L1006141 IREL/01T PPE 4047516

For use as an insecticide to control insect pests in a wide range of agricultural and horticultural crops.Contains 100 g/l lambda-cyhalothrin and 1,2-benzisothiazolin-3-one, FOR USE ONLY AS AN AGRICULTURAL/HORTICULTURAL INSECTICIDE.IN CASE OF TOXIC OR TRANSPORT EMERGENCY RING +44 (0) 1484 538444 ANYTIME (24HR)PROTECT FROM FROST.SHAKE WELL BEFORE USE.© Syngenta AG, 2014.

Authorisation HolderSyngenta UK LimitedCPC4, Capital Park, Fulbourn, Cambridge, CB21 5XETel: +44 (0) 1223 883400

Marketing CompanySyngenta Ireland LtdBlock 6, Cleaboy Business Park, Old Kilmeaden Road, Waterford. Tel: (051) 377203

500mlProduct names marked ® or ™ , the ALLIANCE FRAMEthe SYNGENTA Logo and the PURPOSE ICON are Trademarks of a Syngenta Group Company

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TEXT AREA131 x 82 mm

250ml

175ml

375ml

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NINJA 10CS FOR PROFESSIONAL USE ONLY

A capsule suspension formulation containing 100 g/l lambda-cyhalothrin and 1,2-benzisothiazolin-3-one.

Signal Word Warning

Hazard Statements Harmful if swallowed or inhaled.May cause an allergic skin reaction.Very toxic to aquatic life with long lasting effects.

Precautions Statements Keep out of reach of children.Avoid breathing dust/fume/gas/mist/vapours/spray.Do not eat, drink or smoke when using this product.Wear protective gloves/protective clothing/eye protection/face protection.IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.IF ON SKIN: Wash with plenty of soap and water.IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Collect spillage.Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for triple rinsed empty clean containers which can be disposed of as non-hazardous waste.When applying by tractor mounted/trailed sprayer: To protect aquatic organisms respect an un-sprayed buffer zone of 5m to surface water bodies.When applying by broadcast air-assisted sprayer: To protect aquatic organisms respect an unsprayed buffer zone of 25m to surface water bodies.When applying by knapsack/handheld sprayer: To protect aquatic organisms respect an unsprayed buffer zone of 1m to surface water bodies.

Supplemental Information To protect non-target insects/anthropods respect an unsprayed buffer zone of 5m to non-crop land.Dangerous to bees. To protect bees and pollinating insects do not apply to crop plants when in flower. Do not use where bees are actively foraging. Do not apply when flowering weeds are present.To avoid risks to human health and the environment comply with the instructions for use.

PCS No: 05178

L1006141 IREL/01T PPE 4047516

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NINJA 10CS FOR PROFESSIONAL USE ONLY

A capsule suspension formulation containing 100 g/l lambda-cyhalothrin and 1,2-benzisothiazolin-3-one.

Signal Word Warning

Hazard Statements Harmful if swallowed or inhaled.May cause an allergic skin reaction.Very toxic to aquatic life with long lasting effects.

Precautions Statements Keep out of reach of children.Avoid breathing dust/fume/gas/mist/vapours/spray.Do not eat, drink or smoke when using this product.Wear protective gloves/protective clothing/eye protection/face protection.IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.IF ON SKIN: Wash with plenty of soap and water.IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Collect spillage.Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for triple rinsed empty clean containers which can be disposed of as non-hazardous waste.When applying by tractor mounted/trailed sprayer: To protect aquatic organisms respect an unsprayed buffer zone of 5m to surface water bodies.When applying by broadcast air-assisted sprayer: To protect aquatic organisms respect an unsprayed buffer zone of 25m to surface water bodies.When applying by knapsack/handheld sprayer: To protect aquatic organisms respect an unsprayed buffer zone of 1m to surface water bodies.

Supplemental Information To protect non-target insects/anthropods respect an unsprayed buffer zone of 5m to non-crop land.Dangerous to bees. To protect bees and pollinating insects do not apply to crop plants when in flower. Do not use where bees are actively foraging. Do not apply when flowering weeds are present.To avoid risks to human health and the environment comply with the instructions for use.

PCS No: 05178

L1006141 IREL/01T PPE 4047516

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For use as an insecticide for the control of insect pests in wheat, barley, rye, triticale, oats, potatoes, sugar beet, fodder beet, oilseed rape, field beans, combining peas, edible podded pea, vining pea, broccoli/calabrese, Brussel sprout, cabbage, cauliflower, lettuce, carrots, parsnips and pear.Crop Maximum

individual dose

Maximum number of applications

Minimum interval betweeen sprays

Maximum total dose

Latest timing of application

Specific pest controlled

Winter and spring wheat, winter and spring barley, winter rye and triticale.

50ml/ha 4 14 days 200ml/ha Before late milk stage (GS 77)

Aphids, yellow cereal fly, orange blossom midge and gout fly.

Spring and winter oats 50ml/ha 4 14 days 200ml/ha Before watery ripe stage (GS 71)

Potatoes (seed and ware) 75ml/ha 4 7 days 300ml/ha - AphidsSugar beet & fodder beet 75ml/ha 4 7 days 150ml/ha 8 weeks pre-

harvestFlea beetle, beet leaf miner, cut worms

Oilseed rape (winter) 75ml/ha 4 7 days 225ml/ha Before the end of flowering

Cabbage stem flea beetle, aphids, pollen beetles, seed weevils, pod midge.

Oilseed rape (spring) 75ml/ha 4 7 days 225ml/ha 6 weeks before harvest

Field beans 75ml/ha 4 7 days 150ml/ha 25 days before harvset

Pea and bean weevil and aphids

Combining peas 75ml/ha 4 7 days 150ml/ha 25 days before harvest

Pea and bean weevil, pea moth, pea midge and pea aphid.Edible podded pea, vining

pea75ml/ha 4 7 days 150ml/ha -

Broccoli/calabrese, Brussels sprout, cabbage and cauliflower

100ml/ha 4 10 days 200ml/ha - Caterpillars and whitefly

Lettuce (outdoor) 75ml/ha 4 7 days 150ml/ha 7 days pre-harvest CutwormCarrot and parsnip 150ml/ha 4 7 days 450ml/ha 14 days pre-harvest Cutworm and carrot flyPear 90 ml/ha 4 14 days 270ml/ha 7 days pre-harvest Aphids A maximum of 4 applications per crop muust not be exceeded.Processed Crops: CONSULT PROCESSORS BEFORE TREATING CROPS INTENDED FOR PROCESSING

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Additional Safety Information.Operator protectionWash splashes from skin and eyes immediately.Wash hands and exposed skin before meals and after work.When using do not eat drink or smoke.

Environmental protectionDo not contaminate water with the product or its container. Do not clean application equipment near surface water. Avoid contamination via drains from farmyards and roads.

Storage and disposal.Keep in original container, tightly closed in a safe place.Wash out containers thoroughly, preferably using an integrated pressure rinsing device, or manually rinse three times. Add washings to the sprayer at the time of filling. Complete filling to the required volume and continue to agitate throughout the spraying operation. Do not reuse container for any other purpose.

CROP RECOMMENDATIONS

WINTER AND SPRING WHEAT, WINTER AND SPRING BARLEY, SPRING AND WINTER OATS, RYE AND TRITICALE.

Barley Yellow Dwarf Virus (Aphid Vectors) RATE OF USE 50 ml/ha

WATER VOLUME 200 l/ha

Timing:a) Cereals emerging during September: Apply a single NINJA 10CS spray as a routine in the period mid-late October if BYDV is

commonly a problem on the farm or in the locality. If aphids can be found in the crop earlier, spray immediately. Further treatments may be required in high risk areas especially during mild winters.

b) Cereals sown from October onwards: Follow recommendations for low risk areas.

Timing for Low Risk Areas:A spray should only be applied in the years when the risk of infection is high, based on aphid monitoring and according to specialist advice. When aphids can be found in the crop and/or specialists identify a BYDV risk, spray immediately.

Note: Crops which follow closely a grass ley or weedy stubble, where there is a risk of direct aphid transfer to the crop should be treated as high risk.

Spring useIn the absence of an earlier application of NINJA 10CS, treatment can also be worthwhile if aphids carrying BYDV are present up to GS 32.

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WINTER AND SPRING WHEAT, WINTER AND SPRING BARLEY, SPRING AND WINTER OATS, RYE AND TRITICALE.Aphids on the ears Eg. Grain Aphid, Rose-grain Aphid

RATE OF USE 50 ml/ha

WATER VOLUME 200-300l/ha (see notes below)

Timing: The optimum timing for application is after ear emergence (GS 59)The latest time of application is before GS 77. Apply according to official thresholds.Notes: When NINJA 10CS is used for control of aphids on the ear, some reduction of aphids on the flag leaf will occur.Use sufficient water volume to ensure thorough crop penetration.

WINTER AND SPRING WHEATYellow cereal fly(Opomyza florum)

RATE OF USE 50 ml/ha

WATER VOLUME 200 l/ha

Timing: Apply at egg hatch, usually from late January onwards depending on the season. Early emerged crops are most at risk. Sprays applied for the control of BYDV will also give some control of this pest.

Orange wheat blossom midge (Sitodiplosis mosellana)

50 ml/ha 200 l/ha

Timing: Applications should be made if a threshold number of midges laying eggs on the ears are found. Best results are achieved if application timing coincides with adult midge flight. Midges start laying on the lower ears within a crop in the early evening and work higher as the light fails; egg laying continues until dark.

Gout fly (Chlorops tumilionis) 50 ml/ha 200 l/ha

Timing: Apply at the one leaf stage of the crop when the first eggs are laid. Sprays applied for the control of BYDV will also give some control of this pest.

MAXIMUM TOTAL DOSE: 200 ml per cereal crop per hectare

This product must not be applied to a cereal crop if any product containing a pyrethroid insecticide or dimethoate has been applied to that crop after the start of ear emergence (GS 51).

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WINTER AND SPRING OILSEED RAPEFlea Beetle RATE OF USE

75 ml/haWATER VOLUME 200 l/ha

Timing: Apply at first signs of attack. Repeat 10-14 days later if necessary.

Cabbage Stem Flea Beetle 50 ml/ha 200 l/ha

Timing: Apply in the autumn when feeding damage is first seen on young rape plants to control the adults. To control the larvae, spray once larvae can be found in the plants, normally late October/early November. Monitor crops carefully for signs of further larvae infestation and apply a second spray if required. A routine spray in late October/early November can often be justified in known high risk areas.

Beet Western Yellow Virus (Aphid Vectors)

75 ml/ha 200 l/ha Add a non-ionic surfactant adjuvant that is not an organosilicone in accordance with the manufacturer’s instructions.

Timing: Apply as soon as aphids can be found in the crop. A second spray may be needed 3-5 weeks later if aphids continue to migrate into the crop. Applications made late in the autumn, ie. from November onwards, may be less effective in controlling the virus if aphid migration and virus transmission had begun several weeks earlier. NINJA 10CS applied to control aphid vectors of Beet Western Yellow Virus will reduce the level of virus in the crop and will also provide good control of Cabbage Stem Flea Beetle adults and larvae depending on their incidence and the period of egg hatch.

Pollen Beetles 75 ml/ha 200-300l/ha (Use sufficient water volume to ensure thorough crop penetration)

Timing: Apply at the green/yellow bud stage according to specialist advice or if official thresholds are reached.

Seed Weevil and Pod Midge 75 ml/ha 200-300l/ha (Use sufficient water volume to ensure thorough crop penetration)

Timing: Applications should be made during the flowering period when seed weevil numbers reach the threshold for spraying. Best results are normally achieved when application coincides with the onset of peak adult activity. This often occurs between the 20% pod set stage and the end of flowering on the main raceme (i.e. 75% petal fall across the entire crop). Avoid spraying in the heat of the day when bees are particularly active.For spring sown varieties apply at green to yellow bud stage if seed weevils are present at threshold levels. Repeat application during flowering if the attack is prolonged.The latest time of application to winter oilseed rape is the end of flowering and the latest time for spring oilseed rape is six weeks before harvest.

MAXIMUM TOTAL DOSE: 225ml per hectare per crop

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WINTER AND SPRING FIELD BEANSPea and Bean Weevil RATE OF USE

75 ml/haWATER VOLUME 200 l/ha 200-300 l/ha (Use sufficient water volume to ensure thorough crop penetration.)

Timing: For the reduction of leaf notching/feeding damage, apply if there is a risk of severe damage by adult weevils to the growing points of the crop in the early stages of growth. Under high pest pressure a repeat application may be required 2 to 3 weeks after the initial application. Where there is a history of severe weevil damage, a first application made at the first signs of adult attack (leaf notching) may be beneficial in some situations.

MAXIMUM TOTAL DOSE: 150ml per hectare per crop

COMBINING, EDIBLE PODDED AND VINING PEAS

Pea and Bean Weevil RATE OF USE 75 ml/ha

WATER VOLUME 200 l/ha

Timing: For the reduction of leaf notching/feeding damage, apply if there is a risk of severe damage by adult weevils to the growing points of the crop in the early stages of growth. Under high pest pressure a repeat application may be required 2 to 3 weeks after the initial application. Where there is a history of severe weevil damage, a first application made at the first signs of adult attack (leaf notching) may be beneficial in some situations.

Pea Moth 50 ml/ha 300 - 600 l/ha (Use sufficient water volume to ensure thorough crop penetration.)

Timing: Combining Peas - Apply to flowering crops according to official advice or as indicated by pheromone traps. Spray later crops as soon as they are in full flower. Apply a second treatment 10-14 days after the first. Edible Podded and Vining Peas - Crops which are in full flower should be treated with a single spray at the calculated date.

Pea Aphid 50 ml/ha (see notes below) 300 - 600 l/ha (Use sufficient water volume to ensure thorough crop penetration)

Timing: Apply to flowering crops according to specialist advice or when thresholds are reached. Repeat if necessary. Inspect the crop carefully, especially during the early stages of flowering.

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Notes: NINJA 10CS will provide effective control of early infestations of pea aphid which are confined to the terminal growing points of the crop and are exposed to spray droplets. For established aphid infestations on the growing points and for aphid infestations which are sheltered within the crop canopy apply NINJA 10CS in tank mixture with APHOX at 140g/ha.Where aphids are the only pest present and are well established throughout a crop canopy which is dense it is preferable to apply APHOX alone at 280g/ha.Pea Midge 75 ml/ha 300 - 600 l/ha (Use sufficient water volume to ensure thorough crop penetration)Timing: Apply within 3-5 days of the first adult midges being found in the crop. Repeat 7-10 days later if midge activity continues. Sprays can be delayed if the weather is not suitable for midge activity or if the crop is not at a susceptible growth stage.Note: Consult a crop specialist for advice on application timing and information on midge activity in your area.MAXIMUM TOTAL DOSE: 150ml per hectare per crop

CARROT AND PARSNIPCutworm RATE OF USE

75 ml/haWATER VOLUME 400-1000 l/ha

Timing: Apply at egg hatch or according to specialist advice and repeat 10-14 days later.Note: Use sufficient water volume to ensure thorough crop penetration.

Carrot Fly 150 ml/ha 200-300 l/ha

Timing: NINJA 10CS is particularly suitable for the control of second and subsequent generations of carrot fly. A programme of treatments provides the best results. Application should be targeted at the crop foliage, high volume sprays should not be used. NINJA 10CS may give reduction of the first generation, one application is usually sufficient, the crop must have a minimum of 4 true leaves. For the control of the later generations, applications should be made at approximately weekly intervals. The first treatment should occur a week before 10% egg laying, or when the first adult flies are caught on sticky traps. Evenings are the best time to apply. Maximum total dose: 450 ml per hectare per crop (four applications )

MAXIMUM TOTAL DOSE: 450 ml per hectare per crop.SPECIM

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POTATOES (SEED AND WARE CROPS)Aphids RATE OF USE

75 ml/haWATER VOLUME At least 400 l/ha (see note below)

Timing:-Seed crops: Apply in mixture with ‘Aphox’ at 280g/ha. Apply the first spray according to specialist advice (normally at 80% emergence) and apply additional sprays at 7-14 day intervals (according to pest pressure) until the risk of virus transmission has diminished.Ware crops: Apply according to specialist advice or as soon as aphids reach threshold levels. Repeat if necessary. If aphids are present in the base of the crop or if resistant strains of the Peach-potato Aphid are believed to be present tank mix ‘Aphox’ at 280g/ha. Note: Use sufficient water volume to ensure thorough crop penetration.

MAXIMUM TOTAL DOSE: 300 ml per hectare per crop

LETTUCE (OUTDOOR)Cutworm RATE OF USE

75 ml/haWATER VOLUME 400-1000 l/ha

Timing: Apply at egg hatch or according to specialist advice and repeat 10-14 days later.Note: Use sufficient water volume to ensure thorough crop penetration

MAXIMUM TOTAL DOSE: 150 ml per hectare per crop

BRUSSELS SPROUTS, CAULIFLOWER AND BROCCOLI (INCLUDING CALABRESE)Caterpillars RATE OF USE

50 ml/haWATER VOLUME 300-600 l/ha (see note below)

Timing: Apply at first sign of attack. Repeat if necessary. Notes: Use sufficient water volume to ensure thorough crop penetration.Add a non-ionic surfactant adjuvant that is not an organosilicone in accordance with the manufacturer’s instructions.

Whitefly 100 ml/ha 300-600 l/ha (see notes below)

Timing: Apply at first sign of attack. Repeat 10-14 days later if necessary. Notes: Use sufficient water volume to ensure thorough crop penetration.Add a non-ionic surfactant adjuvant that is not an organosilicone in accordance with the manufacturer’s instructions.

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Note on aphid control: If the Peach-potato aphid (M.persicae) is present in the crop at the time of an application to control caterpillars or whitefly use a tank mix with ‘Aphox’ at 280g/ha.

MAXIMUM TOTAL DOSE: 200 ml per hectare per crop. HEAD CABBAGECaterpillars RATE OF USE

50 ml/haWATER VOLUME 300-600 l/ha (see note below)

Notes : Use sufficient water volume to ensure thorough crop penetration. Add a non-ionic surfactant adjuvant that is not an organosilicone in accordance with the manufacturer’s instructions.

Whitefly 100 ml/ha 300-600 l/ha (see notes below)

Timing: Apply at first sign of attack. Repeat 10-14 days later if necessary. Notes: Use sufficient water volume to ensure thorough crop penetration. Add a non-ionic surfactant adjuvant that is not an organosilicone in accordance with the manufacturer’s instructions.

Note on aphid control: If the Peach-potato aphid (M.persicae) is present in the crop at the time of an application to control caterpillars or whitefly use a tank mix with ‘Aphox’ at 280g/ha.

MAXIMUM TOTAL DOSE: 200 ml per hectare per crop. SUGAR AND FODDER BEET

Flea Beetle RATE OF USE 75 ml/ha

WATER VOLUME 200 l/ha

Timing: Apply as soon as adult feeding damage is seen . Repeat if necessary.

Beet Leaf Miner (Mangold Fly) 75 ml/ha 200 l/ha

Timing: Apply at egg hatch or according to specialist advice. Repeat if necessary.

Cutworm 75 ml/ha 400-1000 l/ha See note below.

Timing: Apply according to specialist advice at egg hatch and repeat 10-14 days later. The latest time of application is eight weeks before harvest.Note: Use sufficient water volume to ensure thorough crop penetration.

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Note on aphid control: If peach-potato aphid (M.persicae) or black bean aphid (Aphis fabae) is present in the crop at the time of an application to control flea beetle, leaf miner or cutworm use a tank mix with ‘Aphox’ at 280g/ha.

MAXIMUM TOTAL DOSE: 150 ml per hectare per crop. PEARS

Pear sucker RATE OF USE 90ml/ha

WATER VOLUME 200-2000 l/ha (use sufficient water volume to ensure crop penetration).

Timing: Apply when first sucker eggs are being laid, usually in late February/early March. Should sucker build up in the summer in the absence of predators, apply NINJA 10CS at the same rate and repeat after 2-3 weeks if necessary.

MAXIMUM TOTAL DOSE: 270 ml per hectare per crop.

DIRECTIONS FOR USENINJA 10CS acts by contact, therefore ensure thorough spray cover for good control.

Preparation of sprayer: Part fill the spray tank with clean water and start agitation. Shake the container and add the correct amount of NINJA 10CS to the sprayer using a filling device (eg. induction bowl, probe etc.) or by direct addition to the spray tank.Wash out container thoroughly. Preferably use an integrated pressure rinsing device or manually rinse three times. Add washings to the sprayer at the time of filling.Dispose of rinsed container safely.

Spraying: Ensure adequate volume and pressure is used and that the sprayer is correctly calibrated before use. Do not leave the spray liquid in the sprayer for long periods (i.e. during meals or overnight).

Resistance: Strains of some aphid species are resistant to many aphicides. Where aphids resistant to products containing lambda-cyhalothrin occur, NINJA 10CS is unlikely to give satisfactory control. Repeat treatments are likely to result in lower levels of control.

To ensure maximum and prolonged effectiveness and to minimise the likelihood of resistant strains of pests developing, it is recommended that a non-pyrethroid insecticide is incorporated into annual spray programmes.

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Control may be reduced where strains of pest resistant to NINJA 10CS develop.

Processed crops - Taint tests have shown that NINJA 10CS does not taint crops, but growers should consult processors before use.

This product may only be used in a tank mix or in sequence with other products when these uses comply with the label recommendations of every product in the tank/mix/sequence.

Compatibilty – Please consult Syngenta Ireland for advice on mixture products.

This product is to be used only in accordance with the recommendations and instructions given on the labels provided with this pack. Use in any other circumstances is entirely at user’s risk.For use as an insecticide for the control of insect pests in wheat, barley, rye, triticale, oats, potatoes, sugar beet, fodder beet, oilseed rape, combining pea, field bean, edible podded pea, vining pea, broccoli/calabrese, Brussels sprout, cabbage, cauliflower, lettuce (outdoor), carrot, parsnip and pear.

Contains 100 g/l lambda-cyhalothrin and 1,2-benzisothiazolin-3-one.

FOR USE ONLY AS AN AGRICULTURAL/HORTICULTURAL INSECTICIDE.

IN CASE OF TOXIC OR TRANSPORT EMERGENCY RING 0044 (0) 1484 538444 ANYTIME (24HR).

PROTECT FROM FROST.

SHAKE WELL BEFORE USE.

© Syngenta AG, 2014.

ADDITIONAL PRODUCT SAFETY INFORMATIONThis section does not form part of the approved product label.

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SAFETY DATA SHEETSECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING1.1 Product IdentifierProduct Name: NINJA 10CSDesign Code: A12690B1.2 Relevant Identified Uses of the substance or mixture and uses advised againstUse: Insecticide1.3 Details of the supplier of the safety data sheetCompany: Syngenta Ireland Ltd Block 6, Cleaboy Business Park, Old Kilmeaden Road, Waterford.Phone: (051) 377203Fax: (051) 354748Website: www.syngenta.ie

1.4 Emergency telephone numberEmergency phone No.: +44 (0) 1484 538444

SECTION 2. HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture

Classification according to Regulation (EU) 1272/2008Acute toxicity (Oral) Category 4 H302Acute toxicity (Inhalation) Category 4 H332Skin sensitisation Category 1 H317Acute aquatic toxicity Category 1 H400Chronic aquatic toxicity Category 1 H410For the full text of the H-Statements mentioned in this Section, see Section 16.

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Classification according to EU Directives 67/548/EEC or 1999/45/ECXn, HarmfulN, Dangerous for the environmentR20/22 Harmful by inhalation and if swallowedR43 May cause sensitisation by skin contact.R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

2.2 Label elementsLabelling: Regulation (EC) No. 1272/2008

Hazard pictograms

Signal Word WarningHazard Statements H302/332 Harmful if swallowed or if inhaled.

H317 May cause an allergic skin reaction.H410 Very toxic to aquatic life with long lasting effects.

Precautions Statements P102 Keep out of reach of children.P261 Avoid breathing dust/fume/gas/mist/vapours/spray.P270 Do not eat, drink or smoke when using this product.P280 Wear protective gloves/protective clothing/eye protection/face protection.P301/312 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.P302/352 IF ON SKIN: Wash with plenty of soap and water.P304/340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.P391 Collect spillageP501 Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site

except for empty clean containers which can be disposed of as non-hazardous waste.Supplemental Information EUH401 To avoid risks to human health and the environment comply with the instructions for use. Hazardous components which must be listed on the label:• lambda-cyhalothrin• 1,2-benzisothiazol-3(2H)-one

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Labelling: EU Directives 67/548/EEC or 1999/45/EC

Symbol(s)

R-phrase(s) R20/22R43R50/53

Harmful by inhalation and if swallowed.May cause sensitization by skin contact.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

S-phrase(s) S2S13

Keep out of the reach of children.Keep away from food, drink and animal feedingstuffs.

S-phrase(s) S20/21S24S35S36/37S57

When using do not eat, drink or smoke.Avoid contact with skin.This material and its container must be disposed of in a safe way.Wear suitable protective clothing and gloves.Use appropriate containment to avoid environmental contamination.

Special labelling of certain mixtures

To avoid risks to man and the environment, comply with instructions for use.

Hazardous components which must be listed on the label:• lambda-cyhalothrin• 1,2-benzisothiazol-3(2H)-one

2.3 Other hazardsMay cause temporary itching, tingling, burning or numbness of exposed skin, called paresthesia.

DANGEROUS FOR THE ENVIRONMENT

HARMFUL

Xn N

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SECTION 3. COMPOSITION / INFORMATION ON INGREDIENTS 3.2 Mixtures

Hazardous Components

Chemical Name CAS No. EC No. Registration Number

Classification (67/548/EEC)

Classification (REGULATION (EC) No. 1272/2008

Concentration

lambda-cyhalothrin 91465-08-6415-130-7

T+, NR21R25R26R50/53

Acute Tox.3; H301Acute Tox.3; H311Acute Tox.2; H330Aquatic Acute1; H400Aquatic Chronic1; H410

9.6 % w/w

propane-1,2-diol 57-55-6200-338-0

- - 20 – 30 % w/w

solvent naphtha(petroleum), highly arom.

64742-94-5265-198-5922-153-001-2119451097-39-0000

Xn, NR51/53 R65 R66

Asp. Tox.1; H304Aquatic Chronic2; H411

5 - 10 % w/w

1,2-benzisothiazol-3(2H)-one

2634-33-5220-120-9

Xn, NR22R38R41R43R50

Acute Tox.4; H302Skin Irrit.2; H315Eye Dam.1; H318Skin Sens.1; H317Aquatic Acute1; H400

0.05 - 0.1 % w/w

Substances for which there are Community workplace exposure limitsFor the full text of the R-phrases mentioned in this Section, see Section 16.For the full text of the H-statements mentioned in this Section, see Section 16.

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SECTION 4. FIRST-AID MEASURES4.1 Description of first aid measuresGeneral Advice: Have the product container, label or Material Safety Data Sheet with you when calling the Syngenta emergency number, a poison control centre or physician, or going for treatment.Inhalation: Move the victim to fresh air. If breathing is irregular or stopped, administer artificial respiration. Keep patient warm and at rest. Call a physician or Poison Control Centre immediately.Skin Contact: Take off all contaminated clothing immediately. Wash off immediately with plenty of water. If skin irritation persists, call a physician. Wash contaminated clothing before re-use.Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses. Immediate medical attention is required.Ingestion: If swallowed, seek medical advice immediately and show this container or label. Do NOT induce vomiting.

4.2 Most Important symptoms and effects, both acute and delayedSymptoms: Aspiration may cause pulmonary oedema and pneumonitis.Skin contact paresthesia effects (itching, tingling, burning or numbness) are transient, lasting up to 24 hours.

4.3 Indication of any immediate medical attention and special treatment neededMedical advice: Do not induce vomiting: contains petroleum distillates and/or aromatic solvents. Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES5.1 Extinguishing mediaExtinguishing media - small fires Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Extinguishing media - large firesUse alcohol-resistant foam or water spray. Do not use a solid water stream as it may scatter and spread fire.

5.2 Special hazards arising from the substance or mixture As the product contains combustible organic components, fire will produce dense black smoke containing hazardous products of combustion (see section 10). Exposure to decomposition products may be a hazard to health.

5.3 Advice for fire-fightersWear full protective clothing and self-contained breathing apparatus.Do not allow run-off from fire fighting to enter drains or water courses. Cool closed containers exposed to fire with water spray.

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SECTION 6. ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency proceduresRefer to protective measures listed in sections 7 and 8.

6.2 Environmental precautionsPrevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system.

6.3 Methods and materials for containment and cleaning upContain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). If the product contaminates rivers and lakes or drains inform respective authorities.

6.4 Reference to other sectionsRefer to protective measures listed in sections 7 and 8Refer to disposal considerations listed in section 13.

SECTION 7. HANDLING AND STORAGE7.1 Precautions for safe handlingNo special protective measures against fire required. Avoid contact with skin and eyes. When using, do not eat, drink or smoke. For personal protection see section 8.

7.2 Conditions for safe storage, including any incompatibilitiesNo special storage conditions required. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep away from food, drink and animal feeding stuffs.

7.3 Specific end use(s)Registered Crop Protection products: For proper and safe use of this product, please refer to the approval conditions laid down on the product label.

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SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION8.1 Control parameters

Components Exposure limit(s) Type of exposure limit Sourcelambda-cyhalothrin 0.04 mg/m³ (Skin) 8 h TWA SYNGENTApropane-1,2-diol 10 mg/m³ (particulates)

150 ppm, 470 mg/m³ (Total(vapour and particulates))8 h TWA8 h TWA

UK HSEUK HSE

Solvent naphtha (petroleum), highly arom. 15 ppm, 100 mg/m³ 8 h TWA SUPPLIERsulfuric acid 0.02 mg/m³

0.2 mg/m³8 h TWA8 h TWA

IOELV STM

The following recommendations for exposure controls/personal protection are intended for the manufacture, formulation and packaging of the product.

8.2 Exposure controlsEngineering Measures: Containment and/or segregation is the most reliable technical protection measure if exposure cannot be eliminated. The extent of these protection measures depends on the actual risks in use. If airborne mist or vapours are generated, use local exhaust ventilation controls. Assess exposure and use any additional measures to keep airborne levels below any relevant exposure limit. Where necessary, seek additional occupational hygiene advice.Protective measures: The use of technical measures should always have priority over the use of personal protective equipment. When selecting personal protective equipment, seek appropriate professional advice. Personal protective equipment should be certified to appropriate standards.Respiratory protection: A combination gas, vapour and particulate respirator may be necessary until effective technical measures are installed. Protection provided by air-purifying respirators is limited. Use a self-contained breathing apparatus in cases of emergency spills, when exposure levels are unknown, or under any circumstances where air-purifying respirators may not provide adequate protection.Hand protection: Chemical resistant gloves should be used. Gloves should be certified to an appropriate standard. Gloves should have a minimum breakthrough time that is appropriate to the duration of exposure. The breakthrough time of gloves varies according to the thickness, material and manufacturer. Gloves should be changed when breakthrough is suspected. Suitable material: nitrile rubber.Eye Protection: Eye protection is not usually required. Follow any site specific eye protection policies.Skin and body protection: Assess the exposure and select chemical resistant clothing based on the potential for contact and the permeation / penetration characteristics of the clothing material. Wash with soap and water after removing protective clothing. Decontaminate clothing before re-use, or use disposable equipment (suits, aprons, sleeves, boots, etc.). Wear as appropriate: impervious protective suit.

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SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties

Physical State: LiquidForm: SuspensionColour: Beige to creamOdour: Aromatic, weakOdour Threshold: No data availablepH: 4 - 8 at 1% and 100% w/v (25 °C)Melting point/range: No data availableBoiling point/boiling range: 100 °CFlash point: >103 °C at 102.3 kPa Pensky-Martens c.c.Evaporation rate: No data availableFlammability (solid, gas): No data availableLower explosion limit: No data availableUpper explosion limit: No data availableVapour pressure: No data availableRelative vapour density: No data availableDensity: 1.057 g/cm³ at 20 °CSolubility in other solvents: Miscible in waterPartition Coefficient n-octanol/water: No data availableAutoignition temperature: No data availableThermal decomposition: No data availableViscosity, dynamic: No data availableViscosity, kinematic: No data availableExplosive properties: Not explosiveOxidizing properties: Not oxidising9.2 Other InformationSurface tension: 37.0 mN/m at 20 °C

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SECTION 10. STABILITY AND REACTIVITY10.1 Reactivity: No information available10.2 Chemical Stability: No information available10.3 Possibility of hazardous reactions: None known. Hazardous polymerisation does not occur. 10.4 Conditions to avoid: No information available10.5 Incompatible materials: No information available10.6 Hazardous decomposition products: Combustion or thermal decomposition will evolve toxic and irritant vapours.

SECTION 11. TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects Acute oral toxicity: Median lethal dose male rat, 334 mg/kg Median lethal dose female rat, 404 mg/kgAcute inhalational toxicity: LC50 rat, > 2.5 mg/l, 4 h The toxicological data has been taken from products of similar composition.Acute dermal toxicity: Median lethal dose rat, > 2,000 mg/kgSkin corrosion/irritation: Rabbit: Practically non-irritating May cause temporary itching, tingling, burning or numbness of exposed skin, called paresthesia.Serious eye damage/eye irritation: Rabbit: mildly irritatingRespiratory or skin sensitisation: Buehler Test guinea pig: A mild skin sensitiser in animal tests.Germ cell mutagenicitylambda-cyhalothrin: Did not show mutagenic effects in animal experiments.Carcinogenicitylambda-cyhalothrin: Did not show carcinogenic effects in animal experiments.Reproductive toxicitylambda-cyhalothrin: Did not show reproductive toxicity effects in animal experiments.STOT – repeated exposurelambda-cyhalothrin: No adverse effect has been observed in chronic toxicity tests.Aspiration toxicitySolvent naphtha (petroleum), highly arom.: May be fatal if swallowed and enters airways

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SECTION 12. ECOLOGICAL INFORMATION12.1 ToxicityToxicity to fish: LC50 Cyprinus carpio (carp), 0.012 mg/l, 96 hToxicity to aquatic invertebrates: EC50 Daphnia magna (water flea), 0.0026 mg/l, 48 hToxicity to aquatic plants lambda-cyhalothrin: ErC50 Pseudokirchneriella subcapitata (green algae), > 1 mg/l, 96 h EbC50 Pseudokirchneriella subcapitata (green algae), > 1mg/l, 96 h. solvent naphtha (petroleum) highly arom.: EC50 Pseudokirchneriella subcapitata (green algae), 7.9 mg/l, 72 h

12.2 Persistence and degradabilityBiodegrability lambda-cyhalothrin: Not biodegradable

Stability in water lambda-cyhalothrin: Degradation half life: 7 d Not persistent in waterStability in soil lambda-cyhalothrin: Degradation half life: 56 d Not persistent in soil

12.3 Bioaccumulative potential:lambda-cyhalothrin bioaccumulates.

12.4 Mobility in soil:lambda-cyhalothrin is immobile in soil.

12.5 Results of PBT and vPvB assessmentlambda-cyhalothrin: This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).

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solvent naphtha (petroleum) highly arom.: This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).

Other information: Classification of the product is based on the summation of the concentrations of classified components.

SECTION 13. DISPOSAL CONSIDERATIONS13.1 Waste treatment methodsProduct: Do not contaminate ponds, waterways or ditches with chemical or used container. Do not dispose of waste into sewer. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations.Contaminated packaging: Empty remaining contents. Triple rinse containers. Empty containers should be taken for local recycling or waste disposal. Do not re-use empty containers.

SECTION 14. TRANSPORT INFORMATIONLand transport (ADR/RID), Sea transport (IMDG), Air transport (IATA-DGR)

14.1 UN Number UN 308214.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID N.O.S.

(LAMBDA-CYHALOTHRIN AND SUBSTITUTED BENZENOID HYDROCARBONS)14.3 Transport hazard class(es) 914.4 Packing Group IIILabels 914.5 Environmental hazards Environmentally hazardous, Marine pollutant

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable

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SECTION 15. REGULATORY INFORMATION15.1 Safety, health and environmental regulation/legislation specific for the substance or mixtureGHS-Labelling

Hazard pictograms

Signal Word WarningHazard Statements H302/332 Harmful if swallowed or if inhaled.

H317 May cause an allergic skin reaction.H410 Very toxic to aquatic life with long lasting effects.

Precautions Statements P102 Keep out of reach of children.P261 Avoid breathing dust/fume/gas/mist/vapours/spray.P270 Do not eat, drink or smoke when using this product.P280 Wear protective gloves/protective clothing/eye protection/face protection.P301/312 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.P302/352 IF ON SKIN: Wash with plenty of soap and water.P304/340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breath-

ing.P391 Collect spillageP501 Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection

site except for empty clean containers which can be disposed of as non-hazardous waste.

Supplemental Information EUH401 To avoid risks to human health and the environment comply with the instructions for use.

Hazardous components which must be listed on the label:• lambda-cyhalothrin• 1,2-benzisothiazol-3(2H)-one

15.2 Chemical Safety AssessmentA chemical safety assessment is not required for this substance.

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SECTION 16. OTHER INFORMATIONFurther informationPCS No. 05178.Use plant protection products safely. Always read the label and product information before use.Based upon SDS release dated 12/09/2013, version 11 with local amendment.

Full text of R phrases referred to under Section 2 and 3:

R21 Harmful in contact with skinR22 Harmful if swallowedR25 Toxic if swallowedR26 Very toxic by inhalationR38 Irritating to skinR41 Risk of serious damage to eyesR43 May cause sensitisation by skin contactR50 Very toxic to aquatic organismsR50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environmentR51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environmentR65 Harmful: may cause lung damage if swallowedR66 Repeated exposure may cause skin dryness or cracking

Full text of H-statements referred to under sections 2 and 3:

H301 Toxic if swallowedH302 Harmful if swallowedH304 May be fatal if swallowed and enters airways.H311 Toxic in contact with skinH315 Causes skin irritationH317 May cause an allergic skin reactionH318 Causes serious eye damage

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H330 Fatal if inhaledH332 Harmful if inhaledH400 Very toxic to aquatic lifeH410 Very toxic to aquatic life with long lasting effectsH411 Toxic to aquatic life with long lasting effects

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

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