C C
bull^ ~ CO TO TO gt U iJ
mdash C W to O
5 c c 4J 3 CO X LJ
^ bull bull0 laquolt- ej
TO CJ CO mdash C JJ
z u to mdash T3 4J ai TO CD C laquo bull c c ugt o cr 0) bull mdash CO mdash O bull gt JC TO ^ mdash Q CO O JJ O Q bull- CO to mdash to c Z CC O il mdash 4J gt
mdash Omdash O1O CD mdash U) TO C X mdash O CO C L mdash Cvv O W pound G CO C C
O gtgtgt C C mdash CO C TO CO 3 E mdash -J laquo 1- bullgt CO 0 to
bullo CO
cshyo bull
ugt C CO TO c w 4J-Q co e a c
mdash re TO in E to
Q
JJ c bullo
a LJ co E bull LJLJ
O mdash zx ZQ
ax
z o mdash1mdash Q
mdasha o CO LJ a LJ ~J
s CO
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bullmdash
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bullO bullmdash
gtgt3 TO CT L mdash Olmdash 1 O CD mdash 3 a CT cshy re 3 a c- o
^j C CO E Ol
bullmdash CL
bull CO 01 D 3
U
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bullmdash av^ CO 4J IA TO 5
T3 CO C
bullD
mdash mdash O CO
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bullmdash ^
bulla CO L
4J
C CO o 3
(A C TO
Imdash
03
ai_ 3 a bullo bull mdash 05 3 O) 00
mdash mdash C c gtgt G CO
O O
bullo^ = c a 0)
E C O umdash u a L_ bull OlCD mdash
4J mdash
u) obulla o u) amp 5 c -a 7 O C mdash o mdash _ i- (0
CO E laquoJ
C
a
bulla c bull o bull
c bullQ CO
3 01
CT mdash mdash a mdash -v
t- Ol CC-D 0) 3
CJ raquo
x^ CO
bullo 3
lt) bull_
gtraquomdash CO O 1- Ui O)
bulla ^ c mdash mdash mdash TO co in
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mdash TO
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c mdash
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CO X
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LJ
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tmdash CM CM ^_ CM
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18
bull -a gtgt CD
CO S jj
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bullo CD jJ
bullo z 3 O L
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CD 1-gt o CO
jpound cshy x mdash o mdash
- 0 1 mdash bshy
4J 1 CO
Z u
CO mdash T3 CD CD
co E C mdash z bullD 73 4J O JZ = CD ltshyO C CD
CD 4J laquomdash C
bullO Qmdash U N ET3 bull mdash 0 Cmdash i- L re mdash oltmdash o
O 1 f-u gt Z 03 shy3 mdash CD
O O tshyo
O (Q C N O mdash shy
o agt O 4-raquo bull z in jz 3 CO 4-gt
gt Q ltshy 0
CD JZ N w Oshy- O
laquo ^ mdash 13 mdash m
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z s_ mdash
laquo
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re 3 O L
CD U -D SshyCD CO CO N 0) mdash 0-E S GO CD CO L
i
CO UJ gtmdash
z laquo w mdash ffl JZ CO 4-gt 4J JZ
4_) t_ mdash bull
cz QJ co jZ C C mdash 4J
re (uS a z z
OX) mdash a) O W E
Z O O JZ bull CL V E
C (~ mdash r re O CD
obullz
-J VI O 4J z re o gt o jt o 5
mdash tshy Q mdash CO 0 Q) mdash j j a C5 E U3
mdash CO mdash 4JCO CO E
CO
JZ 0 3 mdash t_
E Ot3 O L
bull
C 3 3 U L
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1 I
bullz o mdashfmdash Q
mdashfV
O CO LJ O
LJ _J Q y
CO
C CO
mdash mdash 0 10
bullc bull CD 0) C 4-gt mdash w CO CO 4-1 to
gtJ CD Sshymdash CD Q-O L- gt
CD 4^
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^
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19
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20
1 (See Plate 53-1) This is the predominant waste material currently
being disposed of in the active landfill
Crushed drums were distributed throughout the original
landfill and were found in Excavations 2 4 4-5 7A 8A and 14 Some
drums such as those found under the road in Excavation 7A may have
been crushed by heavy equipment operating in the landfill Others like
those found at depth in sandy fill in Excavation 2 appear to have been
crushed before burial Drummed liquid and sludge wastes are also
distributed throughout the landfill (See Plate 53-2) They were found
in Excavations 1 4 5 6 8 and 10 These wastes are discussed below
One sealed drum was openedand found filled with refuse -- paper cups
towels paint covered rags etc One open and partially crushed drum
contained a dark granular solid waste This material was sampled
(Sample 10B) and found to be nonhazardous
Small deposits of dried pigmentsludge were found in
Excavations 3 4 6 9 and 13 Discernible layers of pigmentsludge and
stained soils were present in Excavations 7A 8 and 8A (See Plate
53-3) Of particular note was a 2 to 4-inch thick layer of
grey-colored dried sludge found at Excavations 7A and 8 All of these
wastes were sampled and the results are discussed below
Laboratory Analyses
Laboratory analyses were performed on 10 selected samples
obtained from both containerized (drummed) and uncontainerized wastes
Samples were analysed for 3 metals and 87 priority pollutants including
11 acid compounds 45 baseneutral compounds and 31 volatile organic
compounds Table 5-4 summarizes the analytical results and the
laboratory data sheets are presented in Appendix D
Of the 45 priority pollutant baseneutral compounds only 4
were identified in the samples that were analyzed Baseneutral
21
compounds and particularly phthalates were the most prevalent
chemicals and also were reported in the greatest concentrations The
highest levels of naphthalene (1200 ppm) bis (2-ethylhexyl) phthalate
(110000 ppm) and di-n-octyl phthalate (6200 ppm) were found in sample
4A a translucent red liquid obtained from a drum The highest
concentration of benzyl butyl phthalate (13000 ppm) was found in sample
6B a clear liquid and pink sludgepigment obtained from a drum
A total of 8 volatile organic compounds were identified The
highest levels of benzene (100 ppm) xylenes (19000 ppm) and
ethylbenzene (5300 ppm) were found in sample 5A a clear liquid
purple-grey sludge obtained from a drum Toluene was found in highest
concentration (12000 ppm) in sample 1A a purple-grey thick opaque
liquid obtained from a drum Methylene chloride (13 ppm) was
identified in greatest concentration in sample 8A-C a purple stained
soil and powdery waste Sample 10A a purple liquid obtained from a
drum was the only sample found to contain 1-1 dichloroethane (2000
ppm) Finally trace levels of trichloroethylene (sample 10A) and
111-trichloroethane (sample IB) were also reported
Samples were tested for three metals - cadmium zinc and
chromium The highest concentrations of cadmium (2200 ppm) and zinc
(5700 ppm) were found in sample 4A a translucent red liquid obtained
from a drum The highest level of chromium (52 ppm) was reported in
sample 5A a clear liquidpurple-grey sludge obtained from a drum
22
60 DISCUSSION
61 EXISTING SITUATION
Under existing conditions relatively small quantities of
volatile organic compounds (VOC) are indicated to be leaking from wastes
buried on the landfill site To date ground and surface water
monitoring results indicate relatively low concentrations of VOC in the
ground water and below detection limits in the adjacent brook (See
Tables 61-1 to 61-10) The results indicate that no potential health
risks from VOC and other constituents currently under observation are
being caused by the landfill operation to down stream surface water
users It would be prudent for Troy Mills to continue to monitor the
quality of Rockwood Brook upstream and downstream for VOC and on the
basis of waste analyses (previous section) to monitor ground and
surface water points for toxic metals and baseneutral compounds
62 SITE HYDROLOGY
An analysis of the hydrology of the landfill site was
performed in 1982 (NAI report of September 1982) The subwatershed that
contains the landfill site is (about 44 acres) a small fraction of the
watershed area that contributes to Rockwood Brook above surface water
sampling point C (about 1650 acres see Figure 62-1) This indicates
that most of the flow of the brook at point C (about 97) is contributed
by upstream watershed areas Thus leachate discharging into Rockwood
Brook from the landfill site can be expected to be diluted by over 30
times its volume This factor and the volatilization which naturally
occurs results in parameters detected in the Troy Mills monitoring
wells often becoming undetectable when they enter the brook
f 5
Geologic conditions which were defined in the NAI report of
July 1982 indicate that permeable deposits of sand and gravel overlie
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27
TABLE 61-5 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M5 (UPGRADIENT WELL)
Parameter Date Sampled 11-22-83
Specific conductance
pH2 81
Dissolved iron mg1 036
Dissolved manganese mg1 010
Chloride mg1 10
Phenolics mg1
3
023
Identified volatile organics
None identified ND
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (yg1)
28
TABLE 61-6 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M6
Parameter
Specific conductance
PH2
Dissolved iron mg1
Dissolved manganese mg1
Chloride mg1
Phenolies mg1
Identified volatile organics
11-dichloroethane tetrachloroethylene 111-trichloroethane
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vg1)
Date Sampled 11-22-83
152
lt002
29
6
0002
27 trace 140
29
TABLE 61-7 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M7
Parameter Date Sampled 11-22-83
1 47 Specific conductance
pH2 62
Dissolved iron mg1 002
Dissolved manganese mg1 0026
Chloride mg1 gt2
Phenolics mg1 0070
3 Identified volatile organics
111-trichloroethane 5
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vig1)
30
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glacial till and bedrock The sand and gravel deposits form a permeable
conduit through which leachate from the waste burial areas migrates
The permeable deposits lie in the area north of monitoring well M-l (See
Figure 62-1) In general the water saturated thickness of the sand
and gravel in the vicinity of the north-south access road is 6 to 12
feet
64 POTENTIAL FOR GROUND WATER CONTAMINATION
641 Estimated Quantity of Drums
The test pit excavation and sampling in the drum burial area
indicates a potential source of ground water contamination for the
future Many of the drums encountered were in fair to good condition
and contained liquid wastes An estimate of the number of drums in the
deposit was made with the following assumptions
1 The complex magnetic anomaly was simplified into a geometric solid 600 feet long 40 feet wide and 10 feet deep with a volume (V) of 240000 cubic feet
2 Each steel drum (D) occupies 105 cubic feet (including voids)
3 The density of packing (P) was assumed to be 50 of the packing that can be achieved with perfect cubic packing
THEN
N = estimated number of steel drums
N = (VD) (P)
N = (240000105) (05)
N = 11429 drums
The results of the drum excavation work provides a basis for
estimating the potential for specific types of chemical loading In
general three main classes of chemical substances were identified in
35
the drums The chemical substances included baseneutral extractable
organic compounds (mostly phthalates and lesser amounts of naphthalene)
volatile organic chemicals and metals
642 Phthalates
The phthalate esters found in the drums include
bis (2-ethylhexyl) phthalate ^0^3 benzyl butyl phthalate di-n-octyl phthalate Jd~7
Bis (2-ethylhexyl) phthalate was found in the highest
concentration at 110000 ppm (11 percent) Benzyl butyl phthalate is at
the second highest concentration 13000 ppm (13 percent)
Characteristics of those phthalates found are presented in Table 64-1
TABLE 64-1 PHYSICAL PROPERTIES OF PHTHALATE ESTERSshy
di-n-octyl bis (2-ethylhexyl) butyl benzyl DOP DEHP BBP
ALTERNATE o-Benzenedishy di (2-ethylhexyl) benzyl butyl NAMES carboxylic phthalate phthalate
Molecular Weight 3910 3910 312
Melting Point -25degC -50degC -35degC
Boiling Point 220degC 386 9degC 377degC
Vapor Pressure-mdash lt02 torr (150degC) lt001 torr (20degC)
Not
2xlO~7torr (20degC) Available
Solubility 3 rngfc (25degC) 04 mgfc (25degC)
58
13 rngH 48
Log octanolwater 92 873 58 partition coefficient 53 48
Versar Inc 1979 Water-Related Fate of 129 Priority Pollutants Volume II Prepared for US Environmental Protection Agency PBSO-20438 December
bullbullOther names listed in Versar 1979 vMore than one value has been calculatedreported
36
Bis (2-ethylhexyl) phthalate is the most well-studied of the
phthalate esters though the information on phthalate esters as a group
is limited The three phthalates identified at the Troy Mills site have
relatively low solubilities and are readily adsorbed onto suspended
particulates Microbial degradation is effective under aerobic
conditions bur is generally slower under anaerobic conditions
(nonexistent for bis (2-ethylhexyl) phthalate)
The above characteristics are important for two reasons One
the extent and nature of contaminant migration from the site are
dependent upon the physical characteristics Second the treatment
(clean-up) alternatives for contaminated ground water or soil can be
estimated from the characteristics
From the available information it appears that the phthalates
present at the Troy Mills site would be relatively immobile due to their
low solubilities and high adsorption rates The presence of toluene and
methylene chloride at the site however may increase the phthalates rate
of migration
It is important to note that none of the phthalates have been
found to be present in the monitoring wells nor in the surface water
sampled probably due to the low solubility and high adsorption rate
37
643 Napthalene u K r
Naphthalene has also been found in significant quantities in
the sampled drums Naphthalene is a polycyclic aromatic hydrocarbon and
has the following properties
Molecular Weight 12819
Melting Point 8055
Vapor Pressure (20degC) 00492 torr
Solubility in Water (25degC) 344 mgfc
317 mgfc
Log octanolwater partition coefficient 337
Versar 1979
Naphthalene has mid-range adsorption rates and solubility It is
therefore inferred that there would be some adsorption to soils in a
ground water environment It is important to note that naphthalene has
not been detected to date at the monitoring wells or the surface water
sampling locations This is expected to be a result of adsorption on
the soils
644 Volatile Organic Compounds
Volatile organic compounds tend to migrate readily within
soils and ground water They are therefore considered a threat to
surrounding ground and surface waters if they are released in sufficient
quantities
Volatile organic compounds were detected in samples from six
steel drums The total volatile organic (TVO) concentrations in the
38
wastes ranged from 9 ppm to 30100 ppm and averaged 8570 ppm In order
to determine the potential for future contamination by volatile organic
compounds an estimate of waste quantity based on information from the
drum excavation program was made It was assumed that 7000 steel drums
in the deposit are 60 full of liquid waste with an average TVO
concentration of 8570 ppm The computed volume of liquid waste is
231000 gallons with an average TVO concentration of 8570 ppm This is
equivalent to about 1980 gallons of pure TVO
Two of the volatile organic compounds that have been most
prevalent in the existing ground water monitoring system are
111-trichloroethane and ethylbenzene The EPA suggested no adverse
response level (SNARL) for 111-trichloroethane is 330 ugpound for
1 day of exposure and 35 jigd for exposure over a life-time in
drinking water
In general ethylbenzene is a prevalent chemical in the
environment Sources include commercial (eg petroleum and petroleum
by-products) motor vehicle exhaust and cigarette smoke An intake of
16 mgday (1 mgfc) has been calculated as an acceptable rate to
protect from toxic effects Carcinogenic effects have not been
identified to date The physical properties of ethylbenzene are
presented in Table 64-2 The principal mechanism for removal of
ethylbenzene from water is volatilization In addition to
volatilization adsorption may also be an important removal mechanism
based on the log octanolwater coefficient This factor is important in
evaluating the migration of ethylbenzene from the disposal site
Toluene which was also identified in waste and ground water
samples exhibits properties similar to ethylbenzene in that it
volatilizes easily Toluene which is also referred to as methylbenzene
is distinguished from benzene by the substitution of a methyl group for
one hydrogen atom Physical properties of it are presented in Table
39
64-2 The EPA suggested no adverse response level (SNARL) for toluene
is 1 mgpound in drinking water with a maximum exposure time of ten
days
TABLE 64-2 PHYSICAL PROPERTIES OF ETHYLBENZENE AND TOLUENE
ETHYLBENZENE TOLUENE
Molecular Weight 10616 9213
Melting Point -949degC -950degC
Boiling Point 1362degC 1106degC
Vapor Pressure at 20degC 7 torr 287 torr
Solubility in water at 20degC 152 mg2 5348 mgd
Log OctanolWater Partition Coefficient 315 269
645 Metals
One liquid sample contained high concentrations of cadmium
(2200 mgd) and zinc (5700 mgd) indicating that the waste deposit is
also a potential source of certain toxic metals Tests for these metals
have not been made to-date in ground or surface water samples It would
be prudent to add toxic metals such as cadmium chromium lead and
mercury to the list of parameters that are being monitored to further
characterize the quality of adjacent ground and surface waters US
EPA and New Hampshire drinking water standards for these metals are
cadmium 01 mgd chromium 05 mgpound lead 05 mgd mercury 002
mgd Although zinc is not considered a highly toxic metal the
US EPA has set a secondary drinking water maximum contaminant level of
5 mgd on this metal
40
70 CONCLUSIONS
The following conclusions were drawn during this
investigation
1 A steep-gradient irregular-shaped magnetic anomaly is present under closed and covered portions of the south part of the Troy Mills landfill
2 The magnetic anomaly is caused mostly by an irregular-shaped accumulation of disposed steel drums
3 In a randomly conducted sampling of drums in the source area for the magnetic anomaly 16 of the drums contained liquid andor sludge 33 were crushed flat and 51 were not sampled because there were no accessible openings
4 Laboratory analyses indicate that the random waste sampling contained significant concentrations of several volatile organic chemicals several baseneutral priority pollutants and high levels of cadmium and zinc
5 Observed concentrations of volatile organics at the monitoring wells are relatively low Because of their potential for migration in the ground water continued monitoring of volatile organics will be required
6 Volatile organic chemicals have not been detected in Rockwood Brook to-date Because of the presence of low levels of volatile organics in the ground water they should be monitored in the brook on a regular basis to confirm the lack of impact
7 The presence of high concentrations of cadmium and zinc in one of the waste samples indicates that trace metals should be monitored periodically
8 The presence of baseneutral extractable compounds (phthalates and naphthalene) in all of the analyzed waste samples indicates that these compounds should be monitored periodically
9 The phthalates are not expected to migrate freely because they have low solubilities and are readily adsorbed onto soil particles
10 If elevated concentrations of volatile organic compounds trace metals or baseneutral extractable compounds should occur in the monitoring system (wells and brook) in the future a need for site remedial actions to mitigate the potential for downgradient ground and surface water contamination could develop
~
80
41
RECOMMENDED PLAN
Based on the preceding conclusions it is recommended that the
following plan be implemented by Troy Mills Inc
1 Continue monitoring ground and surface water quality at the Troy Mills Inc landfill sampling on a quarterly basis with sample collections during April July October and January
2 To confirm the absence of the landfills impact on Rockwood Brook test samples for volatile organic compounds by GCMS from surface Stations B (upstream) and C (downstream) on the April and October samplings
3 To determine if trace metals are present in downgradient ground waters conduct analyses for cadmium chromium lead mercury and zinc on samples from all monitoring points during the April sampling and on subsequent sampling rounds if necessary
4 To confirm the continued absence of baseneutral extractable compounds in downgradient ground and surface waters conduct analyses for baseneutral extractable compounds on samples from monitoring wells M 2 and 3 and surface Station C (downstream) on the April sampling and on subsequent sampling rounds if necessary
5 If a sudden rise in concentrations toward unacceptable levels should occur in the monitoring system (wells and brook) additional monitoring rounds at a monthly interval should be conducted to confirm the rise in concentrations
6 If elevated concentrations persist and are verified by the additional monitoring remedial alternatives will be defined to mitigate the potential for downgradient ground and surface water contamination
Respectfully submitted NORMANDEAU ASSOCIATES INC
Dennis R Sasseville Project Manager
Donald H Bruehl f laquo | APG Senior Hydrogeologist -^ - - AIPG Certificate No 2272 ^ -v^
^^Z-^^
APPENDIX A
SITE SAFETY PLAN
GENERAL SAFETY PLAH FOR
TROT MILLS LANDFILL TROY MEW HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
Prepared by
NORMANDEAU ASSOCIATES INC Bedford New Hampshire
R-457
November 1983
TABLE OF COHTENTS
PAGE
SECTION 1 BACKGROUND INFORMATION 2
Identification 2 Personnel 2 Site Description 3 Project Description 5
SECTION 2 HAZARD EVALUATION 6
Overall Degree of Hazard 6 Specific Hazards 8 Necessary LPP 8
SECTION 3 FIRST AID FOR EXPOSURE 10
SECTION 4 OPERATIONS SAFETY PLAN 11
General Personnel Protection GuidelinesAction Levels 11 Site Reconnaissance 13 Task 1 - Magnetic Survey Topographic Survey 14 Task 2 - Drum excavation and Sampling 15
SECTION 5 EMERGENCY INFORMATION 16
Emergency Telephone Numbers 16 Route to Hospital 16 Contingency Plan 17
APPENDICES 18
A - LEVELS OF PERSONNEL PROTECTION 18 B - DECONTAMINATION PROCEDURES 23 C - PERSONNEL AND RESPONSIBILITIES 25 D - PERSONNEL CASUALTY 26 E - GUIDELINES FOR SITE OPERATIONS 27
GENERAL SAFETY PLAN FOR
TROY MILLS LANDFILL TROY NEraquo HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
The following is a Safety Plan for on-site activities performed
during the Investigation of the Troy Mills Landfill being conducted by
Normandeau Associates Inc (NAI) of Bedford New Hampshire
The document is intended to be an in house working guideline
for personnel trained and experienced in hazardous waste field work and
not a treatise on safety Familiarity with standard equipment and proshy
cedures is expected Where possible non-site specific information has
been appended
All NAI employees subcontractors and visitors will be required
to follow this safety procedure plan and to report to either NAIs proshy
ject manager (P M) on site coordinator (OSC) or safety officer (SO) on
issues relating to safety
SECTION 1
BACKGROUND INFORMATION
IDENTIFICATION
Site Name Trey Mills Landfill NAI-ID No 457
Trey Mills Inc Troy NH 03465
AddressLocation At the south end of the dirt road about 15 miles
south of Troy NH between Rockwood Brook and the
old Boston and Maine Railroad grade
County Cheshire Phone 603-242-7711
PERSONNEL
Brook Dupee Bureau Hazardous Waste 603-271-4611
State Contact John Regan Bureau Solid Waste 603-271-4586
Dan Allen WSPCC 603-271-2755
EPA Contact
Other Contacts
Client Contacts Barrett F Ripley (Vice President)
NAI Personnel - (472-5191)
Project Manager - Dennis Sasseville
On Site Coordinators - Alton Stone
Safety Officer - Elizabeth Gross (Phoenix Safety)
Technical Director - Don Bruehl
Other - Douglas DeNatale Steve Ransom
SITE DESCRIPTION
Type of Facility Company (on-site) landfill
RCRA Status Generator Disposer
Size About 15 acres BuildingsStructures None
Surrounding Land Use N Forested
(one mile radius) E Abandoned Railroad
Forest RuralResidential
S Forested
W Forested Mountain side
Unusual Features or Terrain None
Site Activities - Troy Mills manufactures textiles carpets and related
products Since 1968 waste materials including
drummed wastes have been landfilled on company proshy
perty Drums mostmany of which may be emptycrushed
are buried in an inactive section of the landfill
The active section is currently accepting waste
which is considered to be non hazardous
Specific - Improper disposal of hazardous waste
Problems - Leachate seep
Contamination of ground water
Hazardous WastesMaterials On-5ite
Wastes - Uncured foam rubber latex sludge
SBR rubber silicone defoamer potassium oleate soap
calcium carbonate and feldspar filters zinc oxide
and sulpher salt cure system
- Vinyl plastisol sludge
PVC dispersion resin DOP and DOA plasticiser
calcium carbonate filler organic pigments AZO
dicarbcnamid blowing agent zinc salts expoxidized
soybean oil cadmLum-bariin-zinc stabilizer Varsol
MEK prints and topcoats sludges
PVC acrylic resins organic and inorganic pigments
MEK solvent toluene silicate fillers
Industrial solvents and chemicals
11 -dichlorethane 12-dichlorothane
111-trichloroethane trichlorethylene tetrachshy
lorethene methylene chloride toluene benzene
ethylbenzene benzidine 33-dichlorobenzidine aeroshy
lein acrylonitrile napthalene benzoperylene dibenshy
zoanthrasene idenopyrene
Pesticides
There is a possibility for low levels of pesticides
to be on site These would include Chlorodane
heptachlor expoxide toxaphene aldrin alpha BHC
beta BHC 4-4-DDT endosulphan 1 heptachlor
PROJECT DESCRIPTION
Purpose Tb characterize ground water conditions at the site and to
characterize wastes buried on site
Specific Tasks
Site Reconnaisance
Task 1 - Magnetometer SurveyTopographic Survey
Task 2 - Excavation for inspection of drums
SECTION 2
HAZARD EVALUATION
Overall Degree of Hazard - Moderate
Task Hazard Proposed LPP
Site Reconnaissance Low Level C
Task 1 MagnetometerTopographic Surveys Low Level CD
Task 2 Drum ExcavationSampling Moderate Level B
Conpany records have indicated that a variety of industrial
and potentially hazardous wastes including drummed wastes
were disposed of on site Several of the subtances are
trade name materials or industrial process materials and it
is difficult to determine the specific chemical composition
Hazard is dependent upon concentration of material state of
material (solid sludge drummed liquid) and degree of
decomposition
Many of the materials - SBR rubber silicone defoamer
potassium oleate soap calcium carbonate and feldspar
fillers zinc oxide and sulpher salts plasticiser
calcium carbonate filler organicinorganic pigments AZO
dicarbonamid blowing agent epoxidized soy bean oil
cadmiura-bariun-zinc stabilizer - probably do not represent
a significant hazard to an inspection team if they are
bound into a sludge or solid Personnel are not likely
to injest or come into a prolonged high concentration
contact with these materials In powdered or dust conshy
ditions the materials are more hazardous due to the inhashy
lation of contaminated particulates
MEK (TLV-200ppm) toluene (TLV-100ppm) and Varsol
(turpentine thinner composition unknown) are volatile
organics which require respiratory protection and contact
protection
Depending upon state and decomposition PVC resins could
be a source of vinyl chloride monomer (VCM-a carcinogen)
requiring respiratory protection VCM is not adequately
filtered by air purifying respirators
Results from ground water sampling showed low levels of
industrial chemicals (PPB range) At these low conshy
centrations the chemicals do not represent a significant
hazard However the low concentrations in ground water indishy
cate the possibility of higher concentrations in the waste
materials
Industrial chemicals - napthalene (TLV-10 ppm) peryshy
lene anthrocene and pyrene which are hazardous
through inhalation or absorbtion Furthermore as
double benzene ring chemicals they are potential
carcinogens
Results from ground water sampling indicated possible
low levels (parts per trillion) of several pesticides
- chlorodane heptachlor epoxide toxaphene eldrin
Alpha BHC Beta BHC 4-4-DDT endosulphan These were
tentatively identified during a first analytical run
but not confirmed during a second run laboratory
review (GCA Bedford Mass) determined that the
material was actually a complex of highly degraded
heavy organics derived from the industrial waste The
presence of pesticides in industrial textile waste is
unlikely
Specific Hazards
1) Inhalation of organic vapors
Excavation of buried material and sampling of drums could
initiate high vapor concentrations
2) Fire and explosion
Many of the solvents are flammable liquids and volatile
Excavation of material and sampling of drums should
proceed cautiously in order to avoid rupturing shocking
or sparking of drums and material
3) Inhalation of contaminated dustparticulates
Excavation of buried material may result in a release of
particulates
4) Contact contamination
Excavation and sampling of wastes could possibly result in
contact with contaminated waste and soils necessitating
protective clothing
Necessary LPP
Site Reconnaissance - Level C The site has been visited on numerous
occassions by the state and private personnel Use of an HNU (102 ev
probe)- has not indicated significant vapor concentrations Significant
odors during dry weather or other hazards have not been noted
Sections of the landfill are currently active and adverse effects to
personnel have not been noted Level C - (tyveks rubber safety boots
organic vapor cartridges) is sufficient
Task 1 MagnetometerTopographic Survey - Level CD LPP will depend
upon the results of the Site Recon Significant vapor concentrations
or likelihood of particulates will necessitate an upgrade in the LPP
Otherwise Level D (work clothes safety boots boot wash) is sufficient
Task 2 Excavation and Sampling of Buried Drums - Level B The potenshy
tial for encountering significant concentrations of hazardous
materials during this task is moderately high Full Level B - (SCBA
chemical resistant tyveks hoods rubber safety boots rubber gloves)
will provide necessary respiratory and contactsplash protection
The use of the hooded yellow tyveck and the taping of ankleboots
wristsgloves and face maskhood junctions will provide complete conshy
tact protection
10
SECTION 3
FIRST AID FOR EXPOSURE
INHALATION OF VAPORSPARTICUIATES
Symptoms - eyenosethroat irritation nausea dizziness headache weakness fatigue lightheadedness drowsiness Loss of coordination confusion vomiting cramps (These sympshytoms are similar for most organic vapors particularly solvents)
Treatment Mild Exposure - Bring victim to fresh air Rinse eyes and throat if
irritated Heavy Exposure - (victim vomits very dizzy groggy faints etc)
Bring victim to fresh air Evacuate to hospital Prepare to administer CPR
Victim should be monitored for 48 hours in case of a delayed reaction
CONTACT EXPOSURE
Symptoms - Itching burning redness of skin Severe contact exposure for certain solvents will progress to CNS (central nervous system) symptoms similar to those for inhalation
Treatment - Remove contaminated clothing flush with water dry and banshydage Monitor victim for CNS symptoms for at least 48 hours
FIRST AIDSAFETY EQUIPMENT
The following equipment will be stationed at the Hotline or when appropriate down range
- Fully equipped first aid kit - Oxygen bottlekit - Nine (9) Ib chemical fire extinguisher - Eyewash bottle or other pressurized water filled container
11
SECTION 4
OPERATIONS SAFETY PLAN
This section outlines the specifics of safety procedures to be
used during each phase of the operations Safety procedures may be
upgraded or downgraded during site activities pending monitored changes
in the working environment All changes will be in line with the
General Level of Personnel Protection GuidelinesAction Levels for the
Troy Mills Landfill On-Site Investigation as described below
General Personnel Protection GuidelinesAction Levels
An in depth review of levels of personnel protection (LPP) is
presented in Appendix A
Level B (SCBA cotton coveralls or work clothes yellow tyveks (chemical resistant) steel toed rubber boots or work boots with disposhysible over boots and gloves)
Vapor concentrations (as measured on an OVA or HNU 117 EV Probe) greater than 5 ppm above background
- Oxygen deficient atmospheres less than 195
Specific actions (ie excavationsampling of drums) which could initiate a sudden moderate or high concentration of vapor
Level C (full face respirator organic vapor dust combo cartridge tyveks over work clothscoverails rubber safety boots gloves)
Vapor concentrations above an established clean zone backshyground level
During conditions (natural or personnel induced) which result in high levels of dust (visable above background atmospheric concentrations of particulates)
Level C activities require continual air monitoring
12
Level D (cotton coveralls or other work clothes safety shoes and safety glasses when down range Tyveks may also be needed)
Support areas and downrange areas where a higher LPP has not been deemed necessary
Continual air monitoring in downrange areas
Explosive Atmospheres
- 20 LEL (lower explosive limit) as recorded by an explosishymeter Secure and evacuate the work area
Oxygen Deficient Atmospheres
- Less than 195 (by volume) oxygen atmosphere requires upgrading the level of Personnel Protection to Level B
Task Specific Safety Plans
Levels of Personnel Protection indicated for specific tasks below are those which are anticipated to be used Changes in site conshyditions and results of air monitoring may indicate the upgrade downgrade of the LPP
13
Site Reconnaissance (SR) Date Sept 21 1983
Purpose To review on-site conditions and determine LPP necessary for further tasks To evaluate safety hazards Preliminary planning of future tasks
LPP - Initially Level C Updowngrade as necessary
Equipment - OVA HNU (102 ev probe)
Hotline - End of access road Upwind if possible
Command PostFirst Aid - Behind Hotline
Decontamination - Boot wash
Operations
Three man team Two persons advance in front with instrushyments Third person at distance as backup
Team methodically sweeps (criss cross) the proposed work areas with instruments
Specific points of interest (leachate seeps etc) are closely checked
All information is loggedsketch mapped
Upgraded LPP as necessary
14
Task 1 - Magnetic Survey Topographic Survey Date Week of October 3 1983
Purpose - Determine the location(s) and extent of buried drums Provide topographic information for site base map
LPP - Level CD
Hotline - End of access road (upwind if possible)
Decontamination - Boot wash
Operations - SO or other NAI personnel will perform a brief safety sweep of the work area
- Work team will then proceed downrange at the appropriate LPP Using the magnetometer the team will systematically criss cross -the work area
Task 2 - Drum Excavation and Sampling Date Week of November 14 1983
Purpose - Excavationsampling of buried drums in order to characterize the condition of the drums and the nature of the wastes conshytained in the drums and buried in the landfill
Msthod - Backhoe and hand labor will be used to uncover the drums in specified locations Samples will be obtained from spillage or leakage around the drums and of contaninated soil Selected drums which have accessible and openable bungs may be opened and sampled Drums will not be moved or staged Clean drums will be available to receive any significant spillage during the opening and sampling
Specific Hazards - Inhalation of organic vapors - Fire and explosion of drummed waste - Contact with contaminated waste or soil
LPP - Full Level B protection Backhoe operator at Level B Backshyhoe equipped with splash shield and without teeth on bucket
Hotline - At the end of the access road Upwind if possible
Decontamination - Procedures will essentially follow those as outlined by the EPA for Level B work Due to the inaccessibility of the site a field shower will not be available See Appendix B
Safety Equipment - OVA HNU eyewash fire extinguisher oxygen kit first aid kit metal detector non sparking implements
15
Operations - The cover soil is very sandy and the drums appear to be buried close to the surface which should facilitate excavation
- Minimum of 4 man team (exclusive of backhoe operator) Two or three man downrange team for digging and sampling One or two men in supportbackup at hotline
- Personnel will hand dig several small holes to approximately one (1) foot depth in each Location area If drums are not encountered the backhoe will scrape off soil to that depth
- Excavation will proceed alternating hand and backhoe methods At depths below four (4) feet the sides of the pit must be angled back to less than 45deg
- Prior to opening a closed drum the backhoe will nudgebump the drum to check for shock sensitive material An alternate method will be to attach a length of rope to the drum and from a distance pull on the rope to jog the drum
mdash Backhoe The backhoe operator will work at Level B utilizing air supplied from a large cylinder attached to the backhoe The backhoe will also be equipped with a splash shield A scraping bucket without teeth will be used
Prior to backhoe excavation at each location the area where the backhoe will be stationed will be checked for drums which could be ruptured by the backhoe feet
f Excavation areas will be checked for drums utilizing hand excavations or a metal detector prior to removing material by machine
16
SECTION 5
EMERGENCY INFORMATION
Emergency Telephone Numbers
If calling one of these numbers please state NAME LOCATION
and type of PROBLEM
Local Emergency Support
Fire Department (Troy 242-7759) For all emergencies use
Ambulance 352-1100 Mutual Aid (Keene) 352-1100
Police Department (Troy 242-7992)
Hospital 352-4111 (Cheshire Hospital in Keene)
Town Clerk 242-3845 State Agencies
NH Bureau of Hazardous Waste Management 271-4608
NH Water Supply and Pollution Control Commission 271-3503
NH Fire Marshall Office 271-3336
NH State Police (24-Hour Dispatch) 1-800-852-3411
Other
US EPA (24-Hour Hotline) 617-223-7265
Poison Center Mary Hitchcock Hospital 1-800-562-8236
Route to Hospital
- Follow dirt access road to Bowkerville Road - Left on Bowkerville Road to Rt 12 - Left (north) on Rt 12 through Troy to Keene NH - At major junction of Rts 9 10 101 and 12 go straight through
into Keene - At common go half-way around and go right on Court Street - Hospital is at 580 Court Street
17
Contingency Plan
Signal - five (5) one second blasts of auto or air horn Action - All personnel immediately excavate dovmrange areas and
report to Hotline for instructions
Personnel Unexplained Fire (if small) Accident (serious) Collapse of Personnel
Evacuate area Emergency ^ ^Evacuation Evacuate Area
First Aid
Estimate Explosion Level B (for Potential Contact Outside Help evcavation)
Evacuate Victim i If
Level B Prepare for Transportation
1 First AidCPR Use extinguisher Transport
Contact Outside Help Notify Coup any Have Proper Information Personnel (see below) 1
Transport
Call Fire Dept (if necessary)
For Hospital Victim
- Name and Phone of family physician
- Description of Incident chemicals involved symptoms nature of injury proposed treatment and plan of transportation
18
APPENDIX A
LEVELS OF PERSONNEL PROTECTION
Because of the possible dangers of exposure to toxic or harmshyful chemicals protective equipment must be worn during work on hazardous waste sites Levels of Personnel Protection (LPP) describe respiratory clothing and other equipment necessary for protecting personnel against expected hazards
The descriptions below are for full dress at a given LPP where hazards are expected to be at a maximum for which the given LPP is conshysidered adequate Depending on site conditions and work activities the clothing and dress requirements of a given LPP are commonly modified
LEVEL A
1 Personal Protection Equipment
Positive Pressure SCBA (MSHANIOSH approved) Operated in the positive pressure mode
Totally Encapsulating Suit (boots and gloves attached)
Gloves - Inner (tight fitting and chemical resistant)
- Boots - Chemical - protective steel toe and shank Depending on suit boot construction worn over suit boot
- Gloves shy Outer chemical-resistanttion worn over suit gloves May bchemical-resistant gloves worn insid
Dependinge replaced withe suit glo
on s
ves
uit construcshy tight-fitting
- Underwear shy Cotton long-John type
- Hard Hat (under suit)
- Disposable protective suitover encapsulating suit)
gloves and boots (Worn under or
- Coveralls (under suit)
- 2-way Radio Communications
Optional
19
2 Criteria for Use
A The type and concentration of toxic substances are known and require the highest level of combined protection to the respirashytory tract skin and eyes These conditions would be
1 Atmospheres which are immediately dangerous to life and health (IDLH)
a IDLHs can be found in the NIOSHOSHAs Pocket Guide to Chemical Hazards andor other references
2 Known atmospheres or potential situations that would effect the skin or eyes or could be absorbed into the body through these surfaces in toxic quantities
a Potential situations are those where vapors may be generated or splashing may occur through site activities
b Standard reference books should be consulted to obtain concentrations hazardous to skin eyes or mucous memshybranes
3 Oxygen deficient atmospheres with above conditions
3 At sites where the type andor potential concentration of toxic substances are unknown
1 Unless circumstances strongly indicate otherwise the site should be presumed to present hazards to the respiratory system skin and eyes Level A protection would provide the highest level of protection for the initial entry team
a Such circumstances might be
1 Environmental measurements contiguous to the site
2 Reliable accurate historical data
3 Open unconfined areas
4 Minimal probability of vapors presence or splashing with cutaneous effecting substances
2 Enclosed areas such as buildings railroad cars ships holds etc
20
LEVEL B
1 Personal Protective Equipment
Positive Pressure SCBA (MSHANIOSH approved) operated in the positive pressure mode
- Hooded chemical-resistant suit
Gloves - Outer chemical-protective
Gloves - Inner tight-fitting chemical-resistant
Boots - Outer (chemical-protective heavy rubber disposables)
Boots - Inner (chemical-protective steel toe and shank)
2-way Radio Communications
Hard Hat
Face Shield
2 Criteria for Use
A The type and concentration of hazardous substances are known and require the highest degree of respiratory protective but a lower level of skin protection
1 Atmospheres which are immediately dangerous to life and health (IDLH) Type and concentration of vapors in air do not present a hazard to the small unprotected areas of the body
2 Atmospheres with concentrations of known substances greater than protection factors associated with full-face air-purifying respirators with appropriate cartridges
3 Atmospheres with less than 195 oxygen
B When a determination is made that potential exposure to the body parts not protected by a fully encapsulated suit (primarily neck ears etc) is highly unlikely
1 Known absence of cutaneous or percutaneous hazards
2 Activities performed preclude splashing of individuals
C Level B protection is recommended as the lowest level of protecshytion for initial entries until the hazards have been further identified and defined by monitoring sampling and other reliable methods of analysis and personnel protection equipment commensurate with these findings utilized
21
LEVEL C
1 Personal Protective Equipment
Full-face or half-face air purifying respirator (MSHANIOSH approved)
Chemical-resistant clothing
Gloves - Outer (chemical-protective)
Gloves - Inner (tight-fitting chemical-resistant type (or woven liners)
Hard Hat (face shield optional)
Boots - Outer (chemical-protective heavy rubber throw aways)
Boots - Inner (chemical-protective steel toe and shank)
2-way radio comnunications
Safety glasses required with half-face respirator
2 Criteria for Use
A Site known to contain potentially hazardous materials exceeding
1 Air concentrations requiring a protection factor no greater than that afforded by a full-face mask
2 Harmful levels to unprotected body areas (face neck etc)
3 Well-documented reliable history of site and patterns of prior entry
C No evidence to suspect acute or chronic toxicity to exposed personnel
D Continuous air or personnel monitoring should occur while wearing Level C protection
22
LEVEL D
1 Person Protective Equipment
Chemical resistant aprons
BootsShoes - Safety or chemical-resistant steel toed boots
Boots - Outer (chemical-protective heavy rubber throw-away)
Half-face respirators immediately available
Safety glasses or safety goggles
Gloves
2 Criteria for Use
a No indication of airborne health hazards present
b No gross indications above background on the photoionizer andor organic vapor analyzer
c Continuous air or personnel monitoring should occur while wearing Level D protection
23
APPENDIX B
DECONTAMIHATION PROCEDURES
Depending upon activities and location on site it may be
necessary for personnel to decontaminate prior to leaving the conshy
taminated zone Procedures described below are typical for Level C
operations
Upon exiting downrange (contaminated) areas all personnel are
required to decontaminate by means of the following procedure
1 Place equipment in the Drop Zone at the Hotline
2 Enter the Decontamination Station
Boot Wash Walk through wash tub and scrub boots then rinse boots in second tube
Glove Wash In two pan wash scrub over gloves rinse set out to dry
2 Remove tyvek - if leaving the contamination reduction zone (CRZ) and proceed to clean zones
3 Dispose of heavily contaminated clothing and under gloves
4 Remove respirator
5 Use disposable gloves to clean equipment
6 Use a two bucket (washrinse) to decon respirators at the end of the working day or if they become heavily contami nated
The procedures for a typical Level B Decontamination are
outlined on the following page
TANK CHANGE 9
CONTAMINATION REDUCTION
ZONE
OUTER GLOVE REMOVAL
EXCLUSION ZONE
TAPE REMOVAL
BOOT COVER
GLOVE WASH
(bull)mdashQ-G--copyshySOOT COVEH SCOT COVES 4
REMOVAL GLOVE RINSE
SUITSAFETY BOOT WASH
SU1TSC8A78OOTGLOVE RINSE
SAFETY BOOT 10 REMOVAL
SCSA BACKPACK REMOVAL
SPLASH SUIT 12 REMOVAL
INNER GLOVE WASH
INNER GLOVE RINSE
FACE PIECE REMOVAL
INNER GLOVE 16 I REMOVAL
INNER CLOTHING REMOVAL
FIEUJ 19 REDRESS WASH
SEGREGATED EQUIPMENT
OROP
mdash -HOTLINE-shy
DECONTAMINATION LAYOUT LEVEL B PROTECTION
FIGURE A2-1
CONTAMINATION CONTROLLING
SUPPORT ZONE
25
APPENDIX C
PERSOHNEL AND RESPONSIBILITIES
Project Manager (PM)
Overall responsibility for all Project activates budget
schedule investigative operations safety personnel
On Site Coordinator (OSC)
Responsibility for activities at the site Primary responshy
sibilities include
1) Interfacing with the client state EPA media or other groups
2) Reviewing technical operations
3) Reviewing site safety in particular information supplied by the Site Safety Officer
4) Enforcing site safety and compliance with the Safety Plan
5) Directing Emergency Contingency operations
Safety Officer (SO)
Responsibility for directing the safety of operations and impleshy
menting the Safety Plan Specific responsibilities include
1 Assuring that appropriate personnel protective equipment is available and properly utilized by all site personnel
2 Assuring that personnel are aware of the provisions of this plan are instructed in the work practices necessary to ensure safety and in planned procedures for dealing with emergencies
3 Assuring that personnel are aware of the potential hazards associated with site operations
4 Supervising the monitoring of safety performance by all pershysonnel to ensure that required work practices are employed
26
APPENDIX D
PERSOHHEL CASUALTY
Personnel casualty would most likely result from either chemical
contamination heat-related problems physical injury from accidents
(ie falling lacerations etc) in performing the work or a comshy
bination of one or more of the above The appropriate action depends on
the type of injury involved with the priority being to assist the
casualty as soon as possible without endangering other personnel
Riysical and heat-related injuries can and should be treated
immediately with appropriate first-aid measures and follow-up medical
attention if necessary The injured worker(s) shall immediately move
out of the hot zone or if necessary be moved out by fellow workers as
soon as possible The OSC and Safety Officer shall be notified immeshy
diately and shall recommend further measures as needed
Chemical-related injuries require a much more cautious approach
so as to keep casualties to a minimum If a worker injured by chemical
ejqgtosure is able he shall notify the nearest co-worker and leave the hot
zone immediately- The co-worker shall ensure that the OSC and Safety
Officer are immediately informed and shall accompany the casualty from
the hot zone to the decontamination zone The OSC and Safety Officer
shall determine the appropriate measure
27
APPENDIX E
GUIDELINES FOR SITE OPERATIONS
In order to deal with the potential dangers of exposure and conshy
tamination of a hazardous waste site three zones are delineated
according to the degree of hazard The three zones are 1) Downrange
or Contamination Zone 2 Contamination Reduction Zone (CRZ) 3) Support
or Clean Zone
Downrange or Contamination Zone
The Contamination Zone is the active work area of the site which
encortpasses the areas where there is a potential for exposure and in
which investigative activities will occur (drilling sampling etc)
Within the Contamination Zone the designated level of hazard will be
established necessitating the utilization of personnel protective
equipment
Hot spots are those areas Downrange where observations instrushy
ment readings or specific activities indicate a high probability of
closure or contamination and may require an upgrade in the LPP in the
vicinity of the Hot Spot
Contamination Reduction Zone
The CRZ is an area between the Downrange and Support Zones where
decontamination of equipment and personnel occurs
28
Personnel entering the CRZ shall wear protective clothing and
carry the respiratory protection required for entry within the
Contamination Zone
Personnel working within the CRZ shall remain cognizant of the
CRZ in order to be prepared for any need to increase their level of proshy
tection within the CRZ
A decontamination station will be located at the outer perimeter
of the CRZ All personnel who have been within the Hot lane shall pass
through a decontamination procedure prior to re-entering the Support
Zone
Support or Clean Zone
The Support Zone is the outer area and may be considered to be
clear of contamination potential The command post will be located
within the Support Zone
a) The Command Post will serve as the OSCs headquarters and
will be equipped with
1 Communications
2 Safety Plans
3 First Aid Supplies
4 Analytical Equipment
5 Safety Equipment
APPENDIX B
WORK PLAN
WORK PLAN FOR
TROY MILLS LANDFILL TROY NEW HAMPSHIRE
DRUM EXCAVATION AND SAMPLING
Prepared by
NORHANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
1933
WORX PLAN FOR
TKOt MILLS LANDFILL TROT NEW HAMPSHIRE
DRUM EXCAVATION AHD SAMPLING
DATS November 16-18 1983
PURPOSE
To determine the condition of drums (ie erroty or full
crushed rusted leaking etc) buried in the Troy Mills Landfill To
obtain representative samples toward identifying the types of materials
buried in the landfill This information will be used in the detershy
mination of the level of remedial action needed at the site
METHOD
Using the results of the magnetometer survey the (10) points
have been randomly chosen across the area where the buried drans are
expected to be found Each point is central to an Excavation Location
-- an area four (4) to six (6) feet in diameter which will be excavated
in order to characterize the condition of the drams and to obtain waste
sarples
Preliminary observations have indicated that many of the drums
may be buried within 1-2 feet of the surface Therefore the investigashy
tion will proceed in two phases
Phase 1 mdash Hand Excavation By digging several small holes in
each Location personnel will determine if drums are located within
about one to two feet of the surface If drums are encountered the
excavation will proceed by hand uncovering the dnris for evaluation and
sampling Where drums are not encountered near the surface excavation
at this location will be postponed until Phase 2
Phase 2 mdash HandBackhoe Excavation After all Locations have
been attempted during Phase 1 those Locations in which drums were not
encountered wall be further excavated using a combination of hand
backhoe digging
It is expected that one to two days will be necessary to
cor^piete each phase Depending upon the results of Phase 1 it may not
be necessary to iroleraent Phase 2
Spare drums will be on hand for containerizing any significant
spillage resulting from sampling efforts Excavation locations will be
identified with marked stakes and the holes will be backfilled at the
conclusion of the investigation
SPECIFICS
Excavation Locations (Holes)
Number of proposed excavations is ten (10)
Locations of excavations are presented in Appendix A
Hole Size mdash It is expected that a hole from four (4) feet to six (6) feet in diameter at the bottom (depth at which drums are encountered) will be sufficient to characterize the drums at each Location Deeper excavations will require increasingly large top diameters
Hole Depth -- Holes will be excavated to a maximum depth of six (6) feet Due to the sandy cover material the excavation of deeper holes is probably impractical from both safety and efficiency stand points
If after attempting excavation at each of t-ie 10 proposed
1ocatiors irums are not encountered within six (6) fet of the surf ice
in enough locations to characterize the site excavations nay be
attempted to depths greater than six (6) feet if scil stability permits
or a new set of sampling locations may be chosen
(Excavations to depths greater than six (6) feet require a
significant increase in work The sides of the hole crust be graded back
to less than 45deg in order to insure the safety of investigatorysampling
personnel It may also be necessary to employ bracing bulkheads etc
for trench support)
Excavation Identification
Proposed excavation Locations have been consecutively numbered
from 1 to 10 beginning at the east end of the landfill They will be
marked with numbered stakes
Excavation Methods
Phase 1 mdash Within each Location personnel will dig a nunber of
small holes - about one (1) foot in depth - to probe for drums If
druns are encountered they will continue to excavate until the drur3
are sufficiently uncovered for characterization
Phase 2 mdash After hand probing the Location with snail holes
the backhoe will remove cover material to the one (1) foot depth The
Location will then be probed to a two (2) foot depth before removing
further material Excavation will proceed alternating handprobing and
backhoe excavation until drums are encountered or the maximum six (6)
foot depth is reached
If excavations to depths greater than six (6) feet are undershy
taken they will proceed using the above method
Santnlea
Due to the effort involved in excavating and because conshycentrated waste samples are not expected to undergo rapid degradation it is considered expedient to obtain all readily available samples (exclusive of closed drum samples -- see belcw) These can then be submitted for laboratory characterization as determined by need and budget restrictions
An attempt will be trade to secure at least one sample froa each excavation in order to help characterize the distrishybution of waste materials across the site An attempt will also be made to secure samples of observably difshyferent materials
Sample Types and Mediums - Solid liquid and sludge samples are possible Samples will be obtained from in order of preference -- 1) leakage uncontainerized waste or contaminated soil 2) waste contained in open conshytainers - drum already has a hole or no top or other access point 3) sealed containers
The opening of closed containers will be considered if it is decided that it has not been possible to obtain a sufshyficient number of representative samples from the other mediums
Each sample will consist of two (2) 8-oz jars (with teflon-lids) filled about 23 full One jar will be for organic analysis and the other for inorganic analysis
Sanole Identification - Samples will be identified with a number corresponding to the Excavation Location and a letter Example if three samples were obtained from Location 2 they would be samples 2A 23 and 2C and Samples 2Ad 23d and 2Cd for duplicates
Sampling Methods and Volumes - 11 mm hollow glass tubing trowels disposable scoops will be available to obtain samples Samples tools will be disposed of or deconshytaminated between each sample
Drum Samples - If necessary an attempt will be cude to obtain samples from sealed drums Oily o^und non-rusted drums will be considered Bunjs rust be xn suitable conshydition -jo that the dram cm be openoi withrut cvis ing dainai -ind ca-i be resell od to pr-jvcrt l V-i 30
There wil l be no staging or movement of drums in order to faci l i tate sampling Only drums with accessible bungs will be considered for sampling
Procedure for Drum Sampling
1) Excavate around top of drum
2) Monitor air in the adjacent area
3) Chec for shock sensitive - Loop rope around top of drum stand at a distance give drum several hard jogs by pulling on the rope An alternative nethod is to lightly jog the drum with the backhoe bucket
4) If the drum is not upright place a catch basin under the bung
5) Open drum with bung wrench
6) Monitor the air atin bung
7) Sample drum -- liquids insert glass tube the fu l l length into the drum in order to obtain a column of the materials in the drum Solids use scoop to dig out material through the bung or use a sampling trowel
3) Reseal the dram
Spill Control
The possibility exists during the sampling and excavation for a
drum to be ruptured or otherwise have spillage Clean drums wil l be on
hand to receive significant spillage resulting frora sampling or excavashy
tion They will not be used for clean up of widespread uncontainerized
waste or existing leakage
Personnel
The work team will require four (4) persons (exclusive of the
backhoe opera tor) Trie downrange team will consist of three (3) persons
-- two (2) for d igg ing and sampl ing and on ( 1 ) for logging air moni shy
toring and photographing One (1) person will be at the hotline in
support mdash as safety backup person to fill air bottles to deconshy
taminate samoles to assist in decontamination of personnel
Documentation Logging
The following information will be recorded at each location
nmber of drums uncovered and the condition (crushed empty rusted
sealed etc) of each drum evidence of spillage or contaminated soil
labels on uncovered drums samples (time drum ID type description)
periodic air monitoring information depth at which specific events
occur or drums are buried soil condition presence of ground water
In addition photographs will be taken of specific events or
items of importance during each excavation and of each sampling incishy
dent The time description of subject photographer excavation
location and photo number will be logged for each photograph
Analytical Laboratories and Schedule
RAI Hampton NH
Initial schedule
Ten samples for GCrns for organic priority pollutants Samples may also be submitted for inorganic anlaysis or volatile organic analysis depending upon waste materials observed during the excavation
APPENDIX A
TABLE A-1 EXCAVATION LOCATIONS
EXCAVATION BASELINE RANDOM RANDOM
NUMBER GRID COORD SEGMENT STATIOH OFFSET
1 7E+1 565N 0- 60 26 (25) 16
2 9E+5 13S 60-120 50 (110) 9
3 8E+0 31S 120-180 20 (140) 7
4 4E+5 483 180-240 50 (230) 25
5 3E+3 45S 240-300 14 (254) 20
6 OE+6 5S 300-360 34 ( 334) 50
7 2W1 5 24N 360-420 45 (-155) 14
8 5W+6 42N 420-480 38 (518) 20
9 6W+1474N 480-540 8 (543) 7
10 8W 5 11011 540-600 11 (611) 31
Locations are plotted on Map A-1
Method of Choice A stratified random sampling method was used to choose 10 Excavation Locations within the magnetic anomaly
The axis of the magnetic anomaly was used as a base line and divided into ten 60 foot long segments Using a randora nirnbers table a distance along each secpent was chosen (Random Station) and a line drawn at that point perpendicular to the base line Again using a random numbers table a distance was located along each perpendicular line by measuring inward from the line denoting the edge of Area A (Random Offset) The Grid Coordinates for each of the Excavation Locations were graphically determined from the grid overlay (this overlay has been surveyed and intersections field located)
It was judged that 10 excavation locations within the magnetic zone and two outside of the zone would be sufficient to characterize the area would produce statistically valid iati and coli be expected to be co~letod within 2-3 days work period
to
80
cu0
cgtc
APPENDIX C
MAGNETIC INVESTIGATION TROY MILLS INC LANDFILL SITE
TROY NEW HAMPSHIRE
For
NORMANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
By
JOHN F KICK PhD GEOPHYSICIST
Box 6 Dunstable Massachusetts 01827
(617) 649-6650
Noverber 19S3
MAGNETIC INVESTIGATION
TROY MILLS INC LANDFILL SITE
TROY NEK HAMPSHIRE
INTRODUCTION
A high resolution ragnetic investigation was completed on the Troy
Mills Inc landfill site in Troy New Hampshire by John F Kick
Consulting Geophysicist The purpose of the investigation was to
delineate the extent of buried steel drums under closed portions of the
Troy Mills landfill The information is needed as a part of a study of
the landfill that is being conducted by Normandeau Associates Inc
FIELDKORK
Magnetometer measurements of total field intensity were made over an
area that was reported to contain buried steel drums and adjacent
landfilled areas that contained unknown waste materials The area of
investigation included capped and grassed closed areas along the south
margin of the landfill site and adjacent areas The fieldwork was
performed during October of 1983
Eighteen parallel rows of measurements were conducted along north-
south lines (using magnetic compass directions) A spacing of 20-feet
was used between rows and magnetometer measurements were made at 10-foot
intervals along the rows Greater intervals between measurements were
used at the ends of the rows and in periferal areas with low magnetic
-JF Kick 01shy
field gradients
A series of magnetic field measurements were made at an adjacent
base station throughout the survey to torn the basis for a daily
variation curve The base station was located at a site with typical low-
gradient background magnetic field intensity measurements
MAGNETIC SEARCH METHOD
Theory Magnetic search methods involve the detection and
measurement of anomalies in the Earths magnetic field caused by the
presence of materials with contrasting magnetic susceptibility Iron and
steel objects generally have very high magnetic susceptibility contrasts
with usual surrounding materials and therefore produce magnetic
anomalies The amplitude shape and detectable distance of the anomaly
depend mostly on the particular susceptibility contrast and size of the
object Magnetic anomalies are measured in units called gammas The
normal magnetic field in this area is over 50000 gammas A 5-inch
screwdriver will produce an anomaly of 5 to 10 gammas at a depth of 5
feet and an anomaly of 1 gamma at a depth of 10 feet A 1 ton automobile
will produce an anomaly of 40 gammas at a depth of 30 feet and an anomaly
of 1 gamma at a depth of 100 feet The magnitude of an anomaly caused by
a single steel drum will vary with its condition (new heavily rusted
etc) Tests using a single light weight (somewhat rusted) drum on the
surface with the magnetic detector at a height of of 12 feet produced an
anomaly in the range of 40 to 50 gammas
Total magnetic intensity disturbances or anomalies are almost always
asymmetrical sometimes appear complex even from simple sources and
usually exhibit the combined magnetic effects of several sources which
can produce a given anomaly The apparent complexity of such anomalies
is a result of several relatively simple functions of magnetic dipole
-JF Kick 02shy
behavior Reasonable assumptions about the geology and buried source
conbined with an understanding of magnetic dipole behavior can usually
lead to a satisfactory qualitative interpretation More detailed
interpretations nay require modeling studies
Instrumentation Field equipment on this project included a EGampG
Geometries Memory-Mag G-856 proton precession magnetmeter The
instrument has a resolution of +01 gamma The magnetic field detector
is separate from the rest of the instrument and is mounted on an 8-foot
staff to provide measurements that are a constant height above land
surface
Magnetic Data Analysis For the purposes of data reduction and
anomaly delineation it was assumed that base station total field
intensity measurements were typical background values for the site
Measurements made at frequent intervals at the base station were used to
prepare a diurnal variation curve for the site Anoraly values were
obtained by subtracting background values from the base station curve
from measurements collected in the area of investigation
RESULTS
The reduced results are presented in the form of a magnetic anomaly
contour map (Figure 1) and two profiles across the area of investigation
(Figures 2 and 3) The map and profiles show that very steep magnetic
field gradients and large departures form background occur in an
irregular shaped band that is about 460 feet long and ranges from about
30 to about 200 feet in width The magnitude of the anomaly is such that
a significant deposit of ferromagnetic materials (such as steel drums) is
indicated
In using the plotted magnetic results it should be noted that the
greatest concentrations of ferromagnetic materials probably do not
-JF Kick 03shy
directly underlie the peak magnetic anomalies A shift is caused by the
inclination of the Earths magnetic field and by the dipolar nature of
ferromagnetic deposits The inclination of the Earths field is about 76shy
degrees northward in the vicinity of Troy The dipolar effect is induced
by the Earths field and results in negative anomalies immediately north
of large positive anomalies
Magnetic Anomaly Map The magnetic anomaly map (Figure 1) indicates
10 positive peaks of varying size shape and intensity Associated
negative anomalies of a broader and less intense nature lie immediately
north of the belt of positive anomalies The configuration of the
anomalous area is indicative of lense-shaped and cigar-shaped bodies of
ferromagnetic materials Steep-sloped anomalies are indicative of very
shallow source materials The thickness of the ferromagnetic deposit
cannot be easily determined on the basis of intensity and size of
anomalous peaks because a small mass of iron or steel at the surface can
duplicate the anomaly caused by a much larger mass at depth The
ferromagnetic source materials can generally be expected to lie north of
the positive peak of anomalies and south of the adjacent negative
anomaly Modeling can provide the best approximations of the depth and
density of the ferromagnetic source materials The outer boundaries of
the source materials can be expected to overlap the positive peak and
negative anomaly somewhat depending on the depth and configuration of
the deposit
For illustration purposes two north-south rows that were profiled
are discussed below
Magnetic Anomaly Along Row 9-East Two strong positive magnetic
anomalies (3645 and 2436 gammas) and adjacent negative anomalies were
profiled along Row 9-East (Figure 2) The approximate centers of the
ferromagnetic deposits are believed to underlie stations 50 north and 75
feet south of the base line The rounded shape of the north positive
-JF Kick
anoraly nay indicate somewhat deeper burial of the ferromagnetic deposit
Magnetic Anomaly Alone Row 7-West Figure 3 shows the most intense
positive magnetic anomaly (4470 gammas) that was detected on this
project The steepeness of the slopes is indicative of very shallow
source materials An uneven burial pattern is suggested by the two-
peaked positive anoraly The negative anomaly south of the two peaks is
unusual and may be related to another positive anomaly to the southeast
(along Rows 5 and 6 20 feet north of the base line) The centers of the
sources of the positive anomalies are probably approximately 80 and 120
feet north of the base line along Row 7-West
-JF Kick 05shy
DISTANCE FROM BASE LINE(FEET)
CO
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APPENDIX D
LABORATORY ANALYSES
RAI
Resource Analysts Incorporated Box 4778 Hampton H 03842
(603) 92^7777
TO PO 830318
Mr Doug DeNatale Date Received 12-2-83 Kormandeau Associates 25 Nashua Road Lab Number 2887 Bedford NH 03102 J
Date Reported 1-3-84
IDENTIFICATION
SAMPLE DESIGNATION PARAMETER
Volatile Organics Analyses by EPA Method 624
Acid and BaseNeutral Extractable Compounds Analyzed by EPA Method 625
Metals Analyzed by Standard Methods 303A
Please see attachments for all results
Results expressed in mgL unless otherwise designated lt = Less Than
ClarkeFosterVan K o u w e i b r h 1 ANALYST DIRECTOR
METHODS Standard Methods (or the Examination ol Water and Waitewaler 15th Edition or other EPA approved mtlhodologiei unless otherwise designated
Phys ica l descr ip t ion of sample
LiquidSludop
Saiple workup
Volitile f ract ion Methannl F-1-rarMrm CSVJ Rdfi-Smm
Semivolatile f ra ictio0onication Extraction fSW 846-3540^ Inorganic f rac t on Acid Digestion (SW 84h-iOS(V)
ACS3 COMPOUNDS
rr t CAS CAS
(71 A) tt-Ot-2 i^t TT i^MoroprvrfgtOi (73B) 30-32-1
(23 A) J9-JO-7 ^bull^^ lof o^^ft^crt gto (7 OB) 205-M-2
(2 A) 13-37 -J 2- chlorophenol (75B) 207-01-
(3 A) 120-13-2 2raquo^icMoroorgtenol (748) 211-01-9
(MA) 103-47-9 2-dimethv lohenol (77 B) 201-94-1
(37A) U-73-3 2- niiroDhenol (7IB) 120-12-7
(MA) 100-02-7 raquo-niiroprienol (7raquoB) lraquol-2raquo-2
(raquoA) Jl-21-3 2 - in i tr opheno 1 (106) raquoi-73-7
(40 A) 33-J7-l k4-dinnro-2-mlaquothylplaquogtergtol (I IB) 15-01-1
(4A) I7-U-3 (xntictiloroorraquonol (I2B) J3-70-3
USA) 101-93-2 pxmol (I3B) 193-39-J
(14 B) 179-00-0 RASENEUTOAL COMPOUNDS
( I B ) 13-32- raquocmlaquophtgtgtefgtlaquo
(36) 92-173 benzidine (2V) 107-02-S
( I B ) I20-I2-I l2t-tricMorobenzlaquonlt (3V) 10713-1
OB) 111-71-1 he laquo laquoch 1 or o benz erve (laquoV) 71-A3-2
(176) 47-72-1 hetraquocWoroltthlaquone (4V) X-23-5
U S B ) 111-- bu(7-cloroetrivl)ether (7V) 101- 90-7
(7CB) 9 I -3J -7 2-Chlororuprthraquolene (10V) 107-04-2
(73B) 95-50-1 l2-diCMoroblaquonzene ( I 1 V ) 7|3j^
( K B ) XI-73-1 13-didilorobtnzene (13V) 7J-3-3
(27B) 104-M7 1tmdash djcMorobenzene dkV) 79-00-3
C2IS) 9i9i-l 33-dictgtloroblaquoazidinr ( I JV) laquo-3-J
(33B) 12I -U-7 2gt-dinicrotoluer (14V) 7J-00-3 (KB) 4O4-7C-7 24-dinitrotoluene (UV) 110-73-1 (J7B) 122-A4-7 1J -diprienv lhydrraquo z irf (23V) lt7 tt 3
(MB) Z0-fc-0 UuorraquonThelaquo (2raquoV) 7J-35-
(W551 700J77-3 -ctilorophenyl prlaquonyl ether (JOV) 1M-40-3
( raquo I 6 ) 10I-J3-3 raquo-6romoprgtefgtyl prtenyl ether (32V) 71-17-3
(raquo7B) 33132-9 bU (2-cMorobopropyl) ether (33V) 10041-02-4
(raquoJ6) i l l -91- l bu (2-laquo^loroeTho)ry) methane 10041-01-03
(B) D-U) hexraquopoundj1|orobutaltlicne (31 V) 100--
(33B) 77-raquo7- heiKCtilorocycIopentadicrve (WV) 7J-CT-2
OB) 7IJraquo-I traquoo oh or or (raquo3V) 7raquo-17-3
(J3B) gtl-20-3 nphthraquolene (UV) 7raquo-I3-9
(546) n-tj) nitrobenzene (7V) 7J-2J-7
(426) U-Xl-4 bullJ -n itr o tod iphenyU mi ne (UV) 75-27-J
(OR) 421-W-7 N-oitrcnodipropYlirrUne ^raquoraquoV) 73-49-k
(446) I 1 7 J I - 7 bu (2-eltr^lheryl) phtfaUte 8200 (3ov) 73-71-1
(476) 13-U7 benzyl buryl phttwlite (51V) 124-kt-l
( U B I M-71-2 di-fl-utgtl pMhUre (13V) 177-II-
( lraquo6) 117-1 -0 dj-n-octvl prithlaquoUte (UV) 101-IS-3
(7CB) W-44-2 dielhvlphtraquollaquo (17V) 79-OI-t
( 7 | B ) I 3 I - I I - J dj^laquorTvipnthraquoUtr (UV) 7J-OI- (776) H-J5-5 bnro(raquogtnthrraquocefvr
Iab I D N o 2SS-10
C l ien t ID 1A64223
RASENEUTRAL COMPOUNDS
bfzoltraquogtprrene
benzoltb)flucrraquornNene
benio(llaquo)fluorraquonthene
chryiene
bullcenaDhthvien
raquontnrraquoctne
benzoltghi)perrlefgte
Iluorene
phergtraquonthrmlaquo
dibenzoltraquoMaithrraquocenraquo
indeno(123-cd)pvrene
prrene
VOLATHES
(frolein
bullcrvlooitrdf
benien
orbon Temchloide
CMorobeniene
1 7-dJchlorolaquothnr
111-trieftloroethine
ll-ltJichloroetrufle ll7-triCilorigtetMrlaquor
l127-tetrraquocMorothfllaquo
chloroethlaquo-e
7-dMoroeThraquo|virgtvl eirwshy
chloroform
11-didMoro^tfwnr
trinj- 1 2-dictMorolaquoirgtene
1 7-ltlicMoroproplaquorve
trini- 1 3-ltJichloroorcrpeoe
cu-lJ-lieMorocT oo eashy
rthy Uveniene
methrlene chloridf
chloromethine
bromome thraquone
bro mod iCTi lore met Mrgt
(Juorotr ichloromthraquor
di cMlor od 1 f 1 uore ngtet hj^gt
chloreltJbnjmomethne
te tr ten 1 or oet rx-r
laquouene 12000
tncMeroethe^e
Cidrr ium Chromiutr 10
All results are expressed as ucg veicht as received Nc ertrv denotes -0r ~ ^ 1 i rt
P h y s i c a l d e s c r i p t i o n of
SoilSludge
sample
Sanple workup
Vol i t i le f ract ion p^r Exf- rar r ion fST7Semivola t i le f rac t ion So^h^Pt Fgtr f ra r f ion
846-SOTO^ (SWRdfi-^SiO1)
Inorganic fract ion Ar id nio-psrirm
AOD COMPOUNDS
m CAS (2i A) tt-04-2 2raquot- Wichlorophenol
(22 A) J1-50-7 p-cfi I or o-n-cre laquoo 1
(2A) 13-57-1 2- ctiloroprienol
O iA) 120-13-2 2raquo^icMoroprnol
(gtraquoA) 103-47-1 2f 4mdash^imetSv Ip^enol
(37 A) U-73-3 7mdash Ti j oprtenol
(JraquoA) 100-07-7 mdash mdasho i Br opr^e no 1
JJ1A) 31-21-3 if mdash4 irtiTroprienol
(40A) J34-32-1 4 T4-4initrogtmdash 7 nte tny Ipnenol
(4A) f y _H 5 plaquontchlaroorwnol
(43A) J 01-95-7 prienol
rV ipoundNEUTRAlaquo- COMPOUNDS
( I B ) raquoJ-32-raquo
(3B) 17-17-5
( IB) 170-12-1
(IB) 1I1-7I-I
(17B) 4777-1
( I t B ) 111--
(20B) 11-31-7
(236) 15-50-1
(245) 51-73-1
(77B) 104-4-7
(285) 11-14-1
(336) 121-142
(34B) 404-70-2
(J7B) 127-M7
O1B) 2O4--0
(406) 7003-72-3
(416) 101-35-3 lt raquo 2 6 gt 3H3I32-1 ltraquo36) 111-11-1 (57B) S7-U-3
(336) 77 -raquo7-
(36) 71-31-1
(33B) 11-20-3
pound34 6 1 n-i33 (UB) tt-30-4
(436) CI-44-7
(4461 117-11-7
(47B) U-417
( U B I 14-747
(U6) I17_t-0
(7CS) l-laquo2
(7 I B ) t J U t l - gt
(7761 54-55-3
CT-~- i_i w i Miirn 0
resul ts
b^TMdint
1 2 t-o- icn lorobenl ergtlaquo
SeTraquochloroblaquorierraquoe
hrxchlorolaquotSlaquone
bu(2-chloroethv|gtether
2 -lt3M or onraquo ph ti1 ene
1 2-ltJictilorotgtmzcne
13-dicWorotxerzene
1 4-djch 1 or otxn z ergte
33-ditfgtlorolgtlaquoniidirraquo
24-dinitrotoloene
2 4-dtnitro toluene
U-dlpoenylfiydrraquoiilaquo
(luoranthene
raquo-cfJorophenyl poenyl ether
Mx-omopfieflyl phenyl ether
bis (2-cMorooopropyt) ether
bu (2-ctilorcxtSorv) meiSkte
hezkOilorobutadicne
hei acM or ocyc1 ofMn udi cne
oo prior one
nphthlene
nurotxniene N -ni tro Kxd ipoenyU mi ne
N-rutrowxhpropYUmJrw
bu (2-thylherl)(gthlaquoiraquoUtraquo
blaquoniyl buryl phtfraquolaquoUte
dt-^t-^xjrvl pfttfuiLitY
dj-n-octyl pitflaquoLitraquo
dirthvl phtruUtt
OArriett^vt prraquoT^Lraquot
bnzoltklaquonihnicer
22 Chronium
ire ev^rescei as uc ^ ^i-~ht-
Lab 1U N o 28B-1
C l i en t I D 1 R R 7 A A R
RASpoundNEbTRAL COMPOUNDS
benroltb)fluorraquorgtthfflf
benzoraquollt)fluor intone
ltrylaquo-gte
bullcenioithylen
raquomtirraquoenlaquo
ben z oltxh i)per v lene
lloorene
poentnthrrne
dibnzo(4h)laquonthricrne
mdeno(I23-rt)pvre-ie
pyrene
VOLATU-Ei
bullcrelem
bullcrvlonio-Ue
benzene
caj-bon traquotrraquochloraquo-idr
Ctilorobernene
l2-diehlongtethne
iii-tnctltiorotKraquor Trace 1 T 1 -4)Ctilorampe^hArw
l f 1 ^-tric^i lor oefvtrve
l t l 22-teTrtclloroetl^Ane
ehloroethraquone
2-chloroltthr|viw| ttrve-
Chloroform
1 1 -ltSicMorot^nr
trinraquo-l2-dictiloroetrne
12-d^loropOStn
trinil3^ichloroproone
eis-lJ-diChloroprooene
rrhylberuene Tarce methrlene ehlor tat Trace
Ct1 or o m e t Kirgte
bromometKtrte
bro mod i rfi lor o rrgte t Mne
Uuorotrlchloromethraquo^e
OJ CJ lor od 1 f 1 uoro met hraquone
chJorodibromometKATgte
laquotrlaquociloroethrrx
toluene 9
tricolor otheir
fsw
T9
Sifi-TOSO)
(73B)
(7IB)
(75B)
(7(B)
(77 B)
(71 B)
(71B)
(SOB)
( t lB)
(I2B)
U3B)
(M B)
(7V)
(3V)
(4V)
(4V)
(7V)
(10V)
(11V)
(13V)
(14V)
(13V)
(14V)
(11V)
(23V)
(21V)
(30V)
(32V)
(33V)
(34V)
ltlaquoV)
( raquo J V )
(44 V)
f raquo 7 V )
(UV)
(V)
000 (30V)
Tlfl 151V)
(15V)
^00 (14V)
(17V)
(UVgt
-1 ZINT
CAS 30-32-J
205-11-7
207-01-1
211-01-1
201-14-1
120-12-7
111-24-2
14-73-7
13-01 -laquo
33-70-3
113-31-5
121-00-0
107-07-t
107-13-1
71-43-7
34-23-3
101-W-7
107-04-7
71-35-t
75-3-3
7^-00-5
71-34-5
75-00-3
110-73-1
(7-14-3
73-35-4
154-40-5
71-17-5
10041-07-6
10041-01-05
100-4I-
73-OT-2
74-17-3
74-13-1
73-25-2
75-27-4
73-41-4
75-71-1
174-41-1
127-U- IOUIS-) 71-01- 75-OI-
130
Lab ID Mo 2887-4
Phys i ca l d e s c r i p t i o n of sample C l i en t ID 4A5760
Liquid Sample was predominantlv a hvrlrnrarhnn bl pnd
Sanple workup Voli t i le f ract ion PEG Extraction (SW 846-5030) Scrnivola t ile f rac t ion Sonication Extraction (SW 846-3550) Inorganic f rac t ion Acid Digestion (SW 846-3050)
AC3D CS3U POUNDS 5AipoundNEUTlUgtJ- COMPOUNDS
ri CAS PPraquo CASf
(210 U-04-2 2raquot- tricMorophrnol (7)6) raquo-32-l braquoniolttVyre
[EM 51-50-7 ^-cti 1 or raquo-m-lt rlaquo laquoo 1 (7raquoB) 203-M-2 biMo(b)(luorinth^f
2 A) raquo5-57-J 2- cfiloropheryjl (7 3 B) 20701 benro(ilt) floor in tlaquo^e
(31 A) 120J3-2 2raquo-ltJicWoro(ygtlaquotx)l (74B) 2II-OI- chryve^e
(MA) 105-47- 2l-dimlaquothvloSrrgtol (77 B) 20Uraquot-J bullcwrioMhylene
(57A) u-73-3 2- ruTroohrgtol (TIB) 120-12-7 raquontnncergte
(34 A) 100-02-7 -oitrophenol (7gtB) lraquol-2raquo-2 benio(ghi)cgtrrylngtlaquo
(3Agt 51- 21-3 2 -4 initropherwl (SOB) tt-73-7 fluorme
(tOA) 53-37-l t-dinitro-2-mlaquothy lpNlaquoxil (II B) 15-01-4 pheAinthrrnlaquo
(A) I7-U-5 tgtentraquochlQroiywnol (I2B) 53-70-3 dibenplusmnoltraquoh)fcnthrraquocrne UJJ 101-55-2 rfwtwl (I3B) lraquo3-3raquo-3 indenol 1 23-cd)vrtie
(UB) I2raquo^X3-0 pyrer BASENEUTOAL COMPOUNDS
VOLATO-ES (161 I3-32- raquoclaquonraquophttgtngtf
(5B) 12-17 -J btniidir (2V) gt 07 -07-1 bullcrolem
(IB) 120-17-1 l^^iricfvleroboMux (3V) 107-13-1 bullcrvlonit Jlaquo (raquoBI IIS-7t| SeraquoChlorotgtlaquoterlaquo (raquoV) 7IJ3-7 benient
(I7S) 4772-1 heLCMorolaquothinc (tV) J-23-5 crtgton wtrraquocMoidf (UB) I11-U-I bll(2lttllorolaquot^w gtetNer (7V) 101-W-7 ltAtoroxniergtlaquo
(203) Jl-31-7 2 -etvl or onlaquo ph traquo I en e (IOV) 107-04-2 1 2-ltlicMorolaquoTKlaquone
(25B) raquo5-30-l 1 2-dichlorobenzene ( 1 1 V ) 71-JJ-t llI-trichlorolaquotNlaquoe (2 B) 31-73-1 l3-ltlichoroblaquonzenlaquo (13V) 7J-3A-) 1 1-6 1 cM or Of t (Mr
(77B) I04-M7 I -di CM oro ben z eoe ( I k V ) rraquo-oo-j l12-niichlorolaquotfvirraquolaquo
(2IB) raquol-raquo-l )J-dichlcroblaquorLiidinr (IJV) rgt-3laquo-3 J122-tetrraquochlcrolaquoTrie
(33B) 12I-Ilaquo 2 2-dinia-otoluer (UV) 73-00-3 Ctgtloroltthne U4B) laquoJ-70-7 2 t-dtnitrotoluene (1raquoV) HO-73-1 2-ltJilorocthv|vL-v| etrveshy
(J7B) 127-M7 14-dip^wnylhydraiine (23V) C7-U^-3 Ctilorofcrm
(JraquoBJ 2Ot-ugt-0 CJuarlLnthefe (2raquoV) 7J-33- 11 -ltlicMorcxil^nr
(mei TOCJ-77-3 -chJorophcnyl phenyl laquoKr (xgtvraquo lK-^0-3 tnjM-l^-diC^lofCKtl^nf
( M B I IOI-J5-3 -6romophnyl phenyl ether (32V) 7I-J7-3 12-dicMoroprosaA
(raquo2B) 3M3I32) bU (2-cMarobopropyU rtNer (3JV) ICXU 1-07-4 trraquoni- 1 3-ltjictgtloroBoor^f
(OB) t l l f l - 1 bi5 (2-cMoroetfxgtrv) meihtrw lOOt 1-01-03 cu-O-dichloroprose- (32B) D-U-3 hrxaetilorobutadierw (UV) 100-laquol-raquo rthylbenien 1^00
(33B) 77^7- he i kcMor ocyc 1 openudi crw (UV) 7J-OT-2 rrveThvlerw chlof idf
(36) 7I-gtraquo| oop^troo (raquoJV) 7raquoJ7-3 CtgtlorBmethne
(338) raquo|20-3 nraquopfitfillaquofx 1200 (wv) 7raquo-l3-raquo bromorrgtlaquothne
(34B) nraquo3) nitrobenzene (raquo7V) 73-23-2
(CBI U-Xl-4 N -fl i iro lod iphen yU mi nr (UV) 7J-27- bro mod i cti lor o mT bull- (OR) 42l^-7 N-^itrolaquoodipropylmlrlte (raquoraquoV) 73-traquo-laquo tl uor o tr i cfi lor o mlaquoT itr (UB) I I 7 J I - 7 bn (^thylheraquoy|) phttilaquoUtT 110000 (XIV) 75-71J QJ ct )or oltJ 1 f 1 uoro rrgtei ^bull gte U76) U-U7 blaquonzyl buryl pttTfKUie 12000 ( j i v ) m-i-i ctil or od ib ro mo met h xnf (UB) M-7i2 d i -n -bo TV 1 ft thlaquo U tlaquo (13V) 127-11- te trraquo cfl lor ot hlaquoTgtf (OBI 117-4J-0 dj -n -oc t y1 Jgth fflaquo U re 6 200 tuv) iom-3 tolucie ^70
(7CB) u-u- djrthyl phtJMlire (17V) 7raquo-OI-4 irictilarcraquo^lt-ir (715) 1 3 1 - 1 1 - 5 oVnrrhyl pMtfaUte (UV) 75-OI- v i M v l CMor idr
(T76I 5-55-3 blaquorgtzo( Unihrlaquocme Xylenes 1SOO
Cad- iurn 2 2 on Chromium - - Z I N C ^ ~ P r
Ai results arc expressed as ugc weight as received Xo entry denotes not detects
Lab ID No 2887-3 5A 57709 Phys ica l d e s c r i p t i o n of sample Cl ien t ID
LiquidSludge Liquid appeared to be a hvdrnc-Arhnn blonrl
Sample workup
Vol i t i l e f r ac t ion Methanol Extraction fSW 846-5030^ Semivolatile fract ion Sonicatlon Extraction fSW 84 f i_3550gt) Inorganic f rac t ion Acid nic-psr-inn fSW 846-30501
ACS3 COMPOUNDS BASENEUTRAL COMPOUNDS
f f t CAS CAS (2IA) tt-04-2 (738) JO-32-J DCftZ OTamp p V^^^ff
(22 A) 3laquo9-50-7 p-cttl or o-m-cre laquoo 1 (7VB) 205-99-2 p^^izot oil lyor 4-^ t ^ltf ^^
(2 A) raquo5-37-l 2- CJiloroprieno (75B) 207-01-9 blaquonioltllt)flultxtn^it
(31A) 120-13-2 2raquo-dictgtlcr8tgtrfX)l (74B) 211-01-9 Chryeolaquo
(3 A) 103-47-9 2 -d irrgtet hv Ipherto1 (77B) 201-94-1 laquocnphthyle^
(37 A) 11-73-5 2- rutrop^enol (7IB) 120-12-7 bull^thrjc c^
(MA) 100-02-7 -flitroprlaquorv3l (79B) 91-2-2 bcnroltKhi)pefraquoler
(79A) 31-21-3 2 -d in itr eoricno 1 (IOB) 14-73-7 tluoren
(40 A) 33-37-l 4-d in itr raquo-2 -met hy Iphtnol ( I IB) 13-01-1 poltrtAOthrvTgt^
(44 A) 17-14-3 plaquon1 CM or o^eno I (I2B) 33-70-3 dib^fi-o( 4(K)Aji thirl c c^f (43A) 101-93-7 prwnol (S3B) 193-39-3 indcnotlIJ-ctflsvfie
(SB) 129-00-0 pyrene ftASENEUTRAL COMPOUNDS
( I D )
(5B) 92-X7-3 b^zidrw (2V) 107-02-1 bullcrolrm
(IB) 120-17-1 1 2 fc-Tr ICJ caro blaquoni crw (3V) 107-13-1 bullcrvlonitrij
(93) 1IU7I1 Seraquochlcrotgttniegtlaquo (4V) 71J3-2 blaquonienlaquo inn (17B) 4777-1 hexat^lorcwthgine (4V) H-23-5 carbon ttTricllixidf
( I I B ) 111-wJ bll(2-lt3^1oroltt^w)ether (7V) 101-90-7 ciloroblaquonzene
(20B) 91-31-7 2-ctdo-ont she Ime (10V) 107-04-2 12-dieftloroerane (25B) 95-50-1 l2-dilorobenzene ( 1 1 V ) 71-35-4 11 1 -tricMorotn-laquo
(2ampSI 51-73-1 13-dicMo-obenxerw (13V) 73-3-3 1 1 -d i CM orcxt M-
(77 B) I04-H-7 1 -di ci 1 or o benI erw (UV) 79-00-3 llJ-WiChlorolaquoflaquonlaquo
(2J6) 91-90-1 SS-dKJilorotxniidinc (13V) rraquo-3laquo-3 l122-tetrlaquocftlorelaquoTrne
(35B) 12| |k-2 2fc-dintrotoluene (14V) 73-00-3 diloroeth^e
(gt4B1 404-20-2 24-diniTrotoluenlaquo (19V) 110-73-1 2-cMortxfthv|vL-raquo trlaquoshy
(37B) 122-447 12-diphenylhydriin (23V) 47-44-3 cMoroform
(J9B) 204-U-0 Ouormntherve (29V) 73-33-i ll-diCMorolaquot^nf
(fcOB) 7005-77-3 k-cMarophfy| prlaquonyl etScr (gtOV) 134-40-3 trraquonraquo- 1 2 -dicMoroc t Nenf
(raquo I6) 101-35) raquo-6romoprny| phenyl rther (32V) 71-17-3 12-diChloropostn
(raquo2B) JH3IO2-9 bU (2-ltplusmnlaronopropyl) rthrr (J3V) 10041-02-4 trni-l)-diirMoroxtgtOpnf
(OB) I I 1 - 9 I - I bu (Z-chloroethxjrv) metSampnlaquo 10041-01-05 CU-D-djcMoroproOf-W
(32B) 17 -U -3 hiraquocfilarobutraquodiergtlt (3JV) 100-4U rttyligtlaquonitrgtlaquo 5300 (33B) 77-raquo7-raquo hrxicftl or ocrclopei tidier (UV) 75-09-2 nxthylenf ctilor ifif
lt3B) 71-391 ao prior or (raquo3V) 7raquo-17-3 rtloromrtha^r
(356) 91-20-3 nlaquoprithienraquo Trace (44V) 7raquo1Jraquo bromltmlaquoth^
(MB) n-93) ft i vo b^nz c^^ (raquo7V) 73-23-2
(425) U-30-4 ^bullf i^OftOOL^ri^ny lArrunf (UV) 73-27- bro mod i cgt lor o i~ t gt
U3amp1 Ul-4-7 N i itr CrtoO ip ro py 1 laquo ml r (raquo9V) 73-49-k U uor o IT 1 et loront Mrgt (UB) II7-1I-7 bu (2-Ihythlaquoryl)prtfUtr 59J300 (30V) 73-71-1 dj ci kr olt11 f 1 uoro rrrt (Nrgtraquo
(47 B) L3-41-7 txniyl burvl phthlaquoUtr ( 3 1 V ) I2-1-1 ch1 or od i b ro mo mi IMP r
(UBI U-71- 0-A-fcurl BMMliw (13V) 127-ll-i rt tr t cM or of tNr
Uraquo6) 117-li-O di-n-oCTv| pnttlaquoUfr 6000 (UV) lOt-II-3 toluenf 5700 (7CB) U-447 djrthvl p^tfvilirt (17V) 79-01-4 WiCMoroth^e ( 7 J B I U l - l l - 3 d^M^vl prttgtraquoUW (UV) 73-01- vinv t cMor 10 (77 Bgt H-35-) brto(raquollaquonthncrTraquo Xylenes 19000
Caen 1U~ 1 Chromium =2 Z I N C
All results are expressed as up g weight as received No errrv ripn^t-plt
Lab 1Lgt No 2887-5
rhyr i r n l d e s c r i p t i o n o f sample C l i e n t in 6857710
LiquidSludge
Sample workup Vol i t i l e f r a c t i o n PEG Extraction (SW 846-5030) Semivolat i le fr action Sonication Extraction (SW 846-3550) Inorganic f rac t ionAcid Digestion (SW 846-3030)
AOD COMPOUNDS BAStNELTTRAL COMPOUNDS
rr i CASI CAS (21 A) tt-04-7 (736) 30-32-1 bntoltraquogtprrene
(23A) 3-9-50-7 p~lt1 or o-m-c rraquo1 (78) 205-99-2 ben to( Sgt )1 1 uor raquon I he-gtf
(7raquoA) 93-37J 2- etilorophenol (73B) 207-01-9 beriioltk)(luortntrgt^f
(3 IA) 170J3-2 2raquo-dicMoroprnol (7(B) 2II-OI-9 eifVMTie
(3 A) 03-(7-9 24-4mlaquoThvlDheno| (77B) 20l-9(-i bullceraoMhyler
(37 A) tt-73-5 2- rue-oorienol (718) 1 20- 2-7 laquoflthrraquocene
(3 A) IOO-02-7 ^Mtroprwnol (7fB) 191-24-2 beraquoMoltsrM)plaquovllaquox
(39 A) 3I-71-5 2-4 ini tr ophero1 (tOamp) K-7J-7 tluwtrie
((OA) 33-37l (-lt iMtro-2-methylphenol (tlB) D-01-J phenATithrene
(4A) I7-44-J pentichlorophenol (128) J3-70-3 dilwnioltraquoh)laquonthrraquoceif
(OA) IOI-95-2 prwnol U38) 193-39-3 indeno(123-cd)vcne
(MB) 129-00-0 pyrergtlaquo 6 ASENEUTILW- COMPOUNDS
VOLATH-tS ( I B ) 13-32-9 ftCYTNA pO IT H I raquolt
(38) 92-17- o^nzioinc (7V) 107-02-1 aero le in
( IB) 120-I2-I l2k-o-i(3iloroblaquontergtlaquo (3V) 107-13-1 laquocrvlono-U
OB) Jl l-7fc | he I raquocti 1 or o blaquonI enlaquo (V) 71-43-2 Oltf2 tO^
(17B) (772-I he uc^i 1 or of t h ne ((V) 34-23-3 CJU JOO Tt TTlCfllo^ iCpound
( I I S ) bu(2-rfilcroethv|)ether (7V) 10J-90-7 laquoWoroblaquonzeoe III-44-4
(KB) 9I-51-7 2ltfMoronlaquoohttvraquolwe (10V) 107^)4-2 1 t2^ojo^loroetfft^c (2JB) 95-50-I 1 2 -dichlorotgtlaquorlene (11V) 71-55-4 1 1 1 -trichloroeihtr (251 541-73-I 13-dchlorotxniene (13V) 73-J4-3 1 1 -dieMoreeraquohraquorlaquo
(77Bgt 04-lgt4-7 1 mdash djcMorobenlene (IkV) 79-OO-3 t12-tricriloroeflaquofgte (2gtB) raquolraquo-l 33-didMoroblaquonjidirlaquo (13V) 79-34-3 1122-tetrcnicroeir^ne (33B) 12 I I 4 -2 Z4-diniiroioluerlte (1(Vgt 73-00-3 e^loroetruuie (KB) (04-7C2 2 (-dinitro toluene (19V) 110-73-4 2ltJilorolaquotr(v|vLnraquolnhlaquo (175) 122-447 12-dipr-enylfiydrmiine (23V) (7-44-3 chloroform
(J1B) 704JJ-O Huor^thrr (29V) 73-33-4 lI-ltJicMoroltthcne
(OBgt 7003-77-3 -ctJoroprienvl phenyl ether (JOV) 134-40-3 irirraquo-12-dictila-olaquotrlaquone
( raquo I B ) IOJ 33-3 -6ogtmoprienyl phenyl ether (32V) 7I-I7-3 l7^lichlorepreoine (laquo2BI 3H3raquoO2raquo bit (2-chlororaquoopfT5pyO ether (3JV) 10041-02-4 trint-l3-ltJicnloroBlt-ooee (OB) 111-11-1 bis (2-cMcroetro(v) metSuvr 100(1-01-03 CU-lJ-itflloropOO-^
(376) t7-U-3 hraquoz raquoch1 or o bu tlaquodi ene (J1V) )00-1- erhylberuer 1400 (33B) 77 -gt7- hei tchl or ocyc1 open traquodi ene (raquoV) 73-09-2 methylene chloriCf OB) 7raquo-3raquo-l BO prior one (raquo3V) 74J7-J eMorametrutne (33B) raquol-raquo-3 naphtfalene 100 (UV) 74-13-9 bro rrvome t hrgt (3iB) n-raquo3-3 niireblaquor)iergte (raquo7V) 7J23-2 (CB) U-XH N -01 ITo tod 4gthenyU rru rr (UV) 75-27-4 bro mod i ch lor o rrx t f4Ugt ((36) 42IO4-7 N-nnroodipropYlraquomlrlaquo (raquolaquoV) 73-4t-4 JJuorotr lchloronvlaquoiMftlaquo (Uol U7-1I-7 ba (2-etrylNraquoYl) phtt^Ure 100000 (30V) 75-71 -raquo dj cftlcr od U 1 vraquooro rri NUT
(47 Bl 13-44-7 t^niyl butvl phthiUte 13000 (31V) 124-41-1 chlorodibromorrwt^r
lt U E gt ) U-71-2 d-ojjurvl phtf^Ure (13V) 127-11-4 tr trbullcti loro rirr
laquoraquo6gt 11704-0 dl-fl-OCTvl pfltMUM (UV) 10t-ll-3 toluene fiin (TtS) raquo-laquo djrthvl phttuliTr (17V) 79-01-4 tricolor oethenr lt 7 | o l 131 -11 -1 (UV) v i n v i chlcwidr dimrlKyl rrftlaquoUTraquo 75-OI-J
(T75I J4-35-J blaquoTMOlt^trrlaquocr^ gtylenes 1200
Cadr ium 3 Chromium 21 ZINC 150
All results are expressed as ugg weight as received y0 entry denotes not detect
Iah I D No 2887-2
Physical descr ip t ion of sample
Strained Soil
Sample workup
Voli t i le f rac t ion PFG Extraction (^W 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-3540) Inorganic fract ion Acid Digestion (SW 846-3050)
ACS) COMPOUNDS
rn CAS Tft CASf
(21 A) tt-04-2 (73B) 50-32-4
U2A) 71-50-7 P-ch 1 or o-m-cre laquoo 1 (7k 8) 205-11-2
(2 A) raquo3-37-l 2- chloroprraquoeno| (75B) 207-01-1
(3IA) 120-13-2 2raquo-4ichlorophenol (74B) 21UOI-1
(3 A) 103-47-1 24-dimethvlphenol (77 B) 201-14-1
(57A) U-75-3 2- njtroDhenol C7I5) 120-12-7
(MA) 100-02-7 a-flitrophenol (71B) |1l-2raquo-2
(51A) 51-21-5 2 -d in i tr o phetio 1 (SOB) K-73-7
(40 A) 53-57-l raquo 4-dinitro-2-methy lprnol (tlB) 15-01-1
(4 A) 17-14-3 plaquoitraquochloroorlaquonol (I2B) 53-70-3
(43A) IOt-13-2 prlaquonol (13B) m-31-3 (MB) 121-00-0
BJ KSENCLmLAL COMPOUNDS
(IB)
(3B) 12-17-3 bcnzidine (2V) 107-07-1
(IB) 120-17-1 1 2 k- tr i ch 1 oro benr ene (3V) 107-13-1
(IB) I1U7I-1 he it raquocM or o boiz ergte (raquoV) 7I-J3-7
(12B) 47-77-1 he traquoch 1 or oet hlaquo ne (4V) 54-23-3
(116) 111-- buC-cJiloroethv|gtether (7V) 101- W-7
(20B) 11-31-7 2 -ltft 1 or on ph ttvraquo 1 laquon e (10V1 107-04-2
(23B) 15-30-1 1 2 -dictilorobeni ene (11V) 71-55-4
(25) VI-73-1 1 3 -ltJ i ci 1 or o blaquoiz ene (13V) 73-3-3
(77 B) 104-M7 llaquo-dchloroblaquoMeoe (HV) n-00-3
(2IB) 11-lk-l 33-dicMorotxTLtidinr (15V) n-3raquo-3 (33B) 12I-U-2 2 ltgt -4 in i tr ot o luene (14V) 75-00-3
(MB) 464-20-2 2 4-d initrotoluene (11V) 1 10-7 3-1
(J7B) 122-447 1 2-diprieny Ihydrti ine (23V) 47-44-3
(316) 2O4-UO Ouorraquonthene (21V) 73-33Jshy
(WB) 7t)03-77-3 ^-cJJorophenyl prienyl ether (JXgtV) 154-40-3
(MB) 101-33-3 -6romopriefgtyl prienyl ether (32V) 71-J7-3
(raquo2B) 3431-32-1 bit (2-chloroboproprO ether (33V) 10041-07-4
(OB) I1U1I- I bu (2-ltMoroethorv) methane 10041-01-03
(52B) r-u-3 hexachlorobutadiene (J1V) 100-l-raquo
(33B) 77-47- he z raquoctlt lor ocycloqenud i crte (MV) 75-01-2
OB) 71-31-1 ao prior one (raquo3V) 7raquo-17-3
(33B) 11-20-3 nlaquopntrlaquollaquone (UV) 7raquo-13-1
(MB) n-13-3 nitrobenzene (raquo7V) 73-23-2
(UB) U-30-4 N-nnroiodiprienyUmine (UV) 75-27-k
(436) Ol-U-7 N-nitrModiproOYlmJne (raquo1V) 73-41-
(UB) 117-117 bu (2-laquothylheiry) phtrlaquolte 8800 (50V) 75-71-1
( 4 7 B ) L3-U7 blaquoniyl buryl phthaUte 30 (31V) 12I-H-1
(UB) U-7U-2 di-o-burvl phtrMUte U3V) I27-I1-
(416) II7-U-0 dj-n-oCTvl pritntUtr 1200 (raquo4V) IOUI1-3
17CB) U-44-2 djetiTi phrtultrt (raquo7V) 71-01-4
( 7 I B I 1 3 1 - 1 1 - 3 dimnfTraquo| prThraquoUtr (UV) 73-01-
(776) H-35-3 berMolta^thrCF^
Cl ien t ID 8 A - S 7 4 6 1
RASENEUTRAL COMPOUNDS
benzofbtfluor^tMe
benzodclfluorintoent
Ctiryiene
cenoithylene
raquonthrraquoctne
benzoltKhilpervlefgte
floor ene
prlaquofnnthrene
ltlibenplusmno(4h)knthricrnlaquo
inogtno(123-rt)pvrrne
pyrene
VCX-ATIIE5
bullcrolem
bullcrvlomn-U
benzene
carbon tetrtchloridf
chlorobenzene
1 2-oUchloroethAnf
lll-trichloroethlaquone
ll-dcfioroethrraquo
1 1 2-tricilorolaquothraquorw
1122-tetrichloroeTtvin
chloroethre
J-ctiloroethv|vinv| etrgte
chloroform
11 -denier oethene
trinraquo- 1 2 -4 cMor oe t hens
12-dcMoroprooine
^Lns~ I f 3-4ic^ lo^opf oo^^^
Cli-l 3-dicMoroprooe^e
rttiylbenzene
methylene cnlonfle
Ch 1 or o me t hane
bromome thane
Trace
bro mod i cMor 0 me t hane
(Juorotrlchlorome thane
chlorodibromometKinf
tetracnloroethervp
toluenetr icMoroel he-if
Trace
CacTiiun Chromium ZINC f
All resxil ts are exprp^spr i K-i
Phys ica l de sc r ip t ion of sample
Strained Soil
Sample workup Vol i t i le f ract ion PEG Extraction (SU 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-5340) Inorganic fract ion Acid Digestion CSV 846-3050)
ACE) C30laquo POUNDS
m CA5i CASraquo (2i A tt-C-2 (73B) JO- 52-1
(22 A) J1-JO-7 p-ch 1 or raquowTv-cre 101 (7raquoB) 203-raquoraquo2
(2 A) raquo)57-J 2- chlorophenol (73B) 20701-
(31 A) I25J3-2 2k-4icttlltroptlaquonol (7tB) 211-01-1
(3A) IO)-7-raquo 2-dimlaquothvlpNrnol (77 B) 20l-raquoi-
(37 A) u-rj-j 7- niTTOphenol (TIB) 120-11-7
(MA) 100-02-7 -rtropN-rraquol (7raquoB) lraquol-2-2
(JraquoA) JI-21-) 2-d initroprietys 1 (IOB) U-73-7
(MA) 53-37-l Udinnro-2-mlaquothylphenol (UB) I5-OI-J
(Agt I7-U-3 pentichlcropwnol (126) 33-70-3
laquo)Agt 10l-raquo)-2 phenol (I3B) IJ3-31-3
(MB) 12raquo-00-0 AASCVflCUTRAl COMPOUNDS
( I B ) I3-32- bullcnraquophtber
(56) raquo2-17) bnzidirlaquo (2Vgt 107-02-1
(IB) 120-12-1 l2btrilt7tlorotgteizegtlaquo (3V) 107-13-1
traquoB) IIraquo-7fc | heikcMeroblaquonzergte (V) 7l-3-2
( I 2 B ) 4772-1 he ueft 1 or olaquot hraquo rgte (tV) laquo-23-3
( i ts) III-- biraquo(2-cMoroethv Dethrr (7V) 101-W-7
(20Bgt 1I-3I-7 2-cMoroflaquophthlene (10V) 107-Ofc-2
(2)6) raquo5-50-l l2-dchlorotgtlaquonzefgte (11V) 71-33-4
(28) 3l-7)-| 1 3-didMoroblaquonrenlaquo (13V) 73-3-3
(27B) 10t--7 l-diclorolgtmzerlaquo (iV) rraquo-00)
(216) raquoI raquoltbull- 33-dichloroblaquoMidiflaquo (13V) 79-31-
(356gt 2I- l-2 21-dinitrotoloen (UV1 73-00-3
(UB) laquogt- 20-2 2 (-dinitroto luenlaquo (HV) 110-7J-J
(376) 122-W-7 14 -dipheny Ihydrzire (23V) lt7-M-3
(396) 2O--0 tJuoruMSene (2raquoV) 7J-35- (OB) 7003-77-3 -c^lvophenyl pNrnyl ethlaquor (30V) 1H-W-)
(MB) 101-33-3 bull-bromopriefiyl prienyl ether (32V) 7t-t7-3
ltraquo25) 3HJI-32-1 bU (2-cMoroaopropyl) rthrr (33V1 10ltX 1-02 -6
(06) l l t - t l - l bis (2-cftloroetSorv) metwne 100lt]-01-03
(32B) C7U-3 heraquoraquochlorobutidierx (31V) 1 00-41-
(3361 77-7-raquo hexiOilorocycloptfiudlerve (raquoV) 73-0raquo-2
(56) 71-51-1 no ph or one (raquo3V) 7raquo-17-3
(3)6) raquol-raquo-3 rwiphtfalme (UV) 7raquoJ3-raquo
1361
LUB)
H-133
14-30-4
nitrobenzene
^ ri i iy o too ipf^^ y LA r^i rtf ^ 7V) (UV)
73-23-2
73-27-
(436) t21--7 M^TI iff frfcO^ip ropy Ift mJf^ (gtraquoV) 73-4raquo-raquo (UB) I17J1-7 bu (2-rThyiruMcyDpMtvUtr 570 (jov) 73-71-1 ( U B ) U-41-7 blaquonzyl buryl phthlaquoLite (31V) l2k-raquo-l ( U B I U-7I-2 di-n-burvl pitftALtTe (raquo)V) 127-lt-fc
(OB) 117- -0 dJ-fraquo-oCTvl phlJ^Ute (UV) IOt-It-3
(7CB) 14 -W- 2 djelftvl phtfalitt (17V) Tt-01- ( 7 I B I 1 J I - I 1 - ) duTNnhylphttsraquoUw ltUV) 75-01-
(77BI X-))O lgtmrlaquoigtmhrraquoctf
Cadmium f iQ Chromium 15 ZINC
Tab ID No oo -
Cl ient ID 8A-A-64220
fcASENEUTTRAL COMPOUNDi
blaquofuo(raquo)pyrrtgte
bfizo(b)(loortAth^e
benzo(k)f|ulaquoin1herf
Ctiryiene
cenDraquoMrwlene
fcftT^rict^t
D^flZCT (fftl)pC^ V Itf^p
(luorene
phen^threne
diiwnztKthlanthricene
indlaquono( 1 23-lttf)pvrene
oyrene
VOCATtLES
bullcrolem
bullcrvlooitriJe
bervteoe
carbon WTTicMoridf
chlorobenze^e
12-djcMoroetfane
1 1 1 -tricolor ex tKraquon
1 1 -dicMarcx t hrlaquo
1 1 2-triChlorothraquorw
1 122 -laquotrraquocM or o-hraquorgt
cMoroettu^e
2-cMorlaquothv|vuy| rseshy
chlexeform
ll-dchloroctfgtn
tri^iraquo l 2laquoflic^ loTo^i rgtcnt
12-dicWoroproptrs
Winl-l3-dicMoropfooene
Cu-lJ-djChleroprooe^
rrtiylfrenzene
methylene ctiloride 0 64
cMorometHAne
bromomlaquothlaquone
bnsmoform
bro mod i eti lor e me t Nine
0 uor o tr 1 cMor e rrgtlaquo t Nnlaquo
dj di tor olaquol If 1 uoro mraquoi Nrraquo
chlorodibromonveiKme
re tr a en 1 or or fxrvr
toluene
D-ieWoroefwne
entry denotes not detect All results are expressed as ugg weight as received Xo
Lab 1) No 2887-8
Physical descr ipt ion of sample
Sf-rs inpH 9 n i l
Sample workup
Vol iCi le f ract ion PEG Extraction (SW 846-5030)
Scmivolat i le f ract ion Soxhlet Extraction (SW 846-3540) Inorganic fraction Acid Digestion (SW 846-3050)
ACD O3MPOUNDS
m CAS fPraquo CASf pi A) tt-Ot-2 Zraquot- tritilorophrgtol (73B) 30-32-1
ft M -3o-7 p-cMorraquo-m-crTraquool (7kB) 205-raquo-2
(2 A) raquoS-37-l 2- cMorop^erxgtl J73B) 207-OI-raquo
(31 A) 120-13-2 l^ictiloropix)l ^7tB) JII-01-
(3 A) |03-7-raquo 21^-dimeThvlphenol (77B) 20t-raquot-l
(J7A) tl-73-3 2- rutropwnol (71 B) 120-12-7
(MA) 100-02-7 -MO-opwnol lt7raquoB) lraquol-2-2
fJraquoA) 3I-2J-3 2-dinitrop^laquoTgtoI ((OB) U-7J7
(laquogtA) J34-37-1 lt-dinitrfr-2-methylpwrxgtl (I IB) I 3-0 1-1 (raquoAI 17-1 3 pcmacMcroptonol (S2B) J3-70-J UJA) IOI-raquo5-2 phenol (IJB) MJ-39-J
(tBgt 12raquo-00-0 RASEfZUTRAL COMPOUNDS
( IB) 13-32-f raquocertaprithene
(3B) J2-17-3 twnndinc (2V) 107J2-J (IB) 170-I2- lr2k-triOilorobenzerlaquo (3V) 107-13-1 (raquoB) I11-7I-I hei bulllt1 ore blaquont ergtlaquo (raquoV) 7l-3-2 (1B) 47-72-I he ucft 1 or oe t h n (tV) 3-23-3 (116) |II_wJ bu(2-ctiIarothvI)laquotNer (7V) 101-90-7
(20B) raquoI-JI7 2 -cW or orvraquo ph tf I ene (10V) I07-Ofc-2 (23B) J3-30-I l2-lt5ictiloroblaquonzeoe (11V) 71-3J- (245) 3I-7J-I 13-dic^lorotxenzenc (13V) 7J-3-3 (27B) 104-K-7 1 mdash diC^lorobtnrerve ( lraquoV) 7^-OO-5 (21 B) raquo|raquo| 33^icftlorobenzidifv (I3V) rgt-j-3 (33B) I 2 I - U - 2 2ltgt-dinin-o1olvraquorgte (UV1 75-00-3
(J4B) 404-JO-2 21-dinitrotoluerve (1raquoV) 110-73-1
(37B) I22-W7 1 2 -d ipheny Ihydra z ine (23V) C7-14-3
(318) 2O4-W-0 tJuortnihrne lt29V) 75-3J- (kOBt 700J-77-J ^-tfMoropheTgtyl p^enyl ether (30V) 1J4-W-3
( raquo I B ) IOI03-J raquo-6romopfgtenyl phenyl ether (32V) 7I-I7-J
(06) 3H3raquo-)2-raquo bU (2-tfilerobopropyO ether (3)V) 10041-02-i
(OB) lll|| bii (2-cMoroethoxv) methane 10041-01-03
(37B) PUt) hxzraquocMorobutadienlaquo (J1V) 100-raquol-raquo
(JJB) T7^7U heztctilarocrclotMnttdicrgte (V) 7gt-0raquo-2 OB) 7l-3raquo-l BO ph or one (raquo3V) 7raquo-17-J
(338) raquo|20-3 rlaquopritrilaquolene (UV) raquo-laquo-raquo
(3iBl n-raquo3) nitrobenzene (raquo7V) 75-23-2
(CB) li-X)-t N -n i tr o tod ipheny U mi nr (UV) 73-27-fc
(06) CI-U7 N^iitroiodipropYUmlr ^raquo1V) 73-H-fc (UB) 117JI-7 bu (2-ethYlNerrl)pM^Utr 12000 (JOV) 75-71-1 (47 B) L3-U7 llaquoniyl buryl pht^UTe 2 800 ( 3 I V ) 2laquo-raquo-I (UB) raquo-7i2 di-o-ourvl pritfwiUrr (I3V) 127-lt-i (196) 117-14 3 dj-n-ocryl pritfiiUrr (UV) IOUIS-3
(TCB) J4-W-2 djnhYl phtfalitt (17V) 7t-01-lt (716 ) 1 3 1 - 1 1 ) damnhYl pMtuUTT (UV) 73-01- (77 Bl 3 33-3 frlaquon z olt raquo klaquom h rraquo c prgte
Cadmium T^ Chromiurn T Z T N C 100
Client ID 8A-C64221
BASENEUTRAL COtPOUNOS
bnzo(t)pyrrrie
benzobXluoriflthei blaquorizoltVHluorraquontrraquone
chryiene
bullcenphthylene
tnthneene
benzoltRM)perylene
fluorene
prienlaquonthcTTgte ditgtmplusmnolt4hluithrraquoctnf
indenof 1 23-cd)pvrf ne
pyrer
VOUATILES
bullcrolein raquocrvlonnrile benzene cmrbort Tetrichloride
chlorobenieoe 1 2-oUchloroethirie
11 1 -tricolor oethne ll-dvchlorolaquollMr 1 1 2-w icMoroethAoe l122-tetrieMoroeihilaquonlaquo
chloroetKvne JltJilorothvlvmv| ethe chloroform
11-dicMoroethent
trani- 1 2 -dicti lorolt t hene
1 J^JictiloroproBfVf
trim- 1 3-4ietiloroproperie
Cil-IJ-dicMoropfoOerie
rrhyUxrmene
methylene criloride
chlorornethine
bromome thne
007
13
tluorotr l^VoromlaquotNraquorgtt
da ch lor od 1 1 1 ooro frvet hraquone
chlorodibromometlvinf
te trraquocnloroeT rrrr
tricMoroetSmr
All results are expressed as us2 weight as receixred No entrv denotes not detect i
Phys ica l descr ip t ion of sample
SoilCake
Sample workup
vol i t i le fract ion ^FP FvfrarfMnn (ltU Rif i mdash Smrn
Semivolatile fraction Soxhlet Extraction (SW 846-3540^ Inorganic fraction Acid Digestion (SW 846-1050)
AC23 COMPOUNDS
rrt CAS CAS
(21 A) 11-04-2 2raquo4- trieMorophenol (738) 50mdash 3-4
122 A) J1-30-7 p-ctil or raquo-nvltrlaquo laquoo 1 (7laquoB) 205-11-2
12 A) 13-37-4 2- etilorophenol (75B) 207-01-1
(31 A) 120-13-2 2raquo-diclorophlaquoTgtol (74B) 211-01-1
(34A) 103-471 24-dmlaquothylphrnol (77 B) 201-14-4
(57 A) U-73-3 2- rutrop^nol (7raquoB) 120-12-7
(54 A) 100 -02-7 bull i tro p^c 01 (71B) 111-24-2
(J9M 31213 Z o trt i tr o poc^oI (MB) U-73-7
(40 A) 334-32-1 T^Hjinitrfr2^rt^T ny tp^gt^noi ( t lB) 13^)1-4
(44A) 17-44-3 pcnttchlaroprwnol (S2B) 33-70-3ltOA) IOt-IJ-2 pTUfNOl (136) 113-31-3
ftASENtUTRAL COMPOUNDS (MB) 121-00-0
(IB)
(56) 12-473 Iwnndine (2V) 107-02-1(IB) I20-IJ-I 1 2 4-tr icJi lorobeniervr (3V) 107-13-1(IB) 11 1-711 hexkcMarobcnzeM (4V) 71-43-2(126) 47-72-1 hexch)eroeihlaquone (4V) 54-23-J( I I S ) 111-4- bu(2-eMorlaquothv|)laquothr (7V) 101-10-7
(208) 11-51-7 2-c^laronraquophtfgtlene (IOV) 107-04-2(23B) 1J-30-I 1 2-dichloroblaquonime (11V) 71-35-4(2651 341-73-1 gt3-ltiictitaroblaquonxcnc (13V) 73-54-3
(27 B) 104-47 l4-dicMorotKmrerlaquo (14V) 71-OO-3
(21 Bgt 11-14) 33-4ichlaroblaquon2idine (15V) 71-34-3
(338) 121-14-2 24-dinitrotoluene (14V1 73-OO-3(J4Bgt 4O4-20-2 24-dinitretoluenc (11V) 110-73-4(37B) 122-447 lraquo2-dip^nylhydrraquoxirlaquo (23V) 47-44-)(MB) ro--0 Uuaranthene (21V) 73-33-4(406) 7003-72-3 4-ltUorepfraquonyl phenvl rtSer (30V) IH-40-J( raquo I 6 ) 101-333 4-6romoprlaquonyl pflaquony| ether (32V) 71-17-3
(OB) 3H3I-J21 bll (2-cti|orobopfrgtpyO ether (33V) 10041-02-4
(OB) I11-1I-I bis (2-cMaroethoxv) methane 10041-0103
(57B) P-44-) hczw^lorobundiene (J4V) 100-41-4
(JJ6I 77-47-4 htTicMarocyclojxrtadien (44 V) 75-01-2
(346) 71-31-1 aophoroo ( raquo ) V ) 74-47-3
(33B) raquo|203 r^pn thA Icr^ (44V) 7 -raquobull J-
(546) n-i3) H i frovCftZfl^^ (raquo7V) 73-23-2
142B) 14-30-4 S -n i tr o laquood ipheny Lt mi nc (44V) 73-27-4
(43 B) 421-447 N^iitrotodtpropyUmlne (41V) 73-41-4(MB) 117-41-7 bu (2-raquoThylhlaquolaquoyl)pMtgtlaquoUtr 52000 (30V) 73-71-4(4B ) 13-447 (xniyl bviryl ptithiUre 6700 (3 lV) 12raquo-l-l(UB) 147U- di-n-burvl pMhUre (I3V) 127-11-4laquoampgt 117-4J-0 ltjj-n-octyl phtfaUtr (UV) 101-11-)
(7CB) U-44-2 djrthyl pht)raquolraquort ( I7V) 71-01-4( 7 I B I 131-11 ) dimrthyl phttgtUTe (UV) 73-01-
(T76) H-33O tgtnzoUtlaquoftthncmr
Cadmium l i r^ Chromiurn 2 0 ZINC 140
All results are expressed as ugg weight as received
Lab ID No 2887-6
Cl ien t I D 8AD64219
Dd20( amp py(re
blaquonio(bHluorraquoflthegtlaquo
berzo(Mf luorampnThene
chryraquoefgte
ftctnAoMhy(ergte
raquonthncene
benioltK(M)plaquovlene
(Juorene
picnintfirtTX
dihwvioltraquoh)laquonThrraquocene
mdeno(l23-rt)pvrraquone
pyrene
raquocrolein
raquocrvloourUf
benzene
carbon laquoTrraquochlofifle
chlorobenieo
l24JcMarolaquotlxine
lll-trichlcroltthlaquorlaquo
-ltJicMorigtnKraquorgtlaquo
l12-trichlorolaquot^nlt
1 1 22-tetrcftloroetrvtnlaquo
^tloroeThAne
2^^1orolaquothvlvuiivt ethe
etila-oform
ll^liailoroltN^
trtni-12-dichlcxolaquoTfgtene
12-ditfiloropropine
trtni-l3-ltjicti|orocltX)t^f
cu-l3-djcMoroprooe^f
rttiylbtnztTve
methvlene cWoride
ciloromnM^f
Dco^^oroct^A^^
bromofarm
bromodicJiloromltlfraquon
tluorotrlctiloromttNir
diOilorodKloororfvrir^Ar
ct^lorodraquobrofTorrgttKAne
wtricnlorampctNrr
toluene
trirfilorolaquoThfif
v i n v CMor ilt3^
No-entry denotes not detect
ih i n N O 2887-9
Phys ica l d-asc r ip t ion of sample Cl ient ID 10A64222
Linnir l ShtHcp
Sample workup Volitile f rac t ion PEG Extraction (SW 846-^030^ Semivolatile fract ion Sonication Extraction (SW 846-3-540 Inorganic f ract ion Acid Digestion (SW 846-3050)
AOD COM POUNDS BAStNELTTRAL CXLPCXJNDS
rrt CAS CAS
(21 AJ U-Ot-7 Z4- trichloropSeno (73B) 30-J2-
(22 A) 55-30-7 p-ctilarraquo-m-erelaquoo1 (7kB) 205-raquoraquo-2 ben r olt b) 1 uor ifl t Ne~gtf
(2AJ raquo3-37-i 2- ctilorophenol (75B) 207-0raquoraquo benzoltllt)floofraquontslaquor
(31A) 120-13-2 2raquo-ltJictilcroooenol (76) 211-01 9 ctiryjene
(3A) I03-47- 2k-dimethylphenol (77 B) 20t-raquo4-i bullceruphthv lerraquoe
(37A) U-73-3 Zmdash Ajtropheooi (7SB) 120-12-7 fcntftricene
(34 A) 100-02-7 w^ i ff o phe rgto 1 (7raquoB) Iraquol-2-2 ben z o( Rh i )per v 1 me
(31A1 51-21-3 Z^ - d iA iV opheno1 (SOB) U-7J-7 Iluorene
(MA) 3X-37-I T v-4iAiv omdash laquo mdash fl^et ny Ipoenoi (I1B) 13-01-1 poeftraquonthrene
(4 Al 17-14-5 p^ntBCfllGrOprlC 1 Vol |I2B) 33-70-3 dilgtenioltraquoh)laquontwraquocenr
USA) IOl-raquo5-2 phenol (13fi) U3-31-3 indeno(l73-cd)oraquorrie
(MB) I2raquo-OO-0 pyrene RASENCimiAL COMPOUNDS
VCH-ATUL5 ( I B ) 13-32- raquoclaquonraquophtflaquorgte
(58) 12-I7-J benzidire (2V) 107-02-1 bullcrolem
(IB) 120-J7-I 1 2k-tr icnlorobenzene (3V) 107-13-1 acrvlonitr UP
(IB) 11U7I-I heKicMorobtnzme (raquoV) 7I-A3-2 benzene
(176) 4772-1 hexcftla-oethtgte (4V) J4-23-5 campr~toon TeTrscftlo itit
(116) III-- bii(2-lttilorolaquothv iVether (7V) lOt-W-7 chlocobenieo
(2C5gt raquol-3l-7 2-cM oroolaquo ptittu lene (10V) I07-O4-2 1 2-dicrtloreetranr
(23B) raquo5-30-l 12-dichlarobenime ( 1 I V ) 71-33-4 11 1 -tricMoroethr
(24 B) 31-73-1 1 3-ltl icJgt lor obcn i ene (13V) 73-3^-3 1 1 -dicMoroeth^i
(27B) 104-^4-7 1 4-dich lorobenzergte ( t k V ) n-00-3 11 2-tncfiloroetvlaquorie
(215) 91901 33-didMoroblaquozidinr (I3V) rraquo-3k-3 l122-tetrraquoOMo-oethne
(335) 121-I-2 2-dinitrotoluergte (ItV) 73JW-3 chloroethjin
(3461 (0420-2 24-dinitrotoluene (19V) 110-73-1 2-cMoroethraquo|vuiv| trgteshy
(37 B1 122-44-7 12-diphenylhydrnine (23V) 47-44-3 ctiloroform
(316) 204- Jgt tluarmrnhene lt2V) 73-35-4 1 1 -^iCMoroeThe^f
(C6) 7003-77-3 -chlorophenyl poenyl ether (gtOV) 154-40-5 trraquonraquo-l2-dicrloroltthene
(bull16) 101-35-3 raquo-6romophenyl phenyl ether (32V) 7I-I7-3 l2^ipoundMoroproBirgte
(raquo26) 3H3I-32- bit (2-cMarobopropvt) ether (33V) 1 004 1-02 -4 trmni-l^-dictilwoproom
(OB) l l l - raquo l - l bis (2-cMeroethoxv) methane 1004 1-0 1-05 cu-13-laquoicMoroprooe^e
(J2BI D-U-3 rraquolaquoeftlorobutraquodilaquooe (JJV) IOOJM- rttylbenzene
(336) 77 -raquo7- hezactilarocyclooentadiene (WV) 75-OT-2 methylene cniorifle
(56) 7raquo-3raquo-l ao ph or one (raquo5V) 7raquoJ7-3 eMoromeirune
(33B) JI-20-3 nraquophtMlene (UV) 7raquoJ3-raquo bromomethAftf
1X6) n-raquov) nitrobtnxerw (raquo7V) 7J-25-2
(CB1 14-30-4 J -ltii TT o vxJ ipheny U rru rraquo ^UV) 75-27- bro mod i cfilor o me t r)e
(CB) 47I-U-7 N-nnrotodipropylraquomJne (tV) 75-4raquo- 11 uor o tr i cMor o me t htgte (US) V17-1I-7 bu (2-eifrrlhryl)praquogtttilaquoUMshy 69 000 (30V) 75-71-1 di cti tor odl1 1 van m^i rajgtr
(476) U-U-7 benzyl buryl phihiUte 890 (31V) 12laquo-kraquo-l cMorodbremof^etNrr (US) U-7I-2 di-n-burvl prittuUre (13V) 127-lt- Uraquo6gt 117-t-0 dJ-laquo-ocTvl phttviUre (UV) IOLtS-3 Wluenr
(75) u-w djrrhylphtnltt ( i rv) 71-01-4
(715) t J I - l l - 3 dimnhrl pfthUte (UVI 73-01- viny l CMcriOr
(779) J4-35-3 0laquoMo(UnthrraquoCflaquoe
C a d m i u m 130 Chromium 20 ZINC 170
o nnn Z-UUU
^0(^ Trace
All results are expressed as ugg weight as received No en
APPENDIX E
PLATES
I I I I I I I I I i Plate 10-1 Troy Mills Landfill with a backhoe excavation
in progress in a former drum burial area
I I I
I I I I I I I I
I I Plate 20-1 NAI field investigation team preparing for
Level B activities during the drum excavation task Troy Mills Landfill
I I I
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
I I I I I I I I
I I Plate 20-3 NAI field investigation team member undergoing
personal decontamination at the hot line Troy Mills Landfill
I 1 I
I I I I I I
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
1
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
I
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
I I I
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
I I I I I I I I I I I 1 I Plate 53-3 Pigmentsludge deposits interbedded with
soil layers in Excavation 8A Troy Mills
I Landfill
1
ABBREVIATIONS AND SYMBOLS
EBP benzyl butyl phthalate degC degrees Celsius Ca circa D volume occupied by one drum DEHP di (2-ethylhexyl) phthalate DOP di-n-octyl phthalate E east eg exempli gratia (for example) EPA US Environmental Protection Agency HNU HNU Systems Inc photo-ionization detector LEL lower explosive limit LPP level of personnel protection MCL maximum contaminant level mg1 milligrams per liter ug1 micrograms per liter MSA Mine Safety Appliances Inc N north also number of steel drums NAI Normandeau Associates Inc OS over sample OVA Foxboro Century Organic Vapor Analyzer P estimated packing density of drums PPM parts per million RAI Resource Analysts Inc RCRA Resource Conservation and Recovery Act S south SCBA Self contained breathing apparatus SNARL EPA suggested no adverse response level T trace Troy Troy Mills Inc TVO total volatile organics V estimated volume of drum burial area VOC volatile organic compounds W west gt greater than lt less than
PLATES
Plate 10-1 Troy Mills Landfill with a backhoe excavation in progress in a former drum burial area
Plate 20-1 NAI field investigation team preparing for Level B activities during the drum excavation task Troy Mills Landfill
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
Plate 20-3 NAI field investigation team member undergoing personal decontamination at the hot line Troy Mills Landfill
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
Plate 53-3 Pigmentsludge deposits interbedded with soil layers in Excavation 8A Troy Mills Landfill
VI
10 INTRODUCTION
As a part of a phased program to investigate potential ground
and surface water contamination associated with the Troy Mills Inc
landfill Normandeau Associates Inc (NAI) has completed a waste
characterization at portions of the landfill that were formerly used for
the disposal of steel drums containing wastes (See Plate 10-1 for site
overview) The objectives of this phase of study included
1 Delineation of the horizontal extent of the drum burial area
2 Estimate ofthe number of drums
3 Characterization of the physical condition of the drums
4 Assessment of the contents of the drums and
5 Assessment of potential for ground water contamination
6 Development of a remedial action plan for the site
The work involved developing and implementing an extensive
site safety program conducting a magnetometer survey digging a series
of test pits on randomly selected sites laboratory analyses of selected
samples of soil and waste and formulation of a remedial action plan for
the site
The Troy Mills landfill is roughly eight acres in total area
and divided into two main sections One section is currently being
operated as a solid waste (non-hazardous) disposal area for fabric
scraps and trimmings as well as other non-hazardous materials such as
wood and broken tools The solid waste landfill covers about six acres
of the site An estimated three acres presently contain deposits of
solid waste and about three acres are being prepared for future
disposal A closed former steel drum burial area is the second section
occupying about two acres of the site The drum burial area is now
covered with soil and a light cover crop of grasses The drum burial
area received wastes between 1968 and 1978 The disposed drums are
reported to have contained various materials including waste
plasticisers pigments and organic solvents
Previous site investigations by NAI have included site
reconnaissance studies test pitting water quality analyses (NAI report
of August 12 1981) geophysical (seismic refraction and electrical
resistivity) investigations (NAI report of December 1981) installation
of a ground water monitoring system (4 wells) and sampling and analyses
of ground and surface water samples (NAI report of July 1982) A water
budget analysis was performed to assess the leachate generation
potential of the site (NAI report of September 1982) Concurrent with
the study of the drum burial area additional seismic refraction lines
were conducted and three additional ground water monitoring wells were
installed to further assess leachates from the solid waste
(non-hazardous) portion of the site
Laboratory Analyses were conducted by Resource Analysts Inc
(RAI) We also wish to acknowledge the assistance and cooperation
provided by the management and personnel of Troy Mills especially
Messrs Barrett Ripley and Carl Patten
20 SAFETY PLAN
A Bureau of Hazardous Waste approved safety plan for on-site
activities was developed for the waste characterization phase of work
because of the potential for encountering hazardous materials The
safety plan is presented in Appendix A of this report It assesses the
overall degree of hazard identifies specific potential hazardous
situations and presents guidelines for personnel protection and action
levels as required The plan was made available to all field personnel
during the field work
The magnetic and topographic surveys were considered to be low
hazard activities with a prescribed level of personnel protection (LPP)
of C or D depending on the results of air monitoring Level C proshy
tection involves wearing a full face respirator with organic vapor dust
combo cartridge Tyvek suit over work clothes rubber safety boots and
gloves Level D protection requires cotton coveralls or other work
clothes safety shoes safety glasses and possibly a Tyvek suit
During the drum excavation and sampling task which was
determined to be moderately hazardous Level B protection was preshy
scribed Level B protection requires that personnel wear SCBA (self
contained breathing apparatus) chemical resistance Tyvek suit steel-
toed rubber boots and gloves Plate 20-1 shows NAI personnel on the
site preparing for Level B activities Plates 20-2 and 20-3 show
personnel decontamination equipment and the hot line during the drum
excavation task
30 MAGNETIC SURVEY
To delineate the landfill area underlain by steel drums a
high resolution magnetic investigation was conducted by John F Kick
PhD consulting geophysicist The magnetic method was chosen over
other search methods because ferromagnetic substances (drums) were the
target objects and the majority of Troy Mills other wastes are
non-magnetic (largely fabric scraps) Dr Kicks report is presented in
Appendix C
Eighteen parallel rows of magnetic field measurements were
made along north-south lines The measurements were made at 10-foot
intervals along the rows This work resulted in a detailed contour plot
of the magnetic anomaly (Figure 1 in Appendix C) The source materials
which cause the magnetic anomalies do not usually directly underlie the
peak of the anomaly A shift is caused by the inclination of the
earths magnetic field and by dipolar effects Figure 30-1 shows NAls
delineation of probable source areas for the magnetic anomaly and
peripheral areas which may contain some magnetic source material The
plotted source area is generally the area between the peak of the
magnetic anomaly northward to the zero anomaly contour This is to
compensate for a southward shift of the peak of the magnetic anomaly
from the center of the source deposit The complex geometry of the
anomaly necessitated much interpolation between peaks and ridges
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40 TEST PIT EXCAVATION
41 WORK PLAN
A series of test pits were excavated in the Troy landfill for
observation and sampling More specifically the purpose of the
excavation was to estimate the number and distribution of drums buried
in the landfill determine the condition of the drums (full empty
crushed rusted leaking etc) identify types of buried and drummed
waste and verify the results of the magnetometer survey A stratified
random sampling method was used to choose 10 locations within the
delineated area of magnetic source material This insured that
excavations were distributed randomly across the landfill and that the
resulting data could be evaluated with a level of statistical
reliability Excavations were also selected in areas on either side of
the anomaly which were considered free of buried magnetic material and
also where drums were visible at the landfill surface
The following procedure was used in choosing the locations for
the random excavations The center of the delineated area of magnetic
source material was used as a base line The base line was drawn onto a
map of the source material (Figure 30-1) and then divided into ten
60-foot long segments Using a random numbers table a point-distance
was located on each segment (designated the random station) and a
line drawn at that point perpendicular to the base line segment Again
using a random numbers table a point-distance (designated the random
offset) measured along the perpendicular line located the point of
excavation The grid coordinates for each excavation were graphically
determined from the grid overlay and then field-located from the
surveyed grid intersections Grid coordinates and selection data are
presented in Table 41-1
It was judged that 10 excavations in the delineated area of
magnetic source material and two excavations out of the area would be
sufficient to characterize the site would produce statistically valid
TABLE 41-1 RANDOMLY SELECTED EXCAVATION SITES TROY MILLS LANDFILL TROY NEW HAMPSHIRE
BASELINE RANDOM RANDOM EXCAVATION GRID SEGMENT STATION OFFSET
NUMBER COORDINATE (FEET) fFEET) (FEET)
1 7E+15 65N 0-60 26 16
2 9E+5 13S 60-120 110 9
3 8E+0 31S 120-180 140 7
4 4E+5 48S 180-240 230 26
5 3E+8 45S 240-300 254 20
6 OE+8 45S 300-360 394 50
7 2W+15 24N 360-420 465 14
8 5W+6 42N 420-480 518 20
9 6V+14 74N 480-540 548 7
10 8W+5110N 540-600 611 31
Locations are plotted on Map in Figure 30-1
data and could be expected to be completed within a scheduled 2-3 day
work period
42 FIELD WORK
Test pit excavation was conducted in two phases On the first
day each of the 10 random locations (Excavation 1 through 10 Figure
30-1) was probed to a depth of 2 feet using hand shovels On the
second and third days excavation was conducted using a combination of
hand shovelling and power backhoe The NAI field investigation team
consisted of six members Four of the team members were equipped to
work at Level B for work in and near the actual test pit excavation
(See Plate 42-1) The other two team members spent much of their time
with personnel and equipment decontamination and refilling compressed
air bottles at the hot line Mr Timothy W Drew an engineer of the
New Hampshire Bureau of Hazardous Waste Management was present during
most probing and excavation work Mr Robert Lynch an experienced
Level B equipment operator of Jet-Line Services Inc operated a power
backhoe which was provided by Troy Mills Inc
An average excavation size using the backhoe was approximately
7-feet wide and 10-feet long Excavation continued downward until drums
were encountered or to a minimum depth of five feet Drums were careshy
fully uncovered and fully described A total of 17 samples were
obtained from uncontainerized wastes (solids dried sludges pigments
stained soil) and where possible from drums using EPA sampling methods
and protocols All of the excavations were backfilled upon completion
of this task
Each sample consisted of one filled 8-ounce glass jar sealed
with a Teflon-lined lid Samples were submitted to Resource Analysts
Inc (RAI) Laboratory in Hampton Falls NH for priority pollutant
analysis
Air monitoring was conducted during each excavation using a
Foxboro Century Flame lonization Organic Vapor Analyzer (OVA) an HNU
Systems photo-ionization detector (HNU) and an MSA combined oxygen and
explosimeter High explosimeter measurements were considered cause for
an immediate halt in exploratory work in the interest of personnel
safety
10
50 RESULTS
51 GENERAL
On November 17 1983 Excavations 1 through 10 were initiated
using hand shovels to a depth of approximately two feet A total of
two buried drums were discovered Excavation 13 was completed and a
third partially buried drum uncovered On November 21 1983
Excavations 1 through 9 were completed and on November 23 1983
Excavations 7A 8A 10 11 12 and 14 were completed An additional
42 drums were uncovered on the last two days of excavation
Excavation Locations Seventeen test pit excavations were
completed at locations which are shown on Figure 30-1 Two pits were
excavated at three of the locations Noteworthy aspects of the
excavation operation are
Excavations 1 through 10 were randomly located in the area of delineated magnetic source material (on-anomaly)
One excavation connected Excavations 4 and 5 This was done because of the proximity of Excavations 4 and 5
Excavation 7A was located immediately adjacent to Excavation 7 Excavation 7 was located on the boundary line of the anomaly and proceeded in a southerly direction off the area of delineated magnetic source material (off-anomaly) Excavation 7A was initiated in the opposite direction (north on-anomaly)
Excavation 8A was initiated one foot north of Excavation 8 after the latter was abandoned due to the detection of a potentially explosive drum
Excavations 11 and 12 were selected off-anomaly to the north and south (respectively) in areas considered to be free of buried magnetic material (drums)
Excavation 13 involved minor hand shovelling necessary to uncover a partially buried drum located on the periphery of the anomaly at the east end of the landfill
11
Excavation 14 was a surface scrape which extended from an exposed drum found to the south of the magnetic anomaly northward toward the anomaly
The details of each excavation are presented in Table 52-1
Drum Locations The excavation results support the
interpretation of the magnetometer survey with buried drums as the
source of the magnetic anomaly With the exception of a few strands of
wire found in Excavation 1 ferromagnetic materials other than drums
were not encountered during the test pit excavations
Drums were foundin 9 of the 10 excavations located in the
area of delineated magnetic source material (See Plate 51-1) No drums
were found in Excavations 11 and 12 located out of the area of
delineated magnetic source materials The location point for Excavation
7 was on the boundary of the anomaly Excavation 7 which proceeded
south away from the area of source materials was free of drums
Excavation 7A proceeding north toward the area of magnetic source
materials uncovered 6 drums Excavation 14 located just out of the
delineated area to the south produced unexpected results Five drums
were uncovered just under the surface in an area with low positive to
slightly negative total magnetic field values It is possible that
Excavation 14 was improperly located in the field If adjusted just 20
feet to the east it would be well into the delineated area It is also
possible that a negative dipole derived from the mass of material to the
southeast is cancelling positive readings at this location
Fill Material and Vegetation Cover and fill material was
predominantly fine to medium sand with an occasional boulder Till with
a siltclay component was also used as a cover particularly at
Excavations 6 and 7A This material was densely compacted and difficult
to dig through Excavations 7 11 and 12 each extending to a minimum
depth of 5 feet were characterized by uniform silt and fine to medium
sand and traces of dark discoloration Excavation 12 was located in
to a s
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mdash C bullmdash U SI bull-gtCOES 03gtO0
E 3 t-
bullD
^ ltshy
CO 0
Imdashmdash
-gt COmdash
1--30Z 4Jr e r e shyw E JJ
in O jj 01 o i-
i- agt n c i shy -mdash O gt E lA
O 0 (13 AJ O O X C es uJ o N
mdash mdash JT Ol t-
J J C I - C D laquo re O shyu
bull3 lt 0 3 N
bullmdash V c t C3 mdash a C S bull U r o
CO shygt bullA ^ mdash bull o
o - C Z
X =mdash Z O
mdash C 3 r e O -Z Z pound bullmdash re-JOlaquo C r e X
C c c gt r eC O r e J raquoZ o u r e X
mdash in X mdashl -CS-U fOCO
CJ EE lt- ~~ O
C T3 shy lt 0 t i re^ltmdash raquotrade-^t
mdash 3 O - C i C 3 mdashbull
^ v a c E gt = E mdash _gt re C J pound o y 5 O
rez O C3 - C
bdquo
O (T shyg shy =c _) 2 shyo mdash o
Q3 ^D 1- mdash C bullmdash mdash shy3 t = s ~amp lt Z ^ C N
c o r e mdash mdash c bull mdash o mdash bull _ mdash X 3 C c
mdash C T D O lt C o c o mdash gt mdash laquoomdash
JJpound J c
o
xo obullo w c-i-C C i-re o re O CO shy3 0 J
XbullOCcoW
t- 0) shygt bull tfl bull = B E 3 laquo Obull
3 mdashraquo O W i- o re c re a bull- shy 3 gt
XbullOCreVI
Q t-
03 pound mdash U
0 L- (8
X a s ar e gt Emdash COC i O O
mdash gt shyc laquo- O raquo bull t- mdash CO
X c - gt c c i shy r e w O t r e
mdash re X i- - z ^E l - IC C3O
Z cJ Xt E J r mdash o in trade re ^ cc U pound -gt
^ mdashJ O ^ 11 CSLJ - gt ^ c olt- c umdash C CT-3 O B 3= mdashmdash z - ^r mdash c = s J
mdash laquo f j 3 -3mdash O
pound mdash z = J 3 3 S O laquo
s re -re mdashmdash ~mdash gt
cO t 3 r e C - ^ laquo gtC ltshy O gt mdash Z CD o c re mdash rei 3 u
O C S li = i U) x^shy mdash x x r z r e JO w L J C ^ 3 i
mdashi
a
IS shyJmdash _jii) OS
aa I i
a 1 1
a 1 1 O
a
z CC w ^ 1raquo oo o o
CM o o
zx
o
ltamdashZLraquo
pound a o
^ 3 Z
Q a mdash mdash
o rmdash IA
i 0
QoOIA
a mdash
lA r~ r~
a mdash o CO
amdashoCOttrade
Q o o
laquobull
O
o o 1mdash
i ia o o lA
i
Z mdash m
CO CO
h_
0^zmdash
^
S c-c_ 1_
0 a mdash mdash 0
o O ro mdash 1
O O
0o CM1
a mdash
O O
Q
O O
1
o mdash
oO-
Q o o
lA 1
Q _
o o
1
WO
O
Q O
lA 1
gt o
0 o
O0
CM O lA
v o3- V
CM
CM r ~ CM
mdash =^ a
S 5^ 0lt r ~ ~
1 1 1 a- lA
a o
1 1 I I
CVJ
c UJ pound3
O
~ v z
1 mdash a z ZO o mdash Ui-
raquo o
a laquo
Lu
raquomdash lt^
U
It(O
ltfgt r~ u Lu
laquo fcCC
mdash
-1-mdash u 00
r-CM
_j^^ U Cpound C- u
mdash K ^
O U P- mdash
cs shyo L ^ t-oshy0 ~ CMr-
J c~1
Vi UuL
laquof~
u o bullmdash mdash
bull- t-
^ LL ^
K f- Ci bull-bull
shy shyU LJ LJ
rr shyo laquot- t_
O ^~ O c
CM Q
mdash c-Omdash
^
^V f-
mdash U
fc ^ aa L 1_ ou C- C
1
w
0
X L
raquo( CC-mdash
LJ
O
lA
_
0 1
^v U
Oi
laquo-O n
mdash
Z o to
ltr s _3 OK
CVJ CM ro
raquo~
j CM VO
ro bull-CM
ro 1 VO laquomdash
z o
r-Q
I C
o X UJ
poundo| s~a
a CM CVI CVJ fO lA CM 1 lA lt-
a o
o mdash LJ o raquomdash L
lt ^^ gt lt UJ C N X mdash _ in
o X o X CO
f)XCOXr-
X CM
bull-X ot^
ro X ^y X O rmdash
rXlAXOv
CM X
00 X
CM V
ro X ~
0
lAX roX o
mdashX
00X
o
r-X
^3 X^
z C o
lt a
lt 5 rmdash fl ro ^ -~
I O C- 83 ^ ~
lt gt- CO
X
0 O
13
E
23
eo ETC CU
gt i- Nlt (_ mdash
E O i-
lt~o ON dgt
N Q) mdash
i-tt) gtOO
bullDC
gt 0) C
T3 O
-D C CD
tgt
-U mdash mdash
C5
E 33
E-0 gtgts-O CD mdash T3 1- N JO ( =
0 0 U - O C5 t- t-ushy ro L jj bull
3 C 0 gtgt cnmdash 4J mdash
bullD CD bull C E E
I t -
lt Q 0)eo i c
lt mdash
mdash L
aagt E C CO mdash
CO i-W CO
bull obullDmdash 0
gtgt mdash
re bull E bulllt-gt
gtgt mdash
CD bull E-0
L W O lt tu en i-fgt c O Q
gtgt0 3 O mdash 4-gt i C
CD X -o eo E 0
w co CD bullO 4J COmdash ^ C d)CO O ^E 1 O W
co eo 4J bull
bull C CU ^ O ^
C O W
c eo Qeo mdash eo
t-JJ 0 E
o mdash c mdash
eo w
D C c eo CD laquo)
CO T3 0 4J Q) - C 0 mdash CO gt mdash E O w mdash
O 01shyC CU O O CD aw
CD O CO u- sshy amdash
re lt c eo cc c CD mdash CD 1- ltshy C C_ C re c co o - O X X CO CO3 gt CO 3 gt to E O O co O co CO 3 jt w O cfl 0) eo
cr LJ
LJ-J u mdash j CO 0amp5
a O 1 O
Q
1 1 i l
CD Dl bulla
CO _ mdash O D o
O ^ (A
ZX mdash Ld
O
en 3 10 O a
LJa a
Q 1 1 O
Q
+
O
X
_
mdash
o o I
gtgt O
h~Z
-^ 3
o0
mdash i-
1A 1
a a co agt C
LJ
sectK
Z= tM O 0 to bullo
X
mdashshyo
CD O
o mdash _ o
E umdash 3 E eo sshy
ltr-toZmdash
mdash s
0shy c
^
^ gt o
D o
a-rmdash
1
Q-
0 0oo r-V
tO 0
= mdash
O
tO 0
= mdash
O
Q O
O r-i O NO
1
awi
i mdash _ 3
Imdash I O
bullO C
1- 3 gt 0) bullo sshy co w
bullO CJ ID O X E C CU tt) bullw^ T3
w agt u C pound -gt
a a CO CD
mdash L 4J CD o gt
T3 gt C CO UJtt
2 mdash1 LJ Z) d CO 1 1
COO
~
lt O
~ I 1 1 I
Dl C 10 3 -D
lt - T J O
Dl C
1gt Omdash O bulllaquo Xl- i s o cu
Q lt3 toz cshy
mdash W f
r-B O c
mdashgtgt3 01O O u
W ID CO bullgt C -O mdash 4-gt 4-gt C
O -x mdash1 CO o CU c c co
1
OZ ZO o mdash Ol-
LJ -
L
0
1
C- bull 14 u- o laquoc~
bull mdash u bullDT3 O laquoccce tshy ^ D
l_ Cshy CCO O 0 0-0 Qmdash
CJ I- r-CM
1 1
U-Qshy
bull bullbull ^
O t_ 0 Q
-LJ
raquol
a o iT o c o
U) c
c u CD O
I I I CU c
Q) CJ CU W a ltshyon J2 o l- E E gt QCO CD O
I I I
ID JJ CU ES
J-gt imdash O Q Z CO w t --shy O mdash O 3 O laquoshy ^ c
_ICO a 0 0 0
^ sect5oa I-Q
CO X u_ y o- o=gtLJt-a
3shy
^
1
1
VO
m
1
i
1
t
_
3 lta i- U) 0 0
a
lA
lAbull
0 O
JI E oj3 gt E re mdash O X X co Qj
C 1 O
W 3
U L CO O
4J CO
0mdash CCD gt j ti --shy c JJ 4J
1- laquo 3 = C 3 or cu ogt tn Q -shy
E L n CD J-gt o o gt gt s o ---shyDior 3 3
mdash Tgt o cr cr mdash mdash CU 0)
o a CD -a OLJ U CU
N CU COT 4JT3 poundmdash 0gt U V
raquoT3 mdash agt OJ gtgtcu laquo c c
T3 O
C
C
Zlshyo ui u- Li ^ ^~bullgt lt LJ
lAXvOX
VO X ^ X
Xcjltshy
lA x
CM
O x
3shy
_ X
r^5 X
_ X
CM X
mdash c^ C3 O
c a bullbull o c c
mdash 4J O I I 4J
01 JJ 4J 1C laquo
3 t- C raquoJ O L (D CU C mdash o a~o mdash o
i i
C J J W CO II) O W IT OC N 03 = OJJ C O I- -= C O
I I
o o
ON X mdash
CMr-raquo
00 Orshy
X CO
vo ro O C 5) JJ Jshy I- I gtJZ-00 s a o
LJ CO eo UTJ a- I I O C X J O gtZ 1 re O
i CM
LA
LJ
O mdash c imdash LJ lt a gt y lt 2
ltCO O
O^mdash
laquoshy rmdash
CM Tmdash
n rmdash
_^jshymdash CO
LJ
j ^ |
52
14
what appeared to be natural materials although its location on the
cleared and leveled landfill tend to contradict this possibility
Most of the landfill is vegetated by a thin layer of grasses
sedges mosses and annual herbaceous species The northeast corner of
the landfill is unvegetated and cover material appears to have been more
recently applied This section is elevated 4 to 6 feet above the rest
of the landfill and appears to have received a second newer layer of
waste A 4-foot thick layer of carpet waste was encountered in
Excavation 1 but not in other excavations This section is adjacent to
the newer active landfill The landfill area just west of the access
road crossing (near Excavations 7A 8 and 8A) was also unvegetated due
to relatively recent grading operations
Ground Water The landfill appears well drained as ground
water was not encountered during any of the excavations Excavated
overburden was damp from the recent heavy rain but intergranular macro
pore spaces were free of water
OBSERVED QUANTITY AND CHARACTER OF DRUMS
A total of 45 drums were observed buried in the landfill
Table 52-1 presents a drum log describing each excavation and the
observed drums Data on the contents and condition of drums is
summarized in Table 52-2
Of the total drums observed 15 (33) were crushed flat
Although these could possibly still contain small amounts of waste they
are probably considered empty under RCRA guidelines Thirty (67) of
the total drums discovered were uncrushed and capable of containing
waste Seven (88) of the 8 drums sampled contained liquid or sludge
waste material Thus at least 7 (23) of the uncrushed drums contained
some liquid or sludge waste
15
en C Cl
bullo gtraquormdash
c mdash a
o c re bull mdash c
~ o mdashbull 4Jmdash
10 0 mdash
gt O
ro CO
fcshy0
c
C
vgt 3 0
1 rea
-gt
mdash
3 o T3
lt-O
C j C
CB 3 TJ ii i- 3 mdashQCOa
ifl u bull c c
t_ o
mdash shyO
mdash
L re N
co
t-O
mdash
mdash lfl
V) O
CO N CO pound re
0 mdash
^1 10
ltP O C raquo
CM reO
o f shyi O
mdash mdash 3 - D
c 1
CD bulllaquo
mdash3
D mdash
1 C
Q CO
CD Ifl 4-gt CO
Q
CM
r-
Ul
Q Ul gt EC Ul CJ CO o t5bullpound
z O mdash
C Ci o^
O Cbulla 3v iC MW5 CO 4J3 u CS- Ifl CBC J C O - U
gt Cgt Omdash Oi O
U- 0) Ifl bullgt-gt 1 W C
to lt-gtT3 gtmdash
0) gt shyJ 0)
C OltJ bull O T 3 C D C P
133mdash 4J bull ifl tshy Vgt~ V a O V4JJ
C o
C mdash
O Ifl
3 fc 0)
i-
c
U) re gt
ai C mdash
C mdash
CO gt c o
bull to y 3 cc Q
ltbull-CB
1 4Jin
bullD reCD jCJJC TJCD mdashbullD bull mdash
CD 0t- u iflo ifl
0 C ^-
CB laquo
3 ltbull-
0)^shy
C
0 Cgt O
1 O CTl C
T3 1 mdash CB O
mdash CB mdash in J o 3 tfl C ^ CO 0 gtltgtshy
O gtgtc 01
CO 3 1- mdash C Cregtmdash laquo
TJ W TJ mdash i re traquo-
shyU mdash
O Q
COCO^^
mdash ^
mdash gt C 0gt mdashO ~ bull
Ul
o auO
CCUl
mdash K o tO Ul Q
mdash OT30Jj c mdash4Jt- Jpound O Wre c i re03 gt
lt~i- laquo o ai
0 ) 3 gt O ^crc Ifl - CO -^mdash
3 mdash Q iflmdash 1- O 3 3
O V O ltraquo-o laquoTJ
gt
T3 - o
gtgtmdash J-gtmdash
Dmdash
6-o
09 bull mdash gtpoundbulllt-gt
re a
Ul X t5
Cpound O Z
fl) mdash^ C B gttflOl3T3T3l_ 3 Q)O mdash mdash
tn mdash
shyD CB
mdash mdash
mdash tt
CO C T3 poundi mdash JCmdash re
^ C O C X CB ^ - S - C C O mdash re O Q DW4shy
re shyu O 1
O Ul X EC Ul mdash
x a^s ox
CO
^) Z
J
1-o t-Ul X r-u 0
o j c gt T3 i -gt c tu mdash c u r e mdash
- C D mdash T3 - C M mdashbullOJJQmdash re3inecrec u c r e o mdash lt~ bullz c~4J O CX t ^Jw o r e -gtgtOgtgtshy3 c j t shy re mdash mdash ret- i o Qmdash gtgtpoundgt a
i reraquo CD 0) bullbull Ifl t-
Q ) t ) O pound O ^ laquo gt - Ow re re ro re re -gt Q mdashc 5 shyu a j-gt D t- raquomdash mdashCB C re C CO 3Q mdash O mdash O U
Htshy ae cu coo)
1 O i i
shya shyo j CD C bullgt o mdash c o c o coco mdash plusmngt o ~a v c en CD
mdash C O
raquoCJ 3C c re amp- ogtCD J o 3 CC C I-Omdash 3gt O
3
O ro
Ul X 1mdash
u O
Ul o r-Z Ul
gtV~ omdash Dlshy ^mdash mdash wre3 i cc
mdash cr bull gtJJ mdash C mdashi QIgtJ^re a shyJQI- o 0mdash
O bullO 3laquo laquo
jjmdash ureoO mdash O N 0)rc3recomdash4Jt-4JpoundmdashC C mdashmdash mdash u
1
shya 0 -
mdash gtgt re-raquo-gt CUD laquo E CD
^ J-1
CJ eoc
4JCB CO
mdash O
C 1- C mdash O C B C B C E J mdash J ltshy shyo cn o o c o r e c shyU -gtO OJC D ifl roc
T3 3 I U 3 laquo-
Ifl CD 1 W ^J 4 J 4 J c -aiflj jc
CB C r e O C B lt-gt -Jgtcoraquo C C -WE O O ) ~ O O O mdash O
Ul O
c ui =gt z
o
1-CC Ul Q
Q z ^ Ul
2 gt Ul O
o Cpound
^ CO
Ul Q ^
z o
(O U S Q
Slt
t5 lt
Z5O
1mdash z ui
Qa Ul
CD 0-1
u m O_J
O2^ltUl
O CC Ul Q
VOCO
CNlA |3
VO ^
CJ |CO |
CJ CMI3 f~ rojO VO rolo
^
ymdash3 CC
roCM
ro O ICNj
ro rolvO ro ro
ro A
rolvO r-jO
00 C3N
ec a m
r3
CO
3 a ty r-
cc Q
(M CM
to z
m 3 c O
u _i co
U-O
O 3-IObull - I c y
fshy lt- ICO r- r-ICM O U lfN ro -mdashla1 f~ laquo- ]CO bull- -ICM O O J|O O
c U) CO
mdashbullre re
mdash re
mdash i ltC c tz
j lt
i lt
5 0 0 G O o o o o z bullU 4J J h- J shyJ tmdash tmdash
^33
J3 3
O 3
Q 3
_Cr(bull
shyC 3 t)
CC IP y
C2 zgt c J
1mdash O 5
53
16
The condition of the uncrushed drums was highly variable with
only 4 (13) rusted and decomposed to the point of structural weakness
These drums were found in Excavation 10 at the far west end of the
landfill which is believed to be the oldest section (See Plate 52-1)
Interestingly two almost new looking drums were also found in
Excavation 10 at a greater depth than the four rusted drums The
remaining 26 drums were observed to be generally intact and structurally
sound Some were dented partially crushed or rusty
CHARACTER OF WASTES
Air Monitoring An OVA and HNU were used to monitor the air
for concentrations of organic vapors during each excavation Above
background instrument readings indicative of contamination were
regularly recorded when monitoring the air just above or inside of
drums A general contamination of the ambient air in the workspace was
noted only during Excavation 8A where above background readings of +13
in the excavation pit and of +6 above the excavation pit were recorded
Explosimeter readings were obtained from three drums -- 10 lower
explosive limit (LEL) from drum sample 10A 20 LEL from drum sample 6B
and 100 LEL from a drum in Excavation 8 Instrument readings are
presented in Table 52-1 and Table 53-1
Visual Observations The following types of waste were
observed during the excavations
fabric waste (carpet waste)
crushed drums
drummed waste - liquid sludge and solid
uncontainerized dried sludges and pigments
stained soils
Fabric waste scraps of synthetic non-woven fabrics5 heavy
carpet-like fabric and backing material were found only in Excavation
17
CM
CO LJ fmdash O z
laquo 4J
u TO 4-gt
c bullmdash
k bull mdash E mdash 3 3 i-^ O
mdash TJ --raquo co co 4J
E CO O U L U
E 3 c T3
C O a o
is
CO c to 3
U
TO
E O t_ U_
o o
1 ltmdash c
mdash tmdash TO 4J bull C TO 0 O o c u 3 TO
t_ 0) 0 4J
U)
mdashOTOgt
Cw bull aco jc
N 4J a
mdash L Q) re co T E
CO
bullo gt egt mdash c mdash bull o ^^73 C E gtO O mdash 3 J-gtmdash N 4J L 3 mdash 1--C gttTC bull
CX 01C JJ TO O mdash
TO trt mdash t- E mdash 3 JJ a O Q
C I 0 X E mdash C mdash CO
mdash o laquo (D-O mdash O O bullbull B Ol o -cmdash e oic f~ to a (gt TD mdash
E 1- Cpoundmdash 3 O O CO P m T1
L u
T3 CO
lto sshy0 O CA W
laquoT3 O CO 0 C J= CO tlaquo Q bull 3 O Ol 1- C o mdash 3 E a
3 E E i- to
Z L
mdash bull mdash O 4-3 Cl Q
bullD 0) CO T5 N CO mdash C -P 1 0 U TO O mdash 4J Cfc
mdash U) c shybullgt O w C O Q (5 4J 0
3 -J bull U)
5 gt TO_ U
bull gt pound mdash 3 mdash L ro TD
JJ-D - CO TO laquo QO
C 0
^ 0) T3 mdash O
r to 3
O O L L
0
01 TO gt bull
tshy mdash OT3 mdash
CD O C N U) O mdash
TO O CO mdash C C
bull^ ~ CO TO TO gt U iJ
mdash C W to O
5 c c 4J 3 CO X LJ
^ bull bull0 laquolt- ej
TO CJ CO mdash C JJ
z u to mdash T3 4J ai TO CD C laquo bull c c ugt o cr 0) bull mdash CO mdash O bull gt JC TO ^ mdash Q CO O JJ O Q bull- CO to mdash to c Z CC O il mdash 4J gt
mdash Omdash O1O CD mdash U) TO C X mdash O CO C L mdash Cvv O W pound G CO C C
O gtgtgt C C mdash CO C TO CO 3 E mdash -J laquo 1- bullgt CO 0 to
bullo CO
cshyo bull
ugt C CO TO c w 4J-Q co e a c
mdash re TO in E to
Q
JJ c bullo
a LJ co E bull LJLJ
O mdash zx ZQ
ax
z o mdash1mdash Q
mdasha o CO LJ a LJ ~J
s CO
JC u
bullmdash
^ 4J bull
bullO bullmdash
gtgt3 TO CT L mdash Olmdash 1 O CD mdash 3 a CT cshy re 3 a c- o
^j C CO E Ol
bullmdash CL
bull CO 01 D 3
U
T O a
E Ol
bullmdash av^ CO 4J IA TO 5
T3 CO C
bullD
mdash mdash O CO
3 CT
bullmdash ^
bulla CO L
4J
C CO o 3
(A C TO
Imdash
03
ai_ 3 a bullo bull mdash 05 3 O) 00
mdash mdash C c gtgt G CO
O O
bullo^ = c a 0)
E C O umdash u a L_ bull OlCD mdash
4J mdash
u) obulla o u) amp 5 c -a 7 O C mdash o mdash _ i- (0
CO E laquoJ
C
a
bulla c bull o bull
c bullQ CO
3 01
CT mdash mdash a mdash -v
t- Ol CC-D 0) 3
CJ raquo
x^ CO
bullo 3
lt) bull_
gtraquomdash CO O 1- Ui O)
bulla ^ c mdash mdash mdash TO co in
s^
COOlbullo3
U) mdash
gtgtmdashCO O1- U)Ol
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mdash TO
i) ltgt
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c mdash
TO 4J
U)
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laquo_
o to
T3 to C
TO
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bullo ltr
1
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o wo LJtshy to
o z
CO d _l O LJ LJ _J hmdash J C- LJ XZampS LJ mdash
Q mdash
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Q mdash
O
to o o
Q
O 1
to O
O
O
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I 1 1 i
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ceo oz u lt
O CJ O-J
o ltDpound 15 t-
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1mdash 3E LJ
13
rshyC5 Z
y a Q ^
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mdash s Cu a
gt 0
Q
mdash
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O
r-
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o r-
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o
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o
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a mdash o o T~
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O o or_
A
to 2T
f ro
CO X
O
Q
O O
Q
mdash O o o rmdash A
CO X
0 ON
CO X
o o ^
1
f
CO
o
to X
00
to X
CO
to X
CO
if
LJ
CO lt
LJ CM 51 r-rmdash
tmdash CM CM ^_ CM
CO CM ^x
CM (M CO CM
Q -
-^ ^ -
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^ shy-
1
gtZLJ lt O C3 o-s - shy laquo raquo laquo S laquo 5 2 LJ Z
ui o -1 LJ
i mdash lt sectco z 1
ltT -^
bull~
lt
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deg
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^
lt 1
sect
lt 1
eS
CO 1
CC
18
bull -a gtgt CD
CO S jj
0 0
CO O
bullo CD jJ
bullo z 3 O L
E 3
CD 1-gt o CO
jpound cshy x mdash o mdash
- 0 1 mdash bshy
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19
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20
1 (See Plate 53-1) This is the predominant waste material currently
being disposed of in the active landfill
Crushed drums were distributed throughout the original
landfill and were found in Excavations 2 4 4-5 7A 8A and 14 Some
drums such as those found under the road in Excavation 7A may have
been crushed by heavy equipment operating in the landfill Others like
those found at depth in sandy fill in Excavation 2 appear to have been
crushed before burial Drummed liquid and sludge wastes are also
distributed throughout the landfill (See Plate 53-2) They were found
in Excavations 1 4 5 6 8 and 10 These wastes are discussed below
One sealed drum was openedand found filled with refuse -- paper cups
towels paint covered rags etc One open and partially crushed drum
contained a dark granular solid waste This material was sampled
(Sample 10B) and found to be nonhazardous
Small deposits of dried pigmentsludge were found in
Excavations 3 4 6 9 and 13 Discernible layers of pigmentsludge and
stained soils were present in Excavations 7A 8 and 8A (See Plate
53-3) Of particular note was a 2 to 4-inch thick layer of
grey-colored dried sludge found at Excavations 7A and 8 All of these
wastes were sampled and the results are discussed below
Laboratory Analyses
Laboratory analyses were performed on 10 selected samples
obtained from both containerized (drummed) and uncontainerized wastes
Samples were analysed for 3 metals and 87 priority pollutants including
11 acid compounds 45 baseneutral compounds and 31 volatile organic
compounds Table 5-4 summarizes the analytical results and the
laboratory data sheets are presented in Appendix D
Of the 45 priority pollutant baseneutral compounds only 4
were identified in the samples that were analyzed Baseneutral
21
compounds and particularly phthalates were the most prevalent
chemicals and also were reported in the greatest concentrations The
highest levels of naphthalene (1200 ppm) bis (2-ethylhexyl) phthalate
(110000 ppm) and di-n-octyl phthalate (6200 ppm) were found in sample
4A a translucent red liquid obtained from a drum The highest
concentration of benzyl butyl phthalate (13000 ppm) was found in sample
6B a clear liquid and pink sludgepigment obtained from a drum
A total of 8 volatile organic compounds were identified The
highest levels of benzene (100 ppm) xylenes (19000 ppm) and
ethylbenzene (5300 ppm) were found in sample 5A a clear liquid
purple-grey sludge obtained from a drum Toluene was found in highest
concentration (12000 ppm) in sample 1A a purple-grey thick opaque
liquid obtained from a drum Methylene chloride (13 ppm) was
identified in greatest concentration in sample 8A-C a purple stained
soil and powdery waste Sample 10A a purple liquid obtained from a
drum was the only sample found to contain 1-1 dichloroethane (2000
ppm) Finally trace levels of trichloroethylene (sample 10A) and
111-trichloroethane (sample IB) were also reported
Samples were tested for three metals - cadmium zinc and
chromium The highest concentrations of cadmium (2200 ppm) and zinc
(5700 ppm) were found in sample 4A a translucent red liquid obtained
from a drum The highest level of chromium (52 ppm) was reported in
sample 5A a clear liquidpurple-grey sludge obtained from a drum
22
60 DISCUSSION
61 EXISTING SITUATION
Under existing conditions relatively small quantities of
volatile organic compounds (VOC) are indicated to be leaking from wastes
buried on the landfill site To date ground and surface water
monitoring results indicate relatively low concentrations of VOC in the
ground water and below detection limits in the adjacent brook (See
Tables 61-1 to 61-10) The results indicate that no potential health
risks from VOC and other constituents currently under observation are
being caused by the landfill operation to down stream surface water
users It would be prudent for Troy Mills to continue to monitor the
quality of Rockwood Brook upstream and downstream for VOC and on the
basis of waste analyses (previous section) to monitor ground and
surface water points for toxic metals and baseneutral compounds
62 SITE HYDROLOGY
An analysis of the hydrology of the landfill site was
performed in 1982 (NAI report of September 1982) The subwatershed that
contains the landfill site is (about 44 acres) a small fraction of the
watershed area that contributes to Rockwood Brook above surface water
sampling point C (about 1650 acres see Figure 62-1) This indicates
that most of the flow of the brook at point C (about 97) is contributed
by upstream watershed areas Thus leachate discharging into Rockwood
Brook from the landfill site can be expected to be diluted by over 30
times its volume This factor and the volatilization which naturally
occurs results in parameters detected in the Troy Mills monitoring
wells often becoming undetectable when they enter the brook
f 5
Geologic conditions which were defined in the NAI report of
July 1982 indicate that permeable deposits of sand and gravel overlie
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27
TABLE 61-5 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M5 (UPGRADIENT WELL)
Parameter Date Sampled 11-22-83
Specific conductance
pH2 81
Dissolved iron mg1 036
Dissolved manganese mg1 010
Chloride mg1 10
Phenolics mg1
3
023
Identified volatile organics
None identified ND
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (yg1)
28
TABLE 61-6 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M6
Parameter
Specific conductance
PH2
Dissolved iron mg1
Dissolved manganese mg1
Chloride mg1
Phenolies mg1
Identified volatile organics
11-dichloroethane tetrachloroethylene 111-trichloroethane
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vg1)
Date Sampled 11-22-83
152
lt002
29
6
0002
27 trace 140
29
TABLE 61-7 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M7
Parameter Date Sampled 11-22-83
1 47 Specific conductance
pH2 62
Dissolved iron mg1 002
Dissolved manganese mg1 0026
Chloride mg1 gt2
Phenolics mg1 0070
3 Identified volatile organics
111-trichloroethane 5
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vig1)
30
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34
glacial till and bedrock The sand and gravel deposits form a permeable
conduit through which leachate from the waste burial areas migrates
The permeable deposits lie in the area north of monitoring well M-l (See
Figure 62-1) In general the water saturated thickness of the sand
and gravel in the vicinity of the north-south access road is 6 to 12
feet
64 POTENTIAL FOR GROUND WATER CONTAMINATION
641 Estimated Quantity of Drums
The test pit excavation and sampling in the drum burial area
indicates a potential source of ground water contamination for the
future Many of the drums encountered were in fair to good condition
and contained liquid wastes An estimate of the number of drums in the
deposit was made with the following assumptions
1 The complex magnetic anomaly was simplified into a geometric solid 600 feet long 40 feet wide and 10 feet deep with a volume (V) of 240000 cubic feet
2 Each steel drum (D) occupies 105 cubic feet (including voids)
3 The density of packing (P) was assumed to be 50 of the packing that can be achieved with perfect cubic packing
THEN
N = estimated number of steel drums
N = (VD) (P)
N = (240000105) (05)
N = 11429 drums
The results of the drum excavation work provides a basis for
estimating the potential for specific types of chemical loading In
general three main classes of chemical substances were identified in
35
the drums The chemical substances included baseneutral extractable
organic compounds (mostly phthalates and lesser amounts of naphthalene)
volatile organic chemicals and metals
642 Phthalates
The phthalate esters found in the drums include
bis (2-ethylhexyl) phthalate ^0^3 benzyl butyl phthalate di-n-octyl phthalate Jd~7
Bis (2-ethylhexyl) phthalate was found in the highest
concentration at 110000 ppm (11 percent) Benzyl butyl phthalate is at
the second highest concentration 13000 ppm (13 percent)
Characteristics of those phthalates found are presented in Table 64-1
TABLE 64-1 PHYSICAL PROPERTIES OF PHTHALATE ESTERSshy
di-n-octyl bis (2-ethylhexyl) butyl benzyl DOP DEHP BBP
ALTERNATE o-Benzenedishy di (2-ethylhexyl) benzyl butyl NAMES carboxylic phthalate phthalate
Molecular Weight 3910 3910 312
Melting Point -25degC -50degC -35degC
Boiling Point 220degC 386 9degC 377degC
Vapor Pressure-mdash lt02 torr (150degC) lt001 torr (20degC)
Not
2xlO~7torr (20degC) Available
Solubility 3 rngfc (25degC) 04 mgfc (25degC)
58
13 rngH 48
Log octanolwater 92 873 58 partition coefficient 53 48
Versar Inc 1979 Water-Related Fate of 129 Priority Pollutants Volume II Prepared for US Environmental Protection Agency PBSO-20438 December
bullbullOther names listed in Versar 1979 vMore than one value has been calculatedreported
36
Bis (2-ethylhexyl) phthalate is the most well-studied of the
phthalate esters though the information on phthalate esters as a group
is limited The three phthalates identified at the Troy Mills site have
relatively low solubilities and are readily adsorbed onto suspended
particulates Microbial degradation is effective under aerobic
conditions bur is generally slower under anaerobic conditions
(nonexistent for bis (2-ethylhexyl) phthalate)
The above characteristics are important for two reasons One
the extent and nature of contaminant migration from the site are
dependent upon the physical characteristics Second the treatment
(clean-up) alternatives for contaminated ground water or soil can be
estimated from the characteristics
From the available information it appears that the phthalates
present at the Troy Mills site would be relatively immobile due to their
low solubilities and high adsorption rates The presence of toluene and
methylene chloride at the site however may increase the phthalates rate
of migration
It is important to note that none of the phthalates have been
found to be present in the monitoring wells nor in the surface water
sampled probably due to the low solubility and high adsorption rate
37
643 Napthalene u K r
Naphthalene has also been found in significant quantities in
the sampled drums Naphthalene is a polycyclic aromatic hydrocarbon and
has the following properties
Molecular Weight 12819
Melting Point 8055
Vapor Pressure (20degC) 00492 torr
Solubility in Water (25degC) 344 mgfc
317 mgfc
Log octanolwater partition coefficient 337
Versar 1979
Naphthalene has mid-range adsorption rates and solubility It is
therefore inferred that there would be some adsorption to soils in a
ground water environment It is important to note that naphthalene has
not been detected to date at the monitoring wells or the surface water
sampling locations This is expected to be a result of adsorption on
the soils
644 Volatile Organic Compounds
Volatile organic compounds tend to migrate readily within
soils and ground water They are therefore considered a threat to
surrounding ground and surface waters if they are released in sufficient
quantities
Volatile organic compounds were detected in samples from six
steel drums The total volatile organic (TVO) concentrations in the
38
wastes ranged from 9 ppm to 30100 ppm and averaged 8570 ppm In order
to determine the potential for future contamination by volatile organic
compounds an estimate of waste quantity based on information from the
drum excavation program was made It was assumed that 7000 steel drums
in the deposit are 60 full of liquid waste with an average TVO
concentration of 8570 ppm The computed volume of liquid waste is
231000 gallons with an average TVO concentration of 8570 ppm This is
equivalent to about 1980 gallons of pure TVO
Two of the volatile organic compounds that have been most
prevalent in the existing ground water monitoring system are
111-trichloroethane and ethylbenzene The EPA suggested no adverse
response level (SNARL) for 111-trichloroethane is 330 ugpound for
1 day of exposure and 35 jigd for exposure over a life-time in
drinking water
In general ethylbenzene is a prevalent chemical in the
environment Sources include commercial (eg petroleum and petroleum
by-products) motor vehicle exhaust and cigarette smoke An intake of
16 mgday (1 mgfc) has been calculated as an acceptable rate to
protect from toxic effects Carcinogenic effects have not been
identified to date The physical properties of ethylbenzene are
presented in Table 64-2 The principal mechanism for removal of
ethylbenzene from water is volatilization In addition to
volatilization adsorption may also be an important removal mechanism
based on the log octanolwater coefficient This factor is important in
evaluating the migration of ethylbenzene from the disposal site
Toluene which was also identified in waste and ground water
samples exhibits properties similar to ethylbenzene in that it
volatilizes easily Toluene which is also referred to as methylbenzene
is distinguished from benzene by the substitution of a methyl group for
one hydrogen atom Physical properties of it are presented in Table
39
64-2 The EPA suggested no adverse response level (SNARL) for toluene
is 1 mgpound in drinking water with a maximum exposure time of ten
days
TABLE 64-2 PHYSICAL PROPERTIES OF ETHYLBENZENE AND TOLUENE
ETHYLBENZENE TOLUENE
Molecular Weight 10616 9213
Melting Point -949degC -950degC
Boiling Point 1362degC 1106degC
Vapor Pressure at 20degC 7 torr 287 torr
Solubility in water at 20degC 152 mg2 5348 mgd
Log OctanolWater Partition Coefficient 315 269
645 Metals
One liquid sample contained high concentrations of cadmium
(2200 mgd) and zinc (5700 mgd) indicating that the waste deposit is
also a potential source of certain toxic metals Tests for these metals
have not been made to-date in ground or surface water samples It would
be prudent to add toxic metals such as cadmium chromium lead and
mercury to the list of parameters that are being monitored to further
characterize the quality of adjacent ground and surface waters US
EPA and New Hampshire drinking water standards for these metals are
cadmium 01 mgd chromium 05 mgpound lead 05 mgd mercury 002
mgd Although zinc is not considered a highly toxic metal the
US EPA has set a secondary drinking water maximum contaminant level of
5 mgd on this metal
40
70 CONCLUSIONS
The following conclusions were drawn during this
investigation
1 A steep-gradient irregular-shaped magnetic anomaly is present under closed and covered portions of the south part of the Troy Mills landfill
2 The magnetic anomaly is caused mostly by an irregular-shaped accumulation of disposed steel drums
3 In a randomly conducted sampling of drums in the source area for the magnetic anomaly 16 of the drums contained liquid andor sludge 33 were crushed flat and 51 were not sampled because there were no accessible openings
4 Laboratory analyses indicate that the random waste sampling contained significant concentrations of several volatile organic chemicals several baseneutral priority pollutants and high levels of cadmium and zinc
5 Observed concentrations of volatile organics at the monitoring wells are relatively low Because of their potential for migration in the ground water continued monitoring of volatile organics will be required
6 Volatile organic chemicals have not been detected in Rockwood Brook to-date Because of the presence of low levels of volatile organics in the ground water they should be monitored in the brook on a regular basis to confirm the lack of impact
7 The presence of high concentrations of cadmium and zinc in one of the waste samples indicates that trace metals should be monitored periodically
8 The presence of baseneutral extractable compounds (phthalates and naphthalene) in all of the analyzed waste samples indicates that these compounds should be monitored periodically
9 The phthalates are not expected to migrate freely because they have low solubilities and are readily adsorbed onto soil particles
10 If elevated concentrations of volatile organic compounds trace metals or baseneutral extractable compounds should occur in the monitoring system (wells and brook) in the future a need for site remedial actions to mitigate the potential for downgradient ground and surface water contamination could develop
~
80
41
RECOMMENDED PLAN
Based on the preceding conclusions it is recommended that the
following plan be implemented by Troy Mills Inc
1 Continue monitoring ground and surface water quality at the Troy Mills Inc landfill sampling on a quarterly basis with sample collections during April July October and January
2 To confirm the absence of the landfills impact on Rockwood Brook test samples for volatile organic compounds by GCMS from surface Stations B (upstream) and C (downstream) on the April and October samplings
3 To determine if trace metals are present in downgradient ground waters conduct analyses for cadmium chromium lead mercury and zinc on samples from all monitoring points during the April sampling and on subsequent sampling rounds if necessary
4 To confirm the continued absence of baseneutral extractable compounds in downgradient ground and surface waters conduct analyses for baseneutral extractable compounds on samples from monitoring wells M 2 and 3 and surface Station C (downstream) on the April sampling and on subsequent sampling rounds if necessary
5 If a sudden rise in concentrations toward unacceptable levels should occur in the monitoring system (wells and brook) additional monitoring rounds at a monthly interval should be conducted to confirm the rise in concentrations
6 If elevated concentrations persist and are verified by the additional monitoring remedial alternatives will be defined to mitigate the potential for downgradient ground and surface water contamination
Respectfully submitted NORMANDEAU ASSOCIATES INC
Dennis R Sasseville Project Manager
Donald H Bruehl f laquo | APG Senior Hydrogeologist -^ - - AIPG Certificate No 2272 ^ -v^
^^Z-^^
APPENDIX A
SITE SAFETY PLAN
GENERAL SAFETY PLAH FOR
TROT MILLS LANDFILL TROY MEW HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
Prepared by
NORMANDEAU ASSOCIATES INC Bedford New Hampshire
R-457
November 1983
TABLE OF COHTENTS
PAGE
SECTION 1 BACKGROUND INFORMATION 2
Identification 2 Personnel 2 Site Description 3 Project Description 5
SECTION 2 HAZARD EVALUATION 6
Overall Degree of Hazard 6 Specific Hazards 8 Necessary LPP 8
SECTION 3 FIRST AID FOR EXPOSURE 10
SECTION 4 OPERATIONS SAFETY PLAN 11
General Personnel Protection GuidelinesAction Levels 11 Site Reconnaissance 13 Task 1 - Magnetic Survey Topographic Survey 14 Task 2 - Drum excavation and Sampling 15
SECTION 5 EMERGENCY INFORMATION 16
Emergency Telephone Numbers 16 Route to Hospital 16 Contingency Plan 17
APPENDICES 18
A - LEVELS OF PERSONNEL PROTECTION 18 B - DECONTAMINATION PROCEDURES 23 C - PERSONNEL AND RESPONSIBILITIES 25 D - PERSONNEL CASUALTY 26 E - GUIDELINES FOR SITE OPERATIONS 27
GENERAL SAFETY PLAN FOR
TROY MILLS LANDFILL TROY NEraquo HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
The following is a Safety Plan for on-site activities performed
during the Investigation of the Troy Mills Landfill being conducted by
Normandeau Associates Inc (NAI) of Bedford New Hampshire
The document is intended to be an in house working guideline
for personnel trained and experienced in hazardous waste field work and
not a treatise on safety Familiarity with standard equipment and proshy
cedures is expected Where possible non-site specific information has
been appended
All NAI employees subcontractors and visitors will be required
to follow this safety procedure plan and to report to either NAIs proshy
ject manager (P M) on site coordinator (OSC) or safety officer (SO) on
issues relating to safety
SECTION 1
BACKGROUND INFORMATION
IDENTIFICATION
Site Name Trey Mills Landfill NAI-ID No 457
Trey Mills Inc Troy NH 03465
AddressLocation At the south end of the dirt road about 15 miles
south of Troy NH between Rockwood Brook and the
old Boston and Maine Railroad grade
County Cheshire Phone 603-242-7711
PERSONNEL
Brook Dupee Bureau Hazardous Waste 603-271-4611
State Contact John Regan Bureau Solid Waste 603-271-4586
Dan Allen WSPCC 603-271-2755
EPA Contact
Other Contacts
Client Contacts Barrett F Ripley (Vice President)
NAI Personnel - (472-5191)
Project Manager - Dennis Sasseville
On Site Coordinators - Alton Stone
Safety Officer - Elizabeth Gross (Phoenix Safety)
Technical Director - Don Bruehl
Other - Douglas DeNatale Steve Ransom
SITE DESCRIPTION
Type of Facility Company (on-site) landfill
RCRA Status Generator Disposer
Size About 15 acres BuildingsStructures None
Surrounding Land Use N Forested
(one mile radius) E Abandoned Railroad
Forest RuralResidential
S Forested
W Forested Mountain side
Unusual Features or Terrain None
Site Activities - Troy Mills manufactures textiles carpets and related
products Since 1968 waste materials including
drummed wastes have been landfilled on company proshy
perty Drums mostmany of which may be emptycrushed
are buried in an inactive section of the landfill
The active section is currently accepting waste
which is considered to be non hazardous
Specific - Improper disposal of hazardous waste
Problems - Leachate seep
Contamination of ground water
Hazardous WastesMaterials On-5ite
Wastes - Uncured foam rubber latex sludge
SBR rubber silicone defoamer potassium oleate soap
calcium carbonate and feldspar filters zinc oxide
and sulpher salt cure system
- Vinyl plastisol sludge
PVC dispersion resin DOP and DOA plasticiser
calcium carbonate filler organic pigments AZO
dicarbcnamid blowing agent zinc salts expoxidized
soybean oil cadmLum-bariin-zinc stabilizer Varsol
MEK prints and topcoats sludges
PVC acrylic resins organic and inorganic pigments
MEK solvent toluene silicate fillers
Industrial solvents and chemicals
11 -dichlorethane 12-dichlorothane
111-trichloroethane trichlorethylene tetrachshy
lorethene methylene chloride toluene benzene
ethylbenzene benzidine 33-dichlorobenzidine aeroshy
lein acrylonitrile napthalene benzoperylene dibenshy
zoanthrasene idenopyrene
Pesticides
There is a possibility for low levels of pesticides
to be on site These would include Chlorodane
heptachlor expoxide toxaphene aldrin alpha BHC
beta BHC 4-4-DDT endosulphan 1 heptachlor
PROJECT DESCRIPTION
Purpose Tb characterize ground water conditions at the site and to
characterize wastes buried on site
Specific Tasks
Site Reconnaisance
Task 1 - Magnetometer SurveyTopographic Survey
Task 2 - Excavation for inspection of drums
SECTION 2
HAZARD EVALUATION
Overall Degree of Hazard - Moderate
Task Hazard Proposed LPP
Site Reconnaissance Low Level C
Task 1 MagnetometerTopographic Surveys Low Level CD
Task 2 Drum ExcavationSampling Moderate Level B
Conpany records have indicated that a variety of industrial
and potentially hazardous wastes including drummed wastes
were disposed of on site Several of the subtances are
trade name materials or industrial process materials and it
is difficult to determine the specific chemical composition
Hazard is dependent upon concentration of material state of
material (solid sludge drummed liquid) and degree of
decomposition
Many of the materials - SBR rubber silicone defoamer
potassium oleate soap calcium carbonate and feldspar
fillers zinc oxide and sulpher salts plasticiser
calcium carbonate filler organicinorganic pigments AZO
dicarbonamid blowing agent epoxidized soy bean oil
cadmiura-bariun-zinc stabilizer - probably do not represent
a significant hazard to an inspection team if they are
bound into a sludge or solid Personnel are not likely
to injest or come into a prolonged high concentration
contact with these materials In powdered or dust conshy
ditions the materials are more hazardous due to the inhashy
lation of contaminated particulates
MEK (TLV-200ppm) toluene (TLV-100ppm) and Varsol
(turpentine thinner composition unknown) are volatile
organics which require respiratory protection and contact
protection
Depending upon state and decomposition PVC resins could
be a source of vinyl chloride monomer (VCM-a carcinogen)
requiring respiratory protection VCM is not adequately
filtered by air purifying respirators
Results from ground water sampling showed low levels of
industrial chemicals (PPB range) At these low conshy
centrations the chemicals do not represent a significant
hazard However the low concentrations in ground water indishy
cate the possibility of higher concentrations in the waste
materials
Industrial chemicals - napthalene (TLV-10 ppm) peryshy
lene anthrocene and pyrene which are hazardous
through inhalation or absorbtion Furthermore as
double benzene ring chemicals they are potential
carcinogens
Results from ground water sampling indicated possible
low levels (parts per trillion) of several pesticides
- chlorodane heptachlor epoxide toxaphene eldrin
Alpha BHC Beta BHC 4-4-DDT endosulphan These were
tentatively identified during a first analytical run
but not confirmed during a second run laboratory
review (GCA Bedford Mass) determined that the
material was actually a complex of highly degraded
heavy organics derived from the industrial waste The
presence of pesticides in industrial textile waste is
unlikely
Specific Hazards
1) Inhalation of organic vapors
Excavation of buried material and sampling of drums could
initiate high vapor concentrations
2) Fire and explosion
Many of the solvents are flammable liquids and volatile
Excavation of material and sampling of drums should
proceed cautiously in order to avoid rupturing shocking
or sparking of drums and material
3) Inhalation of contaminated dustparticulates
Excavation of buried material may result in a release of
particulates
4) Contact contamination
Excavation and sampling of wastes could possibly result in
contact with contaminated waste and soils necessitating
protective clothing
Necessary LPP
Site Reconnaissance - Level C The site has been visited on numerous
occassions by the state and private personnel Use of an HNU (102 ev
probe)- has not indicated significant vapor concentrations Significant
odors during dry weather or other hazards have not been noted
Sections of the landfill are currently active and adverse effects to
personnel have not been noted Level C - (tyveks rubber safety boots
organic vapor cartridges) is sufficient
Task 1 MagnetometerTopographic Survey - Level CD LPP will depend
upon the results of the Site Recon Significant vapor concentrations
or likelihood of particulates will necessitate an upgrade in the LPP
Otherwise Level D (work clothes safety boots boot wash) is sufficient
Task 2 Excavation and Sampling of Buried Drums - Level B The potenshy
tial for encountering significant concentrations of hazardous
materials during this task is moderately high Full Level B - (SCBA
chemical resistant tyveks hoods rubber safety boots rubber gloves)
will provide necessary respiratory and contactsplash protection
The use of the hooded yellow tyveck and the taping of ankleboots
wristsgloves and face maskhood junctions will provide complete conshy
tact protection
10
SECTION 3
FIRST AID FOR EXPOSURE
INHALATION OF VAPORSPARTICUIATES
Symptoms - eyenosethroat irritation nausea dizziness headache weakness fatigue lightheadedness drowsiness Loss of coordination confusion vomiting cramps (These sympshytoms are similar for most organic vapors particularly solvents)
Treatment Mild Exposure - Bring victim to fresh air Rinse eyes and throat if
irritated Heavy Exposure - (victim vomits very dizzy groggy faints etc)
Bring victim to fresh air Evacuate to hospital Prepare to administer CPR
Victim should be monitored for 48 hours in case of a delayed reaction
CONTACT EXPOSURE
Symptoms - Itching burning redness of skin Severe contact exposure for certain solvents will progress to CNS (central nervous system) symptoms similar to those for inhalation
Treatment - Remove contaminated clothing flush with water dry and banshydage Monitor victim for CNS symptoms for at least 48 hours
FIRST AIDSAFETY EQUIPMENT
The following equipment will be stationed at the Hotline or when appropriate down range
- Fully equipped first aid kit - Oxygen bottlekit - Nine (9) Ib chemical fire extinguisher - Eyewash bottle or other pressurized water filled container
11
SECTION 4
OPERATIONS SAFETY PLAN
This section outlines the specifics of safety procedures to be
used during each phase of the operations Safety procedures may be
upgraded or downgraded during site activities pending monitored changes
in the working environment All changes will be in line with the
General Level of Personnel Protection GuidelinesAction Levels for the
Troy Mills Landfill On-Site Investigation as described below
General Personnel Protection GuidelinesAction Levels
An in depth review of levels of personnel protection (LPP) is
presented in Appendix A
Level B (SCBA cotton coveralls or work clothes yellow tyveks (chemical resistant) steel toed rubber boots or work boots with disposhysible over boots and gloves)
Vapor concentrations (as measured on an OVA or HNU 117 EV Probe) greater than 5 ppm above background
- Oxygen deficient atmospheres less than 195
Specific actions (ie excavationsampling of drums) which could initiate a sudden moderate or high concentration of vapor
Level C (full face respirator organic vapor dust combo cartridge tyveks over work clothscoverails rubber safety boots gloves)
Vapor concentrations above an established clean zone backshyground level
During conditions (natural or personnel induced) which result in high levels of dust (visable above background atmospheric concentrations of particulates)
Level C activities require continual air monitoring
12
Level D (cotton coveralls or other work clothes safety shoes and safety glasses when down range Tyveks may also be needed)
Support areas and downrange areas where a higher LPP has not been deemed necessary
Continual air monitoring in downrange areas
Explosive Atmospheres
- 20 LEL (lower explosive limit) as recorded by an explosishymeter Secure and evacuate the work area
Oxygen Deficient Atmospheres
- Less than 195 (by volume) oxygen atmosphere requires upgrading the level of Personnel Protection to Level B
Task Specific Safety Plans
Levels of Personnel Protection indicated for specific tasks below are those which are anticipated to be used Changes in site conshyditions and results of air monitoring may indicate the upgrade downgrade of the LPP
13
Site Reconnaissance (SR) Date Sept 21 1983
Purpose To review on-site conditions and determine LPP necessary for further tasks To evaluate safety hazards Preliminary planning of future tasks
LPP - Initially Level C Updowngrade as necessary
Equipment - OVA HNU (102 ev probe)
Hotline - End of access road Upwind if possible
Command PostFirst Aid - Behind Hotline
Decontamination - Boot wash
Operations
Three man team Two persons advance in front with instrushyments Third person at distance as backup
Team methodically sweeps (criss cross) the proposed work areas with instruments
Specific points of interest (leachate seeps etc) are closely checked
All information is loggedsketch mapped
Upgraded LPP as necessary
14
Task 1 - Magnetic Survey Topographic Survey Date Week of October 3 1983
Purpose - Determine the location(s) and extent of buried drums Provide topographic information for site base map
LPP - Level CD
Hotline - End of access road (upwind if possible)
Decontamination - Boot wash
Operations - SO or other NAI personnel will perform a brief safety sweep of the work area
- Work team will then proceed downrange at the appropriate LPP Using the magnetometer the team will systematically criss cross -the work area
Task 2 - Drum Excavation and Sampling Date Week of November 14 1983
Purpose - Excavationsampling of buried drums in order to characterize the condition of the drums and the nature of the wastes conshytained in the drums and buried in the landfill
Msthod - Backhoe and hand labor will be used to uncover the drums in specified locations Samples will be obtained from spillage or leakage around the drums and of contaninated soil Selected drums which have accessible and openable bungs may be opened and sampled Drums will not be moved or staged Clean drums will be available to receive any significant spillage during the opening and sampling
Specific Hazards - Inhalation of organic vapors - Fire and explosion of drummed waste - Contact with contaminated waste or soil
LPP - Full Level B protection Backhoe operator at Level B Backshyhoe equipped with splash shield and without teeth on bucket
Hotline - At the end of the access road Upwind if possible
Decontamination - Procedures will essentially follow those as outlined by the EPA for Level B work Due to the inaccessibility of the site a field shower will not be available See Appendix B
Safety Equipment - OVA HNU eyewash fire extinguisher oxygen kit first aid kit metal detector non sparking implements
15
Operations - The cover soil is very sandy and the drums appear to be buried close to the surface which should facilitate excavation
- Minimum of 4 man team (exclusive of backhoe operator) Two or three man downrange team for digging and sampling One or two men in supportbackup at hotline
- Personnel will hand dig several small holes to approximately one (1) foot depth in each Location area If drums are not encountered the backhoe will scrape off soil to that depth
- Excavation will proceed alternating hand and backhoe methods At depths below four (4) feet the sides of the pit must be angled back to less than 45deg
- Prior to opening a closed drum the backhoe will nudgebump the drum to check for shock sensitive material An alternate method will be to attach a length of rope to the drum and from a distance pull on the rope to jog the drum
mdash Backhoe The backhoe operator will work at Level B utilizing air supplied from a large cylinder attached to the backhoe The backhoe will also be equipped with a splash shield A scraping bucket without teeth will be used
Prior to backhoe excavation at each location the area where the backhoe will be stationed will be checked for drums which could be ruptured by the backhoe feet
f Excavation areas will be checked for drums utilizing hand excavations or a metal detector prior to removing material by machine
16
SECTION 5
EMERGENCY INFORMATION
Emergency Telephone Numbers
If calling one of these numbers please state NAME LOCATION
and type of PROBLEM
Local Emergency Support
Fire Department (Troy 242-7759) For all emergencies use
Ambulance 352-1100 Mutual Aid (Keene) 352-1100
Police Department (Troy 242-7992)
Hospital 352-4111 (Cheshire Hospital in Keene)
Town Clerk 242-3845 State Agencies
NH Bureau of Hazardous Waste Management 271-4608
NH Water Supply and Pollution Control Commission 271-3503
NH Fire Marshall Office 271-3336
NH State Police (24-Hour Dispatch) 1-800-852-3411
Other
US EPA (24-Hour Hotline) 617-223-7265
Poison Center Mary Hitchcock Hospital 1-800-562-8236
Route to Hospital
- Follow dirt access road to Bowkerville Road - Left on Bowkerville Road to Rt 12 - Left (north) on Rt 12 through Troy to Keene NH - At major junction of Rts 9 10 101 and 12 go straight through
into Keene - At common go half-way around and go right on Court Street - Hospital is at 580 Court Street
17
Contingency Plan
Signal - five (5) one second blasts of auto or air horn Action - All personnel immediately excavate dovmrange areas and
report to Hotline for instructions
Personnel Unexplained Fire (if small) Accident (serious) Collapse of Personnel
Evacuate area Emergency ^ ^Evacuation Evacuate Area
First Aid
Estimate Explosion Level B (for Potential Contact Outside Help evcavation)
Evacuate Victim i If
Level B Prepare for Transportation
1 First AidCPR Use extinguisher Transport
Contact Outside Help Notify Coup any Have Proper Information Personnel (see below) 1
Transport
Call Fire Dept (if necessary)
For Hospital Victim
- Name and Phone of family physician
- Description of Incident chemicals involved symptoms nature of injury proposed treatment and plan of transportation
18
APPENDIX A
LEVELS OF PERSONNEL PROTECTION
Because of the possible dangers of exposure to toxic or harmshyful chemicals protective equipment must be worn during work on hazardous waste sites Levels of Personnel Protection (LPP) describe respiratory clothing and other equipment necessary for protecting personnel against expected hazards
The descriptions below are for full dress at a given LPP where hazards are expected to be at a maximum for which the given LPP is conshysidered adequate Depending on site conditions and work activities the clothing and dress requirements of a given LPP are commonly modified
LEVEL A
1 Personal Protection Equipment
Positive Pressure SCBA (MSHANIOSH approved) Operated in the positive pressure mode
Totally Encapsulating Suit (boots and gloves attached)
Gloves - Inner (tight fitting and chemical resistant)
- Boots - Chemical - protective steel toe and shank Depending on suit boot construction worn over suit boot
- Gloves shy Outer chemical-resistanttion worn over suit gloves May bchemical-resistant gloves worn insid
Dependinge replaced withe suit glo
on s
ves
uit construcshy tight-fitting
- Underwear shy Cotton long-John type
- Hard Hat (under suit)
- Disposable protective suitover encapsulating suit)
gloves and boots (Worn under or
- Coveralls (under suit)
- 2-way Radio Communications
Optional
19
2 Criteria for Use
A The type and concentration of toxic substances are known and require the highest level of combined protection to the respirashytory tract skin and eyes These conditions would be
1 Atmospheres which are immediately dangerous to life and health (IDLH)
a IDLHs can be found in the NIOSHOSHAs Pocket Guide to Chemical Hazards andor other references
2 Known atmospheres or potential situations that would effect the skin or eyes or could be absorbed into the body through these surfaces in toxic quantities
a Potential situations are those where vapors may be generated or splashing may occur through site activities
b Standard reference books should be consulted to obtain concentrations hazardous to skin eyes or mucous memshybranes
3 Oxygen deficient atmospheres with above conditions
3 At sites where the type andor potential concentration of toxic substances are unknown
1 Unless circumstances strongly indicate otherwise the site should be presumed to present hazards to the respiratory system skin and eyes Level A protection would provide the highest level of protection for the initial entry team
a Such circumstances might be
1 Environmental measurements contiguous to the site
2 Reliable accurate historical data
3 Open unconfined areas
4 Minimal probability of vapors presence or splashing with cutaneous effecting substances
2 Enclosed areas such as buildings railroad cars ships holds etc
20
LEVEL B
1 Personal Protective Equipment
Positive Pressure SCBA (MSHANIOSH approved) operated in the positive pressure mode
- Hooded chemical-resistant suit
Gloves - Outer chemical-protective
Gloves - Inner tight-fitting chemical-resistant
Boots - Outer (chemical-protective heavy rubber disposables)
Boots - Inner (chemical-protective steel toe and shank)
2-way Radio Communications
Hard Hat
Face Shield
2 Criteria for Use
A The type and concentration of hazardous substances are known and require the highest degree of respiratory protective but a lower level of skin protection
1 Atmospheres which are immediately dangerous to life and health (IDLH) Type and concentration of vapors in air do not present a hazard to the small unprotected areas of the body
2 Atmospheres with concentrations of known substances greater than protection factors associated with full-face air-purifying respirators with appropriate cartridges
3 Atmospheres with less than 195 oxygen
B When a determination is made that potential exposure to the body parts not protected by a fully encapsulated suit (primarily neck ears etc) is highly unlikely
1 Known absence of cutaneous or percutaneous hazards
2 Activities performed preclude splashing of individuals
C Level B protection is recommended as the lowest level of protecshytion for initial entries until the hazards have been further identified and defined by monitoring sampling and other reliable methods of analysis and personnel protection equipment commensurate with these findings utilized
21
LEVEL C
1 Personal Protective Equipment
Full-face or half-face air purifying respirator (MSHANIOSH approved)
Chemical-resistant clothing
Gloves - Outer (chemical-protective)
Gloves - Inner (tight-fitting chemical-resistant type (or woven liners)
Hard Hat (face shield optional)
Boots - Outer (chemical-protective heavy rubber throw aways)
Boots - Inner (chemical-protective steel toe and shank)
2-way radio comnunications
Safety glasses required with half-face respirator
2 Criteria for Use
A Site known to contain potentially hazardous materials exceeding
1 Air concentrations requiring a protection factor no greater than that afforded by a full-face mask
2 Harmful levels to unprotected body areas (face neck etc)
3 Well-documented reliable history of site and patterns of prior entry
C No evidence to suspect acute or chronic toxicity to exposed personnel
D Continuous air or personnel monitoring should occur while wearing Level C protection
22
LEVEL D
1 Person Protective Equipment
Chemical resistant aprons
BootsShoes - Safety or chemical-resistant steel toed boots
Boots - Outer (chemical-protective heavy rubber throw-away)
Half-face respirators immediately available
Safety glasses or safety goggles
Gloves
2 Criteria for Use
a No indication of airborne health hazards present
b No gross indications above background on the photoionizer andor organic vapor analyzer
c Continuous air or personnel monitoring should occur while wearing Level D protection
23
APPENDIX B
DECONTAMIHATION PROCEDURES
Depending upon activities and location on site it may be
necessary for personnel to decontaminate prior to leaving the conshy
taminated zone Procedures described below are typical for Level C
operations
Upon exiting downrange (contaminated) areas all personnel are
required to decontaminate by means of the following procedure
1 Place equipment in the Drop Zone at the Hotline
2 Enter the Decontamination Station
Boot Wash Walk through wash tub and scrub boots then rinse boots in second tube
Glove Wash In two pan wash scrub over gloves rinse set out to dry
2 Remove tyvek - if leaving the contamination reduction zone (CRZ) and proceed to clean zones
3 Dispose of heavily contaminated clothing and under gloves
4 Remove respirator
5 Use disposable gloves to clean equipment
6 Use a two bucket (washrinse) to decon respirators at the end of the working day or if they become heavily contami nated
The procedures for a typical Level B Decontamination are
outlined on the following page
TANK CHANGE 9
CONTAMINATION REDUCTION
ZONE
OUTER GLOVE REMOVAL
EXCLUSION ZONE
TAPE REMOVAL
BOOT COVER
GLOVE WASH
(bull)mdashQ-G--copyshySOOT COVEH SCOT COVES 4
REMOVAL GLOVE RINSE
SUITSAFETY BOOT WASH
SU1TSC8A78OOTGLOVE RINSE
SAFETY BOOT 10 REMOVAL
SCSA BACKPACK REMOVAL
SPLASH SUIT 12 REMOVAL
INNER GLOVE WASH
INNER GLOVE RINSE
FACE PIECE REMOVAL
INNER GLOVE 16 I REMOVAL
INNER CLOTHING REMOVAL
FIEUJ 19 REDRESS WASH
SEGREGATED EQUIPMENT
OROP
mdash -HOTLINE-shy
DECONTAMINATION LAYOUT LEVEL B PROTECTION
FIGURE A2-1
CONTAMINATION CONTROLLING
SUPPORT ZONE
25
APPENDIX C
PERSOHNEL AND RESPONSIBILITIES
Project Manager (PM)
Overall responsibility for all Project activates budget
schedule investigative operations safety personnel
On Site Coordinator (OSC)
Responsibility for activities at the site Primary responshy
sibilities include
1) Interfacing with the client state EPA media or other groups
2) Reviewing technical operations
3) Reviewing site safety in particular information supplied by the Site Safety Officer
4) Enforcing site safety and compliance with the Safety Plan
5) Directing Emergency Contingency operations
Safety Officer (SO)
Responsibility for directing the safety of operations and impleshy
menting the Safety Plan Specific responsibilities include
1 Assuring that appropriate personnel protective equipment is available and properly utilized by all site personnel
2 Assuring that personnel are aware of the provisions of this plan are instructed in the work practices necessary to ensure safety and in planned procedures for dealing with emergencies
3 Assuring that personnel are aware of the potential hazards associated with site operations
4 Supervising the monitoring of safety performance by all pershysonnel to ensure that required work practices are employed
26
APPENDIX D
PERSOHHEL CASUALTY
Personnel casualty would most likely result from either chemical
contamination heat-related problems physical injury from accidents
(ie falling lacerations etc) in performing the work or a comshy
bination of one or more of the above The appropriate action depends on
the type of injury involved with the priority being to assist the
casualty as soon as possible without endangering other personnel
Riysical and heat-related injuries can and should be treated
immediately with appropriate first-aid measures and follow-up medical
attention if necessary The injured worker(s) shall immediately move
out of the hot zone or if necessary be moved out by fellow workers as
soon as possible The OSC and Safety Officer shall be notified immeshy
diately and shall recommend further measures as needed
Chemical-related injuries require a much more cautious approach
so as to keep casualties to a minimum If a worker injured by chemical
ejqgtosure is able he shall notify the nearest co-worker and leave the hot
zone immediately- The co-worker shall ensure that the OSC and Safety
Officer are immediately informed and shall accompany the casualty from
the hot zone to the decontamination zone The OSC and Safety Officer
shall determine the appropriate measure
27
APPENDIX E
GUIDELINES FOR SITE OPERATIONS
In order to deal with the potential dangers of exposure and conshy
tamination of a hazardous waste site three zones are delineated
according to the degree of hazard The three zones are 1) Downrange
or Contamination Zone 2 Contamination Reduction Zone (CRZ) 3) Support
or Clean Zone
Downrange or Contamination Zone
The Contamination Zone is the active work area of the site which
encortpasses the areas where there is a potential for exposure and in
which investigative activities will occur (drilling sampling etc)
Within the Contamination Zone the designated level of hazard will be
established necessitating the utilization of personnel protective
equipment
Hot spots are those areas Downrange where observations instrushy
ment readings or specific activities indicate a high probability of
closure or contamination and may require an upgrade in the LPP in the
vicinity of the Hot Spot
Contamination Reduction Zone
The CRZ is an area between the Downrange and Support Zones where
decontamination of equipment and personnel occurs
28
Personnel entering the CRZ shall wear protective clothing and
carry the respiratory protection required for entry within the
Contamination Zone
Personnel working within the CRZ shall remain cognizant of the
CRZ in order to be prepared for any need to increase their level of proshy
tection within the CRZ
A decontamination station will be located at the outer perimeter
of the CRZ All personnel who have been within the Hot lane shall pass
through a decontamination procedure prior to re-entering the Support
Zone
Support or Clean Zone
The Support Zone is the outer area and may be considered to be
clear of contamination potential The command post will be located
within the Support Zone
a) The Command Post will serve as the OSCs headquarters and
will be equipped with
1 Communications
2 Safety Plans
3 First Aid Supplies
4 Analytical Equipment
5 Safety Equipment
APPENDIX B
WORK PLAN
WORK PLAN FOR
TROY MILLS LANDFILL TROY NEW HAMPSHIRE
DRUM EXCAVATION AND SAMPLING
Prepared by
NORHANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
1933
WORX PLAN FOR
TKOt MILLS LANDFILL TROT NEW HAMPSHIRE
DRUM EXCAVATION AHD SAMPLING
DATS November 16-18 1983
PURPOSE
To determine the condition of drums (ie erroty or full
crushed rusted leaking etc) buried in the Troy Mills Landfill To
obtain representative samples toward identifying the types of materials
buried in the landfill This information will be used in the detershy
mination of the level of remedial action needed at the site
METHOD
Using the results of the magnetometer survey the (10) points
have been randomly chosen across the area where the buried drans are
expected to be found Each point is central to an Excavation Location
-- an area four (4) to six (6) feet in diameter which will be excavated
in order to characterize the condition of the drams and to obtain waste
sarples
Preliminary observations have indicated that many of the drums
may be buried within 1-2 feet of the surface Therefore the investigashy
tion will proceed in two phases
Phase 1 mdash Hand Excavation By digging several small holes in
each Location personnel will determine if drums are located within
about one to two feet of the surface If drums are encountered the
excavation will proceed by hand uncovering the dnris for evaluation and
sampling Where drums are not encountered near the surface excavation
at this location will be postponed until Phase 2
Phase 2 mdash HandBackhoe Excavation After all Locations have
been attempted during Phase 1 those Locations in which drums were not
encountered wall be further excavated using a combination of hand
backhoe digging
It is expected that one to two days will be necessary to
cor^piete each phase Depending upon the results of Phase 1 it may not
be necessary to iroleraent Phase 2
Spare drums will be on hand for containerizing any significant
spillage resulting from sampling efforts Excavation locations will be
identified with marked stakes and the holes will be backfilled at the
conclusion of the investigation
SPECIFICS
Excavation Locations (Holes)
Number of proposed excavations is ten (10)
Locations of excavations are presented in Appendix A
Hole Size mdash It is expected that a hole from four (4) feet to six (6) feet in diameter at the bottom (depth at which drums are encountered) will be sufficient to characterize the drums at each Location Deeper excavations will require increasingly large top diameters
Hole Depth -- Holes will be excavated to a maximum depth of six (6) feet Due to the sandy cover material the excavation of deeper holes is probably impractical from both safety and efficiency stand points
If after attempting excavation at each of t-ie 10 proposed
1ocatiors irums are not encountered within six (6) fet of the surf ice
in enough locations to characterize the site excavations nay be
attempted to depths greater than six (6) feet if scil stability permits
or a new set of sampling locations may be chosen
(Excavations to depths greater than six (6) feet require a
significant increase in work The sides of the hole crust be graded back
to less than 45deg in order to insure the safety of investigatorysampling
personnel It may also be necessary to employ bracing bulkheads etc
for trench support)
Excavation Identification
Proposed excavation Locations have been consecutively numbered
from 1 to 10 beginning at the east end of the landfill They will be
marked with numbered stakes
Excavation Methods
Phase 1 mdash Within each Location personnel will dig a nunber of
small holes - about one (1) foot in depth - to probe for drums If
druns are encountered they will continue to excavate until the drur3
are sufficiently uncovered for characterization
Phase 2 mdash After hand probing the Location with snail holes
the backhoe will remove cover material to the one (1) foot depth The
Location will then be probed to a two (2) foot depth before removing
further material Excavation will proceed alternating handprobing and
backhoe excavation until drums are encountered or the maximum six (6)
foot depth is reached
If excavations to depths greater than six (6) feet are undershy
taken they will proceed using the above method
Santnlea
Due to the effort involved in excavating and because conshycentrated waste samples are not expected to undergo rapid degradation it is considered expedient to obtain all readily available samples (exclusive of closed drum samples -- see belcw) These can then be submitted for laboratory characterization as determined by need and budget restrictions
An attempt will be trade to secure at least one sample froa each excavation in order to help characterize the distrishybution of waste materials across the site An attempt will also be made to secure samples of observably difshyferent materials
Sample Types and Mediums - Solid liquid and sludge samples are possible Samples will be obtained from in order of preference -- 1) leakage uncontainerized waste or contaminated soil 2) waste contained in open conshytainers - drum already has a hole or no top or other access point 3) sealed containers
The opening of closed containers will be considered if it is decided that it has not been possible to obtain a sufshyficient number of representative samples from the other mediums
Each sample will consist of two (2) 8-oz jars (with teflon-lids) filled about 23 full One jar will be for organic analysis and the other for inorganic analysis
Sanole Identification - Samples will be identified with a number corresponding to the Excavation Location and a letter Example if three samples were obtained from Location 2 they would be samples 2A 23 and 2C and Samples 2Ad 23d and 2Cd for duplicates
Sampling Methods and Volumes - 11 mm hollow glass tubing trowels disposable scoops will be available to obtain samples Samples tools will be disposed of or deconshytaminated between each sample
Drum Samples - If necessary an attempt will be cude to obtain samples from sealed drums Oily o^und non-rusted drums will be considered Bunjs rust be xn suitable conshydition -jo that the dram cm be openoi withrut cvis ing dainai -ind ca-i be resell od to pr-jvcrt l V-i 30
There wil l be no staging or movement of drums in order to faci l i tate sampling Only drums with accessible bungs will be considered for sampling
Procedure for Drum Sampling
1) Excavate around top of drum
2) Monitor air in the adjacent area
3) Chec for shock sensitive - Loop rope around top of drum stand at a distance give drum several hard jogs by pulling on the rope An alternative nethod is to lightly jog the drum with the backhoe bucket
4) If the drum is not upright place a catch basin under the bung
5) Open drum with bung wrench
6) Monitor the air atin bung
7) Sample drum -- liquids insert glass tube the fu l l length into the drum in order to obtain a column of the materials in the drum Solids use scoop to dig out material through the bung or use a sampling trowel
3) Reseal the dram
Spill Control
The possibility exists during the sampling and excavation for a
drum to be ruptured or otherwise have spillage Clean drums wil l be on
hand to receive significant spillage resulting frora sampling or excavashy
tion They will not be used for clean up of widespread uncontainerized
waste or existing leakage
Personnel
The work team will require four (4) persons (exclusive of the
backhoe opera tor) Trie downrange team will consist of three (3) persons
-- two (2) for d igg ing and sampl ing and on ( 1 ) for logging air moni shy
toring and photographing One (1) person will be at the hotline in
support mdash as safety backup person to fill air bottles to deconshy
taminate samoles to assist in decontamination of personnel
Documentation Logging
The following information will be recorded at each location
nmber of drums uncovered and the condition (crushed empty rusted
sealed etc) of each drum evidence of spillage or contaminated soil
labels on uncovered drums samples (time drum ID type description)
periodic air monitoring information depth at which specific events
occur or drums are buried soil condition presence of ground water
In addition photographs will be taken of specific events or
items of importance during each excavation and of each sampling incishy
dent The time description of subject photographer excavation
location and photo number will be logged for each photograph
Analytical Laboratories and Schedule
RAI Hampton NH
Initial schedule
Ten samples for GCrns for organic priority pollutants Samples may also be submitted for inorganic anlaysis or volatile organic analysis depending upon waste materials observed during the excavation
APPENDIX A
TABLE A-1 EXCAVATION LOCATIONS
EXCAVATION BASELINE RANDOM RANDOM
NUMBER GRID COORD SEGMENT STATIOH OFFSET
1 7E+1 565N 0- 60 26 (25) 16
2 9E+5 13S 60-120 50 (110) 9
3 8E+0 31S 120-180 20 (140) 7
4 4E+5 483 180-240 50 (230) 25
5 3E+3 45S 240-300 14 (254) 20
6 OE+6 5S 300-360 34 ( 334) 50
7 2W1 5 24N 360-420 45 (-155) 14
8 5W+6 42N 420-480 38 (518) 20
9 6W+1474N 480-540 8 (543) 7
10 8W 5 11011 540-600 11 (611) 31
Locations are plotted on Map A-1
Method of Choice A stratified random sampling method was used to choose 10 Excavation Locations within the magnetic anomaly
The axis of the magnetic anomaly was used as a base line and divided into ten 60 foot long segments Using a randora nirnbers table a distance along each secpent was chosen (Random Station) and a line drawn at that point perpendicular to the base line Again using a random numbers table a distance was located along each perpendicular line by measuring inward from the line denoting the edge of Area A (Random Offset) The Grid Coordinates for each of the Excavation Locations were graphically determined from the grid overlay (this overlay has been surveyed and intersections field located)
It was judged that 10 excavation locations within the magnetic zone and two outside of the zone would be sufficient to characterize the area would produce statistically valid iati and coli be expected to be co~letod within 2-3 days work period
to
80
cu0
cgtc
APPENDIX C
MAGNETIC INVESTIGATION TROY MILLS INC LANDFILL SITE
TROY NEW HAMPSHIRE
For
NORMANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
By
JOHN F KICK PhD GEOPHYSICIST
Box 6 Dunstable Massachusetts 01827
(617) 649-6650
Noverber 19S3
MAGNETIC INVESTIGATION
TROY MILLS INC LANDFILL SITE
TROY NEK HAMPSHIRE
INTRODUCTION
A high resolution ragnetic investigation was completed on the Troy
Mills Inc landfill site in Troy New Hampshire by John F Kick
Consulting Geophysicist The purpose of the investigation was to
delineate the extent of buried steel drums under closed portions of the
Troy Mills landfill The information is needed as a part of a study of
the landfill that is being conducted by Normandeau Associates Inc
FIELDKORK
Magnetometer measurements of total field intensity were made over an
area that was reported to contain buried steel drums and adjacent
landfilled areas that contained unknown waste materials The area of
investigation included capped and grassed closed areas along the south
margin of the landfill site and adjacent areas The fieldwork was
performed during October of 1983
Eighteen parallel rows of measurements were conducted along north-
south lines (using magnetic compass directions) A spacing of 20-feet
was used between rows and magnetometer measurements were made at 10-foot
intervals along the rows Greater intervals between measurements were
used at the ends of the rows and in periferal areas with low magnetic
-JF Kick 01shy
field gradients
A series of magnetic field measurements were made at an adjacent
base station throughout the survey to torn the basis for a daily
variation curve The base station was located at a site with typical low-
gradient background magnetic field intensity measurements
MAGNETIC SEARCH METHOD
Theory Magnetic search methods involve the detection and
measurement of anomalies in the Earths magnetic field caused by the
presence of materials with contrasting magnetic susceptibility Iron and
steel objects generally have very high magnetic susceptibility contrasts
with usual surrounding materials and therefore produce magnetic
anomalies The amplitude shape and detectable distance of the anomaly
depend mostly on the particular susceptibility contrast and size of the
object Magnetic anomalies are measured in units called gammas The
normal magnetic field in this area is over 50000 gammas A 5-inch
screwdriver will produce an anomaly of 5 to 10 gammas at a depth of 5
feet and an anomaly of 1 gamma at a depth of 10 feet A 1 ton automobile
will produce an anomaly of 40 gammas at a depth of 30 feet and an anomaly
of 1 gamma at a depth of 100 feet The magnitude of an anomaly caused by
a single steel drum will vary with its condition (new heavily rusted
etc) Tests using a single light weight (somewhat rusted) drum on the
surface with the magnetic detector at a height of of 12 feet produced an
anomaly in the range of 40 to 50 gammas
Total magnetic intensity disturbances or anomalies are almost always
asymmetrical sometimes appear complex even from simple sources and
usually exhibit the combined magnetic effects of several sources which
can produce a given anomaly The apparent complexity of such anomalies
is a result of several relatively simple functions of magnetic dipole
-JF Kick 02shy
behavior Reasonable assumptions about the geology and buried source
conbined with an understanding of magnetic dipole behavior can usually
lead to a satisfactory qualitative interpretation More detailed
interpretations nay require modeling studies
Instrumentation Field equipment on this project included a EGampG
Geometries Memory-Mag G-856 proton precession magnetmeter The
instrument has a resolution of +01 gamma The magnetic field detector
is separate from the rest of the instrument and is mounted on an 8-foot
staff to provide measurements that are a constant height above land
surface
Magnetic Data Analysis For the purposes of data reduction and
anomaly delineation it was assumed that base station total field
intensity measurements were typical background values for the site
Measurements made at frequent intervals at the base station were used to
prepare a diurnal variation curve for the site Anoraly values were
obtained by subtracting background values from the base station curve
from measurements collected in the area of investigation
RESULTS
The reduced results are presented in the form of a magnetic anomaly
contour map (Figure 1) and two profiles across the area of investigation
(Figures 2 and 3) The map and profiles show that very steep magnetic
field gradients and large departures form background occur in an
irregular shaped band that is about 460 feet long and ranges from about
30 to about 200 feet in width The magnitude of the anomaly is such that
a significant deposit of ferromagnetic materials (such as steel drums) is
indicated
In using the plotted magnetic results it should be noted that the
greatest concentrations of ferromagnetic materials probably do not
-JF Kick 03shy
directly underlie the peak magnetic anomalies A shift is caused by the
inclination of the Earths magnetic field and by the dipolar nature of
ferromagnetic deposits The inclination of the Earths field is about 76shy
degrees northward in the vicinity of Troy The dipolar effect is induced
by the Earths field and results in negative anomalies immediately north
of large positive anomalies
Magnetic Anomaly Map The magnetic anomaly map (Figure 1) indicates
10 positive peaks of varying size shape and intensity Associated
negative anomalies of a broader and less intense nature lie immediately
north of the belt of positive anomalies The configuration of the
anomalous area is indicative of lense-shaped and cigar-shaped bodies of
ferromagnetic materials Steep-sloped anomalies are indicative of very
shallow source materials The thickness of the ferromagnetic deposit
cannot be easily determined on the basis of intensity and size of
anomalous peaks because a small mass of iron or steel at the surface can
duplicate the anomaly caused by a much larger mass at depth The
ferromagnetic source materials can generally be expected to lie north of
the positive peak of anomalies and south of the adjacent negative
anomaly Modeling can provide the best approximations of the depth and
density of the ferromagnetic source materials The outer boundaries of
the source materials can be expected to overlap the positive peak and
negative anomaly somewhat depending on the depth and configuration of
the deposit
For illustration purposes two north-south rows that were profiled
are discussed below
Magnetic Anomaly Along Row 9-East Two strong positive magnetic
anomalies (3645 and 2436 gammas) and adjacent negative anomalies were
profiled along Row 9-East (Figure 2) The approximate centers of the
ferromagnetic deposits are believed to underlie stations 50 north and 75
feet south of the base line The rounded shape of the north positive
-JF Kick
anoraly nay indicate somewhat deeper burial of the ferromagnetic deposit
Magnetic Anomaly Alone Row 7-West Figure 3 shows the most intense
positive magnetic anomaly (4470 gammas) that was detected on this
project The steepeness of the slopes is indicative of very shallow
source materials An uneven burial pattern is suggested by the two-
peaked positive anoraly The negative anomaly south of the two peaks is
unusual and may be related to another positive anomaly to the southeast
(along Rows 5 and 6 20 feet north of the base line) The centers of the
sources of the positive anomalies are probably approximately 80 and 120
feet north of the base line along Row 7-West
-JF Kick 05shy
DISTANCE FROM BASE LINE(FEET)
CO
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6a
CO
LU CD
o cr CD o lt
i-mdash LU Lu 2 Q lt2 Z
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CsJ
LU aIDCD Li_
SVWWV9 N A1VWONV
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SVWWV9 NI A1VWONV
t o H
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D 8 j~ 00
UJ UJ en UJ u UJ
o ui o CC
CO
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UI o
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0020
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ro 8 LU
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APPENDIX D
LABORATORY ANALYSES
RAI
Resource Analysts Incorporated Box 4778 Hampton H 03842
(603) 92^7777
TO PO 830318
Mr Doug DeNatale Date Received 12-2-83 Kormandeau Associates 25 Nashua Road Lab Number 2887 Bedford NH 03102 J
Date Reported 1-3-84
IDENTIFICATION
SAMPLE DESIGNATION PARAMETER
Volatile Organics Analyses by EPA Method 624
Acid and BaseNeutral Extractable Compounds Analyzed by EPA Method 625
Metals Analyzed by Standard Methods 303A
Please see attachments for all results
Results expressed in mgL unless otherwise designated lt = Less Than
ClarkeFosterVan K o u w e i b r h 1 ANALYST DIRECTOR
METHODS Standard Methods (or the Examination ol Water and Waitewaler 15th Edition or other EPA approved mtlhodologiei unless otherwise designated
Phys ica l descr ip t ion of sample
LiquidSludop
Saiple workup
Volitile f ract ion Methannl F-1-rarMrm CSVJ Rdfi-Smm
Semivolatile f ra ictio0onication Extraction fSW 846-3540^ Inorganic f rac t on Acid Digestion (SW 84h-iOS(V)
ACS3 COMPOUNDS
rr t CAS CAS
(71 A) tt-Ot-2 i^t TT i^MoroprvrfgtOi (73B) 30-32-1
(23 A) J9-JO-7 ^bull^^ lof o^^ft^crt gto (7 OB) 205-M-2
(2 A) 13-37 -J 2- chlorophenol (75B) 207-01-
(3 A) 120-13-2 2raquo^icMoroorgtenol (748) 211-01-9
(MA) 103-47-9 2-dimethv lohenol (77 B) 201-94-1
(37A) U-73-3 2- niiroDhenol (7IB) 120-12-7
(MA) 100-02-7 raquo-niiroprienol (7raquoB) lraquol-2raquo-2
(raquoA) Jl-21-3 2 - in i tr opheno 1 (106) raquoi-73-7
(40 A) 33-J7-l k4-dinnro-2-mlaquothylplaquogtergtol (I IB) 15-01-1
(4A) I7-U-3 (xntictiloroorraquonol (I2B) J3-70-3
USA) 101-93-2 pxmol (I3B) 193-39-J
(14 B) 179-00-0 RASENEUTOAL COMPOUNDS
( I B ) 13-32- raquocmlaquophtgtgtefgtlaquo
(36) 92-173 benzidine (2V) 107-02-S
( I B ) I20-I2-I l2t-tricMorobenzlaquonlt (3V) 10713-1
OB) 111-71-1 he laquo laquoch 1 or o benz erve (laquoV) 71-A3-2
(176) 47-72-1 hetraquocWoroltthlaquone (4V) X-23-5
U S B ) 111-- bu(7-cloroetrivl)ether (7V) 101- 90-7
(7CB) 9 I -3J -7 2-Chlororuprthraquolene (10V) 107-04-2
(73B) 95-50-1 l2-diCMoroblaquonzene ( I 1 V ) 7|3j^
( K B ) XI-73-1 13-didilorobtnzene (13V) 7J-3-3
(27B) 104-M7 1tmdash djcMorobenzene dkV) 79-00-3
C2IS) 9i9i-l 33-dictgtloroblaquoazidinr ( I JV) laquo-3-J
(33B) 12I -U-7 2gt-dinicrotoluer (14V) 7J-00-3 (KB) 4O4-7C-7 24-dinitrotoluene (UV) 110-73-1 (J7B) 122-A4-7 1J -diprienv lhydrraquo z irf (23V) lt7 tt 3
(MB) Z0-fc-0 UuorraquonThelaquo (2raquoV) 7J-35-
(W551 700J77-3 -ctilorophenyl prlaquonyl ether (JOV) 1M-40-3
( raquo I 6 ) 10I-J3-3 raquo-6romoprgtefgtyl prtenyl ether (32V) 71-17-3
(raquo7B) 33132-9 bU (2-cMorobopropyl) ether (33V) 10041-02-4
(raquoJ6) i l l -91- l bu (2-laquo^loroeTho)ry) methane 10041-01-03
(B) D-U) hexraquopoundj1|orobutaltlicne (31 V) 100--
(33B) 77-raquo7- heiKCtilorocycIopentadicrve (WV) 7J-CT-2
OB) 7IJraquo-I traquoo oh or or (raquo3V) 7raquo-17-3
(J3B) gtl-20-3 nphthraquolene (UV) 7raquo-I3-9
(546) n-tj) nitrobenzene (7V) 7J-2J-7
(426) U-Xl-4 bullJ -n itr o tod iphenyU mi ne (UV) 75-27-J
(OR) 421-W-7 N-oitrcnodipropYlirrUne ^raquoraquoV) 73-49-k
(446) I 1 7 J I - 7 bu (2-eltr^lheryl) phtfaUte 8200 (3ov) 73-71-1
(476) 13-U7 benzyl buryl phttwlite (51V) 124-kt-l
( U B I M-71-2 di-fl-utgtl pMhUre (13V) 177-II-
( lraquo6) 117-1 -0 dj-n-octvl prithlaquoUte (UV) 101-IS-3
(7CB) W-44-2 dielhvlphtraquollaquo (17V) 79-OI-t
( 7 | B ) I 3 I - I I - J dj^laquorTvipnthraquoUtr (UV) 7J-OI- (776) H-J5-5 bnro(raquogtnthrraquocefvr
Iab I D N o 2SS-10
C l ien t ID 1A64223
RASENEUTRAL COMPOUNDS
bfzoltraquogtprrene
benzoltb)flucrraquornNene
benio(llaquo)fluorraquonthene
chryiene
bullcenaDhthvien
raquontnrraquoctne
benzoltghi)perrlefgte
Iluorene
phergtraquonthrmlaquo
dibenzoltraquoMaithrraquocenraquo
indeno(123-cd)pvrene
prrene
VOLATHES
(frolein
bullcrvlooitrdf
benien
orbon Temchloide
CMorobeniene
1 7-dJchlorolaquothnr
111-trieftloroethine
ll-ltJichloroetrufle ll7-triCilorigtetMrlaquor
l127-tetrraquocMorothfllaquo
chloroethlaquo-e
7-dMoroeThraquo|virgtvl eirwshy
chloroform
11-didMoro^tfwnr
trinj- 1 2-dictMorolaquoirgtene
1 7-ltlicMoroproplaquorve
trini- 1 3-ltJichloroorcrpeoe
cu-lJ-lieMorocT oo eashy
rthy Uveniene
methrlene chloridf
chloromethine
bromome thraquone
bro mod iCTi lore met Mrgt
(Juorotr ichloromthraquor
di cMlor od 1 f 1 uore ngtet hj^gt
chloreltJbnjmomethne
te tr ten 1 or oet rx-r
laquouene 12000
tncMeroethe^e
Cidrr ium Chromiutr 10
All results are expressed as ucg veicht as received Nc ertrv denotes -0r ~ ^ 1 i rt
P h y s i c a l d e s c r i p t i o n of
SoilSludge
sample
Sanple workup
Vol i t i le f ract ion p^r Exf- rar r ion fST7Semivola t i le f rac t ion So^h^Pt Fgtr f ra r f ion
846-SOTO^ (SWRdfi-^SiO1)
Inorganic fract ion Ar id nio-psrirm
AOD COMPOUNDS
m CAS (2i A) tt-04-2 2raquot- Wichlorophenol
(22 A) J1-50-7 p-cfi I or o-n-cre laquoo 1
(2A) 13-57-1 2- ctiloroprienol
O iA) 120-13-2 2raquo^icMoroprnol
(gtraquoA) 103-47-1 2f 4mdash^imetSv Ip^enol
(37 A) U-73-3 7mdash Ti j oprtenol
(JraquoA) 100-07-7 mdash mdasho i Br opr^e no 1
JJ1A) 31-21-3 if mdash4 irtiTroprienol
(40A) J34-32-1 4 T4-4initrogtmdash 7 nte tny Ipnenol
(4A) f y _H 5 plaquontchlaroorwnol
(43A) J 01-95-7 prienol
rV ipoundNEUTRAlaquo- COMPOUNDS
( I B ) raquoJ-32-raquo
(3B) 17-17-5
( IB) 170-12-1
(IB) 1I1-7I-I
(17B) 4777-1
( I t B ) 111--
(20B) 11-31-7
(236) 15-50-1
(245) 51-73-1
(77B) 104-4-7
(285) 11-14-1
(336) 121-142
(34B) 404-70-2
(J7B) 127-M7
O1B) 2O4--0
(406) 7003-72-3
(416) 101-35-3 lt raquo 2 6 gt 3H3I32-1 ltraquo36) 111-11-1 (57B) S7-U-3
(336) 77 -raquo7-
(36) 71-31-1
(33B) 11-20-3
pound34 6 1 n-i33 (UB) tt-30-4
(436) CI-44-7
(4461 117-11-7
(47B) U-417
( U B I 14-747
(U6) I17_t-0
(7CS) l-laquo2
(7 I B ) t J U t l - gt
(7761 54-55-3
CT-~- i_i w i Miirn 0
resul ts
b^TMdint
1 2 t-o- icn lorobenl ergtlaquo
SeTraquochloroblaquorierraquoe
hrxchlorolaquotSlaquone
bu(2-chloroethv|gtether
2 -lt3M or onraquo ph ti1 ene
1 2-ltJictilorotgtmzcne
13-dicWorotxerzene
1 4-djch 1 or otxn z ergte
33-ditfgtlorolgtlaquoniidirraquo
24-dinitrotoloene
2 4-dtnitro toluene
U-dlpoenylfiydrraquoiilaquo
(luoranthene
raquo-cfJorophenyl poenyl ether
Mx-omopfieflyl phenyl ether
bis (2-cMorooopropyt) ether
bu (2-ctilorcxtSorv) meiSkte
hezkOilorobutadicne
hei acM or ocyc1 ofMn udi cne
oo prior one
nphthlene
nurotxniene N -ni tro Kxd ipoenyU mi ne
N-rutrowxhpropYUmJrw
bu (2-thylherl)(gthlaquoiraquoUtraquo
blaquoniyl buryl phtfraquolaquoUte
dt-^t-^xjrvl pfttfuiLitY
dj-n-octyl pitflaquoLitraquo
dirthvl phtruUtt
OArriett^vt prraquoT^Lraquot
bnzoltklaquonihnicer
22 Chronium
ire ev^rescei as uc ^ ^i-~ht-
Lab 1U N o 28B-1
C l i en t I D 1 R R 7 A A R
RASpoundNEbTRAL COMPOUNDS
benroltb)fluorraquorgtthfflf
benzoraquollt)fluor intone
ltrylaquo-gte
bullcenioithylen
raquomtirraquoenlaquo
ben z oltxh i)per v lene
lloorene
poentnthrrne
dibnzo(4h)laquonthricrne
mdeno(I23-rt)pvre-ie
pyrene
VOLATU-Ei
bullcrelem
bullcrvlonio-Ue
benzene
caj-bon traquotrraquochloraquo-idr
Ctilorobernene
l2-diehlongtethne
iii-tnctltiorotKraquor Trace 1 T 1 -4)Ctilorampe^hArw
l f 1 ^-tric^i lor oefvtrve
l t l 22-teTrtclloroetl^Ane
ehloroethraquone
2-chloroltthr|viw| ttrve-
Chloroform
1 1 -ltSicMorot^nr
trinraquo-l2-dictiloroetrne
12-d^loropOStn
trinil3^ichloroproone
eis-lJ-diChloroprooene
rrhylberuene Tarce methrlene ehlor tat Trace
Ct1 or o m e t Kirgte
bromometKtrte
bro mod i rfi lor o rrgte t Mne
Uuorotrlchloromethraquo^e
OJ CJ lor od 1 f 1 uoro met hraquone
chJorodibromometKATgte
laquotrlaquociloroethrrx
toluene 9
tricolor otheir
fsw
T9
Sifi-TOSO)
(73B)
(7IB)
(75B)
(7(B)
(77 B)
(71 B)
(71B)
(SOB)
( t lB)
(I2B)
U3B)
(M B)
(7V)
(3V)
(4V)
(4V)
(7V)
(10V)
(11V)
(13V)
(14V)
(13V)
(14V)
(11V)
(23V)
(21V)
(30V)
(32V)
(33V)
(34V)
ltlaquoV)
( raquo J V )
(44 V)
f raquo 7 V )
(UV)
(V)
000 (30V)
Tlfl 151V)
(15V)
^00 (14V)
(17V)
(UVgt
-1 ZINT
CAS 30-32-J
205-11-7
207-01-1
211-01-1
201-14-1
120-12-7
111-24-2
14-73-7
13-01 -laquo
33-70-3
113-31-5
121-00-0
107-07-t
107-13-1
71-43-7
34-23-3
101-W-7
107-04-7
71-35-t
75-3-3
7^-00-5
71-34-5
75-00-3
110-73-1
(7-14-3
73-35-4
154-40-5
71-17-5
10041-07-6
10041-01-05
100-4I-
73-OT-2
74-17-3
74-13-1
73-25-2
75-27-4
73-41-4
75-71-1
174-41-1
127-U- IOUIS-) 71-01- 75-OI-
130
Lab ID Mo 2887-4
Phys i ca l d e s c r i p t i o n of sample C l i en t ID 4A5760
Liquid Sample was predominantlv a hvrlrnrarhnn bl pnd
Sanple workup Voli t i le f ract ion PEG Extraction (SW 846-5030) Scrnivola t ile f rac t ion Sonication Extraction (SW 846-3550) Inorganic f rac t ion Acid Digestion (SW 846-3050)
AC3D CS3U POUNDS 5AipoundNEUTlUgtJ- COMPOUNDS
ri CAS PPraquo CASf
(210 U-04-2 2raquot- tricMorophrnol (7)6) raquo-32-l braquoniolttVyre
[EM 51-50-7 ^-cti 1 or raquo-m-lt rlaquo laquoo 1 (7raquoB) 203-M-2 biMo(b)(luorinth^f
2 A) raquo5-57-J 2- cfiloropheryjl (7 3 B) 20701 benro(ilt) floor in tlaquo^e
(31 A) 120J3-2 2raquo-ltJicWoro(ygtlaquotx)l (74B) 2II-OI- chryve^e
(MA) 105-47- 2l-dimlaquothvloSrrgtol (77 B) 20Uraquot-J bullcwrioMhylene
(57A) u-73-3 2- ruTroohrgtol (TIB) 120-12-7 raquontnncergte
(34 A) 100-02-7 -oitrophenol (7gtB) lraquol-2raquo-2 benio(ghi)cgtrrylngtlaquo
(3Agt 51- 21-3 2 -4 initropherwl (SOB) tt-73-7 fluorme
(tOA) 53-37-l t-dinitro-2-mlaquothy lpNlaquoxil (II B) 15-01-4 pheAinthrrnlaquo
(A) I7-U-5 tgtentraquochlQroiywnol (I2B) 53-70-3 dibenplusmnoltraquoh)fcnthrraquocrne UJJ 101-55-2 rfwtwl (I3B) lraquo3-3raquo-3 indenol 1 23-cd)vrtie
(UB) I2raquo^X3-0 pyrer BASENEUTOAL COMPOUNDS
VOLATO-ES (161 I3-32- raquoclaquonraquophttgtngtf
(5B) 12-17 -J btniidir (2V) gt 07 -07-1 bullcrolem
(IB) 120-17-1 l^^iricfvleroboMux (3V) 107-13-1 bullcrvlonit Jlaquo (raquoBI IIS-7t| SeraquoChlorotgtlaquoterlaquo (raquoV) 7IJ3-7 benient
(I7S) 4772-1 heLCMorolaquothinc (tV) J-23-5 crtgton wtrraquocMoidf (UB) I11-U-I bll(2lttllorolaquot^w gtetNer (7V) 101-W-7 ltAtoroxniergtlaquo
(203) Jl-31-7 2 -etvl or onlaquo ph traquo I en e (IOV) 107-04-2 1 2-ltlicMorolaquoTKlaquone
(25B) raquo5-30-l 1 2-dichlorobenzene ( 1 1 V ) 71-JJ-t llI-trichlorolaquotNlaquoe (2 B) 31-73-1 l3-ltlichoroblaquonzenlaquo (13V) 7J-3A-) 1 1-6 1 cM or Of t (Mr
(77B) I04-M7 I -di CM oro ben z eoe ( I k V ) rraquo-oo-j l12-niichlorolaquotfvirraquolaquo
(2IB) raquol-raquo-l )J-dichlcroblaquorLiidinr (IJV) rgt-3laquo-3 J122-tetrraquochlcrolaquoTrie
(33B) 12I-Ilaquo 2 2-dinia-otoluer (UV) 73-00-3 Ctgtloroltthne U4B) laquoJ-70-7 2 t-dtnitrotoluene (1raquoV) HO-73-1 2-ltJilorocthv|vL-v| etrveshy
(J7B) 127-M7 14-dip^wnylhydraiine (23V) C7-U^-3 Ctilorofcrm
(JraquoBJ 2Ot-ugt-0 CJuarlLnthefe (2raquoV) 7J-33- 11 -ltlicMorcxil^nr
(mei TOCJ-77-3 -chJorophcnyl phenyl laquoKr (xgtvraquo lK-^0-3 tnjM-l^-diC^lofCKtl^nf
( M B I IOI-J5-3 -6romophnyl phenyl ether (32V) 7I-J7-3 12-dicMoroprosaA
(raquo2B) 3M3I32) bU (2-cMarobopropyU rtNer (3JV) ICXU 1-07-4 trraquoni- 1 3-ltjictgtloroBoor^f
(OB) t l l f l - 1 bi5 (2-cMoroetfxgtrv) meihtrw lOOt 1-01-03 cu-O-dichloroprose- (32B) D-U-3 hrxaetilorobutadierw (UV) 100-laquol-raquo rthylbenien 1^00
(33B) 77^7- he i kcMor ocyc 1 openudi crw (UV) 7J-OT-2 rrveThvlerw chlof idf
(36) 7I-gtraquo| oop^troo (raquoJV) 7raquoJ7-3 CtgtlorBmethne
(338) raquo|20-3 nraquopfitfillaquofx 1200 (wv) 7raquo-l3-raquo bromorrgtlaquothne
(34B) nraquo3) nitrobenzene (raquo7V) 73-23-2
(CBI U-Xl-4 N -fl i iro lod iphen yU mi nr (UV) 7J-27- bro mod i cti lor o mT bull- (OR) 42l^-7 N-^itrolaquoodipropylmlrlte (raquoraquoV) 73-traquo-laquo tl uor o tr i cfi lor o mlaquoT itr (UB) I I 7 J I - 7 bn (^thylheraquoy|) phttilaquoUtT 110000 (XIV) 75-71J QJ ct )or oltJ 1 f 1 uoro rrgtei ^bull gte U76) U-U7 blaquonzyl buryl pttTfKUie 12000 ( j i v ) m-i-i ctil or od ib ro mo met h xnf (UB) M-7i2 d i -n -bo TV 1 ft thlaquo U tlaquo (13V) 127-11- te trraquo cfl lor ot hlaquoTgtf (OBI 117-4J-0 dj -n -oc t y1 Jgth fflaquo U re 6 200 tuv) iom-3 tolucie ^70
(7CB) u-u- djrthyl phtJMlire (17V) 7raquo-OI-4 irictilarcraquo^lt-ir (715) 1 3 1 - 1 1 - 5 oVnrrhyl pMtfaUte (UV) 75-OI- v i M v l CMor idr
(T76I 5-55-3 blaquorgtzo( Unihrlaquocme Xylenes 1SOO
Cad- iurn 2 2 on Chromium - - Z I N C ^ ~ P r
Ai results arc expressed as ugc weight as received Xo entry denotes not detects
Lab ID No 2887-3 5A 57709 Phys ica l d e s c r i p t i o n of sample Cl ien t ID
LiquidSludge Liquid appeared to be a hvdrnc-Arhnn blonrl
Sample workup
Vol i t i l e f r ac t ion Methanol Extraction fSW 846-5030^ Semivolatile fract ion Sonicatlon Extraction fSW 84 f i_3550gt) Inorganic f rac t ion Acid nic-psr-inn fSW 846-30501
ACS3 COMPOUNDS BASENEUTRAL COMPOUNDS
f f t CAS CAS (2IA) tt-04-2 (738) JO-32-J DCftZ OTamp p V^^^ff
(22 A) 3laquo9-50-7 p-cttl or o-m-cre laquoo 1 (7VB) 205-99-2 p^^izot oil lyor 4-^ t ^ltf ^^
(2 A) raquo5-37-l 2- CJiloroprieno (75B) 207-01-9 blaquonioltllt)flultxtn^it
(31A) 120-13-2 2raquo-dictgtlcr8tgtrfX)l (74B) 211-01-9 Chryeolaquo
(3 A) 103-47-9 2 -d irrgtet hv Ipherto1 (77B) 201-94-1 laquocnphthyle^
(37 A) 11-73-5 2- rutrop^enol (7IB) 120-12-7 bull^thrjc c^
(MA) 100-02-7 -flitroprlaquorv3l (79B) 91-2-2 bcnroltKhi)pefraquoler
(79A) 31-21-3 2 -d in itr eoricno 1 (IOB) 14-73-7 tluoren
(40 A) 33-37-l 4-d in itr raquo-2 -met hy Iphtnol ( I IB) 13-01-1 poltrtAOthrvTgt^
(44 A) 17-14-3 plaquon1 CM or o^eno I (I2B) 33-70-3 dib^fi-o( 4(K)Aji thirl c c^f (43A) 101-93-7 prwnol (S3B) 193-39-3 indcnotlIJ-ctflsvfie
(SB) 129-00-0 pyrene ftASENEUTRAL COMPOUNDS
( I D )
(5B) 92-X7-3 b^zidrw (2V) 107-02-1 bullcrolrm
(IB) 120-17-1 1 2 fc-Tr ICJ caro blaquoni crw (3V) 107-13-1 bullcrvlonitrij
(93) 1IU7I1 Seraquochlcrotgttniegtlaquo (4V) 71J3-2 blaquonienlaquo inn (17B) 4777-1 hexat^lorcwthgine (4V) H-23-5 carbon ttTricllixidf
( I I B ) 111-wJ bll(2-lt3^1oroltt^w)ether (7V) 101-90-7 ciloroblaquonzene
(20B) 91-31-7 2-ctdo-ont she Ime (10V) 107-04-2 12-dieftloroerane (25B) 95-50-1 l2-dilorobenzene ( 1 1 V ) 71-35-4 11 1 -tricMorotn-laquo
(2ampSI 51-73-1 13-dicMo-obenxerw (13V) 73-3-3 1 1 -d i CM orcxt M-
(77 B) I04-H-7 1 -di ci 1 or o benI erw (UV) 79-00-3 llJ-WiChlorolaquoflaquonlaquo
(2J6) 91-90-1 SS-dKJilorotxniidinc (13V) rraquo-3laquo-3 l122-tetrlaquocftlorelaquoTrne
(35B) 12| |k-2 2fc-dintrotoluene (14V) 73-00-3 diloroeth^e
(gt4B1 404-20-2 24-diniTrotoluenlaquo (19V) 110-73-1 2-cMortxfthv|vL-raquo trlaquoshy
(37B) 122-447 12-diphenylhydriin (23V) 47-44-3 cMoroform
(J9B) 204-U-0 Ouormntherve (29V) 73-33-i ll-diCMorolaquot^nf
(fcOB) 7005-77-3 k-cMarophfy| prlaquonyl etScr (gtOV) 134-40-3 trraquonraquo- 1 2 -dicMoroc t Nenf
(raquo I6) 101-35) raquo-6romoprny| phenyl rther (32V) 71-17-3 12-diChloropostn
(raquo2B) JH3IO2-9 bU (2-ltplusmnlaronopropyl) rthrr (J3V) 10041-02-4 trni-l)-diirMoroxtgtOpnf
(OB) I I 1 - 9 I - I bu (Z-chloroethxjrv) metSampnlaquo 10041-01-05 CU-D-djcMoroproOf-W
(32B) 17 -U -3 hiraquocfilarobutraquodiergtlt (3JV) 100-4U rttyligtlaquonitrgtlaquo 5300 (33B) 77-raquo7-raquo hrxicftl or ocrclopei tidier (UV) 75-09-2 nxthylenf ctilor ifif
lt3B) 71-391 ao prior or (raquo3V) 7raquo-17-3 rtloromrtha^r
(356) 91-20-3 nlaquoprithienraquo Trace (44V) 7raquo1Jraquo bromltmlaquoth^
(MB) n-93) ft i vo b^nz c^^ (raquo7V) 73-23-2
(425) U-30-4 ^bullf i^OftOOL^ri^ny lArrunf (UV) 73-27- bro mod i cgt lor o i~ t gt
U3amp1 Ul-4-7 N i itr CrtoO ip ro py 1 laquo ml r (raquo9V) 73-49-k U uor o IT 1 et loront Mrgt (UB) II7-1I-7 bu (2-Ihythlaquoryl)prtfUtr 59J300 (30V) 73-71-1 dj ci kr olt11 f 1 uoro rrrt (Nrgtraquo
(47 B) L3-41-7 txniyl burvl phthlaquoUtr ( 3 1 V ) I2-1-1 ch1 or od i b ro mo mi IMP r
(UBI U-71- 0-A-fcurl BMMliw (13V) 127-ll-i rt tr t cM or of tNr
Uraquo6) 117-li-O di-n-oCTv| pnttlaquoUfr 6000 (UV) lOt-II-3 toluenf 5700 (7CB) U-447 djrthvl p^tfvilirt (17V) 79-01-4 WiCMoroth^e ( 7 J B I U l - l l - 3 d^M^vl prttgtraquoUW (UV) 73-01- vinv t cMor 10 (77 Bgt H-35-) brto(raquollaquonthncrTraquo Xylenes 19000
Caen 1U~ 1 Chromium =2 Z I N C
All results are expressed as up g weight as received No errrv ripn^t-plt
Lab 1Lgt No 2887-5
rhyr i r n l d e s c r i p t i o n o f sample C l i e n t in 6857710
LiquidSludge
Sample workup Vol i t i l e f r a c t i o n PEG Extraction (SW 846-5030) Semivolat i le fr action Sonication Extraction (SW 846-3550) Inorganic f rac t ionAcid Digestion (SW 846-3030)
AOD COMPOUNDS BAStNELTTRAL COMPOUNDS
rr i CASI CAS (21 A) tt-04-7 (736) 30-32-1 bntoltraquogtprrene
(23A) 3-9-50-7 p~lt1 or o-m-c rraquo1 (78) 205-99-2 ben to( Sgt )1 1 uor raquon I he-gtf
(7raquoA) 93-37J 2- etilorophenol (73B) 207-01-9 beriioltk)(luortntrgt^f
(3 IA) 170J3-2 2raquo-dicMoroprnol (7(B) 2II-OI-9 eifVMTie
(3 A) 03-(7-9 24-4mlaquoThvlDheno| (77B) 20l-9(-i bullceraoMhyler
(37 A) tt-73-5 2- rue-oorienol (718) 1 20- 2-7 laquoflthrraquocene
(3 A) IOO-02-7 ^Mtroprwnol (7fB) 191-24-2 beraquoMoltsrM)plaquovllaquox
(39 A) 3I-71-5 2-4 ini tr ophero1 (tOamp) K-7J-7 tluwtrie
((OA) 33-37l (-lt iMtro-2-methylphenol (tlB) D-01-J phenATithrene
(4A) I7-44-J pentichlorophenol (128) J3-70-3 dilwnioltraquoh)laquonthrraquoceif
(OA) IOI-95-2 prwnol U38) 193-39-3 indeno(123-cd)vcne
(MB) 129-00-0 pyrergtlaquo 6 ASENEUTILW- COMPOUNDS
VOLATH-tS ( I B ) 13-32-9 ftCYTNA pO IT H I raquolt
(38) 92-17- o^nzioinc (7V) 107-02-1 aero le in
( IB) 120-I2-I l2k-o-i(3iloroblaquontergtlaquo (3V) 107-13-1 laquocrvlono-U
OB) Jl l-7fc | he I raquocti 1 or o blaquonI enlaquo (V) 71-43-2 Oltf2 tO^
(17B) (772-I he uc^i 1 or of t h ne ((V) 34-23-3 CJU JOO Tt TTlCfllo^ iCpound
( I I S ) bu(2-rfilcroethv|)ether (7V) 10J-90-7 laquoWoroblaquonzeoe III-44-4
(KB) 9I-51-7 2ltfMoronlaquoohttvraquolwe (10V) 107^)4-2 1 t2^ojo^loroetfft^c (2JB) 95-50-I 1 2 -dichlorotgtlaquorlene (11V) 71-55-4 1 1 1 -trichloroeihtr (251 541-73-I 13-dchlorotxniene (13V) 73-J4-3 1 1 -dieMoreeraquohraquorlaquo
(77Bgt 04-lgt4-7 1 mdash djcMorobenlene (IkV) 79-OO-3 t12-tricriloroeflaquofgte (2gtB) raquolraquo-l 33-didMoroblaquonjidirlaquo (13V) 79-34-3 1122-tetrcnicroeir^ne (33B) 12 I I 4 -2 Z4-diniiroioluerlte (1(Vgt 73-00-3 e^loroetruuie (KB) (04-7C2 2 (-dinitro toluene (19V) 110-73-4 2ltJilorolaquotr(v|vLnraquolnhlaquo (175) 122-447 12-dipr-enylfiydrmiine (23V) (7-44-3 chloroform
(J1B) 704JJ-O Huor^thrr (29V) 73-33-4 lI-ltJicMoroltthcne
(OBgt 7003-77-3 -ctJoroprienvl phenyl ether (JOV) 134-40-3 irirraquo-12-dictila-olaquotrlaquone
( raquo I B ) IOJ 33-3 -6ogtmoprienyl phenyl ether (32V) 7I-I7-3 l7^lichlorepreoine (laquo2BI 3H3raquoO2raquo bit (2-chlororaquoopfT5pyO ether (3JV) 10041-02-4 trint-l3-ltJicnloroBlt-ooee (OB) 111-11-1 bis (2-cMcroetro(v) metSuvr 100(1-01-03 CU-lJ-itflloropOO-^
(376) t7-U-3 hraquoz raquoch1 or o bu tlaquodi ene (J1V) )00-1- erhylberuer 1400 (33B) 77 -gt7- hei tchl or ocyc1 open traquodi ene (raquoV) 73-09-2 methylene chloriCf OB) 7raquo-3raquo-l BO prior one (raquo3V) 74J7-J eMorametrutne (33B) raquol-raquo-3 naphtfalene 100 (UV) 74-13-9 bro rrvome t hrgt (3iB) n-raquo3-3 niireblaquor)iergte (raquo7V) 7J23-2 (CB) U-XH N -01 ITo tod 4gthenyU rru rr (UV) 75-27-4 bro mod i ch lor o rrx t f4Ugt ((36) 42IO4-7 N-nnroodipropYlraquomlrlaquo (raquolaquoV) 73-4t-4 JJuorotr lchloronvlaquoiMftlaquo (Uol U7-1I-7 ba (2-etrylNraquoYl) phtt^Ure 100000 (30V) 75-71 -raquo dj cftlcr od U 1 vraquooro rri NUT
(47 Bl 13-44-7 t^niyl butvl phthiUte 13000 (31V) 124-41-1 chlorodibromorrwt^r
lt U E gt ) U-71-2 d-ojjurvl phtf^Ure (13V) 127-11-4 tr trbullcti loro rirr
laquoraquo6gt 11704-0 dl-fl-OCTvl pfltMUM (UV) 10t-ll-3 toluene fiin (TtS) raquo-laquo djrthvl phttuliTr (17V) 79-01-4 tricolor oethenr lt 7 | o l 131 -11 -1 (UV) v i n v i chlcwidr dimrlKyl rrftlaquoUTraquo 75-OI-J
(T75I J4-35-J blaquoTMOlt^trrlaquocr^ gtylenes 1200
Cadr ium 3 Chromium 21 ZINC 150
All results are expressed as ugg weight as received y0 entry denotes not detect
Iah I D No 2887-2
Physical descr ip t ion of sample
Strained Soil
Sample workup
Voli t i le f rac t ion PFG Extraction (^W 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-3540) Inorganic fract ion Acid Digestion (SW 846-3050)
ACS) COMPOUNDS
rn CAS Tft CASf
(21 A) tt-04-2 (73B) 50-32-4
U2A) 71-50-7 P-ch 1 or o-m-cre laquoo 1 (7k 8) 205-11-2
(2 A) raquo3-37-l 2- chloroprraquoeno| (75B) 207-01-1
(3IA) 120-13-2 2raquo-4ichlorophenol (74B) 21UOI-1
(3 A) 103-47-1 24-dimethvlphenol (77 B) 201-14-1
(57A) U-75-3 2- njtroDhenol C7I5) 120-12-7
(MA) 100-02-7 a-flitrophenol (71B) |1l-2raquo-2
(51A) 51-21-5 2 -d in i tr o phetio 1 (SOB) K-73-7
(40 A) 53-57-l raquo 4-dinitro-2-methy lprnol (tlB) 15-01-1
(4 A) 17-14-3 plaquoitraquochloroorlaquonol (I2B) 53-70-3
(43A) IOt-13-2 prlaquonol (13B) m-31-3 (MB) 121-00-0
BJ KSENCLmLAL COMPOUNDS
(IB)
(3B) 12-17-3 bcnzidine (2V) 107-07-1
(IB) 120-17-1 1 2 k- tr i ch 1 oro benr ene (3V) 107-13-1
(IB) I1U7I-1 he it raquocM or o boiz ergte (raquoV) 7I-J3-7
(12B) 47-77-1 he traquoch 1 or oet hlaquo ne (4V) 54-23-3
(116) 111-- buC-cJiloroethv|gtether (7V) 101- W-7
(20B) 11-31-7 2 -ltft 1 or on ph ttvraquo 1 laquon e (10V1 107-04-2
(23B) 15-30-1 1 2 -dictilorobeni ene (11V) 71-55-4
(25) VI-73-1 1 3 -ltJ i ci 1 or o blaquoiz ene (13V) 73-3-3
(77 B) 104-M7 llaquo-dchloroblaquoMeoe (HV) n-00-3
(2IB) 11-lk-l 33-dicMorotxTLtidinr (15V) n-3raquo-3 (33B) 12I-U-2 2 ltgt -4 in i tr ot o luene (14V) 75-00-3
(MB) 464-20-2 2 4-d initrotoluene (11V) 1 10-7 3-1
(J7B) 122-447 1 2-diprieny Ihydrti ine (23V) 47-44-3
(316) 2O4-UO Ouorraquonthene (21V) 73-33Jshy
(WB) 7t)03-77-3 ^-cJJorophenyl prienyl ether (JXgtV) 154-40-3
(MB) 101-33-3 -6romopriefgtyl prienyl ether (32V) 71-J7-3
(raquo2B) 3431-32-1 bit (2-chloroboproprO ether (33V) 10041-07-4
(OB) I1U1I- I bu (2-ltMoroethorv) methane 10041-01-03
(52B) r-u-3 hexachlorobutadiene (J1V) 100-l-raquo
(33B) 77-47- he z raquoctlt lor ocycloqenud i crte (MV) 75-01-2
OB) 71-31-1 ao prior one (raquo3V) 7raquo-17-3
(33B) 11-20-3 nlaquopntrlaquollaquone (UV) 7raquo-13-1
(MB) n-13-3 nitrobenzene (raquo7V) 73-23-2
(UB) U-30-4 N-nnroiodiprienyUmine (UV) 75-27-k
(436) Ol-U-7 N-nitrModiproOYlmJne (raquo1V) 73-41-
(UB) 117-117 bu (2-laquothylheiry) phtrlaquolte 8800 (50V) 75-71-1
( 4 7 B ) L3-U7 blaquoniyl buryl phthaUte 30 (31V) 12I-H-1
(UB) U-7U-2 di-o-burvl phtrMUte U3V) I27-I1-
(416) II7-U-0 dj-n-oCTvl pritntUtr 1200 (raquo4V) IOUI1-3
17CB) U-44-2 djetiTi phrtultrt (raquo7V) 71-01-4
( 7 I B I 1 3 1 - 1 1 - 3 dimnfTraquo| prThraquoUtr (UV) 73-01-
(776) H-35-3 berMolta^thrCF^
Cl ien t ID 8 A - S 7 4 6 1
RASENEUTRAL COMPOUNDS
benzofbtfluor^tMe
benzodclfluorintoent
Ctiryiene
cenoithylene
raquonthrraquoctne
benzoltKhilpervlefgte
floor ene
prlaquofnnthrene
ltlibenplusmno(4h)knthricrnlaquo
inogtno(123-rt)pvrrne
pyrene
VCX-ATIIE5
bullcrolem
bullcrvlomn-U
benzene
carbon tetrtchloridf
chlorobenzene
1 2-oUchloroethAnf
lll-trichloroethlaquone
ll-dcfioroethrraquo
1 1 2-tricilorolaquothraquorw
1122-tetrichloroeTtvin
chloroethre
J-ctiloroethv|vinv| etrgte
chloroform
11 -denier oethene
trinraquo- 1 2 -4 cMor oe t hens
12-dcMoroprooine
^Lns~ I f 3-4ic^ lo^opf oo^^^
Cli-l 3-dicMoroprooe^e
rttiylbenzene
methylene cnlonfle
Ch 1 or o me t hane
bromome thane
Trace
bro mod i cMor 0 me t hane
(Juorotrlchlorome thane
chlorodibromometKinf
tetracnloroethervp
toluenetr icMoroel he-if
Trace
CacTiiun Chromium ZINC f
All resxil ts are exprp^spr i K-i
Phys ica l de sc r ip t ion of sample
Strained Soil
Sample workup Vol i t i le f ract ion PEG Extraction (SU 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-5340) Inorganic fract ion Acid Digestion CSV 846-3050)
ACE) C30laquo POUNDS
m CA5i CASraquo (2i A tt-C-2 (73B) JO- 52-1
(22 A) J1-JO-7 p-ch 1 or raquowTv-cre 101 (7raquoB) 203-raquoraquo2
(2 A) raquo)57-J 2- chlorophenol (73B) 20701-
(31 A) I25J3-2 2k-4icttlltroptlaquonol (7tB) 211-01-1
(3A) IO)-7-raquo 2-dimlaquothvlpNrnol (77 B) 20l-raquoi-
(37 A) u-rj-j 7- niTTOphenol (TIB) 120-11-7
(MA) 100-02-7 -rtropN-rraquol (7raquoB) lraquol-2-2
(JraquoA) JI-21-) 2-d initroprietys 1 (IOB) U-73-7
(MA) 53-37-l Udinnro-2-mlaquothylphenol (UB) I5-OI-J
(Agt I7-U-3 pentichlcropwnol (126) 33-70-3
laquo)Agt 10l-raquo)-2 phenol (I3B) IJ3-31-3
(MB) 12raquo-00-0 AASCVflCUTRAl COMPOUNDS
( I B ) I3-32- bullcnraquophtber
(56) raquo2-17) bnzidirlaquo (2Vgt 107-02-1
(IB) 120-12-1 l2btrilt7tlorotgteizegtlaquo (3V) 107-13-1
traquoB) IIraquo-7fc | heikcMeroblaquonzergte (V) 7l-3-2
( I 2 B ) 4772-1 he ueft 1 or olaquot hraquo rgte (tV) laquo-23-3
( i ts) III-- biraquo(2-cMoroethv Dethrr (7V) 101-W-7
(20Bgt 1I-3I-7 2-cMoroflaquophthlene (10V) 107-Ofc-2
(2)6) raquo5-50-l l2-dchlorotgtlaquonzefgte (11V) 71-33-4
(28) 3l-7)-| 1 3-didMoroblaquonrenlaquo (13V) 73-3-3
(27B) 10t--7 l-diclorolgtmzerlaquo (iV) rraquo-00)
(216) raquoI raquoltbull- 33-dichloroblaquoMidiflaquo (13V) 79-31-
(356gt 2I- l-2 21-dinitrotoloen (UV1 73-00-3
(UB) laquogt- 20-2 2 (-dinitroto luenlaquo (HV) 110-7J-J
(376) 122-W-7 14 -dipheny Ihydrzire (23V) lt7-M-3
(396) 2O--0 tJuoruMSene (2raquoV) 7J-35- (OB) 7003-77-3 -c^lvophenyl pNrnyl ethlaquor (30V) 1H-W-)
(MB) 101-33-3 bull-bromopriefiyl prienyl ether (32V) 7t-t7-3
ltraquo25) 3HJI-32-1 bU (2-cMoroaopropyl) rthrr (33V1 10ltX 1-02 -6
(06) l l t - t l - l bis (2-cftloroetSorv) metwne 100lt]-01-03
(32B) C7U-3 heraquoraquochlorobutidierx (31V) 1 00-41-
(3361 77-7-raquo hexiOilorocycloptfiudlerve (raquoV) 73-0raquo-2
(56) 71-51-1 no ph or one (raquo3V) 7raquo-17-3
(3)6) raquol-raquo-3 rwiphtfalme (UV) 7raquoJ3-raquo
1361
LUB)
H-133
14-30-4
nitrobenzene
^ ri i iy o too ipf^^ y LA r^i rtf ^ 7V) (UV)
73-23-2
73-27-
(436) t21--7 M^TI iff frfcO^ip ropy Ift mJf^ (gtraquoV) 73-4raquo-raquo (UB) I17J1-7 bu (2-rThyiruMcyDpMtvUtr 570 (jov) 73-71-1 ( U B ) U-41-7 blaquonzyl buryl phthlaquoLite (31V) l2k-raquo-l ( U B I U-7I-2 di-n-burvl pitftALtTe (raquo)V) 127-lt-fc
(OB) 117- -0 dJ-fraquo-oCTvl phlJ^Ute (UV) IOt-It-3
(7CB) 14 -W- 2 djelftvl phtfalitt (17V) Tt-01- ( 7 I B I 1 J I - I 1 - ) duTNnhylphttsraquoUw ltUV) 75-01-
(77BI X-))O lgtmrlaquoigtmhrraquoctf
Cadmium f iQ Chromium 15 ZINC
Tab ID No oo -
Cl ient ID 8A-A-64220
fcASENEUTTRAL COMPOUNDi
blaquofuo(raquo)pyrrtgte
bfizo(b)(loortAth^e
benzo(k)f|ulaquoin1herf
Ctiryiene
cenDraquoMrwlene
fcftT^rict^t
D^flZCT (fftl)pC^ V Itf^p
(luorene
phen^threne
diiwnztKthlanthricene
indlaquono( 1 23-lttf)pvrene
oyrene
VOCATtLES
bullcrolem
bullcrvlooitriJe
bervteoe
carbon WTTicMoridf
chlorobenze^e
12-djcMoroetfane
1 1 1 -tricolor ex tKraquon
1 1 -dicMarcx t hrlaquo
1 1 2-triChlorothraquorw
1 122 -laquotrraquocM or o-hraquorgt
cMoroettu^e
2-cMorlaquothv|vuy| rseshy
chlexeform
ll-dchloroctfgtn
tri^iraquo l 2laquoflic^ loTo^i rgtcnt
12-dicWoroproptrs
Winl-l3-dicMoropfooene
Cu-lJ-djChleroprooe^
rrtiylfrenzene
methylene ctiloride 0 64
cMorometHAne
bromomlaquothlaquone
bnsmoform
bro mod i eti lor e me t Nine
0 uor o tr 1 cMor e rrgtlaquo t Nnlaquo
dj di tor olaquol If 1 uoro mraquoi Nrraquo
chlorodibromonveiKme
re tr a en 1 or or fxrvr
toluene
D-ieWoroefwne
entry denotes not detect All results are expressed as ugg weight as received Xo
Lab 1) No 2887-8
Physical descr ipt ion of sample
Sf-rs inpH 9 n i l
Sample workup
Vol iCi le f ract ion PEG Extraction (SW 846-5030)
Scmivolat i le f ract ion Soxhlet Extraction (SW 846-3540) Inorganic fraction Acid Digestion (SW 846-3050)
ACD O3MPOUNDS
m CAS fPraquo CASf pi A) tt-Ot-2 Zraquot- tritilorophrgtol (73B) 30-32-1
ft M -3o-7 p-cMorraquo-m-crTraquool (7kB) 205-raquo-2
(2 A) raquoS-37-l 2- cMorop^erxgtl J73B) 207-OI-raquo
(31 A) 120-13-2 l^ictiloropix)l ^7tB) JII-01-
(3 A) |03-7-raquo 21^-dimeThvlphenol (77B) 20t-raquot-l
(J7A) tl-73-3 2- rutropwnol (71 B) 120-12-7
(MA) 100-02-7 -MO-opwnol lt7raquoB) lraquol-2-2
fJraquoA) 3I-2J-3 2-dinitrop^laquoTgtoI ((OB) U-7J7
(laquogtA) J34-37-1 lt-dinitrfr-2-methylpwrxgtl (I IB) I 3-0 1-1 (raquoAI 17-1 3 pcmacMcroptonol (S2B) J3-70-J UJA) IOI-raquo5-2 phenol (IJB) MJ-39-J
(tBgt 12raquo-00-0 RASEfZUTRAL COMPOUNDS
( IB) 13-32-f raquocertaprithene
(3B) J2-17-3 twnndinc (2V) 107J2-J (IB) 170-I2- lr2k-triOilorobenzerlaquo (3V) 107-13-1 (raquoB) I11-7I-I hei bulllt1 ore blaquont ergtlaquo (raquoV) 7l-3-2 (1B) 47-72-I he ucft 1 or oe t h n (tV) 3-23-3 (116) |II_wJ bu(2-ctiIarothvI)laquotNer (7V) 101-90-7
(20B) raquoI-JI7 2 -cW or orvraquo ph tf I ene (10V) I07-Ofc-2 (23B) J3-30-I l2-lt5ictiloroblaquonzeoe (11V) 71-3J- (245) 3I-7J-I 13-dic^lorotxenzenc (13V) 7J-3-3 (27B) 104-K-7 1 mdash diC^lorobtnrerve ( lraquoV) 7^-OO-5 (21 B) raquo|raquo| 33^icftlorobenzidifv (I3V) rgt-j-3 (33B) I 2 I - U - 2 2ltgt-dinin-o1olvraquorgte (UV1 75-00-3
(J4B) 404-JO-2 21-dinitrotoluerve (1raquoV) 110-73-1
(37B) I22-W7 1 2 -d ipheny Ihydra z ine (23V) C7-14-3
(318) 2O4-W-0 tJuortnihrne lt29V) 75-3J- (kOBt 700J-77-J ^-tfMoropheTgtyl p^enyl ether (30V) 1J4-W-3
( raquo I B ) IOI03-J raquo-6romopfgtenyl phenyl ether (32V) 7I-I7-J
(06) 3H3raquo-)2-raquo bU (2-tfilerobopropyO ether (3)V) 10041-02-i
(OB) lll|| bii (2-cMoroethoxv) methane 10041-01-03
(37B) PUt) hxzraquocMorobutadienlaquo (J1V) 100-raquol-raquo
(JJB) T7^7U heztctilarocrclotMnttdicrgte (V) 7gt-0raquo-2 OB) 7l-3raquo-l BO ph or one (raquo3V) 7raquo-17-J
(338) raquo|20-3 rlaquopritrilaquolene (UV) raquo-laquo-raquo
(3iBl n-raquo3) nitrobenzene (raquo7V) 75-23-2
(CB) li-X)-t N -n i tr o tod ipheny U mi nr (UV) 73-27-fc
(06) CI-U7 N^iitroiodipropYUmlr ^raquo1V) 73-H-fc (UB) 117JI-7 bu (2-ethYlNerrl)pM^Utr 12000 (JOV) 75-71-1 (47 B) L3-U7 llaquoniyl buryl pht^UTe 2 800 ( 3 I V ) 2laquo-raquo-I (UB) raquo-7i2 di-o-ourvl pritfwiUrr (I3V) 127-lt-i (196) 117-14 3 dj-n-ocryl pritfiiUrr (UV) IOUIS-3
(TCB) J4-W-2 djnhYl phtfalitt (17V) 7t-01-lt (716 ) 1 3 1 - 1 1 ) damnhYl pMtuUTT (UV) 73-01- (77 Bl 3 33-3 frlaquon z olt raquo klaquom h rraquo c prgte
Cadmium T^ Chromiurn T Z T N C 100
Client ID 8A-C64221
BASENEUTRAL COtPOUNOS
bnzo(t)pyrrrie
benzobXluoriflthei blaquorizoltVHluorraquontrraquone
chryiene
bullcenphthylene
tnthneene
benzoltRM)perylene
fluorene
prienlaquonthcTTgte ditgtmplusmnolt4hluithrraquoctnf
indenof 1 23-cd)pvrf ne
pyrer
VOUATILES
bullcrolein raquocrvlonnrile benzene cmrbort Tetrichloride
chlorobenieoe 1 2-oUchloroethirie
11 1 -tricolor oethne ll-dvchlorolaquollMr 1 1 2-w icMoroethAoe l122-tetrieMoroeihilaquonlaquo
chloroetKvne JltJilorothvlvmv| ethe chloroform
11-dicMoroethent
trani- 1 2 -dicti lorolt t hene
1 J^JictiloroproBfVf
trim- 1 3-4ietiloroproperie
Cil-IJ-dicMoropfoOerie
rrhyUxrmene
methylene criloride
chlorornethine
bromome thne
007
13
tluorotr l^VoromlaquotNraquorgtt
da ch lor od 1 1 1 ooro frvet hraquone
chlorodibromometlvinf
te trraquocnloroeT rrrr
tricMoroetSmr
All results are expressed as us2 weight as receixred No entrv denotes not detect i
Phys ica l descr ip t ion of sample
SoilCake
Sample workup
vol i t i le fract ion ^FP FvfrarfMnn (ltU Rif i mdash Smrn
Semivolatile fraction Soxhlet Extraction (SW 846-3540^ Inorganic fraction Acid Digestion (SW 846-1050)
AC23 COMPOUNDS
rrt CAS CAS
(21 A) 11-04-2 2raquo4- trieMorophenol (738) 50mdash 3-4
122 A) J1-30-7 p-ctil or raquo-nvltrlaquo laquoo 1 (7laquoB) 205-11-2
12 A) 13-37-4 2- etilorophenol (75B) 207-01-1
(31 A) 120-13-2 2raquo-diclorophlaquoTgtol (74B) 211-01-1
(34A) 103-471 24-dmlaquothylphrnol (77 B) 201-14-4
(57 A) U-73-3 2- rutrop^nol (7raquoB) 120-12-7
(54 A) 100 -02-7 bull i tro p^c 01 (71B) 111-24-2
(J9M 31213 Z o trt i tr o poc^oI (MB) U-73-7
(40 A) 334-32-1 T^Hjinitrfr2^rt^T ny tp^gt^noi ( t lB) 13^)1-4
(44A) 17-44-3 pcnttchlaroprwnol (S2B) 33-70-3ltOA) IOt-IJ-2 pTUfNOl (136) 113-31-3
ftASENtUTRAL COMPOUNDS (MB) 121-00-0
(IB)
(56) 12-473 Iwnndine (2V) 107-02-1(IB) I20-IJ-I 1 2 4-tr icJi lorobeniervr (3V) 107-13-1(IB) 11 1-711 hexkcMarobcnzeM (4V) 71-43-2(126) 47-72-1 hexch)eroeihlaquone (4V) 54-23-J( I I S ) 111-4- bu(2-eMorlaquothv|)laquothr (7V) 101-10-7
(208) 11-51-7 2-c^laronraquophtfgtlene (IOV) 107-04-2(23B) 1J-30-I 1 2-dichloroblaquonime (11V) 71-35-4(2651 341-73-1 gt3-ltiictitaroblaquonxcnc (13V) 73-54-3
(27 B) 104-47 l4-dicMorotKmrerlaquo (14V) 71-OO-3
(21 Bgt 11-14) 33-4ichlaroblaquon2idine (15V) 71-34-3
(338) 121-14-2 24-dinitrotoluene (14V1 73-OO-3(J4Bgt 4O4-20-2 24-dinitretoluenc (11V) 110-73-4(37B) 122-447 lraquo2-dip^nylhydrraquoxirlaquo (23V) 47-44-)(MB) ro--0 Uuaranthene (21V) 73-33-4(406) 7003-72-3 4-ltUorepfraquonyl phenvl rtSer (30V) IH-40-J( raquo I 6 ) 101-333 4-6romoprlaquonyl pflaquony| ether (32V) 71-17-3
(OB) 3H3I-J21 bll (2-cti|orobopfrgtpyO ether (33V) 10041-02-4
(OB) I11-1I-I bis (2-cMaroethoxv) methane 10041-0103
(57B) P-44-) hczw^lorobundiene (J4V) 100-41-4
(JJ6I 77-47-4 htTicMarocyclojxrtadien (44 V) 75-01-2
(346) 71-31-1 aophoroo ( raquo ) V ) 74-47-3
(33B) raquo|203 r^pn thA Icr^ (44V) 7 -raquobull J-
(546) n-i3) H i frovCftZfl^^ (raquo7V) 73-23-2
142B) 14-30-4 S -n i tr o laquood ipheny Lt mi nc (44V) 73-27-4
(43 B) 421-447 N^iitrotodtpropyUmlne (41V) 73-41-4(MB) 117-41-7 bu (2-raquoThylhlaquolaquoyl)pMtgtlaquoUtr 52000 (30V) 73-71-4(4B ) 13-447 (xniyl bviryl ptithiUre 6700 (3 lV) 12raquo-l-l(UB) 147U- di-n-burvl pMhUre (I3V) 127-11-4laquoampgt 117-4J-0 ltjj-n-octyl phtfaUtr (UV) 101-11-)
(7CB) U-44-2 djrthyl pht)raquolraquort ( I7V) 71-01-4( 7 I B I 131-11 ) dimrthyl phttgtUTe (UV) 73-01-
(T76) H-33O tgtnzoUtlaquoftthncmr
Cadmium l i r^ Chromiurn 2 0 ZINC 140
All results are expressed as ugg weight as received
Lab ID No 2887-6
Cl ien t I D 8AD64219
Dd20( amp py(re
blaquonio(bHluorraquoflthegtlaquo
berzo(Mf luorampnThene
chryraquoefgte
ftctnAoMhy(ergte
raquonthncene
benioltK(M)plaquovlene
(Juorene
picnintfirtTX
dihwvioltraquoh)laquonThrraquocene
mdeno(l23-rt)pvrraquone
pyrene
raquocrolein
raquocrvloourUf
benzene
carbon laquoTrraquochlofifle
chlorobenieo
l24JcMarolaquotlxine
lll-trichlcroltthlaquorlaquo
-ltJicMorigtnKraquorgtlaquo
l12-trichlorolaquot^nlt
1 1 22-tetrcftloroetrvtnlaquo
^tloroeThAne
2^^1orolaquothvlvuiivt ethe
etila-oform
ll^liailoroltN^
trtni-12-dichlcxolaquoTfgtene
12-ditfiloropropine
trtni-l3-ltjicti|orocltX)t^f
cu-l3-djcMoroprooe^f
rttiylbtnztTve
methvlene cWoride
ciloromnM^f
Dco^^oroct^A^^
bromofarm
bromodicJiloromltlfraquon
tluorotrlctiloromttNir
diOilorodKloororfvrir^Ar
ct^lorodraquobrofTorrgttKAne
wtricnlorampctNrr
toluene
trirfilorolaquoThfif
v i n v CMor ilt3^
No-entry denotes not detect
ih i n N O 2887-9
Phys ica l d-asc r ip t ion of sample Cl ient ID 10A64222
Linnir l ShtHcp
Sample workup Volitile f rac t ion PEG Extraction (SW 846-^030^ Semivolatile fract ion Sonication Extraction (SW 846-3-540 Inorganic f ract ion Acid Digestion (SW 846-3050)
AOD COM POUNDS BAStNELTTRAL CXLPCXJNDS
rrt CAS CAS
(21 AJ U-Ot-7 Z4- trichloropSeno (73B) 30-J2-
(22 A) 55-30-7 p-ctilarraquo-m-erelaquoo1 (7kB) 205-raquoraquo-2 ben r olt b) 1 uor ifl t Ne~gtf
(2AJ raquo3-37-i 2- ctilorophenol (75B) 207-0raquoraquo benzoltllt)floofraquontslaquor
(31A) 120-13-2 2raquo-ltJictilcroooenol (76) 211-01 9 ctiryjene
(3A) I03-47- 2k-dimethylphenol (77 B) 20t-raquo4-i bullceruphthv lerraquoe
(37A) U-73-3 Zmdash Ajtropheooi (7SB) 120-12-7 fcntftricene
(34 A) 100-02-7 w^ i ff o phe rgto 1 (7raquoB) Iraquol-2-2 ben z o( Rh i )per v 1 me
(31A1 51-21-3 Z^ - d iA iV opheno1 (SOB) U-7J-7 Iluorene
(MA) 3X-37-I T v-4iAiv omdash laquo mdash fl^et ny Ipoenoi (I1B) 13-01-1 poeftraquonthrene
(4 Al 17-14-5 p^ntBCfllGrOprlC 1 Vol |I2B) 33-70-3 dilgtenioltraquoh)laquontwraquocenr
USA) IOl-raquo5-2 phenol (13fi) U3-31-3 indeno(l73-cd)oraquorrie
(MB) I2raquo-OO-0 pyrene RASENCimiAL COMPOUNDS
VCH-ATUL5 ( I B ) 13-32- raquoclaquonraquophtflaquorgte
(58) 12-I7-J benzidire (2V) 107-02-1 bullcrolem
(IB) 120-J7-I 1 2k-tr icnlorobenzene (3V) 107-13-1 acrvlonitr UP
(IB) 11U7I-I heKicMorobtnzme (raquoV) 7I-A3-2 benzene
(176) 4772-1 hexcftla-oethtgte (4V) J4-23-5 campr~toon TeTrscftlo itit
(116) III-- bii(2-lttilorolaquothv iVether (7V) lOt-W-7 chlocobenieo
(2C5gt raquol-3l-7 2-cM oroolaquo ptittu lene (10V) I07-O4-2 1 2-dicrtloreetranr
(23B) raquo5-30-l 12-dichlarobenime ( 1 I V ) 71-33-4 11 1 -tricMoroethr
(24 B) 31-73-1 1 3-ltl icJgt lor obcn i ene (13V) 73-3^-3 1 1 -dicMoroeth^i
(27B) 104-^4-7 1 4-dich lorobenzergte ( t k V ) n-00-3 11 2-tncfiloroetvlaquorie
(215) 91901 33-didMoroblaquozidinr (I3V) rraquo-3k-3 l122-tetrraquoOMo-oethne
(335) 121-I-2 2-dinitrotoluergte (ItV) 73JW-3 chloroethjin
(3461 (0420-2 24-dinitrotoluene (19V) 110-73-1 2-cMoroethraquo|vuiv| trgteshy
(37 B1 122-44-7 12-diphenylhydrnine (23V) 47-44-3 ctiloroform
(316) 204- Jgt tluarmrnhene lt2V) 73-35-4 1 1 -^iCMoroeThe^f
(C6) 7003-77-3 -chlorophenyl poenyl ether (gtOV) 154-40-5 trraquonraquo-l2-dicrloroltthene
(bull16) 101-35-3 raquo-6romophenyl phenyl ether (32V) 7I-I7-3 l2^ipoundMoroproBirgte
(raquo26) 3H3I-32- bit (2-cMarobopropvt) ether (33V) 1 004 1-02 -4 trmni-l^-dictilwoproom
(OB) l l l - raquo l - l bis (2-cMeroethoxv) methane 1004 1-0 1-05 cu-13-laquoicMoroprooe^e
(J2BI D-U-3 rraquolaquoeftlorobutraquodilaquooe (JJV) IOOJM- rttylbenzene
(336) 77 -raquo7- hezactilarocyclooentadiene (WV) 75-OT-2 methylene cniorifle
(56) 7raquo-3raquo-l ao ph or one (raquo5V) 7raquoJ7-3 eMoromeirune
(33B) JI-20-3 nraquophtMlene (UV) 7raquoJ3-raquo bromomethAftf
1X6) n-raquov) nitrobtnxerw (raquo7V) 7J-25-2
(CB1 14-30-4 J -ltii TT o vxJ ipheny U rru rraquo ^UV) 75-27- bro mod i cfilor o me t r)e
(CB) 47I-U-7 N-nnrotodipropylraquomJne (tV) 75-4raquo- 11 uor o tr i cMor o me t htgte (US) V17-1I-7 bu (2-eifrrlhryl)praquogtttilaquoUMshy 69 000 (30V) 75-71-1 di cti tor odl1 1 van m^i rajgtr
(476) U-U-7 benzyl buryl phihiUte 890 (31V) 12laquo-kraquo-l cMorodbremof^etNrr (US) U-7I-2 di-n-burvl prittuUre (13V) 127-lt- Uraquo6gt 117-t-0 dJ-laquo-ocTvl phttviUre (UV) IOLtS-3 Wluenr
(75) u-w djrrhylphtnltt ( i rv) 71-01-4
(715) t J I - l l - 3 dimnhrl pfthUte (UVI 73-01- viny l CMcriOr
(779) J4-35-3 0laquoMo(UnthrraquoCflaquoe
C a d m i u m 130 Chromium 20 ZINC 170
o nnn Z-UUU
^0(^ Trace
All results are expressed as ugg weight as received No en
APPENDIX E
PLATES
I I I I I I I I I i Plate 10-1 Troy Mills Landfill with a backhoe excavation
in progress in a former drum burial area
I I I
I I I I I I I I
I I Plate 20-1 NAI field investigation team preparing for
Level B activities during the drum excavation task Troy Mills Landfill
I I I
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
I I I I I I I I
I I Plate 20-3 NAI field investigation team member undergoing
personal decontamination at the hot line Troy Mills Landfill
I 1 I
I I I I I I
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
1
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
I
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
I I I
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
I I I I I I I I I I I 1 I Plate 53-3 Pigmentsludge deposits interbedded with
soil layers in Excavation 8A Troy Mills
I Landfill
1
PLATES
Plate 10-1 Troy Mills Landfill with a backhoe excavation in progress in a former drum burial area
Plate 20-1 NAI field investigation team preparing for Level B activities during the drum excavation task Troy Mills Landfill
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
Plate 20-3 NAI field investigation team member undergoing personal decontamination at the hot line Troy Mills Landfill
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
Plate 53-3 Pigmentsludge deposits interbedded with soil layers in Excavation 8A Troy Mills Landfill
VI
10 INTRODUCTION
As a part of a phased program to investigate potential ground
and surface water contamination associated with the Troy Mills Inc
landfill Normandeau Associates Inc (NAI) has completed a waste
characterization at portions of the landfill that were formerly used for
the disposal of steel drums containing wastes (See Plate 10-1 for site
overview) The objectives of this phase of study included
1 Delineation of the horizontal extent of the drum burial area
2 Estimate ofthe number of drums
3 Characterization of the physical condition of the drums
4 Assessment of the contents of the drums and
5 Assessment of potential for ground water contamination
6 Development of a remedial action plan for the site
The work involved developing and implementing an extensive
site safety program conducting a magnetometer survey digging a series
of test pits on randomly selected sites laboratory analyses of selected
samples of soil and waste and formulation of a remedial action plan for
the site
The Troy Mills landfill is roughly eight acres in total area
and divided into two main sections One section is currently being
operated as a solid waste (non-hazardous) disposal area for fabric
scraps and trimmings as well as other non-hazardous materials such as
wood and broken tools The solid waste landfill covers about six acres
of the site An estimated three acres presently contain deposits of
solid waste and about three acres are being prepared for future
disposal A closed former steel drum burial area is the second section
occupying about two acres of the site The drum burial area is now
covered with soil and a light cover crop of grasses The drum burial
area received wastes between 1968 and 1978 The disposed drums are
reported to have contained various materials including waste
plasticisers pigments and organic solvents
Previous site investigations by NAI have included site
reconnaissance studies test pitting water quality analyses (NAI report
of August 12 1981) geophysical (seismic refraction and electrical
resistivity) investigations (NAI report of December 1981) installation
of a ground water monitoring system (4 wells) and sampling and analyses
of ground and surface water samples (NAI report of July 1982) A water
budget analysis was performed to assess the leachate generation
potential of the site (NAI report of September 1982) Concurrent with
the study of the drum burial area additional seismic refraction lines
were conducted and three additional ground water monitoring wells were
installed to further assess leachates from the solid waste
(non-hazardous) portion of the site
Laboratory Analyses were conducted by Resource Analysts Inc
(RAI) We also wish to acknowledge the assistance and cooperation
provided by the management and personnel of Troy Mills especially
Messrs Barrett Ripley and Carl Patten
20 SAFETY PLAN
A Bureau of Hazardous Waste approved safety plan for on-site
activities was developed for the waste characterization phase of work
because of the potential for encountering hazardous materials The
safety plan is presented in Appendix A of this report It assesses the
overall degree of hazard identifies specific potential hazardous
situations and presents guidelines for personnel protection and action
levels as required The plan was made available to all field personnel
during the field work
The magnetic and topographic surveys were considered to be low
hazard activities with a prescribed level of personnel protection (LPP)
of C or D depending on the results of air monitoring Level C proshy
tection involves wearing a full face respirator with organic vapor dust
combo cartridge Tyvek suit over work clothes rubber safety boots and
gloves Level D protection requires cotton coveralls or other work
clothes safety shoes safety glasses and possibly a Tyvek suit
During the drum excavation and sampling task which was
determined to be moderately hazardous Level B protection was preshy
scribed Level B protection requires that personnel wear SCBA (self
contained breathing apparatus) chemical resistance Tyvek suit steel-
toed rubber boots and gloves Plate 20-1 shows NAI personnel on the
site preparing for Level B activities Plates 20-2 and 20-3 show
personnel decontamination equipment and the hot line during the drum
excavation task
30 MAGNETIC SURVEY
To delineate the landfill area underlain by steel drums a
high resolution magnetic investigation was conducted by John F Kick
PhD consulting geophysicist The magnetic method was chosen over
other search methods because ferromagnetic substances (drums) were the
target objects and the majority of Troy Mills other wastes are
non-magnetic (largely fabric scraps) Dr Kicks report is presented in
Appendix C
Eighteen parallel rows of magnetic field measurements were
made along north-south lines The measurements were made at 10-foot
intervals along the rows This work resulted in a detailed contour plot
of the magnetic anomaly (Figure 1 in Appendix C) The source materials
which cause the magnetic anomalies do not usually directly underlie the
peak of the anomaly A shift is caused by the inclination of the
earths magnetic field and by dipolar effects Figure 30-1 shows NAls
delineation of probable source areas for the magnetic anomaly and
peripheral areas which may contain some magnetic source material The
plotted source area is generally the area between the peak of the
magnetic anomaly northward to the zero anomaly contour This is to
compensate for a southward shift of the peak of the magnetic anomaly
from the center of the source deposit The complex geometry of the
anomaly necessitated much interpolation between peaks and ridges
gt QJ
LJ LLj
ro U -r- X j_gt 0 QJ bullimdash -4-) QJ CJ bullrmdash o 1C
gtsj
-= QJ 3pound c
CT1 -a 3J +shygt
LO
^mdash 4
4-gt
^O gtbull
c
QJ ltmdash U ltT3 f - ~ 3 0 O C ll ro
QJ CJ rmdash -r
-0 -U ro QJ XI C O O1 Sshy (T3
Qshy pound
ro ro OJ E S_ ro QJ
mdash bullmdash O ro ti
rmdash J_3 CC3 U CU
mdash i-0
4_gt
ro
QJ H r^ C
~t
QJ QJI) (
QJ 1
Sshy E gt4-gt QJQJ C
JC bull-
r^ ro
bullmdash rshy c0) u
E in bullbullshy0 rshy
bullbull- bull(-gt s_ -o c O)s_ c QJ O Oshy U
3 O I)
c o toro srshy ro
DC -t-gt CO
o rO U i_
ro X a
imdash 3 O
-rshy -a
C QJ
rmdash
t^ C o
bullptrade
4^ CL -ishy s_ -o QJ -a Q lt
O J
oo
OJM bullH
rv i^^ 1 ^
bulla 03 ^0 I
1 I
bullH lt- T3
2 EH
0)AJ
aLU ca Q)
U
13 O en
O rmdash u
bullH 4Jltu c
0)M lt8
bull0 ltV
JJ ltV 0)c
bullH M
a I o
o V
Z 2 d ) 3NI13SVS UOiid 33NV1SIQ
40 TEST PIT EXCAVATION
41 WORK PLAN
A series of test pits were excavated in the Troy landfill for
observation and sampling More specifically the purpose of the
excavation was to estimate the number and distribution of drums buried
in the landfill determine the condition of the drums (full empty
crushed rusted leaking etc) identify types of buried and drummed
waste and verify the results of the magnetometer survey A stratified
random sampling method was used to choose 10 locations within the
delineated area of magnetic source material This insured that
excavations were distributed randomly across the landfill and that the
resulting data could be evaluated with a level of statistical
reliability Excavations were also selected in areas on either side of
the anomaly which were considered free of buried magnetic material and
also where drums were visible at the landfill surface
The following procedure was used in choosing the locations for
the random excavations The center of the delineated area of magnetic
source material was used as a base line The base line was drawn onto a
map of the source material (Figure 30-1) and then divided into ten
60-foot long segments Using a random numbers table a point-distance
was located on each segment (designated the random station) and a
line drawn at that point perpendicular to the base line segment Again
using a random numbers table a point-distance (designated the random
offset) measured along the perpendicular line located the point of
excavation The grid coordinates for each excavation were graphically
determined from the grid overlay and then field-located from the
surveyed grid intersections Grid coordinates and selection data are
presented in Table 41-1
It was judged that 10 excavations in the delineated area of
magnetic source material and two excavations out of the area would be
sufficient to characterize the site would produce statistically valid
TABLE 41-1 RANDOMLY SELECTED EXCAVATION SITES TROY MILLS LANDFILL TROY NEW HAMPSHIRE
BASELINE RANDOM RANDOM EXCAVATION GRID SEGMENT STATION OFFSET
NUMBER COORDINATE (FEET) fFEET) (FEET)
1 7E+15 65N 0-60 26 16
2 9E+5 13S 60-120 110 9
3 8E+0 31S 120-180 140 7
4 4E+5 48S 180-240 230 26
5 3E+8 45S 240-300 254 20
6 OE+8 45S 300-360 394 50
7 2W+15 24N 360-420 465 14
8 5W+6 42N 420-480 518 20
9 6V+14 74N 480-540 548 7
10 8W+5110N 540-600 611 31
Locations are plotted on Map in Figure 30-1
data and could be expected to be completed within a scheduled 2-3 day
work period
42 FIELD WORK
Test pit excavation was conducted in two phases On the first
day each of the 10 random locations (Excavation 1 through 10 Figure
30-1) was probed to a depth of 2 feet using hand shovels On the
second and third days excavation was conducted using a combination of
hand shovelling and power backhoe The NAI field investigation team
consisted of six members Four of the team members were equipped to
work at Level B for work in and near the actual test pit excavation
(See Plate 42-1) The other two team members spent much of their time
with personnel and equipment decontamination and refilling compressed
air bottles at the hot line Mr Timothy W Drew an engineer of the
New Hampshire Bureau of Hazardous Waste Management was present during
most probing and excavation work Mr Robert Lynch an experienced
Level B equipment operator of Jet-Line Services Inc operated a power
backhoe which was provided by Troy Mills Inc
An average excavation size using the backhoe was approximately
7-feet wide and 10-feet long Excavation continued downward until drums
were encountered or to a minimum depth of five feet Drums were careshy
fully uncovered and fully described A total of 17 samples were
obtained from uncontainerized wastes (solids dried sludges pigments
stained soil) and where possible from drums using EPA sampling methods
and protocols All of the excavations were backfilled upon completion
of this task
Each sample consisted of one filled 8-ounce glass jar sealed
with a Teflon-lined lid Samples were submitted to Resource Analysts
Inc (RAI) Laboratory in Hampton Falls NH for priority pollutant
analysis
Air monitoring was conducted during each excavation using a
Foxboro Century Flame lonization Organic Vapor Analyzer (OVA) an HNU
Systems photo-ionization detector (HNU) and an MSA combined oxygen and
explosimeter High explosimeter measurements were considered cause for
an immediate halt in exploratory work in the interest of personnel
safety
10
50 RESULTS
51 GENERAL
On November 17 1983 Excavations 1 through 10 were initiated
using hand shovels to a depth of approximately two feet A total of
two buried drums were discovered Excavation 13 was completed and a
third partially buried drum uncovered On November 21 1983
Excavations 1 through 9 were completed and on November 23 1983
Excavations 7A 8A 10 11 12 and 14 were completed An additional
42 drums were uncovered on the last two days of excavation
Excavation Locations Seventeen test pit excavations were
completed at locations which are shown on Figure 30-1 Two pits were
excavated at three of the locations Noteworthy aspects of the
excavation operation are
Excavations 1 through 10 were randomly located in the area of delineated magnetic source material (on-anomaly)
One excavation connected Excavations 4 and 5 This was done because of the proximity of Excavations 4 and 5
Excavation 7A was located immediately adjacent to Excavation 7 Excavation 7 was located on the boundary line of the anomaly and proceeded in a southerly direction off the area of delineated magnetic source material (off-anomaly) Excavation 7A was initiated in the opposite direction (north on-anomaly)
Excavation 8A was initiated one foot north of Excavation 8 after the latter was abandoned due to the detection of a potentially explosive drum
Excavations 11 and 12 were selected off-anomaly to the north and south (respectively) in areas considered to be free of buried magnetic material (drums)
Excavation 13 involved minor hand shovelling necessary to uncover a partially buried drum located on the periphery of the anomaly at the east end of the landfill
11
Excavation 14 was a surface scrape which extended from an exposed drum found to the south of the magnetic anomaly northward toward the anomaly
The details of each excavation are presented in Table 52-1
Drum Locations The excavation results support the
interpretation of the magnetometer survey with buried drums as the
source of the magnetic anomaly With the exception of a few strands of
wire found in Excavation 1 ferromagnetic materials other than drums
were not encountered during the test pit excavations
Drums were foundin 9 of the 10 excavations located in the
area of delineated magnetic source material (See Plate 51-1) No drums
were found in Excavations 11 and 12 located out of the area of
delineated magnetic source materials The location point for Excavation
7 was on the boundary of the anomaly Excavation 7 which proceeded
south away from the area of source materials was free of drums
Excavation 7A proceeding north toward the area of magnetic source
materials uncovered 6 drums Excavation 14 located just out of the
delineated area to the south produced unexpected results Five drums
were uncovered just under the surface in an area with low positive to
slightly negative total magnetic field values It is possible that
Excavation 14 was improperly located in the field If adjusted just 20
feet to the east it would be well into the delineated area It is also
possible that a negative dipole derived from the mass of material to the
southeast is cancelling positive readings at this location
Fill Material and Vegetation Cover and fill material was
predominantly fine to medium sand with an occasional boulder Till with
a siltclay component was also used as a cover particularly at
Excavations 6 and 7A This material was densely compacted and difficult
to dig through Excavations 7 11 and 12 each extending to a minimum
depth of 5 feet were characterized by uniform silt and fine to medium
sand and traces of dark discoloration Excavation 12 was located in
to a s
to LJ imdash O z
^ mdash re CM mdash(_ E CO O bull 4J LZ n (- _ E 0 c
o u L t ij-3 o agt w gt Xre JJ o c iomdash o
o
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mdash o tgt~ mdash CD
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1--30Z 4Jr e r e shyw E JJ
in O jj 01 o i-
i- agt n c i shy -mdash O gt E lA
O 0 (13 AJ O O X C es uJ o N
mdash mdash JT Ol t-
J J C I - C D laquo re O shyu
bull3 lt 0 3 N
bullmdash V c t C3 mdash a C S bull U r o
CO shygt bullA ^ mdash bull o
o - C Z
X =mdash Z O
mdash C 3 r e O -Z Z pound bullmdash re-JOlaquo C r e X
C c c gt r eC O r e J raquoZ o u r e X
mdash in X mdashl -CS-U fOCO
CJ EE lt- ~~ O
C T3 shy lt 0 t i re^ltmdash raquotrade-^t
mdash 3 O - C i C 3 mdashbull
^ v a c E gt = E mdash _gt re C J pound o y 5 O
rez O C3 - C
bdquo
O (T shyg shy =c _) 2 shyo mdash o
Q3 ^D 1- mdash C bullmdash mdash shy3 t = s ~amp lt Z ^ C N
c o r e mdash mdash c bull mdash o mdash bull _ mdash X 3 C c
mdash C T D O lt C o c o mdash gt mdash laquoomdash
JJpound J c
o
xo obullo w c-i-C C i-re o re O CO shy3 0 J
XbullOCcoW
t- 0) shygt bull tfl bull = B E 3 laquo Obull
3 mdashraquo O W i- o re c re a bull- shy 3 gt
XbullOCreVI
Q t-
03 pound mdash U
0 L- (8
X a s ar e gt Emdash COC i O O
mdash gt shyc laquo- O raquo bull t- mdash CO
X c - gt c c i shy r e w O t r e
mdash re X i- - z ^E l - IC C3O
Z cJ Xt E J r mdash o in trade re ^ cc U pound -gt
^ mdashJ O ^ 11 CSLJ - gt ^ c olt- c umdash C CT-3 O B 3= mdashmdash z - ^r mdash c = s J
mdash laquo f j 3 -3mdash O
pound mdash z = J 3 3 S O laquo
s re -re mdashmdash ~mdash gt
cO t 3 r e C - ^ laquo gtC ltshy O gt mdash Z CD o c re mdash rei 3 u
O C S li = i U) x^shy mdash x x r z r e JO w L J C ^ 3 i
mdashi
a
IS shyJmdash _jii) OS
aa I i
a 1 1
a 1 1 O
a
z CC w ^ 1raquo oo o o
CM o o
zx
o
ltamdashZLraquo
pound a o
^ 3 Z
Q a mdash mdash
o rmdash IA
i 0
QoOIA
a mdash
lA r~ r~
a mdash o CO
amdashoCOttrade
Q o o
laquobull
O
o o 1mdash
i ia o o lA
i
Z mdash m
CO CO
h_
0^zmdash
^
S c-c_ 1_
0 a mdash mdash 0
o O ro mdash 1
O O
0o CM1
a mdash
O O
Q
O O
1
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oO-
Q o o
lA 1
Q _
o o
1
WO
O
Q O
lA 1
gt o
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O0
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v o3- V
CM
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mdash =^ a
S 5^ 0lt r ~ ~
1 1 1 a- lA
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1 mdash a z ZO o mdash Ui-
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r-CM
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mdash K ^
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cs shyo L ^ t-oshy0 ~ CMr-
J c~1
Vi UuL
laquof~
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bull- t-
^ LL ^
K f- Ci bull-bull
shy shyU LJ LJ
rr shyo laquot- t_
O ^~ O c
CM Q
mdash c-Omdash
^
^V f-
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fc ^ aa L 1_ ou C- C
1
w
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X L
raquo( CC-mdash
LJ
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mdash
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ltr s _3 OK
CVJ CM ro
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ro bull-CM
ro 1 VO laquomdash
z o
r-Q
I C
o X UJ
poundo| s~a
a CM CVI CVJ fO lA CM 1 lA lt-
a o
o mdash LJ o raquomdash L
lt ^^ gt lt UJ C N X mdash _ in
o X o X CO
f)XCOXr-
X CM
bull-X ot^
ro X ^y X O rmdash
rXlAXOv
CM X
00 X
CM V
ro X ~
0
lAX roX o
mdashX
00X
o
r-X
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z C o
lt a
lt 5 rmdash fl ro ^ -~
I O C- 83 ^ ~
lt gt- CO
X
0 O
13
E
23
eo ETC CU
gt i- Nlt (_ mdash
E O i-
lt~o ON dgt
N Q) mdash
i-tt) gtOO
bullDC
gt 0) C
T3 O
-D C CD
tgt
-U mdash mdash
C5
E 33
E-0 gtgts-O CD mdash T3 1- N JO ( =
0 0 U - O C5 t- t-ushy ro L jj bull
3 C 0 gtgt cnmdash 4J mdash
bullD CD bull C E E
I t -
lt Q 0)eo i c
lt mdash
mdash L
aagt E C CO mdash
CO i-W CO
bull obullDmdash 0
gtgt mdash
re bull E bulllt-gt
gtgt mdash
CD bull E-0
L W O lt tu en i-fgt c O Q
gtgt0 3 O mdash 4-gt i C
CD X -o eo E 0
w co CD bullO 4J COmdash ^ C d)CO O ^E 1 O W
co eo 4J bull
bull C CU ^ O ^
C O W
c eo Qeo mdash eo
t-JJ 0 E
o mdash c mdash
eo w
D C c eo CD laquo)
CO T3 0 4J Q) - C 0 mdash CO gt mdash E O w mdash
O 01shyC CU O O CD aw
CD O CO u- sshy amdash
re lt c eo cc c CD mdash CD 1- ltshy C C_ C re c co o - O X X CO CO3 gt CO 3 gt to E O O co O co CO 3 jt w O cfl 0) eo
cr LJ
LJ-J u mdash j CO 0amp5
a O 1 O
Q
1 1 i l
CD Dl bulla
CO _ mdash O D o
O ^ (A
ZX mdash Ld
O
en 3 10 O a
LJa a
Q 1 1 O
Q
+
O
X
_
mdash
o o I
gtgt O
h~Z
-^ 3
o0
mdash i-
1A 1
a a co agt C
LJ
sectK
Z= tM O 0 to bullo
X
mdashshyo
CD O
o mdash _ o
E umdash 3 E eo sshy
ltr-toZmdash
mdash s
0shy c
^
^ gt o
D o
a-rmdash
1
Q-
0 0oo r-V
tO 0
= mdash
O
tO 0
= mdash
O
Q O
O r-i O NO
1
awi
i mdash _ 3
Imdash I O
bullO C
1- 3 gt 0) bullo sshy co w
bullO CJ ID O X E C CU tt) bullw^ T3
w agt u C pound -gt
a a CO CD
mdash L 4J CD o gt
T3 gt C CO UJtt
2 mdash1 LJ Z) d CO 1 1
COO
~
lt O
~ I 1 1 I
Dl C 10 3 -D
lt - T J O
Dl C
1gt Omdash O bulllaquo Xl- i s o cu
Q lt3 toz cshy
mdash W f
r-B O c
mdashgtgt3 01O O u
W ID CO bullgt C -O mdash 4-gt 4-gt C
O -x mdash1 CO o CU c c co
1
OZ ZO o mdash Ol-
LJ -
L
0
1
C- bull 14 u- o laquoc~
bull mdash u bullDT3 O laquoccce tshy ^ D
l_ Cshy CCO O 0 0-0 Qmdash
CJ I- r-CM
1 1
U-Qshy
bull bullbull ^
O t_ 0 Q
-LJ
raquol
a o iT o c o
U) c
c u CD O
I I I CU c
Q) CJ CU W a ltshyon J2 o l- E E gt QCO CD O
I I I
ID JJ CU ES
J-gt imdash O Q Z CO w t --shy O mdash O 3 O laquoshy ^ c
_ICO a 0 0 0
^ sect5oa I-Q
CO X u_ y o- o=gtLJt-a
3shy
^
1
1
VO
m
1
i
1
t
_
3 lta i- U) 0 0
a
lA
lAbull
0 O
JI E oj3 gt E re mdash O X X co Qj
C 1 O
W 3
U L CO O
4J CO
0mdash CCD gt j ti --shy c JJ 4J
1- laquo 3 = C 3 or cu ogt tn Q -shy
E L n CD J-gt o o gt gt s o ---shyDior 3 3
mdash Tgt o cr cr mdash mdash CU 0)
o a CD -a OLJ U CU
N CU COT 4JT3 poundmdash 0gt U V
raquoT3 mdash agt OJ gtgtcu laquo c c
T3 O
C
C
Zlshyo ui u- Li ^ ^~bullgt lt LJ
lAXvOX
VO X ^ X
Xcjltshy
lA x
CM
O x
3shy
_ X
r^5 X
_ X
CM X
mdash c^ C3 O
c a bullbull o c c
mdash 4J O I I 4J
01 JJ 4J 1C laquo
3 t- C raquoJ O L (D CU C mdash o a~o mdash o
i i
C J J W CO II) O W IT OC N 03 = OJJ C O I- -= C O
I I
o o
ON X mdash
CMr-raquo
00 Orshy
X CO
vo ro O C 5) JJ Jshy I- I gtJZ-00 s a o
LJ CO eo UTJ a- I I O C X J O gtZ 1 re O
i CM
LA
LJ
O mdash c imdash LJ lt a gt y lt 2
ltCO O
O^mdash
laquoshy rmdash
CM Tmdash
n rmdash
_^jshymdash CO
LJ
j ^ |
52
14
what appeared to be natural materials although its location on the
cleared and leveled landfill tend to contradict this possibility
Most of the landfill is vegetated by a thin layer of grasses
sedges mosses and annual herbaceous species The northeast corner of
the landfill is unvegetated and cover material appears to have been more
recently applied This section is elevated 4 to 6 feet above the rest
of the landfill and appears to have received a second newer layer of
waste A 4-foot thick layer of carpet waste was encountered in
Excavation 1 but not in other excavations This section is adjacent to
the newer active landfill The landfill area just west of the access
road crossing (near Excavations 7A 8 and 8A) was also unvegetated due
to relatively recent grading operations
Ground Water The landfill appears well drained as ground
water was not encountered during any of the excavations Excavated
overburden was damp from the recent heavy rain but intergranular macro
pore spaces were free of water
OBSERVED QUANTITY AND CHARACTER OF DRUMS
A total of 45 drums were observed buried in the landfill
Table 52-1 presents a drum log describing each excavation and the
observed drums Data on the contents and condition of drums is
summarized in Table 52-2
Of the total drums observed 15 (33) were crushed flat
Although these could possibly still contain small amounts of waste they
are probably considered empty under RCRA guidelines Thirty (67) of
the total drums discovered were uncrushed and capable of containing
waste Seven (88) of the 8 drums sampled contained liquid or sludge
waste material Thus at least 7 (23) of the uncrushed drums contained
some liquid or sludge waste
15
en C Cl
bullo gtraquormdash
c mdash a
o c re bull mdash c
~ o mdashbull 4Jmdash
10 0 mdash
gt O
ro CO
fcshy0
c
C
vgt 3 0
1 rea
-gt
mdash
3 o T3
lt-O
C j C
CB 3 TJ ii i- 3 mdashQCOa
ifl u bull c c
t_ o
mdash shyO
mdash
L re N
co
t-O
mdash
mdash lfl
V) O
CO N CO pound re
0 mdash
^1 10
ltP O C raquo
CM reO
o f shyi O
mdash mdash 3 - D
c 1
CD bulllaquo
mdash3
D mdash
1 C
Q CO
CD Ifl 4-gt CO
Q
CM
r-
Ul
Q Ul gt EC Ul CJ CO o t5bullpound
z O mdash
C Ci o^
O Cbulla 3v iC MW5 CO 4J3 u CS- Ifl CBC J C O - U
gt Cgt Omdash Oi O
U- 0) Ifl bullgt-gt 1 W C
to lt-gtT3 gtmdash
0) gt shyJ 0)
C OltJ bull O T 3 C D C P
133mdash 4J bull ifl tshy Vgt~ V a O V4JJ
C o
C mdash
O Ifl
3 fc 0)
i-
c
U) re gt
ai C mdash
C mdash
CO gt c o
bull to y 3 cc Q
ltbull-CB
1 4Jin
bullD reCD jCJJC TJCD mdashbullD bull mdash
CD 0t- u iflo ifl
0 C ^-
CB laquo
3 ltbull-
0)^shy
C
0 Cgt O
1 O CTl C
T3 1 mdash CB O
mdash CB mdash in J o 3 tfl C ^ CO 0 gtltgtshy
O gtgtc 01
CO 3 1- mdash C Cregtmdash laquo
TJ W TJ mdash i re traquo-
shyU mdash
O Q
COCO^^
mdash ^
mdash gt C 0gt mdashO ~ bull
Ul
o auO
CCUl
mdash K o tO Ul Q
mdash OT30Jj c mdash4Jt- Jpound O Wre c i re03 gt
lt~i- laquo o ai
0 ) 3 gt O ^crc Ifl - CO -^mdash
3 mdash Q iflmdash 1- O 3 3
O V O ltraquo-o laquoTJ
gt
T3 - o
gtgtmdash J-gtmdash
Dmdash
6-o
09 bull mdash gtpoundbulllt-gt
re a
Ul X t5
Cpound O Z
fl) mdash^ C B gttflOl3T3T3l_ 3 Q)O mdash mdash
tn mdash
shyD CB
mdash mdash
mdash tt
CO C T3 poundi mdash JCmdash re
^ C O C X CB ^ - S - C C O mdash re O Q DW4shy
re shyu O 1
O Ul X EC Ul mdash
x a^s ox
CO
^) Z
J
1-o t-Ul X r-u 0
o j c gt T3 i -gt c tu mdash c u r e mdash
- C D mdash T3 - C M mdashbullOJJQmdash re3inecrec u c r e o mdash lt~ bullz c~4J O CX t ^Jw o r e -gtgtOgtgtshy3 c j t shy re mdash mdash ret- i o Qmdash gtgtpoundgt a
i reraquo CD 0) bullbull Ifl t-
Q ) t ) O pound O ^ laquo gt - Ow re re ro re re -gt Q mdashc 5 shyu a j-gt D t- raquomdash mdashCB C re C CO 3Q mdash O mdash O U
Htshy ae cu coo)
1 O i i
shya shyo j CD C bullgt o mdash c o c o coco mdash plusmngt o ~a v c en CD
mdash C O
raquoCJ 3C c re amp- ogtCD J o 3 CC C I-Omdash 3gt O
3
O ro
Ul X 1mdash
u O
Ul o r-Z Ul
gtV~ omdash Dlshy ^mdash mdash wre3 i cc
mdash cr bull gtJJ mdash C mdashi QIgtJ^re a shyJQI- o 0mdash
O bullO 3laquo laquo
jjmdash ureoO mdash O N 0)rc3recomdash4Jt-4JpoundmdashC C mdashmdash mdash u
1
shya 0 -
mdash gtgt re-raquo-gt CUD laquo E CD
^ J-1
CJ eoc
4JCB CO
mdash O
C 1- C mdash O C B C B C E J mdash J ltshy shyo cn o o c o r e c shyU -gtO OJC D ifl roc
T3 3 I U 3 laquo-
Ifl CD 1 W ^J 4 J 4 J c -aiflj jc
CB C r e O C B lt-gt -Jgtcoraquo C C -WE O O ) ~ O O O mdash O
Ul O
c ui =gt z
o
1-CC Ul Q
Q z ^ Ul
2 gt Ul O
o Cpound
^ CO
Ul Q ^
z o
(O U S Q
Slt
t5 lt
Z5O
1mdash z ui
Qa Ul
CD 0-1
u m O_J
O2^ltUl
O CC Ul Q
VOCO
CNlA |3
VO ^
CJ |CO |
CJ CMI3 f~ rojO VO rolo
^
ymdash3 CC
roCM
ro O ICNj
ro rolvO ro ro
ro A
rolvO r-jO
00 C3N
ec a m
r3
CO
3 a ty r-
cc Q
(M CM
to z
m 3 c O
u _i co
U-O
O 3-IObull - I c y
fshy lt- ICO r- r-ICM O U lfN ro -mdashla1 f~ laquo- ]CO bull- -ICM O O J|O O
c U) CO
mdashbullre re
mdash re
mdash i ltC c tz
j lt
i lt
5 0 0 G O o o o o z bullU 4J J h- J shyJ tmdash tmdash
^33
J3 3
O 3
Q 3
_Cr(bull
shyC 3 t)
CC IP y
C2 zgt c J
1mdash O 5
53
16
The condition of the uncrushed drums was highly variable with
only 4 (13) rusted and decomposed to the point of structural weakness
These drums were found in Excavation 10 at the far west end of the
landfill which is believed to be the oldest section (See Plate 52-1)
Interestingly two almost new looking drums were also found in
Excavation 10 at a greater depth than the four rusted drums The
remaining 26 drums were observed to be generally intact and structurally
sound Some were dented partially crushed or rusty
CHARACTER OF WASTES
Air Monitoring An OVA and HNU were used to monitor the air
for concentrations of organic vapors during each excavation Above
background instrument readings indicative of contamination were
regularly recorded when monitoring the air just above or inside of
drums A general contamination of the ambient air in the workspace was
noted only during Excavation 8A where above background readings of +13
in the excavation pit and of +6 above the excavation pit were recorded
Explosimeter readings were obtained from three drums -- 10 lower
explosive limit (LEL) from drum sample 10A 20 LEL from drum sample 6B
and 100 LEL from a drum in Excavation 8 Instrument readings are
presented in Table 52-1 and Table 53-1
Visual Observations The following types of waste were
observed during the excavations
fabric waste (carpet waste)
crushed drums
drummed waste - liquid sludge and solid
uncontainerized dried sludges and pigments
stained soils
Fabric waste scraps of synthetic non-woven fabrics5 heavy
carpet-like fabric and backing material were found only in Excavation
17
CM
CO LJ fmdash O z
laquo 4J
u TO 4-gt
c bullmdash
k bull mdash E mdash 3 3 i-^ O
mdash TJ --raquo co co 4J
E CO O U L U
E 3 c T3
C O a o
is
CO c to 3
U
TO
E O t_ U_
o o
1 ltmdash c
mdash tmdash TO 4J bull C TO 0 O o c u 3 TO
t_ 0) 0 4J
U)
mdashOTOgt
Cw bull aco jc
N 4J a
mdash L Q) re co T E
CO
bullo gt egt mdash c mdash bull o ^^73 C E gtO O mdash 3 J-gtmdash N 4J L 3 mdash 1--C gttTC bull
CX 01C JJ TO O mdash
TO trt mdash t- E mdash 3 JJ a O Q
C I 0 X E mdash C mdash CO
mdash o laquo (D-O mdash O O bullbull B Ol o -cmdash e oic f~ to a (gt TD mdash
E 1- Cpoundmdash 3 O O CO P m T1
L u
T3 CO
lto sshy0 O CA W
laquoT3 O CO 0 C J= CO tlaquo Q bull 3 O Ol 1- C o mdash 3 E a
3 E E i- to
Z L
mdash bull mdash O 4-3 Cl Q
bullD 0) CO T5 N CO mdash C -P 1 0 U TO O mdash 4J Cfc
mdash U) c shybullgt O w C O Q (5 4J 0
3 -J bull U)
5 gt TO_ U
bull gt pound mdash 3 mdash L ro TD
JJ-D - CO TO laquo QO
C 0
^ 0) T3 mdash O
r to 3
O O L L
0
01 TO gt bull
tshy mdash OT3 mdash
CD O C N U) O mdash
TO O CO mdash C C
bull^ ~ CO TO TO gt U iJ
mdash C W to O
5 c c 4J 3 CO X LJ
^ bull bull0 laquolt- ej
TO CJ CO mdash C JJ
z u to mdash T3 4J ai TO CD C laquo bull c c ugt o cr 0) bull mdash CO mdash O bull gt JC TO ^ mdash Q CO O JJ O Q bull- CO to mdash to c Z CC O il mdash 4J gt
mdash Omdash O1O CD mdash U) TO C X mdash O CO C L mdash Cvv O W pound G CO C C
O gtgtgt C C mdash CO C TO CO 3 E mdash -J laquo 1- bullgt CO 0 to
bullo CO
cshyo bull
ugt C CO TO c w 4J-Q co e a c
mdash re TO in E to
Q
JJ c bullo
a LJ co E bull LJLJ
O mdash zx ZQ
ax
z o mdash1mdash Q
mdasha o CO LJ a LJ ~J
s CO
JC u
bullmdash
^ 4J bull
bullO bullmdash
gtgt3 TO CT L mdash Olmdash 1 O CD mdash 3 a CT cshy re 3 a c- o
^j C CO E Ol
bullmdash CL
bull CO 01 D 3
U
T O a
E Ol
bullmdash av^ CO 4J IA TO 5
T3 CO C
bullD
mdash mdash O CO
3 CT
bullmdash ^
bulla CO L
4J
C CO o 3
(A C TO
Imdash
03
ai_ 3 a bullo bull mdash 05 3 O) 00
mdash mdash C c gtgt G CO
O O
bullo^ = c a 0)
E C O umdash u a L_ bull OlCD mdash
4J mdash
u) obulla o u) amp 5 c -a 7 O C mdash o mdash _ i- (0
CO E laquoJ
C
a
bulla c bull o bull
c bullQ CO
3 01
CT mdash mdash a mdash -v
t- Ol CC-D 0) 3
CJ raquo
x^ CO
bullo 3
lt) bull_
gtraquomdash CO O 1- Ui O)
bulla ^ c mdash mdash mdash TO co in
s^
COOlbullo3
U) mdash
gtgtmdashCO O1- U)Ol
T3
D C
mdash TO
i) ltgt
mdash mdash o
ltn
-D CO
c mdash
TO 4J
U)
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O
laquo_
o to
T3 to C
TO
U)
bullo ltr
1
03 shyogt
o wo LJtshy to
o z
CO d _l O LJ LJ _J hmdash J C- LJ XZampS LJ mdash
Q mdash
O
Q mdash
O
to o o
Q
O 1
to O
O
O
o CM
I 1 1 i
Q
ceo oz u lt
O CJ O-J
o ltDpound 15 t-
LJ K
1mdash 3E LJ
13
rshyC5 Z
y a Q ^
Z X
mdash s Cu a
gt 0
Q
mdash
Oini O CO
Q
O 0 CO 1 O O CM
O
r-
o
o r-
CO o
o
CO o
o
Q
O CO
a mdash o o T~
1 o
0 -~
o CO ~
Q mdashbull
O o or_
A
to 2T
f ro
CO X
O
Q
O O
Q
mdash O o o rmdash A
CO X
0 ON
CO X
o o ^
1
f
CO
o
to X
00
to X
CO
to X
CO
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19
c o C M O - L bull O C M bullmdash co ujn iiupeo CM
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20
1 (See Plate 53-1) This is the predominant waste material currently
being disposed of in the active landfill
Crushed drums were distributed throughout the original
landfill and were found in Excavations 2 4 4-5 7A 8A and 14 Some
drums such as those found under the road in Excavation 7A may have
been crushed by heavy equipment operating in the landfill Others like
those found at depth in sandy fill in Excavation 2 appear to have been
crushed before burial Drummed liquid and sludge wastes are also
distributed throughout the landfill (See Plate 53-2) They were found
in Excavations 1 4 5 6 8 and 10 These wastes are discussed below
One sealed drum was openedand found filled with refuse -- paper cups
towels paint covered rags etc One open and partially crushed drum
contained a dark granular solid waste This material was sampled
(Sample 10B) and found to be nonhazardous
Small deposits of dried pigmentsludge were found in
Excavations 3 4 6 9 and 13 Discernible layers of pigmentsludge and
stained soils were present in Excavations 7A 8 and 8A (See Plate
53-3) Of particular note was a 2 to 4-inch thick layer of
grey-colored dried sludge found at Excavations 7A and 8 All of these
wastes were sampled and the results are discussed below
Laboratory Analyses
Laboratory analyses were performed on 10 selected samples
obtained from both containerized (drummed) and uncontainerized wastes
Samples were analysed for 3 metals and 87 priority pollutants including
11 acid compounds 45 baseneutral compounds and 31 volatile organic
compounds Table 5-4 summarizes the analytical results and the
laboratory data sheets are presented in Appendix D
Of the 45 priority pollutant baseneutral compounds only 4
were identified in the samples that were analyzed Baseneutral
21
compounds and particularly phthalates were the most prevalent
chemicals and also were reported in the greatest concentrations The
highest levels of naphthalene (1200 ppm) bis (2-ethylhexyl) phthalate
(110000 ppm) and di-n-octyl phthalate (6200 ppm) were found in sample
4A a translucent red liquid obtained from a drum The highest
concentration of benzyl butyl phthalate (13000 ppm) was found in sample
6B a clear liquid and pink sludgepigment obtained from a drum
A total of 8 volatile organic compounds were identified The
highest levels of benzene (100 ppm) xylenes (19000 ppm) and
ethylbenzene (5300 ppm) were found in sample 5A a clear liquid
purple-grey sludge obtained from a drum Toluene was found in highest
concentration (12000 ppm) in sample 1A a purple-grey thick opaque
liquid obtained from a drum Methylene chloride (13 ppm) was
identified in greatest concentration in sample 8A-C a purple stained
soil and powdery waste Sample 10A a purple liquid obtained from a
drum was the only sample found to contain 1-1 dichloroethane (2000
ppm) Finally trace levels of trichloroethylene (sample 10A) and
111-trichloroethane (sample IB) were also reported
Samples were tested for three metals - cadmium zinc and
chromium The highest concentrations of cadmium (2200 ppm) and zinc
(5700 ppm) were found in sample 4A a translucent red liquid obtained
from a drum The highest level of chromium (52 ppm) was reported in
sample 5A a clear liquidpurple-grey sludge obtained from a drum
22
60 DISCUSSION
61 EXISTING SITUATION
Under existing conditions relatively small quantities of
volatile organic compounds (VOC) are indicated to be leaking from wastes
buried on the landfill site To date ground and surface water
monitoring results indicate relatively low concentrations of VOC in the
ground water and below detection limits in the adjacent brook (See
Tables 61-1 to 61-10) The results indicate that no potential health
risks from VOC and other constituents currently under observation are
being caused by the landfill operation to down stream surface water
users It would be prudent for Troy Mills to continue to monitor the
quality of Rockwood Brook upstream and downstream for VOC and on the
basis of waste analyses (previous section) to monitor ground and
surface water points for toxic metals and baseneutral compounds
62 SITE HYDROLOGY
An analysis of the hydrology of the landfill site was
performed in 1982 (NAI report of September 1982) The subwatershed that
contains the landfill site is (about 44 acres) a small fraction of the
watershed area that contributes to Rockwood Brook above surface water
sampling point C (about 1650 acres see Figure 62-1) This indicates
that most of the flow of the brook at point C (about 97) is contributed
by upstream watershed areas Thus leachate discharging into Rockwood
Brook from the landfill site can be expected to be diluted by over 30
times its volume This factor and the volatilization which naturally
occurs results in parameters detected in the Troy Mills monitoring
wells often becoming undetectable when they enter the brook
f 5
Geologic conditions which were defined in the NAI report of
July 1982 indicate that permeable deposits of sand and gravel overlie
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27
TABLE 61-5 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M5 (UPGRADIENT WELL)
Parameter Date Sampled 11-22-83
Specific conductance
pH2 81
Dissolved iron mg1 036
Dissolved manganese mg1 010
Chloride mg1 10
Phenolics mg1
3
023
Identified volatile organics
None identified ND
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (yg1)
28
TABLE 61-6 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M6
Parameter
Specific conductance
PH2
Dissolved iron mg1
Dissolved manganese mg1
Chloride mg1
Phenolies mg1
Identified volatile organics
11-dichloroethane tetrachloroethylene 111-trichloroethane
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vg1)
Date Sampled 11-22-83
152
lt002
29
6
0002
27 trace 140
29
TABLE 61-7 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M7
Parameter Date Sampled 11-22-83
1 47 Specific conductance
pH2 62
Dissolved iron mg1 002
Dissolved manganese mg1 0026
Chloride mg1 gt2
Phenolics mg1 0070
3 Identified volatile organics
111-trichloroethane 5
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vig1)
30
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34
glacial till and bedrock The sand and gravel deposits form a permeable
conduit through which leachate from the waste burial areas migrates
The permeable deposits lie in the area north of monitoring well M-l (See
Figure 62-1) In general the water saturated thickness of the sand
and gravel in the vicinity of the north-south access road is 6 to 12
feet
64 POTENTIAL FOR GROUND WATER CONTAMINATION
641 Estimated Quantity of Drums
The test pit excavation and sampling in the drum burial area
indicates a potential source of ground water contamination for the
future Many of the drums encountered were in fair to good condition
and contained liquid wastes An estimate of the number of drums in the
deposit was made with the following assumptions
1 The complex magnetic anomaly was simplified into a geometric solid 600 feet long 40 feet wide and 10 feet deep with a volume (V) of 240000 cubic feet
2 Each steel drum (D) occupies 105 cubic feet (including voids)
3 The density of packing (P) was assumed to be 50 of the packing that can be achieved with perfect cubic packing
THEN
N = estimated number of steel drums
N = (VD) (P)
N = (240000105) (05)
N = 11429 drums
The results of the drum excavation work provides a basis for
estimating the potential for specific types of chemical loading In
general three main classes of chemical substances were identified in
35
the drums The chemical substances included baseneutral extractable
organic compounds (mostly phthalates and lesser amounts of naphthalene)
volatile organic chemicals and metals
642 Phthalates
The phthalate esters found in the drums include
bis (2-ethylhexyl) phthalate ^0^3 benzyl butyl phthalate di-n-octyl phthalate Jd~7
Bis (2-ethylhexyl) phthalate was found in the highest
concentration at 110000 ppm (11 percent) Benzyl butyl phthalate is at
the second highest concentration 13000 ppm (13 percent)
Characteristics of those phthalates found are presented in Table 64-1
TABLE 64-1 PHYSICAL PROPERTIES OF PHTHALATE ESTERSshy
di-n-octyl bis (2-ethylhexyl) butyl benzyl DOP DEHP BBP
ALTERNATE o-Benzenedishy di (2-ethylhexyl) benzyl butyl NAMES carboxylic phthalate phthalate
Molecular Weight 3910 3910 312
Melting Point -25degC -50degC -35degC
Boiling Point 220degC 386 9degC 377degC
Vapor Pressure-mdash lt02 torr (150degC) lt001 torr (20degC)
Not
2xlO~7torr (20degC) Available
Solubility 3 rngfc (25degC) 04 mgfc (25degC)
58
13 rngH 48
Log octanolwater 92 873 58 partition coefficient 53 48
Versar Inc 1979 Water-Related Fate of 129 Priority Pollutants Volume II Prepared for US Environmental Protection Agency PBSO-20438 December
bullbullOther names listed in Versar 1979 vMore than one value has been calculatedreported
36
Bis (2-ethylhexyl) phthalate is the most well-studied of the
phthalate esters though the information on phthalate esters as a group
is limited The three phthalates identified at the Troy Mills site have
relatively low solubilities and are readily adsorbed onto suspended
particulates Microbial degradation is effective under aerobic
conditions bur is generally slower under anaerobic conditions
(nonexistent for bis (2-ethylhexyl) phthalate)
The above characteristics are important for two reasons One
the extent and nature of contaminant migration from the site are
dependent upon the physical characteristics Second the treatment
(clean-up) alternatives for contaminated ground water or soil can be
estimated from the characteristics
From the available information it appears that the phthalates
present at the Troy Mills site would be relatively immobile due to their
low solubilities and high adsorption rates The presence of toluene and
methylene chloride at the site however may increase the phthalates rate
of migration
It is important to note that none of the phthalates have been
found to be present in the monitoring wells nor in the surface water
sampled probably due to the low solubility and high adsorption rate
37
643 Napthalene u K r
Naphthalene has also been found in significant quantities in
the sampled drums Naphthalene is a polycyclic aromatic hydrocarbon and
has the following properties
Molecular Weight 12819
Melting Point 8055
Vapor Pressure (20degC) 00492 torr
Solubility in Water (25degC) 344 mgfc
317 mgfc
Log octanolwater partition coefficient 337
Versar 1979
Naphthalene has mid-range adsorption rates and solubility It is
therefore inferred that there would be some adsorption to soils in a
ground water environment It is important to note that naphthalene has
not been detected to date at the monitoring wells or the surface water
sampling locations This is expected to be a result of adsorption on
the soils
644 Volatile Organic Compounds
Volatile organic compounds tend to migrate readily within
soils and ground water They are therefore considered a threat to
surrounding ground and surface waters if they are released in sufficient
quantities
Volatile organic compounds were detected in samples from six
steel drums The total volatile organic (TVO) concentrations in the
38
wastes ranged from 9 ppm to 30100 ppm and averaged 8570 ppm In order
to determine the potential for future contamination by volatile organic
compounds an estimate of waste quantity based on information from the
drum excavation program was made It was assumed that 7000 steel drums
in the deposit are 60 full of liquid waste with an average TVO
concentration of 8570 ppm The computed volume of liquid waste is
231000 gallons with an average TVO concentration of 8570 ppm This is
equivalent to about 1980 gallons of pure TVO
Two of the volatile organic compounds that have been most
prevalent in the existing ground water monitoring system are
111-trichloroethane and ethylbenzene The EPA suggested no adverse
response level (SNARL) for 111-trichloroethane is 330 ugpound for
1 day of exposure and 35 jigd for exposure over a life-time in
drinking water
In general ethylbenzene is a prevalent chemical in the
environment Sources include commercial (eg petroleum and petroleum
by-products) motor vehicle exhaust and cigarette smoke An intake of
16 mgday (1 mgfc) has been calculated as an acceptable rate to
protect from toxic effects Carcinogenic effects have not been
identified to date The physical properties of ethylbenzene are
presented in Table 64-2 The principal mechanism for removal of
ethylbenzene from water is volatilization In addition to
volatilization adsorption may also be an important removal mechanism
based on the log octanolwater coefficient This factor is important in
evaluating the migration of ethylbenzene from the disposal site
Toluene which was also identified in waste and ground water
samples exhibits properties similar to ethylbenzene in that it
volatilizes easily Toluene which is also referred to as methylbenzene
is distinguished from benzene by the substitution of a methyl group for
one hydrogen atom Physical properties of it are presented in Table
39
64-2 The EPA suggested no adverse response level (SNARL) for toluene
is 1 mgpound in drinking water with a maximum exposure time of ten
days
TABLE 64-2 PHYSICAL PROPERTIES OF ETHYLBENZENE AND TOLUENE
ETHYLBENZENE TOLUENE
Molecular Weight 10616 9213
Melting Point -949degC -950degC
Boiling Point 1362degC 1106degC
Vapor Pressure at 20degC 7 torr 287 torr
Solubility in water at 20degC 152 mg2 5348 mgd
Log OctanolWater Partition Coefficient 315 269
645 Metals
One liquid sample contained high concentrations of cadmium
(2200 mgd) and zinc (5700 mgd) indicating that the waste deposit is
also a potential source of certain toxic metals Tests for these metals
have not been made to-date in ground or surface water samples It would
be prudent to add toxic metals such as cadmium chromium lead and
mercury to the list of parameters that are being monitored to further
characterize the quality of adjacent ground and surface waters US
EPA and New Hampshire drinking water standards for these metals are
cadmium 01 mgd chromium 05 mgpound lead 05 mgd mercury 002
mgd Although zinc is not considered a highly toxic metal the
US EPA has set a secondary drinking water maximum contaminant level of
5 mgd on this metal
40
70 CONCLUSIONS
The following conclusions were drawn during this
investigation
1 A steep-gradient irregular-shaped magnetic anomaly is present under closed and covered portions of the south part of the Troy Mills landfill
2 The magnetic anomaly is caused mostly by an irregular-shaped accumulation of disposed steel drums
3 In a randomly conducted sampling of drums in the source area for the magnetic anomaly 16 of the drums contained liquid andor sludge 33 were crushed flat and 51 were not sampled because there were no accessible openings
4 Laboratory analyses indicate that the random waste sampling contained significant concentrations of several volatile organic chemicals several baseneutral priority pollutants and high levels of cadmium and zinc
5 Observed concentrations of volatile organics at the monitoring wells are relatively low Because of their potential for migration in the ground water continued monitoring of volatile organics will be required
6 Volatile organic chemicals have not been detected in Rockwood Brook to-date Because of the presence of low levels of volatile organics in the ground water they should be monitored in the brook on a regular basis to confirm the lack of impact
7 The presence of high concentrations of cadmium and zinc in one of the waste samples indicates that trace metals should be monitored periodically
8 The presence of baseneutral extractable compounds (phthalates and naphthalene) in all of the analyzed waste samples indicates that these compounds should be monitored periodically
9 The phthalates are not expected to migrate freely because they have low solubilities and are readily adsorbed onto soil particles
10 If elevated concentrations of volatile organic compounds trace metals or baseneutral extractable compounds should occur in the monitoring system (wells and brook) in the future a need for site remedial actions to mitigate the potential for downgradient ground and surface water contamination could develop
~
80
41
RECOMMENDED PLAN
Based on the preceding conclusions it is recommended that the
following plan be implemented by Troy Mills Inc
1 Continue monitoring ground and surface water quality at the Troy Mills Inc landfill sampling on a quarterly basis with sample collections during April July October and January
2 To confirm the absence of the landfills impact on Rockwood Brook test samples for volatile organic compounds by GCMS from surface Stations B (upstream) and C (downstream) on the April and October samplings
3 To determine if trace metals are present in downgradient ground waters conduct analyses for cadmium chromium lead mercury and zinc on samples from all monitoring points during the April sampling and on subsequent sampling rounds if necessary
4 To confirm the continued absence of baseneutral extractable compounds in downgradient ground and surface waters conduct analyses for baseneutral extractable compounds on samples from monitoring wells M 2 and 3 and surface Station C (downstream) on the April sampling and on subsequent sampling rounds if necessary
5 If a sudden rise in concentrations toward unacceptable levels should occur in the monitoring system (wells and brook) additional monitoring rounds at a monthly interval should be conducted to confirm the rise in concentrations
6 If elevated concentrations persist and are verified by the additional monitoring remedial alternatives will be defined to mitigate the potential for downgradient ground and surface water contamination
Respectfully submitted NORMANDEAU ASSOCIATES INC
Dennis R Sasseville Project Manager
Donald H Bruehl f laquo | APG Senior Hydrogeologist -^ - - AIPG Certificate No 2272 ^ -v^
^^Z-^^
APPENDIX A
SITE SAFETY PLAN
GENERAL SAFETY PLAH FOR
TROT MILLS LANDFILL TROY MEW HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
Prepared by
NORMANDEAU ASSOCIATES INC Bedford New Hampshire
R-457
November 1983
TABLE OF COHTENTS
PAGE
SECTION 1 BACKGROUND INFORMATION 2
Identification 2 Personnel 2 Site Description 3 Project Description 5
SECTION 2 HAZARD EVALUATION 6
Overall Degree of Hazard 6 Specific Hazards 8 Necessary LPP 8
SECTION 3 FIRST AID FOR EXPOSURE 10
SECTION 4 OPERATIONS SAFETY PLAN 11
General Personnel Protection GuidelinesAction Levels 11 Site Reconnaissance 13 Task 1 - Magnetic Survey Topographic Survey 14 Task 2 - Drum excavation and Sampling 15
SECTION 5 EMERGENCY INFORMATION 16
Emergency Telephone Numbers 16 Route to Hospital 16 Contingency Plan 17
APPENDICES 18
A - LEVELS OF PERSONNEL PROTECTION 18 B - DECONTAMINATION PROCEDURES 23 C - PERSONNEL AND RESPONSIBILITIES 25 D - PERSONNEL CASUALTY 26 E - GUIDELINES FOR SITE OPERATIONS 27
GENERAL SAFETY PLAN FOR
TROY MILLS LANDFILL TROY NEraquo HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
The following is a Safety Plan for on-site activities performed
during the Investigation of the Troy Mills Landfill being conducted by
Normandeau Associates Inc (NAI) of Bedford New Hampshire
The document is intended to be an in house working guideline
for personnel trained and experienced in hazardous waste field work and
not a treatise on safety Familiarity with standard equipment and proshy
cedures is expected Where possible non-site specific information has
been appended
All NAI employees subcontractors and visitors will be required
to follow this safety procedure plan and to report to either NAIs proshy
ject manager (P M) on site coordinator (OSC) or safety officer (SO) on
issues relating to safety
SECTION 1
BACKGROUND INFORMATION
IDENTIFICATION
Site Name Trey Mills Landfill NAI-ID No 457
Trey Mills Inc Troy NH 03465
AddressLocation At the south end of the dirt road about 15 miles
south of Troy NH between Rockwood Brook and the
old Boston and Maine Railroad grade
County Cheshire Phone 603-242-7711
PERSONNEL
Brook Dupee Bureau Hazardous Waste 603-271-4611
State Contact John Regan Bureau Solid Waste 603-271-4586
Dan Allen WSPCC 603-271-2755
EPA Contact
Other Contacts
Client Contacts Barrett F Ripley (Vice President)
NAI Personnel - (472-5191)
Project Manager - Dennis Sasseville
On Site Coordinators - Alton Stone
Safety Officer - Elizabeth Gross (Phoenix Safety)
Technical Director - Don Bruehl
Other - Douglas DeNatale Steve Ransom
SITE DESCRIPTION
Type of Facility Company (on-site) landfill
RCRA Status Generator Disposer
Size About 15 acres BuildingsStructures None
Surrounding Land Use N Forested
(one mile radius) E Abandoned Railroad
Forest RuralResidential
S Forested
W Forested Mountain side
Unusual Features or Terrain None
Site Activities - Troy Mills manufactures textiles carpets and related
products Since 1968 waste materials including
drummed wastes have been landfilled on company proshy
perty Drums mostmany of which may be emptycrushed
are buried in an inactive section of the landfill
The active section is currently accepting waste
which is considered to be non hazardous
Specific - Improper disposal of hazardous waste
Problems - Leachate seep
Contamination of ground water
Hazardous WastesMaterials On-5ite
Wastes - Uncured foam rubber latex sludge
SBR rubber silicone defoamer potassium oleate soap
calcium carbonate and feldspar filters zinc oxide
and sulpher salt cure system
- Vinyl plastisol sludge
PVC dispersion resin DOP and DOA plasticiser
calcium carbonate filler organic pigments AZO
dicarbcnamid blowing agent zinc salts expoxidized
soybean oil cadmLum-bariin-zinc stabilizer Varsol
MEK prints and topcoats sludges
PVC acrylic resins organic and inorganic pigments
MEK solvent toluene silicate fillers
Industrial solvents and chemicals
11 -dichlorethane 12-dichlorothane
111-trichloroethane trichlorethylene tetrachshy
lorethene methylene chloride toluene benzene
ethylbenzene benzidine 33-dichlorobenzidine aeroshy
lein acrylonitrile napthalene benzoperylene dibenshy
zoanthrasene idenopyrene
Pesticides
There is a possibility for low levels of pesticides
to be on site These would include Chlorodane
heptachlor expoxide toxaphene aldrin alpha BHC
beta BHC 4-4-DDT endosulphan 1 heptachlor
PROJECT DESCRIPTION
Purpose Tb characterize ground water conditions at the site and to
characterize wastes buried on site
Specific Tasks
Site Reconnaisance
Task 1 - Magnetometer SurveyTopographic Survey
Task 2 - Excavation for inspection of drums
SECTION 2
HAZARD EVALUATION
Overall Degree of Hazard - Moderate
Task Hazard Proposed LPP
Site Reconnaissance Low Level C
Task 1 MagnetometerTopographic Surveys Low Level CD
Task 2 Drum ExcavationSampling Moderate Level B
Conpany records have indicated that a variety of industrial
and potentially hazardous wastes including drummed wastes
were disposed of on site Several of the subtances are
trade name materials or industrial process materials and it
is difficult to determine the specific chemical composition
Hazard is dependent upon concentration of material state of
material (solid sludge drummed liquid) and degree of
decomposition
Many of the materials - SBR rubber silicone defoamer
potassium oleate soap calcium carbonate and feldspar
fillers zinc oxide and sulpher salts plasticiser
calcium carbonate filler organicinorganic pigments AZO
dicarbonamid blowing agent epoxidized soy bean oil
cadmiura-bariun-zinc stabilizer - probably do not represent
a significant hazard to an inspection team if they are
bound into a sludge or solid Personnel are not likely
to injest or come into a prolonged high concentration
contact with these materials In powdered or dust conshy
ditions the materials are more hazardous due to the inhashy
lation of contaminated particulates
MEK (TLV-200ppm) toluene (TLV-100ppm) and Varsol
(turpentine thinner composition unknown) are volatile
organics which require respiratory protection and contact
protection
Depending upon state and decomposition PVC resins could
be a source of vinyl chloride monomer (VCM-a carcinogen)
requiring respiratory protection VCM is not adequately
filtered by air purifying respirators
Results from ground water sampling showed low levels of
industrial chemicals (PPB range) At these low conshy
centrations the chemicals do not represent a significant
hazard However the low concentrations in ground water indishy
cate the possibility of higher concentrations in the waste
materials
Industrial chemicals - napthalene (TLV-10 ppm) peryshy
lene anthrocene and pyrene which are hazardous
through inhalation or absorbtion Furthermore as
double benzene ring chemicals they are potential
carcinogens
Results from ground water sampling indicated possible
low levels (parts per trillion) of several pesticides
- chlorodane heptachlor epoxide toxaphene eldrin
Alpha BHC Beta BHC 4-4-DDT endosulphan These were
tentatively identified during a first analytical run
but not confirmed during a second run laboratory
review (GCA Bedford Mass) determined that the
material was actually a complex of highly degraded
heavy organics derived from the industrial waste The
presence of pesticides in industrial textile waste is
unlikely
Specific Hazards
1) Inhalation of organic vapors
Excavation of buried material and sampling of drums could
initiate high vapor concentrations
2) Fire and explosion
Many of the solvents are flammable liquids and volatile
Excavation of material and sampling of drums should
proceed cautiously in order to avoid rupturing shocking
or sparking of drums and material
3) Inhalation of contaminated dustparticulates
Excavation of buried material may result in a release of
particulates
4) Contact contamination
Excavation and sampling of wastes could possibly result in
contact with contaminated waste and soils necessitating
protective clothing
Necessary LPP
Site Reconnaissance - Level C The site has been visited on numerous
occassions by the state and private personnel Use of an HNU (102 ev
probe)- has not indicated significant vapor concentrations Significant
odors during dry weather or other hazards have not been noted
Sections of the landfill are currently active and adverse effects to
personnel have not been noted Level C - (tyveks rubber safety boots
organic vapor cartridges) is sufficient
Task 1 MagnetometerTopographic Survey - Level CD LPP will depend
upon the results of the Site Recon Significant vapor concentrations
or likelihood of particulates will necessitate an upgrade in the LPP
Otherwise Level D (work clothes safety boots boot wash) is sufficient
Task 2 Excavation and Sampling of Buried Drums - Level B The potenshy
tial for encountering significant concentrations of hazardous
materials during this task is moderately high Full Level B - (SCBA
chemical resistant tyveks hoods rubber safety boots rubber gloves)
will provide necessary respiratory and contactsplash protection
The use of the hooded yellow tyveck and the taping of ankleboots
wristsgloves and face maskhood junctions will provide complete conshy
tact protection
10
SECTION 3
FIRST AID FOR EXPOSURE
INHALATION OF VAPORSPARTICUIATES
Symptoms - eyenosethroat irritation nausea dizziness headache weakness fatigue lightheadedness drowsiness Loss of coordination confusion vomiting cramps (These sympshytoms are similar for most organic vapors particularly solvents)
Treatment Mild Exposure - Bring victim to fresh air Rinse eyes and throat if
irritated Heavy Exposure - (victim vomits very dizzy groggy faints etc)
Bring victim to fresh air Evacuate to hospital Prepare to administer CPR
Victim should be monitored for 48 hours in case of a delayed reaction
CONTACT EXPOSURE
Symptoms - Itching burning redness of skin Severe contact exposure for certain solvents will progress to CNS (central nervous system) symptoms similar to those for inhalation
Treatment - Remove contaminated clothing flush with water dry and banshydage Monitor victim for CNS symptoms for at least 48 hours
FIRST AIDSAFETY EQUIPMENT
The following equipment will be stationed at the Hotline or when appropriate down range
- Fully equipped first aid kit - Oxygen bottlekit - Nine (9) Ib chemical fire extinguisher - Eyewash bottle or other pressurized water filled container
11
SECTION 4
OPERATIONS SAFETY PLAN
This section outlines the specifics of safety procedures to be
used during each phase of the operations Safety procedures may be
upgraded or downgraded during site activities pending monitored changes
in the working environment All changes will be in line with the
General Level of Personnel Protection GuidelinesAction Levels for the
Troy Mills Landfill On-Site Investigation as described below
General Personnel Protection GuidelinesAction Levels
An in depth review of levels of personnel protection (LPP) is
presented in Appendix A
Level B (SCBA cotton coveralls or work clothes yellow tyveks (chemical resistant) steel toed rubber boots or work boots with disposhysible over boots and gloves)
Vapor concentrations (as measured on an OVA or HNU 117 EV Probe) greater than 5 ppm above background
- Oxygen deficient atmospheres less than 195
Specific actions (ie excavationsampling of drums) which could initiate a sudden moderate or high concentration of vapor
Level C (full face respirator organic vapor dust combo cartridge tyveks over work clothscoverails rubber safety boots gloves)
Vapor concentrations above an established clean zone backshyground level
During conditions (natural or personnel induced) which result in high levels of dust (visable above background atmospheric concentrations of particulates)
Level C activities require continual air monitoring
12
Level D (cotton coveralls or other work clothes safety shoes and safety glasses when down range Tyveks may also be needed)
Support areas and downrange areas where a higher LPP has not been deemed necessary
Continual air monitoring in downrange areas
Explosive Atmospheres
- 20 LEL (lower explosive limit) as recorded by an explosishymeter Secure and evacuate the work area
Oxygen Deficient Atmospheres
- Less than 195 (by volume) oxygen atmosphere requires upgrading the level of Personnel Protection to Level B
Task Specific Safety Plans
Levels of Personnel Protection indicated for specific tasks below are those which are anticipated to be used Changes in site conshyditions and results of air monitoring may indicate the upgrade downgrade of the LPP
13
Site Reconnaissance (SR) Date Sept 21 1983
Purpose To review on-site conditions and determine LPP necessary for further tasks To evaluate safety hazards Preliminary planning of future tasks
LPP - Initially Level C Updowngrade as necessary
Equipment - OVA HNU (102 ev probe)
Hotline - End of access road Upwind if possible
Command PostFirst Aid - Behind Hotline
Decontamination - Boot wash
Operations
Three man team Two persons advance in front with instrushyments Third person at distance as backup
Team methodically sweeps (criss cross) the proposed work areas with instruments
Specific points of interest (leachate seeps etc) are closely checked
All information is loggedsketch mapped
Upgraded LPP as necessary
14
Task 1 - Magnetic Survey Topographic Survey Date Week of October 3 1983
Purpose - Determine the location(s) and extent of buried drums Provide topographic information for site base map
LPP - Level CD
Hotline - End of access road (upwind if possible)
Decontamination - Boot wash
Operations - SO or other NAI personnel will perform a brief safety sweep of the work area
- Work team will then proceed downrange at the appropriate LPP Using the magnetometer the team will systematically criss cross -the work area
Task 2 - Drum Excavation and Sampling Date Week of November 14 1983
Purpose - Excavationsampling of buried drums in order to characterize the condition of the drums and the nature of the wastes conshytained in the drums and buried in the landfill
Msthod - Backhoe and hand labor will be used to uncover the drums in specified locations Samples will be obtained from spillage or leakage around the drums and of contaninated soil Selected drums which have accessible and openable bungs may be opened and sampled Drums will not be moved or staged Clean drums will be available to receive any significant spillage during the opening and sampling
Specific Hazards - Inhalation of organic vapors - Fire and explosion of drummed waste - Contact with contaminated waste or soil
LPP - Full Level B protection Backhoe operator at Level B Backshyhoe equipped with splash shield and without teeth on bucket
Hotline - At the end of the access road Upwind if possible
Decontamination - Procedures will essentially follow those as outlined by the EPA for Level B work Due to the inaccessibility of the site a field shower will not be available See Appendix B
Safety Equipment - OVA HNU eyewash fire extinguisher oxygen kit first aid kit metal detector non sparking implements
15
Operations - The cover soil is very sandy and the drums appear to be buried close to the surface which should facilitate excavation
- Minimum of 4 man team (exclusive of backhoe operator) Two or three man downrange team for digging and sampling One or two men in supportbackup at hotline
- Personnel will hand dig several small holes to approximately one (1) foot depth in each Location area If drums are not encountered the backhoe will scrape off soil to that depth
- Excavation will proceed alternating hand and backhoe methods At depths below four (4) feet the sides of the pit must be angled back to less than 45deg
- Prior to opening a closed drum the backhoe will nudgebump the drum to check for shock sensitive material An alternate method will be to attach a length of rope to the drum and from a distance pull on the rope to jog the drum
mdash Backhoe The backhoe operator will work at Level B utilizing air supplied from a large cylinder attached to the backhoe The backhoe will also be equipped with a splash shield A scraping bucket without teeth will be used
Prior to backhoe excavation at each location the area where the backhoe will be stationed will be checked for drums which could be ruptured by the backhoe feet
f Excavation areas will be checked for drums utilizing hand excavations or a metal detector prior to removing material by machine
16
SECTION 5
EMERGENCY INFORMATION
Emergency Telephone Numbers
If calling one of these numbers please state NAME LOCATION
and type of PROBLEM
Local Emergency Support
Fire Department (Troy 242-7759) For all emergencies use
Ambulance 352-1100 Mutual Aid (Keene) 352-1100
Police Department (Troy 242-7992)
Hospital 352-4111 (Cheshire Hospital in Keene)
Town Clerk 242-3845 State Agencies
NH Bureau of Hazardous Waste Management 271-4608
NH Water Supply and Pollution Control Commission 271-3503
NH Fire Marshall Office 271-3336
NH State Police (24-Hour Dispatch) 1-800-852-3411
Other
US EPA (24-Hour Hotline) 617-223-7265
Poison Center Mary Hitchcock Hospital 1-800-562-8236
Route to Hospital
- Follow dirt access road to Bowkerville Road - Left on Bowkerville Road to Rt 12 - Left (north) on Rt 12 through Troy to Keene NH - At major junction of Rts 9 10 101 and 12 go straight through
into Keene - At common go half-way around and go right on Court Street - Hospital is at 580 Court Street
17
Contingency Plan
Signal - five (5) one second blasts of auto or air horn Action - All personnel immediately excavate dovmrange areas and
report to Hotline for instructions
Personnel Unexplained Fire (if small) Accident (serious) Collapse of Personnel
Evacuate area Emergency ^ ^Evacuation Evacuate Area
First Aid
Estimate Explosion Level B (for Potential Contact Outside Help evcavation)
Evacuate Victim i If
Level B Prepare for Transportation
1 First AidCPR Use extinguisher Transport
Contact Outside Help Notify Coup any Have Proper Information Personnel (see below) 1
Transport
Call Fire Dept (if necessary)
For Hospital Victim
- Name and Phone of family physician
- Description of Incident chemicals involved symptoms nature of injury proposed treatment and plan of transportation
18
APPENDIX A
LEVELS OF PERSONNEL PROTECTION
Because of the possible dangers of exposure to toxic or harmshyful chemicals protective equipment must be worn during work on hazardous waste sites Levels of Personnel Protection (LPP) describe respiratory clothing and other equipment necessary for protecting personnel against expected hazards
The descriptions below are for full dress at a given LPP where hazards are expected to be at a maximum for which the given LPP is conshysidered adequate Depending on site conditions and work activities the clothing and dress requirements of a given LPP are commonly modified
LEVEL A
1 Personal Protection Equipment
Positive Pressure SCBA (MSHANIOSH approved) Operated in the positive pressure mode
Totally Encapsulating Suit (boots and gloves attached)
Gloves - Inner (tight fitting and chemical resistant)
- Boots - Chemical - protective steel toe and shank Depending on suit boot construction worn over suit boot
- Gloves shy Outer chemical-resistanttion worn over suit gloves May bchemical-resistant gloves worn insid
Dependinge replaced withe suit glo
on s
ves
uit construcshy tight-fitting
- Underwear shy Cotton long-John type
- Hard Hat (under suit)
- Disposable protective suitover encapsulating suit)
gloves and boots (Worn under or
- Coveralls (under suit)
- 2-way Radio Communications
Optional
19
2 Criteria for Use
A The type and concentration of toxic substances are known and require the highest level of combined protection to the respirashytory tract skin and eyes These conditions would be
1 Atmospheres which are immediately dangerous to life and health (IDLH)
a IDLHs can be found in the NIOSHOSHAs Pocket Guide to Chemical Hazards andor other references
2 Known atmospheres or potential situations that would effect the skin or eyes or could be absorbed into the body through these surfaces in toxic quantities
a Potential situations are those where vapors may be generated or splashing may occur through site activities
b Standard reference books should be consulted to obtain concentrations hazardous to skin eyes or mucous memshybranes
3 Oxygen deficient atmospheres with above conditions
3 At sites where the type andor potential concentration of toxic substances are unknown
1 Unless circumstances strongly indicate otherwise the site should be presumed to present hazards to the respiratory system skin and eyes Level A protection would provide the highest level of protection for the initial entry team
a Such circumstances might be
1 Environmental measurements contiguous to the site
2 Reliable accurate historical data
3 Open unconfined areas
4 Minimal probability of vapors presence or splashing with cutaneous effecting substances
2 Enclosed areas such as buildings railroad cars ships holds etc
20
LEVEL B
1 Personal Protective Equipment
Positive Pressure SCBA (MSHANIOSH approved) operated in the positive pressure mode
- Hooded chemical-resistant suit
Gloves - Outer chemical-protective
Gloves - Inner tight-fitting chemical-resistant
Boots - Outer (chemical-protective heavy rubber disposables)
Boots - Inner (chemical-protective steel toe and shank)
2-way Radio Communications
Hard Hat
Face Shield
2 Criteria for Use
A The type and concentration of hazardous substances are known and require the highest degree of respiratory protective but a lower level of skin protection
1 Atmospheres which are immediately dangerous to life and health (IDLH) Type and concentration of vapors in air do not present a hazard to the small unprotected areas of the body
2 Atmospheres with concentrations of known substances greater than protection factors associated with full-face air-purifying respirators with appropriate cartridges
3 Atmospheres with less than 195 oxygen
B When a determination is made that potential exposure to the body parts not protected by a fully encapsulated suit (primarily neck ears etc) is highly unlikely
1 Known absence of cutaneous or percutaneous hazards
2 Activities performed preclude splashing of individuals
C Level B protection is recommended as the lowest level of protecshytion for initial entries until the hazards have been further identified and defined by monitoring sampling and other reliable methods of analysis and personnel protection equipment commensurate with these findings utilized
21
LEVEL C
1 Personal Protective Equipment
Full-face or half-face air purifying respirator (MSHANIOSH approved)
Chemical-resistant clothing
Gloves - Outer (chemical-protective)
Gloves - Inner (tight-fitting chemical-resistant type (or woven liners)
Hard Hat (face shield optional)
Boots - Outer (chemical-protective heavy rubber throw aways)
Boots - Inner (chemical-protective steel toe and shank)
2-way radio comnunications
Safety glasses required with half-face respirator
2 Criteria for Use
A Site known to contain potentially hazardous materials exceeding
1 Air concentrations requiring a protection factor no greater than that afforded by a full-face mask
2 Harmful levels to unprotected body areas (face neck etc)
3 Well-documented reliable history of site and patterns of prior entry
C No evidence to suspect acute or chronic toxicity to exposed personnel
D Continuous air or personnel monitoring should occur while wearing Level C protection
22
LEVEL D
1 Person Protective Equipment
Chemical resistant aprons
BootsShoes - Safety or chemical-resistant steel toed boots
Boots - Outer (chemical-protective heavy rubber throw-away)
Half-face respirators immediately available
Safety glasses or safety goggles
Gloves
2 Criteria for Use
a No indication of airborne health hazards present
b No gross indications above background on the photoionizer andor organic vapor analyzer
c Continuous air or personnel monitoring should occur while wearing Level D protection
23
APPENDIX B
DECONTAMIHATION PROCEDURES
Depending upon activities and location on site it may be
necessary for personnel to decontaminate prior to leaving the conshy
taminated zone Procedures described below are typical for Level C
operations
Upon exiting downrange (contaminated) areas all personnel are
required to decontaminate by means of the following procedure
1 Place equipment in the Drop Zone at the Hotline
2 Enter the Decontamination Station
Boot Wash Walk through wash tub and scrub boots then rinse boots in second tube
Glove Wash In two pan wash scrub over gloves rinse set out to dry
2 Remove tyvek - if leaving the contamination reduction zone (CRZ) and proceed to clean zones
3 Dispose of heavily contaminated clothing and under gloves
4 Remove respirator
5 Use disposable gloves to clean equipment
6 Use a two bucket (washrinse) to decon respirators at the end of the working day or if they become heavily contami nated
The procedures for a typical Level B Decontamination are
outlined on the following page
TANK CHANGE 9
CONTAMINATION REDUCTION
ZONE
OUTER GLOVE REMOVAL
EXCLUSION ZONE
TAPE REMOVAL
BOOT COVER
GLOVE WASH
(bull)mdashQ-G--copyshySOOT COVEH SCOT COVES 4
REMOVAL GLOVE RINSE
SUITSAFETY BOOT WASH
SU1TSC8A78OOTGLOVE RINSE
SAFETY BOOT 10 REMOVAL
SCSA BACKPACK REMOVAL
SPLASH SUIT 12 REMOVAL
INNER GLOVE WASH
INNER GLOVE RINSE
FACE PIECE REMOVAL
INNER GLOVE 16 I REMOVAL
INNER CLOTHING REMOVAL
FIEUJ 19 REDRESS WASH
SEGREGATED EQUIPMENT
OROP
mdash -HOTLINE-shy
DECONTAMINATION LAYOUT LEVEL B PROTECTION
FIGURE A2-1
CONTAMINATION CONTROLLING
SUPPORT ZONE
25
APPENDIX C
PERSOHNEL AND RESPONSIBILITIES
Project Manager (PM)
Overall responsibility for all Project activates budget
schedule investigative operations safety personnel
On Site Coordinator (OSC)
Responsibility for activities at the site Primary responshy
sibilities include
1) Interfacing with the client state EPA media or other groups
2) Reviewing technical operations
3) Reviewing site safety in particular information supplied by the Site Safety Officer
4) Enforcing site safety and compliance with the Safety Plan
5) Directing Emergency Contingency operations
Safety Officer (SO)
Responsibility for directing the safety of operations and impleshy
menting the Safety Plan Specific responsibilities include
1 Assuring that appropriate personnel protective equipment is available and properly utilized by all site personnel
2 Assuring that personnel are aware of the provisions of this plan are instructed in the work practices necessary to ensure safety and in planned procedures for dealing with emergencies
3 Assuring that personnel are aware of the potential hazards associated with site operations
4 Supervising the monitoring of safety performance by all pershysonnel to ensure that required work practices are employed
26
APPENDIX D
PERSOHHEL CASUALTY
Personnel casualty would most likely result from either chemical
contamination heat-related problems physical injury from accidents
(ie falling lacerations etc) in performing the work or a comshy
bination of one or more of the above The appropriate action depends on
the type of injury involved with the priority being to assist the
casualty as soon as possible without endangering other personnel
Riysical and heat-related injuries can and should be treated
immediately with appropriate first-aid measures and follow-up medical
attention if necessary The injured worker(s) shall immediately move
out of the hot zone or if necessary be moved out by fellow workers as
soon as possible The OSC and Safety Officer shall be notified immeshy
diately and shall recommend further measures as needed
Chemical-related injuries require a much more cautious approach
so as to keep casualties to a minimum If a worker injured by chemical
ejqgtosure is able he shall notify the nearest co-worker and leave the hot
zone immediately- The co-worker shall ensure that the OSC and Safety
Officer are immediately informed and shall accompany the casualty from
the hot zone to the decontamination zone The OSC and Safety Officer
shall determine the appropriate measure
27
APPENDIX E
GUIDELINES FOR SITE OPERATIONS
In order to deal with the potential dangers of exposure and conshy
tamination of a hazardous waste site three zones are delineated
according to the degree of hazard The three zones are 1) Downrange
or Contamination Zone 2 Contamination Reduction Zone (CRZ) 3) Support
or Clean Zone
Downrange or Contamination Zone
The Contamination Zone is the active work area of the site which
encortpasses the areas where there is a potential for exposure and in
which investigative activities will occur (drilling sampling etc)
Within the Contamination Zone the designated level of hazard will be
established necessitating the utilization of personnel protective
equipment
Hot spots are those areas Downrange where observations instrushy
ment readings or specific activities indicate a high probability of
closure or contamination and may require an upgrade in the LPP in the
vicinity of the Hot Spot
Contamination Reduction Zone
The CRZ is an area between the Downrange and Support Zones where
decontamination of equipment and personnel occurs
28
Personnel entering the CRZ shall wear protective clothing and
carry the respiratory protection required for entry within the
Contamination Zone
Personnel working within the CRZ shall remain cognizant of the
CRZ in order to be prepared for any need to increase their level of proshy
tection within the CRZ
A decontamination station will be located at the outer perimeter
of the CRZ All personnel who have been within the Hot lane shall pass
through a decontamination procedure prior to re-entering the Support
Zone
Support or Clean Zone
The Support Zone is the outer area and may be considered to be
clear of contamination potential The command post will be located
within the Support Zone
a) The Command Post will serve as the OSCs headquarters and
will be equipped with
1 Communications
2 Safety Plans
3 First Aid Supplies
4 Analytical Equipment
5 Safety Equipment
APPENDIX B
WORK PLAN
WORK PLAN FOR
TROY MILLS LANDFILL TROY NEW HAMPSHIRE
DRUM EXCAVATION AND SAMPLING
Prepared by
NORHANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
1933
WORX PLAN FOR
TKOt MILLS LANDFILL TROT NEW HAMPSHIRE
DRUM EXCAVATION AHD SAMPLING
DATS November 16-18 1983
PURPOSE
To determine the condition of drums (ie erroty or full
crushed rusted leaking etc) buried in the Troy Mills Landfill To
obtain representative samples toward identifying the types of materials
buried in the landfill This information will be used in the detershy
mination of the level of remedial action needed at the site
METHOD
Using the results of the magnetometer survey the (10) points
have been randomly chosen across the area where the buried drans are
expected to be found Each point is central to an Excavation Location
-- an area four (4) to six (6) feet in diameter which will be excavated
in order to characterize the condition of the drams and to obtain waste
sarples
Preliminary observations have indicated that many of the drums
may be buried within 1-2 feet of the surface Therefore the investigashy
tion will proceed in two phases
Phase 1 mdash Hand Excavation By digging several small holes in
each Location personnel will determine if drums are located within
about one to two feet of the surface If drums are encountered the
excavation will proceed by hand uncovering the dnris for evaluation and
sampling Where drums are not encountered near the surface excavation
at this location will be postponed until Phase 2
Phase 2 mdash HandBackhoe Excavation After all Locations have
been attempted during Phase 1 those Locations in which drums were not
encountered wall be further excavated using a combination of hand
backhoe digging
It is expected that one to two days will be necessary to
cor^piete each phase Depending upon the results of Phase 1 it may not
be necessary to iroleraent Phase 2
Spare drums will be on hand for containerizing any significant
spillage resulting from sampling efforts Excavation locations will be
identified with marked stakes and the holes will be backfilled at the
conclusion of the investigation
SPECIFICS
Excavation Locations (Holes)
Number of proposed excavations is ten (10)
Locations of excavations are presented in Appendix A
Hole Size mdash It is expected that a hole from four (4) feet to six (6) feet in diameter at the bottom (depth at which drums are encountered) will be sufficient to characterize the drums at each Location Deeper excavations will require increasingly large top diameters
Hole Depth -- Holes will be excavated to a maximum depth of six (6) feet Due to the sandy cover material the excavation of deeper holes is probably impractical from both safety and efficiency stand points
If after attempting excavation at each of t-ie 10 proposed
1ocatiors irums are not encountered within six (6) fet of the surf ice
in enough locations to characterize the site excavations nay be
attempted to depths greater than six (6) feet if scil stability permits
or a new set of sampling locations may be chosen
(Excavations to depths greater than six (6) feet require a
significant increase in work The sides of the hole crust be graded back
to less than 45deg in order to insure the safety of investigatorysampling
personnel It may also be necessary to employ bracing bulkheads etc
for trench support)
Excavation Identification
Proposed excavation Locations have been consecutively numbered
from 1 to 10 beginning at the east end of the landfill They will be
marked with numbered stakes
Excavation Methods
Phase 1 mdash Within each Location personnel will dig a nunber of
small holes - about one (1) foot in depth - to probe for drums If
druns are encountered they will continue to excavate until the drur3
are sufficiently uncovered for characterization
Phase 2 mdash After hand probing the Location with snail holes
the backhoe will remove cover material to the one (1) foot depth The
Location will then be probed to a two (2) foot depth before removing
further material Excavation will proceed alternating handprobing and
backhoe excavation until drums are encountered or the maximum six (6)
foot depth is reached
If excavations to depths greater than six (6) feet are undershy
taken they will proceed using the above method
Santnlea
Due to the effort involved in excavating and because conshycentrated waste samples are not expected to undergo rapid degradation it is considered expedient to obtain all readily available samples (exclusive of closed drum samples -- see belcw) These can then be submitted for laboratory characterization as determined by need and budget restrictions
An attempt will be trade to secure at least one sample froa each excavation in order to help characterize the distrishybution of waste materials across the site An attempt will also be made to secure samples of observably difshyferent materials
Sample Types and Mediums - Solid liquid and sludge samples are possible Samples will be obtained from in order of preference -- 1) leakage uncontainerized waste or contaminated soil 2) waste contained in open conshytainers - drum already has a hole or no top or other access point 3) sealed containers
The opening of closed containers will be considered if it is decided that it has not been possible to obtain a sufshyficient number of representative samples from the other mediums
Each sample will consist of two (2) 8-oz jars (with teflon-lids) filled about 23 full One jar will be for organic analysis and the other for inorganic analysis
Sanole Identification - Samples will be identified with a number corresponding to the Excavation Location and a letter Example if three samples were obtained from Location 2 they would be samples 2A 23 and 2C and Samples 2Ad 23d and 2Cd for duplicates
Sampling Methods and Volumes - 11 mm hollow glass tubing trowels disposable scoops will be available to obtain samples Samples tools will be disposed of or deconshytaminated between each sample
Drum Samples - If necessary an attempt will be cude to obtain samples from sealed drums Oily o^und non-rusted drums will be considered Bunjs rust be xn suitable conshydition -jo that the dram cm be openoi withrut cvis ing dainai -ind ca-i be resell od to pr-jvcrt l V-i 30
There wil l be no staging or movement of drums in order to faci l i tate sampling Only drums with accessible bungs will be considered for sampling
Procedure for Drum Sampling
1) Excavate around top of drum
2) Monitor air in the adjacent area
3) Chec for shock sensitive - Loop rope around top of drum stand at a distance give drum several hard jogs by pulling on the rope An alternative nethod is to lightly jog the drum with the backhoe bucket
4) If the drum is not upright place a catch basin under the bung
5) Open drum with bung wrench
6) Monitor the air atin bung
7) Sample drum -- liquids insert glass tube the fu l l length into the drum in order to obtain a column of the materials in the drum Solids use scoop to dig out material through the bung or use a sampling trowel
3) Reseal the dram
Spill Control
The possibility exists during the sampling and excavation for a
drum to be ruptured or otherwise have spillage Clean drums wil l be on
hand to receive significant spillage resulting frora sampling or excavashy
tion They will not be used for clean up of widespread uncontainerized
waste or existing leakage
Personnel
The work team will require four (4) persons (exclusive of the
backhoe opera tor) Trie downrange team will consist of three (3) persons
-- two (2) for d igg ing and sampl ing and on ( 1 ) for logging air moni shy
toring and photographing One (1) person will be at the hotline in
support mdash as safety backup person to fill air bottles to deconshy
taminate samoles to assist in decontamination of personnel
Documentation Logging
The following information will be recorded at each location
nmber of drums uncovered and the condition (crushed empty rusted
sealed etc) of each drum evidence of spillage or contaminated soil
labels on uncovered drums samples (time drum ID type description)
periodic air monitoring information depth at which specific events
occur or drums are buried soil condition presence of ground water
In addition photographs will be taken of specific events or
items of importance during each excavation and of each sampling incishy
dent The time description of subject photographer excavation
location and photo number will be logged for each photograph
Analytical Laboratories and Schedule
RAI Hampton NH
Initial schedule
Ten samples for GCrns for organic priority pollutants Samples may also be submitted for inorganic anlaysis or volatile organic analysis depending upon waste materials observed during the excavation
APPENDIX A
TABLE A-1 EXCAVATION LOCATIONS
EXCAVATION BASELINE RANDOM RANDOM
NUMBER GRID COORD SEGMENT STATIOH OFFSET
1 7E+1 565N 0- 60 26 (25) 16
2 9E+5 13S 60-120 50 (110) 9
3 8E+0 31S 120-180 20 (140) 7
4 4E+5 483 180-240 50 (230) 25
5 3E+3 45S 240-300 14 (254) 20
6 OE+6 5S 300-360 34 ( 334) 50
7 2W1 5 24N 360-420 45 (-155) 14
8 5W+6 42N 420-480 38 (518) 20
9 6W+1474N 480-540 8 (543) 7
10 8W 5 11011 540-600 11 (611) 31
Locations are plotted on Map A-1
Method of Choice A stratified random sampling method was used to choose 10 Excavation Locations within the magnetic anomaly
The axis of the magnetic anomaly was used as a base line and divided into ten 60 foot long segments Using a randora nirnbers table a distance along each secpent was chosen (Random Station) and a line drawn at that point perpendicular to the base line Again using a random numbers table a distance was located along each perpendicular line by measuring inward from the line denoting the edge of Area A (Random Offset) The Grid Coordinates for each of the Excavation Locations were graphically determined from the grid overlay (this overlay has been surveyed and intersections field located)
It was judged that 10 excavation locations within the magnetic zone and two outside of the zone would be sufficient to characterize the area would produce statistically valid iati and coli be expected to be co~letod within 2-3 days work period
to
80
cu0
cgtc
APPENDIX C
MAGNETIC INVESTIGATION TROY MILLS INC LANDFILL SITE
TROY NEW HAMPSHIRE
For
NORMANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
By
JOHN F KICK PhD GEOPHYSICIST
Box 6 Dunstable Massachusetts 01827
(617) 649-6650
Noverber 19S3
MAGNETIC INVESTIGATION
TROY MILLS INC LANDFILL SITE
TROY NEK HAMPSHIRE
INTRODUCTION
A high resolution ragnetic investigation was completed on the Troy
Mills Inc landfill site in Troy New Hampshire by John F Kick
Consulting Geophysicist The purpose of the investigation was to
delineate the extent of buried steel drums under closed portions of the
Troy Mills landfill The information is needed as a part of a study of
the landfill that is being conducted by Normandeau Associates Inc
FIELDKORK
Magnetometer measurements of total field intensity were made over an
area that was reported to contain buried steel drums and adjacent
landfilled areas that contained unknown waste materials The area of
investigation included capped and grassed closed areas along the south
margin of the landfill site and adjacent areas The fieldwork was
performed during October of 1983
Eighteen parallel rows of measurements were conducted along north-
south lines (using magnetic compass directions) A spacing of 20-feet
was used between rows and magnetometer measurements were made at 10-foot
intervals along the rows Greater intervals between measurements were
used at the ends of the rows and in periferal areas with low magnetic
-JF Kick 01shy
field gradients
A series of magnetic field measurements were made at an adjacent
base station throughout the survey to torn the basis for a daily
variation curve The base station was located at a site with typical low-
gradient background magnetic field intensity measurements
MAGNETIC SEARCH METHOD
Theory Magnetic search methods involve the detection and
measurement of anomalies in the Earths magnetic field caused by the
presence of materials with contrasting magnetic susceptibility Iron and
steel objects generally have very high magnetic susceptibility contrasts
with usual surrounding materials and therefore produce magnetic
anomalies The amplitude shape and detectable distance of the anomaly
depend mostly on the particular susceptibility contrast and size of the
object Magnetic anomalies are measured in units called gammas The
normal magnetic field in this area is over 50000 gammas A 5-inch
screwdriver will produce an anomaly of 5 to 10 gammas at a depth of 5
feet and an anomaly of 1 gamma at a depth of 10 feet A 1 ton automobile
will produce an anomaly of 40 gammas at a depth of 30 feet and an anomaly
of 1 gamma at a depth of 100 feet The magnitude of an anomaly caused by
a single steel drum will vary with its condition (new heavily rusted
etc) Tests using a single light weight (somewhat rusted) drum on the
surface with the magnetic detector at a height of of 12 feet produced an
anomaly in the range of 40 to 50 gammas
Total magnetic intensity disturbances or anomalies are almost always
asymmetrical sometimes appear complex even from simple sources and
usually exhibit the combined magnetic effects of several sources which
can produce a given anomaly The apparent complexity of such anomalies
is a result of several relatively simple functions of magnetic dipole
-JF Kick 02shy
behavior Reasonable assumptions about the geology and buried source
conbined with an understanding of magnetic dipole behavior can usually
lead to a satisfactory qualitative interpretation More detailed
interpretations nay require modeling studies
Instrumentation Field equipment on this project included a EGampG
Geometries Memory-Mag G-856 proton precession magnetmeter The
instrument has a resolution of +01 gamma The magnetic field detector
is separate from the rest of the instrument and is mounted on an 8-foot
staff to provide measurements that are a constant height above land
surface
Magnetic Data Analysis For the purposes of data reduction and
anomaly delineation it was assumed that base station total field
intensity measurements were typical background values for the site
Measurements made at frequent intervals at the base station were used to
prepare a diurnal variation curve for the site Anoraly values were
obtained by subtracting background values from the base station curve
from measurements collected in the area of investigation
RESULTS
The reduced results are presented in the form of a magnetic anomaly
contour map (Figure 1) and two profiles across the area of investigation
(Figures 2 and 3) The map and profiles show that very steep magnetic
field gradients and large departures form background occur in an
irregular shaped band that is about 460 feet long and ranges from about
30 to about 200 feet in width The magnitude of the anomaly is such that
a significant deposit of ferromagnetic materials (such as steel drums) is
indicated
In using the plotted magnetic results it should be noted that the
greatest concentrations of ferromagnetic materials probably do not
-JF Kick 03shy
directly underlie the peak magnetic anomalies A shift is caused by the
inclination of the Earths magnetic field and by the dipolar nature of
ferromagnetic deposits The inclination of the Earths field is about 76shy
degrees northward in the vicinity of Troy The dipolar effect is induced
by the Earths field and results in negative anomalies immediately north
of large positive anomalies
Magnetic Anomaly Map The magnetic anomaly map (Figure 1) indicates
10 positive peaks of varying size shape and intensity Associated
negative anomalies of a broader and less intense nature lie immediately
north of the belt of positive anomalies The configuration of the
anomalous area is indicative of lense-shaped and cigar-shaped bodies of
ferromagnetic materials Steep-sloped anomalies are indicative of very
shallow source materials The thickness of the ferromagnetic deposit
cannot be easily determined on the basis of intensity and size of
anomalous peaks because a small mass of iron or steel at the surface can
duplicate the anomaly caused by a much larger mass at depth The
ferromagnetic source materials can generally be expected to lie north of
the positive peak of anomalies and south of the adjacent negative
anomaly Modeling can provide the best approximations of the depth and
density of the ferromagnetic source materials The outer boundaries of
the source materials can be expected to overlap the positive peak and
negative anomaly somewhat depending on the depth and configuration of
the deposit
For illustration purposes two north-south rows that were profiled
are discussed below
Magnetic Anomaly Along Row 9-East Two strong positive magnetic
anomalies (3645 and 2436 gammas) and adjacent negative anomalies were
profiled along Row 9-East (Figure 2) The approximate centers of the
ferromagnetic deposits are believed to underlie stations 50 north and 75
feet south of the base line The rounded shape of the north positive
-JF Kick
anoraly nay indicate somewhat deeper burial of the ferromagnetic deposit
Magnetic Anomaly Alone Row 7-West Figure 3 shows the most intense
positive magnetic anomaly (4470 gammas) that was detected on this
project The steepeness of the slopes is indicative of very shallow
source materials An uneven burial pattern is suggested by the two-
peaked positive anoraly The negative anomaly south of the two peaks is
unusual and may be related to another positive anomaly to the southeast
(along Rows 5 and 6 20 feet north of the base line) The centers of the
sources of the positive anomalies are probably approximately 80 and 120
feet north of the base line along Row 7-West
-JF Kick 05shy
DISTANCE FROM BASE LINE(FEET)
CO
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S u
UI o
O Cgt mdash o
0020
UJ U
o o CJ
ro 8 LU
CC ID egt LL
APPENDIX D
LABORATORY ANALYSES
RAI
Resource Analysts Incorporated Box 4778 Hampton H 03842
(603) 92^7777
TO PO 830318
Mr Doug DeNatale Date Received 12-2-83 Kormandeau Associates 25 Nashua Road Lab Number 2887 Bedford NH 03102 J
Date Reported 1-3-84
IDENTIFICATION
SAMPLE DESIGNATION PARAMETER
Volatile Organics Analyses by EPA Method 624
Acid and BaseNeutral Extractable Compounds Analyzed by EPA Method 625
Metals Analyzed by Standard Methods 303A
Please see attachments for all results
Results expressed in mgL unless otherwise designated lt = Less Than
ClarkeFosterVan K o u w e i b r h 1 ANALYST DIRECTOR
METHODS Standard Methods (or the Examination ol Water and Waitewaler 15th Edition or other EPA approved mtlhodologiei unless otherwise designated
Phys ica l descr ip t ion of sample
LiquidSludop
Saiple workup
Volitile f ract ion Methannl F-1-rarMrm CSVJ Rdfi-Smm
Semivolatile f ra ictio0onication Extraction fSW 846-3540^ Inorganic f rac t on Acid Digestion (SW 84h-iOS(V)
ACS3 COMPOUNDS
rr t CAS CAS
(71 A) tt-Ot-2 i^t TT i^MoroprvrfgtOi (73B) 30-32-1
(23 A) J9-JO-7 ^bull^^ lof o^^ft^crt gto (7 OB) 205-M-2
(2 A) 13-37 -J 2- chlorophenol (75B) 207-01-
(3 A) 120-13-2 2raquo^icMoroorgtenol (748) 211-01-9
(MA) 103-47-9 2-dimethv lohenol (77 B) 201-94-1
(37A) U-73-3 2- niiroDhenol (7IB) 120-12-7
(MA) 100-02-7 raquo-niiroprienol (7raquoB) lraquol-2raquo-2
(raquoA) Jl-21-3 2 - in i tr opheno 1 (106) raquoi-73-7
(40 A) 33-J7-l k4-dinnro-2-mlaquothylplaquogtergtol (I IB) 15-01-1
(4A) I7-U-3 (xntictiloroorraquonol (I2B) J3-70-3
USA) 101-93-2 pxmol (I3B) 193-39-J
(14 B) 179-00-0 RASENEUTOAL COMPOUNDS
( I B ) 13-32- raquocmlaquophtgtgtefgtlaquo
(36) 92-173 benzidine (2V) 107-02-S
( I B ) I20-I2-I l2t-tricMorobenzlaquonlt (3V) 10713-1
OB) 111-71-1 he laquo laquoch 1 or o benz erve (laquoV) 71-A3-2
(176) 47-72-1 hetraquocWoroltthlaquone (4V) X-23-5
U S B ) 111-- bu(7-cloroetrivl)ether (7V) 101- 90-7
(7CB) 9 I -3J -7 2-Chlororuprthraquolene (10V) 107-04-2
(73B) 95-50-1 l2-diCMoroblaquonzene ( I 1 V ) 7|3j^
( K B ) XI-73-1 13-didilorobtnzene (13V) 7J-3-3
(27B) 104-M7 1tmdash djcMorobenzene dkV) 79-00-3
C2IS) 9i9i-l 33-dictgtloroblaquoazidinr ( I JV) laquo-3-J
(33B) 12I -U-7 2gt-dinicrotoluer (14V) 7J-00-3 (KB) 4O4-7C-7 24-dinitrotoluene (UV) 110-73-1 (J7B) 122-A4-7 1J -diprienv lhydrraquo z irf (23V) lt7 tt 3
(MB) Z0-fc-0 UuorraquonThelaquo (2raquoV) 7J-35-
(W551 700J77-3 -ctilorophenyl prlaquonyl ether (JOV) 1M-40-3
( raquo I 6 ) 10I-J3-3 raquo-6romoprgtefgtyl prtenyl ether (32V) 71-17-3
(raquo7B) 33132-9 bU (2-cMorobopropyl) ether (33V) 10041-02-4
(raquoJ6) i l l -91- l bu (2-laquo^loroeTho)ry) methane 10041-01-03
(B) D-U) hexraquopoundj1|orobutaltlicne (31 V) 100--
(33B) 77-raquo7- heiKCtilorocycIopentadicrve (WV) 7J-CT-2
OB) 7IJraquo-I traquoo oh or or (raquo3V) 7raquo-17-3
(J3B) gtl-20-3 nphthraquolene (UV) 7raquo-I3-9
(546) n-tj) nitrobenzene (7V) 7J-2J-7
(426) U-Xl-4 bullJ -n itr o tod iphenyU mi ne (UV) 75-27-J
(OR) 421-W-7 N-oitrcnodipropYlirrUne ^raquoraquoV) 73-49-k
(446) I 1 7 J I - 7 bu (2-eltr^lheryl) phtfaUte 8200 (3ov) 73-71-1
(476) 13-U7 benzyl buryl phttwlite (51V) 124-kt-l
( U B I M-71-2 di-fl-utgtl pMhUre (13V) 177-II-
( lraquo6) 117-1 -0 dj-n-octvl prithlaquoUte (UV) 101-IS-3
(7CB) W-44-2 dielhvlphtraquollaquo (17V) 79-OI-t
( 7 | B ) I 3 I - I I - J dj^laquorTvipnthraquoUtr (UV) 7J-OI- (776) H-J5-5 bnro(raquogtnthrraquocefvr
Iab I D N o 2SS-10
C l ien t ID 1A64223
RASENEUTRAL COMPOUNDS
bfzoltraquogtprrene
benzoltb)flucrraquornNene
benio(llaquo)fluorraquonthene
chryiene
bullcenaDhthvien
raquontnrraquoctne
benzoltghi)perrlefgte
Iluorene
phergtraquonthrmlaquo
dibenzoltraquoMaithrraquocenraquo
indeno(123-cd)pvrene
prrene
VOLATHES
(frolein
bullcrvlooitrdf
benien
orbon Temchloide
CMorobeniene
1 7-dJchlorolaquothnr
111-trieftloroethine
ll-ltJichloroetrufle ll7-triCilorigtetMrlaquor
l127-tetrraquocMorothfllaquo
chloroethlaquo-e
7-dMoroeThraquo|virgtvl eirwshy
chloroform
11-didMoro^tfwnr
trinj- 1 2-dictMorolaquoirgtene
1 7-ltlicMoroproplaquorve
trini- 1 3-ltJichloroorcrpeoe
cu-lJ-lieMorocT oo eashy
rthy Uveniene
methrlene chloridf
chloromethine
bromome thraquone
bro mod iCTi lore met Mrgt
(Juorotr ichloromthraquor
di cMlor od 1 f 1 uore ngtet hj^gt
chloreltJbnjmomethne
te tr ten 1 or oet rx-r
laquouene 12000
tncMeroethe^e
Cidrr ium Chromiutr 10
All results are expressed as ucg veicht as received Nc ertrv denotes -0r ~ ^ 1 i rt
P h y s i c a l d e s c r i p t i o n of
SoilSludge
sample
Sanple workup
Vol i t i le f ract ion p^r Exf- rar r ion fST7Semivola t i le f rac t ion So^h^Pt Fgtr f ra r f ion
846-SOTO^ (SWRdfi-^SiO1)
Inorganic fract ion Ar id nio-psrirm
AOD COMPOUNDS
m CAS (2i A) tt-04-2 2raquot- Wichlorophenol
(22 A) J1-50-7 p-cfi I or o-n-cre laquoo 1
(2A) 13-57-1 2- ctiloroprienol
O iA) 120-13-2 2raquo^icMoroprnol
(gtraquoA) 103-47-1 2f 4mdash^imetSv Ip^enol
(37 A) U-73-3 7mdash Ti j oprtenol
(JraquoA) 100-07-7 mdash mdasho i Br opr^e no 1
JJ1A) 31-21-3 if mdash4 irtiTroprienol
(40A) J34-32-1 4 T4-4initrogtmdash 7 nte tny Ipnenol
(4A) f y _H 5 plaquontchlaroorwnol
(43A) J 01-95-7 prienol
rV ipoundNEUTRAlaquo- COMPOUNDS
( I B ) raquoJ-32-raquo
(3B) 17-17-5
( IB) 170-12-1
(IB) 1I1-7I-I
(17B) 4777-1
( I t B ) 111--
(20B) 11-31-7
(236) 15-50-1
(245) 51-73-1
(77B) 104-4-7
(285) 11-14-1
(336) 121-142
(34B) 404-70-2
(J7B) 127-M7
O1B) 2O4--0
(406) 7003-72-3
(416) 101-35-3 lt raquo 2 6 gt 3H3I32-1 ltraquo36) 111-11-1 (57B) S7-U-3
(336) 77 -raquo7-
(36) 71-31-1
(33B) 11-20-3
pound34 6 1 n-i33 (UB) tt-30-4
(436) CI-44-7
(4461 117-11-7
(47B) U-417
( U B I 14-747
(U6) I17_t-0
(7CS) l-laquo2
(7 I B ) t J U t l - gt
(7761 54-55-3
CT-~- i_i w i Miirn 0
resul ts
b^TMdint
1 2 t-o- icn lorobenl ergtlaquo
SeTraquochloroblaquorierraquoe
hrxchlorolaquotSlaquone
bu(2-chloroethv|gtether
2 -lt3M or onraquo ph ti1 ene
1 2-ltJictilorotgtmzcne
13-dicWorotxerzene
1 4-djch 1 or otxn z ergte
33-ditfgtlorolgtlaquoniidirraquo
24-dinitrotoloene
2 4-dtnitro toluene
U-dlpoenylfiydrraquoiilaquo
(luoranthene
raquo-cfJorophenyl poenyl ether
Mx-omopfieflyl phenyl ether
bis (2-cMorooopropyt) ether
bu (2-ctilorcxtSorv) meiSkte
hezkOilorobutadicne
hei acM or ocyc1 ofMn udi cne
oo prior one
nphthlene
nurotxniene N -ni tro Kxd ipoenyU mi ne
N-rutrowxhpropYUmJrw
bu (2-thylherl)(gthlaquoiraquoUtraquo
blaquoniyl buryl phtfraquolaquoUte
dt-^t-^xjrvl pfttfuiLitY
dj-n-octyl pitflaquoLitraquo
dirthvl phtruUtt
OArriett^vt prraquoT^Lraquot
bnzoltklaquonihnicer
22 Chronium
ire ev^rescei as uc ^ ^i-~ht-
Lab 1U N o 28B-1
C l i en t I D 1 R R 7 A A R
RASpoundNEbTRAL COMPOUNDS
benroltb)fluorraquorgtthfflf
benzoraquollt)fluor intone
ltrylaquo-gte
bullcenioithylen
raquomtirraquoenlaquo
ben z oltxh i)per v lene
lloorene
poentnthrrne
dibnzo(4h)laquonthricrne
mdeno(I23-rt)pvre-ie
pyrene
VOLATU-Ei
bullcrelem
bullcrvlonio-Ue
benzene
caj-bon traquotrraquochloraquo-idr
Ctilorobernene
l2-diehlongtethne
iii-tnctltiorotKraquor Trace 1 T 1 -4)Ctilorampe^hArw
l f 1 ^-tric^i lor oefvtrve
l t l 22-teTrtclloroetl^Ane
ehloroethraquone
2-chloroltthr|viw| ttrve-
Chloroform
1 1 -ltSicMorot^nr
trinraquo-l2-dictiloroetrne
12-d^loropOStn
trinil3^ichloroproone
eis-lJ-diChloroprooene
rrhylberuene Tarce methrlene ehlor tat Trace
Ct1 or o m e t Kirgte
bromometKtrte
bro mod i rfi lor o rrgte t Mne
Uuorotrlchloromethraquo^e
OJ CJ lor od 1 f 1 uoro met hraquone
chJorodibromometKATgte
laquotrlaquociloroethrrx
toluene 9
tricolor otheir
fsw
T9
Sifi-TOSO)
(73B)
(7IB)
(75B)
(7(B)
(77 B)
(71 B)
(71B)
(SOB)
( t lB)
(I2B)
U3B)
(M B)
(7V)
(3V)
(4V)
(4V)
(7V)
(10V)
(11V)
(13V)
(14V)
(13V)
(14V)
(11V)
(23V)
(21V)
(30V)
(32V)
(33V)
(34V)
ltlaquoV)
( raquo J V )
(44 V)
f raquo 7 V )
(UV)
(V)
000 (30V)
Tlfl 151V)
(15V)
^00 (14V)
(17V)
(UVgt
-1 ZINT
CAS 30-32-J
205-11-7
207-01-1
211-01-1
201-14-1
120-12-7
111-24-2
14-73-7
13-01 -laquo
33-70-3
113-31-5
121-00-0
107-07-t
107-13-1
71-43-7
34-23-3
101-W-7
107-04-7
71-35-t
75-3-3
7^-00-5
71-34-5
75-00-3
110-73-1
(7-14-3
73-35-4
154-40-5
71-17-5
10041-07-6
10041-01-05
100-4I-
73-OT-2
74-17-3
74-13-1
73-25-2
75-27-4
73-41-4
75-71-1
174-41-1
127-U- IOUIS-) 71-01- 75-OI-
130
Lab ID Mo 2887-4
Phys i ca l d e s c r i p t i o n of sample C l i en t ID 4A5760
Liquid Sample was predominantlv a hvrlrnrarhnn bl pnd
Sanple workup Voli t i le f ract ion PEG Extraction (SW 846-5030) Scrnivola t ile f rac t ion Sonication Extraction (SW 846-3550) Inorganic f rac t ion Acid Digestion (SW 846-3050)
AC3D CS3U POUNDS 5AipoundNEUTlUgtJ- COMPOUNDS
ri CAS PPraquo CASf
(210 U-04-2 2raquot- tricMorophrnol (7)6) raquo-32-l braquoniolttVyre
[EM 51-50-7 ^-cti 1 or raquo-m-lt rlaquo laquoo 1 (7raquoB) 203-M-2 biMo(b)(luorinth^f
2 A) raquo5-57-J 2- cfiloropheryjl (7 3 B) 20701 benro(ilt) floor in tlaquo^e
(31 A) 120J3-2 2raquo-ltJicWoro(ygtlaquotx)l (74B) 2II-OI- chryve^e
(MA) 105-47- 2l-dimlaquothvloSrrgtol (77 B) 20Uraquot-J bullcwrioMhylene
(57A) u-73-3 2- ruTroohrgtol (TIB) 120-12-7 raquontnncergte
(34 A) 100-02-7 -oitrophenol (7gtB) lraquol-2raquo-2 benio(ghi)cgtrrylngtlaquo
(3Agt 51- 21-3 2 -4 initropherwl (SOB) tt-73-7 fluorme
(tOA) 53-37-l t-dinitro-2-mlaquothy lpNlaquoxil (II B) 15-01-4 pheAinthrrnlaquo
(A) I7-U-5 tgtentraquochlQroiywnol (I2B) 53-70-3 dibenplusmnoltraquoh)fcnthrraquocrne UJJ 101-55-2 rfwtwl (I3B) lraquo3-3raquo-3 indenol 1 23-cd)vrtie
(UB) I2raquo^X3-0 pyrer BASENEUTOAL COMPOUNDS
VOLATO-ES (161 I3-32- raquoclaquonraquophttgtngtf
(5B) 12-17 -J btniidir (2V) gt 07 -07-1 bullcrolem
(IB) 120-17-1 l^^iricfvleroboMux (3V) 107-13-1 bullcrvlonit Jlaquo (raquoBI IIS-7t| SeraquoChlorotgtlaquoterlaquo (raquoV) 7IJ3-7 benient
(I7S) 4772-1 heLCMorolaquothinc (tV) J-23-5 crtgton wtrraquocMoidf (UB) I11-U-I bll(2lttllorolaquot^w gtetNer (7V) 101-W-7 ltAtoroxniergtlaquo
(203) Jl-31-7 2 -etvl or onlaquo ph traquo I en e (IOV) 107-04-2 1 2-ltlicMorolaquoTKlaquone
(25B) raquo5-30-l 1 2-dichlorobenzene ( 1 1 V ) 71-JJ-t llI-trichlorolaquotNlaquoe (2 B) 31-73-1 l3-ltlichoroblaquonzenlaquo (13V) 7J-3A-) 1 1-6 1 cM or Of t (Mr
(77B) I04-M7 I -di CM oro ben z eoe ( I k V ) rraquo-oo-j l12-niichlorolaquotfvirraquolaquo
(2IB) raquol-raquo-l )J-dichlcroblaquorLiidinr (IJV) rgt-3laquo-3 J122-tetrraquochlcrolaquoTrie
(33B) 12I-Ilaquo 2 2-dinia-otoluer (UV) 73-00-3 Ctgtloroltthne U4B) laquoJ-70-7 2 t-dtnitrotoluene (1raquoV) HO-73-1 2-ltJilorocthv|vL-v| etrveshy
(J7B) 127-M7 14-dip^wnylhydraiine (23V) C7-U^-3 Ctilorofcrm
(JraquoBJ 2Ot-ugt-0 CJuarlLnthefe (2raquoV) 7J-33- 11 -ltlicMorcxil^nr
(mei TOCJ-77-3 -chJorophcnyl phenyl laquoKr (xgtvraquo lK-^0-3 tnjM-l^-diC^lofCKtl^nf
( M B I IOI-J5-3 -6romophnyl phenyl ether (32V) 7I-J7-3 12-dicMoroprosaA
(raquo2B) 3M3I32) bU (2-cMarobopropyU rtNer (3JV) ICXU 1-07-4 trraquoni- 1 3-ltjictgtloroBoor^f
(OB) t l l f l - 1 bi5 (2-cMoroetfxgtrv) meihtrw lOOt 1-01-03 cu-O-dichloroprose- (32B) D-U-3 hrxaetilorobutadierw (UV) 100-laquol-raquo rthylbenien 1^00
(33B) 77^7- he i kcMor ocyc 1 openudi crw (UV) 7J-OT-2 rrveThvlerw chlof idf
(36) 7I-gtraquo| oop^troo (raquoJV) 7raquoJ7-3 CtgtlorBmethne
(338) raquo|20-3 nraquopfitfillaquofx 1200 (wv) 7raquo-l3-raquo bromorrgtlaquothne
(34B) nraquo3) nitrobenzene (raquo7V) 73-23-2
(CBI U-Xl-4 N -fl i iro lod iphen yU mi nr (UV) 7J-27- bro mod i cti lor o mT bull- (OR) 42l^-7 N-^itrolaquoodipropylmlrlte (raquoraquoV) 73-traquo-laquo tl uor o tr i cfi lor o mlaquoT itr (UB) I I 7 J I - 7 bn (^thylheraquoy|) phttilaquoUtT 110000 (XIV) 75-71J QJ ct )or oltJ 1 f 1 uoro rrgtei ^bull gte U76) U-U7 blaquonzyl buryl pttTfKUie 12000 ( j i v ) m-i-i ctil or od ib ro mo met h xnf (UB) M-7i2 d i -n -bo TV 1 ft thlaquo U tlaquo (13V) 127-11- te trraquo cfl lor ot hlaquoTgtf (OBI 117-4J-0 dj -n -oc t y1 Jgth fflaquo U re 6 200 tuv) iom-3 tolucie ^70
(7CB) u-u- djrthyl phtJMlire (17V) 7raquo-OI-4 irictilarcraquo^lt-ir (715) 1 3 1 - 1 1 - 5 oVnrrhyl pMtfaUte (UV) 75-OI- v i M v l CMor idr
(T76I 5-55-3 blaquorgtzo( Unihrlaquocme Xylenes 1SOO
Cad- iurn 2 2 on Chromium - - Z I N C ^ ~ P r
Ai results arc expressed as ugc weight as received Xo entry denotes not detects
Lab ID No 2887-3 5A 57709 Phys ica l d e s c r i p t i o n of sample Cl ien t ID
LiquidSludge Liquid appeared to be a hvdrnc-Arhnn blonrl
Sample workup
Vol i t i l e f r ac t ion Methanol Extraction fSW 846-5030^ Semivolatile fract ion Sonicatlon Extraction fSW 84 f i_3550gt) Inorganic f rac t ion Acid nic-psr-inn fSW 846-30501
ACS3 COMPOUNDS BASENEUTRAL COMPOUNDS
f f t CAS CAS (2IA) tt-04-2 (738) JO-32-J DCftZ OTamp p V^^^ff
(22 A) 3laquo9-50-7 p-cttl or o-m-cre laquoo 1 (7VB) 205-99-2 p^^izot oil lyor 4-^ t ^ltf ^^
(2 A) raquo5-37-l 2- CJiloroprieno (75B) 207-01-9 blaquonioltllt)flultxtn^it
(31A) 120-13-2 2raquo-dictgtlcr8tgtrfX)l (74B) 211-01-9 Chryeolaquo
(3 A) 103-47-9 2 -d irrgtet hv Ipherto1 (77B) 201-94-1 laquocnphthyle^
(37 A) 11-73-5 2- rutrop^enol (7IB) 120-12-7 bull^thrjc c^
(MA) 100-02-7 -flitroprlaquorv3l (79B) 91-2-2 bcnroltKhi)pefraquoler
(79A) 31-21-3 2 -d in itr eoricno 1 (IOB) 14-73-7 tluoren
(40 A) 33-37-l 4-d in itr raquo-2 -met hy Iphtnol ( I IB) 13-01-1 poltrtAOthrvTgt^
(44 A) 17-14-3 plaquon1 CM or o^eno I (I2B) 33-70-3 dib^fi-o( 4(K)Aji thirl c c^f (43A) 101-93-7 prwnol (S3B) 193-39-3 indcnotlIJ-ctflsvfie
(SB) 129-00-0 pyrene ftASENEUTRAL COMPOUNDS
( I D )
(5B) 92-X7-3 b^zidrw (2V) 107-02-1 bullcrolrm
(IB) 120-17-1 1 2 fc-Tr ICJ caro blaquoni crw (3V) 107-13-1 bullcrvlonitrij
(93) 1IU7I1 Seraquochlcrotgttniegtlaquo (4V) 71J3-2 blaquonienlaquo inn (17B) 4777-1 hexat^lorcwthgine (4V) H-23-5 carbon ttTricllixidf
( I I B ) 111-wJ bll(2-lt3^1oroltt^w)ether (7V) 101-90-7 ciloroblaquonzene
(20B) 91-31-7 2-ctdo-ont she Ime (10V) 107-04-2 12-dieftloroerane (25B) 95-50-1 l2-dilorobenzene ( 1 1 V ) 71-35-4 11 1 -tricMorotn-laquo
(2ampSI 51-73-1 13-dicMo-obenxerw (13V) 73-3-3 1 1 -d i CM orcxt M-
(77 B) I04-H-7 1 -di ci 1 or o benI erw (UV) 79-00-3 llJ-WiChlorolaquoflaquonlaquo
(2J6) 91-90-1 SS-dKJilorotxniidinc (13V) rraquo-3laquo-3 l122-tetrlaquocftlorelaquoTrne
(35B) 12| |k-2 2fc-dintrotoluene (14V) 73-00-3 diloroeth^e
(gt4B1 404-20-2 24-diniTrotoluenlaquo (19V) 110-73-1 2-cMortxfthv|vL-raquo trlaquoshy
(37B) 122-447 12-diphenylhydriin (23V) 47-44-3 cMoroform
(J9B) 204-U-0 Ouormntherve (29V) 73-33-i ll-diCMorolaquot^nf
(fcOB) 7005-77-3 k-cMarophfy| prlaquonyl etScr (gtOV) 134-40-3 trraquonraquo- 1 2 -dicMoroc t Nenf
(raquo I6) 101-35) raquo-6romoprny| phenyl rther (32V) 71-17-3 12-diChloropostn
(raquo2B) JH3IO2-9 bU (2-ltplusmnlaronopropyl) rthrr (J3V) 10041-02-4 trni-l)-diirMoroxtgtOpnf
(OB) I I 1 - 9 I - I bu (Z-chloroethxjrv) metSampnlaquo 10041-01-05 CU-D-djcMoroproOf-W
(32B) 17 -U -3 hiraquocfilarobutraquodiergtlt (3JV) 100-4U rttyligtlaquonitrgtlaquo 5300 (33B) 77-raquo7-raquo hrxicftl or ocrclopei tidier (UV) 75-09-2 nxthylenf ctilor ifif
lt3B) 71-391 ao prior or (raquo3V) 7raquo-17-3 rtloromrtha^r
(356) 91-20-3 nlaquoprithienraquo Trace (44V) 7raquo1Jraquo bromltmlaquoth^
(MB) n-93) ft i vo b^nz c^^ (raquo7V) 73-23-2
(425) U-30-4 ^bullf i^OftOOL^ri^ny lArrunf (UV) 73-27- bro mod i cgt lor o i~ t gt
U3amp1 Ul-4-7 N i itr CrtoO ip ro py 1 laquo ml r (raquo9V) 73-49-k U uor o IT 1 et loront Mrgt (UB) II7-1I-7 bu (2-Ihythlaquoryl)prtfUtr 59J300 (30V) 73-71-1 dj ci kr olt11 f 1 uoro rrrt (Nrgtraquo
(47 B) L3-41-7 txniyl burvl phthlaquoUtr ( 3 1 V ) I2-1-1 ch1 or od i b ro mo mi IMP r
(UBI U-71- 0-A-fcurl BMMliw (13V) 127-ll-i rt tr t cM or of tNr
Uraquo6) 117-li-O di-n-oCTv| pnttlaquoUfr 6000 (UV) lOt-II-3 toluenf 5700 (7CB) U-447 djrthvl p^tfvilirt (17V) 79-01-4 WiCMoroth^e ( 7 J B I U l - l l - 3 d^M^vl prttgtraquoUW (UV) 73-01- vinv t cMor 10 (77 Bgt H-35-) brto(raquollaquonthncrTraquo Xylenes 19000
Caen 1U~ 1 Chromium =2 Z I N C
All results are expressed as up g weight as received No errrv ripn^t-plt
Lab 1Lgt No 2887-5
rhyr i r n l d e s c r i p t i o n o f sample C l i e n t in 6857710
LiquidSludge
Sample workup Vol i t i l e f r a c t i o n PEG Extraction (SW 846-5030) Semivolat i le fr action Sonication Extraction (SW 846-3550) Inorganic f rac t ionAcid Digestion (SW 846-3030)
AOD COMPOUNDS BAStNELTTRAL COMPOUNDS
rr i CASI CAS (21 A) tt-04-7 (736) 30-32-1 bntoltraquogtprrene
(23A) 3-9-50-7 p~lt1 or o-m-c rraquo1 (78) 205-99-2 ben to( Sgt )1 1 uor raquon I he-gtf
(7raquoA) 93-37J 2- etilorophenol (73B) 207-01-9 beriioltk)(luortntrgt^f
(3 IA) 170J3-2 2raquo-dicMoroprnol (7(B) 2II-OI-9 eifVMTie
(3 A) 03-(7-9 24-4mlaquoThvlDheno| (77B) 20l-9(-i bullceraoMhyler
(37 A) tt-73-5 2- rue-oorienol (718) 1 20- 2-7 laquoflthrraquocene
(3 A) IOO-02-7 ^Mtroprwnol (7fB) 191-24-2 beraquoMoltsrM)plaquovllaquox
(39 A) 3I-71-5 2-4 ini tr ophero1 (tOamp) K-7J-7 tluwtrie
((OA) 33-37l (-lt iMtro-2-methylphenol (tlB) D-01-J phenATithrene
(4A) I7-44-J pentichlorophenol (128) J3-70-3 dilwnioltraquoh)laquonthrraquoceif
(OA) IOI-95-2 prwnol U38) 193-39-3 indeno(123-cd)vcne
(MB) 129-00-0 pyrergtlaquo 6 ASENEUTILW- COMPOUNDS
VOLATH-tS ( I B ) 13-32-9 ftCYTNA pO IT H I raquolt
(38) 92-17- o^nzioinc (7V) 107-02-1 aero le in
( IB) 120-I2-I l2k-o-i(3iloroblaquontergtlaquo (3V) 107-13-1 laquocrvlono-U
OB) Jl l-7fc | he I raquocti 1 or o blaquonI enlaquo (V) 71-43-2 Oltf2 tO^
(17B) (772-I he uc^i 1 or of t h ne ((V) 34-23-3 CJU JOO Tt TTlCfllo^ iCpound
( I I S ) bu(2-rfilcroethv|)ether (7V) 10J-90-7 laquoWoroblaquonzeoe III-44-4
(KB) 9I-51-7 2ltfMoronlaquoohttvraquolwe (10V) 107^)4-2 1 t2^ojo^loroetfft^c (2JB) 95-50-I 1 2 -dichlorotgtlaquorlene (11V) 71-55-4 1 1 1 -trichloroeihtr (251 541-73-I 13-dchlorotxniene (13V) 73-J4-3 1 1 -dieMoreeraquohraquorlaquo
(77Bgt 04-lgt4-7 1 mdash djcMorobenlene (IkV) 79-OO-3 t12-tricriloroeflaquofgte (2gtB) raquolraquo-l 33-didMoroblaquonjidirlaquo (13V) 79-34-3 1122-tetrcnicroeir^ne (33B) 12 I I 4 -2 Z4-diniiroioluerlte (1(Vgt 73-00-3 e^loroetruuie (KB) (04-7C2 2 (-dinitro toluene (19V) 110-73-4 2ltJilorolaquotr(v|vLnraquolnhlaquo (175) 122-447 12-dipr-enylfiydrmiine (23V) (7-44-3 chloroform
(J1B) 704JJ-O Huor^thrr (29V) 73-33-4 lI-ltJicMoroltthcne
(OBgt 7003-77-3 -ctJoroprienvl phenyl ether (JOV) 134-40-3 irirraquo-12-dictila-olaquotrlaquone
( raquo I B ) IOJ 33-3 -6ogtmoprienyl phenyl ether (32V) 7I-I7-3 l7^lichlorepreoine (laquo2BI 3H3raquoO2raquo bit (2-chlororaquoopfT5pyO ether (3JV) 10041-02-4 trint-l3-ltJicnloroBlt-ooee (OB) 111-11-1 bis (2-cMcroetro(v) metSuvr 100(1-01-03 CU-lJ-itflloropOO-^
(376) t7-U-3 hraquoz raquoch1 or o bu tlaquodi ene (J1V) )00-1- erhylberuer 1400 (33B) 77 -gt7- hei tchl or ocyc1 open traquodi ene (raquoV) 73-09-2 methylene chloriCf OB) 7raquo-3raquo-l BO prior one (raquo3V) 74J7-J eMorametrutne (33B) raquol-raquo-3 naphtfalene 100 (UV) 74-13-9 bro rrvome t hrgt (3iB) n-raquo3-3 niireblaquor)iergte (raquo7V) 7J23-2 (CB) U-XH N -01 ITo tod 4gthenyU rru rr (UV) 75-27-4 bro mod i ch lor o rrx t f4Ugt ((36) 42IO4-7 N-nnroodipropYlraquomlrlaquo (raquolaquoV) 73-4t-4 JJuorotr lchloronvlaquoiMftlaquo (Uol U7-1I-7 ba (2-etrylNraquoYl) phtt^Ure 100000 (30V) 75-71 -raquo dj cftlcr od U 1 vraquooro rri NUT
(47 Bl 13-44-7 t^niyl butvl phthiUte 13000 (31V) 124-41-1 chlorodibromorrwt^r
lt U E gt ) U-71-2 d-ojjurvl phtf^Ure (13V) 127-11-4 tr trbullcti loro rirr
laquoraquo6gt 11704-0 dl-fl-OCTvl pfltMUM (UV) 10t-ll-3 toluene fiin (TtS) raquo-laquo djrthvl phttuliTr (17V) 79-01-4 tricolor oethenr lt 7 | o l 131 -11 -1 (UV) v i n v i chlcwidr dimrlKyl rrftlaquoUTraquo 75-OI-J
(T75I J4-35-J blaquoTMOlt^trrlaquocr^ gtylenes 1200
Cadr ium 3 Chromium 21 ZINC 150
All results are expressed as ugg weight as received y0 entry denotes not detect
Iah I D No 2887-2
Physical descr ip t ion of sample
Strained Soil
Sample workup
Voli t i le f rac t ion PFG Extraction (^W 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-3540) Inorganic fract ion Acid Digestion (SW 846-3050)
ACS) COMPOUNDS
rn CAS Tft CASf
(21 A) tt-04-2 (73B) 50-32-4
U2A) 71-50-7 P-ch 1 or o-m-cre laquoo 1 (7k 8) 205-11-2
(2 A) raquo3-37-l 2- chloroprraquoeno| (75B) 207-01-1
(3IA) 120-13-2 2raquo-4ichlorophenol (74B) 21UOI-1
(3 A) 103-47-1 24-dimethvlphenol (77 B) 201-14-1
(57A) U-75-3 2- njtroDhenol C7I5) 120-12-7
(MA) 100-02-7 a-flitrophenol (71B) |1l-2raquo-2
(51A) 51-21-5 2 -d in i tr o phetio 1 (SOB) K-73-7
(40 A) 53-57-l raquo 4-dinitro-2-methy lprnol (tlB) 15-01-1
(4 A) 17-14-3 plaquoitraquochloroorlaquonol (I2B) 53-70-3
(43A) IOt-13-2 prlaquonol (13B) m-31-3 (MB) 121-00-0
BJ KSENCLmLAL COMPOUNDS
(IB)
(3B) 12-17-3 bcnzidine (2V) 107-07-1
(IB) 120-17-1 1 2 k- tr i ch 1 oro benr ene (3V) 107-13-1
(IB) I1U7I-1 he it raquocM or o boiz ergte (raquoV) 7I-J3-7
(12B) 47-77-1 he traquoch 1 or oet hlaquo ne (4V) 54-23-3
(116) 111-- buC-cJiloroethv|gtether (7V) 101- W-7
(20B) 11-31-7 2 -ltft 1 or on ph ttvraquo 1 laquon e (10V1 107-04-2
(23B) 15-30-1 1 2 -dictilorobeni ene (11V) 71-55-4
(25) VI-73-1 1 3 -ltJ i ci 1 or o blaquoiz ene (13V) 73-3-3
(77 B) 104-M7 llaquo-dchloroblaquoMeoe (HV) n-00-3
(2IB) 11-lk-l 33-dicMorotxTLtidinr (15V) n-3raquo-3 (33B) 12I-U-2 2 ltgt -4 in i tr ot o luene (14V) 75-00-3
(MB) 464-20-2 2 4-d initrotoluene (11V) 1 10-7 3-1
(J7B) 122-447 1 2-diprieny Ihydrti ine (23V) 47-44-3
(316) 2O4-UO Ouorraquonthene (21V) 73-33Jshy
(WB) 7t)03-77-3 ^-cJJorophenyl prienyl ether (JXgtV) 154-40-3
(MB) 101-33-3 -6romopriefgtyl prienyl ether (32V) 71-J7-3
(raquo2B) 3431-32-1 bit (2-chloroboproprO ether (33V) 10041-07-4
(OB) I1U1I- I bu (2-ltMoroethorv) methane 10041-01-03
(52B) r-u-3 hexachlorobutadiene (J1V) 100-l-raquo
(33B) 77-47- he z raquoctlt lor ocycloqenud i crte (MV) 75-01-2
OB) 71-31-1 ao prior one (raquo3V) 7raquo-17-3
(33B) 11-20-3 nlaquopntrlaquollaquone (UV) 7raquo-13-1
(MB) n-13-3 nitrobenzene (raquo7V) 73-23-2
(UB) U-30-4 N-nnroiodiprienyUmine (UV) 75-27-k
(436) Ol-U-7 N-nitrModiproOYlmJne (raquo1V) 73-41-
(UB) 117-117 bu (2-laquothylheiry) phtrlaquolte 8800 (50V) 75-71-1
( 4 7 B ) L3-U7 blaquoniyl buryl phthaUte 30 (31V) 12I-H-1
(UB) U-7U-2 di-o-burvl phtrMUte U3V) I27-I1-
(416) II7-U-0 dj-n-oCTvl pritntUtr 1200 (raquo4V) IOUI1-3
17CB) U-44-2 djetiTi phrtultrt (raquo7V) 71-01-4
( 7 I B I 1 3 1 - 1 1 - 3 dimnfTraquo| prThraquoUtr (UV) 73-01-
(776) H-35-3 berMolta^thrCF^
Cl ien t ID 8 A - S 7 4 6 1
RASENEUTRAL COMPOUNDS
benzofbtfluor^tMe
benzodclfluorintoent
Ctiryiene
cenoithylene
raquonthrraquoctne
benzoltKhilpervlefgte
floor ene
prlaquofnnthrene
ltlibenplusmno(4h)knthricrnlaquo
inogtno(123-rt)pvrrne
pyrene
VCX-ATIIE5
bullcrolem
bullcrvlomn-U
benzene
carbon tetrtchloridf
chlorobenzene
1 2-oUchloroethAnf
lll-trichloroethlaquone
ll-dcfioroethrraquo
1 1 2-tricilorolaquothraquorw
1122-tetrichloroeTtvin
chloroethre
J-ctiloroethv|vinv| etrgte
chloroform
11 -denier oethene
trinraquo- 1 2 -4 cMor oe t hens
12-dcMoroprooine
^Lns~ I f 3-4ic^ lo^opf oo^^^
Cli-l 3-dicMoroprooe^e
rttiylbenzene
methylene cnlonfle
Ch 1 or o me t hane
bromome thane
Trace
bro mod i cMor 0 me t hane
(Juorotrlchlorome thane
chlorodibromometKinf
tetracnloroethervp
toluenetr icMoroel he-if
Trace
CacTiiun Chromium ZINC f
All resxil ts are exprp^spr i K-i
Phys ica l de sc r ip t ion of sample
Strained Soil
Sample workup Vol i t i le f ract ion PEG Extraction (SU 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-5340) Inorganic fract ion Acid Digestion CSV 846-3050)
ACE) C30laquo POUNDS
m CA5i CASraquo (2i A tt-C-2 (73B) JO- 52-1
(22 A) J1-JO-7 p-ch 1 or raquowTv-cre 101 (7raquoB) 203-raquoraquo2
(2 A) raquo)57-J 2- chlorophenol (73B) 20701-
(31 A) I25J3-2 2k-4icttlltroptlaquonol (7tB) 211-01-1
(3A) IO)-7-raquo 2-dimlaquothvlpNrnol (77 B) 20l-raquoi-
(37 A) u-rj-j 7- niTTOphenol (TIB) 120-11-7
(MA) 100-02-7 -rtropN-rraquol (7raquoB) lraquol-2-2
(JraquoA) JI-21-) 2-d initroprietys 1 (IOB) U-73-7
(MA) 53-37-l Udinnro-2-mlaquothylphenol (UB) I5-OI-J
(Agt I7-U-3 pentichlcropwnol (126) 33-70-3
laquo)Agt 10l-raquo)-2 phenol (I3B) IJ3-31-3
(MB) 12raquo-00-0 AASCVflCUTRAl COMPOUNDS
( I B ) I3-32- bullcnraquophtber
(56) raquo2-17) bnzidirlaquo (2Vgt 107-02-1
(IB) 120-12-1 l2btrilt7tlorotgteizegtlaquo (3V) 107-13-1
traquoB) IIraquo-7fc | heikcMeroblaquonzergte (V) 7l-3-2
( I 2 B ) 4772-1 he ueft 1 or olaquot hraquo rgte (tV) laquo-23-3
( i ts) III-- biraquo(2-cMoroethv Dethrr (7V) 101-W-7
(20Bgt 1I-3I-7 2-cMoroflaquophthlene (10V) 107-Ofc-2
(2)6) raquo5-50-l l2-dchlorotgtlaquonzefgte (11V) 71-33-4
(28) 3l-7)-| 1 3-didMoroblaquonrenlaquo (13V) 73-3-3
(27B) 10t--7 l-diclorolgtmzerlaquo (iV) rraquo-00)
(216) raquoI raquoltbull- 33-dichloroblaquoMidiflaquo (13V) 79-31-
(356gt 2I- l-2 21-dinitrotoloen (UV1 73-00-3
(UB) laquogt- 20-2 2 (-dinitroto luenlaquo (HV) 110-7J-J
(376) 122-W-7 14 -dipheny Ihydrzire (23V) lt7-M-3
(396) 2O--0 tJuoruMSene (2raquoV) 7J-35- (OB) 7003-77-3 -c^lvophenyl pNrnyl ethlaquor (30V) 1H-W-)
(MB) 101-33-3 bull-bromopriefiyl prienyl ether (32V) 7t-t7-3
ltraquo25) 3HJI-32-1 bU (2-cMoroaopropyl) rthrr (33V1 10ltX 1-02 -6
(06) l l t - t l - l bis (2-cftloroetSorv) metwne 100lt]-01-03
(32B) C7U-3 heraquoraquochlorobutidierx (31V) 1 00-41-
(3361 77-7-raquo hexiOilorocycloptfiudlerve (raquoV) 73-0raquo-2
(56) 71-51-1 no ph or one (raquo3V) 7raquo-17-3
(3)6) raquol-raquo-3 rwiphtfalme (UV) 7raquoJ3-raquo
1361
LUB)
H-133
14-30-4
nitrobenzene
^ ri i iy o too ipf^^ y LA r^i rtf ^ 7V) (UV)
73-23-2
73-27-
(436) t21--7 M^TI iff frfcO^ip ropy Ift mJf^ (gtraquoV) 73-4raquo-raquo (UB) I17J1-7 bu (2-rThyiruMcyDpMtvUtr 570 (jov) 73-71-1 ( U B ) U-41-7 blaquonzyl buryl phthlaquoLite (31V) l2k-raquo-l ( U B I U-7I-2 di-n-burvl pitftALtTe (raquo)V) 127-lt-fc
(OB) 117- -0 dJ-fraquo-oCTvl phlJ^Ute (UV) IOt-It-3
(7CB) 14 -W- 2 djelftvl phtfalitt (17V) Tt-01- ( 7 I B I 1 J I - I 1 - ) duTNnhylphttsraquoUw ltUV) 75-01-
(77BI X-))O lgtmrlaquoigtmhrraquoctf
Cadmium f iQ Chromium 15 ZINC
Tab ID No oo -
Cl ient ID 8A-A-64220
fcASENEUTTRAL COMPOUNDi
blaquofuo(raquo)pyrrtgte
bfizo(b)(loortAth^e
benzo(k)f|ulaquoin1herf
Ctiryiene
cenDraquoMrwlene
fcftT^rict^t
D^flZCT (fftl)pC^ V Itf^p
(luorene
phen^threne
diiwnztKthlanthricene
indlaquono( 1 23-lttf)pvrene
oyrene
VOCATtLES
bullcrolem
bullcrvlooitriJe
bervteoe
carbon WTTicMoridf
chlorobenze^e
12-djcMoroetfane
1 1 1 -tricolor ex tKraquon
1 1 -dicMarcx t hrlaquo
1 1 2-triChlorothraquorw
1 122 -laquotrraquocM or o-hraquorgt
cMoroettu^e
2-cMorlaquothv|vuy| rseshy
chlexeform
ll-dchloroctfgtn
tri^iraquo l 2laquoflic^ loTo^i rgtcnt
12-dicWoroproptrs
Winl-l3-dicMoropfooene
Cu-lJ-djChleroprooe^
rrtiylfrenzene
methylene ctiloride 0 64
cMorometHAne
bromomlaquothlaquone
bnsmoform
bro mod i eti lor e me t Nine
0 uor o tr 1 cMor e rrgtlaquo t Nnlaquo
dj di tor olaquol If 1 uoro mraquoi Nrraquo
chlorodibromonveiKme
re tr a en 1 or or fxrvr
toluene
D-ieWoroefwne
entry denotes not detect All results are expressed as ugg weight as received Xo
Lab 1) No 2887-8
Physical descr ipt ion of sample
Sf-rs inpH 9 n i l
Sample workup
Vol iCi le f ract ion PEG Extraction (SW 846-5030)
Scmivolat i le f ract ion Soxhlet Extraction (SW 846-3540) Inorganic fraction Acid Digestion (SW 846-3050)
ACD O3MPOUNDS
m CAS fPraquo CASf pi A) tt-Ot-2 Zraquot- tritilorophrgtol (73B) 30-32-1
ft M -3o-7 p-cMorraquo-m-crTraquool (7kB) 205-raquo-2
(2 A) raquoS-37-l 2- cMorop^erxgtl J73B) 207-OI-raquo
(31 A) 120-13-2 l^ictiloropix)l ^7tB) JII-01-
(3 A) |03-7-raquo 21^-dimeThvlphenol (77B) 20t-raquot-l
(J7A) tl-73-3 2- rutropwnol (71 B) 120-12-7
(MA) 100-02-7 -MO-opwnol lt7raquoB) lraquol-2-2
fJraquoA) 3I-2J-3 2-dinitrop^laquoTgtoI ((OB) U-7J7
(laquogtA) J34-37-1 lt-dinitrfr-2-methylpwrxgtl (I IB) I 3-0 1-1 (raquoAI 17-1 3 pcmacMcroptonol (S2B) J3-70-J UJA) IOI-raquo5-2 phenol (IJB) MJ-39-J
(tBgt 12raquo-00-0 RASEfZUTRAL COMPOUNDS
( IB) 13-32-f raquocertaprithene
(3B) J2-17-3 twnndinc (2V) 107J2-J (IB) 170-I2- lr2k-triOilorobenzerlaquo (3V) 107-13-1 (raquoB) I11-7I-I hei bulllt1 ore blaquont ergtlaquo (raquoV) 7l-3-2 (1B) 47-72-I he ucft 1 or oe t h n (tV) 3-23-3 (116) |II_wJ bu(2-ctiIarothvI)laquotNer (7V) 101-90-7
(20B) raquoI-JI7 2 -cW or orvraquo ph tf I ene (10V) I07-Ofc-2 (23B) J3-30-I l2-lt5ictiloroblaquonzeoe (11V) 71-3J- (245) 3I-7J-I 13-dic^lorotxenzenc (13V) 7J-3-3 (27B) 104-K-7 1 mdash diC^lorobtnrerve ( lraquoV) 7^-OO-5 (21 B) raquo|raquo| 33^icftlorobenzidifv (I3V) rgt-j-3 (33B) I 2 I - U - 2 2ltgt-dinin-o1olvraquorgte (UV1 75-00-3
(J4B) 404-JO-2 21-dinitrotoluerve (1raquoV) 110-73-1
(37B) I22-W7 1 2 -d ipheny Ihydra z ine (23V) C7-14-3
(318) 2O4-W-0 tJuortnihrne lt29V) 75-3J- (kOBt 700J-77-J ^-tfMoropheTgtyl p^enyl ether (30V) 1J4-W-3
( raquo I B ) IOI03-J raquo-6romopfgtenyl phenyl ether (32V) 7I-I7-J
(06) 3H3raquo-)2-raquo bU (2-tfilerobopropyO ether (3)V) 10041-02-i
(OB) lll|| bii (2-cMoroethoxv) methane 10041-01-03
(37B) PUt) hxzraquocMorobutadienlaquo (J1V) 100-raquol-raquo
(JJB) T7^7U heztctilarocrclotMnttdicrgte (V) 7gt-0raquo-2 OB) 7l-3raquo-l BO ph or one (raquo3V) 7raquo-17-J
(338) raquo|20-3 rlaquopritrilaquolene (UV) raquo-laquo-raquo
(3iBl n-raquo3) nitrobenzene (raquo7V) 75-23-2
(CB) li-X)-t N -n i tr o tod ipheny U mi nr (UV) 73-27-fc
(06) CI-U7 N^iitroiodipropYUmlr ^raquo1V) 73-H-fc (UB) 117JI-7 bu (2-ethYlNerrl)pM^Utr 12000 (JOV) 75-71-1 (47 B) L3-U7 llaquoniyl buryl pht^UTe 2 800 ( 3 I V ) 2laquo-raquo-I (UB) raquo-7i2 di-o-ourvl pritfwiUrr (I3V) 127-lt-i (196) 117-14 3 dj-n-ocryl pritfiiUrr (UV) IOUIS-3
(TCB) J4-W-2 djnhYl phtfalitt (17V) 7t-01-lt (716 ) 1 3 1 - 1 1 ) damnhYl pMtuUTT (UV) 73-01- (77 Bl 3 33-3 frlaquon z olt raquo klaquom h rraquo c prgte
Cadmium T^ Chromiurn T Z T N C 100
Client ID 8A-C64221
BASENEUTRAL COtPOUNOS
bnzo(t)pyrrrie
benzobXluoriflthei blaquorizoltVHluorraquontrraquone
chryiene
bullcenphthylene
tnthneene
benzoltRM)perylene
fluorene
prienlaquonthcTTgte ditgtmplusmnolt4hluithrraquoctnf
indenof 1 23-cd)pvrf ne
pyrer
VOUATILES
bullcrolein raquocrvlonnrile benzene cmrbort Tetrichloride
chlorobenieoe 1 2-oUchloroethirie
11 1 -tricolor oethne ll-dvchlorolaquollMr 1 1 2-w icMoroethAoe l122-tetrieMoroeihilaquonlaquo
chloroetKvne JltJilorothvlvmv| ethe chloroform
11-dicMoroethent
trani- 1 2 -dicti lorolt t hene
1 J^JictiloroproBfVf
trim- 1 3-4ietiloroproperie
Cil-IJ-dicMoropfoOerie
rrhyUxrmene
methylene criloride
chlorornethine
bromome thne
007
13
tluorotr l^VoromlaquotNraquorgtt
da ch lor od 1 1 1 ooro frvet hraquone
chlorodibromometlvinf
te trraquocnloroeT rrrr
tricMoroetSmr
All results are expressed as us2 weight as receixred No entrv denotes not detect i
Phys ica l descr ip t ion of sample
SoilCake
Sample workup
vol i t i le fract ion ^FP FvfrarfMnn (ltU Rif i mdash Smrn
Semivolatile fraction Soxhlet Extraction (SW 846-3540^ Inorganic fraction Acid Digestion (SW 846-1050)
AC23 COMPOUNDS
rrt CAS CAS
(21 A) 11-04-2 2raquo4- trieMorophenol (738) 50mdash 3-4
122 A) J1-30-7 p-ctil or raquo-nvltrlaquo laquoo 1 (7laquoB) 205-11-2
12 A) 13-37-4 2- etilorophenol (75B) 207-01-1
(31 A) 120-13-2 2raquo-diclorophlaquoTgtol (74B) 211-01-1
(34A) 103-471 24-dmlaquothylphrnol (77 B) 201-14-4
(57 A) U-73-3 2- rutrop^nol (7raquoB) 120-12-7
(54 A) 100 -02-7 bull i tro p^c 01 (71B) 111-24-2
(J9M 31213 Z o trt i tr o poc^oI (MB) U-73-7
(40 A) 334-32-1 T^Hjinitrfr2^rt^T ny tp^gt^noi ( t lB) 13^)1-4
(44A) 17-44-3 pcnttchlaroprwnol (S2B) 33-70-3ltOA) IOt-IJ-2 pTUfNOl (136) 113-31-3
ftASENtUTRAL COMPOUNDS (MB) 121-00-0
(IB)
(56) 12-473 Iwnndine (2V) 107-02-1(IB) I20-IJ-I 1 2 4-tr icJi lorobeniervr (3V) 107-13-1(IB) 11 1-711 hexkcMarobcnzeM (4V) 71-43-2(126) 47-72-1 hexch)eroeihlaquone (4V) 54-23-J( I I S ) 111-4- bu(2-eMorlaquothv|)laquothr (7V) 101-10-7
(208) 11-51-7 2-c^laronraquophtfgtlene (IOV) 107-04-2(23B) 1J-30-I 1 2-dichloroblaquonime (11V) 71-35-4(2651 341-73-1 gt3-ltiictitaroblaquonxcnc (13V) 73-54-3
(27 B) 104-47 l4-dicMorotKmrerlaquo (14V) 71-OO-3
(21 Bgt 11-14) 33-4ichlaroblaquon2idine (15V) 71-34-3
(338) 121-14-2 24-dinitrotoluene (14V1 73-OO-3(J4Bgt 4O4-20-2 24-dinitretoluenc (11V) 110-73-4(37B) 122-447 lraquo2-dip^nylhydrraquoxirlaquo (23V) 47-44-)(MB) ro--0 Uuaranthene (21V) 73-33-4(406) 7003-72-3 4-ltUorepfraquonyl phenvl rtSer (30V) IH-40-J( raquo I 6 ) 101-333 4-6romoprlaquonyl pflaquony| ether (32V) 71-17-3
(OB) 3H3I-J21 bll (2-cti|orobopfrgtpyO ether (33V) 10041-02-4
(OB) I11-1I-I bis (2-cMaroethoxv) methane 10041-0103
(57B) P-44-) hczw^lorobundiene (J4V) 100-41-4
(JJ6I 77-47-4 htTicMarocyclojxrtadien (44 V) 75-01-2
(346) 71-31-1 aophoroo ( raquo ) V ) 74-47-3
(33B) raquo|203 r^pn thA Icr^ (44V) 7 -raquobull J-
(546) n-i3) H i frovCftZfl^^ (raquo7V) 73-23-2
142B) 14-30-4 S -n i tr o laquood ipheny Lt mi nc (44V) 73-27-4
(43 B) 421-447 N^iitrotodtpropyUmlne (41V) 73-41-4(MB) 117-41-7 bu (2-raquoThylhlaquolaquoyl)pMtgtlaquoUtr 52000 (30V) 73-71-4(4B ) 13-447 (xniyl bviryl ptithiUre 6700 (3 lV) 12raquo-l-l(UB) 147U- di-n-burvl pMhUre (I3V) 127-11-4laquoampgt 117-4J-0 ltjj-n-octyl phtfaUtr (UV) 101-11-)
(7CB) U-44-2 djrthyl pht)raquolraquort ( I7V) 71-01-4( 7 I B I 131-11 ) dimrthyl phttgtUTe (UV) 73-01-
(T76) H-33O tgtnzoUtlaquoftthncmr
Cadmium l i r^ Chromiurn 2 0 ZINC 140
All results are expressed as ugg weight as received
Lab ID No 2887-6
Cl ien t I D 8AD64219
Dd20( amp py(re
blaquonio(bHluorraquoflthegtlaquo
berzo(Mf luorampnThene
chryraquoefgte
ftctnAoMhy(ergte
raquonthncene
benioltK(M)plaquovlene
(Juorene
picnintfirtTX
dihwvioltraquoh)laquonThrraquocene
mdeno(l23-rt)pvrraquone
pyrene
raquocrolein
raquocrvloourUf
benzene
carbon laquoTrraquochlofifle
chlorobenieo
l24JcMarolaquotlxine
lll-trichlcroltthlaquorlaquo
-ltJicMorigtnKraquorgtlaquo
l12-trichlorolaquot^nlt
1 1 22-tetrcftloroetrvtnlaquo
^tloroeThAne
2^^1orolaquothvlvuiivt ethe
etila-oform
ll^liailoroltN^
trtni-12-dichlcxolaquoTfgtene
12-ditfiloropropine
trtni-l3-ltjicti|orocltX)t^f
cu-l3-djcMoroprooe^f
rttiylbtnztTve
methvlene cWoride
ciloromnM^f
Dco^^oroct^A^^
bromofarm
bromodicJiloromltlfraquon
tluorotrlctiloromttNir
diOilorodKloororfvrir^Ar
ct^lorodraquobrofTorrgttKAne
wtricnlorampctNrr
toluene
trirfilorolaquoThfif
v i n v CMor ilt3^
No-entry denotes not detect
ih i n N O 2887-9
Phys ica l d-asc r ip t ion of sample Cl ient ID 10A64222
Linnir l ShtHcp
Sample workup Volitile f rac t ion PEG Extraction (SW 846-^030^ Semivolatile fract ion Sonication Extraction (SW 846-3-540 Inorganic f ract ion Acid Digestion (SW 846-3050)
AOD COM POUNDS BAStNELTTRAL CXLPCXJNDS
rrt CAS CAS
(21 AJ U-Ot-7 Z4- trichloropSeno (73B) 30-J2-
(22 A) 55-30-7 p-ctilarraquo-m-erelaquoo1 (7kB) 205-raquoraquo-2 ben r olt b) 1 uor ifl t Ne~gtf
(2AJ raquo3-37-i 2- ctilorophenol (75B) 207-0raquoraquo benzoltllt)floofraquontslaquor
(31A) 120-13-2 2raquo-ltJictilcroooenol (76) 211-01 9 ctiryjene
(3A) I03-47- 2k-dimethylphenol (77 B) 20t-raquo4-i bullceruphthv lerraquoe
(37A) U-73-3 Zmdash Ajtropheooi (7SB) 120-12-7 fcntftricene
(34 A) 100-02-7 w^ i ff o phe rgto 1 (7raquoB) Iraquol-2-2 ben z o( Rh i )per v 1 me
(31A1 51-21-3 Z^ - d iA iV opheno1 (SOB) U-7J-7 Iluorene
(MA) 3X-37-I T v-4iAiv omdash laquo mdash fl^et ny Ipoenoi (I1B) 13-01-1 poeftraquonthrene
(4 Al 17-14-5 p^ntBCfllGrOprlC 1 Vol |I2B) 33-70-3 dilgtenioltraquoh)laquontwraquocenr
USA) IOl-raquo5-2 phenol (13fi) U3-31-3 indeno(l73-cd)oraquorrie
(MB) I2raquo-OO-0 pyrene RASENCimiAL COMPOUNDS
VCH-ATUL5 ( I B ) 13-32- raquoclaquonraquophtflaquorgte
(58) 12-I7-J benzidire (2V) 107-02-1 bullcrolem
(IB) 120-J7-I 1 2k-tr icnlorobenzene (3V) 107-13-1 acrvlonitr UP
(IB) 11U7I-I heKicMorobtnzme (raquoV) 7I-A3-2 benzene
(176) 4772-1 hexcftla-oethtgte (4V) J4-23-5 campr~toon TeTrscftlo itit
(116) III-- bii(2-lttilorolaquothv iVether (7V) lOt-W-7 chlocobenieo
(2C5gt raquol-3l-7 2-cM oroolaquo ptittu lene (10V) I07-O4-2 1 2-dicrtloreetranr
(23B) raquo5-30-l 12-dichlarobenime ( 1 I V ) 71-33-4 11 1 -tricMoroethr
(24 B) 31-73-1 1 3-ltl icJgt lor obcn i ene (13V) 73-3^-3 1 1 -dicMoroeth^i
(27B) 104-^4-7 1 4-dich lorobenzergte ( t k V ) n-00-3 11 2-tncfiloroetvlaquorie
(215) 91901 33-didMoroblaquozidinr (I3V) rraquo-3k-3 l122-tetrraquoOMo-oethne
(335) 121-I-2 2-dinitrotoluergte (ItV) 73JW-3 chloroethjin
(3461 (0420-2 24-dinitrotoluene (19V) 110-73-1 2-cMoroethraquo|vuiv| trgteshy
(37 B1 122-44-7 12-diphenylhydrnine (23V) 47-44-3 ctiloroform
(316) 204- Jgt tluarmrnhene lt2V) 73-35-4 1 1 -^iCMoroeThe^f
(C6) 7003-77-3 -chlorophenyl poenyl ether (gtOV) 154-40-5 trraquonraquo-l2-dicrloroltthene
(bull16) 101-35-3 raquo-6romophenyl phenyl ether (32V) 7I-I7-3 l2^ipoundMoroproBirgte
(raquo26) 3H3I-32- bit (2-cMarobopropvt) ether (33V) 1 004 1-02 -4 trmni-l^-dictilwoproom
(OB) l l l - raquo l - l bis (2-cMeroethoxv) methane 1004 1-0 1-05 cu-13-laquoicMoroprooe^e
(J2BI D-U-3 rraquolaquoeftlorobutraquodilaquooe (JJV) IOOJM- rttylbenzene
(336) 77 -raquo7- hezactilarocyclooentadiene (WV) 75-OT-2 methylene cniorifle
(56) 7raquo-3raquo-l ao ph or one (raquo5V) 7raquoJ7-3 eMoromeirune
(33B) JI-20-3 nraquophtMlene (UV) 7raquoJ3-raquo bromomethAftf
1X6) n-raquov) nitrobtnxerw (raquo7V) 7J-25-2
(CB1 14-30-4 J -ltii TT o vxJ ipheny U rru rraquo ^UV) 75-27- bro mod i cfilor o me t r)e
(CB) 47I-U-7 N-nnrotodipropylraquomJne (tV) 75-4raquo- 11 uor o tr i cMor o me t htgte (US) V17-1I-7 bu (2-eifrrlhryl)praquogtttilaquoUMshy 69 000 (30V) 75-71-1 di cti tor odl1 1 van m^i rajgtr
(476) U-U-7 benzyl buryl phihiUte 890 (31V) 12laquo-kraquo-l cMorodbremof^etNrr (US) U-7I-2 di-n-burvl prittuUre (13V) 127-lt- Uraquo6gt 117-t-0 dJ-laquo-ocTvl phttviUre (UV) IOLtS-3 Wluenr
(75) u-w djrrhylphtnltt ( i rv) 71-01-4
(715) t J I - l l - 3 dimnhrl pfthUte (UVI 73-01- viny l CMcriOr
(779) J4-35-3 0laquoMo(UnthrraquoCflaquoe
C a d m i u m 130 Chromium 20 ZINC 170
o nnn Z-UUU
^0(^ Trace
All results are expressed as ugg weight as received No en
APPENDIX E
PLATES
I I I I I I I I I i Plate 10-1 Troy Mills Landfill with a backhoe excavation
in progress in a former drum burial area
I I I
I I I I I I I I
I I Plate 20-1 NAI field investigation team preparing for
Level B activities during the drum excavation task Troy Mills Landfill
I I I
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
I I I I I I I I
I I Plate 20-3 NAI field investigation team member undergoing
personal decontamination at the hot line Troy Mills Landfill
I 1 I
I I I I I I
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
1
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
I
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
I I I
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
I I I I I I I I I I I 1 I Plate 53-3 Pigmentsludge deposits interbedded with
soil layers in Excavation 8A Troy Mills
I Landfill
1
10 INTRODUCTION
As a part of a phased program to investigate potential ground
and surface water contamination associated with the Troy Mills Inc
landfill Normandeau Associates Inc (NAI) has completed a waste
characterization at portions of the landfill that were formerly used for
the disposal of steel drums containing wastes (See Plate 10-1 for site
overview) The objectives of this phase of study included
1 Delineation of the horizontal extent of the drum burial area
2 Estimate ofthe number of drums
3 Characterization of the physical condition of the drums
4 Assessment of the contents of the drums and
5 Assessment of potential for ground water contamination
6 Development of a remedial action plan for the site
The work involved developing and implementing an extensive
site safety program conducting a magnetometer survey digging a series
of test pits on randomly selected sites laboratory analyses of selected
samples of soil and waste and formulation of a remedial action plan for
the site
The Troy Mills landfill is roughly eight acres in total area
and divided into two main sections One section is currently being
operated as a solid waste (non-hazardous) disposal area for fabric
scraps and trimmings as well as other non-hazardous materials such as
wood and broken tools The solid waste landfill covers about six acres
of the site An estimated three acres presently contain deposits of
solid waste and about three acres are being prepared for future
disposal A closed former steel drum burial area is the second section
occupying about two acres of the site The drum burial area is now
covered with soil and a light cover crop of grasses The drum burial
area received wastes between 1968 and 1978 The disposed drums are
reported to have contained various materials including waste
plasticisers pigments and organic solvents
Previous site investigations by NAI have included site
reconnaissance studies test pitting water quality analyses (NAI report
of August 12 1981) geophysical (seismic refraction and electrical
resistivity) investigations (NAI report of December 1981) installation
of a ground water monitoring system (4 wells) and sampling and analyses
of ground and surface water samples (NAI report of July 1982) A water
budget analysis was performed to assess the leachate generation
potential of the site (NAI report of September 1982) Concurrent with
the study of the drum burial area additional seismic refraction lines
were conducted and three additional ground water monitoring wells were
installed to further assess leachates from the solid waste
(non-hazardous) portion of the site
Laboratory Analyses were conducted by Resource Analysts Inc
(RAI) We also wish to acknowledge the assistance and cooperation
provided by the management and personnel of Troy Mills especially
Messrs Barrett Ripley and Carl Patten
20 SAFETY PLAN
A Bureau of Hazardous Waste approved safety plan for on-site
activities was developed for the waste characterization phase of work
because of the potential for encountering hazardous materials The
safety plan is presented in Appendix A of this report It assesses the
overall degree of hazard identifies specific potential hazardous
situations and presents guidelines for personnel protection and action
levels as required The plan was made available to all field personnel
during the field work
The magnetic and topographic surveys were considered to be low
hazard activities with a prescribed level of personnel protection (LPP)
of C or D depending on the results of air monitoring Level C proshy
tection involves wearing a full face respirator with organic vapor dust
combo cartridge Tyvek suit over work clothes rubber safety boots and
gloves Level D protection requires cotton coveralls or other work
clothes safety shoes safety glasses and possibly a Tyvek suit
During the drum excavation and sampling task which was
determined to be moderately hazardous Level B protection was preshy
scribed Level B protection requires that personnel wear SCBA (self
contained breathing apparatus) chemical resistance Tyvek suit steel-
toed rubber boots and gloves Plate 20-1 shows NAI personnel on the
site preparing for Level B activities Plates 20-2 and 20-3 show
personnel decontamination equipment and the hot line during the drum
excavation task
30 MAGNETIC SURVEY
To delineate the landfill area underlain by steel drums a
high resolution magnetic investigation was conducted by John F Kick
PhD consulting geophysicist The magnetic method was chosen over
other search methods because ferromagnetic substances (drums) were the
target objects and the majority of Troy Mills other wastes are
non-magnetic (largely fabric scraps) Dr Kicks report is presented in
Appendix C
Eighteen parallel rows of magnetic field measurements were
made along north-south lines The measurements were made at 10-foot
intervals along the rows This work resulted in a detailed contour plot
of the magnetic anomaly (Figure 1 in Appendix C) The source materials
which cause the magnetic anomalies do not usually directly underlie the
peak of the anomaly A shift is caused by the inclination of the
earths magnetic field and by dipolar effects Figure 30-1 shows NAls
delineation of probable source areas for the magnetic anomaly and
peripheral areas which may contain some magnetic source material The
plotted source area is generally the area between the peak of the
magnetic anomaly northward to the zero anomaly contour This is to
compensate for a southward shift of the peak of the magnetic anomaly
from the center of the source deposit The complex geometry of the
anomaly necessitated much interpolation between peaks and ridges
gt QJ
LJ LLj
ro U -r- X j_gt 0 QJ bullimdash -4-) QJ CJ bullrmdash o 1C
gtsj
-= QJ 3pound c
CT1 -a 3J +shygt
LO
^mdash 4
4-gt
^O gtbull
c
QJ ltmdash U ltT3 f - ~ 3 0 O C ll ro
QJ CJ rmdash -r
-0 -U ro QJ XI C O O1 Sshy (T3
Qshy pound
ro ro OJ E S_ ro QJ
mdash bullmdash O ro ti
rmdash J_3 CC3 U CU
mdash i-0
4_gt
ro
QJ H r^ C
~t
QJ QJI) (
QJ 1
Sshy E gt4-gt QJQJ C
JC bull-
r^ ro
bullmdash rshy c0) u
E in bullbullshy0 rshy
bullbull- bull(-gt s_ -o c O)s_ c QJ O Oshy U
3 O I)
c o toro srshy ro
DC -t-gt CO
o rO U i_
ro X a
imdash 3 O
-rshy -a
C QJ
rmdash
t^ C o
bullptrade
4^ CL -ishy s_ -o QJ -a Q lt
O J
oo
OJM bullH
rv i^^ 1 ^
bulla 03 ^0 I
1 I
bullH lt- T3
2 EH
0)AJ
aLU ca Q)
U
13 O en
O rmdash u
bullH 4Jltu c
0)M lt8
bull0 ltV
JJ ltV 0)c
bullH M
a I o
o V
Z 2 d ) 3NI13SVS UOiid 33NV1SIQ
40 TEST PIT EXCAVATION
41 WORK PLAN
A series of test pits were excavated in the Troy landfill for
observation and sampling More specifically the purpose of the
excavation was to estimate the number and distribution of drums buried
in the landfill determine the condition of the drums (full empty
crushed rusted leaking etc) identify types of buried and drummed
waste and verify the results of the magnetometer survey A stratified
random sampling method was used to choose 10 locations within the
delineated area of magnetic source material This insured that
excavations were distributed randomly across the landfill and that the
resulting data could be evaluated with a level of statistical
reliability Excavations were also selected in areas on either side of
the anomaly which were considered free of buried magnetic material and
also where drums were visible at the landfill surface
The following procedure was used in choosing the locations for
the random excavations The center of the delineated area of magnetic
source material was used as a base line The base line was drawn onto a
map of the source material (Figure 30-1) and then divided into ten
60-foot long segments Using a random numbers table a point-distance
was located on each segment (designated the random station) and a
line drawn at that point perpendicular to the base line segment Again
using a random numbers table a point-distance (designated the random
offset) measured along the perpendicular line located the point of
excavation The grid coordinates for each excavation were graphically
determined from the grid overlay and then field-located from the
surveyed grid intersections Grid coordinates and selection data are
presented in Table 41-1
It was judged that 10 excavations in the delineated area of
magnetic source material and two excavations out of the area would be
sufficient to characterize the site would produce statistically valid
TABLE 41-1 RANDOMLY SELECTED EXCAVATION SITES TROY MILLS LANDFILL TROY NEW HAMPSHIRE
BASELINE RANDOM RANDOM EXCAVATION GRID SEGMENT STATION OFFSET
NUMBER COORDINATE (FEET) fFEET) (FEET)
1 7E+15 65N 0-60 26 16
2 9E+5 13S 60-120 110 9
3 8E+0 31S 120-180 140 7
4 4E+5 48S 180-240 230 26
5 3E+8 45S 240-300 254 20
6 OE+8 45S 300-360 394 50
7 2W+15 24N 360-420 465 14
8 5W+6 42N 420-480 518 20
9 6V+14 74N 480-540 548 7
10 8W+5110N 540-600 611 31
Locations are plotted on Map in Figure 30-1
data and could be expected to be completed within a scheduled 2-3 day
work period
42 FIELD WORK
Test pit excavation was conducted in two phases On the first
day each of the 10 random locations (Excavation 1 through 10 Figure
30-1) was probed to a depth of 2 feet using hand shovels On the
second and third days excavation was conducted using a combination of
hand shovelling and power backhoe The NAI field investigation team
consisted of six members Four of the team members were equipped to
work at Level B for work in and near the actual test pit excavation
(See Plate 42-1) The other two team members spent much of their time
with personnel and equipment decontamination and refilling compressed
air bottles at the hot line Mr Timothy W Drew an engineer of the
New Hampshire Bureau of Hazardous Waste Management was present during
most probing and excavation work Mr Robert Lynch an experienced
Level B equipment operator of Jet-Line Services Inc operated a power
backhoe which was provided by Troy Mills Inc
An average excavation size using the backhoe was approximately
7-feet wide and 10-feet long Excavation continued downward until drums
were encountered or to a minimum depth of five feet Drums were careshy
fully uncovered and fully described A total of 17 samples were
obtained from uncontainerized wastes (solids dried sludges pigments
stained soil) and where possible from drums using EPA sampling methods
and protocols All of the excavations were backfilled upon completion
of this task
Each sample consisted of one filled 8-ounce glass jar sealed
with a Teflon-lined lid Samples were submitted to Resource Analysts
Inc (RAI) Laboratory in Hampton Falls NH for priority pollutant
analysis
Air monitoring was conducted during each excavation using a
Foxboro Century Flame lonization Organic Vapor Analyzer (OVA) an HNU
Systems photo-ionization detector (HNU) and an MSA combined oxygen and
explosimeter High explosimeter measurements were considered cause for
an immediate halt in exploratory work in the interest of personnel
safety
10
50 RESULTS
51 GENERAL
On November 17 1983 Excavations 1 through 10 were initiated
using hand shovels to a depth of approximately two feet A total of
two buried drums were discovered Excavation 13 was completed and a
third partially buried drum uncovered On November 21 1983
Excavations 1 through 9 were completed and on November 23 1983
Excavations 7A 8A 10 11 12 and 14 were completed An additional
42 drums were uncovered on the last two days of excavation
Excavation Locations Seventeen test pit excavations were
completed at locations which are shown on Figure 30-1 Two pits were
excavated at three of the locations Noteworthy aspects of the
excavation operation are
Excavations 1 through 10 were randomly located in the area of delineated magnetic source material (on-anomaly)
One excavation connected Excavations 4 and 5 This was done because of the proximity of Excavations 4 and 5
Excavation 7A was located immediately adjacent to Excavation 7 Excavation 7 was located on the boundary line of the anomaly and proceeded in a southerly direction off the area of delineated magnetic source material (off-anomaly) Excavation 7A was initiated in the opposite direction (north on-anomaly)
Excavation 8A was initiated one foot north of Excavation 8 after the latter was abandoned due to the detection of a potentially explosive drum
Excavations 11 and 12 were selected off-anomaly to the north and south (respectively) in areas considered to be free of buried magnetic material (drums)
Excavation 13 involved minor hand shovelling necessary to uncover a partially buried drum located on the periphery of the anomaly at the east end of the landfill
11
Excavation 14 was a surface scrape which extended from an exposed drum found to the south of the magnetic anomaly northward toward the anomaly
The details of each excavation are presented in Table 52-1
Drum Locations The excavation results support the
interpretation of the magnetometer survey with buried drums as the
source of the magnetic anomaly With the exception of a few strands of
wire found in Excavation 1 ferromagnetic materials other than drums
were not encountered during the test pit excavations
Drums were foundin 9 of the 10 excavations located in the
area of delineated magnetic source material (See Plate 51-1) No drums
were found in Excavations 11 and 12 located out of the area of
delineated magnetic source materials The location point for Excavation
7 was on the boundary of the anomaly Excavation 7 which proceeded
south away from the area of source materials was free of drums
Excavation 7A proceeding north toward the area of magnetic source
materials uncovered 6 drums Excavation 14 located just out of the
delineated area to the south produced unexpected results Five drums
were uncovered just under the surface in an area with low positive to
slightly negative total magnetic field values It is possible that
Excavation 14 was improperly located in the field If adjusted just 20
feet to the east it would be well into the delineated area It is also
possible that a negative dipole derived from the mass of material to the
southeast is cancelling positive readings at this location
Fill Material and Vegetation Cover and fill material was
predominantly fine to medium sand with an occasional boulder Till with
a siltclay component was also used as a cover particularly at
Excavations 6 and 7A This material was densely compacted and difficult
to dig through Excavations 7 11 and 12 each extending to a minimum
depth of 5 feet were characterized by uniform silt and fine to medium
sand and traces of dark discoloration Excavation 12 was located in
to a s
to LJ imdash O z
^ mdash re CM mdash(_ E CO O bull 4J LZ n (- _ E 0 c
o u L t ij-3 o agt w gt Xre JJ o c iomdash o
o
mdashra
mdashL-03AJreE
L03gtoo
E O i-it
mdash Slt J rn shy
mdash tfl 0) gtre tt)N
^ mdash -jj a -C TJ E CD mdashc re c
mdash o tgt~ mdash CD
mdash C bullmdash U SI bull-gtCOES 03gtO0
E 3 t-
bullD
^ ltshy
CO 0
Imdashmdash
-gt COmdash
1--30Z 4Jr e r e shyw E JJ
in O jj 01 o i-
i- agt n c i shy -mdash O gt E lA
O 0 (13 AJ O O X C es uJ o N
mdash mdash JT Ol t-
J J C I - C D laquo re O shyu
bull3 lt 0 3 N
bullmdash V c t C3 mdash a C S bull U r o
CO shygt bullA ^ mdash bull o
o - C Z
X =mdash Z O
mdash C 3 r e O -Z Z pound bullmdash re-JOlaquo C r e X
C c c gt r eC O r e J raquoZ o u r e X
mdash in X mdashl -CS-U fOCO
CJ EE lt- ~~ O
C T3 shy lt 0 t i re^ltmdash raquotrade-^t
mdash 3 O - C i C 3 mdashbull
^ v a c E gt = E mdash _gt re C J pound o y 5 O
rez O C3 - C
bdquo
O (T shyg shy =c _) 2 shyo mdash o
Q3 ^D 1- mdash C bullmdash mdash shy3 t = s ~amp lt Z ^ C N
c o r e mdash mdash c bull mdash o mdash bull _ mdash X 3 C c
mdash C T D O lt C o c o mdash gt mdash laquoomdash
JJpound J c
o
xo obullo w c-i-C C i-re o re O CO shy3 0 J
XbullOCcoW
t- 0) shygt bull tfl bull = B E 3 laquo Obull
3 mdashraquo O W i- o re c re a bull- shy 3 gt
XbullOCreVI
Q t-
03 pound mdash U
0 L- (8
X a s ar e gt Emdash COC i O O
mdash gt shyc laquo- O raquo bull t- mdash CO
X c - gt c c i shy r e w O t r e
mdash re X i- - z ^E l - IC C3O
Z cJ Xt E J r mdash o in trade re ^ cc U pound -gt
^ mdashJ O ^ 11 CSLJ - gt ^ c olt- c umdash C CT-3 O B 3= mdashmdash z - ^r mdash c = s J
mdash laquo f j 3 -3mdash O
pound mdash z = J 3 3 S O laquo
s re -re mdashmdash ~mdash gt
cO t 3 r e C - ^ laquo gtC ltshy O gt mdash Z CD o c re mdash rei 3 u
O C S li = i U) x^shy mdash x x r z r e JO w L J C ^ 3 i
mdashi
a
IS shyJmdash _jii) OS
aa I i
a 1 1
a 1 1 O
a
z CC w ^ 1raquo oo o o
CM o o
zx
o
ltamdashZLraquo
pound a o
^ 3 Z
Q a mdash mdash
o rmdash IA
i 0
QoOIA
a mdash
lA r~ r~
a mdash o CO
amdashoCOttrade
Q o o
laquobull
O
o o 1mdash
i ia o o lA
i
Z mdash m
CO CO
h_
0^zmdash
^
S c-c_ 1_
0 a mdash mdash 0
o O ro mdash 1
O O
0o CM1
a mdash
O O
Q
O O
1
o mdash
oO-
Q o o
lA 1
Q _
o o
1
WO
O
Q O
lA 1
gt o
0 o
O0
CM O lA
v o3- V
CM
CM r ~ CM
mdash =^ a
S 5^ 0lt r ~ ~
1 1 1 a- lA
a o
1 1 I I
CVJ
c UJ pound3
O
~ v z
1 mdash a z ZO o mdash Ui-
raquo o
a laquo
Lu
raquomdash lt^
U
It(O
ltfgt r~ u Lu
laquo fcCC
mdash
-1-mdash u 00
r-CM
_j^^ U Cpound C- u
mdash K ^
O U P- mdash
cs shyo L ^ t-oshy0 ~ CMr-
J c~1
Vi UuL
laquof~
u o bullmdash mdash
bull- t-
^ LL ^
K f- Ci bull-bull
shy shyU LJ LJ
rr shyo laquot- t_
O ^~ O c
CM Q
mdash c-Omdash
^
^V f-
mdash U
fc ^ aa L 1_ ou C- C
1
w
0
X L
raquo( CC-mdash
LJ
O
lA
_
0 1
^v U
Oi
laquo-O n
mdash
Z o to
ltr s _3 OK
CVJ CM ro
raquo~
j CM VO
ro bull-CM
ro 1 VO laquomdash
z o
r-Q
I C
o X UJ
poundo| s~a
a CM CVI CVJ fO lA CM 1 lA lt-
a o
o mdash LJ o raquomdash L
lt ^^ gt lt UJ C N X mdash _ in
o X o X CO
f)XCOXr-
X CM
bull-X ot^
ro X ^y X O rmdash
rXlAXOv
CM X
00 X
CM V
ro X ~
0
lAX roX o
mdashX
00X
o
r-X
^3 X^
z C o
lt a
lt 5 rmdash fl ro ^ -~
I O C- 83 ^ ~
lt gt- CO
X
0 O
13
E
23
eo ETC CU
gt i- Nlt (_ mdash
E O i-
lt~o ON dgt
N Q) mdash
i-tt) gtOO
bullDC
gt 0) C
T3 O
-D C CD
tgt
-U mdash mdash
C5
E 33
E-0 gtgts-O CD mdash T3 1- N JO ( =
0 0 U - O C5 t- t-ushy ro L jj bull
3 C 0 gtgt cnmdash 4J mdash
bullD CD bull C E E
I t -
lt Q 0)eo i c
lt mdash
mdash L
aagt E C CO mdash
CO i-W CO
bull obullDmdash 0
gtgt mdash
re bull E bulllt-gt
gtgt mdash
CD bull E-0
L W O lt tu en i-fgt c O Q
gtgt0 3 O mdash 4-gt i C
CD X -o eo E 0
w co CD bullO 4J COmdash ^ C d)CO O ^E 1 O W
co eo 4J bull
bull C CU ^ O ^
C O W
c eo Qeo mdash eo
t-JJ 0 E
o mdash c mdash
eo w
D C c eo CD laquo)
CO T3 0 4J Q) - C 0 mdash CO gt mdash E O w mdash
O 01shyC CU O O CD aw
CD O CO u- sshy amdash
re lt c eo cc c CD mdash CD 1- ltshy C C_ C re c co o - O X X CO CO3 gt CO 3 gt to E O O co O co CO 3 jt w O cfl 0) eo
cr LJ
LJ-J u mdash j CO 0amp5
a O 1 O
Q
1 1 i l
CD Dl bulla
CO _ mdash O D o
O ^ (A
ZX mdash Ld
O
en 3 10 O a
LJa a
Q 1 1 O
Q
+
O
X
_
mdash
o o I
gtgt O
h~Z
-^ 3
o0
mdash i-
1A 1
a a co agt C
LJ
sectK
Z= tM O 0 to bullo
X
mdashshyo
CD O
o mdash _ o
E umdash 3 E eo sshy
ltr-toZmdash
mdash s
0shy c
^
^ gt o
D o
a-rmdash
1
Q-
0 0oo r-V
tO 0
= mdash
O
tO 0
= mdash
O
Q O
O r-i O NO
1
awi
i mdash _ 3
Imdash I O
bullO C
1- 3 gt 0) bullo sshy co w
bullO CJ ID O X E C CU tt) bullw^ T3
w agt u C pound -gt
a a CO CD
mdash L 4J CD o gt
T3 gt C CO UJtt
2 mdash1 LJ Z) d CO 1 1
COO
~
lt O
~ I 1 1 I
Dl C 10 3 -D
lt - T J O
Dl C
1gt Omdash O bulllaquo Xl- i s o cu
Q lt3 toz cshy
mdash W f
r-B O c
mdashgtgt3 01O O u
W ID CO bullgt C -O mdash 4-gt 4-gt C
O -x mdash1 CO o CU c c co
1
OZ ZO o mdash Ol-
LJ -
L
0
1
C- bull 14 u- o laquoc~
bull mdash u bullDT3 O laquoccce tshy ^ D
l_ Cshy CCO O 0 0-0 Qmdash
CJ I- r-CM
1 1
U-Qshy
bull bullbull ^
O t_ 0 Q
-LJ
raquol
a o iT o c o
U) c
c u CD O
I I I CU c
Q) CJ CU W a ltshyon J2 o l- E E gt QCO CD O
I I I
ID JJ CU ES
J-gt imdash O Q Z CO w t --shy O mdash O 3 O laquoshy ^ c
_ICO a 0 0 0
^ sect5oa I-Q
CO X u_ y o- o=gtLJt-a
3shy
^
1
1
VO
m
1
i
1
t
_
3 lta i- U) 0 0
a
lA
lAbull
0 O
JI E oj3 gt E re mdash O X X co Qj
C 1 O
W 3
U L CO O
4J CO
0mdash CCD gt j ti --shy c JJ 4J
1- laquo 3 = C 3 or cu ogt tn Q -shy
E L n CD J-gt o o gt gt s o ---shyDior 3 3
mdash Tgt o cr cr mdash mdash CU 0)
o a CD -a OLJ U CU
N CU COT 4JT3 poundmdash 0gt U V
raquoT3 mdash agt OJ gtgtcu laquo c c
T3 O
C
C
Zlshyo ui u- Li ^ ^~bullgt lt LJ
lAXvOX
VO X ^ X
Xcjltshy
lA x
CM
O x
3shy
_ X
r^5 X
_ X
CM X
mdash c^ C3 O
c a bullbull o c c
mdash 4J O I I 4J
01 JJ 4J 1C laquo
3 t- C raquoJ O L (D CU C mdash o a~o mdash o
i i
C J J W CO II) O W IT OC N 03 = OJJ C O I- -= C O
I I
o o
ON X mdash
CMr-raquo
00 Orshy
X CO
vo ro O C 5) JJ Jshy I- I gtJZ-00 s a o
LJ CO eo UTJ a- I I O C X J O gtZ 1 re O
i CM
LA
LJ
O mdash c imdash LJ lt a gt y lt 2
ltCO O
O^mdash
laquoshy rmdash
CM Tmdash
n rmdash
_^jshymdash CO
LJ
j ^ |
52
14
what appeared to be natural materials although its location on the
cleared and leveled landfill tend to contradict this possibility
Most of the landfill is vegetated by a thin layer of grasses
sedges mosses and annual herbaceous species The northeast corner of
the landfill is unvegetated and cover material appears to have been more
recently applied This section is elevated 4 to 6 feet above the rest
of the landfill and appears to have received a second newer layer of
waste A 4-foot thick layer of carpet waste was encountered in
Excavation 1 but not in other excavations This section is adjacent to
the newer active landfill The landfill area just west of the access
road crossing (near Excavations 7A 8 and 8A) was also unvegetated due
to relatively recent grading operations
Ground Water The landfill appears well drained as ground
water was not encountered during any of the excavations Excavated
overburden was damp from the recent heavy rain but intergranular macro
pore spaces were free of water
OBSERVED QUANTITY AND CHARACTER OF DRUMS
A total of 45 drums were observed buried in the landfill
Table 52-1 presents a drum log describing each excavation and the
observed drums Data on the contents and condition of drums is
summarized in Table 52-2
Of the total drums observed 15 (33) were crushed flat
Although these could possibly still contain small amounts of waste they
are probably considered empty under RCRA guidelines Thirty (67) of
the total drums discovered were uncrushed and capable of containing
waste Seven (88) of the 8 drums sampled contained liquid or sludge
waste material Thus at least 7 (23) of the uncrushed drums contained
some liquid or sludge waste
15
en C Cl
bullo gtraquormdash
c mdash a
o c re bull mdash c
~ o mdashbull 4Jmdash
10 0 mdash
gt O
ro CO
fcshy0
c
C
vgt 3 0
1 rea
-gt
mdash
3 o T3
lt-O
C j C
CB 3 TJ ii i- 3 mdashQCOa
ifl u bull c c
t_ o
mdash shyO
mdash
L re N
co
t-O
mdash
mdash lfl
V) O
CO N CO pound re
0 mdash
^1 10
ltP O C raquo
CM reO
o f shyi O
mdash mdash 3 - D
c 1
CD bulllaquo
mdash3
D mdash
1 C
Q CO
CD Ifl 4-gt CO
Q
CM
r-
Ul
Q Ul gt EC Ul CJ CO o t5bullpound
z O mdash
C Ci o^
O Cbulla 3v iC MW5 CO 4J3 u CS- Ifl CBC J C O - U
gt Cgt Omdash Oi O
U- 0) Ifl bullgt-gt 1 W C
to lt-gtT3 gtmdash
0) gt shyJ 0)
C OltJ bull O T 3 C D C P
133mdash 4J bull ifl tshy Vgt~ V a O V4JJ
C o
C mdash
O Ifl
3 fc 0)
i-
c
U) re gt
ai C mdash
C mdash
CO gt c o
bull to y 3 cc Q
ltbull-CB
1 4Jin
bullD reCD jCJJC TJCD mdashbullD bull mdash
CD 0t- u iflo ifl
0 C ^-
CB laquo
3 ltbull-
0)^shy
C
0 Cgt O
1 O CTl C
T3 1 mdash CB O
mdash CB mdash in J o 3 tfl C ^ CO 0 gtltgtshy
O gtgtc 01
CO 3 1- mdash C Cregtmdash laquo
TJ W TJ mdash i re traquo-
shyU mdash
O Q
COCO^^
mdash ^
mdash gt C 0gt mdashO ~ bull
Ul
o auO
CCUl
mdash K o tO Ul Q
mdash OT30Jj c mdash4Jt- Jpound O Wre c i re03 gt
lt~i- laquo o ai
0 ) 3 gt O ^crc Ifl - CO -^mdash
3 mdash Q iflmdash 1- O 3 3
O V O ltraquo-o laquoTJ
gt
T3 - o
gtgtmdash J-gtmdash
Dmdash
6-o
09 bull mdash gtpoundbulllt-gt
re a
Ul X t5
Cpound O Z
fl) mdash^ C B gttflOl3T3T3l_ 3 Q)O mdash mdash
tn mdash
shyD CB
mdash mdash
mdash tt
CO C T3 poundi mdash JCmdash re
^ C O C X CB ^ - S - C C O mdash re O Q DW4shy
re shyu O 1
O Ul X EC Ul mdash
x a^s ox
CO
^) Z
J
1-o t-Ul X r-u 0
o j c gt T3 i -gt c tu mdash c u r e mdash
- C D mdash T3 - C M mdashbullOJJQmdash re3inecrec u c r e o mdash lt~ bullz c~4J O CX t ^Jw o r e -gtgtOgtgtshy3 c j t shy re mdash mdash ret- i o Qmdash gtgtpoundgt a
i reraquo CD 0) bullbull Ifl t-
Q ) t ) O pound O ^ laquo gt - Ow re re ro re re -gt Q mdashc 5 shyu a j-gt D t- raquomdash mdashCB C re C CO 3Q mdash O mdash O U
Htshy ae cu coo)
1 O i i
shya shyo j CD C bullgt o mdash c o c o coco mdash plusmngt o ~a v c en CD
mdash C O
raquoCJ 3C c re amp- ogtCD J o 3 CC C I-Omdash 3gt O
3
O ro
Ul X 1mdash
u O
Ul o r-Z Ul
gtV~ omdash Dlshy ^mdash mdash wre3 i cc
mdash cr bull gtJJ mdash C mdashi QIgtJ^re a shyJQI- o 0mdash
O bullO 3laquo laquo
jjmdash ureoO mdash O N 0)rc3recomdash4Jt-4JpoundmdashC C mdashmdash mdash u
1
shya 0 -
mdash gtgt re-raquo-gt CUD laquo E CD
^ J-1
CJ eoc
4JCB CO
mdash O
C 1- C mdash O C B C B C E J mdash J ltshy shyo cn o o c o r e c shyU -gtO OJC D ifl roc
T3 3 I U 3 laquo-
Ifl CD 1 W ^J 4 J 4 J c -aiflj jc
CB C r e O C B lt-gt -Jgtcoraquo C C -WE O O ) ~ O O O mdash O
Ul O
c ui =gt z
o
1-CC Ul Q
Q z ^ Ul
2 gt Ul O
o Cpound
^ CO
Ul Q ^
z o
(O U S Q
Slt
t5 lt
Z5O
1mdash z ui
Qa Ul
CD 0-1
u m O_J
O2^ltUl
O CC Ul Q
VOCO
CNlA |3
VO ^
CJ |CO |
CJ CMI3 f~ rojO VO rolo
^
ymdash3 CC
roCM
ro O ICNj
ro rolvO ro ro
ro A
rolvO r-jO
00 C3N
ec a m
r3
CO
3 a ty r-
cc Q
(M CM
to z
m 3 c O
u _i co
U-O
O 3-IObull - I c y
fshy lt- ICO r- r-ICM O U lfN ro -mdashla1 f~ laquo- ]CO bull- -ICM O O J|O O
c U) CO
mdashbullre re
mdash re
mdash i ltC c tz
j lt
i lt
5 0 0 G O o o o o z bullU 4J J h- J shyJ tmdash tmdash
^33
J3 3
O 3
Q 3
_Cr(bull
shyC 3 t)
CC IP y
C2 zgt c J
1mdash O 5
53
16
The condition of the uncrushed drums was highly variable with
only 4 (13) rusted and decomposed to the point of structural weakness
These drums were found in Excavation 10 at the far west end of the
landfill which is believed to be the oldest section (See Plate 52-1)
Interestingly two almost new looking drums were also found in
Excavation 10 at a greater depth than the four rusted drums The
remaining 26 drums were observed to be generally intact and structurally
sound Some were dented partially crushed or rusty
CHARACTER OF WASTES
Air Monitoring An OVA and HNU were used to monitor the air
for concentrations of organic vapors during each excavation Above
background instrument readings indicative of contamination were
regularly recorded when monitoring the air just above or inside of
drums A general contamination of the ambient air in the workspace was
noted only during Excavation 8A where above background readings of +13
in the excavation pit and of +6 above the excavation pit were recorded
Explosimeter readings were obtained from three drums -- 10 lower
explosive limit (LEL) from drum sample 10A 20 LEL from drum sample 6B
and 100 LEL from a drum in Excavation 8 Instrument readings are
presented in Table 52-1 and Table 53-1
Visual Observations The following types of waste were
observed during the excavations
fabric waste (carpet waste)
crushed drums
drummed waste - liquid sludge and solid
uncontainerized dried sludges and pigments
stained soils
Fabric waste scraps of synthetic non-woven fabrics5 heavy
carpet-like fabric and backing material were found only in Excavation
17
CM
CO LJ fmdash O z
laquo 4J
u TO 4-gt
c bullmdash
k bull mdash E mdash 3 3 i-^ O
mdash TJ --raquo co co 4J
E CO O U L U
E 3 c T3
C O a o
is
CO c to 3
U
TO
E O t_ U_
o o
1 ltmdash c
mdash tmdash TO 4J bull C TO 0 O o c u 3 TO
t_ 0) 0 4J
U)
mdashOTOgt
Cw bull aco jc
N 4J a
mdash L Q) re co T E
CO
bullo gt egt mdash c mdash bull o ^^73 C E gtO O mdash 3 J-gtmdash N 4J L 3 mdash 1--C gttTC bull
CX 01C JJ TO O mdash
TO trt mdash t- E mdash 3 JJ a O Q
C I 0 X E mdash C mdash CO
mdash o laquo (D-O mdash O O bullbull B Ol o -cmdash e oic f~ to a (gt TD mdash
E 1- Cpoundmdash 3 O O CO P m T1
L u
T3 CO
lto sshy0 O CA W
laquoT3 O CO 0 C J= CO tlaquo Q bull 3 O Ol 1- C o mdash 3 E a
3 E E i- to
Z L
mdash bull mdash O 4-3 Cl Q
bullD 0) CO T5 N CO mdash C -P 1 0 U TO O mdash 4J Cfc
mdash U) c shybullgt O w C O Q (5 4J 0
3 -J bull U)
5 gt TO_ U
bull gt pound mdash 3 mdash L ro TD
JJ-D - CO TO laquo QO
C 0
^ 0) T3 mdash O
r to 3
O O L L
0
01 TO gt bull
tshy mdash OT3 mdash
CD O C N U) O mdash
TO O CO mdash C C
bull^ ~ CO TO TO gt U iJ
mdash C W to O
5 c c 4J 3 CO X LJ
^ bull bull0 laquolt- ej
TO CJ CO mdash C JJ
z u to mdash T3 4J ai TO CD C laquo bull c c ugt o cr 0) bull mdash CO mdash O bull gt JC TO ^ mdash Q CO O JJ O Q bull- CO to mdash to c Z CC O il mdash 4J gt
mdash Omdash O1O CD mdash U) TO C X mdash O CO C L mdash Cvv O W pound G CO C C
O gtgtgt C C mdash CO C TO CO 3 E mdash -J laquo 1- bullgt CO 0 to
bullo CO
cshyo bull
ugt C CO TO c w 4J-Q co e a c
mdash re TO in E to
Q
JJ c bullo
a LJ co E bull LJLJ
O mdash zx ZQ
ax
z o mdash1mdash Q
mdasha o CO LJ a LJ ~J
s CO
JC u
bullmdash
^ 4J bull
bullO bullmdash
gtgt3 TO CT L mdash Olmdash 1 O CD mdash 3 a CT cshy re 3 a c- o
^j C CO E Ol
bullmdash CL
bull CO 01 D 3
U
T O a
E Ol
bullmdash av^ CO 4J IA TO 5
T3 CO C
bullD
mdash mdash O CO
3 CT
bullmdash ^
bulla CO L
4J
C CO o 3
(A C TO
Imdash
03
ai_ 3 a bullo bull mdash 05 3 O) 00
mdash mdash C c gtgt G CO
O O
bullo^ = c a 0)
E C O umdash u a L_ bull OlCD mdash
4J mdash
u) obulla o u) amp 5 c -a 7 O C mdash o mdash _ i- (0
CO E laquoJ
C
a
bulla c bull o bull
c bullQ CO
3 01
CT mdash mdash a mdash -v
t- Ol CC-D 0) 3
CJ raquo
x^ CO
bullo 3
lt) bull_
gtraquomdash CO O 1- Ui O)
bulla ^ c mdash mdash mdash TO co in
s^
COOlbullo3
U) mdash
gtgtmdashCO O1- U)Ol
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D C
mdash TO
i) ltgt
mdash mdash o
ltn
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c mdash
TO 4J
U)
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laquo_
o to
T3 to C
TO
U)
bullo ltr
1
03 shyogt
o wo LJtshy to
o z
CO d _l O LJ LJ _J hmdash J C- LJ XZampS LJ mdash
Q mdash
O
Q mdash
O
to o o
Q
O 1
to O
O
O
o CM
I 1 1 i
Q
ceo oz u lt
O CJ O-J
o ltDpound 15 t-
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1mdash 3E LJ
13
rshyC5 Z
y a Q ^
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mdash s Cu a
gt 0
Q
mdash
Oini O CO
Q
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O
r-
o
o r-
CO o
o
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o
Q
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a mdash o o T~
1 o
0 -~
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Q mdashbull
O o or_
A
to 2T
f ro
CO X
O
Q
O O
Q
mdash O o o rmdash A
CO X
0 ON
CO X
o o ^
1
f
CO
o
to X
00
to X
CO
to X
CO
if
LJ
CO lt
LJ CM 51 r-rmdash
tmdash CM CM ^_ CM
CO CM ^x
CM (M CO CM
Q -
-^ ^ -
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^ shy-
1
gtZLJ lt O C3 o-s - shy laquo raquo laquo S laquo 5 2 LJ Z
ui o -1 LJ
i mdash lt sectco z 1
ltT -^
bull~
lt
^
deg
bull VC
^
lt 1
sect
lt 1
eS
CO 1
CC
18
bull -a gtgt CD
CO S jj
0 0
CO O
bullo CD jJ
bullo z 3 O L
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19
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20
1 (See Plate 53-1) This is the predominant waste material currently
being disposed of in the active landfill
Crushed drums were distributed throughout the original
landfill and were found in Excavations 2 4 4-5 7A 8A and 14 Some
drums such as those found under the road in Excavation 7A may have
been crushed by heavy equipment operating in the landfill Others like
those found at depth in sandy fill in Excavation 2 appear to have been
crushed before burial Drummed liquid and sludge wastes are also
distributed throughout the landfill (See Plate 53-2) They were found
in Excavations 1 4 5 6 8 and 10 These wastes are discussed below
One sealed drum was openedand found filled with refuse -- paper cups
towels paint covered rags etc One open and partially crushed drum
contained a dark granular solid waste This material was sampled
(Sample 10B) and found to be nonhazardous
Small deposits of dried pigmentsludge were found in
Excavations 3 4 6 9 and 13 Discernible layers of pigmentsludge and
stained soils were present in Excavations 7A 8 and 8A (See Plate
53-3) Of particular note was a 2 to 4-inch thick layer of
grey-colored dried sludge found at Excavations 7A and 8 All of these
wastes were sampled and the results are discussed below
Laboratory Analyses
Laboratory analyses were performed on 10 selected samples
obtained from both containerized (drummed) and uncontainerized wastes
Samples were analysed for 3 metals and 87 priority pollutants including
11 acid compounds 45 baseneutral compounds and 31 volatile organic
compounds Table 5-4 summarizes the analytical results and the
laboratory data sheets are presented in Appendix D
Of the 45 priority pollutant baseneutral compounds only 4
were identified in the samples that were analyzed Baseneutral
21
compounds and particularly phthalates were the most prevalent
chemicals and also were reported in the greatest concentrations The
highest levels of naphthalene (1200 ppm) bis (2-ethylhexyl) phthalate
(110000 ppm) and di-n-octyl phthalate (6200 ppm) were found in sample
4A a translucent red liquid obtained from a drum The highest
concentration of benzyl butyl phthalate (13000 ppm) was found in sample
6B a clear liquid and pink sludgepigment obtained from a drum
A total of 8 volatile organic compounds were identified The
highest levels of benzene (100 ppm) xylenes (19000 ppm) and
ethylbenzene (5300 ppm) were found in sample 5A a clear liquid
purple-grey sludge obtained from a drum Toluene was found in highest
concentration (12000 ppm) in sample 1A a purple-grey thick opaque
liquid obtained from a drum Methylene chloride (13 ppm) was
identified in greatest concentration in sample 8A-C a purple stained
soil and powdery waste Sample 10A a purple liquid obtained from a
drum was the only sample found to contain 1-1 dichloroethane (2000
ppm) Finally trace levels of trichloroethylene (sample 10A) and
111-trichloroethane (sample IB) were also reported
Samples were tested for three metals - cadmium zinc and
chromium The highest concentrations of cadmium (2200 ppm) and zinc
(5700 ppm) were found in sample 4A a translucent red liquid obtained
from a drum The highest level of chromium (52 ppm) was reported in
sample 5A a clear liquidpurple-grey sludge obtained from a drum
22
60 DISCUSSION
61 EXISTING SITUATION
Under existing conditions relatively small quantities of
volatile organic compounds (VOC) are indicated to be leaking from wastes
buried on the landfill site To date ground and surface water
monitoring results indicate relatively low concentrations of VOC in the
ground water and below detection limits in the adjacent brook (See
Tables 61-1 to 61-10) The results indicate that no potential health
risks from VOC and other constituents currently under observation are
being caused by the landfill operation to down stream surface water
users It would be prudent for Troy Mills to continue to monitor the
quality of Rockwood Brook upstream and downstream for VOC and on the
basis of waste analyses (previous section) to monitor ground and
surface water points for toxic metals and baseneutral compounds
62 SITE HYDROLOGY
An analysis of the hydrology of the landfill site was
performed in 1982 (NAI report of September 1982) The subwatershed that
contains the landfill site is (about 44 acres) a small fraction of the
watershed area that contributes to Rockwood Brook above surface water
sampling point C (about 1650 acres see Figure 62-1) This indicates
that most of the flow of the brook at point C (about 97) is contributed
by upstream watershed areas Thus leachate discharging into Rockwood
Brook from the landfill site can be expected to be diluted by over 30
times its volume This factor and the volatilization which naturally
occurs results in parameters detected in the Troy Mills monitoring
wells often becoming undetectable when they enter the brook
f 5
Geologic conditions which were defined in the NAI report of
July 1982 indicate that permeable deposits of sand and gravel overlie
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27
TABLE 61-5 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M5 (UPGRADIENT WELL)
Parameter Date Sampled 11-22-83
Specific conductance
pH2 81
Dissolved iron mg1 036
Dissolved manganese mg1 010
Chloride mg1 10
Phenolics mg1
3
023
Identified volatile organics
None identified ND
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (yg1)
28
TABLE 61-6 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M6
Parameter
Specific conductance
PH2
Dissolved iron mg1
Dissolved manganese mg1
Chloride mg1
Phenolies mg1
Identified volatile organics
11-dichloroethane tetrachloroethylene 111-trichloroethane
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vg1)
Date Sampled 11-22-83
152
lt002
29
6
0002
27 trace 140
29
TABLE 61-7 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M7
Parameter Date Sampled 11-22-83
1 47 Specific conductance
pH2 62
Dissolved iron mg1 002
Dissolved manganese mg1 0026
Chloride mg1 gt2
Phenolics mg1 0070
3 Identified volatile organics
111-trichloroethane 5
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vig1)
30
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glacial till and bedrock The sand and gravel deposits form a permeable
conduit through which leachate from the waste burial areas migrates
The permeable deposits lie in the area north of monitoring well M-l (See
Figure 62-1) In general the water saturated thickness of the sand
and gravel in the vicinity of the north-south access road is 6 to 12
feet
64 POTENTIAL FOR GROUND WATER CONTAMINATION
641 Estimated Quantity of Drums
The test pit excavation and sampling in the drum burial area
indicates a potential source of ground water contamination for the
future Many of the drums encountered were in fair to good condition
and contained liquid wastes An estimate of the number of drums in the
deposit was made with the following assumptions
1 The complex magnetic anomaly was simplified into a geometric solid 600 feet long 40 feet wide and 10 feet deep with a volume (V) of 240000 cubic feet
2 Each steel drum (D) occupies 105 cubic feet (including voids)
3 The density of packing (P) was assumed to be 50 of the packing that can be achieved with perfect cubic packing
THEN
N = estimated number of steel drums
N = (VD) (P)
N = (240000105) (05)
N = 11429 drums
The results of the drum excavation work provides a basis for
estimating the potential for specific types of chemical loading In
general three main classes of chemical substances were identified in
35
the drums The chemical substances included baseneutral extractable
organic compounds (mostly phthalates and lesser amounts of naphthalene)
volatile organic chemicals and metals
642 Phthalates
The phthalate esters found in the drums include
bis (2-ethylhexyl) phthalate ^0^3 benzyl butyl phthalate di-n-octyl phthalate Jd~7
Bis (2-ethylhexyl) phthalate was found in the highest
concentration at 110000 ppm (11 percent) Benzyl butyl phthalate is at
the second highest concentration 13000 ppm (13 percent)
Characteristics of those phthalates found are presented in Table 64-1
TABLE 64-1 PHYSICAL PROPERTIES OF PHTHALATE ESTERSshy
di-n-octyl bis (2-ethylhexyl) butyl benzyl DOP DEHP BBP
ALTERNATE o-Benzenedishy di (2-ethylhexyl) benzyl butyl NAMES carboxylic phthalate phthalate
Molecular Weight 3910 3910 312
Melting Point -25degC -50degC -35degC
Boiling Point 220degC 386 9degC 377degC
Vapor Pressure-mdash lt02 torr (150degC) lt001 torr (20degC)
Not
2xlO~7torr (20degC) Available
Solubility 3 rngfc (25degC) 04 mgfc (25degC)
58
13 rngH 48
Log octanolwater 92 873 58 partition coefficient 53 48
Versar Inc 1979 Water-Related Fate of 129 Priority Pollutants Volume II Prepared for US Environmental Protection Agency PBSO-20438 December
bullbullOther names listed in Versar 1979 vMore than one value has been calculatedreported
36
Bis (2-ethylhexyl) phthalate is the most well-studied of the
phthalate esters though the information on phthalate esters as a group
is limited The three phthalates identified at the Troy Mills site have
relatively low solubilities and are readily adsorbed onto suspended
particulates Microbial degradation is effective under aerobic
conditions bur is generally slower under anaerobic conditions
(nonexistent for bis (2-ethylhexyl) phthalate)
The above characteristics are important for two reasons One
the extent and nature of contaminant migration from the site are
dependent upon the physical characteristics Second the treatment
(clean-up) alternatives for contaminated ground water or soil can be
estimated from the characteristics
From the available information it appears that the phthalates
present at the Troy Mills site would be relatively immobile due to their
low solubilities and high adsorption rates The presence of toluene and
methylene chloride at the site however may increase the phthalates rate
of migration
It is important to note that none of the phthalates have been
found to be present in the monitoring wells nor in the surface water
sampled probably due to the low solubility and high adsorption rate
37
643 Napthalene u K r
Naphthalene has also been found in significant quantities in
the sampled drums Naphthalene is a polycyclic aromatic hydrocarbon and
has the following properties
Molecular Weight 12819
Melting Point 8055
Vapor Pressure (20degC) 00492 torr
Solubility in Water (25degC) 344 mgfc
317 mgfc
Log octanolwater partition coefficient 337
Versar 1979
Naphthalene has mid-range adsorption rates and solubility It is
therefore inferred that there would be some adsorption to soils in a
ground water environment It is important to note that naphthalene has
not been detected to date at the monitoring wells or the surface water
sampling locations This is expected to be a result of adsorption on
the soils
644 Volatile Organic Compounds
Volatile organic compounds tend to migrate readily within
soils and ground water They are therefore considered a threat to
surrounding ground and surface waters if they are released in sufficient
quantities
Volatile organic compounds were detected in samples from six
steel drums The total volatile organic (TVO) concentrations in the
38
wastes ranged from 9 ppm to 30100 ppm and averaged 8570 ppm In order
to determine the potential for future contamination by volatile organic
compounds an estimate of waste quantity based on information from the
drum excavation program was made It was assumed that 7000 steel drums
in the deposit are 60 full of liquid waste with an average TVO
concentration of 8570 ppm The computed volume of liquid waste is
231000 gallons with an average TVO concentration of 8570 ppm This is
equivalent to about 1980 gallons of pure TVO
Two of the volatile organic compounds that have been most
prevalent in the existing ground water monitoring system are
111-trichloroethane and ethylbenzene The EPA suggested no adverse
response level (SNARL) for 111-trichloroethane is 330 ugpound for
1 day of exposure and 35 jigd for exposure over a life-time in
drinking water
In general ethylbenzene is a prevalent chemical in the
environment Sources include commercial (eg petroleum and petroleum
by-products) motor vehicle exhaust and cigarette smoke An intake of
16 mgday (1 mgfc) has been calculated as an acceptable rate to
protect from toxic effects Carcinogenic effects have not been
identified to date The physical properties of ethylbenzene are
presented in Table 64-2 The principal mechanism for removal of
ethylbenzene from water is volatilization In addition to
volatilization adsorption may also be an important removal mechanism
based on the log octanolwater coefficient This factor is important in
evaluating the migration of ethylbenzene from the disposal site
Toluene which was also identified in waste and ground water
samples exhibits properties similar to ethylbenzene in that it
volatilizes easily Toluene which is also referred to as methylbenzene
is distinguished from benzene by the substitution of a methyl group for
one hydrogen atom Physical properties of it are presented in Table
39
64-2 The EPA suggested no adverse response level (SNARL) for toluene
is 1 mgpound in drinking water with a maximum exposure time of ten
days
TABLE 64-2 PHYSICAL PROPERTIES OF ETHYLBENZENE AND TOLUENE
ETHYLBENZENE TOLUENE
Molecular Weight 10616 9213
Melting Point -949degC -950degC
Boiling Point 1362degC 1106degC
Vapor Pressure at 20degC 7 torr 287 torr
Solubility in water at 20degC 152 mg2 5348 mgd
Log OctanolWater Partition Coefficient 315 269
645 Metals
One liquid sample contained high concentrations of cadmium
(2200 mgd) and zinc (5700 mgd) indicating that the waste deposit is
also a potential source of certain toxic metals Tests for these metals
have not been made to-date in ground or surface water samples It would
be prudent to add toxic metals such as cadmium chromium lead and
mercury to the list of parameters that are being monitored to further
characterize the quality of adjacent ground and surface waters US
EPA and New Hampshire drinking water standards for these metals are
cadmium 01 mgd chromium 05 mgpound lead 05 mgd mercury 002
mgd Although zinc is not considered a highly toxic metal the
US EPA has set a secondary drinking water maximum contaminant level of
5 mgd on this metal
40
70 CONCLUSIONS
The following conclusions were drawn during this
investigation
1 A steep-gradient irregular-shaped magnetic anomaly is present under closed and covered portions of the south part of the Troy Mills landfill
2 The magnetic anomaly is caused mostly by an irregular-shaped accumulation of disposed steel drums
3 In a randomly conducted sampling of drums in the source area for the magnetic anomaly 16 of the drums contained liquid andor sludge 33 were crushed flat and 51 were not sampled because there were no accessible openings
4 Laboratory analyses indicate that the random waste sampling contained significant concentrations of several volatile organic chemicals several baseneutral priority pollutants and high levels of cadmium and zinc
5 Observed concentrations of volatile organics at the monitoring wells are relatively low Because of their potential for migration in the ground water continued monitoring of volatile organics will be required
6 Volatile organic chemicals have not been detected in Rockwood Brook to-date Because of the presence of low levels of volatile organics in the ground water they should be monitored in the brook on a regular basis to confirm the lack of impact
7 The presence of high concentrations of cadmium and zinc in one of the waste samples indicates that trace metals should be monitored periodically
8 The presence of baseneutral extractable compounds (phthalates and naphthalene) in all of the analyzed waste samples indicates that these compounds should be monitored periodically
9 The phthalates are not expected to migrate freely because they have low solubilities and are readily adsorbed onto soil particles
10 If elevated concentrations of volatile organic compounds trace metals or baseneutral extractable compounds should occur in the monitoring system (wells and brook) in the future a need for site remedial actions to mitigate the potential for downgradient ground and surface water contamination could develop
~
80
41
RECOMMENDED PLAN
Based on the preceding conclusions it is recommended that the
following plan be implemented by Troy Mills Inc
1 Continue monitoring ground and surface water quality at the Troy Mills Inc landfill sampling on a quarterly basis with sample collections during April July October and January
2 To confirm the absence of the landfills impact on Rockwood Brook test samples for volatile organic compounds by GCMS from surface Stations B (upstream) and C (downstream) on the April and October samplings
3 To determine if trace metals are present in downgradient ground waters conduct analyses for cadmium chromium lead mercury and zinc on samples from all monitoring points during the April sampling and on subsequent sampling rounds if necessary
4 To confirm the continued absence of baseneutral extractable compounds in downgradient ground and surface waters conduct analyses for baseneutral extractable compounds on samples from monitoring wells M 2 and 3 and surface Station C (downstream) on the April sampling and on subsequent sampling rounds if necessary
5 If a sudden rise in concentrations toward unacceptable levels should occur in the monitoring system (wells and brook) additional monitoring rounds at a monthly interval should be conducted to confirm the rise in concentrations
6 If elevated concentrations persist and are verified by the additional monitoring remedial alternatives will be defined to mitigate the potential for downgradient ground and surface water contamination
Respectfully submitted NORMANDEAU ASSOCIATES INC
Dennis R Sasseville Project Manager
Donald H Bruehl f laquo | APG Senior Hydrogeologist -^ - - AIPG Certificate No 2272 ^ -v^
^^Z-^^
APPENDIX A
SITE SAFETY PLAN
GENERAL SAFETY PLAH FOR
TROT MILLS LANDFILL TROY MEW HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
Prepared by
NORMANDEAU ASSOCIATES INC Bedford New Hampshire
R-457
November 1983
TABLE OF COHTENTS
PAGE
SECTION 1 BACKGROUND INFORMATION 2
Identification 2 Personnel 2 Site Description 3 Project Description 5
SECTION 2 HAZARD EVALUATION 6
Overall Degree of Hazard 6 Specific Hazards 8 Necessary LPP 8
SECTION 3 FIRST AID FOR EXPOSURE 10
SECTION 4 OPERATIONS SAFETY PLAN 11
General Personnel Protection GuidelinesAction Levels 11 Site Reconnaissance 13 Task 1 - Magnetic Survey Topographic Survey 14 Task 2 - Drum excavation and Sampling 15
SECTION 5 EMERGENCY INFORMATION 16
Emergency Telephone Numbers 16 Route to Hospital 16 Contingency Plan 17
APPENDICES 18
A - LEVELS OF PERSONNEL PROTECTION 18 B - DECONTAMINATION PROCEDURES 23 C - PERSONNEL AND RESPONSIBILITIES 25 D - PERSONNEL CASUALTY 26 E - GUIDELINES FOR SITE OPERATIONS 27
GENERAL SAFETY PLAN FOR
TROY MILLS LANDFILL TROY NEraquo HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
The following is a Safety Plan for on-site activities performed
during the Investigation of the Troy Mills Landfill being conducted by
Normandeau Associates Inc (NAI) of Bedford New Hampshire
The document is intended to be an in house working guideline
for personnel trained and experienced in hazardous waste field work and
not a treatise on safety Familiarity with standard equipment and proshy
cedures is expected Where possible non-site specific information has
been appended
All NAI employees subcontractors and visitors will be required
to follow this safety procedure plan and to report to either NAIs proshy
ject manager (P M) on site coordinator (OSC) or safety officer (SO) on
issues relating to safety
SECTION 1
BACKGROUND INFORMATION
IDENTIFICATION
Site Name Trey Mills Landfill NAI-ID No 457
Trey Mills Inc Troy NH 03465
AddressLocation At the south end of the dirt road about 15 miles
south of Troy NH between Rockwood Brook and the
old Boston and Maine Railroad grade
County Cheshire Phone 603-242-7711
PERSONNEL
Brook Dupee Bureau Hazardous Waste 603-271-4611
State Contact John Regan Bureau Solid Waste 603-271-4586
Dan Allen WSPCC 603-271-2755
EPA Contact
Other Contacts
Client Contacts Barrett F Ripley (Vice President)
NAI Personnel - (472-5191)
Project Manager - Dennis Sasseville
On Site Coordinators - Alton Stone
Safety Officer - Elizabeth Gross (Phoenix Safety)
Technical Director - Don Bruehl
Other - Douglas DeNatale Steve Ransom
SITE DESCRIPTION
Type of Facility Company (on-site) landfill
RCRA Status Generator Disposer
Size About 15 acres BuildingsStructures None
Surrounding Land Use N Forested
(one mile radius) E Abandoned Railroad
Forest RuralResidential
S Forested
W Forested Mountain side
Unusual Features or Terrain None
Site Activities - Troy Mills manufactures textiles carpets and related
products Since 1968 waste materials including
drummed wastes have been landfilled on company proshy
perty Drums mostmany of which may be emptycrushed
are buried in an inactive section of the landfill
The active section is currently accepting waste
which is considered to be non hazardous
Specific - Improper disposal of hazardous waste
Problems - Leachate seep
Contamination of ground water
Hazardous WastesMaterials On-5ite
Wastes - Uncured foam rubber latex sludge
SBR rubber silicone defoamer potassium oleate soap
calcium carbonate and feldspar filters zinc oxide
and sulpher salt cure system
- Vinyl plastisol sludge
PVC dispersion resin DOP and DOA plasticiser
calcium carbonate filler organic pigments AZO
dicarbcnamid blowing agent zinc salts expoxidized
soybean oil cadmLum-bariin-zinc stabilizer Varsol
MEK prints and topcoats sludges
PVC acrylic resins organic and inorganic pigments
MEK solvent toluene silicate fillers
Industrial solvents and chemicals
11 -dichlorethane 12-dichlorothane
111-trichloroethane trichlorethylene tetrachshy
lorethene methylene chloride toluene benzene
ethylbenzene benzidine 33-dichlorobenzidine aeroshy
lein acrylonitrile napthalene benzoperylene dibenshy
zoanthrasene idenopyrene
Pesticides
There is a possibility for low levels of pesticides
to be on site These would include Chlorodane
heptachlor expoxide toxaphene aldrin alpha BHC
beta BHC 4-4-DDT endosulphan 1 heptachlor
PROJECT DESCRIPTION
Purpose Tb characterize ground water conditions at the site and to
characterize wastes buried on site
Specific Tasks
Site Reconnaisance
Task 1 - Magnetometer SurveyTopographic Survey
Task 2 - Excavation for inspection of drums
SECTION 2
HAZARD EVALUATION
Overall Degree of Hazard - Moderate
Task Hazard Proposed LPP
Site Reconnaissance Low Level C
Task 1 MagnetometerTopographic Surveys Low Level CD
Task 2 Drum ExcavationSampling Moderate Level B
Conpany records have indicated that a variety of industrial
and potentially hazardous wastes including drummed wastes
were disposed of on site Several of the subtances are
trade name materials or industrial process materials and it
is difficult to determine the specific chemical composition
Hazard is dependent upon concentration of material state of
material (solid sludge drummed liquid) and degree of
decomposition
Many of the materials - SBR rubber silicone defoamer
potassium oleate soap calcium carbonate and feldspar
fillers zinc oxide and sulpher salts plasticiser
calcium carbonate filler organicinorganic pigments AZO
dicarbonamid blowing agent epoxidized soy bean oil
cadmiura-bariun-zinc stabilizer - probably do not represent
a significant hazard to an inspection team if they are
bound into a sludge or solid Personnel are not likely
to injest or come into a prolonged high concentration
contact with these materials In powdered or dust conshy
ditions the materials are more hazardous due to the inhashy
lation of contaminated particulates
MEK (TLV-200ppm) toluene (TLV-100ppm) and Varsol
(turpentine thinner composition unknown) are volatile
organics which require respiratory protection and contact
protection
Depending upon state and decomposition PVC resins could
be a source of vinyl chloride monomer (VCM-a carcinogen)
requiring respiratory protection VCM is not adequately
filtered by air purifying respirators
Results from ground water sampling showed low levels of
industrial chemicals (PPB range) At these low conshy
centrations the chemicals do not represent a significant
hazard However the low concentrations in ground water indishy
cate the possibility of higher concentrations in the waste
materials
Industrial chemicals - napthalene (TLV-10 ppm) peryshy
lene anthrocene and pyrene which are hazardous
through inhalation or absorbtion Furthermore as
double benzene ring chemicals they are potential
carcinogens
Results from ground water sampling indicated possible
low levels (parts per trillion) of several pesticides
- chlorodane heptachlor epoxide toxaphene eldrin
Alpha BHC Beta BHC 4-4-DDT endosulphan These were
tentatively identified during a first analytical run
but not confirmed during a second run laboratory
review (GCA Bedford Mass) determined that the
material was actually a complex of highly degraded
heavy organics derived from the industrial waste The
presence of pesticides in industrial textile waste is
unlikely
Specific Hazards
1) Inhalation of organic vapors
Excavation of buried material and sampling of drums could
initiate high vapor concentrations
2) Fire and explosion
Many of the solvents are flammable liquids and volatile
Excavation of material and sampling of drums should
proceed cautiously in order to avoid rupturing shocking
or sparking of drums and material
3) Inhalation of contaminated dustparticulates
Excavation of buried material may result in a release of
particulates
4) Contact contamination
Excavation and sampling of wastes could possibly result in
contact with contaminated waste and soils necessitating
protective clothing
Necessary LPP
Site Reconnaissance - Level C The site has been visited on numerous
occassions by the state and private personnel Use of an HNU (102 ev
probe)- has not indicated significant vapor concentrations Significant
odors during dry weather or other hazards have not been noted
Sections of the landfill are currently active and adverse effects to
personnel have not been noted Level C - (tyveks rubber safety boots
organic vapor cartridges) is sufficient
Task 1 MagnetometerTopographic Survey - Level CD LPP will depend
upon the results of the Site Recon Significant vapor concentrations
or likelihood of particulates will necessitate an upgrade in the LPP
Otherwise Level D (work clothes safety boots boot wash) is sufficient
Task 2 Excavation and Sampling of Buried Drums - Level B The potenshy
tial for encountering significant concentrations of hazardous
materials during this task is moderately high Full Level B - (SCBA
chemical resistant tyveks hoods rubber safety boots rubber gloves)
will provide necessary respiratory and contactsplash protection
The use of the hooded yellow tyveck and the taping of ankleboots
wristsgloves and face maskhood junctions will provide complete conshy
tact protection
10
SECTION 3
FIRST AID FOR EXPOSURE
INHALATION OF VAPORSPARTICUIATES
Symptoms - eyenosethroat irritation nausea dizziness headache weakness fatigue lightheadedness drowsiness Loss of coordination confusion vomiting cramps (These sympshytoms are similar for most organic vapors particularly solvents)
Treatment Mild Exposure - Bring victim to fresh air Rinse eyes and throat if
irritated Heavy Exposure - (victim vomits very dizzy groggy faints etc)
Bring victim to fresh air Evacuate to hospital Prepare to administer CPR
Victim should be monitored for 48 hours in case of a delayed reaction
CONTACT EXPOSURE
Symptoms - Itching burning redness of skin Severe contact exposure for certain solvents will progress to CNS (central nervous system) symptoms similar to those for inhalation
Treatment - Remove contaminated clothing flush with water dry and banshydage Monitor victim for CNS symptoms for at least 48 hours
FIRST AIDSAFETY EQUIPMENT
The following equipment will be stationed at the Hotline or when appropriate down range
- Fully equipped first aid kit - Oxygen bottlekit - Nine (9) Ib chemical fire extinguisher - Eyewash bottle or other pressurized water filled container
11
SECTION 4
OPERATIONS SAFETY PLAN
This section outlines the specifics of safety procedures to be
used during each phase of the operations Safety procedures may be
upgraded or downgraded during site activities pending monitored changes
in the working environment All changes will be in line with the
General Level of Personnel Protection GuidelinesAction Levels for the
Troy Mills Landfill On-Site Investigation as described below
General Personnel Protection GuidelinesAction Levels
An in depth review of levels of personnel protection (LPP) is
presented in Appendix A
Level B (SCBA cotton coveralls or work clothes yellow tyveks (chemical resistant) steel toed rubber boots or work boots with disposhysible over boots and gloves)
Vapor concentrations (as measured on an OVA or HNU 117 EV Probe) greater than 5 ppm above background
- Oxygen deficient atmospheres less than 195
Specific actions (ie excavationsampling of drums) which could initiate a sudden moderate or high concentration of vapor
Level C (full face respirator organic vapor dust combo cartridge tyveks over work clothscoverails rubber safety boots gloves)
Vapor concentrations above an established clean zone backshyground level
During conditions (natural or personnel induced) which result in high levels of dust (visable above background atmospheric concentrations of particulates)
Level C activities require continual air monitoring
12
Level D (cotton coveralls or other work clothes safety shoes and safety glasses when down range Tyveks may also be needed)
Support areas and downrange areas where a higher LPP has not been deemed necessary
Continual air monitoring in downrange areas
Explosive Atmospheres
- 20 LEL (lower explosive limit) as recorded by an explosishymeter Secure and evacuate the work area
Oxygen Deficient Atmospheres
- Less than 195 (by volume) oxygen atmosphere requires upgrading the level of Personnel Protection to Level B
Task Specific Safety Plans
Levels of Personnel Protection indicated for specific tasks below are those which are anticipated to be used Changes in site conshyditions and results of air monitoring may indicate the upgrade downgrade of the LPP
13
Site Reconnaissance (SR) Date Sept 21 1983
Purpose To review on-site conditions and determine LPP necessary for further tasks To evaluate safety hazards Preliminary planning of future tasks
LPP - Initially Level C Updowngrade as necessary
Equipment - OVA HNU (102 ev probe)
Hotline - End of access road Upwind if possible
Command PostFirst Aid - Behind Hotline
Decontamination - Boot wash
Operations
Three man team Two persons advance in front with instrushyments Third person at distance as backup
Team methodically sweeps (criss cross) the proposed work areas with instruments
Specific points of interest (leachate seeps etc) are closely checked
All information is loggedsketch mapped
Upgraded LPP as necessary
14
Task 1 - Magnetic Survey Topographic Survey Date Week of October 3 1983
Purpose - Determine the location(s) and extent of buried drums Provide topographic information for site base map
LPP - Level CD
Hotline - End of access road (upwind if possible)
Decontamination - Boot wash
Operations - SO or other NAI personnel will perform a brief safety sweep of the work area
- Work team will then proceed downrange at the appropriate LPP Using the magnetometer the team will systematically criss cross -the work area
Task 2 - Drum Excavation and Sampling Date Week of November 14 1983
Purpose - Excavationsampling of buried drums in order to characterize the condition of the drums and the nature of the wastes conshytained in the drums and buried in the landfill
Msthod - Backhoe and hand labor will be used to uncover the drums in specified locations Samples will be obtained from spillage or leakage around the drums and of contaninated soil Selected drums which have accessible and openable bungs may be opened and sampled Drums will not be moved or staged Clean drums will be available to receive any significant spillage during the opening and sampling
Specific Hazards - Inhalation of organic vapors - Fire and explosion of drummed waste - Contact with contaminated waste or soil
LPP - Full Level B protection Backhoe operator at Level B Backshyhoe equipped with splash shield and without teeth on bucket
Hotline - At the end of the access road Upwind if possible
Decontamination - Procedures will essentially follow those as outlined by the EPA for Level B work Due to the inaccessibility of the site a field shower will not be available See Appendix B
Safety Equipment - OVA HNU eyewash fire extinguisher oxygen kit first aid kit metal detector non sparking implements
15
Operations - The cover soil is very sandy and the drums appear to be buried close to the surface which should facilitate excavation
- Minimum of 4 man team (exclusive of backhoe operator) Two or three man downrange team for digging and sampling One or two men in supportbackup at hotline
- Personnel will hand dig several small holes to approximately one (1) foot depth in each Location area If drums are not encountered the backhoe will scrape off soil to that depth
- Excavation will proceed alternating hand and backhoe methods At depths below four (4) feet the sides of the pit must be angled back to less than 45deg
- Prior to opening a closed drum the backhoe will nudgebump the drum to check for shock sensitive material An alternate method will be to attach a length of rope to the drum and from a distance pull on the rope to jog the drum
mdash Backhoe The backhoe operator will work at Level B utilizing air supplied from a large cylinder attached to the backhoe The backhoe will also be equipped with a splash shield A scraping bucket without teeth will be used
Prior to backhoe excavation at each location the area where the backhoe will be stationed will be checked for drums which could be ruptured by the backhoe feet
f Excavation areas will be checked for drums utilizing hand excavations or a metal detector prior to removing material by machine
16
SECTION 5
EMERGENCY INFORMATION
Emergency Telephone Numbers
If calling one of these numbers please state NAME LOCATION
and type of PROBLEM
Local Emergency Support
Fire Department (Troy 242-7759) For all emergencies use
Ambulance 352-1100 Mutual Aid (Keene) 352-1100
Police Department (Troy 242-7992)
Hospital 352-4111 (Cheshire Hospital in Keene)
Town Clerk 242-3845 State Agencies
NH Bureau of Hazardous Waste Management 271-4608
NH Water Supply and Pollution Control Commission 271-3503
NH Fire Marshall Office 271-3336
NH State Police (24-Hour Dispatch) 1-800-852-3411
Other
US EPA (24-Hour Hotline) 617-223-7265
Poison Center Mary Hitchcock Hospital 1-800-562-8236
Route to Hospital
- Follow dirt access road to Bowkerville Road - Left on Bowkerville Road to Rt 12 - Left (north) on Rt 12 through Troy to Keene NH - At major junction of Rts 9 10 101 and 12 go straight through
into Keene - At common go half-way around and go right on Court Street - Hospital is at 580 Court Street
17
Contingency Plan
Signal - five (5) one second blasts of auto or air horn Action - All personnel immediately excavate dovmrange areas and
report to Hotline for instructions
Personnel Unexplained Fire (if small) Accident (serious) Collapse of Personnel
Evacuate area Emergency ^ ^Evacuation Evacuate Area
First Aid
Estimate Explosion Level B (for Potential Contact Outside Help evcavation)
Evacuate Victim i If
Level B Prepare for Transportation
1 First AidCPR Use extinguisher Transport
Contact Outside Help Notify Coup any Have Proper Information Personnel (see below) 1
Transport
Call Fire Dept (if necessary)
For Hospital Victim
- Name and Phone of family physician
- Description of Incident chemicals involved symptoms nature of injury proposed treatment and plan of transportation
18
APPENDIX A
LEVELS OF PERSONNEL PROTECTION
Because of the possible dangers of exposure to toxic or harmshyful chemicals protective equipment must be worn during work on hazardous waste sites Levels of Personnel Protection (LPP) describe respiratory clothing and other equipment necessary for protecting personnel against expected hazards
The descriptions below are for full dress at a given LPP where hazards are expected to be at a maximum for which the given LPP is conshysidered adequate Depending on site conditions and work activities the clothing and dress requirements of a given LPP are commonly modified
LEVEL A
1 Personal Protection Equipment
Positive Pressure SCBA (MSHANIOSH approved) Operated in the positive pressure mode
Totally Encapsulating Suit (boots and gloves attached)
Gloves - Inner (tight fitting and chemical resistant)
- Boots - Chemical - protective steel toe and shank Depending on suit boot construction worn over suit boot
- Gloves shy Outer chemical-resistanttion worn over suit gloves May bchemical-resistant gloves worn insid
Dependinge replaced withe suit glo
on s
ves
uit construcshy tight-fitting
- Underwear shy Cotton long-John type
- Hard Hat (under suit)
- Disposable protective suitover encapsulating suit)
gloves and boots (Worn under or
- Coveralls (under suit)
- 2-way Radio Communications
Optional
19
2 Criteria for Use
A The type and concentration of toxic substances are known and require the highest level of combined protection to the respirashytory tract skin and eyes These conditions would be
1 Atmospheres which are immediately dangerous to life and health (IDLH)
a IDLHs can be found in the NIOSHOSHAs Pocket Guide to Chemical Hazards andor other references
2 Known atmospheres or potential situations that would effect the skin or eyes or could be absorbed into the body through these surfaces in toxic quantities
a Potential situations are those where vapors may be generated or splashing may occur through site activities
b Standard reference books should be consulted to obtain concentrations hazardous to skin eyes or mucous memshybranes
3 Oxygen deficient atmospheres with above conditions
3 At sites where the type andor potential concentration of toxic substances are unknown
1 Unless circumstances strongly indicate otherwise the site should be presumed to present hazards to the respiratory system skin and eyes Level A protection would provide the highest level of protection for the initial entry team
a Such circumstances might be
1 Environmental measurements contiguous to the site
2 Reliable accurate historical data
3 Open unconfined areas
4 Minimal probability of vapors presence or splashing with cutaneous effecting substances
2 Enclosed areas such as buildings railroad cars ships holds etc
20
LEVEL B
1 Personal Protective Equipment
Positive Pressure SCBA (MSHANIOSH approved) operated in the positive pressure mode
- Hooded chemical-resistant suit
Gloves - Outer chemical-protective
Gloves - Inner tight-fitting chemical-resistant
Boots - Outer (chemical-protective heavy rubber disposables)
Boots - Inner (chemical-protective steel toe and shank)
2-way Radio Communications
Hard Hat
Face Shield
2 Criteria for Use
A The type and concentration of hazardous substances are known and require the highest degree of respiratory protective but a lower level of skin protection
1 Atmospheres which are immediately dangerous to life and health (IDLH) Type and concentration of vapors in air do not present a hazard to the small unprotected areas of the body
2 Atmospheres with concentrations of known substances greater than protection factors associated with full-face air-purifying respirators with appropriate cartridges
3 Atmospheres with less than 195 oxygen
B When a determination is made that potential exposure to the body parts not protected by a fully encapsulated suit (primarily neck ears etc) is highly unlikely
1 Known absence of cutaneous or percutaneous hazards
2 Activities performed preclude splashing of individuals
C Level B protection is recommended as the lowest level of protecshytion for initial entries until the hazards have been further identified and defined by monitoring sampling and other reliable methods of analysis and personnel protection equipment commensurate with these findings utilized
21
LEVEL C
1 Personal Protective Equipment
Full-face or half-face air purifying respirator (MSHANIOSH approved)
Chemical-resistant clothing
Gloves - Outer (chemical-protective)
Gloves - Inner (tight-fitting chemical-resistant type (or woven liners)
Hard Hat (face shield optional)
Boots - Outer (chemical-protective heavy rubber throw aways)
Boots - Inner (chemical-protective steel toe and shank)
2-way radio comnunications
Safety glasses required with half-face respirator
2 Criteria for Use
A Site known to contain potentially hazardous materials exceeding
1 Air concentrations requiring a protection factor no greater than that afforded by a full-face mask
2 Harmful levels to unprotected body areas (face neck etc)
3 Well-documented reliable history of site and patterns of prior entry
C No evidence to suspect acute or chronic toxicity to exposed personnel
D Continuous air or personnel monitoring should occur while wearing Level C protection
22
LEVEL D
1 Person Protective Equipment
Chemical resistant aprons
BootsShoes - Safety or chemical-resistant steel toed boots
Boots - Outer (chemical-protective heavy rubber throw-away)
Half-face respirators immediately available
Safety glasses or safety goggles
Gloves
2 Criteria for Use
a No indication of airborne health hazards present
b No gross indications above background on the photoionizer andor organic vapor analyzer
c Continuous air or personnel monitoring should occur while wearing Level D protection
23
APPENDIX B
DECONTAMIHATION PROCEDURES
Depending upon activities and location on site it may be
necessary for personnel to decontaminate prior to leaving the conshy
taminated zone Procedures described below are typical for Level C
operations
Upon exiting downrange (contaminated) areas all personnel are
required to decontaminate by means of the following procedure
1 Place equipment in the Drop Zone at the Hotline
2 Enter the Decontamination Station
Boot Wash Walk through wash tub and scrub boots then rinse boots in second tube
Glove Wash In two pan wash scrub over gloves rinse set out to dry
2 Remove tyvek - if leaving the contamination reduction zone (CRZ) and proceed to clean zones
3 Dispose of heavily contaminated clothing and under gloves
4 Remove respirator
5 Use disposable gloves to clean equipment
6 Use a two bucket (washrinse) to decon respirators at the end of the working day or if they become heavily contami nated
The procedures for a typical Level B Decontamination are
outlined on the following page
TANK CHANGE 9
CONTAMINATION REDUCTION
ZONE
OUTER GLOVE REMOVAL
EXCLUSION ZONE
TAPE REMOVAL
BOOT COVER
GLOVE WASH
(bull)mdashQ-G--copyshySOOT COVEH SCOT COVES 4
REMOVAL GLOVE RINSE
SUITSAFETY BOOT WASH
SU1TSC8A78OOTGLOVE RINSE
SAFETY BOOT 10 REMOVAL
SCSA BACKPACK REMOVAL
SPLASH SUIT 12 REMOVAL
INNER GLOVE WASH
INNER GLOVE RINSE
FACE PIECE REMOVAL
INNER GLOVE 16 I REMOVAL
INNER CLOTHING REMOVAL
FIEUJ 19 REDRESS WASH
SEGREGATED EQUIPMENT
OROP
mdash -HOTLINE-shy
DECONTAMINATION LAYOUT LEVEL B PROTECTION
FIGURE A2-1
CONTAMINATION CONTROLLING
SUPPORT ZONE
25
APPENDIX C
PERSOHNEL AND RESPONSIBILITIES
Project Manager (PM)
Overall responsibility for all Project activates budget
schedule investigative operations safety personnel
On Site Coordinator (OSC)
Responsibility for activities at the site Primary responshy
sibilities include
1) Interfacing with the client state EPA media or other groups
2) Reviewing technical operations
3) Reviewing site safety in particular information supplied by the Site Safety Officer
4) Enforcing site safety and compliance with the Safety Plan
5) Directing Emergency Contingency operations
Safety Officer (SO)
Responsibility for directing the safety of operations and impleshy
menting the Safety Plan Specific responsibilities include
1 Assuring that appropriate personnel protective equipment is available and properly utilized by all site personnel
2 Assuring that personnel are aware of the provisions of this plan are instructed in the work practices necessary to ensure safety and in planned procedures for dealing with emergencies
3 Assuring that personnel are aware of the potential hazards associated with site operations
4 Supervising the monitoring of safety performance by all pershysonnel to ensure that required work practices are employed
26
APPENDIX D
PERSOHHEL CASUALTY
Personnel casualty would most likely result from either chemical
contamination heat-related problems physical injury from accidents
(ie falling lacerations etc) in performing the work or a comshy
bination of one or more of the above The appropriate action depends on
the type of injury involved with the priority being to assist the
casualty as soon as possible without endangering other personnel
Riysical and heat-related injuries can and should be treated
immediately with appropriate first-aid measures and follow-up medical
attention if necessary The injured worker(s) shall immediately move
out of the hot zone or if necessary be moved out by fellow workers as
soon as possible The OSC and Safety Officer shall be notified immeshy
diately and shall recommend further measures as needed
Chemical-related injuries require a much more cautious approach
so as to keep casualties to a minimum If a worker injured by chemical
ejqgtosure is able he shall notify the nearest co-worker and leave the hot
zone immediately- The co-worker shall ensure that the OSC and Safety
Officer are immediately informed and shall accompany the casualty from
the hot zone to the decontamination zone The OSC and Safety Officer
shall determine the appropriate measure
27
APPENDIX E
GUIDELINES FOR SITE OPERATIONS
In order to deal with the potential dangers of exposure and conshy
tamination of a hazardous waste site three zones are delineated
according to the degree of hazard The three zones are 1) Downrange
or Contamination Zone 2 Contamination Reduction Zone (CRZ) 3) Support
or Clean Zone
Downrange or Contamination Zone
The Contamination Zone is the active work area of the site which
encortpasses the areas where there is a potential for exposure and in
which investigative activities will occur (drilling sampling etc)
Within the Contamination Zone the designated level of hazard will be
established necessitating the utilization of personnel protective
equipment
Hot spots are those areas Downrange where observations instrushy
ment readings or specific activities indicate a high probability of
closure or contamination and may require an upgrade in the LPP in the
vicinity of the Hot Spot
Contamination Reduction Zone
The CRZ is an area between the Downrange and Support Zones where
decontamination of equipment and personnel occurs
28
Personnel entering the CRZ shall wear protective clothing and
carry the respiratory protection required for entry within the
Contamination Zone
Personnel working within the CRZ shall remain cognizant of the
CRZ in order to be prepared for any need to increase their level of proshy
tection within the CRZ
A decontamination station will be located at the outer perimeter
of the CRZ All personnel who have been within the Hot lane shall pass
through a decontamination procedure prior to re-entering the Support
Zone
Support or Clean Zone
The Support Zone is the outer area and may be considered to be
clear of contamination potential The command post will be located
within the Support Zone
a) The Command Post will serve as the OSCs headquarters and
will be equipped with
1 Communications
2 Safety Plans
3 First Aid Supplies
4 Analytical Equipment
5 Safety Equipment
APPENDIX B
WORK PLAN
WORK PLAN FOR
TROY MILLS LANDFILL TROY NEW HAMPSHIRE
DRUM EXCAVATION AND SAMPLING
Prepared by
NORHANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
1933
WORX PLAN FOR
TKOt MILLS LANDFILL TROT NEW HAMPSHIRE
DRUM EXCAVATION AHD SAMPLING
DATS November 16-18 1983
PURPOSE
To determine the condition of drums (ie erroty or full
crushed rusted leaking etc) buried in the Troy Mills Landfill To
obtain representative samples toward identifying the types of materials
buried in the landfill This information will be used in the detershy
mination of the level of remedial action needed at the site
METHOD
Using the results of the magnetometer survey the (10) points
have been randomly chosen across the area where the buried drans are
expected to be found Each point is central to an Excavation Location
-- an area four (4) to six (6) feet in diameter which will be excavated
in order to characterize the condition of the drams and to obtain waste
sarples
Preliminary observations have indicated that many of the drums
may be buried within 1-2 feet of the surface Therefore the investigashy
tion will proceed in two phases
Phase 1 mdash Hand Excavation By digging several small holes in
each Location personnel will determine if drums are located within
about one to two feet of the surface If drums are encountered the
excavation will proceed by hand uncovering the dnris for evaluation and
sampling Where drums are not encountered near the surface excavation
at this location will be postponed until Phase 2
Phase 2 mdash HandBackhoe Excavation After all Locations have
been attempted during Phase 1 those Locations in which drums were not
encountered wall be further excavated using a combination of hand
backhoe digging
It is expected that one to two days will be necessary to
cor^piete each phase Depending upon the results of Phase 1 it may not
be necessary to iroleraent Phase 2
Spare drums will be on hand for containerizing any significant
spillage resulting from sampling efforts Excavation locations will be
identified with marked stakes and the holes will be backfilled at the
conclusion of the investigation
SPECIFICS
Excavation Locations (Holes)
Number of proposed excavations is ten (10)
Locations of excavations are presented in Appendix A
Hole Size mdash It is expected that a hole from four (4) feet to six (6) feet in diameter at the bottom (depth at which drums are encountered) will be sufficient to characterize the drums at each Location Deeper excavations will require increasingly large top diameters
Hole Depth -- Holes will be excavated to a maximum depth of six (6) feet Due to the sandy cover material the excavation of deeper holes is probably impractical from both safety and efficiency stand points
If after attempting excavation at each of t-ie 10 proposed
1ocatiors irums are not encountered within six (6) fet of the surf ice
in enough locations to characterize the site excavations nay be
attempted to depths greater than six (6) feet if scil stability permits
or a new set of sampling locations may be chosen
(Excavations to depths greater than six (6) feet require a
significant increase in work The sides of the hole crust be graded back
to less than 45deg in order to insure the safety of investigatorysampling
personnel It may also be necessary to employ bracing bulkheads etc
for trench support)
Excavation Identification
Proposed excavation Locations have been consecutively numbered
from 1 to 10 beginning at the east end of the landfill They will be
marked with numbered stakes
Excavation Methods
Phase 1 mdash Within each Location personnel will dig a nunber of
small holes - about one (1) foot in depth - to probe for drums If
druns are encountered they will continue to excavate until the drur3
are sufficiently uncovered for characterization
Phase 2 mdash After hand probing the Location with snail holes
the backhoe will remove cover material to the one (1) foot depth The
Location will then be probed to a two (2) foot depth before removing
further material Excavation will proceed alternating handprobing and
backhoe excavation until drums are encountered or the maximum six (6)
foot depth is reached
If excavations to depths greater than six (6) feet are undershy
taken they will proceed using the above method
Santnlea
Due to the effort involved in excavating and because conshycentrated waste samples are not expected to undergo rapid degradation it is considered expedient to obtain all readily available samples (exclusive of closed drum samples -- see belcw) These can then be submitted for laboratory characterization as determined by need and budget restrictions
An attempt will be trade to secure at least one sample froa each excavation in order to help characterize the distrishybution of waste materials across the site An attempt will also be made to secure samples of observably difshyferent materials
Sample Types and Mediums - Solid liquid and sludge samples are possible Samples will be obtained from in order of preference -- 1) leakage uncontainerized waste or contaminated soil 2) waste contained in open conshytainers - drum already has a hole or no top or other access point 3) sealed containers
The opening of closed containers will be considered if it is decided that it has not been possible to obtain a sufshyficient number of representative samples from the other mediums
Each sample will consist of two (2) 8-oz jars (with teflon-lids) filled about 23 full One jar will be for organic analysis and the other for inorganic analysis
Sanole Identification - Samples will be identified with a number corresponding to the Excavation Location and a letter Example if three samples were obtained from Location 2 they would be samples 2A 23 and 2C and Samples 2Ad 23d and 2Cd for duplicates
Sampling Methods and Volumes - 11 mm hollow glass tubing trowels disposable scoops will be available to obtain samples Samples tools will be disposed of or deconshytaminated between each sample
Drum Samples - If necessary an attempt will be cude to obtain samples from sealed drums Oily o^und non-rusted drums will be considered Bunjs rust be xn suitable conshydition -jo that the dram cm be openoi withrut cvis ing dainai -ind ca-i be resell od to pr-jvcrt l V-i 30
There wil l be no staging or movement of drums in order to faci l i tate sampling Only drums with accessible bungs will be considered for sampling
Procedure for Drum Sampling
1) Excavate around top of drum
2) Monitor air in the adjacent area
3) Chec for shock sensitive - Loop rope around top of drum stand at a distance give drum several hard jogs by pulling on the rope An alternative nethod is to lightly jog the drum with the backhoe bucket
4) If the drum is not upright place a catch basin under the bung
5) Open drum with bung wrench
6) Monitor the air atin bung
7) Sample drum -- liquids insert glass tube the fu l l length into the drum in order to obtain a column of the materials in the drum Solids use scoop to dig out material through the bung or use a sampling trowel
3) Reseal the dram
Spill Control
The possibility exists during the sampling and excavation for a
drum to be ruptured or otherwise have spillage Clean drums wil l be on
hand to receive significant spillage resulting frora sampling or excavashy
tion They will not be used for clean up of widespread uncontainerized
waste or existing leakage
Personnel
The work team will require four (4) persons (exclusive of the
backhoe opera tor) Trie downrange team will consist of three (3) persons
-- two (2) for d igg ing and sampl ing and on ( 1 ) for logging air moni shy
toring and photographing One (1) person will be at the hotline in
support mdash as safety backup person to fill air bottles to deconshy
taminate samoles to assist in decontamination of personnel
Documentation Logging
The following information will be recorded at each location
nmber of drums uncovered and the condition (crushed empty rusted
sealed etc) of each drum evidence of spillage or contaminated soil
labels on uncovered drums samples (time drum ID type description)
periodic air monitoring information depth at which specific events
occur or drums are buried soil condition presence of ground water
In addition photographs will be taken of specific events or
items of importance during each excavation and of each sampling incishy
dent The time description of subject photographer excavation
location and photo number will be logged for each photograph
Analytical Laboratories and Schedule
RAI Hampton NH
Initial schedule
Ten samples for GCrns for organic priority pollutants Samples may also be submitted for inorganic anlaysis or volatile organic analysis depending upon waste materials observed during the excavation
APPENDIX A
TABLE A-1 EXCAVATION LOCATIONS
EXCAVATION BASELINE RANDOM RANDOM
NUMBER GRID COORD SEGMENT STATIOH OFFSET
1 7E+1 565N 0- 60 26 (25) 16
2 9E+5 13S 60-120 50 (110) 9
3 8E+0 31S 120-180 20 (140) 7
4 4E+5 483 180-240 50 (230) 25
5 3E+3 45S 240-300 14 (254) 20
6 OE+6 5S 300-360 34 ( 334) 50
7 2W1 5 24N 360-420 45 (-155) 14
8 5W+6 42N 420-480 38 (518) 20
9 6W+1474N 480-540 8 (543) 7
10 8W 5 11011 540-600 11 (611) 31
Locations are plotted on Map A-1
Method of Choice A stratified random sampling method was used to choose 10 Excavation Locations within the magnetic anomaly
The axis of the magnetic anomaly was used as a base line and divided into ten 60 foot long segments Using a randora nirnbers table a distance along each secpent was chosen (Random Station) and a line drawn at that point perpendicular to the base line Again using a random numbers table a distance was located along each perpendicular line by measuring inward from the line denoting the edge of Area A (Random Offset) The Grid Coordinates for each of the Excavation Locations were graphically determined from the grid overlay (this overlay has been surveyed and intersections field located)
It was judged that 10 excavation locations within the magnetic zone and two outside of the zone would be sufficient to characterize the area would produce statistically valid iati and coli be expected to be co~letod within 2-3 days work period
to
80
cu0
cgtc
APPENDIX C
MAGNETIC INVESTIGATION TROY MILLS INC LANDFILL SITE
TROY NEW HAMPSHIRE
For
NORMANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
By
JOHN F KICK PhD GEOPHYSICIST
Box 6 Dunstable Massachusetts 01827
(617) 649-6650
Noverber 19S3
MAGNETIC INVESTIGATION
TROY MILLS INC LANDFILL SITE
TROY NEK HAMPSHIRE
INTRODUCTION
A high resolution ragnetic investigation was completed on the Troy
Mills Inc landfill site in Troy New Hampshire by John F Kick
Consulting Geophysicist The purpose of the investigation was to
delineate the extent of buried steel drums under closed portions of the
Troy Mills landfill The information is needed as a part of a study of
the landfill that is being conducted by Normandeau Associates Inc
FIELDKORK
Magnetometer measurements of total field intensity were made over an
area that was reported to contain buried steel drums and adjacent
landfilled areas that contained unknown waste materials The area of
investigation included capped and grassed closed areas along the south
margin of the landfill site and adjacent areas The fieldwork was
performed during October of 1983
Eighteen parallel rows of measurements were conducted along north-
south lines (using magnetic compass directions) A spacing of 20-feet
was used between rows and magnetometer measurements were made at 10-foot
intervals along the rows Greater intervals between measurements were
used at the ends of the rows and in periferal areas with low magnetic
-JF Kick 01shy
field gradients
A series of magnetic field measurements were made at an adjacent
base station throughout the survey to torn the basis for a daily
variation curve The base station was located at a site with typical low-
gradient background magnetic field intensity measurements
MAGNETIC SEARCH METHOD
Theory Magnetic search methods involve the detection and
measurement of anomalies in the Earths magnetic field caused by the
presence of materials with contrasting magnetic susceptibility Iron and
steel objects generally have very high magnetic susceptibility contrasts
with usual surrounding materials and therefore produce magnetic
anomalies The amplitude shape and detectable distance of the anomaly
depend mostly on the particular susceptibility contrast and size of the
object Magnetic anomalies are measured in units called gammas The
normal magnetic field in this area is over 50000 gammas A 5-inch
screwdriver will produce an anomaly of 5 to 10 gammas at a depth of 5
feet and an anomaly of 1 gamma at a depth of 10 feet A 1 ton automobile
will produce an anomaly of 40 gammas at a depth of 30 feet and an anomaly
of 1 gamma at a depth of 100 feet The magnitude of an anomaly caused by
a single steel drum will vary with its condition (new heavily rusted
etc) Tests using a single light weight (somewhat rusted) drum on the
surface with the magnetic detector at a height of of 12 feet produced an
anomaly in the range of 40 to 50 gammas
Total magnetic intensity disturbances or anomalies are almost always
asymmetrical sometimes appear complex even from simple sources and
usually exhibit the combined magnetic effects of several sources which
can produce a given anomaly The apparent complexity of such anomalies
is a result of several relatively simple functions of magnetic dipole
-JF Kick 02shy
behavior Reasonable assumptions about the geology and buried source
conbined with an understanding of magnetic dipole behavior can usually
lead to a satisfactory qualitative interpretation More detailed
interpretations nay require modeling studies
Instrumentation Field equipment on this project included a EGampG
Geometries Memory-Mag G-856 proton precession magnetmeter The
instrument has a resolution of +01 gamma The magnetic field detector
is separate from the rest of the instrument and is mounted on an 8-foot
staff to provide measurements that are a constant height above land
surface
Magnetic Data Analysis For the purposes of data reduction and
anomaly delineation it was assumed that base station total field
intensity measurements were typical background values for the site
Measurements made at frequent intervals at the base station were used to
prepare a diurnal variation curve for the site Anoraly values were
obtained by subtracting background values from the base station curve
from measurements collected in the area of investigation
RESULTS
The reduced results are presented in the form of a magnetic anomaly
contour map (Figure 1) and two profiles across the area of investigation
(Figures 2 and 3) The map and profiles show that very steep magnetic
field gradients and large departures form background occur in an
irregular shaped band that is about 460 feet long and ranges from about
30 to about 200 feet in width The magnitude of the anomaly is such that
a significant deposit of ferromagnetic materials (such as steel drums) is
indicated
In using the plotted magnetic results it should be noted that the
greatest concentrations of ferromagnetic materials probably do not
-JF Kick 03shy
directly underlie the peak magnetic anomalies A shift is caused by the
inclination of the Earths magnetic field and by the dipolar nature of
ferromagnetic deposits The inclination of the Earths field is about 76shy
degrees northward in the vicinity of Troy The dipolar effect is induced
by the Earths field and results in negative anomalies immediately north
of large positive anomalies
Magnetic Anomaly Map The magnetic anomaly map (Figure 1) indicates
10 positive peaks of varying size shape and intensity Associated
negative anomalies of a broader and less intense nature lie immediately
north of the belt of positive anomalies The configuration of the
anomalous area is indicative of lense-shaped and cigar-shaped bodies of
ferromagnetic materials Steep-sloped anomalies are indicative of very
shallow source materials The thickness of the ferromagnetic deposit
cannot be easily determined on the basis of intensity and size of
anomalous peaks because a small mass of iron or steel at the surface can
duplicate the anomaly caused by a much larger mass at depth The
ferromagnetic source materials can generally be expected to lie north of
the positive peak of anomalies and south of the adjacent negative
anomaly Modeling can provide the best approximations of the depth and
density of the ferromagnetic source materials The outer boundaries of
the source materials can be expected to overlap the positive peak and
negative anomaly somewhat depending on the depth and configuration of
the deposit
For illustration purposes two north-south rows that were profiled
are discussed below
Magnetic Anomaly Along Row 9-East Two strong positive magnetic
anomalies (3645 and 2436 gammas) and adjacent negative anomalies were
profiled along Row 9-East (Figure 2) The approximate centers of the
ferromagnetic deposits are believed to underlie stations 50 north and 75
feet south of the base line The rounded shape of the north positive
-JF Kick
anoraly nay indicate somewhat deeper burial of the ferromagnetic deposit
Magnetic Anomaly Alone Row 7-West Figure 3 shows the most intense
positive magnetic anomaly (4470 gammas) that was detected on this
project The steepeness of the slopes is indicative of very shallow
source materials An uneven burial pattern is suggested by the two-
peaked positive anoraly The negative anomaly south of the two peaks is
unusual and may be related to another positive anomaly to the southeast
(along Rows 5 and 6 20 feet north of the base line) The centers of the
sources of the positive anomalies are probably approximately 80 and 120
feet north of the base line along Row 7-West
-JF Kick 05shy
DISTANCE FROM BASE LINE(FEET)
CO
_J
6a
CO
LU CD
o cr CD o lt
i-mdash LU Lu 2 Q lt2 Z
lt ltr
CsJ
LU aIDCD Li_
SVWWV9 N A1VWONV
s
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0 O
0 O o
SVWWV9 NI A1VWONV
t o H
X
D 8 j~ 00
UJ UJ en UJ u UJ
o ui o CC
CO
s o
S u
UI o
O Cgt mdash o
0020
UJ U
o o CJ
ro 8 LU
CC ID egt LL
APPENDIX D
LABORATORY ANALYSES
RAI
Resource Analysts Incorporated Box 4778 Hampton H 03842
(603) 92^7777
TO PO 830318
Mr Doug DeNatale Date Received 12-2-83 Kormandeau Associates 25 Nashua Road Lab Number 2887 Bedford NH 03102 J
Date Reported 1-3-84
IDENTIFICATION
SAMPLE DESIGNATION PARAMETER
Volatile Organics Analyses by EPA Method 624
Acid and BaseNeutral Extractable Compounds Analyzed by EPA Method 625
Metals Analyzed by Standard Methods 303A
Please see attachments for all results
Results expressed in mgL unless otherwise designated lt = Less Than
ClarkeFosterVan K o u w e i b r h 1 ANALYST DIRECTOR
METHODS Standard Methods (or the Examination ol Water and Waitewaler 15th Edition or other EPA approved mtlhodologiei unless otherwise designated
Phys ica l descr ip t ion of sample
LiquidSludop
Saiple workup
Volitile f ract ion Methannl F-1-rarMrm CSVJ Rdfi-Smm
Semivolatile f ra ictio0onication Extraction fSW 846-3540^ Inorganic f rac t on Acid Digestion (SW 84h-iOS(V)
ACS3 COMPOUNDS
rr t CAS CAS
(71 A) tt-Ot-2 i^t TT i^MoroprvrfgtOi (73B) 30-32-1
(23 A) J9-JO-7 ^bull^^ lof o^^ft^crt gto (7 OB) 205-M-2
(2 A) 13-37 -J 2- chlorophenol (75B) 207-01-
(3 A) 120-13-2 2raquo^icMoroorgtenol (748) 211-01-9
(MA) 103-47-9 2-dimethv lohenol (77 B) 201-94-1
(37A) U-73-3 2- niiroDhenol (7IB) 120-12-7
(MA) 100-02-7 raquo-niiroprienol (7raquoB) lraquol-2raquo-2
(raquoA) Jl-21-3 2 - in i tr opheno 1 (106) raquoi-73-7
(40 A) 33-J7-l k4-dinnro-2-mlaquothylplaquogtergtol (I IB) 15-01-1
(4A) I7-U-3 (xntictiloroorraquonol (I2B) J3-70-3
USA) 101-93-2 pxmol (I3B) 193-39-J
(14 B) 179-00-0 RASENEUTOAL COMPOUNDS
( I B ) 13-32- raquocmlaquophtgtgtefgtlaquo
(36) 92-173 benzidine (2V) 107-02-S
( I B ) I20-I2-I l2t-tricMorobenzlaquonlt (3V) 10713-1
OB) 111-71-1 he laquo laquoch 1 or o benz erve (laquoV) 71-A3-2
(176) 47-72-1 hetraquocWoroltthlaquone (4V) X-23-5
U S B ) 111-- bu(7-cloroetrivl)ether (7V) 101- 90-7
(7CB) 9 I -3J -7 2-Chlororuprthraquolene (10V) 107-04-2
(73B) 95-50-1 l2-diCMoroblaquonzene ( I 1 V ) 7|3j^
( K B ) XI-73-1 13-didilorobtnzene (13V) 7J-3-3
(27B) 104-M7 1tmdash djcMorobenzene dkV) 79-00-3
C2IS) 9i9i-l 33-dictgtloroblaquoazidinr ( I JV) laquo-3-J
(33B) 12I -U-7 2gt-dinicrotoluer (14V) 7J-00-3 (KB) 4O4-7C-7 24-dinitrotoluene (UV) 110-73-1 (J7B) 122-A4-7 1J -diprienv lhydrraquo z irf (23V) lt7 tt 3
(MB) Z0-fc-0 UuorraquonThelaquo (2raquoV) 7J-35-
(W551 700J77-3 -ctilorophenyl prlaquonyl ether (JOV) 1M-40-3
( raquo I 6 ) 10I-J3-3 raquo-6romoprgtefgtyl prtenyl ether (32V) 71-17-3
(raquo7B) 33132-9 bU (2-cMorobopropyl) ether (33V) 10041-02-4
(raquoJ6) i l l -91- l bu (2-laquo^loroeTho)ry) methane 10041-01-03
(B) D-U) hexraquopoundj1|orobutaltlicne (31 V) 100--
(33B) 77-raquo7- heiKCtilorocycIopentadicrve (WV) 7J-CT-2
OB) 7IJraquo-I traquoo oh or or (raquo3V) 7raquo-17-3
(J3B) gtl-20-3 nphthraquolene (UV) 7raquo-I3-9
(546) n-tj) nitrobenzene (7V) 7J-2J-7
(426) U-Xl-4 bullJ -n itr o tod iphenyU mi ne (UV) 75-27-J
(OR) 421-W-7 N-oitrcnodipropYlirrUne ^raquoraquoV) 73-49-k
(446) I 1 7 J I - 7 bu (2-eltr^lheryl) phtfaUte 8200 (3ov) 73-71-1
(476) 13-U7 benzyl buryl phttwlite (51V) 124-kt-l
( U B I M-71-2 di-fl-utgtl pMhUre (13V) 177-II-
( lraquo6) 117-1 -0 dj-n-octvl prithlaquoUte (UV) 101-IS-3
(7CB) W-44-2 dielhvlphtraquollaquo (17V) 79-OI-t
( 7 | B ) I 3 I - I I - J dj^laquorTvipnthraquoUtr (UV) 7J-OI- (776) H-J5-5 bnro(raquogtnthrraquocefvr
Iab I D N o 2SS-10
C l ien t ID 1A64223
RASENEUTRAL COMPOUNDS
bfzoltraquogtprrene
benzoltb)flucrraquornNene
benio(llaquo)fluorraquonthene
chryiene
bullcenaDhthvien
raquontnrraquoctne
benzoltghi)perrlefgte
Iluorene
phergtraquonthrmlaquo
dibenzoltraquoMaithrraquocenraquo
indeno(123-cd)pvrene
prrene
VOLATHES
(frolein
bullcrvlooitrdf
benien
orbon Temchloide
CMorobeniene
1 7-dJchlorolaquothnr
111-trieftloroethine
ll-ltJichloroetrufle ll7-triCilorigtetMrlaquor
l127-tetrraquocMorothfllaquo
chloroethlaquo-e
7-dMoroeThraquo|virgtvl eirwshy
chloroform
11-didMoro^tfwnr
trinj- 1 2-dictMorolaquoirgtene
1 7-ltlicMoroproplaquorve
trini- 1 3-ltJichloroorcrpeoe
cu-lJ-lieMorocT oo eashy
rthy Uveniene
methrlene chloridf
chloromethine
bromome thraquone
bro mod iCTi lore met Mrgt
(Juorotr ichloromthraquor
di cMlor od 1 f 1 uore ngtet hj^gt
chloreltJbnjmomethne
te tr ten 1 or oet rx-r
laquouene 12000
tncMeroethe^e
Cidrr ium Chromiutr 10
All results are expressed as ucg veicht as received Nc ertrv denotes -0r ~ ^ 1 i rt
P h y s i c a l d e s c r i p t i o n of
SoilSludge
sample
Sanple workup
Vol i t i le f ract ion p^r Exf- rar r ion fST7Semivola t i le f rac t ion So^h^Pt Fgtr f ra r f ion
846-SOTO^ (SWRdfi-^SiO1)
Inorganic fract ion Ar id nio-psrirm
AOD COMPOUNDS
m CAS (2i A) tt-04-2 2raquot- Wichlorophenol
(22 A) J1-50-7 p-cfi I or o-n-cre laquoo 1
(2A) 13-57-1 2- ctiloroprienol
O iA) 120-13-2 2raquo^icMoroprnol
(gtraquoA) 103-47-1 2f 4mdash^imetSv Ip^enol
(37 A) U-73-3 7mdash Ti j oprtenol
(JraquoA) 100-07-7 mdash mdasho i Br opr^e no 1
JJ1A) 31-21-3 if mdash4 irtiTroprienol
(40A) J34-32-1 4 T4-4initrogtmdash 7 nte tny Ipnenol
(4A) f y _H 5 plaquontchlaroorwnol
(43A) J 01-95-7 prienol
rV ipoundNEUTRAlaquo- COMPOUNDS
( I B ) raquoJ-32-raquo
(3B) 17-17-5
( IB) 170-12-1
(IB) 1I1-7I-I
(17B) 4777-1
( I t B ) 111--
(20B) 11-31-7
(236) 15-50-1
(245) 51-73-1
(77B) 104-4-7
(285) 11-14-1
(336) 121-142
(34B) 404-70-2
(J7B) 127-M7
O1B) 2O4--0
(406) 7003-72-3
(416) 101-35-3 lt raquo 2 6 gt 3H3I32-1 ltraquo36) 111-11-1 (57B) S7-U-3
(336) 77 -raquo7-
(36) 71-31-1
(33B) 11-20-3
pound34 6 1 n-i33 (UB) tt-30-4
(436) CI-44-7
(4461 117-11-7
(47B) U-417
( U B I 14-747
(U6) I17_t-0
(7CS) l-laquo2
(7 I B ) t J U t l - gt
(7761 54-55-3
CT-~- i_i w i Miirn 0
resul ts
b^TMdint
1 2 t-o- icn lorobenl ergtlaquo
SeTraquochloroblaquorierraquoe
hrxchlorolaquotSlaquone
bu(2-chloroethv|gtether
2 -lt3M or onraquo ph ti1 ene
1 2-ltJictilorotgtmzcne
13-dicWorotxerzene
1 4-djch 1 or otxn z ergte
33-ditfgtlorolgtlaquoniidirraquo
24-dinitrotoloene
2 4-dtnitro toluene
U-dlpoenylfiydrraquoiilaquo
(luoranthene
raquo-cfJorophenyl poenyl ether
Mx-omopfieflyl phenyl ether
bis (2-cMorooopropyt) ether
bu (2-ctilorcxtSorv) meiSkte
hezkOilorobutadicne
hei acM or ocyc1 ofMn udi cne
oo prior one
nphthlene
nurotxniene N -ni tro Kxd ipoenyU mi ne
N-rutrowxhpropYUmJrw
bu (2-thylherl)(gthlaquoiraquoUtraquo
blaquoniyl buryl phtfraquolaquoUte
dt-^t-^xjrvl pfttfuiLitY
dj-n-octyl pitflaquoLitraquo
dirthvl phtruUtt
OArriett^vt prraquoT^Lraquot
bnzoltklaquonihnicer
22 Chronium
ire ev^rescei as uc ^ ^i-~ht-
Lab 1U N o 28B-1
C l i en t I D 1 R R 7 A A R
RASpoundNEbTRAL COMPOUNDS
benroltb)fluorraquorgtthfflf
benzoraquollt)fluor intone
ltrylaquo-gte
bullcenioithylen
raquomtirraquoenlaquo
ben z oltxh i)per v lene
lloorene
poentnthrrne
dibnzo(4h)laquonthricrne
mdeno(I23-rt)pvre-ie
pyrene
VOLATU-Ei
bullcrelem
bullcrvlonio-Ue
benzene
caj-bon traquotrraquochloraquo-idr
Ctilorobernene
l2-diehlongtethne
iii-tnctltiorotKraquor Trace 1 T 1 -4)Ctilorampe^hArw
l f 1 ^-tric^i lor oefvtrve
l t l 22-teTrtclloroetl^Ane
ehloroethraquone
2-chloroltthr|viw| ttrve-
Chloroform
1 1 -ltSicMorot^nr
trinraquo-l2-dictiloroetrne
12-d^loropOStn
trinil3^ichloroproone
eis-lJ-diChloroprooene
rrhylberuene Tarce methrlene ehlor tat Trace
Ct1 or o m e t Kirgte
bromometKtrte
bro mod i rfi lor o rrgte t Mne
Uuorotrlchloromethraquo^e
OJ CJ lor od 1 f 1 uoro met hraquone
chJorodibromometKATgte
laquotrlaquociloroethrrx
toluene 9
tricolor otheir
fsw
T9
Sifi-TOSO)
(73B)
(7IB)
(75B)
(7(B)
(77 B)
(71 B)
(71B)
(SOB)
( t lB)
(I2B)
U3B)
(M B)
(7V)
(3V)
(4V)
(4V)
(7V)
(10V)
(11V)
(13V)
(14V)
(13V)
(14V)
(11V)
(23V)
(21V)
(30V)
(32V)
(33V)
(34V)
ltlaquoV)
( raquo J V )
(44 V)
f raquo 7 V )
(UV)
(V)
000 (30V)
Tlfl 151V)
(15V)
^00 (14V)
(17V)
(UVgt
-1 ZINT
CAS 30-32-J
205-11-7
207-01-1
211-01-1
201-14-1
120-12-7
111-24-2
14-73-7
13-01 -laquo
33-70-3
113-31-5
121-00-0
107-07-t
107-13-1
71-43-7
34-23-3
101-W-7
107-04-7
71-35-t
75-3-3
7^-00-5
71-34-5
75-00-3
110-73-1
(7-14-3
73-35-4
154-40-5
71-17-5
10041-07-6
10041-01-05
100-4I-
73-OT-2
74-17-3
74-13-1
73-25-2
75-27-4
73-41-4
75-71-1
174-41-1
127-U- IOUIS-) 71-01- 75-OI-
130
Lab ID Mo 2887-4
Phys i ca l d e s c r i p t i o n of sample C l i en t ID 4A5760
Liquid Sample was predominantlv a hvrlrnrarhnn bl pnd
Sanple workup Voli t i le f ract ion PEG Extraction (SW 846-5030) Scrnivola t ile f rac t ion Sonication Extraction (SW 846-3550) Inorganic f rac t ion Acid Digestion (SW 846-3050)
AC3D CS3U POUNDS 5AipoundNEUTlUgtJ- COMPOUNDS
ri CAS PPraquo CASf
(210 U-04-2 2raquot- tricMorophrnol (7)6) raquo-32-l braquoniolttVyre
[EM 51-50-7 ^-cti 1 or raquo-m-lt rlaquo laquoo 1 (7raquoB) 203-M-2 biMo(b)(luorinth^f
2 A) raquo5-57-J 2- cfiloropheryjl (7 3 B) 20701 benro(ilt) floor in tlaquo^e
(31 A) 120J3-2 2raquo-ltJicWoro(ygtlaquotx)l (74B) 2II-OI- chryve^e
(MA) 105-47- 2l-dimlaquothvloSrrgtol (77 B) 20Uraquot-J bullcwrioMhylene
(57A) u-73-3 2- ruTroohrgtol (TIB) 120-12-7 raquontnncergte
(34 A) 100-02-7 -oitrophenol (7gtB) lraquol-2raquo-2 benio(ghi)cgtrrylngtlaquo
(3Agt 51- 21-3 2 -4 initropherwl (SOB) tt-73-7 fluorme
(tOA) 53-37-l t-dinitro-2-mlaquothy lpNlaquoxil (II B) 15-01-4 pheAinthrrnlaquo
(A) I7-U-5 tgtentraquochlQroiywnol (I2B) 53-70-3 dibenplusmnoltraquoh)fcnthrraquocrne UJJ 101-55-2 rfwtwl (I3B) lraquo3-3raquo-3 indenol 1 23-cd)vrtie
(UB) I2raquo^X3-0 pyrer BASENEUTOAL COMPOUNDS
VOLATO-ES (161 I3-32- raquoclaquonraquophttgtngtf
(5B) 12-17 -J btniidir (2V) gt 07 -07-1 bullcrolem
(IB) 120-17-1 l^^iricfvleroboMux (3V) 107-13-1 bullcrvlonit Jlaquo (raquoBI IIS-7t| SeraquoChlorotgtlaquoterlaquo (raquoV) 7IJ3-7 benient
(I7S) 4772-1 heLCMorolaquothinc (tV) J-23-5 crtgton wtrraquocMoidf (UB) I11-U-I bll(2lttllorolaquot^w gtetNer (7V) 101-W-7 ltAtoroxniergtlaquo
(203) Jl-31-7 2 -etvl or onlaquo ph traquo I en e (IOV) 107-04-2 1 2-ltlicMorolaquoTKlaquone
(25B) raquo5-30-l 1 2-dichlorobenzene ( 1 1 V ) 71-JJ-t llI-trichlorolaquotNlaquoe (2 B) 31-73-1 l3-ltlichoroblaquonzenlaquo (13V) 7J-3A-) 1 1-6 1 cM or Of t (Mr
(77B) I04-M7 I -di CM oro ben z eoe ( I k V ) rraquo-oo-j l12-niichlorolaquotfvirraquolaquo
(2IB) raquol-raquo-l )J-dichlcroblaquorLiidinr (IJV) rgt-3laquo-3 J122-tetrraquochlcrolaquoTrie
(33B) 12I-Ilaquo 2 2-dinia-otoluer (UV) 73-00-3 Ctgtloroltthne U4B) laquoJ-70-7 2 t-dtnitrotoluene (1raquoV) HO-73-1 2-ltJilorocthv|vL-v| etrveshy
(J7B) 127-M7 14-dip^wnylhydraiine (23V) C7-U^-3 Ctilorofcrm
(JraquoBJ 2Ot-ugt-0 CJuarlLnthefe (2raquoV) 7J-33- 11 -ltlicMorcxil^nr
(mei TOCJ-77-3 -chJorophcnyl phenyl laquoKr (xgtvraquo lK-^0-3 tnjM-l^-diC^lofCKtl^nf
( M B I IOI-J5-3 -6romophnyl phenyl ether (32V) 7I-J7-3 12-dicMoroprosaA
(raquo2B) 3M3I32) bU (2-cMarobopropyU rtNer (3JV) ICXU 1-07-4 trraquoni- 1 3-ltjictgtloroBoor^f
(OB) t l l f l - 1 bi5 (2-cMoroetfxgtrv) meihtrw lOOt 1-01-03 cu-O-dichloroprose- (32B) D-U-3 hrxaetilorobutadierw (UV) 100-laquol-raquo rthylbenien 1^00
(33B) 77^7- he i kcMor ocyc 1 openudi crw (UV) 7J-OT-2 rrveThvlerw chlof idf
(36) 7I-gtraquo| oop^troo (raquoJV) 7raquoJ7-3 CtgtlorBmethne
(338) raquo|20-3 nraquopfitfillaquofx 1200 (wv) 7raquo-l3-raquo bromorrgtlaquothne
(34B) nraquo3) nitrobenzene (raquo7V) 73-23-2
(CBI U-Xl-4 N -fl i iro lod iphen yU mi nr (UV) 7J-27- bro mod i cti lor o mT bull- (OR) 42l^-7 N-^itrolaquoodipropylmlrlte (raquoraquoV) 73-traquo-laquo tl uor o tr i cfi lor o mlaquoT itr (UB) I I 7 J I - 7 bn (^thylheraquoy|) phttilaquoUtT 110000 (XIV) 75-71J QJ ct )or oltJ 1 f 1 uoro rrgtei ^bull gte U76) U-U7 blaquonzyl buryl pttTfKUie 12000 ( j i v ) m-i-i ctil or od ib ro mo met h xnf (UB) M-7i2 d i -n -bo TV 1 ft thlaquo U tlaquo (13V) 127-11- te trraquo cfl lor ot hlaquoTgtf (OBI 117-4J-0 dj -n -oc t y1 Jgth fflaquo U re 6 200 tuv) iom-3 tolucie ^70
(7CB) u-u- djrthyl phtJMlire (17V) 7raquo-OI-4 irictilarcraquo^lt-ir (715) 1 3 1 - 1 1 - 5 oVnrrhyl pMtfaUte (UV) 75-OI- v i M v l CMor idr
(T76I 5-55-3 blaquorgtzo( Unihrlaquocme Xylenes 1SOO
Cad- iurn 2 2 on Chromium - - Z I N C ^ ~ P r
Ai results arc expressed as ugc weight as received Xo entry denotes not detects
Lab ID No 2887-3 5A 57709 Phys ica l d e s c r i p t i o n of sample Cl ien t ID
LiquidSludge Liquid appeared to be a hvdrnc-Arhnn blonrl
Sample workup
Vol i t i l e f r ac t ion Methanol Extraction fSW 846-5030^ Semivolatile fract ion Sonicatlon Extraction fSW 84 f i_3550gt) Inorganic f rac t ion Acid nic-psr-inn fSW 846-30501
ACS3 COMPOUNDS BASENEUTRAL COMPOUNDS
f f t CAS CAS (2IA) tt-04-2 (738) JO-32-J DCftZ OTamp p V^^^ff
(22 A) 3laquo9-50-7 p-cttl or o-m-cre laquoo 1 (7VB) 205-99-2 p^^izot oil lyor 4-^ t ^ltf ^^
(2 A) raquo5-37-l 2- CJiloroprieno (75B) 207-01-9 blaquonioltllt)flultxtn^it
(31A) 120-13-2 2raquo-dictgtlcr8tgtrfX)l (74B) 211-01-9 Chryeolaquo
(3 A) 103-47-9 2 -d irrgtet hv Ipherto1 (77B) 201-94-1 laquocnphthyle^
(37 A) 11-73-5 2- rutrop^enol (7IB) 120-12-7 bull^thrjc c^
(MA) 100-02-7 -flitroprlaquorv3l (79B) 91-2-2 bcnroltKhi)pefraquoler
(79A) 31-21-3 2 -d in itr eoricno 1 (IOB) 14-73-7 tluoren
(40 A) 33-37-l 4-d in itr raquo-2 -met hy Iphtnol ( I IB) 13-01-1 poltrtAOthrvTgt^
(44 A) 17-14-3 plaquon1 CM or o^eno I (I2B) 33-70-3 dib^fi-o( 4(K)Aji thirl c c^f (43A) 101-93-7 prwnol (S3B) 193-39-3 indcnotlIJ-ctflsvfie
(SB) 129-00-0 pyrene ftASENEUTRAL COMPOUNDS
( I D )
(5B) 92-X7-3 b^zidrw (2V) 107-02-1 bullcrolrm
(IB) 120-17-1 1 2 fc-Tr ICJ caro blaquoni crw (3V) 107-13-1 bullcrvlonitrij
(93) 1IU7I1 Seraquochlcrotgttniegtlaquo (4V) 71J3-2 blaquonienlaquo inn (17B) 4777-1 hexat^lorcwthgine (4V) H-23-5 carbon ttTricllixidf
( I I B ) 111-wJ bll(2-lt3^1oroltt^w)ether (7V) 101-90-7 ciloroblaquonzene
(20B) 91-31-7 2-ctdo-ont she Ime (10V) 107-04-2 12-dieftloroerane (25B) 95-50-1 l2-dilorobenzene ( 1 1 V ) 71-35-4 11 1 -tricMorotn-laquo
(2ampSI 51-73-1 13-dicMo-obenxerw (13V) 73-3-3 1 1 -d i CM orcxt M-
(77 B) I04-H-7 1 -di ci 1 or o benI erw (UV) 79-00-3 llJ-WiChlorolaquoflaquonlaquo
(2J6) 91-90-1 SS-dKJilorotxniidinc (13V) rraquo-3laquo-3 l122-tetrlaquocftlorelaquoTrne
(35B) 12| |k-2 2fc-dintrotoluene (14V) 73-00-3 diloroeth^e
(gt4B1 404-20-2 24-diniTrotoluenlaquo (19V) 110-73-1 2-cMortxfthv|vL-raquo trlaquoshy
(37B) 122-447 12-diphenylhydriin (23V) 47-44-3 cMoroform
(J9B) 204-U-0 Ouormntherve (29V) 73-33-i ll-diCMorolaquot^nf
(fcOB) 7005-77-3 k-cMarophfy| prlaquonyl etScr (gtOV) 134-40-3 trraquonraquo- 1 2 -dicMoroc t Nenf
(raquo I6) 101-35) raquo-6romoprny| phenyl rther (32V) 71-17-3 12-diChloropostn
(raquo2B) JH3IO2-9 bU (2-ltplusmnlaronopropyl) rthrr (J3V) 10041-02-4 trni-l)-diirMoroxtgtOpnf
(OB) I I 1 - 9 I - I bu (Z-chloroethxjrv) metSampnlaquo 10041-01-05 CU-D-djcMoroproOf-W
(32B) 17 -U -3 hiraquocfilarobutraquodiergtlt (3JV) 100-4U rttyligtlaquonitrgtlaquo 5300 (33B) 77-raquo7-raquo hrxicftl or ocrclopei tidier (UV) 75-09-2 nxthylenf ctilor ifif
lt3B) 71-391 ao prior or (raquo3V) 7raquo-17-3 rtloromrtha^r
(356) 91-20-3 nlaquoprithienraquo Trace (44V) 7raquo1Jraquo bromltmlaquoth^
(MB) n-93) ft i vo b^nz c^^ (raquo7V) 73-23-2
(425) U-30-4 ^bullf i^OftOOL^ri^ny lArrunf (UV) 73-27- bro mod i cgt lor o i~ t gt
U3amp1 Ul-4-7 N i itr CrtoO ip ro py 1 laquo ml r (raquo9V) 73-49-k U uor o IT 1 et loront Mrgt (UB) II7-1I-7 bu (2-Ihythlaquoryl)prtfUtr 59J300 (30V) 73-71-1 dj ci kr olt11 f 1 uoro rrrt (Nrgtraquo
(47 B) L3-41-7 txniyl burvl phthlaquoUtr ( 3 1 V ) I2-1-1 ch1 or od i b ro mo mi IMP r
(UBI U-71- 0-A-fcurl BMMliw (13V) 127-ll-i rt tr t cM or of tNr
Uraquo6) 117-li-O di-n-oCTv| pnttlaquoUfr 6000 (UV) lOt-II-3 toluenf 5700 (7CB) U-447 djrthvl p^tfvilirt (17V) 79-01-4 WiCMoroth^e ( 7 J B I U l - l l - 3 d^M^vl prttgtraquoUW (UV) 73-01- vinv t cMor 10 (77 Bgt H-35-) brto(raquollaquonthncrTraquo Xylenes 19000
Caen 1U~ 1 Chromium =2 Z I N C
All results are expressed as up g weight as received No errrv ripn^t-plt
Lab 1Lgt No 2887-5
rhyr i r n l d e s c r i p t i o n o f sample C l i e n t in 6857710
LiquidSludge
Sample workup Vol i t i l e f r a c t i o n PEG Extraction (SW 846-5030) Semivolat i le fr action Sonication Extraction (SW 846-3550) Inorganic f rac t ionAcid Digestion (SW 846-3030)
AOD COMPOUNDS BAStNELTTRAL COMPOUNDS
rr i CASI CAS (21 A) tt-04-7 (736) 30-32-1 bntoltraquogtprrene
(23A) 3-9-50-7 p~lt1 or o-m-c rraquo1 (78) 205-99-2 ben to( Sgt )1 1 uor raquon I he-gtf
(7raquoA) 93-37J 2- etilorophenol (73B) 207-01-9 beriioltk)(luortntrgt^f
(3 IA) 170J3-2 2raquo-dicMoroprnol (7(B) 2II-OI-9 eifVMTie
(3 A) 03-(7-9 24-4mlaquoThvlDheno| (77B) 20l-9(-i bullceraoMhyler
(37 A) tt-73-5 2- rue-oorienol (718) 1 20- 2-7 laquoflthrraquocene
(3 A) IOO-02-7 ^Mtroprwnol (7fB) 191-24-2 beraquoMoltsrM)plaquovllaquox
(39 A) 3I-71-5 2-4 ini tr ophero1 (tOamp) K-7J-7 tluwtrie
((OA) 33-37l (-lt iMtro-2-methylphenol (tlB) D-01-J phenATithrene
(4A) I7-44-J pentichlorophenol (128) J3-70-3 dilwnioltraquoh)laquonthrraquoceif
(OA) IOI-95-2 prwnol U38) 193-39-3 indeno(123-cd)vcne
(MB) 129-00-0 pyrergtlaquo 6 ASENEUTILW- COMPOUNDS
VOLATH-tS ( I B ) 13-32-9 ftCYTNA pO IT H I raquolt
(38) 92-17- o^nzioinc (7V) 107-02-1 aero le in
( IB) 120-I2-I l2k-o-i(3iloroblaquontergtlaquo (3V) 107-13-1 laquocrvlono-U
OB) Jl l-7fc | he I raquocti 1 or o blaquonI enlaquo (V) 71-43-2 Oltf2 tO^
(17B) (772-I he uc^i 1 or of t h ne ((V) 34-23-3 CJU JOO Tt TTlCfllo^ iCpound
( I I S ) bu(2-rfilcroethv|)ether (7V) 10J-90-7 laquoWoroblaquonzeoe III-44-4
(KB) 9I-51-7 2ltfMoronlaquoohttvraquolwe (10V) 107^)4-2 1 t2^ojo^loroetfft^c (2JB) 95-50-I 1 2 -dichlorotgtlaquorlene (11V) 71-55-4 1 1 1 -trichloroeihtr (251 541-73-I 13-dchlorotxniene (13V) 73-J4-3 1 1 -dieMoreeraquohraquorlaquo
(77Bgt 04-lgt4-7 1 mdash djcMorobenlene (IkV) 79-OO-3 t12-tricriloroeflaquofgte (2gtB) raquolraquo-l 33-didMoroblaquonjidirlaquo (13V) 79-34-3 1122-tetrcnicroeir^ne (33B) 12 I I 4 -2 Z4-diniiroioluerlte (1(Vgt 73-00-3 e^loroetruuie (KB) (04-7C2 2 (-dinitro toluene (19V) 110-73-4 2ltJilorolaquotr(v|vLnraquolnhlaquo (175) 122-447 12-dipr-enylfiydrmiine (23V) (7-44-3 chloroform
(J1B) 704JJ-O Huor^thrr (29V) 73-33-4 lI-ltJicMoroltthcne
(OBgt 7003-77-3 -ctJoroprienvl phenyl ether (JOV) 134-40-3 irirraquo-12-dictila-olaquotrlaquone
( raquo I B ) IOJ 33-3 -6ogtmoprienyl phenyl ether (32V) 7I-I7-3 l7^lichlorepreoine (laquo2BI 3H3raquoO2raquo bit (2-chlororaquoopfT5pyO ether (3JV) 10041-02-4 trint-l3-ltJicnloroBlt-ooee (OB) 111-11-1 bis (2-cMcroetro(v) metSuvr 100(1-01-03 CU-lJ-itflloropOO-^
(376) t7-U-3 hraquoz raquoch1 or o bu tlaquodi ene (J1V) )00-1- erhylberuer 1400 (33B) 77 -gt7- hei tchl or ocyc1 open traquodi ene (raquoV) 73-09-2 methylene chloriCf OB) 7raquo-3raquo-l BO prior one (raquo3V) 74J7-J eMorametrutne (33B) raquol-raquo-3 naphtfalene 100 (UV) 74-13-9 bro rrvome t hrgt (3iB) n-raquo3-3 niireblaquor)iergte (raquo7V) 7J23-2 (CB) U-XH N -01 ITo tod 4gthenyU rru rr (UV) 75-27-4 bro mod i ch lor o rrx t f4Ugt ((36) 42IO4-7 N-nnroodipropYlraquomlrlaquo (raquolaquoV) 73-4t-4 JJuorotr lchloronvlaquoiMftlaquo (Uol U7-1I-7 ba (2-etrylNraquoYl) phtt^Ure 100000 (30V) 75-71 -raquo dj cftlcr od U 1 vraquooro rri NUT
(47 Bl 13-44-7 t^niyl butvl phthiUte 13000 (31V) 124-41-1 chlorodibromorrwt^r
lt U E gt ) U-71-2 d-ojjurvl phtf^Ure (13V) 127-11-4 tr trbullcti loro rirr
laquoraquo6gt 11704-0 dl-fl-OCTvl pfltMUM (UV) 10t-ll-3 toluene fiin (TtS) raquo-laquo djrthvl phttuliTr (17V) 79-01-4 tricolor oethenr lt 7 | o l 131 -11 -1 (UV) v i n v i chlcwidr dimrlKyl rrftlaquoUTraquo 75-OI-J
(T75I J4-35-J blaquoTMOlt^trrlaquocr^ gtylenes 1200
Cadr ium 3 Chromium 21 ZINC 150
All results are expressed as ugg weight as received y0 entry denotes not detect
Iah I D No 2887-2
Physical descr ip t ion of sample
Strained Soil
Sample workup
Voli t i le f rac t ion PFG Extraction (^W 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-3540) Inorganic fract ion Acid Digestion (SW 846-3050)
ACS) COMPOUNDS
rn CAS Tft CASf
(21 A) tt-04-2 (73B) 50-32-4
U2A) 71-50-7 P-ch 1 or o-m-cre laquoo 1 (7k 8) 205-11-2
(2 A) raquo3-37-l 2- chloroprraquoeno| (75B) 207-01-1
(3IA) 120-13-2 2raquo-4ichlorophenol (74B) 21UOI-1
(3 A) 103-47-1 24-dimethvlphenol (77 B) 201-14-1
(57A) U-75-3 2- njtroDhenol C7I5) 120-12-7
(MA) 100-02-7 a-flitrophenol (71B) |1l-2raquo-2
(51A) 51-21-5 2 -d in i tr o phetio 1 (SOB) K-73-7
(40 A) 53-57-l raquo 4-dinitro-2-methy lprnol (tlB) 15-01-1
(4 A) 17-14-3 plaquoitraquochloroorlaquonol (I2B) 53-70-3
(43A) IOt-13-2 prlaquonol (13B) m-31-3 (MB) 121-00-0
BJ KSENCLmLAL COMPOUNDS
(IB)
(3B) 12-17-3 bcnzidine (2V) 107-07-1
(IB) 120-17-1 1 2 k- tr i ch 1 oro benr ene (3V) 107-13-1
(IB) I1U7I-1 he it raquocM or o boiz ergte (raquoV) 7I-J3-7
(12B) 47-77-1 he traquoch 1 or oet hlaquo ne (4V) 54-23-3
(116) 111-- buC-cJiloroethv|gtether (7V) 101- W-7
(20B) 11-31-7 2 -ltft 1 or on ph ttvraquo 1 laquon e (10V1 107-04-2
(23B) 15-30-1 1 2 -dictilorobeni ene (11V) 71-55-4
(25) VI-73-1 1 3 -ltJ i ci 1 or o blaquoiz ene (13V) 73-3-3
(77 B) 104-M7 llaquo-dchloroblaquoMeoe (HV) n-00-3
(2IB) 11-lk-l 33-dicMorotxTLtidinr (15V) n-3raquo-3 (33B) 12I-U-2 2 ltgt -4 in i tr ot o luene (14V) 75-00-3
(MB) 464-20-2 2 4-d initrotoluene (11V) 1 10-7 3-1
(J7B) 122-447 1 2-diprieny Ihydrti ine (23V) 47-44-3
(316) 2O4-UO Ouorraquonthene (21V) 73-33Jshy
(WB) 7t)03-77-3 ^-cJJorophenyl prienyl ether (JXgtV) 154-40-3
(MB) 101-33-3 -6romopriefgtyl prienyl ether (32V) 71-J7-3
(raquo2B) 3431-32-1 bit (2-chloroboproprO ether (33V) 10041-07-4
(OB) I1U1I- I bu (2-ltMoroethorv) methane 10041-01-03
(52B) r-u-3 hexachlorobutadiene (J1V) 100-l-raquo
(33B) 77-47- he z raquoctlt lor ocycloqenud i crte (MV) 75-01-2
OB) 71-31-1 ao prior one (raquo3V) 7raquo-17-3
(33B) 11-20-3 nlaquopntrlaquollaquone (UV) 7raquo-13-1
(MB) n-13-3 nitrobenzene (raquo7V) 73-23-2
(UB) U-30-4 N-nnroiodiprienyUmine (UV) 75-27-k
(436) Ol-U-7 N-nitrModiproOYlmJne (raquo1V) 73-41-
(UB) 117-117 bu (2-laquothylheiry) phtrlaquolte 8800 (50V) 75-71-1
( 4 7 B ) L3-U7 blaquoniyl buryl phthaUte 30 (31V) 12I-H-1
(UB) U-7U-2 di-o-burvl phtrMUte U3V) I27-I1-
(416) II7-U-0 dj-n-oCTvl pritntUtr 1200 (raquo4V) IOUI1-3
17CB) U-44-2 djetiTi phrtultrt (raquo7V) 71-01-4
( 7 I B I 1 3 1 - 1 1 - 3 dimnfTraquo| prThraquoUtr (UV) 73-01-
(776) H-35-3 berMolta^thrCF^
Cl ien t ID 8 A - S 7 4 6 1
RASENEUTRAL COMPOUNDS
benzofbtfluor^tMe
benzodclfluorintoent
Ctiryiene
cenoithylene
raquonthrraquoctne
benzoltKhilpervlefgte
floor ene
prlaquofnnthrene
ltlibenplusmno(4h)knthricrnlaquo
inogtno(123-rt)pvrrne
pyrene
VCX-ATIIE5
bullcrolem
bullcrvlomn-U
benzene
carbon tetrtchloridf
chlorobenzene
1 2-oUchloroethAnf
lll-trichloroethlaquone
ll-dcfioroethrraquo
1 1 2-tricilorolaquothraquorw
1122-tetrichloroeTtvin
chloroethre
J-ctiloroethv|vinv| etrgte
chloroform
11 -denier oethene
trinraquo- 1 2 -4 cMor oe t hens
12-dcMoroprooine
^Lns~ I f 3-4ic^ lo^opf oo^^^
Cli-l 3-dicMoroprooe^e
rttiylbenzene
methylene cnlonfle
Ch 1 or o me t hane
bromome thane
Trace
bro mod i cMor 0 me t hane
(Juorotrlchlorome thane
chlorodibromometKinf
tetracnloroethervp
toluenetr icMoroel he-if
Trace
CacTiiun Chromium ZINC f
All resxil ts are exprp^spr i K-i
Phys ica l de sc r ip t ion of sample
Strained Soil
Sample workup Vol i t i le f ract ion PEG Extraction (SU 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-5340) Inorganic fract ion Acid Digestion CSV 846-3050)
ACE) C30laquo POUNDS
m CA5i CASraquo (2i A tt-C-2 (73B) JO- 52-1
(22 A) J1-JO-7 p-ch 1 or raquowTv-cre 101 (7raquoB) 203-raquoraquo2
(2 A) raquo)57-J 2- chlorophenol (73B) 20701-
(31 A) I25J3-2 2k-4icttlltroptlaquonol (7tB) 211-01-1
(3A) IO)-7-raquo 2-dimlaquothvlpNrnol (77 B) 20l-raquoi-
(37 A) u-rj-j 7- niTTOphenol (TIB) 120-11-7
(MA) 100-02-7 -rtropN-rraquol (7raquoB) lraquol-2-2
(JraquoA) JI-21-) 2-d initroprietys 1 (IOB) U-73-7
(MA) 53-37-l Udinnro-2-mlaquothylphenol (UB) I5-OI-J
(Agt I7-U-3 pentichlcropwnol (126) 33-70-3
laquo)Agt 10l-raquo)-2 phenol (I3B) IJ3-31-3
(MB) 12raquo-00-0 AASCVflCUTRAl COMPOUNDS
( I B ) I3-32- bullcnraquophtber
(56) raquo2-17) bnzidirlaquo (2Vgt 107-02-1
(IB) 120-12-1 l2btrilt7tlorotgteizegtlaquo (3V) 107-13-1
traquoB) IIraquo-7fc | heikcMeroblaquonzergte (V) 7l-3-2
( I 2 B ) 4772-1 he ueft 1 or olaquot hraquo rgte (tV) laquo-23-3
( i ts) III-- biraquo(2-cMoroethv Dethrr (7V) 101-W-7
(20Bgt 1I-3I-7 2-cMoroflaquophthlene (10V) 107-Ofc-2
(2)6) raquo5-50-l l2-dchlorotgtlaquonzefgte (11V) 71-33-4
(28) 3l-7)-| 1 3-didMoroblaquonrenlaquo (13V) 73-3-3
(27B) 10t--7 l-diclorolgtmzerlaquo (iV) rraquo-00)
(216) raquoI raquoltbull- 33-dichloroblaquoMidiflaquo (13V) 79-31-
(356gt 2I- l-2 21-dinitrotoloen (UV1 73-00-3
(UB) laquogt- 20-2 2 (-dinitroto luenlaquo (HV) 110-7J-J
(376) 122-W-7 14 -dipheny Ihydrzire (23V) lt7-M-3
(396) 2O--0 tJuoruMSene (2raquoV) 7J-35- (OB) 7003-77-3 -c^lvophenyl pNrnyl ethlaquor (30V) 1H-W-)
(MB) 101-33-3 bull-bromopriefiyl prienyl ether (32V) 7t-t7-3
ltraquo25) 3HJI-32-1 bU (2-cMoroaopropyl) rthrr (33V1 10ltX 1-02 -6
(06) l l t - t l - l bis (2-cftloroetSorv) metwne 100lt]-01-03
(32B) C7U-3 heraquoraquochlorobutidierx (31V) 1 00-41-
(3361 77-7-raquo hexiOilorocycloptfiudlerve (raquoV) 73-0raquo-2
(56) 71-51-1 no ph or one (raquo3V) 7raquo-17-3
(3)6) raquol-raquo-3 rwiphtfalme (UV) 7raquoJ3-raquo
1361
LUB)
H-133
14-30-4
nitrobenzene
^ ri i iy o too ipf^^ y LA r^i rtf ^ 7V) (UV)
73-23-2
73-27-
(436) t21--7 M^TI iff frfcO^ip ropy Ift mJf^ (gtraquoV) 73-4raquo-raquo (UB) I17J1-7 bu (2-rThyiruMcyDpMtvUtr 570 (jov) 73-71-1 ( U B ) U-41-7 blaquonzyl buryl phthlaquoLite (31V) l2k-raquo-l ( U B I U-7I-2 di-n-burvl pitftALtTe (raquo)V) 127-lt-fc
(OB) 117- -0 dJ-fraquo-oCTvl phlJ^Ute (UV) IOt-It-3
(7CB) 14 -W- 2 djelftvl phtfalitt (17V) Tt-01- ( 7 I B I 1 J I - I 1 - ) duTNnhylphttsraquoUw ltUV) 75-01-
(77BI X-))O lgtmrlaquoigtmhrraquoctf
Cadmium f iQ Chromium 15 ZINC
Tab ID No oo -
Cl ient ID 8A-A-64220
fcASENEUTTRAL COMPOUNDi
blaquofuo(raquo)pyrrtgte
bfizo(b)(loortAth^e
benzo(k)f|ulaquoin1herf
Ctiryiene
cenDraquoMrwlene
fcftT^rict^t
D^flZCT (fftl)pC^ V Itf^p
(luorene
phen^threne
diiwnztKthlanthricene
indlaquono( 1 23-lttf)pvrene
oyrene
VOCATtLES
bullcrolem
bullcrvlooitriJe
bervteoe
carbon WTTicMoridf
chlorobenze^e
12-djcMoroetfane
1 1 1 -tricolor ex tKraquon
1 1 -dicMarcx t hrlaquo
1 1 2-triChlorothraquorw
1 122 -laquotrraquocM or o-hraquorgt
cMoroettu^e
2-cMorlaquothv|vuy| rseshy
chlexeform
ll-dchloroctfgtn
tri^iraquo l 2laquoflic^ loTo^i rgtcnt
12-dicWoroproptrs
Winl-l3-dicMoropfooene
Cu-lJ-djChleroprooe^
rrtiylfrenzene
methylene ctiloride 0 64
cMorometHAne
bromomlaquothlaquone
bnsmoform
bro mod i eti lor e me t Nine
0 uor o tr 1 cMor e rrgtlaquo t Nnlaquo
dj di tor olaquol If 1 uoro mraquoi Nrraquo
chlorodibromonveiKme
re tr a en 1 or or fxrvr
toluene
D-ieWoroefwne
entry denotes not detect All results are expressed as ugg weight as received Xo
Lab 1) No 2887-8
Physical descr ipt ion of sample
Sf-rs inpH 9 n i l
Sample workup
Vol iCi le f ract ion PEG Extraction (SW 846-5030)
Scmivolat i le f ract ion Soxhlet Extraction (SW 846-3540) Inorganic fraction Acid Digestion (SW 846-3050)
ACD O3MPOUNDS
m CAS fPraquo CASf pi A) tt-Ot-2 Zraquot- tritilorophrgtol (73B) 30-32-1
ft M -3o-7 p-cMorraquo-m-crTraquool (7kB) 205-raquo-2
(2 A) raquoS-37-l 2- cMorop^erxgtl J73B) 207-OI-raquo
(31 A) 120-13-2 l^ictiloropix)l ^7tB) JII-01-
(3 A) |03-7-raquo 21^-dimeThvlphenol (77B) 20t-raquot-l
(J7A) tl-73-3 2- rutropwnol (71 B) 120-12-7
(MA) 100-02-7 -MO-opwnol lt7raquoB) lraquol-2-2
fJraquoA) 3I-2J-3 2-dinitrop^laquoTgtoI ((OB) U-7J7
(laquogtA) J34-37-1 lt-dinitrfr-2-methylpwrxgtl (I IB) I 3-0 1-1 (raquoAI 17-1 3 pcmacMcroptonol (S2B) J3-70-J UJA) IOI-raquo5-2 phenol (IJB) MJ-39-J
(tBgt 12raquo-00-0 RASEfZUTRAL COMPOUNDS
( IB) 13-32-f raquocertaprithene
(3B) J2-17-3 twnndinc (2V) 107J2-J (IB) 170-I2- lr2k-triOilorobenzerlaquo (3V) 107-13-1 (raquoB) I11-7I-I hei bulllt1 ore blaquont ergtlaquo (raquoV) 7l-3-2 (1B) 47-72-I he ucft 1 or oe t h n (tV) 3-23-3 (116) |II_wJ bu(2-ctiIarothvI)laquotNer (7V) 101-90-7
(20B) raquoI-JI7 2 -cW or orvraquo ph tf I ene (10V) I07-Ofc-2 (23B) J3-30-I l2-lt5ictiloroblaquonzeoe (11V) 71-3J- (245) 3I-7J-I 13-dic^lorotxenzenc (13V) 7J-3-3 (27B) 104-K-7 1 mdash diC^lorobtnrerve ( lraquoV) 7^-OO-5 (21 B) raquo|raquo| 33^icftlorobenzidifv (I3V) rgt-j-3 (33B) I 2 I - U - 2 2ltgt-dinin-o1olvraquorgte (UV1 75-00-3
(J4B) 404-JO-2 21-dinitrotoluerve (1raquoV) 110-73-1
(37B) I22-W7 1 2 -d ipheny Ihydra z ine (23V) C7-14-3
(318) 2O4-W-0 tJuortnihrne lt29V) 75-3J- (kOBt 700J-77-J ^-tfMoropheTgtyl p^enyl ether (30V) 1J4-W-3
( raquo I B ) IOI03-J raquo-6romopfgtenyl phenyl ether (32V) 7I-I7-J
(06) 3H3raquo-)2-raquo bU (2-tfilerobopropyO ether (3)V) 10041-02-i
(OB) lll|| bii (2-cMoroethoxv) methane 10041-01-03
(37B) PUt) hxzraquocMorobutadienlaquo (J1V) 100-raquol-raquo
(JJB) T7^7U heztctilarocrclotMnttdicrgte (V) 7gt-0raquo-2 OB) 7l-3raquo-l BO ph or one (raquo3V) 7raquo-17-J
(338) raquo|20-3 rlaquopritrilaquolene (UV) raquo-laquo-raquo
(3iBl n-raquo3) nitrobenzene (raquo7V) 75-23-2
(CB) li-X)-t N -n i tr o tod ipheny U mi nr (UV) 73-27-fc
(06) CI-U7 N^iitroiodipropYUmlr ^raquo1V) 73-H-fc (UB) 117JI-7 bu (2-ethYlNerrl)pM^Utr 12000 (JOV) 75-71-1 (47 B) L3-U7 llaquoniyl buryl pht^UTe 2 800 ( 3 I V ) 2laquo-raquo-I (UB) raquo-7i2 di-o-ourvl pritfwiUrr (I3V) 127-lt-i (196) 117-14 3 dj-n-ocryl pritfiiUrr (UV) IOUIS-3
(TCB) J4-W-2 djnhYl phtfalitt (17V) 7t-01-lt (716 ) 1 3 1 - 1 1 ) damnhYl pMtuUTT (UV) 73-01- (77 Bl 3 33-3 frlaquon z olt raquo klaquom h rraquo c prgte
Cadmium T^ Chromiurn T Z T N C 100
Client ID 8A-C64221
BASENEUTRAL COtPOUNOS
bnzo(t)pyrrrie
benzobXluoriflthei blaquorizoltVHluorraquontrraquone
chryiene
bullcenphthylene
tnthneene
benzoltRM)perylene
fluorene
prienlaquonthcTTgte ditgtmplusmnolt4hluithrraquoctnf
indenof 1 23-cd)pvrf ne
pyrer
VOUATILES
bullcrolein raquocrvlonnrile benzene cmrbort Tetrichloride
chlorobenieoe 1 2-oUchloroethirie
11 1 -tricolor oethne ll-dvchlorolaquollMr 1 1 2-w icMoroethAoe l122-tetrieMoroeihilaquonlaquo
chloroetKvne JltJilorothvlvmv| ethe chloroform
11-dicMoroethent
trani- 1 2 -dicti lorolt t hene
1 J^JictiloroproBfVf
trim- 1 3-4ietiloroproperie
Cil-IJ-dicMoropfoOerie
rrhyUxrmene
methylene criloride
chlorornethine
bromome thne
007
13
tluorotr l^VoromlaquotNraquorgtt
da ch lor od 1 1 1 ooro frvet hraquone
chlorodibromometlvinf
te trraquocnloroeT rrrr
tricMoroetSmr
All results are expressed as us2 weight as receixred No entrv denotes not detect i
Phys ica l descr ip t ion of sample
SoilCake
Sample workup
vol i t i le fract ion ^FP FvfrarfMnn (ltU Rif i mdash Smrn
Semivolatile fraction Soxhlet Extraction (SW 846-3540^ Inorganic fraction Acid Digestion (SW 846-1050)
AC23 COMPOUNDS
rrt CAS CAS
(21 A) 11-04-2 2raquo4- trieMorophenol (738) 50mdash 3-4
122 A) J1-30-7 p-ctil or raquo-nvltrlaquo laquoo 1 (7laquoB) 205-11-2
12 A) 13-37-4 2- etilorophenol (75B) 207-01-1
(31 A) 120-13-2 2raquo-diclorophlaquoTgtol (74B) 211-01-1
(34A) 103-471 24-dmlaquothylphrnol (77 B) 201-14-4
(57 A) U-73-3 2- rutrop^nol (7raquoB) 120-12-7
(54 A) 100 -02-7 bull i tro p^c 01 (71B) 111-24-2
(J9M 31213 Z o trt i tr o poc^oI (MB) U-73-7
(40 A) 334-32-1 T^Hjinitrfr2^rt^T ny tp^gt^noi ( t lB) 13^)1-4
(44A) 17-44-3 pcnttchlaroprwnol (S2B) 33-70-3ltOA) IOt-IJ-2 pTUfNOl (136) 113-31-3
ftASENtUTRAL COMPOUNDS (MB) 121-00-0
(IB)
(56) 12-473 Iwnndine (2V) 107-02-1(IB) I20-IJ-I 1 2 4-tr icJi lorobeniervr (3V) 107-13-1(IB) 11 1-711 hexkcMarobcnzeM (4V) 71-43-2(126) 47-72-1 hexch)eroeihlaquone (4V) 54-23-J( I I S ) 111-4- bu(2-eMorlaquothv|)laquothr (7V) 101-10-7
(208) 11-51-7 2-c^laronraquophtfgtlene (IOV) 107-04-2(23B) 1J-30-I 1 2-dichloroblaquonime (11V) 71-35-4(2651 341-73-1 gt3-ltiictitaroblaquonxcnc (13V) 73-54-3
(27 B) 104-47 l4-dicMorotKmrerlaquo (14V) 71-OO-3
(21 Bgt 11-14) 33-4ichlaroblaquon2idine (15V) 71-34-3
(338) 121-14-2 24-dinitrotoluene (14V1 73-OO-3(J4Bgt 4O4-20-2 24-dinitretoluenc (11V) 110-73-4(37B) 122-447 lraquo2-dip^nylhydrraquoxirlaquo (23V) 47-44-)(MB) ro--0 Uuaranthene (21V) 73-33-4(406) 7003-72-3 4-ltUorepfraquonyl phenvl rtSer (30V) IH-40-J( raquo I 6 ) 101-333 4-6romoprlaquonyl pflaquony| ether (32V) 71-17-3
(OB) 3H3I-J21 bll (2-cti|orobopfrgtpyO ether (33V) 10041-02-4
(OB) I11-1I-I bis (2-cMaroethoxv) methane 10041-0103
(57B) P-44-) hczw^lorobundiene (J4V) 100-41-4
(JJ6I 77-47-4 htTicMarocyclojxrtadien (44 V) 75-01-2
(346) 71-31-1 aophoroo ( raquo ) V ) 74-47-3
(33B) raquo|203 r^pn thA Icr^ (44V) 7 -raquobull J-
(546) n-i3) H i frovCftZfl^^ (raquo7V) 73-23-2
142B) 14-30-4 S -n i tr o laquood ipheny Lt mi nc (44V) 73-27-4
(43 B) 421-447 N^iitrotodtpropyUmlne (41V) 73-41-4(MB) 117-41-7 bu (2-raquoThylhlaquolaquoyl)pMtgtlaquoUtr 52000 (30V) 73-71-4(4B ) 13-447 (xniyl bviryl ptithiUre 6700 (3 lV) 12raquo-l-l(UB) 147U- di-n-burvl pMhUre (I3V) 127-11-4laquoampgt 117-4J-0 ltjj-n-octyl phtfaUtr (UV) 101-11-)
(7CB) U-44-2 djrthyl pht)raquolraquort ( I7V) 71-01-4( 7 I B I 131-11 ) dimrthyl phttgtUTe (UV) 73-01-
(T76) H-33O tgtnzoUtlaquoftthncmr
Cadmium l i r^ Chromiurn 2 0 ZINC 140
All results are expressed as ugg weight as received
Lab ID No 2887-6
Cl ien t I D 8AD64219
Dd20( amp py(re
blaquonio(bHluorraquoflthegtlaquo
berzo(Mf luorampnThene
chryraquoefgte
ftctnAoMhy(ergte
raquonthncene
benioltK(M)plaquovlene
(Juorene
picnintfirtTX
dihwvioltraquoh)laquonThrraquocene
mdeno(l23-rt)pvrraquone
pyrene
raquocrolein
raquocrvloourUf
benzene
carbon laquoTrraquochlofifle
chlorobenieo
l24JcMarolaquotlxine
lll-trichlcroltthlaquorlaquo
-ltJicMorigtnKraquorgtlaquo
l12-trichlorolaquot^nlt
1 1 22-tetrcftloroetrvtnlaquo
^tloroeThAne
2^^1orolaquothvlvuiivt ethe
etila-oform
ll^liailoroltN^
trtni-12-dichlcxolaquoTfgtene
12-ditfiloropropine
trtni-l3-ltjicti|orocltX)t^f
cu-l3-djcMoroprooe^f
rttiylbtnztTve
methvlene cWoride
ciloromnM^f
Dco^^oroct^A^^
bromofarm
bromodicJiloromltlfraquon
tluorotrlctiloromttNir
diOilorodKloororfvrir^Ar
ct^lorodraquobrofTorrgttKAne
wtricnlorampctNrr
toluene
trirfilorolaquoThfif
v i n v CMor ilt3^
No-entry denotes not detect
ih i n N O 2887-9
Phys ica l d-asc r ip t ion of sample Cl ient ID 10A64222
Linnir l ShtHcp
Sample workup Volitile f rac t ion PEG Extraction (SW 846-^030^ Semivolatile fract ion Sonication Extraction (SW 846-3-540 Inorganic f ract ion Acid Digestion (SW 846-3050)
AOD COM POUNDS BAStNELTTRAL CXLPCXJNDS
rrt CAS CAS
(21 AJ U-Ot-7 Z4- trichloropSeno (73B) 30-J2-
(22 A) 55-30-7 p-ctilarraquo-m-erelaquoo1 (7kB) 205-raquoraquo-2 ben r olt b) 1 uor ifl t Ne~gtf
(2AJ raquo3-37-i 2- ctilorophenol (75B) 207-0raquoraquo benzoltllt)floofraquontslaquor
(31A) 120-13-2 2raquo-ltJictilcroooenol (76) 211-01 9 ctiryjene
(3A) I03-47- 2k-dimethylphenol (77 B) 20t-raquo4-i bullceruphthv lerraquoe
(37A) U-73-3 Zmdash Ajtropheooi (7SB) 120-12-7 fcntftricene
(34 A) 100-02-7 w^ i ff o phe rgto 1 (7raquoB) Iraquol-2-2 ben z o( Rh i )per v 1 me
(31A1 51-21-3 Z^ - d iA iV opheno1 (SOB) U-7J-7 Iluorene
(MA) 3X-37-I T v-4iAiv omdash laquo mdash fl^et ny Ipoenoi (I1B) 13-01-1 poeftraquonthrene
(4 Al 17-14-5 p^ntBCfllGrOprlC 1 Vol |I2B) 33-70-3 dilgtenioltraquoh)laquontwraquocenr
USA) IOl-raquo5-2 phenol (13fi) U3-31-3 indeno(l73-cd)oraquorrie
(MB) I2raquo-OO-0 pyrene RASENCimiAL COMPOUNDS
VCH-ATUL5 ( I B ) 13-32- raquoclaquonraquophtflaquorgte
(58) 12-I7-J benzidire (2V) 107-02-1 bullcrolem
(IB) 120-J7-I 1 2k-tr icnlorobenzene (3V) 107-13-1 acrvlonitr UP
(IB) 11U7I-I heKicMorobtnzme (raquoV) 7I-A3-2 benzene
(176) 4772-1 hexcftla-oethtgte (4V) J4-23-5 campr~toon TeTrscftlo itit
(116) III-- bii(2-lttilorolaquothv iVether (7V) lOt-W-7 chlocobenieo
(2C5gt raquol-3l-7 2-cM oroolaquo ptittu lene (10V) I07-O4-2 1 2-dicrtloreetranr
(23B) raquo5-30-l 12-dichlarobenime ( 1 I V ) 71-33-4 11 1 -tricMoroethr
(24 B) 31-73-1 1 3-ltl icJgt lor obcn i ene (13V) 73-3^-3 1 1 -dicMoroeth^i
(27B) 104-^4-7 1 4-dich lorobenzergte ( t k V ) n-00-3 11 2-tncfiloroetvlaquorie
(215) 91901 33-didMoroblaquozidinr (I3V) rraquo-3k-3 l122-tetrraquoOMo-oethne
(335) 121-I-2 2-dinitrotoluergte (ItV) 73JW-3 chloroethjin
(3461 (0420-2 24-dinitrotoluene (19V) 110-73-1 2-cMoroethraquo|vuiv| trgteshy
(37 B1 122-44-7 12-diphenylhydrnine (23V) 47-44-3 ctiloroform
(316) 204- Jgt tluarmrnhene lt2V) 73-35-4 1 1 -^iCMoroeThe^f
(C6) 7003-77-3 -chlorophenyl poenyl ether (gtOV) 154-40-5 trraquonraquo-l2-dicrloroltthene
(bull16) 101-35-3 raquo-6romophenyl phenyl ether (32V) 7I-I7-3 l2^ipoundMoroproBirgte
(raquo26) 3H3I-32- bit (2-cMarobopropvt) ether (33V) 1 004 1-02 -4 trmni-l^-dictilwoproom
(OB) l l l - raquo l - l bis (2-cMeroethoxv) methane 1004 1-0 1-05 cu-13-laquoicMoroprooe^e
(J2BI D-U-3 rraquolaquoeftlorobutraquodilaquooe (JJV) IOOJM- rttylbenzene
(336) 77 -raquo7- hezactilarocyclooentadiene (WV) 75-OT-2 methylene cniorifle
(56) 7raquo-3raquo-l ao ph or one (raquo5V) 7raquoJ7-3 eMoromeirune
(33B) JI-20-3 nraquophtMlene (UV) 7raquoJ3-raquo bromomethAftf
1X6) n-raquov) nitrobtnxerw (raquo7V) 7J-25-2
(CB1 14-30-4 J -ltii TT o vxJ ipheny U rru rraquo ^UV) 75-27- bro mod i cfilor o me t r)e
(CB) 47I-U-7 N-nnrotodipropylraquomJne (tV) 75-4raquo- 11 uor o tr i cMor o me t htgte (US) V17-1I-7 bu (2-eifrrlhryl)praquogtttilaquoUMshy 69 000 (30V) 75-71-1 di cti tor odl1 1 van m^i rajgtr
(476) U-U-7 benzyl buryl phihiUte 890 (31V) 12laquo-kraquo-l cMorodbremof^etNrr (US) U-7I-2 di-n-burvl prittuUre (13V) 127-lt- Uraquo6gt 117-t-0 dJ-laquo-ocTvl phttviUre (UV) IOLtS-3 Wluenr
(75) u-w djrrhylphtnltt ( i rv) 71-01-4
(715) t J I - l l - 3 dimnhrl pfthUte (UVI 73-01- viny l CMcriOr
(779) J4-35-3 0laquoMo(UnthrraquoCflaquoe
C a d m i u m 130 Chromium 20 ZINC 170
o nnn Z-UUU
^0(^ Trace
All results are expressed as ugg weight as received No en
APPENDIX E
PLATES
I I I I I I I I I i Plate 10-1 Troy Mills Landfill with a backhoe excavation
in progress in a former drum burial area
I I I
I I I I I I I I
I I Plate 20-1 NAI field investigation team preparing for
Level B activities during the drum excavation task Troy Mills Landfill
I I I
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
I I I I I I I I
I I Plate 20-3 NAI field investigation team member undergoing
personal decontamination at the hot line Troy Mills Landfill
I 1 I
I I I I I I
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
1
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
I
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
I I I
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
I I I I I I I I I I I 1 I Plate 53-3 Pigmentsludge deposits interbedded with
soil layers in Excavation 8A Troy Mills
I Landfill
1
reported to have contained various materials including waste
plasticisers pigments and organic solvents
Previous site investigations by NAI have included site
reconnaissance studies test pitting water quality analyses (NAI report
of August 12 1981) geophysical (seismic refraction and electrical
resistivity) investigations (NAI report of December 1981) installation
of a ground water monitoring system (4 wells) and sampling and analyses
of ground and surface water samples (NAI report of July 1982) A water
budget analysis was performed to assess the leachate generation
potential of the site (NAI report of September 1982) Concurrent with
the study of the drum burial area additional seismic refraction lines
were conducted and three additional ground water monitoring wells were
installed to further assess leachates from the solid waste
(non-hazardous) portion of the site
Laboratory Analyses were conducted by Resource Analysts Inc
(RAI) We also wish to acknowledge the assistance and cooperation
provided by the management and personnel of Troy Mills especially
Messrs Barrett Ripley and Carl Patten
20 SAFETY PLAN
A Bureau of Hazardous Waste approved safety plan for on-site
activities was developed for the waste characterization phase of work
because of the potential for encountering hazardous materials The
safety plan is presented in Appendix A of this report It assesses the
overall degree of hazard identifies specific potential hazardous
situations and presents guidelines for personnel protection and action
levels as required The plan was made available to all field personnel
during the field work
The magnetic and topographic surveys were considered to be low
hazard activities with a prescribed level of personnel protection (LPP)
of C or D depending on the results of air monitoring Level C proshy
tection involves wearing a full face respirator with organic vapor dust
combo cartridge Tyvek suit over work clothes rubber safety boots and
gloves Level D protection requires cotton coveralls or other work
clothes safety shoes safety glasses and possibly a Tyvek suit
During the drum excavation and sampling task which was
determined to be moderately hazardous Level B protection was preshy
scribed Level B protection requires that personnel wear SCBA (self
contained breathing apparatus) chemical resistance Tyvek suit steel-
toed rubber boots and gloves Plate 20-1 shows NAI personnel on the
site preparing for Level B activities Plates 20-2 and 20-3 show
personnel decontamination equipment and the hot line during the drum
excavation task
30 MAGNETIC SURVEY
To delineate the landfill area underlain by steel drums a
high resolution magnetic investigation was conducted by John F Kick
PhD consulting geophysicist The magnetic method was chosen over
other search methods because ferromagnetic substances (drums) were the
target objects and the majority of Troy Mills other wastes are
non-magnetic (largely fabric scraps) Dr Kicks report is presented in
Appendix C
Eighteen parallel rows of magnetic field measurements were
made along north-south lines The measurements were made at 10-foot
intervals along the rows This work resulted in a detailed contour plot
of the magnetic anomaly (Figure 1 in Appendix C) The source materials
which cause the magnetic anomalies do not usually directly underlie the
peak of the anomaly A shift is caused by the inclination of the
earths magnetic field and by dipolar effects Figure 30-1 shows NAls
delineation of probable source areas for the magnetic anomaly and
peripheral areas which may contain some magnetic source material The
plotted source area is generally the area between the peak of the
magnetic anomaly northward to the zero anomaly contour This is to
compensate for a southward shift of the peak of the magnetic anomaly
from the center of the source deposit The complex geometry of the
anomaly necessitated much interpolation between peaks and ridges
gt QJ
LJ LLj
ro U -r- X j_gt 0 QJ bullimdash -4-) QJ CJ bullrmdash o 1C
gtsj
-= QJ 3pound c
CT1 -a 3J +shygt
LO
^mdash 4
4-gt
^O gtbull
c
QJ ltmdash U ltT3 f - ~ 3 0 O C ll ro
QJ CJ rmdash -r
-0 -U ro QJ XI C O O1 Sshy (T3
Qshy pound
ro ro OJ E S_ ro QJ
mdash bullmdash O ro ti
rmdash J_3 CC3 U CU
mdash i-0
4_gt
ro
QJ H r^ C
~t
QJ QJI) (
QJ 1
Sshy E gt4-gt QJQJ C
JC bull-
r^ ro
bullmdash rshy c0) u
E in bullbullshy0 rshy
bullbull- bull(-gt s_ -o c O)s_ c QJ O Oshy U
3 O I)
c o toro srshy ro
DC -t-gt CO
o rO U i_
ro X a
imdash 3 O
-rshy -a
C QJ
rmdash
t^ C o
bullptrade
4^ CL -ishy s_ -o QJ -a Q lt
O J
oo
OJM bullH
rv i^^ 1 ^
bulla 03 ^0 I
1 I
bullH lt- T3
2 EH
0)AJ
aLU ca Q)
U
13 O en
O rmdash u
bullH 4Jltu c
0)M lt8
bull0 ltV
JJ ltV 0)c
bullH M
a I o
o V
Z 2 d ) 3NI13SVS UOiid 33NV1SIQ
40 TEST PIT EXCAVATION
41 WORK PLAN
A series of test pits were excavated in the Troy landfill for
observation and sampling More specifically the purpose of the
excavation was to estimate the number and distribution of drums buried
in the landfill determine the condition of the drums (full empty
crushed rusted leaking etc) identify types of buried and drummed
waste and verify the results of the magnetometer survey A stratified
random sampling method was used to choose 10 locations within the
delineated area of magnetic source material This insured that
excavations were distributed randomly across the landfill and that the
resulting data could be evaluated with a level of statistical
reliability Excavations were also selected in areas on either side of
the anomaly which were considered free of buried magnetic material and
also where drums were visible at the landfill surface
The following procedure was used in choosing the locations for
the random excavations The center of the delineated area of magnetic
source material was used as a base line The base line was drawn onto a
map of the source material (Figure 30-1) and then divided into ten
60-foot long segments Using a random numbers table a point-distance
was located on each segment (designated the random station) and a
line drawn at that point perpendicular to the base line segment Again
using a random numbers table a point-distance (designated the random
offset) measured along the perpendicular line located the point of
excavation The grid coordinates for each excavation were graphically
determined from the grid overlay and then field-located from the
surveyed grid intersections Grid coordinates and selection data are
presented in Table 41-1
It was judged that 10 excavations in the delineated area of
magnetic source material and two excavations out of the area would be
sufficient to characterize the site would produce statistically valid
TABLE 41-1 RANDOMLY SELECTED EXCAVATION SITES TROY MILLS LANDFILL TROY NEW HAMPSHIRE
BASELINE RANDOM RANDOM EXCAVATION GRID SEGMENT STATION OFFSET
NUMBER COORDINATE (FEET) fFEET) (FEET)
1 7E+15 65N 0-60 26 16
2 9E+5 13S 60-120 110 9
3 8E+0 31S 120-180 140 7
4 4E+5 48S 180-240 230 26
5 3E+8 45S 240-300 254 20
6 OE+8 45S 300-360 394 50
7 2W+15 24N 360-420 465 14
8 5W+6 42N 420-480 518 20
9 6V+14 74N 480-540 548 7
10 8W+5110N 540-600 611 31
Locations are plotted on Map in Figure 30-1
data and could be expected to be completed within a scheduled 2-3 day
work period
42 FIELD WORK
Test pit excavation was conducted in two phases On the first
day each of the 10 random locations (Excavation 1 through 10 Figure
30-1) was probed to a depth of 2 feet using hand shovels On the
second and third days excavation was conducted using a combination of
hand shovelling and power backhoe The NAI field investigation team
consisted of six members Four of the team members were equipped to
work at Level B for work in and near the actual test pit excavation
(See Plate 42-1) The other two team members spent much of their time
with personnel and equipment decontamination and refilling compressed
air bottles at the hot line Mr Timothy W Drew an engineer of the
New Hampshire Bureau of Hazardous Waste Management was present during
most probing and excavation work Mr Robert Lynch an experienced
Level B equipment operator of Jet-Line Services Inc operated a power
backhoe which was provided by Troy Mills Inc
An average excavation size using the backhoe was approximately
7-feet wide and 10-feet long Excavation continued downward until drums
were encountered or to a minimum depth of five feet Drums were careshy
fully uncovered and fully described A total of 17 samples were
obtained from uncontainerized wastes (solids dried sludges pigments
stained soil) and where possible from drums using EPA sampling methods
and protocols All of the excavations were backfilled upon completion
of this task
Each sample consisted of one filled 8-ounce glass jar sealed
with a Teflon-lined lid Samples were submitted to Resource Analysts
Inc (RAI) Laboratory in Hampton Falls NH for priority pollutant
analysis
Air monitoring was conducted during each excavation using a
Foxboro Century Flame lonization Organic Vapor Analyzer (OVA) an HNU
Systems photo-ionization detector (HNU) and an MSA combined oxygen and
explosimeter High explosimeter measurements were considered cause for
an immediate halt in exploratory work in the interest of personnel
safety
10
50 RESULTS
51 GENERAL
On November 17 1983 Excavations 1 through 10 were initiated
using hand shovels to a depth of approximately two feet A total of
two buried drums were discovered Excavation 13 was completed and a
third partially buried drum uncovered On November 21 1983
Excavations 1 through 9 were completed and on November 23 1983
Excavations 7A 8A 10 11 12 and 14 were completed An additional
42 drums were uncovered on the last two days of excavation
Excavation Locations Seventeen test pit excavations were
completed at locations which are shown on Figure 30-1 Two pits were
excavated at three of the locations Noteworthy aspects of the
excavation operation are
Excavations 1 through 10 were randomly located in the area of delineated magnetic source material (on-anomaly)
One excavation connected Excavations 4 and 5 This was done because of the proximity of Excavations 4 and 5
Excavation 7A was located immediately adjacent to Excavation 7 Excavation 7 was located on the boundary line of the anomaly and proceeded in a southerly direction off the area of delineated magnetic source material (off-anomaly) Excavation 7A was initiated in the opposite direction (north on-anomaly)
Excavation 8A was initiated one foot north of Excavation 8 after the latter was abandoned due to the detection of a potentially explosive drum
Excavations 11 and 12 were selected off-anomaly to the north and south (respectively) in areas considered to be free of buried magnetic material (drums)
Excavation 13 involved minor hand shovelling necessary to uncover a partially buried drum located on the periphery of the anomaly at the east end of the landfill
11
Excavation 14 was a surface scrape which extended from an exposed drum found to the south of the magnetic anomaly northward toward the anomaly
The details of each excavation are presented in Table 52-1
Drum Locations The excavation results support the
interpretation of the magnetometer survey with buried drums as the
source of the magnetic anomaly With the exception of a few strands of
wire found in Excavation 1 ferromagnetic materials other than drums
were not encountered during the test pit excavations
Drums were foundin 9 of the 10 excavations located in the
area of delineated magnetic source material (See Plate 51-1) No drums
were found in Excavations 11 and 12 located out of the area of
delineated magnetic source materials The location point for Excavation
7 was on the boundary of the anomaly Excavation 7 which proceeded
south away from the area of source materials was free of drums
Excavation 7A proceeding north toward the area of magnetic source
materials uncovered 6 drums Excavation 14 located just out of the
delineated area to the south produced unexpected results Five drums
were uncovered just under the surface in an area with low positive to
slightly negative total magnetic field values It is possible that
Excavation 14 was improperly located in the field If adjusted just 20
feet to the east it would be well into the delineated area It is also
possible that a negative dipole derived from the mass of material to the
southeast is cancelling positive readings at this location
Fill Material and Vegetation Cover and fill material was
predominantly fine to medium sand with an occasional boulder Till with
a siltclay component was also used as a cover particularly at
Excavations 6 and 7A This material was densely compacted and difficult
to dig through Excavations 7 11 and 12 each extending to a minimum
depth of 5 feet were characterized by uniform silt and fine to medium
sand and traces of dark discoloration Excavation 12 was located in
to a s
to LJ imdash O z
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o u L t ij-3 o agt w gt Xre JJ o c iomdash o
o
mdashra
mdashL-03AJreE
L03gtoo
E O i-it
mdash Slt J rn shy
mdash tfl 0) gtre tt)N
^ mdash -jj a -C TJ E CD mdashc re c
mdash o tgt~ mdash CD
mdash C bullmdash U SI bull-gtCOES 03gtO0
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bullD
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Imdashmdash
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1--30Z 4Jr e r e shyw E JJ
in O jj 01 o i-
i- agt n c i shy -mdash O gt E lA
O 0 (13 AJ O O X C es uJ o N
mdash mdash JT Ol t-
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bull3 lt 0 3 N
bullmdash V c t C3 mdash a C S bull U r o
CO shygt bullA ^ mdash bull o
o - C Z
X =mdash Z O
mdash C 3 r e O -Z Z pound bullmdash re-JOlaquo C r e X
C c c gt r eC O r e J raquoZ o u r e X
mdash in X mdashl -CS-U fOCO
CJ EE lt- ~~ O
C T3 shy lt 0 t i re^ltmdash raquotrade-^t
mdash 3 O - C i C 3 mdashbull
^ v a c E gt = E mdash _gt re C J pound o y 5 O
rez O C3 - C
bdquo
O (T shyg shy =c _) 2 shyo mdash o
Q3 ^D 1- mdash C bullmdash mdash shy3 t = s ~amp lt Z ^ C N
c o r e mdash mdash c bull mdash o mdash bull _ mdash X 3 C c
mdash C T D O lt C o c o mdash gt mdash laquoomdash
JJpound J c
o
xo obullo w c-i-C C i-re o re O CO shy3 0 J
XbullOCcoW
t- 0) shygt bull tfl bull = B E 3 laquo Obull
3 mdashraquo O W i- o re c re a bull- shy 3 gt
XbullOCreVI
Q t-
03 pound mdash U
0 L- (8
X a s ar e gt Emdash COC i O O
mdash gt shyc laquo- O raquo bull t- mdash CO
X c - gt c c i shy r e w O t r e
mdash re X i- - z ^E l - IC C3O
Z cJ Xt E J r mdash o in trade re ^ cc U pound -gt
^ mdashJ O ^ 11 CSLJ - gt ^ c olt- c umdash C CT-3 O B 3= mdashmdash z - ^r mdash c = s J
mdash laquo f j 3 -3mdash O
pound mdash z = J 3 3 S O laquo
s re -re mdashmdash ~mdash gt
cO t 3 r e C - ^ laquo gtC ltshy O gt mdash Z CD o c re mdash rei 3 u
O C S li = i U) x^shy mdash x x r z r e JO w L J C ^ 3 i
mdashi
a
IS shyJmdash _jii) OS
aa I i
a 1 1
a 1 1 O
a
z CC w ^ 1raquo oo o o
CM o o
zx
o
ltamdashZLraquo
pound a o
^ 3 Z
Q a mdash mdash
o rmdash IA
i 0
QoOIA
a mdash
lA r~ r~
a mdash o CO
amdashoCOttrade
Q o o
laquobull
O
o o 1mdash
i ia o o lA
i
Z mdash m
CO CO
h_
0^zmdash
^
S c-c_ 1_
0 a mdash mdash 0
o O ro mdash 1
O O
0o CM1
a mdash
O O
Q
O O
1
o mdash
oO-
Q o o
lA 1
Q _
o o
1
WO
O
Q O
lA 1
gt o
0 o
O0
CM O lA
v o3- V
CM
CM r ~ CM
mdash =^ a
S 5^ 0lt r ~ ~
1 1 1 a- lA
a o
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O
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1 mdash a z ZO o mdash Ui-
raquo o
a laquo
Lu
raquomdash lt^
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laquo fcCC
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r-CM
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mdash K ^
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cs shyo L ^ t-oshy0 ~ CMr-
J c~1
Vi UuL
laquof~
u o bullmdash mdash
bull- t-
^ LL ^
K f- Ci bull-bull
shy shyU LJ LJ
rr shyo laquot- t_
O ^~ O c
CM Q
mdash c-Omdash
^
^V f-
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fc ^ aa L 1_ ou C- C
1
w
0
X L
raquo( CC-mdash
LJ
O
lA
_
0 1
^v U
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mdash
Z o to
ltr s _3 OK
CVJ CM ro
raquo~
j CM VO
ro bull-CM
ro 1 VO laquomdash
z o
r-Q
I C
o X UJ
poundo| s~a
a CM CVI CVJ fO lA CM 1 lA lt-
a o
o mdash LJ o raquomdash L
lt ^^ gt lt UJ C N X mdash _ in
o X o X CO
f)XCOXr-
X CM
bull-X ot^
ro X ^y X O rmdash
rXlAXOv
CM X
00 X
CM V
ro X ~
0
lAX roX o
mdashX
00X
o
r-X
^3 X^
z C o
lt a
lt 5 rmdash fl ro ^ -~
I O C- 83 ^ ~
lt gt- CO
X
0 O
13
E
23
eo ETC CU
gt i- Nlt (_ mdash
E O i-
lt~o ON dgt
N Q) mdash
i-tt) gtOO
bullDC
gt 0) C
T3 O
-D C CD
tgt
-U mdash mdash
C5
E 33
E-0 gtgts-O CD mdash T3 1- N JO ( =
0 0 U - O C5 t- t-ushy ro L jj bull
3 C 0 gtgt cnmdash 4J mdash
bullD CD bull C E E
I t -
lt Q 0)eo i c
lt mdash
mdash L
aagt E C CO mdash
CO i-W CO
bull obullDmdash 0
gtgt mdash
re bull E bulllt-gt
gtgt mdash
CD bull E-0
L W O lt tu en i-fgt c O Q
gtgt0 3 O mdash 4-gt i C
CD X -o eo E 0
w co CD bullO 4J COmdash ^ C d)CO O ^E 1 O W
co eo 4J bull
bull C CU ^ O ^
C O W
c eo Qeo mdash eo
t-JJ 0 E
o mdash c mdash
eo w
D C c eo CD laquo)
CO T3 0 4J Q) - C 0 mdash CO gt mdash E O w mdash
O 01shyC CU O O CD aw
CD O CO u- sshy amdash
re lt c eo cc c CD mdash CD 1- ltshy C C_ C re c co o - O X X CO CO3 gt CO 3 gt to E O O co O co CO 3 jt w O cfl 0) eo
cr LJ
LJ-J u mdash j CO 0amp5
a O 1 O
Q
1 1 i l
CD Dl bulla
CO _ mdash O D o
O ^ (A
ZX mdash Ld
O
en 3 10 O a
LJa a
Q 1 1 O
Q
+
O
X
_
mdash
o o I
gtgt O
h~Z
-^ 3
o0
mdash i-
1A 1
a a co agt C
LJ
sectK
Z= tM O 0 to bullo
X
mdashshyo
CD O
o mdash _ o
E umdash 3 E eo sshy
ltr-toZmdash
mdash s
0shy c
^
^ gt o
D o
a-rmdash
1
Q-
0 0oo r-V
tO 0
= mdash
O
tO 0
= mdash
O
Q O
O r-i O NO
1
awi
i mdash _ 3
Imdash I O
bullO C
1- 3 gt 0) bullo sshy co w
bullO CJ ID O X E C CU tt) bullw^ T3
w agt u C pound -gt
a a CO CD
mdash L 4J CD o gt
T3 gt C CO UJtt
2 mdash1 LJ Z) d CO 1 1
COO
~
lt O
~ I 1 1 I
Dl C 10 3 -D
lt - T J O
Dl C
1gt Omdash O bulllaquo Xl- i s o cu
Q lt3 toz cshy
mdash W f
r-B O c
mdashgtgt3 01O O u
W ID CO bullgt C -O mdash 4-gt 4-gt C
O -x mdash1 CO o CU c c co
1
OZ ZO o mdash Ol-
LJ -
L
0
1
C- bull 14 u- o laquoc~
bull mdash u bullDT3 O laquoccce tshy ^ D
l_ Cshy CCO O 0 0-0 Qmdash
CJ I- r-CM
1 1
U-Qshy
bull bullbull ^
O t_ 0 Q
-LJ
raquol
a o iT o c o
U) c
c u CD O
I I I CU c
Q) CJ CU W a ltshyon J2 o l- E E gt QCO CD O
I I I
ID JJ CU ES
J-gt imdash O Q Z CO w t --shy O mdash O 3 O laquoshy ^ c
_ICO a 0 0 0
^ sect5oa I-Q
CO X u_ y o- o=gtLJt-a
3shy
^
1
1
VO
m
1
i
1
t
_
3 lta i- U) 0 0
a
lA
lAbull
0 O
JI E oj3 gt E re mdash O X X co Qj
C 1 O
W 3
U L CO O
4J CO
0mdash CCD gt j ti --shy c JJ 4J
1- laquo 3 = C 3 or cu ogt tn Q -shy
E L n CD J-gt o o gt gt s o ---shyDior 3 3
mdash Tgt o cr cr mdash mdash CU 0)
o a CD -a OLJ U CU
N CU COT 4JT3 poundmdash 0gt U V
raquoT3 mdash agt OJ gtgtcu laquo c c
T3 O
C
C
Zlshyo ui u- Li ^ ^~bullgt lt LJ
lAXvOX
VO X ^ X
Xcjltshy
lA x
CM
O x
3shy
_ X
r^5 X
_ X
CM X
mdash c^ C3 O
c a bullbull o c c
mdash 4J O I I 4J
01 JJ 4J 1C laquo
3 t- C raquoJ O L (D CU C mdash o a~o mdash o
i i
C J J W CO II) O W IT OC N 03 = OJJ C O I- -= C O
I I
o o
ON X mdash
CMr-raquo
00 Orshy
X CO
vo ro O C 5) JJ Jshy I- I gtJZ-00 s a o
LJ CO eo UTJ a- I I O C X J O gtZ 1 re O
i CM
LA
LJ
O mdash c imdash LJ lt a gt y lt 2
ltCO O
O^mdash
laquoshy rmdash
CM Tmdash
n rmdash
_^jshymdash CO
LJ
j ^ |
52
14
what appeared to be natural materials although its location on the
cleared and leveled landfill tend to contradict this possibility
Most of the landfill is vegetated by a thin layer of grasses
sedges mosses and annual herbaceous species The northeast corner of
the landfill is unvegetated and cover material appears to have been more
recently applied This section is elevated 4 to 6 feet above the rest
of the landfill and appears to have received a second newer layer of
waste A 4-foot thick layer of carpet waste was encountered in
Excavation 1 but not in other excavations This section is adjacent to
the newer active landfill The landfill area just west of the access
road crossing (near Excavations 7A 8 and 8A) was also unvegetated due
to relatively recent grading operations
Ground Water The landfill appears well drained as ground
water was not encountered during any of the excavations Excavated
overburden was damp from the recent heavy rain but intergranular macro
pore spaces were free of water
OBSERVED QUANTITY AND CHARACTER OF DRUMS
A total of 45 drums were observed buried in the landfill
Table 52-1 presents a drum log describing each excavation and the
observed drums Data on the contents and condition of drums is
summarized in Table 52-2
Of the total drums observed 15 (33) were crushed flat
Although these could possibly still contain small amounts of waste they
are probably considered empty under RCRA guidelines Thirty (67) of
the total drums discovered were uncrushed and capable of containing
waste Seven (88) of the 8 drums sampled contained liquid or sludge
waste material Thus at least 7 (23) of the uncrushed drums contained
some liquid or sludge waste
15
en C Cl
bullo gtraquormdash
c mdash a
o c re bull mdash c
~ o mdashbull 4Jmdash
10 0 mdash
gt O
ro CO
fcshy0
c
C
vgt 3 0
1 rea
-gt
mdash
3 o T3
lt-O
C j C
CB 3 TJ ii i- 3 mdashQCOa
ifl u bull c c
t_ o
mdash shyO
mdash
L re N
co
t-O
mdash
mdash lfl
V) O
CO N CO pound re
0 mdash
^1 10
ltP O C raquo
CM reO
o f shyi O
mdash mdash 3 - D
c 1
CD bulllaquo
mdash3
D mdash
1 C
Q CO
CD Ifl 4-gt CO
Q
CM
r-
Ul
Q Ul gt EC Ul CJ CO o t5bullpound
z O mdash
C Ci o^
O Cbulla 3v iC MW5 CO 4J3 u CS- Ifl CBC J C O - U
gt Cgt Omdash Oi O
U- 0) Ifl bullgt-gt 1 W C
to lt-gtT3 gtmdash
0) gt shyJ 0)
C OltJ bull O T 3 C D C P
133mdash 4J bull ifl tshy Vgt~ V a O V4JJ
C o
C mdash
O Ifl
3 fc 0)
i-
c
U) re gt
ai C mdash
C mdash
CO gt c o
bull to y 3 cc Q
ltbull-CB
1 4Jin
bullD reCD jCJJC TJCD mdashbullD bull mdash
CD 0t- u iflo ifl
0 C ^-
CB laquo
3 ltbull-
0)^shy
C
0 Cgt O
1 O CTl C
T3 1 mdash CB O
mdash CB mdash in J o 3 tfl C ^ CO 0 gtltgtshy
O gtgtc 01
CO 3 1- mdash C Cregtmdash laquo
TJ W TJ mdash i re traquo-
shyU mdash
O Q
COCO^^
mdash ^
mdash gt C 0gt mdashO ~ bull
Ul
o auO
CCUl
mdash K o tO Ul Q
mdash OT30Jj c mdash4Jt- Jpound O Wre c i re03 gt
lt~i- laquo o ai
0 ) 3 gt O ^crc Ifl - CO -^mdash
3 mdash Q iflmdash 1- O 3 3
O V O ltraquo-o laquoTJ
gt
T3 - o
gtgtmdash J-gtmdash
Dmdash
6-o
09 bull mdash gtpoundbulllt-gt
re a
Ul X t5
Cpound O Z
fl) mdash^ C B gttflOl3T3T3l_ 3 Q)O mdash mdash
tn mdash
shyD CB
mdash mdash
mdash tt
CO C T3 poundi mdash JCmdash re
^ C O C X CB ^ - S - C C O mdash re O Q DW4shy
re shyu O 1
O Ul X EC Ul mdash
x a^s ox
CO
^) Z
J
1-o t-Ul X r-u 0
o j c gt T3 i -gt c tu mdash c u r e mdash
- C D mdash T3 - C M mdashbullOJJQmdash re3inecrec u c r e o mdash lt~ bullz c~4J O CX t ^Jw o r e -gtgtOgtgtshy3 c j t shy re mdash mdash ret- i o Qmdash gtgtpoundgt a
i reraquo CD 0) bullbull Ifl t-
Q ) t ) O pound O ^ laquo gt - Ow re re ro re re -gt Q mdashc 5 shyu a j-gt D t- raquomdash mdashCB C re C CO 3Q mdash O mdash O U
Htshy ae cu coo)
1 O i i
shya shyo j CD C bullgt o mdash c o c o coco mdash plusmngt o ~a v c en CD
mdash C O
raquoCJ 3C c re amp- ogtCD J o 3 CC C I-Omdash 3gt O
3
O ro
Ul X 1mdash
u O
Ul o r-Z Ul
gtV~ omdash Dlshy ^mdash mdash wre3 i cc
mdash cr bull gtJJ mdash C mdashi QIgtJ^re a shyJQI- o 0mdash
O bullO 3laquo laquo
jjmdash ureoO mdash O N 0)rc3recomdash4Jt-4JpoundmdashC C mdashmdash mdash u
1
shya 0 -
mdash gtgt re-raquo-gt CUD laquo E CD
^ J-1
CJ eoc
4JCB CO
mdash O
C 1- C mdash O C B C B C E J mdash J ltshy shyo cn o o c o r e c shyU -gtO OJC D ifl roc
T3 3 I U 3 laquo-
Ifl CD 1 W ^J 4 J 4 J c -aiflj jc
CB C r e O C B lt-gt -Jgtcoraquo C C -WE O O ) ~ O O O mdash O
Ul O
c ui =gt z
o
1-CC Ul Q
Q z ^ Ul
2 gt Ul O
o Cpound
^ CO
Ul Q ^
z o
(O U S Q
Slt
t5 lt
Z5O
1mdash z ui
Qa Ul
CD 0-1
u m O_J
O2^ltUl
O CC Ul Q
VOCO
CNlA |3
VO ^
CJ |CO |
CJ CMI3 f~ rojO VO rolo
^
ymdash3 CC
roCM
ro O ICNj
ro rolvO ro ro
ro A
rolvO r-jO
00 C3N
ec a m
r3
CO
3 a ty r-
cc Q
(M CM
to z
m 3 c O
u _i co
U-O
O 3-IObull - I c y
fshy lt- ICO r- r-ICM O U lfN ro -mdashla1 f~ laquo- ]CO bull- -ICM O O J|O O
c U) CO
mdashbullre re
mdash re
mdash i ltC c tz
j lt
i lt
5 0 0 G O o o o o z bullU 4J J h- J shyJ tmdash tmdash
^33
J3 3
O 3
Q 3
_Cr(bull
shyC 3 t)
CC IP y
C2 zgt c J
1mdash O 5
53
16
The condition of the uncrushed drums was highly variable with
only 4 (13) rusted and decomposed to the point of structural weakness
These drums were found in Excavation 10 at the far west end of the
landfill which is believed to be the oldest section (See Plate 52-1)
Interestingly two almost new looking drums were also found in
Excavation 10 at a greater depth than the four rusted drums The
remaining 26 drums were observed to be generally intact and structurally
sound Some were dented partially crushed or rusty
CHARACTER OF WASTES
Air Monitoring An OVA and HNU were used to monitor the air
for concentrations of organic vapors during each excavation Above
background instrument readings indicative of contamination were
regularly recorded when monitoring the air just above or inside of
drums A general contamination of the ambient air in the workspace was
noted only during Excavation 8A where above background readings of +13
in the excavation pit and of +6 above the excavation pit were recorded
Explosimeter readings were obtained from three drums -- 10 lower
explosive limit (LEL) from drum sample 10A 20 LEL from drum sample 6B
and 100 LEL from a drum in Excavation 8 Instrument readings are
presented in Table 52-1 and Table 53-1
Visual Observations The following types of waste were
observed during the excavations
fabric waste (carpet waste)
crushed drums
drummed waste - liquid sludge and solid
uncontainerized dried sludges and pigments
stained soils
Fabric waste scraps of synthetic non-woven fabrics5 heavy
carpet-like fabric and backing material were found only in Excavation
17
CM
CO LJ fmdash O z
laquo 4J
u TO 4-gt
c bullmdash
k bull mdash E mdash 3 3 i-^ O
mdash TJ --raquo co co 4J
E CO O U L U
E 3 c T3
C O a o
is
CO c to 3
U
TO
E O t_ U_
o o
1 ltmdash c
mdash tmdash TO 4J bull C TO 0 O o c u 3 TO
t_ 0) 0 4J
U)
mdashOTOgt
Cw bull aco jc
N 4J a
mdash L Q) re co T E
CO
bullo gt egt mdash c mdash bull o ^^73 C E gtO O mdash 3 J-gtmdash N 4J L 3 mdash 1--C gttTC bull
CX 01C JJ TO O mdash
TO trt mdash t- E mdash 3 JJ a O Q
C I 0 X E mdash C mdash CO
mdash o laquo (D-O mdash O O bullbull B Ol o -cmdash e oic f~ to a (gt TD mdash
E 1- Cpoundmdash 3 O O CO P m T1
L u
T3 CO
lto sshy0 O CA W
laquoT3 O CO 0 C J= CO tlaquo Q bull 3 O Ol 1- C o mdash 3 E a
3 E E i- to
Z L
mdash bull mdash O 4-3 Cl Q
bullD 0) CO T5 N CO mdash C -P 1 0 U TO O mdash 4J Cfc
mdash U) c shybullgt O w C O Q (5 4J 0
3 -J bull U)
5 gt TO_ U
bull gt pound mdash 3 mdash L ro TD
JJ-D - CO TO laquo QO
C 0
^ 0) T3 mdash O
r to 3
O O L L
0
01 TO gt bull
tshy mdash OT3 mdash
CD O C N U) O mdash
TO O CO mdash C C
bull^ ~ CO TO TO gt U iJ
mdash C W to O
5 c c 4J 3 CO X LJ
^ bull bull0 laquolt- ej
TO CJ CO mdash C JJ
z u to mdash T3 4J ai TO CD C laquo bull c c ugt o cr 0) bull mdash CO mdash O bull gt JC TO ^ mdash Q CO O JJ O Q bull- CO to mdash to c Z CC O il mdash 4J gt
mdash Omdash O1O CD mdash U) TO C X mdash O CO C L mdash Cvv O W pound G CO C C
O gtgtgt C C mdash CO C TO CO 3 E mdash -J laquo 1- bullgt CO 0 to
bullo CO
cshyo bull
ugt C CO TO c w 4J-Q co e a c
mdash re TO in E to
Q
JJ c bullo
a LJ co E bull LJLJ
O mdash zx ZQ
ax
z o mdash1mdash Q
mdasha o CO LJ a LJ ~J
s CO
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bullmdash
^ 4J bull
bullO bullmdash
gtgt3 TO CT L mdash Olmdash 1 O CD mdash 3 a CT cshy re 3 a c- o
^j C CO E Ol
bullmdash CL
bull CO 01 D 3
U
T O a
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bullmdash av^ CO 4J IA TO 5
T3 CO C
bullD
mdash mdash O CO
3 CT
bullmdash ^
bulla CO L
4J
C CO o 3
(A C TO
Imdash
03
ai_ 3 a bullo bull mdash 05 3 O) 00
mdash mdash C c gtgt G CO
O O
bullo^ = c a 0)
E C O umdash u a L_ bull OlCD mdash
4J mdash
u) obulla o u) amp 5 c -a 7 O C mdash o mdash _ i- (0
CO E laquoJ
C
a
bulla c bull o bull
c bullQ CO
3 01
CT mdash mdash a mdash -v
t- Ol CC-D 0) 3
CJ raquo
x^ CO
bullo 3
lt) bull_
gtraquomdash CO O 1- Ui O)
bulla ^ c mdash mdash mdash TO co in
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mdash TO
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c mdash
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TO
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Q mdash
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I 1 1 i
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rshyC5 Z
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a mdash o o T~
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f ro
CO X
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mdash O o o rmdash A
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f
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if
LJ
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tmdash CM CM ^_ CM
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ui o -1 LJ
i mdash lt sectco z 1
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18
bull -a gtgt CD
CO S jj
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bullo CD jJ
bullo z 3 O L
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CD 1-gt o CO
jpound cshy x mdash o mdash
- 0 1 mdash bshy
4J 1 CO
Z u
CO mdash T3 CD CD
co E C mdash z bullD 73 4J O JZ = CD ltshyO C CD
CD 4J laquomdash C
bullO Qmdash U N ET3 bull mdash 0 Cmdash i- L re mdash oltmdash o
O 1 f-u gt Z 03 shy3 mdash CD
O O tshyo
O (Q C N O mdash shy
o agt O 4-raquo bull z in jz 3 CO 4-gt
gt Q ltshy 0
CD JZ N w Oshy- O
laquo ^ mdash 13 mdash m
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z s_ mdash
laquo
laquo CO T3 0 bull E in 3 3 1-L ^3
-TJ
re 3 O L
CD U -D SshyCD CO CO N 0) mdash 0-E S GO CD CO L
i
CO UJ gtmdash
z laquo w mdash ffl JZ CO 4-gt 4J JZ
4_) t_ mdash bull
cz QJ co jZ C C mdash 4J
re (uS a z z
OX) mdash a) O W E
Z O O JZ bull CL V E
C (~ mdash r re O CD
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19
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20
1 (See Plate 53-1) This is the predominant waste material currently
being disposed of in the active landfill
Crushed drums were distributed throughout the original
landfill and were found in Excavations 2 4 4-5 7A 8A and 14 Some
drums such as those found under the road in Excavation 7A may have
been crushed by heavy equipment operating in the landfill Others like
those found at depth in sandy fill in Excavation 2 appear to have been
crushed before burial Drummed liquid and sludge wastes are also
distributed throughout the landfill (See Plate 53-2) They were found
in Excavations 1 4 5 6 8 and 10 These wastes are discussed below
One sealed drum was openedand found filled with refuse -- paper cups
towels paint covered rags etc One open and partially crushed drum
contained a dark granular solid waste This material was sampled
(Sample 10B) and found to be nonhazardous
Small deposits of dried pigmentsludge were found in
Excavations 3 4 6 9 and 13 Discernible layers of pigmentsludge and
stained soils were present in Excavations 7A 8 and 8A (See Plate
53-3) Of particular note was a 2 to 4-inch thick layer of
grey-colored dried sludge found at Excavations 7A and 8 All of these
wastes were sampled and the results are discussed below
Laboratory Analyses
Laboratory analyses were performed on 10 selected samples
obtained from both containerized (drummed) and uncontainerized wastes
Samples were analysed for 3 metals and 87 priority pollutants including
11 acid compounds 45 baseneutral compounds and 31 volatile organic
compounds Table 5-4 summarizes the analytical results and the
laboratory data sheets are presented in Appendix D
Of the 45 priority pollutant baseneutral compounds only 4
were identified in the samples that were analyzed Baseneutral
21
compounds and particularly phthalates were the most prevalent
chemicals and also were reported in the greatest concentrations The
highest levels of naphthalene (1200 ppm) bis (2-ethylhexyl) phthalate
(110000 ppm) and di-n-octyl phthalate (6200 ppm) were found in sample
4A a translucent red liquid obtained from a drum The highest
concentration of benzyl butyl phthalate (13000 ppm) was found in sample
6B a clear liquid and pink sludgepigment obtained from a drum
A total of 8 volatile organic compounds were identified The
highest levels of benzene (100 ppm) xylenes (19000 ppm) and
ethylbenzene (5300 ppm) were found in sample 5A a clear liquid
purple-grey sludge obtained from a drum Toluene was found in highest
concentration (12000 ppm) in sample 1A a purple-grey thick opaque
liquid obtained from a drum Methylene chloride (13 ppm) was
identified in greatest concentration in sample 8A-C a purple stained
soil and powdery waste Sample 10A a purple liquid obtained from a
drum was the only sample found to contain 1-1 dichloroethane (2000
ppm) Finally trace levels of trichloroethylene (sample 10A) and
111-trichloroethane (sample IB) were also reported
Samples were tested for three metals - cadmium zinc and
chromium The highest concentrations of cadmium (2200 ppm) and zinc
(5700 ppm) were found in sample 4A a translucent red liquid obtained
from a drum The highest level of chromium (52 ppm) was reported in
sample 5A a clear liquidpurple-grey sludge obtained from a drum
22
60 DISCUSSION
61 EXISTING SITUATION
Under existing conditions relatively small quantities of
volatile organic compounds (VOC) are indicated to be leaking from wastes
buried on the landfill site To date ground and surface water
monitoring results indicate relatively low concentrations of VOC in the
ground water and below detection limits in the adjacent brook (See
Tables 61-1 to 61-10) The results indicate that no potential health
risks from VOC and other constituents currently under observation are
being caused by the landfill operation to down stream surface water
users It would be prudent for Troy Mills to continue to monitor the
quality of Rockwood Brook upstream and downstream for VOC and on the
basis of waste analyses (previous section) to monitor ground and
surface water points for toxic metals and baseneutral compounds
62 SITE HYDROLOGY
An analysis of the hydrology of the landfill site was
performed in 1982 (NAI report of September 1982) The subwatershed that
contains the landfill site is (about 44 acres) a small fraction of the
watershed area that contributes to Rockwood Brook above surface water
sampling point C (about 1650 acres see Figure 62-1) This indicates
that most of the flow of the brook at point C (about 97) is contributed
by upstream watershed areas Thus leachate discharging into Rockwood
Brook from the landfill site can be expected to be diluted by over 30
times its volume This factor and the volatilization which naturally
occurs results in parameters detected in the Troy Mills monitoring
wells often becoming undetectable when they enter the brook
f 5
Geologic conditions which were defined in the NAI report of
July 1982 indicate that permeable deposits of sand and gravel overlie
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27
TABLE 61-5 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M5 (UPGRADIENT WELL)
Parameter Date Sampled 11-22-83
Specific conductance
pH2 81
Dissolved iron mg1 036
Dissolved manganese mg1 010
Chloride mg1 10
Phenolics mg1
3
023
Identified volatile organics
None identified ND
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (yg1)
28
TABLE 61-6 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M6
Parameter
Specific conductance
PH2
Dissolved iron mg1
Dissolved manganese mg1
Chloride mg1
Phenolies mg1
Identified volatile organics
11-dichloroethane tetrachloroethylene 111-trichloroethane
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vg1)
Date Sampled 11-22-83
152
lt002
29
6
0002
27 trace 140
29
TABLE 61-7 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M7
Parameter Date Sampled 11-22-83
1 47 Specific conductance
pH2 62
Dissolved iron mg1 002
Dissolved manganese mg1 0026
Chloride mg1 gt2
Phenolics mg1 0070
3 Identified volatile organics
111-trichloroethane 5
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vig1)
30
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34
glacial till and bedrock The sand and gravel deposits form a permeable
conduit through which leachate from the waste burial areas migrates
The permeable deposits lie in the area north of monitoring well M-l (See
Figure 62-1) In general the water saturated thickness of the sand
and gravel in the vicinity of the north-south access road is 6 to 12
feet
64 POTENTIAL FOR GROUND WATER CONTAMINATION
641 Estimated Quantity of Drums
The test pit excavation and sampling in the drum burial area
indicates a potential source of ground water contamination for the
future Many of the drums encountered were in fair to good condition
and contained liquid wastes An estimate of the number of drums in the
deposit was made with the following assumptions
1 The complex magnetic anomaly was simplified into a geometric solid 600 feet long 40 feet wide and 10 feet deep with a volume (V) of 240000 cubic feet
2 Each steel drum (D) occupies 105 cubic feet (including voids)
3 The density of packing (P) was assumed to be 50 of the packing that can be achieved with perfect cubic packing
THEN
N = estimated number of steel drums
N = (VD) (P)
N = (240000105) (05)
N = 11429 drums
The results of the drum excavation work provides a basis for
estimating the potential for specific types of chemical loading In
general three main classes of chemical substances were identified in
35
the drums The chemical substances included baseneutral extractable
organic compounds (mostly phthalates and lesser amounts of naphthalene)
volatile organic chemicals and metals
642 Phthalates
The phthalate esters found in the drums include
bis (2-ethylhexyl) phthalate ^0^3 benzyl butyl phthalate di-n-octyl phthalate Jd~7
Bis (2-ethylhexyl) phthalate was found in the highest
concentration at 110000 ppm (11 percent) Benzyl butyl phthalate is at
the second highest concentration 13000 ppm (13 percent)
Characteristics of those phthalates found are presented in Table 64-1
TABLE 64-1 PHYSICAL PROPERTIES OF PHTHALATE ESTERSshy
di-n-octyl bis (2-ethylhexyl) butyl benzyl DOP DEHP BBP
ALTERNATE o-Benzenedishy di (2-ethylhexyl) benzyl butyl NAMES carboxylic phthalate phthalate
Molecular Weight 3910 3910 312
Melting Point -25degC -50degC -35degC
Boiling Point 220degC 386 9degC 377degC
Vapor Pressure-mdash lt02 torr (150degC) lt001 torr (20degC)
Not
2xlO~7torr (20degC) Available
Solubility 3 rngfc (25degC) 04 mgfc (25degC)
58
13 rngH 48
Log octanolwater 92 873 58 partition coefficient 53 48
Versar Inc 1979 Water-Related Fate of 129 Priority Pollutants Volume II Prepared for US Environmental Protection Agency PBSO-20438 December
bullbullOther names listed in Versar 1979 vMore than one value has been calculatedreported
36
Bis (2-ethylhexyl) phthalate is the most well-studied of the
phthalate esters though the information on phthalate esters as a group
is limited The three phthalates identified at the Troy Mills site have
relatively low solubilities and are readily adsorbed onto suspended
particulates Microbial degradation is effective under aerobic
conditions bur is generally slower under anaerobic conditions
(nonexistent for bis (2-ethylhexyl) phthalate)
The above characteristics are important for two reasons One
the extent and nature of contaminant migration from the site are
dependent upon the physical characteristics Second the treatment
(clean-up) alternatives for contaminated ground water or soil can be
estimated from the characteristics
From the available information it appears that the phthalates
present at the Troy Mills site would be relatively immobile due to their
low solubilities and high adsorption rates The presence of toluene and
methylene chloride at the site however may increase the phthalates rate
of migration
It is important to note that none of the phthalates have been
found to be present in the monitoring wells nor in the surface water
sampled probably due to the low solubility and high adsorption rate
37
643 Napthalene u K r
Naphthalene has also been found in significant quantities in
the sampled drums Naphthalene is a polycyclic aromatic hydrocarbon and
has the following properties
Molecular Weight 12819
Melting Point 8055
Vapor Pressure (20degC) 00492 torr
Solubility in Water (25degC) 344 mgfc
317 mgfc
Log octanolwater partition coefficient 337
Versar 1979
Naphthalene has mid-range adsorption rates and solubility It is
therefore inferred that there would be some adsorption to soils in a
ground water environment It is important to note that naphthalene has
not been detected to date at the monitoring wells or the surface water
sampling locations This is expected to be a result of adsorption on
the soils
644 Volatile Organic Compounds
Volatile organic compounds tend to migrate readily within
soils and ground water They are therefore considered a threat to
surrounding ground and surface waters if they are released in sufficient
quantities
Volatile organic compounds were detected in samples from six
steel drums The total volatile organic (TVO) concentrations in the
38
wastes ranged from 9 ppm to 30100 ppm and averaged 8570 ppm In order
to determine the potential for future contamination by volatile organic
compounds an estimate of waste quantity based on information from the
drum excavation program was made It was assumed that 7000 steel drums
in the deposit are 60 full of liquid waste with an average TVO
concentration of 8570 ppm The computed volume of liquid waste is
231000 gallons with an average TVO concentration of 8570 ppm This is
equivalent to about 1980 gallons of pure TVO
Two of the volatile organic compounds that have been most
prevalent in the existing ground water monitoring system are
111-trichloroethane and ethylbenzene The EPA suggested no adverse
response level (SNARL) for 111-trichloroethane is 330 ugpound for
1 day of exposure and 35 jigd for exposure over a life-time in
drinking water
In general ethylbenzene is a prevalent chemical in the
environment Sources include commercial (eg petroleum and petroleum
by-products) motor vehicle exhaust and cigarette smoke An intake of
16 mgday (1 mgfc) has been calculated as an acceptable rate to
protect from toxic effects Carcinogenic effects have not been
identified to date The physical properties of ethylbenzene are
presented in Table 64-2 The principal mechanism for removal of
ethylbenzene from water is volatilization In addition to
volatilization adsorption may also be an important removal mechanism
based on the log octanolwater coefficient This factor is important in
evaluating the migration of ethylbenzene from the disposal site
Toluene which was also identified in waste and ground water
samples exhibits properties similar to ethylbenzene in that it
volatilizes easily Toluene which is also referred to as methylbenzene
is distinguished from benzene by the substitution of a methyl group for
one hydrogen atom Physical properties of it are presented in Table
39
64-2 The EPA suggested no adverse response level (SNARL) for toluene
is 1 mgpound in drinking water with a maximum exposure time of ten
days
TABLE 64-2 PHYSICAL PROPERTIES OF ETHYLBENZENE AND TOLUENE
ETHYLBENZENE TOLUENE
Molecular Weight 10616 9213
Melting Point -949degC -950degC
Boiling Point 1362degC 1106degC
Vapor Pressure at 20degC 7 torr 287 torr
Solubility in water at 20degC 152 mg2 5348 mgd
Log OctanolWater Partition Coefficient 315 269
645 Metals
One liquid sample contained high concentrations of cadmium
(2200 mgd) and zinc (5700 mgd) indicating that the waste deposit is
also a potential source of certain toxic metals Tests for these metals
have not been made to-date in ground or surface water samples It would
be prudent to add toxic metals such as cadmium chromium lead and
mercury to the list of parameters that are being monitored to further
characterize the quality of adjacent ground and surface waters US
EPA and New Hampshire drinking water standards for these metals are
cadmium 01 mgd chromium 05 mgpound lead 05 mgd mercury 002
mgd Although zinc is not considered a highly toxic metal the
US EPA has set a secondary drinking water maximum contaminant level of
5 mgd on this metal
40
70 CONCLUSIONS
The following conclusions were drawn during this
investigation
1 A steep-gradient irregular-shaped magnetic anomaly is present under closed and covered portions of the south part of the Troy Mills landfill
2 The magnetic anomaly is caused mostly by an irregular-shaped accumulation of disposed steel drums
3 In a randomly conducted sampling of drums in the source area for the magnetic anomaly 16 of the drums contained liquid andor sludge 33 were crushed flat and 51 were not sampled because there were no accessible openings
4 Laboratory analyses indicate that the random waste sampling contained significant concentrations of several volatile organic chemicals several baseneutral priority pollutants and high levels of cadmium and zinc
5 Observed concentrations of volatile organics at the monitoring wells are relatively low Because of their potential for migration in the ground water continued monitoring of volatile organics will be required
6 Volatile organic chemicals have not been detected in Rockwood Brook to-date Because of the presence of low levels of volatile organics in the ground water they should be monitored in the brook on a regular basis to confirm the lack of impact
7 The presence of high concentrations of cadmium and zinc in one of the waste samples indicates that trace metals should be monitored periodically
8 The presence of baseneutral extractable compounds (phthalates and naphthalene) in all of the analyzed waste samples indicates that these compounds should be monitored periodically
9 The phthalates are not expected to migrate freely because they have low solubilities and are readily adsorbed onto soil particles
10 If elevated concentrations of volatile organic compounds trace metals or baseneutral extractable compounds should occur in the monitoring system (wells and brook) in the future a need for site remedial actions to mitigate the potential for downgradient ground and surface water contamination could develop
~
80
41
RECOMMENDED PLAN
Based on the preceding conclusions it is recommended that the
following plan be implemented by Troy Mills Inc
1 Continue monitoring ground and surface water quality at the Troy Mills Inc landfill sampling on a quarterly basis with sample collections during April July October and January
2 To confirm the absence of the landfills impact on Rockwood Brook test samples for volatile organic compounds by GCMS from surface Stations B (upstream) and C (downstream) on the April and October samplings
3 To determine if trace metals are present in downgradient ground waters conduct analyses for cadmium chromium lead mercury and zinc on samples from all monitoring points during the April sampling and on subsequent sampling rounds if necessary
4 To confirm the continued absence of baseneutral extractable compounds in downgradient ground and surface waters conduct analyses for baseneutral extractable compounds on samples from monitoring wells M 2 and 3 and surface Station C (downstream) on the April sampling and on subsequent sampling rounds if necessary
5 If a sudden rise in concentrations toward unacceptable levels should occur in the monitoring system (wells and brook) additional monitoring rounds at a monthly interval should be conducted to confirm the rise in concentrations
6 If elevated concentrations persist and are verified by the additional monitoring remedial alternatives will be defined to mitigate the potential for downgradient ground and surface water contamination
Respectfully submitted NORMANDEAU ASSOCIATES INC
Dennis R Sasseville Project Manager
Donald H Bruehl f laquo | APG Senior Hydrogeologist -^ - - AIPG Certificate No 2272 ^ -v^
^^Z-^^
APPENDIX A
SITE SAFETY PLAN
GENERAL SAFETY PLAH FOR
TROT MILLS LANDFILL TROY MEW HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
Prepared by
NORMANDEAU ASSOCIATES INC Bedford New Hampshire
R-457
November 1983
TABLE OF COHTENTS
PAGE
SECTION 1 BACKGROUND INFORMATION 2
Identification 2 Personnel 2 Site Description 3 Project Description 5
SECTION 2 HAZARD EVALUATION 6
Overall Degree of Hazard 6 Specific Hazards 8 Necessary LPP 8
SECTION 3 FIRST AID FOR EXPOSURE 10
SECTION 4 OPERATIONS SAFETY PLAN 11
General Personnel Protection GuidelinesAction Levels 11 Site Reconnaissance 13 Task 1 - Magnetic Survey Topographic Survey 14 Task 2 - Drum excavation and Sampling 15
SECTION 5 EMERGENCY INFORMATION 16
Emergency Telephone Numbers 16 Route to Hospital 16 Contingency Plan 17
APPENDICES 18
A - LEVELS OF PERSONNEL PROTECTION 18 B - DECONTAMINATION PROCEDURES 23 C - PERSONNEL AND RESPONSIBILITIES 25 D - PERSONNEL CASUALTY 26 E - GUIDELINES FOR SITE OPERATIONS 27
GENERAL SAFETY PLAN FOR
TROY MILLS LANDFILL TROY NEraquo HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
The following is a Safety Plan for on-site activities performed
during the Investigation of the Troy Mills Landfill being conducted by
Normandeau Associates Inc (NAI) of Bedford New Hampshire
The document is intended to be an in house working guideline
for personnel trained and experienced in hazardous waste field work and
not a treatise on safety Familiarity with standard equipment and proshy
cedures is expected Where possible non-site specific information has
been appended
All NAI employees subcontractors and visitors will be required
to follow this safety procedure plan and to report to either NAIs proshy
ject manager (P M) on site coordinator (OSC) or safety officer (SO) on
issues relating to safety
SECTION 1
BACKGROUND INFORMATION
IDENTIFICATION
Site Name Trey Mills Landfill NAI-ID No 457
Trey Mills Inc Troy NH 03465
AddressLocation At the south end of the dirt road about 15 miles
south of Troy NH between Rockwood Brook and the
old Boston and Maine Railroad grade
County Cheshire Phone 603-242-7711
PERSONNEL
Brook Dupee Bureau Hazardous Waste 603-271-4611
State Contact John Regan Bureau Solid Waste 603-271-4586
Dan Allen WSPCC 603-271-2755
EPA Contact
Other Contacts
Client Contacts Barrett F Ripley (Vice President)
NAI Personnel - (472-5191)
Project Manager - Dennis Sasseville
On Site Coordinators - Alton Stone
Safety Officer - Elizabeth Gross (Phoenix Safety)
Technical Director - Don Bruehl
Other - Douglas DeNatale Steve Ransom
SITE DESCRIPTION
Type of Facility Company (on-site) landfill
RCRA Status Generator Disposer
Size About 15 acres BuildingsStructures None
Surrounding Land Use N Forested
(one mile radius) E Abandoned Railroad
Forest RuralResidential
S Forested
W Forested Mountain side
Unusual Features or Terrain None
Site Activities - Troy Mills manufactures textiles carpets and related
products Since 1968 waste materials including
drummed wastes have been landfilled on company proshy
perty Drums mostmany of which may be emptycrushed
are buried in an inactive section of the landfill
The active section is currently accepting waste
which is considered to be non hazardous
Specific - Improper disposal of hazardous waste
Problems - Leachate seep
Contamination of ground water
Hazardous WastesMaterials On-5ite
Wastes - Uncured foam rubber latex sludge
SBR rubber silicone defoamer potassium oleate soap
calcium carbonate and feldspar filters zinc oxide
and sulpher salt cure system
- Vinyl plastisol sludge
PVC dispersion resin DOP and DOA plasticiser
calcium carbonate filler organic pigments AZO
dicarbcnamid blowing agent zinc salts expoxidized
soybean oil cadmLum-bariin-zinc stabilizer Varsol
MEK prints and topcoats sludges
PVC acrylic resins organic and inorganic pigments
MEK solvent toluene silicate fillers
Industrial solvents and chemicals
11 -dichlorethane 12-dichlorothane
111-trichloroethane trichlorethylene tetrachshy
lorethene methylene chloride toluene benzene
ethylbenzene benzidine 33-dichlorobenzidine aeroshy
lein acrylonitrile napthalene benzoperylene dibenshy
zoanthrasene idenopyrene
Pesticides
There is a possibility for low levels of pesticides
to be on site These would include Chlorodane
heptachlor expoxide toxaphene aldrin alpha BHC
beta BHC 4-4-DDT endosulphan 1 heptachlor
PROJECT DESCRIPTION
Purpose Tb characterize ground water conditions at the site and to
characterize wastes buried on site
Specific Tasks
Site Reconnaisance
Task 1 - Magnetometer SurveyTopographic Survey
Task 2 - Excavation for inspection of drums
SECTION 2
HAZARD EVALUATION
Overall Degree of Hazard - Moderate
Task Hazard Proposed LPP
Site Reconnaissance Low Level C
Task 1 MagnetometerTopographic Surveys Low Level CD
Task 2 Drum ExcavationSampling Moderate Level B
Conpany records have indicated that a variety of industrial
and potentially hazardous wastes including drummed wastes
were disposed of on site Several of the subtances are
trade name materials or industrial process materials and it
is difficult to determine the specific chemical composition
Hazard is dependent upon concentration of material state of
material (solid sludge drummed liquid) and degree of
decomposition
Many of the materials - SBR rubber silicone defoamer
potassium oleate soap calcium carbonate and feldspar
fillers zinc oxide and sulpher salts plasticiser
calcium carbonate filler organicinorganic pigments AZO
dicarbonamid blowing agent epoxidized soy bean oil
cadmiura-bariun-zinc stabilizer - probably do not represent
a significant hazard to an inspection team if they are
bound into a sludge or solid Personnel are not likely
to injest or come into a prolonged high concentration
contact with these materials In powdered or dust conshy
ditions the materials are more hazardous due to the inhashy
lation of contaminated particulates
MEK (TLV-200ppm) toluene (TLV-100ppm) and Varsol
(turpentine thinner composition unknown) are volatile
organics which require respiratory protection and contact
protection
Depending upon state and decomposition PVC resins could
be a source of vinyl chloride monomer (VCM-a carcinogen)
requiring respiratory protection VCM is not adequately
filtered by air purifying respirators
Results from ground water sampling showed low levels of
industrial chemicals (PPB range) At these low conshy
centrations the chemicals do not represent a significant
hazard However the low concentrations in ground water indishy
cate the possibility of higher concentrations in the waste
materials
Industrial chemicals - napthalene (TLV-10 ppm) peryshy
lene anthrocene and pyrene which are hazardous
through inhalation or absorbtion Furthermore as
double benzene ring chemicals they are potential
carcinogens
Results from ground water sampling indicated possible
low levels (parts per trillion) of several pesticides
- chlorodane heptachlor epoxide toxaphene eldrin
Alpha BHC Beta BHC 4-4-DDT endosulphan These were
tentatively identified during a first analytical run
but not confirmed during a second run laboratory
review (GCA Bedford Mass) determined that the
material was actually a complex of highly degraded
heavy organics derived from the industrial waste The
presence of pesticides in industrial textile waste is
unlikely
Specific Hazards
1) Inhalation of organic vapors
Excavation of buried material and sampling of drums could
initiate high vapor concentrations
2) Fire and explosion
Many of the solvents are flammable liquids and volatile
Excavation of material and sampling of drums should
proceed cautiously in order to avoid rupturing shocking
or sparking of drums and material
3) Inhalation of contaminated dustparticulates
Excavation of buried material may result in a release of
particulates
4) Contact contamination
Excavation and sampling of wastes could possibly result in
contact with contaminated waste and soils necessitating
protective clothing
Necessary LPP
Site Reconnaissance - Level C The site has been visited on numerous
occassions by the state and private personnel Use of an HNU (102 ev
probe)- has not indicated significant vapor concentrations Significant
odors during dry weather or other hazards have not been noted
Sections of the landfill are currently active and adverse effects to
personnel have not been noted Level C - (tyveks rubber safety boots
organic vapor cartridges) is sufficient
Task 1 MagnetometerTopographic Survey - Level CD LPP will depend
upon the results of the Site Recon Significant vapor concentrations
or likelihood of particulates will necessitate an upgrade in the LPP
Otherwise Level D (work clothes safety boots boot wash) is sufficient
Task 2 Excavation and Sampling of Buried Drums - Level B The potenshy
tial for encountering significant concentrations of hazardous
materials during this task is moderately high Full Level B - (SCBA
chemical resistant tyveks hoods rubber safety boots rubber gloves)
will provide necessary respiratory and contactsplash protection
The use of the hooded yellow tyveck and the taping of ankleboots
wristsgloves and face maskhood junctions will provide complete conshy
tact protection
10
SECTION 3
FIRST AID FOR EXPOSURE
INHALATION OF VAPORSPARTICUIATES
Symptoms - eyenosethroat irritation nausea dizziness headache weakness fatigue lightheadedness drowsiness Loss of coordination confusion vomiting cramps (These sympshytoms are similar for most organic vapors particularly solvents)
Treatment Mild Exposure - Bring victim to fresh air Rinse eyes and throat if
irritated Heavy Exposure - (victim vomits very dizzy groggy faints etc)
Bring victim to fresh air Evacuate to hospital Prepare to administer CPR
Victim should be monitored for 48 hours in case of a delayed reaction
CONTACT EXPOSURE
Symptoms - Itching burning redness of skin Severe contact exposure for certain solvents will progress to CNS (central nervous system) symptoms similar to those for inhalation
Treatment - Remove contaminated clothing flush with water dry and banshydage Monitor victim for CNS symptoms for at least 48 hours
FIRST AIDSAFETY EQUIPMENT
The following equipment will be stationed at the Hotline or when appropriate down range
- Fully equipped first aid kit - Oxygen bottlekit - Nine (9) Ib chemical fire extinguisher - Eyewash bottle or other pressurized water filled container
11
SECTION 4
OPERATIONS SAFETY PLAN
This section outlines the specifics of safety procedures to be
used during each phase of the operations Safety procedures may be
upgraded or downgraded during site activities pending monitored changes
in the working environment All changes will be in line with the
General Level of Personnel Protection GuidelinesAction Levels for the
Troy Mills Landfill On-Site Investigation as described below
General Personnel Protection GuidelinesAction Levels
An in depth review of levels of personnel protection (LPP) is
presented in Appendix A
Level B (SCBA cotton coveralls or work clothes yellow tyveks (chemical resistant) steel toed rubber boots or work boots with disposhysible over boots and gloves)
Vapor concentrations (as measured on an OVA or HNU 117 EV Probe) greater than 5 ppm above background
- Oxygen deficient atmospheres less than 195
Specific actions (ie excavationsampling of drums) which could initiate a sudden moderate or high concentration of vapor
Level C (full face respirator organic vapor dust combo cartridge tyveks over work clothscoverails rubber safety boots gloves)
Vapor concentrations above an established clean zone backshyground level
During conditions (natural or personnel induced) which result in high levels of dust (visable above background atmospheric concentrations of particulates)
Level C activities require continual air monitoring
12
Level D (cotton coveralls or other work clothes safety shoes and safety glasses when down range Tyveks may also be needed)
Support areas and downrange areas where a higher LPP has not been deemed necessary
Continual air monitoring in downrange areas
Explosive Atmospheres
- 20 LEL (lower explosive limit) as recorded by an explosishymeter Secure and evacuate the work area
Oxygen Deficient Atmospheres
- Less than 195 (by volume) oxygen atmosphere requires upgrading the level of Personnel Protection to Level B
Task Specific Safety Plans
Levels of Personnel Protection indicated for specific tasks below are those which are anticipated to be used Changes in site conshyditions and results of air monitoring may indicate the upgrade downgrade of the LPP
13
Site Reconnaissance (SR) Date Sept 21 1983
Purpose To review on-site conditions and determine LPP necessary for further tasks To evaluate safety hazards Preliminary planning of future tasks
LPP - Initially Level C Updowngrade as necessary
Equipment - OVA HNU (102 ev probe)
Hotline - End of access road Upwind if possible
Command PostFirst Aid - Behind Hotline
Decontamination - Boot wash
Operations
Three man team Two persons advance in front with instrushyments Third person at distance as backup
Team methodically sweeps (criss cross) the proposed work areas with instruments
Specific points of interest (leachate seeps etc) are closely checked
All information is loggedsketch mapped
Upgraded LPP as necessary
14
Task 1 - Magnetic Survey Topographic Survey Date Week of October 3 1983
Purpose - Determine the location(s) and extent of buried drums Provide topographic information for site base map
LPP - Level CD
Hotline - End of access road (upwind if possible)
Decontamination - Boot wash
Operations - SO or other NAI personnel will perform a brief safety sweep of the work area
- Work team will then proceed downrange at the appropriate LPP Using the magnetometer the team will systematically criss cross -the work area
Task 2 - Drum Excavation and Sampling Date Week of November 14 1983
Purpose - Excavationsampling of buried drums in order to characterize the condition of the drums and the nature of the wastes conshytained in the drums and buried in the landfill
Msthod - Backhoe and hand labor will be used to uncover the drums in specified locations Samples will be obtained from spillage or leakage around the drums and of contaninated soil Selected drums which have accessible and openable bungs may be opened and sampled Drums will not be moved or staged Clean drums will be available to receive any significant spillage during the opening and sampling
Specific Hazards - Inhalation of organic vapors - Fire and explosion of drummed waste - Contact with contaminated waste or soil
LPP - Full Level B protection Backhoe operator at Level B Backshyhoe equipped with splash shield and without teeth on bucket
Hotline - At the end of the access road Upwind if possible
Decontamination - Procedures will essentially follow those as outlined by the EPA for Level B work Due to the inaccessibility of the site a field shower will not be available See Appendix B
Safety Equipment - OVA HNU eyewash fire extinguisher oxygen kit first aid kit metal detector non sparking implements
15
Operations - The cover soil is very sandy and the drums appear to be buried close to the surface which should facilitate excavation
- Minimum of 4 man team (exclusive of backhoe operator) Two or three man downrange team for digging and sampling One or two men in supportbackup at hotline
- Personnel will hand dig several small holes to approximately one (1) foot depth in each Location area If drums are not encountered the backhoe will scrape off soil to that depth
- Excavation will proceed alternating hand and backhoe methods At depths below four (4) feet the sides of the pit must be angled back to less than 45deg
- Prior to opening a closed drum the backhoe will nudgebump the drum to check for shock sensitive material An alternate method will be to attach a length of rope to the drum and from a distance pull on the rope to jog the drum
mdash Backhoe The backhoe operator will work at Level B utilizing air supplied from a large cylinder attached to the backhoe The backhoe will also be equipped with a splash shield A scraping bucket without teeth will be used
Prior to backhoe excavation at each location the area where the backhoe will be stationed will be checked for drums which could be ruptured by the backhoe feet
f Excavation areas will be checked for drums utilizing hand excavations or a metal detector prior to removing material by machine
16
SECTION 5
EMERGENCY INFORMATION
Emergency Telephone Numbers
If calling one of these numbers please state NAME LOCATION
and type of PROBLEM
Local Emergency Support
Fire Department (Troy 242-7759) For all emergencies use
Ambulance 352-1100 Mutual Aid (Keene) 352-1100
Police Department (Troy 242-7992)
Hospital 352-4111 (Cheshire Hospital in Keene)
Town Clerk 242-3845 State Agencies
NH Bureau of Hazardous Waste Management 271-4608
NH Water Supply and Pollution Control Commission 271-3503
NH Fire Marshall Office 271-3336
NH State Police (24-Hour Dispatch) 1-800-852-3411
Other
US EPA (24-Hour Hotline) 617-223-7265
Poison Center Mary Hitchcock Hospital 1-800-562-8236
Route to Hospital
- Follow dirt access road to Bowkerville Road - Left on Bowkerville Road to Rt 12 - Left (north) on Rt 12 through Troy to Keene NH - At major junction of Rts 9 10 101 and 12 go straight through
into Keene - At common go half-way around and go right on Court Street - Hospital is at 580 Court Street
17
Contingency Plan
Signal - five (5) one second blasts of auto or air horn Action - All personnel immediately excavate dovmrange areas and
report to Hotline for instructions
Personnel Unexplained Fire (if small) Accident (serious) Collapse of Personnel
Evacuate area Emergency ^ ^Evacuation Evacuate Area
First Aid
Estimate Explosion Level B (for Potential Contact Outside Help evcavation)
Evacuate Victim i If
Level B Prepare for Transportation
1 First AidCPR Use extinguisher Transport
Contact Outside Help Notify Coup any Have Proper Information Personnel (see below) 1
Transport
Call Fire Dept (if necessary)
For Hospital Victim
- Name and Phone of family physician
- Description of Incident chemicals involved symptoms nature of injury proposed treatment and plan of transportation
18
APPENDIX A
LEVELS OF PERSONNEL PROTECTION
Because of the possible dangers of exposure to toxic or harmshyful chemicals protective equipment must be worn during work on hazardous waste sites Levels of Personnel Protection (LPP) describe respiratory clothing and other equipment necessary for protecting personnel against expected hazards
The descriptions below are for full dress at a given LPP where hazards are expected to be at a maximum for which the given LPP is conshysidered adequate Depending on site conditions and work activities the clothing and dress requirements of a given LPP are commonly modified
LEVEL A
1 Personal Protection Equipment
Positive Pressure SCBA (MSHANIOSH approved) Operated in the positive pressure mode
Totally Encapsulating Suit (boots and gloves attached)
Gloves - Inner (tight fitting and chemical resistant)
- Boots - Chemical - protective steel toe and shank Depending on suit boot construction worn over suit boot
- Gloves shy Outer chemical-resistanttion worn over suit gloves May bchemical-resistant gloves worn insid
Dependinge replaced withe suit glo
on s
ves
uit construcshy tight-fitting
- Underwear shy Cotton long-John type
- Hard Hat (under suit)
- Disposable protective suitover encapsulating suit)
gloves and boots (Worn under or
- Coveralls (under suit)
- 2-way Radio Communications
Optional
19
2 Criteria for Use
A The type and concentration of toxic substances are known and require the highest level of combined protection to the respirashytory tract skin and eyes These conditions would be
1 Atmospheres which are immediately dangerous to life and health (IDLH)
a IDLHs can be found in the NIOSHOSHAs Pocket Guide to Chemical Hazards andor other references
2 Known atmospheres or potential situations that would effect the skin or eyes or could be absorbed into the body through these surfaces in toxic quantities
a Potential situations are those where vapors may be generated or splashing may occur through site activities
b Standard reference books should be consulted to obtain concentrations hazardous to skin eyes or mucous memshybranes
3 Oxygen deficient atmospheres with above conditions
3 At sites where the type andor potential concentration of toxic substances are unknown
1 Unless circumstances strongly indicate otherwise the site should be presumed to present hazards to the respiratory system skin and eyes Level A protection would provide the highest level of protection for the initial entry team
a Such circumstances might be
1 Environmental measurements contiguous to the site
2 Reliable accurate historical data
3 Open unconfined areas
4 Minimal probability of vapors presence or splashing with cutaneous effecting substances
2 Enclosed areas such as buildings railroad cars ships holds etc
20
LEVEL B
1 Personal Protective Equipment
Positive Pressure SCBA (MSHANIOSH approved) operated in the positive pressure mode
- Hooded chemical-resistant suit
Gloves - Outer chemical-protective
Gloves - Inner tight-fitting chemical-resistant
Boots - Outer (chemical-protective heavy rubber disposables)
Boots - Inner (chemical-protective steel toe and shank)
2-way Radio Communications
Hard Hat
Face Shield
2 Criteria for Use
A The type and concentration of hazardous substances are known and require the highest degree of respiratory protective but a lower level of skin protection
1 Atmospheres which are immediately dangerous to life and health (IDLH) Type and concentration of vapors in air do not present a hazard to the small unprotected areas of the body
2 Atmospheres with concentrations of known substances greater than protection factors associated with full-face air-purifying respirators with appropriate cartridges
3 Atmospheres with less than 195 oxygen
B When a determination is made that potential exposure to the body parts not protected by a fully encapsulated suit (primarily neck ears etc) is highly unlikely
1 Known absence of cutaneous or percutaneous hazards
2 Activities performed preclude splashing of individuals
C Level B protection is recommended as the lowest level of protecshytion for initial entries until the hazards have been further identified and defined by monitoring sampling and other reliable methods of analysis and personnel protection equipment commensurate with these findings utilized
21
LEVEL C
1 Personal Protective Equipment
Full-face or half-face air purifying respirator (MSHANIOSH approved)
Chemical-resistant clothing
Gloves - Outer (chemical-protective)
Gloves - Inner (tight-fitting chemical-resistant type (or woven liners)
Hard Hat (face shield optional)
Boots - Outer (chemical-protective heavy rubber throw aways)
Boots - Inner (chemical-protective steel toe and shank)
2-way radio comnunications
Safety glasses required with half-face respirator
2 Criteria for Use
A Site known to contain potentially hazardous materials exceeding
1 Air concentrations requiring a protection factor no greater than that afforded by a full-face mask
2 Harmful levels to unprotected body areas (face neck etc)
3 Well-documented reliable history of site and patterns of prior entry
C No evidence to suspect acute or chronic toxicity to exposed personnel
D Continuous air or personnel monitoring should occur while wearing Level C protection
22
LEVEL D
1 Person Protective Equipment
Chemical resistant aprons
BootsShoes - Safety or chemical-resistant steel toed boots
Boots - Outer (chemical-protective heavy rubber throw-away)
Half-face respirators immediately available
Safety glasses or safety goggles
Gloves
2 Criteria for Use
a No indication of airborne health hazards present
b No gross indications above background on the photoionizer andor organic vapor analyzer
c Continuous air or personnel monitoring should occur while wearing Level D protection
23
APPENDIX B
DECONTAMIHATION PROCEDURES
Depending upon activities and location on site it may be
necessary for personnel to decontaminate prior to leaving the conshy
taminated zone Procedures described below are typical for Level C
operations
Upon exiting downrange (contaminated) areas all personnel are
required to decontaminate by means of the following procedure
1 Place equipment in the Drop Zone at the Hotline
2 Enter the Decontamination Station
Boot Wash Walk through wash tub and scrub boots then rinse boots in second tube
Glove Wash In two pan wash scrub over gloves rinse set out to dry
2 Remove tyvek - if leaving the contamination reduction zone (CRZ) and proceed to clean zones
3 Dispose of heavily contaminated clothing and under gloves
4 Remove respirator
5 Use disposable gloves to clean equipment
6 Use a two bucket (washrinse) to decon respirators at the end of the working day or if they become heavily contami nated
The procedures for a typical Level B Decontamination are
outlined on the following page
TANK CHANGE 9
CONTAMINATION REDUCTION
ZONE
OUTER GLOVE REMOVAL
EXCLUSION ZONE
TAPE REMOVAL
BOOT COVER
GLOVE WASH
(bull)mdashQ-G--copyshySOOT COVEH SCOT COVES 4
REMOVAL GLOVE RINSE
SUITSAFETY BOOT WASH
SU1TSC8A78OOTGLOVE RINSE
SAFETY BOOT 10 REMOVAL
SCSA BACKPACK REMOVAL
SPLASH SUIT 12 REMOVAL
INNER GLOVE WASH
INNER GLOVE RINSE
FACE PIECE REMOVAL
INNER GLOVE 16 I REMOVAL
INNER CLOTHING REMOVAL
FIEUJ 19 REDRESS WASH
SEGREGATED EQUIPMENT
OROP
mdash -HOTLINE-shy
DECONTAMINATION LAYOUT LEVEL B PROTECTION
FIGURE A2-1
CONTAMINATION CONTROLLING
SUPPORT ZONE
25
APPENDIX C
PERSOHNEL AND RESPONSIBILITIES
Project Manager (PM)
Overall responsibility for all Project activates budget
schedule investigative operations safety personnel
On Site Coordinator (OSC)
Responsibility for activities at the site Primary responshy
sibilities include
1) Interfacing with the client state EPA media or other groups
2) Reviewing technical operations
3) Reviewing site safety in particular information supplied by the Site Safety Officer
4) Enforcing site safety and compliance with the Safety Plan
5) Directing Emergency Contingency operations
Safety Officer (SO)
Responsibility for directing the safety of operations and impleshy
menting the Safety Plan Specific responsibilities include
1 Assuring that appropriate personnel protective equipment is available and properly utilized by all site personnel
2 Assuring that personnel are aware of the provisions of this plan are instructed in the work practices necessary to ensure safety and in planned procedures for dealing with emergencies
3 Assuring that personnel are aware of the potential hazards associated with site operations
4 Supervising the monitoring of safety performance by all pershysonnel to ensure that required work practices are employed
26
APPENDIX D
PERSOHHEL CASUALTY
Personnel casualty would most likely result from either chemical
contamination heat-related problems physical injury from accidents
(ie falling lacerations etc) in performing the work or a comshy
bination of one or more of the above The appropriate action depends on
the type of injury involved with the priority being to assist the
casualty as soon as possible without endangering other personnel
Riysical and heat-related injuries can and should be treated
immediately with appropriate first-aid measures and follow-up medical
attention if necessary The injured worker(s) shall immediately move
out of the hot zone or if necessary be moved out by fellow workers as
soon as possible The OSC and Safety Officer shall be notified immeshy
diately and shall recommend further measures as needed
Chemical-related injuries require a much more cautious approach
so as to keep casualties to a minimum If a worker injured by chemical
ejqgtosure is able he shall notify the nearest co-worker and leave the hot
zone immediately- The co-worker shall ensure that the OSC and Safety
Officer are immediately informed and shall accompany the casualty from
the hot zone to the decontamination zone The OSC and Safety Officer
shall determine the appropriate measure
27
APPENDIX E
GUIDELINES FOR SITE OPERATIONS
In order to deal with the potential dangers of exposure and conshy
tamination of a hazardous waste site three zones are delineated
according to the degree of hazard The three zones are 1) Downrange
or Contamination Zone 2 Contamination Reduction Zone (CRZ) 3) Support
or Clean Zone
Downrange or Contamination Zone
The Contamination Zone is the active work area of the site which
encortpasses the areas where there is a potential for exposure and in
which investigative activities will occur (drilling sampling etc)
Within the Contamination Zone the designated level of hazard will be
established necessitating the utilization of personnel protective
equipment
Hot spots are those areas Downrange where observations instrushy
ment readings or specific activities indicate a high probability of
closure or contamination and may require an upgrade in the LPP in the
vicinity of the Hot Spot
Contamination Reduction Zone
The CRZ is an area between the Downrange and Support Zones where
decontamination of equipment and personnel occurs
28
Personnel entering the CRZ shall wear protective clothing and
carry the respiratory protection required for entry within the
Contamination Zone
Personnel working within the CRZ shall remain cognizant of the
CRZ in order to be prepared for any need to increase their level of proshy
tection within the CRZ
A decontamination station will be located at the outer perimeter
of the CRZ All personnel who have been within the Hot lane shall pass
through a decontamination procedure prior to re-entering the Support
Zone
Support or Clean Zone
The Support Zone is the outer area and may be considered to be
clear of contamination potential The command post will be located
within the Support Zone
a) The Command Post will serve as the OSCs headquarters and
will be equipped with
1 Communications
2 Safety Plans
3 First Aid Supplies
4 Analytical Equipment
5 Safety Equipment
APPENDIX B
WORK PLAN
WORK PLAN FOR
TROY MILLS LANDFILL TROY NEW HAMPSHIRE
DRUM EXCAVATION AND SAMPLING
Prepared by
NORHANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
1933
WORX PLAN FOR
TKOt MILLS LANDFILL TROT NEW HAMPSHIRE
DRUM EXCAVATION AHD SAMPLING
DATS November 16-18 1983
PURPOSE
To determine the condition of drums (ie erroty or full
crushed rusted leaking etc) buried in the Troy Mills Landfill To
obtain representative samples toward identifying the types of materials
buried in the landfill This information will be used in the detershy
mination of the level of remedial action needed at the site
METHOD
Using the results of the magnetometer survey the (10) points
have been randomly chosen across the area where the buried drans are
expected to be found Each point is central to an Excavation Location
-- an area four (4) to six (6) feet in diameter which will be excavated
in order to characterize the condition of the drams and to obtain waste
sarples
Preliminary observations have indicated that many of the drums
may be buried within 1-2 feet of the surface Therefore the investigashy
tion will proceed in two phases
Phase 1 mdash Hand Excavation By digging several small holes in
each Location personnel will determine if drums are located within
about one to two feet of the surface If drums are encountered the
excavation will proceed by hand uncovering the dnris for evaluation and
sampling Where drums are not encountered near the surface excavation
at this location will be postponed until Phase 2
Phase 2 mdash HandBackhoe Excavation After all Locations have
been attempted during Phase 1 those Locations in which drums were not
encountered wall be further excavated using a combination of hand
backhoe digging
It is expected that one to two days will be necessary to
cor^piete each phase Depending upon the results of Phase 1 it may not
be necessary to iroleraent Phase 2
Spare drums will be on hand for containerizing any significant
spillage resulting from sampling efforts Excavation locations will be
identified with marked stakes and the holes will be backfilled at the
conclusion of the investigation
SPECIFICS
Excavation Locations (Holes)
Number of proposed excavations is ten (10)
Locations of excavations are presented in Appendix A
Hole Size mdash It is expected that a hole from four (4) feet to six (6) feet in diameter at the bottom (depth at which drums are encountered) will be sufficient to characterize the drums at each Location Deeper excavations will require increasingly large top diameters
Hole Depth -- Holes will be excavated to a maximum depth of six (6) feet Due to the sandy cover material the excavation of deeper holes is probably impractical from both safety and efficiency stand points
If after attempting excavation at each of t-ie 10 proposed
1ocatiors irums are not encountered within six (6) fet of the surf ice
in enough locations to characterize the site excavations nay be
attempted to depths greater than six (6) feet if scil stability permits
or a new set of sampling locations may be chosen
(Excavations to depths greater than six (6) feet require a
significant increase in work The sides of the hole crust be graded back
to less than 45deg in order to insure the safety of investigatorysampling
personnel It may also be necessary to employ bracing bulkheads etc
for trench support)
Excavation Identification
Proposed excavation Locations have been consecutively numbered
from 1 to 10 beginning at the east end of the landfill They will be
marked with numbered stakes
Excavation Methods
Phase 1 mdash Within each Location personnel will dig a nunber of
small holes - about one (1) foot in depth - to probe for drums If
druns are encountered they will continue to excavate until the drur3
are sufficiently uncovered for characterization
Phase 2 mdash After hand probing the Location with snail holes
the backhoe will remove cover material to the one (1) foot depth The
Location will then be probed to a two (2) foot depth before removing
further material Excavation will proceed alternating handprobing and
backhoe excavation until drums are encountered or the maximum six (6)
foot depth is reached
If excavations to depths greater than six (6) feet are undershy
taken they will proceed using the above method
Santnlea
Due to the effort involved in excavating and because conshycentrated waste samples are not expected to undergo rapid degradation it is considered expedient to obtain all readily available samples (exclusive of closed drum samples -- see belcw) These can then be submitted for laboratory characterization as determined by need and budget restrictions
An attempt will be trade to secure at least one sample froa each excavation in order to help characterize the distrishybution of waste materials across the site An attempt will also be made to secure samples of observably difshyferent materials
Sample Types and Mediums - Solid liquid and sludge samples are possible Samples will be obtained from in order of preference -- 1) leakage uncontainerized waste or contaminated soil 2) waste contained in open conshytainers - drum already has a hole or no top or other access point 3) sealed containers
The opening of closed containers will be considered if it is decided that it has not been possible to obtain a sufshyficient number of representative samples from the other mediums
Each sample will consist of two (2) 8-oz jars (with teflon-lids) filled about 23 full One jar will be for organic analysis and the other for inorganic analysis
Sanole Identification - Samples will be identified with a number corresponding to the Excavation Location and a letter Example if three samples were obtained from Location 2 they would be samples 2A 23 and 2C and Samples 2Ad 23d and 2Cd for duplicates
Sampling Methods and Volumes - 11 mm hollow glass tubing trowels disposable scoops will be available to obtain samples Samples tools will be disposed of or deconshytaminated between each sample
Drum Samples - If necessary an attempt will be cude to obtain samples from sealed drums Oily o^und non-rusted drums will be considered Bunjs rust be xn suitable conshydition -jo that the dram cm be openoi withrut cvis ing dainai -ind ca-i be resell od to pr-jvcrt l V-i 30
There wil l be no staging or movement of drums in order to faci l i tate sampling Only drums with accessible bungs will be considered for sampling
Procedure for Drum Sampling
1) Excavate around top of drum
2) Monitor air in the adjacent area
3) Chec for shock sensitive - Loop rope around top of drum stand at a distance give drum several hard jogs by pulling on the rope An alternative nethod is to lightly jog the drum with the backhoe bucket
4) If the drum is not upright place a catch basin under the bung
5) Open drum with bung wrench
6) Monitor the air atin bung
7) Sample drum -- liquids insert glass tube the fu l l length into the drum in order to obtain a column of the materials in the drum Solids use scoop to dig out material through the bung or use a sampling trowel
3) Reseal the dram
Spill Control
The possibility exists during the sampling and excavation for a
drum to be ruptured or otherwise have spillage Clean drums wil l be on
hand to receive significant spillage resulting frora sampling or excavashy
tion They will not be used for clean up of widespread uncontainerized
waste or existing leakage
Personnel
The work team will require four (4) persons (exclusive of the
backhoe opera tor) Trie downrange team will consist of three (3) persons
-- two (2) for d igg ing and sampl ing and on ( 1 ) for logging air moni shy
toring and photographing One (1) person will be at the hotline in
support mdash as safety backup person to fill air bottles to deconshy
taminate samoles to assist in decontamination of personnel
Documentation Logging
The following information will be recorded at each location
nmber of drums uncovered and the condition (crushed empty rusted
sealed etc) of each drum evidence of spillage or contaminated soil
labels on uncovered drums samples (time drum ID type description)
periodic air monitoring information depth at which specific events
occur or drums are buried soil condition presence of ground water
In addition photographs will be taken of specific events or
items of importance during each excavation and of each sampling incishy
dent The time description of subject photographer excavation
location and photo number will be logged for each photograph
Analytical Laboratories and Schedule
RAI Hampton NH
Initial schedule
Ten samples for GCrns for organic priority pollutants Samples may also be submitted for inorganic anlaysis or volatile organic analysis depending upon waste materials observed during the excavation
APPENDIX A
TABLE A-1 EXCAVATION LOCATIONS
EXCAVATION BASELINE RANDOM RANDOM
NUMBER GRID COORD SEGMENT STATIOH OFFSET
1 7E+1 565N 0- 60 26 (25) 16
2 9E+5 13S 60-120 50 (110) 9
3 8E+0 31S 120-180 20 (140) 7
4 4E+5 483 180-240 50 (230) 25
5 3E+3 45S 240-300 14 (254) 20
6 OE+6 5S 300-360 34 ( 334) 50
7 2W1 5 24N 360-420 45 (-155) 14
8 5W+6 42N 420-480 38 (518) 20
9 6W+1474N 480-540 8 (543) 7
10 8W 5 11011 540-600 11 (611) 31
Locations are plotted on Map A-1
Method of Choice A stratified random sampling method was used to choose 10 Excavation Locations within the magnetic anomaly
The axis of the magnetic anomaly was used as a base line and divided into ten 60 foot long segments Using a randora nirnbers table a distance along each secpent was chosen (Random Station) and a line drawn at that point perpendicular to the base line Again using a random numbers table a distance was located along each perpendicular line by measuring inward from the line denoting the edge of Area A (Random Offset) The Grid Coordinates for each of the Excavation Locations were graphically determined from the grid overlay (this overlay has been surveyed and intersections field located)
It was judged that 10 excavation locations within the magnetic zone and two outside of the zone would be sufficient to characterize the area would produce statistically valid iati and coli be expected to be co~letod within 2-3 days work period
to
80
cu0
cgtc
APPENDIX C
MAGNETIC INVESTIGATION TROY MILLS INC LANDFILL SITE
TROY NEW HAMPSHIRE
For
NORMANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
By
JOHN F KICK PhD GEOPHYSICIST
Box 6 Dunstable Massachusetts 01827
(617) 649-6650
Noverber 19S3
MAGNETIC INVESTIGATION
TROY MILLS INC LANDFILL SITE
TROY NEK HAMPSHIRE
INTRODUCTION
A high resolution ragnetic investigation was completed on the Troy
Mills Inc landfill site in Troy New Hampshire by John F Kick
Consulting Geophysicist The purpose of the investigation was to
delineate the extent of buried steel drums under closed portions of the
Troy Mills landfill The information is needed as a part of a study of
the landfill that is being conducted by Normandeau Associates Inc
FIELDKORK
Magnetometer measurements of total field intensity were made over an
area that was reported to contain buried steel drums and adjacent
landfilled areas that contained unknown waste materials The area of
investigation included capped and grassed closed areas along the south
margin of the landfill site and adjacent areas The fieldwork was
performed during October of 1983
Eighteen parallel rows of measurements were conducted along north-
south lines (using magnetic compass directions) A spacing of 20-feet
was used between rows and magnetometer measurements were made at 10-foot
intervals along the rows Greater intervals between measurements were
used at the ends of the rows and in periferal areas with low magnetic
-JF Kick 01shy
field gradients
A series of magnetic field measurements were made at an adjacent
base station throughout the survey to torn the basis for a daily
variation curve The base station was located at a site with typical low-
gradient background magnetic field intensity measurements
MAGNETIC SEARCH METHOD
Theory Magnetic search methods involve the detection and
measurement of anomalies in the Earths magnetic field caused by the
presence of materials with contrasting magnetic susceptibility Iron and
steel objects generally have very high magnetic susceptibility contrasts
with usual surrounding materials and therefore produce magnetic
anomalies The amplitude shape and detectable distance of the anomaly
depend mostly on the particular susceptibility contrast and size of the
object Magnetic anomalies are measured in units called gammas The
normal magnetic field in this area is over 50000 gammas A 5-inch
screwdriver will produce an anomaly of 5 to 10 gammas at a depth of 5
feet and an anomaly of 1 gamma at a depth of 10 feet A 1 ton automobile
will produce an anomaly of 40 gammas at a depth of 30 feet and an anomaly
of 1 gamma at a depth of 100 feet The magnitude of an anomaly caused by
a single steel drum will vary with its condition (new heavily rusted
etc) Tests using a single light weight (somewhat rusted) drum on the
surface with the magnetic detector at a height of of 12 feet produced an
anomaly in the range of 40 to 50 gammas
Total magnetic intensity disturbances or anomalies are almost always
asymmetrical sometimes appear complex even from simple sources and
usually exhibit the combined magnetic effects of several sources which
can produce a given anomaly The apparent complexity of such anomalies
is a result of several relatively simple functions of magnetic dipole
-JF Kick 02shy
behavior Reasonable assumptions about the geology and buried source
conbined with an understanding of magnetic dipole behavior can usually
lead to a satisfactory qualitative interpretation More detailed
interpretations nay require modeling studies
Instrumentation Field equipment on this project included a EGampG
Geometries Memory-Mag G-856 proton precession magnetmeter The
instrument has a resolution of +01 gamma The magnetic field detector
is separate from the rest of the instrument and is mounted on an 8-foot
staff to provide measurements that are a constant height above land
surface
Magnetic Data Analysis For the purposes of data reduction and
anomaly delineation it was assumed that base station total field
intensity measurements were typical background values for the site
Measurements made at frequent intervals at the base station were used to
prepare a diurnal variation curve for the site Anoraly values were
obtained by subtracting background values from the base station curve
from measurements collected in the area of investigation
RESULTS
The reduced results are presented in the form of a magnetic anomaly
contour map (Figure 1) and two profiles across the area of investigation
(Figures 2 and 3) The map and profiles show that very steep magnetic
field gradients and large departures form background occur in an
irregular shaped band that is about 460 feet long and ranges from about
30 to about 200 feet in width The magnitude of the anomaly is such that
a significant deposit of ferromagnetic materials (such as steel drums) is
indicated
In using the plotted magnetic results it should be noted that the
greatest concentrations of ferromagnetic materials probably do not
-JF Kick 03shy
directly underlie the peak magnetic anomalies A shift is caused by the
inclination of the Earths magnetic field and by the dipolar nature of
ferromagnetic deposits The inclination of the Earths field is about 76shy
degrees northward in the vicinity of Troy The dipolar effect is induced
by the Earths field and results in negative anomalies immediately north
of large positive anomalies
Magnetic Anomaly Map The magnetic anomaly map (Figure 1) indicates
10 positive peaks of varying size shape and intensity Associated
negative anomalies of a broader and less intense nature lie immediately
north of the belt of positive anomalies The configuration of the
anomalous area is indicative of lense-shaped and cigar-shaped bodies of
ferromagnetic materials Steep-sloped anomalies are indicative of very
shallow source materials The thickness of the ferromagnetic deposit
cannot be easily determined on the basis of intensity and size of
anomalous peaks because a small mass of iron or steel at the surface can
duplicate the anomaly caused by a much larger mass at depth The
ferromagnetic source materials can generally be expected to lie north of
the positive peak of anomalies and south of the adjacent negative
anomaly Modeling can provide the best approximations of the depth and
density of the ferromagnetic source materials The outer boundaries of
the source materials can be expected to overlap the positive peak and
negative anomaly somewhat depending on the depth and configuration of
the deposit
For illustration purposes two north-south rows that were profiled
are discussed below
Magnetic Anomaly Along Row 9-East Two strong positive magnetic
anomalies (3645 and 2436 gammas) and adjacent negative anomalies were
profiled along Row 9-East (Figure 2) The approximate centers of the
ferromagnetic deposits are believed to underlie stations 50 north and 75
feet south of the base line The rounded shape of the north positive
-JF Kick
anoraly nay indicate somewhat deeper burial of the ferromagnetic deposit
Magnetic Anomaly Alone Row 7-West Figure 3 shows the most intense
positive magnetic anomaly (4470 gammas) that was detected on this
project The steepeness of the slopes is indicative of very shallow
source materials An uneven burial pattern is suggested by the two-
peaked positive anoraly The negative anomaly south of the two peaks is
unusual and may be related to another positive anomaly to the southeast
(along Rows 5 and 6 20 feet north of the base line) The centers of the
sources of the positive anomalies are probably approximately 80 and 120
feet north of the base line along Row 7-West
-JF Kick 05shy
DISTANCE FROM BASE LINE(FEET)
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APPENDIX D
LABORATORY ANALYSES
RAI
Resource Analysts Incorporated Box 4778 Hampton H 03842
(603) 92^7777
TO PO 830318
Mr Doug DeNatale Date Received 12-2-83 Kormandeau Associates 25 Nashua Road Lab Number 2887 Bedford NH 03102 J
Date Reported 1-3-84
IDENTIFICATION
SAMPLE DESIGNATION PARAMETER
Volatile Organics Analyses by EPA Method 624
Acid and BaseNeutral Extractable Compounds Analyzed by EPA Method 625
Metals Analyzed by Standard Methods 303A
Please see attachments for all results
Results expressed in mgL unless otherwise designated lt = Less Than
ClarkeFosterVan K o u w e i b r h 1 ANALYST DIRECTOR
METHODS Standard Methods (or the Examination ol Water and Waitewaler 15th Edition or other EPA approved mtlhodologiei unless otherwise designated
Phys ica l descr ip t ion of sample
LiquidSludop
Saiple workup
Volitile f ract ion Methannl F-1-rarMrm CSVJ Rdfi-Smm
Semivolatile f ra ictio0onication Extraction fSW 846-3540^ Inorganic f rac t on Acid Digestion (SW 84h-iOS(V)
ACS3 COMPOUNDS
rr t CAS CAS
(71 A) tt-Ot-2 i^t TT i^MoroprvrfgtOi (73B) 30-32-1
(23 A) J9-JO-7 ^bull^^ lof o^^ft^crt gto (7 OB) 205-M-2
(2 A) 13-37 -J 2- chlorophenol (75B) 207-01-
(3 A) 120-13-2 2raquo^icMoroorgtenol (748) 211-01-9
(MA) 103-47-9 2-dimethv lohenol (77 B) 201-94-1
(37A) U-73-3 2- niiroDhenol (7IB) 120-12-7
(MA) 100-02-7 raquo-niiroprienol (7raquoB) lraquol-2raquo-2
(raquoA) Jl-21-3 2 - in i tr opheno 1 (106) raquoi-73-7
(40 A) 33-J7-l k4-dinnro-2-mlaquothylplaquogtergtol (I IB) 15-01-1
(4A) I7-U-3 (xntictiloroorraquonol (I2B) J3-70-3
USA) 101-93-2 pxmol (I3B) 193-39-J
(14 B) 179-00-0 RASENEUTOAL COMPOUNDS
( I B ) 13-32- raquocmlaquophtgtgtefgtlaquo
(36) 92-173 benzidine (2V) 107-02-S
( I B ) I20-I2-I l2t-tricMorobenzlaquonlt (3V) 10713-1
OB) 111-71-1 he laquo laquoch 1 or o benz erve (laquoV) 71-A3-2
(176) 47-72-1 hetraquocWoroltthlaquone (4V) X-23-5
U S B ) 111-- bu(7-cloroetrivl)ether (7V) 101- 90-7
(7CB) 9 I -3J -7 2-Chlororuprthraquolene (10V) 107-04-2
(73B) 95-50-1 l2-diCMoroblaquonzene ( I 1 V ) 7|3j^
( K B ) XI-73-1 13-didilorobtnzene (13V) 7J-3-3
(27B) 104-M7 1tmdash djcMorobenzene dkV) 79-00-3
C2IS) 9i9i-l 33-dictgtloroblaquoazidinr ( I JV) laquo-3-J
(33B) 12I -U-7 2gt-dinicrotoluer (14V) 7J-00-3 (KB) 4O4-7C-7 24-dinitrotoluene (UV) 110-73-1 (J7B) 122-A4-7 1J -diprienv lhydrraquo z irf (23V) lt7 tt 3
(MB) Z0-fc-0 UuorraquonThelaquo (2raquoV) 7J-35-
(W551 700J77-3 -ctilorophenyl prlaquonyl ether (JOV) 1M-40-3
( raquo I 6 ) 10I-J3-3 raquo-6romoprgtefgtyl prtenyl ether (32V) 71-17-3
(raquo7B) 33132-9 bU (2-cMorobopropyl) ether (33V) 10041-02-4
(raquoJ6) i l l -91- l bu (2-laquo^loroeTho)ry) methane 10041-01-03
(B) D-U) hexraquopoundj1|orobutaltlicne (31 V) 100--
(33B) 77-raquo7- heiKCtilorocycIopentadicrve (WV) 7J-CT-2
OB) 7IJraquo-I traquoo oh or or (raquo3V) 7raquo-17-3
(J3B) gtl-20-3 nphthraquolene (UV) 7raquo-I3-9
(546) n-tj) nitrobenzene (7V) 7J-2J-7
(426) U-Xl-4 bullJ -n itr o tod iphenyU mi ne (UV) 75-27-J
(OR) 421-W-7 N-oitrcnodipropYlirrUne ^raquoraquoV) 73-49-k
(446) I 1 7 J I - 7 bu (2-eltr^lheryl) phtfaUte 8200 (3ov) 73-71-1
(476) 13-U7 benzyl buryl phttwlite (51V) 124-kt-l
( U B I M-71-2 di-fl-utgtl pMhUre (13V) 177-II-
( lraquo6) 117-1 -0 dj-n-octvl prithlaquoUte (UV) 101-IS-3
(7CB) W-44-2 dielhvlphtraquollaquo (17V) 79-OI-t
( 7 | B ) I 3 I - I I - J dj^laquorTvipnthraquoUtr (UV) 7J-OI- (776) H-J5-5 bnro(raquogtnthrraquocefvr
Iab I D N o 2SS-10
C l ien t ID 1A64223
RASENEUTRAL COMPOUNDS
bfzoltraquogtprrene
benzoltb)flucrraquornNene
benio(llaquo)fluorraquonthene
chryiene
bullcenaDhthvien
raquontnrraquoctne
benzoltghi)perrlefgte
Iluorene
phergtraquonthrmlaquo
dibenzoltraquoMaithrraquocenraquo
indeno(123-cd)pvrene
prrene
VOLATHES
(frolein
bullcrvlooitrdf
benien
orbon Temchloide
CMorobeniene
1 7-dJchlorolaquothnr
111-trieftloroethine
ll-ltJichloroetrufle ll7-triCilorigtetMrlaquor
l127-tetrraquocMorothfllaquo
chloroethlaquo-e
7-dMoroeThraquo|virgtvl eirwshy
chloroform
11-didMoro^tfwnr
trinj- 1 2-dictMorolaquoirgtene
1 7-ltlicMoroproplaquorve
trini- 1 3-ltJichloroorcrpeoe
cu-lJ-lieMorocT oo eashy
rthy Uveniene
methrlene chloridf
chloromethine
bromome thraquone
bro mod iCTi lore met Mrgt
(Juorotr ichloromthraquor
di cMlor od 1 f 1 uore ngtet hj^gt
chloreltJbnjmomethne
te tr ten 1 or oet rx-r
laquouene 12000
tncMeroethe^e
Cidrr ium Chromiutr 10
All results are expressed as ucg veicht as received Nc ertrv denotes -0r ~ ^ 1 i rt
P h y s i c a l d e s c r i p t i o n of
SoilSludge
sample
Sanple workup
Vol i t i le f ract ion p^r Exf- rar r ion fST7Semivola t i le f rac t ion So^h^Pt Fgtr f ra r f ion
846-SOTO^ (SWRdfi-^SiO1)
Inorganic fract ion Ar id nio-psrirm
AOD COMPOUNDS
m CAS (2i A) tt-04-2 2raquot- Wichlorophenol
(22 A) J1-50-7 p-cfi I or o-n-cre laquoo 1
(2A) 13-57-1 2- ctiloroprienol
O iA) 120-13-2 2raquo^icMoroprnol
(gtraquoA) 103-47-1 2f 4mdash^imetSv Ip^enol
(37 A) U-73-3 7mdash Ti j oprtenol
(JraquoA) 100-07-7 mdash mdasho i Br opr^e no 1
JJ1A) 31-21-3 if mdash4 irtiTroprienol
(40A) J34-32-1 4 T4-4initrogtmdash 7 nte tny Ipnenol
(4A) f y _H 5 plaquontchlaroorwnol
(43A) J 01-95-7 prienol
rV ipoundNEUTRAlaquo- COMPOUNDS
( I B ) raquoJ-32-raquo
(3B) 17-17-5
( IB) 170-12-1
(IB) 1I1-7I-I
(17B) 4777-1
( I t B ) 111--
(20B) 11-31-7
(236) 15-50-1
(245) 51-73-1
(77B) 104-4-7
(285) 11-14-1
(336) 121-142
(34B) 404-70-2
(J7B) 127-M7
O1B) 2O4--0
(406) 7003-72-3
(416) 101-35-3 lt raquo 2 6 gt 3H3I32-1 ltraquo36) 111-11-1 (57B) S7-U-3
(336) 77 -raquo7-
(36) 71-31-1
(33B) 11-20-3
pound34 6 1 n-i33 (UB) tt-30-4
(436) CI-44-7
(4461 117-11-7
(47B) U-417
( U B I 14-747
(U6) I17_t-0
(7CS) l-laquo2
(7 I B ) t J U t l - gt
(7761 54-55-3
CT-~- i_i w i Miirn 0
resul ts
b^TMdint
1 2 t-o- icn lorobenl ergtlaquo
SeTraquochloroblaquorierraquoe
hrxchlorolaquotSlaquone
bu(2-chloroethv|gtether
2 -lt3M or onraquo ph ti1 ene
1 2-ltJictilorotgtmzcne
13-dicWorotxerzene
1 4-djch 1 or otxn z ergte
33-ditfgtlorolgtlaquoniidirraquo
24-dinitrotoloene
2 4-dtnitro toluene
U-dlpoenylfiydrraquoiilaquo
(luoranthene
raquo-cfJorophenyl poenyl ether
Mx-omopfieflyl phenyl ether
bis (2-cMorooopropyt) ether
bu (2-ctilorcxtSorv) meiSkte
hezkOilorobutadicne
hei acM or ocyc1 ofMn udi cne
oo prior one
nphthlene
nurotxniene N -ni tro Kxd ipoenyU mi ne
N-rutrowxhpropYUmJrw
bu (2-thylherl)(gthlaquoiraquoUtraquo
blaquoniyl buryl phtfraquolaquoUte
dt-^t-^xjrvl pfttfuiLitY
dj-n-octyl pitflaquoLitraquo
dirthvl phtruUtt
OArriett^vt prraquoT^Lraquot
bnzoltklaquonihnicer
22 Chronium
ire ev^rescei as uc ^ ^i-~ht-
Lab 1U N o 28B-1
C l i en t I D 1 R R 7 A A R
RASpoundNEbTRAL COMPOUNDS
benroltb)fluorraquorgtthfflf
benzoraquollt)fluor intone
ltrylaquo-gte
bullcenioithylen
raquomtirraquoenlaquo
ben z oltxh i)per v lene
lloorene
poentnthrrne
dibnzo(4h)laquonthricrne
mdeno(I23-rt)pvre-ie
pyrene
VOLATU-Ei
bullcrelem
bullcrvlonio-Ue
benzene
caj-bon traquotrraquochloraquo-idr
Ctilorobernene
l2-diehlongtethne
iii-tnctltiorotKraquor Trace 1 T 1 -4)Ctilorampe^hArw
l f 1 ^-tric^i lor oefvtrve
l t l 22-teTrtclloroetl^Ane
ehloroethraquone
2-chloroltthr|viw| ttrve-
Chloroform
1 1 -ltSicMorot^nr
trinraquo-l2-dictiloroetrne
12-d^loropOStn
trinil3^ichloroproone
eis-lJ-diChloroprooene
rrhylberuene Tarce methrlene ehlor tat Trace
Ct1 or o m e t Kirgte
bromometKtrte
bro mod i rfi lor o rrgte t Mne
Uuorotrlchloromethraquo^e
OJ CJ lor od 1 f 1 uoro met hraquone
chJorodibromometKATgte
laquotrlaquociloroethrrx
toluene 9
tricolor otheir
fsw
T9
Sifi-TOSO)
(73B)
(7IB)
(75B)
(7(B)
(77 B)
(71 B)
(71B)
(SOB)
( t lB)
(I2B)
U3B)
(M B)
(7V)
(3V)
(4V)
(4V)
(7V)
(10V)
(11V)
(13V)
(14V)
(13V)
(14V)
(11V)
(23V)
(21V)
(30V)
(32V)
(33V)
(34V)
ltlaquoV)
( raquo J V )
(44 V)
f raquo 7 V )
(UV)
(V)
000 (30V)
Tlfl 151V)
(15V)
^00 (14V)
(17V)
(UVgt
-1 ZINT
CAS 30-32-J
205-11-7
207-01-1
211-01-1
201-14-1
120-12-7
111-24-2
14-73-7
13-01 -laquo
33-70-3
113-31-5
121-00-0
107-07-t
107-13-1
71-43-7
34-23-3
101-W-7
107-04-7
71-35-t
75-3-3
7^-00-5
71-34-5
75-00-3
110-73-1
(7-14-3
73-35-4
154-40-5
71-17-5
10041-07-6
10041-01-05
100-4I-
73-OT-2
74-17-3
74-13-1
73-25-2
75-27-4
73-41-4
75-71-1
174-41-1
127-U- IOUIS-) 71-01- 75-OI-
130
Lab ID Mo 2887-4
Phys i ca l d e s c r i p t i o n of sample C l i en t ID 4A5760
Liquid Sample was predominantlv a hvrlrnrarhnn bl pnd
Sanple workup Voli t i le f ract ion PEG Extraction (SW 846-5030) Scrnivola t ile f rac t ion Sonication Extraction (SW 846-3550) Inorganic f rac t ion Acid Digestion (SW 846-3050)
AC3D CS3U POUNDS 5AipoundNEUTlUgtJ- COMPOUNDS
ri CAS PPraquo CASf
(210 U-04-2 2raquot- tricMorophrnol (7)6) raquo-32-l braquoniolttVyre
[EM 51-50-7 ^-cti 1 or raquo-m-lt rlaquo laquoo 1 (7raquoB) 203-M-2 biMo(b)(luorinth^f
2 A) raquo5-57-J 2- cfiloropheryjl (7 3 B) 20701 benro(ilt) floor in tlaquo^e
(31 A) 120J3-2 2raquo-ltJicWoro(ygtlaquotx)l (74B) 2II-OI- chryve^e
(MA) 105-47- 2l-dimlaquothvloSrrgtol (77 B) 20Uraquot-J bullcwrioMhylene
(57A) u-73-3 2- ruTroohrgtol (TIB) 120-12-7 raquontnncergte
(34 A) 100-02-7 -oitrophenol (7gtB) lraquol-2raquo-2 benio(ghi)cgtrrylngtlaquo
(3Agt 51- 21-3 2 -4 initropherwl (SOB) tt-73-7 fluorme
(tOA) 53-37-l t-dinitro-2-mlaquothy lpNlaquoxil (II B) 15-01-4 pheAinthrrnlaquo
(A) I7-U-5 tgtentraquochlQroiywnol (I2B) 53-70-3 dibenplusmnoltraquoh)fcnthrraquocrne UJJ 101-55-2 rfwtwl (I3B) lraquo3-3raquo-3 indenol 1 23-cd)vrtie
(UB) I2raquo^X3-0 pyrer BASENEUTOAL COMPOUNDS
VOLATO-ES (161 I3-32- raquoclaquonraquophttgtngtf
(5B) 12-17 -J btniidir (2V) gt 07 -07-1 bullcrolem
(IB) 120-17-1 l^^iricfvleroboMux (3V) 107-13-1 bullcrvlonit Jlaquo (raquoBI IIS-7t| SeraquoChlorotgtlaquoterlaquo (raquoV) 7IJ3-7 benient
(I7S) 4772-1 heLCMorolaquothinc (tV) J-23-5 crtgton wtrraquocMoidf (UB) I11-U-I bll(2lttllorolaquot^w gtetNer (7V) 101-W-7 ltAtoroxniergtlaquo
(203) Jl-31-7 2 -etvl or onlaquo ph traquo I en e (IOV) 107-04-2 1 2-ltlicMorolaquoTKlaquone
(25B) raquo5-30-l 1 2-dichlorobenzene ( 1 1 V ) 71-JJ-t llI-trichlorolaquotNlaquoe (2 B) 31-73-1 l3-ltlichoroblaquonzenlaquo (13V) 7J-3A-) 1 1-6 1 cM or Of t (Mr
(77B) I04-M7 I -di CM oro ben z eoe ( I k V ) rraquo-oo-j l12-niichlorolaquotfvirraquolaquo
(2IB) raquol-raquo-l )J-dichlcroblaquorLiidinr (IJV) rgt-3laquo-3 J122-tetrraquochlcrolaquoTrie
(33B) 12I-Ilaquo 2 2-dinia-otoluer (UV) 73-00-3 Ctgtloroltthne U4B) laquoJ-70-7 2 t-dtnitrotoluene (1raquoV) HO-73-1 2-ltJilorocthv|vL-v| etrveshy
(J7B) 127-M7 14-dip^wnylhydraiine (23V) C7-U^-3 Ctilorofcrm
(JraquoBJ 2Ot-ugt-0 CJuarlLnthefe (2raquoV) 7J-33- 11 -ltlicMorcxil^nr
(mei TOCJ-77-3 -chJorophcnyl phenyl laquoKr (xgtvraquo lK-^0-3 tnjM-l^-diC^lofCKtl^nf
( M B I IOI-J5-3 -6romophnyl phenyl ether (32V) 7I-J7-3 12-dicMoroprosaA
(raquo2B) 3M3I32) bU (2-cMarobopropyU rtNer (3JV) ICXU 1-07-4 trraquoni- 1 3-ltjictgtloroBoor^f
(OB) t l l f l - 1 bi5 (2-cMoroetfxgtrv) meihtrw lOOt 1-01-03 cu-O-dichloroprose- (32B) D-U-3 hrxaetilorobutadierw (UV) 100-laquol-raquo rthylbenien 1^00
(33B) 77^7- he i kcMor ocyc 1 openudi crw (UV) 7J-OT-2 rrveThvlerw chlof idf
(36) 7I-gtraquo| oop^troo (raquoJV) 7raquoJ7-3 CtgtlorBmethne
(338) raquo|20-3 nraquopfitfillaquofx 1200 (wv) 7raquo-l3-raquo bromorrgtlaquothne
(34B) nraquo3) nitrobenzene (raquo7V) 73-23-2
(CBI U-Xl-4 N -fl i iro lod iphen yU mi nr (UV) 7J-27- bro mod i cti lor o mT bull- (OR) 42l^-7 N-^itrolaquoodipropylmlrlte (raquoraquoV) 73-traquo-laquo tl uor o tr i cfi lor o mlaquoT itr (UB) I I 7 J I - 7 bn (^thylheraquoy|) phttilaquoUtT 110000 (XIV) 75-71J QJ ct )or oltJ 1 f 1 uoro rrgtei ^bull gte U76) U-U7 blaquonzyl buryl pttTfKUie 12000 ( j i v ) m-i-i ctil or od ib ro mo met h xnf (UB) M-7i2 d i -n -bo TV 1 ft thlaquo U tlaquo (13V) 127-11- te trraquo cfl lor ot hlaquoTgtf (OBI 117-4J-0 dj -n -oc t y1 Jgth fflaquo U re 6 200 tuv) iom-3 tolucie ^70
(7CB) u-u- djrthyl phtJMlire (17V) 7raquo-OI-4 irictilarcraquo^lt-ir (715) 1 3 1 - 1 1 - 5 oVnrrhyl pMtfaUte (UV) 75-OI- v i M v l CMor idr
(T76I 5-55-3 blaquorgtzo( Unihrlaquocme Xylenes 1SOO
Cad- iurn 2 2 on Chromium - - Z I N C ^ ~ P r
Ai results arc expressed as ugc weight as received Xo entry denotes not detects
Lab ID No 2887-3 5A 57709 Phys ica l d e s c r i p t i o n of sample Cl ien t ID
LiquidSludge Liquid appeared to be a hvdrnc-Arhnn blonrl
Sample workup
Vol i t i l e f r ac t ion Methanol Extraction fSW 846-5030^ Semivolatile fract ion Sonicatlon Extraction fSW 84 f i_3550gt) Inorganic f rac t ion Acid nic-psr-inn fSW 846-30501
ACS3 COMPOUNDS BASENEUTRAL COMPOUNDS
f f t CAS CAS (2IA) tt-04-2 (738) JO-32-J DCftZ OTamp p V^^^ff
(22 A) 3laquo9-50-7 p-cttl or o-m-cre laquoo 1 (7VB) 205-99-2 p^^izot oil lyor 4-^ t ^ltf ^^
(2 A) raquo5-37-l 2- CJiloroprieno (75B) 207-01-9 blaquonioltllt)flultxtn^it
(31A) 120-13-2 2raquo-dictgtlcr8tgtrfX)l (74B) 211-01-9 Chryeolaquo
(3 A) 103-47-9 2 -d irrgtet hv Ipherto1 (77B) 201-94-1 laquocnphthyle^
(37 A) 11-73-5 2- rutrop^enol (7IB) 120-12-7 bull^thrjc c^
(MA) 100-02-7 -flitroprlaquorv3l (79B) 91-2-2 bcnroltKhi)pefraquoler
(79A) 31-21-3 2 -d in itr eoricno 1 (IOB) 14-73-7 tluoren
(40 A) 33-37-l 4-d in itr raquo-2 -met hy Iphtnol ( I IB) 13-01-1 poltrtAOthrvTgt^
(44 A) 17-14-3 plaquon1 CM or o^eno I (I2B) 33-70-3 dib^fi-o( 4(K)Aji thirl c c^f (43A) 101-93-7 prwnol (S3B) 193-39-3 indcnotlIJ-ctflsvfie
(SB) 129-00-0 pyrene ftASENEUTRAL COMPOUNDS
( I D )
(5B) 92-X7-3 b^zidrw (2V) 107-02-1 bullcrolrm
(IB) 120-17-1 1 2 fc-Tr ICJ caro blaquoni crw (3V) 107-13-1 bullcrvlonitrij
(93) 1IU7I1 Seraquochlcrotgttniegtlaquo (4V) 71J3-2 blaquonienlaquo inn (17B) 4777-1 hexat^lorcwthgine (4V) H-23-5 carbon ttTricllixidf
( I I B ) 111-wJ bll(2-lt3^1oroltt^w)ether (7V) 101-90-7 ciloroblaquonzene
(20B) 91-31-7 2-ctdo-ont she Ime (10V) 107-04-2 12-dieftloroerane (25B) 95-50-1 l2-dilorobenzene ( 1 1 V ) 71-35-4 11 1 -tricMorotn-laquo
(2ampSI 51-73-1 13-dicMo-obenxerw (13V) 73-3-3 1 1 -d i CM orcxt M-
(77 B) I04-H-7 1 -di ci 1 or o benI erw (UV) 79-00-3 llJ-WiChlorolaquoflaquonlaquo
(2J6) 91-90-1 SS-dKJilorotxniidinc (13V) rraquo-3laquo-3 l122-tetrlaquocftlorelaquoTrne
(35B) 12| |k-2 2fc-dintrotoluene (14V) 73-00-3 diloroeth^e
(gt4B1 404-20-2 24-diniTrotoluenlaquo (19V) 110-73-1 2-cMortxfthv|vL-raquo trlaquoshy
(37B) 122-447 12-diphenylhydriin (23V) 47-44-3 cMoroform
(J9B) 204-U-0 Ouormntherve (29V) 73-33-i ll-diCMorolaquot^nf
(fcOB) 7005-77-3 k-cMarophfy| prlaquonyl etScr (gtOV) 134-40-3 trraquonraquo- 1 2 -dicMoroc t Nenf
(raquo I6) 101-35) raquo-6romoprny| phenyl rther (32V) 71-17-3 12-diChloropostn
(raquo2B) JH3IO2-9 bU (2-ltplusmnlaronopropyl) rthrr (J3V) 10041-02-4 trni-l)-diirMoroxtgtOpnf
(OB) I I 1 - 9 I - I bu (Z-chloroethxjrv) metSampnlaquo 10041-01-05 CU-D-djcMoroproOf-W
(32B) 17 -U -3 hiraquocfilarobutraquodiergtlt (3JV) 100-4U rttyligtlaquonitrgtlaquo 5300 (33B) 77-raquo7-raquo hrxicftl or ocrclopei tidier (UV) 75-09-2 nxthylenf ctilor ifif
lt3B) 71-391 ao prior or (raquo3V) 7raquo-17-3 rtloromrtha^r
(356) 91-20-3 nlaquoprithienraquo Trace (44V) 7raquo1Jraquo bromltmlaquoth^
(MB) n-93) ft i vo b^nz c^^ (raquo7V) 73-23-2
(425) U-30-4 ^bullf i^OftOOL^ri^ny lArrunf (UV) 73-27- bro mod i cgt lor o i~ t gt
U3amp1 Ul-4-7 N i itr CrtoO ip ro py 1 laquo ml r (raquo9V) 73-49-k U uor o IT 1 et loront Mrgt (UB) II7-1I-7 bu (2-Ihythlaquoryl)prtfUtr 59J300 (30V) 73-71-1 dj ci kr olt11 f 1 uoro rrrt (Nrgtraquo
(47 B) L3-41-7 txniyl burvl phthlaquoUtr ( 3 1 V ) I2-1-1 ch1 or od i b ro mo mi IMP r
(UBI U-71- 0-A-fcurl BMMliw (13V) 127-ll-i rt tr t cM or of tNr
Uraquo6) 117-li-O di-n-oCTv| pnttlaquoUfr 6000 (UV) lOt-II-3 toluenf 5700 (7CB) U-447 djrthvl p^tfvilirt (17V) 79-01-4 WiCMoroth^e ( 7 J B I U l - l l - 3 d^M^vl prttgtraquoUW (UV) 73-01- vinv t cMor 10 (77 Bgt H-35-) brto(raquollaquonthncrTraquo Xylenes 19000
Caen 1U~ 1 Chromium =2 Z I N C
All results are expressed as up g weight as received No errrv ripn^t-plt
Lab 1Lgt No 2887-5
rhyr i r n l d e s c r i p t i o n o f sample C l i e n t in 6857710
LiquidSludge
Sample workup Vol i t i l e f r a c t i o n PEG Extraction (SW 846-5030) Semivolat i le fr action Sonication Extraction (SW 846-3550) Inorganic f rac t ionAcid Digestion (SW 846-3030)
AOD COMPOUNDS BAStNELTTRAL COMPOUNDS
rr i CASI CAS (21 A) tt-04-7 (736) 30-32-1 bntoltraquogtprrene
(23A) 3-9-50-7 p~lt1 or o-m-c rraquo1 (78) 205-99-2 ben to( Sgt )1 1 uor raquon I he-gtf
(7raquoA) 93-37J 2- etilorophenol (73B) 207-01-9 beriioltk)(luortntrgt^f
(3 IA) 170J3-2 2raquo-dicMoroprnol (7(B) 2II-OI-9 eifVMTie
(3 A) 03-(7-9 24-4mlaquoThvlDheno| (77B) 20l-9(-i bullceraoMhyler
(37 A) tt-73-5 2- rue-oorienol (718) 1 20- 2-7 laquoflthrraquocene
(3 A) IOO-02-7 ^Mtroprwnol (7fB) 191-24-2 beraquoMoltsrM)plaquovllaquox
(39 A) 3I-71-5 2-4 ini tr ophero1 (tOamp) K-7J-7 tluwtrie
((OA) 33-37l (-lt iMtro-2-methylphenol (tlB) D-01-J phenATithrene
(4A) I7-44-J pentichlorophenol (128) J3-70-3 dilwnioltraquoh)laquonthrraquoceif
(OA) IOI-95-2 prwnol U38) 193-39-3 indeno(123-cd)vcne
(MB) 129-00-0 pyrergtlaquo 6 ASENEUTILW- COMPOUNDS
VOLATH-tS ( I B ) 13-32-9 ftCYTNA pO IT H I raquolt
(38) 92-17- o^nzioinc (7V) 107-02-1 aero le in
( IB) 120-I2-I l2k-o-i(3iloroblaquontergtlaquo (3V) 107-13-1 laquocrvlono-U
OB) Jl l-7fc | he I raquocti 1 or o blaquonI enlaquo (V) 71-43-2 Oltf2 tO^
(17B) (772-I he uc^i 1 or of t h ne ((V) 34-23-3 CJU JOO Tt TTlCfllo^ iCpound
( I I S ) bu(2-rfilcroethv|)ether (7V) 10J-90-7 laquoWoroblaquonzeoe III-44-4
(KB) 9I-51-7 2ltfMoronlaquoohttvraquolwe (10V) 107^)4-2 1 t2^ojo^loroetfft^c (2JB) 95-50-I 1 2 -dichlorotgtlaquorlene (11V) 71-55-4 1 1 1 -trichloroeihtr (251 541-73-I 13-dchlorotxniene (13V) 73-J4-3 1 1 -dieMoreeraquohraquorlaquo
(77Bgt 04-lgt4-7 1 mdash djcMorobenlene (IkV) 79-OO-3 t12-tricriloroeflaquofgte (2gtB) raquolraquo-l 33-didMoroblaquonjidirlaquo (13V) 79-34-3 1122-tetrcnicroeir^ne (33B) 12 I I 4 -2 Z4-diniiroioluerlte (1(Vgt 73-00-3 e^loroetruuie (KB) (04-7C2 2 (-dinitro toluene (19V) 110-73-4 2ltJilorolaquotr(v|vLnraquolnhlaquo (175) 122-447 12-dipr-enylfiydrmiine (23V) (7-44-3 chloroform
(J1B) 704JJ-O Huor^thrr (29V) 73-33-4 lI-ltJicMoroltthcne
(OBgt 7003-77-3 -ctJoroprienvl phenyl ether (JOV) 134-40-3 irirraquo-12-dictila-olaquotrlaquone
( raquo I B ) IOJ 33-3 -6ogtmoprienyl phenyl ether (32V) 7I-I7-3 l7^lichlorepreoine (laquo2BI 3H3raquoO2raquo bit (2-chlororaquoopfT5pyO ether (3JV) 10041-02-4 trint-l3-ltJicnloroBlt-ooee (OB) 111-11-1 bis (2-cMcroetro(v) metSuvr 100(1-01-03 CU-lJ-itflloropOO-^
(376) t7-U-3 hraquoz raquoch1 or o bu tlaquodi ene (J1V) )00-1- erhylberuer 1400 (33B) 77 -gt7- hei tchl or ocyc1 open traquodi ene (raquoV) 73-09-2 methylene chloriCf OB) 7raquo-3raquo-l BO prior one (raquo3V) 74J7-J eMorametrutne (33B) raquol-raquo-3 naphtfalene 100 (UV) 74-13-9 bro rrvome t hrgt (3iB) n-raquo3-3 niireblaquor)iergte (raquo7V) 7J23-2 (CB) U-XH N -01 ITo tod 4gthenyU rru rr (UV) 75-27-4 bro mod i ch lor o rrx t f4Ugt ((36) 42IO4-7 N-nnroodipropYlraquomlrlaquo (raquolaquoV) 73-4t-4 JJuorotr lchloronvlaquoiMftlaquo (Uol U7-1I-7 ba (2-etrylNraquoYl) phtt^Ure 100000 (30V) 75-71 -raquo dj cftlcr od U 1 vraquooro rri NUT
(47 Bl 13-44-7 t^niyl butvl phthiUte 13000 (31V) 124-41-1 chlorodibromorrwt^r
lt U E gt ) U-71-2 d-ojjurvl phtf^Ure (13V) 127-11-4 tr trbullcti loro rirr
laquoraquo6gt 11704-0 dl-fl-OCTvl pfltMUM (UV) 10t-ll-3 toluene fiin (TtS) raquo-laquo djrthvl phttuliTr (17V) 79-01-4 tricolor oethenr lt 7 | o l 131 -11 -1 (UV) v i n v i chlcwidr dimrlKyl rrftlaquoUTraquo 75-OI-J
(T75I J4-35-J blaquoTMOlt^trrlaquocr^ gtylenes 1200
Cadr ium 3 Chromium 21 ZINC 150
All results are expressed as ugg weight as received y0 entry denotes not detect
Iah I D No 2887-2
Physical descr ip t ion of sample
Strained Soil
Sample workup
Voli t i le f rac t ion PFG Extraction (^W 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-3540) Inorganic fract ion Acid Digestion (SW 846-3050)
ACS) COMPOUNDS
rn CAS Tft CASf
(21 A) tt-04-2 (73B) 50-32-4
U2A) 71-50-7 P-ch 1 or o-m-cre laquoo 1 (7k 8) 205-11-2
(2 A) raquo3-37-l 2- chloroprraquoeno| (75B) 207-01-1
(3IA) 120-13-2 2raquo-4ichlorophenol (74B) 21UOI-1
(3 A) 103-47-1 24-dimethvlphenol (77 B) 201-14-1
(57A) U-75-3 2- njtroDhenol C7I5) 120-12-7
(MA) 100-02-7 a-flitrophenol (71B) |1l-2raquo-2
(51A) 51-21-5 2 -d in i tr o phetio 1 (SOB) K-73-7
(40 A) 53-57-l raquo 4-dinitro-2-methy lprnol (tlB) 15-01-1
(4 A) 17-14-3 plaquoitraquochloroorlaquonol (I2B) 53-70-3
(43A) IOt-13-2 prlaquonol (13B) m-31-3 (MB) 121-00-0
BJ KSENCLmLAL COMPOUNDS
(IB)
(3B) 12-17-3 bcnzidine (2V) 107-07-1
(IB) 120-17-1 1 2 k- tr i ch 1 oro benr ene (3V) 107-13-1
(IB) I1U7I-1 he it raquocM or o boiz ergte (raquoV) 7I-J3-7
(12B) 47-77-1 he traquoch 1 or oet hlaquo ne (4V) 54-23-3
(116) 111-- buC-cJiloroethv|gtether (7V) 101- W-7
(20B) 11-31-7 2 -ltft 1 or on ph ttvraquo 1 laquon e (10V1 107-04-2
(23B) 15-30-1 1 2 -dictilorobeni ene (11V) 71-55-4
(25) VI-73-1 1 3 -ltJ i ci 1 or o blaquoiz ene (13V) 73-3-3
(77 B) 104-M7 llaquo-dchloroblaquoMeoe (HV) n-00-3
(2IB) 11-lk-l 33-dicMorotxTLtidinr (15V) n-3raquo-3 (33B) 12I-U-2 2 ltgt -4 in i tr ot o luene (14V) 75-00-3
(MB) 464-20-2 2 4-d initrotoluene (11V) 1 10-7 3-1
(J7B) 122-447 1 2-diprieny Ihydrti ine (23V) 47-44-3
(316) 2O4-UO Ouorraquonthene (21V) 73-33Jshy
(WB) 7t)03-77-3 ^-cJJorophenyl prienyl ether (JXgtV) 154-40-3
(MB) 101-33-3 -6romopriefgtyl prienyl ether (32V) 71-J7-3
(raquo2B) 3431-32-1 bit (2-chloroboproprO ether (33V) 10041-07-4
(OB) I1U1I- I bu (2-ltMoroethorv) methane 10041-01-03
(52B) r-u-3 hexachlorobutadiene (J1V) 100-l-raquo
(33B) 77-47- he z raquoctlt lor ocycloqenud i crte (MV) 75-01-2
OB) 71-31-1 ao prior one (raquo3V) 7raquo-17-3
(33B) 11-20-3 nlaquopntrlaquollaquone (UV) 7raquo-13-1
(MB) n-13-3 nitrobenzene (raquo7V) 73-23-2
(UB) U-30-4 N-nnroiodiprienyUmine (UV) 75-27-k
(436) Ol-U-7 N-nitrModiproOYlmJne (raquo1V) 73-41-
(UB) 117-117 bu (2-laquothylheiry) phtrlaquolte 8800 (50V) 75-71-1
( 4 7 B ) L3-U7 blaquoniyl buryl phthaUte 30 (31V) 12I-H-1
(UB) U-7U-2 di-o-burvl phtrMUte U3V) I27-I1-
(416) II7-U-0 dj-n-oCTvl pritntUtr 1200 (raquo4V) IOUI1-3
17CB) U-44-2 djetiTi phrtultrt (raquo7V) 71-01-4
( 7 I B I 1 3 1 - 1 1 - 3 dimnfTraquo| prThraquoUtr (UV) 73-01-
(776) H-35-3 berMolta^thrCF^
Cl ien t ID 8 A - S 7 4 6 1
RASENEUTRAL COMPOUNDS
benzofbtfluor^tMe
benzodclfluorintoent
Ctiryiene
cenoithylene
raquonthrraquoctne
benzoltKhilpervlefgte
floor ene
prlaquofnnthrene
ltlibenplusmno(4h)knthricrnlaquo
inogtno(123-rt)pvrrne
pyrene
VCX-ATIIE5
bullcrolem
bullcrvlomn-U
benzene
carbon tetrtchloridf
chlorobenzene
1 2-oUchloroethAnf
lll-trichloroethlaquone
ll-dcfioroethrraquo
1 1 2-tricilorolaquothraquorw
1122-tetrichloroeTtvin
chloroethre
J-ctiloroethv|vinv| etrgte
chloroform
11 -denier oethene
trinraquo- 1 2 -4 cMor oe t hens
12-dcMoroprooine
^Lns~ I f 3-4ic^ lo^opf oo^^^
Cli-l 3-dicMoroprooe^e
rttiylbenzene
methylene cnlonfle
Ch 1 or o me t hane
bromome thane
Trace
bro mod i cMor 0 me t hane
(Juorotrlchlorome thane
chlorodibromometKinf
tetracnloroethervp
toluenetr icMoroel he-if
Trace
CacTiiun Chromium ZINC f
All resxil ts are exprp^spr i K-i
Phys ica l de sc r ip t ion of sample
Strained Soil
Sample workup Vol i t i le f ract ion PEG Extraction (SU 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-5340) Inorganic fract ion Acid Digestion CSV 846-3050)
ACE) C30laquo POUNDS
m CA5i CASraquo (2i A tt-C-2 (73B) JO- 52-1
(22 A) J1-JO-7 p-ch 1 or raquowTv-cre 101 (7raquoB) 203-raquoraquo2
(2 A) raquo)57-J 2- chlorophenol (73B) 20701-
(31 A) I25J3-2 2k-4icttlltroptlaquonol (7tB) 211-01-1
(3A) IO)-7-raquo 2-dimlaquothvlpNrnol (77 B) 20l-raquoi-
(37 A) u-rj-j 7- niTTOphenol (TIB) 120-11-7
(MA) 100-02-7 -rtropN-rraquol (7raquoB) lraquol-2-2
(JraquoA) JI-21-) 2-d initroprietys 1 (IOB) U-73-7
(MA) 53-37-l Udinnro-2-mlaquothylphenol (UB) I5-OI-J
(Agt I7-U-3 pentichlcropwnol (126) 33-70-3
laquo)Agt 10l-raquo)-2 phenol (I3B) IJ3-31-3
(MB) 12raquo-00-0 AASCVflCUTRAl COMPOUNDS
( I B ) I3-32- bullcnraquophtber
(56) raquo2-17) bnzidirlaquo (2Vgt 107-02-1
(IB) 120-12-1 l2btrilt7tlorotgteizegtlaquo (3V) 107-13-1
traquoB) IIraquo-7fc | heikcMeroblaquonzergte (V) 7l-3-2
( I 2 B ) 4772-1 he ueft 1 or olaquot hraquo rgte (tV) laquo-23-3
( i ts) III-- biraquo(2-cMoroethv Dethrr (7V) 101-W-7
(20Bgt 1I-3I-7 2-cMoroflaquophthlene (10V) 107-Ofc-2
(2)6) raquo5-50-l l2-dchlorotgtlaquonzefgte (11V) 71-33-4
(28) 3l-7)-| 1 3-didMoroblaquonrenlaquo (13V) 73-3-3
(27B) 10t--7 l-diclorolgtmzerlaquo (iV) rraquo-00)
(216) raquoI raquoltbull- 33-dichloroblaquoMidiflaquo (13V) 79-31-
(356gt 2I- l-2 21-dinitrotoloen (UV1 73-00-3
(UB) laquogt- 20-2 2 (-dinitroto luenlaquo (HV) 110-7J-J
(376) 122-W-7 14 -dipheny Ihydrzire (23V) lt7-M-3
(396) 2O--0 tJuoruMSene (2raquoV) 7J-35- (OB) 7003-77-3 -c^lvophenyl pNrnyl ethlaquor (30V) 1H-W-)
(MB) 101-33-3 bull-bromopriefiyl prienyl ether (32V) 7t-t7-3
ltraquo25) 3HJI-32-1 bU (2-cMoroaopropyl) rthrr (33V1 10ltX 1-02 -6
(06) l l t - t l - l bis (2-cftloroetSorv) metwne 100lt]-01-03
(32B) C7U-3 heraquoraquochlorobutidierx (31V) 1 00-41-
(3361 77-7-raquo hexiOilorocycloptfiudlerve (raquoV) 73-0raquo-2
(56) 71-51-1 no ph or one (raquo3V) 7raquo-17-3
(3)6) raquol-raquo-3 rwiphtfalme (UV) 7raquoJ3-raquo
1361
LUB)
H-133
14-30-4
nitrobenzene
^ ri i iy o too ipf^^ y LA r^i rtf ^ 7V) (UV)
73-23-2
73-27-
(436) t21--7 M^TI iff frfcO^ip ropy Ift mJf^ (gtraquoV) 73-4raquo-raquo (UB) I17J1-7 bu (2-rThyiruMcyDpMtvUtr 570 (jov) 73-71-1 ( U B ) U-41-7 blaquonzyl buryl phthlaquoLite (31V) l2k-raquo-l ( U B I U-7I-2 di-n-burvl pitftALtTe (raquo)V) 127-lt-fc
(OB) 117- -0 dJ-fraquo-oCTvl phlJ^Ute (UV) IOt-It-3
(7CB) 14 -W- 2 djelftvl phtfalitt (17V) Tt-01- ( 7 I B I 1 J I - I 1 - ) duTNnhylphttsraquoUw ltUV) 75-01-
(77BI X-))O lgtmrlaquoigtmhrraquoctf
Cadmium f iQ Chromium 15 ZINC
Tab ID No oo -
Cl ient ID 8A-A-64220
fcASENEUTTRAL COMPOUNDi
blaquofuo(raquo)pyrrtgte
bfizo(b)(loortAth^e
benzo(k)f|ulaquoin1herf
Ctiryiene
cenDraquoMrwlene
fcftT^rict^t
D^flZCT (fftl)pC^ V Itf^p
(luorene
phen^threne
diiwnztKthlanthricene
indlaquono( 1 23-lttf)pvrene
oyrene
VOCATtLES
bullcrolem
bullcrvlooitriJe
bervteoe
carbon WTTicMoridf
chlorobenze^e
12-djcMoroetfane
1 1 1 -tricolor ex tKraquon
1 1 -dicMarcx t hrlaquo
1 1 2-triChlorothraquorw
1 122 -laquotrraquocM or o-hraquorgt
cMoroettu^e
2-cMorlaquothv|vuy| rseshy
chlexeform
ll-dchloroctfgtn
tri^iraquo l 2laquoflic^ loTo^i rgtcnt
12-dicWoroproptrs
Winl-l3-dicMoropfooene
Cu-lJ-djChleroprooe^
rrtiylfrenzene
methylene ctiloride 0 64
cMorometHAne
bromomlaquothlaquone
bnsmoform
bro mod i eti lor e me t Nine
0 uor o tr 1 cMor e rrgtlaquo t Nnlaquo
dj di tor olaquol If 1 uoro mraquoi Nrraquo
chlorodibromonveiKme
re tr a en 1 or or fxrvr
toluene
D-ieWoroefwne
entry denotes not detect All results are expressed as ugg weight as received Xo
Lab 1) No 2887-8
Physical descr ipt ion of sample
Sf-rs inpH 9 n i l
Sample workup
Vol iCi le f ract ion PEG Extraction (SW 846-5030)
Scmivolat i le f ract ion Soxhlet Extraction (SW 846-3540) Inorganic fraction Acid Digestion (SW 846-3050)
ACD O3MPOUNDS
m CAS fPraquo CASf pi A) tt-Ot-2 Zraquot- tritilorophrgtol (73B) 30-32-1
ft M -3o-7 p-cMorraquo-m-crTraquool (7kB) 205-raquo-2
(2 A) raquoS-37-l 2- cMorop^erxgtl J73B) 207-OI-raquo
(31 A) 120-13-2 l^ictiloropix)l ^7tB) JII-01-
(3 A) |03-7-raquo 21^-dimeThvlphenol (77B) 20t-raquot-l
(J7A) tl-73-3 2- rutropwnol (71 B) 120-12-7
(MA) 100-02-7 -MO-opwnol lt7raquoB) lraquol-2-2
fJraquoA) 3I-2J-3 2-dinitrop^laquoTgtoI ((OB) U-7J7
(laquogtA) J34-37-1 lt-dinitrfr-2-methylpwrxgtl (I IB) I 3-0 1-1 (raquoAI 17-1 3 pcmacMcroptonol (S2B) J3-70-J UJA) IOI-raquo5-2 phenol (IJB) MJ-39-J
(tBgt 12raquo-00-0 RASEfZUTRAL COMPOUNDS
( IB) 13-32-f raquocertaprithene
(3B) J2-17-3 twnndinc (2V) 107J2-J (IB) 170-I2- lr2k-triOilorobenzerlaquo (3V) 107-13-1 (raquoB) I11-7I-I hei bulllt1 ore blaquont ergtlaquo (raquoV) 7l-3-2 (1B) 47-72-I he ucft 1 or oe t h n (tV) 3-23-3 (116) |II_wJ bu(2-ctiIarothvI)laquotNer (7V) 101-90-7
(20B) raquoI-JI7 2 -cW or orvraquo ph tf I ene (10V) I07-Ofc-2 (23B) J3-30-I l2-lt5ictiloroblaquonzeoe (11V) 71-3J- (245) 3I-7J-I 13-dic^lorotxenzenc (13V) 7J-3-3 (27B) 104-K-7 1 mdash diC^lorobtnrerve ( lraquoV) 7^-OO-5 (21 B) raquo|raquo| 33^icftlorobenzidifv (I3V) rgt-j-3 (33B) I 2 I - U - 2 2ltgt-dinin-o1olvraquorgte (UV1 75-00-3
(J4B) 404-JO-2 21-dinitrotoluerve (1raquoV) 110-73-1
(37B) I22-W7 1 2 -d ipheny Ihydra z ine (23V) C7-14-3
(318) 2O4-W-0 tJuortnihrne lt29V) 75-3J- (kOBt 700J-77-J ^-tfMoropheTgtyl p^enyl ether (30V) 1J4-W-3
( raquo I B ) IOI03-J raquo-6romopfgtenyl phenyl ether (32V) 7I-I7-J
(06) 3H3raquo-)2-raquo bU (2-tfilerobopropyO ether (3)V) 10041-02-i
(OB) lll|| bii (2-cMoroethoxv) methane 10041-01-03
(37B) PUt) hxzraquocMorobutadienlaquo (J1V) 100-raquol-raquo
(JJB) T7^7U heztctilarocrclotMnttdicrgte (V) 7gt-0raquo-2 OB) 7l-3raquo-l BO ph or one (raquo3V) 7raquo-17-J
(338) raquo|20-3 rlaquopritrilaquolene (UV) raquo-laquo-raquo
(3iBl n-raquo3) nitrobenzene (raquo7V) 75-23-2
(CB) li-X)-t N -n i tr o tod ipheny U mi nr (UV) 73-27-fc
(06) CI-U7 N^iitroiodipropYUmlr ^raquo1V) 73-H-fc (UB) 117JI-7 bu (2-ethYlNerrl)pM^Utr 12000 (JOV) 75-71-1 (47 B) L3-U7 llaquoniyl buryl pht^UTe 2 800 ( 3 I V ) 2laquo-raquo-I (UB) raquo-7i2 di-o-ourvl pritfwiUrr (I3V) 127-lt-i (196) 117-14 3 dj-n-ocryl pritfiiUrr (UV) IOUIS-3
(TCB) J4-W-2 djnhYl phtfalitt (17V) 7t-01-lt (716 ) 1 3 1 - 1 1 ) damnhYl pMtuUTT (UV) 73-01- (77 Bl 3 33-3 frlaquon z olt raquo klaquom h rraquo c prgte
Cadmium T^ Chromiurn T Z T N C 100
Client ID 8A-C64221
BASENEUTRAL COtPOUNOS
bnzo(t)pyrrrie
benzobXluoriflthei blaquorizoltVHluorraquontrraquone
chryiene
bullcenphthylene
tnthneene
benzoltRM)perylene
fluorene
prienlaquonthcTTgte ditgtmplusmnolt4hluithrraquoctnf
indenof 1 23-cd)pvrf ne
pyrer
VOUATILES
bullcrolein raquocrvlonnrile benzene cmrbort Tetrichloride
chlorobenieoe 1 2-oUchloroethirie
11 1 -tricolor oethne ll-dvchlorolaquollMr 1 1 2-w icMoroethAoe l122-tetrieMoroeihilaquonlaquo
chloroetKvne JltJilorothvlvmv| ethe chloroform
11-dicMoroethent
trani- 1 2 -dicti lorolt t hene
1 J^JictiloroproBfVf
trim- 1 3-4ietiloroproperie
Cil-IJ-dicMoropfoOerie
rrhyUxrmene
methylene criloride
chlorornethine
bromome thne
007
13
tluorotr l^VoromlaquotNraquorgtt
da ch lor od 1 1 1 ooro frvet hraquone
chlorodibromometlvinf
te trraquocnloroeT rrrr
tricMoroetSmr
All results are expressed as us2 weight as receixred No entrv denotes not detect i
Phys ica l descr ip t ion of sample
SoilCake
Sample workup
vol i t i le fract ion ^FP FvfrarfMnn (ltU Rif i mdash Smrn
Semivolatile fraction Soxhlet Extraction (SW 846-3540^ Inorganic fraction Acid Digestion (SW 846-1050)
AC23 COMPOUNDS
rrt CAS CAS
(21 A) 11-04-2 2raquo4- trieMorophenol (738) 50mdash 3-4
122 A) J1-30-7 p-ctil or raquo-nvltrlaquo laquoo 1 (7laquoB) 205-11-2
12 A) 13-37-4 2- etilorophenol (75B) 207-01-1
(31 A) 120-13-2 2raquo-diclorophlaquoTgtol (74B) 211-01-1
(34A) 103-471 24-dmlaquothylphrnol (77 B) 201-14-4
(57 A) U-73-3 2- rutrop^nol (7raquoB) 120-12-7
(54 A) 100 -02-7 bull i tro p^c 01 (71B) 111-24-2
(J9M 31213 Z o trt i tr o poc^oI (MB) U-73-7
(40 A) 334-32-1 T^Hjinitrfr2^rt^T ny tp^gt^noi ( t lB) 13^)1-4
(44A) 17-44-3 pcnttchlaroprwnol (S2B) 33-70-3ltOA) IOt-IJ-2 pTUfNOl (136) 113-31-3
ftASENtUTRAL COMPOUNDS (MB) 121-00-0
(IB)
(56) 12-473 Iwnndine (2V) 107-02-1(IB) I20-IJ-I 1 2 4-tr icJi lorobeniervr (3V) 107-13-1(IB) 11 1-711 hexkcMarobcnzeM (4V) 71-43-2(126) 47-72-1 hexch)eroeihlaquone (4V) 54-23-J( I I S ) 111-4- bu(2-eMorlaquothv|)laquothr (7V) 101-10-7
(208) 11-51-7 2-c^laronraquophtfgtlene (IOV) 107-04-2(23B) 1J-30-I 1 2-dichloroblaquonime (11V) 71-35-4(2651 341-73-1 gt3-ltiictitaroblaquonxcnc (13V) 73-54-3
(27 B) 104-47 l4-dicMorotKmrerlaquo (14V) 71-OO-3
(21 Bgt 11-14) 33-4ichlaroblaquon2idine (15V) 71-34-3
(338) 121-14-2 24-dinitrotoluene (14V1 73-OO-3(J4Bgt 4O4-20-2 24-dinitretoluenc (11V) 110-73-4(37B) 122-447 lraquo2-dip^nylhydrraquoxirlaquo (23V) 47-44-)(MB) ro--0 Uuaranthene (21V) 73-33-4(406) 7003-72-3 4-ltUorepfraquonyl phenvl rtSer (30V) IH-40-J( raquo I 6 ) 101-333 4-6romoprlaquonyl pflaquony| ether (32V) 71-17-3
(OB) 3H3I-J21 bll (2-cti|orobopfrgtpyO ether (33V) 10041-02-4
(OB) I11-1I-I bis (2-cMaroethoxv) methane 10041-0103
(57B) P-44-) hczw^lorobundiene (J4V) 100-41-4
(JJ6I 77-47-4 htTicMarocyclojxrtadien (44 V) 75-01-2
(346) 71-31-1 aophoroo ( raquo ) V ) 74-47-3
(33B) raquo|203 r^pn thA Icr^ (44V) 7 -raquobull J-
(546) n-i3) H i frovCftZfl^^ (raquo7V) 73-23-2
142B) 14-30-4 S -n i tr o laquood ipheny Lt mi nc (44V) 73-27-4
(43 B) 421-447 N^iitrotodtpropyUmlne (41V) 73-41-4(MB) 117-41-7 bu (2-raquoThylhlaquolaquoyl)pMtgtlaquoUtr 52000 (30V) 73-71-4(4B ) 13-447 (xniyl bviryl ptithiUre 6700 (3 lV) 12raquo-l-l(UB) 147U- di-n-burvl pMhUre (I3V) 127-11-4laquoampgt 117-4J-0 ltjj-n-octyl phtfaUtr (UV) 101-11-)
(7CB) U-44-2 djrthyl pht)raquolraquort ( I7V) 71-01-4( 7 I B I 131-11 ) dimrthyl phttgtUTe (UV) 73-01-
(T76) H-33O tgtnzoUtlaquoftthncmr
Cadmium l i r^ Chromiurn 2 0 ZINC 140
All results are expressed as ugg weight as received
Lab ID No 2887-6
Cl ien t I D 8AD64219
Dd20( amp py(re
blaquonio(bHluorraquoflthegtlaquo
berzo(Mf luorampnThene
chryraquoefgte
ftctnAoMhy(ergte
raquonthncene
benioltK(M)plaquovlene
(Juorene
picnintfirtTX
dihwvioltraquoh)laquonThrraquocene
mdeno(l23-rt)pvrraquone
pyrene
raquocrolein
raquocrvloourUf
benzene
carbon laquoTrraquochlofifle
chlorobenieo
l24JcMarolaquotlxine
lll-trichlcroltthlaquorlaquo
-ltJicMorigtnKraquorgtlaquo
l12-trichlorolaquot^nlt
1 1 22-tetrcftloroetrvtnlaquo
^tloroeThAne
2^^1orolaquothvlvuiivt ethe
etila-oform
ll^liailoroltN^
trtni-12-dichlcxolaquoTfgtene
12-ditfiloropropine
trtni-l3-ltjicti|orocltX)t^f
cu-l3-djcMoroprooe^f
rttiylbtnztTve
methvlene cWoride
ciloromnM^f
Dco^^oroct^A^^
bromofarm
bromodicJiloromltlfraquon
tluorotrlctiloromttNir
diOilorodKloororfvrir^Ar
ct^lorodraquobrofTorrgttKAne
wtricnlorampctNrr
toluene
trirfilorolaquoThfif
v i n v CMor ilt3^
No-entry denotes not detect
ih i n N O 2887-9
Phys ica l d-asc r ip t ion of sample Cl ient ID 10A64222
Linnir l ShtHcp
Sample workup Volitile f rac t ion PEG Extraction (SW 846-^030^ Semivolatile fract ion Sonication Extraction (SW 846-3-540 Inorganic f ract ion Acid Digestion (SW 846-3050)
AOD COM POUNDS BAStNELTTRAL CXLPCXJNDS
rrt CAS CAS
(21 AJ U-Ot-7 Z4- trichloropSeno (73B) 30-J2-
(22 A) 55-30-7 p-ctilarraquo-m-erelaquoo1 (7kB) 205-raquoraquo-2 ben r olt b) 1 uor ifl t Ne~gtf
(2AJ raquo3-37-i 2- ctilorophenol (75B) 207-0raquoraquo benzoltllt)floofraquontslaquor
(31A) 120-13-2 2raquo-ltJictilcroooenol (76) 211-01 9 ctiryjene
(3A) I03-47- 2k-dimethylphenol (77 B) 20t-raquo4-i bullceruphthv lerraquoe
(37A) U-73-3 Zmdash Ajtropheooi (7SB) 120-12-7 fcntftricene
(34 A) 100-02-7 w^ i ff o phe rgto 1 (7raquoB) Iraquol-2-2 ben z o( Rh i )per v 1 me
(31A1 51-21-3 Z^ - d iA iV opheno1 (SOB) U-7J-7 Iluorene
(MA) 3X-37-I T v-4iAiv omdash laquo mdash fl^et ny Ipoenoi (I1B) 13-01-1 poeftraquonthrene
(4 Al 17-14-5 p^ntBCfllGrOprlC 1 Vol |I2B) 33-70-3 dilgtenioltraquoh)laquontwraquocenr
USA) IOl-raquo5-2 phenol (13fi) U3-31-3 indeno(l73-cd)oraquorrie
(MB) I2raquo-OO-0 pyrene RASENCimiAL COMPOUNDS
VCH-ATUL5 ( I B ) 13-32- raquoclaquonraquophtflaquorgte
(58) 12-I7-J benzidire (2V) 107-02-1 bullcrolem
(IB) 120-J7-I 1 2k-tr icnlorobenzene (3V) 107-13-1 acrvlonitr UP
(IB) 11U7I-I heKicMorobtnzme (raquoV) 7I-A3-2 benzene
(176) 4772-1 hexcftla-oethtgte (4V) J4-23-5 campr~toon TeTrscftlo itit
(116) III-- bii(2-lttilorolaquothv iVether (7V) lOt-W-7 chlocobenieo
(2C5gt raquol-3l-7 2-cM oroolaquo ptittu lene (10V) I07-O4-2 1 2-dicrtloreetranr
(23B) raquo5-30-l 12-dichlarobenime ( 1 I V ) 71-33-4 11 1 -tricMoroethr
(24 B) 31-73-1 1 3-ltl icJgt lor obcn i ene (13V) 73-3^-3 1 1 -dicMoroeth^i
(27B) 104-^4-7 1 4-dich lorobenzergte ( t k V ) n-00-3 11 2-tncfiloroetvlaquorie
(215) 91901 33-didMoroblaquozidinr (I3V) rraquo-3k-3 l122-tetrraquoOMo-oethne
(335) 121-I-2 2-dinitrotoluergte (ItV) 73JW-3 chloroethjin
(3461 (0420-2 24-dinitrotoluene (19V) 110-73-1 2-cMoroethraquo|vuiv| trgteshy
(37 B1 122-44-7 12-diphenylhydrnine (23V) 47-44-3 ctiloroform
(316) 204- Jgt tluarmrnhene lt2V) 73-35-4 1 1 -^iCMoroeThe^f
(C6) 7003-77-3 -chlorophenyl poenyl ether (gtOV) 154-40-5 trraquonraquo-l2-dicrloroltthene
(bull16) 101-35-3 raquo-6romophenyl phenyl ether (32V) 7I-I7-3 l2^ipoundMoroproBirgte
(raquo26) 3H3I-32- bit (2-cMarobopropvt) ether (33V) 1 004 1-02 -4 trmni-l^-dictilwoproom
(OB) l l l - raquo l - l bis (2-cMeroethoxv) methane 1004 1-0 1-05 cu-13-laquoicMoroprooe^e
(J2BI D-U-3 rraquolaquoeftlorobutraquodilaquooe (JJV) IOOJM- rttylbenzene
(336) 77 -raquo7- hezactilarocyclooentadiene (WV) 75-OT-2 methylene cniorifle
(56) 7raquo-3raquo-l ao ph or one (raquo5V) 7raquoJ7-3 eMoromeirune
(33B) JI-20-3 nraquophtMlene (UV) 7raquoJ3-raquo bromomethAftf
1X6) n-raquov) nitrobtnxerw (raquo7V) 7J-25-2
(CB1 14-30-4 J -ltii TT o vxJ ipheny U rru rraquo ^UV) 75-27- bro mod i cfilor o me t r)e
(CB) 47I-U-7 N-nnrotodipropylraquomJne (tV) 75-4raquo- 11 uor o tr i cMor o me t htgte (US) V17-1I-7 bu (2-eifrrlhryl)praquogtttilaquoUMshy 69 000 (30V) 75-71-1 di cti tor odl1 1 van m^i rajgtr
(476) U-U-7 benzyl buryl phihiUte 890 (31V) 12laquo-kraquo-l cMorodbremof^etNrr (US) U-7I-2 di-n-burvl prittuUre (13V) 127-lt- Uraquo6gt 117-t-0 dJ-laquo-ocTvl phttviUre (UV) IOLtS-3 Wluenr
(75) u-w djrrhylphtnltt ( i rv) 71-01-4
(715) t J I - l l - 3 dimnhrl pfthUte (UVI 73-01- viny l CMcriOr
(779) J4-35-3 0laquoMo(UnthrraquoCflaquoe
C a d m i u m 130 Chromium 20 ZINC 170
o nnn Z-UUU
^0(^ Trace
All results are expressed as ugg weight as received No en
APPENDIX E
PLATES
I I I I I I I I I i Plate 10-1 Troy Mills Landfill with a backhoe excavation
in progress in a former drum burial area
I I I
I I I I I I I I
I I Plate 20-1 NAI field investigation team preparing for
Level B activities during the drum excavation task Troy Mills Landfill
I I I
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
I I I I I I I I
I I Plate 20-3 NAI field investigation team member undergoing
personal decontamination at the hot line Troy Mills Landfill
I 1 I
I I I I I I
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
1
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
I
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
I I I
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
I I I I I I I I I I I 1 I Plate 53-3 Pigmentsludge deposits interbedded with
soil layers in Excavation 8A Troy Mills
I Landfill
1
20 SAFETY PLAN
A Bureau of Hazardous Waste approved safety plan for on-site
activities was developed for the waste characterization phase of work
because of the potential for encountering hazardous materials The
safety plan is presented in Appendix A of this report It assesses the
overall degree of hazard identifies specific potential hazardous
situations and presents guidelines for personnel protection and action
levels as required The plan was made available to all field personnel
during the field work
The magnetic and topographic surveys were considered to be low
hazard activities with a prescribed level of personnel protection (LPP)
of C or D depending on the results of air monitoring Level C proshy
tection involves wearing a full face respirator with organic vapor dust
combo cartridge Tyvek suit over work clothes rubber safety boots and
gloves Level D protection requires cotton coveralls or other work
clothes safety shoes safety glasses and possibly a Tyvek suit
During the drum excavation and sampling task which was
determined to be moderately hazardous Level B protection was preshy
scribed Level B protection requires that personnel wear SCBA (self
contained breathing apparatus) chemical resistance Tyvek suit steel-
toed rubber boots and gloves Plate 20-1 shows NAI personnel on the
site preparing for Level B activities Plates 20-2 and 20-3 show
personnel decontamination equipment and the hot line during the drum
excavation task
30 MAGNETIC SURVEY
To delineate the landfill area underlain by steel drums a
high resolution magnetic investigation was conducted by John F Kick
PhD consulting geophysicist The magnetic method was chosen over
other search methods because ferromagnetic substances (drums) were the
target objects and the majority of Troy Mills other wastes are
non-magnetic (largely fabric scraps) Dr Kicks report is presented in
Appendix C
Eighteen parallel rows of magnetic field measurements were
made along north-south lines The measurements were made at 10-foot
intervals along the rows This work resulted in a detailed contour plot
of the magnetic anomaly (Figure 1 in Appendix C) The source materials
which cause the magnetic anomalies do not usually directly underlie the
peak of the anomaly A shift is caused by the inclination of the
earths magnetic field and by dipolar effects Figure 30-1 shows NAls
delineation of probable source areas for the magnetic anomaly and
peripheral areas which may contain some magnetic source material The
plotted source area is generally the area between the peak of the
magnetic anomaly northward to the zero anomaly contour This is to
compensate for a southward shift of the peak of the magnetic anomaly
from the center of the source deposit The complex geometry of the
anomaly necessitated much interpolation between peaks and ridges
gt QJ
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40 TEST PIT EXCAVATION
41 WORK PLAN
A series of test pits were excavated in the Troy landfill for
observation and sampling More specifically the purpose of the
excavation was to estimate the number and distribution of drums buried
in the landfill determine the condition of the drums (full empty
crushed rusted leaking etc) identify types of buried and drummed
waste and verify the results of the magnetometer survey A stratified
random sampling method was used to choose 10 locations within the
delineated area of magnetic source material This insured that
excavations were distributed randomly across the landfill and that the
resulting data could be evaluated with a level of statistical
reliability Excavations were also selected in areas on either side of
the anomaly which were considered free of buried magnetic material and
also where drums were visible at the landfill surface
The following procedure was used in choosing the locations for
the random excavations The center of the delineated area of magnetic
source material was used as a base line The base line was drawn onto a
map of the source material (Figure 30-1) and then divided into ten
60-foot long segments Using a random numbers table a point-distance
was located on each segment (designated the random station) and a
line drawn at that point perpendicular to the base line segment Again
using a random numbers table a point-distance (designated the random
offset) measured along the perpendicular line located the point of
excavation The grid coordinates for each excavation were graphically
determined from the grid overlay and then field-located from the
surveyed grid intersections Grid coordinates and selection data are
presented in Table 41-1
It was judged that 10 excavations in the delineated area of
magnetic source material and two excavations out of the area would be
sufficient to characterize the site would produce statistically valid
TABLE 41-1 RANDOMLY SELECTED EXCAVATION SITES TROY MILLS LANDFILL TROY NEW HAMPSHIRE
BASELINE RANDOM RANDOM EXCAVATION GRID SEGMENT STATION OFFSET
NUMBER COORDINATE (FEET) fFEET) (FEET)
1 7E+15 65N 0-60 26 16
2 9E+5 13S 60-120 110 9
3 8E+0 31S 120-180 140 7
4 4E+5 48S 180-240 230 26
5 3E+8 45S 240-300 254 20
6 OE+8 45S 300-360 394 50
7 2W+15 24N 360-420 465 14
8 5W+6 42N 420-480 518 20
9 6V+14 74N 480-540 548 7
10 8W+5110N 540-600 611 31
Locations are plotted on Map in Figure 30-1
data and could be expected to be completed within a scheduled 2-3 day
work period
42 FIELD WORK
Test pit excavation was conducted in two phases On the first
day each of the 10 random locations (Excavation 1 through 10 Figure
30-1) was probed to a depth of 2 feet using hand shovels On the
second and third days excavation was conducted using a combination of
hand shovelling and power backhoe The NAI field investigation team
consisted of six members Four of the team members were equipped to
work at Level B for work in and near the actual test pit excavation
(See Plate 42-1) The other two team members spent much of their time
with personnel and equipment decontamination and refilling compressed
air bottles at the hot line Mr Timothy W Drew an engineer of the
New Hampshire Bureau of Hazardous Waste Management was present during
most probing and excavation work Mr Robert Lynch an experienced
Level B equipment operator of Jet-Line Services Inc operated a power
backhoe which was provided by Troy Mills Inc
An average excavation size using the backhoe was approximately
7-feet wide and 10-feet long Excavation continued downward until drums
were encountered or to a minimum depth of five feet Drums were careshy
fully uncovered and fully described A total of 17 samples were
obtained from uncontainerized wastes (solids dried sludges pigments
stained soil) and where possible from drums using EPA sampling methods
and protocols All of the excavations were backfilled upon completion
of this task
Each sample consisted of one filled 8-ounce glass jar sealed
with a Teflon-lined lid Samples were submitted to Resource Analysts
Inc (RAI) Laboratory in Hampton Falls NH for priority pollutant
analysis
Air monitoring was conducted during each excavation using a
Foxboro Century Flame lonization Organic Vapor Analyzer (OVA) an HNU
Systems photo-ionization detector (HNU) and an MSA combined oxygen and
explosimeter High explosimeter measurements were considered cause for
an immediate halt in exploratory work in the interest of personnel
safety
10
50 RESULTS
51 GENERAL
On November 17 1983 Excavations 1 through 10 were initiated
using hand shovels to a depth of approximately two feet A total of
two buried drums were discovered Excavation 13 was completed and a
third partially buried drum uncovered On November 21 1983
Excavations 1 through 9 were completed and on November 23 1983
Excavations 7A 8A 10 11 12 and 14 were completed An additional
42 drums were uncovered on the last two days of excavation
Excavation Locations Seventeen test pit excavations were
completed at locations which are shown on Figure 30-1 Two pits were
excavated at three of the locations Noteworthy aspects of the
excavation operation are
Excavations 1 through 10 were randomly located in the area of delineated magnetic source material (on-anomaly)
One excavation connected Excavations 4 and 5 This was done because of the proximity of Excavations 4 and 5
Excavation 7A was located immediately adjacent to Excavation 7 Excavation 7 was located on the boundary line of the anomaly and proceeded in a southerly direction off the area of delineated magnetic source material (off-anomaly) Excavation 7A was initiated in the opposite direction (north on-anomaly)
Excavation 8A was initiated one foot north of Excavation 8 after the latter was abandoned due to the detection of a potentially explosive drum
Excavations 11 and 12 were selected off-anomaly to the north and south (respectively) in areas considered to be free of buried magnetic material (drums)
Excavation 13 involved minor hand shovelling necessary to uncover a partially buried drum located on the periphery of the anomaly at the east end of the landfill
11
Excavation 14 was a surface scrape which extended from an exposed drum found to the south of the magnetic anomaly northward toward the anomaly
The details of each excavation are presented in Table 52-1
Drum Locations The excavation results support the
interpretation of the magnetometer survey with buried drums as the
source of the magnetic anomaly With the exception of a few strands of
wire found in Excavation 1 ferromagnetic materials other than drums
were not encountered during the test pit excavations
Drums were foundin 9 of the 10 excavations located in the
area of delineated magnetic source material (See Plate 51-1) No drums
were found in Excavations 11 and 12 located out of the area of
delineated magnetic source materials The location point for Excavation
7 was on the boundary of the anomaly Excavation 7 which proceeded
south away from the area of source materials was free of drums
Excavation 7A proceeding north toward the area of magnetic source
materials uncovered 6 drums Excavation 14 located just out of the
delineated area to the south produced unexpected results Five drums
were uncovered just under the surface in an area with low positive to
slightly negative total magnetic field values It is possible that
Excavation 14 was improperly located in the field If adjusted just 20
feet to the east it would be well into the delineated area It is also
possible that a negative dipole derived from the mass of material to the
southeast is cancelling positive readings at this location
Fill Material and Vegetation Cover and fill material was
predominantly fine to medium sand with an occasional boulder Till with
a siltclay component was also used as a cover particularly at
Excavations 6 and 7A This material was densely compacted and difficult
to dig through Excavations 7 11 and 12 each extending to a minimum
depth of 5 feet were characterized by uniform silt and fine to medium
sand and traces of dark discoloration Excavation 12 was located in
to a s
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o O ro mdash 1
O O
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a mdash
O O
Q
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1
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lA 1
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WO
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CM
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mdash =^ a
S 5^ 0lt r ~ ~
1 1 1 a- lA
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shy shyU LJ LJ
rr shyo laquot- t_
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fc ^ aa L 1_ ou C- C
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CVJ CM ro
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ro bull-CM
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z o
r-Q
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o X UJ
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a CM CVI CVJ fO lA CM 1 lA lt-
a o
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lt ^^ gt lt UJ C N X mdash _ in
o X o X CO
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ro X ^y X O rmdash
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X
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23
eo ETC CU
gt i- Nlt (_ mdash
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i-tt) gtOO
bullDC
gt 0) C
T3 O
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tgt
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C5
E 33
E-0 gtgts-O CD mdash T3 1- N JO ( =
0 0 U - O C5 t- t-ushy ro L jj bull
3 C 0 gtgt cnmdash 4J mdash
bullD CD bull C E E
I t -
lt Q 0)eo i c
lt mdash
mdash L
aagt E C CO mdash
CO i-W CO
bull obullDmdash 0
gtgt mdash
re bull E bulllt-gt
gtgt mdash
CD bull E-0
L W O lt tu en i-fgt c O Q
gtgt0 3 O mdash 4-gt i C
CD X -o eo E 0
w co CD bullO 4J COmdash ^ C d)CO O ^E 1 O W
co eo 4J bull
bull C CU ^ O ^
C O W
c eo Qeo mdash eo
t-JJ 0 E
o mdash c mdash
eo w
D C c eo CD laquo)
CO T3 0 4J Q) - C 0 mdash CO gt mdash E O w mdash
O 01shyC CU O O CD aw
CD O CO u- sshy amdash
re lt c eo cc c CD mdash CD 1- ltshy C C_ C re c co o - O X X CO CO3 gt CO 3 gt to E O O co O co CO 3 jt w O cfl 0) eo
cr LJ
LJ-J u mdash j CO 0amp5
a O 1 O
Q
1 1 i l
CD Dl bulla
CO _ mdash O D o
O ^ (A
ZX mdash Ld
O
en 3 10 O a
LJa a
Q 1 1 O
Q
+
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X
_
mdash
o o I
gtgt O
h~Z
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mdash i-
1A 1
a a co agt C
LJ
sectK
Z= tM O 0 to bullo
X
mdashshyo
CD O
o mdash _ o
E umdash 3 E eo sshy
ltr-toZmdash
mdash s
0shy c
^
^ gt o
D o
a-rmdash
1
Q-
0 0oo r-V
tO 0
= mdash
O
tO 0
= mdash
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Q O
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1
awi
i mdash _ 3
Imdash I O
bullO C
1- 3 gt 0) bullo sshy co w
bullO CJ ID O X E C CU tt) bullw^ T3
w agt u C pound -gt
a a CO CD
mdash L 4J CD o gt
T3 gt C CO UJtt
2 mdash1 LJ Z) d CO 1 1
COO
~
lt O
~ I 1 1 I
Dl C 10 3 -D
lt - T J O
Dl C
1gt Omdash O bulllaquo Xl- i s o cu
Q lt3 toz cshy
mdash W f
r-B O c
mdashgtgt3 01O O u
W ID CO bullgt C -O mdash 4-gt 4-gt C
O -x mdash1 CO o CU c c co
1
OZ ZO o mdash Ol-
LJ -
L
0
1
C- bull 14 u- o laquoc~
bull mdash u bullDT3 O laquoccce tshy ^ D
l_ Cshy CCO O 0 0-0 Qmdash
CJ I- r-CM
1 1
U-Qshy
bull bullbull ^
O t_ 0 Q
-LJ
raquol
a o iT o c o
U) c
c u CD O
I I I CU c
Q) CJ CU W a ltshyon J2 o l- E E gt QCO CD O
I I I
ID JJ CU ES
J-gt imdash O Q Z CO w t --shy O mdash O 3 O laquoshy ^ c
_ICO a 0 0 0
^ sect5oa I-Q
CO X u_ y o- o=gtLJt-a
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^
1
1
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1
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1
t
_
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a
lA
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0 O
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C 1 O
W 3
U L CO O
4J CO
0mdash CCD gt j ti --shy c JJ 4J
1- laquo 3 = C 3 or cu ogt tn Q -shy
E L n CD J-gt o o gt gt s o ---shyDior 3 3
mdash Tgt o cr cr mdash mdash CU 0)
o a CD -a OLJ U CU
N CU COT 4JT3 poundmdash 0gt U V
raquoT3 mdash agt OJ gtgtcu laquo c c
T3 O
C
C
Zlshyo ui u- Li ^ ^~bullgt lt LJ
lAXvOX
VO X ^ X
Xcjltshy
lA x
CM
O x
3shy
_ X
r^5 X
_ X
CM X
mdash c^ C3 O
c a bullbull o c c
mdash 4J O I I 4J
01 JJ 4J 1C laquo
3 t- C raquoJ O L (D CU C mdash o a~o mdash o
i i
C J J W CO II) O W IT OC N 03 = OJJ C O I- -= C O
I I
o o
ON X mdash
CMr-raquo
00 Orshy
X CO
vo ro O C 5) JJ Jshy I- I gtJZ-00 s a o
LJ CO eo UTJ a- I I O C X J O gtZ 1 re O
i CM
LA
LJ
O mdash c imdash LJ lt a gt y lt 2
ltCO O
O^mdash
laquoshy rmdash
CM Tmdash
n rmdash
_^jshymdash CO
LJ
j ^ |
52
14
what appeared to be natural materials although its location on the
cleared and leveled landfill tend to contradict this possibility
Most of the landfill is vegetated by a thin layer of grasses
sedges mosses and annual herbaceous species The northeast corner of
the landfill is unvegetated and cover material appears to have been more
recently applied This section is elevated 4 to 6 feet above the rest
of the landfill and appears to have received a second newer layer of
waste A 4-foot thick layer of carpet waste was encountered in
Excavation 1 but not in other excavations This section is adjacent to
the newer active landfill The landfill area just west of the access
road crossing (near Excavations 7A 8 and 8A) was also unvegetated due
to relatively recent grading operations
Ground Water The landfill appears well drained as ground
water was not encountered during any of the excavations Excavated
overburden was damp from the recent heavy rain but intergranular macro
pore spaces were free of water
OBSERVED QUANTITY AND CHARACTER OF DRUMS
A total of 45 drums were observed buried in the landfill
Table 52-1 presents a drum log describing each excavation and the
observed drums Data on the contents and condition of drums is
summarized in Table 52-2
Of the total drums observed 15 (33) were crushed flat
Although these could possibly still contain small amounts of waste they
are probably considered empty under RCRA guidelines Thirty (67) of
the total drums discovered were uncrushed and capable of containing
waste Seven (88) of the 8 drums sampled contained liquid or sludge
waste material Thus at least 7 (23) of the uncrushed drums contained
some liquid or sludge waste
15
en C Cl
bullo gtraquormdash
c mdash a
o c re bull mdash c
~ o mdashbull 4Jmdash
10 0 mdash
gt O
ro CO
fcshy0
c
C
vgt 3 0
1 rea
-gt
mdash
3 o T3
lt-O
C j C
CB 3 TJ ii i- 3 mdashQCOa
ifl u bull c c
t_ o
mdash shyO
mdash
L re N
co
t-O
mdash
mdash lfl
V) O
CO N CO pound re
0 mdash
^1 10
ltP O C raquo
CM reO
o f shyi O
mdash mdash 3 - D
c 1
CD bulllaquo
mdash3
D mdash
1 C
Q CO
CD Ifl 4-gt CO
Q
CM
r-
Ul
Q Ul gt EC Ul CJ CO o t5bullpound
z O mdash
C Ci o^
O Cbulla 3v iC MW5 CO 4J3 u CS- Ifl CBC J C O - U
gt Cgt Omdash Oi O
U- 0) Ifl bullgt-gt 1 W C
to lt-gtT3 gtmdash
0) gt shyJ 0)
C OltJ bull O T 3 C D C P
133mdash 4J bull ifl tshy Vgt~ V a O V4JJ
C o
C mdash
O Ifl
3 fc 0)
i-
c
U) re gt
ai C mdash
C mdash
CO gt c o
bull to y 3 cc Q
ltbull-CB
1 4Jin
bullD reCD jCJJC TJCD mdashbullD bull mdash
CD 0t- u iflo ifl
0 C ^-
CB laquo
3 ltbull-
0)^shy
C
0 Cgt O
1 O CTl C
T3 1 mdash CB O
mdash CB mdash in J o 3 tfl C ^ CO 0 gtltgtshy
O gtgtc 01
CO 3 1- mdash C Cregtmdash laquo
TJ W TJ mdash i re traquo-
shyU mdash
O Q
COCO^^
mdash ^
mdash gt C 0gt mdashO ~ bull
Ul
o auO
CCUl
mdash K o tO Ul Q
mdash OT30Jj c mdash4Jt- Jpound O Wre c i re03 gt
lt~i- laquo o ai
0 ) 3 gt O ^crc Ifl - CO -^mdash
3 mdash Q iflmdash 1- O 3 3
O V O ltraquo-o laquoTJ
gt
T3 - o
gtgtmdash J-gtmdash
Dmdash
6-o
09 bull mdash gtpoundbulllt-gt
re a
Ul X t5
Cpound O Z
fl) mdash^ C B gttflOl3T3T3l_ 3 Q)O mdash mdash
tn mdash
shyD CB
mdash mdash
mdash tt
CO C T3 poundi mdash JCmdash re
^ C O C X CB ^ - S - C C O mdash re O Q DW4shy
re shyu O 1
O Ul X EC Ul mdash
x a^s ox
CO
^) Z
J
1-o t-Ul X r-u 0
o j c gt T3 i -gt c tu mdash c u r e mdash
- C D mdash T3 - C M mdashbullOJJQmdash re3inecrec u c r e o mdash lt~ bullz c~4J O CX t ^Jw o r e -gtgtOgtgtshy3 c j t shy re mdash mdash ret- i o Qmdash gtgtpoundgt a
i reraquo CD 0) bullbull Ifl t-
Q ) t ) O pound O ^ laquo gt - Ow re re ro re re -gt Q mdashc 5 shyu a j-gt D t- raquomdash mdashCB C re C CO 3Q mdash O mdash O U
Htshy ae cu coo)
1 O i i
shya shyo j CD C bullgt o mdash c o c o coco mdash plusmngt o ~a v c en CD
mdash C O
raquoCJ 3C c re amp- ogtCD J o 3 CC C I-Omdash 3gt O
3
O ro
Ul X 1mdash
u O
Ul o r-Z Ul
gtV~ omdash Dlshy ^mdash mdash wre3 i cc
mdash cr bull gtJJ mdash C mdashi QIgtJ^re a shyJQI- o 0mdash
O bullO 3laquo laquo
jjmdash ureoO mdash O N 0)rc3recomdash4Jt-4JpoundmdashC C mdashmdash mdash u
1
shya 0 -
mdash gtgt re-raquo-gt CUD laquo E CD
^ J-1
CJ eoc
4JCB CO
mdash O
C 1- C mdash O C B C B C E J mdash J ltshy shyo cn o o c o r e c shyU -gtO OJC D ifl roc
T3 3 I U 3 laquo-
Ifl CD 1 W ^J 4 J 4 J c -aiflj jc
CB C r e O C B lt-gt -Jgtcoraquo C C -WE O O ) ~ O O O mdash O
Ul O
c ui =gt z
o
1-CC Ul Q
Q z ^ Ul
2 gt Ul O
o Cpound
^ CO
Ul Q ^
z o
(O U S Q
Slt
t5 lt
Z5O
1mdash z ui
Qa Ul
CD 0-1
u m O_J
O2^ltUl
O CC Ul Q
VOCO
CNlA |3
VO ^
CJ |CO |
CJ CMI3 f~ rojO VO rolo
^
ymdash3 CC
roCM
ro O ICNj
ro rolvO ro ro
ro A
rolvO r-jO
00 C3N
ec a m
r3
CO
3 a ty r-
cc Q
(M CM
to z
m 3 c O
u _i co
U-O
O 3-IObull - I c y
fshy lt- ICO r- r-ICM O U lfN ro -mdashla1 f~ laquo- ]CO bull- -ICM O O J|O O
c U) CO
mdashbullre re
mdash re
mdash i ltC c tz
j lt
i lt
5 0 0 G O o o o o z bullU 4J J h- J shyJ tmdash tmdash
^33
J3 3
O 3
Q 3
_Cr(bull
shyC 3 t)
CC IP y
C2 zgt c J
1mdash O 5
53
16
The condition of the uncrushed drums was highly variable with
only 4 (13) rusted and decomposed to the point of structural weakness
These drums were found in Excavation 10 at the far west end of the
landfill which is believed to be the oldest section (See Plate 52-1)
Interestingly two almost new looking drums were also found in
Excavation 10 at a greater depth than the four rusted drums The
remaining 26 drums were observed to be generally intact and structurally
sound Some were dented partially crushed or rusty
CHARACTER OF WASTES
Air Monitoring An OVA and HNU were used to monitor the air
for concentrations of organic vapors during each excavation Above
background instrument readings indicative of contamination were
regularly recorded when monitoring the air just above or inside of
drums A general contamination of the ambient air in the workspace was
noted only during Excavation 8A where above background readings of +13
in the excavation pit and of +6 above the excavation pit were recorded
Explosimeter readings were obtained from three drums -- 10 lower
explosive limit (LEL) from drum sample 10A 20 LEL from drum sample 6B
and 100 LEL from a drum in Excavation 8 Instrument readings are
presented in Table 52-1 and Table 53-1
Visual Observations The following types of waste were
observed during the excavations
fabric waste (carpet waste)
crushed drums
drummed waste - liquid sludge and solid
uncontainerized dried sludges and pigments
stained soils
Fabric waste scraps of synthetic non-woven fabrics5 heavy
carpet-like fabric and backing material were found only in Excavation
17
CM
CO LJ fmdash O z
laquo 4J
u TO 4-gt
c bullmdash
k bull mdash E mdash 3 3 i-^ O
mdash TJ --raquo co co 4J
E CO O U L U
E 3 c T3
C O a o
is
CO c to 3
U
TO
E O t_ U_
o o
1 ltmdash c
mdash tmdash TO 4J bull C TO 0 O o c u 3 TO
t_ 0) 0 4J
U)
mdashOTOgt
Cw bull aco jc
N 4J a
mdash L Q) re co T E
CO
bullo gt egt mdash c mdash bull o ^^73 C E gtO O mdash 3 J-gtmdash N 4J L 3 mdash 1--C gttTC bull
CX 01C JJ TO O mdash
TO trt mdash t- E mdash 3 JJ a O Q
C I 0 X E mdash C mdash CO
mdash o laquo (D-O mdash O O bullbull B Ol o -cmdash e oic f~ to a (gt TD mdash
E 1- Cpoundmdash 3 O O CO P m T1
L u
T3 CO
lto sshy0 O CA W
laquoT3 O CO 0 C J= CO tlaquo Q bull 3 O Ol 1- C o mdash 3 E a
3 E E i- to
Z L
mdash bull mdash O 4-3 Cl Q
bullD 0) CO T5 N CO mdash C -P 1 0 U TO O mdash 4J Cfc
mdash U) c shybullgt O w C O Q (5 4J 0
3 -J bull U)
5 gt TO_ U
bull gt pound mdash 3 mdash L ro TD
JJ-D - CO TO laquo QO
C 0
^ 0) T3 mdash O
r to 3
O O L L
0
01 TO gt bull
tshy mdash OT3 mdash
CD O C N U) O mdash
TO O CO mdash C C
bull^ ~ CO TO TO gt U iJ
mdash C W to O
5 c c 4J 3 CO X LJ
^ bull bull0 laquolt- ej
TO CJ CO mdash C JJ
z u to mdash T3 4J ai TO CD C laquo bull c c ugt o cr 0) bull mdash CO mdash O bull gt JC TO ^ mdash Q CO O JJ O Q bull- CO to mdash to c Z CC O il mdash 4J gt
mdash Omdash O1O CD mdash U) TO C X mdash O CO C L mdash Cvv O W pound G CO C C
O gtgtgt C C mdash CO C TO CO 3 E mdash -J laquo 1- bullgt CO 0 to
bullo CO
cshyo bull
ugt C CO TO c w 4J-Q co e a c
mdash re TO in E to
Q
JJ c bullo
a LJ co E bull LJLJ
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ax
z o mdash1mdash Q
mdasha o CO LJ a LJ ~J
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bullmdash
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bullO bullmdash
gtgt3 TO CT L mdash Olmdash 1 O CD mdash 3 a CT cshy re 3 a c- o
^j C CO E Ol
bullmdash CL
bull CO 01 D 3
U
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bullmdash av^ CO 4J IA TO 5
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bullmdash ^
bulla CO L
4J
C CO o 3
(A C TO
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03
ai_ 3 a bullo bull mdash 05 3 O) 00
mdash mdash C c gtgt G CO
O O
bullo^ = c a 0)
E C O umdash u a L_ bull OlCD mdash
4J mdash
u) obulla o u) amp 5 c -a 7 O C mdash o mdash _ i- (0
CO E laquoJ
C
a
bulla c bull o bull
c bullQ CO
3 01
CT mdash mdash a mdash -v
t- Ol CC-D 0) 3
CJ raquo
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bullo 3
lt) bull_
gtraquomdash CO O 1- Ui O)
bulla ^ c mdash mdash mdash TO co in
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mdash TO
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CO X
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LJ
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tmdash CM CM ^_ CM
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18
bull -a gtgt CD
CO S jj
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bullo CD jJ
bullo z 3 O L
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CD 1-gt o CO
jpound cshy x mdash o mdash
- 0 1 mdash bshy
4J 1 CO
Z u
CO mdash T3 CD CD
co E C mdash z bullD 73 4J O JZ = CD ltshyO C CD
CD 4J laquomdash C
bullO Qmdash U N ET3 bull mdash 0 Cmdash i- L re mdash oltmdash o
O 1 f-u gt Z 03 shy3 mdash CD
O O tshyo
O (Q C N O mdash shy
o agt O 4-raquo bull z in jz 3 CO 4-gt
gt Q ltshy 0
CD JZ N w Oshy- O
laquo ^ mdash 13 mdash m
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laquo
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re 3 O L
CD U -D SshyCD CO CO N 0) mdash 0-E S GO CD CO L
i
CO UJ gtmdash
z laquo w mdash ffl JZ CO 4-gt 4J JZ
4_) t_ mdash bull
cz QJ co jZ C C mdash 4J
re (uS a z z
OX) mdash a) O W E
Z O O JZ bull CL V E
C (~ mdash r re O CD
obullz
-J VI O 4J z re o gt o jt o 5
mdash tshy Q mdash CO 0 Q) mdash j j a C5 E U3
mdash CO mdash 4JCO CO E
CO
JZ 0 3 mdash t_
E Ot3 O L
bull
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bullz o mdashfmdash Q
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O CO LJ O
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mdash mdash 0 10
bullc bull CD 0) C 4-gt mdash w CO CO 4-1 to
gtJ CD Sshymdash CD Q-O L- gt
CD 4^
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^
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bullD 4J C C CO CD
E -3 Ol CD mdash - a bullc cu mdash 4J mdash CO
v^4-gt C 0)E01 Q
agt 3 ^ j3
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t
bullabullmdash 3 CT _
mdash
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co (0
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i
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O rmdash 1 1
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c V
co in
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1mdash bullz LJ s
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1
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13
CD
Ct
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bullz ~ CO CO CO O
0 o ^^
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laquobullgt CM
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fshy
ltshy
fO CM
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20
1 (See Plate 53-1) This is the predominant waste material currently
being disposed of in the active landfill
Crushed drums were distributed throughout the original
landfill and were found in Excavations 2 4 4-5 7A 8A and 14 Some
drums such as those found under the road in Excavation 7A may have
been crushed by heavy equipment operating in the landfill Others like
those found at depth in sandy fill in Excavation 2 appear to have been
crushed before burial Drummed liquid and sludge wastes are also
distributed throughout the landfill (See Plate 53-2) They were found
in Excavations 1 4 5 6 8 and 10 These wastes are discussed below
One sealed drum was openedand found filled with refuse -- paper cups
towels paint covered rags etc One open and partially crushed drum
contained a dark granular solid waste This material was sampled
(Sample 10B) and found to be nonhazardous
Small deposits of dried pigmentsludge were found in
Excavations 3 4 6 9 and 13 Discernible layers of pigmentsludge and
stained soils were present in Excavations 7A 8 and 8A (See Plate
53-3) Of particular note was a 2 to 4-inch thick layer of
grey-colored dried sludge found at Excavations 7A and 8 All of these
wastes were sampled and the results are discussed below
Laboratory Analyses
Laboratory analyses were performed on 10 selected samples
obtained from both containerized (drummed) and uncontainerized wastes
Samples were analysed for 3 metals and 87 priority pollutants including
11 acid compounds 45 baseneutral compounds and 31 volatile organic
compounds Table 5-4 summarizes the analytical results and the
laboratory data sheets are presented in Appendix D
Of the 45 priority pollutant baseneutral compounds only 4
were identified in the samples that were analyzed Baseneutral
21
compounds and particularly phthalates were the most prevalent
chemicals and also were reported in the greatest concentrations The
highest levels of naphthalene (1200 ppm) bis (2-ethylhexyl) phthalate
(110000 ppm) and di-n-octyl phthalate (6200 ppm) were found in sample
4A a translucent red liquid obtained from a drum The highest
concentration of benzyl butyl phthalate (13000 ppm) was found in sample
6B a clear liquid and pink sludgepigment obtained from a drum
A total of 8 volatile organic compounds were identified The
highest levels of benzene (100 ppm) xylenes (19000 ppm) and
ethylbenzene (5300 ppm) were found in sample 5A a clear liquid
purple-grey sludge obtained from a drum Toluene was found in highest
concentration (12000 ppm) in sample 1A a purple-grey thick opaque
liquid obtained from a drum Methylene chloride (13 ppm) was
identified in greatest concentration in sample 8A-C a purple stained
soil and powdery waste Sample 10A a purple liquid obtained from a
drum was the only sample found to contain 1-1 dichloroethane (2000
ppm) Finally trace levels of trichloroethylene (sample 10A) and
111-trichloroethane (sample IB) were also reported
Samples were tested for three metals - cadmium zinc and
chromium The highest concentrations of cadmium (2200 ppm) and zinc
(5700 ppm) were found in sample 4A a translucent red liquid obtained
from a drum The highest level of chromium (52 ppm) was reported in
sample 5A a clear liquidpurple-grey sludge obtained from a drum
22
60 DISCUSSION
61 EXISTING SITUATION
Under existing conditions relatively small quantities of
volatile organic compounds (VOC) are indicated to be leaking from wastes
buried on the landfill site To date ground and surface water
monitoring results indicate relatively low concentrations of VOC in the
ground water and below detection limits in the adjacent brook (See
Tables 61-1 to 61-10) The results indicate that no potential health
risks from VOC and other constituents currently under observation are
being caused by the landfill operation to down stream surface water
users It would be prudent for Troy Mills to continue to monitor the
quality of Rockwood Brook upstream and downstream for VOC and on the
basis of waste analyses (previous section) to monitor ground and
surface water points for toxic metals and baseneutral compounds
62 SITE HYDROLOGY
An analysis of the hydrology of the landfill site was
performed in 1982 (NAI report of September 1982) The subwatershed that
contains the landfill site is (about 44 acres) a small fraction of the
watershed area that contributes to Rockwood Brook above surface water
sampling point C (about 1650 acres see Figure 62-1) This indicates
that most of the flow of the brook at point C (about 97) is contributed
by upstream watershed areas Thus leachate discharging into Rockwood
Brook from the landfill site can be expected to be diluted by over 30
times its volume This factor and the volatilization which naturally
occurs results in parameters detected in the Troy Mills monitoring
wells often becoming undetectable when they enter the brook
f 5
Geologic conditions which were defined in the NAI report of
July 1982 indicate that permeable deposits of sand and gravel overlie
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27
TABLE 61-5 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M5 (UPGRADIENT WELL)
Parameter Date Sampled 11-22-83
Specific conductance
pH2 81
Dissolved iron mg1 036
Dissolved manganese mg1 010
Chloride mg1 10
Phenolics mg1
3
023
Identified volatile organics
None identified ND
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (yg1)
28
TABLE 61-6 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M6
Parameter
Specific conductance
PH2
Dissolved iron mg1
Dissolved manganese mg1
Chloride mg1
Phenolies mg1
Identified volatile organics
11-dichloroethane tetrachloroethylene 111-trichloroethane
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vg1)
Date Sampled 11-22-83
152
lt002
29
6
0002
27 trace 140
29
TABLE 61-7 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M7
Parameter Date Sampled 11-22-83
1 47 Specific conductance
pH2 62
Dissolved iron mg1 002
Dissolved manganese mg1 0026
Chloride mg1 gt2
Phenolics mg1 0070
3 Identified volatile organics
111-trichloroethane 5
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vig1)
30
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34
glacial till and bedrock The sand and gravel deposits form a permeable
conduit through which leachate from the waste burial areas migrates
The permeable deposits lie in the area north of monitoring well M-l (See
Figure 62-1) In general the water saturated thickness of the sand
and gravel in the vicinity of the north-south access road is 6 to 12
feet
64 POTENTIAL FOR GROUND WATER CONTAMINATION
641 Estimated Quantity of Drums
The test pit excavation and sampling in the drum burial area
indicates a potential source of ground water contamination for the
future Many of the drums encountered were in fair to good condition
and contained liquid wastes An estimate of the number of drums in the
deposit was made with the following assumptions
1 The complex magnetic anomaly was simplified into a geometric solid 600 feet long 40 feet wide and 10 feet deep with a volume (V) of 240000 cubic feet
2 Each steel drum (D) occupies 105 cubic feet (including voids)
3 The density of packing (P) was assumed to be 50 of the packing that can be achieved with perfect cubic packing
THEN
N = estimated number of steel drums
N = (VD) (P)
N = (240000105) (05)
N = 11429 drums
The results of the drum excavation work provides a basis for
estimating the potential for specific types of chemical loading In
general three main classes of chemical substances were identified in
35
the drums The chemical substances included baseneutral extractable
organic compounds (mostly phthalates and lesser amounts of naphthalene)
volatile organic chemicals and metals
642 Phthalates
The phthalate esters found in the drums include
bis (2-ethylhexyl) phthalate ^0^3 benzyl butyl phthalate di-n-octyl phthalate Jd~7
Bis (2-ethylhexyl) phthalate was found in the highest
concentration at 110000 ppm (11 percent) Benzyl butyl phthalate is at
the second highest concentration 13000 ppm (13 percent)
Characteristics of those phthalates found are presented in Table 64-1
TABLE 64-1 PHYSICAL PROPERTIES OF PHTHALATE ESTERSshy
di-n-octyl bis (2-ethylhexyl) butyl benzyl DOP DEHP BBP
ALTERNATE o-Benzenedishy di (2-ethylhexyl) benzyl butyl NAMES carboxylic phthalate phthalate
Molecular Weight 3910 3910 312
Melting Point -25degC -50degC -35degC
Boiling Point 220degC 386 9degC 377degC
Vapor Pressure-mdash lt02 torr (150degC) lt001 torr (20degC)
Not
2xlO~7torr (20degC) Available
Solubility 3 rngfc (25degC) 04 mgfc (25degC)
58
13 rngH 48
Log octanolwater 92 873 58 partition coefficient 53 48
Versar Inc 1979 Water-Related Fate of 129 Priority Pollutants Volume II Prepared for US Environmental Protection Agency PBSO-20438 December
bullbullOther names listed in Versar 1979 vMore than one value has been calculatedreported
36
Bis (2-ethylhexyl) phthalate is the most well-studied of the
phthalate esters though the information on phthalate esters as a group
is limited The three phthalates identified at the Troy Mills site have
relatively low solubilities and are readily adsorbed onto suspended
particulates Microbial degradation is effective under aerobic
conditions bur is generally slower under anaerobic conditions
(nonexistent for bis (2-ethylhexyl) phthalate)
The above characteristics are important for two reasons One
the extent and nature of contaminant migration from the site are
dependent upon the physical characteristics Second the treatment
(clean-up) alternatives for contaminated ground water or soil can be
estimated from the characteristics
From the available information it appears that the phthalates
present at the Troy Mills site would be relatively immobile due to their
low solubilities and high adsorption rates The presence of toluene and
methylene chloride at the site however may increase the phthalates rate
of migration
It is important to note that none of the phthalates have been
found to be present in the monitoring wells nor in the surface water
sampled probably due to the low solubility and high adsorption rate
37
643 Napthalene u K r
Naphthalene has also been found in significant quantities in
the sampled drums Naphthalene is a polycyclic aromatic hydrocarbon and
has the following properties
Molecular Weight 12819
Melting Point 8055
Vapor Pressure (20degC) 00492 torr
Solubility in Water (25degC) 344 mgfc
317 mgfc
Log octanolwater partition coefficient 337
Versar 1979
Naphthalene has mid-range adsorption rates and solubility It is
therefore inferred that there would be some adsorption to soils in a
ground water environment It is important to note that naphthalene has
not been detected to date at the monitoring wells or the surface water
sampling locations This is expected to be a result of adsorption on
the soils
644 Volatile Organic Compounds
Volatile organic compounds tend to migrate readily within
soils and ground water They are therefore considered a threat to
surrounding ground and surface waters if they are released in sufficient
quantities
Volatile organic compounds were detected in samples from six
steel drums The total volatile organic (TVO) concentrations in the
38
wastes ranged from 9 ppm to 30100 ppm and averaged 8570 ppm In order
to determine the potential for future contamination by volatile organic
compounds an estimate of waste quantity based on information from the
drum excavation program was made It was assumed that 7000 steel drums
in the deposit are 60 full of liquid waste with an average TVO
concentration of 8570 ppm The computed volume of liquid waste is
231000 gallons with an average TVO concentration of 8570 ppm This is
equivalent to about 1980 gallons of pure TVO
Two of the volatile organic compounds that have been most
prevalent in the existing ground water monitoring system are
111-trichloroethane and ethylbenzene The EPA suggested no adverse
response level (SNARL) for 111-trichloroethane is 330 ugpound for
1 day of exposure and 35 jigd for exposure over a life-time in
drinking water
In general ethylbenzene is a prevalent chemical in the
environment Sources include commercial (eg petroleum and petroleum
by-products) motor vehicle exhaust and cigarette smoke An intake of
16 mgday (1 mgfc) has been calculated as an acceptable rate to
protect from toxic effects Carcinogenic effects have not been
identified to date The physical properties of ethylbenzene are
presented in Table 64-2 The principal mechanism for removal of
ethylbenzene from water is volatilization In addition to
volatilization adsorption may also be an important removal mechanism
based on the log octanolwater coefficient This factor is important in
evaluating the migration of ethylbenzene from the disposal site
Toluene which was also identified in waste and ground water
samples exhibits properties similar to ethylbenzene in that it
volatilizes easily Toluene which is also referred to as methylbenzene
is distinguished from benzene by the substitution of a methyl group for
one hydrogen atom Physical properties of it are presented in Table
39
64-2 The EPA suggested no adverse response level (SNARL) for toluene
is 1 mgpound in drinking water with a maximum exposure time of ten
days
TABLE 64-2 PHYSICAL PROPERTIES OF ETHYLBENZENE AND TOLUENE
ETHYLBENZENE TOLUENE
Molecular Weight 10616 9213
Melting Point -949degC -950degC
Boiling Point 1362degC 1106degC
Vapor Pressure at 20degC 7 torr 287 torr
Solubility in water at 20degC 152 mg2 5348 mgd
Log OctanolWater Partition Coefficient 315 269
645 Metals
One liquid sample contained high concentrations of cadmium
(2200 mgd) and zinc (5700 mgd) indicating that the waste deposit is
also a potential source of certain toxic metals Tests for these metals
have not been made to-date in ground or surface water samples It would
be prudent to add toxic metals such as cadmium chromium lead and
mercury to the list of parameters that are being monitored to further
characterize the quality of adjacent ground and surface waters US
EPA and New Hampshire drinking water standards for these metals are
cadmium 01 mgd chromium 05 mgpound lead 05 mgd mercury 002
mgd Although zinc is not considered a highly toxic metal the
US EPA has set a secondary drinking water maximum contaminant level of
5 mgd on this metal
40
70 CONCLUSIONS
The following conclusions were drawn during this
investigation
1 A steep-gradient irregular-shaped magnetic anomaly is present under closed and covered portions of the south part of the Troy Mills landfill
2 The magnetic anomaly is caused mostly by an irregular-shaped accumulation of disposed steel drums
3 In a randomly conducted sampling of drums in the source area for the magnetic anomaly 16 of the drums contained liquid andor sludge 33 were crushed flat and 51 were not sampled because there were no accessible openings
4 Laboratory analyses indicate that the random waste sampling contained significant concentrations of several volatile organic chemicals several baseneutral priority pollutants and high levels of cadmium and zinc
5 Observed concentrations of volatile organics at the monitoring wells are relatively low Because of their potential for migration in the ground water continued monitoring of volatile organics will be required
6 Volatile organic chemicals have not been detected in Rockwood Brook to-date Because of the presence of low levels of volatile organics in the ground water they should be monitored in the brook on a regular basis to confirm the lack of impact
7 The presence of high concentrations of cadmium and zinc in one of the waste samples indicates that trace metals should be monitored periodically
8 The presence of baseneutral extractable compounds (phthalates and naphthalene) in all of the analyzed waste samples indicates that these compounds should be monitored periodically
9 The phthalates are not expected to migrate freely because they have low solubilities and are readily adsorbed onto soil particles
10 If elevated concentrations of volatile organic compounds trace metals or baseneutral extractable compounds should occur in the monitoring system (wells and brook) in the future a need for site remedial actions to mitigate the potential for downgradient ground and surface water contamination could develop
~
80
41
RECOMMENDED PLAN
Based on the preceding conclusions it is recommended that the
following plan be implemented by Troy Mills Inc
1 Continue monitoring ground and surface water quality at the Troy Mills Inc landfill sampling on a quarterly basis with sample collections during April July October and January
2 To confirm the absence of the landfills impact on Rockwood Brook test samples for volatile organic compounds by GCMS from surface Stations B (upstream) and C (downstream) on the April and October samplings
3 To determine if trace metals are present in downgradient ground waters conduct analyses for cadmium chromium lead mercury and zinc on samples from all monitoring points during the April sampling and on subsequent sampling rounds if necessary
4 To confirm the continued absence of baseneutral extractable compounds in downgradient ground and surface waters conduct analyses for baseneutral extractable compounds on samples from monitoring wells M 2 and 3 and surface Station C (downstream) on the April sampling and on subsequent sampling rounds if necessary
5 If a sudden rise in concentrations toward unacceptable levels should occur in the monitoring system (wells and brook) additional monitoring rounds at a monthly interval should be conducted to confirm the rise in concentrations
6 If elevated concentrations persist and are verified by the additional monitoring remedial alternatives will be defined to mitigate the potential for downgradient ground and surface water contamination
Respectfully submitted NORMANDEAU ASSOCIATES INC
Dennis R Sasseville Project Manager
Donald H Bruehl f laquo | APG Senior Hydrogeologist -^ - - AIPG Certificate No 2272 ^ -v^
^^Z-^^
APPENDIX A
SITE SAFETY PLAN
GENERAL SAFETY PLAH FOR
TROT MILLS LANDFILL TROY MEW HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
Prepared by
NORMANDEAU ASSOCIATES INC Bedford New Hampshire
R-457
November 1983
TABLE OF COHTENTS
PAGE
SECTION 1 BACKGROUND INFORMATION 2
Identification 2 Personnel 2 Site Description 3 Project Description 5
SECTION 2 HAZARD EVALUATION 6
Overall Degree of Hazard 6 Specific Hazards 8 Necessary LPP 8
SECTION 3 FIRST AID FOR EXPOSURE 10
SECTION 4 OPERATIONS SAFETY PLAN 11
General Personnel Protection GuidelinesAction Levels 11 Site Reconnaissance 13 Task 1 - Magnetic Survey Topographic Survey 14 Task 2 - Drum excavation and Sampling 15
SECTION 5 EMERGENCY INFORMATION 16
Emergency Telephone Numbers 16 Route to Hospital 16 Contingency Plan 17
APPENDICES 18
A - LEVELS OF PERSONNEL PROTECTION 18 B - DECONTAMINATION PROCEDURES 23 C - PERSONNEL AND RESPONSIBILITIES 25 D - PERSONNEL CASUALTY 26 E - GUIDELINES FOR SITE OPERATIONS 27
GENERAL SAFETY PLAN FOR
TROY MILLS LANDFILL TROY NEraquo HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
The following is a Safety Plan for on-site activities performed
during the Investigation of the Troy Mills Landfill being conducted by
Normandeau Associates Inc (NAI) of Bedford New Hampshire
The document is intended to be an in house working guideline
for personnel trained and experienced in hazardous waste field work and
not a treatise on safety Familiarity with standard equipment and proshy
cedures is expected Where possible non-site specific information has
been appended
All NAI employees subcontractors and visitors will be required
to follow this safety procedure plan and to report to either NAIs proshy
ject manager (P M) on site coordinator (OSC) or safety officer (SO) on
issues relating to safety
SECTION 1
BACKGROUND INFORMATION
IDENTIFICATION
Site Name Trey Mills Landfill NAI-ID No 457
Trey Mills Inc Troy NH 03465
AddressLocation At the south end of the dirt road about 15 miles
south of Troy NH between Rockwood Brook and the
old Boston and Maine Railroad grade
County Cheshire Phone 603-242-7711
PERSONNEL
Brook Dupee Bureau Hazardous Waste 603-271-4611
State Contact John Regan Bureau Solid Waste 603-271-4586
Dan Allen WSPCC 603-271-2755
EPA Contact
Other Contacts
Client Contacts Barrett F Ripley (Vice President)
NAI Personnel - (472-5191)
Project Manager - Dennis Sasseville
On Site Coordinators - Alton Stone
Safety Officer - Elizabeth Gross (Phoenix Safety)
Technical Director - Don Bruehl
Other - Douglas DeNatale Steve Ransom
SITE DESCRIPTION
Type of Facility Company (on-site) landfill
RCRA Status Generator Disposer
Size About 15 acres BuildingsStructures None
Surrounding Land Use N Forested
(one mile radius) E Abandoned Railroad
Forest RuralResidential
S Forested
W Forested Mountain side
Unusual Features or Terrain None
Site Activities - Troy Mills manufactures textiles carpets and related
products Since 1968 waste materials including
drummed wastes have been landfilled on company proshy
perty Drums mostmany of which may be emptycrushed
are buried in an inactive section of the landfill
The active section is currently accepting waste
which is considered to be non hazardous
Specific - Improper disposal of hazardous waste
Problems - Leachate seep
Contamination of ground water
Hazardous WastesMaterials On-5ite
Wastes - Uncured foam rubber latex sludge
SBR rubber silicone defoamer potassium oleate soap
calcium carbonate and feldspar filters zinc oxide
and sulpher salt cure system
- Vinyl plastisol sludge
PVC dispersion resin DOP and DOA plasticiser
calcium carbonate filler organic pigments AZO
dicarbcnamid blowing agent zinc salts expoxidized
soybean oil cadmLum-bariin-zinc stabilizer Varsol
MEK prints and topcoats sludges
PVC acrylic resins organic and inorganic pigments
MEK solvent toluene silicate fillers
Industrial solvents and chemicals
11 -dichlorethane 12-dichlorothane
111-trichloroethane trichlorethylene tetrachshy
lorethene methylene chloride toluene benzene
ethylbenzene benzidine 33-dichlorobenzidine aeroshy
lein acrylonitrile napthalene benzoperylene dibenshy
zoanthrasene idenopyrene
Pesticides
There is a possibility for low levels of pesticides
to be on site These would include Chlorodane
heptachlor expoxide toxaphene aldrin alpha BHC
beta BHC 4-4-DDT endosulphan 1 heptachlor
PROJECT DESCRIPTION
Purpose Tb characterize ground water conditions at the site and to
characterize wastes buried on site
Specific Tasks
Site Reconnaisance
Task 1 - Magnetometer SurveyTopographic Survey
Task 2 - Excavation for inspection of drums
SECTION 2
HAZARD EVALUATION
Overall Degree of Hazard - Moderate
Task Hazard Proposed LPP
Site Reconnaissance Low Level C
Task 1 MagnetometerTopographic Surveys Low Level CD
Task 2 Drum ExcavationSampling Moderate Level B
Conpany records have indicated that a variety of industrial
and potentially hazardous wastes including drummed wastes
were disposed of on site Several of the subtances are
trade name materials or industrial process materials and it
is difficult to determine the specific chemical composition
Hazard is dependent upon concentration of material state of
material (solid sludge drummed liquid) and degree of
decomposition
Many of the materials - SBR rubber silicone defoamer
potassium oleate soap calcium carbonate and feldspar
fillers zinc oxide and sulpher salts plasticiser
calcium carbonate filler organicinorganic pigments AZO
dicarbonamid blowing agent epoxidized soy bean oil
cadmiura-bariun-zinc stabilizer - probably do not represent
a significant hazard to an inspection team if they are
bound into a sludge or solid Personnel are not likely
to injest or come into a prolonged high concentration
contact with these materials In powdered or dust conshy
ditions the materials are more hazardous due to the inhashy
lation of contaminated particulates
MEK (TLV-200ppm) toluene (TLV-100ppm) and Varsol
(turpentine thinner composition unknown) are volatile
organics which require respiratory protection and contact
protection
Depending upon state and decomposition PVC resins could
be a source of vinyl chloride monomer (VCM-a carcinogen)
requiring respiratory protection VCM is not adequately
filtered by air purifying respirators
Results from ground water sampling showed low levels of
industrial chemicals (PPB range) At these low conshy
centrations the chemicals do not represent a significant
hazard However the low concentrations in ground water indishy
cate the possibility of higher concentrations in the waste
materials
Industrial chemicals - napthalene (TLV-10 ppm) peryshy
lene anthrocene and pyrene which are hazardous
through inhalation or absorbtion Furthermore as
double benzene ring chemicals they are potential
carcinogens
Results from ground water sampling indicated possible
low levels (parts per trillion) of several pesticides
- chlorodane heptachlor epoxide toxaphene eldrin
Alpha BHC Beta BHC 4-4-DDT endosulphan These were
tentatively identified during a first analytical run
but not confirmed during a second run laboratory
review (GCA Bedford Mass) determined that the
material was actually a complex of highly degraded
heavy organics derived from the industrial waste The
presence of pesticides in industrial textile waste is
unlikely
Specific Hazards
1) Inhalation of organic vapors
Excavation of buried material and sampling of drums could
initiate high vapor concentrations
2) Fire and explosion
Many of the solvents are flammable liquids and volatile
Excavation of material and sampling of drums should
proceed cautiously in order to avoid rupturing shocking
or sparking of drums and material
3) Inhalation of contaminated dustparticulates
Excavation of buried material may result in a release of
particulates
4) Contact contamination
Excavation and sampling of wastes could possibly result in
contact with contaminated waste and soils necessitating
protective clothing
Necessary LPP
Site Reconnaissance - Level C The site has been visited on numerous
occassions by the state and private personnel Use of an HNU (102 ev
probe)- has not indicated significant vapor concentrations Significant
odors during dry weather or other hazards have not been noted
Sections of the landfill are currently active and adverse effects to
personnel have not been noted Level C - (tyveks rubber safety boots
organic vapor cartridges) is sufficient
Task 1 MagnetometerTopographic Survey - Level CD LPP will depend
upon the results of the Site Recon Significant vapor concentrations
or likelihood of particulates will necessitate an upgrade in the LPP
Otherwise Level D (work clothes safety boots boot wash) is sufficient
Task 2 Excavation and Sampling of Buried Drums - Level B The potenshy
tial for encountering significant concentrations of hazardous
materials during this task is moderately high Full Level B - (SCBA
chemical resistant tyveks hoods rubber safety boots rubber gloves)
will provide necessary respiratory and contactsplash protection
The use of the hooded yellow tyveck and the taping of ankleboots
wristsgloves and face maskhood junctions will provide complete conshy
tact protection
10
SECTION 3
FIRST AID FOR EXPOSURE
INHALATION OF VAPORSPARTICUIATES
Symptoms - eyenosethroat irritation nausea dizziness headache weakness fatigue lightheadedness drowsiness Loss of coordination confusion vomiting cramps (These sympshytoms are similar for most organic vapors particularly solvents)
Treatment Mild Exposure - Bring victim to fresh air Rinse eyes and throat if
irritated Heavy Exposure - (victim vomits very dizzy groggy faints etc)
Bring victim to fresh air Evacuate to hospital Prepare to administer CPR
Victim should be monitored for 48 hours in case of a delayed reaction
CONTACT EXPOSURE
Symptoms - Itching burning redness of skin Severe contact exposure for certain solvents will progress to CNS (central nervous system) symptoms similar to those for inhalation
Treatment - Remove contaminated clothing flush with water dry and banshydage Monitor victim for CNS symptoms for at least 48 hours
FIRST AIDSAFETY EQUIPMENT
The following equipment will be stationed at the Hotline or when appropriate down range
- Fully equipped first aid kit - Oxygen bottlekit - Nine (9) Ib chemical fire extinguisher - Eyewash bottle or other pressurized water filled container
11
SECTION 4
OPERATIONS SAFETY PLAN
This section outlines the specifics of safety procedures to be
used during each phase of the operations Safety procedures may be
upgraded or downgraded during site activities pending monitored changes
in the working environment All changes will be in line with the
General Level of Personnel Protection GuidelinesAction Levels for the
Troy Mills Landfill On-Site Investigation as described below
General Personnel Protection GuidelinesAction Levels
An in depth review of levels of personnel protection (LPP) is
presented in Appendix A
Level B (SCBA cotton coveralls or work clothes yellow tyveks (chemical resistant) steel toed rubber boots or work boots with disposhysible over boots and gloves)
Vapor concentrations (as measured on an OVA or HNU 117 EV Probe) greater than 5 ppm above background
- Oxygen deficient atmospheres less than 195
Specific actions (ie excavationsampling of drums) which could initiate a sudden moderate or high concentration of vapor
Level C (full face respirator organic vapor dust combo cartridge tyveks over work clothscoverails rubber safety boots gloves)
Vapor concentrations above an established clean zone backshyground level
During conditions (natural or personnel induced) which result in high levels of dust (visable above background atmospheric concentrations of particulates)
Level C activities require continual air monitoring
12
Level D (cotton coveralls or other work clothes safety shoes and safety glasses when down range Tyveks may also be needed)
Support areas and downrange areas where a higher LPP has not been deemed necessary
Continual air monitoring in downrange areas
Explosive Atmospheres
- 20 LEL (lower explosive limit) as recorded by an explosishymeter Secure and evacuate the work area
Oxygen Deficient Atmospheres
- Less than 195 (by volume) oxygen atmosphere requires upgrading the level of Personnel Protection to Level B
Task Specific Safety Plans
Levels of Personnel Protection indicated for specific tasks below are those which are anticipated to be used Changes in site conshyditions and results of air monitoring may indicate the upgrade downgrade of the LPP
13
Site Reconnaissance (SR) Date Sept 21 1983
Purpose To review on-site conditions and determine LPP necessary for further tasks To evaluate safety hazards Preliminary planning of future tasks
LPP - Initially Level C Updowngrade as necessary
Equipment - OVA HNU (102 ev probe)
Hotline - End of access road Upwind if possible
Command PostFirst Aid - Behind Hotline
Decontamination - Boot wash
Operations
Three man team Two persons advance in front with instrushyments Third person at distance as backup
Team methodically sweeps (criss cross) the proposed work areas with instruments
Specific points of interest (leachate seeps etc) are closely checked
All information is loggedsketch mapped
Upgraded LPP as necessary
14
Task 1 - Magnetic Survey Topographic Survey Date Week of October 3 1983
Purpose - Determine the location(s) and extent of buried drums Provide topographic information for site base map
LPP - Level CD
Hotline - End of access road (upwind if possible)
Decontamination - Boot wash
Operations - SO or other NAI personnel will perform a brief safety sweep of the work area
- Work team will then proceed downrange at the appropriate LPP Using the magnetometer the team will systematically criss cross -the work area
Task 2 - Drum Excavation and Sampling Date Week of November 14 1983
Purpose - Excavationsampling of buried drums in order to characterize the condition of the drums and the nature of the wastes conshytained in the drums and buried in the landfill
Msthod - Backhoe and hand labor will be used to uncover the drums in specified locations Samples will be obtained from spillage or leakage around the drums and of contaninated soil Selected drums which have accessible and openable bungs may be opened and sampled Drums will not be moved or staged Clean drums will be available to receive any significant spillage during the opening and sampling
Specific Hazards - Inhalation of organic vapors - Fire and explosion of drummed waste - Contact with contaminated waste or soil
LPP - Full Level B protection Backhoe operator at Level B Backshyhoe equipped with splash shield and without teeth on bucket
Hotline - At the end of the access road Upwind if possible
Decontamination - Procedures will essentially follow those as outlined by the EPA for Level B work Due to the inaccessibility of the site a field shower will not be available See Appendix B
Safety Equipment - OVA HNU eyewash fire extinguisher oxygen kit first aid kit metal detector non sparking implements
15
Operations - The cover soil is very sandy and the drums appear to be buried close to the surface which should facilitate excavation
- Minimum of 4 man team (exclusive of backhoe operator) Two or three man downrange team for digging and sampling One or two men in supportbackup at hotline
- Personnel will hand dig several small holes to approximately one (1) foot depth in each Location area If drums are not encountered the backhoe will scrape off soil to that depth
- Excavation will proceed alternating hand and backhoe methods At depths below four (4) feet the sides of the pit must be angled back to less than 45deg
- Prior to opening a closed drum the backhoe will nudgebump the drum to check for shock sensitive material An alternate method will be to attach a length of rope to the drum and from a distance pull on the rope to jog the drum
mdash Backhoe The backhoe operator will work at Level B utilizing air supplied from a large cylinder attached to the backhoe The backhoe will also be equipped with a splash shield A scraping bucket without teeth will be used
Prior to backhoe excavation at each location the area where the backhoe will be stationed will be checked for drums which could be ruptured by the backhoe feet
f Excavation areas will be checked for drums utilizing hand excavations or a metal detector prior to removing material by machine
16
SECTION 5
EMERGENCY INFORMATION
Emergency Telephone Numbers
If calling one of these numbers please state NAME LOCATION
and type of PROBLEM
Local Emergency Support
Fire Department (Troy 242-7759) For all emergencies use
Ambulance 352-1100 Mutual Aid (Keene) 352-1100
Police Department (Troy 242-7992)
Hospital 352-4111 (Cheshire Hospital in Keene)
Town Clerk 242-3845 State Agencies
NH Bureau of Hazardous Waste Management 271-4608
NH Water Supply and Pollution Control Commission 271-3503
NH Fire Marshall Office 271-3336
NH State Police (24-Hour Dispatch) 1-800-852-3411
Other
US EPA (24-Hour Hotline) 617-223-7265
Poison Center Mary Hitchcock Hospital 1-800-562-8236
Route to Hospital
- Follow dirt access road to Bowkerville Road - Left on Bowkerville Road to Rt 12 - Left (north) on Rt 12 through Troy to Keene NH - At major junction of Rts 9 10 101 and 12 go straight through
into Keene - At common go half-way around and go right on Court Street - Hospital is at 580 Court Street
17
Contingency Plan
Signal - five (5) one second blasts of auto or air horn Action - All personnel immediately excavate dovmrange areas and
report to Hotline for instructions
Personnel Unexplained Fire (if small) Accident (serious) Collapse of Personnel
Evacuate area Emergency ^ ^Evacuation Evacuate Area
First Aid
Estimate Explosion Level B (for Potential Contact Outside Help evcavation)
Evacuate Victim i If
Level B Prepare for Transportation
1 First AidCPR Use extinguisher Transport
Contact Outside Help Notify Coup any Have Proper Information Personnel (see below) 1
Transport
Call Fire Dept (if necessary)
For Hospital Victim
- Name and Phone of family physician
- Description of Incident chemicals involved symptoms nature of injury proposed treatment and plan of transportation
18
APPENDIX A
LEVELS OF PERSONNEL PROTECTION
Because of the possible dangers of exposure to toxic or harmshyful chemicals protective equipment must be worn during work on hazardous waste sites Levels of Personnel Protection (LPP) describe respiratory clothing and other equipment necessary for protecting personnel against expected hazards
The descriptions below are for full dress at a given LPP where hazards are expected to be at a maximum for which the given LPP is conshysidered adequate Depending on site conditions and work activities the clothing and dress requirements of a given LPP are commonly modified
LEVEL A
1 Personal Protection Equipment
Positive Pressure SCBA (MSHANIOSH approved) Operated in the positive pressure mode
Totally Encapsulating Suit (boots and gloves attached)
Gloves - Inner (tight fitting and chemical resistant)
- Boots - Chemical - protective steel toe and shank Depending on suit boot construction worn over suit boot
- Gloves shy Outer chemical-resistanttion worn over suit gloves May bchemical-resistant gloves worn insid
Dependinge replaced withe suit glo
on s
ves
uit construcshy tight-fitting
- Underwear shy Cotton long-John type
- Hard Hat (under suit)
- Disposable protective suitover encapsulating suit)
gloves and boots (Worn under or
- Coveralls (under suit)
- 2-way Radio Communications
Optional
19
2 Criteria for Use
A The type and concentration of toxic substances are known and require the highest level of combined protection to the respirashytory tract skin and eyes These conditions would be
1 Atmospheres which are immediately dangerous to life and health (IDLH)
a IDLHs can be found in the NIOSHOSHAs Pocket Guide to Chemical Hazards andor other references
2 Known atmospheres or potential situations that would effect the skin or eyes or could be absorbed into the body through these surfaces in toxic quantities
a Potential situations are those where vapors may be generated or splashing may occur through site activities
b Standard reference books should be consulted to obtain concentrations hazardous to skin eyes or mucous memshybranes
3 Oxygen deficient atmospheres with above conditions
3 At sites where the type andor potential concentration of toxic substances are unknown
1 Unless circumstances strongly indicate otherwise the site should be presumed to present hazards to the respiratory system skin and eyes Level A protection would provide the highest level of protection for the initial entry team
a Such circumstances might be
1 Environmental measurements contiguous to the site
2 Reliable accurate historical data
3 Open unconfined areas
4 Minimal probability of vapors presence or splashing with cutaneous effecting substances
2 Enclosed areas such as buildings railroad cars ships holds etc
20
LEVEL B
1 Personal Protective Equipment
Positive Pressure SCBA (MSHANIOSH approved) operated in the positive pressure mode
- Hooded chemical-resistant suit
Gloves - Outer chemical-protective
Gloves - Inner tight-fitting chemical-resistant
Boots - Outer (chemical-protective heavy rubber disposables)
Boots - Inner (chemical-protective steel toe and shank)
2-way Radio Communications
Hard Hat
Face Shield
2 Criteria for Use
A The type and concentration of hazardous substances are known and require the highest degree of respiratory protective but a lower level of skin protection
1 Atmospheres which are immediately dangerous to life and health (IDLH) Type and concentration of vapors in air do not present a hazard to the small unprotected areas of the body
2 Atmospheres with concentrations of known substances greater than protection factors associated with full-face air-purifying respirators with appropriate cartridges
3 Atmospheres with less than 195 oxygen
B When a determination is made that potential exposure to the body parts not protected by a fully encapsulated suit (primarily neck ears etc) is highly unlikely
1 Known absence of cutaneous or percutaneous hazards
2 Activities performed preclude splashing of individuals
C Level B protection is recommended as the lowest level of protecshytion for initial entries until the hazards have been further identified and defined by monitoring sampling and other reliable methods of analysis and personnel protection equipment commensurate with these findings utilized
21
LEVEL C
1 Personal Protective Equipment
Full-face or half-face air purifying respirator (MSHANIOSH approved)
Chemical-resistant clothing
Gloves - Outer (chemical-protective)
Gloves - Inner (tight-fitting chemical-resistant type (or woven liners)
Hard Hat (face shield optional)
Boots - Outer (chemical-protective heavy rubber throw aways)
Boots - Inner (chemical-protective steel toe and shank)
2-way radio comnunications
Safety glasses required with half-face respirator
2 Criteria for Use
A Site known to contain potentially hazardous materials exceeding
1 Air concentrations requiring a protection factor no greater than that afforded by a full-face mask
2 Harmful levels to unprotected body areas (face neck etc)
3 Well-documented reliable history of site and patterns of prior entry
C No evidence to suspect acute or chronic toxicity to exposed personnel
D Continuous air or personnel monitoring should occur while wearing Level C protection
22
LEVEL D
1 Person Protective Equipment
Chemical resistant aprons
BootsShoes - Safety or chemical-resistant steel toed boots
Boots - Outer (chemical-protective heavy rubber throw-away)
Half-face respirators immediately available
Safety glasses or safety goggles
Gloves
2 Criteria for Use
a No indication of airborne health hazards present
b No gross indications above background on the photoionizer andor organic vapor analyzer
c Continuous air or personnel monitoring should occur while wearing Level D protection
23
APPENDIX B
DECONTAMIHATION PROCEDURES
Depending upon activities and location on site it may be
necessary for personnel to decontaminate prior to leaving the conshy
taminated zone Procedures described below are typical for Level C
operations
Upon exiting downrange (contaminated) areas all personnel are
required to decontaminate by means of the following procedure
1 Place equipment in the Drop Zone at the Hotline
2 Enter the Decontamination Station
Boot Wash Walk through wash tub and scrub boots then rinse boots in second tube
Glove Wash In two pan wash scrub over gloves rinse set out to dry
2 Remove tyvek - if leaving the contamination reduction zone (CRZ) and proceed to clean zones
3 Dispose of heavily contaminated clothing and under gloves
4 Remove respirator
5 Use disposable gloves to clean equipment
6 Use a two bucket (washrinse) to decon respirators at the end of the working day or if they become heavily contami nated
The procedures for a typical Level B Decontamination are
outlined on the following page
TANK CHANGE 9
CONTAMINATION REDUCTION
ZONE
OUTER GLOVE REMOVAL
EXCLUSION ZONE
TAPE REMOVAL
BOOT COVER
GLOVE WASH
(bull)mdashQ-G--copyshySOOT COVEH SCOT COVES 4
REMOVAL GLOVE RINSE
SUITSAFETY BOOT WASH
SU1TSC8A78OOTGLOVE RINSE
SAFETY BOOT 10 REMOVAL
SCSA BACKPACK REMOVAL
SPLASH SUIT 12 REMOVAL
INNER GLOVE WASH
INNER GLOVE RINSE
FACE PIECE REMOVAL
INNER GLOVE 16 I REMOVAL
INNER CLOTHING REMOVAL
FIEUJ 19 REDRESS WASH
SEGREGATED EQUIPMENT
OROP
mdash -HOTLINE-shy
DECONTAMINATION LAYOUT LEVEL B PROTECTION
FIGURE A2-1
CONTAMINATION CONTROLLING
SUPPORT ZONE
25
APPENDIX C
PERSOHNEL AND RESPONSIBILITIES
Project Manager (PM)
Overall responsibility for all Project activates budget
schedule investigative operations safety personnel
On Site Coordinator (OSC)
Responsibility for activities at the site Primary responshy
sibilities include
1) Interfacing with the client state EPA media or other groups
2) Reviewing technical operations
3) Reviewing site safety in particular information supplied by the Site Safety Officer
4) Enforcing site safety and compliance with the Safety Plan
5) Directing Emergency Contingency operations
Safety Officer (SO)
Responsibility for directing the safety of operations and impleshy
menting the Safety Plan Specific responsibilities include
1 Assuring that appropriate personnel protective equipment is available and properly utilized by all site personnel
2 Assuring that personnel are aware of the provisions of this plan are instructed in the work practices necessary to ensure safety and in planned procedures for dealing with emergencies
3 Assuring that personnel are aware of the potential hazards associated with site operations
4 Supervising the monitoring of safety performance by all pershysonnel to ensure that required work practices are employed
26
APPENDIX D
PERSOHHEL CASUALTY
Personnel casualty would most likely result from either chemical
contamination heat-related problems physical injury from accidents
(ie falling lacerations etc) in performing the work or a comshy
bination of one or more of the above The appropriate action depends on
the type of injury involved with the priority being to assist the
casualty as soon as possible without endangering other personnel
Riysical and heat-related injuries can and should be treated
immediately with appropriate first-aid measures and follow-up medical
attention if necessary The injured worker(s) shall immediately move
out of the hot zone or if necessary be moved out by fellow workers as
soon as possible The OSC and Safety Officer shall be notified immeshy
diately and shall recommend further measures as needed
Chemical-related injuries require a much more cautious approach
so as to keep casualties to a minimum If a worker injured by chemical
ejqgtosure is able he shall notify the nearest co-worker and leave the hot
zone immediately- The co-worker shall ensure that the OSC and Safety
Officer are immediately informed and shall accompany the casualty from
the hot zone to the decontamination zone The OSC and Safety Officer
shall determine the appropriate measure
27
APPENDIX E
GUIDELINES FOR SITE OPERATIONS
In order to deal with the potential dangers of exposure and conshy
tamination of a hazardous waste site three zones are delineated
according to the degree of hazard The three zones are 1) Downrange
or Contamination Zone 2 Contamination Reduction Zone (CRZ) 3) Support
or Clean Zone
Downrange or Contamination Zone
The Contamination Zone is the active work area of the site which
encortpasses the areas where there is a potential for exposure and in
which investigative activities will occur (drilling sampling etc)
Within the Contamination Zone the designated level of hazard will be
established necessitating the utilization of personnel protective
equipment
Hot spots are those areas Downrange where observations instrushy
ment readings or specific activities indicate a high probability of
closure or contamination and may require an upgrade in the LPP in the
vicinity of the Hot Spot
Contamination Reduction Zone
The CRZ is an area between the Downrange and Support Zones where
decontamination of equipment and personnel occurs
28
Personnel entering the CRZ shall wear protective clothing and
carry the respiratory protection required for entry within the
Contamination Zone
Personnel working within the CRZ shall remain cognizant of the
CRZ in order to be prepared for any need to increase their level of proshy
tection within the CRZ
A decontamination station will be located at the outer perimeter
of the CRZ All personnel who have been within the Hot lane shall pass
through a decontamination procedure prior to re-entering the Support
Zone
Support or Clean Zone
The Support Zone is the outer area and may be considered to be
clear of contamination potential The command post will be located
within the Support Zone
a) The Command Post will serve as the OSCs headquarters and
will be equipped with
1 Communications
2 Safety Plans
3 First Aid Supplies
4 Analytical Equipment
5 Safety Equipment
APPENDIX B
WORK PLAN
WORK PLAN FOR
TROY MILLS LANDFILL TROY NEW HAMPSHIRE
DRUM EXCAVATION AND SAMPLING
Prepared by
NORHANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
1933
WORX PLAN FOR
TKOt MILLS LANDFILL TROT NEW HAMPSHIRE
DRUM EXCAVATION AHD SAMPLING
DATS November 16-18 1983
PURPOSE
To determine the condition of drums (ie erroty or full
crushed rusted leaking etc) buried in the Troy Mills Landfill To
obtain representative samples toward identifying the types of materials
buried in the landfill This information will be used in the detershy
mination of the level of remedial action needed at the site
METHOD
Using the results of the magnetometer survey the (10) points
have been randomly chosen across the area where the buried drans are
expected to be found Each point is central to an Excavation Location
-- an area four (4) to six (6) feet in diameter which will be excavated
in order to characterize the condition of the drams and to obtain waste
sarples
Preliminary observations have indicated that many of the drums
may be buried within 1-2 feet of the surface Therefore the investigashy
tion will proceed in two phases
Phase 1 mdash Hand Excavation By digging several small holes in
each Location personnel will determine if drums are located within
about one to two feet of the surface If drums are encountered the
excavation will proceed by hand uncovering the dnris for evaluation and
sampling Where drums are not encountered near the surface excavation
at this location will be postponed until Phase 2
Phase 2 mdash HandBackhoe Excavation After all Locations have
been attempted during Phase 1 those Locations in which drums were not
encountered wall be further excavated using a combination of hand
backhoe digging
It is expected that one to two days will be necessary to
cor^piete each phase Depending upon the results of Phase 1 it may not
be necessary to iroleraent Phase 2
Spare drums will be on hand for containerizing any significant
spillage resulting from sampling efforts Excavation locations will be
identified with marked stakes and the holes will be backfilled at the
conclusion of the investigation
SPECIFICS
Excavation Locations (Holes)
Number of proposed excavations is ten (10)
Locations of excavations are presented in Appendix A
Hole Size mdash It is expected that a hole from four (4) feet to six (6) feet in diameter at the bottom (depth at which drums are encountered) will be sufficient to characterize the drums at each Location Deeper excavations will require increasingly large top diameters
Hole Depth -- Holes will be excavated to a maximum depth of six (6) feet Due to the sandy cover material the excavation of deeper holes is probably impractical from both safety and efficiency stand points
If after attempting excavation at each of t-ie 10 proposed
1ocatiors irums are not encountered within six (6) fet of the surf ice
in enough locations to characterize the site excavations nay be
attempted to depths greater than six (6) feet if scil stability permits
or a new set of sampling locations may be chosen
(Excavations to depths greater than six (6) feet require a
significant increase in work The sides of the hole crust be graded back
to less than 45deg in order to insure the safety of investigatorysampling
personnel It may also be necessary to employ bracing bulkheads etc
for trench support)
Excavation Identification
Proposed excavation Locations have been consecutively numbered
from 1 to 10 beginning at the east end of the landfill They will be
marked with numbered stakes
Excavation Methods
Phase 1 mdash Within each Location personnel will dig a nunber of
small holes - about one (1) foot in depth - to probe for drums If
druns are encountered they will continue to excavate until the drur3
are sufficiently uncovered for characterization
Phase 2 mdash After hand probing the Location with snail holes
the backhoe will remove cover material to the one (1) foot depth The
Location will then be probed to a two (2) foot depth before removing
further material Excavation will proceed alternating handprobing and
backhoe excavation until drums are encountered or the maximum six (6)
foot depth is reached
If excavations to depths greater than six (6) feet are undershy
taken they will proceed using the above method
Santnlea
Due to the effort involved in excavating and because conshycentrated waste samples are not expected to undergo rapid degradation it is considered expedient to obtain all readily available samples (exclusive of closed drum samples -- see belcw) These can then be submitted for laboratory characterization as determined by need and budget restrictions
An attempt will be trade to secure at least one sample froa each excavation in order to help characterize the distrishybution of waste materials across the site An attempt will also be made to secure samples of observably difshyferent materials
Sample Types and Mediums - Solid liquid and sludge samples are possible Samples will be obtained from in order of preference -- 1) leakage uncontainerized waste or contaminated soil 2) waste contained in open conshytainers - drum already has a hole or no top or other access point 3) sealed containers
The opening of closed containers will be considered if it is decided that it has not been possible to obtain a sufshyficient number of representative samples from the other mediums
Each sample will consist of two (2) 8-oz jars (with teflon-lids) filled about 23 full One jar will be for organic analysis and the other for inorganic analysis
Sanole Identification - Samples will be identified with a number corresponding to the Excavation Location and a letter Example if three samples were obtained from Location 2 they would be samples 2A 23 and 2C and Samples 2Ad 23d and 2Cd for duplicates
Sampling Methods and Volumes - 11 mm hollow glass tubing trowels disposable scoops will be available to obtain samples Samples tools will be disposed of or deconshytaminated between each sample
Drum Samples - If necessary an attempt will be cude to obtain samples from sealed drums Oily o^und non-rusted drums will be considered Bunjs rust be xn suitable conshydition -jo that the dram cm be openoi withrut cvis ing dainai -ind ca-i be resell od to pr-jvcrt l V-i 30
There wil l be no staging or movement of drums in order to faci l i tate sampling Only drums with accessible bungs will be considered for sampling
Procedure for Drum Sampling
1) Excavate around top of drum
2) Monitor air in the adjacent area
3) Chec for shock sensitive - Loop rope around top of drum stand at a distance give drum several hard jogs by pulling on the rope An alternative nethod is to lightly jog the drum with the backhoe bucket
4) If the drum is not upright place a catch basin under the bung
5) Open drum with bung wrench
6) Monitor the air atin bung
7) Sample drum -- liquids insert glass tube the fu l l length into the drum in order to obtain a column of the materials in the drum Solids use scoop to dig out material through the bung or use a sampling trowel
3) Reseal the dram
Spill Control
The possibility exists during the sampling and excavation for a
drum to be ruptured or otherwise have spillage Clean drums wil l be on
hand to receive significant spillage resulting frora sampling or excavashy
tion They will not be used for clean up of widespread uncontainerized
waste or existing leakage
Personnel
The work team will require four (4) persons (exclusive of the
backhoe opera tor) Trie downrange team will consist of three (3) persons
-- two (2) for d igg ing and sampl ing and on ( 1 ) for logging air moni shy
toring and photographing One (1) person will be at the hotline in
support mdash as safety backup person to fill air bottles to deconshy
taminate samoles to assist in decontamination of personnel
Documentation Logging
The following information will be recorded at each location
nmber of drums uncovered and the condition (crushed empty rusted
sealed etc) of each drum evidence of spillage or contaminated soil
labels on uncovered drums samples (time drum ID type description)
periodic air monitoring information depth at which specific events
occur or drums are buried soil condition presence of ground water
In addition photographs will be taken of specific events or
items of importance during each excavation and of each sampling incishy
dent The time description of subject photographer excavation
location and photo number will be logged for each photograph
Analytical Laboratories and Schedule
RAI Hampton NH
Initial schedule
Ten samples for GCrns for organic priority pollutants Samples may also be submitted for inorganic anlaysis or volatile organic analysis depending upon waste materials observed during the excavation
APPENDIX A
TABLE A-1 EXCAVATION LOCATIONS
EXCAVATION BASELINE RANDOM RANDOM
NUMBER GRID COORD SEGMENT STATIOH OFFSET
1 7E+1 565N 0- 60 26 (25) 16
2 9E+5 13S 60-120 50 (110) 9
3 8E+0 31S 120-180 20 (140) 7
4 4E+5 483 180-240 50 (230) 25
5 3E+3 45S 240-300 14 (254) 20
6 OE+6 5S 300-360 34 ( 334) 50
7 2W1 5 24N 360-420 45 (-155) 14
8 5W+6 42N 420-480 38 (518) 20
9 6W+1474N 480-540 8 (543) 7
10 8W 5 11011 540-600 11 (611) 31
Locations are plotted on Map A-1
Method of Choice A stratified random sampling method was used to choose 10 Excavation Locations within the magnetic anomaly
The axis of the magnetic anomaly was used as a base line and divided into ten 60 foot long segments Using a randora nirnbers table a distance along each secpent was chosen (Random Station) and a line drawn at that point perpendicular to the base line Again using a random numbers table a distance was located along each perpendicular line by measuring inward from the line denoting the edge of Area A (Random Offset) The Grid Coordinates for each of the Excavation Locations were graphically determined from the grid overlay (this overlay has been surveyed and intersections field located)
It was judged that 10 excavation locations within the magnetic zone and two outside of the zone would be sufficient to characterize the area would produce statistically valid iati and coli be expected to be co~letod within 2-3 days work period
to
80
cu0
cgtc
APPENDIX C
MAGNETIC INVESTIGATION TROY MILLS INC LANDFILL SITE
TROY NEW HAMPSHIRE
For
NORMANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
By
JOHN F KICK PhD GEOPHYSICIST
Box 6 Dunstable Massachusetts 01827
(617) 649-6650
Noverber 19S3
MAGNETIC INVESTIGATION
TROY MILLS INC LANDFILL SITE
TROY NEK HAMPSHIRE
INTRODUCTION
A high resolution ragnetic investigation was completed on the Troy
Mills Inc landfill site in Troy New Hampshire by John F Kick
Consulting Geophysicist The purpose of the investigation was to
delineate the extent of buried steel drums under closed portions of the
Troy Mills landfill The information is needed as a part of a study of
the landfill that is being conducted by Normandeau Associates Inc
FIELDKORK
Magnetometer measurements of total field intensity were made over an
area that was reported to contain buried steel drums and adjacent
landfilled areas that contained unknown waste materials The area of
investigation included capped and grassed closed areas along the south
margin of the landfill site and adjacent areas The fieldwork was
performed during October of 1983
Eighteen parallel rows of measurements were conducted along north-
south lines (using magnetic compass directions) A spacing of 20-feet
was used between rows and magnetometer measurements were made at 10-foot
intervals along the rows Greater intervals between measurements were
used at the ends of the rows and in periferal areas with low magnetic
-JF Kick 01shy
field gradients
A series of magnetic field measurements were made at an adjacent
base station throughout the survey to torn the basis for a daily
variation curve The base station was located at a site with typical low-
gradient background magnetic field intensity measurements
MAGNETIC SEARCH METHOD
Theory Magnetic search methods involve the detection and
measurement of anomalies in the Earths magnetic field caused by the
presence of materials with contrasting magnetic susceptibility Iron and
steel objects generally have very high magnetic susceptibility contrasts
with usual surrounding materials and therefore produce magnetic
anomalies The amplitude shape and detectable distance of the anomaly
depend mostly on the particular susceptibility contrast and size of the
object Magnetic anomalies are measured in units called gammas The
normal magnetic field in this area is over 50000 gammas A 5-inch
screwdriver will produce an anomaly of 5 to 10 gammas at a depth of 5
feet and an anomaly of 1 gamma at a depth of 10 feet A 1 ton automobile
will produce an anomaly of 40 gammas at a depth of 30 feet and an anomaly
of 1 gamma at a depth of 100 feet The magnitude of an anomaly caused by
a single steel drum will vary with its condition (new heavily rusted
etc) Tests using a single light weight (somewhat rusted) drum on the
surface with the magnetic detector at a height of of 12 feet produced an
anomaly in the range of 40 to 50 gammas
Total magnetic intensity disturbances or anomalies are almost always
asymmetrical sometimes appear complex even from simple sources and
usually exhibit the combined magnetic effects of several sources which
can produce a given anomaly The apparent complexity of such anomalies
is a result of several relatively simple functions of magnetic dipole
-JF Kick 02shy
behavior Reasonable assumptions about the geology and buried source
conbined with an understanding of magnetic dipole behavior can usually
lead to a satisfactory qualitative interpretation More detailed
interpretations nay require modeling studies
Instrumentation Field equipment on this project included a EGampG
Geometries Memory-Mag G-856 proton precession magnetmeter The
instrument has a resolution of +01 gamma The magnetic field detector
is separate from the rest of the instrument and is mounted on an 8-foot
staff to provide measurements that are a constant height above land
surface
Magnetic Data Analysis For the purposes of data reduction and
anomaly delineation it was assumed that base station total field
intensity measurements were typical background values for the site
Measurements made at frequent intervals at the base station were used to
prepare a diurnal variation curve for the site Anoraly values were
obtained by subtracting background values from the base station curve
from measurements collected in the area of investigation
RESULTS
The reduced results are presented in the form of a magnetic anomaly
contour map (Figure 1) and two profiles across the area of investigation
(Figures 2 and 3) The map and profiles show that very steep magnetic
field gradients and large departures form background occur in an
irregular shaped band that is about 460 feet long and ranges from about
30 to about 200 feet in width The magnitude of the anomaly is such that
a significant deposit of ferromagnetic materials (such as steel drums) is
indicated
In using the plotted magnetic results it should be noted that the
greatest concentrations of ferromagnetic materials probably do not
-JF Kick 03shy
directly underlie the peak magnetic anomalies A shift is caused by the
inclination of the Earths magnetic field and by the dipolar nature of
ferromagnetic deposits The inclination of the Earths field is about 76shy
degrees northward in the vicinity of Troy The dipolar effect is induced
by the Earths field and results in negative anomalies immediately north
of large positive anomalies
Magnetic Anomaly Map The magnetic anomaly map (Figure 1) indicates
10 positive peaks of varying size shape and intensity Associated
negative anomalies of a broader and less intense nature lie immediately
north of the belt of positive anomalies The configuration of the
anomalous area is indicative of lense-shaped and cigar-shaped bodies of
ferromagnetic materials Steep-sloped anomalies are indicative of very
shallow source materials The thickness of the ferromagnetic deposit
cannot be easily determined on the basis of intensity and size of
anomalous peaks because a small mass of iron or steel at the surface can
duplicate the anomaly caused by a much larger mass at depth The
ferromagnetic source materials can generally be expected to lie north of
the positive peak of anomalies and south of the adjacent negative
anomaly Modeling can provide the best approximations of the depth and
density of the ferromagnetic source materials The outer boundaries of
the source materials can be expected to overlap the positive peak and
negative anomaly somewhat depending on the depth and configuration of
the deposit
For illustration purposes two north-south rows that were profiled
are discussed below
Magnetic Anomaly Along Row 9-East Two strong positive magnetic
anomalies (3645 and 2436 gammas) and adjacent negative anomalies were
profiled along Row 9-East (Figure 2) The approximate centers of the
ferromagnetic deposits are believed to underlie stations 50 north and 75
feet south of the base line The rounded shape of the north positive
-JF Kick
anoraly nay indicate somewhat deeper burial of the ferromagnetic deposit
Magnetic Anomaly Alone Row 7-West Figure 3 shows the most intense
positive magnetic anomaly (4470 gammas) that was detected on this
project The steepeness of the slopes is indicative of very shallow
source materials An uneven burial pattern is suggested by the two-
peaked positive anoraly The negative anomaly south of the two peaks is
unusual and may be related to another positive anomaly to the southeast
(along Rows 5 and 6 20 feet north of the base line) The centers of the
sources of the positive anomalies are probably approximately 80 and 120
feet north of the base line along Row 7-West
-JF Kick 05shy
DISTANCE FROM BASE LINE(FEET)
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APPENDIX D
LABORATORY ANALYSES
RAI
Resource Analysts Incorporated Box 4778 Hampton H 03842
(603) 92^7777
TO PO 830318
Mr Doug DeNatale Date Received 12-2-83 Kormandeau Associates 25 Nashua Road Lab Number 2887 Bedford NH 03102 J
Date Reported 1-3-84
IDENTIFICATION
SAMPLE DESIGNATION PARAMETER
Volatile Organics Analyses by EPA Method 624
Acid and BaseNeutral Extractable Compounds Analyzed by EPA Method 625
Metals Analyzed by Standard Methods 303A
Please see attachments for all results
Results expressed in mgL unless otherwise designated lt = Less Than
ClarkeFosterVan K o u w e i b r h 1 ANALYST DIRECTOR
METHODS Standard Methods (or the Examination ol Water and Waitewaler 15th Edition or other EPA approved mtlhodologiei unless otherwise designated
Phys ica l descr ip t ion of sample
LiquidSludop
Saiple workup
Volitile f ract ion Methannl F-1-rarMrm CSVJ Rdfi-Smm
Semivolatile f ra ictio0onication Extraction fSW 846-3540^ Inorganic f rac t on Acid Digestion (SW 84h-iOS(V)
ACS3 COMPOUNDS
rr t CAS CAS
(71 A) tt-Ot-2 i^t TT i^MoroprvrfgtOi (73B) 30-32-1
(23 A) J9-JO-7 ^bull^^ lof o^^ft^crt gto (7 OB) 205-M-2
(2 A) 13-37 -J 2- chlorophenol (75B) 207-01-
(3 A) 120-13-2 2raquo^icMoroorgtenol (748) 211-01-9
(MA) 103-47-9 2-dimethv lohenol (77 B) 201-94-1
(37A) U-73-3 2- niiroDhenol (7IB) 120-12-7
(MA) 100-02-7 raquo-niiroprienol (7raquoB) lraquol-2raquo-2
(raquoA) Jl-21-3 2 - in i tr opheno 1 (106) raquoi-73-7
(40 A) 33-J7-l k4-dinnro-2-mlaquothylplaquogtergtol (I IB) 15-01-1
(4A) I7-U-3 (xntictiloroorraquonol (I2B) J3-70-3
USA) 101-93-2 pxmol (I3B) 193-39-J
(14 B) 179-00-0 RASENEUTOAL COMPOUNDS
( I B ) 13-32- raquocmlaquophtgtgtefgtlaquo
(36) 92-173 benzidine (2V) 107-02-S
( I B ) I20-I2-I l2t-tricMorobenzlaquonlt (3V) 10713-1
OB) 111-71-1 he laquo laquoch 1 or o benz erve (laquoV) 71-A3-2
(176) 47-72-1 hetraquocWoroltthlaquone (4V) X-23-5
U S B ) 111-- bu(7-cloroetrivl)ether (7V) 101- 90-7
(7CB) 9 I -3J -7 2-Chlororuprthraquolene (10V) 107-04-2
(73B) 95-50-1 l2-diCMoroblaquonzene ( I 1 V ) 7|3j^
( K B ) XI-73-1 13-didilorobtnzene (13V) 7J-3-3
(27B) 104-M7 1tmdash djcMorobenzene dkV) 79-00-3
C2IS) 9i9i-l 33-dictgtloroblaquoazidinr ( I JV) laquo-3-J
(33B) 12I -U-7 2gt-dinicrotoluer (14V) 7J-00-3 (KB) 4O4-7C-7 24-dinitrotoluene (UV) 110-73-1 (J7B) 122-A4-7 1J -diprienv lhydrraquo z irf (23V) lt7 tt 3
(MB) Z0-fc-0 UuorraquonThelaquo (2raquoV) 7J-35-
(W551 700J77-3 -ctilorophenyl prlaquonyl ether (JOV) 1M-40-3
( raquo I 6 ) 10I-J3-3 raquo-6romoprgtefgtyl prtenyl ether (32V) 71-17-3
(raquo7B) 33132-9 bU (2-cMorobopropyl) ether (33V) 10041-02-4
(raquoJ6) i l l -91- l bu (2-laquo^loroeTho)ry) methane 10041-01-03
(B) D-U) hexraquopoundj1|orobutaltlicne (31 V) 100--
(33B) 77-raquo7- heiKCtilorocycIopentadicrve (WV) 7J-CT-2
OB) 7IJraquo-I traquoo oh or or (raquo3V) 7raquo-17-3
(J3B) gtl-20-3 nphthraquolene (UV) 7raquo-I3-9
(546) n-tj) nitrobenzene (7V) 7J-2J-7
(426) U-Xl-4 bullJ -n itr o tod iphenyU mi ne (UV) 75-27-J
(OR) 421-W-7 N-oitrcnodipropYlirrUne ^raquoraquoV) 73-49-k
(446) I 1 7 J I - 7 bu (2-eltr^lheryl) phtfaUte 8200 (3ov) 73-71-1
(476) 13-U7 benzyl buryl phttwlite (51V) 124-kt-l
( U B I M-71-2 di-fl-utgtl pMhUre (13V) 177-II-
( lraquo6) 117-1 -0 dj-n-octvl prithlaquoUte (UV) 101-IS-3
(7CB) W-44-2 dielhvlphtraquollaquo (17V) 79-OI-t
( 7 | B ) I 3 I - I I - J dj^laquorTvipnthraquoUtr (UV) 7J-OI- (776) H-J5-5 bnro(raquogtnthrraquocefvr
Iab I D N o 2SS-10
C l ien t ID 1A64223
RASENEUTRAL COMPOUNDS
bfzoltraquogtprrene
benzoltb)flucrraquornNene
benio(llaquo)fluorraquonthene
chryiene
bullcenaDhthvien
raquontnrraquoctne
benzoltghi)perrlefgte
Iluorene
phergtraquonthrmlaquo
dibenzoltraquoMaithrraquocenraquo
indeno(123-cd)pvrene
prrene
VOLATHES
(frolein
bullcrvlooitrdf
benien
orbon Temchloide
CMorobeniene
1 7-dJchlorolaquothnr
111-trieftloroethine
ll-ltJichloroetrufle ll7-triCilorigtetMrlaquor
l127-tetrraquocMorothfllaquo
chloroethlaquo-e
7-dMoroeThraquo|virgtvl eirwshy
chloroform
11-didMoro^tfwnr
trinj- 1 2-dictMorolaquoirgtene
1 7-ltlicMoroproplaquorve
trini- 1 3-ltJichloroorcrpeoe
cu-lJ-lieMorocT oo eashy
rthy Uveniene
methrlene chloridf
chloromethine
bromome thraquone
bro mod iCTi lore met Mrgt
(Juorotr ichloromthraquor
di cMlor od 1 f 1 uore ngtet hj^gt
chloreltJbnjmomethne
te tr ten 1 or oet rx-r
laquouene 12000
tncMeroethe^e
Cidrr ium Chromiutr 10
All results are expressed as ucg veicht as received Nc ertrv denotes -0r ~ ^ 1 i rt
P h y s i c a l d e s c r i p t i o n of
SoilSludge
sample
Sanple workup
Vol i t i le f ract ion p^r Exf- rar r ion fST7Semivola t i le f rac t ion So^h^Pt Fgtr f ra r f ion
846-SOTO^ (SWRdfi-^SiO1)
Inorganic fract ion Ar id nio-psrirm
AOD COMPOUNDS
m CAS (2i A) tt-04-2 2raquot- Wichlorophenol
(22 A) J1-50-7 p-cfi I or o-n-cre laquoo 1
(2A) 13-57-1 2- ctiloroprienol
O iA) 120-13-2 2raquo^icMoroprnol
(gtraquoA) 103-47-1 2f 4mdash^imetSv Ip^enol
(37 A) U-73-3 7mdash Ti j oprtenol
(JraquoA) 100-07-7 mdash mdasho i Br opr^e no 1
JJ1A) 31-21-3 if mdash4 irtiTroprienol
(40A) J34-32-1 4 T4-4initrogtmdash 7 nte tny Ipnenol
(4A) f y _H 5 plaquontchlaroorwnol
(43A) J 01-95-7 prienol
rV ipoundNEUTRAlaquo- COMPOUNDS
( I B ) raquoJ-32-raquo
(3B) 17-17-5
( IB) 170-12-1
(IB) 1I1-7I-I
(17B) 4777-1
( I t B ) 111--
(20B) 11-31-7
(236) 15-50-1
(245) 51-73-1
(77B) 104-4-7
(285) 11-14-1
(336) 121-142
(34B) 404-70-2
(J7B) 127-M7
O1B) 2O4--0
(406) 7003-72-3
(416) 101-35-3 lt raquo 2 6 gt 3H3I32-1 ltraquo36) 111-11-1 (57B) S7-U-3
(336) 77 -raquo7-
(36) 71-31-1
(33B) 11-20-3
pound34 6 1 n-i33 (UB) tt-30-4
(436) CI-44-7
(4461 117-11-7
(47B) U-417
( U B I 14-747
(U6) I17_t-0
(7CS) l-laquo2
(7 I B ) t J U t l - gt
(7761 54-55-3
CT-~- i_i w i Miirn 0
resul ts
b^TMdint
1 2 t-o- icn lorobenl ergtlaquo
SeTraquochloroblaquorierraquoe
hrxchlorolaquotSlaquone
bu(2-chloroethv|gtether
2 -lt3M or onraquo ph ti1 ene
1 2-ltJictilorotgtmzcne
13-dicWorotxerzene
1 4-djch 1 or otxn z ergte
33-ditfgtlorolgtlaquoniidirraquo
24-dinitrotoloene
2 4-dtnitro toluene
U-dlpoenylfiydrraquoiilaquo
(luoranthene
raquo-cfJorophenyl poenyl ether
Mx-omopfieflyl phenyl ether
bis (2-cMorooopropyt) ether
bu (2-ctilorcxtSorv) meiSkte
hezkOilorobutadicne
hei acM or ocyc1 ofMn udi cne
oo prior one
nphthlene
nurotxniene N -ni tro Kxd ipoenyU mi ne
N-rutrowxhpropYUmJrw
bu (2-thylherl)(gthlaquoiraquoUtraquo
blaquoniyl buryl phtfraquolaquoUte
dt-^t-^xjrvl pfttfuiLitY
dj-n-octyl pitflaquoLitraquo
dirthvl phtruUtt
OArriett^vt prraquoT^Lraquot
bnzoltklaquonihnicer
22 Chronium
ire ev^rescei as uc ^ ^i-~ht-
Lab 1U N o 28B-1
C l i en t I D 1 R R 7 A A R
RASpoundNEbTRAL COMPOUNDS
benroltb)fluorraquorgtthfflf
benzoraquollt)fluor intone
ltrylaquo-gte
bullcenioithylen
raquomtirraquoenlaquo
ben z oltxh i)per v lene
lloorene
poentnthrrne
dibnzo(4h)laquonthricrne
mdeno(I23-rt)pvre-ie
pyrene
VOLATU-Ei
bullcrelem
bullcrvlonio-Ue
benzene
caj-bon traquotrraquochloraquo-idr
Ctilorobernene
l2-diehlongtethne
iii-tnctltiorotKraquor Trace 1 T 1 -4)Ctilorampe^hArw
l f 1 ^-tric^i lor oefvtrve
l t l 22-teTrtclloroetl^Ane
ehloroethraquone
2-chloroltthr|viw| ttrve-
Chloroform
1 1 -ltSicMorot^nr
trinraquo-l2-dictiloroetrne
12-d^loropOStn
trinil3^ichloroproone
eis-lJ-diChloroprooene
rrhylberuene Tarce methrlene ehlor tat Trace
Ct1 or o m e t Kirgte
bromometKtrte
bro mod i rfi lor o rrgte t Mne
Uuorotrlchloromethraquo^e
OJ CJ lor od 1 f 1 uoro met hraquone
chJorodibromometKATgte
laquotrlaquociloroethrrx
toluene 9
tricolor otheir
fsw
T9
Sifi-TOSO)
(73B)
(7IB)
(75B)
(7(B)
(77 B)
(71 B)
(71B)
(SOB)
( t lB)
(I2B)
U3B)
(M B)
(7V)
(3V)
(4V)
(4V)
(7V)
(10V)
(11V)
(13V)
(14V)
(13V)
(14V)
(11V)
(23V)
(21V)
(30V)
(32V)
(33V)
(34V)
ltlaquoV)
( raquo J V )
(44 V)
f raquo 7 V )
(UV)
(V)
000 (30V)
Tlfl 151V)
(15V)
^00 (14V)
(17V)
(UVgt
-1 ZINT
CAS 30-32-J
205-11-7
207-01-1
211-01-1
201-14-1
120-12-7
111-24-2
14-73-7
13-01 -laquo
33-70-3
113-31-5
121-00-0
107-07-t
107-13-1
71-43-7
34-23-3
101-W-7
107-04-7
71-35-t
75-3-3
7^-00-5
71-34-5
75-00-3
110-73-1
(7-14-3
73-35-4
154-40-5
71-17-5
10041-07-6
10041-01-05
100-4I-
73-OT-2
74-17-3
74-13-1
73-25-2
75-27-4
73-41-4
75-71-1
174-41-1
127-U- IOUIS-) 71-01- 75-OI-
130
Lab ID Mo 2887-4
Phys i ca l d e s c r i p t i o n of sample C l i en t ID 4A5760
Liquid Sample was predominantlv a hvrlrnrarhnn bl pnd
Sanple workup Voli t i le f ract ion PEG Extraction (SW 846-5030) Scrnivola t ile f rac t ion Sonication Extraction (SW 846-3550) Inorganic f rac t ion Acid Digestion (SW 846-3050)
AC3D CS3U POUNDS 5AipoundNEUTlUgtJ- COMPOUNDS
ri CAS PPraquo CASf
(210 U-04-2 2raquot- tricMorophrnol (7)6) raquo-32-l braquoniolttVyre
[EM 51-50-7 ^-cti 1 or raquo-m-lt rlaquo laquoo 1 (7raquoB) 203-M-2 biMo(b)(luorinth^f
2 A) raquo5-57-J 2- cfiloropheryjl (7 3 B) 20701 benro(ilt) floor in tlaquo^e
(31 A) 120J3-2 2raquo-ltJicWoro(ygtlaquotx)l (74B) 2II-OI- chryve^e
(MA) 105-47- 2l-dimlaquothvloSrrgtol (77 B) 20Uraquot-J bullcwrioMhylene
(57A) u-73-3 2- ruTroohrgtol (TIB) 120-12-7 raquontnncergte
(34 A) 100-02-7 -oitrophenol (7gtB) lraquol-2raquo-2 benio(ghi)cgtrrylngtlaquo
(3Agt 51- 21-3 2 -4 initropherwl (SOB) tt-73-7 fluorme
(tOA) 53-37-l t-dinitro-2-mlaquothy lpNlaquoxil (II B) 15-01-4 pheAinthrrnlaquo
(A) I7-U-5 tgtentraquochlQroiywnol (I2B) 53-70-3 dibenplusmnoltraquoh)fcnthrraquocrne UJJ 101-55-2 rfwtwl (I3B) lraquo3-3raquo-3 indenol 1 23-cd)vrtie
(UB) I2raquo^X3-0 pyrer BASENEUTOAL COMPOUNDS
VOLATO-ES (161 I3-32- raquoclaquonraquophttgtngtf
(5B) 12-17 -J btniidir (2V) gt 07 -07-1 bullcrolem
(IB) 120-17-1 l^^iricfvleroboMux (3V) 107-13-1 bullcrvlonit Jlaquo (raquoBI IIS-7t| SeraquoChlorotgtlaquoterlaquo (raquoV) 7IJ3-7 benient
(I7S) 4772-1 heLCMorolaquothinc (tV) J-23-5 crtgton wtrraquocMoidf (UB) I11-U-I bll(2lttllorolaquot^w gtetNer (7V) 101-W-7 ltAtoroxniergtlaquo
(203) Jl-31-7 2 -etvl or onlaquo ph traquo I en e (IOV) 107-04-2 1 2-ltlicMorolaquoTKlaquone
(25B) raquo5-30-l 1 2-dichlorobenzene ( 1 1 V ) 71-JJ-t llI-trichlorolaquotNlaquoe (2 B) 31-73-1 l3-ltlichoroblaquonzenlaquo (13V) 7J-3A-) 1 1-6 1 cM or Of t (Mr
(77B) I04-M7 I -di CM oro ben z eoe ( I k V ) rraquo-oo-j l12-niichlorolaquotfvirraquolaquo
(2IB) raquol-raquo-l )J-dichlcroblaquorLiidinr (IJV) rgt-3laquo-3 J122-tetrraquochlcrolaquoTrie
(33B) 12I-Ilaquo 2 2-dinia-otoluer (UV) 73-00-3 Ctgtloroltthne U4B) laquoJ-70-7 2 t-dtnitrotoluene (1raquoV) HO-73-1 2-ltJilorocthv|vL-v| etrveshy
(J7B) 127-M7 14-dip^wnylhydraiine (23V) C7-U^-3 Ctilorofcrm
(JraquoBJ 2Ot-ugt-0 CJuarlLnthefe (2raquoV) 7J-33- 11 -ltlicMorcxil^nr
(mei TOCJ-77-3 -chJorophcnyl phenyl laquoKr (xgtvraquo lK-^0-3 tnjM-l^-diC^lofCKtl^nf
( M B I IOI-J5-3 -6romophnyl phenyl ether (32V) 7I-J7-3 12-dicMoroprosaA
(raquo2B) 3M3I32) bU (2-cMarobopropyU rtNer (3JV) ICXU 1-07-4 trraquoni- 1 3-ltjictgtloroBoor^f
(OB) t l l f l - 1 bi5 (2-cMoroetfxgtrv) meihtrw lOOt 1-01-03 cu-O-dichloroprose- (32B) D-U-3 hrxaetilorobutadierw (UV) 100-laquol-raquo rthylbenien 1^00
(33B) 77^7- he i kcMor ocyc 1 openudi crw (UV) 7J-OT-2 rrveThvlerw chlof idf
(36) 7I-gtraquo| oop^troo (raquoJV) 7raquoJ7-3 CtgtlorBmethne
(338) raquo|20-3 nraquopfitfillaquofx 1200 (wv) 7raquo-l3-raquo bromorrgtlaquothne
(34B) nraquo3) nitrobenzene (raquo7V) 73-23-2
(CBI U-Xl-4 N -fl i iro lod iphen yU mi nr (UV) 7J-27- bro mod i cti lor o mT bull- (OR) 42l^-7 N-^itrolaquoodipropylmlrlte (raquoraquoV) 73-traquo-laquo tl uor o tr i cfi lor o mlaquoT itr (UB) I I 7 J I - 7 bn (^thylheraquoy|) phttilaquoUtT 110000 (XIV) 75-71J QJ ct )or oltJ 1 f 1 uoro rrgtei ^bull gte U76) U-U7 blaquonzyl buryl pttTfKUie 12000 ( j i v ) m-i-i ctil or od ib ro mo met h xnf (UB) M-7i2 d i -n -bo TV 1 ft thlaquo U tlaquo (13V) 127-11- te trraquo cfl lor ot hlaquoTgtf (OBI 117-4J-0 dj -n -oc t y1 Jgth fflaquo U re 6 200 tuv) iom-3 tolucie ^70
(7CB) u-u- djrthyl phtJMlire (17V) 7raquo-OI-4 irictilarcraquo^lt-ir (715) 1 3 1 - 1 1 - 5 oVnrrhyl pMtfaUte (UV) 75-OI- v i M v l CMor idr
(T76I 5-55-3 blaquorgtzo( Unihrlaquocme Xylenes 1SOO
Cad- iurn 2 2 on Chromium - - Z I N C ^ ~ P r
Ai results arc expressed as ugc weight as received Xo entry denotes not detects
Lab ID No 2887-3 5A 57709 Phys ica l d e s c r i p t i o n of sample Cl ien t ID
LiquidSludge Liquid appeared to be a hvdrnc-Arhnn blonrl
Sample workup
Vol i t i l e f r ac t ion Methanol Extraction fSW 846-5030^ Semivolatile fract ion Sonicatlon Extraction fSW 84 f i_3550gt) Inorganic f rac t ion Acid nic-psr-inn fSW 846-30501
ACS3 COMPOUNDS BASENEUTRAL COMPOUNDS
f f t CAS CAS (2IA) tt-04-2 (738) JO-32-J DCftZ OTamp p V^^^ff
(22 A) 3laquo9-50-7 p-cttl or o-m-cre laquoo 1 (7VB) 205-99-2 p^^izot oil lyor 4-^ t ^ltf ^^
(2 A) raquo5-37-l 2- CJiloroprieno (75B) 207-01-9 blaquonioltllt)flultxtn^it
(31A) 120-13-2 2raquo-dictgtlcr8tgtrfX)l (74B) 211-01-9 Chryeolaquo
(3 A) 103-47-9 2 -d irrgtet hv Ipherto1 (77B) 201-94-1 laquocnphthyle^
(37 A) 11-73-5 2- rutrop^enol (7IB) 120-12-7 bull^thrjc c^
(MA) 100-02-7 -flitroprlaquorv3l (79B) 91-2-2 bcnroltKhi)pefraquoler
(79A) 31-21-3 2 -d in itr eoricno 1 (IOB) 14-73-7 tluoren
(40 A) 33-37-l 4-d in itr raquo-2 -met hy Iphtnol ( I IB) 13-01-1 poltrtAOthrvTgt^
(44 A) 17-14-3 plaquon1 CM or o^eno I (I2B) 33-70-3 dib^fi-o( 4(K)Aji thirl c c^f (43A) 101-93-7 prwnol (S3B) 193-39-3 indcnotlIJ-ctflsvfie
(SB) 129-00-0 pyrene ftASENEUTRAL COMPOUNDS
( I D )
(5B) 92-X7-3 b^zidrw (2V) 107-02-1 bullcrolrm
(IB) 120-17-1 1 2 fc-Tr ICJ caro blaquoni crw (3V) 107-13-1 bullcrvlonitrij
(93) 1IU7I1 Seraquochlcrotgttniegtlaquo (4V) 71J3-2 blaquonienlaquo inn (17B) 4777-1 hexat^lorcwthgine (4V) H-23-5 carbon ttTricllixidf
( I I B ) 111-wJ bll(2-lt3^1oroltt^w)ether (7V) 101-90-7 ciloroblaquonzene
(20B) 91-31-7 2-ctdo-ont she Ime (10V) 107-04-2 12-dieftloroerane (25B) 95-50-1 l2-dilorobenzene ( 1 1 V ) 71-35-4 11 1 -tricMorotn-laquo
(2ampSI 51-73-1 13-dicMo-obenxerw (13V) 73-3-3 1 1 -d i CM orcxt M-
(77 B) I04-H-7 1 -di ci 1 or o benI erw (UV) 79-00-3 llJ-WiChlorolaquoflaquonlaquo
(2J6) 91-90-1 SS-dKJilorotxniidinc (13V) rraquo-3laquo-3 l122-tetrlaquocftlorelaquoTrne
(35B) 12| |k-2 2fc-dintrotoluene (14V) 73-00-3 diloroeth^e
(gt4B1 404-20-2 24-diniTrotoluenlaquo (19V) 110-73-1 2-cMortxfthv|vL-raquo trlaquoshy
(37B) 122-447 12-diphenylhydriin (23V) 47-44-3 cMoroform
(J9B) 204-U-0 Ouormntherve (29V) 73-33-i ll-diCMorolaquot^nf
(fcOB) 7005-77-3 k-cMarophfy| prlaquonyl etScr (gtOV) 134-40-3 trraquonraquo- 1 2 -dicMoroc t Nenf
(raquo I6) 101-35) raquo-6romoprny| phenyl rther (32V) 71-17-3 12-diChloropostn
(raquo2B) JH3IO2-9 bU (2-ltplusmnlaronopropyl) rthrr (J3V) 10041-02-4 trni-l)-diirMoroxtgtOpnf
(OB) I I 1 - 9 I - I bu (Z-chloroethxjrv) metSampnlaquo 10041-01-05 CU-D-djcMoroproOf-W
(32B) 17 -U -3 hiraquocfilarobutraquodiergtlt (3JV) 100-4U rttyligtlaquonitrgtlaquo 5300 (33B) 77-raquo7-raquo hrxicftl or ocrclopei tidier (UV) 75-09-2 nxthylenf ctilor ifif
lt3B) 71-391 ao prior or (raquo3V) 7raquo-17-3 rtloromrtha^r
(356) 91-20-3 nlaquoprithienraquo Trace (44V) 7raquo1Jraquo bromltmlaquoth^
(MB) n-93) ft i vo b^nz c^^ (raquo7V) 73-23-2
(425) U-30-4 ^bullf i^OftOOL^ri^ny lArrunf (UV) 73-27- bro mod i cgt lor o i~ t gt
U3amp1 Ul-4-7 N i itr CrtoO ip ro py 1 laquo ml r (raquo9V) 73-49-k U uor o IT 1 et loront Mrgt (UB) II7-1I-7 bu (2-Ihythlaquoryl)prtfUtr 59J300 (30V) 73-71-1 dj ci kr olt11 f 1 uoro rrrt (Nrgtraquo
(47 B) L3-41-7 txniyl burvl phthlaquoUtr ( 3 1 V ) I2-1-1 ch1 or od i b ro mo mi IMP r
(UBI U-71- 0-A-fcurl BMMliw (13V) 127-ll-i rt tr t cM or of tNr
Uraquo6) 117-li-O di-n-oCTv| pnttlaquoUfr 6000 (UV) lOt-II-3 toluenf 5700 (7CB) U-447 djrthvl p^tfvilirt (17V) 79-01-4 WiCMoroth^e ( 7 J B I U l - l l - 3 d^M^vl prttgtraquoUW (UV) 73-01- vinv t cMor 10 (77 Bgt H-35-) brto(raquollaquonthncrTraquo Xylenes 19000
Caen 1U~ 1 Chromium =2 Z I N C
All results are expressed as up g weight as received No errrv ripn^t-plt
Lab 1Lgt No 2887-5
rhyr i r n l d e s c r i p t i o n o f sample C l i e n t in 6857710
LiquidSludge
Sample workup Vol i t i l e f r a c t i o n PEG Extraction (SW 846-5030) Semivolat i le fr action Sonication Extraction (SW 846-3550) Inorganic f rac t ionAcid Digestion (SW 846-3030)
AOD COMPOUNDS BAStNELTTRAL COMPOUNDS
rr i CASI CAS (21 A) tt-04-7 (736) 30-32-1 bntoltraquogtprrene
(23A) 3-9-50-7 p~lt1 or o-m-c rraquo1 (78) 205-99-2 ben to( Sgt )1 1 uor raquon I he-gtf
(7raquoA) 93-37J 2- etilorophenol (73B) 207-01-9 beriioltk)(luortntrgt^f
(3 IA) 170J3-2 2raquo-dicMoroprnol (7(B) 2II-OI-9 eifVMTie
(3 A) 03-(7-9 24-4mlaquoThvlDheno| (77B) 20l-9(-i bullceraoMhyler
(37 A) tt-73-5 2- rue-oorienol (718) 1 20- 2-7 laquoflthrraquocene
(3 A) IOO-02-7 ^Mtroprwnol (7fB) 191-24-2 beraquoMoltsrM)plaquovllaquox
(39 A) 3I-71-5 2-4 ini tr ophero1 (tOamp) K-7J-7 tluwtrie
((OA) 33-37l (-lt iMtro-2-methylphenol (tlB) D-01-J phenATithrene
(4A) I7-44-J pentichlorophenol (128) J3-70-3 dilwnioltraquoh)laquonthrraquoceif
(OA) IOI-95-2 prwnol U38) 193-39-3 indeno(123-cd)vcne
(MB) 129-00-0 pyrergtlaquo 6 ASENEUTILW- COMPOUNDS
VOLATH-tS ( I B ) 13-32-9 ftCYTNA pO IT H I raquolt
(38) 92-17- o^nzioinc (7V) 107-02-1 aero le in
( IB) 120-I2-I l2k-o-i(3iloroblaquontergtlaquo (3V) 107-13-1 laquocrvlono-U
OB) Jl l-7fc | he I raquocti 1 or o blaquonI enlaquo (V) 71-43-2 Oltf2 tO^
(17B) (772-I he uc^i 1 or of t h ne ((V) 34-23-3 CJU JOO Tt TTlCfllo^ iCpound
( I I S ) bu(2-rfilcroethv|)ether (7V) 10J-90-7 laquoWoroblaquonzeoe III-44-4
(KB) 9I-51-7 2ltfMoronlaquoohttvraquolwe (10V) 107^)4-2 1 t2^ojo^loroetfft^c (2JB) 95-50-I 1 2 -dichlorotgtlaquorlene (11V) 71-55-4 1 1 1 -trichloroeihtr (251 541-73-I 13-dchlorotxniene (13V) 73-J4-3 1 1 -dieMoreeraquohraquorlaquo
(77Bgt 04-lgt4-7 1 mdash djcMorobenlene (IkV) 79-OO-3 t12-tricriloroeflaquofgte (2gtB) raquolraquo-l 33-didMoroblaquonjidirlaquo (13V) 79-34-3 1122-tetrcnicroeir^ne (33B) 12 I I 4 -2 Z4-diniiroioluerlte (1(Vgt 73-00-3 e^loroetruuie (KB) (04-7C2 2 (-dinitro toluene (19V) 110-73-4 2ltJilorolaquotr(v|vLnraquolnhlaquo (175) 122-447 12-dipr-enylfiydrmiine (23V) (7-44-3 chloroform
(J1B) 704JJ-O Huor^thrr (29V) 73-33-4 lI-ltJicMoroltthcne
(OBgt 7003-77-3 -ctJoroprienvl phenyl ether (JOV) 134-40-3 irirraquo-12-dictila-olaquotrlaquone
( raquo I B ) IOJ 33-3 -6ogtmoprienyl phenyl ether (32V) 7I-I7-3 l7^lichlorepreoine (laquo2BI 3H3raquoO2raquo bit (2-chlororaquoopfT5pyO ether (3JV) 10041-02-4 trint-l3-ltJicnloroBlt-ooee (OB) 111-11-1 bis (2-cMcroetro(v) metSuvr 100(1-01-03 CU-lJ-itflloropOO-^
(376) t7-U-3 hraquoz raquoch1 or o bu tlaquodi ene (J1V) )00-1- erhylberuer 1400 (33B) 77 -gt7- hei tchl or ocyc1 open traquodi ene (raquoV) 73-09-2 methylene chloriCf OB) 7raquo-3raquo-l BO prior one (raquo3V) 74J7-J eMorametrutne (33B) raquol-raquo-3 naphtfalene 100 (UV) 74-13-9 bro rrvome t hrgt (3iB) n-raquo3-3 niireblaquor)iergte (raquo7V) 7J23-2 (CB) U-XH N -01 ITo tod 4gthenyU rru rr (UV) 75-27-4 bro mod i ch lor o rrx t f4Ugt ((36) 42IO4-7 N-nnroodipropYlraquomlrlaquo (raquolaquoV) 73-4t-4 JJuorotr lchloronvlaquoiMftlaquo (Uol U7-1I-7 ba (2-etrylNraquoYl) phtt^Ure 100000 (30V) 75-71 -raquo dj cftlcr od U 1 vraquooro rri NUT
(47 Bl 13-44-7 t^niyl butvl phthiUte 13000 (31V) 124-41-1 chlorodibromorrwt^r
lt U E gt ) U-71-2 d-ojjurvl phtf^Ure (13V) 127-11-4 tr trbullcti loro rirr
laquoraquo6gt 11704-0 dl-fl-OCTvl pfltMUM (UV) 10t-ll-3 toluene fiin (TtS) raquo-laquo djrthvl phttuliTr (17V) 79-01-4 tricolor oethenr lt 7 | o l 131 -11 -1 (UV) v i n v i chlcwidr dimrlKyl rrftlaquoUTraquo 75-OI-J
(T75I J4-35-J blaquoTMOlt^trrlaquocr^ gtylenes 1200
Cadr ium 3 Chromium 21 ZINC 150
All results are expressed as ugg weight as received y0 entry denotes not detect
Iah I D No 2887-2
Physical descr ip t ion of sample
Strained Soil
Sample workup
Voli t i le f rac t ion PFG Extraction (^W 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-3540) Inorganic fract ion Acid Digestion (SW 846-3050)
ACS) COMPOUNDS
rn CAS Tft CASf
(21 A) tt-04-2 (73B) 50-32-4
U2A) 71-50-7 P-ch 1 or o-m-cre laquoo 1 (7k 8) 205-11-2
(2 A) raquo3-37-l 2- chloroprraquoeno| (75B) 207-01-1
(3IA) 120-13-2 2raquo-4ichlorophenol (74B) 21UOI-1
(3 A) 103-47-1 24-dimethvlphenol (77 B) 201-14-1
(57A) U-75-3 2- njtroDhenol C7I5) 120-12-7
(MA) 100-02-7 a-flitrophenol (71B) |1l-2raquo-2
(51A) 51-21-5 2 -d in i tr o phetio 1 (SOB) K-73-7
(40 A) 53-57-l raquo 4-dinitro-2-methy lprnol (tlB) 15-01-1
(4 A) 17-14-3 plaquoitraquochloroorlaquonol (I2B) 53-70-3
(43A) IOt-13-2 prlaquonol (13B) m-31-3 (MB) 121-00-0
BJ KSENCLmLAL COMPOUNDS
(IB)
(3B) 12-17-3 bcnzidine (2V) 107-07-1
(IB) 120-17-1 1 2 k- tr i ch 1 oro benr ene (3V) 107-13-1
(IB) I1U7I-1 he it raquocM or o boiz ergte (raquoV) 7I-J3-7
(12B) 47-77-1 he traquoch 1 or oet hlaquo ne (4V) 54-23-3
(116) 111-- buC-cJiloroethv|gtether (7V) 101- W-7
(20B) 11-31-7 2 -ltft 1 or on ph ttvraquo 1 laquon e (10V1 107-04-2
(23B) 15-30-1 1 2 -dictilorobeni ene (11V) 71-55-4
(25) VI-73-1 1 3 -ltJ i ci 1 or o blaquoiz ene (13V) 73-3-3
(77 B) 104-M7 llaquo-dchloroblaquoMeoe (HV) n-00-3
(2IB) 11-lk-l 33-dicMorotxTLtidinr (15V) n-3raquo-3 (33B) 12I-U-2 2 ltgt -4 in i tr ot o luene (14V) 75-00-3
(MB) 464-20-2 2 4-d initrotoluene (11V) 1 10-7 3-1
(J7B) 122-447 1 2-diprieny Ihydrti ine (23V) 47-44-3
(316) 2O4-UO Ouorraquonthene (21V) 73-33Jshy
(WB) 7t)03-77-3 ^-cJJorophenyl prienyl ether (JXgtV) 154-40-3
(MB) 101-33-3 -6romopriefgtyl prienyl ether (32V) 71-J7-3
(raquo2B) 3431-32-1 bit (2-chloroboproprO ether (33V) 10041-07-4
(OB) I1U1I- I bu (2-ltMoroethorv) methane 10041-01-03
(52B) r-u-3 hexachlorobutadiene (J1V) 100-l-raquo
(33B) 77-47- he z raquoctlt lor ocycloqenud i crte (MV) 75-01-2
OB) 71-31-1 ao prior one (raquo3V) 7raquo-17-3
(33B) 11-20-3 nlaquopntrlaquollaquone (UV) 7raquo-13-1
(MB) n-13-3 nitrobenzene (raquo7V) 73-23-2
(UB) U-30-4 N-nnroiodiprienyUmine (UV) 75-27-k
(436) Ol-U-7 N-nitrModiproOYlmJne (raquo1V) 73-41-
(UB) 117-117 bu (2-laquothylheiry) phtrlaquolte 8800 (50V) 75-71-1
( 4 7 B ) L3-U7 blaquoniyl buryl phthaUte 30 (31V) 12I-H-1
(UB) U-7U-2 di-o-burvl phtrMUte U3V) I27-I1-
(416) II7-U-0 dj-n-oCTvl pritntUtr 1200 (raquo4V) IOUI1-3
17CB) U-44-2 djetiTi phrtultrt (raquo7V) 71-01-4
( 7 I B I 1 3 1 - 1 1 - 3 dimnfTraquo| prThraquoUtr (UV) 73-01-
(776) H-35-3 berMolta^thrCF^
Cl ien t ID 8 A - S 7 4 6 1
RASENEUTRAL COMPOUNDS
benzofbtfluor^tMe
benzodclfluorintoent
Ctiryiene
cenoithylene
raquonthrraquoctne
benzoltKhilpervlefgte
floor ene
prlaquofnnthrene
ltlibenplusmno(4h)knthricrnlaquo
inogtno(123-rt)pvrrne
pyrene
VCX-ATIIE5
bullcrolem
bullcrvlomn-U
benzene
carbon tetrtchloridf
chlorobenzene
1 2-oUchloroethAnf
lll-trichloroethlaquone
ll-dcfioroethrraquo
1 1 2-tricilorolaquothraquorw
1122-tetrichloroeTtvin
chloroethre
J-ctiloroethv|vinv| etrgte
chloroform
11 -denier oethene
trinraquo- 1 2 -4 cMor oe t hens
12-dcMoroprooine
^Lns~ I f 3-4ic^ lo^opf oo^^^
Cli-l 3-dicMoroprooe^e
rttiylbenzene
methylene cnlonfle
Ch 1 or o me t hane
bromome thane
Trace
bro mod i cMor 0 me t hane
(Juorotrlchlorome thane
chlorodibromometKinf
tetracnloroethervp
toluenetr icMoroel he-if
Trace
CacTiiun Chromium ZINC f
All resxil ts are exprp^spr i K-i
Phys ica l de sc r ip t ion of sample
Strained Soil
Sample workup Vol i t i le f ract ion PEG Extraction (SU 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-5340) Inorganic fract ion Acid Digestion CSV 846-3050)
ACE) C30laquo POUNDS
m CA5i CASraquo (2i A tt-C-2 (73B) JO- 52-1
(22 A) J1-JO-7 p-ch 1 or raquowTv-cre 101 (7raquoB) 203-raquoraquo2
(2 A) raquo)57-J 2- chlorophenol (73B) 20701-
(31 A) I25J3-2 2k-4icttlltroptlaquonol (7tB) 211-01-1
(3A) IO)-7-raquo 2-dimlaquothvlpNrnol (77 B) 20l-raquoi-
(37 A) u-rj-j 7- niTTOphenol (TIB) 120-11-7
(MA) 100-02-7 -rtropN-rraquol (7raquoB) lraquol-2-2
(JraquoA) JI-21-) 2-d initroprietys 1 (IOB) U-73-7
(MA) 53-37-l Udinnro-2-mlaquothylphenol (UB) I5-OI-J
(Agt I7-U-3 pentichlcropwnol (126) 33-70-3
laquo)Agt 10l-raquo)-2 phenol (I3B) IJ3-31-3
(MB) 12raquo-00-0 AASCVflCUTRAl COMPOUNDS
( I B ) I3-32- bullcnraquophtber
(56) raquo2-17) bnzidirlaquo (2Vgt 107-02-1
(IB) 120-12-1 l2btrilt7tlorotgteizegtlaquo (3V) 107-13-1
traquoB) IIraquo-7fc | heikcMeroblaquonzergte (V) 7l-3-2
( I 2 B ) 4772-1 he ueft 1 or olaquot hraquo rgte (tV) laquo-23-3
( i ts) III-- biraquo(2-cMoroethv Dethrr (7V) 101-W-7
(20Bgt 1I-3I-7 2-cMoroflaquophthlene (10V) 107-Ofc-2
(2)6) raquo5-50-l l2-dchlorotgtlaquonzefgte (11V) 71-33-4
(28) 3l-7)-| 1 3-didMoroblaquonrenlaquo (13V) 73-3-3
(27B) 10t--7 l-diclorolgtmzerlaquo (iV) rraquo-00)
(216) raquoI raquoltbull- 33-dichloroblaquoMidiflaquo (13V) 79-31-
(356gt 2I- l-2 21-dinitrotoloen (UV1 73-00-3
(UB) laquogt- 20-2 2 (-dinitroto luenlaquo (HV) 110-7J-J
(376) 122-W-7 14 -dipheny Ihydrzire (23V) lt7-M-3
(396) 2O--0 tJuoruMSene (2raquoV) 7J-35- (OB) 7003-77-3 -c^lvophenyl pNrnyl ethlaquor (30V) 1H-W-)
(MB) 101-33-3 bull-bromopriefiyl prienyl ether (32V) 7t-t7-3
ltraquo25) 3HJI-32-1 bU (2-cMoroaopropyl) rthrr (33V1 10ltX 1-02 -6
(06) l l t - t l - l bis (2-cftloroetSorv) metwne 100lt]-01-03
(32B) C7U-3 heraquoraquochlorobutidierx (31V) 1 00-41-
(3361 77-7-raquo hexiOilorocycloptfiudlerve (raquoV) 73-0raquo-2
(56) 71-51-1 no ph or one (raquo3V) 7raquo-17-3
(3)6) raquol-raquo-3 rwiphtfalme (UV) 7raquoJ3-raquo
1361
LUB)
H-133
14-30-4
nitrobenzene
^ ri i iy o too ipf^^ y LA r^i rtf ^ 7V) (UV)
73-23-2
73-27-
(436) t21--7 M^TI iff frfcO^ip ropy Ift mJf^ (gtraquoV) 73-4raquo-raquo (UB) I17J1-7 bu (2-rThyiruMcyDpMtvUtr 570 (jov) 73-71-1 ( U B ) U-41-7 blaquonzyl buryl phthlaquoLite (31V) l2k-raquo-l ( U B I U-7I-2 di-n-burvl pitftALtTe (raquo)V) 127-lt-fc
(OB) 117- -0 dJ-fraquo-oCTvl phlJ^Ute (UV) IOt-It-3
(7CB) 14 -W- 2 djelftvl phtfalitt (17V) Tt-01- ( 7 I B I 1 J I - I 1 - ) duTNnhylphttsraquoUw ltUV) 75-01-
(77BI X-))O lgtmrlaquoigtmhrraquoctf
Cadmium f iQ Chromium 15 ZINC
Tab ID No oo -
Cl ient ID 8A-A-64220
fcASENEUTTRAL COMPOUNDi
blaquofuo(raquo)pyrrtgte
bfizo(b)(loortAth^e
benzo(k)f|ulaquoin1herf
Ctiryiene
cenDraquoMrwlene
fcftT^rict^t
D^flZCT (fftl)pC^ V Itf^p
(luorene
phen^threne
diiwnztKthlanthricene
indlaquono( 1 23-lttf)pvrene
oyrene
VOCATtLES
bullcrolem
bullcrvlooitriJe
bervteoe
carbon WTTicMoridf
chlorobenze^e
12-djcMoroetfane
1 1 1 -tricolor ex tKraquon
1 1 -dicMarcx t hrlaquo
1 1 2-triChlorothraquorw
1 122 -laquotrraquocM or o-hraquorgt
cMoroettu^e
2-cMorlaquothv|vuy| rseshy
chlexeform
ll-dchloroctfgtn
tri^iraquo l 2laquoflic^ loTo^i rgtcnt
12-dicWoroproptrs
Winl-l3-dicMoropfooene
Cu-lJ-djChleroprooe^
rrtiylfrenzene
methylene ctiloride 0 64
cMorometHAne
bromomlaquothlaquone
bnsmoform
bro mod i eti lor e me t Nine
0 uor o tr 1 cMor e rrgtlaquo t Nnlaquo
dj di tor olaquol If 1 uoro mraquoi Nrraquo
chlorodibromonveiKme
re tr a en 1 or or fxrvr
toluene
D-ieWoroefwne
entry denotes not detect All results are expressed as ugg weight as received Xo
Lab 1) No 2887-8
Physical descr ipt ion of sample
Sf-rs inpH 9 n i l
Sample workup
Vol iCi le f ract ion PEG Extraction (SW 846-5030)
Scmivolat i le f ract ion Soxhlet Extraction (SW 846-3540) Inorganic fraction Acid Digestion (SW 846-3050)
ACD O3MPOUNDS
m CAS fPraquo CASf pi A) tt-Ot-2 Zraquot- tritilorophrgtol (73B) 30-32-1
ft M -3o-7 p-cMorraquo-m-crTraquool (7kB) 205-raquo-2
(2 A) raquoS-37-l 2- cMorop^erxgtl J73B) 207-OI-raquo
(31 A) 120-13-2 l^ictiloropix)l ^7tB) JII-01-
(3 A) |03-7-raquo 21^-dimeThvlphenol (77B) 20t-raquot-l
(J7A) tl-73-3 2- rutropwnol (71 B) 120-12-7
(MA) 100-02-7 -MO-opwnol lt7raquoB) lraquol-2-2
fJraquoA) 3I-2J-3 2-dinitrop^laquoTgtoI ((OB) U-7J7
(laquogtA) J34-37-1 lt-dinitrfr-2-methylpwrxgtl (I IB) I 3-0 1-1 (raquoAI 17-1 3 pcmacMcroptonol (S2B) J3-70-J UJA) IOI-raquo5-2 phenol (IJB) MJ-39-J
(tBgt 12raquo-00-0 RASEfZUTRAL COMPOUNDS
( IB) 13-32-f raquocertaprithene
(3B) J2-17-3 twnndinc (2V) 107J2-J (IB) 170-I2- lr2k-triOilorobenzerlaquo (3V) 107-13-1 (raquoB) I11-7I-I hei bulllt1 ore blaquont ergtlaquo (raquoV) 7l-3-2 (1B) 47-72-I he ucft 1 or oe t h n (tV) 3-23-3 (116) |II_wJ bu(2-ctiIarothvI)laquotNer (7V) 101-90-7
(20B) raquoI-JI7 2 -cW or orvraquo ph tf I ene (10V) I07-Ofc-2 (23B) J3-30-I l2-lt5ictiloroblaquonzeoe (11V) 71-3J- (245) 3I-7J-I 13-dic^lorotxenzenc (13V) 7J-3-3 (27B) 104-K-7 1 mdash diC^lorobtnrerve ( lraquoV) 7^-OO-5 (21 B) raquo|raquo| 33^icftlorobenzidifv (I3V) rgt-j-3 (33B) I 2 I - U - 2 2ltgt-dinin-o1olvraquorgte (UV1 75-00-3
(J4B) 404-JO-2 21-dinitrotoluerve (1raquoV) 110-73-1
(37B) I22-W7 1 2 -d ipheny Ihydra z ine (23V) C7-14-3
(318) 2O4-W-0 tJuortnihrne lt29V) 75-3J- (kOBt 700J-77-J ^-tfMoropheTgtyl p^enyl ether (30V) 1J4-W-3
( raquo I B ) IOI03-J raquo-6romopfgtenyl phenyl ether (32V) 7I-I7-J
(06) 3H3raquo-)2-raquo bU (2-tfilerobopropyO ether (3)V) 10041-02-i
(OB) lll|| bii (2-cMoroethoxv) methane 10041-01-03
(37B) PUt) hxzraquocMorobutadienlaquo (J1V) 100-raquol-raquo
(JJB) T7^7U heztctilarocrclotMnttdicrgte (V) 7gt-0raquo-2 OB) 7l-3raquo-l BO ph or one (raquo3V) 7raquo-17-J
(338) raquo|20-3 rlaquopritrilaquolene (UV) raquo-laquo-raquo
(3iBl n-raquo3) nitrobenzene (raquo7V) 75-23-2
(CB) li-X)-t N -n i tr o tod ipheny U mi nr (UV) 73-27-fc
(06) CI-U7 N^iitroiodipropYUmlr ^raquo1V) 73-H-fc (UB) 117JI-7 bu (2-ethYlNerrl)pM^Utr 12000 (JOV) 75-71-1 (47 B) L3-U7 llaquoniyl buryl pht^UTe 2 800 ( 3 I V ) 2laquo-raquo-I (UB) raquo-7i2 di-o-ourvl pritfwiUrr (I3V) 127-lt-i (196) 117-14 3 dj-n-ocryl pritfiiUrr (UV) IOUIS-3
(TCB) J4-W-2 djnhYl phtfalitt (17V) 7t-01-lt (716 ) 1 3 1 - 1 1 ) damnhYl pMtuUTT (UV) 73-01- (77 Bl 3 33-3 frlaquon z olt raquo klaquom h rraquo c prgte
Cadmium T^ Chromiurn T Z T N C 100
Client ID 8A-C64221
BASENEUTRAL COtPOUNOS
bnzo(t)pyrrrie
benzobXluoriflthei blaquorizoltVHluorraquontrraquone
chryiene
bullcenphthylene
tnthneene
benzoltRM)perylene
fluorene
prienlaquonthcTTgte ditgtmplusmnolt4hluithrraquoctnf
indenof 1 23-cd)pvrf ne
pyrer
VOUATILES
bullcrolein raquocrvlonnrile benzene cmrbort Tetrichloride
chlorobenieoe 1 2-oUchloroethirie
11 1 -tricolor oethne ll-dvchlorolaquollMr 1 1 2-w icMoroethAoe l122-tetrieMoroeihilaquonlaquo
chloroetKvne JltJilorothvlvmv| ethe chloroform
11-dicMoroethent
trani- 1 2 -dicti lorolt t hene
1 J^JictiloroproBfVf
trim- 1 3-4ietiloroproperie
Cil-IJ-dicMoropfoOerie
rrhyUxrmene
methylene criloride
chlorornethine
bromome thne
007
13
tluorotr l^VoromlaquotNraquorgtt
da ch lor od 1 1 1 ooro frvet hraquone
chlorodibromometlvinf
te trraquocnloroeT rrrr
tricMoroetSmr
All results are expressed as us2 weight as receixred No entrv denotes not detect i
Phys ica l descr ip t ion of sample
SoilCake
Sample workup
vol i t i le fract ion ^FP FvfrarfMnn (ltU Rif i mdash Smrn
Semivolatile fraction Soxhlet Extraction (SW 846-3540^ Inorganic fraction Acid Digestion (SW 846-1050)
AC23 COMPOUNDS
rrt CAS CAS
(21 A) 11-04-2 2raquo4- trieMorophenol (738) 50mdash 3-4
122 A) J1-30-7 p-ctil or raquo-nvltrlaquo laquoo 1 (7laquoB) 205-11-2
12 A) 13-37-4 2- etilorophenol (75B) 207-01-1
(31 A) 120-13-2 2raquo-diclorophlaquoTgtol (74B) 211-01-1
(34A) 103-471 24-dmlaquothylphrnol (77 B) 201-14-4
(57 A) U-73-3 2- rutrop^nol (7raquoB) 120-12-7
(54 A) 100 -02-7 bull i tro p^c 01 (71B) 111-24-2
(J9M 31213 Z o trt i tr o poc^oI (MB) U-73-7
(40 A) 334-32-1 T^Hjinitrfr2^rt^T ny tp^gt^noi ( t lB) 13^)1-4
(44A) 17-44-3 pcnttchlaroprwnol (S2B) 33-70-3ltOA) IOt-IJ-2 pTUfNOl (136) 113-31-3
ftASENtUTRAL COMPOUNDS (MB) 121-00-0
(IB)
(56) 12-473 Iwnndine (2V) 107-02-1(IB) I20-IJ-I 1 2 4-tr icJi lorobeniervr (3V) 107-13-1(IB) 11 1-711 hexkcMarobcnzeM (4V) 71-43-2(126) 47-72-1 hexch)eroeihlaquone (4V) 54-23-J( I I S ) 111-4- bu(2-eMorlaquothv|)laquothr (7V) 101-10-7
(208) 11-51-7 2-c^laronraquophtfgtlene (IOV) 107-04-2(23B) 1J-30-I 1 2-dichloroblaquonime (11V) 71-35-4(2651 341-73-1 gt3-ltiictitaroblaquonxcnc (13V) 73-54-3
(27 B) 104-47 l4-dicMorotKmrerlaquo (14V) 71-OO-3
(21 Bgt 11-14) 33-4ichlaroblaquon2idine (15V) 71-34-3
(338) 121-14-2 24-dinitrotoluene (14V1 73-OO-3(J4Bgt 4O4-20-2 24-dinitretoluenc (11V) 110-73-4(37B) 122-447 lraquo2-dip^nylhydrraquoxirlaquo (23V) 47-44-)(MB) ro--0 Uuaranthene (21V) 73-33-4(406) 7003-72-3 4-ltUorepfraquonyl phenvl rtSer (30V) IH-40-J( raquo I 6 ) 101-333 4-6romoprlaquonyl pflaquony| ether (32V) 71-17-3
(OB) 3H3I-J21 bll (2-cti|orobopfrgtpyO ether (33V) 10041-02-4
(OB) I11-1I-I bis (2-cMaroethoxv) methane 10041-0103
(57B) P-44-) hczw^lorobundiene (J4V) 100-41-4
(JJ6I 77-47-4 htTicMarocyclojxrtadien (44 V) 75-01-2
(346) 71-31-1 aophoroo ( raquo ) V ) 74-47-3
(33B) raquo|203 r^pn thA Icr^ (44V) 7 -raquobull J-
(546) n-i3) H i frovCftZfl^^ (raquo7V) 73-23-2
142B) 14-30-4 S -n i tr o laquood ipheny Lt mi nc (44V) 73-27-4
(43 B) 421-447 N^iitrotodtpropyUmlne (41V) 73-41-4(MB) 117-41-7 bu (2-raquoThylhlaquolaquoyl)pMtgtlaquoUtr 52000 (30V) 73-71-4(4B ) 13-447 (xniyl bviryl ptithiUre 6700 (3 lV) 12raquo-l-l(UB) 147U- di-n-burvl pMhUre (I3V) 127-11-4laquoampgt 117-4J-0 ltjj-n-octyl phtfaUtr (UV) 101-11-)
(7CB) U-44-2 djrthyl pht)raquolraquort ( I7V) 71-01-4( 7 I B I 131-11 ) dimrthyl phttgtUTe (UV) 73-01-
(T76) H-33O tgtnzoUtlaquoftthncmr
Cadmium l i r^ Chromiurn 2 0 ZINC 140
All results are expressed as ugg weight as received
Lab ID No 2887-6
Cl ien t I D 8AD64219
Dd20( amp py(re
blaquonio(bHluorraquoflthegtlaquo
berzo(Mf luorampnThene
chryraquoefgte
ftctnAoMhy(ergte
raquonthncene
benioltK(M)plaquovlene
(Juorene
picnintfirtTX
dihwvioltraquoh)laquonThrraquocene
mdeno(l23-rt)pvrraquone
pyrene
raquocrolein
raquocrvloourUf
benzene
carbon laquoTrraquochlofifle
chlorobenieo
l24JcMarolaquotlxine
lll-trichlcroltthlaquorlaquo
-ltJicMorigtnKraquorgtlaquo
l12-trichlorolaquot^nlt
1 1 22-tetrcftloroetrvtnlaquo
^tloroeThAne
2^^1orolaquothvlvuiivt ethe
etila-oform
ll^liailoroltN^
trtni-12-dichlcxolaquoTfgtene
12-ditfiloropropine
trtni-l3-ltjicti|orocltX)t^f
cu-l3-djcMoroprooe^f
rttiylbtnztTve
methvlene cWoride
ciloromnM^f
Dco^^oroct^A^^
bromofarm
bromodicJiloromltlfraquon
tluorotrlctiloromttNir
diOilorodKloororfvrir^Ar
ct^lorodraquobrofTorrgttKAne
wtricnlorampctNrr
toluene
trirfilorolaquoThfif
v i n v CMor ilt3^
No-entry denotes not detect
ih i n N O 2887-9
Phys ica l d-asc r ip t ion of sample Cl ient ID 10A64222
Linnir l ShtHcp
Sample workup Volitile f rac t ion PEG Extraction (SW 846-^030^ Semivolatile fract ion Sonication Extraction (SW 846-3-540 Inorganic f ract ion Acid Digestion (SW 846-3050)
AOD COM POUNDS BAStNELTTRAL CXLPCXJNDS
rrt CAS CAS
(21 AJ U-Ot-7 Z4- trichloropSeno (73B) 30-J2-
(22 A) 55-30-7 p-ctilarraquo-m-erelaquoo1 (7kB) 205-raquoraquo-2 ben r olt b) 1 uor ifl t Ne~gtf
(2AJ raquo3-37-i 2- ctilorophenol (75B) 207-0raquoraquo benzoltllt)floofraquontslaquor
(31A) 120-13-2 2raquo-ltJictilcroooenol (76) 211-01 9 ctiryjene
(3A) I03-47- 2k-dimethylphenol (77 B) 20t-raquo4-i bullceruphthv lerraquoe
(37A) U-73-3 Zmdash Ajtropheooi (7SB) 120-12-7 fcntftricene
(34 A) 100-02-7 w^ i ff o phe rgto 1 (7raquoB) Iraquol-2-2 ben z o( Rh i )per v 1 me
(31A1 51-21-3 Z^ - d iA iV opheno1 (SOB) U-7J-7 Iluorene
(MA) 3X-37-I T v-4iAiv omdash laquo mdash fl^et ny Ipoenoi (I1B) 13-01-1 poeftraquonthrene
(4 Al 17-14-5 p^ntBCfllGrOprlC 1 Vol |I2B) 33-70-3 dilgtenioltraquoh)laquontwraquocenr
USA) IOl-raquo5-2 phenol (13fi) U3-31-3 indeno(l73-cd)oraquorrie
(MB) I2raquo-OO-0 pyrene RASENCimiAL COMPOUNDS
VCH-ATUL5 ( I B ) 13-32- raquoclaquonraquophtflaquorgte
(58) 12-I7-J benzidire (2V) 107-02-1 bullcrolem
(IB) 120-J7-I 1 2k-tr icnlorobenzene (3V) 107-13-1 acrvlonitr UP
(IB) 11U7I-I heKicMorobtnzme (raquoV) 7I-A3-2 benzene
(176) 4772-1 hexcftla-oethtgte (4V) J4-23-5 campr~toon TeTrscftlo itit
(116) III-- bii(2-lttilorolaquothv iVether (7V) lOt-W-7 chlocobenieo
(2C5gt raquol-3l-7 2-cM oroolaquo ptittu lene (10V) I07-O4-2 1 2-dicrtloreetranr
(23B) raquo5-30-l 12-dichlarobenime ( 1 I V ) 71-33-4 11 1 -tricMoroethr
(24 B) 31-73-1 1 3-ltl icJgt lor obcn i ene (13V) 73-3^-3 1 1 -dicMoroeth^i
(27B) 104-^4-7 1 4-dich lorobenzergte ( t k V ) n-00-3 11 2-tncfiloroetvlaquorie
(215) 91901 33-didMoroblaquozidinr (I3V) rraquo-3k-3 l122-tetrraquoOMo-oethne
(335) 121-I-2 2-dinitrotoluergte (ItV) 73JW-3 chloroethjin
(3461 (0420-2 24-dinitrotoluene (19V) 110-73-1 2-cMoroethraquo|vuiv| trgteshy
(37 B1 122-44-7 12-diphenylhydrnine (23V) 47-44-3 ctiloroform
(316) 204- Jgt tluarmrnhene lt2V) 73-35-4 1 1 -^iCMoroeThe^f
(C6) 7003-77-3 -chlorophenyl poenyl ether (gtOV) 154-40-5 trraquonraquo-l2-dicrloroltthene
(bull16) 101-35-3 raquo-6romophenyl phenyl ether (32V) 7I-I7-3 l2^ipoundMoroproBirgte
(raquo26) 3H3I-32- bit (2-cMarobopropvt) ether (33V) 1 004 1-02 -4 trmni-l^-dictilwoproom
(OB) l l l - raquo l - l bis (2-cMeroethoxv) methane 1004 1-0 1-05 cu-13-laquoicMoroprooe^e
(J2BI D-U-3 rraquolaquoeftlorobutraquodilaquooe (JJV) IOOJM- rttylbenzene
(336) 77 -raquo7- hezactilarocyclooentadiene (WV) 75-OT-2 methylene cniorifle
(56) 7raquo-3raquo-l ao ph or one (raquo5V) 7raquoJ7-3 eMoromeirune
(33B) JI-20-3 nraquophtMlene (UV) 7raquoJ3-raquo bromomethAftf
1X6) n-raquov) nitrobtnxerw (raquo7V) 7J-25-2
(CB1 14-30-4 J -ltii TT o vxJ ipheny U rru rraquo ^UV) 75-27- bro mod i cfilor o me t r)e
(CB) 47I-U-7 N-nnrotodipropylraquomJne (tV) 75-4raquo- 11 uor o tr i cMor o me t htgte (US) V17-1I-7 bu (2-eifrrlhryl)praquogtttilaquoUMshy 69 000 (30V) 75-71-1 di cti tor odl1 1 van m^i rajgtr
(476) U-U-7 benzyl buryl phihiUte 890 (31V) 12laquo-kraquo-l cMorodbremof^etNrr (US) U-7I-2 di-n-burvl prittuUre (13V) 127-lt- Uraquo6gt 117-t-0 dJ-laquo-ocTvl phttviUre (UV) IOLtS-3 Wluenr
(75) u-w djrrhylphtnltt ( i rv) 71-01-4
(715) t J I - l l - 3 dimnhrl pfthUte (UVI 73-01- viny l CMcriOr
(779) J4-35-3 0laquoMo(UnthrraquoCflaquoe
C a d m i u m 130 Chromium 20 ZINC 170
o nnn Z-UUU
^0(^ Trace
All results are expressed as ugg weight as received No en
APPENDIX E
PLATES
I I I I I I I I I i Plate 10-1 Troy Mills Landfill with a backhoe excavation
in progress in a former drum burial area
I I I
I I I I I I I I
I I Plate 20-1 NAI field investigation team preparing for
Level B activities during the drum excavation task Troy Mills Landfill
I I I
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
I I I I I I I I
I I Plate 20-3 NAI field investigation team member undergoing
personal decontamination at the hot line Troy Mills Landfill
I 1 I
I I I I I I
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
1
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
I
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
I I I
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
I I I I I I I I I I I 1 I Plate 53-3 Pigmentsludge deposits interbedded with
soil layers in Excavation 8A Troy Mills
I Landfill
1
30 MAGNETIC SURVEY
To delineate the landfill area underlain by steel drums a
high resolution magnetic investigation was conducted by John F Kick
PhD consulting geophysicist The magnetic method was chosen over
other search methods because ferromagnetic substances (drums) were the
target objects and the majority of Troy Mills other wastes are
non-magnetic (largely fabric scraps) Dr Kicks report is presented in
Appendix C
Eighteen parallel rows of magnetic field measurements were
made along north-south lines The measurements were made at 10-foot
intervals along the rows This work resulted in a detailed contour plot
of the magnetic anomaly (Figure 1 in Appendix C) The source materials
which cause the magnetic anomalies do not usually directly underlie the
peak of the anomaly A shift is caused by the inclination of the
earths magnetic field and by dipolar effects Figure 30-1 shows NAls
delineation of probable source areas for the magnetic anomaly and
peripheral areas which may contain some magnetic source material The
plotted source area is generally the area between the peak of the
magnetic anomaly northward to the zero anomaly contour This is to
compensate for a southward shift of the peak of the magnetic anomaly
from the center of the source deposit The complex geometry of the
anomaly necessitated much interpolation between peaks and ridges
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40 TEST PIT EXCAVATION
41 WORK PLAN
A series of test pits were excavated in the Troy landfill for
observation and sampling More specifically the purpose of the
excavation was to estimate the number and distribution of drums buried
in the landfill determine the condition of the drums (full empty
crushed rusted leaking etc) identify types of buried and drummed
waste and verify the results of the magnetometer survey A stratified
random sampling method was used to choose 10 locations within the
delineated area of magnetic source material This insured that
excavations were distributed randomly across the landfill and that the
resulting data could be evaluated with a level of statistical
reliability Excavations were also selected in areas on either side of
the anomaly which were considered free of buried magnetic material and
also where drums were visible at the landfill surface
The following procedure was used in choosing the locations for
the random excavations The center of the delineated area of magnetic
source material was used as a base line The base line was drawn onto a
map of the source material (Figure 30-1) and then divided into ten
60-foot long segments Using a random numbers table a point-distance
was located on each segment (designated the random station) and a
line drawn at that point perpendicular to the base line segment Again
using a random numbers table a point-distance (designated the random
offset) measured along the perpendicular line located the point of
excavation The grid coordinates for each excavation were graphically
determined from the grid overlay and then field-located from the
surveyed grid intersections Grid coordinates and selection data are
presented in Table 41-1
It was judged that 10 excavations in the delineated area of
magnetic source material and two excavations out of the area would be
sufficient to characterize the site would produce statistically valid
TABLE 41-1 RANDOMLY SELECTED EXCAVATION SITES TROY MILLS LANDFILL TROY NEW HAMPSHIRE
BASELINE RANDOM RANDOM EXCAVATION GRID SEGMENT STATION OFFSET
NUMBER COORDINATE (FEET) fFEET) (FEET)
1 7E+15 65N 0-60 26 16
2 9E+5 13S 60-120 110 9
3 8E+0 31S 120-180 140 7
4 4E+5 48S 180-240 230 26
5 3E+8 45S 240-300 254 20
6 OE+8 45S 300-360 394 50
7 2W+15 24N 360-420 465 14
8 5W+6 42N 420-480 518 20
9 6V+14 74N 480-540 548 7
10 8W+5110N 540-600 611 31
Locations are plotted on Map in Figure 30-1
data and could be expected to be completed within a scheduled 2-3 day
work period
42 FIELD WORK
Test pit excavation was conducted in two phases On the first
day each of the 10 random locations (Excavation 1 through 10 Figure
30-1) was probed to a depth of 2 feet using hand shovels On the
second and third days excavation was conducted using a combination of
hand shovelling and power backhoe The NAI field investigation team
consisted of six members Four of the team members were equipped to
work at Level B for work in and near the actual test pit excavation
(See Plate 42-1) The other two team members spent much of their time
with personnel and equipment decontamination and refilling compressed
air bottles at the hot line Mr Timothy W Drew an engineer of the
New Hampshire Bureau of Hazardous Waste Management was present during
most probing and excavation work Mr Robert Lynch an experienced
Level B equipment operator of Jet-Line Services Inc operated a power
backhoe which was provided by Troy Mills Inc
An average excavation size using the backhoe was approximately
7-feet wide and 10-feet long Excavation continued downward until drums
were encountered or to a minimum depth of five feet Drums were careshy
fully uncovered and fully described A total of 17 samples were
obtained from uncontainerized wastes (solids dried sludges pigments
stained soil) and where possible from drums using EPA sampling methods
and protocols All of the excavations were backfilled upon completion
of this task
Each sample consisted of one filled 8-ounce glass jar sealed
with a Teflon-lined lid Samples were submitted to Resource Analysts
Inc (RAI) Laboratory in Hampton Falls NH for priority pollutant
analysis
Air monitoring was conducted during each excavation using a
Foxboro Century Flame lonization Organic Vapor Analyzer (OVA) an HNU
Systems photo-ionization detector (HNU) and an MSA combined oxygen and
explosimeter High explosimeter measurements were considered cause for
an immediate halt in exploratory work in the interest of personnel
safety
10
50 RESULTS
51 GENERAL
On November 17 1983 Excavations 1 through 10 were initiated
using hand shovels to a depth of approximately two feet A total of
two buried drums were discovered Excavation 13 was completed and a
third partially buried drum uncovered On November 21 1983
Excavations 1 through 9 were completed and on November 23 1983
Excavations 7A 8A 10 11 12 and 14 were completed An additional
42 drums were uncovered on the last two days of excavation
Excavation Locations Seventeen test pit excavations were
completed at locations which are shown on Figure 30-1 Two pits were
excavated at three of the locations Noteworthy aspects of the
excavation operation are
Excavations 1 through 10 were randomly located in the area of delineated magnetic source material (on-anomaly)
One excavation connected Excavations 4 and 5 This was done because of the proximity of Excavations 4 and 5
Excavation 7A was located immediately adjacent to Excavation 7 Excavation 7 was located on the boundary line of the anomaly and proceeded in a southerly direction off the area of delineated magnetic source material (off-anomaly) Excavation 7A was initiated in the opposite direction (north on-anomaly)
Excavation 8A was initiated one foot north of Excavation 8 after the latter was abandoned due to the detection of a potentially explosive drum
Excavations 11 and 12 were selected off-anomaly to the north and south (respectively) in areas considered to be free of buried magnetic material (drums)
Excavation 13 involved minor hand shovelling necessary to uncover a partially buried drum located on the periphery of the anomaly at the east end of the landfill
11
Excavation 14 was a surface scrape which extended from an exposed drum found to the south of the magnetic anomaly northward toward the anomaly
The details of each excavation are presented in Table 52-1
Drum Locations The excavation results support the
interpretation of the magnetometer survey with buried drums as the
source of the magnetic anomaly With the exception of a few strands of
wire found in Excavation 1 ferromagnetic materials other than drums
were not encountered during the test pit excavations
Drums were foundin 9 of the 10 excavations located in the
area of delineated magnetic source material (See Plate 51-1) No drums
were found in Excavations 11 and 12 located out of the area of
delineated magnetic source materials The location point for Excavation
7 was on the boundary of the anomaly Excavation 7 which proceeded
south away from the area of source materials was free of drums
Excavation 7A proceeding north toward the area of magnetic source
materials uncovered 6 drums Excavation 14 located just out of the
delineated area to the south produced unexpected results Five drums
were uncovered just under the surface in an area with low positive to
slightly negative total magnetic field values It is possible that
Excavation 14 was improperly located in the field If adjusted just 20
feet to the east it would be well into the delineated area It is also
possible that a negative dipole derived from the mass of material to the
southeast is cancelling positive readings at this location
Fill Material and Vegetation Cover and fill material was
predominantly fine to medium sand with an occasional boulder Till with
a siltclay component was also used as a cover particularly at
Excavations 6 and 7A This material was densely compacted and difficult
to dig through Excavations 7 11 and 12 each extending to a minimum
depth of 5 feet were characterized by uniform silt and fine to medium
sand and traces of dark discoloration Excavation 12 was located in
to a s
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c eo Qeo mdash eo
t-JJ 0 E
o mdash c mdash
eo w
D C c eo CD laquo)
CO T3 0 4J Q) - C 0 mdash CO gt mdash E O w mdash
O 01shyC CU O O CD aw
CD O CO u- sshy amdash
re lt c eo cc c CD mdash CD 1- ltshy C C_ C re c co o - O X X CO CO3 gt CO 3 gt to E O O co O co CO 3 jt w O cfl 0) eo
cr LJ
LJ-J u mdash j CO 0amp5
a O 1 O
Q
1 1 i l
CD Dl bulla
CO _ mdash O D o
O ^ (A
ZX mdash Ld
O
en 3 10 O a
LJa a
Q 1 1 O
Q
+
O
X
_
mdash
o o I
gtgt O
h~Z
-^ 3
o0
mdash i-
1A 1
a a co agt C
LJ
sectK
Z= tM O 0 to bullo
X
mdashshyo
CD O
o mdash _ o
E umdash 3 E eo sshy
ltr-toZmdash
mdash s
0shy c
^
^ gt o
D o
a-rmdash
1
Q-
0 0oo r-V
tO 0
= mdash
O
tO 0
= mdash
O
Q O
O r-i O NO
1
awi
i mdash _ 3
Imdash I O
bullO C
1- 3 gt 0) bullo sshy co w
bullO CJ ID O X E C CU tt) bullw^ T3
w agt u C pound -gt
a a CO CD
mdash L 4J CD o gt
T3 gt C CO UJtt
2 mdash1 LJ Z) d CO 1 1
COO
~
lt O
~ I 1 1 I
Dl C 10 3 -D
lt - T J O
Dl C
1gt Omdash O bulllaquo Xl- i s o cu
Q lt3 toz cshy
mdash W f
r-B O c
mdashgtgt3 01O O u
W ID CO bullgt C -O mdash 4-gt 4-gt C
O -x mdash1 CO o CU c c co
1
OZ ZO o mdash Ol-
LJ -
L
0
1
C- bull 14 u- o laquoc~
bull mdash u bullDT3 O laquoccce tshy ^ D
l_ Cshy CCO O 0 0-0 Qmdash
CJ I- r-CM
1 1
U-Qshy
bull bullbull ^
O t_ 0 Q
-LJ
raquol
a o iT o c o
U) c
c u CD O
I I I CU c
Q) CJ CU W a ltshyon J2 o l- E E gt QCO CD O
I I I
ID JJ CU ES
J-gt imdash O Q Z CO w t --shy O mdash O 3 O laquoshy ^ c
_ICO a 0 0 0
^ sect5oa I-Q
CO X u_ y o- o=gtLJt-a
3shy
^
1
1
VO
m
1
i
1
t
_
3 lta i- U) 0 0
a
lA
lAbull
0 O
JI E oj3 gt E re mdash O X X co Qj
C 1 O
W 3
U L CO O
4J CO
0mdash CCD gt j ti --shy c JJ 4J
1- laquo 3 = C 3 or cu ogt tn Q -shy
E L n CD J-gt o o gt gt s o ---shyDior 3 3
mdash Tgt o cr cr mdash mdash CU 0)
o a CD -a OLJ U CU
N CU COT 4JT3 poundmdash 0gt U V
raquoT3 mdash agt OJ gtgtcu laquo c c
T3 O
C
C
Zlshyo ui u- Li ^ ^~bullgt lt LJ
lAXvOX
VO X ^ X
Xcjltshy
lA x
CM
O x
3shy
_ X
r^5 X
_ X
CM X
mdash c^ C3 O
c a bullbull o c c
mdash 4J O I I 4J
01 JJ 4J 1C laquo
3 t- C raquoJ O L (D CU C mdash o a~o mdash o
i i
C J J W CO II) O W IT OC N 03 = OJJ C O I- -= C O
I I
o o
ON X mdash
CMr-raquo
00 Orshy
X CO
vo ro O C 5) JJ Jshy I- I gtJZ-00 s a o
LJ CO eo UTJ a- I I O C X J O gtZ 1 re O
i CM
LA
LJ
O mdash c imdash LJ lt a gt y lt 2
ltCO O
O^mdash
laquoshy rmdash
CM Tmdash
n rmdash
_^jshymdash CO
LJ
j ^ |
52
14
what appeared to be natural materials although its location on the
cleared and leveled landfill tend to contradict this possibility
Most of the landfill is vegetated by a thin layer of grasses
sedges mosses and annual herbaceous species The northeast corner of
the landfill is unvegetated and cover material appears to have been more
recently applied This section is elevated 4 to 6 feet above the rest
of the landfill and appears to have received a second newer layer of
waste A 4-foot thick layer of carpet waste was encountered in
Excavation 1 but not in other excavations This section is adjacent to
the newer active landfill The landfill area just west of the access
road crossing (near Excavations 7A 8 and 8A) was also unvegetated due
to relatively recent grading operations
Ground Water The landfill appears well drained as ground
water was not encountered during any of the excavations Excavated
overburden was damp from the recent heavy rain but intergranular macro
pore spaces were free of water
OBSERVED QUANTITY AND CHARACTER OF DRUMS
A total of 45 drums were observed buried in the landfill
Table 52-1 presents a drum log describing each excavation and the
observed drums Data on the contents and condition of drums is
summarized in Table 52-2
Of the total drums observed 15 (33) were crushed flat
Although these could possibly still contain small amounts of waste they
are probably considered empty under RCRA guidelines Thirty (67) of
the total drums discovered were uncrushed and capable of containing
waste Seven (88) of the 8 drums sampled contained liquid or sludge
waste material Thus at least 7 (23) of the uncrushed drums contained
some liquid or sludge waste
15
en C Cl
bullo gtraquormdash
c mdash a
o c re bull mdash c
~ o mdashbull 4Jmdash
10 0 mdash
gt O
ro CO
fcshy0
c
C
vgt 3 0
1 rea
-gt
mdash
3 o T3
lt-O
C j C
CB 3 TJ ii i- 3 mdashQCOa
ifl u bull c c
t_ o
mdash shyO
mdash
L re N
co
t-O
mdash
mdash lfl
V) O
CO N CO pound re
0 mdash
^1 10
ltP O C raquo
CM reO
o f shyi O
mdash mdash 3 - D
c 1
CD bulllaquo
mdash3
D mdash
1 C
Q CO
CD Ifl 4-gt CO
Q
CM
r-
Ul
Q Ul gt EC Ul CJ CO o t5bullpound
z O mdash
C Ci o^
O Cbulla 3v iC MW5 CO 4J3 u CS- Ifl CBC J C O - U
gt Cgt Omdash Oi O
U- 0) Ifl bullgt-gt 1 W C
to lt-gtT3 gtmdash
0) gt shyJ 0)
C OltJ bull O T 3 C D C P
133mdash 4J bull ifl tshy Vgt~ V a O V4JJ
C o
C mdash
O Ifl
3 fc 0)
i-
c
U) re gt
ai C mdash
C mdash
CO gt c o
bull to y 3 cc Q
ltbull-CB
1 4Jin
bullD reCD jCJJC TJCD mdashbullD bull mdash
CD 0t- u iflo ifl
0 C ^-
CB laquo
3 ltbull-
0)^shy
C
0 Cgt O
1 O CTl C
T3 1 mdash CB O
mdash CB mdash in J o 3 tfl C ^ CO 0 gtltgtshy
O gtgtc 01
CO 3 1- mdash C Cregtmdash laquo
TJ W TJ mdash i re traquo-
shyU mdash
O Q
COCO^^
mdash ^
mdash gt C 0gt mdashO ~ bull
Ul
o auO
CCUl
mdash K o tO Ul Q
mdash OT30Jj c mdash4Jt- Jpound O Wre c i re03 gt
lt~i- laquo o ai
0 ) 3 gt O ^crc Ifl - CO -^mdash
3 mdash Q iflmdash 1- O 3 3
O V O ltraquo-o laquoTJ
gt
T3 - o
gtgtmdash J-gtmdash
Dmdash
6-o
09 bull mdash gtpoundbulllt-gt
re a
Ul X t5
Cpound O Z
fl) mdash^ C B gttflOl3T3T3l_ 3 Q)O mdash mdash
tn mdash
shyD CB
mdash mdash
mdash tt
CO C T3 poundi mdash JCmdash re
^ C O C X CB ^ - S - C C O mdash re O Q DW4shy
re shyu O 1
O Ul X EC Ul mdash
x a^s ox
CO
^) Z
J
1-o t-Ul X r-u 0
o j c gt T3 i -gt c tu mdash c u r e mdash
- C D mdash T3 - C M mdashbullOJJQmdash re3inecrec u c r e o mdash lt~ bullz c~4J O CX t ^Jw o r e -gtgtOgtgtshy3 c j t shy re mdash mdash ret- i o Qmdash gtgtpoundgt a
i reraquo CD 0) bullbull Ifl t-
Q ) t ) O pound O ^ laquo gt - Ow re re ro re re -gt Q mdashc 5 shyu a j-gt D t- raquomdash mdashCB C re C CO 3Q mdash O mdash O U
Htshy ae cu coo)
1 O i i
shya shyo j CD C bullgt o mdash c o c o coco mdash plusmngt o ~a v c en CD
mdash C O
raquoCJ 3C c re amp- ogtCD J o 3 CC C I-Omdash 3gt O
3
O ro
Ul X 1mdash
u O
Ul o r-Z Ul
gtV~ omdash Dlshy ^mdash mdash wre3 i cc
mdash cr bull gtJJ mdash C mdashi QIgtJ^re a shyJQI- o 0mdash
O bullO 3laquo laquo
jjmdash ureoO mdash O N 0)rc3recomdash4Jt-4JpoundmdashC C mdashmdash mdash u
1
shya 0 -
mdash gtgt re-raquo-gt CUD laquo E CD
^ J-1
CJ eoc
4JCB CO
mdash O
C 1- C mdash O C B C B C E J mdash J ltshy shyo cn o o c o r e c shyU -gtO OJC D ifl roc
T3 3 I U 3 laquo-
Ifl CD 1 W ^J 4 J 4 J c -aiflj jc
CB C r e O C B lt-gt -Jgtcoraquo C C -WE O O ) ~ O O O mdash O
Ul O
c ui =gt z
o
1-CC Ul Q
Q z ^ Ul
2 gt Ul O
o Cpound
^ CO
Ul Q ^
z o
(O U S Q
Slt
t5 lt
Z5O
1mdash z ui
Qa Ul
CD 0-1
u m O_J
O2^ltUl
O CC Ul Q
VOCO
CNlA |3
VO ^
CJ |CO |
CJ CMI3 f~ rojO VO rolo
^
ymdash3 CC
roCM
ro O ICNj
ro rolvO ro ro
ro A
rolvO r-jO
00 C3N
ec a m
r3
CO
3 a ty r-
cc Q
(M CM
to z
m 3 c O
u _i co
U-O
O 3-IObull - I c y
fshy lt- ICO r- r-ICM O U lfN ro -mdashla1 f~ laquo- ]CO bull- -ICM O O J|O O
c U) CO
mdashbullre re
mdash re
mdash i ltC c tz
j lt
i lt
5 0 0 G O o o o o z bullU 4J J h- J shyJ tmdash tmdash
^33
J3 3
O 3
Q 3
_Cr(bull
shyC 3 t)
CC IP y
C2 zgt c J
1mdash O 5
53
16
The condition of the uncrushed drums was highly variable with
only 4 (13) rusted and decomposed to the point of structural weakness
These drums were found in Excavation 10 at the far west end of the
landfill which is believed to be the oldest section (See Plate 52-1)
Interestingly two almost new looking drums were also found in
Excavation 10 at a greater depth than the four rusted drums The
remaining 26 drums were observed to be generally intact and structurally
sound Some were dented partially crushed or rusty
CHARACTER OF WASTES
Air Monitoring An OVA and HNU were used to monitor the air
for concentrations of organic vapors during each excavation Above
background instrument readings indicative of contamination were
regularly recorded when monitoring the air just above or inside of
drums A general contamination of the ambient air in the workspace was
noted only during Excavation 8A where above background readings of +13
in the excavation pit and of +6 above the excavation pit were recorded
Explosimeter readings were obtained from three drums -- 10 lower
explosive limit (LEL) from drum sample 10A 20 LEL from drum sample 6B
and 100 LEL from a drum in Excavation 8 Instrument readings are
presented in Table 52-1 and Table 53-1
Visual Observations The following types of waste were
observed during the excavations
fabric waste (carpet waste)
crushed drums
drummed waste - liquid sludge and solid
uncontainerized dried sludges and pigments
stained soils
Fabric waste scraps of synthetic non-woven fabrics5 heavy
carpet-like fabric and backing material were found only in Excavation
17
CM
CO LJ fmdash O z
laquo 4J
u TO 4-gt
c bullmdash
k bull mdash E mdash 3 3 i-^ O
mdash TJ --raquo co co 4J
E CO O U L U
E 3 c T3
C O a o
is
CO c to 3
U
TO
E O t_ U_
o o
1 ltmdash c
mdash tmdash TO 4J bull C TO 0 O o c u 3 TO
t_ 0) 0 4J
U)
mdashOTOgt
Cw bull aco jc
N 4J a
mdash L Q) re co T E
CO
bullo gt egt mdash c mdash bull o ^^73 C E gtO O mdash 3 J-gtmdash N 4J L 3 mdash 1--C gttTC bull
CX 01C JJ TO O mdash
TO trt mdash t- E mdash 3 JJ a O Q
C I 0 X E mdash C mdash CO
mdash o laquo (D-O mdash O O bullbull B Ol o -cmdash e oic f~ to a (gt TD mdash
E 1- Cpoundmdash 3 O O CO P m T1
L u
T3 CO
lto sshy0 O CA W
laquoT3 O CO 0 C J= CO tlaquo Q bull 3 O Ol 1- C o mdash 3 E a
3 E E i- to
Z L
mdash bull mdash O 4-3 Cl Q
bullD 0) CO T5 N CO mdash C -P 1 0 U TO O mdash 4J Cfc
mdash U) c shybullgt O w C O Q (5 4J 0
3 -J bull U)
5 gt TO_ U
bull gt pound mdash 3 mdash L ro TD
JJ-D - CO TO laquo QO
C 0
^ 0) T3 mdash O
r to 3
O O L L
0
01 TO gt bull
tshy mdash OT3 mdash
CD O C N U) O mdash
TO O CO mdash C C
bull^ ~ CO TO TO gt U iJ
mdash C W to O
5 c c 4J 3 CO X LJ
^ bull bull0 laquolt- ej
TO CJ CO mdash C JJ
z u to mdash T3 4J ai TO CD C laquo bull c c ugt o cr 0) bull mdash CO mdash O bull gt JC TO ^ mdash Q CO O JJ O Q bull- CO to mdash to c Z CC O il mdash 4J gt
mdash Omdash O1O CD mdash U) TO C X mdash O CO C L mdash Cvv O W pound G CO C C
O gtgtgt C C mdash CO C TO CO 3 E mdash -J laquo 1- bullgt CO 0 to
bullo CO
cshyo bull
ugt C CO TO c w 4J-Q co e a c
mdash re TO in E to
Q
JJ c bullo
a LJ co E bull LJLJ
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ax
z o mdash1mdash Q
mdasha o CO LJ a LJ ~J
s CO
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gtgt3 TO CT L mdash Olmdash 1 O CD mdash 3 a CT cshy re 3 a c- o
^j C CO E Ol
bullmdash CL
bull CO 01 D 3
U
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bullmdash av^ CO 4J IA TO 5
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bullD
mdash mdash O CO
3 CT
bullmdash ^
bulla CO L
4J
C CO o 3
(A C TO
Imdash
03
ai_ 3 a bullo bull mdash 05 3 O) 00
mdash mdash C c gtgt G CO
O O
bullo^ = c a 0)
E C O umdash u a L_ bull OlCD mdash
4J mdash
u) obulla o u) amp 5 c -a 7 O C mdash o mdash _ i- (0
CO E laquoJ
C
a
bulla c bull o bull
c bullQ CO
3 01
CT mdash mdash a mdash -v
t- Ol CC-D 0) 3
CJ raquo
x^ CO
bullo 3
lt) bull_
gtraquomdash CO O 1- Ui O)
bulla ^ c mdash mdash mdash TO co in
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mdash TO
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c mdash
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CO d _l O LJ LJ _J hmdash J C- LJ XZampS LJ mdash
Q mdash
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I 1 1 i
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CO X
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LJ
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tmdash CM CM ^_ CM
CO CM ^x
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18
bull -a gtgt CD
CO S jj
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bullo CD jJ
bullo z 3 O L
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CD 1-gt o CO
jpound cshy x mdash o mdash
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4J 1 CO
Z u
CO mdash T3 CD CD
co E C mdash z bullD 73 4J O JZ = CD ltshyO C CD
CD 4J laquomdash C
bullO Qmdash U N ET3 bull mdash 0 Cmdash i- L re mdash oltmdash o
O 1 f-u gt Z 03 shy3 mdash CD
O O tshyo
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o agt O 4-raquo bull z in jz 3 CO 4-gt
gt Q ltshy 0
CD JZ N w Oshy- O
laquo ^ mdash 13 mdash m
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laquo
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re 3 O L
CD U -D SshyCD CO CO N 0) mdash 0-E S GO CD CO L
i
CO UJ gtmdash
z laquo w mdash ffl JZ CO 4-gt 4J JZ
4_) t_ mdash bull
cz QJ co jZ C C mdash 4J
re (uS a z z
OX) mdash a) O W E
Z O O JZ bull CL V E
C (~ mdash r re O CD
obullz
-J VI O 4J z re o gt o jt o 5
mdash tshy Q mdash CO 0 Q) mdash j j a C5 E U3
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CO
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bullz o mdashfmdash Q
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mdash mdash 0 10
bullc bull CD 0) C 4-gt mdash w CO CO 4-1 to
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bullD 4J C C CO CD
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v^4-gt C 0)E01 Q
agt 3 ^ j3
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t
bullabullmdash 3 CT _
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i
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13
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Ct
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a
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LJ a
clt
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z 2 lt o O
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CC ^
lt^(V
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CO Z 05 CO Ch ~ rmdash
19
c o C M O - L bull O C M bullmdash co ujn iiupeo CM
CM h- fO i- X
bull k_ c _Jlaquo _Jo
laquok ro
mn i LJOJ 140 CM
3-
bull CM
m CM
tshy r- ro CM
CV
sshy = sO r sshy~ - 2
CM ^ ~ ~ mdash rs
a
2
ou tz S S o w S S o | ^
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mdash o r gtgtlt_
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m raquo
rmdash r- i- o o o r^ CZ LJ
auazuaq |ua oCO
laquo o PO laquo
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O ~S 5
LJ
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0
a 5 ausni oa O O O J ^ O O r o r~ If o ^rO VO ^ f~ VO deg-
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O 1
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5
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5 Tmdash
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LJ =CO ^CltLJ3Z
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mdash O
lt
lt 3U BL|3 3OJ O I U ^ P mdash l l p^
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poundC M- CM 1 3 1mdash H|
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aua iXquaojomoi ja bull LJ mdash mdash O
Q _JZ lt lt C _J to
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o o OJ
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o o
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oOCM
o O O
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o O O
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o (O
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o O r~
gtO
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mdashV^
rgtE
C
o Jj
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C bullc
o i
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1-o
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hmdash gt-poundi ltc bull ^ ro
sects
lt 2
mdash
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3 4 C J cI^JLJU
( iJxsn iXuia-2 ) s j q
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20
1 (See Plate 53-1) This is the predominant waste material currently
being disposed of in the active landfill
Crushed drums were distributed throughout the original
landfill and were found in Excavations 2 4 4-5 7A 8A and 14 Some
drums such as those found under the road in Excavation 7A may have
been crushed by heavy equipment operating in the landfill Others like
those found at depth in sandy fill in Excavation 2 appear to have been
crushed before burial Drummed liquid and sludge wastes are also
distributed throughout the landfill (See Plate 53-2) They were found
in Excavations 1 4 5 6 8 and 10 These wastes are discussed below
One sealed drum was openedand found filled with refuse -- paper cups
towels paint covered rags etc One open and partially crushed drum
contained a dark granular solid waste This material was sampled
(Sample 10B) and found to be nonhazardous
Small deposits of dried pigmentsludge were found in
Excavations 3 4 6 9 and 13 Discernible layers of pigmentsludge and
stained soils were present in Excavations 7A 8 and 8A (See Plate
53-3) Of particular note was a 2 to 4-inch thick layer of
grey-colored dried sludge found at Excavations 7A and 8 All of these
wastes were sampled and the results are discussed below
Laboratory Analyses
Laboratory analyses were performed on 10 selected samples
obtained from both containerized (drummed) and uncontainerized wastes
Samples were analysed for 3 metals and 87 priority pollutants including
11 acid compounds 45 baseneutral compounds and 31 volatile organic
compounds Table 5-4 summarizes the analytical results and the
laboratory data sheets are presented in Appendix D
Of the 45 priority pollutant baseneutral compounds only 4
were identified in the samples that were analyzed Baseneutral
21
compounds and particularly phthalates were the most prevalent
chemicals and also were reported in the greatest concentrations The
highest levels of naphthalene (1200 ppm) bis (2-ethylhexyl) phthalate
(110000 ppm) and di-n-octyl phthalate (6200 ppm) were found in sample
4A a translucent red liquid obtained from a drum The highest
concentration of benzyl butyl phthalate (13000 ppm) was found in sample
6B a clear liquid and pink sludgepigment obtained from a drum
A total of 8 volatile organic compounds were identified The
highest levels of benzene (100 ppm) xylenes (19000 ppm) and
ethylbenzene (5300 ppm) were found in sample 5A a clear liquid
purple-grey sludge obtained from a drum Toluene was found in highest
concentration (12000 ppm) in sample 1A a purple-grey thick opaque
liquid obtained from a drum Methylene chloride (13 ppm) was
identified in greatest concentration in sample 8A-C a purple stained
soil and powdery waste Sample 10A a purple liquid obtained from a
drum was the only sample found to contain 1-1 dichloroethane (2000
ppm) Finally trace levels of trichloroethylene (sample 10A) and
111-trichloroethane (sample IB) were also reported
Samples were tested for three metals - cadmium zinc and
chromium The highest concentrations of cadmium (2200 ppm) and zinc
(5700 ppm) were found in sample 4A a translucent red liquid obtained
from a drum The highest level of chromium (52 ppm) was reported in
sample 5A a clear liquidpurple-grey sludge obtained from a drum
22
60 DISCUSSION
61 EXISTING SITUATION
Under existing conditions relatively small quantities of
volatile organic compounds (VOC) are indicated to be leaking from wastes
buried on the landfill site To date ground and surface water
monitoring results indicate relatively low concentrations of VOC in the
ground water and below detection limits in the adjacent brook (See
Tables 61-1 to 61-10) The results indicate that no potential health
risks from VOC and other constituents currently under observation are
being caused by the landfill operation to down stream surface water
users It would be prudent for Troy Mills to continue to monitor the
quality of Rockwood Brook upstream and downstream for VOC and on the
basis of waste analyses (previous section) to monitor ground and
surface water points for toxic metals and baseneutral compounds
62 SITE HYDROLOGY
An analysis of the hydrology of the landfill site was
performed in 1982 (NAI report of September 1982) The subwatershed that
contains the landfill site is (about 44 acres) a small fraction of the
watershed area that contributes to Rockwood Brook above surface water
sampling point C (about 1650 acres see Figure 62-1) This indicates
that most of the flow of the brook at point C (about 97) is contributed
by upstream watershed areas Thus leachate discharging into Rockwood
Brook from the landfill site can be expected to be diluted by over 30
times its volume This factor and the volatilization which naturally
occurs results in parameters detected in the Troy Mills monitoring
wells often becoming undetectable when they enter the brook
f 5
Geologic conditions which were defined in the NAI report of
July 1982 indicate that permeable deposits of sand and gravel overlie
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27
TABLE 61-5 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M5 (UPGRADIENT WELL)
Parameter Date Sampled 11-22-83
Specific conductance
pH2 81
Dissolved iron mg1 036
Dissolved manganese mg1 010
Chloride mg1 10
Phenolics mg1
3
023
Identified volatile organics
None identified ND
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (yg1)
28
TABLE 61-6 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M6
Parameter
Specific conductance
PH2
Dissolved iron mg1
Dissolved manganese mg1
Chloride mg1
Phenolies mg1
Identified volatile organics
11-dichloroethane tetrachloroethylene 111-trichloroethane
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vg1)
Date Sampled 11-22-83
152
lt002
29
6
0002
27 trace 140
29
TABLE 61-7 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M7
Parameter Date Sampled 11-22-83
1 47 Specific conductance
pH2 62
Dissolved iron mg1 002
Dissolved manganese mg1 0026
Chloride mg1 gt2
Phenolics mg1 0070
3 Identified volatile organics
111-trichloroethane 5
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vig1)
30
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34
glacial till and bedrock The sand and gravel deposits form a permeable
conduit through which leachate from the waste burial areas migrates
The permeable deposits lie in the area north of monitoring well M-l (See
Figure 62-1) In general the water saturated thickness of the sand
and gravel in the vicinity of the north-south access road is 6 to 12
feet
64 POTENTIAL FOR GROUND WATER CONTAMINATION
641 Estimated Quantity of Drums
The test pit excavation and sampling in the drum burial area
indicates a potential source of ground water contamination for the
future Many of the drums encountered were in fair to good condition
and contained liquid wastes An estimate of the number of drums in the
deposit was made with the following assumptions
1 The complex magnetic anomaly was simplified into a geometric solid 600 feet long 40 feet wide and 10 feet deep with a volume (V) of 240000 cubic feet
2 Each steel drum (D) occupies 105 cubic feet (including voids)
3 The density of packing (P) was assumed to be 50 of the packing that can be achieved with perfect cubic packing
THEN
N = estimated number of steel drums
N = (VD) (P)
N = (240000105) (05)
N = 11429 drums
The results of the drum excavation work provides a basis for
estimating the potential for specific types of chemical loading In
general three main classes of chemical substances were identified in
35
the drums The chemical substances included baseneutral extractable
organic compounds (mostly phthalates and lesser amounts of naphthalene)
volatile organic chemicals and metals
642 Phthalates
The phthalate esters found in the drums include
bis (2-ethylhexyl) phthalate ^0^3 benzyl butyl phthalate di-n-octyl phthalate Jd~7
Bis (2-ethylhexyl) phthalate was found in the highest
concentration at 110000 ppm (11 percent) Benzyl butyl phthalate is at
the second highest concentration 13000 ppm (13 percent)
Characteristics of those phthalates found are presented in Table 64-1
TABLE 64-1 PHYSICAL PROPERTIES OF PHTHALATE ESTERSshy
di-n-octyl bis (2-ethylhexyl) butyl benzyl DOP DEHP BBP
ALTERNATE o-Benzenedishy di (2-ethylhexyl) benzyl butyl NAMES carboxylic phthalate phthalate
Molecular Weight 3910 3910 312
Melting Point -25degC -50degC -35degC
Boiling Point 220degC 386 9degC 377degC
Vapor Pressure-mdash lt02 torr (150degC) lt001 torr (20degC)
Not
2xlO~7torr (20degC) Available
Solubility 3 rngfc (25degC) 04 mgfc (25degC)
58
13 rngH 48
Log octanolwater 92 873 58 partition coefficient 53 48
Versar Inc 1979 Water-Related Fate of 129 Priority Pollutants Volume II Prepared for US Environmental Protection Agency PBSO-20438 December
bullbullOther names listed in Versar 1979 vMore than one value has been calculatedreported
36
Bis (2-ethylhexyl) phthalate is the most well-studied of the
phthalate esters though the information on phthalate esters as a group
is limited The three phthalates identified at the Troy Mills site have
relatively low solubilities and are readily adsorbed onto suspended
particulates Microbial degradation is effective under aerobic
conditions bur is generally slower under anaerobic conditions
(nonexistent for bis (2-ethylhexyl) phthalate)
The above characteristics are important for two reasons One
the extent and nature of contaminant migration from the site are
dependent upon the physical characteristics Second the treatment
(clean-up) alternatives for contaminated ground water or soil can be
estimated from the characteristics
From the available information it appears that the phthalates
present at the Troy Mills site would be relatively immobile due to their
low solubilities and high adsorption rates The presence of toluene and
methylene chloride at the site however may increase the phthalates rate
of migration
It is important to note that none of the phthalates have been
found to be present in the monitoring wells nor in the surface water
sampled probably due to the low solubility and high adsorption rate
37
643 Napthalene u K r
Naphthalene has also been found in significant quantities in
the sampled drums Naphthalene is a polycyclic aromatic hydrocarbon and
has the following properties
Molecular Weight 12819
Melting Point 8055
Vapor Pressure (20degC) 00492 torr
Solubility in Water (25degC) 344 mgfc
317 mgfc
Log octanolwater partition coefficient 337
Versar 1979
Naphthalene has mid-range adsorption rates and solubility It is
therefore inferred that there would be some adsorption to soils in a
ground water environment It is important to note that naphthalene has
not been detected to date at the monitoring wells or the surface water
sampling locations This is expected to be a result of adsorption on
the soils
644 Volatile Organic Compounds
Volatile organic compounds tend to migrate readily within
soils and ground water They are therefore considered a threat to
surrounding ground and surface waters if they are released in sufficient
quantities
Volatile organic compounds were detected in samples from six
steel drums The total volatile organic (TVO) concentrations in the
38
wastes ranged from 9 ppm to 30100 ppm and averaged 8570 ppm In order
to determine the potential for future contamination by volatile organic
compounds an estimate of waste quantity based on information from the
drum excavation program was made It was assumed that 7000 steel drums
in the deposit are 60 full of liquid waste with an average TVO
concentration of 8570 ppm The computed volume of liquid waste is
231000 gallons with an average TVO concentration of 8570 ppm This is
equivalent to about 1980 gallons of pure TVO
Two of the volatile organic compounds that have been most
prevalent in the existing ground water monitoring system are
111-trichloroethane and ethylbenzene The EPA suggested no adverse
response level (SNARL) for 111-trichloroethane is 330 ugpound for
1 day of exposure and 35 jigd for exposure over a life-time in
drinking water
In general ethylbenzene is a prevalent chemical in the
environment Sources include commercial (eg petroleum and petroleum
by-products) motor vehicle exhaust and cigarette smoke An intake of
16 mgday (1 mgfc) has been calculated as an acceptable rate to
protect from toxic effects Carcinogenic effects have not been
identified to date The physical properties of ethylbenzene are
presented in Table 64-2 The principal mechanism for removal of
ethylbenzene from water is volatilization In addition to
volatilization adsorption may also be an important removal mechanism
based on the log octanolwater coefficient This factor is important in
evaluating the migration of ethylbenzene from the disposal site
Toluene which was also identified in waste and ground water
samples exhibits properties similar to ethylbenzene in that it
volatilizes easily Toluene which is also referred to as methylbenzene
is distinguished from benzene by the substitution of a methyl group for
one hydrogen atom Physical properties of it are presented in Table
39
64-2 The EPA suggested no adverse response level (SNARL) for toluene
is 1 mgpound in drinking water with a maximum exposure time of ten
days
TABLE 64-2 PHYSICAL PROPERTIES OF ETHYLBENZENE AND TOLUENE
ETHYLBENZENE TOLUENE
Molecular Weight 10616 9213
Melting Point -949degC -950degC
Boiling Point 1362degC 1106degC
Vapor Pressure at 20degC 7 torr 287 torr
Solubility in water at 20degC 152 mg2 5348 mgd
Log OctanolWater Partition Coefficient 315 269
645 Metals
One liquid sample contained high concentrations of cadmium
(2200 mgd) and zinc (5700 mgd) indicating that the waste deposit is
also a potential source of certain toxic metals Tests for these metals
have not been made to-date in ground or surface water samples It would
be prudent to add toxic metals such as cadmium chromium lead and
mercury to the list of parameters that are being monitored to further
characterize the quality of adjacent ground and surface waters US
EPA and New Hampshire drinking water standards for these metals are
cadmium 01 mgd chromium 05 mgpound lead 05 mgd mercury 002
mgd Although zinc is not considered a highly toxic metal the
US EPA has set a secondary drinking water maximum contaminant level of
5 mgd on this metal
40
70 CONCLUSIONS
The following conclusions were drawn during this
investigation
1 A steep-gradient irregular-shaped magnetic anomaly is present under closed and covered portions of the south part of the Troy Mills landfill
2 The magnetic anomaly is caused mostly by an irregular-shaped accumulation of disposed steel drums
3 In a randomly conducted sampling of drums in the source area for the magnetic anomaly 16 of the drums contained liquid andor sludge 33 were crushed flat and 51 were not sampled because there were no accessible openings
4 Laboratory analyses indicate that the random waste sampling contained significant concentrations of several volatile organic chemicals several baseneutral priority pollutants and high levels of cadmium and zinc
5 Observed concentrations of volatile organics at the monitoring wells are relatively low Because of their potential for migration in the ground water continued monitoring of volatile organics will be required
6 Volatile organic chemicals have not been detected in Rockwood Brook to-date Because of the presence of low levels of volatile organics in the ground water they should be monitored in the brook on a regular basis to confirm the lack of impact
7 The presence of high concentrations of cadmium and zinc in one of the waste samples indicates that trace metals should be monitored periodically
8 The presence of baseneutral extractable compounds (phthalates and naphthalene) in all of the analyzed waste samples indicates that these compounds should be monitored periodically
9 The phthalates are not expected to migrate freely because they have low solubilities and are readily adsorbed onto soil particles
10 If elevated concentrations of volatile organic compounds trace metals or baseneutral extractable compounds should occur in the monitoring system (wells and brook) in the future a need for site remedial actions to mitigate the potential for downgradient ground and surface water contamination could develop
~
80
41
RECOMMENDED PLAN
Based on the preceding conclusions it is recommended that the
following plan be implemented by Troy Mills Inc
1 Continue monitoring ground and surface water quality at the Troy Mills Inc landfill sampling on a quarterly basis with sample collections during April July October and January
2 To confirm the absence of the landfills impact on Rockwood Brook test samples for volatile organic compounds by GCMS from surface Stations B (upstream) and C (downstream) on the April and October samplings
3 To determine if trace metals are present in downgradient ground waters conduct analyses for cadmium chromium lead mercury and zinc on samples from all monitoring points during the April sampling and on subsequent sampling rounds if necessary
4 To confirm the continued absence of baseneutral extractable compounds in downgradient ground and surface waters conduct analyses for baseneutral extractable compounds on samples from monitoring wells M 2 and 3 and surface Station C (downstream) on the April sampling and on subsequent sampling rounds if necessary
5 If a sudden rise in concentrations toward unacceptable levels should occur in the monitoring system (wells and brook) additional monitoring rounds at a monthly interval should be conducted to confirm the rise in concentrations
6 If elevated concentrations persist and are verified by the additional monitoring remedial alternatives will be defined to mitigate the potential for downgradient ground and surface water contamination
Respectfully submitted NORMANDEAU ASSOCIATES INC
Dennis R Sasseville Project Manager
Donald H Bruehl f laquo | APG Senior Hydrogeologist -^ - - AIPG Certificate No 2272 ^ -v^
^^Z-^^
APPENDIX A
SITE SAFETY PLAN
GENERAL SAFETY PLAH FOR
TROT MILLS LANDFILL TROY MEW HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
Prepared by
NORMANDEAU ASSOCIATES INC Bedford New Hampshire
R-457
November 1983
TABLE OF COHTENTS
PAGE
SECTION 1 BACKGROUND INFORMATION 2
Identification 2 Personnel 2 Site Description 3 Project Description 5
SECTION 2 HAZARD EVALUATION 6
Overall Degree of Hazard 6 Specific Hazards 8 Necessary LPP 8
SECTION 3 FIRST AID FOR EXPOSURE 10
SECTION 4 OPERATIONS SAFETY PLAN 11
General Personnel Protection GuidelinesAction Levels 11 Site Reconnaissance 13 Task 1 - Magnetic Survey Topographic Survey 14 Task 2 - Drum excavation and Sampling 15
SECTION 5 EMERGENCY INFORMATION 16
Emergency Telephone Numbers 16 Route to Hospital 16 Contingency Plan 17
APPENDICES 18
A - LEVELS OF PERSONNEL PROTECTION 18 B - DECONTAMINATION PROCEDURES 23 C - PERSONNEL AND RESPONSIBILITIES 25 D - PERSONNEL CASUALTY 26 E - GUIDELINES FOR SITE OPERATIONS 27
GENERAL SAFETY PLAN FOR
TROY MILLS LANDFILL TROY NEraquo HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
The following is a Safety Plan for on-site activities performed
during the Investigation of the Troy Mills Landfill being conducted by
Normandeau Associates Inc (NAI) of Bedford New Hampshire
The document is intended to be an in house working guideline
for personnel trained and experienced in hazardous waste field work and
not a treatise on safety Familiarity with standard equipment and proshy
cedures is expected Where possible non-site specific information has
been appended
All NAI employees subcontractors and visitors will be required
to follow this safety procedure plan and to report to either NAIs proshy
ject manager (P M) on site coordinator (OSC) or safety officer (SO) on
issues relating to safety
SECTION 1
BACKGROUND INFORMATION
IDENTIFICATION
Site Name Trey Mills Landfill NAI-ID No 457
Trey Mills Inc Troy NH 03465
AddressLocation At the south end of the dirt road about 15 miles
south of Troy NH between Rockwood Brook and the
old Boston and Maine Railroad grade
County Cheshire Phone 603-242-7711
PERSONNEL
Brook Dupee Bureau Hazardous Waste 603-271-4611
State Contact John Regan Bureau Solid Waste 603-271-4586
Dan Allen WSPCC 603-271-2755
EPA Contact
Other Contacts
Client Contacts Barrett F Ripley (Vice President)
NAI Personnel - (472-5191)
Project Manager - Dennis Sasseville
On Site Coordinators - Alton Stone
Safety Officer - Elizabeth Gross (Phoenix Safety)
Technical Director - Don Bruehl
Other - Douglas DeNatale Steve Ransom
SITE DESCRIPTION
Type of Facility Company (on-site) landfill
RCRA Status Generator Disposer
Size About 15 acres BuildingsStructures None
Surrounding Land Use N Forested
(one mile radius) E Abandoned Railroad
Forest RuralResidential
S Forested
W Forested Mountain side
Unusual Features or Terrain None
Site Activities - Troy Mills manufactures textiles carpets and related
products Since 1968 waste materials including
drummed wastes have been landfilled on company proshy
perty Drums mostmany of which may be emptycrushed
are buried in an inactive section of the landfill
The active section is currently accepting waste
which is considered to be non hazardous
Specific - Improper disposal of hazardous waste
Problems - Leachate seep
Contamination of ground water
Hazardous WastesMaterials On-5ite
Wastes - Uncured foam rubber latex sludge
SBR rubber silicone defoamer potassium oleate soap
calcium carbonate and feldspar filters zinc oxide
and sulpher salt cure system
- Vinyl plastisol sludge
PVC dispersion resin DOP and DOA plasticiser
calcium carbonate filler organic pigments AZO
dicarbcnamid blowing agent zinc salts expoxidized
soybean oil cadmLum-bariin-zinc stabilizer Varsol
MEK prints and topcoats sludges
PVC acrylic resins organic and inorganic pigments
MEK solvent toluene silicate fillers
Industrial solvents and chemicals
11 -dichlorethane 12-dichlorothane
111-trichloroethane trichlorethylene tetrachshy
lorethene methylene chloride toluene benzene
ethylbenzene benzidine 33-dichlorobenzidine aeroshy
lein acrylonitrile napthalene benzoperylene dibenshy
zoanthrasene idenopyrene
Pesticides
There is a possibility for low levels of pesticides
to be on site These would include Chlorodane
heptachlor expoxide toxaphene aldrin alpha BHC
beta BHC 4-4-DDT endosulphan 1 heptachlor
PROJECT DESCRIPTION
Purpose Tb characterize ground water conditions at the site and to
characterize wastes buried on site
Specific Tasks
Site Reconnaisance
Task 1 - Magnetometer SurveyTopographic Survey
Task 2 - Excavation for inspection of drums
SECTION 2
HAZARD EVALUATION
Overall Degree of Hazard - Moderate
Task Hazard Proposed LPP
Site Reconnaissance Low Level C
Task 1 MagnetometerTopographic Surveys Low Level CD
Task 2 Drum ExcavationSampling Moderate Level B
Conpany records have indicated that a variety of industrial
and potentially hazardous wastes including drummed wastes
were disposed of on site Several of the subtances are
trade name materials or industrial process materials and it
is difficult to determine the specific chemical composition
Hazard is dependent upon concentration of material state of
material (solid sludge drummed liquid) and degree of
decomposition
Many of the materials - SBR rubber silicone defoamer
potassium oleate soap calcium carbonate and feldspar
fillers zinc oxide and sulpher salts plasticiser
calcium carbonate filler organicinorganic pigments AZO
dicarbonamid blowing agent epoxidized soy bean oil
cadmiura-bariun-zinc stabilizer - probably do not represent
a significant hazard to an inspection team if they are
bound into a sludge or solid Personnel are not likely
to injest or come into a prolonged high concentration
contact with these materials In powdered or dust conshy
ditions the materials are more hazardous due to the inhashy
lation of contaminated particulates
MEK (TLV-200ppm) toluene (TLV-100ppm) and Varsol
(turpentine thinner composition unknown) are volatile
organics which require respiratory protection and contact
protection
Depending upon state and decomposition PVC resins could
be a source of vinyl chloride monomer (VCM-a carcinogen)
requiring respiratory protection VCM is not adequately
filtered by air purifying respirators
Results from ground water sampling showed low levels of
industrial chemicals (PPB range) At these low conshy
centrations the chemicals do not represent a significant
hazard However the low concentrations in ground water indishy
cate the possibility of higher concentrations in the waste
materials
Industrial chemicals - napthalene (TLV-10 ppm) peryshy
lene anthrocene and pyrene which are hazardous
through inhalation or absorbtion Furthermore as
double benzene ring chemicals they are potential
carcinogens
Results from ground water sampling indicated possible
low levels (parts per trillion) of several pesticides
- chlorodane heptachlor epoxide toxaphene eldrin
Alpha BHC Beta BHC 4-4-DDT endosulphan These were
tentatively identified during a first analytical run
but not confirmed during a second run laboratory
review (GCA Bedford Mass) determined that the
material was actually a complex of highly degraded
heavy organics derived from the industrial waste The
presence of pesticides in industrial textile waste is
unlikely
Specific Hazards
1) Inhalation of organic vapors
Excavation of buried material and sampling of drums could
initiate high vapor concentrations
2) Fire and explosion
Many of the solvents are flammable liquids and volatile
Excavation of material and sampling of drums should
proceed cautiously in order to avoid rupturing shocking
or sparking of drums and material
3) Inhalation of contaminated dustparticulates
Excavation of buried material may result in a release of
particulates
4) Contact contamination
Excavation and sampling of wastes could possibly result in
contact with contaminated waste and soils necessitating
protective clothing
Necessary LPP
Site Reconnaissance - Level C The site has been visited on numerous
occassions by the state and private personnel Use of an HNU (102 ev
probe)- has not indicated significant vapor concentrations Significant
odors during dry weather or other hazards have not been noted
Sections of the landfill are currently active and adverse effects to
personnel have not been noted Level C - (tyveks rubber safety boots
organic vapor cartridges) is sufficient
Task 1 MagnetometerTopographic Survey - Level CD LPP will depend
upon the results of the Site Recon Significant vapor concentrations
or likelihood of particulates will necessitate an upgrade in the LPP
Otherwise Level D (work clothes safety boots boot wash) is sufficient
Task 2 Excavation and Sampling of Buried Drums - Level B The potenshy
tial for encountering significant concentrations of hazardous
materials during this task is moderately high Full Level B - (SCBA
chemical resistant tyveks hoods rubber safety boots rubber gloves)
will provide necessary respiratory and contactsplash protection
The use of the hooded yellow tyveck and the taping of ankleboots
wristsgloves and face maskhood junctions will provide complete conshy
tact protection
10
SECTION 3
FIRST AID FOR EXPOSURE
INHALATION OF VAPORSPARTICUIATES
Symptoms - eyenosethroat irritation nausea dizziness headache weakness fatigue lightheadedness drowsiness Loss of coordination confusion vomiting cramps (These sympshytoms are similar for most organic vapors particularly solvents)
Treatment Mild Exposure - Bring victim to fresh air Rinse eyes and throat if
irritated Heavy Exposure - (victim vomits very dizzy groggy faints etc)
Bring victim to fresh air Evacuate to hospital Prepare to administer CPR
Victim should be monitored for 48 hours in case of a delayed reaction
CONTACT EXPOSURE
Symptoms - Itching burning redness of skin Severe contact exposure for certain solvents will progress to CNS (central nervous system) symptoms similar to those for inhalation
Treatment - Remove contaminated clothing flush with water dry and banshydage Monitor victim for CNS symptoms for at least 48 hours
FIRST AIDSAFETY EQUIPMENT
The following equipment will be stationed at the Hotline or when appropriate down range
- Fully equipped first aid kit - Oxygen bottlekit - Nine (9) Ib chemical fire extinguisher - Eyewash bottle or other pressurized water filled container
11
SECTION 4
OPERATIONS SAFETY PLAN
This section outlines the specifics of safety procedures to be
used during each phase of the operations Safety procedures may be
upgraded or downgraded during site activities pending monitored changes
in the working environment All changes will be in line with the
General Level of Personnel Protection GuidelinesAction Levels for the
Troy Mills Landfill On-Site Investigation as described below
General Personnel Protection GuidelinesAction Levels
An in depth review of levels of personnel protection (LPP) is
presented in Appendix A
Level B (SCBA cotton coveralls or work clothes yellow tyveks (chemical resistant) steel toed rubber boots or work boots with disposhysible over boots and gloves)
Vapor concentrations (as measured on an OVA or HNU 117 EV Probe) greater than 5 ppm above background
- Oxygen deficient atmospheres less than 195
Specific actions (ie excavationsampling of drums) which could initiate a sudden moderate or high concentration of vapor
Level C (full face respirator organic vapor dust combo cartridge tyveks over work clothscoverails rubber safety boots gloves)
Vapor concentrations above an established clean zone backshyground level
During conditions (natural or personnel induced) which result in high levels of dust (visable above background atmospheric concentrations of particulates)
Level C activities require continual air monitoring
12
Level D (cotton coveralls or other work clothes safety shoes and safety glasses when down range Tyveks may also be needed)
Support areas and downrange areas where a higher LPP has not been deemed necessary
Continual air monitoring in downrange areas
Explosive Atmospheres
- 20 LEL (lower explosive limit) as recorded by an explosishymeter Secure and evacuate the work area
Oxygen Deficient Atmospheres
- Less than 195 (by volume) oxygen atmosphere requires upgrading the level of Personnel Protection to Level B
Task Specific Safety Plans
Levels of Personnel Protection indicated for specific tasks below are those which are anticipated to be used Changes in site conshyditions and results of air monitoring may indicate the upgrade downgrade of the LPP
13
Site Reconnaissance (SR) Date Sept 21 1983
Purpose To review on-site conditions and determine LPP necessary for further tasks To evaluate safety hazards Preliminary planning of future tasks
LPP - Initially Level C Updowngrade as necessary
Equipment - OVA HNU (102 ev probe)
Hotline - End of access road Upwind if possible
Command PostFirst Aid - Behind Hotline
Decontamination - Boot wash
Operations
Three man team Two persons advance in front with instrushyments Third person at distance as backup
Team methodically sweeps (criss cross) the proposed work areas with instruments
Specific points of interest (leachate seeps etc) are closely checked
All information is loggedsketch mapped
Upgraded LPP as necessary
14
Task 1 - Magnetic Survey Topographic Survey Date Week of October 3 1983
Purpose - Determine the location(s) and extent of buried drums Provide topographic information for site base map
LPP - Level CD
Hotline - End of access road (upwind if possible)
Decontamination - Boot wash
Operations - SO or other NAI personnel will perform a brief safety sweep of the work area
- Work team will then proceed downrange at the appropriate LPP Using the magnetometer the team will systematically criss cross -the work area
Task 2 - Drum Excavation and Sampling Date Week of November 14 1983
Purpose - Excavationsampling of buried drums in order to characterize the condition of the drums and the nature of the wastes conshytained in the drums and buried in the landfill
Msthod - Backhoe and hand labor will be used to uncover the drums in specified locations Samples will be obtained from spillage or leakage around the drums and of contaninated soil Selected drums which have accessible and openable bungs may be opened and sampled Drums will not be moved or staged Clean drums will be available to receive any significant spillage during the opening and sampling
Specific Hazards - Inhalation of organic vapors - Fire and explosion of drummed waste - Contact with contaminated waste or soil
LPP - Full Level B protection Backhoe operator at Level B Backshyhoe equipped with splash shield and without teeth on bucket
Hotline - At the end of the access road Upwind if possible
Decontamination - Procedures will essentially follow those as outlined by the EPA for Level B work Due to the inaccessibility of the site a field shower will not be available See Appendix B
Safety Equipment - OVA HNU eyewash fire extinguisher oxygen kit first aid kit metal detector non sparking implements
15
Operations - The cover soil is very sandy and the drums appear to be buried close to the surface which should facilitate excavation
- Minimum of 4 man team (exclusive of backhoe operator) Two or three man downrange team for digging and sampling One or two men in supportbackup at hotline
- Personnel will hand dig several small holes to approximately one (1) foot depth in each Location area If drums are not encountered the backhoe will scrape off soil to that depth
- Excavation will proceed alternating hand and backhoe methods At depths below four (4) feet the sides of the pit must be angled back to less than 45deg
- Prior to opening a closed drum the backhoe will nudgebump the drum to check for shock sensitive material An alternate method will be to attach a length of rope to the drum and from a distance pull on the rope to jog the drum
mdash Backhoe The backhoe operator will work at Level B utilizing air supplied from a large cylinder attached to the backhoe The backhoe will also be equipped with a splash shield A scraping bucket without teeth will be used
Prior to backhoe excavation at each location the area where the backhoe will be stationed will be checked for drums which could be ruptured by the backhoe feet
f Excavation areas will be checked for drums utilizing hand excavations or a metal detector prior to removing material by machine
16
SECTION 5
EMERGENCY INFORMATION
Emergency Telephone Numbers
If calling one of these numbers please state NAME LOCATION
and type of PROBLEM
Local Emergency Support
Fire Department (Troy 242-7759) For all emergencies use
Ambulance 352-1100 Mutual Aid (Keene) 352-1100
Police Department (Troy 242-7992)
Hospital 352-4111 (Cheshire Hospital in Keene)
Town Clerk 242-3845 State Agencies
NH Bureau of Hazardous Waste Management 271-4608
NH Water Supply and Pollution Control Commission 271-3503
NH Fire Marshall Office 271-3336
NH State Police (24-Hour Dispatch) 1-800-852-3411
Other
US EPA (24-Hour Hotline) 617-223-7265
Poison Center Mary Hitchcock Hospital 1-800-562-8236
Route to Hospital
- Follow dirt access road to Bowkerville Road - Left on Bowkerville Road to Rt 12 - Left (north) on Rt 12 through Troy to Keene NH - At major junction of Rts 9 10 101 and 12 go straight through
into Keene - At common go half-way around and go right on Court Street - Hospital is at 580 Court Street
17
Contingency Plan
Signal - five (5) one second blasts of auto or air horn Action - All personnel immediately excavate dovmrange areas and
report to Hotline for instructions
Personnel Unexplained Fire (if small) Accident (serious) Collapse of Personnel
Evacuate area Emergency ^ ^Evacuation Evacuate Area
First Aid
Estimate Explosion Level B (for Potential Contact Outside Help evcavation)
Evacuate Victim i If
Level B Prepare for Transportation
1 First AidCPR Use extinguisher Transport
Contact Outside Help Notify Coup any Have Proper Information Personnel (see below) 1
Transport
Call Fire Dept (if necessary)
For Hospital Victim
- Name and Phone of family physician
- Description of Incident chemicals involved symptoms nature of injury proposed treatment and plan of transportation
18
APPENDIX A
LEVELS OF PERSONNEL PROTECTION
Because of the possible dangers of exposure to toxic or harmshyful chemicals protective equipment must be worn during work on hazardous waste sites Levels of Personnel Protection (LPP) describe respiratory clothing and other equipment necessary for protecting personnel against expected hazards
The descriptions below are for full dress at a given LPP where hazards are expected to be at a maximum for which the given LPP is conshysidered adequate Depending on site conditions and work activities the clothing and dress requirements of a given LPP are commonly modified
LEVEL A
1 Personal Protection Equipment
Positive Pressure SCBA (MSHANIOSH approved) Operated in the positive pressure mode
Totally Encapsulating Suit (boots and gloves attached)
Gloves - Inner (tight fitting and chemical resistant)
- Boots - Chemical - protective steel toe and shank Depending on suit boot construction worn over suit boot
- Gloves shy Outer chemical-resistanttion worn over suit gloves May bchemical-resistant gloves worn insid
Dependinge replaced withe suit glo
on s
ves
uit construcshy tight-fitting
- Underwear shy Cotton long-John type
- Hard Hat (under suit)
- Disposable protective suitover encapsulating suit)
gloves and boots (Worn under or
- Coveralls (under suit)
- 2-way Radio Communications
Optional
19
2 Criteria for Use
A The type and concentration of toxic substances are known and require the highest level of combined protection to the respirashytory tract skin and eyes These conditions would be
1 Atmospheres which are immediately dangerous to life and health (IDLH)
a IDLHs can be found in the NIOSHOSHAs Pocket Guide to Chemical Hazards andor other references
2 Known atmospheres or potential situations that would effect the skin or eyes or could be absorbed into the body through these surfaces in toxic quantities
a Potential situations are those where vapors may be generated or splashing may occur through site activities
b Standard reference books should be consulted to obtain concentrations hazardous to skin eyes or mucous memshybranes
3 Oxygen deficient atmospheres with above conditions
3 At sites where the type andor potential concentration of toxic substances are unknown
1 Unless circumstances strongly indicate otherwise the site should be presumed to present hazards to the respiratory system skin and eyes Level A protection would provide the highest level of protection for the initial entry team
a Such circumstances might be
1 Environmental measurements contiguous to the site
2 Reliable accurate historical data
3 Open unconfined areas
4 Minimal probability of vapors presence or splashing with cutaneous effecting substances
2 Enclosed areas such as buildings railroad cars ships holds etc
20
LEVEL B
1 Personal Protective Equipment
Positive Pressure SCBA (MSHANIOSH approved) operated in the positive pressure mode
- Hooded chemical-resistant suit
Gloves - Outer chemical-protective
Gloves - Inner tight-fitting chemical-resistant
Boots - Outer (chemical-protective heavy rubber disposables)
Boots - Inner (chemical-protective steel toe and shank)
2-way Radio Communications
Hard Hat
Face Shield
2 Criteria for Use
A The type and concentration of hazardous substances are known and require the highest degree of respiratory protective but a lower level of skin protection
1 Atmospheres which are immediately dangerous to life and health (IDLH) Type and concentration of vapors in air do not present a hazard to the small unprotected areas of the body
2 Atmospheres with concentrations of known substances greater than protection factors associated with full-face air-purifying respirators with appropriate cartridges
3 Atmospheres with less than 195 oxygen
B When a determination is made that potential exposure to the body parts not protected by a fully encapsulated suit (primarily neck ears etc) is highly unlikely
1 Known absence of cutaneous or percutaneous hazards
2 Activities performed preclude splashing of individuals
C Level B protection is recommended as the lowest level of protecshytion for initial entries until the hazards have been further identified and defined by monitoring sampling and other reliable methods of analysis and personnel protection equipment commensurate with these findings utilized
21
LEVEL C
1 Personal Protective Equipment
Full-face or half-face air purifying respirator (MSHANIOSH approved)
Chemical-resistant clothing
Gloves - Outer (chemical-protective)
Gloves - Inner (tight-fitting chemical-resistant type (or woven liners)
Hard Hat (face shield optional)
Boots - Outer (chemical-protective heavy rubber throw aways)
Boots - Inner (chemical-protective steel toe and shank)
2-way radio comnunications
Safety glasses required with half-face respirator
2 Criteria for Use
A Site known to contain potentially hazardous materials exceeding
1 Air concentrations requiring a protection factor no greater than that afforded by a full-face mask
2 Harmful levels to unprotected body areas (face neck etc)
3 Well-documented reliable history of site and patterns of prior entry
C No evidence to suspect acute or chronic toxicity to exposed personnel
D Continuous air or personnel monitoring should occur while wearing Level C protection
22
LEVEL D
1 Person Protective Equipment
Chemical resistant aprons
BootsShoes - Safety or chemical-resistant steel toed boots
Boots - Outer (chemical-protective heavy rubber throw-away)
Half-face respirators immediately available
Safety glasses or safety goggles
Gloves
2 Criteria for Use
a No indication of airborne health hazards present
b No gross indications above background on the photoionizer andor organic vapor analyzer
c Continuous air or personnel monitoring should occur while wearing Level D protection
23
APPENDIX B
DECONTAMIHATION PROCEDURES
Depending upon activities and location on site it may be
necessary for personnel to decontaminate prior to leaving the conshy
taminated zone Procedures described below are typical for Level C
operations
Upon exiting downrange (contaminated) areas all personnel are
required to decontaminate by means of the following procedure
1 Place equipment in the Drop Zone at the Hotline
2 Enter the Decontamination Station
Boot Wash Walk through wash tub and scrub boots then rinse boots in second tube
Glove Wash In two pan wash scrub over gloves rinse set out to dry
2 Remove tyvek - if leaving the contamination reduction zone (CRZ) and proceed to clean zones
3 Dispose of heavily contaminated clothing and under gloves
4 Remove respirator
5 Use disposable gloves to clean equipment
6 Use a two bucket (washrinse) to decon respirators at the end of the working day or if they become heavily contami nated
The procedures for a typical Level B Decontamination are
outlined on the following page
TANK CHANGE 9
CONTAMINATION REDUCTION
ZONE
OUTER GLOVE REMOVAL
EXCLUSION ZONE
TAPE REMOVAL
BOOT COVER
GLOVE WASH
(bull)mdashQ-G--copyshySOOT COVEH SCOT COVES 4
REMOVAL GLOVE RINSE
SUITSAFETY BOOT WASH
SU1TSC8A78OOTGLOVE RINSE
SAFETY BOOT 10 REMOVAL
SCSA BACKPACK REMOVAL
SPLASH SUIT 12 REMOVAL
INNER GLOVE WASH
INNER GLOVE RINSE
FACE PIECE REMOVAL
INNER GLOVE 16 I REMOVAL
INNER CLOTHING REMOVAL
FIEUJ 19 REDRESS WASH
SEGREGATED EQUIPMENT
OROP
mdash -HOTLINE-shy
DECONTAMINATION LAYOUT LEVEL B PROTECTION
FIGURE A2-1
CONTAMINATION CONTROLLING
SUPPORT ZONE
25
APPENDIX C
PERSOHNEL AND RESPONSIBILITIES
Project Manager (PM)
Overall responsibility for all Project activates budget
schedule investigative operations safety personnel
On Site Coordinator (OSC)
Responsibility for activities at the site Primary responshy
sibilities include
1) Interfacing with the client state EPA media or other groups
2) Reviewing technical operations
3) Reviewing site safety in particular information supplied by the Site Safety Officer
4) Enforcing site safety and compliance with the Safety Plan
5) Directing Emergency Contingency operations
Safety Officer (SO)
Responsibility for directing the safety of operations and impleshy
menting the Safety Plan Specific responsibilities include
1 Assuring that appropriate personnel protective equipment is available and properly utilized by all site personnel
2 Assuring that personnel are aware of the provisions of this plan are instructed in the work practices necessary to ensure safety and in planned procedures for dealing with emergencies
3 Assuring that personnel are aware of the potential hazards associated with site operations
4 Supervising the monitoring of safety performance by all pershysonnel to ensure that required work practices are employed
26
APPENDIX D
PERSOHHEL CASUALTY
Personnel casualty would most likely result from either chemical
contamination heat-related problems physical injury from accidents
(ie falling lacerations etc) in performing the work or a comshy
bination of one or more of the above The appropriate action depends on
the type of injury involved with the priority being to assist the
casualty as soon as possible without endangering other personnel
Riysical and heat-related injuries can and should be treated
immediately with appropriate first-aid measures and follow-up medical
attention if necessary The injured worker(s) shall immediately move
out of the hot zone or if necessary be moved out by fellow workers as
soon as possible The OSC and Safety Officer shall be notified immeshy
diately and shall recommend further measures as needed
Chemical-related injuries require a much more cautious approach
so as to keep casualties to a minimum If a worker injured by chemical
ejqgtosure is able he shall notify the nearest co-worker and leave the hot
zone immediately- The co-worker shall ensure that the OSC and Safety
Officer are immediately informed and shall accompany the casualty from
the hot zone to the decontamination zone The OSC and Safety Officer
shall determine the appropriate measure
27
APPENDIX E
GUIDELINES FOR SITE OPERATIONS
In order to deal with the potential dangers of exposure and conshy
tamination of a hazardous waste site three zones are delineated
according to the degree of hazard The three zones are 1) Downrange
or Contamination Zone 2 Contamination Reduction Zone (CRZ) 3) Support
or Clean Zone
Downrange or Contamination Zone
The Contamination Zone is the active work area of the site which
encortpasses the areas where there is a potential for exposure and in
which investigative activities will occur (drilling sampling etc)
Within the Contamination Zone the designated level of hazard will be
established necessitating the utilization of personnel protective
equipment
Hot spots are those areas Downrange where observations instrushy
ment readings or specific activities indicate a high probability of
closure or contamination and may require an upgrade in the LPP in the
vicinity of the Hot Spot
Contamination Reduction Zone
The CRZ is an area between the Downrange and Support Zones where
decontamination of equipment and personnel occurs
28
Personnel entering the CRZ shall wear protective clothing and
carry the respiratory protection required for entry within the
Contamination Zone
Personnel working within the CRZ shall remain cognizant of the
CRZ in order to be prepared for any need to increase their level of proshy
tection within the CRZ
A decontamination station will be located at the outer perimeter
of the CRZ All personnel who have been within the Hot lane shall pass
through a decontamination procedure prior to re-entering the Support
Zone
Support or Clean Zone
The Support Zone is the outer area and may be considered to be
clear of contamination potential The command post will be located
within the Support Zone
a) The Command Post will serve as the OSCs headquarters and
will be equipped with
1 Communications
2 Safety Plans
3 First Aid Supplies
4 Analytical Equipment
5 Safety Equipment
APPENDIX B
WORK PLAN
WORK PLAN FOR
TROY MILLS LANDFILL TROY NEW HAMPSHIRE
DRUM EXCAVATION AND SAMPLING
Prepared by
NORHANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
1933
WORX PLAN FOR
TKOt MILLS LANDFILL TROT NEW HAMPSHIRE
DRUM EXCAVATION AHD SAMPLING
DATS November 16-18 1983
PURPOSE
To determine the condition of drums (ie erroty or full
crushed rusted leaking etc) buried in the Troy Mills Landfill To
obtain representative samples toward identifying the types of materials
buried in the landfill This information will be used in the detershy
mination of the level of remedial action needed at the site
METHOD
Using the results of the magnetometer survey the (10) points
have been randomly chosen across the area where the buried drans are
expected to be found Each point is central to an Excavation Location
-- an area four (4) to six (6) feet in diameter which will be excavated
in order to characterize the condition of the drams and to obtain waste
sarples
Preliminary observations have indicated that many of the drums
may be buried within 1-2 feet of the surface Therefore the investigashy
tion will proceed in two phases
Phase 1 mdash Hand Excavation By digging several small holes in
each Location personnel will determine if drums are located within
about one to two feet of the surface If drums are encountered the
excavation will proceed by hand uncovering the dnris for evaluation and
sampling Where drums are not encountered near the surface excavation
at this location will be postponed until Phase 2
Phase 2 mdash HandBackhoe Excavation After all Locations have
been attempted during Phase 1 those Locations in which drums were not
encountered wall be further excavated using a combination of hand
backhoe digging
It is expected that one to two days will be necessary to
cor^piete each phase Depending upon the results of Phase 1 it may not
be necessary to iroleraent Phase 2
Spare drums will be on hand for containerizing any significant
spillage resulting from sampling efforts Excavation locations will be
identified with marked stakes and the holes will be backfilled at the
conclusion of the investigation
SPECIFICS
Excavation Locations (Holes)
Number of proposed excavations is ten (10)
Locations of excavations are presented in Appendix A
Hole Size mdash It is expected that a hole from four (4) feet to six (6) feet in diameter at the bottom (depth at which drums are encountered) will be sufficient to characterize the drums at each Location Deeper excavations will require increasingly large top diameters
Hole Depth -- Holes will be excavated to a maximum depth of six (6) feet Due to the sandy cover material the excavation of deeper holes is probably impractical from both safety and efficiency stand points
If after attempting excavation at each of t-ie 10 proposed
1ocatiors irums are not encountered within six (6) fet of the surf ice
in enough locations to characterize the site excavations nay be
attempted to depths greater than six (6) feet if scil stability permits
or a new set of sampling locations may be chosen
(Excavations to depths greater than six (6) feet require a
significant increase in work The sides of the hole crust be graded back
to less than 45deg in order to insure the safety of investigatorysampling
personnel It may also be necessary to employ bracing bulkheads etc
for trench support)
Excavation Identification
Proposed excavation Locations have been consecutively numbered
from 1 to 10 beginning at the east end of the landfill They will be
marked with numbered stakes
Excavation Methods
Phase 1 mdash Within each Location personnel will dig a nunber of
small holes - about one (1) foot in depth - to probe for drums If
druns are encountered they will continue to excavate until the drur3
are sufficiently uncovered for characterization
Phase 2 mdash After hand probing the Location with snail holes
the backhoe will remove cover material to the one (1) foot depth The
Location will then be probed to a two (2) foot depth before removing
further material Excavation will proceed alternating handprobing and
backhoe excavation until drums are encountered or the maximum six (6)
foot depth is reached
If excavations to depths greater than six (6) feet are undershy
taken they will proceed using the above method
Santnlea
Due to the effort involved in excavating and because conshycentrated waste samples are not expected to undergo rapid degradation it is considered expedient to obtain all readily available samples (exclusive of closed drum samples -- see belcw) These can then be submitted for laboratory characterization as determined by need and budget restrictions
An attempt will be trade to secure at least one sample froa each excavation in order to help characterize the distrishybution of waste materials across the site An attempt will also be made to secure samples of observably difshyferent materials
Sample Types and Mediums - Solid liquid and sludge samples are possible Samples will be obtained from in order of preference -- 1) leakage uncontainerized waste or contaminated soil 2) waste contained in open conshytainers - drum already has a hole or no top or other access point 3) sealed containers
The opening of closed containers will be considered if it is decided that it has not been possible to obtain a sufshyficient number of representative samples from the other mediums
Each sample will consist of two (2) 8-oz jars (with teflon-lids) filled about 23 full One jar will be for organic analysis and the other for inorganic analysis
Sanole Identification - Samples will be identified with a number corresponding to the Excavation Location and a letter Example if three samples were obtained from Location 2 they would be samples 2A 23 and 2C and Samples 2Ad 23d and 2Cd for duplicates
Sampling Methods and Volumes - 11 mm hollow glass tubing trowels disposable scoops will be available to obtain samples Samples tools will be disposed of or deconshytaminated between each sample
Drum Samples - If necessary an attempt will be cude to obtain samples from sealed drums Oily o^und non-rusted drums will be considered Bunjs rust be xn suitable conshydition -jo that the dram cm be openoi withrut cvis ing dainai -ind ca-i be resell od to pr-jvcrt l V-i 30
There wil l be no staging or movement of drums in order to faci l i tate sampling Only drums with accessible bungs will be considered for sampling
Procedure for Drum Sampling
1) Excavate around top of drum
2) Monitor air in the adjacent area
3) Chec for shock sensitive - Loop rope around top of drum stand at a distance give drum several hard jogs by pulling on the rope An alternative nethod is to lightly jog the drum with the backhoe bucket
4) If the drum is not upright place a catch basin under the bung
5) Open drum with bung wrench
6) Monitor the air atin bung
7) Sample drum -- liquids insert glass tube the fu l l length into the drum in order to obtain a column of the materials in the drum Solids use scoop to dig out material through the bung or use a sampling trowel
3) Reseal the dram
Spill Control
The possibility exists during the sampling and excavation for a
drum to be ruptured or otherwise have spillage Clean drums wil l be on
hand to receive significant spillage resulting frora sampling or excavashy
tion They will not be used for clean up of widespread uncontainerized
waste or existing leakage
Personnel
The work team will require four (4) persons (exclusive of the
backhoe opera tor) Trie downrange team will consist of three (3) persons
-- two (2) for d igg ing and sampl ing and on ( 1 ) for logging air moni shy
toring and photographing One (1) person will be at the hotline in
support mdash as safety backup person to fill air bottles to deconshy
taminate samoles to assist in decontamination of personnel
Documentation Logging
The following information will be recorded at each location
nmber of drums uncovered and the condition (crushed empty rusted
sealed etc) of each drum evidence of spillage or contaminated soil
labels on uncovered drums samples (time drum ID type description)
periodic air monitoring information depth at which specific events
occur or drums are buried soil condition presence of ground water
In addition photographs will be taken of specific events or
items of importance during each excavation and of each sampling incishy
dent The time description of subject photographer excavation
location and photo number will be logged for each photograph
Analytical Laboratories and Schedule
RAI Hampton NH
Initial schedule
Ten samples for GCrns for organic priority pollutants Samples may also be submitted for inorganic anlaysis or volatile organic analysis depending upon waste materials observed during the excavation
APPENDIX A
TABLE A-1 EXCAVATION LOCATIONS
EXCAVATION BASELINE RANDOM RANDOM
NUMBER GRID COORD SEGMENT STATIOH OFFSET
1 7E+1 565N 0- 60 26 (25) 16
2 9E+5 13S 60-120 50 (110) 9
3 8E+0 31S 120-180 20 (140) 7
4 4E+5 483 180-240 50 (230) 25
5 3E+3 45S 240-300 14 (254) 20
6 OE+6 5S 300-360 34 ( 334) 50
7 2W1 5 24N 360-420 45 (-155) 14
8 5W+6 42N 420-480 38 (518) 20
9 6W+1474N 480-540 8 (543) 7
10 8W 5 11011 540-600 11 (611) 31
Locations are plotted on Map A-1
Method of Choice A stratified random sampling method was used to choose 10 Excavation Locations within the magnetic anomaly
The axis of the magnetic anomaly was used as a base line and divided into ten 60 foot long segments Using a randora nirnbers table a distance along each secpent was chosen (Random Station) and a line drawn at that point perpendicular to the base line Again using a random numbers table a distance was located along each perpendicular line by measuring inward from the line denoting the edge of Area A (Random Offset) The Grid Coordinates for each of the Excavation Locations were graphically determined from the grid overlay (this overlay has been surveyed and intersections field located)
It was judged that 10 excavation locations within the magnetic zone and two outside of the zone would be sufficient to characterize the area would produce statistically valid iati and coli be expected to be co~letod within 2-3 days work period
to
80
cu0
cgtc
APPENDIX C
MAGNETIC INVESTIGATION TROY MILLS INC LANDFILL SITE
TROY NEW HAMPSHIRE
For
NORMANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
By
JOHN F KICK PhD GEOPHYSICIST
Box 6 Dunstable Massachusetts 01827
(617) 649-6650
Noverber 19S3
MAGNETIC INVESTIGATION
TROY MILLS INC LANDFILL SITE
TROY NEK HAMPSHIRE
INTRODUCTION
A high resolution ragnetic investigation was completed on the Troy
Mills Inc landfill site in Troy New Hampshire by John F Kick
Consulting Geophysicist The purpose of the investigation was to
delineate the extent of buried steel drums under closed portions of the
Troy Mills landfill The information is needed as a part of a study of
the landfill that is being conducted by Normandeau Associates Inc
FIELDKORK
Magnetometer measurements of total field intensity were made over an
area that was reported to contain buried steel drums and adjacent
landfilled areas that contained unknown waste materials The area of
investigation included capped and grassed closed areas along the south
margin of the landfill site and adjacent areas The fieldwork was
performed during October of 1983
Eighteen parallel rows of measurements were conducted along north-
south lines (using magnetic compass directions) A spacing of 20-feet
was used between rows and magnetometer measurements were made at 10-foot
intervals along the rows Greater intervals between measurements were
used at the ends of the rows and in periferal areas with low magnetic
-JF Kick 01shy
field gradients
A series of magnetic field measurements were made at an adjacent
base station throughout the survey to torn the basis for a daily
variation curve The base station was located at a site with typical low-
gradient background magnetic field intensity measurements
MAGNETIC SEARCH METHOD
Theory Magnetic search methods involve the detection and
measurement of anomalies in the Earths magnetic field caused by the
presence of materials with contrasting magnetic susceptibility Iron and
steel objects generally have very high magnetic susceptibility contrasts
with usual surrounding materials and therefore produce magnetic
anomalies The amplitude shape and detectable distance of the anomaly
depend mostly on the particular susceptibility contrast and size of the
object Magnetic anomalies are measured in units called gammas The
normal magnetic field in this area is over 50000 gammas A 5-inch
screwdriver will produce an anomaly of 5 to 10 gammas at a depth of 5
feet and an anomaly of 1 gamma at a depth of 10 feet A 1 ton automobile
will produce an anomaly of 40 gammas at a depth of 30 feet and an anomaly
of 1 gamma at a depth of 100 feet The magnitude of an anomaly caused by
a single steel drum will vary with its condition (new heavily rusted
etc) Tests using a single light weight (somewhat rusted) drum on the
surface with the magnetic detector at a height of of 12 feet produced an
anomaly in the range of 40 to 50 gammas
Total magnetic intensity disturbances or anomalies are almost always
asymmetrical sometimes appear complex even from simple sources and
usually exhibit the combined magnetic effects of several sources which
can produce a given anomaly The apparent complexity of such anomalies
is a result of several relatively simple functions of magnetic dipole
-JF Kick 02shy
behavior Reasonable assumptions about the geology and buried source
conbined with an understanding of magnetic dipole behavior can usually
lead to a satisfactory qualitative interpretation More detailed
interpretations nay require modeling studies
Instrumentation Field equipment on this project included a EGampG
Geometries Memory-Mag G-856 proton precession magnetmeter The
instrument has a resolution of +01 gamma The magnetic field detector
is separate from the rest of the instrument and is mounted on an 8-foot
staff to provide measurements that are a constant height above land
surface
Magnetic Data Analysis For the purposes of data reduction and
anomaly delineation it was assumed that base station total field
intensity measurements were typical background values for the site
Measurements made at frequent intervals at the base station were used to
prepare a diurnal variation curve for the site Anoraly values were
obtained by subtracting background values from the base station curve
from measurements collected in the area of investigation
RESULTS
The reduced results are presented in the form of a magnetic anomaly
contour map (Figure 1) and two profiles across the area of investigation
(Figures 2 and 3) The map and profiles show that very steep magnetic
field gradients and large departures form background occur in an
irregular shaped band that is about 460 feet long and ranges from about
30 to about 200 feet in width The magnitude of the anomaly is such that
a significant deposit of ferromagnetic materials (such as steel drums) is
indicated
In using the plotted magnetic results it should be noted that the
greatest concentrations of ferromagnetic materials probably do not
-JF Kick 03shy
directly underlie the peak magnetic anomalies A shift is caused by the
inclination of the Earths magnetic field and by the dipolar nature of
ferromagnetic deposits The inclination of the Earths field is about 76shy
degrees northward in the vicinity of Troy The dipolar effect is induced
by the Earths field and results in negative anomalies immediately north
of large positive anomalies
Magnetic Anomaly Map The magnetic anomaly map (Figure 1) indicates
10 positive peaks of varying size shape and intensity Associated
negative anomalies of a broader and less intense nature lie immediately
north of the belt of positive anomalies The configuration of the
anomalous area is indicative of lense-shaped and cigar-shaped bodies of
ferromagnetic materials Steep-sloped anomalies are indicative of very
shallow source materials The thickness of the ferromagnetic deposit
cannot be easily determined on the basis of intensity and size of
anomalous peaks because a small mass of iron or steel at the surface can
duplicate the anomaly caused by a much larger mass at depth The
ferromagnetic source materials can generally be expected to lie north of
the positive peak of anomalies and south of the adjacent negative
anomaly Modeling can provide the best approximations of the depth and
density of the ferromagnetic source materials The outer boundaries of
the source materials can be expected to overlap the positive peak and
negative anomaly somewhat depending on the depth and configuration of
the deposit
For illustration purposes two north-south rows that were profiled
are discussed below
Magnetic Anomaly Along Row 9-East Two strong positive magnetic
anomalies (3645 and 2436 gammas) and adjacent negative anomalies were
profiled along Row 9-East (Figure 2) The approximate centers of the
ferromagnetic deposits are believed to underlie stations 50 north and 75
feet south of the base line The rounded shape of the north positive
-JF Kick
anoraly nay indicate somewhat deeper burial of the ferromagnetic deposit
Magnetic Anomaly Alone Row 7-West Figure 3 shows the most intense
positive magnetic anomaly (4470 gammas) that was detected on this
project The steepeness of the slopes is indicative of very shallow
source materials An uneven burial pattern is suggested by the two-
peaked positive anoraly The negative anomaly south of the two peaks is
unusual and may be related to another positive anomaly to the southeast
(along Rows 5 and 6 20 feet north of the base line) The centers of the
sources of the positive anomalies are probably approximately 80 and 120
feet north of the base line along Row 7-West
-JF Kick 05shy
DISTANCE FROM BASE LINE(FEET)
CO
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i-mdash LU Lu 2 Q lt2 Z
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SVWWV9 N A1VWONV
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t o H
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UJ UJ en UJ u UJ
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APPENDIX D
LABORATORY ANALYSES
RAI
Resource Analysts Incorporated Box 4778 Hampton H 03842
(603) 92^7777
TO PO 830318
Mr Doug DeNatale Date Received 12-2-83 Kormandeau Associates 25 Nashua Road Lab Number 2887 Bedford NH 03102 J
Date Reported 1-3-84
IDENTIFICATION
SAMPLE DESIGNATION PARAMETER
Volatile Organics Analyses by EPA Method 624
Acid and BaseNeutral Extractable Compounds Analyzed by EPA Method 625
Metals Analyzed by Standard Methods 303A
Please see attachments for all results
Results expressed in mgL unless otherwise designated lt = Less Than
ClarkeFosterVan K o u w e i b r h 1 ANALYST DIRECTOR
METHODS Standard Methods (or the Examination ol Water and Waitewaler 15th Edition or other EPA approved mtlhodologiei unless otherwise designated
Phys ica l descr ip t ion of sample
LiquidSludop
Saiple workup
Volitile f ract ion Methannl F-1-rarMrm CSVJ Rdfi-Smm
Semivolatile f ra ictio0onication Extraction fSW 846-3540^ Inorganic f rac t on Acid Digestion (SW 84h-iOS(V)
ACS3 COMPOUNDS
rr t CAS CAS
(71 A) tt-Ot-2 i^t TT i^MoroprvrfgtOi (73B) 30-32-1
(23 A) J9-JO-7 ^bull^^ lof o^^ft^crt gto (7 OB) 205-M-2
(2 A) 13-37 -J 2- chlorophenol (75B) 207-01-
(3 A) 120-13-2 2raquo^icMoroorgtenol (748) 211-01-9
(MA) 103-47-9 2-dimethv lohenol (77 B) 201-94-1
(37A) U-73-3 2- niiroDhenol (7IB) 120-12-7
(MA) 100-02-7 raquo-niiroprienol (7raquoB) lraquol-2raquo-2
(raquoA) Jl-21-3 2 - in i tr opheno 1 (106) raquoi-73-7
(40 A) 33-J7-l k4-dinnro-2-mlaquothylplaquogtergtol (I IB) 15-01-1
(4A) I7-U-3 (xntictiloroorraquonol (I2B) J3-70-3
USA) 101-93-2 pxmol (I3B) 193-39-J
(14 B) 179-00-0 RASENEUTOAL COMPOUNDS
( I B ) 13-32- raquocmlaquophtgtgtefgtlaquo
(36) 92-173 benzidine (2V) 107-02-S
( I B ) I20-I2-I l2t-tricMorobenzlaquonlt (3V) 10713-1
OB) 111-71-1 he laquo laquoch 1 or o benz erve (laquoV) 71-A3-2
(176) 47-72-1 hetraquocWoroltthlaquone (4V) X-23-5
U S B ) 111-- bu(7-cloroetrivl)ether (7V) 101- 90-7
(7CB) 9 I -3J -7 2-Chlororuprthraquolene (10V) 107-04-2
(73B) 95-50-1 l2-diCMoroblaquonzene ( I 1 V ) 7|3j^
( K B ) XI-73-1 13-didilorobtnzene (13V) 7J-3-3
(27B) 104-M7 1tmdash djcMorobenzene dkV) 79-00-3
C2IS) 9i9i-l 33-dictgtloroblaquoazidinr ( I JV) laquo-3-J
(33B) 12I -U-7 2gt-dinicrotoluer (14V) 7J-00-3 (KB) 4O4-7C-7 24-dinitrotoluene (UV) 110-73-1 (J7B) 122-A4-7 1J -diprienv lhydrraquo z irf (23V) lt7 tt 3
(MB) Z0-fc-0 UuorraquonThelaquo (2raquoV) 7J-35-
(W551 700J77-3 -ctilorophenyl prlaquonyl ether (JOV) 1M-40-3
( raquo I 6 ) 10I-J3-3 raquo-6romoprgtefgtyl prtenyl ether (32V) 71-17-3
(raquo7B) 33132-9 bU (2-cMorobopropyl) ether (33V) 10041-02-4
(raquoJ6) i l l -91- l bu (2-laquo^loroeTho)ry) methane 10041-01-03
(B) D-U) hexraquopoundj1|orobutaltlicne (31 V) 100--
(33B) 77-raquo7- heiKCtilorocycIopentadicrve (WV) 7J-CT-2
OB) 7IJraquo-I traquoo oh or or (raquo3V) 7raquo-17-3
(J3B) gtl-20-3 nphthraquolene (UV) 7raquo-I3-9
(546) n-tj) nitrobenzene (7V) 7J-2J-7
(426) U-Xl-4 bullJ -n itr o tod iphenyU mi ne (UV) 75-27-J
(OR) 421-W-7 N-oitrcnodipropYlirrUne ^raquoraquoV) 73-49-k
(446) I 1 7 J I - 7 bu (2-eltr^lheryl) phtfaUte 8200 (3ov) 73-71-1
(476) 13-U7 benzyl buryl phttwlite (51V) 124-kt-l
( U B I M-71-2 di-fl-utgtl pMhUre (13V) 177-II-
( lraquo6) 117-1 -0 dj-n-octvl prithlaquoUte (UV) 101-IS-3
(7CB) W-44-2 dielhvlphtraquollaquo (17V) 79-OI-t
( 7 | B ) I 3 I - I I - J dj^laquorTvipnthraquoUtr (UV) 7J-OI- (776) H-J5-5 bnro(raquogtnthrraquocefvr
Iab I D N o 2SS-10
C l ien t ID 1A64223
RASENEUTRAL COMPOUNDS
bfzoltraquogtprrene
benzoltb)flucrraquornNene
benio(llaquo)fluorraquonthene
chryiene
bullcenaDhthvien
raquontnrraquoctne
benzoltghi)perrlefgte
Iluorene
phergtraquonthrmlaquo
dibenzoltraquoMaithrraquocenraquo
indeno(123-cd)pvrene
prrene
VOLATHES
(frolein
bullcrvlooitrdf
benien
orbon Temchloide
CMorobeniene
1 7-dJchlorolaquothnr
111-trieftloroethine
ll-ltJichloroetrufle ll7-triCilorigtetMrlaquor
l127-tetrraquocMorothfllaquo
chloroethlaquo-e
7-dMoroeThraquo|virgtvl eirwshy
chloroform
11-didMoro^tfwnr
trinj- 1 2-dictMorolaquoirgtene
1 7-ltlicMoroproplaquorve
trini- 1 3-ltJichloroorcrpeoe
cu-lJ-lieMorocT oo eashy
rthy Uveniene
methrlene chloridf
chloromethine
bromome thraquone
bro mod iCTi lore met Mrgt
(Juorotr ichloromthraquor
di cMlor od 1 f 1 uore ngtet hj^gt
chloreltJbnjmomethne
te tr ten 1 or oet rx-r
laquouene 12000
tncMeroethe^e
Cidrr ium Chromiutr 10
All results are expressed as ucg veicht as received Nc ertrv denotes -0r ~ ^ 1 i rt
P h y s i c a l d e s c r i p t i o n of
SoilSludge
sample
Sanple workup
Vol i t i le f ract ion p^r Exf- rar r ion fST7Semivola t i le f rac t ion So^h^Pt Fgtr f ra r f ion
846-SOTO^ (SWRdfi-^SiO1)
Inorganic fract ion Ar id nio-psrirm
AOD COMPOUNDS
m CAS (2i A) tt-04-2 2raquot- Wichlorophenol
(22 A) J1-50-7 p-cfi I or o-n-cre laquoo 1
(2A) 13-57-1 2- ctiloroprienol
O iA) 120-13-2 2raquo^icMoroprnol
(gtraquoA) 103-47-1 2f 4mdash^imetSv Ip^enol
(37 A) U-73-3 7mdash Ti j oprtenol
(JraquoA) 100-07-7 mdash mdasho i Br opr^e no 1
JJ1A) 31-21-3 if mdash4 irtiTroprienol
(40A) J34-32-1 4 T4-4initrogtmdash 7 nte tny Ipnenol
(4A) f y _H 5 plaquontchlaroorwnol
(43A) J 01-95-7 prienol
rV ipoundNEUTRAlaquo- COMPOUNDS
( I B ) raquoJ-32-raquo
(3B) 17-17-5
( IB) 170-12-1
(IB) 1I1-7I-I
(17B) 4777-1
( I t B ) 111--
(20B) 11-31-7
(236) 15-50-1
(245) 51-73-1
(77B) 104-4-7
(285) 11-14-1
(336) 121-142
(34B) 404-70-2
(J7B) 127-M7
O1B) 2O4--0
(406) 7003-72-3
(416) 101-35-3 lt raquo 2 6 gt 3H3I32-1 ltraquo36) 111-11-1 (57B) S7-U-3
(336) 77 -raquo7-
(36) 71-31-1
(33B) 11-20-3
pound34 6 1 n-i33 (UB) tt-30-4
(436) CI-44-7
(4461 117-11-7
(47B) U-417
( U B I 14-747
(U6) I17_t-0
(7CS) l-laquo2
(7 I B ) t J U t l - gt
(7761 54-55-3
CT-~- i_i w i Miirn 0
resul ts
b^TMdint
1 2 t-o- icn lorobenl ergtlaquo
SeTraquochloroblaquorierraquoe
hrxchlorolaquotSlaquone
bu(2-chloroethv|gtether
2 -lt3M or onraquo ph ti1 ene
1 2-ltJictilorotgtmzcne
13-dicWorotxerzene
1 4-djch 1 or otxn z ergte
33-ditfgtlorolgtlaquoniidirraquo
24-dinitrotoloene
2 4-dtnitro toluene
U-dlpoenylfiydrraquoiilaquo
(luoranthene
raquo-cfJorophenyl poenyl ether
Mx-omopfieflyl phenyl ether
bis (2-cMorooopropyt) ether
bu (2-ctilorcxtSorv) meiSkte
hezkOilorobutadicne
hei acM or ocyc1 ofMn udi cne
oo prior one
nphthlene
nurotxniene N -ni tro Kxd ipoenyU mi ne
N-rutrowxhpropYUmJrw
bu (2-thylherl)(gthlaquoiraquoUtraquo
blaquoniyl buryl phtfraquolaquoUte
dt-^t-^xjrvl pfttfuiLitY
dj-n-octyl pitflaquoLitraquo
dirthvl phtruUtt
OArriett^vt prraquoT^Lraquot
bnzoltklaquonihnicer
22 Chronium
ire ev^rescei as uc ^ ^i-~ht-
Lab 1U N o 28B-1
C l i en t I D 1 R R 7 A A R
RASpoundNEbTRAL COMPOUNDS
benroltb)fluorraquorgtthfflf
benzoraquollt)fluor intone
ltrylaquo-gte
bullcenioithylen
raquomtirraquoenlaquo
ben z oltxh i)per v lene
lloorene
poentnthrrne
dibnzo(4h)laquonthricrne
mdeno(I23-rt)pvre-ie
pyrene
VOLATU-Ei
bullcrelem
bullcrvlonio-Ue
benzene
caj-bon traquotrraquochloraquo-idr
Ctilorobernene
l2-diehlongtethne
iii-tnctltiorotKraquor Trace 1 T 1 -4)Ctilorampe^hArw
l f 1 ^-tric^i lor oefvtrve
l t l 22-teTrtclloroetl^Ane
ehloroethraquone
2-chloroltthr|viw| ttrve-
Chloroform
1 1 -ltSicMorot^nr
trinraquo-l2-dictiloroetrne
12-d^loropOStn
trinil3^ichloroproone
eis-lJ-diChloroprooene
rrhylberuene Tarce methrlene ehlor tat Trace
Ct1 or o m e t Kirgte
bromometKtrte
bro mod i rfi lor o rrgte t Mne
Uuorotrlchloromethraquo^e
OJ CJ lor od 1 f 1 uoro met hraquone
chJorodibromometKATgte
laquotrlaquociloroethrrx
toluene 9
tricolor otheir
fsw
T9
Sifi-TOSO)
(73B)
(7IB)
(75B)
(7(B)
(77 B)
(71 B)
(71B)
(SOB)
( t lB)
(I2B)
U3B)
(M B)
(7V)
(3V)
(4V)
(4V)
(7V)
(10V)
(11V)
(13V)
(14V)
(13V)
(14V)
(11V)
(23V)
(21V)
(30V)
(32V)
(33V)
(34V)
ltlaquoV)
( raquo J V )
(44 V)
f raquo 7 V )
(UV)
(V)
000 (30V)
Tlfl 151V)
(15V)
^00 (14V)
(17V)
(UVgt
-1 ZINT
CAS 30-32-J
205-11-7
207-01-1
211-01-1
201-14-1
120-12-7
111-24-2
14-73-7
13-01 -laquo
33-70-3
113-31-5
121-00-0
107-07-t
107-13-1
71-43-7
34-23-3
101-W-7
107-04-7
71-35-t
75-3-3
7^-00-5
71-34-5
75-00-3
110-73-1
(7-14-3
73-35-4
154-40-5
71-17-5
10041-07-6
10041-01-05
100-4I-
73-OT-2
74-17-3
74-13-1
73-25-2
75-27-4
73-41-4
75-71-1
174-41-1
127-U- IOUIS-) 71-01- 75-OI-
130
Lab ID Mo 2887-4
Phys i ca l d e s c r i p t i o n of sample C l i en t ID 4A5760
Liquid Sample was predominantlv a hvrlrnrarhnn bl pnd
Sanple workup Voli t i le f ract ion PEG Extraction (SW 846-5030) Scrnivola t ile f rac t ion Sonication Extraction (SW 846-3550) Inorganic f rac t ion Acid Digestion (SW 846-3050)
AC3D CS3U POUNDS 5AipoundNEUTlUgtJ- COMPOUNDS
ri CAS PPraquo CASf
(210 U-04-2 2raquot- tricMorophrnol (7)6) raquo-32-l braquoniolttVyre
[EM 51-50-7 ^-cti 1 or raquo-m-lt rlaquo laquoo 1 (7raquoB) 203-M-2 biMo(b)(luorinth^f
2 A) raquo5-57-J 2- cfiloropheryjl (7 3 B) 20701 benro(ilt) floor in tlaquo^e
(31 A) 120J3-2 2raquo-ltJicWoro(ygtlaquotx)l (74B) 2II-OI- chryve^e
(MA) 105-47- 2l-dimlaquothvloSrrgtol (77 B) 20Uraquot-J bullcwrioMhylene
(57A) u-73-3 2- ruTroohrgtol (TIB) 120-12-7 raquontnncergte
(34 A) 100-02-7 -oitrophenol (7gtB) lraquol-2raquo-2 benio(ghi)cgtrrylngtlaquo
(3Agt 51- 21-3 2 -4 initropherwl (SOB) tt-73-7 fluorme
(tOA) 53-37-l t-dinitro-2-mlaquothy lpNlaquoxil (II B) 15-01-4 pheAinthrrnlaquo
(A) I7-U-5 tgtentraquochlQroiywnol (I2B) 53-70-3 dibenplusmnoltraquoh)fcnthrraquocrne UJJ 101-55-2 rfwtwl (I3B) lraquo3-3raquo-3 indenol 1 23-cd)vrtie
(UB) I2raquo^X3-0 pyrer BASENEUTOAL COMPOUNDS
VOLATO-ES (161 I3-32- raquoclaquonraquophttgtngtf
(5B) 12-17 -J btniidir (2V) gt 07 -07-1 bullcrolem
(IB) 120-17-1 l^^iricfvleroboMux (3V) 107-13-1 bullcrvlonit Jlaquo (raquoBI IIS-7t| SeraquoChlorotgtlaquoterlaquo (raquoV) 7IJ3-7 benient
(I7S) 4772-1 heLCMorolaquothinc (tV) J-23-5 crtgton wtrraquocMoidf (UB) I11-U-I bll(2lttllorolaquot^w gtetNer (7V) 101-W-7 ltAtoroxniergtlaquo
(203) Jl-31-7 2 -etvl or onlaquo ph traquo I en e (IOV) 107-04-2 1 2-ltlicMorolaquoTKlaquone
(25B) raquo5-30-l 1 2-dichlorobenzene ( 1 1 V ) 71-JJ-t llI-trichlorolaquotNlaquoe (2 B) 31-73-1 l3-ltlichoroblaquonzenlaquo (13V) 7J-3A-) 1 1-6 1 cM or Of t (Mr
(77B) I04-M7 I -di CM oro ben z eoe ( I k V ) rraquo-oo-j l12-niichlorolaquotfvirraquolaquo
(2IB) raquol-raquo-l )J-dichlcroblaquorLiidinr (IJV) rgt-3laquo-3 J122-tetrraquochlcrolaquoTrie
(33B) 12I-Ilaquo 2 2-dinia-otoluer (UV) 73-00-3 Ctgtloroltthne U4B) laquoJ-70-7 2 t-dtnitrotoluene (1raquoV) HO-73-1 2-ltJilorocthv|vL-v| etrveshy
(J7B) 127-M7 14-dip^wnylhydraiine (23V) C7-U^-3 Ctilorofcrm
(JraquoBJ 2Ot-ugt-0 CJuarlLnthefe (2raquoV) 7J-33- 11 -ltlicMorcxil^nr
(mei TOCJ-77-3 -chJorophcnyl phenyl laquoKr (xgtvraquo lK-^0-3 tnjM-l^-diC^lofCKtl^nf
( M B I IOI-J5-3 -6romophnyl phenyl ether (32V) 7I-J7-3 12-dicMoroprosaA
(raquo2B) 3M3I32) bU (2-cMarobopropyU rtNer (3JV) ICXU 1-07-4 trraquoni- 1 3-ltjictgtloroBoor^f
(OB) t l l f l - 1 bi5 (2-cMoroetfxgtrv) meihtrw lOOt 1-01-03 cu-O-dichloroprose- (32B) D-U-3 hrxaetilorobutadierw (UV) 100-laquol-raquo rthylbenien 1^00
(33B) 77^7- he i kcMor ocyc 1 openudi crw (UV) 7J-OT-2 rrveThvlerw chlof idf
(36) 7I-gtraquo| oop^troo (raquoJV) 7raquoJ7-3 CtgtlorBmethne
(338) raquo|20-3 nraquopfitfillaquofx 1200 (wv) 7raquo-l3-raquo bromorrgtlaquothne
(34B) nraquo3) nitrobenzene (raquo7V) 73-23-2
(CBI U-Xl-4 N -fl i iro lod iphen yU mi nr (UV) 7J-27- bro mod i cti lor o mT bull- (OR) 42l^-7 N-^itrolaquoodipropylmlrlte (raquoraquoV) 73-traquo-laquo tl uor o tr i cfi lor o mlaquoT itr (UB) I I 7 J I - 7 bn (^thylheraquoy|) phttilaquoUtT 110000 (XIV) 75-71J QJ ct )or oltJ 1 f 1 uoro rrgtei ^bull gte U76) U-U7 blaquonzyl buryl pttTfKUie 12000 ( j i v ) m-i-i ctil or od ib ro mo met h xnf (UB) M-7i2 d i -n -bo TV 1 ft thlaquo U tlaquo (13V) 127-11- te trraquo cfl lor ot hlaquoTgtf (OBI 117-4J-0 dj -n -oc t y1 Jgth fflaquo U re 6 200 tuv) iom-3 tolucie ^70
(7CB) u-u- djrthyl phtJMlire (17V) 7raquo-OI-4 irictilarcraquo^lt-ir (715) 1 3 1 - 1 1 - 5 oVnrrhyl pMtfaUte (UV) 75-OI- v i M v l CMor idr
(T76I 5-55-3 blaquorgtzo( Unihrlaquocme Xylenes 1SOO
Cad- iurn 2 2 on Chromium - - Z I N C ^ ~ P r
Ai results arc expressed as ugc weight as received Xo entry denotes not detects
Lab ID No 2887-3 5A 57709 Phys ica l d e s c r i p t i o n of sample Cl ien t ID
LiquidSludge Liquid appeared to be a hvdrnc-Arhnn blonrl
Sample workup
Vol i t i l e f r ac t ion Methanol Extraction fSW 846-5030^ Semivolatile fract ion Sonicatlon Extraction fSW 84 f i_3550gt) Inorganic f rac t ion Acid nic-psr-inn fSW 846-30501
ACS3 COMPOUNDS BASENEUTRAL COMPOUNDS
f f t CAS CAS (2IA) tt-04-2 (738) JO-32-J DCftZ OTamp p V^^^ff
(22 A) 3laquo9-50-7 p-cttl or o-m-cre laquoo 1 (7VB) 205-99-2 p^^izot oil lyor 4-^ t ^ltf ^^
(2 A) raquo5-37-l 2- CJiloroprieno (75B) 207-01-9 blaquonioltllt)flultxtn^it
(31A) 120-13-2 2raquo-dictgtlcr8tgtrfX)l (74B) 211-01-9 Chryeolaquo
(3 A) 103-47-9 2 -d irrgtet hv Ipherto1 (77B) 201-94-1 laquocnphthyle^
(37 A) 11-73-5 2- rutrop^enol (7IB) 120-12-7 bull^thrjc c^
(MA) 100-02-7 -flitroprlaquorv3l (79B) 91-2-2 bcnroltKhi)pefraquoler
(79A) 31-21-3 2 -d in itr eoricno 1 (IOB) 14-73-7 tluoren
(40 A) 33-37-l 4-d in itr raquo-2 -met hy Iphtnol ( I IB) 13-01-1 poltrtAOthrvTgt^
(44 A) 17-14-3 plaquon1 CM or o^eno I (I2B) 33-70-3 dib^fi-o( 4(K)Aji thirl c c^f (43A) 101-93-7 prwnol (S3B) 193-39-3 indcnotlIJ-ctflsvfie
(SB) 129-00-0 pyrene ftASENEUTRAL COMPOUNDS
( I D )
(5B) 92-X7-3 b^zidrw (2V) 107-02-1 bullcrolrm
(IB) 120-17-1 1 2 fc-Tr ICJ caro blaquoni crw (3V) 107-13-1 bullcrvlonitrij
(93) 1IU7I1 Seraquochlcrotgttniegtlaquo (4V) 71J3-2 blaquonienlaquo inn (17B) 4777-1 hexat^lorcwthgine (4V) H-23-5 carbon ttTricllixidf
( I I B ) 111-wJ bll(2-lt3^1oroltt^w)ether (7V) 101-90-7 ciloroblaquonzene
(20B) 91-31-7 2-ctdo-ont she Ime (10V) 107-04-2 12-dieftloroerane (25B) 95-50-1 l2-dilorobenzene ( 1 1 V ) 71-35-4 11 1 -tricMorotn-laquo
(2ampSI 51-73-1 13-dicMo-obenxerw (13V) 73-3-3 1 1 -d i CM orcxt M-
(77 B) I04-H-7 1 -di ci 1 or o benI erw (UV) 79-00-3 llJ-WiChlorolaquoflaquonlaquo
(2J6) 91-90-1 SS-dKJilorotxniidinc (13V) rraquo-3laquo-3 l122-tetrlaquocftlorelaquoTrne
(35B) 12| |k-2 2fc-dintrotoluene (14V) 73-00-3 diloroeth^e
(gt4B1 404-20-2 24-diniTrotoluenlaquo (19V) 110-73-1 2-cMortxfthv|vL-raquo trlaquoshy
(37B) 122-447 12-diphenylhydriin (23V) 47-44-3 cMoroform
(J9B) 204-U-0 Ouormntherve (29V) 73-33-i ll-diCMorolaquot^nf
(fcOB) 7005-77-3 k-cMarophfy| prlaquonyl etScr (gtOV) 134-40-3 trraquonraquo- 1 2 -dicMoroc t Nenf
(raquo I6) 101-35) raquo-6romoprny| phenyl rther (32V) 71-17-3 12-diChloropostn
(raquo2B) JH3IO2-9 bU (2-ltplusmnlaronopropyl) rthrr (J3V) 10041-02-4 trni-l)-diirMoroxtgtOpnf
(OB) I I 1 - 9 I - I bu (Z-chloroethxjrv) metSampnlaquo 10041-01-05 CU-D-djcMoroproOf-W
(32B) 17 -U -3 hiraquocfilarobutraquodiergtlt (3JV) 100-4U rttyligtlaquonitrgtlaquo 5300 (33B) 77-raquo7-raquo hrxicftl or ocrclopei tidier (UV) 75-09-2 nxthylenf ctilor ifif
lt3B) 71-391 ao prior or (raquo3V) 7raquo-17-3 rtloromrtha^r
(356) 91-20-3 nlaquoprithienraquo Trace (44V) 7raquo1Jraquo bromltmlaquoth^
(MB) n-93) ft i vo b^nz c^^ (raquo7V) 73-23-2
(425) U-30-4 ^bullf i^OftOOL^ri^ny lArrunf (UV) 73-27- bro mod i cgt lor o i~ t gt
U3amp1 Ul-4-7 N i itr CrtoO ip ro py 1 laquo ml r (raquo9V) 73-49-k U uor o IT 1 et loront Mrgt (UB) II7-1I-7 bu (2-Ihythlaquoryl)prtfUtr 59J300 (30V) 73-71-1 dj ci kr olt11 f 1 uoro rrrt (Nrgtraquo
(47 B) L3-41-7 txniyl burvl phthlaquoUtr ( 3 1 V ) I2-1-1 ch1 or od i b ro mo mi IMP r
(UBI U-71- 0-A-fcurl BMMliw (13V) 127-ll-i rt tr t cM or of tNr
Uraquo6) 117-li-O di-n-oCTv| pnttlaquoUfr 6000 (UV) lOt-II-3 toluenf 5700 (7CB) U-447 djrthvl p^tfvilirt (17V) 79-01-4 WiCMoroth^e ( 7 J B I U l - l l - 3 d^M^vl prttgtraquoUW (UV) 73-01- vinv t cMor 10 (77 Bgt H-35-) brto(raquollaquonthncrTraquo Xylenes 19000
Caen 1U~ 1 Chromium =2 Z I N C
All results are expressed as up g weight as received No errrv ripn^t-plt
Lab 1Lgt No 2887-5
rhyr i r n l d e s c r i p t i o n o f sample C l i e n t in 6857710
LiquidSludge
Sample workup Vol i t i l e f r a c t i o n PEG Extraction (SW 846-5030) Semivolat i le fr action Sonication Extraction (SW 846-3550) Inorganic f rac t ionAcid Digestion (SW 846-3030)
AOD COMPOUNDS BAStNELTTRAL COMPOUNDS
rr i CASI CAS (21 A) tt-04-7 (736) 30-32-1 bntoltraquogtprrene
(23A) 3-9-50-7 p~lt1 or o-m-c rraquo1 (78) 205-99-2 ben to( Sgt )1 1 uor raquon I he-gtf
(7raquoA) 93-37J 2- etilorophenol (73B) 207-01-9 beriioltk)(luortntrgt^f
(3 IA) 170J3-2 2raquo-dicMoroprnol (7(B) 2II-OI-9 eifVMTie
(3 A) 03-(7-9 24-4mlaquoThvlDheno| (77B) 20l-9(-i bullceraoMhyler
(37 A) tt-73-5 2- rue-oorienol (718) 1 20- 2-7 laquoflthrraquocene
(3 A) IOO-02-7 ^Mtroprwnol (7fB) 191-24-2 beraquoMoltsrM)plaquovllaquox
(39 A) 3I-71-5 2-4 ini tr ophero1 (tOamp) K-7J-7 tluwtrie
((OA) 33-37l (-lt iMtro-2-methylphenol (tlB) D-01-J phenATithrene
(4A) I7-44-J pentichlorophenol (128) J3-70-3 dilwnioltraquoh)laquonthrraquoceif
(OA) IOI-95-2 prwnol U38) 193-39-3 indeno(123-cd)vcne
(MB) 129-00-0 pyrergtlaquo 6 ASENEUTILW- COMPOUNDS
VOLATH-tS ( I B ) 13-32-9 ftCYTNA pO IT H I raquolt
(38) 92-17- o^nzioinc (7V) 107-02-1 aero le in
( IB) 120-I2-I l2k-o-i(3iloroblaquontergtlaquo (3V) 107-13-1 laquocrvlono-U
OB) Jl l-7fc | he I raquocti 1 or o blaquonI enlaquo (V) 71-43-2 Oltf2 tO^
(17B) (772-I he uc^i 1 or of t h ne ((V) 34-23-3 CJU JOO Tt TTlCfllo^ iCpound
( I I S ) bu(2-rfilcroethv|)ether (7V) 10J-90-7 laquoWoroblaquonzeoe III-44-4
(KB) 9I-51-7 2ltfMoronlaquoohttvraquolwe (10V) 107^)4-2 1 t2^ojo^loroetfft^c (2JB) 95-50-I 1 2 -dichlorotgtlaquorlene (11V) 71-55-4 1 1 1 -trichloroeihtr (251 541-73-I 13-dchlorotxniene (13V) 73-J4-3 1 1 -dieMoreeraquohraquorlaquo
(77Bgt 04-lgt4-7 1 mdash djcMorobenlene (IkV) 79-OO-3 t12-tricriloroeflaquofgte (2gtB) raquolraquo-l 33-didMoroblaquonjidirlaquo (13V) 79-34-3 1122-tetrcnicroeir^ne (33B) 12 I I 4 -2 Z4-diniiroioluerlte (1(Vgt 73-00-3 e^loroetruuie (KB) (04-7C2 2 (-dinitro toluene (19V) 110-73-4 2ltJilorolaquotr(v|vLnraquolnhlaquo (175) 122-447 12-dipr-enylfiydrmiine (23V) (7-44-3 chloroform
(J1B) 704JJ-O Huor^thrr (29V) 73-33-4 lI-ltJicMoroltthcne
(OBgt 7003-77-3 -ctJoroprienvl phenyl ether (JOV) 134-40-3 irirraquo-12-dictila-olaquotrlaquone
( raquo I B ) IOJ 33-3 -6ogtmoprienyl phenyl ether (32V) 7I-I7-3 l7^lichlorepreoine (laquo2BI 3H3raquoO2raquo bit (2-chlororaquoopfT5pyO ether (3JV) 10041-02-4 trint-l3-ltJicnloroBlt-ooee (OB) 111-11-1 bis (2-cMcroetro(v) metSuvr 100(1-01-03 CU-lJ-itflloropOO-^
(376) t7-U-3 hraquoz raquoch1 or o bu tlaquodi ene (J1V) )00-1- erhylberuer 1400 (33B) 77 -gt7- hei tchl or ocyc1 open traquodi ene (raquoV) 73-09-2 methylene chloriCf OB) 7raquo-3raquo-l BO prior one (raquo3V) 74J7-J eMorametrutne (33B) raquol-raquo-3 naphtfalene 100 (UV) 74-13-9 bro rrvome t hrgt (3iB) n-raquo3-3 niireblaquor)iergte (raquo7V) 7J23-2 (CB) U-XH N -01 ITo tod 4gthenyU rru rr (UV) 75-27-4 bro mod i ch lor o rrx t f4Ugt ((36) 42IO4-7 N-nnroodipropYlraquomlrlaquo (raquolaquoV) 73-4t-4 JJuorotr lchloronvlaquoiMftlaquo (Uol U7-1I-7 ba (2-etrylNraquoYl) phtt^Ure 100000 (30V) 75-71 -raquo dj cftlcr od U 1 vraquooro rri NUT
(47 Bl 13-44-7 t^niyl butvl phthiUte 13000 (31V) 124-41-1 chlorodibromorrwt^r
lt U E gt ) U-71-2 d-ojjurvl phtf^Ure (13V) 127-11-4 tr trbullcti loro rirr
laquoraquo6gt 11704-0 dl-fl-OCTvl pfltMUM (UV) 10t-ll-3 toluene fiin (TtS) raquo-laquo djrthvl phttuliTr (17V) 79-01-4 tricolor oethenr lt 7 | o l 131 -11 -1 (UV) v i n v i chlcwidr dimrlKyl rrftlaquoUTraquo 75-OI-J
(T75I J4-35-J blaquoTMOlt^trrlaquocr^ gtylenes 1200
Cadr ium 3 Chromium 21 ZINC 150
All results are expressed as ugg weight as received y0 entry denotes not detect
Iah I D No 2887-2
Physical descr ip t ion of sample
Strained Soil
Sample workup
Voli t i le f rac t ion PFG Extraction (^W 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-3540) Inorganic fract ion Acid Digestion (SW 846-3050)
ACS) COMPOUNDS
rn CAS Tft CASf
(21 A) tt-04-2 (73B) 50-32-4
U2A) 71-50-7 P-ch 1 or o-m-cre laquoo 1 (7k 8) 205-11-2
(2 A) raquo3-37-l 2- chloroprraquoeno| (75B) 207-01-1
(3IA) 120-13-2 2raquo-4ichlorophenol (74B) 21UOI-1
(3 A) 103-47-1 24-dimethvlphenol (77 B) 201-14-1
(57A) U-75-3 2- njtroDhenol C7I5) 120-12-7
(MA) 100-02-7 a-flitrophenol (71B) |1l-2raquo-2
(51A) 51-21-5 2 -d in i tr o phetio 1 (SOB) K-73-7
(40 A) 53-57-l raquo 4-dinitro-2-methy lprnol (tlB) 15-01-1
(4 A) 17-14-3 plaquoitraquochloroorlaquonol (I2B) 53-70-3
(43A) IOt-13-2 prlaquonol (13B) m-31-3 (MB) 121-00-0
BJ KSENCLmLAL COMPOUNDS
(IB)
(3B) 12-17-3 bcnzidine (2V) 107-07-1
(IB) 120-17-1 1 2 k- tr i ch 1 oro benr ene (3V) 107-13-1
(IB) I1U7I-1 he it raquocM or o boiz ergte (raquoV) 7I-J3-7
(12B) 47-77-1 he traquoch 1 or oet hlaquo ne (4V) 54-23-3
(116) 111-- buC-cJiloroethv|gtether (7V) 101- W-7
(20B) 11-31-7 2 -ltft 1 or on ph ttvraquo 1 laquon e (10V1 107-04-2
(23B) 15-30-1 1 2 -dictilorobeni ene (11V) 71-55-4
(25) VI-73-1 1 3 -ltJ i ci 1 or o blaquoiz ene (13V) 73-3-3
(77 B) 104-M7 llaquo-dchloroblaquoMeoe (HV) n-00-3
(2IB) 11-lk-l 33-dicMorotxTLtidinr (15V) n-3raquo-3 (33B) 12I-U-2 2 ltgt -4 in i tr ot o luene (14V) 75-00-3
(MB) 464-20-2 2 4-d initrotoluene (11V) 1 10-7 3-1
(J7B) 122-447 1 2-diprieny Ihydrti ine (23V) 47-44-3
(316) 2O4-UO Ouorraquonthene (21V) 73-33Jshy
(WB) 7t)03-77-3 ^-cJJorophenyl prienyl ether (JXgtV) 154-40-3
(MB) 101-33-3 -6romopriefgtyl prienyl ether (32V) 71-J7-3
(raquo2B) 3431-32-1 bit (2-chloroboproprO ether (33V) 10041-07-4
(OB) I1U1I- I bu (2-ltMoroethorv) methane 10041-01-03
(52B) r-u-3 hexachlorobutadiene (J1V) 100-l-raquo
(33B) 77-47- he z raquoctlt lor ocycloqenud i crte (MV) 75-01-2
OB) 71-31-1 ao prior one (raquo3V) 7raquo-17-3
(33B) 11-20-3 nlaquopntrlaquollaquone (UV) 7raquo-13-1
(MB) n-13-3 nitrobenzene (raquo7V) 73-23-2
(UB) U-30-4 N-nnroiodiprienyUmine (UV) 75-27-k
(436) Ol-U-7 N-nitrModiproOYlmJne (raquo1V) 73-41-
(UB) 117-117 bu (2-laquothylheiry) phtrlaquolte 8800 (50V) 75-71-1
( 4 7 B ) L3-U7 blaquoniyl buryl phthaUte 30 (31V) 12I-H-1
(UB) U-7U-2 di-o-burvl phtrMUte U3V) I27-I1-
(416) II7-U-0 dj-n-oCTvl pritntUtr 1200 (raquo4V) IOUI1-3
17CB) U-44-2 djetiTi phrtultrt (raquo7V) 71-01-4
( 7 I B I 1 3 1 - 1 1 - 3 dimnfTraquo| prThraquoUtr (UV) 73-01-
(776) H-35-3 berMolta^thrCF^
Cl ien t ID 8 A - S 7 4 6 1
RASENEUTRAL COMPOUNDS
benzofbtfluor^tMe
benzodclfluorintoent
Ctiryiene
cenoithylene
raquonthrraquoctne
benzoltKhilpervlefgte
floor ene
prlaquofnnthrene
ltlibenplusmno(4h)knthricrnlaquo
inogtno(123-rt)pvrrne
pyrene
VCX-ATIIE5
bullcrolem
bullcrvlomn-U
benzene
carbon tetrtchloridf
chlorobenzene
1 2-oUchloroethAnf
lll-trichloroethlaquone
ll-dcfioroethrraquo
1 1 2-tricilorolaquothraquorw
1122-tetrichloroeTtvin
chloroethre
J-ctiloroethv|vinv| etrgte
chloroform
11 -denier oethene
trinraquo- 1 2 -4 cMor oe t hens
12-dcMoroprooine
^Lns~ I f 3-4ic^ lo^opf oo^^^
Cli-l 3-dicMoroprooe^e
rttiylbenzene
methylene cnlonfle
Ch 1 or o me t hane
bromome thane
Trace
bro mod i cMor 0 me t hane
(Juorotrlchlorome thane
chlorodibromometKinf
tetracnloroethervp
toluenetr icMoroel he-if
Trace
CacTiiun Chromium ZINC f
All resxil ts are exprp^spr i K-i
Phys ica l de sc r ip t ion of sample
Strained Soil
Sample workup Vol i t i le f ract ion PEG Extraction (SU 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-5340) Inorganic fract ion Acid Digestion CSV 846-3050)
ACE) C30laquo POUNDS
m CA5i CASraquo (2i A tt-C-2 (73B) JO- 52-1
(22 A) J1-JO-7 p-ch 1 or raquowTv-cre 101 (7raquoB) 203-raquoraquo2
(2 A) raquo)57-J 2- chlorophenol (73B) 20701-
(31 A) I25J3-2 2k-4icttlltroptlaquonol (7tB) 211-01-1
(3A) IO)-7-raquo 2-dimlaquothvlpNrnol (77 B) 20l-raquoi-
(37 A) u-rj-j 7- niTTOphenol (TIB) 120-11-7
(MA) 100-02-7 -rtropN-rraquol (7raquoB) lraquol-2-2
(JraquoA) JI-21-) 2-d initroprietys 1 (IOB) U-73-7
(MA) 53-37-l Udinnro-2-mlaquothylphenol (UB) I5-OI-J
(Agt I7-U-3 pentichlcropwnol (126) 33-70-3
laquo)Agt 10l-raquo)-2 phenol (I3B) IJ3-31-3
(MB) 12raquo-00-0 AASCVflCUTRAl COMPOUNDS
( I B ) I3-32- bullcnraquophtber
(56) raquo2-17) bnzidirlaquo (2Vgt 107-02-1
(IB) 120-12-1 l2btrilt7tlorotgteizegtlaquo (3V) 107-13-1
traquoB) IIraquo-7fc | heikcMeroblaquonzergte (V) 7l-3-2
( I 2 B ) 4772-1 he ueft 1 or olaquot hraquo rgte (tV) laquo-23-3
( i ts) III-- biraquo(2-cMoroethv Dethrr (7V) 101-W-7
(20Bgt 1I-3I-7 2-cMoroflaquophthlene (10V) 107-Ofc-2
(2)6) raquo5-50-l l2-dchlorotgtlaquonzefgte (11V) 71-33-4
(28) 3l-7)-| 1 3-didMoroblaquonrenlaquo (13V) 73-3-3
(27B) 10t--7 l-diclorolgtmzerlaquo (iV) rraquo-00)
(216) raquoI raquoltbull- 33-dichloroblaquoMidiflaquo (13V) 79-31-
(356gt 2I- l-2 21-dinitrotoloen (UV1 73-00-3
(UB) laquogt- 20-2 2 (-dinitroto luenlaquo (HV) 110-7J-J
(376) 122-W-7 14 -dipheny Ihydrzire (23V) lt7-M-3
(396) 2O--0 tJuoruMSene (2raquoV) 7J-35- (OB) 7003-77-3 -c^lvophenyl pNrnyl ethlaquor (30V) 1H-W-)
(MB) 101-33-3 bull-bromopriefiyl prienyl ether (32V) 7t-t7-3
ltraquo25) 3HJI-32-1 bU (2-cMoroaopropyl) rthrr (33V1 10ltX 1-02 -6
(06) l l t - t l - l bis (2-cftloroetSorv) metwne 100lt]-01-03
(32B) C7U-3 heraquoraquochlorobutidierx (31V) 1 00-41-
(3361 77-7-raquo hexiOilorocycloptfiudlerve (raquoV) 73-0raquo-2
(56) 71-51-1 no ph or one (raquo3V) 7raquo-17-3
(3)6) raquol-raquo-3 rwiphtfalme (UV) 7raquoJ3-raquo
1361
LUB)
H-133
14-30-4
nitrobenzene
^ ri i iy o too ipf^^ y LA r^i rtf ^ 7V) (UV)
73-23-2
73-27-
(436) t21--7 M^TI iff frfcO^ip ropy Ift mJf^ (gtraquoV) 73-4raquo-raquo (UB) I17J1-7 bu (2-rThyiruMcyDpMtvUtr 570 (jov) 73-71-1 ( U B ) U-41-7 blaquonzyl buryl phthlaquoLite (31V) l2k-raquo-l ( U B I U-7I-2 di-n-burvl pitftALtTe (raquo)V) 127-lt-fc
(OB) 117- -0 dJ-fraquo-oCTvl phlJ^Ute (UV) IOt-It-3
(7CB) 14 -W- 2 djelftvl phtfalitt (17V) Tt-01- ( 7 I B I 1 J I - I 1 - ) duTNnhylphttsraquoUw ltUV) 75-01-
(77BI X-))O lgtmrlaquoigtmhrraquoctf
Cadmium f iQ Chromium 15 ZINC
Tab ID No oo -
Cl ient ID 8A-A-64220
fcASENEUTTRAL COMPOUNDi
blaquofuo(raquo)pyrrtgte
bfizo(b)(loortAth^e
benzo(k)f|ulaquoin1herf
Ctiryiene
cenDraquoMrwlene
fcftT^rict^t
D^flZCT (fftl)pC^ V Itf^p
(luorene
phen^threne
diiwnztKthlanthricene
indlaquono( 1 23-lttf)pvrene
oyrene
VOCATtLES
bullcrolem
bullcrvlooitriJe
bervteoe
carbon WTTicMoridf
chlorobenze^e
12-djcMoroetfane
1 1 1 -tricolor ex tKraquon
1 1 -dicMarcx t hrlaquo
1 1 2-triChlorothraquorw
1 122 -laquotrraquocM or o-hraquorgt
cMoroettu^e
2-cMorlaquothv|vuy| rseshy
chlexeform
ll-dchloroctfgtn
tri^iraquo l 2laquoflic^ loTo^i rgtcnt
12-dicWoroproptrs
Winl-l3-dicMoropfooene
Cu-lJ-djChleroprooe^
rrtiylfrenzene
methylene ctiloride 0 64
cMorometHAne
bromomlaquothlaquone
bnsmoform
bro mod i eti lor e me t Nine
0 uor o tr 1 cMor e rrgtlaquo t Nnlaquo
dj di tor olaquol If 1 uoro mraquoi Nrraquo
chlorodibromonveiKme
re tr a en 1 or or fxrvr
toluene
D-ieWoroefwne
entry denotes not detect All results are expressed as ugg weight as received Xo
Lab 1) No 2887-8
Physical descr ipt ion of sample
Sf-rs inpH 9 n i l
Sample workup
Vol iCi le f ract ion PEG Extraction (SW 846-5030)
Scmivolat i le f ract ion Soxhlet Extraction (SW 846-3540) Inorganic fraction Acid Digestion (SW 846-3050)
ACD O3MPOUNDS
m CAS fPraquo CASf pi A) tt-Ot-2 Zraquot- tritilorophrgtol (73B) 30-32-1
ft M -3o-7 p-cMorraquo-m-crTraquool (7kB) 205-raquo-2
(2 A) raquoS-37-l 2- cMorop^erxgtl J73B) 207-OI-raquo
(31 A) 120-13-2 l^ictiloropix)l ^7tB) JII-01-
(3 A) |03-7-raquo 21^-dimeThvlphenol (77B) 20t-raquot-l
(J7A) tl-73-3 2- rutropwnol (71 B) 120-12-7
(MA) 100-02-7 -MO-opwnol lt7raquoB) lraquol-2-2
fJraquoA) 3I-2J-3 2-dinitrop^laquoTgtoI ((OB) U-7J7
(laquogtA) J34-37-1 lt-dinitrfr-2-methylpwrxgtl (I IB) I 3-0 1-1 (raquoAI 17-1 3 pcmacMcroptonol (S2B) J3-70-J UJA) IOI-raquo5-2 phenol (IJB) MJ-39-J
(tBgt 12raquo-00-0 RASEfZUTRAL COMPOUNDS
( IB) 13-32-f raquocertaprithene
(3B) J2-17-3 twnndinc (2V) 107J2-J (IB) 170-I2- lr2k-triOilorobenzerlaquo (3V) 107-13-1 (raquoB) I11-7I-I hei bulllt1 ore blaquont ergtlaquo (raquoV) 7l-3-2 (1B) 47-72-I he ucft 1 or oe t h n (tV) 3-23-3 (116) |II_wJ bu(2-ctiIarothvI)laquotNer (7V) 101-90-7
(20B) raquoI-JI7 2 -cW or orvraquo ph tf I ene (10V) I07-Ofc-2 (23B) J3-30-I l2-lt5ictiloroblaquonzeoe (11V) 71-3J- (245) 3I-7J-I 13-dic^lorotxenzenc (13V) 7J-3-3 (27B) 104-K-7 1 mdash diC^lorobtnrerve ( lraquoV) 7^-OO-5 (21 B) raquo|raquo| 33^icftlorobenzidifv (I3V) rgt-j-3 (33B) I 2 I - U - 2 2ltgt-dinin-o1olvraquorgte (UV1 75-00-3
(J4B) 404-JO-2 21-dinitrotoluerve (1raquoV) 110-73-1
(37B) I22-W7 1 2 -d ipheny Ihydra z ine (23V) C7-14-3
(318) 2O4-W-0 tJuortnihrne lt29V) 75-3J- (kOBt 700J-77-J ^-tfMoropheTgtyl p^enyl ether (30V) 1J4-W-3
( raquo I B ) IOI03-J raquo-6romopfgtenyl phenyl ether (32V) 7I-I7-J
(06) 3H3raquo-)2-raquo bU (2-tfilerobopropyO ether (3)V) 10041-02-i
(OB) lll|| bii (2-cMoroethoxv) methane 10041-01-03
(37B) PUt) hxzraquocMorobutadienlaquo (J1V) 100-raquol-raquo
(JJB) T7^7U heztctilarocrclotMnttdicrgte (V) 7gt-0raquo-2 OB) 7l-3raquo-l BO ph or one (raquo3V) 7raquo-17-J
(338) raquo|20-3 rlaquopritrilaquolene (UV) raquo-laquo-raquo
(3iBl n-raquo3) nitrobenzene (raquo7V) 75-23-2
(CB) li-X)-t N -n i tr o tod ipheny U mi nr (UV) 73-27-fc
(06) CI-U7 N^iitroiodipropYUmlr ^raquo1V) 73-H-fc (UB) 117JI-7 bu (2-ethYlNerrl)pM^Utr 12000 (JOV) 75-71-1 (47 B) L3-U7 llaquoniyl buryl pht^UTe 2 800 ( 3 I V ) 2laquo-raquo-I (UB) raquo-7i2 di-o-ourvl pritfwiUrr (I3V) 127-lt-i (196) 117-14 3 dj-n-ocryl pritfiiUrr (UV) IOUIS-3
(TCB) J4-W-2 djnhYl phtfalitt (17V) 7t-01-lt (716 ) 1 3 1 - 1 1 ) damnhYl pMtuUTT (UV) 73-01- (77 Bl 3 33-3 frlaquon z olt raquo klaquom h rraquo c prgte
Cadmium T^ Chromiurn T Z T N C 100
Client ID 8A-C64221
BASENEUTRAL COtPOUNOS
bnzo(t)pyrrrie
benzobXluoriflthei blaquorizoltVHluorraquontrraquone
chryiene
bullcenphthylene
tnthneene
benzoltRM)perylene
fluorene
prienlaquonthcTTgte ditgtmplusmnolt4hluithrraquoctnf
indenof 1 23-cd)pvrf ne
pyrer
VOUATILES
bullcrolein raquocrvlonnrile benzene cmrbort Tetrichloride
chlorobenieoe 1 2-oUchloroethirie
11 1 -tricolor oethne ll-dvchlorolaquollMr 1 1 2-w icMoroethAoe l122-tetrieMoroeihilaquonlaquo
chloroetKvne JltJilorothvlvmv| ethe chloroform
11-dicMoroethent
trani- 1 2 -dicti lorolt t hene
1 J^JictiloroproBfVf
trim- 1 3-4ietiloroproperie
Cil-IJ-dicMoropfoOerie
rrhyUxrmene
methylene criloride
chlorornethine
bromome thne
007
13
tluorotr l^VoromlaquotNraquorgtt
da ch lor od 1 1 1 ooro frvet hraquone
chlorodibromometlvinf
te trraquocnloroeT rrrr
tricMoroetSmr
All results are expressed as us2 weight as receixred No entrv denotes not detect i
Phys ica l descr ip t ion of sample
SoilCake
Sample workup
vol i t i le fract ion ^FP FvfrarfMnn (ltU Rif i mdash Smrn
Semivolatile fraction Soxhlet Extraction (SW 846-3540^ Inorganic fraction Acid Digestion (SW 846-1050)
AC23 COMPOUNDS
rrt CAS CAS
(21 A) 11-04-2 2raquo4- trieMorophenol (738) 50mdash 3-4
122 A) J1-30-7 p-ctil or raquo-nvltrlaquo laquoo 1 (7laquoB) 205-11-2
12 A) 13-37-4 2- etilorophenol (75B) 207-01-1
(31 A) 120-13-2 2raquo-diclorophlaquoTgtol (74B) 211-01-1
(34A) 103-471 24-dmlaquothylphrnol (77 B) 201-14-4
(57 A) U-73-3 2- rutrop^nol (7raquoB) 120-12-7
(54 A) 100 -02-7 bull i tro p^c 01 (71B) 111-24-2
(J9M 31213 Z o trt i tr o poc^oI (MB) U-73-7
(40 A) 334-32-1 T^Hjinitrfr2^rt^T ny tp^gt^noi ( t lB) 13^)1-4
(44A) 17-44-3 pcnttchlaroprwnol (S2B) 33-70-3ltOA) IOt-IJ-2 pTUfNOl (136) 113-31-3
ftASENtUTRAL COMPOUNDS (MB) 121-00-0
(IB)
(56) 12-473 Iwnndine (2V) 107-02-1(IB) I20-IJ-I 1 2 4-tr icJi lorobeniervr (3V) 107-13-1(IB) 11 1-711 hexkcMarobcnzeM (4V) 71-43-2(126) 47-72-1 hexch)eroeihlaquone (4V) 54-23-J( I I S ) 111-4- bu(2-eMorlaquothv|)laquothr (7V) 101-10-7
(208) 11-51-7 2-c^laronraquophtfgtlene (IOV) 107-04-2(23B) 1J-30-I 1 2-dichloroblaquonime (11V) 71-35-4(2651 341-73-1 gt3-ltiictitaroblaquonxcnc (13V) 73-54-3
(27 B) 104-47 l4-dicMorotKmrerlaquo (14V) 71-OO-3
(21 Bgt 11-14) 33-4ichlaroblaquon2idine (15V) 71-34-3
(338) 121-14-2 24-dinitrotoluene (14V1 73-OO-3(J4Bgt 4O4-20-2 24-dinitretoluenc (11V) 110-73-4(37B) 122-447 lraquo2-dip^nylhydrraquoxirlaquo (23V) 47-44-)(MB) ro--0 Uuaranthene (21V) 73-33-4(406) 7003-72-3 4-ltUorepfraquonyl phenvl rtSer (30V) IH-40-J( raquo I 6 ) 101-333 4-6romoprlaquonyl pflaquony| ether (32V) 71-17-3
(OB) 3H3I-J21 bll (2-cti|orobopfrgtpyO ether (33V) 10041-02-4
(OB) I11-1I-I bis (2-cMaroethoxv) methane 10041-0103
(57B) P-44-) hczw^lorobundiene (J4V) 100-41-4
(JJ6I 77-47-4 htTicMarocyclojxrtadien (44 V) 75-01-2
(346) 71-31-1 aophoroo ( raquo ) V ) 74-47-3
(33B) raquo|203 r^pn thA Icr^ (44V) 7 -raquobull J-
(546) n-i3) H i frovCftZfl^^ (raquo7V) 73-23-2
142B) 14-30-4 S -n i tr o laquood ipheny Lt mi nc (44V) 73-27-4
(43 B) 421-447 N^iitrotodtpropyUmlne (41V) 73-41-4(MB) 117-41-7 bu (2-raquoThylhlaquolaquoyl)pMtgtlaquoUtr 52000 (30V) 73-71-4(4B ) 13-447 (xniyl bviryl ptithiUre 6700 (3 lV) 12raquo-l-l(UB) 147U- di-n-burvl pMhUre (I3V) 127-11-4laquoampgt 117-4J-0 ltjj-n-octyl phtfaUtr (UV) 101-11-)
(7CB) U-44-2 djrthyl pht)raquolraquort ( I7V) 71-01-4( 7 I B I 131-11 ) dimrthyl phttgtUTe (UV) 73-01-
(T76) H-33O tgtnzoUtlaquoftthncmr
Cadmium l i r^ Chromiurn 2 0 ZINC 140
All results are expressed as ugg weight as received
Lab ID No 2887-6
Cl ien t I D 8AD64219
Dd20( amp py(re
blaquonio(bHluorraquoflthegtlaquo
berzo(Mf luorampnThene
chryraquoefgte
ftctnAoMhy(ergte
raquonthncene
benioltK(M)plaquovlene
(Juorene
picnintfirtTX
dihwvioltraquoh)laquonThrraquocene
mdeno(l23-rt)pvrraquone
pyrene
raquocrolein
raquocrvloourUf
benzene
carbon laquoTrraquochlofifle
chlorobenieo
l24JcMarolaquotlxine
lll-trichlcroltthlaquorlaquo
-ltJicMorigtnKraquorgtlaquo
l12-trichlorolaquot^nlt
1 1 22-tetrcftloroetrvtnlaquo
^tloroeThAne
2^^1orolaquothvlvuiivt ethe
etila-oform
ll^liailoroltN^
trtni-12-dichlcxolaquoTfgtene
12-ditfiloropropine
trtni-l3-ltjicti|orocltX)t^f
cu-l3-djcMoroprooe^f
rttiylbtnztTve
methvlene cWoride
ciloromnM^f
Dco^^oroct^A^^
bromofarm
bromodicJiloromltlfraquon
tluorotrlctiloromttNir
diOilorodKloororfvrir^Ar
ct^lorodraquobrofTorrgttKAne
wtricnlorampctNrr
toluene
trirfilorolaquoThfif
v i n v CMor ilt3^
No-entry denotes not detect
ih i n N O 2887-9
Phys ica l d-asc r ip t ion of sample Cl ient ID 10A64222
Linnir l ShtHcp
Sample workup Volitile f rac t ion PEG Extraction (SW 846-^030^ Semivolatile fract ion Sonication Extraction (SW 846-3-540 Inorganic f ract ion Acid Digestion (SW 846-3050)
AOD COM POUNDS BAStNELTTRAL CXLPCXJNDS
rrt CAS CAS
(21 AJ U-Ot-7 Z4- trichloropSeno (73B) 30-J2-
(22 A) 55-30-7 p-ctilarraquo-m-erelaquoo1 (7kB) 205-raquoraquo-2 ben r olt b) 1 uor ifl t Ne~gtf
(2AJ raquo3-37-i 2- ctilorophenol (75B) 207-0raquoraquo benzoltllt)floofraquontslaquor
(31A) 120-13-2 2raquo-ltJictilcroooenol (76) 211-01 9 ctiryjene
(3A) I03-47- 2k-dimethylphenol (77 B) 20t-raquo4-i bullceruphthv lerraquoe
(37A) U-73-3 Zmdash Ajtropheooi (7SB) 120-12-7 fcntftricene
(34 A) 100-02-7 w^ i ff o phe rgto 1 (7raquoB) Iraquol-2-2 ben z o( Rh i )per v 1 me
(31A1 51-21-3 Z^ - d iA iV opheno1 (SOB) U-7J-7 Iluorene
(MA) 3X-37-I T v-4iAiv omdash laquo mdash fl^et ny Ipoenoi (I1B) 13-01-1 poeftraquonthrene
(4 Al 17-14-5 p^ntBCfllGrOprlC 1 Vol |I2B) 33-70-3 dilgtenioltraquoh)laquontwraquocenr
USA) IOl-raquo5-2 phenol (13fi) U3-31-3 indeno(l73-cd)oraquorrie
(MB) I2raquo-OO-0 pyrene RASENCimiAL COMPOUNDS
VCH-ATUL5 ( I B ) 13-32- raquoclaquonraquophtflaquorgte
(58) 12-I7-J benzidire (2V) 107-02-1 bullcrolem
(IB) 120-J7-I 1 2k-tr icnlorobenzene (3V) 107-13-1 acrvlonitr UP
(IB) 11U7I-I heKicMorobtnzme (raquoV) 7I-A3-2 benzene
(176) 4772-1 hexcftla-oethtgte (4V) J4-23-5 campr~toon TeTrscftlo itit
(116) III-- bii(2-lttilorolaquothv iVether (7V) lOt-W-7 chlocobenieo
(2C5gt raquol-3l-7 2-cM oroolaquo ptittu lene (10V) I07-O4-2 1 2-dicrtloreetranr
(23B) raquo5-30-l 12-dichlarobenime ( 1 I V ) 71-33-4 11 1 -tricMoroethr
(24 B) 31-73-1 1 3-ltl icJgt lor obcn i ene (13V) 73-3^-3 1 1 -dicMoroeth^i
(27B) 104-^4-7 1 4-dich lorobenzergte ( t k V ) n-00-3 11 2-tncfiloroetvlaquorie
(215) 91901 33-didMoroblaquozidinr (I3V) rraquo-3k-3 l122-tetrraquoOMo-oethne
(335) 121-I-2 2-dinitrotoluergte (ItV) 73JW-3 chloroethjin
(3461 (0420-2 24-dinitrotoluene (19V) 110-73-1 2-cMoroethraquo|vuiv| trgteshy
(37 B1 122-44-7 12-diphenylhydrnine (23V) 47-44-3 ctiloroform
(316) 204- Jgt tluarmrnhene lt2V) 73-35-4 1 1 -^iCMoroeThe^f
(C6) 7003-77-3 -chlorophenyl poenyl ether (gtOV) 154-40-5 trraquonraquo-l2-dicrloroltthene
(bull16) 101-35-3 raquo-6romophenyl phenyl ether (32V) 7I-I7-3 l2^ipoundMoroproBirgte
(raquo26) 3H3I-32- bit (2-cMarobopropvt) ether (33V) 1 004 1-02 -4 trmni-l^-dictilwoproom
(OB) l l l - raquo l - l bis (2-cMeroethoxv) methane 1004 1-0 1-05 cu-13-laquoicMoroprooe^e
(J2BI D-U-3 rraquolaquoeftlorobutraquodilaquooe (JJV) IOOJM- rttylbenzene
(336) 77 -raquo7- hezactilarocyclooentadiene (WV) 75-OT-2 methylene cniorifle
(56) 7raquo-3raquo-l ao ph or one (raquo5V) 7raquoJ7-3 eMoromeirune
(33B) JI-20-3 nraquophtMlene (UV) 7raquoJ3-raquo bromomethAftf
1X6) n-raquov) nitrobtnxerw (raquo7V) 7J-25-2
(CB1 14-30-4 J -ltii TT o vxJ ipheny U rru rraquo ^UV) 75-27- bro mod i cfilor o me t r)e
(CB) 47I-U-7 N-nnrotodipropylraquomJne (tV) 75-4raquo- 11 uor o tr i cMor o me t htgte (US) V17-1I-7 bu (2-eifrrlhryl)praquogtttilaquoUMshy 69 000 (30V) 75-71-1 di cti tor odl1 1 van m^i rajgtr
(476) U-U-7 benzyl buryl phihiUte 890 (31V) 12laquo-kraquo-l cMorodbremof^etNrr (US) U-7I-2 di-n-burvl prittuUre (13V) 127-lt- Uraquo6gt 117-t-0 dJ-laquo-ocTvl phttviUre (UV) IOLtS-3 Wluenr
(75) u-w djrrhylphtnltt ( i rv) 71-01-4
(715) t J I - l l - 3 dimnhrl pfthUte (UVI 73-01- viny l CMcriOr
(779) J4-35-3 0laquoMo(UnthrraquoCflaquoe
C a d m i u m 130 Chromium 20 ZINC 170
o nnn Z-UUU
^0(^ Trace
All results are expressed as ugg weight as received No en
APPENDIX E
PLATES
I I I I I I I I I i Plate 10-1 Troy Mills Landfill with a backhoe excavation
in progress in a former drum burial area
I I I
I I I I I I I I
I I Plate 20-1 NAI field investigation team preparing for
Level B activities during the drum excavation task Troy Mills Landfill
I I I
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
I I I I I I I I
I I Plate 20-3 NAI field investigation team member undergoing
personal decontamination at the hot line Troy Mills Landfill
I 1 I
I I I I I I
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
1
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
I
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
I I I
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
I I I I I I I I I I I 1 I Plate 53-3 Pigmentsludge deposits interbedded with
soil layers in Excavation 8A Troy Mills
I Landfill
1
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40 TEST PIT EXCAVATION
41 WORK PLAN
A series of test pits were excavated in the Troy landfill for
observation and sampling More specifically the purpose of the
excavation was to estimate the number and distribution of drums buried
in the landfill determine the condition of the drums (full empty
crushed rusted leaking etc) identify types of buried and drummed
waste and verify the results of the magnetometer survey A stratified
random sampling method was used to choose 10 locations within the
delineated area of magnetic source material This insured that
excavations were distributed randomly across the landfill and that the
resulting data could be evaluated with a level of statistical
reliability Excavations were also selected in areas on either side of
the anomaly which were considered free of buried magnetic material and
also where drums were visible at the landfill surface
The following procedure was used in choosing the locations for
the random excavations The center of the delineated area of magnetic
source material was used as a base line The base line was drawn onto a
map of the source material (Figure 30-1) and then divided into ten
60-foot long segments Using a random numbers table a point-distance
was located on each segment (designated the random station) and a
line drawn at that point perpendicular to the base line segment Again
using a random numbers table a point-distance (designated the random
offset) measured along the perpendicular line located the point of
excavation The grid coordinates for each excavation were graphically
determined from the grid overlay and then field-located from the
surveyed grid intersections Grid coordinates and selection data are
presented in Table 41-1
It was judged that 10 excavations in the delineated area of
magnetic source material and two excavations out of the area would be
sufficient to characterize the site would produce statistically valid
TABLE 41-1 RANDOMLY SELECTED EXCAVATION SITES TROY MILLS LANDFILL TROY NEW HAMPSHIRE
BASELINE RANDOM RANDOM EXCAVATION GRID SEGMENT STATION OFFSET
NUMBER COORDINATE (FEET) fFEET) (FEET)
1 7E+15 65N 0-60 26 16
2 9E+5 13S 60-120 110 9
3 8E+0 31S 120-180 140 7
4 4E+5 48S 180-240 230 26
5 3E+8 45S 240-300 254 20
6 OE+8 45S 300-360 394 50
7 2W+15 24N 360-420 465 14
8 5W+6 42N 420-480 518 20
9 6V+14 74N 480-540 548 7
10 8W+5110N 540-600 611 31
Locations are plotted on Map in Figure 30-1
data and could be expected to be completed within a scheduled 2-3 day
work period
42 FIELD WORK
Test pit excavation was conducted in two phases On the first
day each of the 10 random locations (Excavation 1 through 10 Figure
30-1) was probed to a depth of 2 feet using hand shovels On the
second and third days excavation was conducted using a combination of
hand shovelling and power backhoe The NAI field investigation team
consisted of six members Four of the team members were equipped to
work at Level B for work in and near the actual test pit excavation
(See Plate 42-1) The other two team members spent much of their time
with personnel and equipment decontamination and refilling compressed
air bottles at the hot line Mr Timothy W Drew an engineer of the
New Hampshire Bureau of Hazardous Waste Management was present during
most probing and excavation work Mr Robert Lynch an experienced
Level B equipment operator of Jet-Line Services Inc operated a power
backhoe which was provided by Troy Mills Inc
An average excavation size using the backhoe was approximately
7-feet wide and 10-feet long Excavation continued downward until drums
were encountered or to a minimum depth of five feet Drums were careshy
fully uncovered and fully described A total of 17 samples were
obtained from uncontainerized wastes (solids dried sludges pigments
stained soil) and where possible from drums using EPA sampling methods
and protocols All of the excavations were backfilled upon completion
of this task
Each sample consisted of one filled 8-ounce glass jar sealed
with a Teflon-lined lid Samples were submitted to Resource Analysts
Inc (RAI) Laboratory in Hampton Falls NH for priority pollutant
analysis
Air monitoring was conducted during each excavation using a
Foxboro Century Flame lonization Organic Vapor Analyzer (OVA) an HNU
Systems photo-ionization detector (HNU) and an MSA combined oxygen and
explosimeter High explosimeter measurements were considered cause for
an immediate halt in exploratory work in the interest of personnel
safety
10
50 RESULTS
51 GENERAL
On November 17 1983 Excavations 1 through 10 were initiated
using hand shovels to a depth of approximately two feet A total of
two buried drums were discovered Excavation 13 was completed and a
third partially buried drum uncovered On November 21 1983
Excavations 1 through 9 were completed and on November 23 1983
Excavations 7A 8A 10 11 12 and 14 were completed An additional
42 drums were uncovered on the last two days of excavation
Excavation Locations Seventeen test pit excavations were
completed at locations which are shown on Figure 30-1 Two pits were
excavated at three of the locations Noteworthy aspects of the
excavation operation are
Excavations 1 through 10 were randomly located in the area of delineated magnetic source material (on-anomaly)
One excavation connected Excavations 4 and 5 This was done because of the proximity of Excavations 4 and 5
Excavation 7A was located immediately adjacent to Excavation 7 Excavation 7 was located on the boundary line of the anomaly and proceeded in a southerly direction off the area of delineated magnetic source material (off-anomaly) Excavation 7A was initiated in the opposite direction (north on-anomaly)
Excavation 8A was initiated one foot north of Excavation 8 after the latter was abandoned due to the detection of a potentially explosive drum
Excavations 11 and 12 were selected off-anomaly to the north and south (respectively) in areas considered to be free of buried magnetic material (drums)
Excavation 13 involved minor hand shovelling necessary to uncover a partially buried drum located on the periphery of the anomaly at the east end of the landfill
11
Excavation 14 was a surface scrape which extended from an exposed drum found to the south of the magnetic anomaly northward toward the anomaly
The details of each excavation are presented in Table 52-1
Drum Locations The excavation results support the
interpretation of the magnetometer survey with buried drums as the
source of the magnetic anomaly With the exception of a few strands of
wire found in Excavation 1 ferromagnetic materials other than drums
were not encountered during the test pit excavations
Drums were foundin 9 of the 10 excavations located in the
area of delineated magnetic source material (See Plate 51-1) No drums
were found in Excavations 11 and 12 located out of the area of
delineated magnetic source materials The location point for Excavation
7 was on the boundary of the anomaly Excavation 7 which proceeded
south away from the area of source materials was free of drums
Excavation 7A proceeding north toward the area of magnetic source
materials uncovered 6 drums Excavation 14 located just out of the
delineated area to the south produced unexpected results Five drums
were uncovered just under the surface in an area with low positive to
slightly negative total magnetic field values It is possible that
Excavation 14 was improperly located in the field If adjusted just 20
feet to the east it would be well into the delineated area It is also
possible that a negative dipole derived from the mass of material to the
southeast is cancelling positive readings at this location
Fill Material and Vegetation Cover and fill material was
predominantly fine to medium sand with an occasional boulder Till with
a siltclay component was also used as a cover particularly at
Excavations 6 and 7A This material was densely compacted and difficult
to dig through Excavations 7 11 and 12 each extending to a minimum
depth of 5 feet were characterized by uniform silt and fine to medium
sand and traces of dark discoloration Excavation 12 was located in
to a s
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ltCO O
O^mdash
laquoshy rmdash
CM Tmdash
n rmdash
_^jshymdash CO
LJ
j ^ |
52
14
what appeared to be natural materials although its location on the
cleared and leveled landfill tend to contradict this possibility
Most of the landfill is vegetated by a thin layer of grasses
sedges mosses and annual herbaceous species The northeast corner of
the landfill is unvegetated and cover material appears to have been more
recently applied This section is elevated 4 to 6 feet above the rest
of the landfill and appears to have received a second newer layer of
waste A 4-foot thick layer of carpet waste was encountered in
Excavation 1 but not in other excavations This section is adjacent to
the newer active landfill The landfill area just west of the access
road crossing (near Excavations 7A 8 and 8A) was also unvegetated due
to relatively recent grading operations
Ground Water The landfill appears well drained as ground
water was not encountered during any of the excavations Excavated
overburden was damp from the recent heavy rain but intergranular macro
pore spaces were free of water
OBSERVED QUANTITY AND CHARACTER OF DRUMS
A total of 45 drums were observed buried in the landfill
Table 52-1 presents a drum log describing each excavation and the
observed drums Data on the contents and condition of drums is
summarized in Table 52-2
Of the total drums observed 15 (33) were crushed flat
Although these could possibly still contain small amounts of waste they
are probably considered empty under RCRA guidelines Thirty (67) of
the total drums discovered were uncrushed and capable of containing
waste Seven (88) of the 8 drums sampled contained liquid or sludge
waste material Thus at least 7 (23) of the uncrushed drums contained
some liquid or sludge waste
15
en C Cl
bullo gtraquormdash
c mdash a
o c re bull mdash c
~ o mdashbull 4Jmdash
10 0 mdash
gt O
ro CO
fcshy0
c
C
vgt 3 0
1 rea
-gt
mdash
3 o T3
lt-O
C j C
CB 3 TJ ii i- 3 mdashQCOa
ifl u bull c c
t_ o
mdash shyO
mdash
L re N
co
t-O
mdash
mdash lfl
V) O
CO N CO pound re
0 mdash
^1 10
ltP O C raquo
CM reO
o f shyi O
mdash mdash 3 - D
c 1
CD bulllaquo
mdash3
D mdash
1 C
Q CO
CD Ifl 4-gt CO
Q
CM
r-
Ul
Q Ul gt EC Ul CJ CO o t5bullpound
z O mdash
C Ci o^
O Cbulla 3v iC MW5 CO 4J3 u CS- Ifl CBC J C O - U
gt Cgt Omdash Oi O
U- 0) Ifl bullgt-gt 1 W C
to lt-gtT3 gtmdash
0) gt shyJ 0)
C OltJ bull O T 3 C D C P
133mdash 4J bull ifl tshy Vgt~ V a O V4JJ
C o
C mdash
O Ifl
3 fc 0)
i-
c
U) re gt
ai C mdash
C mdash
CO gt c o
bull to y 3 cc Q
ltbull-CB
1 4Jin
bullD reCD jCJJC TJCD mdashbullD bull mdash
CD 0t- u iflo ifl
0 C ^-
CB laquo
3 ltbull-
0)^shy
C
0 Cgt O
1 O CTl C
T3 1 mdash CB O
mdash CB mdash in J o 3 tfl C ^ CO 0 gtltgtshy
O gtgtc 01
CO 3 1- mdash C Cregtmdash laquo
TJ W TJ mdash i re traquo-
shyU mdash
O Q
COCO^^
mdash ^
mdash gt C 0gt mdashO ~ bull
Ul
o auO
CCUl
mdash K o tO Ul Q
mdash OT30Jj c mdash4Jt- Jpound O Wre c i re03 gt
lt~i- laquo o ai
0 ) 3 gt O ^crc Ifl - CO -^mdash
3 mdash Q iflmdash 1- O 3 3
O V O ltraquo-o laquoTJ
gt
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gtgtmdash J-gtmdash
Dmdash
6-o
09 bull mdash gtpoundbulllt-gt
re a
Ul X t5
Cpound O Z
fl) mdash^ C B gttflOl3T3T3l_ 3 Q)O mdash mdash
tn mdash
shyD CB
mdash mdash
mdash tt
CO C T3 poundi mdash JCmdash re
^ C O C X CB ^ - S - C C O mdash re O Q DW4shy
re shyu O 1
O Ul X EC Ul mdash
x a^s ox
CO
^) Z
J
1-o t-Ul X r-u 0
o j c gt T3 i -gt c tu mdash c u r e mdash
- C D mdash T3 - C M mdashbullOJJQmdash re3inecrec u c r e o mdash lt~ bullz c~4J O CX t ^Jw o r e -gtgtOgtgtshy3 c j t shy re mdash mdash ret- i o Qmdash gtgtpoundgt a
i reraquo CD 0) bullbull Ifl t-
Q ) t ) O pound O ^ laquo gt - Ow re re ro re re -gt Q mdashc 5 shyu a j-gt D t- raquomdash mdashCB C re C CO 3Q mdash O mdash O U
Htshy ae cu coo)
1 O i i
shya shyo j CD C bullgt o mdash c o c o coco mdash plusmngt o ~a v c en CD
mdash C O
raquoCJ 3C c re amp- ogtCD J o 3 CC C I-Omdash 3gt O
3
O ro
Ul X 1mdash
u O
Ul o r-Z Ul
gtV~ omdash Dlshy ^mdash mdash wre3 i cc
mdash cr bull gtJJ mdash C mdashi QIgtJ^re a shyJQI- o 0mdash
O bullO 3laquo laquo
jjmdash ureoO mdash O N 0)rc3recomdash4Jt-4JpoundmdashC C mdashmdash mdash u
1
shya 0 -
mdash gtgt re-raquo-gt CUD laquo E CD
^ J-1
CJ eoc
4JCB CO
mdash O
C 1- C mdash O C B C B C E J mdash J ltshy shyo cn o o c o r e c shyU -gtO OJC D ifl roc
T3 3 I U 3 laquo-
Ifl CD 1 W ^J 4 J 4 J c -aiflj jc
CB C r e O C B lt-gt -Jgtcoraquo C C -WE O O ) ~ O O O mdash O
Ul O
c ui =gt z
o
1-CC Ul Q
Q z ^ Ul
2 gt Ul O
o Cpound
^ CO
Ul Q ^
z o
(O U S Q
Slt
t5 lt
Z5O
1mdash z ui
Qa Ul
CD 0-1
u m O_J
O2^ltUl
O CC Ul Q
VOCO
CNlA |3
VO ^
CJ |CO |
CJ CMI3 f~ rojO VO rolo
^
ymdash3 CC
roCM
ro O ICNj
ro rolvO ro ro
ro A
rolvO r-jO
00 C3N
ec a m
r3
CO
3 a ty r-
cc Q
(M CM
to z
m 3 c O
u _i co
U-O
O 3-IObull - I c y
fshy lt- ICO r- r-ICM O U lfN ro -mdashla1 f~ laquo- ]CO bull- -ICM O O J|O O
c U) CO
mdashbullre re
mdash re
mdash i ltC c tz
j lt
i lt
5 0 0 G O o o o o z bullU 4J J h- J shyJ tmdash tmdash
^33
J3 3
O 3
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53
16
The condition of the uncrushed drums was highly variable with
only 4 (13) rusted and decomposed to the point of structural weakness
These drums were found in Excavation 10 at the far west end of the
landfill which is believed to be the oldest section (See Plate 52-1)
Interestingly two almost new looking drums were also found in
Excavation 10 at a greater depth than the four rusted drums The
remaining 26 drums were observed to be generally intact and structurally
sound Some were dented partially crushed or rusty
CHARACTER OF WASTES
Air Monitoring An OVA and HNU were used to monitor the air
for concentrations of organic vapors during each excavation Above
background instrument readings indicative of contamination were
regularly recorded when monitoring the air just above or inside of
drums A general contamination of the ambient air in the workspace was
noted only during Excavation 8A where above background readings of +13
in the excavation pit and of +6 above the excavation pit were recorded
Explosimeter readings were obtained from three drums -- 10 lower
explosive limit (LEL) from drum sample 10A 20 LEL from drum sample 6B
and 100 LEL from a drum in Excavation 8 Instrument readings are
presented in Table 52-1 and Table 53-1
Visual Observations The following types of waste were
observed during the excavations
fabric waste (carpet waste)
crushed drums
drummed waste - liquid sludge and solid
uncontainerized dried sludges and pigments
stained soils
Fabric waste scraps of synthetic non-woven fabrics5 heavy
carpet-like fabric and backing material were found only in Excavation
17
CM
CO LJ fmdash O z
laquo 4J
u TO 4-gt
c bullmdash
k bull mdash E mdash 3 3 i-^ O
mdash TJ --raquo co co 4J
E CO O U L U
E 3 c T3
C O a o
is
CO c to 3
U
TO
E O t_ U_
o o
1 ltmdash c
mdash tmdash TO 4J bull C TO 0 O o c u 3 TO
t_ 0) 0 4J
U)
mdashOTOgt
Cw bull aco jc
N 4J a
mdash L Q) re co T E
CO
bullo gt egt mdash c mdash bull o ^^73 C E gtO O mdash 3 J-gtmdash N 4J L 3 mdash 1--C gttTC bull
CX 01C JJ TO O mdash
TO trt mdash t- E mdash 3 JJ a O Q
C I 0 X E mdash C mdash CO
mdash o laquo (D-O mdash O O bullbull B Ol o -cmdash e oic f~ to a (gt TD mdash
E 1- Cpoundmdash 3 O O CO P m T1
L u
T3 CO
lto sshy0 O CA W
laquoT3 O CO 0 C J= CO tlaquo Q bull 3 O Ol 1- C o mdash 3 E a
3 E E i- to
Z L
mdash bull mdash O 4-3 Cl Q
bullD 0) CO T5 N CO mdash C -P 1 0 U TO O mdash 4J Cfc
mdash U) c shybullgt O w C O Q (5 4J 0
3 -J bull U)
5 gt TO_ U
bull gt pound mdash 3 mdash L ro TD
JJ-D - CO TO laquo QO
C 0
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r to 3
O O L L
0
01 TO gt bull
tshy mdash OT3 mdash
CD O C N U) O mdash
TO O CO mdash C C
bull^ ~ CO TO TO gt U iJ
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5 c c 4J 3 CO X LJ
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TO CJ CO mdash C JJ
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O gtgtgt C C mdash CO C TO CO 3 E mdash -J laquo 1- bullgt CO 0 to
bullo CO
cshyo bull
ugt C CO TO c w 4J-Q co e a c
mdash re TO in E to
Q
JJ c bullo
a LJ co E bull LJLJ
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^j C CO E Ol
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U
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bullmdash av^ CO 4J IA TO 5
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ai_ 3 a bullo bull mdash 05 3 O) 00
mdash mdash C c gtgt G CO
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4J mdash
u) obulla o u) amp 5 c -a 7 O C mdash o mdash _ i- (0
CO E laquoJ
C
a
bulla c bull o bull
c bullQ CO
3 01
CT mdash mdash a mdash -v
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CJ raquo
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bullo 3
lt) bull_
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CO X
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CO X
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f
CO
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if
LJ
CO lt
LJ CM 51 r-rmdash
tmdash CM CM ^_ CM
CO CM ^x
CM (M CO CM
Q -
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1
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ui o -1 LJ
i mdash lt sectco z 1
ltT -^
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^
lt 1
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CO 1
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18
bull -a gtgt CD
CO S jj
0 0
CO O
bullo CD jJ
bullo z 3 O L
E 3
CD 1-gt o CO
jpound cshy x mdash o mdash
- 0 1 mdash bshy
4J 1 CO
Z u
CO mdash T3 CD CD
co E C mdash z bullD 73 4J O JZ = CD ltshyO C CD
CD 4J laquomdash C
bullO Qmdash U N ET3 bull mdash 0 Cmdash i- L re mdash oltmdash o
O 1 f-u gt Z 03 shy3 mdash CD
O O tshyo
O (Q C N O mdash shy
o agt O 4-raquo bull z in jz 3 CO 4-gt
gt Q ltshy 0
CD JZ N w Oshy- O
laquo ^ mdash 13 mdash m
mdash in 3
z s_ mdash
laquo
laquo CO T3 0 bull E in 3 3 1-L ^3
-TJ
re 3 O L
CD U -D SshyCD CO CO N 0) mdash 0-E S GO CD CO L
i
CO UJ gtmdash
z laquo w mdash ffl JZ CO 4-gt 4J JZ
4_) t_ mdash bull
cz QJ co jZ C C mdash 4J
re (uS a z z
OX) mdash a) O W E
Z O O JZ bull CL V E
C (~ mdash r re O CD
obullz
-J VI O 4J z re o gt o jt o 5
mdash tshy Q mdash CO 0 Q) mdash j j a C5 E U3
mdash CO mdash 4JCO CO E
CO
JZ 0 3 mdash t_
E Ot3 O L
bull
C 3 3 U L
E OT3 O LshyU
Z JZ 0 0 gt 0 o c 3)
T3
1 I
bullz o mdashfmdash Q
mdashfV
O CO LJ O
LJ _J Q y
CO
C CO
mdash mdash 0 10
bullc bull CD 0) C 4-gt mdash w CO CO 4-1 to
gtJ CD Sshymdash CD Q-O L- gt
CD 4^
~mdash
^
^ bull
bullD 4J C C CO CD
E -3 Ol CD mdash - a bullc cu mdash 4J mdash CO
v^4-gt C 0)E01 Q
agt 3 ^ j3
D CD bullbullbull lpound mdash ltn
t
bullabullmdash 3 CT _
mdash
O
mdash a
bulla
co (0
T3 0) C
a 4J UJ
jpound O CO
bull 05 4J CO CO
^s^
^gtc CD E C)
a c CD 0
3 O c a
O CO vgt gt
O CO co j
3 a CO
O CO
i
COK-IOLJ LJ laquoJ ^ i 1 i
O rmdash 1 1
C-ld to o z
XZS9 jj mdash a
E
i UJ bull~ CO CO
c V
co in
bullo
1mdash bullz LJ s
o Q bull
3)
~
ro
^
r-i
4
O o CM
1
O
1 o ro
Ol c
13
CD
Ct
gtgt imdash CO
tmdash CO (U
bullz ~ CO CO CO O
0 o ^^
X X o 0 O O Ttrade 1
O
|
C CO a
^ gtO
ashyf
o o A O
o T3 ffi
bulla 03 3 C
C o o 1
lt
LJ tshy
o
a
CM
^~
laquobullgt CM
-
fshy
ltshy
fO CM
-
flCM
rlaquoshy
^
3 3D- cr CD ltu CD U C Z CO 0) jZ N 4J Z
C 0)
0)u z
CD n oL Q
a CD ltO pound2 o mdash s CO 00
O o _
CD C ZE
3
E O CO CD ti O
sshy laquo a ^3 ^ T3 SEE C re re c a z gt c
LJ a
clt
-J LJ
z 2 lt o O
1 1 lt o
CC ^
lt^(V
E I I i I I
L lt 13 O 00 CO
CO Z 05 CO Ch ~ rmdash
19
c o C M O - L bull O C M bullmdash co ujn iiupeo CM
CM h- fO i- X
bull k_ c _Jlaquo _Jo
laquok ro
mn i LJOJ 140 CM
3-
bull CM
m CM
tshy r- ro CM
CV
sshy = sO r sshy~ - 2
CM ^ ~ ~ mdash rs
a
2
ou tz S S o w S S o | ^
O gt atshy
mdash o r gtgtlt_
CM 1
m raquo
rmdash r- i- o o o r^ CZ LJ
auazuaq |ua oCO
laquo o PO laquo
o J
o bull
O ~S 5
LJ
O apiJO|L|3 au3|Aq5auj H- r-
J 0
CO
Z
0
a 5 ausni oa O O O J ^ O O r o r~ If o ^rO VO ^ f~ VO deg-
- ^ bull rshy
O o
ro
LJ ^ CM 3 lf kmdash o Tmdash shy
O 1
_J-i
5
O aueu3aojoiuoiu-i i L 1mdash
lts
o o bull
^J mdashZ
0 0 0 0
0 O
^UJ g sauaiJx CO O CM
^ mdashS W
^^ S
5 Tmdash
bullft S
LJ =CO ^CltLJ3Z
^|
i IjJ
ltrshy UJ
LJ ^
shy _jo gt
auazuaq o o
mdashshy
o L-
ia O
pound3 bull
mdash O
lt
lt 3U BL|3 3OJ O I U ^ P mdash l l p^
C N
poundC M- CM 1 3 1mdash H|
W _J
aua iXquaojomoi ja bull LJ mdash mdash O
Q _JZ lt lt C _J to
a)e | eu3Ljd | X ^ O O mdash Umdash 1 p
ooCM
o o OJ
VO
o o O raquo
vO
o o
CM laquo
~
IshyOishy
bull r
bullO
O C 3
E V_ () gt- mdash1 mdash _l lt ~
lt gt
z n o pound
o o
DlllllH 34B 1 eH-gtM -|A3nq lAzuaq
oOCM
o O O
CMrmdash
o O O
ro laquomdash
o (O
o O
CO
CM
o O r~
gtO
o O
(O
mdashV^
rgtE
C
o Jj
o C
C bullc
o i
ltshy
1-o
i-O OCC -J C S O
hmdash gt-poundi ltc bull ^ ro
sects
lt 2
mdash
hlaquo
J
3 4 C J cI^JLJU
( iJxsn iXuia-2 ) s j q
o o C
laquo C
o o
M laquo
O f ro
o o o o
O O O laquo ^
M O O r- LA
o o o
O t ^
O e o
o r
O laquo
O
o ~
i
o o
A O laquo
C M
o o O
( M ^
o o O
C^ 0
laquo C
i raquo
~gto
E c
lt O 1- O bull
CMi
M s ja i cu^dcrj^ ^ 0CM^
0 bull-
ro
J u- e
u-J
_u ^C3 lt1 CJ1 mdash1 lt
=lt r r
lt= - - J L - N O K S c C z -
^
20
1 (See Plate 53-1) This is the predominant waste material currently
being disposed of in the active landfill
Crushed drums were distributed throughout the original
landfill and were found in Excavations 2 4 4-5 7A 8A and 14 Some
drums such as those found under the road in Excavation 7A may have
been crushed by heavy equipment operating in the landfill Others like
those found at depth in sandy fill in Excavation 2 appear to have been
crushed before burial Drummed liquid and sludge wastes are also
distributed throughout the landfill (See Plate 53-2) They were found
in Excavations 1 4 5 6 8 and 10 These wastes are discussed below
One sealed drum was openedand found filled with refuse -- paper cups
towels paint covered rags etc One open and partially crushed drum
contained a dark granular solid waste This material was sampled
(Sample 10B) and found to be nonhazardous
Small deposits of dried pigmentsludge were found in
Excavations 3 4 6 9 and 13 Discernible layers of pigmentsludge and
stained soils were present in Excavations 7A 8 and 8A (See Plate
53-3) Of particular note was a 2 to 4-inch thick layer of
grey-colored dried sludge found at Excavations 7A and 8 All of these
wastes were sampled and the results are discussed below
Laboratory Analyses
Laboratory analyses were performed on 10 selected samples
obtained from both containerized (drummed) and uncontainerized wastes
Samples were analysed for 3 metals and 87 priority pollutants including
11 acid compounds 45 baseneutral compounds and 31 volatile organic
compounds Table 5-4 summarizes the analytical results and the
laboratory data sheets are presented in Appendix D
Of the 45 priority pollutant baseneutral compounds only 4
were identified in the samples that were analyzed Baseneutral
21
compounds and particularly phthalates were the most prevalent
chemicals and also were reported in the greatest concentrations The
highest levels of naphthalene (1200 ppm) bis (2-ethylhexyl) phthalate
(110000 ppm) and di-n-octyl phthalate (6200 ppm) were found in sample
4A a translucent red liquid obtained from a drum The highest
concentration of benzyl butyl phthalate (13000 ppm) was found in sample
6B a clear liquid and pink sludgepigment obtained from a drum
A total of 8 volatile organic compounds were identified The
highest levels of benzene (100 ppm) xylenes (19000 ppm) and
ethylbenzene (5300 ppm) were found in sample 5A a clear liquid
purple-grey sludge obtained from a drum Toluene was found in highest
concentration (12000 ppm) in sample 1A a purple-grey thick opaque
liquid obtained from a drum Methylene chloride (13 ppm) was
identified in greatest concentration in sample 8A-C a purple stained
soil and powdery waste Sample 10A a purple liquid obtained from a
drum was the only sample found to contain 1-1 dichloroethane (2000
ppm) Finally trace levels of trichloroethylene (sample 10A) and
111-trichloroethane (sample IB) were also reported
Samples were tested for three metals - cadmium zinc and
chromium The highest concentrations of cadmium (2200 ppm) and zinc
(5700 ppm) were found in sample 4A a translucent red liquid obtained
from a drum The highest level of chromium (52 ppm) was reported in
sample 5A a clear liquidpurple-grey sludge obtained from a drum
22
60 DISCUSSION
61 EXISTING SITUATION
Under existing conditions relatively small quantities of
volatile organic compounds (VOC) are indicated to be leaking from wastes
buried on the landfill site To date ground and surface water
monitoring results indicate relatively low concentrations of VOC in the
ground water and below detection limits in the adjacent brook (See
Tables 61-1 to 61-10) The results indicate that no potential health
risks from VOC and other constituents currently under observation are
being caused by the landfill operation to down stream surface water
users It would be prudent for Troy Mills to continue to monitor the
quality of Rockwood Brook upstream and downstream for VOC and on the
basis of waste analyses (previous section) to monitor ground and
surface water points for toxic metals and baseneutral compounds
62 SITE HYDROLOGY
An analysis of the hydrology of the landfill site was
performed in 1982 (NAI report of September 1982) The subwatershed that
contains the landfill site is (about 44 acres) a small fraction of the
watershed area that contributes to Rockwood Brook above surface water
sampling point C (about 1650 acres see Figure 62-1) This indicates
that most of the flow of the brook at point C (about 97) is contributed
by upstream watershed areas Thus leachate discharging into Rockwood
Brook from the landfill site can be expected to be diluted by over 30
times its volume This factor and the volatilization which naturally
occurs results in parameters detected in the Troy Mills monitoring
wells often becoming undetectable when they enter the brook
f 5
Geologic conditions which were defined in the NAI report of
July 1982 indicate that permeable deposits of sand and gravel overlie
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27
TABLE 61-5 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M5 (UPGRADIENT WELL)
Parameter Date Sampled 11-22-83
Specific conductance
pH2 81
Dissolved iron mg1 036
Dissolved manganese mg1 010
Chloride mg1 10
Phenolics mg1
3
023
Identified volatile organics
None identified ND
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (yg1)
28
TABLE 61-6 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M6
Parameter
Specific conductance
PH2
Dissolved iron mg1
Dissolved manganese mg1
Chloride mg1
Phenolies mg1
Identified volatile organics
11-dichloroethane tetrachloroethylene 111-trichloroethane
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vg1)
Date Sampled 11-22-83
152
lt002
29
6
0002
27 trace 140
29
TABLE 61-7 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M7
Parameter Date Sampled 11-22-83
1 47 Specific conductance
pH2 62
Dissolved iron mg1 002
Dissolved manganese mg1 0026
Chloride mg1 gt2
Phenolics mg1 0070
3 Identified volatile organics
111-trichloroethane 5
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vig1)
30
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34
glacial till and bedrock The sand and gravel deposits form a permeable
conduit through which leachate from the waste burial areas migrates
The permeable deposits lie in the area north of monitoring well M-l (See
Figure 62-1) In general the water saturated thickness of the sand
and gravel in the vicinity of the north-south access road is 6 to 12
feet
64 POTENTIAL FOR GROUND WATER CONTAMINATION
641 Estimated Quantity of Drums
The test pit excavation and sampling in the drum burial area
indicates a potential source of ground water contamination for the
future Many of the drums encountered were in fair to good condition
and contained liquid wastes An estimate of the number of drums in the
deposit was made with the following assumptions
1 The complex magnetic anomaly was simplified into a geometric solid 600 feet long 40 feet wide and 10 feet deep with a volume (V) of 240000 cubic feet
2 Each steel drum (D) occupies 105 cubic feet (including voids)
3 The density of packing (P) was assumed to be 50 of the packing that can be achieved with perfect cubic packing
THEN
N = estimated number of steel drums
N = (VD) (P)
N = (240000105) (05)
N = 11429 drums
The results of the drum excavation work provides a basis for
estimating the potential for specific types of chemical loading In
general three main classes of chemical substances were identified in
35
the drums The chemical substances included baseneutral extractable
organic compounds (mostly phthalates and lesser amounts of naphthalene)
volatile organic chemicals and metals
642 Phthalates
The phthalate esters found in the drums include
bis (2-ethylhexyl) phthalate ^0^3 benzyl butyl phthalate di-n-octyl phthalate Jd~7
Bis (2-ethylhexyl) phthalate was found in the highest
concentration at 110000 ppm (11 percent) Benzyl butyl phthalate is at
the second highest concentration 13000 ppm (13 percent)
Characteristics of those phthalates found are presented in Table 64-1
TABLE 64-1 PHYSICAL PROPERTIES OF PHTHALATE ESTERSshy
di-n-octyl bis (2-ethylhexyl) butyl benzyl DOP DEHP BBP
ALTERNATE o-Benzenedishy di (2-ethylhexyl) benzyl butyl NAMES carboxylic phthalate phthalate
Molecular Weight 3910 3910 312
Melting Point -25degC -50degC -35degC
Boiling Point 220degC 386 9degC 377degC
Vapor Pressure-mdash lt02 torr (150degC) lt001 torr (20degC)
Not
2xlO~7torr (20degC) Available
Solubility 3 rngfc (25degC) 04 mgfc (25degC)
58
13 rngH 48
Log octanolwater 92 873 58 partition coefficient 53 48
Versar Inc 1979 Water-Related Fate of 129 Priority Pollutants Volume II Prepared for US Environmental Protection Agency PBSO-20438 December
bullbullOther names listed in Versar 1979 vMore than one value has been calculatedreported
36
Bis (2-ethylhexyl) phthalate is the most well-studied of the
phthalate esters though the information on phthalate esters as a group
is limited The three phthalates identified at the Troy Mills site have
relatively low solubilities and are readily adsorbed onto suspended
particulates Microbial degradation is effective under aerobic
conditions bur is generally slower under anaerobic conditions
(nonexistent for bis (2-ethylhexyl) phthalate)
The above characteristics are important for two reasons One
the extent and nature of contaminant migration from the site are
dependent upon the physical characteristics Second the treatment
(clean-up) alternatives for contaminated ground water or soil can be
estimated from the characteristics
From the available information it appears that the phthalates
present at the Troy Mills site would be relatively immobile due to their
low solubilities and high adsorption rates The presence of toluene and
methylene chloride at the site however may increase the phthalates rate
of migration
It is important to note that none of the phthalates have been
found to be present in the monitoring wells nor in the surface water
sampled probably due to the low solubility and high adsorption rate
37
643 Napthalene u K r
Naphthalene has also been found in significant quantities in
the sampled drums Naphthalene is a polycyclic aromatic hydrocarbon and
has the following properties
Molecular Weight 12819
Melting Point 8055
Vapor Pressure (20degC) 00492 torr
Solubility in Water (25degC) 344 mgfc
317 mgfc
Log octanolwater partition coefficient 337
Versar 1979
Naphthalene has mid-range adsorption rates and solubility It is
therefore inferred that there would be some adsorption to soils in a
ground water environment It is important to note that naphthalene has
not been detected to date at the monitoring wells or the surface water
sampling locations This is expected to be a result of adsorption on
the soils
644 Volatile Organic Compounds
Volatile organic compounds tend to migrate readily within
soils and ground water They are therefore considered a threat to
surrounding ground and surface waters if they are released in sufficient
quantities
Volatile organic compounds were detected in samples from six
steel drums The total volatile organic (TVO) concentrations in the
38
wastes ranged from 9 ppm to 30100 ppm and averaged 8570 ppm In order
to determine the potential for future contamination by volatile organic
compounds an estimate of waste quantity based on information from the
drum excavation program was made It was assumed that 7000 steel drums
in the deposit are 60 full of liquid waste with an average TVO
concentration of 8570 ppm The computed volume of liquid waste is
231000 gallons with an average TVO concentration of 8570 ppm This is
equivalent to about 1980 gallons of pure TVO
Two of the volatile organic compounds that have been most
prevalent in the existing ground water monitoring system are
111-trichloroethane and ethylbenzene The EPA suggested no adverse
response level (SNARL) for 111-trichloroethane is 330 ugpound for
1 day of exposure and 35 jigd for exposure over a life-time in
drinking water
In general ethylbenzene is a prevalent chemical in the
environment Sources include commercial (eg petroleum and petroleum
by-products) motor vehicle exhaust and cigarette smoke An intake of
16 mgday (1 mgfc) has been calculated as an acceptable rate to
protect from toxic effects Carcinogenic effects have not been
identified to date The physical properties of ethylbenzene are
presented in Table 64-2 The principal mechanism for removal of
ethylbenzene from water is volatilization In addition to
volatilization adsorption may also be an important removal mechanism
based on the log octanolwater coefficient This factor is important in
evaluating the migration of ethylbenzene from the disposal site
Toluene which was also identified in waste and ground water
samples exhibits properties similar to ethylbenzene in that it
volatilizes easily Toluene which is also referred to as methylbenzene
is distinguished from benzene by the substitution of a methyl group for
one hydrogen atom Physical properties of it are presented in Table
39
64-2 The EPA suggested no adverse response level (SNARL) for toluene
is 1 mgpound in drinking water with a maximum exposure time of ten
days
TABLE 64-2 PHYSICAL PROPERTIES OF ETHYLBENZENE AND TOLUENE
ETHYLBENZENE TOLUENE
Molecular Weight 10616 9213
Melting Point -949degC -950degC
Boiling Point 1362degC 1106degC
Vapor Pressure at 20degC 7 torr 287 torr
Solubility in water at 20degC 152 mg2 5348 mgd
Log OctanolWater Partition Coefficient 315 269
645 Metals
One liquid sample contained high concentrations of cadmium
(2200 mgd) and zinc (5700 mgd) indicating that the waste deposit is
also a potential source of certain toxic metals Tests for these metals
have not been made to-date in ground or surface water samples It would
be prudent to add toxic metals such as cadmium chromium lead and
mercury to the list of parameters that are being monitored to further
characterize the quality of adjacent ground and surface waters US
EPA and New Hampshire drinking water standards for these metals are
cadmium 01 mgd chromium 05 mgpound lead 05 mgd mercury 002
mgd Although zinc is not considered a highly toxic metal the
US EPA has set a secondary drinking water maximum contaminant level of
5 mgd on this metal
40
70 CONCLUSIONS
The following conclusions were drawn during this
investigation
1 A steep-gradient irregular-shaped magnetic anomaly is present under closed and covered portions of the south part of the Troy Mills landfill
2 The magnetic anomaly is caused mostly by an irregular-shaped accumulation of disposed steel drums
3 In a randomly conducted sampling of drums in the source area for the magnetic anomaly 16 of the drums contained liquid andor sludge 33 were crushed flat and 51 were not sampled because there were no accessible openings
4 Laboratory analyses indicate that the random waste sampling contained significant concentrations of several volatile organic chemicals several baseneutral priority pollutants and high levels of cadmium and zinc
5 Observed concentrations of volatile organics at the monitoring wells are relatively low Because of their potential for migration in the ground water continued monitoring of volatile organics will be required
6 Volatile organic chemicals have not been detected in Rockwood Brook to-date Because of the presence of low levels of volatile organics in the ground water they should be monitored in the brook on a regular basis to confirm the lack of impact
7 The presence of high concentrations of cadmium and zinc in one of the waste samples indicates that trace metals should be monitored periodically
8 The presence of baseneutral extractable compounds (phthalates and naphthalene) in all of the analyzed waste samples indicates that these compounds should be monitored periodically
9 The phthalates are not expected to migrate freely because they have low solubilities and are readily adsorbed onto soil particles
10 If elevated concentrations of volatile organic compounds trace metals or baseneutral extractable compounds should occur in the monitoring system (wells and brook) in the future a need for site remedial actions to mitigate the potential for downgradient ground and surface water contamination could develop
~
80
41
RECOMMENDED PLAN
Based on the preceding conclusions it is recommended that the
following plan be implemented by Troy Mills Inc
1 Continue monitoring ground and surface water quality at the Troy Mills Inc landfill sampling on a quarterly basis with sample collections during April July October and January
2 To confirm the absence of the landfills impact on Rockwood Brook test samples for volatile organic compounds by GCMS from surface Stations B (upstream) and C (downstream) on the April and October samplings
3 To determine if trace metals are present in downgradient ground waters conduct analyses for cadmium chromium lead mercury and zinc on samples from all monitoring points during the April sampling and on subsequent sampling rounds if necessary
4 To confirm the continued absence of baseneutral extractable compounds in downgradient ground and surface waters conduct analyses for baseneutral extractable compounds on samples from monitoring wells M 2 and 3 and surface Station C (downstream) on the April sampling and on subsequent sampling rounds if necessary
5 If a sudden rise in concentrations toward unacceptable levels should occur in the monitoring system (wells and brook) additional monitoring rounds at a monthly interval should be conducted to confirm the rise in concentrations
6 If elevated concentrations persist and are verified by the additional monitoring remedial alternatives will be defined to mitigate the potential for downgradient ground and surface water contamination
Respectfully submitted NORMANDEAU ASSOCIATES INC
Dennis R Sasseville Project Manager
Donald H Bruehl f laquo | APG Senior Hydrogeologist -^ - - AIPG Certificate No 2272 ^ -v^
^^Z-^^
APPENDIX A
SITE SAFETY PLAN
GENERAL SAFETY PLAH FOR
TROT MILLS LANDFILL TROY MEW HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
Prepared by
NORMANDEAU ASSOCIATES INC Bedford New Hampshire
R-457
November 1983
TABLE OF COHTENTS
PAGE
SECTION 1 BACKGROUND INFORMATION 2
Identification 2 Personnel 2 Site Description 3 Project Description 5
SECTION 2 HAZARD EVALUATION 6
Overall Degree of Hazard 6 Specific Hazards 8 Necessary LPP 8
SECTION 3 FIRST AID FOR EXPOSURE 10
SECTION 4 OPERATIONS SAFETY PLAN 11
General Personnel Protection GuidelinesAction Levels 11 Site Reconnaissance 13 Task 1 - Magnetic Survey Topographic Survey 14 Task 2 - Drum excavation and Sampling 15
SECTION 5 EMERGENCY INFORMATION 16
Emergency Telephone Numbers 16 Route to Hospital 16 Contingency Plan 17
APPENDICES 18
A - LEVELS OF PERSONNEL PROTECTION 18 B - DECONTAMINATION PROCEDURES 23 C - PERSONNEL AND RESPONSIBILITIES 25 D - PERSONNEL CASUALTY 26 E - GUIDELINES FOR SITE OPERATIONS 27
GENERAL SAFETY PLAN FOR
TROY MILLS LANDFILL TROY NEraquo HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
The following is a Safety Plan for on-site activities performed
during the Investigation of the Troy Mills Landfill being conducted by
Normandeau Associates Inc (NAI) of Bedford New Hampshire
The document is intended to be an in house working guideline
for personnel trained and experienced in hazardous waste field work and
not a treatise on safety Familiarity with standard equipment and proshy
cedures is expected Where possible non-site specific information has
been appended
All NAI employees subcontractors and visitors will be required
to follow this safety procedure plan and to report to either NAIs proshy
ject manager (P M) on site coordinator (OSC) or safety officer (SO) on
issues relating to safety
SECTION 1
BACKGROUND INFORMATION
IDENTIFICATION
Site Name Trey Mills Landfill NAI-ID No 457
Trey Mills Inc Troy NH 03465
AddressLocation At the south end of the dirt road about 15 miles
south of Troy NH between Rockwood Brook and the
old Boston and Maine Railroad grade
County Cheshire Phone 603-242-7711
PERSONNEL
Brook Dupee Bureau Hazardous Waste 603-271-4611
State Contact John Regan Bureau Solid Waste 603-271-4586
Dan Allen WSPCC 603-271-2755
EPA Contact
Other Contacts
Client Contacts Barrett F Ripley (Vice President)
NAI Personnel - (472-5191)
Project Manager - Dennis Sasseville
On Site Coordinators - Alton Stone
Safety Officer - Elizabeth Gross (Phoenix Safety)
Technical Director - Don Bruehl
Other - Douglas DeNatale Steve Ransom
SITE DESCRIPTION
Type of Facility Company (on-site) landfill
RCRA Status Generator Disposer
Size About 15 acres BuildingsStructures None
Surrounding Land Use N Forested
(one mile radius) E Abandoned Railroad
Forest RuralResidential
S Forested
W Forested Mountain side
Unusual Features or Terrain None
Site Activities - Troy Mills manufactures textiles carpets and related
products Since 1968 waste materials including
drummed wastes have been landfilled on company proshy
perty Drums mostmany of which may be emptycrushed
are buried in an inactive section of the landfill
The active section is currently accepting waste
which is considered to be non hazardous
Specific - Improper disposal of hazardous waste
Problems - Leachate seep
Contamination of ground water
Hazardous WastesMaterials On-5ite
Wastes - Uncured foam rubber latex sludge
SBR rubber silicone defoamer potassium oleate soap
calcium carbonate and feldspar filters zinc oxide
and sulpher salt cure system
- Vinyl plastisol sludge
PVC dispersion resin DOP and DOA plasticiser
calcium carbonate filler organic pigments AZO
dicarbcnamid blowing agent zinc salts expoxidized
soybean oil cadmLum-bariin-zinc stabilizer Varsol
MEK prints and topcoats sludges
PVC acrylic resins organic and inorganic pigments
MEK solvent toluene silicate fillers
Industrial solvents and chemicals
11 -dichlorethane 12-dichlorothane
111-trichloroethane trichlorethylene tetrachshy
lorethene methylene chloride toluene benzene
ethylbenzene benzidine 33-dichlorobenzidine aeroshy
lein acrylonitrile napthalene benzoperylene dibenshy
zoanthrasene idenopyrene
Pesticides
There is a possibility for low levels of pesticides
to be on site These would include Chlorodane
heptachlor expoxide toxaphene aldrin alpha BHC
beta BHC 4-4-DDT endosulphan 1 heptachlor
PROJECT DESCRIPTION
Purpose Tb characterize ground water conditions at the site and to
characterize wastes buried on site
Specific Tasks
Site Reconnaisance
Task 1 - Magnetometer SurveyTopographic Survey
Task 2 - Excavation for inspection of drums
SECTION 2
HAZARD EVALUATION
Overall Degree of Hazard - Moderate
Task Hazard Proposed LPP
Site Reconnaissance Low Level C
Task 1 MagnetometerTopographic Surveys Low Level CD
Task 2 Drum ExcavationSampling Moderate Level B
Conpany records have indicated that a variety of industrial
and potentially hazardous wastes including drummed wastes
were disposed of on site Several of the subtances are
trade name materials or industrial process materials and it
is difficult to determine the specific chemical composition
Hazard is dependent upon concentration of material state of
material (solid sludge drummed liquid) and degree of
decomposition
Many of the materials - SBR rubber silicone defoamer
potassium oleate soap calcium carbonate and feldspar
fillers zinc oxide and sulpher salts plasticiser
calcium carbonate filler organicinorganic pigments AZO
dicarbonamid blowing agent epoxidized soy bean oil
cadmiura-bariun-zinc stabilizer - probably do not represent
a significant hazard to an inspection team if they are
bound into a sludge or solid Personnel are not likely
to injest or come into a prolonged high concentration
contact with these materials In powdered or dust conshy
ditions the materials are more hazardous due to the inhashy
lation of contaminated particulates
MEK (TLV-200ppm) toluene (TLV-100ppm) and Varsol
(turpentine thinner composition unknown) are volatile
organics which require respiratory protection and contact
protection
Depending upon state and decomposition PVC resins could
be a source of vinyl chloride monomer (VCM-a carcinogen)
requiring respiratory protection VCM is not adequately
filtered by air purifying respirators
Results from ground water sampling showed low levels of
industrial chemicals (PPB range) At these low conshy
centrations the chemicals do not represent a significant
hazard However the low concentrations in ground water indishy
cate the possibility of higher concentrations in the waste
materials
Industrial chemicals - napthalene (TLV-10 ppm) peryshy
lene anthrocene and pyrene which are hazardous
through inhalation or absorbtion Furthermore as
double benzene ring chemicals they are potential
carcinogens
Results from ground water sampling indicated possible
low levels (parts per trillion) of several pesticides
- chlorodane heptachlor epoxide toxaphene eldrin
Alpha BHC Beta BHC 4-4-DDT endosulphan These were
tentatively identified during a first analytical run
but not confirmed during a second run laboratory
review (GCA Bedford Mass) determined that the
material was actually a complex of highly degraded
heavy organics derived from the industrial waste The
presence of pesticides in industrial textile waste is
unlikely
Specific Hazards
1) Inhalation of organic vapors
Excavation of buried material and sampling of drums could
initiate high vapor concentrations
2) Fire and explosion
Many of the solvents are flammable liquids and volatile
Excavation of material and sampling of drums should
proceed cautiously in order to avoid rupturing shocking
or sparking of drums and material
3) Inhalation of contaminated dustparticulates
Excavation of buried material may result in a release of
particulates
4) Contact contamination
Excavation and sampling of wastes could possibly result in
contact with contaminated waste and soils necessitating
protective clothing
Necessary LPP
Site Reconnaissance - Level C The site has been visited on numerous
occassions by the state and private personnel Use of an HNU (102 ev
probe)- has not indicated significant vapor concentrations Significant
odors during dry weather or other hazards have not been noted
Sections of the landfill are currently active and adverse effects to
personnel have not been noted Level C - (tyveks rubber safety boots
organic vapor cartridges) is sufficient
Task 1 MagnetometerTopographic Survey - Level CD LPP will depend
upon the results of the Site Recon Significant vapor concentrations
or likelihood of particulates will necessitate an upgrade in the LPP
Otherwise Level D (work clothes safety boots boot wash) is sufficient
Task 2 Excavation and Sampling of Buried Drums - Level B The potenshy
tial for encountering significant concentrations of hazardous
materials during this task is moderately high Full Level B - (SCBA
chemical resistant tyveks hoods rubber safety boots rubber gloves)
will provide necessary respiratory and contactsplash protection
The use of the hooded yellow tyveck and the taping of ankleboots
wristsgloves and face maskhood junctions will provide complete conshy
tact protection
10
SECTION 3
FIRST AID FOR EXPOSURE
INHALATION OF VAPORSPARTICUIATES
Symptoms - eyenosethroat irritation nausea dizziness headache weakness fatigue lightheadedness drowsiness Loss of coordination confusion vomiting cramps (These sympshytoms are similar for most organic vapors particularly solvents)
Treatment Mild Exposure - Bring victim to fresh air Rinse eyes and throat if
irritated Heavy Exposure - (victim vomits very dizzy groggy faints etc)
Bring victim to fresh air Evacuate to hospital Prepare to administer CPR
Victim should be monitored for 48 hours in case of a delayed reaction
CONTACT EXPOSURE
Symptoms - Itching burning redness of skin Severe contact exposure for certain solvents will progress to CNS (central nervous system) symptoms similar to those for inhalation
Treatment - Remove contaminated clothing flush with water dry and banshydage Monitor victim for CNS symptoms for at least 48 hours
FIRST AIDSAFETY EQUIPMENT
The following equipment will be stationed at the Hotline or when appropriate down range
- Fully equipped first aid kit - Oxygen bottlekit - Nine (9) Ib chemical fire extinguisher - Eyewash bottle or other pressurized water filled container
11
SECTION 4
OPERATIONS SAFETY PLAN
This section outlines the specifics of safety procedures to be
used during each phase of the operations Safety procedures may be
upgraded or downgraded during site activities pending monitored changes
in the working environment All changes will be in line with the
General Level of Personnel Protection GuidelinesAction Levels for the
Troy Mills Landfill On-Site Investigation as described below
General Personnel Protection GuidelinesAction Levels
An in depth review of levels of personnel protection (LPP) is
presented in Appendix A
Level B (SCBA cotton coveralls or work clothes yellow tyveks (chemical resistant) steel toed rubber boots or work boots with disposhysible over boots and gloves)
Vapor concentrations (as measured on an OVA or HNU 117 EV Probe) greater than 5 ppm above background
- Oxygen deficient atmospheres less than 195
Specific actions (ie excavationsampling of drums) which could initiate a sudden moderate or high concentration of vapor
Level C (full face respirator organic vapor dust combo cartridge tyveks over work clothscoverails rubber safety boots gloves)
Vapor concentrations above an established clean zone backshyground level
During conditions (natural or personnel induced) which result in high levels of dust (visable above background atmospheric concentrations of particulates)
Level C activities require continual air monitoring
12
Level D (cotton coveralls or other work clothes safety shoes and safety glasses when down range Tyveks may also be needed)
Support areas and downrange areas where a higher LPP has not been deemed necessary
Continual air monitoring in downrange areas
Explosive Atmospheres
- 20 LEL (lower explosive limit) as recorded by an explosishymeter Secure and evacuate the work area
Oxygen Deficient Atmospheres
- Less than 195 (by volume) oxygen atmosphere requires upgrading the level of Personnel Protection to Level B
Task Specific Safety Plans
Levels of Personnel Protection indicated for specific tasks below are those which are anticipated to be used Changes in site conshyditions and results of air monitoring may indicate the upgrade downgrade of the LPP
13
Site Reconnaissance (SR) Date Sept 21 1983
Purpose To review on-site conditions and determine LPP necessary for further tasks To evaluate safety hazards Preliminary planning of future tasks
LPP - Initially Level C Updowngrade as necessary
Equipment - OVA HNU (102 ev probe)
Hotline - End of access road Upwind if possible
Command PostFirst Aid - Behind Hotline
Decontamination - Boot wash
Operations
Three man team Two persons advance in front with instrushyments Third person at distance as backup
Team methodically sweeps (criss cross) the proposed work areas with instruments
Specific points of interest (leachate seeps etc) are closely checked
All information is loggedsketch mapped
Upgraded LPP as necessary
14
Task 1 - Magnetic Survey Topographic Survey Date Week of October 3 1983
Purpose - Determine the location(s) and extent of buried drums Provide topographic information for site base map
LPP - Level CD
Hotline - End of access road (upwind if possible)
Decontamination - Boot wash
Operations - SO or other NAI personnel will perform a brief safety sweep of the work area
- Work team will then proceed downrange at the appropriate LPP Using the magnetometer the team will systematically criss cross -the work area
Task 2 - Drum Excavation and Sampling Date Week of November 14 1983
Purpose - Excavationsampling of buried drums in order to characterize the condition of the drums and the nature of the wastes conshytained in the drums and buried in the landfill
Msthod - Backhoe and hand labor will be used to uncover the drums in specified locations Samples will be obtained from spillage or leakage around the drums and of contaninated soil Selected drums which have accessible and openable bungs may be opened and sampled Drums will not be moved or staged Clean drums will be available to receive any significant spillage during the opening and sampling
Specific Hazards - Inhalation of organic vapors - Fire and explosion of drummed waste - Contact with contaminated waste or soil
LPP - Full Level B protection Backhoe operator at Level B Backshyhoe equipped with splash shield and without teeth on bucket
Hotline - At the end of the access road Upwind if possible
Decontamination - Procedures will essentially follow those as outlined by the EPA for Level B work Due to the inaccessibility of the site a field shower will not be available See Appendix B
Safety Equipment - OVA HNU eyewash fire extinguisher oxygen kit first aid kit metal detector non sparking implements
15
Operations - The cover soil is very sandy and the drums appear to be buried close to the surface which should facilitate excavation
- Minimum of 4 man team (exclusive of backhoe operator) Two or three man downrange team for digging and sampling One or two men in supportbackup at hotline
- Personnel will hand dig several small holes to approximately one (1) foot depth in each Location area If drums are not encountered the backhoe will scrape off soil to that depth
- Excavation will proceed alternating hand and backhoe methods At depths below four (4) feet the sides of the pit must be angled back to less than 45deg
- Prior to opening a closed drum the backhoe will nudgebump the drum to check for shock sensitive material An alternate method will be to attach a length of rope to the drum and from a distance pull on the rope to jog the drum
mdash Backhoe The backhoe operator will work at Level B utilizing air supplied from a large cylinder attached to the backhoe The backhoe will also be equipped with a splash shield A scraping bucket without teeth will be used
Prior to backhoe excavation at each location the area where the backhoe will be stationed will be checked for drums which could be ruptured by the backhoe feet
f Excavation areas will be checked for drums utilizing hand excavations or a metal detector prior to removing material by machine
16
SECTION 5
EMERGENCY INFORMATION
Emergency Telephone Numbers
If calling one of these numbers please state NAME LOCATION
and type of PROBLEM
Local Emergency Support
Fire Department (Troy 242-7759) For all emergencies use
Ambulance 352-1100 Mutual Aid (Keene) 352-1100
Police Department (Troy 242-7992)
Hospital 352-4111 (Cheshire Hospital in Keene)
Town Clerk 242-3845 State Agencies
NH Bureau of Hazardous Waste Management 271-4608
NH Water Supply and Pollution Control Commission 271-3503
NH Fire Marshall Office 271-3336
NH State Police (24-Hour Dispatch) 1-800-852-3411
Other
US EPA (24-Hour Hotline) 617-223-7265
Poison Center Mary Hitchcock Hospital 1-800-562-8236
Route to Hospital
- Follow dirt access road to Bowkerville Road - Left on Bowkerville Road to Rt 12 - Left (north) on Rt 12 through Troy to Keene NH - At major junction of Rts 9 10 101 and 12 go straight through
into Keene - At common go half-way around and go right on Court Street - Hospital is at 580 Court Street
17
Contingency Plan
Signal - five (5) one second blasts of auto or air horn Action - All personnel immediately excavate dovmrange areas and
report to Hotline for instructions
Personnel Unexplained Fire (if small) Accident (serious) Collapse of Personnel
Evacuate area Emergency ^ ^Evacuation Evacuate Area
First Aid
Estimate Explosion Level B (for Potential Contact Outside Help evcavation)
Evacuate Victim i If
Level B Prepare for Transportation
1 First AidCPR Use extinguisher Transport
Contact Outside Help Notify Coup any Have Proper Information Personnel (see below) 1
Transport
Call Fire Dept (if necessary)
For Hospital Victim
- Name and Phone of family physician
- Description of Incident chemicals involved symptoms nature of injury proposed treatment and plan of transportation
18
APPENDIX A
LEVELS OF PERSONNEL PROTECTION
Because of the possible dangers of exposure to toxic or harmshyful chemicals protective equipment must be worn during work on hazardous waste sites Levels of Personnel Protection (LPP) describe respiratory clothing and other equipment necessary for protecting personnel against expected hazards
The descriptions below are for full dress at a given LPP where hazards are expected to be at a maximum for which the given LPP is conshysidered adequate Depending on site conditions and work activities the clothing and dress requirements of a given LPP are commonly modified
LEVEL A
1 Personal Protection Equipment
Positive Pressure SCBA (MSHANIOSH approved) Operated in the positive pressure mode
Totally Encapsulating Suit (boots and gloves attached)
Gloves - Inner (tight fitting and chemical resistant)
- Boots - Chemical - protective steel toe and shank Depending on suit boot construction worn over suit boot
- Gloves shy Outer chemical-resistanttion worn over suit gloves May bchemical-resistant gloves worn insid
Dependinge replaced withe suit glo
on s
ves
uit construcshy tight-fitting
- Underwear shy Cotton long-John type
- Hard Hat (under suit)
- Disposable protective suitover encapsulating suit)
gloves and boots (Worn under or
- Coveralls (under suit)
- 2-way Radio Communications
Optional
19
2 Criteria for Use
A The type and concentration of toxic substances are known and require the highest level of combined protection to the respirashytory tract skin and eyes These conditions would be
1 Atmospheres which are immediately dangerous to life and health (IDLH)
a IDLHs can be found in the NIOSHOSHAs Pocket Guide to Chemical Hazards andor other references
2 Known atmospheres or potential situations that would effect the skin or eyes or could be absorbed into the body through these surfaces in toxic quantities
a Potential situations are those where vapors may be generated or splashing may occur through site activities
b Standard reference books should be consulted to obtain concentrations hazardous to skin eyes or mucous memshybranes
3 Oxygen deficient atmospheres with above conditions
3 At sites where the type andor potential concentration of toxic substances are unknown
1 Unless circumstances strongly indicate otherwise the site should be presumed to present hazards to the respiratory system skin and eyes Level A protection would provide the highest level of protection for the initial entry team
a Such circumstances might be
1 Environmental measurements contiguous to the site
2 Reliable accurate historical data
3 Open unconfined areas
4 Minimal probability of vapors presence or splashing with cutaneous effecting substances
2 Enclosed areas such as buildings railroad cars ships holds etc
20
LEVEL B
1 Personal Protective Equipment
Positive Pressure SCBA (MSHANIOSH approved) operated in the positive pressure mode
- Hooded chemical-resistant suit
Gloves - Outer chemical-protective
Gloves - Inner tight-fitting chemical-resistant
Boots - Outer (chemical-protective heavy rubber disposables)
Boots - Inner (chemical-protective steel toe and shank)
2-way Radio Communications
Hard Hat
Face Shield
2 Criteria for Use
A The type and concentration of hazardous substances are known and require the highest degree of respiratory protective but a lower level of skin protection
1 Atmospheres which are immediately dangerous to life and health (IDLH) Type and concentration of vapors in air do not present a hazard to the small unprotected areas of the body
2 Atmospheres with concentrations of known substances greater than protection factors associated with full-face air-purifying respirators with appropriate cartridges
3 Atmospheres with less than 195 oxygen
B When a determination is made that potential exposure to the body parts not protected by a fully encapsulated suit (primarily neck ears etc) is highly unlikely
1 Known absence of cutaneous or percutaneous hazards
2 Activities performed preclude splashing of individuals
C Level B protection is recommended as the lowest level of protecshytion for initial entries until the hazards have been further identified and defined by monitoring sampling and other reliable methods of analysis and personnel protection equipment commensurate with these findings utilized
21
LEVEL C
1 Personal Protective Equipment
Full-face or half-face air purifying respirator (MSHANIOSH approved)
Chemical-resistant clothing
Gloves - Outer (chemical-protective)
Gloves - Inner (tight-fitting chemical-resistant type (or woven liners)
Hard Hat (face shield optional)
Boots - Outer (chemical-protective heavy rubber throw aways)
Boots - Inner (chemical-protective steel toe and shank)
2-way radio comnunications
Safety glasses required with half-face respirator
2 Criteria for Use
A Site known to contain potentially hazardous materials exceeding
1 Air concentrations requiring a protection factor no greater than that afforded by a full-face mask
2 Harmful levels to unprotected body areas (face neck etc)
3 Well-documented reliable history of site and patterns of prior entry
C No evidence to suspect acute or chronic toxicity to exposed personnel
D Continuous air or personnel monitoring should occur while wearing Level C protection
22
LEVEL D
1 Person Protective Equipment
Chemical resistant aprons
BootsShoes - Safety or chemical-resistant steel toed boots
Boots - Outer (chemical-protective heavy rubber throw-away)
Half-face respirators immediately available
Safety glasses or safety goggles
Gloves
2 Criteria for Use
a No indication of airborne health hazards present
b No gross indications above background on the photoionizer andor organic vapor analyzer
c Continuous air or personnel monitoring should occur while wearing Level D protection
23
APPENDIX B
DECONTAMIHATION PROCEDURES
Depending upon activities and location on site it may be
necessary for personnel to decontaminate prior to leaving the conshy
taminated zone Procedures described below are typical for Level C
operations
Upon exiting downrange (contaminated) areas all personnel are
required to decontaminate by means of the following procedure
1 Place equipment in the Drop Zone at the Hotline
2 Enter the Decontamination Station
Boot Wash Walk through wash tub and scrub boots then rinse boots in second tube
Glove Wash In two pan wash scrub over gloves rinse set out to dry
2 Remove tyvek - if leaving the contamination reduction zone (CRZ) and proceed to clean zones
3 Dispose of heavily contaminated clothing and under gloves
4 Remove respirator
5 Use disposable gloves to clean equipment
6 Use a two bucket (washrinse) to decon respirators at the end of the working day or if they become heavily contami nated
The procedures for a typical Level B Decontamination are
outlined on the following page
TANK CHANGE 9
CONTAMINATION REDUCTION
ZONE
OUTER GLOVE REMOVAL
EXCLUSION ZONE
TAPE REMOVAL
BOOT COVER
GLOVE WASH
(bull)mdashQ-G--copyshySOOT COVEH SCOT COVES 4
REMOVAL GLOVE RINSE
SUITSAFETY BOOT WASH
SU1TSC8A78OOTGLOVE RINSE
SAFETY BOOT 10 REMOVAL
SCSA BACKPACK REMOVAL
SPLASH SUIT 12 REMOVAL
INNER GLOVE WASH
INNER GLOVE RINSE
FACE PIECE REMOVAL
INNER GLOVE 16 I REMOVAL
INNER CLOTHING REMOVAL
FIEUJ 19 REDRESS WASH
SEGREGATED EQUIPMENT
OROP
mdash -HOTLINE-shy
DECONTAMINATION LAYOUT LEVEL B PROTECTION
FIGURE A2-1
CONTAMINATION CONTROLLING
SUPPORT ZONE
25
APPENDIX C
PERSOHNEL AND RESPONSIBILITIES
Project Manager (PM)
Overall responsibility for all Project activates budget
schedule investigative operations safety personnel
On Site Coordinator (OSC)
Responsibility for activities at the site Primary responshy
sibilities include
1) Interfacing with the client state EPA media or other groups
2) Reviewing technical operations
3) Reviewing site safety in particular information supplied by the Site Safety Officer
4) Enforcing site safety and compliance with the Safety Plan
5) Directing Emergency Contingency operations
Safety Officer (SO)
Responsibility for directing the safety of operations and impleshy
menting the Safety Plan Specific responsibilities include
1 Assuring that appropriate personnel protective equipment is available and properly utilized by all site personnel
2 Assuring that personnel are aware of the provisions of this plan are instructed in the work practices necessary to ensure safety and in planned procedures for dealing with emergencies
3 Assuring that personnel are aware of the potential hazards associated with site operations
4 Supervising the monitoring of safety performance by all pershysonnel to ensure that required work practices are employed
26
APPENDIX D
PERSOHHEL CASUALTY
Personnel casualty would most likely result from either chemical
contamination heat-related problems physical injury from accidents
(ie falling lacerations etc) in performing the work or a comshy
bination of one or more of the above The appropriate action depends on
the type of injury involved with the priority being to assist the
casualty as soon as possible without endangering other personnel
Riysical and heat-related injuries can and should be treated
immediately with appropriate first-aid measures and follow-up medical
attention if necessary The injured worker(s) shall immediately move
out of the hot zone or if necessary be moved out by fellow workers as
soon as possible The OSC and Safety Officer shall be notified immeshy
diately and shall recommend further measures as needed
Chemical-related injuries require a much more cautious approach
so as to keep casualties to a minimum If a worker injured by chemical
ejqgtosure is able he shall notify the nearest co-worker and leave the hot
zone immediately- The co-worker shall ensure that the OSC and Safety
Officer are immediately informed and shall accompany the casualty from
the hot zone to the decontamination zone The OSC and Safety Officer
shall determine the appropriate measure
27
APPENDIX E
GUIDELINES FOR SITE OPERATIONS
In order to deal with the potential dangers of exposure and conshy
tamination of a hazardous waste site three zones are delineated
according to the degree of hazard The three zones are 1) Downrange
or Contamination Zone 2 Contamination Reduction Zone (CRZ) 3) Support
or Clean Zone
Downrange or Contamination Zone
The Contamination Zone is the active work area of the site which
encortpasses the areas where there is a potential for exposure and in
which investigative activities will occur (drilling sampling etc)
Within the Contamination Zone the designated level of hazard will be
established necessitating the utilization of personnel protective
equipment
Hot spots are those areas Downrange where observations instrushy
ment readings or specific activities indicate a high probability of
closure or contamination and may require an upgrade in the LPP in the
vicinity of the Hot Spot
Contamination Reduction Zone
The CRZ is an area between the Downrange and Support Zones where
decontamination of equipment and personnel occurs
28
Personnel entering the CRZ shall wear protective clothing and
carry the respiratory protection required for entry within the
Contamination Zone
Personnel working within the CRZ shall remain cognizant of the
CRZ in order to be prepared for any need to increase their level of proshy
tection within the CRZ
A decontamination station will be located at the outer perimeter
of the CRZ All personnel who have been within the Hot lane shall pass
through a decontamination procedure prior to re-entering the Support
Zone
Support or Clean Zone
The Support Zone is the outer area and may be considered to be
clear of contamination potential The command post will be located
within the Support Zone
a) The Command Post will serve as the OSCs headquarters and
will be equipped with
1 Communications
2 Safety Plans
3 First Aid Supplies
4 Analytical Equipment
5 Safety Equipment
APPENDIX B
WORK PLAN
WORK PLAN FOR
TROY MILLS LANDFILL TROY NEW HAMPSHIRE
DRUM EXCAVATION AND SAMPLING
Prepared by
NORHANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
1933
WORX PLAN FOR
TKOt MILLS LANDFILL TROT NEW HAMPSHIRE
DRUM EXCAVATION AHD SAMPLING
DATS November 16-18 1983
PURPOSE
To determine the condition of drums (ie erroty or full
crushed rusted leaking etc) buried in the Troy Mills Landfill To
obtain representative samples toward identifying the types of materials
buried in the landfill This information will be used in the detershy
mination of the level of remedial action needed at the site
METHOD
Using the results of the magnetometer survey the (10) points
have been randomly chosen across the area where the buried drans are
expected to be found Each point is central to an Excavation Location
-- an area four (4) to six (6) feet in diameter which will be excavated
in order to characterize the condition of the drams and to obtain waste
sarples
Preliminary observations have indicated that many of the drums
may be buried within 1-2 feet of the surface Therefore the investigashy
tion will proceed in two phases
Phase 1 mdash Hand Excavation By digging several small holes in
each Location personnel will determine if drums are located within
about one to two feet of the surface If drums are encountered the
excavation will proceed by hand uncovering the dnris for evaluation and
sampling Where drums are not encountered near the surface excavation
at this location will be postponed until Phase 2
Phase 2 mdash HandBackhoe Excavation After all Locations have
been attempted during Phase 1 those Locations in which drums were not
encountered wall be further excavated using a combination of hand
backhoe digging
It is expected that one to two days will be necessary to
cor^piete each phase Depending upon the results of Phase 1 it may not
be necessary to iroleraent Phase 2
Spare drums will be on hand for containerizing any significant
spillage resulting from sampling efforts Excavation locations will be
identified with marked stakes and the holes will be backfilled at the
conclusion of the investigation
SPECIFICS
Excavation Locations (Holes)
Number of proposed excavations is ten (10)
Locations of excavations are presented in Appendix A
Hole Size mdash It is expected that a hole from four (4) feet to six (6) feet in diameter at the bottom (depth at which drums are encountered) will be sufficient to characterize the drums at each Location Deeper excavations will require increasingly large top diameters
Hole Depth -- Holes will be excavated to a maximum depth of six (6) feet Due to the sandy cover material the excavation of deeper holes is probably impractical from both safety and efficiency stand points
If after attempting excavation at each of t-ie 10 proposed
1ocatiors irums are not encountered within six (6) fet of the surf ice
in enough locations to characterize the site excavations nay be
attempted to depths greater than six (6) feet if scil stability permits
or a new set of sampling locations may be chosen
(Excavations to depths greater than six (6) feet require a
significant increase in work The sides of the hole crust be graded back
to less than 45deg in order to insure the safety of investigatorysampling
personnel It may also be necessary to employ bracing bulkheads etc
for trench support)
Excavation Identification
Proposed excavation Locations have been consecutively numbered
from 1 to 10 beginning at the east end of the landfill They will be
marked with numbered stakes
Excavation Methods
Phase 1 mdash Within each Location personnel will dig a nunber of
small holes - about one (1) foot in depth - to probe for drums If
druns are encountered they will continue to excavate until the drur3
are sufficiently uncovered for characterization
Phase 2 mdash After hand probing the Location with snail holes
the backhoe will remove cover material to the one (1) foot depth The
Location will then be probed to a two (2) foot depth before removing
further material Excavation will proceed alternating handprobing and
backhoe excavation until drums are encountered or the maximum six (6)
foot depth is reached
If excavations to depths greater than six (6) feet are undershy
taken they will proceed using the above method
Santnlea
Due to the effort involved in excavating and because conshycentrated waste samples are not expected to undergo rapid degradation it is considered expedient to obtain all readily available samples (exclusive of closed drum samples -- see belcw) These can then be submitted for laboratory characterization as determined by need and budget restrictions
An attempt will be trade to secure at least one sample froa each excavation in order to help characterize the distrishybution of waste materials across the site An attempt will also be made to secure samples of observably difshyferent materials
Sample Types and Mediums - Solid liquid and sludge samples are possible Samples will be obtained from in order of preference -- 1) leakage uncontainerized waste or contaminated soil 2) waste contained in open conshytainers - drum already has a hole or no top or other access point 3) sealed containers
The opening of closed containers will be considered if it is decided that it has not been possible to obtain a sufshyficient number of representative samples from the other mediums
Each sample will consist of two (2) 8-oz jars (with teflon-lids) filled about 23 full One jar will be for organic analysis and the other for inorganic analysis
Sanole Identification - Samples will be identified with a number corresponding to the Excavation Location and a letter Example if three samples were obtained from Location 2 they would be samples 2A 23 and 2C and Samples 2Ad 23d and 2Cd for duplicates
Sampling Methods and Volumes - 11 mm hollow glass tubing trowels disposable scoops will be available to obtain samples Samples tools will be disposed of or deconshytaminated between each sample
Drum Samples - If necessary an attempt will be cude to obtain samples from sealed drums Oily o^und non-rusted drums will be considered Bunjs rust be xn suitable conshydition -jo that the dram cm be openoi withrut cvis ing dainai -ind ca-i be resell od to pr-jvcrt l V-i 30
There wil l be no staging or movement of drums in order to faci l i tate sampling Only drums with accessible bungs will be considered for sampling
Procedure for Drum Sampling
1) Excavate around top of drum
2) Monitor air in the adjacent area
3) Chec for shock sensitive - Loop rope around top of drum stand at a distance give drum several hard jogs by pulling on the rope An alternative nethod is to lightly jog the drum with the backhoe bucket
4) If the drum is not upright place a catch basin under the bung
5) Open drum with bung wrench
6) Monitor the air atin bung
7) Sample drum -- liquids insert glass tube the fu l l length into the drum in order to obtain a column of the materials in the drum Solids use scoop to dig out material through the bung or use a sampling trowel
3) Reseal the dram
Spill Control
The possibility exists during the sampling and excavation for a
drum to be ruptured or otherwise have spillage Clean drums wil l be on
hand to receive significant spillage resulting frora sampling or excavashy
tion They will not be used for clean up of widespread uncontainerized
waste or existing leakage
Personnel
The work team will require four (4) persons (exclusive of the
backhoe opera tor) Trie downrange team will consist of three (3) persons
-- two (2) for d igg ing and sampl ing and on ( 1 ) for logging air moni shy
toring and photographing One (1) person will be at the hotline in
support mdash as safety backup person to fill air bottles to deconshy
taminate samoles to assist in decontamination of personnel
Documentation Logging
The following information will be recorded at each location
nmber of drums uncovered and the condition (crushed empty rusted
sealed etc) of each drum evidence of spillage or contaminated soil
labels on uncovered drums samples (time drum ID type description)
periodic air monitoring information depth at which specific events
occur or drums are buried soil condition presence of ground water
In addition photographs will be taken of specific events or
items of importance during each excavation and of each sampling incishy
dent The time description of subject photographer excavation
location and photo number will be logged for each photograph
Analytical Laboratories and Schedule
RAI Hampton NH
Initial schedule
Ten samples for GCrns for organic priority pollutants Samples may also be submitted for inorganic anlaysis or volatile organic analysis depending upon waste materials observed during the excavation
APPENDIX A
TABLE A-1 EXCAVATION LOCATIONS
EXCAVATION BASELINE RANDOM RANDOM
NUMBER GRID COORD SEGMENT STATIOH OFFSET
1 7E+1 565N 0- 60 26 (25) 16
2 9E+5 13S 60-120 50 (110) 9
3 8E+0 31S 120-180 20 (140) 7
4 4E+5 483 180-240 50 (230) 25
5 3E+3 45S 240-300 14 (254) 20
6 OE+6 5S 300-360 34 ( 334) 50
7 2W1 5 24N 360-420 45 (-155) 14
8 5W+6 42N 420-480 38 (518) 20
9 6W+1474N 480-540 8 (543) 7
10 8W 5 11011 540-600 11 (611) 31
Locations are plotted on Map A-1
Method of Choice A stratified random sampling method was used to choose 10 Excavation Locations within the magnetic anomaly
The axis of the magnetic anomaly was used as a base line and divided into ten 60 foot long segments Using a randora nirnbers table a distance along each secpent was chosen (Random Station) and a line drawn at that point perpendicular to the base line Again using a random numbers table a distance was located along each perpendicular line by measuring inward from the line denoting the edge of Area A (Random Offset) The Grid Coordinates for each of the Excavation Locations were graphically determined from the grid overlay (this overlay has been surveyed and intersections field located)
It was judged that 10 excavation locations within the magnetic zone and two outside of the zone would be sufficient to characterize the area would produce statistically valid iati and coli be expected to be co~letod within 2-3 days work period
to
80
cu0
cgtc
APPENDIX C
MAGNETIC INVESTIGATION TROY MILLS INC LANDFILL SITE
TROY NEW HAMPSHIRE
For
NORMANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
By
JOHN F KICK PhD GEOPHYSICIST
Box 6 Dunstable Massachusetts 01827
(617) 649-6650
Noverber 19S3
MAGNETIC INVESTIGATION
TROY MILLS INC LANDFILL SITE
TROY NEK HAMPSHIRE
INTRODUCTION
A high resolution ragnetic investigation was completed on the Troy
Mills Inc landfill site in Troy New Hampshire by John F Kick
Consulting Geophysicist The purpose of the investigation was to
delineate the extent of buried steel drums under closed portions of the
Troy Mills landfill The information is needed as a part of a study of
the landfill that is being conducted by Normandeau Associates Inc
FIELDKORK
Magnetometer measurements of total field intensity were made over an
area that was reported to contain buried steel drums and adjacent
landfilled areas that contained unknown waste materials The area of
investigation included capped and grassed closed areas along the south
margin of the landfill site and adjacent areas The fieldwork was
performed during October of 1983
Eighteen parallel rows of measurements were conducted along north-
south lines (using magnetic compass directions) A spacing of 20-feet
was used between rows and magnetometer measurements were made at 10-foot
intervals along the rows Greater intervals between measurements were
used at the ends of the rows and in periferal areas with low magnetic
-JF Kick 01shy
field gradients
A series of magnetic field measurements were made at an adjacent
base station throughout the survey to torn the basis for a daily
variation curve The base station was located at a site with typical low-
gradient background magnetic field intensity measurements
MAGNETIC SEARCH METHOD
Theory Magnetic search methods involve the detection and
measurement of anomalies in the Earths magnetic field caused by the
presence of materials with contrasting magnetic susceptibility Iron and
steel objects generally have very high magnetic susceptibility contrasts
with usual surrounding materials and therefore produce magnetic
anomalies The amplitude shape and detectable distance of the anomaly
depend mostly on the particular susceptibility contrast and size of the
object Magnetic anomalies are measured in units called gammas The
normal magnetic field in this area is over 50000 gammas A 5-inch
screwdriver will produce an anomaly of 5 to 10 gammas at a depth of 5
feet and an anomaly of 1 gamma at a depth of 10 feet A 1 ton automobile
will produce an anomaly of 40 gammas at a depth of 30 feet and an anomaly
of 1 gamma at a depth of 100 feet The magnitude of an anomaly caused by
a single steel drum will vary with its condition (new heavily rusted
etc) Tests using a single light weight (somewhat rusted) drum on the
surface with the magnetic detector at a height of of 12 feet produced an
anomaly in the range of 40 to 50 gammas
Total magnetic intensity disturbances or anomalies are almost always
asymmetrical sometimes appear complex even from simple sources and
usually exhibit the combined magnetic effects of several sources which
can produce a given anomaly The apparent complexity of such anomalies
is a result of several relatively simple functions of magnetic dipole
-JF Kick 02shy
behavior Reasonable assumptions about the geology and buried source
conbined with an understanding of magnetic dipole behavior can usually
lead to a satisfactory qualitative interpretation More detailed
interpretations nay require modeling studies
Instrumentation Field equipment on this project included a EGampG
Geometries Memory-Mag G-856 proton precession magnetmeter The
instrument has a resolution of +01 gamma The magnetic field detector
is separate from the rest of the instrument and is mounted on an 8-foot
staff to provide measurements that are a constant height above land
surface
Magnetic Data Analysis For the purposes of data reduction and
anomaly delineation it was assumed that base station total field
intensity measurements were typical background values for the site
Measurements made at frequent intervals at the base station were used to
prepare a diurnal variation curve for the site Anoraly values were
obtained by subtracting background values from the base station curve
from measurements collected in the area of investigation
RESULTS
The reduced results are presented in the form of a magnetic anomaly
contour map (Figure 1) and two profiles across the area of investigation
(Figures 2 and 3) The map and profiles show that very steep magnetic
field gradients and large departures form background occur in an
irregular shaped band that is about 460 feet long and ranges from about
30 to about 200 feet in width The magnitude of the anomaly is such that
a significant deposit of ferromagnetic materials (such as steel drums) is
indicated
In using the plotted magnetic results it should be noted that the
greatest concentrations of ferromagnetic materials probably do not
-JF Kick 03shy
directly underlie the peak magnetic anomalies A shift is caused by the
inclination of the Earths magnetic field and by the dipolar nature of
ferromagnetic deposits The inclination of the Earths field is about 76shy
degrees northward in the vicinity of Troy The dipolar effect is induced
by the Earths field and results in negative anomalies immediately north
of large positive anomalies
Magnetic Anomaly Map The magnetic anomaly map (Figure 1) indicates
10 positive peaks of varying size shape and intensity Associated
negative anomalies of a broader and less intense nature lie immediately
north of the belt of positive anomalies The configuration of the
anomalous area is indicative of lense-shaped and cigar-shaped bodies of
ferromagnetic materials Steep-sloped anomalies are indicative of very
shallow source materials The thickness of the ferromagnetic deposit
cannot be easily determined on the basis of intensity and size of
anomalous peaks because a small mass of iron or steel at the surface can
duplicate the anomaly caused by a much larger mass at depth The
ferromagnetic source materials can generally be expected to lie north of
the positive peak of anomalies and south of the adjacent negative
anomaly Modeling can provide the best approximations of the depth and
density of the ferromagnetic source materials The outer boundaries of
the source materials can be expected to overlap the positive peak and
negative anomaly somewhat depending on the depth and configuration of
the deposit
For illustration purposes two north-south rows that were profiled
are discussed below
Magnetic Anomaly Along Row 9-East Two strong positive magnetic
anomalies (3645 and 2436 gammas) and adjacent negative anomalies were
profiled along Row 9-East (Figure 2) The approximate centers of the
ferromagnetic deposits are believed to underlie stations 50 north and 75
feet south of the base line The rounded shape of the north positive
-JF Kick
anoraly nay indicate somewhat deeper burial of the ferromagnetic deposit
Magnetic Anomaly Alone Row 7-West Figure 3 shows the most intense
positive magnetic anomaly (4470 gammas) that was detected on this
project The steepeness of the slopes is indicative of very shallow
source materials An uneven burial pattern is suggested by the two-
peaked positive anoraly The negative anomaly south of the two peaks is
unusual and may be related to another positive anomaly to the southeast
(along Rows 5 and 6 20 feet north of the base line) The centers of the
sources of the positive anomalies are probably approximately 80 and 120
feet north of the base line along Row 7-West
-JF Kick 05shy
DISTANCE FROM BASE LINE(FEET)
CO
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6a
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LU CD
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i-mdash LU Lu 2 Q lt2 Z
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LU aIDCD Li_
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t o H
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UJ UJ en UJ u UJ
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CO
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0020
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APPENDIX D
LABORATORY ANALYSES
RAI
Resource Analysts Incorporated Box 4778 Hampton H 03842
(603) 92^7777
TO PO 830318
Mr Doug DeNatale Date Received 12-2-83 Kormandeau Associates 25 Nashua Road Lab Number 2887 Bedford NH 03102 J
Date Reported 1-3-84
IDENTIFICATION
SAMPLE DESIGNATION PARAMETER
Volatile Organics Analyses by EPA Method 624
Acid and BaseNeutral Extractable Compounds Analyzed by EPA Method 625
Metals Analyzed by Standard Methods 303A
Please see attachments for all results
Results expressed in mgL unless otherwise designated lt = Less Than
ClarkeFosterVan K o u w e i b r h 1 ANALYST DIRECTOR
METHODS Standard Methods (or the Examination ol Water and Waitewaler 15th Edition or other EPA approved mtlhodologiei unless otherwise designated
Phys ica l descr ip t ion of sample
LiquidSludop
Saiple workup
Volitile f ract ion Methannl F-1-rarMrm CSVJ Rdfi-Smm
Semivolatile f ra ictio0onication Extraction fSW 846-3540^ Inorganic f rac t on Acid Digestion (SW 84h-iOS(V)
ACS3 COMPOUNDS
rr t CAS CAS
(71 A) tt-Ot-2 i^t TT i^MoroprvrfgtOi (73B) 30-32-1
(23 A) J9-JO-7 ^bull^^ lof o^^ft^crt gto (7 OB) 205-M-2
(2 A) 13-37 -J 2- chlorophenol (75B) 207-01-
(3 A) 120-13-2 2raquo^icMoroorgtenol (748) 211-01-9
(MA) 103-47-9 2-dimethv lohenol (77 B) 201-94-1
(37A) U-73-3 2- niiroDhenol (7IB) 120-12-7
(MA) 100-02-7 raquo-niiroprienol (7raquoB) lraquol-2raquo-2
(raquoA) Jl-21-3 2 - in i tr opheno 1 (106) raquoi-73-7
(40 A) 33-J7-l k4-dinnro-2-mlaquothylplaquogtergtol (I IB) 15-01-1
(4A) I7-U-3 (xntictiloroorraquonol (I2B) J3-70-3
USA) 101-93-2 pxmol (I3B) 193-39-J
(14 B) 179-00-0 RASENEUTOAL COMPOUNDS
( I B ) 13-32- raquocmlaquophtgtgtefgtlaquo
(36) 92-173 benzidine (2V) 107-02-S
( I B ) I20-I2-I l2t-tricMorobenzlaquonlt (3V) 10713-1
OB) 111-71-1 he laquo laquoch 1 or o benz erve (laquoV) 71-A3-2
(176) 47-72-1 hetraquocWoroltthlaquone (4V) X-23-5
U S B ) 111-- bu(7-cloroetrivl)ether (7V) 101- 90-7
(7CB) 9 I -3J -7 2-Chlororuprthraquolene (10V) 107-04-2
(73B) 95-50-1 l2-diCMoroblaquonzene ( I 1 V ) 7|3j^
( K B ) XI-73-1 13-didilorobtnzene (13V) 7J-3-3
(27B) 104-M7 1tmdash djcMorobenzene dkV) 79-00-3
C2IS) 9i9i-l 33-dictgtloroblaquoazidinr ( I JV) laquo-3-J
(33B) 12I -U-7 2gt-dinicrotoluer (14V) 7J-00-3 (KB) 4O4-7C-7 24-dinitrotoluene (UV) 110-73-1 (J7B) 122-A4-7 1J -diprienv lhydrraquo z irf (23V) lt7 tt 3
(MB) Z0-fc-0 UuorraquonThelaquo (2raquoV) 7J-35-
(W551 700J77-3 -ctilorophenyl prlaquonyl ether (JOV) 1M-40-3
( raquo I 6 ) 10I-J3-3 raquo-6romoprgtefgtyl prtenyl ether (32V) 71-17-3
(raquo7B) 33132-9 bU (2-cMorobopropyl) ether (33V) 10041-02-4
(raquoJ6) i l l -91- l bu (2-laquo^loroeTho)ry) methane 10041-01-03
(B) D-U) hexraquopoundj1|orobutaltlicne (31 V) 100--
(33B) 77-raquo7- heiKCtilorocycIopentadicrve (WV) 7J-CT-2
OB) 7IJraquo-I traquoo oh or or (raquo3V) 7raquo-17-3
(J3B) gtl-20-3 nphthraquolene (UV) 7raquo-I3-9
(546) n-tj) nitrobenzene (7V) 7J-2J-7
(426) U-Xl-4 bullJ -n itr o tod iphenyU mi ne (UV) 75-27-J
(OR) 421-W-7 N-oitrcnodipropYlirrUne ^raquoraquoV) 73-49-k
(446) I 1 7 J I - 7 bu (2-eltr^lheryl) phtfaUte 8200 (3ov) 73-71-1
(476) 13-U7 benzyl buryl phttwlite (51V) 124-kt-l
( U B I M-71-2 di-fl-utgtl pMhUre (13V) 177-II-
( lraquo6) 117-1 -0 dj-n-octvl prithlaquoUte (UV) 101-IS-3
(7CB) W-44-2 dielhvlphtraquollaquo (17V) 79-OI-t
( 7 | B ) I 3 I - I I - J dj^laquorTvipnthraquoUtr (UV) 7J-OI- (776) H-J5-5 bnro(raquogtnthrraquocefvr
Iab I D N o 2SS-10
C l ien t ID 1A64223
RASENEUTRAL COMPOUNDS
bfzoltraquogtprrene
benzoltb)flucrraquornNene
benio(llaquo)fluorraquonthene
chryiene
bullcenaDhthvien
raquontnrraquoctne
benzoltghi)perrlefgte
Iluorene
phergtraquonthrmlaquo
dibenzoltraquoMaithrraquocenraquo
indeno(123-cd)pvrene
prrene
VOLATHES
(frolein
bullcrvlooitrdf
benien
orbon Temchloide
CMorobeniene
1 7-dJchlorolaquothnr
111-trieftloroethine
ll-ltJichloroetrufle ll7-triCilorigtetMrlaquor
l127-tetrraquocMorothfllaquo
chloroethlaquo-e
7-dMoroeThraquo|virgtvl eirwshy
chloroform
11-didMoro^tfwnr
trinj- 1 2-dictMorolaquoirgtene
1 7-ltlicMoroproplaquorve
trini- 1 3-ltJichloroorcrpeoe
cu-lJ-lieMorocT oo eashy
rthy Uveniene
methrlene chloridf
chloromethine
bromome thraquone
bro mod iCTi lore met Mrgt
(Juorotr ichloromthraquor
di cMlor od 1 f 1 uore ngtet hj^gt
chloreltJbnjmomethne
te tr ten 1 or oet rx-r
laquouene 12000
tncMeroethe^e
Cidrr ium Chromiutr 10
All results are expressed as ucg veicht as received Nc ertrv denotes -0r ~ ^ 1 i rt
P h y s i c a l d e s c r i p t i o n of
SoilSludge
sample
Sanple workup
Vol i t i le f ract ion p^r Exf- rar r ion fST7Semivola t i le f rac t ion So^h^Pt Fgtr f ra r f ion
846-SOTO^ (SWRdfi-^SiO1)
Inorganic fract ion Ar id nio-psrirm
AOD COMPOUNDS
m CAS (2i A) tt-04-2 2raquot- Wichlorophenol
(22 A) J1-50-7 p-cfi I or o-n-cre laquoo 1
(2A) 13-57-1 2- ctiloroprienol
O iA) 120-13-2 2raquo^icMoroprnol
(gtraquoA) 103-47-1 2f 4mdash^imetSv Ip^enol
(37 A) U-73-3 7mdash Ti j oprtenol
(JraquoA) 100-07-7 mdash mdasho i Br opr^e no 1
JJ1A) 31-21-3 if mdash4 irtiTroprienol
(40A) J34-32-1 4 T4-4initrogtmdash 7 nte tny Ipnenol
(4A) f y _H 5 plaquontchlaroorwnol
(43A) J 01-95-7 prienol
rV ipoundNEUTRAlaquo- COMPOUNDS
( I B ) raquoJ-32-raquo
(3B) 17-17-5
( IB) 170-12-1
(IB) 1I1-7I-I
(17B) 4777-1
( I t B ) 111--
(20B) 11-31-7
(236) 15-50-1
(245) 51-73-1
(77B) 104-4-7
(285) 11-14-1
(336) 121-142
(34B) 404-70-2
(J7B) 127-M7
O1B) 2O4--0
(406) 7003-72-3
(416) 101-35-3 lt raquo 2 6 gt 3H3I32-1 ltraquo36) 111-11-1 (57B) S7-U-3
(336) 77 -raquo7-
(36) 71-31-1
(33B) 11-20-3
pound34 6 1 n-i33 (UB) tt-30-4
(436) CI-44-7
(4461 117-11-7
(47B) U-417
( U B I 14-747
(U6) I17_t-0
(7CS) l-laquo2
(7 I B ) t J U t l - gt
(7761 54-55-3
CT-~- i_i w i Miirn 0
resul ts
b^TMdint
1 2 t-o- icn lorobenl ergtlaquo
SeTraquochloroblaquorierraquoe
hrxchlorolaquotSlaquone
bu(2-chloroethv|gtether
2 -lt3M or onraquo ph ti1 ene
1 2-ltJictilorotgtmzcne
13-dicWorotxerzene
1 4-djch 1 or otxn z ergte
33-ditfgtlorolgtlaquoniidirraquo
24-dinitrotoloene
2 4-dtnitro toluene
U-dlpoenylfiydrraquoiilaquo
(luoranthene
raquo-cfJorophenyl poenyl ether
Mx-omopfieflyl phenyl ether
bis (2-cMorooopropyt) ether
bu (2-ctilorcxtSorv) meiSkte
hezkOilorobutadicne
hei acM or ocyc1 ofMn udi cne
oo prior one
nphthlene
nurotxniene N -ni tro Kxd ipoenyU mi ne
N-rutrowxhpropYUmJrw
bu (2-thylherl)(gthlaquoiraquoUtraquo
blaquoniyl buryl phtfraquolaquoUte
dt-^t-^xjrvl pfttfuiLitY
dj-n-octyl pitflaquoLitraquo
dirthvl phtruUtt
OArriett^vt prraquoT^Lraquot
bnzoltklaquonihnicer
22 Chronium
ire ev^rescei as uc ^ ^i-~ht-
Lab 1U N o 28B-1
C l i en t I D 1 R R 7 A A R
RASpoundNEbTRAL COMPOUNDS
benroltb)fluorraquorgtthfflf
benzoraquollt)fluor intone
ltrylaquo-gte
bullcenioithylen
raquomtirraquoenlaquo
ben z oltxh i)per v lene
lloorene
poentnthrrne
dibnzo(4h)laquonthricrne
mdeno(I23-rt)pvre-ie
pyrene
VOLATU-Ei
bullcrelem
bullcrvlonio-Ue
benzene
caj-bon traquotrraquochloraquo-idr
Ctilorobernene
l2-diehlongtethne
iii-tnctltiorotKraquor Trace 1 T 1 -4)Ctilorampe^hArw
l f 1 ^-tric^i lor oefvtrve
l t l 22-teTrtclloroetl^Ane
ehloroethraquone
2-chloroltthr|viw| ttrve-
Chloroform
1 1 -ltSicMorot^nr
trinraquo-l2-dictiloroetrne
12-d^loropOStn
trinil3^ichloroproone
eis-lJ-diChloroprooene
rrhylberuene Tarce methrlene ehlor tat Trace
Ct1 or o m e t Kirgte
bromometKtrte
bro mod i rfi lor o rrgte t Mne
Uuorotrlchloromethraquo^e
OJ CJ lor od 1 f 1 uoro met hraquone
chJorodibromometKATgte
laquotrlaquociloroethrrx
toluene 9
tricolor otheir
fsw
T9
Sifi-TOSO)
(73B)
(7IB)
(75B)
(7(B)
(77 B)
(71 B)
(71B)
(SOB)
( t lB)
(I2B)
U3B)
(M B)
(7V)
(3V)
(4V)
(4V)
(7V)
(10V)
(11V)
(13V)
(14V)
(13V)
(14V)
(11V)
(23V)
(21V)
(30V)
(32V)
(33V)
(34V)
ltlaquoV)
( raquo J V )
(44 V)
f raquo 7 V )
(UV)
(V)
000 (30V)
Tlfl 151V)
(15V)
^00 (14V)
(17V)
(UVgt
-1 ZINT
CAS 30-32-J
205-11-7
207-01-1
211-01-1
201-14-1
120-12-7
111-24-2
14-73-7
13-01 -laquo
33-70-3
113-31-5
121-00-0
107-07-t
107-13-1
71-43-7
34-23-3
101-W-7
107-04-7
71-35-t
75-3-3
7^-00-5
71-34-5
75-00-3
110-73-1
(7-14-3
73-35-4
154-40-5
71-17-5
10041-07-6
10041-01-05
100-4I-
73-OT-2
74-17-3
74-13-1
73-25-2
75-27-4
73-41-4
75-71-1
174-41-1
127-U- IOUIS-) 71-01- 75-OI-
130
Lab ID Mo 2887-4
Phys i ca l d e s c r i p t i o n of sample C l i en t ID 4A5760
Liquid Sample was predominantlv a hvrlrnrarhnn bl pnd
Sanple workup Voli t i le f ract ion PEG Extraction (SW 846-5030) Scrnivola t ile f rac t ion Sonication Extraction (SW 846-3550) Inorganic f rac t ion Acid Digestion (SW 846-3050)
AC3D CS3U POUNDS 5AipoundNEUTlUgtJ- COMPOUNDS
ri CAS PPraquo CASf
(210 U-04-2 2raquot- tricMorophrnol (7)6) raquo-32-l braquoniolttVyre
[EM 51-50-7 ^-cti 1 or raquo-m-lt rlaquo laquoo 1 (7raquoB) 203-M-2 biMo(b)(luorinth^f
2 A) raquo5-57-J 2- cfiloropheryjl (7 3 B) 20701 benro(ilt) floor in tlaquo^e
(31 A) 120J3-2 2raquo-ltJicWoro(ygtlaquotx)l (74B) 2II-OI- chryve^e
(MA) 105-47- 2l-dimlaquothvloSrrgtol (77 B) 20Uraquot-J bullcwrioMhylene
(57A) u-73-3 2- ruTroohrgtol (TIB) 120-12-7 raquontnncergte
(34 A) 100-02-7 -oitrophenol (7gtB) lraquol-2raquo-2 benio(ghi)cgtrrylngtlaquo
(3Agt 51- 21-3 2 -4 initropherwl (SOB) tt-73-7 fluorme
(tOA) 53-37-l t-dinitro-2-mlaquothy lpNlaquoxil (II B) 15-01-4 pheAinthrrnlaquo
(A) I7-U-5 tgtentraquochlQroiywnol (I2B) 53-70-3 dibenplusmnoltraquoh)fcnthrraquocrne UJJ 101-55-2 rfwtwl (I3B) lraquo3-3raquo-3 indenol 1 23-cd)vrtie
(UB) I2raquo^X3-0 pyrer BASENEUTOAL COMPOUNDS
VOLATO-ES (161 I3-32- raquoclaquonraquophttgtngtf
(5B) 12-17 -J btniidir (2V) gt 07 -07-1 bullcrolem
(IB) 120-17-1 l^^iricfvleroboMux (3V) 107-13-1 bullcrvlonit Jlaquo (raquoBI IIS-7t| SeraquoChlorotgtlaquoterlaquo (raquoV) 7IJ3-7 benient
(I7S) 4772-1 heLCMorolaquothinc (tV) J-23-5 crtgton wtrraquocMoidf (UB) I11-U-I bll(2lttllorolaquot^w gtetNer (7V) 101-W-7 ltAtoroxniergtlaquo
(203) Jl-31-7 2 -etvl or onlaquo ph traquo I en e (IOV) 107-04-2 1 2-ltlicMorolaquoTKlaquone
(25B) raquo5-30-l 1 2-dichlorobenzene ( 1 1 V ) 71-JJ-t llI-trichlorolaquotNlaquoe (2 B) 31-73-1 l3-ltlichoroblaquonzenlaquo (13V) 7J-3A-) 1 1-6 1 cM or Of t (Mr
(77B) I04-M7 I -di CM oro ben z eoe ( I k V ) rraquo-oo-j l12-niichlorolaquotfvirraquolaquo
(2IB) raquol-raquo-l )J-dichlcroblaquorLiidinr (IJV) rgt-3laquo-3 J122-tetrraquochlcrolaquoTrie
(33B) 12I-Ilaquo 2 2-dinia-otoluer (UV) 73-00-3 Ctgtloroltthne U4B) laquoJ-70-7 2 t-dtnitrotoluene (1raquoV) HO-73-1 2-ltJilorocthv|vL-v| etrveshy
(J7B) 127-M7 14-dip^wnylhydraiine (23V) C7-U^-3 Ctilorofcrm
(JraquoBJ 2Ot-ugt-0 CJuarlLnthefe (2raquoV) 7J-33- 11 -ltlicMorcxil^nr
(mei TOCJ-77-3 -chJorophcnyl phenyl laquoKr (xgtvraquo lK-^0-3 tnjM-l^-diC^lofCKtl^nf
( M B I IOI-J5-3 -6romophnyl phenyl ether (32V) 7I-J7-3 12-dicMoroprosaA
(raquo2B) 3M3I32) bU (2-cMarobopropyU rtNer (3JV) ICXU 1-07-4 trraquoni- 1 3-ltjictgtloroBoor^f
(OB) t l l f l - 1 bi5 (2-cMoroetfxgtrv) meihtrw lOOt 1-01-03 cu-O-dichloroprose- (32B) D-U-3 hrxaetilorobutadierw (UV) 100-laquol-raquo rthylbenien 1^00
(33B) 77^7- he i kcMor ocyc 1 openudi crw (UV) 7J-OT-2 rrveThvlerw chlof idf
(36) 7I-gtraquo| oop^troo (raquoJV) 7raquoJ7-3 CtgtlorBmethne
(338) raquo|20-3 nraquopfitfillaquofx 1200 (wv) 7raquo-l3-raquo bromorrgtlaquothne
(34B) nraquo3) nitrobenzene (raquo7V) 73-23-2
(CBI U-Xl-4 N -fl i iro lod iphen yU mi nr (UV) 7J-27- bro mod i cti lor o mT bull- (OR) 42l^-7 N-^itrolaquoodipropylmlrlte (raquoraquoV) 73-traquo-laquo tl uor o tr i cfi lor o mlaquoT itr (UB) I I 7 J I - 7 bn (^thylheraquoy|) phttilaquoUtT 110000 (XIV) 75-71J QJ ct )or oltJ 1 f 1 uoro rrgtei ^bull gte U76) U-U7 blaquonzyl buryl pttTfKUie 12000 ( j i v ) m-i-i ctil or od ib ro mo met h xnf (UB) M-7i2 d i -n -bo TV 1 ft thlaquo U tlaquo (13V) 127-11- te trraquo cfl lor ot hlaquoTgtf (OBI 117-4J-0 dj -n -oc t y1 Jgth fflaquo U re 6 200 tuv) iom-3 tolucie ^70
(7CB) u-u- djrthyl phtJMlire (17V) 7raquo-OI-4 irictilarcraquo^lt-ir (715) 1 3 1 - 1 1 - 5 oVnrrhyl pMtfaUte (UV) 75-OI- v i M v l CMor idr
(T76I 5-55-3 blaquorgtzo( Unihrlaquocme Xylenes 1SOO
Cad- iurn 2 2 on Chromium - - Z I N C ^ ~ P r
Ai results arc expressed as ugc weight as received Xo entry denotes not detects
Lab ID No 2887-3 5A 57709 Phys ica l d e s c r i p t i o n of sample Cl ien t ID
LiquidSludge Liquid appeared to be a hvdrnc-Arhnn blonrl
Sample workup
Vol i t i l e f r ac t ion Methanol Extraction fSW 846-5030^ Semivolatile fract ion Sonicatlon Extraction fSW 84 f i_3550gt) Inorganic f rac t ion Acid nic-psr-inn fSW 846-30501
ACS3 COMPOUNDS BASENEUTRAL COMPOUNDS
f f t CAS CAS (2IA) tt-04-2 (738) JO-32-J DCftZ OTamp p V^^^ff
(22 A) 3laquo9-50-7 p-cttl or o-m-cre laquoo 1 (7VB) 205-99-2 p^^izot oil lyor 4-^ t ^ltf ^^
(2 A) raquo5-37-l 2- CJiloroprieno (75B) 207-01-9 blaquonioltllt)flultxtn^it
(31A) 120-13-2 2raquo-dictgtlcr8tgtrfX)l (74B) 211-01-9 Chryeolaquo
(3 A) 103-47-9 2 -d irrgtet hv Ipherto1 (77B) 201-94-1 laquocnphthyle^
(37 A) 11-73-5 2- rutrop^enol (7IB) 120-12-7 bull^thrjc c^
(MA) 100-02-7 -flitroprlaquorv3l (79B) 91-2-2 bcnroltKhi)pefraquoler
(79A) 31-21-3 2 -d in itr eoricno 1 (IOB) 14-73-7 tluoren
(40 A) 33-37-l 4-d in itr raquo-2 -met hy Iphtnol ( I IB) 13-01-1 poltrtAOthrvTgt^
(44 A) 17-14-3 plaquon1 CM or o^eno I (I2B) 33-70-3 dib^fi-o( 4(K)Aji thirl c c^f (43A) 101-93-7 prwnol (S3B) 193-39-3 indcnotlIJ-ctflsvfie
(SB) 129-00-0 pyrene ftASENEUTRAL COMPOUNDS
( I D )
(5B) 92-X7-3 b^zidrw (2V) 107-02-1 bullcrolrm
(IB) 120-17-1 1 2 fc-Tr ICJ caro blaquoni crw (3V) 107-13-1 bullcrvlonitrij
(93) 1IU7I1 Seraquochlcrotgttniegtlaquo (4V) 71J3-2 blaquonienlaquo inn (17B) 4777-1 hexat^lorcwthgine (4V) H-23-5 carbon ttTricllixidf
( I I B ) 111-wJ bll(2-lt3^1oroltt^w)ether (7V) 101-90-7 ciloroblaquonzene
(20B) 91-31-7 2-ctdo-ont she Ime (10V) 107-04-2 12-dieftloroerane (25B) 95-50-1 l2-dilorobenzene ( 1 1 V ) 71-35-4 11 1 -tricMorotn-laquo
(2ampSI 51-73-1 13-dicMo-obenxerw (13V) 73-3-3 1 1 -d i CM orcxt M-
(77 B) I04-H-7 1 -di ci 1 or o benI erw (UV) 79-00-3 llJ-WiChlorolaquoflaquonlaquo
(2J6) 91-90-1 SS-dKJilorotxniidinc (13V) rraquo-3laquo-3 l122-tetrlaquocftlorelaquoTrne
(35B) 12| |k-2 2fc-dintrotoluene (14V) 73-00-3 diloroeth^e
(gt4B1 404-20-2 24-diniTrotoluenlaquo (19V) 110-73-1 2-cMortxfthv|vL-raquo trlaquoshy
(37B) 122-447 12-diphenylhydriin (23V) 47-44-3 cMoroform
(J9B) 204-U-0 Ouormntherve (29V) 73-33-i ll-diCMorolaquot^nf
(fcOB) 7005-77-3 k-cMarophfy| prlaquonyl etScr (gtOV) 134-40-3 trraquonraquo- 1 2 -dicMoroc t Nenf
(raquo I6) 101-35) raquo-6romoprny| phenyl rther (32V) 71-17-3 12-diChloropostn
(raquo2B) JH3IO2-9 bU (2-ltplusmnlaronopropyl) rthrr (J3V) 10041-02-4 trni-l)-diirMoroxtgtOpnf
(OB) I I 1 - 9 I - I bu (Z-chloroethxjrv) metSampnlaquo 10041-01-05 CU-D-djcMoroproOf-W
(32B) 17 -U -3 hiraquocfilarobutraquodiergtlt (3JV) 100-4U rttyligtlaquonitrgtlaquo 5300 (33B) 77-raquo7-raquo hrxicftl or ocrclopei tidier (UV) 75-09-2 nxthylenf ctilor ifif
lt3B) 71-391 ao prior or (raquo3V) 7raquo-17-3 rtloromrtha^r
(356) 91-20-3 nlaquoprithienraquo Trace (44V) 7raquo1Jraquo bromltmlaquoth^
(MB) n-93) ft i vo b^nz c^^ (raquo7V) 73-23-2
(425) U-30-4 ^bullf i^OftOOL^ri^ny lArrunf (UV) 73-27- bro mod i cgt lor o i~ t gt
U3amp1 Ul-4-7 N i itr CrtoO ip ro py 1 laquo ml r (raquo9V) 73-49-k U uor o IT 1 et loront Mrgt (UB) II7-1I-7 bu (2-Ihythlaquoryl)prtfUtr 59J300 (30V) 73-71-1 dj ci kr olt11 f 1 uoro rrrt (Nrgtraquo
(47 B) L3-41-7 txniyl burvl phthlaquoUtr ( 3 1 V ) I2-1-1 ch1 or od i b ro mo mi IMP r
(UBI U-71- 0-A-fcurl BMMliw (13V) 127-ll-i rt tr t cM or of tNr
Uraquo6) 117-li-O di-n-oCTv| pnttlaquoUfr 6000 (UV) lOt-II-3 toluenf 5700 (7CB) U-447 djrthvl p^tfvilirt (17V) 79-01-4 WiCMoroth^e ( 7 J B I U l - l l - 3 d^M^vl prttgtraquoUW (UV) 73-01- vinv t cMor 10 (77 Bgt H-35-) brto(raquollaquonthncrTraquo Xylenes 19000
Caen 1U~ 1 Chromium =2 Z I N C
All results are expressed as up g weight as received No errrv ripn^t-plt
Lab 1Lgt No 2887-5
rhyr i r n l d e s c r i p t i o n o f sample C l i e n t in 6857710
LiquidSludge
Sample workup Vol i t i l e f r a c t i o n PEG Extraction (SW 846-5030) Semivolat i le fr action Sonication Extraction (SW 846-3550) Inorganic f rac t ionAcid Digestion (SW 846-3030)
AOD COMPOUNDS BAStNELTTRAL COMPOUNDS
rr i CASI CAS (21 A) tt-04-7 (736) 30-32-1 bntoltraquogtprrene
(23A) 3-9-50-7 p~lt1 or o-m-c rraquo1 (78) 205-99-2 ben to( Sgt )1 1 uor raquon I he-gtf
(7raquoA) 93-37J 2- etilorophenol (73B) 207-01-9 beriioltk)(luortntrgt^f
(3 IA) 170J3-2 2raquo-dicMoroprnol (7(B) 2II-OI-9 eifVMTie
(3 A) 03-(7-9 24-4mlaquoThvlDheno| (77B) 20l-9(-i bullceraoMhyler
(37 A) tt-73-5 2- rue-oorienol (718) 1 20- 2-7 laquoflthrraquocene
(3 A) IOO-02-7 ^Mtroprwnol (7fB) 191-24-2 beraquoMoltsrM)plaquovllaquox
(39 A) 3I-71-5 2-4 ini tr ophero1 (tOamp) K-7J-7 tluwtrie
((OA) 33-37l (-lt iMtro-2-methylphenol (tlB) D-01-J phenATithrene
(4A) I7-44-J pentichlorophenol (128) J3-70-3 dilwnioltraquoh)laquonthrraquoceif
(OA) IOI-95-2 prwnol U38) 193-39-3 indeno(123-cd)vcne
(MB) 129-00-0 pyrergtlaquo 6 ASENEUTILW- COMPOUNDS
VOLATH-tS ( I B ) 13-32-9 ftCYTNA pO IT H I raquolt
(38) 92-17- o^nzioinc (7V) 107-02-1 aero le in
( IB) 120-I2-I l2k-o-i(3iloroblaquontergtlaquo (3V) 107-13-1 laquocrvlono-U
OB) Jl l-7fc | he I raquocti 1 or o blaquonI enlaquo (V) 71-43-2 Oltf2 tO^
(17B) (772-I he uc^i 1 or of t h ne ((V) 34-23-3 CJU JOO Tt TTlCfllo^ iCpound
( I I S ) bu(2-rfilcroethv|)ether (7V) 10J-90-7 laquoWoroblaquonzeoe III-44-4
(KB) 9I-51-7 2ltfMoronlaquoohttvraquolwe (10V) 107^)4-2 1 t2^ojo^loroetfft^c (2JB) 95-50-I 1 2 -dichlorotgtlaquorlene (11V) 71-55-4 1 1 1 -trichloroeihtr (251 541-73-I 13-dchlorotxniene (13V) 73-J4-3 1 1 -dieMoreeraquohraquorlaquo
(77Bgt 04-lgt4-7 1 mdash djcMorobenlene (IkV) 79-OO-3 t12-tricriloroeflaquofgte (2gtB) raquolraquo-l 33-didMoroblaquonjidirlaquo (13V) 79-34-3 1122-tetrcnicroeir^ne (33B) 12 I I 4 -2 Z4-diniiroioluerlte (1(Vgt 73-00-3 e^loroetruuie (KB) (04-7C2 2 (-dinitro toluene (19V) 110-73-4 2ltJilorolaquotr(v|vLnraquolnhlaquo (175) 122-447 12-dipr-enylfiydrmiine (23V) (7-44-3 chloroform
(J1B) 704JJ-O Huor^thrr (29V) 73-33-4 lI-ltJicMoroltthcne
(OBgt 7003-77-3 -ctJoroprienvl phenyl ether (JOV) 134-40-3 irirraquo-12-dictila-olaquotrlaquone
( raquo I B ) IOJ 33-3 -6ogtmoprienyl phenyl ether (32V) 7I-I7-3 l7^lichlorepreoine (laquo2BI 3H3raquoO2raquo bit (2-chlororaquoopfT5pyO ether (3JV) 10041-02-4 trint-l3-ltJicnloroBlt-ooee (OB) 111-11-1 bis (2-cMcroetro(v) metSuvr 100(1-01-03 CU-lJ-itflloropOO-^
(376) t7-U-3 hraquoz raquoch1 or o bu tlaquodi ene (J1V) )00-1- erhylberuer 1400 (33B) 77 -gt7- hei tchl or ocyc1 open traquodi ene (raquoV) 73-09-2 methylene chloriCf OB) 7raquo-3raquo-l BO prior one (raquo3V) 74J7-J eMorametrutne (33B) raquol-raquo-3 naphtfalene 100 (UV) 74-13-9 bro rrvome t hrgt (3iB) n-raquo3-3 niireblaquor)iergte (raquo7V) 7J23-2 (CB) U-XH N -01 ITo tod 4gthenyU rru rr (UV) 75-27-4 bro mod i ch lor o rrx t f4Ugt ((36) 42IO4-7 N-nnroodipropYlraquomlrlaquo (raquolaquoV) 73-4t-4 JJuorotr lchloronvlaquoiMftlaquo (Uol U7-1I-7 ba (2-etrylNraquoYl) phtt^Ure 100000 (30V) 75-71 -raquo dj cftlcr od U 1 vraquooro rri NUT
(47 Bl 13-44-7 t^niyl butvl phthiUte 13000 (31V) 124-41-1 chlorodibromorrwt^r
lt U E gt ) U-71-2 d-ojjurvl phtf^Ure (13V) 127-11-4 tr trbullcti loro rirr
laquoraquo6gt 11704-0 dl-fl-OCTvl pfltMUM (UV) 10t-ll-3 toluene fiin (TtS) raquo-laquo djrthvl phttuliTr (17V) 79-01-4 tricolor oethenr lt 7 | o l 131 -11 -1 (UV) v i n v i chlcwidr dimrlKyl rrftlaquoUTraquo 75-OI-J
(T75I J4-35-J blaquoTMOlt^trrlaquocr^ gtylenes 1200
Cadr ium 3 Chromium 21 ZINC 150
All results are expressed as ugg weight as received y0 entry denotes not detect
Iah I D No 2887-2
Physical descr ip t ion of sample
Strained Soil
Sample workup
Voli t i le f rac t ion PFG Extraction (^W 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-3540) Inorganic fract ion Acid Digestion (SW 846-3050)
ACS) COMPOUNDS
rn CAS Tft CASf
(21 A) tt-04-2 (73B) 50-32-4
U2A) 71-50-7 P-ch 1 or o-m-cre laquoo 1 (7k 8) 205-11-2
(2 A) raquo3-37-l 2- chloroprraquoeno| (75B) 207-01-1
(3IA) 120-13-2 2raquo-4ichlorophenol (74B) 21UOI-1
(3 A) 103-47-1 24-dimethvlphenol (77 B) 201-14-1
(57A) U-75-3 2- njtroDhenol C7I5) 120-12-7
(MA) 100-02-7 a-flitrophenol (71B) |1l-2raquo-2
(51A) 51-21-5 2 -d in i tr o phetio 1 (SOB) K-73-7
(40 A) 53-57-l raquo 4-dinitro-2-methy lprnol (tlB) 15-01-1
(4 A) 17-14-3 plaquoitraquochloroorlaquonol (I2B) 53-70-3
(43A) IOt-13-2 prlaquonol (13B) m-31-3 (MB) 121-00-0
BJ KSENCLmLAL COMPOUNDS
(IB)
(3B) 12-17-3 bcnzidine (2V) 107-07-1
(IB) 120-17-1 1 2 k- tr i ch 1 oro benr ene (3V) 107-13-1
(IB) I1U7I-1 he it raquocM or o boiz ergte (raquoV) 7I-J3-7
(12B) 47-77-1 he traquoch 1 or oet hlaquo ne (4V) 54-23-3
(116) 111-- buC-cJiloroethv|gtether (7V) 101- W-7
(20B) 11-31-7 2 -ltft 1 or on ph ttvraquo 1 laquon e (10V1 107-04-2
(23B) 15-30-1 1 2 -dictilorobeni ene (11V) 71-55-4
(25) VI-73-1 1 3 -ltJ i ci 1 or o blaquoiz ene (13V) 73-3-3
(77 B) 104-M7 llaquo-dchloroblaquoMeoe (HV) n-00-3
(2IB) 11-lk-l 33-dicMorotxTLtidinr (15V) n-3raquo-3 (33B) 12I-U-2 2 ltgt -4 in i tr ot o luene (14V) 75-00-3
(MB) 464-20-2 2 4-d initrotoluene (11V) 1 10-7 3-1
(J7B) 122-447 1 2-diprieny Ihydrti ine (23V) 47-44-3
(316) 2O4-UO Ouorraquonthene (21V) 73-33Jshy
(WB) 7t)03-77-3 ^-cJJorophenyl prienyl ether (JXgtV) 154-40-3
(MB) 101-33-3 -6romopriefgtyl prienyl ether (32V) 71-J7-3
(raquo2B) 3431-32-1 bit (2-chloroboproprO ether (33V) 10041-07-4
(OB) I1U1I- I bu (2-ltMoroethorv) methane 10041-01-03
(52B) r-u-3 hexachlorobutadiene (J1V) 100-l-raquo
(33B) 77-47- he z raquoctlt lor ocycloqenud i crte (MV) 75-01-2
OB) 71-31-1 ao prior one (raquo3V) 7raquo-17-3
(33B) 11-20-3 nlaquopntrlaquollaquone (UV) 7raquo-13-1
(MB) n-13-3 nitrobenzene (raquo7V) 73-23-2
(UB) U-30-4 N-nnroiodiprienyUmine (UV) 75-27-k
(436) Ol-U-7 N-nitrModiproOYlmJne (raquo1V) 73-41-
(UB) 117-117 bu (2-laquothylheiry) phtrlaquolte 8800 (50V) 75-71-1
( 4 7 B ) L3-U7 blaquoniyl buryl phthaUte 30 (31V) 12I-H-1
(UB) U-7U-2 di-o-burvl phtrMUte U3V) I27-I1-
(416) II7-U-0 dj-n-oCTvl pritntUtr 1200 (raquo4V) IOUI1-3
17CB) U-44-2 djetiTi phrtultrt (raquo7V) 71-01-4
( 7 I B I 1 3 1 - 1 1 - 3 dimnfTraquo| prThraquoUtr (UV) 73-01-
(776) H-35-3 berMolta^thrCF^
Cl ien t ID 8 A - S 7 4 6 1
RASENEUTRAL COMPOUNDS
benzofbtfluor^tMe
benzodclfluorintoent
Ctiryiene
cenoithylene
raquonthrraquoctne
benzoltKhilpervlefgte
floor ene
prlaquofnnthrene
ltlibenplusmno(4h)knthricrnlaquo
inogtno(123-rt)pvrrne
pyrene
VCX-ATIIE5
bullcrolem
bullcrvlomn-U
benzene
carbon tetrtchloridf
chlorobenzene
1 2-oUchloroethAnf
lll-trichloroethlaquone
ll-dcfioroethrraquo
1 1 2-tricilorolaquothraquorw
1122-tetrichloroeTtvin
chloroethre
J-ctiloroethv|vinv| etrgte
chloroform
11 -denier oethene
trinraquo- 1 2 -4 cMor oe t hens
12-dcMoroprooine
^Lns~ I f 3-4ic^ lo^opf oo^^^
Cli-l 3-dicMoroprooe^e
rttiylbenzene
methylene cnlonfle
Ch 1 or o me t hane
bromome thane
Trace
bro mod i cMor 0 me t hane
(Juorotrlchlorome thane
chlorodibromometKinf
tetracnloroethervp
toluenetr icMoroel he-if
Trace
CacTiiun Chromium ZINC f
All resxil ts are exprp^spr i K-i
Phys ica l de sc r ip t ion of sample
Strained Soil
Sample workup Vol i t i le f ract ion PEG Extraction (SU 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-5340) Inorganic fract ion Acid Digestion CSV 846-3050)
ACE) C30laquo POUNDS
m CA5i CASraquo (2i A tt-C-2 (73B) JO- 52-1
(22 A) J1-JO-7 p-ch 1 or raquowTv-cre 101 (7raquoB) 203-raquoraquo2
(2 A) raquo)57-J 2- chlorophenol (73B) 20701-
(31 A) I25J3-2 2k-4icttlltroptlaquonol (7tB) 211-01-1
(3A) IO)-7-raquo 2-dimlaquothvlpNrnol (77 B) 20l-raquoi-
(37 A) u-rj-j 7- niTTOphenol (TIB) 120-11-7
(MA) 100-02-7 -rtropN-rraquol (7raquoB) lraquol-2-2
(JraquoA) JI-21-) 2-d initroprietys 1 (IOB) U-73-7
(MA) 53-37-l Udinnro-2-mlaquothylphenol (UB) I5-OI-J
(Agt I7-U-3 pentichlcropwnol (126) 33-70-3
laquo)Agt 10l-raquo)-2 phenol (I3B) IJ3-31-3
(MB) 12raquo-00-0 AASCVflCUTRAl COMPOUNDS
( I B ) I3-32- bullcnraquophtber
(56) raquo2-17) bnzidirlaquo (2Vgt 107-02-1
(IB) 120-12-1 l2btrilt7tlorotgteizegtlaquo (3V) 107-13-1
traquoB) IIraquo-7fc | heikcMeroblaquonzergte (V) 7l-3-2
( I 2 B ) 4772-1 he ueft 1 or olaquot hraquo rgte (tV) laquo-23-3
( i ts) III-- biraquo(2-cMoroethv Dethrr (7V) 101-W-7
(20Bgt 1I-3I-7 2-cMoroflaquophthlene (10V) 107-Ofc-2
(2)6) raquo5-50-l l2-dchlorotgtlaquonzefgte (11V) 71-33-4
(28) 3l-7)-| 1 3-didMoroblaquonrenlaquo (13V) 73-3-3
(27B) 10t--7 l-diclorolgtmzerlaquo (iV) rraquo-00)
(216) raquoI raquoltbull- 33-dichloroblaquoMidiflaquo (13V) 79-31-
(356gt 2I- l-2 21-dinitrotoloen (UV1 73-00-3
(UB) laquogt- 20-2 2 (-dinitroto luenlaquo (HV) 110-7J-J
(376) 122-W-7 14 -dipheny Ihydrzire (23V) lt7-M-3
(396) 2O--0 tJuoruMSene (2raquoV) 7J-35- (OB) 7003-77-3 -c^lvophenyl pNrnyl ethlaquor (30V) 1H-W-)
(MB) 101-33-3 bull-bromopriefiyl prienyl ether (32V) 7t-t7-3
ltraquo25) 3HJI-32-1 bU (2-cMoroaopropyl) rthrr (33V1 10ltX 1-02 -6
(06) l l t - t l - l bis (2-cftloroetSorv) metwne 100lt]-01-03
(32B) C7U-3 heraquoraquochlorobutidierx (31V) 1 00-41-
(3361 77-7-raquo hexiOilorocycloptfiudlerve (raquoV) 73-0raquo-2
(56) 71-51-1 no ph or one (raquo3V) 7raquo-17-3
(3)6) raquol-raquo-3 rwiphtfalme (UV) 7raquoJ3-raquo
1361
LUB)
H-133
14-30-4
nitrobenzene
^ ri i iy o too ipf^^ y LA r^i rtf ^ 7V) (UV)
73-23-2
73-27-
(436) t21--7 M^TI iff frfcO^ip ropy Ift mJf^ (gtraquoV) 73-4raquo-raquo (UB) I17J1-7 bu (2-rThyiruMcyDpMtvUtr 570 (jov) 73-71-1 ( U B ) U-41-7 blaquonzyl buryl phthlaquoLite (31V) l2k-raquo-l ( U B I U-7I-2 di-n-burvl pitftALtTe (raquo)V) 127-lt-fc
(OB) 117- -0 dJ-fraquo-oCTvl phlJ^Ute (UV) IOt-It-3
(7CB) 14 -W- 2 djelftvl phtfalitt (17V) Tt-01- ( 7 I B I 1 J I - I 1 - ) duTNnhylphttsraquoUw ltUV) 75-01-
(77BI X-))O lgtmrlaquoigtmhrraquoctf
Cadmium f iQ Chromium 15 ZINC
Tab ID No oo -
Cl ient ID 8A-A-64220
fcASENEUTTRAL COMPOUNDi
blaquofuo(raquo)pyrrtgte
bfizo(b)(loortAth^e
benzo(k)f|ulaquoin1herf
Ctiryiene
cenDraquoMrwlene
fcftT^rict^t
D^flZCT (fftl)pC^ V Itf^p
(luorene
phen^threne
diiwnztKthlanthricene
indlaquono( 1 23-lttf)pvrene
oyrene
VOCATtLES
bullcrolem
bullcrvlooitriJe
bervteoe
carbon WTTicMoridf
chlorobenze^e
12-djcMoroetfane
1 1 1 -tricolor ex tKraquon
1 1 -dicMarcx t hrlaquo
1 1 2-triChlorothraquorw
1 122 -laquotrraquocM or o-hraquorgt
cMoroettu^e
2-cMorlaquothv|vuy| rseshy
chlexeform
ll-dchloroctfgtn
tri^iraquo l 2laquoflic^ loTo^i rgtcnt
12-dicWoroproptrs
Winl-l3-dicMoropfooene
Cu-lJ-djChleroprooe^
rrtiylfrenzene
methylene ctiloride 0 64
cMorometHAne
bromomlaquothlaquone
bnsmoform
bro mod i eti lor e me t Nine
0 uor o tr 1 cMor e rrgtlaquo t Nnlaquo
dj di tor olaquol If 1 uoro mraquoi Nrraquo
chlorodibromonveiKme
re tr a en 1 or or fxrvr
toluene
D-ieWoroefwne
entry denotes not detect All results are expressed as ugg weight as received Xo
Lab 1) No 2887-8
Physical descr ipt ion of sample
Sf-rs inpH 9 n i l
Sample workup
Vol iCi le f ract ion PEG Extraction (SW 846-5030)
Scmivolat i le f ract ion Soxhlet Extraction (SW 846-3540) Inorganic fraction Acid Digestion (SW 846-3050)
ACD O3MPOUNDS
m CAS fPraquo CASf pi A) tt-Ot-2 Zraquot- tritilorophrgtol (73B) 30-32-1
ft M -3o-7 p-cMorraquo-m-crTraquool (7kB) 205-raquo-2
(2 A) raquoS-37-l 2- cMorop^erxgtl J73B) 207-OI-raquo
(31 A) 120-13-2 l^ictiloropix)l ^7tB) JII-01-
(3 A) |03-7-raquo 21^-dimeThvlphenol (77B) 20t-raquot-l
(J7A) tl-73-3 2- rutropwnol (71 B) 120-12-7
(MA) 100-02-7 -MO-opwnol lt7raquoB) lraquol-2-2
fJraquoA) 3I-2J-3 2-dinitrop^laquoTgtoI ((OB) U-7J7
(laquogtA) J34-37-1 lt-dinitrfr-2-methylpwrxgtl (I IB) I 3-0 1-1 (raquoAI 17-1 3 pcmacMcroptonol (S2B) J3-70-J UJA) IOI-raquo5-2 phenol (IJB) MJ-39-J
(tBgt 12raquo-00-0 RASEfZUTRAL COMPOUNDS
( IB) 13-32-f raquocertaprithene
(3B) J2-17-3 twnndinc (2V) 107J2-J (IB) 170-I2- lr2k-triOilorobenzerlaquo (3V) 107-13-1 (raquoB) I11-7I-I hei bulllt1 ore blaquont ergtlaquo (raquoV) 7l-3-2 (1B) 47-72-I he ucft 1 or oe t h n (tV) 3-23-3 (116) |II_wJ bu(2-ctiIarothvI)laquotNer (7V) 101-90-7
(20B) raquoI-JI7 2 -cW or orvraquo ph tf I ene (10V) I07-Ofc-2 (23B) J3-30-I l2-lt5ictiloroblaquonzeoe (11V) 71-3J- (245) 3I-7J-I 13-dic^lorotxenzenc (13V) 7J-3-3 (27B) 104-K-7 1 mdash diC^lorobtnrerve ( lraquoV) 7^-OO-5 (21 B) raquo|raquo| 33^icftlorobenzidifv (I3V) rgt-j-3 (33B) I 2 I - U - 2 2ltgt-dinin-o1olvraquorgte (UV1 75-00-3
(J4B) 404-JO-2 21-dinitrotoluerve (1raquoV) 110-73-1
(37B) I22-W7 1 2 -d ipheny Ihydra z ine (23V) C7-14-3
(318) 2O4-W-0 tJuortnihrne lt29V) 75-3J- (kOBt 700J-77-J ^-tfMoropheTgtyl p^enyl ether (30V) 1J4-W-3
( raquo I B ) IOI03-J raquo-6romopfgtenyl phenyl ether (32V) 7I-I7-J
(06) 3H3raquo-)2-raquo bU (2-tfilerobopropyO ether (3)V) 10041-02-i
(OB) lll|| bii (2-cMoroethoxv) methane 10041-01-03
(37B) PUt) hxzraquocMorobutadienlaquo (J1V) 100-raquol-raquo
(JJB) T7^7U heztctilarocrclotMnttdicrgte (V) 7gt-0raquo-2 OB) 7l-3raquo-l BO ph or one (raquo3V) 7raquo-17-J
(338) raquo|20-3 rlaquopritrilaquolene (UV) raquo-laquo-raquo
(3iBl n-raquo3) nitrobenzene (raquo7V) 75-23-2
(CB) li-X)-t N -n i tr o tod ipheny U mi nr (UV) 73-27-fc
(06) CI-U7 N^iitroiodipropYUmlr ^raquo1V) 73-H-fc (UB) 117JI-7 bu (2-ethYlNerrl)pM^Utr 12000 (JOV) 75-71-1 (47 B) L3-U7 llaquoniyl buryl pht^UTe 2 800 ( 3 I V ) 2laquo-raquo-I (UB) raquo-7i2 di-o-ourvl pritfwiUrr (I3V) 127-lt-i (196) 117-14 3 dj-n-ocryl pritfiiUrr (UV) IOUIS-3
(TCB) J4-W-2 djnhYl phtfalitt (17V) 7t-01-lt (716 ) 1 3 1 - 1 1 ) damnhYl pMtuUTT (UV) 73-01- (77 Bl 3 33-3 frlaquon z olt raquo klaquom h rraquo c prgte
Cadmium T^ Chromiurn T Z T N C 100
Client ID 8A-C64221
BASENEUTRAL COtPOUNOS
bnzo(t)pyrrrie
benzobXluoriflthei blaquorizoltVHluorraquontrraquone
chryiene
bullcenphthylene
tnthneene
benzoltRM)perylene
fluorene
prienlaquonthcTTgte ditgtmplusmnolt4hluithrraquoctnf
indenof 1 23-cd)pvrf ne
pyrer
VOUATILES
bullcrolein raquocrvlonnrile benzene cmrbort Tetrichloride
chlorobenieoe 1 2-oUchloroethirie
11 1 -tricolor oethne ll-dvchlorolaquollMr 1 1 2-w icMoroethAoe l122-tetrieMoroeihilaquonlaquo
chloroetKvne JltJilorothvlvmv| ethe chloroform
11-dicMoroethent
trani- 1 2 -dicti lorolt t hene
1 J^JictiloroproBfVf
trim- 1 3-4ietiloroproperie
Cil-IJ-dicMoropfoOerie
rrhyUxrmene
methylene criloride
chlorornethine
bromome thne
007
13
tluorotr l^VoromlaquotNraquorgtt
da ch lor od 1 1 1 ooro frvet hraquone
chlorodibromometlvinf
te trraquocnloroeT rrrr
tricMoroetSmr
All results are expressed as us2 weight as receixred No entrv denotes not detect i
Phys ica l descr ip t ion of sample
SoilCake
Sample workup
vol i t i le fract ion ^FP FvfrarfMnn (ltU Rif i mdash Smrn
Semivolatile fraction Soxhlet Extraction (SW 846-3540^ Inorganic fraction Acid Digestion (SW 846-1050)
AC23 COMPOUNDS
rrt CAS CAS
(21 A) 11-04-2 2raquo4- trieMorophenol (738) 50mdash 3-4
122 A) J1-30-7 p-ctil or raquo-nvltrlaquo laquoo 1 (7laquoB) 205-11-2
12 A) 13-37-4 2- etilorophenol (75B) 207-01-1
(31 A) 120-13-2 2raquo-diclorophlaquoTgtol (74B) 211-01-1
(34A) 103-471 24-dmlaquothylphrnol (77 B) 201-14-4
(57 A) U-73-3 2- rutrop^nol (7raquoB) 120-12-7
(54 A) 100 -02-7 bull i tro p^c 01 (71B) 111-24-2
(J9M 31213 Z o trt i tr o poc^oI (MB) U-73-7
(40 A) 334-32-1 T^Hjinitrfr2^rt^T ny tp^gt^noi ( t lB) 13^)1-4
(44A) 17-44-3 pcnttchlaroprwnol (S2B) 33-70-3ltOA) IOt-IJ-2 pTUfNOl (136) 113-31-3
ftASENtUTRAL COMPOUNDS (MB) 121-00-0
(IB)
(56) 12-473 Iwnndine (2V) 107-02-1(IB) I20-IJ-I 1 2 4-tr icJi lorobeniervr (3V) 107-13-1(IB) 11 1-711 hexkcMarobcnzeM (4V) 71-43-2(126) 47-72-1 hexch)eroeihlaquone (4V) 54-23-J( I I S ) 111-4- bu(2-eMorlaquothv|)laquothr (7V) 101-10-7
(208) 11-51-7 2-c^laronraquophtfgtlene (IOV) 107-04-2(23B) 1J-30-I 1 2-dichloroblaquonime (11V) 71-35-4(2651 341-73-1 gt3-ltiictitaroblaquonxcnc (13V) 73-54-3
(27 B) 104-47 l4-dicMorotKmrerlaquo (14V) 71-OO-3
(21 Bgt 11-14) 33-4ichlaroblaquon2idine (15V) 71-34-3
(338) 121-14-2 24-dinitrotoluene (14V1 73-OO-3(J4Bgt 4O4-20-2 24-dinitretoluenc (11V) 110-73-4(37B) 122-447 lraquo2-dip^nylhydrraquoxirlaquo (23V) 47-44-)(MB) ro--0 Uuaranthene (21V) 73-33-4(406) 7003-72-3 4-ltUorepfraquonyl phenvl rtSer (30V) IH-40-J( raquo I 6 ) 101-333 4-6romoprlaquonyl pflaquony| ether (32V) 71-17-3
(OB) 3H3I-J21 bll (2-cti|orobopfrgtpyO ether (33V) 10041-02-4
(OB) I11-1I-I bis (2-cMaroethoxv) methane 10041-0103
(57B) P-44-) hczw^lorobundiene (J4V) 100-41-4
(JJ6I 77-47-4 htTicMarocyclojxrtadien (44 V) 75-01-2
(346) 71-31-1 aophoroo ( raquo ) V ) 74-47-3
(33B) raquo|203 r^pn thA Icr^ (44V) 7 -raquobull J-
(546) n-i3) H i frovCftZfl^^ (raquo7V) 73-23-2
142B) 14-30-4 S -n i tr o laquood ipheny Lt mi nc (44V) 73-27-4
(43 B) 421-447 N^iitrotodtpropyUmlne (41V) 73-41-4(MB) 117-41-7 bu (2-raquoThylhlaquolaquoyl)pMtgtlaquoUtr 52000 (30V) 73-71-4(4B ) 13-447 (xniyl bviryl ptithiUre 6700 (3 lV) 12raquo-l-l(UB) 147U- di-n-burvl pMhUre (I3V) 127-11-4laquoampgt 117-4J-0 ltjj-n-octyl phtfaUtr (UV) 101-11-)
(7CB) U-44-2 djrthyl pht)raquolraquort ( I7V) 71-01-4( 7 I B I 131-11 ) dimrthyl phttgtUTe (UV) 73-01-
(T76) H-33O tgtnzoUtlaquoftthncmr
Cadmium l i r^ Chromiurn 2 0 ZINC 140
All results are expressed as ugg weight as received
Lab ID No 2887-6
Cl ien t I D 8AD64219
Dd20( amp py(re
blaquonio(bHluorraquoflthegtlaquo
berzo(Mf luorampnThene
chryraquoefgte
ftctnAoMhy(ergte
raquonthncene
benioltK(M)plaquovlene
(Juorene
picnintfirtTX
dihwvioltraquoh)laquonThrraquocene
mdeno(l23-rt)pvrraquone
pyrene
raquocrolein
raquocrvloourUf
benzene
carbon laquoTrraquochlofifle
chlorobenieo
l24JcMarolaquotlxine
lll-trichlcroltthlaquorlaquo
-ltJicMorigtnKraquorgtlaquo
l12-trichlorolaquot^nlt
1 1 22-tetrcftloroetrvtnlaquo
^tloroeThAne
2^^1orolaquothvlvuiivt ethe
etila-oform
ll^liailoroltN^
trtni-12-dichlcxolaquoTfgtene
12-ditfiloropropine
trtni-l3-ltjicti|orocltX)t^f
cu-l3-djcMoroprooe^f
rttiylbtnztTve
methvlene cWoride
ciloromnM^f
Dco^^oroct^A^^
bromofarm
bromodicJiloromltlfraquon
tluorotrlctiloromttNir
diOilorodKloororfvrir^Ar
ct^lorodraquobrofTorrgttKAne
wtricnlorampctNrr
toluene
trirfilorolaquoThfif
v i n v CMor ilt3^
No-entry denotes not detect
ih i n N O 2887-9
Phys ica l d-asc r ip t ion of sample Cl ient ID 10A64222
Linnir l ShtHcp
Sample workup Volitile f rac t ion PEG Extraction (SW 846-^030^ Semivolatile fract ion Sonication Extraction (SW 846-3-540 Inorganic f ract ion Acid Digestion (SW 846-3050)
AOD COM POUNDS BAStNELTTRAL CXLPCXJNDS
rrt CAS CAS
(21 AJ U-Ot-7 Z4- trichloropSeno (73B) 30-J2-
(22 A) 55-30-7 p-ctilarraquo-m-erelaquoo1 (7kB) 205-raquoraquo-2 ben r olt b) 1 uor ifl t Ne~gtf
(2AJ raquo3-37-i 2- ctilorophenol (75B) 207-0raquoraquo benzoltllt)floofraquontslaquor
(31A) 120-13-2 2raquo-ltJictilcroooenol (76) 211-01 9 ctiryjene
(3A) I03-47- 2k-dimethylphenol (77 B) 20t-raquo4-i bullceruphthv lerraquoe
(37A) U-73-3 Zmdash Ajtropheooi (7SB) 120-12-7 fcntftricene
(34 A) 100-02-7 w^ i ff o phe rgto 1 (7raquoB) Iraquol-2-2 ben z o( Rh i )per v 1 me
(31A1 51-21-3 Z^ - d iA iV opheno1 (SOB) U-7J-7 Iluorene
(MA) 3X-37-I T v-4iAiv omdash laquo mdash fl^et ny Ipoenoi (I1B) 13-01-1 poeftraquonthrene
(4 Al 17-14-5 p^ntBCfllGrOprlC 1 Vol |I2B) 33-70-3 dilgtenioltraquoh)laquontwraquocenr
USA) IOl-raquo5-2 phenol (13fi) U3-31-3 indeno(l73-cd)oraquorrie
(MB) I2raquo-OO-0 pyrene RASENCimiAL COMPOUNDS
VCH-ATUL5 ( I B ) 13-32- raquoclaquonraquophtflaquorgte
(58) 12-I7-J benzidire (2V) 107-02-1 bullcrolem
(IB) 120-J7-I 1 2k-tr icnlorobenzene (3V) 107-13-1 acrvlonitr UP
(IB) 11U7I-I heKicMorobtnzme (raquoV) 7I-A3-2 benzene
(176) 4772-1 hexcftla-oethtgte (4V) J4-23-5 campr~toon TeTrscftlo itit
(116) III-- bii(2-lttilorolaquothv iVether (7V) lOt-W-7 chlocobenieo
(2C5gt raquol-3l-7 2-cM oroolaquo ptittu lene (10V) I07-O4-2 1 2-dicrtloreetranr
(23B) raquo5-30-l 12-dichlarobenime ( 1 I V ) 71-33-4 11 1 -tricMoroethr
(24 B) 31-73-1 1 3-ltl icJgt lor obcn i ene (13V) 73-3^-3 1 1 -dicMoroeth^i
(27B) 104-^4-7 1 4-dich lorobenzergte ( t k V ) n-00-3 11 2-tncfiloroetvlaquorie
(215) 91901 33-didMoroblaquozidinr (I3V) rraquo-3k-3 l122-tetrraquoOMo-oethne
(335) 121-I-2 2-dinitrotoluergte (ItV) 73JW-3 chloroethjin
(3461 (0420-2 24-dinitrotoluene (19V) 110-73-1 2-cMoroethraquo|vuiv| trgteshy
(37 B1 122-44-7 12-diphenylhydrnine (23V) 47-44-3 ctiloroform
(316) 204- Jgt tluarmrnhene lt2V) 73-35-4 1 1 -^iCMoroeThe^f
(C6) 7003-77-3 -chlorophenyl poenyl ether (gtOV) 154-40-5 trraquonraquo-l2-dicrloroltthene
(bull16) 101-35-3 raquo-6romophenyl phenyl ether (32V) 7I-I7-3 l2^ipoundMoroproBirgte
(raquo26) 3H3I-32- bit (2-cMarobopropvt) ether (33V) 1 004 1-02 -4 trmni-l^-dictilwoproom
(OB) l l l - raquo l - l bis (2-cMeroethoxv) methane 1004 1-0 1-05 cu-13-laquoicMoroprooe^e
(J2BI D-U-3 rraquolaquoeftlorobutraquodilaquooe (JJV) IOOJM- rttylbenzene
(336) 77 -raquo7- hezactilarocyclooentadiene (WV) 75-OT-2 methylene cniorifle
(56) 7raquo-3raquo-l ao ph or one (raquo5V) 7raquoJ7-3 eMoromeirune
(33B) JI-20-3 nraquophtMlene (UV) 7raquoJ3-raquo bromomethAftf
1X6) n-raquov) nitrobtnxerw (raquo7V) 7J-25-2
(CB1 14-30-4 J -ltii TT o vxJ ipheny U rru rraquo ^UV) 75-27- bro mod i cfilor o me t r)e
(CB) 47I-U-7 N-nnrotodipropylraquomJne (tV) 75-4raquo- 11 uor o tr i cMor o me t htgte (US) V17-1I-7 bu (2-eifrrlhryl)praquogtttilaquoUMshy 69 000 (30V) 75-71-1 di cti tor odl1 1 van m^i rajgtr
(476) U-U-7 benzyl buryl phihiUte 890 (31V) 12laquo-kraquo-l cMorodbremof^etNrr (US) U-7I-2 di-n-burvl prittuUre (13V) 127-lt- Uraquo6gt 117-t-0 dJ-laquo-ocTvl phttviUre (UV) IOLtS-3 Wluenr
(75) u-w djrrhylphtnltt ( i rv) 71-01-4
(715) t J I - l l - 3 dimnhrl pfthUte (UVI 73-01- viny l CMcriOr
(779) J4-35-3 0laquoMo(UnthrraquoCflaquoe
C a d m i u m 130 Chromium 20 ZINC 170
o nnn Z-UUU
^0(^ Trace
All results are expressed as ugg weight as received No en
APPENDIX E
PLATES
I I I I I I I I I i Plate 10-1 Troy Mills Landfill with a backhoe excavation
in progress in a former drum burial area
I I I
I I I I I I I I
I I Plate 20-1 NAI field investigation team preparing for
Level B activities during the drum excavation task Troy Mills Landfill
I I I
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
I I I I I I I I
I I Plate 20-3 NAI field investigation team member undergoing
personal decontamination at the hot line Troy Mills Landfill
I 1 I
I I I I I I
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
1
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
I
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
I I I
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
I I I I I I I I I I I 1 I Plate 53-3 Pigmentsludge deposits interbedded with
soil layers in Excavation 8A Troy Mills
I Landfill
1
40 TEST PIT EXCAVATION
41 WORK PLAN
A series of test pits were excavated in the Troy landfill for
observation and sampling More specifically the purpose of the
excavation was to estimate the number and distribution of drums buried
in the landfill determine the condition of the drums (full empty
crushed rusted leaking etc) identify types of buried and drummed
waste and verify the results of the magnetometer survey A stratified
random sampling method was used to choose 10 locations within the
delineated area of magnetic source material This insured that
excavations were distributed randomly across the landfill and that the
resulting data could be evaluated with a level of statistical
reliability Excavations were also selected in areas on either side of
the anomaly which were considered free of buried magnetic material and
also where drums were visible at the landfill surface
The following procedure was used in choosing the locations for
the random excavations The center of the delineated area of magnetic
source material was used as a base line The base line was drawn onto a
map of the source material (Figure 30-1) and then divided into ten
60-foot long segments Using a random numbers table a point-distance
was located on each segment (designated the random station) and a
line drawn at that point perpendicular to the base line segment Again
using a random numbers table a point-distance (designated the random
offset) measured along the perpendicular line located the point of
excavation The grid coordinates for each excavation were graphically
determined from the grid overlay and then field-located from the
surveyed grid intersections Grid coordinates and selection data are
presented in Table 41-1
It was judged that 10 excavations in the delineated area of
magnetic source material and two excavations out of the area would be
sufficient to characterize the site would produce statistically valid
TABLE 41-1 RANDOMLY SELECTED EXCAVATION SITES TROY MILLS LANDFILL TROY NEW HAMPSHIRE
BASELINE RANDOM RANDOM EXCAVATION GRID SEGMENT STATION OFFSET
NUMBER COORDINATE (FEET) fFEET) (FEET)
1 7E+15 65N 0-60 26 16
2 9E+5 13S 60-120 110 9
3 8E+0 31S 120-180 140 7
4 4E+5 48S 180-240 230 26
5 3E+8 45S 240-300 254 20
6 OE+8 45S 300-360 394 50
7 2W+15 24N 360-420 465 14
8 5W+6 42N 420-480 518 20
9 6V+14 74N 480-540 548 7
10 8W+5110N 540-600 611 31
Locations are plotted on Map in Figure 30-1
data and could be expected to be completed within a scheduled 2-3 day
work period
42 FIELD WORK
Test pit excavation was conducted in two phases On the first
day each of the 10 random locations (Excavation 1 through 10 Figure
30-1) was probed to a depth of 2 feet using hand shovels On the
second and third days excavation was conducted using a combination of
hand shovelling and power backhoe The NAI field investigation team
consisted of six members Four of the team members were equipped to
work at Level B for work in and near the actual test pit excavation
(See Plate 42-1) The other two team members spent much of their time
with personnel and equipment decontamination and refilling compressed
air bottles at the hot line Mr Timothy W Drew an engineer of the
New Hampshire Bureau of Hazardous Waste Management was present during
most probing and excavation work Mr Robert Lynch an experienced
Level B equipment operator of Jet-Line Services Inc operated a power
backhoe which was provided by Troy Mills Inc
An average excavation size using the backhoe was approximately
7-feet wide and 10-feet long Excavation continued downward until drums
were encountered or to a minimum depth of five feet Drums were careshy
fully uncovered and fully described A total of 17 samples were
obtained from uncontainerized wastes (solids dried sludges pigments
stained soil) and where possible from drums using EPA sampling methods
and protocols All of the excavations were backfilled upon completion
of this task
Each sample consisted of one filled 8-ounce glass jar sealed
with a Teflon-lined lid Samples were submitted to Resource Analysts
Inc (RAI) Laboratory in Hampton Falls NH for priority pollutant
analysis
Air monitoring was conducted during each excavation using a
Foxboro Century Flame lonization Organic Vapor Analyzer (OVA) an HNU
Systems photo-ionization detector (HNU) and an MSA combined oxygen and
explosimeter High explosimeter measurements were considered cause for
an immediate halt in exploratory work in the interest of personnel
safety
10
50 RESULTS
51 GENERAL
On November 17 1983 Excavations 1 through 10 were initiated
using hand shovels to a depth of approximately two feet A total of
two buried drums were discovered Excavation 13 was completed and a
third partially buried drum uncovered On November 21 1983
Excavations 1 through 9 were completed and on November 23 1983
Excavations 7A 8A 10 11 12 and 14 were completed An additional
42 drums were uncovered on the last two days of excavation
Excavation Locations Seventeen test pit excavations were
completed at locations which are shown on Figure 30-1 Two pits were
excavated at three of the locations Noteworthy aspects of the
excavation operation are
Excavations 1 through 10 were randomly located in the area of delineated magnetic source material (on-anomaly)
One excavation connected Excavations 4 and 5 This was done because of the proximity of Excavations 4 and 5
Excavation 7A was located immediately adjacent to Excavation 7 Excavation 7 was located on the boundary line of the anomaly and proceeded in a southerly direction off the area of delineated magnetic source material (off-anomaly) Excavation 7A was initiated in the opposite direction (north on-anomaly)
Excavation 8A was initiated one foot north of Excavation 8 after the latter was abandoned due to the detection of a potentially explosive drum
Excavations 11 and 12 were selected off-anomaly to the north and south (respectively) in areas considered to be free of buried magnetic material (drums)
Excavation 13 involved minor hand shovelling necessary to uncover a partially buried drum located on the periphery of the anomaly at the east end of the landfill
11
Excavation 14 was a surface scrape which extended from an exposed drum found to the south of the magnetic anomaly northward toward the anomaly
The details of each excavation are presented in Table 52-1
Drum Locations The excavation results support the
interpretation of the magnetometer survey with buried drums as the
source of the magnetic anomaly With the exception of a few strands of
wire found in Excavation 1 ferromagnetic materials other than drums
were not encountered during the test pit excavations
Drums were foundin 9 of the 10 excavations located in the
area of delineated magnetic source material (See Plate 51-1) No drums
were found in Excavations 11 and 12 located out of the area of
delineated magnetic source materials The location point for Excavation
7 was on the boundary of the anomaly Excavation 7 which proceeded
south away from the area of source materials was free of drums
Excavation 7A proceeding north toward the area of magnetic source
materials uncovered 6 drums Excavation 14 located just out of the
delineated area to the south produced unexpected results Five drums
were uncovered just under the surface in an area with low positive to
slightly negative total magnetic field values It is possible that
Excavation 14 was improperly located in the field If adjusted just 20
feet to the east it would be well into the delineated area It is also
possible that a negative dipole derived from the mass of material to the
southeast is cancelling positive readings at this location
Fill Material and Vegetation Cover and fill material was
predominantly fine to medium sand with an occasional boulder Till with
a siltclay component was also used as a cover particularly at
Excavations 6 and 7A This material was densely compacted and difficult
to dig through Excavations 7 11 and 12 each extending to a minimum
depth of 5 feet were characterized by uniform silt and fine to medium
sand and traces of dark discoloration Excavation 12 was located in
to a s
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52
14
what appeared to be natural materials although its location on the
cleared and leveled landfill tend to contradict this possibility
Most of the landfill is vegetated by a thin layer of grasses
sedges mosses and annual herbaceous species The northeast corner of
the landfill is unvegetated and cover material appears to have been more
recently applied This section is elevated 4 to 6 feet above the rest
of the landfill and appears to have received a second newer layer of
waste A 4-foot thick layer of carpet waste was encountered in
Excavation 1 but not in other excavations This section is adjacent to
the newer active landfill The landfill area just west of the access
road crossing (near Excavations 7A 8 and 8A) was also unvegetated due
to relatively recent grading operations
Ground Water The landfill appears well drained as ground
water was not encountered during any of the excavations Excavated
overburden was damp from the recent heavy rain but intergranular macro
pore spaces were free of water
OBSERVED QUANTITY AND CHARACTER OF DRUMS
A total of 45 drums were observed buried in the landfill
Table 52-1 presents a drum log describing each excavation and the
observed drums Data on the contents and condition of drums is
summarized in Table 52-2
Of the total drums observed 15 (33) were crushed flat
Although these could possibly still contain small amounts of waste they
are probably considered empty under RCRA guidelines Thirty (67) of
the total drums discovered were uncrushed and capable of containing
waste Seven (88) of the 8 drums sampled contained liquid or sludge
waste material Thus at least 7 (23) of the uncrushed drums contained
some liquid or sludge waste
15
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1
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CJ eoc
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cc Q
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to z
m 3 c O
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c U) CO
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53
16
The condition of the uncrushed drums was highly variable with
only 4 (13) rusted and decomposed to the point of structural weakness
These drums were found in Excavation 10 at the far west end of the
landfill which is believed to be the oldest section (See Plate 52-1)
Interestingly two almost new looking drums were also found in
Excavation 10 at a greater depth than the four rusted drums The
remaining 26 drums were observed to be generally intact and structurally
sound Some were dented partially crushed or rusty
CHARACTER OF WASTES
Air Monitoring An OVA and HNU were used to monitor the air
for concentrations of organic vapors during each excavation Above
background instrument readings indicative of contamination were
regularly recorded when monitoring the air just above or inside of
drums A general contamination of the ambient air in the workspace was
noted only during Excavation 8A where above background readings of +13
in the excavation pit and of +6 above the excavation pit were recorded
Explosimeter readings were obtained from three drums -- 10 lower
explosive limit (LEL) from drum sample 10A 20 LEL from drum sample 6B
and 100 LEL from a drum in Excavation 8 Instrument readings are
presented in Table 52-1 and Table 53-1
Visual Observations The following types of waste were
observed during the excavations
fabric waste (carpet waste)
crushed drums
drummed waste - liquid sludge and solid
uncontainerized dried sludges and pigments
stained soils
Fabric waste scraps of synthetic non-woven fabrics5 heavy
carpet-like fabric and backing material were found only in Excavation
17
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19
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20
1 (See Plate 53-1) This is the predominant waste material currently
being disposed of in the active landfill
Crushed drums were distributed throughout the original
landfill and were found in Excavations 2 4 4-5 7A 8A and 14 Some
drums such as those found under the road in Excavation 7A may have
been crushed by heavy equipment operating in the landfill Others like
those found at depth in sandy fill in Excavation 2 appear to have been
crushed before burial Drummed liquid and sludge wastes are also
distributed throughout the landfill (See Plate 53-2) They were found
in Excavations 1 4 5 6 8 and 10 These wastes are discussed below
One sealed drum was openedand found filled with refuse -- paper cups
towels paint covered rags etc One open and partially crushed drum
contained a dark granular solid waste This material was sampled
(Sample 10B) and found to be nonhazardous
Small deposits of dried pigmentsludge were found in
Excavations 3 4 6 9 and 13 Discernible layers of pigmentsludge and
stained soils were present in Excavations 7A 8 and 8A (See Plate
53-3) Of particular note was a 2 to 4-inch thick layer of
grey-colored dried sludge found at Excavations 7A and 8 All of these
wastes were sampled and the results are discussed below
Laboratory Analyses
Laboratory analyses were performed on 10 selected samples
obtained from both containerized (drummed) and uncontainerized wastes
Samples were analysed for 3 metals and 87 priority pollutants including
11 acid compounds 45 baseneutral compounds and 31 volatile organic
compounds Table 5-4 summarizes the analytical results and the
laboratory data sheets are presented in Appendix D
Of the 45 priority pollutant baseneutral compounds only 4
were identified in the samples that were analyzed Baseneutral
21
compounds and particularly phthalates were the most prevalent
chemicals and also were reported in the greatest concentrations The
highest levels of naphthalene (1200 ppm) bis (2-ethylhexyl) phthalate
(110000 ppm) and di-n-octyl phthalate (6200 ppm) were found in sample
4A a translucent red liquid obtained from a drum The highest
concentration of benzyl butyl phthalate (13000 ppm) was found in sample
6B a clear liquid and pink sludgepigment obtained from a drum
A total of 8 volatile organic compounds were identified The
highest levels of benzene (100 ppm) xylenes (19000 ppm) and
ethylbenzene (5300 ppm) were found in sample 5A a clear liquid
purple-grey sludge obtained from a drum Toluene was found in highest
concentration (12000 ppm) in sample 1A a purple-grey thick opaque
liquid obtained from a drum Methylene chloride (13 ppm) was
identified in greatest concentration in sample 8A-C a purple stained
soil and powdery waste Sample 10A a purple liquid obtained from a
drum was the only sample found to contain 1-1 dichloroethane (2000
ppm) Finally trace levels of trichloroethylene (sample 10A) and
111-trichloroethane (sample IB) were also reported
Samples were tested for three metals - cadmium zinc and
chromium The highest concentrations of cadmium (2200 ppm) and zinc
(5700 ppm) were found in sample 4A a translucent red liquid obtained
from a drum The highest level of chromium (52 ppm) was reported in
sample 5A a clear liquidpurple-grey sludge obtained from a drum
22
60 DISCUSSION
61 EXISTING SITUATION
Under existing conditions relatively small quantities of
volatile organic compounds (VOC) are indicated to be leaking from wastes
buried on the landfill site To date ground and surface water
monitoring results indicate relatively low concentrations of VOC in the
ground water and below detection limits in the adjacent brook (See
Tables 61-1 to 61-10) The results indicate that no potential health
risks from VOC and other constituents currently under observation are
being caused by the landfill operation to down stream surface water
users It would be prudent for Troy Mills to continue to monitor the
quality of Rockwood Brook upstream and downstream for VOC and on the
basis of waste analyses (previous section) to monitor ground and
surface water points for toxic metals and baseneutral compounds
62 SITE HYDROLOGY
An analysis of the hydrology of the landfill site was
performed in 1982 (NAI report of September 1982) The subwatershed that
contains the landfill site is (about 44 acres) a small fraction of the
watershed area that contributes to Rockwood Brook above surface water
sampling point C (about 1650 acres see Figure 62-1) This indicates
that most of the flow of the brook at point C (about 97) is contributed
by upstream watershed areas Thus leachate discharging into Rockwood
Brook from the landfill site can be expected to be diluted by over 30
times its volume This factor and the volatilization which naturally
occurs results in parameters detected in the Troy Mills monitoring
wells often becoming undetectable when they enter the brook
f 5
Geologic conditions which were defined in the NAI report of
July 1982 indicate that permeable deposits of sand and gravel overlie
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27
TABLE 61-5 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M5 (UPGRADIENT WELL)
Parameter Date Sampled 11-22-83
Specific conductance
pH2 81
Dissolved iron mg1 036
Dissolved manganese mg1 010
Chloride mg1 10
Phenolics mg1
3
023
Identified volatile organics
None identified ND
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (yg1)
28
TABLE 61-6 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M6
Parameter
Specific conductance
PH2
Dissolved iron mg1
Dissolved manganese mg1
Chloride mg1
Phenolies mg1
Identified volatile organics
11-dichloroethane tetrachloroethylene 111-trichloroethane
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vg1)
Date Sampled 11-22-83
152
lt002
29
6
0002
27 trace 140
29
TABLE 61-7 ANALYSES OF WATER SAMPLES COLLECTED FROM MONITOR WELL M7
Parameter Date Sampled 11-22-83
1 47 Specific conductance
pH2 62
Dissolved iron mg1 002
Dissolved manganese mg1 0026
Chloride mg1 gt2
Phenolics mg1 0070
3 Identified volatile organics
111-trichloroethane 5
Measurement in micromhoscm at 25 C 2 Field measurement 3 Concentrations in microgramsliter (vig1)
30
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34
glacial till and bedrock The sand and gravel deposits form a permeable
conduit through which leachate from the waste burial areas migrates
The permeable deposits lie in the area north of monitoring well M-l (See
Figure 62-1) In general the water saturated thickness of the sand
and gravel in the vicinity of the north-south access road is 6 to 12
feet
64 POTENTIAL FOR GROUND WATER CONTAMINATION
641 Estimated Quantity of Drums
The test pit excavation and sampling in the drum burial area
indicates a potential source of ground water contamination for the
future Many of the drums encountered were in fair to good condition
and contained liquid wastes An estimate of the number of drums in the
deposit was made with the following assumptions
1 The complex magnetic anomaly was simplified into a geometric solid 600 feet long 40 feet wide and 10 feet deep with a volume (V) of 240000 cubic feet
2 Each steel drum (D) occupies 105 cubic feet (including voids)
3 The density of packing (P) was assumed to be 50 of the packing that can be achieved with perfect cubic packing
THEN
N = estimated number of steel drums
N = (VD) (P)
N = (240000105) (05)
N = 11429 drums
The results of the drum excavation work provides a basis for
estimating the potential for specific types of chemical loading In
general three main classes of chemical substances were identified in
35
the drums The chemical substances included baseneutral extractable
organic compounds (mostly phthalates and lesser amounts of naphthalene)
volatile organic chemicals and metals
642 Phthalates
The phthalate esters found in the drums include
bis (2-ethylhexyl) phthalate ^0^3 benzyl butyl phthalate di-n-octyl phthalate Jd~7
Bis (2-ethylhexyl) phthalate was found in the highest
concentration at 110000 ppm (11 percent) Benzyl butyl phthalate is at
the second highest concentration 13000 ppm (13 percent)
Characteristics of those phthalates found are presented in Table 64-1
TABLE 64-1 PHYSICAL PROPERTIES OF PHTHALATE ESTERSshy
di-n-octyl bis (2-ethylhexyl) butyl benzyl DOP DEHP BBP
ALTERNATE o-Benzenedishy di (2-ethylhexyl) benzyl butyl NAMES carboxylic phthalate phthalate
Molecular Weight 3910 3910 312
Melting Point -25degC -50degC -35degC
Boiling Point 220degC 386 9degC 377degC
Vapor Pressure-mdash lt02 torr (150degC) lt001 torr (20degC)
Not
2xlO~7torr (20degC) Available
Solubility 3 rngfc (25degC) 04 mgfc (25degC)
58
13 rngH 48
Log octanolwater 92 873 58 partition coefficient 53 48
Versar Inc 1979 Water-Related Fate of 129 Priority Pollutants Volume II Prepared for US Environmental Protection Agency PBSO-20438 December
bullbullOther names listed in Versar 1979 vMore than one value has been calculatedreported
36
Bis (2-ethylhexyl) phthalate is the most well-studied of the
phthalate esters though the information on phthalate esters as a group
is limited The three phthalates identified at the Troy Mills site have
relatively low solubilities and are readily adsorbed onto suspended
particulates Microbial degradation is effective under aerobic
conditions bur is generally slower under anaerobic conditions
(nonexistent for bis (2-ethylhexyl) phthalate)
The above characteristics are important for two reasons One
the extent and nature of contaminant migration from the site are
dependent upon the physical characteristics Second the treatment
(clean-up) alternatives for contaminated ground water or soil can be
estimated from the characteristics
From the available information it appears that the phthalates
present at the Troy Mills site would be relatively immobile due to their
low solubilities and high adsorption rates The presence of toluene and
methylene chloride at the site however may increase the phthalates rate
of migration
It is important to note that none of the phthalates have been
found to be present in the monitoring wells nor in the surface water
sampled probably due to the low solubility and high adsorption rate
37
643 Napthalene u K r
Naphthalene has also been found in significant quantities in
the sampled drums Naphthalene is a polycyclic aromatic hydrocarbon and
has the following properties
Molecular Weight 12819
Melting Point 8055
Vapor Pressure (20degC) 00492 torr
Solubility in Water (25degC) 344 mgfc
317 mgfc
Log octanolwater partition coefficient 337
Versar 1979
Naphthalene has mid-range adsorption rates and solubility It is
therefore inferred that there would be some adsorption to soils in a
ground water environment It is important to note that naphthalene has
not been detected to date at the monitoring wells or the surface water
sampling locations This is expected to be a result of adsorption on
the soils
644 Volatile Organic Compounds
Volatile organic compounds tend to migrate readily within
soils and ground water They are therefore considered a threat to
surrounding ground and surface waters if they are released in sufficient
quantities
Volatile organic compounds were detected in samples from six
steel drums The total volatile organic (TVO) concentrations in the
38
wastes ranged from 9 ppm to 30100 ppm and averaged 8570 ppm In order
to determine the potential for future contamination by volatile organic
compounds an estimate of waste quantity based on information from the
drum excavation program was made It was assumed that 7000 steel drums
in the deposit are 60 full of liquid waste with an average TVO
concentration of 8570 ppm The computed volume of liquid waste is
231000 gallons with an average TVO concentration of 8570 ppm This is
equivalent to about 1980 gallons of pure TVO
Two of the volatile organic compounds that have been most
prevalent in the existing ground water monitoring system are
111-trichloroethane and ethylbenzene The EPA suggested no adverse
response level (SNARL) for 111-trichloroethane is 330 ugpound for
1 day of exposure and 35 jigd for exposure over a life-time in
drinking water
In general ethylbenzene is a prevalent chemical in the
environment Sources include commercial (eg petroleum and petroleum
by-products) motor vehicle exhaust and cigarette smoke An intake of
16 mgday (1 mgfc) has been calculated as an acceptable rate to
protect from toxic effects Carcinogenic effects have not been
identified to date The physical properties of ethylbenzene are
presented in Table 64-2 The principal mechanism for removal of
ethylbenzene from water is volatilization In addition to
volatilization adsorption may also be an important removal mechanism
based on the log octanolwater coefficient This factor is important in
evaluating the migration of ethylbenzene from the disposal site
Toluene which was also identified in waste and ground water
samples exhibits properties similar to ethylbenzene in that it
volatilizes easily Toluene which is also referred to as methylbenzene
is distinguished from benzene by the substitution of a methyl group for
one hydrogen atom Physical properties of it are presented in Table
39
64-2 The EPA suggested no adverse response level (SNARL) for toluene
is 1 mgpound in drinking water with a maximum exposure time of ten
days
TABLE 64-2 PHYSICAL PROPERTIES OF ETHYLBENZENE AND TOLUENE
ETHYLBENZENE TOLUENE
Molecular Weight 10616 9213
Melting Point -949degC -950degC
Boiling Point 1362degC 1106degC
Vapor Pressure at 20degC 7 torr 287 torr
Solubility in water at 20degC 152 mg2 5348 mgd
Log OctanolWater Partition Coefficient 315 269
645 Metals
One liquid sample contained high concentrations of cadmium
(2200 mgd) and zinc (5700 mgd) indicating that the waste deposit is
also a potential source of certain toxic metals Tests for these metals
have not been made to-date in ground or surface water samples It would
be prudent to add toxic metals such as cadmium chromium lead and
mercury to the list of parameters that are being monitored to further
characterize the quality of adjacent ground and surface waters US
EPA and New Hampshire drinking water standards for these metals are
cadmium 01 mgd chromium 05 mgpound lead 05 mgd mercury 002
mgd Although zinc is not considered a highly toxic metal the
US EPA has set a secondary drinking water maximum contaminant level of
5 mgd on this metal
40
70 CONCLUSIONS
The following conclusions were drawn during this
investigation
1 A steep-gradient irregular-shaped magnetic anomaly is present under closed and covered portions of the south part of the Troy Mills landfill
2 The magnetic anomaly is caused mostly by an irregular-shaped accumulation of disposed steel drums
3 In a randomly conducted sampling of drums in the source area for the magnetic anomaly 16 of the drums contained liquid andor sludge 33 were crushed flat and 51 were not sampled because there were no accessible openings
4 Laboratory analyses indicate that the random waste sampling contained significant concentrations of several volatile organic chemicals several baseneutral priority pollutants and high levels of cadmium and zinc
5 Observed concentrations of volatile organics at the monitoring wells are relatively low Because of their potential for migration in the ground water continued monitoring of volatile organics will be required
6 Volatile organic chemicals have not been detected in Rockwood Brook to-date Because of the presence of low levels of volatile organics in the ground water they should be monitored in the brook on a regular basis to confirm the lack of impact
7 The presence of high concentrations of cadmium and zinc in one of the waste samples indicates that trace metals should be monitored periodically
8 The presence of baseneutral extractable compounds (phthalates and naphthalene) in all of the analyzed waste samples indicates that these compounds should be monitored periodically
9 The phthalates are not expected to migrate freely because they have low solubilities and are readily adsorbed onto soil particles
10 If elevated concentrations of volatile organic compounds trace metals or baseneutral extractable compounds should occur in the monitoring system (wells and brook) in the future a need for site remedial actions to mitigate the potential for downgradient ground and surface water contamination could develop
~
80
41
RECOMMENDED PLAN
Based on the preceding conclusions it is recommended that the
following plan be implemented by Troy Mills Inc
1 Continue monitoring ground and surface water quality at the Troy Mills Inc landfill sampling on a quarterly basis with sample collections during April July October and January
2 To confirm the absence of the landfills impact on Rockwood Brook test samples for volatile organic compounds by GCMS from surface Stations B (upstream) and C (downstream) on the April and October samplings
3 To determine if trace metals are present in downgradient ground waters conduct analyses for cadmium chromium lead mercury and zinc on samples from all monitoring points during the April sampling and on subsequent sampling rounds if necessary
4 To confirm the continued absence of baseneutral extractable compounds in downgradient ground and surface waters conduct analyses for baseneutral extractable compounds on samples from monitoring wells M 2 and 3 and surface Station C (downstream) on the April sampling and on subsequent sampling rounds if necessary
5 If a sudden rise in concentrations toward unacceptable levels should occur in the monitoring system (wells and brook) additional monitoring rounds at a monthly interval should be conducted to confirm the rise in concentrations
6 If elevated concentrations persist and are verified by the additional monitoring remedial alternatives will be defined to mitigate the potential for downgradient ground and surface water contamination
Respectfully submitted NORMANDEAU ASSOCIATES INC
Dennis R Sasseville Project Manager
Donald H Bruehl f laquo | APG Senior Hydrogeologist -^ - - AIPG Certificate No 2272 ^ -v^
^^Z-^^
APPENDIX A
SITE SAFETY PLAN
GENERAL SAFETY PLAH FOR
TROT MILLS LANDFILL TROY MEW HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
Prepared by
NORMANDEAU ASSOCIATES INC Bedford New Hampshire
R-457
November 1983
TABLE OF COHTENTS
PAGE
SECTION 1 BACKGROUND INFORMATION 2
Identification 2 Personnel 2 Site Description 3 Project Description 5
SECTION 2 HAZARD EVALUATION 6
Overall Degree of Hazard 6 Specific Hazards 8 Necessary LPP 8
SECTION 3 FIRST AID FOR EXPOSURE 10
SECTION 4 OPERATIONS SAFETY PLAN 11
General Personnel Protection GuidelinesAction Levels 11 Site Reconnaissance 13 Task 1 - Magnetic Survey Topographic Survey 14 Task 2 - Drum excavation and Sampling 15
SECTION 5 EMERGENCY INFORMATION 16
Emergency Telephone Numbers 16 Route to Hospital 16 Contingency Plan 17
APPENDICES 18
A - LEVELS OF PERSONNEL PROTECTION 18 B - DECONTAMINATION PROCEDURES 23 C - PERSONNEL AND RESPONSIBILITIES 25 D - PERSONNEL CASUALTY 26 E - GUIDELINES FOR SITE OPERATIONS 27
GENERAL SAFETY PLAN FOR
TROY MILLS LANDFILL TROY NEraquo HAMPSHIRE
MAGNETOMETER AND TOPOGRAPHIC SURVEYS EXCAVATION OF DRUMS
The following is a Safety Plan for on-site activities performed
during the Investigation of the Troy Mills Landfill being conducted by
Normandeau Associates Inc (NAI) of Bedford New Hampshire
The document is intended to be an in house working guideline
for personnel trained and experienced in hazardous waste field work and
not a treatise on safety Familiarity with standard equipment and proshy
cedures is expected Where possible non-site specific information has
been appended
All NAI employees subcontractors and visitors will be required
to follow this safety procedure plan and to report to either NAIs proshy
ject manager (P M) on site coordinator (OSC) or safety officer (SO) on
issues relating to safety
SECTION 1
BACKGROUND INFORMATION
IDENTIFICATION
Site Name Trey Mills Landfill NAI-ID No 457
Trey Mills Inc Troy NH 03465
AddressLocation At the south end of the dirt road about 15 miles
south of Troy NH between Rockwood Brook and the
old Boston and Maine Railroad grade
County Cheshire Phone 603-242-7711
PERSONNEL
Brook Dupee Bureau Hazardous Waste 603-271-4611
State Contact John Regan Bureau Solid Waste 603-271-4586
Dan Allen WSPCC 603-271-2755
EPA Contact
Other Contacts
Client Contacts Barrett F Ripley (Vice President)
NAI Personnel - (472-5191)
Project Manager - Dennis Sasseville
On Site Coordinators - Alton Stone
Safety Officer - Elizabeth Gross (Phoenix Safety)
Technical Director - Don Bruehl
Other - Douglas DeNatale Steve Ransom
SITE DESCRIPTION
Type of Facility Company (on-site) landfill
RCRA Status Generator Disposer
Size About 15 acres BuildingsStructures None
Surrounding Land Use N Forested
(one mile radius) E Abandoned Railroad
Forest RuralResidential
S Forested
W Forested Mountain side
Unusual Features or Terrain None
Site Activities - Troy Mills manufactures textiles carpets and related
products Since 1968 waste materials including
drummed wastes have been landfilled on company proshy
perty Drums mostmany of which may be emptycrushed
are buried in an inactive section of the landfill
The active section is currently accepting waste
which is considered to be non hazardous
Specific - Improper disposal of hazardous waste
Problems - Leachate seep
Contamination of ground water
Hazardous WastesMaterials On-5ite
Wastes - Uncured foam rubber latex sludge
SBR rubber silicone defoamer potassium oleate soap
calcium carbonate and feldspar filters zinc oxide
and sulpher salt cure system
- Vinyl plastisol sludge
PVC dispersion resin DOP and DOA plasticiser
calcium carbonate filler organic pigments AZO
dicarbcnamid blowing agent zinc salts expoxidized
soybean oil cadmLum-bariin-zinc stabilizer Varsol
MEK prints and topcoats sludges
PVC acrylic resins organic and inorganic pigments
MEK solvent toluene silicate fillers
Industrial solvents and chemicals
11 -dichlorethane 12-dichlorothane
111-trichloroethane trichlorethylene tetrachshy
lorethene methylene chloride toluene benzene
ethylbenzene benzidine 33-dichlorobenzidine aeroshy
lein acrylonitrile napthalene benzoperylene dibenshy
zoanthrasene idenopyrene
Pesticides
There is a possibility for low levels of pesticides
to be on site These would include Chlorodane
heptachlor expoxide toxaphene aldrin alpha BHC
beta BHC 4-4-DDT endosulphan 1 heptachlor
PROJECT DESCRIPTION
Purpose Tb characterize ground water conditions at the site and to
characterize wastes buried on site
Specific Tasks
Site Reconnaisance
Task 1 - Magnetometer SurveyTopographic Survey
Task 2 - Excavation for inspection of drums
SECTION 2
HAZARD EVALUATION
Overall Degree of Hazard - Moderate
Task Hazard Proposed LPP
Site Reconnaissance Low Level C
Task 1 MagnetometerTopographic Surveys Low Level CD
Task 2 Drum ExcavationSampling Moderate Level B
Conpany records have indicated that a variety of industrial
and potentially hazardous wastes including drummed wastes
were disposed of on site Several of the subtances are
trade name materials or industrial process materials and it
is difficult to determine the specific chemical composition
Hazard is dependent upon concentration of material state of
material (solid sludge drummed liquid) and degree of
decomposition
Many of the materials - SBR rubber silicone defoamer
potassium oleate soap calcium carbonate and feldspar
fillers zinc oxide and sulpher salts plasticiser
calcium carbonate filler organicinorganic pigments AZO
dicarbonamid blowing agent epoxidized soy bean oil
cadmiura-bariun-zinc stabilizer - probably do not represent
a significant hazard to an inspection team if they are
bound into a sludge or solid Personnel are not likely
to injest or come into a prolonged high concentration
contact with these materials In powdered or dust conshy
ditions the materials are more hazardous due to the inhashy
lation of contaminated particulates
MEK (TLV-200ppm) toluene (TLV-100ppm) and Varsol
(turpentine thinner composition unknown) are volatile
organics which require respiratory protection and contact
protection
Depending upon state and decomposition PVC resins could
be a source of vinyl chloride monomer (VCM-a carcinogen)
requiring respiratory protection VCM is not adequately
filtered by air purifying respirators
Results from ground water sampling showed low levels of
industrial chemicals (PPB range) At these low conshy
centrations the chemicals do not represent a significant
hazard However the low concentrations in ground water indishy
cate the possibility of higher concentrations in the waste
materials
Industrial chemicals - napthalene (TLV-10 ppm) peryshy
lene anthrocene and pyrene which are hazardous
through inhalation or absorbtion Furthermore as
double benzene ring chemicals they are potential
carcinogens
Results from ground water sampling indicated possible
low levels (parts per trillion) of several pesticides
- chlorodane heptachlor epoxide toxaphene eldrin
Alpha BHC Beta BHC 4-4-DDT endosulphan These were
tentatively identified during a first analytical run
but not confirmed during a second run laboratory
review (GCA Bedford Mass) determined that the
material was actually a complex of highly degraded
heavy organics derived from the industrial waste The
presence of pesticides in industrial textile waste is
unlikely
Specific Hazards
1) Inhalation of organic vapors
Excavation of buried material and sampling of drums could
initiate high vapor concentrations
2) Fire and explosion
Many of the solvents are flammable liquids and volatile
Excavation of material and sampling of drums should
proceed cautiously in order to avoid rupturing shocking
or sparking of drums and material
3) Inhalation of contaminated dustparticulates
Excavation of buried material may result in a release of
particulates
4) Contact contamination
Excavation and sampling of wastes could possibly result in
contact with contaminated waste and soils necessitating
protective clothing
Necessary LPP
Site Reconnaissance - Level C The site has been visited on numerous
occassions by the state and private personnel Use of an HNU (102 ev
probe)- has not indicated significant vapor concentrations Significant
odors during dry weather or other hazards have not been noted
Sections of the landfill are currently active and adverse effects to
personnel have not been noted Level C - (tyveks rubber safety boots
organic vapor cartridges) is sufficient
Task 1 MagnetometerTopographic Survey - Level CD LPP will depend
upon the results of the Site Recon Significant vapor concentrations
or likelihood of particulates will necessitate an upgrade in the LPP
Otherwise Level D (work clothes safety boots boot wash) is sufficient
Task 2 Excavation and Sampling of Buried Drums - Level B The potenshy
tial for encountering significant concentrations of hazardous
materials during this task is moderately high Full Level B - (SCBA
chemical resistant tyveks hoods rubber safety boots rubber gloves)
will provide necessary respiratory and contactsplash protection
The use of the hooded yellow tyveck and the taping of ankleboots
wristsgloves and face maskhood junctions will provide complete conshy
tact protection
10
SECTION 3
FIRST AID FOR EXPOSURE
INHALATION OF VAPORSPARTICUIATES
Symptoms - eyenosethroat irritation nausea dizziness headache weakness fatigue lightheadedness drowsiness Loss of coordination confusion vomiting cramps (These sympshytoms are similar for most organic vapors particularly solvents)
Treatment Mild Exposure - Bring victim to fresh air Rinse eyes and throat if
irritated Heavy Exposure - (victim vomits very dizzy groggy faints etc)
Bring victim to fresh air Evacuate to hospital Prepare to administer CPR
Victim should be monitored for 48 hours in case of a delayed reaction
CONTACT EXPOSURE
Symptoms - Itching burning redness of skin Severe contact exposure for certain solvents will progress to CNS (central nervous system) symptoms similar to those for inhalation
Treatment - Remove contaminated clothing flush with water dry and banshydage Monitor victim for CNS symptoms for at least 48 hours
FIRST AIDSAFETY EQUIPMENT
The following equipment will be stationed at the Hotline or when appropriate down range
- Fully equipped first aid kit - Oxygen bottlekit - Nine (9) Ib chemical fire extinguisher - Eyewash bottle or other pressurized water filled container
11
SECTION 4
OPERATIONS SAFETY PLAN
This section outlines the specifics of safety procedures to be
used during each phase of the operations Safety procedures may be
upgraded or downgraded during site activities pending monitored changes
in the working environment All changes will be in line with the
General Level of Personnel Protection GuidelinesAction Levels for the
Troy Mills Landfill On-Site Investigation as described below
General Personnel Protection GuidelinesAction Levels
An in depth review of levels of personnel protection (LPP) is
presented in Appendix A
Level B (SCBA cotton coveralls or work clothes yellow tyveks (chemical resistant) steel toed rubber boots or work boots with disposhysible over boots and gloves)
Vapor concentrations (as measured on an OVA or HNU 117 EV Probe) greater than 5 ppm above background
- Oxygen deficient atmospheres less than 195
Specific actions (ie excavationsampling of drums) which could initiate a sudden moderate or high concentration of vapor
Level C (full face respirator organic vapor dust combo cartridge tyveks over work clothscoverails rubber safety boots gloves)
Vapor concentrations above an established clean zone backshyground level
During conditions (natural or personnel induced) which result in high levels of dust (visable above background atmospheric concentrations of particulates)
Level C activities require continual air monitoring
12
Level D (cotton coveralls or other work clothes safety shoes and safety glasses when down range Tyveks may also be needed)
Support areas and downrange areas where a higher LPP has not been deemed necessary
Continual air monitoring in downrange areas
Explosive Atmospheres
- 20 LEL (lower explosive limit) as recorded by an explosishymeter Secure and evacuate the work area
Oxygen Deficient Atmospheres
- Less than 195 (by volume) oxygen atmosphere requires upgrading the level of Personnel Protection to Level B
Task Specific Safety Plans
Levels of Personnel Protection indicated for specific tasks below are those which are anticipated to be used Changes in site conshyditions and results of air monitoring may indicate the upgrade downgrade of the LPP
13
Site Reconnaissance (SR) Date Sept 21 1983
Purpose To review on-site conditions and determine LPP necessary for further tasks To evaluate safety hazards Preliminary planning of future tasks
LPP - Initially Level C Updowngrade as necessary
Equipment - OVA HNU (102 ev probe)
Hotline - End of access road Upwind if possible
Command PostFirst Aid - Behind Hotline
Decontamination - Boot wash
Operations
Three man team Two persons advance in front with instrushyments Third person at distance as backup
Team methodically sweeps (criss cross) the proposed work areas with instruments
Specific points of interest (leachate seeps etc) are closely checked
All information is loggedsketch mapped
Upgraded LPP as necessary
14
Task 1 - Magnetic Survey Topographic Survey Date Week of October 3 1983
Purpose - Determine the location(s) and extent of buried drums Provide topographic information for site base map
LPP - Level CD
Hotline - End of access road (upwind if possible)
Decontamination - Boot wash
Operations - SO or other NAI personnel will perform a brief safety sweep of the work area
- Work team will then proceed downrange at the appropriate LPP Using the magnetometer the team will systematically criss cross -the work area
Task 2 - Drum Excavation and Sampling Date Week of November 14 1983
Purpose - Excavationsampling of buried drums in order to characterize the condition of the drums and the nature of the wastes conshytained in the drums and buried in the landfill
Msthod - Backhoe and hand labor will be used to uncover the drums in specified locations Samples will be obtained from spillage or leakage around the drums and of contaninated soil Selected drums which have accessible and openable bungs may be opened and sampled Drums will not be moved or staged Clean drums will be available to receive any significant spillage during the opening and sampling
Specific Hazards - Inhalation of organic vapors - Fire and explosion of drummed waste - Contact with contaminated waste or soil
LPP - Full Level B protection Backhoe operator at Level B Backshyhoe equipped with splash shield and without teeth on bucket
Hotline - At the end of the access road Upwind if possible
Decontamination - Procedures will essentially follow those as outlined by the EPA for Level B work Due to the inaccessibility of the site a field shower will not be available See Appendix B
Safety Equipment - OVA HNU eyewash fire extinguisher oxygen kit first aid kit metal detector non sparking implements
15
Operations - The cover soil is very sandy and the drums appear to be buried close to the surface which should facilitate excavation
- Minimum of 4 man team (exclusive of backhoe operator) Two or three man downrange team for digging and sampling One or two men in supportbackup at hotline
- Personnel will hand dig several small holes to approximately one (1) foot depth in each Location area If drums are not encountered the backhoe will scrape off soil to that depth
- Excavation will proceed alternating hand and backhoe methods At depths below four (4) feet the sides of the pit must be angled back to less than 45deg
- Prior to opening a closed drum the backhoe will nudgebump the drum to check for shock sensitive material An alternate method will be to attach a length of rope to the drum and from a distance pull on the rope to jog the drum
mdash Backhoe The backhoe operator will work at Level B utilizing air supplied from a large cylinder attached to the backhoe The backhoe will also be equipped with a splash shield A scraping bucket without teeth will be used
Prior to backhoe excavation at each location the area where the backhoe will be stationed will be checked for drums which could be ruptured by the backhoe feet
f Excavation areas will be checked for drums utilizing hand excavations or a metal detector prior to removing material by machine
16
SECTION 5
EMERGENCY INFORMATION
Emergency Telephone Numbers
If calling one of these numbers please state NAME LOCATION
and type of PROBLEM
Local Emergency Support
Fire Department (Troy 242-7759) For all emergencies use
Ambulance 352-1100 Mutual Aid (Keene) 352-1100
Police Department (Troy 242-7992)
Hospital 352-4111 (Cheshire Hospital in Keene)
Town Clerk 242-3845 State Agencies
NH Bureau of Hazardous Waste Management 271-4608
NH Water Supply and Pollution Control Commission 271-3503
NH Fire Marshall Office 271-3336
NH State Police (24-Hour Dispatch) 1-800-852-3411
Other
US EPA (24-Hour Hotline) 617-223-7265
Poison Center Mary Hitchcock Hospital 1-800-562-8236
Route to Hospital
- Follow dirt access road to Bowkerville Road - Left on Bowkerville Road to Rt 12 - Left (north) on Rt 12 through Troy to Keene NH - At major junction of Rts 9 10 101 and 12 go straight through
into Keene - At common go half-way around and go right on Court Street - Hospital is at 580 Court Street
17
Contingency Plan
Signal - five (5) one second blasts of auto or air horn Action - All personnel immediately excavate dovmrange areas and
report to Hotline for instructions
Personnel Unexplained Fire (if small) Accident (serious) Collapse of Personnel
Evacuate area Emergency ^ ^Evacuation Evacuate Area
First Aid
Estimate Explosion Level B (for Potential Contact Outside Help evcavation)
Evacuate Victim i If
Level B Prepare for Transportation
1 First AidCPR Use extinguisher Transport
Contact Outside Help Notify Coup any Have Proper Information Personnel (see below) 1
Transport
Call Fire Dept (if necessary)
For Hospital Victim
- Name and Phone of family physician
- Description of Incident chemicals involved symptoms nature of injury proposed treatment and plan of transportation
18
APPENDIX A
LEVELS OF PERSONNEL PROTECTION
Because of the possible dangers of exposure to toxic or harmshyful chemicals protective equipment must be worn during work on hazardous waste sites Levels of Personnel Protection (LPP) describe respiratory clothing and other equipment necessary for protecting personnel against expected hazards
The descriptions below are for full dress at a given LPP where hazards are expected to be at a maximum for which the given LPP is conshysidered adequate Depending on site conditions and work activities the clothing and dress requirements of a given LPP are commonly modified
LEVEL A
1 Personal Protection Equipment
Positive Pressure SCBA (MSHANIOSH approved) Operated in the positive pressure mode
Totally Encapsulating Suit (boots and gloves attached)
Gloves - Inner (tight fitting and chemical resistant)
- Boots - Chemical - protective steel toe and shank Depending on suit boot construction worn over suit boot
- Gloves shy Outer chemical-resistanttion worn over suit gloves May bchemical-resistant gloves worn insid
Dependinge replaced withe suit glo
on s
ves
uit construcshy tight-fitting
- Underwear shy Cotton long-John type
- Hard Hat (under suit)
- Disposable protective suitover encapsulating suit)
gloves and boots (Worn under or
- Coveralls (under suit)
- 2-way Radio Communications
Optional
19
2 Criteria for Use
A The type and concentration of toxic substances are known and require the highest level of combined protection to the respirashytory tract skin and eyes These conditions would be
1 Atmospheres which are immediately dangerous to life and health (IDLH)
a IDLHs can be found in the NIOSHOSHAs Pocket Guide to Chemical Hazards andor other references
2 Known atmospheres or potential situations that would effect the skin or eyes or could be absorbed into the body through these surfaces in toxic quantities
a Potential situations are those where vapors may be generated or splashing may occur through site activities
b Standard reference books should be consulted to obtain concentrations hazardous to skin eyes or mucous memshybranes
3 Oxygen deficient atmospheres with above conditions
3 At sites where the type andor potential concentration of toxic substances are unknown
1 Unless circumstances strongly indicate otherwise the site should be presumed to present hazards to the respiratory system skin and eyes Level A protection would provide the highest level of protection for the initial entry team
a Such circumstances might be
1 Environmental measurements contiguous to the site
2 Reliable accurate historical data
3 Open unconfined areas
4 Minimal probability of vapors presence or splashing with cutaneous effecting substances
2 Enclosed areas such as buildings railroad cars ships holds etc
20
LEVEL B
1 Personal Protective Equipment
Positive Pressure SCBA (MSHANIOSH approved) operated in the positive pressure mode
- Hooded chemical-resistant suit
Gloves - Outer chemical-protective
Gloves - Inner tight-fitting chemical-resistant
Boots - Outer (chemical-protective heavy rubber disposables)
Boots - Inner (chemical-protective steel toe and shank)
2-way Radio Communications
Hard Hat
Face Shield
2 Criteria for Use
A The type and concentration of hazardous substances are known and require the highest degree of respiratory protective but a lower level of skin protection
1 Atmospheres which are immediately dangerous to life and health (IDLH) Type and concentration of vapors in air do not present a hazard to the small unprotected areas of the body
2 Atmospheres with concentrations of known substances greater than protection factors associated with full-face air-purifying respirators with appropriate cartridges
3 Atmospheres with less than 195 oxygen
B When a determination is made that potential exposure to the body parts not protected by a fully encapsulated suit (primarily neck ears etc) is highly unlikely
1 Known absence of cutaneous or percutaneous hazards
2 Activities performed preclude splashing of individuals
C Level B protection is recommended as the lowest level of protecshytion for initial entries until the hazards have been further identified and defined by monitoring sampling and other reliable methods of analysis and personnel protection equipment commensurate with these findings utilized
21
LEVEL C
1 Personal Protective Equipment
Full-face or half-face air purifying respirator (MSHANIOSH approved)
Chemical-resistant clothing
Gloves - Outer (chemical-protective)
Gloves - Inner (tight-fitting chemical-resistant type (or woven liners)
Hard Hat (face shield optional)
Boots - Outer (chemical-protective heavy rubber throw aways)
Boots - Inner (chemical-protective steel toe and shank)
2-way radio comnunications
Safety glasses required with half-face respirator
2 Criteria for Use
A Site known to contain potentially hazardous materials exceeding
1 Air concentrations requiring a protection factor no greater than that afforded by a full-face mask
2 Harmful levels to unprotected body areas (face neck etc)
3 Well-documented reliable history of site and patterns of prior entry
C No evidence to suspect acute or chronic toxicity to exposed personnel
D Continuous air or personnel monitoring should occur while wearing Level C protection
22
LEVEL D
1 Person Protective Equipment
Chemical resistant aprons
BootsShoes - Safety or chemical-resistant steel toed boots
Boots - Outer (chemical-protective heavy rubber throw-away)
Half-face respirators immediately available
Safety glasses or safety goggles
Gloves
2 Criteria for Use
a No indication of airborne health hazards present
b No gross indications above background on the photoionizer andor organic vapor analyzer
c Continuous air or personnel monitoring should occur while wearing Level D protection
23
APPENDIX B
DECONTAMIHATION PROCEDURES
Depending upon activities and location on site it may be
necessary for personnel to decontaminate prior to leaving the conshy
taminated zone Procedures described below are typical for Level C
operations
Upon exiting downrange (contaminated) areas all personnel are
required to decontaminate by means of the following procedure
1 Place equipment in the Drop Zone at the Hotline
2 Enter the Decontamination Station
Boot Wash Walk through wash tub and scrub boots then rinse boots in second tube
Glove Wash In two pan wash scrub over gloves rinse set out to dry
2 Remove tyvek - if leaving the contamination reduction zone (CRZ) and proceed to clean zones
3 Dispose of heavily contaminated clothing and under gloves
4 Remove respirator
5 Use disposable gloves to clean equipment
6 Use a two bucket (washrinse) to decon respirators at the end of the working day or if they become heavily contami nated
The procedures for a typical Level B Decontamination are
outlined on the following page
TANK CHANGE 9
CONTAMINATION REDUCTION
ZONE
OUTER GLOVE REMOVAL
EXCLUSION ZONE
TAPE REMOVAL
BOOT COVER
GLOVE WASH
(bull)mdashQ-G--copyshySOOT COVEH SCOT COVES 4
REMOVAL GLOVE RINSE
SUITSAFETY BOOT WASH
SU1TSC8A78OOTGLOVE RINSE
SAFETY BOOT 10 REMOVAL
SCSA BACKPACK REMOVAL
SPLASH SUIT 12 REMOVAL
INNER GLOVE WASH
INNER GLOVE RINSE
FACE PIECE REMOVAL
INNER GLOVE 16 I REMOVAL
INNER CLOTHING REMOVAL
FIEUJ 19 REDRESS WASH
SEGREGATED EQUIPMENT
OROP
mdash -HOTLINE-shy
DECONTAMINATION LAYOUT LEVEL B PROTECTION
FIGURE A2-1
CONTAMINATION CONTROLLING
SUPPORT ZONE
25
APPENDIX C
PERSOHNEL AND RESPONSIBILITIES
Project Manager (PM)
Overall responsibility for all Project activates budget
schedule investigative operations safety personnel
On Site Coordinator (OSC)
Responsibility for activities at the site Primary responshy
sibilities include
1) Interfacing with the client state EPA media or other groups
2) Reviewing technical operations
3) Reviewing site safety in particular information supplied by the Site Safety Officer
4) Enforcing site safety and compliance with the Safety Plan
5) Directing Emergency Contingency operations
Safety Officer (SO)
Responsibility for directing the safety of operations and impleshy
menting the Safety Plan Specific responsibilities include
1 Assuring that appropriate personnel protective equipment is available and properly utilized by all site personnel
2 Assuring that personnel are aware of the provisions of this plan are instructed in the work practices necessary to ensure safety and in planned procedures for dealing with emergencies
3 Assuring that personnel are aware of the potential hazards associated with site operations
4 Supervising the monitoring of safety performance by all pershysonnel to ensure that required work practices are employed
26
APPENDIX D
PERSOHHEL CASUALTY
Personnel casualty would most likely result from either chemical
contamination heat-related problems physical injury from accidents
(ie falling lacerations etc) in performing the work or a comshy
bination of one or more of the above The appropriate action depends on
the type of injury involved with the priority being to assist the
casualty as soon as possible without endangering other personnel
Riysical and heat-related injuries can and should be treated
immediately with appropriate first-aid measures and follow-up medical
attention if necessary The injured worker(s) shall immediately move
out of the hot zone or if necessary be moved out by fellow workers as
soon as possible The OSC and Safety Officer shall be notified immeshy
diately and shall recommend further measures as needed
Chemical-related injuries require a much more cautious approach
so as to keep casualties to a minimum If a worker injured by chemical
ejqgtosure is able he shall notify the nearest co-worker and leave the hot
zone immediately- The co-worker shall ensure that the OSC and Safety
Officer are immediately informed and shall accompany the casualty from
the hot zone to the decontamination zone The OSC and Safety Officer
shall determine the appropriate measure
27
APPENDIX E
GUIDELINES FOR SITE OPERATIONS
In order to deal with the potential dangers of exposure and conshy
tamination of a hazardous waste site three zones are delineated
according to the degree of hazard The three zones are 1) Downrange
or Contamination Zone 2 Contamination Reduction Zone (CRZ) 3) Support
or Clean Zone
Downrange or Contamination Zone
The Contamination Zone is the active work area of the site which
encortpasses the areas where there is a potential for exposure and in
which investigative activities will occur (drilling sampling etc)
Within the Contamination Zone the designated level of hazard will be
established necessitating the utilization of personnel protective
equipment
Hot spots are those areas Downrange where observations instrushy
ment readings or specific activities indicate a high probability of
closure or contamination and may require an upgrade in the LPP in the
vicinity of the Hot Spot
Contamination Reduction Zone
The CRZ is an area between the Downrange and Support Zones where
decontamination of equipment and personnel occurs
28
Personnel entering the CRZ shall wear protective clothing and
carry the respiratory protection required for entry within the
Contamination Zone
Personnel working within the CRZ shall remain cognizant of the
CRZ in order to be prepared for any need to increase their level of proshy
tection within the CRZ
A decontamination station will be located at the outer perimeter
of the CRZ All personnel who have been within the Hot lane shall pass
through a decontamination procedure prior to re-entering the Support
Zone
Support or Clean Zone
The Support Zone is the outer area and may be considered to be
clear of contamination potential The command post will be located
within the Support Zone
a) The Command Post will serve as the OSCs headquarters and
will be equipped with
1 Communications
2 Safety Plans
3 First Aid Supplies
4 Analytical Equipment
5 Safety Equipment
APPENDIX B
WORK PLAN
WORK PLAN FOR
TROY MILLS LANDFILL TROY NEW HAMPSHIRE
DRUM EXCAVATION AND SAMPLING
Prepared by
NORHANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
1933
WORX PLAN FOR
TKOt MILLS LANDFILL TROT NEW HAMPSHIRE
DRUM EXCAVATION AHD SAMPLING
DATS November 16-18 1983
PURPOSE
To determine the condition of drums (ie erroty or full
crushed rusted leaking etc) buried in the Troy Mills Landfill To
obtain representative samples toward identifying the types of materials
buried in the landfill This information will be used in the detershy
mination of the level of remedial action needed at the site
METHOD
Using the results of the magnetometer survey the (10) points
have been randomly chosen across the area where the buried drans are
expected to be found Each point is central to an Excavation Location
-- an area four (4) to six (6) feet in diameter which will be excavated
in order to characterize the condition of the drams and to obtain waste
sarples
Preliminary observations have indicated that many of the drums
may be buried within 1-2 feet of the surface Therefore the investigashy
tion will proceed in two phases
Phase 1 mdash Hand Excavation By digging several small holes in
each Location personnel will determine if drums are located within
about one to two feet of the surface If drums are encountered the
excavation will proceed by hand uncovering the dnris for evaluation and
sampling Where drums are not encountered near the surface excavation
at this location will be postponed until Phase 2
Phase 2 mdash HandBackhoe Excavation After all Locations have
been attempted during Phase 1 those Locations in which drums were not
encountered wall be further excavated using a combination of hand
backhoe digging
It is expected that one to two days will be necessary to
cor^piete each phase Depending upon the results of Phase 1 it may not
be necessary to iroleraent Phase 2
Spare drums will be on hand for containerizing any significant
spillage resulting from sampling efforts Excavation locations will be
identified with marked stakes and the holes will be backfilled at the
conclusion of the investigation
SPECIFICS
Excavation Locations (Holes)
Number of proposed excavations is ten (10)
Locations of excavations are presented in Appendix A
Hole Size mdash It is expected that a hole from four (4) feet to six (6) feet in diameter at the bottom (depth at which drums are encountered) will be sufficient to characterize the drums at each Location Deeper excavations will require increasingly large top diameters
Hole Depth -- Holes will be excavated to a maximum depth of six (6) feet Due to the sandy cover material the excavation of deeper holes is probably impractical from both safety and efficiency stand points
If after attempting excavation at each of t-ie 10 proposed
1ocatiors irums are not encountered within six (6) fet of the surf ice
in enough locations to characterize the site excavations nay be
attempted to depths greater than six (6) feet if scil stability permits
or a new set of sampling locations may be chosen
(Excavations to depths greater than six (6) feet require a
significant increase in work The sides of the hole crust be graded back
to less than 45deg in order to insure the safety of investigatorysampling
personnel It may also be necessary to employ bracing bulkheads etc
for trench support)
Excavation Identification
Proposed excavation Locations have been consecutively numbered
from 1 to 10 beginning at the east end of the landfill They will be
marked with numbered stakes
Excavation Methods
Phase 1 mdash Within each Location personnel will dig a nunber of
small holes - about one (1) foot in depth - to probe for drums If
druns are encountered they will continue to excavate until the drur3
are sufficiently uncovered for characterization
Phase 2 mdash After hand probing the Location with snail holes
the backhoe will remove cover material to the one (1) foot depth The
Location will then be probed to a two (2) foot depth before removing
further material Excavation will proceed alternating handprobing and
backhoe excavation until drums are encountered or the maximum six (6)
foot depth is reached
If excavations to depths greater than six (6) feet are undershy
taken they will proceed using the above method
Santnlea
Due to the effort involved in excavating and because conshycentrated waste samples are not expected to undergo rapid degradation it is considered expedient to obtain all readily available samples (exclusive of closed drum samples -- see belcw) These can then be submitted for laboratory characterization as determined by need and budget restrictions
An attempt will be trade to secure at least one sample froa each excavation in order to help characterize the distrishybution of waste materials across the site An attempt will also be made to secure samples of observably difshyferent materials
Sample Types and Mediums - Solid liquid and sludge samples are possible Samples will be obtained from in order of preference -- 1) leakage uncontainerized waste or contaminated soil 2) waste contained in open conshytainers - drum already has a hole or no top or other access point 3) sealed containers
The opening of closed containers will be considered if it is decided that it has not been possible to obtain a sufshyficient number of representative samples from the other mediums
Each sample will consist of two (2) 8-oz jars (with teflon-lids) filled about 23 full One jar will be for organic analysis and the other for inorganic analysis
Sanole Identification - Samples will be identified with a number corresponding to the Excavation Location and a letter Example if three samples were obtained from Location 2 they would be samples 2A 23 and 2C and Samples 2Ad 23d and 2Cd for duplicates
Sampling Methods and Volumes - 11 mm hollow glass tubing trowels disposable scoops will be available to obtain samples Samples tools will be disposed of or deconshytaminated between each sample
Drum Samples - If necessary an attempt will be cude to obtain samples from sealed drums Oily o^und non-rusted drums will be considered Bunjs rust be xn suitable conshydition -jo that the dram cm be openoi withrut cvis ing dainai -ind ca-i be resell od to pr-jvcrt l V-i 30
There wil l be no staging or movement of drums in order to faci l i tate sampling Only drums with accessible bungs will be considered for sampling
Procedure for Drum Sampling
1) Excavate around top of drum
2) Monitor air in the adjacent area
3) Chec for shock sensitive - Loop rope around top of drum stand at a distance give drum several hard jogs by pulling on the rope An alternative nethod is to lightly jog the drum with the backhoe bucket
4) If the drum is not upright place a catch basin under the bung
5) Open drum with bung wrench
6) Monitor the air atin bung
7) Sample drum -- liquids insert glass tube the fu l l length into the drum in order to obtain a column of the materials in the drum Solids use scoop to dig out material through the bung or use a sampling trowel
3) Reseal the dram
Spill Control
The possibility exists during the sampling and excavation for a
drum to be ruptured or otherwise have spillage Clean drums wil l be on
hand to receive significant spillage resulting frora sampling or excavashy
tion They will not be used for clean up of widespread uncontainerized
waste or existing leakage
Personnel
The work team will require four (4) persons (exclusive of the
backhoe opera tor) Trie downrange team will consist of three (3) persons
-- two (2) for d igg ing and sampl ing and on ( 1 ) for logging air moni shy
toring and photographing One (1) person will be at the hotline in
support mdash as safety backup person to fill air bottles to deconshy
taminate samoles to assist in decontamination of personnel
Documentation Logging
The following information will be recorded at each location
nmber of drums uncovered and the condition (crushed empty rusted
sealed etc) of each drum evidence of spillage or contaminated soil
labels on uncovered drums samples (time drum ID type description)
periodic air monitoring information depth at which specific events
occur or drums are buried soil condition presence of ground water
In addition photographs will be taken of specific events or
items of importance during each excavation and of each sampling incishy
dent The time description of subject photographer excavation
location and photo number will be logged for each photograph
Analytical Laboratories and Schedule
RAI Hampton NH
Initial schedule
Ten samples for GCrns for organic priority pollutants Samples may also be submitted for inorganic anlaysis or volatile organic analysis depending upon waste materials observed during the excavation
APPENDIX A
TABLE A-1 EXCAVATION LOCATIONS
EXCAVATION BASELINE RANDOM RANDOM
NUMBER GRID COORD SEGMENT STATIOH OFFSET
1 7E+1 565N 0- 60 26 (25) 16
2 9E+5 13S 60-120 50 (110) 9
3 8E+0 31S 120-180 20 (140) 7
4 4E+5 483 180-240 50 (230) 25
5 3E+3 45S 240-300 14 (254) 20
6 OE+6 5S 300-360 34 ( 334) 50
7 2W1 5 24N 360-420 45 (-155) 14
8 5W+6 42N 420-480 38 (518) 20
9 6W+1474N 480-540 8 (543) 7
10 8W 5 11011 540-600 11 (611) 31
Locations are plotted on Map A-1
Method of Choice A stratified random sampling method was used to choose 10 Excavation Locations within the magnetic anomaly
The axis of the magnetic anomaly was used as a base line and divided into ten 60 foot long segments Using a randora nirnbers table a distance along each secpent was chosen (Random Station) and a line drawn at that point perpendicular to the base line Again using a random numbers table a distance was located along each perpendicular line by measuring inward from the line denoting the edge of Area A (Random Offset) The Grid Coordinates for each of the Excavation Locations were graphically determined from the grid overlay (this overlay has been surveyed and intersections field located)
It was judged that 10 excavation locations within the magnetic zone and two outside of the zone would be sufficient to characterize the area would produce statistically valid iati and coli be expected to be co~letod within 2-3 days work period
to
80
cu0
cgtc
APPENDIX C
MAGNETIC INVESTIGATION TROY MILLS INC LANDFILL SITE
TROY NEW HAMPSHIRE
For
NORMANDEAU ASSOCIATES INC 25 Nashua Road
Bedford New Hampshire 03102
By
JOHN F KICK PhD GEOPHYSICIST
Box 6 Dunstable Massachusetts 01827
(617) 649-6650
Noverber 19S3
MAGNETIC INVESTIGATION
TROY MILLS INC LANDFILL SITE
TROY NEK HAMPSHIRE
INTRODUCTION
A high resolution ragnetic investigation was completed on the Troy
Mills Inc landfill site in Troy New Hampshire by John F Kick
Consulting Geophysicist The purpose of the investigation was to
delineate the extent of buried steel drums under closed portions of the
Troy Mills landfill The information is needed as a part of a study of
the landfill that is being conducted by Normandeau Associates Inc
FIELDKORK
Magnetometer measurements of total field intensity were made over an
area that was reported to contain buried steel drums and adjacent
landfilled areas that contained unknown waste materials The area of
investigation included capped and grassed closed areas along the south
margin of the landfill site and adjacent areas The fieldwork was
performed during October of 1983
Eighteen parallel rows of measurements were conducted along north-
south lines (using magnetic compass directions) A spacing of 20-feet
was used between rows and magnetometer measurements were made at 10-foot
intervals along the rows Greater intervals between measurements were
used at the ends of the rows and in periferal areas with low magnetic
-JF Kick 01shy
field gradients
A series of magnetic field measurements were made at an adjacent
base station throughout the survey to torn the basis for a daily
variation curve The base station was located at a site with typical low-
gradient background magnetic field intensity measurements
MAGNETIC SEARCH METHOD
Theory Magnetic search methods involve the detection and
measurement of anomalies in the Earths magnetic field caused by the
presence of materials with contrasting magnetic susceptibility Iron and
steel objects generally have very high magnetic susceptibility contrasts
with usual surrounding materials and therefore produce magnetic
anomalies The amplitude shape and detectable distance of the anomaly
depend mostly on the particular susceptibility contrast and size of the
object Magnetic anomalies are measured in units called gammas The
normal magnetic field in this area is over 50000 gammas A 5-inch
screwdriver will produce an anomaly of 5 to 10 gammas at a depth of 5
feet and an anomaly of 1 gamma at a depth of 10 feet A 1 ton automobile
will produce an anomaly of 40 gammas at a depth of 30 feet and an anomaly
of 1 gamma at a depth of 100 feet The magnitude of an anomaly caused by
a single steel drum will vary with its condition (new heavily rusted
etc) Tests using a single light weight (somewhat rusted) drum on the
surface with the magnetic detector at a height of of 12 feet produced an
anomaly in the range of 40 to 50 gammas
Total magnetic intensity disturbances or anomalies are almost always
asymmetrical sometimes appear complex even from simple sources and
usually exhibit the combined magnetic effects of several sources which
can produce a given anomaly The apparent complexity of such anomalies
is a result of several relatively simple functions of magnetic dipole
-JF Kick 02shy
behavior Reasonable assumptions about the geology and buried source
conbined with an understanding of magnetic dipole behavior can usually
lead to a satisfactory qualitative interpretation More detailed
interpretations nay require modeling studies
Instrumentation Field equipment on this project included a EGampG
Geometries Memory-Mag G-856 proton precession magnetmeter The
instrument has a resolution of +01 gamma The magnetic field detector
is separate from the rest of the instrument and is mounted on an 8-foot
staff to provide measurements that are a constant height above land
surface
Magnetic Data Analysis For the purposes of data reduction and
anomaly delineation it was assumed that base station total field
intensity measurements were typical background values for the site
Measurements made at frequent intervals at the base station were used to
prepare a diurnal variation curve for the site Anoraly values were
obtained by subtracting background values from the base station curve
from measurements collected in the area of investigation
RESULTS
The reduced results are presented in the form of a magnetic anomaly
contour map (Figure 1) and two profiles across the area of investigation
(Figures 2 and 3) The map and profiles show that very steep magnetic
field gradients and large departures form background occur in an
irregular shaped band that is about 460 feet long and ranges from about
30 to about 200 feet in width The magnitude of the anomaly is such that
a significant deposit of ferromagnetic materials (such as steel drums) is
indicated
In using the plotted magnetic results it should be noted that the
greatest concentrations of ferromagnetic materials probably do not
-JF Kick 03shy
directly underlie the peak magnetic anomalies A shift is caused by the
inclination of the Earths magnetic field and by the dipolar nature of
ferromagnetic deposits The inclination of the Earths field is about 76shy
degrees northward in the vicinity of Troy The dipolar effect is induced
by the Earths field and results in negative anomalies immediately north
of large positive anomalies
Magnetic Anomaly Map The magnetic anomaly map (Figure 1) indicates
10 positive peaks of varying size shape and intensity Associated
negative anomalies of a broader and less intense nature lie immediately
north of the belt of positive anomalies The configuration of the
anomalous area is indicative of lense-shaped and cigar-shaped bodies of
ferromagnetic materials Steep-sloped anomalies are indicative of very
shallow source materials The thickness of the ferromagnetic deposit
cannot be easily determined on the basis of intensity and size of
anomalous peaks because a small mass of iron or steel at the surface can
duplicate the anomaly caused by a much larger mass at depth The
ferromagnetic source materials can generally be expected to lie north of
the positive peak of anomalies and south of the adjacent negative
anomaly Modeling can provide the best approximations of the depth and
density of the ferromagnetic source materials The outer boundaries of
the source materials can be expected to overlap the positive peak and
negative anomaly somewhat depending on the depth and configuration of
the deposit
For illustration purposes two north-south rows that were profiled
are discussed below
Magnetic Anomaly Along Row 9-East Two strong positive magnetic
anomalies (3645 and 2436 gammas) and adjacent negative anomalies were
profiled along Row 9-East (Figure 2) The approximate centers of the
ferromagnetic deposits are believed to underlie stations 50 north and 75
feet south of the base line The rounded shape of the north positive
-JF Kick
anoraly nay indicate somewhat deeper burial of the ferromagnetic deposit
Magnetic Anomaly Alone Row 7-West Figure 3 shows the most intense
positive magnetic anomaly (4470 gammas) that was detected on this
project The steepeness of the slopes is indicative of very shallow
source materials An uneven burial pattern is suggested by the two-
peaked positive anoraly The negative anomaly south of the two peaks is
unusual and may be related to another positive anomaly to the southeast
(along Rows 5 and 6 20 feet north of the base line) The centers of the
sources of the positive anomalies are probably approximately 80 and 120
feet north of the base line along Row 7-West
-JF Kick 05shy
DISTANCE FROM BASE LINE(FEET)
CO
_J
6a
CO
LU CD
o cr CD o lt
i-mdash LU Lu 2 Q lt2 Z
lt ltr
CsJ
LU aIDCD Li_
SVWWV9 N A1VWONV
s
3U|1
0 O
0 O o
SVWWV9 NI A1VWONV
t o H
X
D 8 j~ 00
UJ UJ en UJ u UJ
o ui o CC
CO
s o
S u
UI o
O Cgt mdash o
0020
UJ U
o o CJ
ro 8 LU
CC ID egt LL
APPENDIX D
LABORATORY ANALYSES
RAI
Resource Analysts Incorporated Box 4778 Hampton H 03842
(603) 92^7777
TO PO 830318
Mr Doug DeNatale Date Received 12-2-83 Kormandeau Associates 25 Nashua Road Lab Number 2887 Bedford NH 03102 J
Date Reported 1-3-84
IDENTIFICATION
SAMPLE DESIGNATION PARAMETER
Volatile Organics Analyses by EPA Method 624
Acid and BaseNeutral Extractable Compounds Analyzed by EPA Method 625
Metals Analyzed by Standard Methods 303A
Please see attachments for all results
Results expressed in mgL unless otherwise designated lt = Less Than
ClarkeFosterVan K o u w e i b r h 1 ANALYST DIRECTOR
METHODS Standard Methods (or the Examination ol Water and Waitewaler 15th Edition or other EPA approved mtlhodologiei unless otherwise designated
Phys ica l descr ip t ion of sample
LiquidSludop
Saiple workup
Volitile f ract ion Methannl F-1-rarMrm CSVJ Rdfi-Smm
Semivolatile f ra ictio0onication Extraction fSW 846-3540^ Inorganic f rac t on Acid Digestion (SW 84h-iOS(V)
ACS3 COMPOUNDS
rr t CAS CAS
(71 A) tt-Ot-2 i^t TT i^MoroprvrfgtOi (73B) 30-32-1
(23 A) J9-JO-7 ^bull^^ lof o^^ft^crt gto (7 OB) 205-M-2
(2 A) 13-37 -J 2- chlorophenol (75B) 207-01-
(3 A) 120-13-2 2raquo^icMoroorgtenol (748) 211-01-9
(MA) 103-47-9 2-dimethv lohenol (77 B) 201-94-1
(37A) U-73-3 2- niiroDhenol (7IB) 120-12-7
(MA) 100-02-7 raquo-niiroprienol (7raquoB) lraquol-2raquo-2
(raquoA) Jl-21-3 2 - in i tr opheno 1 (106) raquoi-73-7
(40 A) 33-J7-l k4-dinnro-2-mlaquothylplaquogtergtol (I IB) 15-01-1
(4A) I7-U-3 (xntictiloroorraquonol (I2B) J3-70-3
USA) 101-93-2 pxmol (I3B) 193-39-J
(14 B) 179-00-0 RASENEUTOAL COMPOUNDS
( I B ) 13-32- raquocmlaquophtgtgtefgtlaquo
(36) 92-173 benzidine (2V) 107-02-S
( I B ) I20-I2-I l2t-tricMorobenzlaquonlt (3V) 10713-1
OB) 111-71-1 he laquo laquoch 1 or o benz erve (laquoV) 71-A3-2
(176) 47-72-1 hetraquocWoroltthlaquone (4V) X-23-5
U S B ) 111-- bu(7-cloroetrivl)ether (7V) 101- 90-7
(7CB) 9 I -3J -7 2-Chlororuprthraquolene (10V) 107-04-2
(73B) 95-50-1 l2-diCMoroblaquonzene ( I 1 V ) 7|3j^
( K B ) XI-73-1 13-didilorobtnzene (13V) 7J-3-3
(27B) 104-M7 1tmdash djcMorobenzene dkV) 79-00-3
C2IS) 9i9i-l 33-dictgtloroblaquoazidinr ( I JV) laquo-3-J
(33B) 12I -U-7 2gt-dinicrotoluer (14V) 7J-00-3 (KB) 4O4-7C-7 24-dinitrotoluene (UV) 110-73-1 (J7B) 122-A4-7 1J -diprienv lhydrraquo z irf (23V) lt7 tt 3
(MB) Z0-fc-0 UuorraquonThelaquo (2raquoV) 7J-35-
(W551 700J77-3 -ctilorophenyl prlaquonyl ether (JOV) 1M-40-3
( raquo I 6 ) 10I-J3-3 raquo-6romoprgtefgtyl prtenyl ether (32V) 71-17-3
(raquo7B) 33132-9 bU (2-cMorobopropyl) ether (33V) 10041-02-4
(raquoJ6) i l l -91- l bu (2-laquo^loroeTho)ry) methane 10041-01-03
(B) D-U) hexraquopoundj1|orobutaltlicne (31 V) 100--
(33B) 77-raquo7- heiKCtilorocycIopentadicrve (WV) 7J-CT-2
OB) 7IJraquo-I traquoo oh or or (raquo3V) 7raquo-17-3
(J3B) gtl-20-3 nphthraquolene (UV) 7raquo-I3-9
(546) n-tj) nitrobenzene (7V) 7J-2J-7
(426) U-Xl-4 bullJ -n itr o tod iphenyU mi ne (UV) 75-27-J
(OR) 421-W-7 N-oitrcnodipropYlirrUne ^raquoraquoV) 73-49-k
(446) I 1 7 J I - 7 bu (2-eltr^lheryl) phtfaUte 8200 (3ov) 73-71-1
(476) 13-U7 benzyl buryl phttwlite (51V) 124-kt-l
( U B I M-71-2 di-fl-utgtl pMhUre (13V) 177-II-
( lraquo6) 117-1 -0 dj-n-octvl prithlaquoUte (UV) 101-IS-3
(7CB) W-44-2 dielhvlphtraquollaquo (17V) 79-OI-t
( 7 | B ) I 3 I - I I - J dj^laquorTvipnthraquoUtr (UV) 7J-OI- (776) H-J5-5 bnro(raquogtnthrraquocefvr
Iab I D N o 2SS-10
C l ien t ID 1A64223
RASENEUTRAL COMPOUNDS
bfzoltraquogtprrene
benzoltb)flucrraquornNene
benio(llaquo)fluorraquonthene
chryiene
bullcenaDhthvien
raquontnrraquoctne
benzoltghi)perrlefgte
Iluorene
phergtraquonthrmlaquo
dibenzoltraquoMaithrraquocenraquo
indeno(123-cd)pvrene
prrene
VOLATHES
(frolein
bullcrvlooitrdf
benien
orbon Temchloide
CMorobeniene
1 7-dJchlorolaquothnr
111-trieftloroethine
ll-ltJichloroetrufle ll7-triCilorigtetMrlaquor
l127-tetrraquocMorothfllaquo
chloroethlaquo-e
7-dMoroeThraquo|virgtvl eirwshy
chloroform
11-didMoro^tfwnr
trinj- 1 2-dictMorolaquoirgtene
1 7-ltlicMoroproplaquorve
trini- 1 3-ltJichloroorcrpeoe
cu-lJ-lieMorocT oo eashy
rthy Uveniene
methrlene chloridf
chloromethine
bromome thraquone
bro mod iCTi lore met Mrgt
(Juorotr ichloromthraquor
di cMlor od 1 f 1 uore ngtet hj^gt
chloreltJbnjmomethne
te tr ten 1 or oet rx-r
laquouene 12000
tncMeroethe^e
Cidrr ium Chromiutr 10
All results are expressed as ucg veicht as received Nc ertrv denotes -0r ~ ^ 1 i rt
P h y s i c a l d e s c r i p t i o n of
SoilSludge
sample
Sanple workup
Vol i t i le f ract ion p^r Exf- rar r ion fST7Semivola t i le f rac t ion So^h^Pt Fgtr f ra r f ion
846-SOTO^ (SWRdfi-^SiO1)
Inorganic fract ion Ar id nio-psrirm
AOD COMPOUNDS
m CAS (2i A) tt-04-2 2raquot- Wichlorophenol
(22 A) J1-50-7 p-cfi I or o-n-cre laquoo 1
(2A) 13-57-1 2- ctiloroprienol
O iA) 120-13-2 2raquo^icMoroprnol
(gtraquoA) 103-47-1 2f 4mdash^imetSv Ip^enol
(37 A) U-73-3 7mdash Ti j oprtenol
(JraquoA) 100-07-7 mdash mdasho i Br opr^e no 1
JJ1A) 31-21-3 if mdash4 irtiTroprienol
(40A) J34-32-1 4 T4-4initrogtmdash 7 nte tny Ipnenol
(4A) f y _H 5 plaquontchlaroorwnol
(43A) J 01-95-7 prienol
rV ipoundNEUTRAlaquo- COMPOUNDS
( I B ) raquoJ-32-raquo
(3B) 17-17-5
( IB) 170-12-1
(IB) 1I1-7I-I
(17B) 4777-1
( I t B ) 111--
(20B) 11-31-7
(236) 15-50-1
(245) 51-73-1
(77B) 104-4-7
(285) 11-14-1
(336) 121-142
(34B) 404-70-2
(J7B) 127-M7
O1B) 2O4--0
(406) 7003-72-3
(416) 101-35-3 lt raquo 2 6 gt 3H3I32-1 ltraquo36) 111-11-1 (57B) S7-U-3
(336) 77 -raquo7-
(36) 71-31-1
(33B) 11-20-3
pound34 6 1 n-i33 (UB) tt-30-4
(436) CI-44-7
(4461 117-11-7
(47B) U-417
( U B I 14-747
(U6) I17_t-0
(7CS) l-laquo2
(7 I B ) t J U t l - gt
(7761 54-55-3
CT-~- i_i w i Miirn 0
resul ts
b^TMdint
1 2 t-o- icn lorobenl ergtlaquo
SeTraquochloroblaquorierraquoe
hrxchlorolaquotSlaquone
bu(2-chloroethv|gtether
2 -lt3M or onraquo ph ti1 ene
1 2-ltJictilorotgtmzcne
13-dicWorotxerzene
1 4-djch 1 or otxn z ergte
33-ditfgtlorolgtlaquoniidirraquo
24-dinitrotoloene
2 4-dtnitro toluene
U-dlpoenylfiydrraquoiilaquo
(luoranthene
raquo-cfJorophenyl poenyl ether
Mx-omopfieflyl phenyl ether
bis (2-cMorooopropyt) ether
bu (2-ctilorcxtSorv) meiSkte
hezkOilorobutadicne
hei acM or ocyc1 ofMn udi cne
oo prior one
nphthlene
nurotxniene N -ni tro Kxd ipoenyU mi ne
N-rutrowxhpropYUmJrw
bu (2-thylherl)(gthlaquoiraquoUtraquo
blaquoniyl buryl phtfraquolaquoUte
dt-^t-^xjrvl pfttfuiLitY
dj-n-octyl pitflaquoLitraquo
dirthvl phtruUtt
OArriett^vt prraquoT^Lraquot
bnzoltklaquonihnicer
22 Chronium
ire ev^rescei as uc ^ ^i-~ht-
Lab 1U N o 28B-1
C l i en t I D 1 R R 7 A A R
RASpoundNEbTRAL COMPOUNDS
benroltb)fluorraquorgtthfflf
benzoraquollt)fluor intone
ltrylaquo-gte
bullcenioithylen
raquomtirraquoenlaquo
ben z oltxh i)per v lene
lloorene
poentnthrrne
dibnzo(4h)laquonthricrne
mdeno(I23-rt)pvre-ie
pyrene
VOLATU-Ei
bullcrelem
bullcrvlonio-Ue
benzene
caj-bon traquotrraquochloraquo-idr
Ctilorobernene
l2-diehlongtethne
iii-tnctltiorotKraquor Trace 1 T 1 -4)Ctilorampe^hArw
l f 1 ^-tric^i lor oefvtrve
l t l 22-teTrtclloroetl^Ane
ehloroethraquone
2-chloroltthr|viw| ttrve-
Chloroform
1 1 -ltSicMorot^nr
trinraquo-l2-dictiloroetrne
12-d^loropOStn
trinil3^ichloroproone
eis-lJ-diChloroprooene
rrhylberuene Tarce methrlene ehlor tat Trace
Ct1 or o m e t Kirgte
bromometKtrte
bro mod i rfi lor o rrgte t Mne
Uuorotrlchloromethraquo^e
OJ CJ lor od 1 f 1 uoro met hraquone
chJorodibromometKATgte
laquotrlaquociloroethrrx
toluene 9
tricolor otheir
fsw
T9
Sifi-TOSO)
(73B)
(7IB)
(75B)
(7(B)
(77 B)
(71 B)
(71B)
(SOB)
( t lB)
(I2B)
U3B)
(M B)
(7V)
(3V)
(4V)
(4V)
(7V)
(10V)
(11V)
(13V)
(14V)
(13V)
(14V)
(11V)
(23V)
(21V)
(30V)
(32V)
(33V)
(34V)
ltlaquoV)
( raquo J V )
(44 V)
f raquo 7 V )
(UV)
(V)
000 (30V)
Tlfl 151V)
(15V)
^00 (14V)
(17V)
(UVgt
-1 ZINT
CAS 30-32-J
205-11-7
207-01-1
211-01-1
201-14-1
120-12-7
111-24-2
14-73-7
13-01 -laquo
33-70-3
113-31-5
121-00-0
107-07-t
107-13-1
71-43-7
34-23-3
101-W-7
107-04-7
71-35-t
75-3-3
7^-00-5
71-34-5
75-00-3
110-73-1
(7-14-3
73-35-4
154-40-5
71-17-5
10041-07-6
10041-01-05
100-4I-
73-OT-2
74-17-3
74-13-1
73-25-2
75-27-4
73-41-4
75-71-1
174-41-1
127-U- IOUIS-) 71-01- 75-OI-
130
Lab ID Mo 2887-4
Phys i ca l d e s c r i p t i o n of sample C l i en t ID 4A5760
Liquid Sample was predominantlv a hvrlrnrarhnn bl pnd
Sanple workup Voli t i le f ract ion PEG Extraction (SW 846-5030) Scrnivola t ile f rac t ion Sonication Extraction (SW 846-3550) Inorganic f rac t ion Acid Digestion (SW 846-3050)
AC3D CS3U POUNDS 5AipoundNEUTlUgtJ- COMPOUNDS
ri CAS PPraquo CASf
(210 U-04-2 2raquot- tricMorophrnol (7)6) raquo-32-l braquoniolttVyre
[EM 51-50-7 ^-cti 1 or raquo-m-lt rlaquo laquoo 1 (7raquoB) 203-M-2 biMo(b)(luorinth^f
2 A) raquo5-57-J 2- cfiloropheryjl (7 3 B) 20701 benro(ilt) floor in tlaquo^e
(31 A) 120J3-2 2raquo-ltJicWoro(ygtlaquotx)l (74B) 2II-OI- chryve^e
(MA) 105-47- 2l-dimlaquothvloSrrgtol (77 B) 20Uraquot-J bullcwrioMhylene
(57A) u-73-3 2- ruTroohrgtol (TIB) 120-12-7 raquontnncergte
(34 A) 100-02-7 -oitrophenol (7gtB) lraquol-2raquo-2 benio(ghi)cgtrrylngtlaquo
(3Agt 51- 21-3 2 -4 initropherwl (SOB) tt-73-7 fluorme
(tOA) 53-37-l t-dinitro-2-mlaquothy lpNlaquoxil (II B) 15-01-4 pheAinthrrnlaquo
(A) I7-U-5 tgtentraquochlQroiywnol (I2B) 53-70-3 dibenplusmnoltraquoh)fcnthrraquocrne UJJ 101-55-2 rfwtwl (I3B) lraquo3-3raquo-3 indenol 1 23-cd)vrtie
(UB) I2raquo^X3-0 pyrer BASENEUTOAL COMPOUNDS
VOLATO-ES (161 I3-32- raquoclaquonraquophttgtngtf
(5B) 12-17 -J btniidir (2V) gt 07 -07-1 bullcrolem
(IB) 120-17-1 l^^iricfvleroboMux (3V) 107-13-1 bullcrvlonit Jlaquo (raquoBI IIS-7t| SeraquoChlorotgtlaquoterlaquo (raquoV) 7IJ3-7 benient
(I7S) 4772-1 heLCMorolaquothinc (tV) J-23-5 crtgton wtrraquocMoidf (UB) I11-U-I bll(2lttllorolaquot^w gtetNer (7V) 101-W-7 ltAtoroxniergtlaquo
(203) Jl-31-7 2 -etvl or onlaquo ph traquo I en e (IOV) 107-04-2 1 2-ltlicMorolaquoTKlaquone
(25B) raquo5-30-l 1 2-dichlorobenzene ( 1 1 V ) 71-JJ-t llI-trichlorolaquotNlaquoe (2 B) 31-73-1 l3-ltlichoroblaquonzenlaquo (13V) 7J-3A-) 1 1-6 1 cM or Of t (Mr
(77B) I04-M7 I -di CM oro ben z eoe ( I k V ) rraquo-oo-j l12-niichlorolaquotfvirraquolaquo
(2IB) raquol-raquo-l )J-dichlcroblaquorLiidinr (IJV) rgt-3laquo-3 J122-tetrraquochlcrolaquoTrie
(33B) 12I-Ilaquo 2 2-dinia-otoluer (UV) 73-00-3 Ctgtloroltthne U4B) laquoJ-70-7 2 t-dtnitrotoluene (1raquoV) HO-73-1 2-ltJilorocthv|vL-v| etrveshy
(J7B) 127-M7 14-dip^wnylhydraiine (23V) C7-U^-3 Ctilorofcrm
(JraquoBJ 2Ot-ugt-0 CJuarlLnthefe (2raquoV) 7J-33- 11 -ltlicMorcxil^nr
(mei TOCJ-77-3 -chJorophcnyl phenyl laquoKr (xgtvraquo lK-^0-3 tnjM-l^-diC^lofCKtl^nf
( M B I IOI-J5-3 -6romophnyl phenyl ether (32V) 7I-J7-3 12-dicMoroprosaA
(raquo2B) 3M3I32) bU (2-cMarobopropyU rtNer (3JV) ICXU 1-07-4 trraquoni- 1 3-ltjictgtloroBoor^f
(OB) t l l f l - 1 bi5 (2-cMoroetfxgtrv) meihtrw lOOt 1-01-03 cu-O-dichloroprose- (32B) D-U-3 hrxaetilorobutadierw (UV) 100-laquol-raquo rthylbenien 1^00
(33B) 77^7- he i kcMor ocyc 1 openudi crw (UV) 7J-OT-2 rrveThvlerw chlof idf
(36) 7I-gtraquo| oop^troo (raquoJV) 7raquoJ7-3 CtgtlorBmethne
(338) raquo|20-3 nraquopfitfillaquofx 1200 (wv) 7raquo-l3-raquo bromorrgtlaquothne
(34B) nraquo3) nitrobenzene (raquo7V) 73-23-2
(CBI U-Xl-4 N -fl i iro lod iphen yU mi nr (UV) 7J-27- bro mod i cti lor o mT bull- (OR) 42l^-7 N-^itrolaquoodipropylmlrlte (raquoraquoV) 73-traquo-laquo tl uor o tr i cfi lor o mlaquoT itr (UB) I I 7 J I - 7 bn (^thylheraquoy|) phttilaquoUtT 110000 (XIV) 75-71J QJ ct )or oltJ 1 f 1 uoro rrgtei ^bull gte U76) U-U7 blaquonzyl buryl pttTfKUie 12000 ( j i v ) m-i-i ctil or od ib ro mo met h xnf (UB) M-7i2 d i -n -bo TV 1 ft thlaquo U tlaquo (13V) 127-11- te trraquo cfl lor ot hlaquoTgtf (OBI 117-4J-0 dj -n -oc t y1 Jgth fflaquo U re 6 200 tuv) iom-3 tolucie ^70
(7CB) u-u- djrthyl phtJMlire (17V) 7raquo-OI-4 irictilarcraquo^lt-ir (715) 1 3 1 - 1 1 - 5 oVnrrhyl pMtfaUte (UV) 75-OI- v i M v l CMor idr
(T76I 5-55-3 blaquorgtzo( Unihrlaquocme Xylenes 1SOO
Cad- iurn 2 2 on Chromium - - Z I N C ^ ~ P r
Ai results arc expressed as ugc weight as received Xo entry denotes not detects
Lab ID No 2887-3 5A 57709 Phys ica l d e s c r i p t i o n of sample Cl ien t ID
LiquidSludge Liquid appeared to be a hvdrnc-Arhnn blonrl
Sample workup
Vol i t i l e f r ac t ion Methanol Extraction fSW 846-5030^ Semivolatile fract ion Sonicatlon Extraction fSW 84 f i_3550gt) Inorganic f rac t ion Acid nic-psr-inn fSW 846-30501
ACS3 COMPOUNDS BASENEUTRAL COMPOUNDS
f f t CAS CAS (2IA) tt-04-2 (738) JO-32-J DCftZ OTamp p V^^^ff
(22 A) 3laquo9-50-7 p-cttl or o-m-cre laquoo 1 (7VB) 205-99-2 p^^izot oil lyor 4-^ t ^ltf ^^
(2 A) raquo5-37-l 2- CJiloroprieno (75B) 207-01-9 blaquonioltllt)flultxtn^it
(31A) 120-13-2 2raquo-dictgtlcr8tgtrfX)l (74B) 211-01-9 Chryeolaquo
(3 A) 103-47-9 2 -d irrgtet hv Ipherto1 (77B) 201-94-1 laquocnphthyle^
(37 A) 11-73-5 2- rutrop^enol (7IB) 120-12-7 bull^thrjc c^
(MA) 100-02-7 -flitroprlaquorv3l (79B) 91-2-2 bcnroltKhi)pefraquoler
(79A) 31-21-3 2 -d in itr eoricno 1 (IOB) 14-73-7 tluoren
(40 A) 33-37-l 4-d in itr raquo-2 -met hy Iphtnol ( I IB) 13-01-1 poltrtAOthrvTgt^
(44 A) 17-14-3 plaquon1 CM or o^eno I (I2B) 33-70-3 dib^fi-o( 4(K)Aji thirl c c^f (43A) 101-93-7 prwnol (S3B) 193-39-3 indcnotlIJ-ctflsvfie
(SB) 129-00-0 pyrene ftASENEUTRAL COMPOUNDS
( I D )
(5B) 92-X7-3 b^zidrw (2V) 107-02-1 bullcrolrm
(IB) 120-17-1 1 2 fc-Tr ICJ caro blaquoni crw (3V) 107-13-1 bullcrvlonitrij
(93) 1IU7I1 Seraquochlcrotgttniegtlaquo (4V) 71J3-2 blaquonienlaquo inn (17B) 4777-1 hexat^lorcwthgine (4V) H-23-5 carbon ttTricllixidf
( I I B ) 111-wJ bll(2-lt3^1oroltt^w)ether (7V) 101-90-7 ciloroblaquonzene
(20B) 91-31-7 2-ctdo-ont she Ime (10V) 107-04-2 12-dieftloroerane (25B) 95-50-1 l2-dilorobenzene ( 1 1 V ) 71-35-4 11 1 -tricMorotn-laquo
(2ampSI 51-73-1 13-dicMo-obenxerw (13V) 73-3-3 1 1 -d i CM orcxt M-
(77 B) I04-H-7 1 -di ci 1 or o benI erw (UV) 79-00-3 llJ-WiChlorolaquoflaquonlaquo
(2J6) 91-90-1 SS-dKJilorotxniidinc (13V) rraquo-3laquo-3 l122-tetrlaquocftlorelaquoTrne
(35B) 12| |k-2 2fc-dintrotoluene (14V) 73-00-3 diloroeth^e
(gt4B1 404-20-2 24-diniTrotoluenlaquo (19V) 110-73-1 2-cMortxfthv|vL-raquo trlaquoshy
(37B) 122-447 12-diphenylhydriin (23V) 47-44-3 cMoroform
(J9B) 204-U-0 Ouormntherve (29V) 73-33-i ll-diCMorolaquot^nf
(fcOB) 7005-77-3 k-cMarophfy| prlaquonyl etScr (gtOV) 134-40-3 trraquonraquo- 1 2 -dicMoroc t Nenf
(raquo I6) 101-35) raquo-6romoprny| phenyl rther (32V) 71-17-3 12-diChloropostn
(raquo2B) JH3IO2-9 bU (2-ltplusmnlaronopropyl) rthrr (J3V) 10041-02-4 trni-l)-diirMoroxtgtOpnf
(OB) I I 1 - 9 I - I bu (Z-chloroethxjrv) metSampnlaquo 10041-01-05 CU-D-djcMoroproOf-W
(32B) 17 -U -3 hiraquocfilarobutraquodiergtlt (3JV) 100-4U rttyligtlaquonitrgtlaquo 5300 (33B) 77-raquo7-raquo hrxicftl or ocrclopei tidier (UV) 75-09-2 nxthylenf ctilor ifif
lt3B) 71-391 ao prior or (raquo3V) 7raquo-17-3 rtloromrtha^r
(356) 91-20-3 nlaquoprithienraquo Trace (44V) 7raquo1Jraquo bromltmlaquoth^
(MB) n-93) ft i vo b^nz c^^ (raquo7V) 73-23-2
(425) U-30-4 ^bullf i^OftOOL^ri^ny lArrunf (UV) 73-27- bro mod i cgt lor o i~ t gt
U3amp1 Ul-4-7 N i itr CrtoO ip ro py 1 laquo ml r (raquo9V) 73-49-k U uor o IT 1 et loront Mrgt (UB) II7-1I-7 bu (2-Ihythlaquoryl)prtfUtr 59J300 (30V) 73-71-1 dj ci kr olt11 f 1 uoro rrrt (Nrgtraquo
(47 B) L3-41-7 txniyl burvl phthlaquoUtr ( 3 1 V ) I2-1-1 ch1 or od i b ro mo mi IMP r
(UBI U-71- 0-A-fcurl BMMliw (13V) 127-ll-i rt tr t cM or of tNr
Uraquo6) 117-li-O di-n-oCTv| pnttlaquoUfr 6000 (UV) lOt-II-3 toluenf 5700 (7CB) U-447 djrthvl p^tfvilirt (17V) 79-01-4 WiCMoroth^e ( 7 J B I U l - l l - 3 d^M^vl prttgtraquoUW (UV) 73-01- vinv t cMor 10 (77 Bgt H-35-) brto(raquollaquonthncrTraquo Xylenes 19000
Caen 1U~ 1 Chromium =2 Z I N C
All results are expressed as up g weight as received No errrv ripn^t-plt
Lab 1Lgt No 2887-5
rhyr i r n l d e s c r i p t i o n o f sample C l i e n t in 6857710
LiquidSludge
Sample workup Vol i t i l e f r a c t i o n PEG Extraction (SW 846-5030) Semivolat i le fr action Sonication Extraction (SW 846-3550) Inorganic f rac t ionAcid Digestion (SW 846-3030)
AOD COMPOUNDS BAStNELTTRAL COMPOUNDS
rr i CASI CAS (21 A) tt-04-7 (736) 30-32-1 bntoltraquogtprrene
(23A) 3-9-50-7 p~lt1 or o-m-c rraquo1 (78) 205-99-2 ben to( Sgt )1 1 uor raquon I he-gtf
(7raquoA) 93-37J 2- etilorophenol (73B) 207-01-9 beriioltk)(luortntrgt^f
(3 IA) 170J3-2 2raquo-dicMoroprnol (7(B) 2II-OI-9 eifVMTie
(3 A) 03-(7-9 24-4mlaquoThvlDheno| (77B) 20l-9(-i bullceraoMhyler
(37 A) tt-73-5 2- rue-oorienol (718) 1 20- 2-7 laquoflthrraquocene
(3 A) IOO-02-7 ^Mtroprwnol (7fB) 191-24-2 beraquoMoltsrM)plaquovllaquox
(39 A) 3I-71-5 2-4 ini tr ophero1 (tOamp) K-7J-7 tluwtrie
((OA) 33-37l (-lt iMtro-2-methylphenol (tlB) D-01-J phenATithrene
(4A) I7-44-J pentichlorophenol (128) J3-70-3 dilwnioltraquoh)laquonthrraquoceif
(OA) IOI-95-2 prwnol U38) 193-39-3 indeno(123-cd)vcne
(MB) 129-00-0 pyrergtlaquo 6 ASENEUTILW- COMPOUNDS
VOLATH-tS ( I B ) 13-32-9 ftCYTNA pO IT H I raquolt
(38) 92-17- o^nzioinc (7V) 107-02-1 aero le in
( IB) 120-I2-I l2k-o-i(3iloroblaquontergtlaquo (3V) 107-13-1 laquocrvlono-U
OB) Jl l-7fc | he I raquocti 1 or o blaquonI enlaquo (V) 71-43-2 Oltf2 tO^
(17B) (772-I he uc^i 1 or of t h ne ((V) 34-23-3 CJU JOO Tt TTlCfllo^ iCpound
( I I S ) bu(2-rfilcroethv|)ether (7V) 10J-90-7 laquoWoroblaquonzeoe III-44-4
(KB) 9I-51-7 2ltfMoronlaquoohttvraquolwe (10V) 107^)4-2 1 t2^ojo^loroetfft^c (2JB) 95-50-I 1 2 -dichlorotgtlaquorlene (11V) 71-55-4 1 1 1 -trichloroeihtr (251 541-73-I 13-dchlorotxniene (13V) 73-J4-3 1 1 -dieMoreeraquohraquorlaquo
(77Bgt 04-lgt4-7 1 mdash djcMorobenlene (IkV) 79-OO-3 t12-tricriloroeflaquofgte (2gtB) raquolraquo-l 33-didMoroblaquonjidirlaquo (13V) 79-34-3 1122-tetrcnicroeir^ne (33B) 12 I I 4 -2 Z4-diniiroioluerlte (1(Vgt 73-00-3 e^loroetruuie (KB) (04-7C2 2 (-dinitro toluene (19V) 110-73-4 2ltJilorolaquotr(v|vLnraquolnhlaquo (175) 122-447 12-dipr-enylfiydrmiine (23V) (7-44-3 chloroform
(J1B) 704JJ-O Huor^thrr (29V) 73-33-4 lI-ltJicMoroltthcne
(OBgt 7003-77-3 -ctJoroprienvl phenyl ether (JOV) 134-40-3 irirraquo-12-dictila-olaquotrlaquone
( raquo I B ) IOJ 33-3 -6ogtmoprienyl phenyl ether (32V) 7I-I7-3 l7^lichlorepreoine (laquo2BI 3H3raquoO2raquo bit (2-chlororaquoopfT5pyO ether (3JV) 10041-02-4 trint-l3-ltJicnloroBlt-ooee (OB) 111-11-1 bis (2-cMcroetro(v) metSuvr 100(1-01-03 CU-lJ-itflloropOO-^
(376) t7-U-3 hraquoz raquoch1 or o bu tlaquodi ene (J1V) )00-1- erhylberuer 1400 (33B) 77 -gt7- hei tchl or ocyc1 open traquodi ene (raquoV) 73-09-2 methylene chloriCf OB) 7raquo-3raquo-l BO prior one (raquo3V) 74J7-J eMorametrutne (33B) raquol-raquo-3 naphtfalene 100 (UV) 74-13-9 bro rrvome t hrgt (3iB) n-raquo3-3 niireblaquor)iergte (raquo7V) 7J23-2 (CB) U-XH N -01 ITo tod 4gthenyU rru rr (UV) 75-27-4 bro mod i ch lor o rrx t f4Ugt ((36) 42IO4-7 N-nnroodipropYlraquomlrlaquo (raquolaquoV) 73-4t-4 JJuorotr lchloronvlaquoiMftlaquo (Uol U7-1I-7 ba (2-etrylNraquoYl) phtt^Ure 100000 (30V) 75-71 -raquo dj cftlcr od U 1 vraquooro rri NUT
(47 Bl 13-44-7 t^niyl butvl phthiUte 13000 (31V) 124-41-1 chlorodibromorrwt^r
lt U E gt ) U-71-2 d-ojjurvl phtf^Ure (13V) 127-11-4 tr trbullcti loro rirr
laquoraquo6gt 11704-0 dl-fl-OCTvl pfltMUM (UV) 10t-ll-3 toluene fiin (TtS) raquo-laquo djrthvl phttuliTr (17V) 79-01-4 tricolor oethenr lt 7 | o l 131 -11 -1 (UV) v i n v i chlcwidr dimrlKyl rrftlaquoUTraquo 75-OI-J
(T75I J4-35-J blaquoTMOlt^trrlaquocr^ gtylenes 1200
Cadr ium 3 Chromium 21 ZINC 150
All results are expressed as ugg weight as received y0 entry denotes not detect
Iah I D No 2887-2
Physical descr ip t ion of sample
Strained Soil
Sample workup
Voli t i le f rac t ion PFG Extraction (^W 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-3540) Inorganic fract ion Acid Digestion (SW 846-3050)
ACS) COMPOUNDS
rn CAS Tft CASf
(21 A) tt-04-2 (73B) 50-32-4
U2A) 71-50-7 P-ch 1 or o-m-cre laquoo 1 (7k 8) 205-11-2
(2 A) raquo3-37-l 2- chloroprraquoeno| (75B) 207-01-1
(3IA) 120-13-2 2raquo-4ichlorophenol (74B) 21UOI-1
(3 A) 103-47-1 24-dimethvlphenol (77 B) 201-14-1
(57A) U-75-3 2- njtroDhenol C7I5) 120-12-7
(MA) 100-02-7 a-flitrophenol (71B) |1l-2raquo-2
(51A) 51-21-5 2 -d in i tr o phetio 1 (SOB) K-73-7
(40 A) 53-57-l raquo 4-dinitro-2-methy lprnol (tlB) 15-01-1
(4 A) 17-14-3 plaquoitraquochloroorlaquonol (I2B) 53-70-3
(43A) IOt-13-2 prlaquonol (13B) m-31-3 (MB) 121-00-0
BJ KSENCLmLAL COMPOUNDS
(IB)
(3B) 12-17-3 bcnzidine (2V) 107-07-1
(IB) 120-17-1 1 2 k- tr i ch 1 oro benr ene (3V) 107-13-1
(IB) I1U7I-1 he it raquocM or o boiz ergte (raquoV) 7I-J3-7
(12B) 47-77-1 he traquoch 1 or oet hlaquo ne (4V) 54-23-3
(116) 111-- buC-cJiloroethv|gtether (7V) 101- W-7
(20B) 11-31-7 2 -ltft 1 or on ph ttvraquo 1 laquon e (10V1 107-04-2
(23B) 15-30-1 1 2 -dictilorobeni ene (11V) 71-55-4
(25) VI-73-1 1 3 -ltJ i ci 1 or o blaquoiz ene (13V) 73-3-3
(77 B) 104-M7 llaquo-dchloroblaquoMeoe (HV) n-00-3
(2IB) 11-lk-l 33-dicMorotxTLtidinr (15V) n-3raquo-3 (33B) 12I-U-2 2 ltgt -4 in i tr ot o luene (14V) 75-00-3
(MB) 464-20-2 2 4-d initrotoluene (11V) 1 10-7 3-1
(J7B) 122-447 1 2-diprieny Ihydrti ine (23V) 47-44-3
(316) 2O4-UO Ouorraquonthene (21V) 73-33Jshy
(WB) 7t)03-77-3 ^-cJJorophenyl prienyl ether (JXgtV) 154-40-3
(MB) 101-33-3 -6romopriefgtyl prienyl ether (32V) 71-J7-3
(raquo2B) 3431-32-1 bit (2-chloroboproprO ether (33V) 10041-07-4
(OB) I1U1I- I bu (2-ltMoroethorv) methane 10041-01-03
(52B) r-u-3 hexachlorobutadiene (J1V) 100-l-raquo
(33B) 77-47- he z raquoctlt lor ocycloqenud i crte (MV) 75-01-2
OB) 71-31-1 ao prior one (raquo3V) 7raquo-17-3
(33B) 11-20-3 nlaquopntrlaquollaquone (UV) 7raquo-13-1
(MB) n-13-3 nitrobenzene (raquo7V) 73-23-2
(UB) U-30-4 N-nnroiodiprienyUmine (UV) 75-27-k
(436) Ol-U-7 N-nitrModiproOYlmJne (raquo1V) 73-41-
(UB) 117-117 bu (2-laquothylheiry) phtrlaquolte 8800 (50V) 75-71-1
( 4 7 B ) L3-U7 blaquoniyl buryl phthaUte 30 (31V) 12I-H-1
(UB) U-7U-2 di-o-burvl phtrMUte U3V) I27-I1-
(416) II7-U-0 dj-n-oCTvl pritntUtr 1200 (raquo4V) IOUI1-3
17CB) U-44-2 djetiTi phrtultrt (raquo7V) 71-01-4
( 7 I B I 1 3 1 - 1 1 - 3 dimnfTraquo| prThraquoUtr (UV) 73-01-
(776) H-35-3 berMolta^thrCF^
Cl ien t ID 8 A - S 7 4 6 1
RASENEUTRAL COMPOUNDS
benzofbtfluor^tMe
benzodclfluorintoent
Ctiryiene
cenoithylene
raquonthrraquoctne
benzoltKhilpervlefgte
floor ene
prlaquofnnthrene
ltlibenplusmno(4h)knthricrnlaquo
inogtno(123-rt)pvrrne
pyrene
VCX-ATIIE5
bullcrolem
bullcrvlomn-U
benzene
carbon tetrtchloridf
chlorobenzene
1 2-oUchloroethAnf
lll-trichloroethlaquone
ll-dcfioroethrraquo
1 1 2-tricilorolaquothraquorw
1122-tetrichloroeTtvin
chloroethre
J-ctiloroethv|vinv| etrgte
chloroform
11 -denier oethene
trinraquo- 1 2 -4 cMor oe t hens
12-dcMoroprooine
^Lns~ I f 3-4ic^ lo^opf oo^^^
Cli-l 3-dicMoroprooe^e
rttiylbenzene
methylene cnlonfle
Ch 1 or o me t hane
bromome thane
Trace
bro mod i cMor 0 me t hane
(Juorotrlchlorome thane
chlorodibromometKinf
tetracnloroethervp
toluenetr icMoroel he-if
Trace
CacTiiun Chromium ZINC f
All resxil ts are exprp^spr i K-i
Phys ica l de sc r ip t ion of sample
Strained Soil
Sample workup Vol i t i le f ract ion PEG Extraction (SU 846-5030) Semivolatile fraction Soxhlet Extraction (SW 846-5340) Inorganic fract ion Acid Digestion CSV 846-3050)
ACE) C30laquo POUNDS
m CA5i CASraquo (2i A tt-C-2 (73B) JO- 52-1
(22 A) J1-JO-7 p-ch 1 or raquowTv-cre 101 (7raquoB) 203-raquoraquo2
(2 A) raquo)57-J 2- chlorophenol (73B) 20701-
(31 A) I25J3-2 2k-4icttlltroptlaquonol (7tB) 211-01-1
(3A) IO)-7-raquo 2-dimlaquothvlpNrnol (77 B) 20l-raquoi-
(37 A) u-rj-j 7- niTTOphenol (TIB) 120-11-7
(MA) 100-02-7 -rtropN-rraquol (7raquoB) lraquol-2-2
(JraquoA) JI-21-) 2-d initroprietys 1 (IOB) U-73-7
(MA) 53-37-l Udinnro-2-mlaquothylphenol (UB) I5-OI-J
(Agt I7-U-3 pentichlcropwnol (126) 33-70-3
laquo)Agt 10l-raquo)-2 phenol (I3B) IJ3-31-3
(MB) 12raquo-00-0 AASCVflCUTRAl COMPOUNDS
( I B ) I3-32- bullcnraquophtber
(56) raquo2-17) bnzidirlaquo (2Vgt 107-02-1
(IB) 120-12-1 l2btrilt7tlorotgteizegtlaquo (3V) 107-13-1
traquoB) IIraquo-7fc | heikcMeroblaquonzergte (V) 7l-3-2
( I 2 B ) 4772-1 he ueft 1 or olaquot hraquo rgte (tV) laquo-23-3
( i ts) III-- biraquo(2-cMoroethv Dethrr (7V) 101-W-7
(20Bgt 1I-3I-7 2-cMoroflaquophthlene (10V) 107-Ofc-2
(2)6) raquo5-50-l l2-dchlorotgtlaquonzefgte (11V) 71-33-4
(28) 3l-7)-| 1 3-didMoroblaquonrenlaquo (13V) 73-3-3
(27B) 10t--7 l-diclorolgtmzerlaquo (iV) rraquo-00)
(216) raquoI raquoltbull- 33-dichloroblaquoMidiflaquo (13V) 79-31-
(356gt 2I- l-2 21-dinitrotoloen (UV1 73-00-3
(UB) laquogt- 20-2 2 (-dinitroto luenlaquo (HV) 110-7J-J
(376) 122-W-7 14 -dipheny Ihydrzire (23V) lt7-M-3
(396) 2O--0 tJuoruMSene (2raquoV) 7J-35- (OB) 7003-77-3 -c^lvophenyl pNrnyl ethlaquor (30V) 1H-W-)
(MB) 101-33-3 bull-bromopriefiyl prienyl ether (32V) 7t-t7-3
ltraquo25) 3HJI-32-1 bU (2-cMoroaopropyl) rthrr (33V1 10ltX 1-02 -6
(06) l l t - t l - l bis (2-cftloroetSorv) metwne 100lt]-01-03
(32B) C7U-3 heraquoraquochlorobutidierx (31V) 1 00-41-
(3361 77-7-raquo hexiOilorocycloptfiudlerve (raquoV) 73-0raquo-2
(56) 71-51-1 no ph or one (raquo3V) 7raquo-17-3
(3)6) raquol-raquo-3 rwiphtfalme (UV) 7raquoJ3-raquo
1361
LUB)
H-133
14-30-4
nitrobenzene
^ ri i iy o too ipf^^ y LA r^i rtf ^ 7V) (UV)
73-23-2
73-27-
(436) t21--7 M^TI iff frfcO^ip ropy Ift mJf^ (gtraquoV) 73-4raquo-raquo (UB) I17J1-7 bu (2-rThyiruMcyDpMtvUtr 570 (jov) 73-71-1 ( U B ) U-41-7 blaquonzyl buryl phthlaquoLite (31V) l2k-raquo-l ( U B I U-7I-2 di-n-burvl pitftALtTe (raquo)V) 127-lt-fc
(OB) 117- -0 dJ-fraquo-oCTvl phlJ^Ute (UV) IOt-It-3
(7CB) 14 -W- 2 djelftvl phtfalitt (17V) Tt-01- ( 7 I B I 1 J I - I 1 - ) duTNnhylphttsraquoUw ltUV) 75-01-
(77BI X-))O lgtmrlaquoigtmhrraquoctf
Cadmium f iQ Chromium 15 ZINC
Tab ID No oo -
Cl ient ID 8A-A-64220
fcASENEUTTRAL COMPOUNDi
blaquofuo(raquo)pyrrtgte
bfizo(b)(loortAth^e
benzo(k)f|ulaquoin1herf
Ctiryiene
cenDraquoMrwlene
fcftT^rict^t
D^flZCT (fftl)pC^ V Itf^p
(luorene
phen^threne
diiwnztKthlanthricene
indlaquono( 1 23-lttf)pvrene
oyrene
VOCATtLES
bullcrolem
bullcrvlooitriJe
bervteoe
carbon WTTicMoridf
chlorobenze^e
12-djcMoroetfane
1 1 1 -tricolor ex tKraquon
1 1 -dicMarcx t hrlaquo
1 1 2-triChlorothraquorw
1 122 -laquotrraquocM or o-hraquorgt
cMoroettu^e
2-cMorlaquothv|vuy| rseshy
chlexeform
ll-dchloroctfgtn
tri^iraquo l 2laquoflic^ loTo^i rgtcnt
12-dicWoroproptrs
Winl-l3-dicMoropfooene
Cu-lJ-djChleroprooe^
rrtiylfrenzene
methylene ctiloride 0 64
cMorometHAne
bromomlaquothlaquone
bnsmoform
bro mod i eti lor e me t Nine
0 uor o tr 1 cMor e rrgtlaquo t Nnlaquo
dj di tor olaquol If 1 uoro mraquoi Nrraquo
chlorodibromonveiKme
re tr a en 1 or or fxrvr
toluene
D-ieWoroefwne
entry denotes not detect All results are expressed as ugg weight as received Xo
Lab 1) No 2887-8
Physical descr ipt ion of sample
Sf-rs inpH 9 n i l
Sample workup
Vol iCi le f ract ion PEG Extraction (SW 846-5030)
Scmivolat i le f ract ion Soxhlet Extraction (SW 846-3540) Inorganic fraction Acid Digestion (SW 846-3050)
ACD O3MPOUNDS
m CAS fPraquo CASf pi A) tt-Ot-2 Zraquot- tritilorophrgtol (73B) 30-32-1
ft M -3o-7 p-cMorraquo-m-crTraquool (7kB) 205-raquo-2
(2 A) raquoS-37-l 2- cMorop^erxgtl J73B) 207-OI-raquo
(31 A) 120-13-2 l^ictiloropix)l ^7tB) JII-01-
(3 A) |03-7-raquo 21^-dimeThvlphenol (77B) 20t-raquot-l
(J7A) tl-73-3 2- rutropwnol (71 B) 120-12-7
(MA) 100-02-7 -MO-opwnol lt7raquoB) lraquol-2-2
fJraquoA) 3I-2J-3 2-dinitrop^laquoTgtoI ((OB) U-7J7
(laquogtA) J34-37-1 lt-dinitrfr-2-methylpwrxgtl (I IB) I 3-0 1-1 (raquoAI 17-1 3 pcmacMcroptonol (S2B) J3-70-J UJA) IOI-raquo5-2 phenol (IJB) MJ-39-J
(tBgt 12raquo-00-0 RASEfZUTRAL COMPOUNDS
( IB) 13-32-f raquocertaprithene
(3B) J2-17-3 twnndinc (2V) 107J2-J (IB) 170-I2- lr2k-triOilorobenzerlaquo (3V) 107-13-1 (raquoB) I11-7I-I hei bulllt1 ore blaquont ergtlaquo (raquoV) 7l-3-2 (1B) 47-72-I he ucft 1 or oe t h n (tV) 3-23-3 (116) |II_wJ bu(2-ctiIarothvI)laquotNer (7V) 101-90-7
(20B) raquoI-JI7 2 -cW or orvraquo ph tf I ene (10V) I07-Ofc-2 (23B) J3-30-I l2-lt5ictiloroblaquonzeoe (11V) 71-3J- (245) 3I-7J-I 13-dic^lorotxenzenc (13V) 7J-3-3 (27B) 104-K-7 1 mdash diC^lorobtnrerve ( lraquoV) 7^-OO-5 (21 B) raquo|raquo| 33^icftlorobenzidifv (I3V) rgt-j-3 (33B) I 2 I - U - 2 2ltgt-dinin-o1olvraquorgte (UV1 75-00-3
(J4B) 404-JO-2 21-dinitrotoluerve (1raquoV) 110-73-1
(37B) I22-W7 1 2 -d ipheny Ihydra z ine (23V) C7-14-3
(318) 2O4-W-0 tJuortnihrne lt29V) 75-3J- (kOBt 700J-77-J ^-tfMoropheTgtyl p^enyl ether (30V) 1J4-W-3
( raquo I B ) IOI03-J raquo-6romopfgtenyl phenyl ether (32V) 7I-I7-J
(06) 3H3raquo-)2-raquo bU (2-tfilerobopropyO ether (3)V) 10041-02-i
(OB) lll|| bii (2-cMoroethoxv) methane 10041-01-03
(37B) PUt) hxzraquocMorobutadienlaquo (J1V) 100-raquol-raquo
(JJB) T7^7U heztctilarocrclotMnttdicrgte (V) 7gt-0raquo-2 OB) 7l-3raquo-l BO ph or one (raquo3V) 7raquo-17-J
(338) raquo|20-3 rlaquopritrilaquolene (UV) raquo-laquo-raquo
(3iBl n-raquo3) nitrobenzene (raquo7V) 75-23-2
(CB) li-X)-t N -n i tr o tod ipheny U mi nr (UV) 73-27-fc
(06) CI-U7 N^iitroiodipropYUmlr ^raquo1V) 73-H-fc (UB) 117JI-7 bu (2-ethYlNerrl)pM^Utr 12000 (JOV) 75-71-1 (47 B) L3-U7 llaquoniyl buryl pht^UTe 2 800 ( 3 I V ) 2laquo-raquo-I (UB) raquo-7i2 di-o-ourvl pritfwiUrr (I3V) 127-lt-i (196) 117-14 3 dj-n-ocryl pritfiiUrr (UV) IOUIS-3
(TCB) J4-W-2 djnhYl phtfalitt (17V) 7t-01-lt (716 ) 1 3 1 - 1 1 ) damnhYl pMtuUTT (UV) 73-01- (77 Bl 3 33-3 frlaquon z olt raquo klaquom h rraquo c prgte
Cadmium T^ Chromiurn T Z T N C 100
Client ID 8A-C64221
BASENEUTRAL COtPOUNOS
bnzo(t)pyrrrie
benzobXluoriflthei blaquorizoltVHluorraquontrraquone
chryiene
bullcenphthylene
tnthneene
benzoltRM)perylene
fluorene
prienlaquonthcTTgte ditgtmplusmnolt4hluithrraquoctnf
indenof 1 23-cd)pvrf ne
pyrer
VOUATILES
bullcrolein raquocrvlonnrile benzene cmrbort Tetrichloride
chlorobenieoe 1 2-oUchloroethirie
11 1 -tricolor oethne ll-dvchlorolaquollMr 1 1 2-w icMoroethAoe l122-tetrieMoroeihilaquonlaquo
chloroetKvne JltJilorothvlvmv| ethe chloroform
11-dicMoroethent
trani- 1 2 -dicti lorolt t hene
1 J^JictiloroproBfVf
trim- 1 3-4ietiloroproperie
Cil-IJ-dicMoropfoOerie
rrhyUxrmene
methylene criloride
chlorornethine
bromome thne
007
13
tluorotr l^VoromlaquotNraquorgtt
da ch lor od 1 1 1 ooro frvet hraquone
chlorodibromometlvinf
te trraquocnloroeT rrrr
tricMoroetSmr
All results are expressed as us2 weight as receixred No entrv denotes not detect i
Phys ica l descr ip t ion of sample
SoilCake
Sample workup
vol i t i le fract ion ^FP FvfrarfMnn (ltU Rif i mdash Smrn
Semivolatile fraction Soxhlet Extraction (SW 846-3540^ Inorganic fraction Acid Digestion (SW 846-1050)
AC23 COMPOUNDS
rrt CAS CAS
(21 A) 11-04-2 2raquo4- trieMorophenol (738) 50mdash 3-4
122 A) J1-30-7 p-ctil or raquo-nvltrlaquo laquoo 1 (7laquoB) 205-11-2
12 A) 13-37-4 2- etilorophenol (75B) 207-01-1
(31 A) 120-13-2 2raquo-diclorophlaquoTgtol (74B) 211-01-1
(34A) 103-471 24-dmlaquothylphrnol (77 B) 201-14-4
(57 A) U-73-3 2- rutrop^nol (7raquoB) 120-12-7
(54 A) 100 -02-7 bull i tro p^c 01 (71B) 111-24-2
(J9M 31213 Z o trt i tr o poc^oI (MB) U-73-7
(40 A) 334-32-1 T^Hjinitrfr2^rt^T ny tp^gt^noi ( t lB) 13^)1-4
(44A) 17-44-3 pcnttchlaroprwnol (S2B) 33-70-3ltOA) IOt-IJ-2 pTUfNOl (136) 113-31-3
ftASENtUTRAL COMPOUNDS (MB) 121-00-0
(IB)
(56) 12-473 Iwnndine (2V) 107-02-1(IB) I20-IJ-I 1 2 4-tr icJi lorobeniervr (3V) 107-13-1(IB) 11 1-711 hexkcMarobcnzeM (4V) 71-43-2(126) 47-72-1 hexch)eroeihlaquone (4V) 54-23-J( I I S ) 111-4- bu(2-eMorlaquothv|)laquothr (7V) 101-10-7
(208) 11-51-7 2-c^laronraquophtfgtlene (IOV) 107-04-2(23B) 1J-30-I 1 2-dichloroblaquonime (11V) 71-35-4(2651 341-73-1 gt3-ltiictitaroblaquonxcnc (13V) 73-54-3
(27 B) 104-47 l4-dicMorotKmrerlaquo (14V) 71-OO-3
(21 Bgt 11-14) 33-4ichlaroblaquon2idine (15V) 71-34-3
(338) 121-14-2 24-dinitrotoluene (14V1 73-OO-3(J4Bgt 4O4-20-2 24-dinitretoluenc (11V) 110-73-4(37B) 122-447 lraquo2-dip^nylhydrraquoxirlaquo (23V) 47-44-)(MB) ro--0 Uuaranthene (21V) 73-33-4(406) 7003-72-3 4-ltUorepfraquonyl phenvl rtSer (30V) IH-40-J( raquo I 6 ) 101-333 4-6romoprlaquonyl pflaquony| ether (32V) 71-17-3
(OB) 3H3I-J21 bll (2-cti|orobopfrgtpyO ether (33V) 10041-02-4
(OB) I11-1I-I bis (2-cMaroethoxv) methane 10041-0103
(57B) P-44-) hczw^lorobundiene (J4V) 100-41-4
(JJ6I 77-47-4 htTicMarocyclojxrtadien (44 V) 75-01-2
(346) 71-31-1 aophoroo ( raquo ) V ) 74-47-3
(33B) raquo|203 r^pn thA Icr^ (44V) 7 -raquobull J-
(546) n-i3) H i frovCftZfl^^ (raquo7V) 73-23-2
142B) 14-30-4 S -n i tr o laquood ipheny Lt mi nc (44V) 73-27-4
(43 B) 421-447 N^iitrotodtpropyUmlne (41V) 73-41-4(MB) 117-41-7 bu (2-raquoThylhlaquolaquoyl)pMtgtlaquoUtr 52000 (30V) 73-71-4(4B ) 13-447 (xniyl bviryl ptithiUre 6700 (3 lV) 12raquo-l-l(UB) 147U- di-n-burvl pMhUre (I3V) 127-11-4laquoampgt 117-4J-0 ltjj-n-octyl phtfaUtr (UV) 101-11-)
(7CB) U-44-2 djrthyl pht)raquolraquort ( I7V) 71-01-4( 7 I B I 131-11 ) dimrthyl phttgtUTe (UV) 73-01-
(T76) H-33O tgtnzoUtlaquoftthncmr
Cadmium l i r^ Chromiurn 2 0 ZINC 140
All results are expressed as ugg weight as received
Lab ID No 2887-6
Cl ien t I D 8AD64219
Dd20( amp py(re
blaquonio(bHluorraquoflthegtlaquo
berzo(Mf luorampnThene
chryraquoefgte
ftctnAoMhy(ergte
raquonthncene
benioltK(M)plaquovlene
(Juorene
picnintfirtTX
dihwvioltraquoh)laquonThrraquocene
mdeno(l23-rt)pvrraquone
pyrene
raquocrolein
raquocrvloourUf
benzene
carbon laquoTrraquochlofifle
chlorobenieo
l24JcMarolaquotlxine
lll-trichlcroltthlaquorlaquo
-ltJicMorigtnKraquorgtlaquo
l12-trichlorolaquot^nlt
1 1 22-tetrcftloroetrvtnlaquo
^tloroeThAne
2^^1orolaquothvlvuiivt ethe
etila-oform
ll^liailoroltN^
trtni-12-dichlcxolaquoTfgtene
12-ditfiloropropine
trtni-l3-ltjicti|orocltX)t^f
cu-l3-djcMoroprooe^f
rttiylbtnztTve
methvlene cWoride
ciloromnM^f
Dco^^oroct^A^^
bromofarm
bromodicJiloromltlfraquon
tluorotrlctiloromttNir
diOilorodKloororfvrir^Ar
ct^lorodraquobrofTorrgttKAne
wtricnlorampctNrr
toluene
trirfilorolaquoThfif
v i n v CMor ilt3^
No-entry denotes not detect
ih i n N O 2887-9
Phys ica l d-asc r ip t ion of sample Cl ient ID 10A64222
Linnir l ShtHcp
Sample workup Volitile f rac t ion PEG Extraction (SW 846-^030^ Semivolatile fract ion Sonication Extraction (SW 846-3-540 Inorganic f ract ion Acid Digestion (SW 846-3050)
AOD COM POUNDS BAStNELTTRAL CXLPCXJNDS
rrt CAS CAS
(21 AJ U-Ot-7 Z4- trichloropSeno (73B) 30-J2-
(22 A) 55-30-7 p-ctilarraquo-m-erelaquoo1 (7kB) 205-raquoraquo-2 ben r olt b) 1 uor ifl t Ne~gtf
(2AJ raquo3-37-i 2- ctilorophenol (75B) 207-0raquoraquo benzoltllt)floofraquontslaquor
(31A) 120-13-2 2raquo-ltJictilcroooenol (76) 211-01 9 ctiryjene
(3A) I03-47- 2k-dimethylphenol (77 B) 20t-raquo4-i bullceruphthv lerraquoe
(37A) U-73-3 Zmdash Ajtropheooi (7SB) 120-12-7 fcntftricene
(34 A) 100-02-7 w^ i ff o phe rgto 1 (7raquoB) Iraquol-2-2 ben z o( Rh i )per v 1 me
(31A1 51-21-3 Z^ - d iA iV opheno1 (SOB) U-7J-7 Iluorene
(MA) 3X-37-I T v-4iAiv omdash laquo mdash fl^et ny Ipoenoi (I1B) 13-01-1 poeftraquonthrene
(4 Al 17-14-5 p^ntBCfllGrOprlC 1 Vol |I2B) 33-70-3 dilgtenioltraquoh)laquontwraquocenr
USA) IOl-raquo5-2 phenol (13fi) U3-31-3 indeno(l73-cd)oraquorrie
(MB) I2raquo-OO-0 pyrene RASENCimiAL COMPOUNDS
VCH-ATUL5 ( I B ) 13-32- raquoclaquonraquophtflaquorgte
(58) 12-I7-J benzidire (2V) 107-02-1 bullcrolem
(IB) 120-J7-I 1 2k-tr icnlorobenzene (3V) 107-13-1 acrvlonitr UP
(IB) 11U7I-I heKicMorobtnzme (raquoV) 7I-A3-2 benzene
(176) 4772-1 hexcftla-oethtgte (4V) J4-23-5 campr~toon TeTrscftlo itit
(116) III-- bii(2-lttilorolaquothv iVether (7V) lOt-W-7 chlocobenieo
(2C5gt raquol-3l-7 2-cM oroolaquo ptittu lene (10V) I07-O4-2 1 2-dicrtloreetranr
(23B) raquo5-30-l 12-dichlarobenime ( 1 I V ) 71-33-4 11 1 -tricMoroethr
(24 B) 31-73-1 1 3-ltl icJgt lor obcn i ene (13V) 73-3^-3 1 1 -dicMoroeth^i
(27B) 104-^4-7 1 4-dich lorobenzergte ( t k V ) n-00-3 11 2-tncfiloroetvlaquorie
(215) 91901 33-didMoroblaquozidinr (I3V) rraquo-3k-3 l122-tetrraquoOMo-oethne
(335) 121-I-2 2-dinitrotoluergte (ItV) 73JW-3 chloroethjin
(3461 (0420-2 24-dinitrotoluene (19V) 110-73-1 2-cMoroethraquo|vuiv| trgteshy
(37 B1 122-44-7 12-diphenylhydrnine (23V) 47-44-3 ctiloroform
(316) 204- Jgt tluarmrnhene lt2V) 73-35-4 1 1 -^iCMoroeThe^f
(C6) 7003-77-3 -chlorophenyl poenyl ether (gtOV) 154-40-5 trraquonraquo-l2-dicrloroltthene
(bull16) 101-35-3 raquo-6romophenyl phenyl ether (32V) 7I-I7-3 l2^ipoundMoroproBirgte
(raquo26) 3H3I-32- bit (2-cMarobopropvt) ether (33V) 1 004 1-02 -4 trmni-l^-dictilwoproom
(OB) l l l - raquo l - l bis (2-cMeroethoxv) methane 1004 1-0 1-05 cu-13-laquoicMoroprooe^e
(J2BI D-U-3 rraquolaquoeftlorobutraquodilaquooe (JJV) IOOJM- rttylbenzene
(336) 77 -raquo7- hezactilarocyclooentadiene (WV) 75-OT-2 methylene cniorifle
(56) 7raquo-3raquo-l ao ph or one (raquo5V) 7raquoJ7-3 eMoromeirune
(33B) JI-20-3 nraquophtMlene (UV) 7raquoJ3-raquo bromomethAftf
1X6) n-raquov) nitrobtnxerw (raquo7V) 7J-25-2
(CB1 14-30-4 J -ltii TT o vxJ ipheny U rru rraquo ^UV) 75-27- bro mod i cfilor o me t r)e
(CB) 47I-U-7 N-nnrotodipropylraquomJne (tV) 75-4raquo- 11 uor o tr i cMor o me t htgte (US) V17-1I-7 bu (2-eifrrlhryl)praquogtttilaquoUMshy 69 000 (30V) 75-71-1 di cti tor odl1 1 van m^i rajgtr
(476) U-U-7 benzyl buryl phihiUte 890 (31V) 12laquo-kraquo-l cMorodbremof^etNrr (US) U-7I-2 di-n-burvl prittuUre (13V) 127-lt- Uraquo6gt 117-t-0 dJ-laquo-ocTvl phttviUre (UV) IOLtS-3 Wluenr
(75) u-w djrrhylphtnltt ( i rv) 71-01-4
(715) t J I - l l - 3 dimnhrl pfthUte (UVI 73-01- viny l CMcriOr
(779) J4-35-3 0laquoMo(UnthrraquoCflaquoe
C a d m i u m 130 Chromium 20 ZINC 170
o nnn Z-UUU
^0(^ Trace
All results are expressed as ugg weight as received No en
APPENDIX E
PLATES
I I I I I I I I I i Plate 10-1 Troy Mills Landfill with a backhoe excavation
in progress in a former drum burial area
I I I
I I I I I I I I
I I Plate 20-1 NAI field investigation team preparing for
Level B activities during the drum excavation task Troy Mills Landfill
I I I
Plate 20-2 NAI hot line and command post for drum excavation task Troy Mills Landfill
I I I I I I I I
I I Plate 20-3 NAI field investigation team member undergoing
personal decontamination at the hot line Troy Mills Landfill
I 1 I
I I I I I I
Plate 42-1 Excavation 1 in progress Troy Mills Landfill
1
Plate 51-1 Ends of two steel drums which appear to be in good condition in Excavation 5 Troy Mills Landfill
Plate 52-1 Six steel drums in various conditions in excavation 10 Troy Mills Landfill
I
Plate 53-1 Excavation 1 showing fabric scraps Crushed steel drums were found in the bottom of the excavation Troy Mills Landfill
I I I
Plate 53-2 Collecting a sample of liquid waste from a steel drum with a hollow glass tube Excavation 6 Troy Mills Landfill
I I I I I I I I I I I 1 I Plate 53-3 Pigmentsludge deposits interbedded with
soil layers in Excavation 8A Troy Mills
I Landfill
1
