job number 2018262 df. john by dr. team john · 2018-10-19 · industrial emission8 ucence.:powo-02...
TRANSCRIPT
Report Title
Company address
Stack Emissions Testing Report Commissioned by
I Factlity Name I dvara Shannon Pharmaceutical Services Ltd
Air Ernissfons Compliance Monitoring Emissions Report Atr Scientific Ltd., 32 BeGranville Court. Dublin road, Tiim, Go.
Meath Avara Shannon Pharmaceutical SeMces Lid
I Contact Person
Job Reference Number
Report Writfen By
1 EPA Ltcertce Number
UCIRTLI 460518 / 2018262
DF. John Casey
Ms, Lourda Moloney
PQ02D-02
Report Date
Report Type
Version
I Llcenca Holder 1 Avara Shannon PhamamuZleal Services Ltd
-I 110~~2018
Test Report Comptiance Monitoring
7
I Stack Reference Number 1 YEI55
1 Dates of the Monitoring Garnaaian I 1610512018
I Report Approved by I Dr. Brian Sheridan
I StackTeding Team I Dr. BTiWI Sheridan & Dr. John Casey
Signature of Approver
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Industrial Emissions Licence . . POOiiO@ Liceme Holder: Avara Shannon PhermawuHtcal Servfces Ltd
Facility Location: Avara Shannon Pharmaceuticat ServioeS Ltd Rev.No: i
Cohmnts 1 .
I . Execwtive Summary ...................................................................... ............................................. 4
Overall Aim of the monitoring Campaign ....................................................................................... 4 Special Requirements ..................................................................................................................... 4 Target Parameters ............................................ .-. ........................................................................... 4 Emfssion Llmk Values ....................................................................................................................... 4 Reference Conditions ....................................................................................................................... 4 Overall Results ........................................................................................................................... +.,, . 6 Accredltatlon detaits ....................................................................................................................... 6 Monitoring Dates &Times .............................................................................................................. 7 Process details ................................................................................................................................. 8 Monitoring. Equipment & Analytical Methods ..............................!............................................!.. 9 Sampling Deviations ...................................................................................................................... 11 Reference Documents .................................................................................................................... 11 Suitability of sampling location., .................................................................................................... 12 Stack diagram ................................................................................................................................ 13
APPENDICES ........,........................................... ....................................................................................... 13: Appendix I Monitoring Personnel & Equipment .................................................................... 14
Stack Emissions Monitoring Personnel ......................................................................................... 14 Ap.pendix H Stack Details &flow characteristics ................................................................... 15
Preliminary stack s w e y calculations .............................................................................................. 15 Appendix III Individual parameter Sampling details and results., ............................................ 22
Deterrnlnatlon aP Dioxins and Furans ............................................................................................................ 2~
Monitoring Objectives .............................................................................................................. 4
II .
Ill.
IV.
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Roournent Na,: UCiRT!-ll605?812018262 VisM No: 2 Year: ~0’18 Office: Trim
Opinions and irtteprefations expresses heretn a n outside the scope of Air SCientHc Limited /NAB accmditafhn. Thb test report shall not be reproduced, w&ouf the wfilten approval ofAir Sclenfinc Limited. All sampling and reporting is completed in
accordance wlth Envkmmenfal Protectfan Agency Air Goldance Note 2 requirements.
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1. Executive Summary
Emlsskn Urnit Values I Mass Emissions Limft Values
Dfnxins $r Furans
Stack Gas Temperature
Volume (d.h-')
I. Monitorrhg Objectives
ng.m" kg -h' 0. I -
21,500 -
Overall Aim of the monitoring Campaign The aim of the monitoring campalgn was to demonstrate compliance with a set af emission limit values as specified in the site
licence.
Temperature K Total Pressure kPa
Moisture %
Thwe Were tip special requirements.
273" 15
10'1.3
Yes
Speclal Requirements
Target Parameters
I Dloxins & Furans I Stack Gas Temperature
Volume (m3.h-')
Emissian Limit Values
Reference Conditione
Reference Conditions 1 Value ~ r Oxygan Reference % I No Oxygen Ref 1
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lnduslrial Emissions Ucence.: P(la20-02 Licence Holder: Avara Shannon Pham6eutlmi Serrvieeg Ud
facility to&onn: Avara Shanhon Phamceutical S e w b s Ltd Rev,No: T
Executive Summary
Dioxins & Furans
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Industrial Emlssions Licence.: POQ20-02 Llcenm? Holder: Avara Shannon Pharmaceutical Services Ltd
Facility Location: Avara Shannon Pharmaceutical Services Ltd Rev.No; I
Executive Summary
Parameter Process status
Capacfty (perfhour) (if appllcabfe)
Contlnuous or Batch Process
Feedstock
Abatement System
Abatement Syst.=mS Running Status
Fuel
Plume Appearance
Other informatton
Normal
NIB Cantinuous
Sofvent Alr
Yes Nrrrmal
Gas
No
None
Licensee
Reg. number PO020 02
58e Contact Ms Lourda Mulonay
RUk
Signature
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Cantractor Air Seiantific La.
Contractor's contact Dr. Brian Sheridan
Rnle
Signature
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Sarnnllnrr Deviations
Standard 1D
Standard ID
I Parameter I Deviation I EN16911 jn accordancewith MID 6991 1
-
Risk Assessment (RA) Site RevkW (SRI Site Specific Protocol (SSP)
Standard ID
Standard ID
SOP1 01 1 SOP1 01 5 SOP1 01 5
Reference Documents
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lndostrlal Emissions Lic%xGe.: PDO20-02 Licence Holder: Awra Shawn Pharmae&diml Senriceti l id
Facility Location: A w a Shnorr Pharmaceutical Services Lfd Rev.No: I
Executive Summary
Oeneral lnformatlon
PermamVTernpomry
InsJdeI OUtside
SuttabtltQ erf sampling location
Valua
Permanent
Outsitside
Platbrnl has vertkat base boards (approx. 0.25 m high)
Plaff~pn ha5 chains / self dosing gates at top of ladUer6 Thew aE no ubstmctians present which hamper Inseltton ddatnpltng
equitmw3-lt Safe Access Available
res Yea
No -
Yes
I Yes I I
BSEN 16259 Homogendty Test Requirements
1: There is no requirement to pei-brm a BSENl5259 HomogenUy Test cm this sbck E.g. Selsct option I: There L no requirement to perform a BIEN752BB ~omog6nI& Twt on Zhts stack a: Test results were obtained from prviaus Homogonetty test carried out by ASL 3: Test results were obtainad from grwiaus Hamcwnelty test wWxl wt by Altarnative Wi tWiCtw 4: Other: Enter Dsscriptfon
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Industrial Emlssbns Licence.: P0020-02 Licence Hdder: Ayara Shannon FharmaceuUcal Services Ud
Facllily Lomlinn: Avara Shetflnun Pi-?armacedcal Sew& Lid f?ew.No: I
Executive Summary
Stack dlagram
I-
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Industha1 Emlssfow Ucence.: POOZD-02 Licenee Holder: Avara Bhannan Pharmaceutical SeWice8 Ltd
Facllity Locafion: Avara Shannon Phzrrmaceutical Serv'rces Ltd Rev,No: 1
APPENDICES
J L fippendlx lh4anitorlng Personnel & Equipment
Stack Emissions MonNorlng Pe~onnel
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Preliminary stack survey cahlations
General Stack Uetails 1 I Units I Value
Dale of survey T@/05/201& Time of survey wm
Stack Diameter / Depth, D m 0.m
TYPe Circular
Stack Width, W m 31 Average Stack Gas Temp., f a C
Average Static Pressure, P slatic kPa 0.1
Average Barometric Pressure, Pb hPa 1 UX7
Type of Pitot 5 Are Water Droplets Present ?
Average Pitot TubpCalibratiDn Coeff. Cp
Negative flow
Hlghly homogeneous flow streamlgas velecity
No
0.85
Ha
I Sample Port Sire 1 mm I
I Finat Pitot Leak Check 17 1.7
I OrtenLdbn of Duct I I Vertical
PKoI Tube Gp 0.998
Number of Lines Available 2 Number of Lines Used 3
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I I
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tK Append& IM Individual pammetersampling defafk and restrifs
TWe: Method:
Determination of Dioxfns andkrans
Avara Shannon Pharmaceutical Services Lid Dr.John Casey 16105l2018 UKAS1549 VE165 09:38-15:38 4.4 0.1
EN 2948-1 2006
Client: Log Sheet Complete by: Test Oafe: Laboratory Used: Sack Name Test Time Dry Volume of Alr Sampled Ernissian Limit Value
Reference Condittons
20.1 20.9
Measured Oxygen Reference Oxygen
Uncertainty Data
21 88.2 5.1 0. t
Deg C kPa m3 x
Temperature at Pump Pfessure at Pump Air Volume at Pump Humidity at Pumps
teak Check Results Resuit X Leak
cc/rnin
cdmin cdmln cclmin cdmin cdrnfn
bar or kPa
G d W I h
Before Blank After Blank Before Sample 1 Changing Pwts Affer Sample 1 Average Flow Rata Standard Maximum Back Pressure
0.12 U. 18 0.93 0.14 0, f4 15 0 5
0.11 7 2 0.9 0.9 0.9 1 2 5%
Standard Criteria ZO be Met Result Standard Requirement
Angle of Flow Negatfve Flow in the Stack Pitot PmsuE DWference Ratb of Flow Measurement
4 5 agrees None >5Pa <3:1
Pitat Tube Leak Check Result
Poslliue Pressute Negatlve Pressure
Pass Pass
Number of Parts 2 2
Straight length before sarnpk pohf Strabht fengih after sample point
YW Yes
5 Hydraulic Diameters > 5 HD from fan or bend f >2 from stack exit
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Industrial Emission8 Ucence.: POWO-02 Liwnce HoHw Avara Shannon Pharmweutlcal Serufces Ltd
Facility Lwation: Avara Shannon Pharmaceutical Servkes Ud R!N,Mu: 1
Sample CalcuIations 201OIT51EU I-TEF
Concentration 201 OIISIEU
ng.Nm" @ Ref 0 2
<0,000045 4l.000023 sO.000227 -=0.000045 -=0.000045 4.000045 a.QQUO45
~0.000011 ~0.000001 <0.000455 <0.000227 <o,oooa45 <0.000045 <0.000045 4.000007 ~ I O O O O ~
<a.ooooi 1
Uncertainty Amount 20101ffUEU I-TEQ
ng,Nmd 1 .OE-05 5.1 E-06 5.1 E-05 1 .QE-O5 1 . om5 1 .OE-05 1 . UE-05 2.6E-06 2.6E-08 2.3E47 1 . W O 4 LIE-05 1.0E-05 1 .OE-O5 4 .OE-O5 1.5E-Q6 7.7E07
n0 0*00020 O.QOOI0 O . O U 7 0 ~ 0.00020 0.00020 0.0002[1 0.000211 0.00005 0.00005 0.OQOOQ 0.00200 0.001 00 o.Do020 0.00020 0.00026 0.00003 13,00002
4.0020 <O.Q020 <o. 0020 c0.0020 ~O,D020 40.0020 40.0020 43.0050 <O.DOSO 4.0045 ~0.0UZO 40. ou20 4.0020 ~ . 0 0 2 0 4.9020 CO. OD30 ~Uo.f!l50
Total A ~ Q u ~ I ~ 40.0665 o.oo5a O.OOP30
Blank Calculations 200017WEG
I-TEF
Amount 2010fl51EU Conoentratian 3OIOlTSIEU I-
TEQ nglNma
I-TEQ
0.00035 O,OMl7Cl 0.00100 0.00045 0.00025 0.00025 0.00026.
0,00009 0,00002 0.00250 0.001[30 0.00020 0.00020 0.00020 0.00D05 0.00002
o.oonas
~0~000080 <0.000023 <0.000227 ~0.0001a2 4.000057 <O. OOOU57 ~0.000057 ammazo ~0.000020 ~o.oooao3 <0.000588 <0.000227 ~0.080045 <0.000045 ~0.000045 .=OO.OOOOIQ ~0.000005
Total Blank <O.OBTS O.OOP0 <:9.00169
Field Blank Status Method Blank Status
1.59 Pass
<lo% of ELV Pass I Fail
Yes I No 3lank < 10% of the Emkslon Umit Vatues Yes
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Document No.: tlClRTL4 1302181 201 8081 usit No: I Year: 2018 Qfkf?: Tzhn
Industrial Emissfdm Licence.: POO20-02 Lkence Holder: Avara Shannon PharmaceuticaI Services Ltd
Facility LacaUon: AVam Shannon PhaFmacellticaf SeMkes Lid Rev.No: 1
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CONCEPT L I F E SCIENCES b C l l V E 1 1 1 6 S C l P l l E t
Concept Life Sciences Certificate of Analysis
Report Number: 738796-1
Date of Report: 06-Jun-2018
Customer: Air Scienfific Unit 32 Degranville Court Dublin Road Trim Ca. Meath Ireland.
Customer Contact: Project Management
Customer Job Reference: UCIRTLI 160618 Date Job Received at Concept: 22-May-2018
Date Analysis Started: 25-May-2018 Date AnalysEs Completed: 06-Jun-2018
The results reported relate to samples received h the laboratory and may not be representative of a whde batch. Opinions and interpretations expressed herein are outside the scope of UKAS accreditation This report should not be reproduced except in full wtthaut the written approval of the laboratory Tests cavered by this certificate were conducted in awordance with Concept Life Sciences SOPS All results have been reviewed in acwrdanm with Section 25 ofthe Coneept Life Sciences, Analytical Services Quality Manual
1549
Report checked and authorised by : Mary Hughes Customer Service Manager
Issued by : Mary Hughes Customer Sewice Manager
Thts document has been ptirrted from it digitally signed master copy
Pagel of6
738796-1
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Summary Of Results
Composite (FIR, Trap, Wash)
Sampling Recoveries
PrQdUcf!d by Concept Life Sciences, Hadfldd House, Hadfleld Street, CDmbrQOk, Manchester, MI6 9FE
Thls document has been printed from a digHally signed master copy Page 2 of 6
738796-7
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Composite (Filt, Trap, Wash)
ample : Combined 755 Dio 4 165 DioW + 155 T W
Our Sample Reference : 738796 004 Data Sampled : 16-MAY-2QlB
Dioxins and Furans (BS EN 1948:06)
Technique : GClMS (Hi?)
Determinand
I TOWS :I 0.0 I 0.0060
Produced by Concepk Life Sclencm, Hadfield Mouse, Hadfield Street, Cornbmok, Manchester, M16 BFE
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Composite (Filt, Trap, Wash)
Totals :I 0.0
Customer Sample Reference : Combined 155 DioW B + 155 Trap B + 155 Dio Blank
Date Sampled : 16-MAY-2018 Our Sample Reference : 738796 008
0.00’10
BS EN 1948 specifies a list of information that should be available within reports. This is extensive, so in the interest of reports being concise the information is omitted. The EA are content with this being the case. Note that all the information Is recorded and can be made available on request.
Dioxin and Furan - Blanks (BS EN 1948:06)
Technique : GClMS (HR)
Delermlnand Lower Bound
Produced by Concept Llfe Sciences, Hadfield House, Hadfield Street, Cornbrook, Manchester, MI6 9FE
This document has been printed from a digitally signed master copy
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Composite (Filt, Trap, Wash)
Customer Sample Reference : Combined METHOD BLANK Our Sample Reference : 738796 012
BS EN 1948 specifies a list of information that should be available within reports. This is extensive, so in the interest of reports being concise the information is omitted. The EA are content with this being the case. Note that all the information is recorded and can be made available on request.
Dioxin and Furan - Method Blank (ES EN 1948:06)
Technique : GC/MS (HR)
Determinand Lower Bound
Totals !I 0.a I 0.0068
Produced by Concept Life Sciences, Hadfield House, HadReld Street, Cornbrook, Manchester, MI6 9FE
This document has been printed from a digitally signed master copy
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738796-1
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Index tu symbols wed in 738796-1
Anasisis UKAS t iwdi ted
Produced by Concept Life Sciences, Hadfield House. Hadfield Street, Cornbrook, Manchester, MI6 9FE
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7387981
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