2. To: (Receiving Organization)

Distribution

5. Proj.lProg.lDept.1Div.:

W-178

11. Receiver Remarks: 11 A. Design Baseline Document? @ Yes 0 No

3. From: (Originating Organization)

222-5 Labs

6. Design AuthorityIDesign AgenVCog. Engr.: L. D. Goodwin

4. Related EDT No.:

NA 7. Purchase Order No.:

DATA TRANSMITTED

(‘):Pt ( D ~ ~ ~ . (E) Title or Description of Data Transmitted

15.

(0) DocumenVDrawing No. (A)

Item No.

1 HNF-4704 A1 1 0 219-5 Chemical

Compatibility

NA 9. Equip.lComponent No.:

NA 14. Required Response Date:

NA

(F) (G) (H) (1)

A proVal Reason Origi- Receb. gesig- for Trans- Di$o. nator mlttai sition

E

NA 10. System/Bldg./Facil~y:

Approval Designator (F)

WT / 219-5 / 25 12. Major Assm. Dwg. No.:

Reason for Transmittal (G) Disposition (H) 8 (I)

NA 13. PermitlPermR Application No.:

E, S, 0, D OR NIA (See WHC-CM-3.5,

sec. 12.7)

1. Ap roval 4. Review 1. Approved 4. Reviewed nolcomment 2. Rekase 5. Post-Review 2. Approved wlcomment 5. Reviewed wlcomment 3. Information 6. Dist. (Receipt Acknow. Required) 3. Disapproved wlcomment 6. Receipt acknowledged

1 Env. KM Lec 18.

Signature of EOT Date Originator

80-7400-172-2 (10197)

~

7 m Authorized Rersentatjve Date Design Authority1 Date for Receiving rganization Cognizant Manag

21. DOE APPROVAL (if required)

Ctrl No.

0 Approved 0 Approved w/comments 0 Disapproved wlcomments

00-7400-1 72-1

HNF-4704, Rev. 0

2 1 9 4 Chemical Compatibility

L. D. Goodwin / C. M. Salisbury. Waste Management Federal Services of Hanford, Inc. Richland, WA 99352 US. Department of Energy Contract DE-AC06-96RL13200

EDTIECN: 619469 uc: Org Code: 32900 Charge Code: 101746 B&R 'Ode: EW0231280 Total Pages: 51

Key Words: 219-S, Chemicals, Waste transfer

Abstract: This document consists of tables of the materials that make up the "wetted" parts of the 219-S waste handling facility and a combination of manufacturer lists of chemicals that are not recommended.

TRADEMARK DlSCLAiMER. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or Imply its endorsement, recommendation. or favoring by the United States Government or any agencq thereof or its contractors or subcontractors.

Printed in the United States of America. To obtain copies of this document, contact: Document Control Services. P.O. Box 950, Mailstop H6-08, Rlchland WA 99352, Phone (509) 372-2420; Fax (509) 376-4989.

n Release Stamp

7 las 194 Dat'e

Approved For Public Release

A-6400-073.1 (1 0197)

Contents

HNF-4704, Rev. 0

. . . 1.0 SCOPE.. , , . . . . . . . . . . . . , . . , .

2.0 BACKGROUND . . . . . . . . . . . .

3 .O SYSTEM MATERIALS . . . . . .

4.0 UNSUITABLE MATERIALS . .

4.1 STAINLESS STEEL. . . .

4.2 TEFLON~ . . . . . . . . . . . .

4.3 VITON~ . . . . . . . . . . . . . . 4.4 BONDSTRAND40003 . .

5.0 BIBLIOGRAPHY.. . . . . . . . . . .

APPENDIXA . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

1

1

2

4

4

5

6

9

10

A- 1

Teflon is a registered trademark of the E. I. du Pont de Nemours & Company, Wilmington, Delaware.

1

Viton is a registered trademark of the E. I. du Pont de Nemours & Company, Wilmington, Delaware.

Bondstrand is a registered trademark of Fiberglass Pipe Systems, Burkburnett, Texas

2

3

.. I I

HNF-4704, Rev. 0

1.0 SCOPE

The purpose of this document is to provide guidance for the disposal of radioactive chemical waste to the 219-S Waste Handling Facility.

This document is not intended to he a “yes” or “no” guideline. Chemicals that are listed as unsuitable may still be discharged to the system with proper controls and approvals. The chemicals entering the waste stream must also meet Tank Farm criteria.

The lists of unsuitable chemicals were compiled from several sources. However, due to the extensive scope of this field, these lists should not be considered complete or conclusive.

The effects of radiation on the materials are not addressed in this information

2.0 BACKGROUND

The 219-S Waste Handling Facility consists ofthree tanks (101, 102, and 104) which areused to store and treat the radioactive liquid waste from the 222-S Laboratory.

Tanks 101 and 104 are the collection tanks. When a quantity of liquid has been collected in these tanks, the liquid is transferred to the 102 tank. The liquid waste is treated to meet Tank Farm specifications in tank 102 and then transferred to Tank Farms.

Tank 101 collects the waste from the 11-A hot cells

Tank 104 collects the waste from hood 16 in room 2B, and the ICP’s located in room I-J through the T-4 tunnel. The I-E-], 1-E-2, 1-F, and I-A hot cells feed the 104 tank through the T-7 and T-8 tunnel.

1

HNF-4704, Rev. 0

3.0 SYSTEM MATEFUALS

304L Stainless Steel Strainer Simplex Basket Strainer-Hayward Model 72 Strainer 316 Stainless Steel

Manufacturerl Description

Pipe

Chemical Compatibility

4 4

I I I I I I

Gasket O-ring Won 6

Garlock"Gy1on" Style 3545. Flexitallic style CGI Teflon 5 wlStainless Steel winding strip and PTFE filler

T I ,,IIII"IIII~II"II r, I 1 1-1 I

PiDe I I 1304L Stainless Steel 14

Manufacturer1 Description lrJettedlil#aterial content Chemical Compatibility #"&.--,:-" I"" UI

Valve Ball Valve-ASTM A 351, Grade CF 8M Housing lstainless Steel e..̂,̂ l7-',--

w1Stainles;Steei winding strip and PTFE filler

(4

Gasket Pipe

I I I I I I

304L Stainless Steel 4 Garlock"Gy1on" Style 3545. Fiexitailic style CGI Teflon 5 w/Stainless Steel winding strip and PTFE filler

Manufacturerl Description

Pipe Valve Ball Valve-ASTM A 351, Grade CF 8M

Gasket Garlock "Gylon" Style 3545 Flexitaliic style CGI

I I I I IwlStainless- Steel winding strip and PTFE filler I

-Material content Chemical Compatibility

304L Stainless Steel 4 Ball Stainless Steel 4 Housing Stainless Steel 4 Seals Teflon 5

Teflon 5

Flex Hose P-2

2

Metal Braided Hose-MH-30201MH-100F 304L Stainless Steel 4

DMS SST 304 Wilden Pump Model M8 SZ TF TF VT 225 Diaphragm Tenon 5

Balls Viton 6 Body Stainless Steel 4

HNF-4704, Rev. 0

Pipe Gasket

14 Tenon 5 Garlock "Gylon" Style 3545. Flexitallic style CGi

wlstainless Steel winding strip and PTFE filler

Flex Hose P-4

I I Bails lviton 16 Body lstainless Steel 14

304L Stainless Steel 4 Teflon 5

Metal Braided Hose-MH-302O/MH-l00F Wilden Pump Model ME SZ TF TF V l 2 2 5 DMS SST 304

Diaphragm

TANK 102 TO TANK FARMS I m l M a n u f a c t u r e r / Description (pet ted Parts IlMaterial content IlChemical COmDatibilitV 11

Flex Hose Valve

304L Stainless Steel 4 316 Stainless Steekast 4 carbon steel

Metal Braided HOSe-MH-3020/MH-lOOF Gate Valve-Crane No. 127

TANK 101 Manufacturerl Description

347 Stainless Steel Tank-1 01

TANK 102 Manufacturerl Description Chemical Compatibility

(347 Stainless Steel 14 Tank-I02

TANK 104 Manufacturer/ Description Chemical Compatibility

1304L Stainless Steel 14 Tank-104

3

.

"F-4704, Rev. 0

4.0 UNSUITABLE MATERIALS

4.1 STAINLESS STEEL

The following chemicals are considered unsuitable for continuous use on stainless steel

GENERAL

ACETAMIDE ANILINE HYDROCHLORIDE AQUA REGIA (80% HCL/20% "03) ARSENIC TRICHLORIDE ~~ BROMINE BROMTNE-ANYHDROUS BROMINE-WATER CHLORINE CHLORINE. ANHYDROUS LIOUID CHLORINE'DIOXIDE

.

CHLOROACETIC-ACID CHLOROSULFOMC ACID CHROME PLATING SOLUTIONS CHROMIC ACID COPPER (II) CHLORIDE COPPER FLUORBORATE ETHYL SULFATE FERRIC CHLORIDE FERROUS CHLORIDE GOLD MONOCYANIDE HYDROBROMIC ACID HYDROCHLORIC ACID HYDROGEN FLUORIDE ~~ ~ HYDROFLUORIC ACID HYDROFLUORSILICIC ACID HYPOCHLOROUS ACID IODINE MAGNESIUM CHLORIDE MELAMINE MERCURIC CHLORIDE

PICRIC ACID SODIUM HYDROXIDE (80%) SODIUM HYPOCHLORITE (>20%) STANNIC CHLORIDE SULFAMIC ACID

PERCHLORIC ACID

S W U R I C ACID (25% - 75%) TRICHLORACETIC ACID

304

ALUMINUM CHLORIDE ANHYDROUS ALUMINUM FLUORIDE ALUMINUM STD ALUMINUM SULFATE. HYDRATE ALUMINUM CHLORIDE ALUMINUM FLORIDE AMMONIUM HYDROXIDE AMMONIUM PERSULFATE AMMONIUM PHOSPHATE AMMONIUM SULFATE ANTIMONY STD BARIUM CHLORIDE, DIHYDRATE BERYLLIUM STD BISMUTH STD BORIC ACID CADMIUM STD CARBON ANODE SOLUTION CHLOROX BLEACH COPPER STD HYDROBROMIC ACID INDIUM STD LEAD STD MAGNESIUM STD NICKEL CHLORIDE NITRIC ACID POTASSIUM HYDROXIDE SILVER CHLORIDE SODIUM FLUORIDE SODIUM HYDROXIDE SODIUM SULFIDE, 9-HYDRATE STANNOUS CHLORIDE SULFUROUS ACID TIN STD URANIUM STD ZINC CHLORIDE ZINC STD

316

NITRIC ACID ALUMINUM CHLORIDE ZINC CHLORIDE

4

HNF-4704, Rev. 0

4.2 TEFLON

The following chemicals are considered unsuitable for continuous use on Teflon:.

BROMINE LIQUID BROMINE WATER DIMETHYLFORM ANIDE FLUORINE GAS F L U O W LIQUID FREON 22 BROMINJZ TRIFLUORIDE CHLORINE TRIFLUORIDE FLUORINE DIOXIDE ELEMENTAL LITHIUM MOLTLEN ALKALI METAL POTASSIUM, ELEMENTAL SODIUM, ELEMENTAL STEAM OF TEMPERATURES LESS THAN 300 DEGREES PERCHLORIC ACID (>70%)

For some of the less corrosive chemicals, there exists certain temperature requirements for waste disposal to prevent excessive corrosion of the Teflon parts. This information can be found in Appendix A.

*Teflon is a registered trademark of E. I. du Pont de Nemours & Company, Wilmington, Delaware.

5

HNF-4704, Rev. 0

4.3 VITON

ACETALDEHYDE ACETATE ANHYDRIDE ACETATE SOLVENT ACETIC ACID ACETIC ACID (30%) ACETOMITRDE ACETONCYNOHYDRAN ACETONE ACETOPHENONE ACETONITRILE + ACETYL BENZENE ACETYL PROPANE ACRYLIC EMULSIONS ACRYTONITRILE ACETIC ETHER ALCOHOL DIACETONE ALCOHOL METHYL ALMOND OIL ALUM ALUMINUM ACETATE AMINES AMMONIA ANHYDRAOUS W O N I A LIQUID -0- ACETATE W O N m PERSULFATE AMMONIA GAS

SULFATE mn BROMATE . --ACETATE m r L m ANSUL ETHER ARSENIC TRICHLORIDE BANANA OIL BENZIL BENZIL ACETATE BRAKE FLUID BROMINE, DRYIGAS BUNKER OIL BUTRAL ACID BUTRALDEHYDE BUTYL ACETATE BUTYL ACRYLATE

BUTYL. AMIhE BUTYL ETHER BUTYL PHTHALATE BUTYRADE CALCIUM ACETATE HYDRATE CELLOSOLVE CHLORAL HYDRATE CHLORALACETIC ACID CHLORINE DIOXIDE CHLORINE GAS (WET) CHLOROSULFONIC ACID CHLOROX BLEACH CLORACETIC COPPER ACETATE CYAMIC ACID

DECANAL DIACETONE DIACETONE ALCOHOL DEKJTHyL AMINE DIBUTYL ETHER DIBUTYL PHTHALATE DIBUTYL SEBUCATE DICHLORO ISOPROPYL ETHER DICHLOROACETIC ACID DIETHYL AMINE DIETHYL ETHER DIETHYL KETONE DIETHYL OXDE DIISOBUTyL KETONE DIISOPROPYL KETONE DIMETHYL AMINE DIMETHYL KETONE DIMETHYL SULFATE DIMETHYLANALm DIMETHYLFORMANIDE DIMETHYLSULFATE DIOXANE DIOXOLANE EPICHLOROHYDIUN ETHANOL=

CYCLOHEXANONE

6

ETHERS ETHYL ACETATE ETHYLACETOACETATE ETHYL ACRYLATE ETHYL AMm

ETHYL BUTAL KEYTONE ETHYL BUTYRALDEHYDE ETHYL CELLOSOLVE ETHYL CYANIDE ETHYL ETHER ETHYL FORMATE

ETHYL BUTAL ACETATE

KW-4704, Rev. 0

ETHYL GLUCON M E N O M E T W ETHYL H E X ACETATE ETHYL SULFATE ETHYLENE DIAMINE ETHYLENE GLYCOL MONOMETHYL.

ETHERACETATE ETHYLENE OXIDE FERRIC ACETATE FORMALDEHYDE FORMAMIDE FREON 142B FREON 152A FREON 2 1 FREON 22 FREON 3 1 FURAN FURFURAL ALCOHOL FURFURAL BRAN OIL GLYCOTIC ACID HYDRAZINE HYDROGEN SULFIDE HYDROXYACETIC ACID IODINE PENTAFLOURIDE ISOAMYL ACETATE ISOAMYL BUTYRITE ISOBUTAL ACETATE ISOBUTAL AMINE ISOPHORONE I X ” Y L ACETATE ISOPROPYL AMINE ISOPROPYL ETHER KETONES LACQUER LACQUER SOLVENTS LEAD ACETATE

METHYL OXIDE METHYL METHYL ACETATE METHYL ACETONE METHYL ACRJLIC ACID METHYL ACRYLATE METHYL AMYL ACETATE METHYL AMYL ALCOHOL METHYL BUTYL KETONE METHYL CELLOSOLVE METHYL ETHYL KETONE METHYL FORMATE METHYL ISOPROPYL KETONE METHYL METHACRYLATE METHYL PROPYL KETONE METHYLANE CHLORZDE METHYLMETH ACRYATE MONOCHLORACETIC ACID MORPHOLm MUSTARD N,N-DIMETHYLANALINE N-AMYLAMINE N-BUTYL ACETATE NICKEL ACETATE NITRIC ACID NITROETHANE NITROMETHAGE NITROPROPANE OCTYL ACETATE

OILS, CINAMON OLEUM PARALDEHYDE PHENETHYL ALCOHOL PHENOL SULFONIC ACID PHENYL ACTETATE PIPERDINE POTASSIUM ACETATE POTASSIUM HYDROXIDE PROPIONALDEHYDE PROPYL ACETATE PROPYLENE OXIDE PYRIDINE RUBBER SOLVENTS SODIUM ACETATE SODIUM CHLORITE

OILS, ANALINE

7

W - 4 7 0 4 , Rev. 0

SODIUM HYDROXIDE STEAM ABOVE 220 F STYRENE SULFUR DIOXIDE TETRAHYDROFURAN TRIACETINE TRBUTYL PHOSPHATE TRIETHANOLAMINE UNSYMMETRICAL DIMETHYL HYDRAZINE VANELA EXTRACT V W ACETATE WAGNER 21B FLUID XYLIDINES ZINC ACETATE

For some of the less corrosive chemicals, there exist certain temperature requirements for waste disposal to prevent excessive corrosion of the viton parts. This information can be found in Appendix A.

*Won is a registered trademark of the E. I. du Pont de Nemours & Company, Wilmington, Delaware

8

HNF-4704, Rev. 0

4.4 BONDSTRAND 4000

The following chemicals are rated as "consult manufacturer" for Bondstrand* 4000 fiberglass pipe:

ACETIC ACID (> 10%) ACRYLIC ACID AQUA REGIA BROMINE CHLORIDE DIOXIDE CHLORINE GAS CHLOROACETIC ACID (25% < 50%) CHLOROFORM CHLOROSULFONIC ACID

CRESYLIC ACID DIACETONE ALCOHOL DICHLOROACETALDEHYDE DICHLOROETHYLENE DIETHANOLAMINE DIETHYL KETONE DIETHYLENE TRIAMINE DIMETHYLAMINE DIMETHYL FORMAMIDE ETHYL CHLORIDE ETHYLENE DIAMINE FLUORINE FLUOROSILCIC ACID FORMIC ACID (

HNF-4704. Rev. 0

5.0 BIBLIOGRAPHY

Bondstrand Corrosion Guide, Ameron International, Fiberglass Pipe Group.

Chemical Engineers’ Handbook, 5th Edition, Robert Perry and Cecil Chilton.

Chemical Resistance Guide, Wilden Pump and Engineering Company, Grand Terrace, California

Chemical Resistance of Garlock Compressed Sheets and Gylon, Garlock Industrial Gasketing.

Hanington Industrial Plastics, Inc., 8th Edition (See Appendix A).

Technical Bulletin 10/92, Warren Rupp, Inc., Mansfield, Ohio, Chemical Resistance Chart.

10

HNF-4704, Rev. 0

APPENDIX A

CHEMICAL RESISTANCE GUIDE

A- 1

f

530

"F-4'704, Rev. 0 .*-- ---, -,.-

CHEMICAL RESISTANCE GUIDE A word about our cliemlcal redstance gulde. 7he chemical resistance data provided hero and on the following pages has been assembled from a wide variety of sourcesinour industry. Thisintormalion is basodonpractical lield experience and actual laboratory testing conducted by the manufacturers 01 various plastic resins and finished prod- ucts. Keep in mind that this inlormation should only be used as a guideline lor recommendations and not a guarantee 01 chemical resistance. Some performance variations may be noticed between homopolymers and copolymers as well as emulsion and suspension type resins of the same general type. In addition. actual service conditions including tempera- ture, concentration and contaminants will affect variances in chemical resistance.

In assembling the chemical resistance data presented here, several sources were checked. When conflicts were uncov- ered, we took aconservative approach and usedthe lowerof two or more ratings. In addition. special consideration was given to the material as supplied by a pariicularvendor; Le.. our polyethylene ratings arebasedon informationprovidedby tank manufacturers rather than pipe suppliers. This wasdone primarily because of the volume of tanks supplied as com- pared to polyethylene pipe.

Plastics and elastomersin anattemptlomaketherscommen- dations more meaningful we have given the maximum recom- mended use temperature lor each plastic and elastomers in thespecificchemicals listed. Lacking complete datain many

Cases we did leave thosa in question as blanks. Whero a material is unsuitable for a specilic chemical an "X' is used.

Metals are rated as:

A = Excellent B =Good, minor slfect C = Fair, needs lurther tests X = Unsuitable

Tothe best of our knowledge the information mnlained in this publication is accurate. However, we do not assume any liability whatsoever lor the accuracy or mmpleteness of such information. Moreover, there is a need to reduce human exposure l o many materials to the lowest physical limits in view 01 possible long-term adverse effects. To the extent that any hazards may have been mentioned in this publication. we neilhersuggesl nor guarantee that such hazards are the only ones which exist. Final determination of the suitability of any inlormation or product for the use contemplated by any user, the manner of that use and whether there IS any infringement of patents, is the sole responsibility of the user. We recom- mend that anyoneintending to rely on any recommendationor to use any equipment, processing technique or material mentioned in this publication should satisfy themselves as to such suitability, and that they meet all applicable safety and health standards. We strongly recommend the user seek and adhere to manulaclurers or suppliers current instruct'onslor handling each material they use.

USE OF THE CHEMICAL RESISTANCE TABLES

The aggressive agents are classified alphabotically according to their most common designation. Further descriptions include trivial or mmmon names as well astradenames.

I1seb~eralmncentralionsaregivenforaparlicularmaterial.lhe' physicaldatain general relate tothe pureproduct,lhatis 100% concentration.

In listing the maximum use temperaturesfor each plastic type in a given chemical it can in general be asssumed that the resistance will be no worse at lower temperatures.

HOW TO SELECT THE CORRECT MATERIAL: 1. Locate the specilic chemical in the system or found in the

surrounding atmosphere using the alphabetical charl of chemicals.

has always been to suggest the least costly material that will do the job.

3. Where a materialor elastome rappearstobe marginal mm- pared to the requirements, we enmurage a call to our technical service group in Chino, California.

EXAMPLES: I . Methylene chloride; in the tables PVDF or Teflon are the

Carbon steel works well for chlorinated Hydrocarbons of this sort and that would be our choice unless there was another reason to justify the higher cost of the PVDF or Tellon.

two materials suitable.

2. Sodium hypochlorite. 20% at 100°F. PVC is good to 140°F and is the least expensive of the malerials available.

3. Nitric acid, 40% at 90°F; CPVC is recommended in the lables to 1OO'F at this concentration,

2. Select the material with a maximum use temperaturethat matches or exceeds the need. The Harrington philosophy

a HfiR INGT N

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