label elements of the clp regulation

7/28/2019 Label Elements of the CLP Regulation

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Label elementso the CLP regulation

The CLP regulation

(Classication, Labelling

and Packaging o substances

and mixtures) institutes new hazardsymbols and standard phrases,

and new classication rules.



Label elements o the CLP regulation1

CNRS – PRCBâtiment 11 – Avenue de la Terrasse

91198 Gi-sur-Yvette cedex – France

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Explosives

Classication Unstable Explosive Division 1.1 Division 1.2 Division 1.3 Division 1.4 Division 1.5 Division 1.6

Pictogram

Signal word Danger Danger Danger Danger Warning Danger No signal word

Hazard statement H200 UnstableExplosive

H201 Explosive;mass explosionhazard

H202 Explosive;severe projectionhazard

H203 Explosive;re, blast orprojection hazard

H204 Fire orprojection hazard

H205 May massexplode in re

No hazardstatement

Gases under pressure

Classication Compressed gas Liqueed gas Rerigerated

liqueed gas

Dissolved gas

Pictogram

Signal word Warning Warning Warning Warning

Hazard statement H280 Contains gasunder pressure;may explode iheated

H280 Contains gasunder pressure;may explode iheated

H281 Containsrerigeratedgas; may causecryogenic burnsor injury

H280 Contains gasunder pressure;may explode iheated

Flammable liquids

Classication Category 1 Category 2 Category 3

Pictogram

Signal word Danger Danger Warning

Hazard statement H224 Extremelyfammable liquidand vapour

H225 Highlyfammable liquidand vapour

H226 Flammableliquid and vapour

Flammable solids

Classication Category 1 Category 2

Pictogram

Signal word Danger Warning

Hazard statement H228 Flammablesolid

H228 Flammablesolid

Oxidising gases

Classication Category 1

Pictogram

Signal word Danger

Hazard statement H270 May causeor intensiy re;oxidizer

Flammable gases


Pictogram No pictogram


Hazard statement H220 Extremelyfammable gas

H221 Flammablegas

Flammable aerosols


Pictogram


Hazard statement H222 Extremelyfammable aerosol

H223 Flammableaerosol

Substances and mixturescorrosive to metals


Pictogram

Signal word Warning

Hazard statement H290 May becorrosive tometals

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1. CLP regulation: regulation (EC) No 1272/2008 o the European Parliament and o the Council o 16 December 2008 on classifcation, labelling and packaging o substances

and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 (Text with EEA relevance).

Physical hazards






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Sel-reactive substances and mixtures

Classication Type A Type B Type C et D Type E et F Type G

Pictogram

There are nolabel elementsallocated to thishazard category

Signal word Danger Danger Danger Warning

Hazard

statementH240 Heatingmay cause anexplosion

H241 Heating may cause are or explosion

H242 Heatingmay cause a re


Organic peroxides

Classication Type A Type B Type C et D Type E et F Type G

Pictogram There are nolabel elementsallocated to thishazard category


Hazard

statementH240 Heatingmay cause anexplosion

H241 Heating may cause are or explosion



Pyrophoric liquids


Pictogram

Signal word Danger

Hazard

statementH250 Catches respontaneously iexposed to air

Pyrophoric solids


Pictogram

Signal word Danger

Hazard

statementH250 Catches respontaneously iexposed to air

Sel-heating substances and mixtures


Pictogram


Hazard

statementH251 Sel-heating: maycatch re

H252 Sel-heating in largequantities: maycatch re

Substances and mixtures which,in contact with water, emit fammable gases


Pictogram


Hazard statement H260 In contactwith waterreleasesfammable gaseswhich may ignitespontaneously

H261 In contactwith waterreleasesfammable gases

H261 In contactwith waterreleasesfammable gases

Oxidising liquids


Pictogram


Hazard

statementH271 Maycause re orexplosion;strong oxidiser

H272 Mayintensiy re;oxidiser


Oxidising solids


Pictogram


Hazard statement H271 May causere or explosion;strong oxidiser



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1. CLP regulation: regulation

(EC) No 1272/2008 o the

European Parliament and o

the Council o 16 December

2008 on classifcation,

labelling and packaging o

substances and mixtures,

amending and repealing

Directives 67/548/EEC

and 1999/45/EC, and

amending Regulation (EC)

No 1907/2006 (Text with

EEA relevance).

Physical hazards






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Serious eye damage/eye irritation


Pictogram


Hazardstatement

H318 Causesserious eyedamage

H319 Causesserious eyeirritation

Germ cell mutagenicity

Classication Category 1A/1B Category 2

Pictogram


Hazard

statementH340 May causegenetic deects(state route oexposure i itis conclusivelyproven that noother routes oexposure cause

the hazard)

H341 Suspectedo causing geneticdeects (stateroute o exposurei it is conclusivelyproven that noother routes oexposure cause

the hazard)

Carcinogenicity

Classication Category 1A/1B Category 2

Pictogram


Hazard

statementH350 May causecancer (stateroute o exposurei it is conclusivelyproven that noother routes oexposure cause

the hazard)

H351 Suspectedo causing cancer(state route oexposure i itis conclusivelyproven that noother routes oexposure cause

the hazard)

Respiratory or skin sensitisation

Classication Respiratorysensitisation

Category 1

Skin sensitisationCategory 1

Pictogram


Hazard

statementH334 May causeallergy or asthmasymptomsor breathingdiculties iinhaled

H317 May causean allergic skinreaction

Acute toxicity

Classication Category 1 Category 2 Category 3 Category 4

Pictogram


Hazard statement :

oralH300 Fatal iswallowed

H300 Fatal iswallowed

H301 Toxic iswallowed

H302 Harmul iswallowed

Hazard statement :

dermalH310 Fatal incontact with skin

H310 Fatal incontact with skin

H311 Toxic incontact with skin

H312 Harmul incontact with skin

Hazard statement :

inhalationH330 Fatal iinhaled

H330 Fatal iinhaled

H331 Toxic iinhaled

H332 Harmul iinhaled

Skin corrosion/irritation

Classication Category

1A/1B/1C

Category 2

Pictogram


Hazardstatement

H314 Causessevere skin burnsand eye damage

H315 Causes skinirritation

Health hazards


(EC) No 1272/2008 o the








and 1999/45/EC, and



EEA relevance).

1/2






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Health hazards


(EC) No 1272/2008 o the




labelling and packaging osubstances and mixtures,



and 1999/45/EC, and



EEA relevance).

Reproductive toxicity

Classication Category 1A/1B Category 2 Additional labelling

or eects on or via

lactation

Pictogram No pictogram

Signal word Danger Warning No signal word

Hazard

statementH360 May damageertility or theunborn child (statespecic eect iknown) (state routeo exposure i it is

conclusively proven that no other routeso exposure cause

the hazard)

H361 Suspected odamaging ertilityor the unborn child(state speciceect i known)(state route o

exposure i it isconclusively proven

that no other routeso exposure cause

the hazard)

H362 May causeharm to breast-edchildren

Specic target organ toxicityater single exposure


Pictogram

Signal word Danger Warning Warning

Hazard

statementH370 Causesdamage to organs(or state all organsaected, i known)(state route oexposure i it isconclusively proven

that no other routes

o exposure cause the hazard)

H371 May causedamage to organs(or state all organsaected, i known)(state route oexposure i it isconclusively proven

that no other routes

o exposure cause the hazard)

H335 May causerespiratory irritation

or

H336 May causedrowsiness ordizziness

Aspiration toxicity


Pictogram

Signal word Danger

Hazard

statementH304 May be fatali swallowed andenters airways

Specic target organ toxicityater repeated exposure


Pictogram


Hazard statement H372 Causesdamage to organs(or state all organsaected, i known)

through prolongedor repeatedexposure (stateroute o exposurei it is conclusivelyproven that no otherroutes o exposurecause the hazard)

H373 May causedamage to organs(or state all organsaected, i known)

through prolongedor repeatedexposure (stateroute o exposurei it is conclusivelyproven that no otherroutes o exposurecause the hazard)

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Environmental hazards


(EC) No 1272/2008 o the








and 1999/45/EC, and



EEA relevance).

Hazardous to the aquatic environment

ACUTE CHRONIC

Classication Category 1 Category 1 Category 2 Category 3 Category 4

Pictogram No pictogramis used

No pictogramis used

Signal word Warning Warning No signal wordis used

No signal wordis used

No signal wordis used

Hazard statement H400 Very toxic toaquatic lie

H410 Very toxic to aquatic liewith long lastingeects

H411 Toxic toaquatic lie withlong lastingeects

H412 Harmul to aquatic liewith long lastingeects

H413 May causelong lastingharmul eects toaquatic lie

Hazardous or the Ozone Layer

Pictogram

Signal word Danger

Hazard statement EUH059 Hazardous or the OzoneLayer






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Code Hazard statement

H200 Unstable explosive.

H201 Explosive; mass explosion hazard.

H202 Explosive; severe projection hazard.

H203 Explosive; re, blast or projection hazard.

H204 Fire or projection hazard.

H205 May mass explode in re.

H220 Extremely fammable gas.

H221 Flammable gas.

H222 Extremely fammable aerosol.

H223 Flammable aerosol.

H224 Extremely fammable liquid and vapour.

H225 Highly fammable liquid and vapour.

H226 Flammable liquid and vapour.

H228 Flammable solid.

H240 Heating may cause an explosion.

H241 Heating may cause a re or explosion.

H242 Heating may cause a re.

H250 Catches re spontaneously i exposed to air.

H251 Sel-heating: may catch re.

H252 Sel-heating in large quantities: may catch re.

H260 In contact with water releases fammable gases which may ignite spontaneously.

H261 In contact with water releases fammable gas.

H270 May cause or intensify re; oxidiser.

H271 May cause re or explosion; strong oxidiser.

H272 May intensify re; oxidiser.

H280 Contains gas under pressure; may explode i heated.

H281 Contains rerigerated gas; may cause cryogenic burns or injury.

H290 May be corrosive to metals.

1. CLP legislation: Regulation (EC) No 1272/2008 o the European Parliament and o the Council o 16 December 2008 on classifcation, labelling and packaging o substances and

mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 (Text with EEA relevance).

Hazard statementsor physical hazards






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Hazard statementsor health hazards


H300 Fatal i swallowed.

H301 Toxic i swallowed.

H302 Harmul i swallowed.

H304 May be fatal if swallowed and enters airways.

H310 Fatal in contact with skin.

H311 Toxic in contact with skin.

H312 Harmul in contact with skin.

H314 Causes severe skin burns and eye damage.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H330 Fatal i inhaled.

H331 Toxic i inhaled.

H332 Harmul i inhaled.

H334 May cause allergy or asthma symptoms of breathing difculties if inhaled.

H335 May cause respiratory irritation.

H336 May cause drowsiness or dizziness.

H340 May cause genetic defects (state route o exposure i it is conclusively proven that no other routes o exposure cause the hazard) .

H341 Suspected o causing genetic deects (state route o exposure i it is conclusively proven that no other routes o exposure cause the hazard).

H350 May cause cancer (state route o exposure i it is conclusively proven that no other routes o exposure cause the hazard) .

H351 Suspected o causing cancer (state route o exposure i it is conclusively proven that no other routes o exposure cause the hazard) .

H360 May damage fertility or the unborn child (state specifc eect i known) (state route o exposure i it is conclusively proven that no other routes o exposure cause the hazard) .

H361 Suspected o damaging ertility or the unborn child (state specifc eect i known) (state route o exposure i it is conclusively proven that no other routes o exposure cause the hazard).

H362 May cause harm to breast-fed children.

H370 Causes damage to organs (or state all organs aected, i known) (state route o exposure i it is conclusively proven that no other routes o exposure cause the hazard) .

H371 May cause damage to organs (or state all organs aected, i known) (state route o exposure i it is conclusively proven that no other routes o exposure cause the hazard) .

H372 Causes damage to organs (or state all organs aected, i known) through prolonged or repeated exposure (state route o exposure i it is conclusively proven that no other routes o exposure cause the hazard) .

H373 May cause damage to organs (or state all organs aected, i known) through prolonged or repeated exposure(state route o exposure i it is conclusively proven that no other routes o exposure cause the hazard) .








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Hazard statementsor environmental hazards




H400 Very toxic to aquatic lie.

H410 Very toxic to aquatic lie with long lasting eects.

H411 Toxic to aquatic lie with long lasting eects.

H412 Harmul to aquatic lie with long lasting eects.

H413 May cause long lasting harmful effects to aquatic life.


EUH001 Explosive when dry.

EUH006 Explosive with or without contact with air.

EUH014 Reacts violently with water.

EUH018 In use may orm fammable/explosive vapour-air mixture.

EUH019 May form explosive peroxides.

EUH029 Contact with water liberates toxic gas.

EUH031 Contact with acids liberates toxic gas.EUH032 Contact with acids liberates very toxic gas.

EUH044 Risk o explosion i heated under connement.

EUH059 Hazardous to the ozone layer.

EUH066 Repeated exposure may cause skin dryness or cracking.

EUH070 Toxic by eye contact.

EUH071 Corrosive to the respiratory tract.

EUH201 Contains lead. Should not be used on suraces liable to be chewed or sucked by children.

EUH201A Warning! Contains lead.

EUH202 Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out o the reach o children.

EUH203Contains chromium (VI). May produce an allergic reaction.

EUH204 Contains isocyanates. May produce an allergic reaction.

EUH205 Contains epoxy constituents. May produce an allergic reaction.

EUH206 Warning! Do not use together with other products. May release dangerous gases (chlorine).

EUH207 Warning! Contains cadmium. Dangerous umes are ormed during use. See inormation supplied by the manuacturer. Comply with the saety instructions.

EUH208 Contains (name o sensitising substance) . May produce an allergic reaction.

EUH209 Can become highly fammable in use.

EUH209A Can become fammable in use.

EUH210 Saety data sheet available on request.

EUH401 To avoid risks to human health and the environment, comply with the instructions or use.

Additional hazard statements





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PRCThe Prevention of chemical risk unit is an intramural serviceo the CNRS Institute o Chemistry. It provides a scienticsupport to the CNRS and the chemical sector. The unit promoteschemical saety and protection o human health againstdangerous chemicals.The activities meet the needs o the scientic community,occupational health and saety managers, public agencies,industry and the general public.

Expert appraisalThe unit contributes to the expertise work at national and

european level or the toxicological and physico-chemical

evaluation o chemicals, and responds to requests rom

government agencies, local authorities and entreprises. InormationThe multidisciplinary team responds to requests or inormationrelated to the hazards o chemicals and their proper conditions

o use. It provides scientic support and implements

communication activities.

Training coursesThe unit oers training courses in the eld o chemical saety.

These courses are intended or users o chemicals, securitymanagers and occupational physicians. Several levels areavailable, rom risk awareness to prociency courses.

Training courses may also be designed to map specic needs.

label elements of the clp regulation

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